HK100291A - A modified block copolymer composition - Google Patents

A modified block copolymer composition

Info

Publication number
HK100291A
HK100291A HK1002/91A HK100291A HK100291A HK 100291 A HK100291 A HK 100291A HK 1002/91 A HK1002/91 A HK 1002/91A HK 100291 A HK100291 A HK 100291A HK 100291 A HK100291 A HK 100291A
Authority
HK
Hong Kong
Prior art keywords
block copolymer
modified
weight
acid
cis
Prior art date
Application number
HK1002/91A
Other languages
English (en)
French (fr)
Inventor
Toshinori Shiraki
Fusakazu Hayano
Hideo Morita
Original Assignee
Asahi Kasei Kogyo Kabushiki Kaisha
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=26462186&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=HK100291(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from JP12588281A external-priority patent/JPS5827740A/ja
Priority claimed from JP13165081A external-priority patent/JPS5834838A/ja
Application filed by Asahi Kasei Kogyo Kabushiki Kaisha filed Critical Asahi Kasei Kogyo Kabushiki Kaisha
Publication of HK100291A publication Critical patent/HK100291A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F287/00—Macromolecular compounds obtained by polymerising monomers on to block polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/04—Reduction, e.g. hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/46—Reaction with unsaturated dicarboxylic acids or anhydrides thereof, e.g. maleinisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/006—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to block copolymers containing at least one sequence of polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/20—Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Claims (10)

1. Modifizierte Blockcopolymer-Zusammensetzung, enthaltend:
(a) ein Polyamid; und
(b) mindestens ein modifiziertes Blockcopolymer, welches umfaßt ein Basisblockcopolymer aus mindestens einem monovinylsubstituierten aromatischen Kohlenwasserstoffpolymerblock A und mindestens einem aus einer Olefinverbindung gebildeten Polymerblock B, wobei dieses Basisblockcopolymer mindestens eine darauf aufgepfropfte Moleküleinheit enthält, die mindestens ein aus einer Carboxylgruppe und davon abgeleiteten Gruppen ausgewähltes Glied aufweist, dadurch gekennzeichnet, daß der aus einer Olefinverbindung gebildete Polymerblock B einen Anteil an ethylenischer Ungesättigtheit aufweist, der 20% nicht überschreitet.
2. Zusammensetzung nach Anspruch 1, worin das Polyamid aus der aus einem Polykondensat einer Dicarbonsäure und eines Diamins, einem Polykondensat aus einer a-Aminocarbonsäure und einem Polymer, das durch ringöffnende Polymerication eines cyclischen Lactams erhalten ist, bestehenden Gruppe ausgewählt ist.
3. Zusammensetzung nach Anspruch 2, worin das Polyamid aus der aus Nylon-6, Nylon-66, Nylon-610, Nylon-11, Nylon-12, einem Copolymer aus Nylon-6 und Nylon-66 und einem Copolymer aus Nylon-6 und Nylon-12 bestehenden Gruppe ausgewählt ist.
4. Zusammensetzung nach Anspruch 1, worin die mindestens ein aus einer Carboxylgruppe und davon abgeleiteten Gruppen ausgewähltes Glied enthaltende Moleküleinheit auf das Basisblockcopolymer in einer Menge von 0,05 bis 30 Gewichtsteilen pro 100 Gewichtsteile des Basisblockcopolymers aufgepfropft ist.
5. Zusammensetzung nach Anspruch 1, worin der monovinylsubstituierte aromatische Kohlenwasserstoff in diesem Basisblockcopolymer in einer Menge von mehr als 60 Gew.-% bis zu einschließlich 95 Gew.-%, bezogen auf das Basisblockcopolymer, enthalten ist und wobei das Polyamid (a) in einem Gewichtsverhältnis von 90:10 bis 5:95, bezogen auf das mindestens eine modifizierte Blockcopolymer (b), vorhanden ist.
6. Zusammensetzung nach Anspruch 1, worin der monovinylsubstituierte aromatische Kohlenwasserstoff in dem Basisblockcopolymer in einer Menge von 5 bis 60 Gew.-%, bezogen auf das Basisblockcopolymer, enthalten ist und wobei das Polyamid (a) in einem Gewichtsverhältnis von über 50:50 is zu einschließlich 98:2, bezogen auf das modifizierte Blockcopolymer (b), vorhanden ist.
7. Zusammensetzung nach Anspruch 1, worin der monovinylsubstituierte aromatische Kohlenwasserstoff in dem Basisblockcopolymer in einer Menge von 5 bis 60 Gew.-%, bezogen auf das Gewicht des Basisblockcopolymeren, enthalten ist, und wobei das Polyamid (a) in einem Gewichtsverhältnis von 2:98 bis 50:50, bezogen auf das mindestens eine modifizierte Blockcopolymer (b), vorhanden ist.
8. Zusammensetzung nach einem der Ansprüche 1 und 4 bis 7, worin das mindestens eine modifizierte Blockcopolymer ein Produkt ist, das durch Additionsreaktion des Basisblockcopolymers mit mindestens einem Modifizierungsmittel der aus ungesättigten Carbonsäuren und ihren Derivaten bestehenden Gruppe erhalten ist, wobei das Basisblockcopolymer ein Produkt ist, das durch selektives Hydrieren der Einheiten der konjugierten Dienverbindung eines Blockcopolymervorläufers erhalten ist, der mindestens einen monovinylsubstituierten aromatischen Kohlenwasserstoffpolymerblock und mindestens einen Polymerblock, der vorwiegend aus einer konjugierten Dienverbindung gebildet ist, umfaßt, in einem solchen Ausmaß, daß der ethylenische Unsättigungsgrad des vorwiegend aus der konjugierten Dienverbindung zusammengesetzten Polymerblockes 20% oder weniger beträgt.
9. Zusammensetzung nach Anspruch 8, wobei das mindestens eine Modifizierungsmittel aus der aus Maleinsäure, Maleinsäureanhydrid, Maleinsäureestern, Maleinsäureamiden, Maleinsäureimiden, Fumarsäure, Fumarsäureestern, Fumarsäureamiden, Fumarsäureimiden, Itaconsäure, Itaconsäureanhydrid, Itaconsäureestern, Itaconsäureamiden, Itaconsäureimiden, halogenierter Maleinsäure, halogeniertem Maleinsäureanhydrid, halogenierten Maleinsäureestern, halogenierten Maleinsäureamiden, halogenierten Maleinsäureimiden, cis-4-Cyclohexen-1,2-dicarbonsäure, cis-4-Cyclohexen-1,2-dicarbonsäureanhydrid, cis-4-Cyclohexen-1,2-dicarbonsäureestern, cis-4-Cyclohexen-1,2-dicarbonsäureamiden, cis-4-Cyciohexen-1,2-dicarbonsäureimiden, Endo-cis-bicyclo(2,2,1)-5-hepten-2,3-dicarbonsäure, Endo-cis-bicyclo(2,2,1)-5- hepten-2,3-dicarbonsäureanhydrid, Endo-cis-bicyclo(2,2,1)-5-hepten-2,3-dicarbonsäureestern, Endo-cis- bicyclo(2,2,1)-5-hepten-2,3-dicarbonsäureamiden, Endo-cis-bicyclo(2,2,1)-5-hepten-2,3-dicarbonsäure- imiden, Acrylsäure, Acrylsäureestern, Acrylsäureamid, Methacrylsäure, Methacrylsäureestern und Methacrylsäureamid bestehenden Gruppe ausgewählt ist.
10. Zusammensetzung nach einem der Ansprüche 1 bis 9, wobei das modifizierte Blockcopolymer durch mindestens ein Metallion, das aus der aus einwertigen, zweiwertigen und dreiwertigen Metallionen bestehenden Gruppe ausgewählt ist, unter Bildung eines ionisch vernetzten modifizierten Blockcopolymers ionisch vernetzt ist.
HK1002/91A 1981-08-13 1991-12-12 A modified block copolymer composition HK100291A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP12588281A JPS5827740A (ja) 1981-08-13 1981-08-13 変性ブロツク共重合体組成物
JP13165081A JPS5834838A (ja) 1981-08-24 1981-08-24 アイオノマ−含有重合体組成物

Publications (1)

Publication Number Publication Date
HK100291A true HK100291A (en) 1991-12-20

Family

ID=26462186

Family Applications (3)

Application Number Title Priority Date Filing Date
HK1002/91A HK100291A (en) 1981-08-13 1991-12-12 A modified block copolymer composition
HK684/93A HK68493A (en) 1981-08-13 1993-07-15 A modified block copolymer
HK189096A HK189096A (en) 1981-08-13 1996-10-10 A modified block copolymer

Family Applications After (2)

Application Number Title Priority Date Filing Date
HK684/93A HK68493A (en) 1981-08-13 1993-07-15 A modified block copolymer
HK189096A HK189096A (en) 1981-08-13 1996-10-10 A modified block copolymer

Country Status (6)

Country Link
US (6) US4628072A (de)
EP (4) EP0262691B1 (de)
DE (3) DE3280421T2 (de)
HK (3) HK100291A (de)
SG (1) SG76591G (de)
WO (1) WO1983000492A1 (de)

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EP0371001B1 (de) 1996-02-07
US4972020A (en) 1990-11-20
US5183857A (en) 1993-02-02
US4628072B1 (de) 1989-04-25
DE3280268D1 (de) 1990-12-13
US4657970B1 (de) 1989-07-04
EP0216347A1 (de) 1987-04-01
EP0262691A3 (en) 1988-12-28
EP0085115A1 (de) 1983-08-10
HK189096A (en) 1996-10-18
EP0371001A3 (de) 1992-04-01
WO1983000492A1 (fr) 1983-02-17
US4657970A (en) 1987-04-14
US4657971B1 (de) 1989-04-25
US4628072A (en) 1986-12-09
EP0262691B1 (de) 1992-12-02
EP0216347B1 (de) 1990-11-07
EP0085115B2 (de) 1995-04-19
EP0262691A2 (de) 1988-04-06
DE3280472D1 (de) 1996-03-21
DE3280472T2 (de) 1996-11-14
US4657971A (en) 1987-04-14
EP0371001A2 (de) 1990-05-30
DE3280421T2 (de) 1993-07-01
HK68493A (en) 1993-07-23
DE3280421D1 (de) 1993-01-14
EP0085115A4 (de) 1985-04-11
SG76591G (en) 1991-11-15
US4927889A (en) 1990-05-22
EP0085115B1 (de) 1989-07-05

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