ES2173560T3 - Compuesto catalitico que comprende magnesio, titanio, un halogeno y undonador de electrones, su preparacion y su utilizacion. - Google Patents
Compuesto catalitico que comprende magnesio, titanio, un halogeno y undonador de electrones, su preparacion y su utilizacion.Info
- Publication number
- ES2173560T3 ES2173560T3 ES98660147T ES98660147T ES2173560T3 ES 2173560 T3 ES2173560 T3 ES 2173560T3 ES 98660147 T ES98660147 T ES 98660147T ES 98660147 T ES98660147 T ES 98660147T ES 2173560 T3 ES2173560 T3 ES 2173560T3
- Authority
- ES
- Spain
- Prior art keywords
- magnesium
- titanium
- halogen
- compound
- intermediate product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title abstract 9
- 229910052749 magnesium Inorganic materials 0.000 title abstract 9
- 239000011777 magnesium Substances 0.000 title abstract 9
- 229910052719 titanium Inorganic materials 0.000 title abstract 6
- 239000010936 titanium Substances 0.000 title abstract 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title abstract 5
- 229910052736 halogen Inorganic materials 0.000 title abstract 4
- 150000002367 halogens Chemical class 0.000 title abstract 4
- 150000001875 compounds Chemical class 0.000 title abstract 3
- 230000003197 catalytic effect Effects 0.000 title 1
- 239000013067 intermediate product Substances 0.000 abstract 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- 239000002131 composite material Substances 0.000 abstract 2
- 150000002366 halogen compounds Chemical class 0.000 abstract 2
- 150000002681 magnesium compounds Chemical class 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- -1 TITANIUM HALIDE Chemical class 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 239000002685 polymerization catalyst Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/003—Compounds containing elements of Groups 2 or 12 of the Periodic Table without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/902—Monomer polymerized in bulk in presence of transition metal containing catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
LA INVENCION SE REFIERE A UN NUEVO PROCEDIMIENTO PARA LA PREPARACION DE UN COMPONENTE CATALIZADOR DE POLIMERIZACION DE OLEFINAS QUE CONTIENE MAGNESIO, TITANIO, UN HALOGENO Y UN DONADOR DE ELECTRONES. EL PROCEDIMIENTO CONSISTE EN LOS PASOS SIGUIENTES: (I) SE HACE REACCIONAR UN COMPUESTO DE MAGNESIO SIN TITANIO (A) QUE CONTENGA UNA FRACCION ALCOXI, SELECCIONANDOSE EL COMPUESTO DE MAGNESIO SIN TITANIO DEL GRUPO QUE CONSISTE EN UN COMPUESTO O COMPLEJO QUE CONTIENE HALOGENO Y ALCOXI ENLAZADO A MAGNESIO, UN COMPLEJO QUE CONTIENE UN DIHALURO DE MAGNESIO Y UN ALCOHOL, Y UN DIALCOXIDO DE MAGNESIO NO COMPLEJO, CON UN COMPUESTO DE HALOGENO (B) CAPAZ DE FORMAR EL DONADOR DE ELECTRONES AL SUSTITUIR SU HALOGENO POR DICHA FRACCION ALCOXI, PARA OBTENER UN PRODUCTO INTERMEDIO (AB), Y (II) HACER REACCIONAR DICHO PRODUCTO INTERMEDIO (AB) CON UN HALURO DE TITANIO (C), O (I)'' HACER REACCIONAR UN COMPUESTO DE MAGNESIO SIN TITANIO (A) QUE CONTENGA UNA FRACCION ALCOXI, SELECCIONANDOSE EL COMPUESTO DE MAGNESIO SINTITANIO DEL GRUPO QUE CONSISTE EN UN COMPUESTO O COMPLEJO QUE CONTIENE HALOGENO Y ALCOXI ENLAZADO A MAGNESIO, Y UN COMPLEJO QUE CONTIENE UN DIHALURO DE MAGNESIO Y UN ALCOHOL, CON UN HALURO DE TITANIO (C) PARA OBTENER UN PRODUCTO INTERMEDIO (AC), Y (II)'' HACER REACCIONAR DICHO PRODUCTO INTERMEDIO (AC) CON UN COMPUESTO DE HALOGENO (B) CAPAZ DE FORMAR EL DONADOR DE ELECTRONES AL SUSTITUIR SU HALOGENO POR DICHA FRACCION ALCOXI.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI974622A FI974622A7 (fi) | 1997-12-23 | 1997-12-23 | Katalysaattorikomponentti, joka käsittää magnesiumia, titaania, halogeenia ja elektronidonoria, sen valmistus ja käyttö |
| FI974621A FI106798B (fi) | 1997-12-23 | 1997-12-23 | Uusi kompleksituote, joka sisältää magnesiumia, halogeenia ja alkoksia, sen valmistus ja käyttö |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2173560T3 true ES2173560T3 (es) | 2002-10-16 |
Family
ID=26160493
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES98962442T Expired - Lifetime ES2195431T3 (es) | 1997-12-23 | 1998-12-21 | Producto que contiene magnesio, halogeno y alcoxido. |
| ES98660147T Expired - Lifetime ES2173560T3 (es) | 1997-12-23 | 1998-12-21 | Compuesto catalitico que comprende magnesio, titanio, un halogeno y undonador de electrones, su preparacion y su utilizacion. |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES98962442T Expired - Lifetime ES2195431T3 (es) | 1997-12-23 | 1998-12-21 | Producto que contiene magnesio, halogeno y alcoxido. |
Country Status (17)
| Country | Link |
|---|---|
| US (2) | US6365540B1 (es) |
| EP (2) | EP0926165B1 (es) |
| JP (1) | JP2001527136A (es) |
| KR (1) | KR100625300B1 (es) |
| CN (1) | CN1255436C (es) |
| AR (1) | AR013018A1 (es) |
| AT (2) | ATE234310T1 (es) |
| AU (2) | AU748975B2 (es) |
| BR (1) | BR9814322A (es) |
| CA (1) | CA2315214A1 (es) |
| DE (2) | DE69812172T2 (es) |
| EA (1) | EA004063B1 (es) |
| ES (2) | ES2195431T3 (es) |
| MY (1) | MY123970A (es) |
| TW (1) | TWI230713B (es) |
| WO (2) | WO1999033883A1 (es) |
| ZA (1) | ZA9811793B (es) |
Families Citing this family (128)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE235497T1 (de) * | 1997-12-23 | 2003-04-15 | Borealis Tech Oy | Löslicher magnesiumhalogenidkomplex, herstellung und verwendung |
| FI981718L (fi) * | 1998-08-07 | 2000-02-08 | Borealis As | Katalysaattorikomponentti, joka käsittää magnesiumia, titaania, halogeenia ja elektrodonorin, sen valmistus ja käyttö |
| FI981717L (fi) | 1998-08-07 | 2000-02-08 | Borealis As | Katalysaattorikomponentti, joka käsittää magnesiumia, titaania, halogeenia ja elektronidonorin, sen valmistus ja käyttö |
| FI991069A0 (fi) * | 1999-05-10 | 1999-05-10 | Borealis As | Katalysaattorikomponentti, joka käsittää magnesiumia, titaania, halogeenia ja elektronidonorin, sen valmistus ja käyttö |
| US20030022786A1 (en) * | 2001-05-03 | 2003-01-30 | Epstein Ronald A. | Catalyst for propylene polymerization |
| ES2266053T3 (es) | 2001-06-20 | 2007-03-01 | Borealis Technology Oy | Preparacion de un componente de catalizador para la polimerizacion de olefina. |
| JP4170667B2 (ja) * | 2002-05-24 | 2008-10-22 | 出光興産株式会社 | マグネシウム化合物、オレフィン重合用固体触媒成分、オレフィン重合用触媒及びポリオレフィンの製造方法 |
| EP1375528A1 (en) | 2002-06-18 | 2004-01-02 | Borealis Polymers Oy | Method for the preparation of olefin polymerisation catalysts |
| DE10236647A1 (de) * | 2002-08-09 | 2004-02-19 | Basell Polyolefine Gmbh | Modifizierter Ziegler Katalysator, Verfahren zu seiner Herstellung und Verfahren zum Herstellen eines Poly-1-olefins in seiner Gegenwart |
| DE60306397T2 (de) * | 2002-08-09 | 2007-08-23 | Basell Polyolefine Gmbh | Modifizierter ziegler-katalysator, herstellungsverfahren dafür und verfahren zur herstellung von poly-1-olefinen in seiner gegenwart |
| EP1403292B1 (en) * | 2002-09-30 | 2016-04-13 | Borealis Polymers Oy | Process for preparing an olefin polymerisation catalyst component with improved high temperature activity |
| WO2006051061A1 (en) * | 2004-11-11 | 2006-05-18 | Basell Poliolefine Italia S.R.L. | Preparation of tio2 powders from a waste liquid containing titanium compounds |
| CN100417670C (zh) * | 2006-03-07 | 2008-09-10 | 中国石油化工股份有限公司 | 一种烯烃聚合催化剂及其制备方法和应用 |
| EP2845868A1 (en) | 2006-05-31 | 2015-03-11 | Borealis Technology Oy | Oxidation state of Ti as means for increasing catalyst activity |
| KR20090034350A (ko) * | 2006-06-23 | 2009-04-07 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 마그네슘 클로로알콜레이트계 촉매 전구체 |
| ES2393382T3 (es) | 2008-06-26 | 2012-12-20 | Borealis Ag | Preparación de catalizador usando H2 |
| EP2174962B1 (en) | 2008-10-08 | 2011-11-30 | Borealis AG | A method to produce very stiff polypropylene |
| EP2174965B1 (en) | 2008-10-08 | 2013-05-29 | Borealis AG | Preparation of propylene copolymer with dynamically operated reactor |
| ES2393976T3 (es) | 2008-12-03 | 2013-01-03 | Süd-Chemie Ip Gmbh & Co. Kg | Composición donadora de electrones para un catalizador sólido, composición para catalizadores sólidos utilizada en la polimerización de alfa-olefinas, y proceso para la producción de un polímero consistente en unidades de alfa-olefinas que utilizan la composición para catalizadores sólidos. |
| WO2010076231A1 (en) | 2008-12-29 | 2010-07-08 | Borealis Ag | Cable layer of modified soft polypropylene with improved stress whitening resistance |
| JP5770103B2 (ja) * | 2008-12-31 | 2015-08-26 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | ランダムプロピレンコポリマー組成物、製品及び方法 |
| CN102325808B (zh) | 2008-12-31 | 2014-03-12 | 陶氏环球技术有限责任公司 | 包含取代的1,2-亚苯基芳族二酯内给体的前催化剂组合物及方法 |
| EP2216347A1 (en) | 2009-01-30 | 2010-08-11 | Borealis AG | A method of catalyst transitions in olefin polymerizations |
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| EP2417195B1 (en) | 2009-04-09 | 2013-03-20 | Borealis AG | Thermoplastic polyolefin composition |
| SA3686B1 (ar) | 2009-10-16 | 2014-10-22 | China Petroleum& Chemical Corp | مكون حفاز لبلمرة الأولفين وحفاز يشتمل عليه |
| EP2330135B1 (en) | 2009-12-02 | 2012-11-07 | Borealis AG | Process for producing polyolefins |
| KR101126946B1 (ko) * | 2009-12-28 | 2012-03-20 | 호남석유화학 주식회사 | 폴리올레핀 중합용 촉매 및 이의 제조방법 |
| KR101126918B1 (ko) * | 2009-12-28 | 2012-03-20 | 호남석유화학 주식회사 | 폴리올레핀 중합용 촉매의 제조방법, 이에 따른 촉매 및 이를 이용한 폴리올레핀의 제조방법 |
| EP2415790B1 (en) | 2010-07-13 | 2014-09-24 | Borealis AG | Catalyst component |
| ES2541701T3 (es) | 2010-07-13 | 2015-07-23 | Borealis Ag | Componente de catalizador |
| EP2452957A1 (en) | 2010-11-12 | 2012-05-16 | Borealis AG | Improved process for producing heterophasic propylene copolymers |
| EP2452956A1 (en) | 2010-11-12 | 2012-05-16 | Borealis AG | Improved process for polymerising propylene |
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| EP2452960B1 (en) | 2010-11-12 | 2015-01-07 | Borealis AG | Process for preparing propylene polymers with an ultra high melt flow rate |
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| EP2617741B1 (en) | 2012-01-18 | 2016-01-13 | Borealis AG | Process for polymerizing olefin polymers in the presence of a catalyst system and a method of controlling the process |
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| EP2886600B1 (en) | 2013-12-19 | 2018-05-30 | Abu Dhabi Polymers Co. Ltd (Borouge) LLC. | Multimodal polypropylene with respect to comonomer content |
| RU2654698C2 (ru) | 2013-12-24 | 2018-05-22 | Абу Даби Полимерс Ко. Лтд (Боруж) Ллс | Каучуковая композиция с превосходной ударной прочностью при низкой температуре |
| EP3094660B1 (en) | 2014-01-17 | 2018-12-19 | Borealis AG | Process for preparing propylene/1-butene copolymers |
| PL3102634T3 (pl) | 2014-02-06 | 2020-11-16 | Borealis Ag | Miękkie i przezroczyste kopolimery odporne na uderzenia |
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| KR102293704B1 (ko) * | 2014-04-24 | 2021-08-24 | 차이나 페트로리움 앤드 케미컬 코포레이션 | 올레핀 중합용 촉매 성분 및 이의 촉매 |
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| GB1603724A (en) * | 1977-05-25 | 1981-11-25 | Montedison Spa | Components and catalysts for the polymerisation of alpha-olefins |
| JPS5610504A (en) * | 1979-07-05 | 1981-02-03 | Idemitsu Kosan Co Ltd | Production of titanium catalyst component for olefin polymerization |
| US4451688A (en) * | 1981-12-03 | 1984-05-29 | Nippon Oil Company, Limited | Process for preparing polyolefins |
| JPH0655780B2 (ja) | 1984-07-09 | 1994-07-27 | 東燃株式会社 | オレフイン重合用触媒成分 |
| JPH072775B2 (ja) * | 1985-01-28 | 1995-01-18 | 東燃株式会社 | オレフイン重合用触媒成分の製造法 |
| FR2578847A1 (fr) | 1985-03-13 | 1986-09-19 | Centre Nat Rech Scient | Sonde adn destinee au diagnostic antenatal de certaines anomalies chromosomiques |
| CN1006071B (zh) * | 1985-04-01 | 1989-12-13 | 中国石油化工总公司 | 用于烯烃聚合和共聚合的催化剂体系 |
| US4727051A (en) | 1986-12-15 | 1988-02-23 | Stauffer Chemical Company | Production of halide-and alkoxy-containing magnesium compositions |
| DE3711919A1 (de) | 1987-04-08 | 1988-10-27 | Basf Ag | Verfahren zum herstellen von homo- und copolymerisaten des propens mittels eines ziegler-natta-katalysatorsystems |
| EP0297076A3 (en) | 1987-06-25 | 1990-01-24 | Lithium Corporation Of America | Hydrocarbon soluble and insoluble organo magnesium chloride complexes, processes and uses |
| WO1991005608A1 (en) | 1989-10-16 | 1991-05-02 | Akzo N.V. | Process of making halide/alkoxy-containing magnesium complex |
| JP2958923B2 (ja) * | 1990-04-27 | 1999-10-06 | 東邦チタニウム株式会社 | オレフィン類重合用固体触媒成分及び触媒 |
| FI86866C (fi) | 1990-12-19 | 1992-10-26 | Neste Oy | Foerfarande foer modifiering av katalysatorer avsedda foer polymerisation av olefiner |
| DE4108204A1 (de) | 1991-03-14 | 1992-09-17 | Schering Ag | Verfahren zur herstellung von alkoxymagnesiumhalogeniden |
| US5262573A (en) | 1991-08-06 | 1993-11-16 | Akzo Nv | Halomagnesium hydrocarbyloxide composition and process for preparation |
| US5488022A (en) * | 1992-10-28 | 1996-01-30 | Mitsubishi Chemical Corporation | Catalyst component for olefin polymerization |
| RU2153932C2 (ru) * | 1995-05-18 | 2000-08-10 | Митсуи Кемикалс, Инк. | Способ получения твердого титанового каталитического компонента, катализатор полимеризации олефина, содержащий его, и способ полимеризации олефина |
| JP3595864B2 (ja) | 1995-06-07 | 2004-12-02 | 住友化学工業株式会社 | α−オレフィン重合用触媒ならびにα−オレフィン重合体の製造方法 |
-
1998
- 1998-12-21 CN CNB988133091A patent/CN1255436C/zh not_active Expired - Fee Related
- 1998-12-21 KR KR1020007007096A patent/KR100625300B1/ko not_active Expired - Fee Related
- 1998-12-21 JP JP2000526554A patent/JP2001527136A/ja active Pending
- 1998-12-21 ES ES98962442T patent/ES2195431T3/es not_active Expired - Lifetime
- 1998-12-21 DE DE69812172T patent/DE69812172T2/de not_active Expired - Lifetime
- 1998-12-21 AU AU17610/99A patent/AU748975B2/en not_active Ceased
- 1998-12-21 AT AT98962442T patent/ATE234310T1/de not_active IP Right Cessation
- 1998-12-21 DE DE69803973T patent/DE69803973T2/de not_active Expired - Lifetime
- 1998-12-21 WO PCT/FI1998/001003 patent/WO1999033883A1/en not_active Ceased
- 1998-12-21 US US09/582,273 patent/US6365540B1/en not_active Expired - Lifetime
- 1998-12-21 AT AT98660147T patent/ATE213745T1/de not_active IP Right Cessation
- 1998-12-21 EA EA200000554A patent/EA004063B1/ru not_active IP Right Cessation
- 1998-12-21 WO PCT/FI1998/001002 patent/WO1999033842A1/en not_active Ceased
- 1998-12-21 US US09/216,882 patent/US6420499B1/en not_active Expired - Lifetime
- 1998-12-21 EP EP98660147A patent/EP0926165B1/en not_active Expired - Lifetime
- 1998-12-21 AU AU17609/99A patent/AU1760999A/en not_active Abandoned
- 1998-12-21 EP EP98962442A patent/EP1042330B1/en not_active Expired - Lifetime
- 1998-12-21 BR BR9814322-0A patent/BR9814322A/pt not_active IP Right Cessation
- 1998-12-21 ES ES98660147T patent/ES2173560T3/es not_active Expired - Lifetime
- 1998-12-21 CA CA002315214A patent/CA2315214A1/en not_active Abandoned
- 1998-12-22 MY MYPI98005825A patent/MY123970A/en unknown
- 1998-12-22 ZA ZA9811793A patent/ZA9811793B/xx unknown
- 1998-12-22 AR ARP980106594A patent/AR013018A1/es active IP Right Grant
-
1999
- 1999-03-08 TW TW088103546A patent/TWI230713B/zh not_active IP Right Cessation
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|---|---|
| KR20010033585A (ko) | 2001-04-25 |
| DE69803973T2 (de) | 2002-08-29 |
| ZA9811793B (en) | 1999-06-22 |
| EP1042330A1 (en) | 2000-10-11 |
| DE69812172D1 (de) | 2003-04-17 |
| EA200000554A1 (ru) | 2001-04-23 |
| BR9814322A (pt) | 2000-10-10 |
| EP0926165A1 (en) | 1999-06-30 |
| WO1999033842A1 (en) | 1999-07-08 |
| CN1284088A (zh) | 2001-02-14 |
| ATE213745T1 (de) | 2002-03-15 |
| JP2001527136A (ja) | 2001-12-25 |
| AU1760999A (en) | 1999-07-19 |
| DE69812172T2 (de) | 2003-08-28 |
| AU1761099A (en) | 1999-07-19 |
| US6420499B1 (en) | 2002-07-16 |
| TWI230713B (en) | 2005-04-11 |
| US6365540B1 (en) | 2002-04-02 |
| CN1255436C (zh) | 2006-05-10 |
| AU748975B2 (en) | 2002-06-13 |
| ATE234310T1 (de) | 2003-03-15 |
| EP1042330B1 (en) | 2003-03-12 |
| EP0926165B1 (en) | 2002-02-27 |
| EA004063B1 (ru) | 2003-12-25 |
| KR100625300B1 (ko) | 2006-09-20 |
| CA2315214A1 (en) | 1999-07-08 |
| AR013018A1 (es) | 2000-11-22 |
| ES2195431T3 (es) | 2003-12-01 |
| WO1999033883A1 (en) | 1999-07-08 |
| MY123970A (en) | 2006-06-30 |
| DE69803973D1 (de) | 2002-04-04 |
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