IL100865A - Destroyed granular aphids soluble in water - Google Patents

Destroyed granular aphids soluble in water

Info

Publication number: IL100865A
Authority: IL; Israel
Prior art keywords: granules; water; weight; active substance; emulsifiable
Prior art date: 1991-02-06

Application number

IL10086592A

Other languages

English (en)

Hebrew (he)

Other versions

IL100865A0 (en

Original Assignee

Hoechst Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1991-02-06

Filing date

1992-02-04

Publication date

1998-09-24

1992-02-04 Application filed by Hoechst Ag filed Critical Hoechst Ag

1992-11-15 Publication of IL100865A0 publication Critical patent/IL100865A0/xx

1998-09-24 Publication of IL100865A publication Critical patent/IL100865A/en

Links

239000008187 granular material Substances 0.000 title claims abstract description 46
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 34
239000000575 pesticide Substances 0.000 title description 3
239000013543 active substance Substances 0.000 claims abstract description 39
229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 35
235000019422 polyvinyl alcohol Nutrition 0.000 claims abstract description 34
238000000034 method Methods 0.000 claims abstract description 26
239000000203 mixture Substances 0.000 claims abstract description 24
238000009472 formulation Methods 0.000 claims abstract description 13
239000000463 material Substances 0.000 claims abstract description 13
238000002360 preparation method Methods 0.000 claims abstract description 12
230000000361 pesticidal effect Effects 0.000 claims abstract description 10
238000009835 boiling Methods 0.000 claims abstract description 9
239000002904 solvent Substances 0.000 claims abstract description 9
239000011877 solvent mixture Substances 0.000 claims abstract description 6
150000002894 organic compounds Chemical class 0.000 claims abstract description 4
239000004372 Polyvinyl alcohol Substances 0.000 claims description 26
230000007062 hydrolysis Effects 0.000 claims description 25
238000006460 hydrolysis reaction Methods 0.000 claims description 25
239000006185 dispersion Substances 0.000 claims description 13
239000000080 wetting agent Substances 0.000 claims description 13
229920002689 polyvinyl acetate Polymers 0.000 claims description 12
239000002245 particle Substances 0.000 claims description 11
239000011118 polyvinyl acetate Substances 0.000 claims description 11
239000004009 herbicide Substances 0.000 claims description 9
239000007864 aqueous solution Substances 0.000 claims description 8
239000007787 solid Substances 0.000 claims description 8
VEMKTZHHVJILDY-UXHICEINSA-N bioresmethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UXHICEINSA-N 0.000 claims description 7
239000002917 insecticide Substances 0.000 claims description 6
239000005892 Deltamethrin Substances 0.000 claims description 4
239000002671 adjuvant Substances 0.000 claims description 4
229960002483 decamethrin Drugs 0.000 claims description 4
OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 claims description 4
PQKBPHSEKWERTG-LLVKDONJSA-N ethyl (2r)-2-[4-[(6-chloro-1,3-benzoxazol-2-yl)oxy]phenoxy]propanoate Chemical group C1=CC(O[C@H](C)C(=O)OCC)=CC=C1OC1=NC2=CC=C(Cl)C=C2O1 PQKBPHSEKWERTG-LLVKDONJSA-N 0.000 claims description 4
230000002363 herbicidal effect Effects 0.000 claims description 4
239000003016 pheromone Substances 0.000 claims description 4
239000005871 repellent Substances 0.000 claims description 4
230000002940 repellent Effects 0.000 claims description 4
HPYNBECUCCGGPA-UHFFFAOYSA-N silafluofen Chemical compound C1=CC(OCC)=CC=C1[Si](C)(C)CCCC1=CC=C(F)C(OC=2C=CC=CC=2)=C1 HPYNBECUCCGGPA-UHFFFAOYSA-N 0.000 claims description 4
239000000417 fungicide Substances 0.000 claims description 3
230000000895 acaricidal effect Effects 0.000 claims description 2
239000000642 acaricide Substances 0.000 claims description 2
239000005645 nematicide Substances 0.000 claims description 2
230000000749 insecticidal effect Effects 0.000 claims 1
238000007127 saponification reaction Methods 0.000 claims 1
239000011814 protection agent Substances 0.000 abstract description 6
239000007788 liquid Substances 0.000 abstract description 5
238000003756 stirring Methods 0.000 description 16
239000008346 aqueous phase Substances 0.000 description 15
QPUYECUOLPXSFR-UHFFFAOYSA-N alpha-methyl-naphthalene Natural products C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 description 13
239000000839 emulsion Substances 0.000 description 11
239000000243 solution Substances 0.000 description 11
239000000126 substance Substances 0.000 description 11
239000004562 water dispersible granule Substances 0.000 description 10
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
239000000428 dust Substances 0.000 description 7
-1 polyethylene Polymers 0.000 description 7
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
239000003960 organic solvent Substances 0.000 description 6
239000000047 product Substances 0.000 description 6
230000015572 biosynthetic process Effects 0.000 description 5
239000003795 chemical substances by application Substances 0.000 description 5
239000003995 emulsifying agent Substances 0.000 description 5
239000000843 powder Substances 0.000 description 5
239000007921 spray Substances 0.000 description 5
230000031018 biological processes and functions Effects 0.000 description 4
239000002270 dispersing agent Substances 0.000 description 4
238000001035 drying Methods 0.000 description 4
239000004495 emulsifiable concentrate Substances 0.000 description 4
239000006260 foam Substances 0.000 description 4
159000000000 sodium salts Chemical class 0.000 description 4
GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 4
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
239000002253 acid Substances 0.000 description 3
125000000217 alkyl group Chemical group 0.000 description 3
239000002518 antifoaming agent Substances 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
238000005469 granulation Methods 0.000 description 3
230000003179 granulation Effects 0.000 description 3
229920000642 polymer Polymers 0.000 description 3
239000004548 suspo-emulsion Substances 0.000 description 3
235000015112 vegetable and seed oil Nutrition 0.000 description 3
HKELWJONQIFBPO-UHFFFAOYSA-N 1-(2,4-dichlorophenyl)-5-(trichloromethyl)-1,2,4-triazole-3-carboxylic acid Chemical compound N1=C(C(=O)O)N=C(C(Cl)(Cl)Cl)N1C1=CC=C(Cl)C=C1Cl HKELWJONQIFBPO-UHFFFAOYSA-N 0.000 description 2
QIMMUPPBPVKWKM-UHFFFAOYSA-N 2-methylnaphthalene Chemical compound C1=CC=CC2=CC(C)=CC=C21 QIMMUPPBPVKWKM-UHFFFAOYSA-N 0.000 description 2
ZRDUSMYWDRPZRM-UHFFFAOYSA-N 2-sec-butyl-4,6-dinitrophenyl 3-methylbut-2-enoate Chemical compound CCC(C)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1OC(=O)C=C(C)C ZRDUSMYWDRPZRM-UHFFFAOYSA-N 0.000 description 2
VGVHNLRUAMRIEW-UHFFFAOYSA-N 4-methylcyclohexan-1-one Chemical compound CC1CCC(=O)CC1 VGVHNLRUAMRIEW-UHFFFAOYSA-N 0.000 description 2
239000005652 Acrinathrin Substances 0.000 description 2
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
239000005946 Cypermethrin Substances 0.000 description 2
NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical group COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 2
NEKOXWSIMFDGMA-UHFFFAOYSA-N Isopropalin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(C)C)C=C1[N+]([O-])=O NEKOXWSIMFDGMA-UHFFFAOYSA-N 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
YLFSVIMMRPNPFK-WEQBUNFVSA-N acrinathrin Chemical compound CC1(C)[C@@H](\C=C/C(=O)OC(C(F)(F)F)C(F)(F)F)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 YLFSVIMMRPNPFK-WEQBUNFVSA-N 0.000 description 2
125000000129 anionic group Chemical group 0.000 description 2
239000003849 aromatic solvent Substances 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
230000004071 biological effect Effects 0.000 description 2
229950002373 bioresmethrin Drugs 0.000 description 2
239000002775 capsule Substances 0.000 description 2
125000002091 cationic group Chemical group 0.000 description 2
239000011248 coating agent Substances 0.000 description 2
238000000576 coating method Methods 0.000 description 2
244000038559 crop plants Species 0.000 description 2
JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
229960005424 cypermethrin Drugs 0.000 description 2
KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 2
239000013530 defoamer Substances 0.000 description 2
235000014113 dietary fatty acids Nutrition 0.000 description 2
MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 2
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
239000000194 fatty acid Substances 0.000 description 2
229930195729 fatty acid Natural products 0.000 description 2
150000004665 fatty acids Chemical class 0.000 description 2
239000000945 filler Substances 0.000 description 2
238000000227 grinding Methods 0.000 description 2
HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 2
WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
239000003094 microcapsule Substances 0.000 description 2
229960000490 permethrin Drugs 0.000 description 2
RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 2
239000012071 phase Substances 0.000 description 2
229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
235000010265 sodium sulphite Nutrition 0.000 description 2
238000001694 spray drying Methods 0.000 description 2
239000000725 suspension Substances 0.000 description 2
YWSCPYYRJXKUDB-KAKFPZCNSA-N tralomethrin Chemical compound CC1(C)[C@@H](C(Br)C(Br)(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 YWSCPYYRJXKUDB-KAKFPZCNSA-N 0.000 description 2
239000008158 vegetable oil Substances 0.000 description 2
238000009736 wetting Methods 0.000 description 2
ZCVAOQKBXKSDMS-PVAVHDDUSA-N (+)-trans-(S)-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)O[C@@H]1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-PVAVHDDUSA-N 0.000 description 1
ZCVAOQKBXKSDMS-AQYZNVCMSA-N (+)-trans-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-AQYZNVCMSA-N 0.000 description 1
KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 description 1
YATDSXRLIUJOQN-SVRRBLITSA-N (2,3,4,5,6-pentafluorophenyl)methyl (1r,3s)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=C(F)C(F)=C(F)C(F)=C1F YATDSXRLIUJOQN-SVRRBLITSA-N 0.000 description 1
LNJXZKBHJZAIKQ-UHFFFAOYSA-N 1,1,1,2-tetrachloro-3-(2,3,3,3-tetrachloropropoxy)propane Chemical compound ClC(Cl)(Cl)C(Cl)COCC(Cl)C(Cl)(Cl)Cl LNJXZKBHJZAIKQ-UHFFFAOYSA-N 0.000 description 1
QNLZIZAQLLYXTC-UHFFFAOYSA-N 1,2-dimethylnaphthalene Chemical class C1=CC=CC2=C(C)C(C)=CC=C21 QNLZIZAQLLYXTC-UHFFFAOYSA-N 0.000 description 1
FMTFEIJHMMQUJI-NJAFHUGGSA-N 102130-98-3 Natural products CC=CCC1=C(C)[C@H](CC1=O)OC(=O)[C@@H]1[C@@H](C=C(C)C)C1(C)C FMTFEIJHMMQUJI-NJAFHUGGSA-N 0.000 description 1
MHKBMNACOMRIAW-UHFFFAOYSA-N 2,3-dinitrophenol Chemical class OC1=CC=CC([N+]([O-])=O)=C1[N+]([O-])=O MHKBMNACOMRIAW-UHFFFAOYSA-N 0.000 description 1
CHZCERSEMVWNHL-UHFFFAOYSA-N 2-hydroxybenzonitrile Chemical class OC1=CC=CC=C1C#N CHZCERSEMVWNHL-UHFFFAOYSA-N 0.000 description 1
HFOFYNMWYRXIBP-MOPGFXCFSA-N 2-methyl-7S,8R-Epoxy-octadecane Chemical compound CCCCCCCCCC[C@H]1O[C@H]1CCCCC(C)C HFOFYNMWYRXIBP-MOPGFXCFSA-N 0.000 description 1
QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
BWDBEAQIHAEVLV-UHFFFAOYSA-N 6-methylheptan-1-ol Chemical compound CC(C)CCCCCO BWDBEAQIHAEVLV-UHFFFAOYSA-N 0.000 description 1
244000215068 Acacia senegal Species 0.000 description 1
239000005877 Alpha-Cypermethrin Substances 0.000 description 1
FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 description 1
239000004375 Dextrin Substances 0.000 description 1
229920001353 Dextrin Polymers 0.000 description 1
IIPZYDQGBIWLBU-UHFFFAOYSA-N Dinoterb Chemical compound CC(C)(C)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O IIPZYDQGBIWLBU-UHFFFAOYSA-N 0.000 description 1
241000196324 Embryophyta Species 0.000 description 1
PQKBPHSEKWERTG-UHFFFAOYSA-N Fenoxaprop ethyl Chemical group C1=CC(OC(C)C(=O)OCC)=CC=C1OC1=NC2=CC=C(Cl)C=C2O1 PQKBPHSEKWERTG-UHFFFAOYSA-N 0.000 description 1
108010010803 Gelatin Proteins 0.000 description 1
229920000084 Gum arabic Polymers 0.000 description 1
241000238631 Hexapoda Species 0.000 description 1
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WABPPBHOPMUJHV-UHFFFAOYSA-N Sesamex Chemical compound CCOCCOCCOC(C)OC1=CC=C2OCOC2=C1 WABPPBHOPMUJHV-UHFFFAOYSA-N 0.000 description 1
244000000231 Sesamum indicum Species 0.000 description 1
235000003434 Sesamum indicum Nutrition 0.000 description 1
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HRKAMJBPFPHCSD-UHFFFAOYSA-N Tri-isobutylphosphate Chemical compound CC(C)COP(=O)(OCC(C)C)OCC(C)C HRKAMJBPFPHCSD-UHFFFAOYSA-N 0.000 description 1
241000384110 Tylos Species 0.000 description 1
241000607479 Yersinia pestis Species 0.000 description 1
FHKPLLOSJHHKNU-INIZCTEOSA-N [(3S)-3-[8-(1-ethyl-5-methylpyrazol-4-yl)-9-methylpurin-6-yl]oxypyrrolidin-1-yl]-(oxan-4-yl)methanone Chemical compound C(C)N1N=CC(=C1C)C=1N(C2=NC=NC(=C2N=1)O[C@@H]1CN(CC1)C(=O)C1CCOCC1)C FHKPLLOSJHHKNU-INIZCTEOSA-N 0.000 description 1
YXWCBRDRVXHABN-JCMHNJIXSA-N [cyano-(4-fluoro-3-phenoxyphenyl)methyl] 3-[(z)-2-chloro-2-(4-chlorophenyl)ethenyl]-2,2-dimethylcyclopropane-1-carboxylate Chemical compound C=1C=C(F)C(OC=2C=CC=CC=2)=CC=1C(C#N)OC(=O)C1C(C)(C)C1\C=C(/Cl)C1=CC=C(Cl)C=C1 YXWCBRDRVXHABN-JCMHNJIXSA-N 0.000 description 1
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125000001931 aliphatic group Chemical group 0.000 description 1
238000005904 alkaline hydrolysis reaction Methods 0.000 description 1
150000004996 alkyl benzenes Chemical class 0.000 description 1
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OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 1
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FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 description 1
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HVCNNTAUBZIYCG-UHFFFAOYSA-N ethyl 2-[4-[(6-chloro-1,3-benzothiazol-2-yl)oxy]phenoxy]propanoate Chemical compound C1=CC(OC(C)C(=O)OCC)=CC=C1OC1=NC2=CC=C(Cl)C=C2S1 HVCNNTAUBZIYCG-UHFFFAOYSA-N 0.000 description 1
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238000010438 heat treatment Methods 0.000 description 1
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150000002576 ketones Chemical class 0.000 description 1
239000008101 lactose Substances 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
MQWCXKGKQLNYQG-UHFFFAOYSA-N methyl cyclohexan-4-ol Natural products CC1CCC(O)CC1 MQWCXKGKQLNYQG-UHFFFAOYSA-N 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
239000011859 microparticle Substances 0.000 description 1
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235000019426 modified starch Nutrition 0.000 description 1
229920000847 nonoxynol Polymers 0.000 description 1
SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
239000003921 oil Substances 0.000 description 1
235000019198 oils Nutrition 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
239000005022 packaging material Substances 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
230000035515 penetration Effects 0.000 description 1
125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
WROZTZHKRRNHBS-UHFFFAOYSA-N phenyl propaneperoxoate Chemical compound CCC(=O)OOC1=CC=CC=C1 WROZTZHKRRNHBS-UHFFFAOYSA-N 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
231100000208 phytotoxic Toxicity 0.000 description 1
230000000885 phytotoxic effect Effects 0.000 description 1
229960005235 piperonyl butoxide Drugs 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
229920000151 polyglycol Polymers 0.000 description 1
239000010695 polyglycol Substances 0.000 description 1
229920001522 polyglycol ester Polymers 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
239000001267 polyvinylpyrrolidone Substances 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
JOOMJVFZQRQWKR-UHFFFAOYSA-N pyrazophos Chemical compound N1=C(C)C(C(=O)OCC)=CN2N=C(OP(=S)(OCC)OCC)C=C21 JOOMJVFZQRQWKR-UHFFFAOYSA-N 0.000 description 1
229940108410 resmethrin Drugs 0.000 description 1
VEMKTZHHVJILDY-FIWHBWSRSA-N resmethrin Chemical compound CC1(C)[C@H](C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-FIWHBWSRSA-N 0.000 description 1
239000013049 sediment Substances 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
235000010413 sodium alginate Nutrition 0.000 description 1
YROXIXLRRCOBKF-UHFFFAOYSA-N sulfonylurea Chemical class OC(=N)N=S(=O)=O YROXIXLRRCOBKF-UHFFFAOYSA-N 0.000 description 1
150000003462 sulfoxides Chemical class 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
208000024891 symptom Diseases 0.000 description 1
229920001059 synthetic polymer Polymers 0.000 description 1
230000008646 thermal stress Effects 0.000 description 1
230000002110 toxicologic effect Effects 0.000 description 1
231100000027 toxicology Toxicity 0.000 description 1
AMFGTOFWMRQMEM-UHFFFAOYSA-N triazophos Chemical compound N1=C(OP(=S)(OCC)OCC)N=CN1C1=CC=CC=C1 AMFGTOFWMRQMEM-UHFFFAOYSA-N 0.000 description 1
STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
ZSDSQXJSNMTJDA-UHFFFAOYSA-N trifluralin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O ZSDSQXJSNMTJDA-UHFFFAOYSA-N 0.000 description 1
229920003169 water-soluble polymer Polymers 0.000 description 1
239000008096 xylene Substances 0.000 description 1
150000003738 xylenes Chemical class 0.000 description 1

Classifications

- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
- A01N25/14—Powders or granules wettable

Landscapes

Life Sciences & Earth Sciences (AREA)
Health & Medical Sciences (AREA)
General Health & Medical Sciences (AREA)
Agronomy & Crop Science (AREA)
Pest Control & Pesticides (AREA)
Plant Pathology (AREA)
Toxicology (AREA)
Engineering & Computer Science (AREA)
Dentistry (AREA)
Wood Science & Technology (AREA)
Zoology (AREA)
Environmental Sciences (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Hydrogenated Pyridines (AREA)
Saccharide Compounds (AREA)
Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Steroid Compounds (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Bakery Products And Manufacturing Methods Therefor (AREA)
Compositions Of Macromolecular Compounds (AREA)
Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Fertilizers (AREA)
Soil Conditioners And Soil-Stabilizing Materials (AREA)
Disintegrating Or Milling (AREA)

IL10086592A 1991-02-06 1992-02-04 Destroyed granular aphids soluble in water IL100865A (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE4103467		1991-02-06
DE4127757A DE4127757A1 (de)	1991-02-06	1991-08-22	Neue pflanzenschutzmittel-formulierungen

Publications (2)

Publication Number	Publication Date
IL100865A0 IL100865A0 (en)	1992-11-15
IL100865A true IL100865A (en)	1998-09-24

Family

ID=25900782

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IL10086592A IL100865A (en)	1991-02-06	1992-02-04	Destroyed granular aphids soluble in water

Country Status (25)

Country	Link
US (2)	US5602177A (cs)
EP (1)	EP0498332B1 (cs)
JP (1)	JP2955109B2 (cs)
KR (1)	KR100201682B1 (cs)
CN (1)	CN1054494C (cs)
AT (1)	ATE171041T1 (cs)
AU (1)	AU655795B2 (cs)
BR (1)	BR9200402A (cs)
CA (1)	CA2060745C (cs)
CZ (1)	CZ289364B6 (cs)
DE (2)	DE4127757A1 (cs)
DK (1)	DK0498332T3 (cs)
EG (1)	EG19693A (cs)
ES (1)	ES2121795T3 (cs)
HU (1)	HU213529B (cs)
IL (1)	IL100865A (cs)
MA (1)	MA22414A1 (cs)
MX (1)	MX9200495A (cs)
MY (1)	MY109496A (cs)
NZ (1)	NZ241518A (cs)
OA (1)	OA09534A (cs)
PH (1)	PH31574A (cs)
PL (1)	PL169873B1 (cs)
SK (1)	SK282383B6 (cs)
TR (1)	TR28352A (cs)

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FR2704387B1 (fr)	1993-04-28	1995-06-09	Rhone Poulenc Agrochimie	Compositions concentrees de matieres actives en agriculture.
FR2713045B1 (fr) *	1993-12-03	1996-08-09	Roussel Uclaf	Granulés émulsionnables dans l'eau, leur procédé de préparation et leur application comme pesticides.
WO1997039626A1 (en) *	1996-04-22	1997-10-30	E.I. Du Pont De Nemours And Company	Pesticides trapped in emulsifiable granules
UA52701C2 (uk)	1996-10-11	2003-01-15	Басф Акцієнгезельшафт	Твердий засіб захисту рослин та спосіб його одержання, спосіб боротьби з небажаним ростом рослин, спосіб боротьби з шкідливими грибами і тваринами-шкідниками та спосіб регулювання росту рослин
DE19641939A1 (de) *	1996-10-11	1998-04-16	Basf Ag	Festes Pflanzenschutzmittel
DE10022989A1 (de) *	2000-05-11	2001-11-22	Aventis Cropscience Gmbh	Kombinationen von Pflanzenschutzmitteln mit organischen oder anorganischen Trägermaterialien
DE10022990A1 (de) *	2000-05-11	2001-11-22	Aventis Cropscience Gmbh	Kombination von Pflanzenschutzmitteln mit Wasserstoffbrücken bildenden Polymeren
GB2374082A (en) *	2001-04-04	2002-10-09	Procter & Gamble	Particles for a detergent product
EP1585392B1 (en) *	2003-01-06	2009-03-18	Yissum Research Development Company Of The Hebrew University Of Jerusalem	Herbicides inhibiting the action of plant acetyl-coa carboxylase for use as pesticides.
RU2245039C1 (ru) *	2003-12-10	2005-01-27	Всероссийский научно-исследовательский институт биологической защиты растений	Способ защиты сельскохозяйственных культур от вредных насекомых
US20080200561A1 (en) *	2004-09-14	2008-08-21	Bayer Cropscience Gmbh	Emulsifiable Granules Formulations With Boron Containing Fertilisers
CA2646445A1 (en) *	2006-03-27	2007-10-04	Randall C. Cush	Granular formulation
DE102006015940A1 (de) *	2006-04-05	2007-10-11	Bayer Cropscience Ag	Flüssige Formulierungen im Pflanzenschutz und deren Verwendung
DE102006055477A1 (de) *	2006-11-24	2008-05-29	Bayer Cropscience Ag	Pflanzenschutzgranulate zur Applikation auf die Blattoberfläche
GB0815936D0 (en) *	2008-08-29	2009-01-14	Bae Systems Plc	Cast Explosive Composition
CN101632361B (zh) *	2009-08-18	2012-07-04	江苏丰登农药有限公司	苯醚甲环唑可乳化粉剂
AP3538A (en)	2010-07-15	2016-01-13	Dow Agrosciences Llc	Solid herbicide compositions with built-in adjuvant
CN102187858A (zh) *	2010-11-19	2011-09-21	南通联农农药制剂研究开发有限公司	一种农药可乳化粒剂及其制备方法
CN102308791B (zh) *	2011-05-18	2014-03-19	江西正邦生物化工股份有限公司	一种咪鲜胺可乳化粒剂及其制备方法
CN102326581A (zh) *	2011-05-18	2012-01-25	江西正邦生物化工股份有限公司	一种三唑磷可乳化粒剂及其制备方法
EP2811830B1 (en) *	2012-01-25	2018-08-15	Dow AgroSciences LLC	Improved solid herbicide compositions with built-in adjuvant
EA030778B1 (ru)	2012-03-02	2018-09-28	Басф Се	Способ изготовления эмульгирующихся гранул посредством смешивания пестицидной эмульсии с твёрдым диспергирующим веществом и экструдирования полученной пасты
WO2014039950A1 (en) *	2012-09-07	2014-03-13	Dong-Hwan Choe	Development of pheromone assisted techniques to improve efficacy of insecticide sprays targeting urban pest ant species
CN105104084A (zh) *	2015-08-25	2015-12-02	钱家静	一种中浓度2,4-d与甘油凝胶的沾根方法
CN105010330A (zh) *	2015-08-25	2015-11-04	钱家静	一种中浓度2,4-d凝胶的沾根方法
CN105104081A (zh) *	2015-08-25	2015-12-02	何其家	一种中浓度kt与甘油凝胶的沾根方法
CN105104082A (zh) *	2015-08-25	2015-12-02	钱家静	一种低浓度kt与甘油凝胶的沾根方法
CN105104078A (zh) *	2015-08-25	2015-12-02	钱夕华	一种高浓度iba与甘油凝胶的沾根方法
CN105123306A (zh) *	2015-08-25	2015-12-09	钱家静	一种低浓度kt凝胶的节位使用方法
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AU621218B2 (en) *	1989-04-26	1992-03-05	Sumitomo Chemical Company, Limited	Emulsifiable pesticidal solid compositions
NZ235752A (en) *	1989-11-10	1993-02-25	Sumitomo Chemical Co	Pesticidal compositions containing a suspended pyrethroid and a microencapsulated organophosphorus compound and/or carbamate, in water

1991
- 1991-08-22 DE DE4127757A patent/DE4127757A1/de not_active Withdrawn
1992
- 1992-02-03 MY MYPI92000181A patent/MY109496A/en unknown
- 1992-02-03 DK DK92101707T patent/DK0498332T3/da active
- 1992-02-03 DE DE59209497T patent/DE59209497D1/de not_active Expired - Fee Related
- 1992-02-03 AT AT92101707T patent/ATE171041T1/de not_active IP Right Cessation
- 1992-02-03 EP EP92101707A patent/EP0498332B1/de not_active Expired - Lifetime
- 1992-02-03 ES ES92101707T patent/ES2121795T3/es not_active Expired - Lifetime
- 1992-02-04 EG EG6992A patent/EG19693A/xx active
- 1992-02-04 TR TR00118/92A patent/TR28352A/xx unknown
- 1992-02-04 CN CN92100788A patent/CN1054494C/zh not_active Expired - Fee Related
- 1992-02-04 PH PH43862A patent/PH31574A/en unknown
- 1992-02-04 NZ NZ241518A patent/NZ241518A/en unknown
- 1992-02-04 IL IL10086592A patent/IL100865A/en not_active IP Right Cessation
- 1992-02-04 MX MX9200495A patent/MX9200495A/es not_active IP Right Cessation
- 1992-02-05 PL PL92293388A patent/PL169873B1/pl unknown
- 1992-02-05 JP JP4020222A patent/JP2955109B2/ja not_active Expired - Fee Related
- 1992-02-05 CA CA002060745A patent/CA2060745C/en not_active Expired - Fee Related
- 1992-02-05 CZ CS1992330A patent/CZ289364B6/cs not_active IP Right Cessation
- 1992-02-05 SK SK330-92A patent/SK282383B6/sk unknown
- 1992-02-05 AU AU10764/92A patent/AU655795B2/en not_active Ceased
- 1992-02-05 BR BR929200402A patent/BR9200402A/pt not_active IP Right Cessation
- 1992-02-06 MA MA22701A patent/MA22414A1/fr unknown
- 1992-02-06 OA OA60143A patent/OA09534A/fr unknown
- 1992-02-06 KR KR1019920001721A patent/KR100201682B1/ko not_active Expired - Fee Related
- 1992-02-06 HU HU9200369A patent/HU213529B/hu not_active IP Right Cessation
1995
- 1995-03-15 US US08/404,940 patent/US5602177A/en not_active Expired - Fee Related
1996
- 1996-09-12 US US08/711,874 patent/US5703010A/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
DE59209497D1 (de)	1998-10-22
JPH04312501A (ja)	1992-11-04
MY109496A (en)	1997-02-28
CN1063794A (zh)	1992-08-26
AU655795B2 (en)	1995-01-12
CS33092A3 (en)	1992-09-16
HU213529B (en)	1997-07-28
JP2955109B2 (ja)	1999-10-04
HU9200369D0 (en)	1992-05-28
EG19693A (en)	1995-09-30
DK0498332T3 (da)	1999-06-14
ES2121795T3 (es)	1998-12-16
ATE171041T1 (de)	1998-10-15
IL100865A0 (en)	1992-11-15
MA22414A1 (fr)	1992-10-01
PL293388A1 (en)	1992-10-19
AU1076492A (en)	1992-08-13
OA09534A (fr)	1992-11-15
HUT60098A (en)	1992-08-28
KR100201682B1 (ko)	1999-06-15
EP0498332B1 (de)	1998-09-16
PL169873B1 (pl)	1996-09-30
MX9200495A (es)	1993-01-01
CZ289364B6 (cs)	2002-01-16
EP0498332A1 (de)	1992-08-12
SK282383B6 (sk)	2002-01-07
US5602177A (en)	1997-02-11
KR920016005A (ko)	1992-09-24
PH31574A (en)	1998-11-03
CA2060745A1 (en)	1992-08-07
BR9200402A (pt)	1992-10-13
DE4127757A1 (de)	1992-08-13
US5703010A (en)	1997-12-30
CA2060745C (en)	2002-11-26
TR28352A (tr)	1996-05-16
NZ241518A (en)	1994-09-27
CN1054494C (zh)	2000-07-19

Legal Events

Date	Code	Title
1999-01-26	FF	Patent granted
1999-08-17	KB	Patent renewed
2006-04-10	KB	Patent renewed
2010-12-30	MM9K	Patent not in force due to non-payment of renewal fees

Publication	Publication Date	Title
US5602177A (en)	1997-02-11	Formulations of deltamethrin
EP0839447B1 (en)	2004-08-25	Pesticidal emulsifiable concentrate
KR100266459B1 (ko)	2000-09-15	농약 마이크로캡슐 및 이의 제조방법
CA1252040A (en)	1989-04-04	Water-soluble pesticidal formulations
AU621218B2 (en)	1992-03-05	Emulsifiable pesticidal solid compositions
JP2813611B2 (ja)	1998-10-22	ラテックスを基剤とする農業用組成物
US5834006A (en)	1998-11-10	Latex-based agricultural compositions
JP3855321B2 (ja)	2006-12-06	農薬組成物
WO2000005951A1 (en)	2000-02-10	Base-triggered release microcapsules
JP3613420B2 (ja)	2005-01-26	有害生物防除マイクロカプセル組成物
FR2638940A1 (fr)	1990-05-18	Composition pesticide perfectionnee a action rapide et a activite residuelle
JP2993031B2 (ja)	1999-12-20	農薬固型乳剤
JPH03218301A (ja)	1991-09-25	改良された有害生物防除剤
JP2000510094A (ja)	2000-08-08	昆虫類防除用の乳化性組成物
HUP9904279A2 (hu)	2000-06-28	Szilárd mikrokapszulás készítmény
EP0755184B1 (fr)	1998-08-12	Nouvelles formulations pesticides et leur procede de preparation
JP2646597B2 (ja)	1997-08-27	安全かつ保存安定性に富む衛生害虫防除剤
CZ333692A3 (en)	1993-05-12	Water-dispersible granulates from suspended emulsions
JP4099288B2 (ja)	2008-06-11	農薬散布方法、農薬セット及び農薬組成物
RU2126207C1 (ru)	1999-02-20	Пестицидное средство в форме эмульгируемого в воде гранулята
JP2764155B2 (ja)	1998-06-11	水田投げ込み用製剤
JPH04352701A (ja)	1992-12-07	農薬用粒剤
JPH02275803A (ja)	1990-11-09	改良された有害生物防除製剤
JPH09124403A (ja)	1997-05-13	水面施用農薬液状製剤組成物及びその使用方法
JP2002037702A (ja)	2002-02-06	水性懸濁農薬組成物