ES2108339T3 - Catalizadores soportados para la polimerizacion de olefinas. - Google Patents

Catalizadores soportados para la polimerizacion de olefinas.

Info

Publication number
ES2108339T3
ES2108339T3 ES94110168T ES94110168T ES2108339T3 ES 2108339 T3 ES2108339 T3 ES 2108339T3 ES 94110168 T ES94110168 T ES 94110168T ES 94110168 T ES94110168 T ES 94110168T ES 2108339 T3 ES2108339 T3 ES 2108339T3
Authority
ES
Spain
Prior art keywords
supported catalysts
polymerization
olefins
groups
organic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94110168T
Other languages
English (en)
Other versions
ES2108339T5 (es
Inventor
Enrico Albizzati
Luigi Resconi
Occo Tiziano Dall
Fabrizio Piemontesi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Technology Co BV
Original Assignee
Montell Technology Co BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=11366547&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2108339(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Montell Technology Co BV filed Critical Montell Technology Co BV
Application granted granted Critical
Publication of ES2108339T3 publication Critical patent/ES2108339T3/es
Publication of ES2108339T5 publication Critical patent/ES2108339T5/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

SE PRESENTAN CATALIZADORES SOPORTADOS PARA LA POLIMERIZACION DE OLEFINAS QUE COMPRENDE LOS SIGUIENTES COMPONENTES: A) UN SOPORTE ORGANICO POROSO FUNCIONALIZADO CON GRUPOS QUE TENGAN ATOMOS DE HIDROGENO ACTIVO; B) UN COMPUESTO ORGANO-METALICO DE ALUMINIO QUE CONTENGAN HETEROATOMOS SELECCIONADOS ENTRE OXIGENO, NITROGENO Y AZUFRE; Y C) UN COMPUESTO DE UN METAL DE TRANSICION SELECCIONADO ENTRE LOS GRUPOS IVB,VB O VIB DE LA TABLA PERIODICA DE ELEMENTOS, QUE CONTENGA LIGANTES DEL TIPO DEL CICLOPENTADIENIL. ESTOS CATALIZADORES SOPORTADOS, OBTENIBLES EN FORMA DE PARTICULAS ESFERICAS, PUEDEN UTILIZARSE EN LA POLIMERIZACION DE OLEFINAS TANTO DE FASE LIQUIDA COMO GASEOSA, PRODUCIENDO DE ESTA FORMA POLIMEROS DOTADOS DE UNA MORFOLOGIA CONTROLADA Y CON UNA ALTA DENSIDAD EN BRUTO.
ES94110168T 1993-07-07 1994-06-30 Catalizadores soportados para la polimerizacion de olefinas. Expired - Lifetime ES2108339T5 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI931467 1993-07-07
IT93MI001467A IT1264680B1 (it) 1993-07-07 1993-07-07 Catalizzatori supportati per la polimerizzazione delle olefine

Publications (2)

Publication Number Publication Date
ES2108339T3 true ES2108339T3 (es) 1997-12-16
ES2108339T5 ES2108339T5 (es) 2005-07-16

Family

ID=11366547

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94110168T Expired - Lifetime ES2108339T5 (es) 1993-07-07 1994-06-30 Catalizadores soportados para la polimerizacion de olefinas.

Country Status (17)

Country Link
US (3) US6423660B1 (es)
EP (1) EP0633272B2 (es)
JP (1) JP3573494B2 (es)
KR (1) KR100335805B1 (es)
CN (1) CN1033860C (es)
AT (1) ATE158309T1 (es)
AU (1) AU675711B2 (es)
BR (1) BR9402237A (es)
CA (1) CA2127601A1 (es)
DE (1) DE69405658T3 (es)
DK (1) DK0633272T3 (es)
ES (1) ES2108339T5 (es)
FI (1) FI111080B (es)
IL (1) IL110219A (es)
IT (1) IT1264680B1 (es)
MY (1) MY110923A (es)
RU (1) RU2116316C1 (es)

Families Citing this family (105)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1271406B (it) * 1993-09-13 1997-05-28 Spherilene Srl Procedimento per la preparazione di polimeri dell'etilene e prodotti ottenuti
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IT1273661B (it) * 1994-07-20 1997-07-09 Spherilene Srl Catalizzatori per la polimerizzazione delle olefine
IT1273662B (it) 1994-07-20 1997-07-09 Spherilene Srl Procedimento per la preparazione di polimeri amorfi del propiline'
US6143686A (en) * 1994-08-03 2000-11-07 Exxon Chemical Patents, Inc. Supported ionic catalyst compositions
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CA2181413A1 (en) * 1995-07-18 1998-01-18 Edwar S. Shamshoum Process for the syndiotactic propagation of olefins
US6211109B1 (en) * 1995-07-18 2001-04-03 Fina Technology, Inc. Process for treating silica with alumoxane
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US6150483A (en) * 1995-08-21 2000-11-21 Dsm N.V. Catalyst system for the preparation of a rubbery copolymer
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EP0839834B1 (en) 1996-10-30 2001-06-13 Repsol Quimica S.A. Catalyst systems for the polymerization and copolymerization of alpha-olefins
ES2210479T3 (es) * 1996-10-30 2004-07-01 Repsol Quimica S.A. Sistemas cataliticos para polimerizar y copolimerizar alfa-olefinas.
DE69703728T2 (de) 1996-10-31 2001-06-28 Repsol Quimica S.A., Madrid Katalysatorsysteme für die Polymerisation und Copolymerisation von Alpha-Olefinen
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US20030134993A1 (en) 2003-07-17
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EP0633272B1 (en) 1997-09-17
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ES2108339T5 (es) 2005-07-16
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US6774194B2 (en) 2004-08-10
DE69405658T2 (de) 1998-02-12
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US6423660B1 (en) 2002-07-23
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CA2127601A1 (en) 1995-01-08
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