DD154997A5 - Sauerstoffhaertbare mercaptoorganopolysiloxanmasse und ihre verwendung zur herstellung hoehermolekularer produkte - Google Patents

Sauerstoffhaertbare mercaptoorganopolysiloxanmasse und ihre verwendung zur herstellung hoehermolekularer produkte Download PDF

Info

Publication number: DD154997A5
Authority: DD; German Democratic Republic
Prior art keywords: weight; parts; mercapto; functional; oxygen
Prior art date: 1979-12-03

Application number

DD80225686A

Other languages

German (de)

English (en)

Inventor

Gary R Homan

Chi-Long Lee

Original Assignee

Dow Corning

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-12-03

Filing date

1980-12-03

Publication date

1982-05-05

1980-12-03 Application filed by Dow Corning filed Critical Dow Corning

1982-05-05 Publication of DD154997A5 publication Critical patent/DD154997A5/de

Links

238000004519 manufacturing process Methods 0.000 title description 3
239000000203 mixture Substances 0.000 claims abstract description 102
-1 siloxane units Chemical group 0.000 claims abstract description 90
150000001875 compounds Chemical class 0.000 claims abstract description 52
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 49
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 33
229910052760 oxygen Inorganic materials 0.000 claims abstract description 33
239000001301 oxygen Substances 0.000 claims abstract description 33
239000003054 catalyst Substances 0.000 claims abstract description 32
239000000945 filler Substances 0.000 claims abstract description 18
125000005375 organosiloxane group Chemical group 0.000 claims abstract description 17
229940087654 iron carbonyl Drugs 0.000 claims abstract description 14
ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims abstract description 13
229910000366 copper(II) sulfate Inorganic materials 0.000 claims abstract description 12
238000002156 mixing Methods 0.000 claims abstract description 8
230000003197 catalytic effect Effects 0.000 claims abstract description 7
230000007717 exclusion Effects 0.000 claims abstract description 3
238000000034 method Methods 0.000 claims description 20
238000002360 preparation method Methods 0.000 claims description 17
229910052742 iron Inorganic materials 0.000 claims description 13
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 11
125000000217 alkyl group Chemical group 0.000 claims description 10
125000004432 carbon atom Chemical group C* 0.000 claims description 8
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 6
230000008569 process Effects 0.000 claims description 6
LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 claims description 5
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 5
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 5
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 4
NBFCJULAAWWTBL-UHFFFAOYSA-N buta-1,3-diene;carbon monoxide;iron Chemical group [Fe].[O+]#[C-].[O+]#[C-].[O+]#[C-].C=CC=C NBFCJULAAWWTBL-UHFFFAOYSA-N 0.000 claims description 3
239000000377 silicon dioxide Substances 0.000 claims description 3
230000009471 action Effects 0.000 claims description 2
BPPVUXSMLBXYGG-UHFFFAOYSA-N 4-[3-(4,5-dihydro-1,2-oxazol-3-yl)-2-methyl-4-methylsulfonylbenzoyl]-2-methyl-1h-pyrazol-3-one Chemical compound CC1=C(C(=O)C=2C(N(C)NC=2)=O)C=CC(S(C)(=O)=O)=C1C1=NOCC1 BPPVUXSMLBXYGG-UHFFFAOYSA-N 0.000 claims 1
241001091551 Clio Species 0.000 claims 1
SVMGVNXXUVNGRK-UHFFFAOYSA-N oxomethylideneiron Chemical class O=C=[Fe] SVMGVNXXUVNGRK-UHFFFAOYSA-N 0.000 claims 1
229920001971 elastomer Polymers 0.000 abstract description 19
239000000806 elastomer Substances 0.000 abstract description 17
239000011347 resin Substances 0.000 abstract description 13
229920005989 resin Polymers 0.000 abstract description 13
239000011521 glass Substances 0.000 abstract description 4
239000004567 concrete Substances 0.000 abstract description 3
229910052751 metal Inorganic materials 0.000 abstract description 3
239000002184 metal Substances 0.000 abstract description 3
239000004615 ingredient Substances 0.000 abstract description 2
UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract description 2
NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 abstract description 2
238000007789 sealing Methods 0.000 abstract description 2
241000189705 Dunedin group Species 0.000 abstract 1
239000000047 product Substances 0.000 description 35
229920000642 polymer Polymers 0.000 description 20
239000000565 sealant Substances 0.000 description 20
238000009472 formulation Methods 0.000 description 18
125000003396 thiol group Chemical group [H]S* 0.000 description 18
125000004122 cyclic group Chemical group 0.000 description 16
235000013870 dimethyl polysiloxane Nutrition 0.000 description 14
229920000435 poly(dimethylsiloxane) Polymers 0.000 description 14
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
125000001424 substituent group Chemical group 0.000 description 12
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
239000000499 gel Substances 0.000 description 10
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 8
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 8
230000015572 biosynthetic process Effects 0.000 description 8
239000004205 dimethyl polysiloxane Substances 0.000 description 8
238000006116 polymerization reaction Methods 0.000 description 8
239000011541 reaction mixture Substances 0.000 description 7
239000000463 material Substances 0.000 description 6
ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 description 6
229910004298 SiO 2 Inorganic materials 0.000 description 5
238000006243 chemical reaction Methods 0.000 description 5
238000010438 heat treatment Methods 0.000 description 5
239000007788 liquid Substances 0.000 description 5
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
229910052757 nitrogen Inorganic materials 0.000 description 5
239000012763 reinforcing filler Substances 0.000 description 5
238000003756 stirring Methods 0.000 description 5
239000005909 Kieselgur Substances 0.000 description 4
229910000019 calcium carbonate Inorganic materials 0.000 description 4
238000004132 cross linking Methods 0.000 description 4
230000007246 mechanism Effects 0.000 description 4
150000002894 organic compounds Chemical class 0.000 description 4
230000000704 physical effect Effects 0.000 description 4
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
229910000030 sodium bicarbonate Inorganic materials 0.000 description 4
235000017557 sodium bicarbonate Nutrition 0.000 description 4
238000003860 storage Methods 0.000 description 4
IKYAJDOSWUATPI-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propane-1-thiol Chemical compound CO[Si](C)(OC)CCCS IKYAJDOSWUATPI-UHFFFAOYSA-N 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
230000002378 acidificating effect Effects 0.000 description 3
230000008901 benefit Effects 0.000 description 3
239000006227 byproduct Substances 0.000 description 3
239000000470 constituent Substances 0.000 description 3
229920001577 copolymer Polymers 0.000 description 3
KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical compound [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 3
239000011159 matrix material Substances 0.000 description 3
239000003566 sealing material Substances 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
GXTPHRPCCNSDTM-UHFFFAOYSA-N 3-silyloxysilylpropane-1-thiol Chemical compound [SiH3]O[SiH2]CCCS GXTPHRPCCNSDTM-UHFFFAOYSA-N 0.000 description 2
BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 2
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
125000003545 alkoxy group Chemical group 0.000 description 2
230000008859 change Effects 0.000 description 2
238000000576 coating method Methods 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
238000010276 construction Methods 0.000 description 2
JZCCFEFSEZPSOG-UHFFFAOYSA-L copper(II) sulfate pentahydrate Chemical compound O.O.O.O.O.[Cu+2].[O-]S([O-])(=O)=O JZCCFEFSEZPSOG-UHFFFAOYSA-L 0.000 description 2
MGNZXYYWBUKAII-UHFFFAOYSA-N cyclohexa-1,3-diene Chemical compound C1CC=CC=C1 MGNZXYYWBUKAII-UHFFFAOYSA-N 0.000 description 2
239000003085 diluting agent Substances 0.000 description 2
125000000524 functional group Chemical group 0.000 description 2
UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 description 2
230000006872 improvement Effects 0.000 description 2
239000002480 mineral oil Substances 0.000 description 2
235000010446 mineral oil Nutrition 0.000 description 2
150000002902 organometallic compounds Chemical class 0.000 description 2
229910052697 platinum Inorganic materials 0.000 description 2
229920001296 polysiloxane Polymers 0.000 description 2
IALUUOKJPBOFJL-UHFFFAOYSA-N potassium oxidosilane Chemical compound [K+].[SiH3][O-] IALUUOKJPBOFJL-UHFFFAOYSA-N 0.000 description 2
229910000077 silane Inorganic materials 0.000 description 2
150000004756 silanes Chemical class 0.000 description 2
SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
239000002904 solvent Substances 0.000 description 2
238000004448 titration Methods 0.000 description 2
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical class N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
GXQCGPVEDZFCGW-UHFFFAOYSA-N 2,3-dihydro-1h-pyrrolo[3,4-c]pyridine;dihydrochloride Chemical group Cl.Cl.N1=CC=C2CNCC2=C1 GXQCGPVEDZFCGW-UHFFFAOYSA-N 0.000 description 1
QURURPFUWRWGSN-UHFFFAOYSA-N 3-sulfanylpropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCS QURURPFUWRWGSN-UHFFFAOYSA-N 0.000 description 1
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
241000566146 Asio Species 0.000 description 1
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
229910017135 Fe—O Inorganic materials 0.000 description 1
235000010678 Paulownia tomentosa Nutrition 0.000 description 1
240000002834 Paulownia tomentosa Species 0.000 description 1
229920000297 Rayon Polymers 0.000 description 1
229910020175 SiOH Inorganic materials 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
JOBBTVPTPXRUBP-UHFFFAOYSA-N [3-(3-sulfanylpropanoyloxy)-2,2-bis(3-sulfanylpropanoyloxymethyl)propyl] 3-sulfanylpropanoate Chemical compound SCCC(=O)OCC(COC(=O)CCS)(COC(=O)CCS)COC(=O)CCS JOBBTVPTPXRUBP-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
239000003377 acid catalyst Substances 0.000 description 1
239000000654 additive Substances 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
238000013459 approach Methods 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
239000010425 asbestos Substances 0.000 description 1
RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
239000012965 benzophenone Substances 0.000 description 1
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
235000008429 bread Nutrition 0.000 description 1
125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000006229 carbon black Substances 0.000 description 1
150000001733 carboxylic acid esters Chemical class 0.000 description 1
239000000969 carrier Substances 0.000 description 1
239000003610 charcoal Substances 0.000 description 1
239000004927 clay Substances 0.000 description 1
229910052570 clay Inorganic materials 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
239000008199 coating composition Substances 0.000 description 1
238000004040 coloring Methods 0.000 description 1
238000013329 compounding Methods 0.000 description 1
239000012050 conventional carrier Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
UCJHMXXKIKBHQP-UHFFFAOYSA-N dichloro-(3-chloropropyl)-methylsilane Chemical compound C[Si](Cl)(Cl)CCCCl UCJHMXXKIKBHQP-UHFFFAOYSA-N 0.000 description 1
238000004821 distillation Methods 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000010894 electron beam technology Methods 0.000 description 1
238000005538 encapsulation Methods 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
239000012765 fibrous filler Substances 0.000 description 1
238000011049 filling Methods 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
229920001002 functional polymer Polymers 0.000 description 1
238000005227 gel permeation chromatography Methods 0.000 description 1
229920000578 graft copolymer Polymers 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
230000003301 hydrolyzing effect Effects 0.000 description 1
230000002209 hydrophobic effect Effects 0.000 description 1
NYMPGSQKHIOWIO-UHFFFAOYSA-N hydroxy(diphenyl)silicon Chemical class C=1C=CC=CC=1[Si](O)C1=CC=CC=C1 NYMPGSQKHIOWIO-UHFFFAOYSA-N 0.000 description 1
230000001771 impaired effect Effects 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
239000011630 iodine Substances 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
229920001684 low density polyethylene Polymers 0.000 description 1
239000004702 low-density polyethylene Substances 0.000 description 1
125000005358 mercaptoalkyl group Chemical group 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
229940094933 n-dodecane Drugs 0.000 description 1
HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
125000002524 organometallic group Chemical group 0.000 description 1
150000004686 pentahydrates Chemical class 0.000 description 1
230000035699 permeability Effects 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
239000000049 pigment Substances 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000011253 protective coating Substances 0.000 description 1
239000010453 quartz Substances 0.000 description 1
230000005855 radiation Effects 0.000 description 1
238000006479 redox reaction Methods 0.000 description 1
238000011160 research Methods 0.000 description 1
229910052895 riebeckite Inorganic materials 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
229910052990 silicon hydride Inorganic materials 0.000 description 1
229910001961 silver nitrate Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
KUNICNFETYAKKO-UHFFFAOYSA-N sulfuric acid;pentahydrate Chemical compound O.O.O.O.O.OS(O)(=O)=O KUNICNFETYAKKO-UHFFFAOYSA-N 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
238000005979 thermal decomposition reaction Methods 0.000 description 1
150000003573 thiols Chemical class 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1
238000009423 ventilation Methods 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
125000002348 vinylic group Chemical group 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/06—Preparatory processes
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Compositions Of Macromolecular Compounds (AREA)
Silicon Polymers (AREA)
Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

DD80225686A 1979-12-03 1980-12-03 Sauerstoffhaertbare mercaptoorganopolysiloxanmasse und ihre verwendung zur herstellung hoehermolekularer produkte DD154997A5 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US06/099,253 US4293676A (en)	1979-12-03	1979-12-03	Oxygen-curable mercaptoorganosiloxane compositions containing both redox and iron carbonyl compounds and method of forming higher molecular weight products therefrom

Publications (1)

Publication Number	Publication Date
DD154997A5 true DD154997A5 (de)	1982-05-05

Family

ID=22273924

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD80225686A DD154997A5 (de)	1979-12-03	1980-12-03	Sauerstoffhaertbare mercaptoorganopolysiloxanmasse und ihre verwendung zur herstellung hoehermolekularer produkte

Country Status (13)

Country	Link
US (1)	US4293676A (fr)
EP (1)	EP0041558B1 (fr)
JP (1)	JPS603427B2 (fr)
KR (1)	KR830004352A (fr)
BE (1)	BE886451A (fr)
BR (1)	BR8008956A (fr)
CA (1)	CA1154900A (fr)
DD (1)	DD154997A5 (fr)
DE (1)	DE3068478D1 (fr)
ES (1)	ES8303478A1 (fr)
IT (1)	IT1209285B (fr)
WO (1)	WO1981001562A1 (fr)
ZA (1)	ZA807488B (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4526954A (en) *	1983-12-28	1985-07-02	Union Carbide Corporation	Organosiloxane polymers and compositions containing same curable upon exposure to gaseous oxygen
JPS61128512A (ja) *	1984-11-28	1986-06-16	Toshiba Corp	半導体基板加工ラインにおける管理方式
US5008422A (en) *	1985-04-26	1991-04-16	Sri International	Polysilazanes and related compositions, processes and uses
JPS62106320A (ja) *	1985-11-05	1987-05-16	Kinmon Seisakusho:Kk	羽根車式流量計
GB8606634D0 (en) *	1986-03-18	1986-04-23	Dow Corning Ltd	Catalyst compositions
FR2654737B1 (fr) *	1989-11-21	1992-03-13	Rhone Poulenc Chimie	Composition organopolysiloxane a resine cyclopentenyle reticulable en un elastomere.
WO2014066684A1 (fr) *	2012-10-24	2014-05-01	Kci Licensing, Inc.	Compositions de polymère à fonctionnalité sulfhydryle pour dispositifs médicaux
EP4442779A4 (fr) *	2021-12-02	2025-04-02	LG Chem, Ltd.	Composition durcissable, film protecteur, élément optique et dispositif d'affichage à cristaux liquides

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3294760A (en) *	1962-11-21	1966-12-27	Gen Electric	Oxidative coupling of organic dithiols
US3445419A (en) *	1966-01-21	1969-05-20	Dow Corning	Room temperature vulcanizable silicones
US3991039A (en) *	1975-02-12	1976-11-09	Products Research & Chemical Corporation	One part curing compositions for mercaptan polymers
US4070329A (en) *	1977-01-03	1978-01-24	Dow Corning Corporation	Siloxane elastomer prepared from mercaptoorg anopolysiloxanes
US4070328A (en) *	1977-01-03	1978-01-24	Dow Corning Corporation	Mercaptoorganopolysiloxanes cured to elastomers with peroxides and nitrogen compounds
US4133939A (en) *	1977-12-16	1979-01-09	Dow Corning Corporation	Method for applying a silicone release coating and coated article therefrom

1979
- 1979-12-03 US US06/099,253 patent/US4293676A/en not_active Expired - Lifetime
1980
- 1980-11-19 JP JP56500343A patent/JPS603427B2/ja not_active Expired
- 1980-11-19 DE DE8181900163T patent/DE3068478D1/de not_active Expired
- 1980-11-19 BR BR8008956A patent/BR8008956A/pt unknown
- 1980-11-19 EP EP81900163A patent/EP0041558B1/fr not_active Expired
- 1980-11-19 WO PCT/US1980/001551 patent/WO1981001562A1/fr not_active Ceased
- 1980-11-20 CA CA000365086A patent/CA1154900A/fr not_active Expired
- 1980-12-01 ZA ZA00807488A patent/ZA807488B/xx unknown
- 1980-12-02 IT IT8026355A patent/IT1209285B/it active
- 1980-12-02 BE BE0/203009A patent/BE886451A/fr not_active IP Right Cessation
- 1980-12-02 ES ES497368A patent/ES8303478A1/es not_active Expired
- 1980-12-03 DD DD80225686A patent/DD154997A5/de unknown
- 1980-12-03 KR KR1019800004612A patent/KR830004352A/ko not_active Ceased

Also Published As

Publication number	Publication date
WO1981001562A1 (fr)	1981-06-11
IT8026355A0 (it)	1980-12-02
KR830004352A (ko)	1983-07-09
JPS603427B2 (ja)	1985-01-28
JPS56501610A (fr)	1981-11-05
EP0041558A1 (fr)	1981-12-16
BR8008956A (pt)	1981-10-20
CA1154900A (fr)	1983-10-04
EP0041558B1 (fr)	1984-07-04
DE3068478D1 (en)	1984-08-09
IT1209285B (it)	1989-07-16
US4293676A (en)	1981-10-06
BE886451A (fr)	1981-06-02
ES497368A0 (es)	1983-02-01
ES8303478A1 (es)	1983-02-01
ZA807488B (en)	1981-12-30
EP0041558A4 (fr)	1982-05-10

Publication	Publication Date	Title
DE68904637T2 (de)	1993-06-03	Silikon-dichtungsmaterialien mit verminderter farbe.
DE2809588C2 (de)	1982-12-23	Verwendung eines Gemischs aus einem Polysiloxan und einem Silan als Haftvermittler in einer Siliconelastomermasse
DE2350369C2 (de)	1982-12-30	Verfahren zum Herstellen von Diorganopolysiloxanen
DE2702046C3 (de)	1980-07-17	Verfahren zur Hefstellung von Polysiloxanelastomeren
DE2754702C3 (de)	1980-06-04	Verfahren zur Herstellung von PoIysiloxanelastomeren bei Raumtemperatur
DE2631957C3 (de)	1981-02-05	Verfahren zur Herstellung eines Copolymeren
DE2754703C3 (de)	1980-09-04	Verfahren zur Herstellung von Mercaptoorganopolysiloxanelastomeren
DE60307169T2 (de)	2007-07-05	Bei Raumtemperatur vernetzbare Organopolysiloxan-Zusammensetzungen
DE3850194T2 (de)	1995-01-05	Polyalkoxysilylalkylendisilazane und Silylamine.
DE2437954A1 (de)	1975-02-20	Aus zwei teilen bestehende, bei raumtemperatur vulkanisierbare systeme
DE2702057A1 (de)	1977-09-08	Zu einem siloxanelastomer haertbare masse
DE3852537T2 (de)	1995-05-18	Gefüllte Zusammensetzungen.
DD154993A5 (de)	1982-05-05	Sauerstoffhaertbare mercaptoorganosiloxanmasse und ihre verwendung zur herstellung hoehermolekularer produkte
DD154997A5 (de)	1982-05-05	Sauerstoffhaertbare mercaptoorganopolysiloxanmasse und ihre verwendung zur herstellung hoehermolekularer produkte
DE3028781C2 (de)	1985-08-14	Mercaptoorganosiloxanmasse und ihre Verwendung
DE2755283A1 (de)	1978-06-15	Silikonkautschuk-zusammensetzungen mit geringer wasserdampfdurchlaessigkeit
EP0333021A2 (fr)	1989-09-20	Composition d'organopolysiloxane transformable à température ambiante en élastomères susceptibles d'être peints
DE69003615T2 (de)	1994-03-31	Reaktionsprodukte als Haftklebezusätze für UV-härtbare Zusammensetzungen und diese enthaltende Zusammensetzungen.
DD154995A5 (de)	1982-05-05	Sauerstoffhaertbare mercaptoorganosiloxanmasse und ihre verwendung zur herstellung hoehermolekularer produkte
DD154991A5 (de)	1982-05-05	Mercaptoorganopolysiloxanmassen aus einem mercaptoorganopolysiloxan,einem aliphatisch ungesaettigten polydorganosiloxan und einem metallsalz einer carbonsaeure
EP1104780A1 (fr)	2001-06-06	Compositions de silicone réticulables
DE2906220A1 (de)	1979-09-13	Selbstbindende siliconkautschukmassen
DE4408660A1 (de)	1995-04-27	Mischungen mit selbstschmierenden Eigenschaften
DD154994A5 (de)	1982-05-05	Sauerstoffhaertbare masse auf basis mercaptofunktioneller organischer verbindungen und ihre verwendung zur herstellung hoehermolekularer produkte
DD155000A5 (de)	1982-05-05	Sauerstoffhaertbare masse auf basis mercaptofunktioneller organischer verbindungen und ihre verwendung zur herstellung hoehermolekularer produkte