IL96751A - Components and catalysts for the polymerization of olefins - Google Patents

Components and catalysts for the polymerization of olefins

Info

Publication number: IL96751A
Authority: IL; Israel
Prior art keywords: compound; component; polymerization; electron; catalyst
Prior art date: 1990-01-10

Application number

IL9675190A

Other languages

English (en)

Other versions

IL96751A0 (en

Original Assignee

Himont Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-01-10

Filing date

1990-12-21

Publication date

1994-05-30

1990-12-21 Application filed by Himont Inc filed Critical Himont Inc

1991-09-16 Publication of IL96751A0 publication Critical patent/IL96751A0/xx

1994-05-30 Publication of IL96751A publication Critical patent/IL96751A/en

Links

239000003054 catalyst Substances 0.000 title claims abstract description 65
238000006116 polymerization reaction Methods 0.000 title claims abstract description 39
150000001336 alkenes Chemical class 0.000 title claims abstract description 15
150000001875 compounds Chemical class 0.000 claims abstract description 43
-1 titanium halide Chemical class 0.000 claims abstract description 38
238000006243 chemical reaction Methods 0.000 claims abstract description 21
125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 17
229910044991 metal oxide Inorganic materials 0.000 claims abstract description 15
150000004706 metal oxides Chemical class 0.000 claims abstract description 15
239000010936 titanium Substances 0.000 claims abstract description 15
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
239000007787 solid Substances 0.000 claims abstract description 14
229910052719 titanium Inorganic materials 0.000 claims abstract description 12
150000003609 titanium compounds Chemical class 0.000 claims abstract description 9
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 5
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 27
239000011777 magnesium Substances 0.000 claims description 16
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical group Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 15
239000000377 silicon dioxide Substances 0.000 claims description 12
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 10
229910052749 magnesium Inorganic materials 0.000 claims description 9
150000002170 ethers Chemical class 0.000 claims description 8
229910052736 halogen Inorganic materials 0.000 claims description 8
150000002367 halogens Chemical class 0.000 claims description 8
229910052739 hydrogen Inorganic materials 0.000 claims description 8
239000001257 hydrogen Substances 0.000 claims description 8
150000005840 aryl radicals Chemical class 0.000 claims description 6
229910052799 carbon Inorganic materials 0.000 claims description 6
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 3
125000003118 aryl group Chemical group 0.000 claims description 3
125000000753 cycloalkyl group Chemical group 0.000 claims description 3
229910001623 magnesium bromide Inorganic materials 0.000 claims description 3
150000003377 silicon compounds Chemical class 0.000 claims description 3
125000000217 alkyl group Chemical group 0.000 claims description 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L magnesium chloride Substances [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 2
229910001629 magnesium chloride Inorganic materials 0.000 claims description 2
239000000395 magnesium oxide Substances 0.000 claims description 2
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 2
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 2
125000002877 alkyl aryl group Chemical group 0.000 claims 1
125000001183 hydrocarbyl group Chemical group 0.000 claims 1
150000003021 phthalic acid derivatives Chemical class 0.000 claims 1
150000003254 radicals Chemical class 0.000 claims 1
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 33
229920000642 polymer Polymers 0.000 description 18
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 17
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 16
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 14
239000005977 Ethylene Substances 0.000 description 14
238000000034 method Methods 0.000 description 13
239000000203 mixture Substances 0.000 description 11
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
229910003074 TiCl4 Inorganic materials 0.000 description 10
150000002681 magnesium compounds Chemical class 0.000 description 8
229910052757 nitrogen Inorganic materials 0.000 description 8
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 6
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
230000000694 effects Effects 0.000 description 6
150000002148 esters Chemical class 0.000 description 6
229930195733 hydrocarbon Natural products 0.000 description 6
150000002430 hydrocarbons Chemical class 0.000 description 6
238000002360 preparation method Methods 0.000 description 6
238000013019 agitation Methods 0.000 description 5
238000006722 reduction reaction Methods 0.000 description 5
239000000725 suspension Substances 0.000 description 5
YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 4
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 4
239000004215 Carbon black (E152) Substances 0.000 description 4
230000000052 comparative effect Effects 0.000 description 4
AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 description 4
239000000178 monomer Substances 0.000 description 4
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
239000004711 α-olefin Substances 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
239000000460 chlorine Substances 0.000 description 3
229910052801 chlorine Inorganic materials 0.000 description 3
150000001993 dienes Chemical class 0.000 description 3
MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 3
238000001914 filtration Methods 0.000 description 3
125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
239000007788 liquid Substances 0.000 description 3
239000001294 propane Substances 0.000 description 3
PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 2
RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 2
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
239000004743 Polypropylene Substances 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 2
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
239000008139 complexing agent Substances 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
239000007792 gaseous phase Substances 0.000 description 2
230000002140 halogenating effect Effects 0.000 description 2
125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 2
239000007791 liquid phase Substances 0.000 description 2
QUXHCILOWRXCEO-UHFFFAOYSA-M magnesium;butane;chloride Chemical compound [Mg+2].[Cl-].CCC[CH2-] QUXHCILOWRXCEO-UHFFFAOYSA-M 0.000 description 2
NXPHGHWWQRMDIA-UHFFFAOYSA-M magnesium;carbanide;bromide Chemical compound [CH3-].[Mg+2].[Br-] NXPHGHWWQRMDIA-UHFFFAOYSA-M 0.000 description 2
CCERQOYLJJULMD-UHFFFAOYSA-M magnesium;carbanide;chloride Chemical compound [CH3-].[Mg+2].[Cl-] CCERQOYLJJULMD-UHFFFAOYSA-M 0.000 description 2
HQDAZWQQKSJCTM-UHFFFAOYSA-M magnesium;octane;chloride Chemical compound [Mg+2].[Cl-].CCCCCCC[CH2-] HQDAZWQQKSJCTM-UHFFFAOYSA-M 0.000 description 2
OFOBLEOULBTSOW-UHFFFAOYSA-N malonic acid group Chemical group C(CC(=O)O)(=O)O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
125000004433 nitrogen atom Chemical group N* 0.000 description 2
239000002245 particle Substances 0.000 description 2
239000011949 solid catalyst Substances 0.000 description 2
239000002904 solvent Substances 0.000 description 2
238000003786 synthesis reaction Methods 0.000 description 2
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
239000008096 xylene Substances 0.000 description 2
MEPSBRTXOHFWCF-UHFFFAOYSA-N (2-cyclohexyl-1,3-dimethoxypropan-2-yl)cyclohexane Chemical compound C1CCCCC1C(COC)(COC)C1CCCCC1 MEPSBRTXOHFWCF-UHFFFAOYSA-N 0.000 description 1
HFVMEOPYDLEHBR-UHFFFAOYSA-N (2-fluorophenyl)-phenylmethanol Chemical compound C=1C=CC=C(F)C=1C(O)C1=CC=CC=C1 HFVMEOPYDLEHBR-UHFFFAOYSA-N 0.000 description 1
DYLIWHYUXAJDOJ-OWOJBTEDSA-N (e)-4-(6-aminopurin-9-yl)but-2-en-1-ol Chemical compound NC1=NC=NC2=C1N=CN2C\C=C\CO DYLIWHYUXAJDOJ-OWOJBTEDSA-N 0.000 description 1
KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 1
LTMRRSWNXVJMBA-UHFFFAOYSA-L 2,2-diethylpropanedioate Chemical compound CCC(CC)(C([O-])=O)C([O-])=O LTMRRSWNXVJMBA-UHFFFAOYSA-L 0.000 description 1
BUZICZZQJDLXJN-UHFFFAOYSA-N 3-azaniumyl-4-hydroxybutanoate Chemical compound OCC(N)CC(O)=O BUZICZZQJDLXJN-UHFFFAOYSA-N 0.000 description 1
RYWDKWWDJJOYEA-UHFFFAOYSA-N CCCC[Mg]OCC Chemical compound CCCC[Mg]OCC RYWDKWWDJJOYEA-UHFFFAOYSA-N 0.000 description 1
LZSVFVHNVQSIDJ-UHFFFAOYSA-N CC[Mg]OC Chemical compound CC[Mg]OC LZSVFVHNVQSIDJ-UHFFFAOYSA-N 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
235000021355 Stearic acid Nutrition 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
ZVGIBQMBZHWERX-UHFFFAOYSA-N [2-(cyclohexylmethyl)-3-methoxy-2-(methoxymethyl)propyl]cyclohexane Chemical compound C1CCCCC1CC(COC)(COC)CC1CCCCC1 ZVGIBQMBZHWERX-UHFFFAOYSA-N 0.000 description 1
OJDYQXBKQIDTEC-UHFFFAOYSA-M [Cl-].CC(C)CC[Mg+] Chemical compound [Cl-].CC(C)CC[Mg+] OJDYQXBKQIDTEC-UHFFFAOYSA-M 0.000 description 1
239000002253 acid Substances 0.000 description 1
159000000032 aromatic acids Chemical class 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
125000003710 aryl alkyl group Chemical group 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
WXCZUWHSJWOTRV-UHFFFAOYSA-N but-1-ene;ethene Chemical compound C=C.CCC=C WXCZUWHSJWOTRV-UHFFFAOYSA-N 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
239000006229 carbon black Substances 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
150000004653 carbonic acids Chemical class 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
150000001923 cyclic compounds Chemical class 0.000 description 1
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 1
230000002950 deficient Effects 0.000 description 1
238000007872 degassing Methods 0.000 description 1
FVAXOELGJXMINU-UHFFFAOYSA-N dicyclopentyl(diethoxy)silane Chemical compound C1CCCC1[Si](OCC)(OCC)C1CCCC1 FVAXOELGJXMINU-UHFFFAOYSA-N 0.000 description 1
IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 1
ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 1
DWNAQMUDCDVSLT-UHFFFAOYSA-N diphenyl phthalate Chemical compound C=1C=CC=C(C(=O)OC=2C=CC=CC=2)C=1C(=O)OC1=CC=CC=C1 DWNAQMUDCDVSLT-UHFFFAOYSA-N 0.000 description 1
229920001198 elastomeric copolymer Polymers 0.000 description 1
HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
HHEIMYAXCOIQCJ-UHFFFAOYSA-N ethyl 2,2-dimethylpropanoate Chemical compound CCOC(=O)C(C)(C)C HHEIMYAXCOIQCJ-UHFFFAOYSA-N 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
YCNSGSUGQPDYTK-UHFFFAOYSA-N ethyl phenyl carbonate Chemical compound CCOC(=O)OC1=CC=CC=C1 YCNSGSUGQPDYTK-UHFFFAOYSA-N 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
230000009969 flowable effect Effects 0.000 description 1
238000009472 formulation Methods 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
AHAREKHAZNPPMI-UHFFFAOYSA-N hexadiene group Chemical group C=CC=CCC AHAREKHAZNPPMI-UHFFFAOYSA-N 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
238000009776 industrial production Methods 0.000 description 1
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
150000002596 lactones Chemical class 0.000 description 1
239000000391 magnesium silicate Substances 0.000 description 1
229910052919 magnesium silicate Inorganic materials 0.000 description 1
235000019792 magnesium silicate Nutrition 0.000 description 1
YSMZEMQBSONIMJ-UHFFFAOYSA-M magnesium;2-methanidylpropane;chloride Chemical compound [Mg+2].[Cl-].CC(C)[CH2-] YSMZEMQBSONIMJ-UHFFFAOYSA-M 0.000 description 1
UGVPKMAWLOMPRS-UHFFFAOYSA-M magnesium;propane;bromide Chemical compound [Mg+2].[Br-].CC[CH2-] UGVPKMAWLOMPRS-UHFFFAOYSA-M 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
230000000877 morphologic effect Effects 0.000 description 1
125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
239000012299 nitrogen atmosphere Substances 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
239000003921 oil Substances 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
125000004437 phosphorous atom Chemical group 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
IUGYQRQAERSCNH-UHFFFAOYSA-N pivalic acid Chemical compound CC(C)(C)C(O)=O IUGYQRQAERSCNH-UHFFFAOYSA-N 0.000 description 1
125000005546 pivalic acid group Chemical group 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
229920005606 polypropylene copolymer Polymers 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
230000001105 regulatory effect Effects 0.000 description 1
238000009877 rendering Methods 0.000 description 1
APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
239000008117 stearic acid Substances 0.000 description 1
239000010959 steel Substances 0.000 description 1
230000000707 stereoselective effect Effects 0.000 description 1
150000003444 succinic acids Chemical class 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
125000004434 sulfur atom Chemical group 0.000 description 1
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
NETBVGNWMHLXRP-UHFFFAOYSA-N tert-butyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C(C)(C)C NETBVGNWMHLXRP-UHFFFAOYSA-N 0.000 description 1
ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
229910003452 thorium oxide Inorganic materials 0.000 description 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
238000004448 titration Methods 0.000 description 1
JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

IL9675190A 1990-01-10 1990-12-21 Components and catalysts for the polymerization of olefins IL96751A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
IT01903090A IT1238387B (it)	1990-01-10	1990-01-10	Componenti e catalizzatori per la polimerizzazione di olefine

Publications (2)

Publication Number	Publication Date
IL96751A0 IL96751A0 (en)	1991-09-16
IL96751A true IL96751A (en)	1994-05-30

Family

ID=11153964

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IL9675190A IL96751A (en)	1990-01-10	1990-12-21	Components and catalysts for the polymerization of olefins

Country Status (28)

Country	Link
US (1)	US5064799A (de)
EP (1)	EP0437264B1 (de)
JP (1)	JP2974797B2 (de)
KR (1)	KR100191184B1 (de)
CN (1)	CN1040118C (de)
AR (1)	AR246276A1 (de)
AT (1)	ATE128989T1 (de)
AU (1)	AU644123B2 (de)
BR (1)	BR9100090A (de)
CA (1)	CA2033809A1 (de)
CZ (1)	CZ280319B6 (de)
DE (1)	DE69113642T2 (de)
DK (1)	DK0437264T3 (de)
ES (1)	ES2079495T3 (de)
FI (1)	FI99117C (de)
HU (1)	HU212193B (de)
IL (1)	IL96751A (de)
IT (1)	IT1238387B (de)
MX (1)	MX24036A (de)
NO (1)	NO177229C (de)
PH (1)	PH27438A (de)
PL (1)	PL288636A1 (de)
PT (1)	PT96459B (de)
RO (1)	RO107124B1 (de)
RU (1)	RU2050365C1 (de)
TW (1)	TW199169B (de)
YU (1)	YU1691A (de)
ZA (1)	ZA9150B (de)

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JP4820376B2 (ja)	2005-01-13	2011-11-24	ドナルドソンカンパニー，インコーポレイティド	エアフィルタカートリッジ及びエアクリーナ装置
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1990
- 1990-01-10 IT IT01903090A patent/IT1238387B/it active IP Right Grant
- 1990-12-21 IL IL9675190A patent/IL96751A/en not_active IP Right Cessation
- 1990-12-28 MX MX24036A patent/MX24036A/es unknown
1991
- 1991-01-02 PH PH41809A patent/PH27438A/en unknown
- 1991-01-03 ZA ZA9150A patent/ZA9150B/xx unknown
- 1991-01-04 US US07/637,407 patent/US5064799A/en not_active Expired - Lifetime
- 1991-01-04 AU AU68659/91A patent/AU644123B2/en not_active Ceased
- 1991-01-08 AR AR91318799A patent/AR246276A1/es active
- 1991-01-08 YU YU1691A patent/YU1691A/sh unknown
- 1991-01-08 CA CA002033809A patent/CA2033809A1/en not_active Abandoned
- 1991-01-09 TW TW080100159A patent/TW199169B/zh active
- 1991-01-09 RU SU914894254A patent/RU2050365C1/ru active
- 1991-01-09 PL PL28863691A patent/PL288636A1/xx unknown
- 1991-01-09 NO NO910096A patent/NO177229C/no not_active IP Right Cessation
- 1991-01-09 HU HU9157A patent/HU212193B/hu not_active IP Right Cessation
- 1991-01-10 BR BR919100090A patent/BR9100090A/pt not_active IP Right Cessation
- 1991-01-10 JP JP3012886A patent/JP2974797B2/ja not_active Expired - Fee Related
- 1991-01-10 KR KR1019910000277A patent/KR100191184B1/ko not_active Expired - Fee Related
- 1991-01-10 FI FI910138A patent/FI99117C/fi not_active IP Right Cessation
- 1991-01-10 AT AT91100271T patent/ATE128989T1/de not_active IP Right Cessation
- 1991-01-10 EP EP91100271A patent/EP0437264B1/de not_active Expired - Lifetime
- 1991-01-10 CN CN91100085A patent/CN1040118C/zh not_active Expired - Fee Related
- 1991-01-10 DK DK91100271.5T patent/DK0437264T3/da active
- 1991-01-10 PT PT96459A patent/PT96459B/pt not_active IP Right Cessation
- 1991-01-10 DE DE69113642T patent/DE69113642T2/de not_active Expired - Fee Related
- 1991-01-10 CZ CS9147A patent/CZ280319B6/cs unknown
- 1991-01-10 RO RO146711A patent/RO107124B1/ro unknown
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Also Published As

Publication number	Publication date
HU910057D0 (en)	1991-08-28
ES2079495T3 (es)	1996-01-16
FI99117B (fi)	1997-06-30
IT9019030A0 (it)	1990-01-10
US5064799A (en)	1991-11-12
IL96751A0 (en)	1991-09-16
BR9100090A (pt)	1991-10-22
JP2974797B2 (ja)	1999-11-10
DK0437264T3 (da)	1996-02-05
KR100191184B1 (ko)	1999-06-15
AR246276A1 (es)	1994-07-29
AU644123B2 (en)	1993-12-02
FI99117C (fi)	1997-10-10
NO910096D0 (no)	1991-01-09
AU6865991A (en)	1991-07-11
TW199169B (de)	1993-02-01
CA2033809A1 (en)	1991-07-11
HUT60294A (en)	1992-08-28
ZA9150B (en)	1991-10-30
EP0437264B1 (de)	1995-10-11
YU1691A (sh)	1994-05-10
PT96459A (pt)	1991-10-31
FI910138L (fi)	1991-07-11
DE69113642T2 (de)	1996-03-21
RU2050365C1 (ru)	1995-12-20
IT9019030A1 (it)	1991-07-11
ATE128989T1 (de)	1995-10-15
NO177229B (no)	1995-05-02
JPH0625331A (ja)	1994-02-01
KR910014403A (ko)	1991-08-31
HU212193B (en)	1996-03-28
PT96459B (pt)	1998-06-30
NO177229C (no)	1995-08-09
CN1053240A (zh)	1991-07-24
PL288636A1 (en)	1992-02-10
RO107124B1 (ro)	1993-09-30
CN1040118C (zh)	1998-10-07
CZ280319B6 (cs)	1995-12-13
MX24036A (es)	1994-03-31
PH27438A (en)	1993-07-02
FI910138A0 (fi)	1991-01-10
EP0437264A1 (de)	1991-07-17
IT1238387B (it)	1993-07-16
CS9100047A2 (en)	1991-09-15
NO910096L (no)	1991-07-11
DE69113642D1 (de)	1995-11-16

Legal Events

Date	Code	Title
1997-03-18	KB	Patent renewed
1997-11-20	HC	Change of name of proprietor(s)
2001-04-30	KB	Patent renewed
2005-09-25	MM9K	Patent not in force due to non-payment of renewal fees

Publication	Publication Date	Title
IL96751A (en)	1994-05-30	Components and catalysts for the polymerization of olefins
US5244854A (en)	1993-09-14	Components and catalysts for the polymerization of olefins
EP0417346B1 (de)	1997-04-16	Verfahren zur Herstellung eines festen Katalysators zur Anwendung in der Olefinpolymerisation
AU645896B2 (en)	1994-01-27	Components and catalysts for the polymerization of olefins
US6228792B1 (en)	2001-05-08	Donor-modified olefin polymerization catalysts
US4499247A (en)	1985-02-12	High-rigidity, high-melt-viscoelasticity polypropylene and process for producing the same
JPH01167311A (ja)	1989-07-03	プロピレン重合体およびその製造方法
EP0347442A1 (de)	1989-12-27	Auf modifizierte silika basierender katalysator
JP3352754B2 (ja)	2002-12-03	オレフィン重合用触媒系、この重合のための方法及び得られたポリマー
US5037789A (en)	1991-08-06	Non-supported catalyst
US4533706A (en)	1985-08-06	Catalyst and process using same for producing olefin polymer
JPH0410889B2 (de)	1992-02-26
US5412025A (en)	1995-05-02	Method to reactor-fill polyolefins by employing a sticky prepolymer as a blending and compatibilizing agent
WO2003089483A1 (en)	2003-10-30	Propylene polymerization process with enhanced catalyst activity
US4988782A (en)	1991-01-29	Alkene polymerization process and catalyst compositions therefor
JPH0618821B2 (ja)	1994-03-16	オレフイン重合用触媒の製法および用法
JPH07278380A (ja)	1995-10-24	ポリプロピレン樹脂組成物
JPH0971697A (ja)	1997-03-18	ポリプロピレン樹脂組成物
JPH09104793A (ja)	1997-04-22	ポリプロピレン樹脂組成物
PL180028B1 (pl)	2000-12-29	Sposób polimeryzacji propylenu
JPH07268143A (ja)	1995-10-17	ポリプロピレン樹脂組成物
JPH06136055A (ja)	1994-05-17	ポリプロピレンの製造方法
JPH06306115A (ja)	1994-11-01	オレフィン重合用触媒