EP0118793A2 - Photographisches Silberhalogenidmaterial - Google Patents

Photographisches Silberhalogenidmaterial Download PDF

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Publication number
EP0118793A2
EP0118793A2 EP84101537A EP84101537A EP0118793A2 EP 0118793 A2 EP0118793 A2 EP 0118793A2 EP 84101537 A EP84101537 A EP 84101537A EP 84101537 A EP84101537 A EP 84101537A EP 0118793 A2 EP0118793 A2 EP 0118793A2
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EP
European Patent Office
Prior art keywords
silver halide
photographic material
layer
halide photographic
particles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP84101537A
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English (en)
French (fr)
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EP0118793B1 (de
EP0118793A3 (en
Inventor
Minoru Ishikawa
Hideo Ohta
Yoshihide Urakawa
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Konica Minolta Inc
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Konica Minolta Inc
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Publication of EP0118793A2 publication Critical patent/EP0118793A2/de
Publication of EP0118793A3 publication Critical patent/EP0118793A3/en
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Publication of EP0118793B1 publication Critical patent/EP0118793B1/de
Expired legal-status Critical Current

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Classifications

    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
    • G03C1/95—Photosensitive materials characterised by the base or auxiliary layers rendered opaque or writable, e.g. with inert particulate additives
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/76—Photosensitive materials characterised by the base or auxiliary layers

Definitions

  • the present invention relates to a silver halide photographic material, and more particularly, to a silver halide photographic material having improved surface properties.
  • Silver halide photographic materials generally consist of a support having formed on one of its surfaces a certain number of photosensitive and non-sensitive layers superimposed in a certain order. At least one silver halide emulsion layer is present as the photosensitive layer, and the outermost layer consists of a nonsensitive hydrophilic colloidal layer containing as a binder a hydrophilic colloid typified by gelatin.
  • the contact or friction of the photographic materials between themselves or other objects will cause scratches or abrasions on the surface of the photographic materials or reduce their drivability within the camera or projector.
  • silver halides are sensitive not only to light but also to pressure, and any surface defects will cause pressure fog or desensitization which eventually leads to an irreparable damage to the photographic image obtained.
  • methods have been proposed for improving the physical properties of a silver halide photographic material by either increasing the resistance of a photographic layer to abrasion or reducing the sliding friction of the surface of the photographic material. These methods aim at making the photographic material adequately resistant to abrasions and improving its drivability in cameras or projectors.
  • a high-boiling organic solvent, solid paraffin or whale oil is dispersed in a hydrophilic colloid used in the outermost layer.
  • This method effectively attains the intended object.
  • the high-boiling organic solvent or other additives in the hydrophilic colloid come to the surface and increase the adhesiveness or stickiness of the photographic material. If such "bleeding" photographic materials come into contact with each other or with other objects, they easily stick to each other to cause “blocking”.
  • the stability of the organic solvent in a dispersion of the hydrophilic colloid depends on the viscosity of the dispersion or the concentration of a surface active agent, so it is difficult to prepare a stable colloidal dispersion.
  • U.S. Patent No. 3,121,060 shows the use of ester compounds for reducing the dynamic friction of silver halide photographic materials.
  • the ester compounds have poor dispersibility and the preparation of a homogeneous and stable dispersion of fine particles is difficult.
  • the dispersed particles easily aggregate to form clumps which are undesirable from a viewpoint of easy application of the dispersion when making the outermost layer.
  • ester compounds shown in Japanese Patent Application (OPI) No. 14163/76 are also effective in reducing the sliding friction, but they cause an undesired side effect in that a photosensitive film material containing them are devitrified upon development.
  • the primary object of the present invention is to provide a silver halide photographic material having its surface properties, particularly slip properties, improved without sacrificing other properties such as resistance to blocking and devitrification.
  • This object of the present invention can be accomplished by a silver halide photographic material having formed on one of its surfaces at least one silver halide emulsion layer and a non-sensitive hydrophilic colloidal layer forming the outermost layer, said non-sensitive hydrophilic colloidal layer containing substantially spherical fine organic particles having an average size of 1.5 to 2.5 microns and such a size distribution that the frequency of particles smaller than 4 microns is at least 95%.
  • the silver halide photographic material of the present invention is characterized by the following two aspects: 1) a non-sensitive hydrophilic colloidal layer is formed one surface of a support as the outermost layer; and 2) this non-sensitive hydrophilic colloidal layer has incorporated therein substantially spherical fine organic particles having an average size of 1.5 to 2.5 microns and such a size distribution that the frequency of particles smaller than 4 microns is at least 95% (such particles are hereunder simply referred to as the fine organic particles or grains of the present invention).
  • the fine particles are used primarily for the purpose of reducing the stickiness of the surface of the photographic material by matting or increasing the surface roughness. So, when a coating solution is prepared from a dispersion of the fine particles, it often occurs that aggregates form to make the formation of a uniform coating impossible. Furthermore, the aggregates reduce the slip properties of the photographic material and may cause other side effects such as impaired transparency and image quality.
  • the silver halide photographic material of the present invention is clearly distinguished from the prior art technique by the two features shown above.
  • the silver halide photographic material of the present invention has its surface properties, in particular slip properties, improved and is capable of effectively preventing the occurrence of scratches or abrasions that may lead to pressure fog or desensitization without sacrificing other desired properties such as transparency and resistance to blocking.
  • the fine organic particles of the present invention are either high-molecular weight compounds in a substantially spherical form that are synthesized by suspension polymerization or those which have been converted to a substantially spherical form by spray drying or other suitable methods.
  • These high-molecular weight compounds include polymethyl methacrylate, cellulose acetate propionate, polystyrene, benzoquanamine-formaldehyde condensate, as well as alkali-soluble foraminous polymers made of acrylic acid and methyl acrylate.
  • Illustrative monomers that can be synthesized to high-molecular weight compounds by suspension polymerization include styrene and styrene derivatives such as alkyl- styrenes (e.g.
  • o-methylstyrene m-methylstyrene, p - methylstyrene, p-ethylstyrene, 2,4-dimethylstyrene, p-butylstyrene, p-tertiary-butylstyrene, p-hexylstyrene, p-octylstyrene, p-nonylstyrene, p-decylstyrene and p-dodecylstyrene), alkoxystyrenes (e.g. p-methoxystyrene), arylstyrenes (e.g.
  • p-phenylstyrene and halogenated styrenes (e.g. p-chlorostyrene and 3,4-dichlorostyrene); olefins such as ethylene, propylene, butylene and isobutylene; vinyl halides such as vinyl chloride, vinylidene chloride, vinyl bromide and vinyl fluoride; vinyl esters such as vinyl acetate, vinyl propionate, vinyl benzoate and vinyl butyrate; acrylate esters such as methyl acrylate, ethyl acrylate, butyl acrylate, isobutyl acrylate, propyl acrylate, octyl acrylate, dodecyl acrylate, 2-ethylhexyl acrylate, phenyl acrylate and methyl a-chloroacrylate; methacrylate esters such as methyl methacrylate, ethyl methacrylate, propyl methacrylate,
  • the average size of the fine organic particles of the present invention is generally determined on the basis of a size distribution curve as obtained by size-frequency analysis of these grains. Specifically, the light transmission method depending on liquid sedimentation is used.
  • the size-frequency of the fine organic particles is generally determined on the basis of a size-frequency curve as also obtained by size-frequency analysis of these grains.
  • the size-frequency curve is also obtained by a known method of measurement of particle size in the fine particle art, but, specifically the light transmission method depending on the fine organic particles is used. The way of obtaining the size-frequency curve is described in detail in, for example, "A Method of Measurement of Particle Grain Size" compiled by the Society for Research in Particle Engineering, published by Yoken-Do (1965).
  • the size distribution such that the frequency of grains smaller than 4 microns is at least 95% means that the cumulative frequency of grains smaller than 4 microns is at least 95% in number of the whole grains present.
  • the organic fine grains have an average size of 1.5 to 2.5 microns. If their average size is less than 1.5 microns, the silver halide photographic material of the present invention is not given high blocking resistance. If their average size exceeds 2.5 microns, the resulting photographic material has an improved resistance to blocking but then its transparency and compatibility with writing instruments are impaired. According to the present invention, the organic fine grains are also required to have such a size distribution that the frequency of grains smaller than 4 microns is at least 95%, but it is particularly preferred that these grains are substantially free of coarse particles.
  • the fine organic grains are generally incorporated in the non-sensitive hydrophilic colloidal layer in an amount ranging from 10 to 500 mg, preferably 20 to 200 mg, per square meter of the final silver halide photographic material.
  • the silver halide photographic material of the present invention has formed on one surface of a support at least one silver halide emulsion layer and a non-sensitive hydrophilic colloidal layer forming the outermost layer. Aside from these requirements, there is no upper limit for the maximum number of the silver halide emulsion layers and the non-sensitive layers that may be included in the present invention. Furthermore, these photographic layers may be arranged in any order.
  • a typical example is a silver halide photographic material having formed on one surface of a support at least one unit of photosensitive silver halide emulsion layers having different degrees of photosensitivity to substantially the same color.
  • a multi-layer silver halide color photographic material generally consists of a support coated with a sequence of red-, green- and blue-sensitive layers, the red-sensitive layer being the closest to the support. This order may be reversed or modified in various ways. Units of photosensitive layers may optionally be interposed with nonsensitive hydrophilic colloidal layers such as filter layers or intermediate layers.
  • the photosensitive silver halide emulsion layers are typically arranged in such a manner that a layer having the highest sensitivity is disposed the farthest from the support and the sensitivity decreases gradually toward the support.
  • a nonsensitive hydrophilic colloidal layer may be disposed between each photosensitive silver- halide emulsion layer.
  • a non-sensitive hydrophilic colloidal layer is formed on one surface of a support as the outermost layer.
  • This is usually a non-sensitive surface protective layer and has incorporated therein a hydrophilic colloid as a binder.
  • the thickness of this non-sensitive hydrophilic colloidal layer generally ranges from 0.1 to 3 microns, perferably from 0.3 to 1 microns.
  • Gelatin is preferred as the hydrophilic colloid. Any of the gelatins that are conventionally used in the art may be used and they include lime-treated gelatin, acid-treated gelatin, enzyme- treated gelatin, as well as gelatin derivatives and modified gelatins.
  • gelatins may be replaced by proteins such as colloidal albumin and casein, cellulose compounds such as carboxymethyl cellulose and hydroxyethyl cellulose, polyvinyl alcohol, poly-N-vinyl pyrrolidone, polyacrylic acid copolymer, polyacrylamide, as well as derivatives or partial hydrolyzates thereof.
  • proteins such as colloidal albumin and casein
  • cellulose compounds such as carboxymethyl cellulose and hydroxyethyl cellulose, polyvinyl alcohol, poly-N-vinyl pyrrolidone, polyacrylic acid copolymer, polyacrylamide, as well as derivatives or partial hydrolyzates thereof.
  • colloids may be used in combination with themselves.
  • the fine organic grains according to the present invention may be incorporated in the non-sensitive hydrophilic colloidal layer in a conventional manner.
  • a solution containing gelatin and a surface active agent is mixed with the fine organic grains and the mixture is homogenized to form a uniform dispersion.
  • the non-sensitive hydrophilic colloidal layer according to the present invention may contain an organic fluorocompound in order to provide a further improved blocking resistance.
  • Suitable organic fluorocompounds include linear or cyclic compounds having at least three fluorine atoms and at least three carbon atoms, and any types of compounds, i.e. cationic, nonionic, anionic or betaine, may be used with advantage.
  • Particularly preferred compounds are anionic organic fluorine-containing surfactants.
  • the organic fluorocompound is used in an amount ranging from 0.1 to 500 mg, preferably from 1 to 200 mg, per square meter of the non-sensitive hydrophilic colloidal layer in which said compound is incorporated.
  • the non-sensitive hydrophilic colloidal layer forming the outermost layer in the present invention may further contain dispersed colloidal silver.
  • the layer may also contain substantially undeveloped, fine grains of silver halide as shown in U.S. Patents Nos. 3,050,391, 3,140,179 and 3,523,022.
  • the layer may further contain a lipophilic additive such as UV absorber.
  • the non-sensitive hydrophilic colloidal layer used in the present invention may be processed by any of the known hardeners, which include ketone compounds such as diacetyl and dichloropentanedione; compounds having a reactive halogen such as bis(2-chloroethylurea), 2-hydroxy-4,6-dichloro-l,3,5-triazine, and those shown in U.S. Patents Nos.3,635,718, 3,232,763, 2,732,316, 2,586,168, 3,103,437, 3,117,280, 2,983,611, 2,725,294, 2,725,295, 3,100,704, 3,091,537, 3,321,313 and 3,543,292, as well as British Patent No. 994,869.
  • ketone compounds such as diacetyl and dichloropentanedione
  • compounds having a reactive halogen such as bis(2-chloroethylurea), 2-hydroxy-4,6-dichloro-l,3,5-triazin
  • one or more surfactants may be employed for various purposes such as facilitating the coating application, emulsification, sensitization, improving the photographic characteristics, and preventing static buildup or blocking of photographic materials.
  • the surfactants that can be used in the present invention are classified into natural surfactants such as saponin; nonionic surfactants such as alkylene oxides, glycerins and glycidols; cationic surfactants such as higher alkylamines, quaternary ammonium salts, pyridine and other hetero compounds, phosphonium and sulfonium compounds; anionic surfactants containing acidic groups such as carboxylic acid, sulfonic acid, phosphoric acid, sulfate ester and phosphate ester groups; and amphoteric surfactants such as amino acids, aminosulfonic acids, and sulfate or phosphate esters of amino alcohols.
  • the silver halide photographic material of the present invention has at least one silver halide emulsion layer formed on a support. Any known techniques may be used for the silver halide emulsion layers, support and optional non-sensitive layers such as anti-halation layer, filter layer, intermediate layer, and subbing layer.
  • the silver halides that are incorporated in the silver halide emulsion layers of the photographic material of the present invention have silver halide grains dispersed in the hydrophilic colloid.
  • Suitable silver halides are silver bromide, silver chlorobromide, silver iodobromide and silver chloroiodobromide. These silver halides may be prepared by various methods such as the ammoniacal method, neutral method, acid method, as well as the conversion method and double-jet method described in British Patent No. 635,841 and U.S. Patent No. 3,622,318.
  • silver halide grains may be dispersed in hydrophilic colloids which are the same as those employed for forming the non-sensitive hydrophilic colloidal layer.
  • the silver halide emulsions shown above may be chemically sensitized by known techniques. They may be optionally subjected to spectral sensitization or supersensitization by cyanine dyes such as cyanine, merocyanine and carbocyanine used either alone or in combination with themselves or with styryl dyes.
  • Various compounds may be incorporated in the photographic emulsions in order to prevent a sensitivity drop or fog from occurring during the manufacture, storage or processing of the photographic material.
  • a great number of compounds are known and they include 4-hydroxy-6-methyl-l,3,3a,7-tetrazaindene, 3-methylbenzothiazole, l-phenyl-5-mercaptotetrazole, as well as many heterocyclic compounds, mercury containing compounds, mercapto compounds and metal salts.
  • the silver halide photographic material of the present invention is a multi-layer color photographic material capable of general color reproduction, it may use the following yellow, magenta and cyan couplers.
  • yellow couplers Conventionally, open-chain ketomethylene compounds are used as yellow couplers, and among them, benzoylacetanilide and pivaloylacetanilide types are extensively used. Two-equivalent type compounds may also be used wherein the carbon atom at a coupling site is substituted by a split-off group that can be eliminated upon coupling reaction. Typical yellow couplers are shown in U.S. Patents Nos.
  • Suitable magenta couplers include pyrazolone, pyrazolotriazole, pyrazolinobenzimidazole and indazolone compounds. Typical magenta couplers of pyrazolone type are shown in
  • Suitable cyan couplers are phenolic and naphtholic couplers. These cyan couplers are shown in, for example, U.S. Patents Nos. 2,423,730, 2,474,293, 2,801,171, 2,895,826, 3,476,563, 3,737,316, 3,758,308, 3,839,044, Japanese Patent Applications (OPI) Nos. 37425 /72, 10135/75, 25228/75, 112038/75, 117422/75 and 130441/75.
  • OPI Japanese Patent Applications
  • Colored magenta couplers and colored cyan couplers may also be used in the present invention with advantage.
  • "DIR" compounds may also be incorporated in the silver halide emulsion layers. The latter may further incorporate -any suitable photographic additives such as agents to prevent dye discoloration and stain.
  • Preferred examples of the support on which the non-sensitive hydrophilic colloidal layers, silver halide emulsion layers and other nonsensitive layers are formed include cellulose ester films such as nitrocellulose and acetyl cellulose; polyester films such as polyethylene terephthalate; polyvinyl acetal, polyvinyl chloride, polystyrene and polycarbonate films; baryta paper and polyethylene-coated paper.
  • the coating method for forming the nonsensitive hydrophilic colloidal layer, the silver halide emulsion layers and other photosensitive layers must be properly determined in order to ensure uniform quality and high process efficiency. Suitable coating methods are dip coating, double-roll coating, air knife coating, extrusion coating and curtain coating. The extrusion coating and curtain coating are particularly useful because either method permits the simultaneous formation of two or more layers.
  • the coating speed may be selected at any value, but for ensuring high process efficiency, a speed not lower than 30 m/min is preferred.
  • the hardener and other components which are so highly reactive that they form a gel if they remain long in the coating solution are preferably mixed in a static mixer with the coating solution just before the latter is applied to the support.
  • the photographic material of the present invention has many applications such as black-and-white photography, X -ray photography, printing, microphotography, recording with electron beams, IR recording and color photography.
  • the silver halide photographic material of the present invention is first exposed and subsequently developed by any of the known methods.
  • Preferred color developers for use in the present invention contain aromatic primary amine compounds as the olor developing agent.
  • Typical color developing agents are p-phenylenediamine compounds such as diethyl-p-phenylenediamine hydrochloride, monomethyl-p-phenylenediamine hydrochloride, dimethyl-p-phenylenediamine hydrochloride, 2-amino-5-diethylaminotoluene hydrochloride, 2-amino-5-(N-ethyl-N-dodecylamino)-toluene, 2-amino-5-(N-ethyl-N-B-methanesulfonamidoethyl)-aminotoluene sulfate, 4-(N-ethyl-N-B-methanesulfornamidoethylamino)
  • the developed silver and silver halide are removed by a sequence of conventional steps including bleaching, fixing (the two steps may be combined into a single step of bleach-fixing), rinsing and drying.
  • the silver halide photographic material of the present invention has its surface properties, especially slip properties, improved without sacrificing other desired properties such as transparency and blocking resistance. Therefore, scratches or abrasions due to contact or friction are less likely to occur on the surface of the photographic material in the course of its manufacture of service, and an image free from such defects as pressure fog and desensitization can be produced.
  • a blue-sensitive silver iodobromide emulsion (with 7 mol% of silver iodide) were prepared from a mixture of 300 g of gelatin, 2.5 x 10 -2 mol of a yellow coupler or ⁇ -pivaloyl- ⁇ -(1-benzyl-2,4-dioxy- imidazoline-3-yl-2-chloro-5- ⁇ -(2,4-tertamylphenoxy)-butylamido)acetanilide, and a hardener or 1,2-bis(vinylsulfonyl)ethane. The respective amounts are based on one mol of the silver halide. Twenty samples of a coating solution for the protective layer were also prepared from the formulation indicated below.
  • Coating aid sodium di-2-ethylhexylsulfosuccinate
  • Hardener 1,2-bis(vinylsulfonyl)ethane
  • the respective silver halide emulsions and coating solutions for the protective layer were applied to subbed triacetyl cellulose film bases simultaneously in a superimposed fashion by the slide hopper method at a coating speed of 50 m/min.
  • the silver halide emulsion layers overlied the protective layers.
  • the respective samples were tested for their slip properyies, blocking resistance and transparency by the methods indicated below.
  • test pieces (5 cm x 5 cm) cut from each sample were held at 23°C and 80% r.h. for 24 hours. Then, the two test pieces were superimposed so that the respective protective layers are in a face-to-face relationship. The superimposed test pieces were pressed at a load of 800 g and held in a hot and humid atmosphere (40°C x 80% r.h.) for 24 hours. Thereafter, the load was removed and the test pieces were peeled from each other. The blocking resistance of each sample was evaluated by the area where two test pieces adhered to each other. The indices of rating were as follows.
  • a set of unexposed samples No. 1 to No. 20 were processed according to the following schedule and dried.
  • the turbidities of the color images on the respective samples were measured with a nephelometer of Nippon Seimitsu Kogyo K.K.
  • the respective processing solutions had the following compositions.
  • sample Nos. 1 to 9 using the fine organic grains having the average size and size frequency defined in the present invention had significantly improved slip properties over comparative sample Nos. 10 to 20 without sacrificing the transparency, blocking resistance and sensitometric characteristics.
  • the fine organic grains remained uniformly dispersed without forming aggregates.
  • a subbed triacetyl cellulose film base was coated with the following layers, the first layer being the closest to the base.
  • Anti-halation layer containing black colloidal silver dry thickness: 1 u.
  • Red-sensitive silver iodobromide emulsion layer (dry thickness: 6 ⁇ , with 8 mol% silver bromide) containing, per mol of silver halide, 6.8 x 10 -2 mol of a cyan coupler or 1-hydroxy-N- ⁇ (-2,4-di-tertamylphenoxy)-butyl)-2-naphthamide, 1.7 x 10 -2 mol of a colored coupler or 1-hydroxy-N- ⁇ 6-(2,4-di-tert-amylphenoxy)-butyl)-4-(2-ethoxycarbonylphenylazo)-2-naphthamide, and 4 x 10 -3 mol of a DIR compound or 2-(1-phenyl-5-tetra- zolylthio)-4-(2,4-di-tertamylphenaxyacetamido)-1-indanone.
  • Green-sensitive (low sensitivity) silver iodobromide emulsion layer (dry thickness: 3.5 ⁇ , with 8 mol% silver iodide) containing, per mol of silver halide, 5.8 x 10 -2 mol of a magenta coupler or 1-(2,4,6-trichloro)-phenyl-3- ⁇ 3-(2,4-di-tert-amylphenoxy)acetamido ⁇ benzamido-5-pyrazolone, 1.7 x 10 -2 mol of a colored coupler or 1-(2,4,6-trichlorophenyl)-3- ⁇ 3-(octadecenylsuccinimido)-2-chloro ⁇ anilido-4-(y-naphthylazo)-5-pyrazolone and 7 x 10 -3 mol of a DIR compound or 2- (1-phenyl-5-tetra- zalylthio)-4-(2,4-di-terta
  • Green-sensitive (high sensitivity) silver iodobromide emulsion layer (dry thickness: 2.5 ⁇ , with 6 mol% silver iodide) containing, per mol of silver halide, -2 1.1 x 10 , 5 x 10 -3 and 2 x 10 mol, respectively, of a magenta coupler, colored coupler and DIR compound which were the same as those used in the third layer.
  • Gelatin layer (dry thickness: 1 ⁇ ) containing yellow colloidal silver and 2,5-di-tert-octylhydroquinone.
  • Blue-sensitive silver iodobromide emulsion layer (dry thickness: 6 ⁇ , with 7 mol% silver iodide) containing, per mol of silver halide, 350 g of gelatin, 3 x 10 mol of a yellow coupler or a-pivaloyl-a-(1-benzyl-2-phenyl-3,5-dioxotriazolidine-4-y1)-5'- ⁇ -(2,4-di-tert-amylphenoxy)butylamido ⁇ -2'-chloroacetanilide and a hardener or 1,2-bis(vinylsulfonyl)ethane.
  • protective layers having the basic formulation indicated below were formed so as to provide sample Nos. 21 to 25 of silver halide color photographic material.
  • Coating aid sodium di-2-ethylhexylsulfosuccinate
  • UV absorber dispersion of Tinuvin PS 320 and 326
  • Example 2 The respective samples were dried and tested for their slip properties, blocking resistance and transparency as in Example 1. Thereafter, the samples were exposed to white light in a sensitometer (Model KS-1 of Konishiroku Photo Industry Co., Ltd.), processed with the same solutions as used in Example 1, and subsequently evaluated for their sensitometric characteristics sensitivity and fog). The results of the tests and sensitometric analysis are shown in Table 2. The sensitivity and fog having the same meanings as in Example 1 were measured for the three different dyes, blue (B), green (G) and red (R).
  • sample Nos. 21 to 23 of the present invention had high blocking resistance and transparency and yet exhibited better slip properties than comparative sample Nos. 24 and 25.
  • the improvement in the slip properties of the samples of the present invention was more marked in a humid atmosphere than in a relatively dry atmosphere. No adverse effects on the photographic characteristics accompanied the improvement in the slip properties.
  • the improved slip properties were not lost even after the photographic materials of the present invention were subjected to photographic processing. In both the unprocessed and processed films, the fine organic grains according to the present invention were uniformly dispersed and formed no visible aggregates.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Silver Salt Photography Or Processing Solution Therefor (AREA)
EP19840101537 1983-02-15 1984-02-15 Photographisches Silberhalogenidmaterial Expired EP0118793B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP23610/83 1983-02-15
JP2361083A JPS59149357A (ja) 1983-02-15 1983-02-15 ハロゲン化銀写真感光材料

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EP0118793A2 true EP0118793A2 (de) 1984-09-19
EP0118793A3 EP0118793A3 (en) 1987-04-01
EP0118793B1 EP0118793B1 (de) 1989-08-02

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DE (1) DE3479246D1 (de)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0267019A3 (en) * 1986-11-04 1989-07-19 Konica Corporation Silver halide photographic light-sensitive material capable of super-rapid processing
EP0289023A3 (de) * 1987-05-01 1990-08-29 Konica Corporation Lichtempfindliches photographisches Silberhalogenidmaterial
US5441860A (en) * 1993-03-30 1995-08-15 Minnesota Mining And Manufacturing Company Silver halide photographic material having improved antistatic properties
EP0675401A1 (de) * 1994-03-31 1995-10-04 Eastman Kodak Company Bildelement
EP0767402A3 (de) * 1995-09-25 1998-01-07 Eastman Kodak Company Photographisches Produkt bestehend aus einem verarbeiteten, photographischen Element in einer Kassette

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Publication number Priority date Publication date Assignee Title
JPH0619509B2 (ja) * 1984-09-05 1994-03-16 コニカ株式会社 ハロゲン化銀写真感光材料
JPS6175338A (ja) * 1984-09-21 1986-04-17 Fuji Photo Film Co Ltd 銀塩拡散転写法用感光材料
JPS63104047A (ja) * 1986-10-22 1988-05-09 Fuji Photo Film Co Ltd ハロゲン化銀写真感光材料及びそれを用いた画像形成法
JP5130625B2 (ja) 2005-12-26 2013-01-30 ブラザー工業株式会社 画像形成装置

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GB1293189A (en) * 1970-06-04 1972-10-18 Agfa Gevaert Photographic silver halide element
JPS5623142B2 (de) * 1974-07-01 1981-05-29
JPS523653A (en) * 1975-06-27 1977-01-12 Fuji Photo Film Co Ltd Process for producing fine polymer particles
DE2919822A1 (de) * 1979-05-16 1980-11-27 Agfa Gevaert Ag Verfahren zur herstellung von mattierungsschichten
JPS5655939A (en) * 1979-10-15 1981-05-16 Fuji Photo Film Co Ltd Silver halide photographic material
JPS56109336A (en) * 1980-02-01 1981-08-29 Konishiroku Photo Ind Co Ltd Silver halide photographic sensitive material

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0267019A3 (en) * 1986-11-04 1989-07-19 Konica Corporation Silver halide photographic light-sensitive material capable of super-rapid processing
EP0289023A3 (de) * 1987-05-01 1990-08-29 Konica Corporation Lichtempfindliches photographisches Silberhalogenidmaterial
US5441860A (en) * 1993-03-30 1995-08-15 Minnesota Mining And Manufacturing Company Silver halide photographic material having improved antistatic properties
EP0675401A1 (de) * 1994-03-31 1995-10-04 Eastman Kodak Company Bildelement
EP0767402A3 (de) * 1995-09-25 1998-01-07 Eastman Kodak Company Photographisches Produkt bestehend aus einem verarbeiteten, photographischen Element in einer Kassette

Also Published As

Publication number Publication date
JPS59149357A (ja) 1984-08-27
EP0118793B1 (de) 1989-08-02
EP0118793A3 (en) 1987-04-01
DE3479246D1 (en) 1989-09-07

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