JPH0129498B2 - - Google Patents
Info
- Publication number
- JPH0129498B2 JPH0129498B2 JP61169971A JP16997186A JPH0129498B2 JP H0129498 B2 JPH0129498 B2 JP H0129498B2 JP 61169971 A JP61169971 A JP 61169971A JP 16997186 A JP16997186 A JP 16997186A JP H0129498 B2 JPH0129498 B2 JP H0129498B2
- Authority
- JP
- Japan
- Prior art keywords
- polyester
- weight
- polycarbonate
- bis
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000728 polyester Polymers 0.000 claims description 177
- 229920000515 polycarbonate Polymers 0.000 claims description 131
- 239000004417 polycarbonate Substances 0.000 claims description 131
- 150000002009 diols Chemical class 0.000 claims description 65
- 238000000034 method Methods 0.000 claims description 38
- 239000000203 mixture Substances 0.000 claims description 26
- 238000004519 manufacturing process Methods 0.000 claims description 23
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 claims description 20
- 230000008569 process Effects 0.000 claims description 19
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 claims description 18
- 238000006243 chemical reaction Methods 0.000 claims description 18
- 239000003960 organic solvent Substances 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 5
- 125000001931 aliphatic group Chemical group 0.000 claims description 5
- 238000006068 polycondensation reaction Methods 0.000 claims description 5
- 150000003512 tertiary amines Chemical class 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- GQWWGRUJOCIUKI-UHFFFAOYSA-N 2-[3-(2-methyl-1-oxopyrrolo[1,2-a]pyrazin-3-yl)propyl]guanidine Chemical compound O=C1N(C)C(CCCN=C(N)N)=CN2C=CC=C21 GQWWGRUJOCIUKI-UHFFFAOYSA-N 0.000 claims 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 95
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 39
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 30
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 26
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 24
- 239000003054 catalyst Substances 0.000 description 23
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 22
- 239000000243 solution Substances 0.000 description 22
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 21
- 239000012071 phase Substances 0.000 description 19
- -1 hydroxyaryl compound Chemical class 0.000 description 17
- 150000002148 esters Chemical class 0.000 description 15
- 230000008018 melting Effects 0.000 description 15
- 238000002844 melting Methods 0.000 description 15
- 229920000642 polymer Polymers 0.000 description 15
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 14
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 14
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 12
- 229910052757 nitrogen Inorganic materials 0.000 description 12
- 229920001169 thermoplastic Polymers 0.000 description 12
- 239000004416 thermosoftening plastic Substances 0.000 description 12
- 239000001361 adipic acid Substances 0.000 description 11
- 235000011037 adipic acid Nutrition 0.000 description 11
- 229920005906 polyester polyol Polymers 0.000 description 11
- 238000003756 stirring Methods 0.000 description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 10
- 239000002904 solvent Substances 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 239000012074 organic phase Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 239000007858 starting material Substances 0.000 description 9
- 239000007795 chemical reaction product Substances 0.000 description 7
- 239000000460 chlorine Substances 0.000 description 7
- 238000004455 differential thermal analysis Methods 0.000 description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 6
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 6
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 6
- 125000003118 aryl group Chemical group 0.000 description 6
- OASFYFTVWALXTH-UHFFFAOYSA-L disodium;diphenoxide Chemical compound [Na+].[Na+].[O-]C1=CC=CC=C1.[O-]C1=CC=CC=C1 OASFYFTVWALXTH-UHFFFAOYSA-L 0.000 description 6
- 238000000926 separation method Methods 0.000 description 6
- NESLWCLHZZISNB-UHFFFAOYSA-M sodium phenolate Chemical compound [Na+].[O-]C1=CC=CC=C1 NESLWCLHZZISNB-UHFFFAOYSA-M 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- ODJUOZPKKHIEOZ-UHFFFAOYSA-N 4-[2-(4-hydroxy-3,5-dimethylphenyl)propan-2-yl]-2,6-dimethylphenol Chemical compound CC1=C(O)C(C)=CC(C(C)(C)C=2C=C(C)C(O)=C(C)C=2)=C1 ODJUOZPKKHIEOZ-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 5
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 5
- 238000005227 gel permeation chromatography Methods 0.000 description 5
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 5
- AZUYLZMQTIKGSC-UHFFFAOYSA-N 1-[6-[4-(5-chloro-6-methyl-1H-indazol-4-yl)-5-methyl-3-(1-methylindazol-5-yl)pyrazol-1-yl]-2-azaspiro[3.3]heptan-2-yl]prop-2-en-1-one Chemical compound ClC=1C(=C2C=NNC2=CC=1C)C=1C(=NN(C=1C)C1CC2(CN(C2)C(C=C)=O)C1)C=1C=C2C=NN(C2=CC=1)C AZUYLZMQTIKGSC-UHFFFAOYSA-N 0.000 description 4
- QHPQWRBYOIRBIT-UHFFFAOYSA-N 4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C=C1 QHPQWRBYOIRBIT-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 4
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 4
- 239000012153 distilled water Substances 0.000 description 4
- 230000009477 glass transition Effects 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 4
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 4
- 239000012299 nitrogen atmosphere Substances 0.000 description 4
- 238000005809 transesterification reaction Methods 0.000 description 4
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 4
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 4
- WDYVUKGVKRZQNM-UHFFFAOYSA-N 6-phosphonohexylphosphonic acid Chemical compound OP(O)(=O)CCCCCCP(O)(O)=O WDYVUKGVKRZQNM-UHFFFAOYSA-N 0.000 description 3
- 229930185605 Bisphenol Natural products 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 238000012696 Interfacial polycondensation Methods 0.000 description 3
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000000149 argon plasma sintering Methods 0.000 description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 3
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 3
- ARXKVVRQIIOZGF-UHFFFAOYSA-N 1,2,4-butanetriol Chemical compound OCCC(O)CO ARXKVVRQIIOZGF-UHFFFAOYSA-N 0.000 description 2
- UIAFKZKHHVMJGS-UHFFFAOYSA-N 2,4-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1O UIAFKZKHHVMJGS-UHFFFAOYSA-N 0.000 description 2
- NXXYKOUNUYWIHA-UHFFFAOYSA-N 2,6-Dimethylphenol Chemical compound CC1=CC=CC(C)=C1O NXXYKOUNUYWIHA-UHFFFAOYSA-N 0.000 description 2
- BLDLRWQLBOJPEB-UHFFFAOYSA-N 2-(2-hydroxyphenyl)sulfanylphenol Chemical compound OC1=CC=CC=C1SC1=CC=CC=C1O BLDLRWQLBOJPEB-UHFFFAOYSA-N 0.000 description 2
- XBQRPFBBTWXIFI-UHFFFAOYSA-N 2-chloro-4-[2-(3-chloro-4-hydroxyphenyl)propan-2-yl]phenol Chemical compound C=1C=C(O)C(Cl)=CC=1C(C)(C)C1=CC=C(O)C(Cl)=C1 XBQRPFBBTWXIFI-UHFFFAOYSA-N 0.000 description 2
- NIRYBKWMEWFDPM-UHFFFAOYSA-N 4-[3-(4-hydroxyphenyl)-3-methylbutyl]phenol Chemical compound C=1C=C(O)C=CC=1C(C)(C)CCC1=CC=C(O)C=C1 NIRYBKWMEWFDPM-UHFFFAOYSA-N 0.000 description 2
- SDDLEVPIDBLVHC-UHFFFAOYSA-N Bisphenol Z Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)CCCCC1 SDDLEVPIDBLVHC-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- KYPYTERUKNKOLP-UHFFFAOYSA-N Tetrachlorobisphenol A Chemical compound C=1C(Cl)=C(O)C(Cl)=CC=1C(C)(C)C1=CC(Cl)=C(O)C(Cl)=C1 KYPYTERUKNKOLP-UHFFFAOYSA-N 0.000 description 2
- 239000003377 acid catalyst Substances 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 150000007860 aryl ester derivatives Chemical class 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical group C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920001610 polycaprolactone Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 230000001376 precipitating effect Effects 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- 150000003510 tertiary aliphatic amines Chemical class 0.000 description 2
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- JZZBTMVTLBHJHL-UHFFFAOYSA-N tris(2,3-dichloropropyl) phosphate Chemical compound ClCC(Cl)COP(=O)(OCC(Cl)CCl)OCC(Cl)CCl JZZBTMVTLBHJHL-UHFFFAOYSA-N 0.000 description 2
- 235000005074 zinc chloride Nutrition 0.000 description 2
- 239000011592 zinc chloride Substances 0.000 description 2
- ZYPNBSUWRMDKPK-UHFFFAOYSA-N (2,3-dichlorophenyl) hydrogen carbonate Chemical compound OC(=O)OC1=CC=CC(Cl)=C1Cl ZYPNBSUWRMDKPK-UHFFFAOYSA-N 0.000 description 1
- SLYBYYOFYNYTAY-UHFFFAOYSA-N (2-chloro-3-phenylphenyl) hydrogen carbonate Chemical compound OC(=O)OC1=CC=CC(C=2C=CC=CC=2)=C1Cl SLYBYYOFYNYTAY-UHFFFAOYSA-N 0.000 description 1
- ZGSHFDSKHTZINF-UHFFFAOYSA-N (2-methyl-6-phenylphenyl) hydrogen carbonate Chemical compound CC1=CC=CC(C=2C=CC=CC=2)=C1OC(O)=O ZGSHFDSKHTZINF-UHFFFAOYSA-N 0.000 description 1
- MUTGBJKUEZFXGO-OLQVQODUSA-N (3as,7ar)-3a,4,5,6,7,7a-hexahydro-2-benzofuran-1,3-dione Chemical compound C1CCC[C@@H]2C(=O)OC(=O)[C@@H]21 MUTGBJKUEZFXGO-OLQVQODUSA-N 0.000 description 1
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- DEIGXXQKDWULML-UHFFFAOYSA-N 1,2,5,6,9,10-hexabromocyclododecane Chemical compound BrC1CCC(Br)C(Br)CCC(Br)C(Br)CCC1Br DEIGXXQKDWULML-UHFFFAOYSA-N 0.000 description 1
- ZWVMLYRJXORSEP-UHFFFAOYSA-N 1,2,6-Hexanetriol Chemical compound OCCCCC(O)CO ZWVMLYRJXORSEP-UHFFFAOYSA-N 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- YIYBRXKMQFDHSM-UHFFFAOYSA-N 2,2'-Dihydroxybenzophenone Chemical class OC1=CC=CC=C1C(=O)C1=CC=CC=C1O YIYBRXKMQFDHSM-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- CMQUQOHNANGDOR-UHFFFAOYSA-N 2,3-dibromo-4-(2,4-dibromo-5-hydroxyphenyl)phenol Chemical compound BrC1=C(Br)C(O)=CC=C1C1=CC(O)=C(Br)C=C1Br CMQUQOHNANGDOR-UHFFFAOYSA-N 0.000 description 1
- VPVTXVHUJHGOCM-UHFFFAOYSA-N 2,4-bis[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound C=1C=C(O)C(C(C)(C)C=2C=CC(O)=CC=2)=CC=1C(C)(C)C1=CC=C(O)C=C1 VPVTXVHUJHGOCM-UHFFFAOYSA-N 0.000 description 1
- MAQOZOILPAMFSW-UHFFFAOYSA-N 2,6-bis[(2-hydroxy-5-methylphenyl)methyl]-4-methylphenol Chemical compound CC1=CC=C(O)C(CC=2C(=C(CC=3C(=CC=C(C)C=3)O)C=C(C)C=2)O)=C1 MAQOZOILPAMFSW-UHFFFAOYSA-N 0.000 description 1
- VXHYVVAUHMGCEX-UHFFFAOYSA-N 2-(2-hydroxyphenoxy)phenol Chemical class OC1=CC=CC=C1OC1=CC=CC=C1O VXHYVVAUHMGCEX-UHFFFAOYSA-N 0.000 description 1
- XSVZEASGNTZBRQ-UHFFFAOYSA-N 2-(2-hydroxyphenyl)sulfinylphenol Chemical class OC1=CC=CC=C1S(=O)C1=CC=CC=C1O XSVZEASGNTZBRQ-UHFFFAOYSA-N 0.000 description 1
- QUWAJPZDCZDTJS-UHFFFAOYSA-N 2-(2-hydroxyphenyl)sulfonylphenol Chemical class OC1=CC=CC=C1S(=O)(=O)C1=CC=CC=C1O QUWAJPZDCZDTJS-UHFFFAOYSA-N 0.000 description 1
- QWGRWMMWNDWRQN-UHFFFAOYSA-N 2-methylpropane-1,3-diol Chemical compound OCC(C)CO QWGRWMMWNDWRQN-UHFFFAOYSA-N 0.000 description 1
- WJQOZHYUIDYNHM-UHFFFAOYSA-N 2-tert-Butylphenol Chemical compound CC(C)(C)C1=CC=CC=C1O WJQOZHYUIDYNHM-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 1
- OWDLYRXJLSPCHE-UHFFFAOYSA-N 3-[1,1-bis(3-hydroxyphenyl)ethyl]phenol Chemical compound C=1C=CC(O)=CC=1C(C=1C=C(O)C=CC=1)(C)C1=CC=CC(O)=C1 OWDLYRXJLSPCHE-UHFFFAOYSA-N 0.000 description 1
- SBCIIUZBBJJGOY-UHFFFAOYSA-N 3-[4,6-bis(3-hydroxyphenyl)-4,6-dimethylhept-2-en-2-yl]phenol Chemical compound C=1C=CC(O)=CC=1C(C)=CC(C)(C=1C=C(O)C=CC=1)CC(C)(C)C1=CC=CC(O)=C1 SBCIIUZBBJJGOY-UHFFFAOYSA-N 0.000 description 1
- XJGTVJRTDRARGO-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)propan-2-yl]benzene-1,3-diol Chemical compound C=1C=C(O)C=C(O)C=1C(C)(C)C1=CC=C(O)C=C1 XJGTVJRTDRARGO-UHFFFAOYSA-N 0.000 description 1
- RQTDWDATSAVLOR-UHFFFAOYSA-N 4-[3,5-bis(4-hydroxyphenyl)phenyl]phenol Chemical compound C1=CC(O)=CC=C1C1=CC(C=2C=CC(O)=CC=2)=CC(C=2C=CC(O)=CC=2)=C1 RQTDWDATSAVLOR-UHFFFAOYSA-N 0.000 description 1
- CIEGINNQDIULCT-UHFFFAOYSA-N 4-[4,6-bis(4-hydroxyphenyl)-4,6-dimethylheptan-2-yl]phenol Chemical compound C=1C=C(O)C=CC=1C(C)CC(C)(C=1C=CC(O)=CC=1)CC(C)(C)C1=CC=C(O)C=C1 CIEGINNQDIULCT-UHFFFAOYSA-N 0.000 description 1
- LIDWAYDGZUAJEG-UHFFFAOYSA-N 4-[bis(4-hydroxyphenyl)-phenylmethyl]phenol Chemical compound C1=CC(O)=CC=C1C(C=1C=CC(O)=CC=1)(C=1C=CC(O)=CC=1)C1=CC=CC=C1 LIDWAYDGZUAJEG-UHFFFAOYSA-N 0.000 description 1
- GZFGOTFRPZRKDS-UHFFFAOYSA-N 4-bromophenol Chemical compound OC1=CC=C(Br)C=C1 GZFGOTFRPZRKDS-UHFFFAOYSA-N 0.000 description 1
- KNDQHSIWLOJIGP-UHFFFAOYSA-N 826-62-0 Chemical compound C1C2C3C(=O)OC(=O)C3C1C=C2 KNDQHSIWLOJIGP-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 229910004261 CaF 2 Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- QHWKHLYUUZGSCW-UHFFFAOYSA-N Tetrabromophthalic anhydride Chemical compound BrC1=C(Br)C(Br)=C2C(=O)OC(=O)C2=C1Br QHWKHLYUUZGSCW-UHFFFAOYSA-N 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N Tetraethylene glycol, Natural products OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- JOZSCPCCPRBYNA-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol;[4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1.OCC1(CO)CCCCC1 JOZSCPCCPRBYNA-UHFFFAOYSA-N 0.000 description 1
- LJCTUEPREAVQFG-UHFFFAOYSA-N [4-methyl-3-(2-methylphenyl)phenyl] hydrogen carbonate Chemical compound CC1=CC=CC=C1C1=CC(OC(O)=O)=CC=C1C LJCTUEPREAVQFG-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 1
- DAMJCWMGELCIMI-UHFFFAOYSA-N benzyl n-(2-oxopyrrolidin-3-yl)carbamate Chemical compound C=1C=CC=CC=1COC(=O)NC1CCNC1=O DAMJCWMGELCIMI-UHFFFAOYSA-N 0.000 description 1
- 229940114055 beta-resorcylic acid Drugs 0.000 description 1
- 229920000402 bisphenol A polycarbonate polymer Polymers 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- MXTOFRMIIQQSOE-UHFFFAOYSA-N butane;titanium(4+) Chemical compound [Ti+4].CCC[CH2-].CCC[CH2-].CCC[CH2-].CCC[CH2-] MXTOFRMIIQQSOE-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- ULSJTMWWIWWXIW-UHFFFAOYSA-N carbonic acid;phenol Chemical compound OC(O)=O.OC1=CC=CC=C1.OC1=CC=CC=C1 ULSJTMWWIWWXIW-UHFFFAOYSA-N 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- VKONPUDBRVKQLM-UHFFFAOYSA-N cyclohexane-1,4-diol Chemical compound OC1CCC(O)CC1 VKONPUDBRVKQLM-UHFFFAOYSA-N 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 229940117389 dichlorobenzene Drugs 0.000 description 1
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N dimethylmethane Natural products CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 1
- FCVCFERLLIDEQL-UHFFFAOYSA-N diphenyl carbonate;hexane-1,6-diol Chemical compound OCCCCCCO.C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 FCVCFERLLIDEQL-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000004508 fractional distillation Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- VANNPISTIUFMLH-UHFFFAOYSA-N glutaric anhydride Chemical compound O=C1CCCC(=O)O1 VANNPISTIUFMLH-UHFFFAOYSA-N 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- SJDACOMXKWHBOW-UHFFFAOYSA-N oxyphenisatine Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2NC1=O SJDACOMXKWHBOW-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 230000005501 phase interface Effects 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- AUHHYELHRWCWEZ-UHFFFAOYSA-N tetrachlorophthalic anhydride Chemical compound ClC1=C(Cl)C(Cl)=C2C(=O)OC(=O)C2=C1Cl AUHHYELHRWCWEZ-UHFFFAOYSA-N 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 description 1
- 229950006389 thiodiglycol Drugs 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/64—Polyesters containing both carboxylic ester groups and carbonate groups
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
Description
æ¬çºæã¯ãããªãšã¹ãã«ïŒããªã«ãŒãããŒãã®
補é æ³ã«é¢ããã ç¬åœå ¬éç¹èš±ç¬¬2651639å·ã«åŸã€ãŠè£œé ããã
ããªãšã¹ãã«ãžãªãŒã«ãã¹âã¢ãªãŒã«ã«ãŒãããŒ
ããéå°ã®ãžããšããŒã«ãšãšã¹ãã«äº€æããŠå¯Ÿå¿
ããããªãšã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«ã«
ãŒãããŒãã補é ããåå¿ã¯ã200âãŸã§ã®åå¿
枩床ã«ãããŠã§ãããé©ãã»ã©å¹³æ»ã«äžã€å¯åå¿
ããªãé²è¡ãããæŽã«åºçºç©è³ªã«ãã€ãŠäžããã
ãååéååžã¯å€åãããããªãšã¹ãã«âããªãª
ãŒã«ã¯åçãããåã³ããªã«ãŒãããŒããžã®éçž®
åã¯èµ·ãããªãã  ããªãšã¹ãã«ãžãªãŒã«ãã¹âã¢ãªãŒã«ã«ãŒã
ããŒãã®è£œé æ¬çºæã§äœ¿çšããããªãšã¹ãã«ãžãªãŒã«ãã¹â
ãžããšããŒã«ã«ãŒãããŒãã®è£œé ã«å¿ èŠãªããªãš
ã¹ãã«ãžãªãŒã«ãã¹âã¢ãªãŒã«ã«ãŒãããŒãã¯ã
ç¬åœå ¬éç¹èš±ç¬¬2651639å·ã«åŸã€ãŠè£œé ãããã ç¬åœå ¬éç¹èš±ç¬¬2951639å·ã¯ãçŽ250以äžã奜ãŸ
ããã¯çŽ600以äžã®ååéïœïŒæ°å¹³åïŒãæãã
ããªãšã¹ãã«ããªãªãŒã«ãçé žãã¹âã¢ãªãŒã«ãš
ã¹ãã«ãšå ±ã«è§Šåªã®ååšäžåã³çŽ35mmHg以äžã
奜ãŸããã¯çŽ25ã0.1mmHgã®ç空äžã«çŽ100ã200
âã奜ãŸããã¯çŽ100ã180âã®æž©åºŠã«å ç±ããäœ
ãããªãšã¹ãã«ããªãªãŒã«ã®OHåºåœãïŒã¢ã«ã
ãå€ãã奜ãŸããã¯çŽ1.25ã2.25ã¢ã«ã®çé žãã¹
âã¢ãªãŒã«ãšã¹ãã«ãçšããåã³çæããããã
ãã·ã¢ãªãŒã«ååç©åã³éå°ã®çé žãã¹âã¢ãªãŒ
ã«ãšã¹ãã«ãçå»ãããçŽ250以äžã奜ãŸããã¯
çŽ600以äžã®ïœãæããããªãšã¹ãã«ããªãªãŒ
ã«ã®çé žã¢ãªãŒã«ãšã¹ãã«ã®è£œé æ³ã«é¢ãããã®
ã§ããã æŽã«ç¬åœå ¬éç¹èš±ç¬¬2651639å·ã¯ããã®æ¹æ³ã§
補é ãããããªãšã¹ãã«ããªãªãŒã«ã®çé žãšã¹ã
ã«ã«ãé¢ããã äžèšæ¹æ³ã«å¯ŸããŠç¹ã«å¥œé©ãªããªãšã¹ãã«ããª
ãªãŒã«ã¯ããªãšã¹ãã«âãžãªãŒã«ã§ããã äžèšæ¹æ³ã§çšããããªãšã¹ãã«ããªãªãŒã«ã¯ã
äŸãã°å€äŸ¡ã奜ãŸããã¯ïŒäŸ¡åã³æŽã«éæïŒäŸ¡ã®
ã¢ã«ã³ãŒã«ãšå€å¡©åºæ§ããŸããã¯ïŒå¡©åºæ§ã®ã«ã«
ãã³é žãšã®åå¿çæç©ã§ãããããªãšã¹ãã«ããª
ãªãŒã«ã®è£œé ã«ã¯ãéé¢ã®ããªã«ã«ãã³é žã®ä»£ã
ã«å¯Ÿå¿ããããªã«ã«ãã³é žç¡æ°Žç©æãã¯å¯Ÿå¿ãã
ããªã«ã«ãã³é žãšäœçŽã¢ã«ã³ãŒã«ãšã®ãšã¹ãã«ã
åã³ãããã®æ··åç©ã䜿çšã§ãããããªã«ã«ãã³
é žã®äŸã¯ãèèªæãèç°æãè³éŠæåã³ïŒåã¯ã
ããç°æã®ãã®ã§ãã€ãŠãããäžã€äŸãã°ããã²
ã³ååã§çœ®æãããŠããŠãåã³ïŒåã¯äžé£œåã§ã
ã€ãŠãããããããã®äŸã¯ãã·ãŠãŠé žãããã³
é žãã³ãã¯é žãã¢ãžãã³é žãã¹ããªã³é žãã¢ãŒã©
ã€ã³é žãã»ãã·ã³é žããã¿ã«é žããã¬ãã¿ã«é žã
ããªã¡ãªããé žãç¡æ°Žãã¿ã«é žãããã©ãããã
ã¿ã«é žç¡æ°Žç©ããããµããããã¿ã«é žç¡æ°Žç©ãã
ãã©ã¯ãã«ãã¿ã«é žç¡æ°Žç©ããšã³ãã¡ãã¬ã³ãã
ã©ããããã¿ã«é žç¡æ°Žç©ãã°ã«ã¿ã«é žç¡æ°Žç©ãã
ã¬ã€ã³é žãç¡æ°Žãã¬ã€ã³é žãããã«é žåã³ïŒéäœ
åã³ïŒéäœã®èèªé žãäŸãã°ãªã¬ã€ã³é žåã³éæ
åéäœèèªé žãšã®æ··åç©ã§ãããå¯èœãªå€äŸ¡ã¢ã«
ã³ãŒã«ã¯ããšãã¬ã³ã°ãªã³ãŒã«ããããã¬ã³ïŒïŒ
ïŒâåã³ïŒïŒïŒâã°ãªã³ãŒã«ãããã¬ã³ïŒïŒïŒâ
åã³ïŒïŒïŒâã°ãªã³ãŒã«ããããµã³âïŒïŒïŒâãž
ãªãŒã«ããªã¯ã¿ã³âïŒïŒïŒâãžãªãŒã«ãããªãã³
ãã«ã°ãªã³ãŒã«ãã·ã¯ããããµã³ãžã¡ã¿ããŒã«
ïŒïŒïŒïŒâãã¹âããããã·ã¡ãã«ã·ã¯ããããµ
ã³ïŒãïŒâã¡ãã«âïŒïŒïŒâãããã³ãžãªãŒã«ã
ã°ãªã»ããŒã«ãããªã¡ãããŒã«ãããã³ããããµ
ã³âïŒïŒïŒïŒïŒâããªãªãŒã«ããã¿ã³âïŒïŒïŒïŒ
ïŒâããªãªãŒã«ãããªã¡ãããŒã«ãšã¿ã³ããã³ã¿
ãšãªã¹ãªããŒã«åã³ããããŒã«åã³æŽã«ããªãžã°
ãªã³ãŒã«ããžãšãã¬ã³ã°ãªã³ãŒã«ãããªãšãã¬ã³
ã°ãªã³ãŒã«ãããã©ãšãã¬ã³ã°ãªã³ãŒã«ãããªãš
ãã¬ã³ã°ãªã³ãŒã«ããžãããã¬ã³ã°ãªã³ãŒã«ãã
ãªãããã¬ã³ã°ãªã³ãŒã«ããžããã¬ã³ã°ãªã³ãŒã«
åã³ããªããã¬ã³ã°ãªã³ãŒã«ã§ããã æ«ç«¯ããããã·ã«åºã®å«éåã³å³ã¡âå¹³åâå
åéïœã¯éãããéå°éã®ã¢ã«ã³ãŒã«ãéžæã
ãããšã«ãã€ãŠæ±ºå®ããããèèªæåºçºååç©ã
ãã®ããªãšã¹ãã«ã¯å¥œé©ã«äœ¿çšãããã æŽã«ããªãšã¹ãã«ããªãªãŒã«ã¯ãäŸãã°ã©ã¯ã
ã³äŸãã°Îµâã«ããã©ã¯ãã³ã®éåã«ãããæã
ã¯ããããã·ã«ã«ãã³é žãäŸãã°Ïâããããã·
ã«ããã³é žãåã³ããããã·å«æã®åºçºååç©ã®
çž®åã«ãã補é ããããã®ã§ãã€ãŠããããïœ
ã¯åè¿°ã®åŠã決å®ãããã äžèšæ¹æ³ã«é©åœãªããªãšã¹ãã«ããªãªãŒã«ã¯ã
奜ãŸããã¯ïŒãïŒåãç¹ã«å¥œãŸããã¯ïŒåã®ãã
ããã·ã«åºãæããã 䜿çšãããçé žãã¹âã¢ãªãŒã«ãšã¹ãã«ã¯ãç¹
ã«åŒ åŒäžãArã¯ççŽ æ°ïŒã18ã®çœ®æåã¯æªçœ®æ
ã¢ãªãŒã«åºã§ãã ã®ãã®ã§ããã å¯èœãªçœ®æåºã¯ãç¹ã«C1ãC4ã¢ã«ãã«ã䞊ã³
ã«ãããåã³ããã²ã³ãäŸãã°å¡©çŽ åã¯èçŽ ã§ã
ãããšã¹ãã«ã®äŸã¯çé žãžããšãã«ãã¢ã«ãã«çœ®
æãžããšãã«ã«ãŒãããŒããäŸãã°çé žãžãã«ã€
ã«ãããã²ã³çœ®æãžããšãã«ã«ãŒãããŒããäŸã
ã°çé žãžã¯ãã«ããšãã«ãçé žãžãããã«åã³ã¢
ã«ãã«çœ®æåã³ããã²ã³çœ®æãžãããã«ã«ãŒãã
ãŒãã§ããããããã®ååç©ã«ãããŠããžã¢ãªãŒ
ã«ã«ãŒãããŒãã®ïŒåã®ããšãã«æ žã¯ãããã«æ ž
ã®ããããã¢ã«ãã«æãã¯ããã²ã³çœ®æåºã¯åäž
ã§ãç°ãªã€ãŠãããäžã€äºãã«å¯Ÿç§°ã§ãé察称ã§
ãã€ãŠããããå³ã¡ãäŸãã°çé žããšãã«ãã«ã€
ã«ãçé žããšãã«ã¯ãã«ããšãã«ãçé žïŒâãã«
ã€ã«âïŒâãã«ã€ã«ãåã¯çé žïŒâãã«ã€ã«âïŒ
âã¯ãã«ããšãã«ãäžèšæ¹æ³ã«é©åœã§ããã å³ã¡ããªãšã¹ãã«ãžãªãŒã«ãã¹âã¢ãªãŒã«ã«ãŒ
ãããŒãã¯ãç¹ã«ç°¡ç¥ååŒ ïŒ»åŒäžãArã¯åè¿°ãšå矩ã§ãããâïŒããªãš
ã¹ãã«ïŒâã¯åè¿°ã®ããªãšã¹ãã«ãžãªãŒã«ã®ïŒã€
ã®ïŒäŸ¡ã®åºã§ãã ã®ãã®ã§ããã äžèšæ¹æ³ã«é©åœãªè§Šåªã¯ãå¡©åºæ§ãšã¹ãã«äº€æ
觊åªãäŸãã°ã¢ã«ã«ãªéå±ããšãã¬ãŒãåã¯ã¢ã«
ã«ãªåé¡éå±ããšãã¬ãŒããã¢ã«ã«ãªéå±ã¢ã«ã³
ã¬ãŒãåã¯ã¢ã«ã«ãªåé¡éå±ã¢ã«ã³ã¬ãŒããåã³
ïŒçŽã¢ãã³ãäŸãã°ããªãšãã¬ã³ãžã¢ãã³ãã¢ã«
ããªãªã³ããããªãžã³ãããªãžã³åã³ããªãšãã«
ã¢ãã³ãæãã¯éå±ååç©ãäžå¡©åã¢ã³ãã¢ã³ã
å¡©åäºéãåå¡©åãã¿ã³åã³ãã¿ã³é žããã©ãã
ã«ãšã¹ãã«ã§ããã 觊åªã¯ããªãšã¹ãã«ããªãªãŒã«åã³çé žãã¹â
ã¢ãªãŒã«ãšã¹ãã«ã®äœ¿çšå šééã«å¯ŸããŠçŽ10ã
300ppmã®éã§ããã 觊åªã¯ãåºçºååç©ãé žè§Šåªãçšããå Žåã«å¡©
åºæ§äžçŽç©ãå«æããªããšãåã³å¡©åºè§Šåªãçšã
ãå Žåã«é žäžçŽç©ãå«æããªããšããäžè¿°ããå°
éã§äœ¿çšããŠããããäžèšæ¹æ³ã«åŸã€ãŠè£œé ãã
ãçé žãšã¹ãã«ã«é¢ããŠãåºæ¥ããããåºæã®è²
ãå°ãªãããããã«ã¯ãã§ããã ãå°éã®è§Šåªã
䜿çšãã¹ãã§ããã äžèšæ¹æ³ã¯ã奜ãŸããã¯ãã«ã¯ã§ãå³ã¡æº¶å€ã®
äžååšäžã«è¡ããããããããªãããåå¿æ¡ä»¶äž
ã«äžæŽ»æ§ã§ãã溶å€ãäŸãã°ãããåºãå«æããŠ
ããŠãããèèªæåã¯è³éŠæçåæ°ŽçŽ ãéæ䜿çš
ã§ããã åå¿æéã¯åå¿æž©åºŠåã³çšãã觊åªã®çš®é¡åã³
éã«äŸåããæ®éçŽ1/2ã24æéã§ããã åå¿ã®çµäºåŸãäžé£ç¶æ³ã®å Žåã«ã¯ãåå¿äžã«
ããããã·ã¢ãªãŒã«ååç©ãçå»ããåã³æªåå¿
ã®ãžã¢ãªãŒã«ã«ãŒãããŒããçå»ããããšã«ã
ããå·¥çšäžã«çæããããããã·ã¢ãªãŒã«ååç©
åã³éå°ã®çé žãã¹âã¢ãªãŒã«ãšã¹ãã«ãé€å»ã
ãããšãã§ããããšã¹ãã«äº€æåå¿ãé£ç¶æ³ã§è¡
ãªãå Žåãããããã·ã¢ãªãŒã«ååç©ã®åå¿æ··å
ç©ããåçã«ããåé¢ããã äžèšæ¹æ³ã®ç¹ã«å¥œé©ãªå ·äœäŸã«ããã°ãåå¿ã¯
ãããªãŠã ããšãã¬ãŒãã觊åªãšããŠçšãäžã€ã
ãªãšãªãã«ãžãªãŒã«åã³çé žãã¹âã¢ãªãŒã«ãšã¹
ãã«ãããããã·åºå¯Ÿçé žãã¹âã¢ãªãŒã«ãšã¹ã
ã«ïŒçŽïŒïŒïŒã®ã¢ã«æ¯ã§çšããããšã«ããçŽ150
âã§è¡ãªãããã åèäŸã«ç€ºãå¹³åååéã¯æ°å¹³åååéïœã§
ãããOHæ°ã枬å®ããããšã«ãã€ãŠæ±ºå®ãã
ãã åèäŸã«ç€ºãã·ãŠã¿ãŠãã€ã³ã¬ãŒææ°ïŒ»Î·ïŒœã¯
THFäž25âã§æž¬å®ãããdlïŒïœã§è¡šç€ºãããã ã·ãŠã¿ãŠãã€ã³ã¬ãŒææ°ã®å®çŸ©ã¯ãH.G.ãšãª
ã¢ã¹ïŒEliasïŒèãâMakromolekušleâïŒHušthig
ïŒWepfâVerlag BasleïŒ265é ãåç §ã®ããšã åèäŸ åèäŸ ïŒ å¹³åååéïœïŒ800ãæããïœâãããµã³â
ïŒïŒïŒâãžãªãŒã«åã³ã¢ãžãã³é žã®ããªãšã¹ãã«
ãžãªãŒã«800éééšãçé žãžããšãã«856éééšå
ã³ãããªãŠã ããšãã¬ãŒã0.05éééšãçªçŽ äžã«
æªæããªãã15mmHgã§3.5æé150âã«å ç±ã
ãïŒãã®æéäžã«ããšããŒã«187éééšãçå»ã
ãã次ãã§éå°ã®çé žãžããšãã«ãæ¿¡å£èžçºæ©ã§
200âïŒ0.1mmHgäžã«é€å»ããããã®çµæç¡è²ã®
ç²çš ãªæ²¹ãåŸãã ηTHFïŒ0.072 OHæ°ïŒïŒ åæïŒèšç®å€ïŒïŒ£ïŒ66.5ïŒ ïŒïŒšïŒ8.2ïŒ å®éšå€ïŒïŒ£ïŒ63.3ïŒ ïŒïŒšïŒ8.3ïŒ åèäŸ ïŒ å¹³åååéïœïŒ800ãæããïœâãããµã³â
ïŒïŒïŒâãžãªãŒã«åã³ã¢ãžãã³é žã®ããªãšã¹ãã«
âãžãªãŒã«800éééšãçé žãžããšãã«750éééš
åã³äžé žåã¢ã³ãã¢ã³0.1éééšãçªçŽ äžã«æªæ
ããªãã15mmHgã§4.5æé170âã«å ç±ãããã®
æéäžã«ããšããŒã«188éééšãçå»ããã次ã
ã§åèäŸïŒã«åŸããéå°ã®çé žãžããšãã«ãé€å»
ããããã®çµæåèäŸïŒã§è£œé ããçæç©ãšåäž
ã®ç¡è²ã®ç²çš ãªæ²¹ãåŸãã åèäŸ ïŒ å¹³åååéïœïŒ1900ãæããã¢ãžãã³é žåã³
çã¢ã«ã®ãšãã¬ã³ã°ãªã³ãŒã«åã³ãã¿ã³âïŒïŒïŒ
âãžãªãŒã«ã®ããªãšã¹ãã«ãžãªãŒã«1000éééšã
çé žãžããšãã«385éééšåã³ãããªãŠã ããšã
ã¬ãŒã0.1éééšãçªçŽ äžã«æªæããã12mmHgã§
4.5æé150âã«å ç±ããããã®æéäžããšããŒã«
100éééšãçå»ããã次ãã§éå°ã®çé žãžããš
ãã«ãæ¿¡å£èžçºæ©ã§200âïŒ0.1mmHgäžã«é€å»ã
ããç¡è²ã®ç²çš ãªæ²¹ãåŸãã ηTHFïŒ0.112 OHæ°ïŒïŒ åæïŒèšç®å€ïŒïŒ£ïŒ55.0ïŒ ïŒïŒšïŒ7.6ïŒ å®éšå€ïŒïŒ£ïŒ54.8ïŒ ïŒïŒšïŒ7.5ïŒ åèäŸ ïŒ å¹³åååéïœïŒ1828ãæããã¢ãžãã³é žåã³
ã¢ã«æ¯65ïŒ35ã®ïœâãããµã³âïŒïŒïŒâãžãªãŒ
ã«ïŒããªãã³ãã«ã°ãªã³ãŒã«ã®æ··åç©ã®ããªãšã¹
ãã«ãžãªãŒã«1000éééšãçé žãžããšãã«385é
ééšåã³ãããªãŠã ããšãã¬ãŒã0.12éééšãçª
çŽ äžã«æªæããªãã12mmHgã§ïŒæé160âã«å ç±
ããããã®æéäžã«ããšããŒã«101éšãçå»ããã
次ãã§ãã®éå°ã®çé žãžããšãã«ãæ¿¡å£èžçºæ©ã§
200âïŒ0.1mmHgäžã«é€å»ãããç²çš ãªæ²¹ãåŸãã ηTHFïŒ0.118 OHæ°ïŒïŒ åæïŒèšç®å€ïŒïŒ£ïŒ58.3ïŒ ïŒïŒšïŒ7.7ïŒ å®éšå€ïŒïŒ£ïŒ58.1ïŒ ïŒïŒšïŒ7.6ïŒ ïŒ¢ ããªãšã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«ã«
ãŒãããŒãã®è£œé ç¬åœå ¬éç¹èš±ç¬¬2651639å·ã«åŸããããªãšã¹ã
ã«ãžãªãŒã«åã³åŒ åŒäžãArã¯ççŽ æ°ïŒã18ã®çœ®æåã¯æªçœ®æ
ã¢ãªãŒã«åºå¥œãŸããã¯ããšãã«ã§ãã ã®çé žãã¹âã¢ãªãŒã«ãšã¹ãã«ãã補é ããäžã€
ç°¡ç¥ååŒ ïŒ»åŒäžâïŒããªãšã¹ãã«ïŒâã¯ããªãšã¹ãã«ãž
ãªãŒã«ã®ïŒäŸ¡ã®åºãè¡šãã ã§è¡šããããããªãšã¹ãã«ãžãªãŒã«ãã¹âã¢ãªãŒ
ã«ã«ãŒãããŒãããžããšããŒã«ãšåå¿ãããŠãæ¬
çºæã«ãããŠåºçºåæãšããŠäœ¿çšããããªãšã¹ã
ã«ãžãªãŒã«ãã¹âãžããšããŒã«ã«ãŒãããŒãã補
é ããã å®éäžãç¹ã«ããªãšã¹ãã«ãžãªãŒã«ãã¹âãžã
ãšããŒã«ã«ãŒãããŒãã®ããªãšã¹ãã«ïŒããªã«ãŒ
ãããŒããžã®è»¢åã«é¢ããŠèšãã°ãããªãšã¹ãã«
ãžãªãŒã«ãã¹âã¢ãªãŒã«ã«ãŒãããŒããéå°ã®ç
é žãã¹âã¢ãªãŒã«ãšã¹ãã«ãšäžç·ã«ãå³ã¡ããã
çå»ããã«ãžããšããŒã«ãšåå¿ãããŠããªãšã¹ã
ã«ãžãªãŒã«ãã¹âãžããšããŒã«ã«ãŒãããŒããšã
ãããšãã§ããã ãã®åå¿äžãäºããçå»ããªãã€ãçé žãã¹â
ã¢ãªãŒã«ãšã¹ãã«ã¯ãžããšããŒã«ãšåå¿ããŠOH
åºãå«æãããžããšããŒã«ã®åéäœåã¯äœéå床
éåäœã«ãŒãããŒããäžããã æ¬çºæã«ãããŠåºçºåæãšããŠäœ¿çšããããªãš
ã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«ã«ãŒãããŒã
ã®è£œé ã«é©åœãªãžããšããŒã«ã¯æ¬¡ã®éãã§ã
ããïŒãã€ããããã³ãã¬ãŸã«ã·ããŒã«ããžãã
ããã·ãžããšãã«ããã¹âïŒããããã·ããšã
ã«ïŒâã¢ã«ã«ã³ããã¹âïŒããããã·ããšãã«ïŒ
âã·ã¯ãã¢ã«ã«ã³ããã¹âïŒããããã·ããšã
ã«ïŒã¹ã«ãã€ãããã¹âïŒããããã·ããšãã«ïŒ
ãšãŒãã«ããã¹âïŒããããã·ããšãã«ïŒã±ã
ã³ããã¹âïŒããããã·ããšãã«ïŒã¹ã«ããã·
ãããã¹âïŒããããã·ããšãã«ïŒã¹ã«ãã³åã³
αïŒÎ±âãã¹âïŒããããã·ããšãã«ïŒâãžã€ãœ
ãããã«ãã³ãŒã³ã䞊ã³ã«ãããã®æ žã¢ã«ãã«å
åã³æ žããã²ã³åååç©ããããã®åã³æŽãªãé©
åœãªè³éŠæããããã·ååç©ã¯ãç±³åœç¹èš±ç¬¬
3028365å·ã第2999835å·ã第314172å·ã第
3271368å·ã第2991273å·ã第3271367å·ã第
3280078å·ã第3014891å·åã³ç¬¬2999846å·ãåã³
ç¬åœå ¬éç¹èš±ç¬¬2063050å·åã³ç¬¬2211957å·ã«è¡šç€º
ãããŠããã é©åœãªãžããšããŒã«ã«äŸã¯ããã¹âïŒïŒâãã
ããã·ããšãã«ïŒâã¡ã¿ã³ãïŒïŒ4â²âãžãããã
ã·ãžããšãã«ãïŒïŒïŒâãã¹âïŒïŒâããããã·
ããšãã«ïŒâïŒâã¡ãã«ãã¿ã³ãαïŒÎ±âãã¹â
ïŒïŒâããããã·ããšãã«ïŒâïœâãžã€ãœããã
ã«ãã³ãŒã³ãïŒïŒïŒâãã¹âïŒïŒâã¯ãã«âïŒâ
ããããã·ããšãã«ïŒâãããã³åã³ïŒïŒïŒâã
ã¹âïŒïŒïŒïŒâãžã¡ãã«âïŒâããããã·ããšã
ã«ïŒâãããã³ã§ããã 奜é©ãªãžããšããŒã«ã¯ãäŸãã°ïŒïŒïŒâãã¹â
ïŒïŒâããããã·ããšãã«ïŒãããã³ãïŒïŒïŒâ
ãã¹âïŒïŒâããããã·ããšãã«ïŒâã·ã¯ããã
ãµã³ãïŒïŒïŒâãã¹ïŒïŒïŒïŒâãžã¯ãã«âïŒâã
ãããã·ããšãã«ïŒâãããã³åã³ïŒïŒïŒâãã¹
âïŒïŒïŒïŒâãžããã âïŒâããããã·ããšã
ã«ïŒâãããã³ã§ããã äžèšè£œé ã«ãããŠãé©åœãªãžããšããŒã«ïŒçš®å
ã¯æ°çš®ã䜿çšã§ããã æ¬çºæã«ãããŠåºçºåæãšããŠäœ¿çšããããªãš
ã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«ã«ãŒãããŒã
ã®è£œé ã«é©åœãªè§Šåªã¯ãå¡©åºæ§ãšã¹ãã«äº€æ觊
åªãäŸãã°ã¢ã«ã«ãªéå±ããšãã¬ãŒãåã¯ã¢ã«ã«
ãªåé¡éå±ããšãã¬ãŒããã¢ã«ã«ãªéå±ã¢ã«ã³ã¬
ãŒãåã¯ã¢ã«ã«ãªåé¡éå±ã¢ã«ã³ã¬ãŒããïŒçŽã¢
ãã³ãäŸãã°ããªãšãã¬ã³ãžã¢ãã³ãã¢ã«ããªãª
ã³ããããªãžã³ãããªãšãã«ã¢ãã³åã³ããªãã
ã«ã¢ãã³ãåã³ããªãžã³ãæãã¯éå±ååç©ãäŸ
ãã°äžé žåã¢ã³ãã¢ã³ãå¡©åäºéãåå¡©åãã¿ã³
åã³ããã©ããã«ãã¿ã³ã§ããã 觊åªã¯ãçšããããªãšã¹ãã«ãžãªãŒã«ãã¹âã¢
ãªãŒã«ã«ãŒãããŒãåã³ãžããšããŒã«ã®å šééã«
察ããŠçŽ10ã200ppmã®éã§äœ¿çšãããã åºçºç©è³ªãå¡©åºæ§äžçŽç©ãå«æããªãå Žåã«é ž
觊åªãçšãããšãåã³é žäžçŽç©ãå«æããªãå Žå
ã«å¡©åºè§Šåªãçšãããšããäžè¿°ãããå°éã®è§Šåª
ãéæ䜿çšããããšãã§ãããçæç©ã®åºæã®è²
ãã§ããéãå ãã«ãããšããèå³ããã¯ãã§ã
ãã ãå°éã®è§Šåªã奜é©ã§ããã äžèšããªãšã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«
ã«ãŒãããŒãã®è£œé æ³ã¯ã奜ãŸããã¯ãã«ã¯ã§ã
å³ã¡æº¶åªã®äžååšäžã«è¡ãªããããããããªã
ããåå¿æ¡ä»¶äžã«äžæŽ»æ§ãªæº¶åªãäŸãã°çœ®æãã
ãŠãªãåã³äŸãã°ãããåºã§çœ®æãããèèªæå
ã¯è³éŠæçåæ°ŽçŽ ãéæ䜿çšã§ããã ããªãšã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«ã«ãŒ
ãããŒãã®è£œé ã«å¯Ÿãããšã¹ãã«äº€æã®åå¿æé
ã¯ãåå¿æž©åºŠåã³è§Šåªã®çš®é¡åã³éã«äŸåããŠçŽ
ïŒïŒïŒãçŽ24æéã§ããã ããªãšã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«ã«ãŒ
ãããŒãã¯ãäŸãã°ç¬åœå ¬éç¹èš±ç¬¬2651639å·ã«
åŸã€ãŠè£œé ããããªãšã¹ãã«ãžãªãŒã«ãã¹âçé ž
ã¢ãã¢ãªãŒã«ãšã¹ãã«ããžããšããŒã«åã³è§Šåªã®
æ··åç©ãçŽ100ãçŽ200âã奜ãŸããã¯çŽ110ã180
âã®æž©åºŠã«ç空äžã§å ç±ããåã³åå¿ã«é²è¡ã«ã€
ããŠçæããããšããŒã«ãåå¿åšããçå»ããã
ãšã«ãã€ãŠè£œé ãããããã®æ¹æ³ã«ãããŠããžã
ãšããŒã«ã¯éå°éã§äœ¿çšãããããªãšã¹ãã«ãžãª
ãŒã«ãã¹âçé žã¢ãã¢ãªãŒã«ãšã¹ãã«ã®çé žããš
ãã«ãšã¹ãã«åºåœãïŒã¢ã«ããå€ãã奜ãŸããã¯
çŽïŒïŒïŒãçŽïŒã¢ã«ã®ãžããšããŒã«ãçšããã
ããç¹ã«å¥œé©ãªå ·äœäŸã«ããã°ããã¹çé žã¢ãã¢
ãªãŒã«ãšã¹ãã«å¯Ÿãã¹ããšããŒã«ïŒ¡ã®ã¢ã«æ¯ã
ïŒïŒïŒã®ããªãšã¹ãã«ãžãªãŒã«ãã¹çé žã¢ãã¢ãª
ãŒã«ãšã¹ãã«åã³ãã¹ããšããŒã«ïŒ¡ã®åå¿ã¯ãã
ã¹ããšããŒã«ïŒ¡ã®ãžãããªãŠã ããšãã¬ãŒãã觊
åªãšããŠçšããããšã«ããã150âäžã€25ã0.1mm
Hgã®ç空äžã«è¡ãªãããã ç¹ã«äžèšæ¹æ³ã«ããã°ãããªãšã¹ãã«ãžãªãŒã«
ãã¹çé žã¢ãã¢ãªãŒã«ãšã¹ãã«ããäžåŒ åŒäžãã¯âCH2âåã¯ã
補é æ³ã«é¢ããã ç¬åœå ¬éç¹èš±ç¬¬2651639å·ã«åŸã€ãŠè£œé ããã
ããªãšã¹ãã«ãžãªãŒã«ãã¹âã¢ãªãŒã«ã«ãŒãããŒ
ããéå°ã®ãžããšããŒã«ãšãšã¹ãã«äº€æããŠå¯Ÿå¿
ããããªãšã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«ã«
ãŒãããŒãã補é ããåå¿ã¯ã200âãŸã§ã®åå¿
枩床ã«ãããŠã§ãããé©ãã»ã©å¹³æ»ã«äžã€å¯åå¿
ããªãé²è¡ãããæŽã«åºçºç©è³ªã«ãã€ãŠäžããã
ãååéååžã¯å€åãããããªãšã¹ãã«âããªãª
ãŒã«ã¯åçãããåã³ããªã«ãŒãããŒããžã®éçž®
åã¯èµ·ãããªãã  ããªãšã¹ãã«ãžãªãŒã«ãã¹âã¢ãªãŒã«ã«ãŒã
ããŒãã®è£œé æ¬çºæã§äœ¿çšããããªãšã¹ãã«ãžãªãŒã«ãã¹â
ãžããšããŒã«ã«ãŒãããŒãã®è£œé ã«å¿ èŠãªããªãš
ã¹ãã«ãžãªãŒã«ãã¹âã¢ãªãŒã«ã«ãŒãããŒãã¯ã
ç¬åœå ¬éç¹èš±ç¬¬2651639å·ã«åŸã€ãŠè£œé ãããã ç¬åœå ¬éç¹èš±ç¬¬2951639å·ã¯ãçŽ250以äžã奜ãŸ
ããã¯çŽ600以äžã®ååéïœïŒæ°å¹³åïŒãæãã
ããªãšã¹ãã«ããªãªãŒã«ãçé žãã¹âã¢ãªãŒã«ãš
ã¹ãã«ãšå ±ã«è§Šåªã®ååšäžåã³çŽ35mmHg以äžã
奜ãŸããã¯çŽ25ã0.1mmHgã®ç空äžã«çŽ100ã200
âã奜ãŸããã¯çŽ100ã180âã®æž©åºŠã«å ç±ããäœ
ãããªãšã¹ãã«ããªãªãŒã«ã®OHåºåœãïŒã¢ã«ã
ãå€ãã奜ãŸããã¯çŽ1.25ã2.25ã¢ã«ã®çé žãã¹
âã¢ãªãŒã«ãšã¹ãã«ãçšããåã³çæããããã
ãã·ã¢ãªãŒã«ååç©åã³éå°ã®çé žãã¹âã¢ãªãŒ
ã«ãšã¹ãã«ãçå»ãããçŽ250以äžã奜ãŸããã¯
çŽ600以äžã®ïœãæããããªãšã¹ãã«ããªãªãŒ
ã«ã®çé žã¢ãªãŒã«ãšã¹ãã«ã®è£œé æ³ã«é¢ãããã®
ã§ããã æŽã«ç¬åœå ¬éç¹èš±ç¬¬2651639å·ã¯ããã®æ¹æ³ã§
補é ãããããªãšã¹ãã«ããªãªãŒã«ã®çé žãšã¹ã
ã«ã«ãé¢ããã äžèšæ¹æ³ã«å¯ŸããŠç¹ã«å¥œé©ãªããªãšã¹ãã«ããª
ãªãŒã«ã¯ããªãšã¹ãã«âãžãªãŒã«ã§ããã äžèšæ¹æ³ã§çšããããªãšã¹ãã«ããªãªãŒã«ã¯ã
äŸãã°å€äŸ¡ã奜ãŸããã¯ïŒäŸ¡åã³æŽã«éæïŒäŸ¡ã®
ã¢ã«ã³ãŒã«ãšå€å¡©åºæ§ããŸããã¯ïŒå¡©åºæ§ã®ã«ã«
ãã³é žãšã®åå¿çæç©ã§ãããããªãšã¹ãã«ããª
ãªãŒã«ã®è£œé ã«ã¯ãéé¢ã®ããªã«ã«ãã³é žã®ä»£ã
ã«å¯Ÿå¿ããããªã«ã«ãã³é žç¡æ°Žç©æãã¯å¯Ÿå¿ãã
ããªã«ã«ãã³é žãšäœçŽã¢ã«ã³ãŒã«ãšã®ãšã¹ãã«ã
åã³ãããã®æ··åç©ã䜿çšã§ãããããªã«ã«ãã³
é žã®äŸã¯ãèèªæãèç°æãè³éŠæåã³ïŒåã¯ã
ããç°æã®ãã®ã§ãã€ãŠãããäžã€äŸãã°ããã²
ã³ååã§çœ®æãããŠããŠãåã³ïŒåã¯äžé£œåã§ã
ã€ãŠãããããããã®äŸã¯ãã·ãŠãŠé žãããã³
é žãã³ãã¯é žãã¢ãžãã³é žãã¹ããªã³é žãã¢ãŒã©
ã€ã³é žãã»ãã·ã³é žããã¿ã«é žããã¬ãã¿ã«é žã
ããªã¡ãªããé žãç¡æ°Žãã¿ã«é žãããã©ãããã
ã¿ã«é žç¡æ°Žç©ããããµããããã¿ã«é žç¡æ°Žç©ãã
ãã©ã¯ãã«ãã¿ã«é žç¡æ°Žç©ããšã³ãã¡ãã¬ã³ãã
ã©ããããã¿ã«é žç¡æ°Žç©ãã°ã«ã¿ã«é žç¡æ°Žç©ãã
ã¬ã€ã³é žãç¡æ°Žãã¬ã€ã³é žãããã«é žåã³ïŒéäœ
åã³ïŒéäœã®èèªé žãäŸãã°ãªã¬ã€ã³é žåã³éæ
åéäœèèªé žãšã®æ··åç©ã§ãããå¯èœãªå€äŸ¡ã¢ã«
ã³ãŒã«ã¯ããšãã¬ã³ã°ãªã³ãŒã«ããããã¬ã³ïŒïŒ
ïŒâåã³ïŒïŒïŒâã°ãªã³ãŒã«ãããã¬ã³ïŒïŒïŒâ
åã³ïŒïŒïŒâã°ãªã³ãŒã«ããããµã³âïŒïŒïŒâãž
ãªãŒã«ããªã¯ã¿ã³âïŒïŒïŒâãžãªãŒã«ãããªãã³
ãã«ã°ãªã³ãŒã«ãã·ã¯ããããµã³ãžã¡ã¿ããŒã«
ïŒïŒïŒïŒâãã¹âããããã·ã¡ãã«ã·ã¯ããããµ
ã³ïŒãïŒâã¡ãã«âïŒïŒïŒâãããã³ãžãªãŒã«ã
ã°ãªã»ããŒã«ãããªã¡ãããŒã«ãããã³ããããµ
ã³âïŒïŒïŒïŒïŒâããªãªãŒã«ããã¿ã³âïŒïŒïŒïŒ
ïŒâããªãªãŒã«ãããªã¡ãããŒã«ãšã¿ã³ããã³ã¿
ãšãªã¹ãªããŒã«åã³ããããŒã«åã³æŽã«ããªãžã°
ãªã³ãŒã«ããžãšãã¬ã³ã°ãªã³ãŒã«ãããªãšãã¬ã³
ã°ãªã³ãŒã«ãããã©ãšãã¬ã³ã°ãªã³ãŒã«ãããªãš
ãã¬ã³ã°ãªã³ãŒã«ããžãããã¬ã³ã°ãªã³ãŒã«ãã
ãªãããã¬ã³ã°ãªã³ãŒã«ããžããã¬ã³ã°ãªã³ãŒã«
åã³ããªããã¬ã³ã°ãªã³ãŒã«ã§ããã æ«ç«¯ããããã·ã«åºã®å«éåã³å³ã¡âå¹³åâå
åéïœã¯éãããéå°éã®ã¢ã«ã³ãŒã«ãéžæã
ãããšã«ãã€ãŠæ±ºå®ããããèèªæåºçºååç©ã
ãã®ããªãšã¹ãã«ã¯å¥œé©ã«äœ¿çšãããã æŽã«ããªãšã¹ãã«ããªãªãŒã«ã¯ãäŸãã°ã©ã¯ã
ã³äŸãã°Îµâã«ããã©ã¯ãã³ã®éåã«ãããæã
ã¯ããããã·ã«ã«ãã³é žãäŸãã°Ïâããããã·
ã«ããã³é žãåã³ããããã·å«æã®åºçºååç©ã®
çž®åã«ãã補é ããããã®ã§ãã€ãŠããããïœ
ã¯åè¿°ã®åŠã決å®ãããã äžèšæ¹æ³ã«é©åœãªããªãšã¹ãã«ããªãªãŒã«ã¯ã
奜ãŸããã¯ïŒãïŒåãç¹ã«å¥œãŸããã¯ïŒåã®ãã
ããã·ã«åºãæããã 䜿çšãããçé žãã¹âã¢ãªãŒã«ãšã¹ãã«ã¯ãç¹
ã«åŒ åŒäžãArã¯ççŽ æ°ïŒã18ã®çœ®æåã¯æªçœ®æ
ã¢ãªãŒã«åºã§ãã ã®ãã®ã§ããã å¯èœãªçœ®æåºã¯ãç¹ã«C1ãC4ã¢ã«ãã«ã䞊ã³
ã«ãããåã³ããã²ã³ãäŸãã°å¡©çŽ åã¯èçŽ ã§ã
ãããšã¹ãã«ã®äŸã¯çé žãžããšãã«ãã¢ã«ãã«çœ®
æãžããšãã«ã«ãŒãããŒããäŸãã°çé žãžãã«ã€
ã«ãããã²ã³çœ®æãžããšãã«ã«ãŒãããŒããäŸã
ã°çé žãžã¯ãã«ããšãã«ãçé žãžãããã«åã³ã¢
ã«ãã«çœ®æåã³ããã²ã³çœ®æãžãããã«ã«ãŒãã
ãŒãã§ããããããã®ååç©ã«ãããŠããžã¢ãªãŒ
ã«ã«ãŒãããŒãã®ïŒåã®ããšãã«æ žã¯ãããã«æ ž
ã®ããããã¢ã«ãã«æãã¯ããã²ã³çœ®æåºã¯åäž
ã§ãç°ãªã€ãŠãããäžã€äºãã«å¯Ÿç§°ã§ãé察称ã§
ãã€ãŠããããå³ã¡ãäŸãã°çé žããšãã«ãã«ã€
ã«ãçé žããšãã«ã¯ãã«ããšãã«ãçé žïŒâãã«
ã€ã«âïŒâãã«ã€ã«ãåã¯çé žïŒâãã«ã€ã«âïŒ
âã¯ãã«ããšãã«ãäžèšæ¹æ³ã«é©åœã§ããã å³ã¡ããªãšã¹ãã«ãžãªãŒã«ãã¹âã¢ãªãŒã«ã«ãŒ
ãããŒãã¯ãç¹ã«ç°¡ç¥ååŒ ïŒ»åŒäžãArã¯åè¿°ãšå矩ã§ãããâïŒããªãš
ã¹ãã«ïŒâã¯åè¿°ã®ããªãšã¹ãã«ãžãªãŒã«ã®ïŒã€
ã®ïŒäŸ¡ã®åºã§ãã ã®ãã®ã§ããã äžèšæ¹æ³ã«é©åœãªè§Šåªã¯ãå¡©åºæ§ãšã¹ãã«äº€æ
觊åªãäŸãã°ã¢ã«ã«ãªéå±ããšãã¬ãŒãåã¯ã¢ã«
ã«ãªåé¡éå±ããšãã¬ãŒããã¢ã«ã«ãªéå±ã¢ã«ã³
ã¬ãŒãåã¯ã¢ã«ã«ãªåé¡éå±ã¢ã«ã³ã¬ãŒããåã³
ïŒçŽã¢ãã³ãäŸãã°ããªãšãã¬ã³ãžã¢ãã³ãã¢ã«
ããªãªã³ããããªãžã³ãããªãžã³åã³ããªãšãã«
ã¢ãã³ãæãã¯éå±ååç©ãäžå¡©åã¢ã³ãã¢ã³ã
å¡©åäºéãåå¡©åãã¿ã³åã³ãã¿ã³é žããã©ãã
ã«ãšã¹ãã«ã§ããã 觊åªã¯ããªãšã¹ãã«ããªãªãŒã«åã³çé žãã¹â
ã¢ãªãŒã«ãšã¹ãã«ã®äœ¿çšå šééã«å¯ŸããŠçŽ10ã
300ppmã®éã§ããã 觊åªã¯ãåºçºååç©ãé žè§Šåªãçšããå Žåã«å¡©
åºæ§äžçŽç©ãå«æããªããšãåã³å¡©åºè§Šåªãçšã
ãå Žåã«é žäžçŽç©ãå«æããªããšããäžè¿°ããå°
éã§äœ¿çšããŠããããäžèšæ¹æ³ã«åŸã€ãŠè£œé ãã
ãçé žãšã¹ãã«ã«é¢ããŠãåºæ¥ããããåºæã®è²
ãå°ãªãããããã«ã¯ãã§ããã ãå°éã®è§Šåªã
䜿çšãã¹ãã§ããã äžèšæ¹æ³ã¯ã奜ãŸããã¯ãã«ã¯ã§ãå³ã¡æº¶å€ã®
äžååšäžã«è¡ããããããããªãããåå¿æ¡ä»¶äž
ã«äžæŽ»æ§ã§ãã溶å€ãäŸãã°ãããåºãå«æããŠ
ããŠãããèèªæåã¯è³éŠæçåæ°ŽçŽ ãéæ䜿çš
ã§ããã åå¿æéã¯åå¿æž©åºŠåã³çšãã觊åªã®çš®é¡åã³
éã«äŸåããæ®éçŽ1/2ã24æéã§ããã åå¿ã®çµäºåŸãäžé£ç¶æ³ã®å Žåã«ã¯ãåå¿äžã«
ããããã·ã¢ãªãŒã«ååç©ãçå»ããåã³æªåå¿
ã®ãžã¢ãªãŒã«ã«ãŒãããŒããçå»ããããšã«ã
ããå·¥çšäžã«çæããããããã·ã¢ãªãŒã«ååç©
åã³éå°ã®çé žãã¹âã¢ãªãŒã«ãšã¹ãã«ãé€å»ã
ãããšãã§ããããšã¹ãã«äº€æåå¿ãé£ç¶æ³ã§è¡
ãªãå Žåãããããã·ã¢ãªãŒã«ååç©ã®åå¿æ··å
ç©ããåçã«ããåé¢ããã äžèšæ¹æ³ã®ç¹ã«å¥œé©ãªå ·äœäŸã«ããã°ãåå¿ã¯
ãããªãŠã ããšãã¬ãŒãã觊åªãšããŠçšãäžã€ã
ãªãšãªãã«ãžãªãŒã«åã³çé žãã¹âã¢ãªãŒã«ãšã¹
ãã«ãããããã·åºå¯Ÿçé žãã¹âã¢ãªãŒã«ãšã¹ã
ã«ïŒçŽïŒïŒïŒã®ã¢ã«æ¯ã§çšããããšã«ããçŽ150
âã§è¡ãªãããã åèäŸã«ç€ºãå¹³åååéã¯æ°å¹³åååéïœã§
ãããOHæ°ã枬å®ããããšã«ãã€ãŠæ±ºå®ãã
ãã åèäŸã«ç€ºãã·ãŠã¿ãŠãã€ã³ã¬ãŒææ°ïŒ»Î·ïŒœã¯
THFäž25âã§æž¬å®ãããdlïŒïœã§è¡šç€ºãããã ã·ãŠã¿ãŠãã€ã³ã¬ãŒææ°ã®å®çŸ©ã¯ãH.G.ãšãª
ã¢ã¹ïŒEliasïŒèãâMakromolekušleâïŒHušthig
ïŒWepfâVerlag BasleïŒ265é ãåç §ã®ããšã åèäŸ åèäŸ ïŒ å¹³åååéïœïŒ800ãæããïœâãããµã³â
ïŒïŒïŒâãžãªãŒã«åã³ã¢ãžãã³é žã®ããªãšã¹ãã«
ãžãªãŒã«800éééšãçé žãžããšãã«856éééšå
ã³ãããªãŠã ããšãã¬ãŒã0.05éééšãçªçŽ äžã«
æªæããªãã15mmHgã§3.5æé150âã«å ç±ã
ãïŒãã®æéäžã«ããšããŒã«187éééšãçå»ã
ãã次ãã§éå°ã®çé žãžããšãã«ãæ¿¡å£èžçºæ©ã§
200âïŒ0.1mmHgäžã«é€å»ããããã®çµæç¡è²ã®
ç²çš ãªæ²¹ãåŸãã ηTHFïŒ0.072 OHæ°ïŒïŒ åæïŒèšç®å€ïŒïŒ£ïŒ66.5ïŒ ïŒïŒšïŒ8.2ïŒ å®éšå€ïŒïŒ£ïŒ63.3ïŒ ïŒïŒšïŒ8.3ïŒ åèäŸ ïŒ å¹³åååéïœïŒ800ãæããïœâãããµã³â
ïŒïŒïŒâãžãªãŒã«åã³ã¢ãžãã³é žã®ããªãšã¹ãã«
âãžãªãŒã«800éééšãçé žãžããšãã«750éééš
åã³äžé žåã¢ã³ãã¢ã³0.1éééšãçªçŽ äžã«æªæ
ããªãã15mmHgã§4.5æé170âã«å ç±ãããã®
æéäžã«ããšããŒã«188éééšãçå»ããã次ã
ã§åèäŸïŒã«åŸããéå°ã®çé žãžããšãã«ãé€å»
ããããã®çµæåèäŸïŒã§è£œé ããçæç©ãšåäž
ã®ç¡è²ã®ç²çš ãªæ²¹ãåŸãã åèäŸ ïŒ å¹³åååéïœïŒ1900ãæããã¢ãžãã³é žåã³
çã¢ã«ã®ãšãã¬ã³ã°ãªã³ãŒã«åã³ãã¿ã³âïŒïŒïŒ
âãžãªãŒã«ã®ããªãšã¹ãã«ãžãªãŒã«1000éééšã
çé žãžããšãã«385éééšåã³ãããªãŠã ããšã
ã¬ãŒã0.1éééšãçªçŽ äžã«æªæããã12mmHgã§
4.5æé150âã«å ç±ããããã®æéäžããšããŒã«
100éééšãçå»ããã次ãã§éå°ã®çé žãžããš
ãã«ãæ¿¡å£èžçºæ©ã§200âïŒ0.1mmHgäžã«é€å»ã
ããç¡è²ã®ç²çš ãªæ²¹ãåŸãã ηTHFïŒ0.112 OHæ°ïŒïŒ åæïŒèšç®å€ïŒïŒ£ïŒ55.0ïŒ ïŒïŒšïŒ7.6ïŒ å®éšå€ïŒïŒ£ïŒ54.8ïŒ ïŒïŒšïŒ7.5ïŒ åèäŸ ïŒ å¹³åååéïœïŒ1828ãæããã¢ãžãã³é žåã³
ã¢ã«æ¯65ïŒ35ã®ïœâãããµã³âïŒïŒïŒâãžãªãŒ
ã«ïŒããªãã³ãã«ã°ãªã³ãŒã«ã®æ··åç©ã®ããªãšã¹
ãã«ãžãªãŒã«1000éééšãçé žãžããšãã«385é
ééšåã³ãããªãŠã ããšãã¬ãŒã0.12éééšãçª
çŽ äžã«æªæããªãã12mmHgã§ïŒæé160âã«å ç±
ããããã®æéäžã«ããšããŒã«101éšãçå»ããã
次ãã§ãã®éå°ã®çé žãžããšãã«ãæ¿¡å£èžçºæ©ã§
200âïŒ0.1mmHgäžã«é€å»ãããç²çš ãªæ²¹ãåŸãã ηTHFïŒ0.118 OHæ°ïŒïŒ åæïŒèšç®å€ïŒïŒ£ïŒ58.3ïŒ ïŒïŒšïŒ7.7ïŒ å®éšå€ïŒïŒ£ïŒ58.1ïŒ ïŒïŒšïŒ7.6ïŒ ïŒ¢ ããªãšã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«ã«
ãŒãããŒãã®è£œé ç¬åœå ¬éç¹èš±ç¬¬2651639å·ã«åŸããããªãšã¹ã
ã«ãžãªãŒã«åã³åŒ åŒäžãArã¯ççŽ æ°ïŒã18ã®çœ®æåã¯æªçœ®æ
ã¢ãªãŒã«åºå¥œãŸããã¯ããšãã«ã§ãã ã®çé žãã¹âã¢ãªãŒã«ãšã¹ãã«ãã補é ããäžã€
ç°¡ç¥ååŒ ïŒ»åŒäžâïŒããªãšã¹ãã«ïŒâã¯ããªãšã¹ãã«ãž
ãªãŒã«ã®ïŒäŸ¡ã®åºãè¡šãã ã§è¡šããããããªãšã¹ãã«ãžãªãŒã«ãã¹âã¢ãªãŒ
ã«ã«ãŒãããŒãããžããšããŒã«ãšåå¿ãããŠãæ¬
çºæã«ãããŠåºçºåæãšããŠäœ¿çšããããªãšã¹ã
ã«ãžãªãŒã«ãã¹âãžããšããŒã«ã«ãŒãããŒãã補
é ããã å®éäžãç¹ã«ããªãšã¹ãã«ãžãªãŒã«ãã¹âãžã
ãšããŒã«ã«ãŒãããŒãã®ããªãšã¹ãã«ïŒããªã«ãŒ
ãããŒããžã®è»¢åã«é¢ããŠèšãã°ãããªãšã¹ãã«
ãžãªãŒã«ãã¹âã¢ãªãŒã«ã«ãŒãããŒããéå°ã®ç
é žãã¹âã¢ãªãŒã«ãšã¹ãã«ãšäžç·ã«ãå³ã¡ããã
çå»ããã«ãžããšããŒã«ãšåå¿ãããŠããªãšã¹ã
ã«ãžãªãŒã«ãã¹âãžããšããŒã«ã«ãŒãããŒããšã
ãããšãã§ããã ãã®åå¿äžãäºããçå»ããªãã€ãçé žãã¹â
ã¢ãªãŒã«ãšã¹ãã«ã¯ãžããšããŒã«ãšåå¿ããŠOH
åºãå«æãããžããšããŒã«ã®åéäœåã¯äœéå床
éåäœã«ãŒãããŒããäžããã æ¬çºæã«ãããŠåºçºåæãšããŠäœ¿çšããããªãš
ã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«ã«ãŒãããŒã
ã®è£œé ã«é©åœãªãžããšããŒã«ã¯æ¬¡ã®éãã§ã
ããïŒãã€ããããã³ãã¬ãŸã«ã·ããŒã«ããžãã
ããã·ãžããšãã«ããã¹âïŒããããã·ããšã
ã«ïŒâã¢ã«ã«ã³ããã¹âïŒããããã·ããšãã«ïŒ
âã·ã¯ãã¢ã«ã«ã³ããã¹âïŒããããã·ããšã
ã«ïŒã¹ã«ãã€ãããã¹âïŒããããã·ããšãã«ïŒ
ãšãŒãã«ããã¹âïŒããããã·ããšãã«ïŒã±ã
ã³ããã¹âïŒããããã·ããšãã«ïŒã¹ã«ããã·
ãããã¹âïŒããããã·ããšãã«ïŒã¹ã«ãã³åã³
αïŒÎ±âãã¹âïŒããããã·ããšãã«ïŒâãžã€ãœ
ãããã«ãã³ãŒã³ã䞊ã³ã«ãããã®æ žã¢ã«ãã«å
åã³æ žããã²ã³åååç©ããããã®åã³æŽãªãé©
åœãªè³éŠæããããã·ååç©ã¯ãç±³åœç¹èš±ç¬¬
3028365å·ã第2999835å·ã第314172å·ã第
3271368å·ã第2991273å·ã第3271367å·ã第
3280078å·ã第3014891å·åã³ç¬¬2999846å·ãåã³
ç¬åœå ¬éç¹èš±ç¬¬2063050å·åã³ç¬¬2211957å·ã«è¡šç€º
ãããŠããã é©åœãªãžããšããŒã«ã«äŸã¯ããã¹âïŒïŒâãã
ããã·ããšãã«ïŒâã¡ã¿ã³ãïŒïŒ4â²âãžãããã
ã·ãžããšãã«ãïŒïŒïŒâãã¹âïŒïŒâããããã·
ããšãã«ïŒâïŒâã¡ãã«ãã¿ã³ãαïŒÎ±âãã¹â
ïŒïŒâããããã·ããšãã«ïŒâïœâãžã€ãœããã
ã«ãã³ãŒã³ãïŒïŒïŒâãã¹âïŒïŒâã¯ãã«âïŒâ
ããããã·ããšãã«ïŒâãããã³åã³ïŒïŒïŒâã
ã¹âïŒïŒïŒïŒâãžã¡ãã«âïŒâããããã·ããšã
ã«ïŒâãããã³ã§ããã 奜é©ãªãžããšããŒã«ã¯ãäŸãã°ïŒïŒïŒâãã¹â
ïŒïŒâããããã·ããšãã«ïŒãããã³ãïŒïŒïŒâ
ãã¹âïŒïŒâããããã·ããšãã«ïŒâã·ã¯ããã
ãµã³ãïŒïŒïŒâãã¹ïŒïŒïŒïŒâãžã¯ãã«âïŒâã
ãããã·ããšãã«ïŒâãããã³åã³ïŒïŒïŒâãã¹
âïŒïŒïŒïŒâãžããã âïŒâããããã·ããšã
ã«ïŒâãããã³ã§ããã äžèšè£œé ã«ãããŠãé©åœãªãžããšããŒã«ïŒçš®å
ã¯æ°çš®ã䜿çšã§ããã æ¬çºæã«ãããŠåºçºåæãšããŠäœ¿çšããããªãš
ã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«ã«ãŒãããŒã
ã®è£œé ã«é©åœãªè§Šåªã¯ãå¡©åºæ§ãšã¹ãã«äº€æ觊
åªãäŸãã°ã¢ã«ã«ãªéå±ããšãã¬ãŒãåã¯ã¢ã«ã«
ãªåé¡éå±ããšãã¬ãŒããã¢ã«ã«ãªéå±ã¢ã«ã³ã¬
ãŒãåã¯ã¢ã«ã«ãªåé¡éå±ã¢ã«ã³ã¬ãŒããïŒçŽã¢
ãã³ãäŸãã°ããªãšãã¬ã³ãžã¢ãã³ãã¢ã«ããªãª
ã³ããããªãžã³ãããªãšãã«ã¢ãã³åã³ããªãã
ã«ã¢ãã³ãåã³ããªãžã³ãæãã¯éå±ååç©ãäŸ
ãã°äžé žåã¢ã³ãã¢ã³ãå¡©åäºéãåå¡©åãã¿ã³
åã³ããã©ããã«ãã¿ã³ã§ããã 觊åªã¯ãçšããããªãšã¹ãã«ãžãªãŒã«ãã¹âã¢
ãªãŒã«ã«ãŒãããŒãåã³ãžããšããŒã«ã®å šééã«
察ããŠçŽ10ã200ppmã®éã§äœ¿çšãããã åºçºç©è³ªãå¡©åºæ§äžçŽç©ãå«æããªãå Žåã«é ž
觊åªãçšãããšãåã³é žäžçŽç©ãå«æããªãå Žå
ã«å¡©åºè§Šåªãçšãããšããäžè¿°ãããå°éã®è§Šåª
ãéæ䜿çšããããšãã§ãããçæç©ã®åºæã®è²
ãã§ããéãå ãã«ãããšããèå³ããã¯ãã§ã
ãã ãå°éã®è§Šåªã奜é©ã§ããã äžèšããªãšã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«
ã«ãŒãããŒãã®è£œé æ³ã¯ã奜ãŸããã¯ãã«ã¯ã§ã
å³ã¡æº¶åªã®äžååšäžã«è¡ãªããããããããªã
ããåå¿æ¡ä»¶äžã«äžæŽ»æ§ãªæº¶åªãäŸãã°çœ®æãã
ãŠãªãåã³äŸãã°ãããåºã§çœ®æãããèèªæå
ã¯è³éŠæçåæ°ŽçŽ ãéæ䜿çšã§ããã ããªãšã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«ã«ãŒ
ãããŒãã®è£œé ã«å¯Ÿãããšã¹ãã«äº€æã®åå¿æé
ã¯ãåå¿æž©åºŠåã³è§Šåªã®çš®é¡åã³éã«äŸåããŠçŽ
ïŒïŒïŒãçŽ24æéã§ããã ããªãšã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«ã«ãŒ
ãããŒãã¯ãäŸãã°ç¬åœå ¬éç¹èš±ç¬¬2651639å·ã«
åŸã€ãŠè£œé ããããªãšã¹ãã«ãžãªãŒã«ãã¹âçé ž
ã¢ãã¢ãªãŒã«ãšã¹ãã«ããžããšããŒã«åã³è§Šåªã®
æ··åç©ãçŽ100ãçŽ200âã奜ãŸããã¯çŽ110ã180
âã®æž©åºŠã«ç空äžã§å ç±ããåã³åå¿ã«é²è¡ã«ã€
ããŠçæããããšããŒã«ãåå¿åšããçå»ããã
ãšã«ãã€ãŠè£œé ãããããã®æ¹æ³ã«ãããŠããžã
ãšããŒã«ã¯éå°éã§äœ¿çšãããããªãšã¹ãã«ãžãª
ãŒã«ãã¹âçé žã¢ãã¢ãªãŒã«ãšã¹ãã«ã®çé žããš
ãã«ãšã¹ãã«åºåœãïŒã¢ã«ããå€ãã奜ãŸããã¯
çŽïŒïŒïŒãçŽïŒã¢ã«ã®ãžããšããŒã«ãçšããã
ããç¹ã«å¥œé©ãªå ·äœäŸã«ããã°ããã¹çé žã¢ãã¢
ãªãŒã«ãšã¹ãã«å¯Ÿãã¹ããšããŒã«ïŒ¡ã®ã¢ã«æ¯ã
ïŒïŒïŒã®ããªãšã¹ãã«ãžãªãŒã«ãã¹çé žã¢ãã¢ãª
ãŒã«ãšã¹ãã«åã³ãã¹ããšããŒã«ïŒ¡ã®åå¿ã¯ãã
ã¹ããšããŒã«ïŒ¡ã®ãžãããªãŠã ããšãã¬ãŒãã觊
åªãšããŠçšããããšã«ããã150âäžã€25ã0.1mm
Hgã®ç空äžã«è¡ãªãããã ç¹ã«äžèšæ¹æ³ã«ããã°ãããªãšã¹ãã«ãžãªãŒã«
ãã¹çé žã¢ãã¢ãªãŒã«ãšã¹ãã«ããäžåŒ åŒäžãã¯âCH2âåã¯ã
ãåŒãã瀺
ããY1ãY4ã¯åäžã§ãç°ãªã€ãŠãããäžã€æ°ŽçŽ
åã¯ã¡ãã«ã瀺ã ã®ãžããšããŒã«ãšåå¿ãããŠç°¡ç¥ååŒ ïŒ»åŒäžãâïŒããªãšã¹ãã«ïŒâã¯èèªæãžãªãŒ
ã«ãšèèªæãžã«ã«ãã³é žãããªãããªãšã¹ãã«ãž
ãªãŒã«ã®ïŒäŸ¡ã®åºãè¡šãããåã³Y1ãY4ã¯äž
è¿°ãšå矩ã§ãã ã®ããªãšã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«ã«ãŒ
ãããŒãã補é ããã äžèšæ¹æ³ã«ããããªãšã¹ãã«ãžãªãŒã«ãã¹âãž
ããšããŒã«ã«ãŒãããŒãã¯ãå³ã¡äŸãã°äžèšã®ã
ã®ã§ããïŒ äžåŒã«ãããŠãâïŒããªãšã¹ãã«ïŒâã¯åè¿°ã
ãããªãšã¹ãã«ãžãªãŒã«ã®ïŒäŸ¡ã®åºã§ããã  ããªãšã¹ãã«ïŒããªã«ãŒãããŒãã®è£œé æ³ äžèšããªãšã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«
ã«ãŒãããŒãã¯ãå ¬ç¥ã®ïŒçžçé¢éçž®åæ³ã«ãã
ããªã«ãŒãããŒãã®è£œé ã«ãããåºçºãã¹âããš
ããŒã«ãšããŠäœ¿çšã§ãããåŸã€ãŠçš®ã ã®æ§é ã®ã
ãªãšã¹ãã«ïŒããªã«ãŒãããŒããåŸãããã æ¬çºæã«ããããªãšã¹ãã«ïŒããªã«ãŒãããŒã
ã®è£œé æ³ã¯ãããªã«ãŒãããŒãã®è£œé ã«å ¬ç¥ã®ïŒ
çžçé¢éçž®åæ³ã«åŸããããªãšã¹ãã«ãžãªãŒã«ã
ã¹âãžããšããŒã«ã«ãŒãããŒããä»ã®ãžããšããŒ
ã«ãç¹ã«åŒã®ãã®ãåã³ãã¹ã²ã³ãšPHçŽïŒã14
åã³æž©åºŠçŽïŒã80âã奜ãŸããã¯çŽ15ã40âäžã«
åå¿ãããããšãç¹è²ã§ãããæ¬çºæã«ãã€ãŠåŸ
ãããããªãšã¹ãã«ïŒããªã«ãŒãããŒãã¯ãç¡å®
圢ïŒåŒŸæ§ïŒããªãšã¹ãã«çžåã³çµæ¶åœ¢ïŒç¡¬ãïŒã
ãªã«ãŒãããŒãçžåã¯ç¡å®åœ¢ïŒçµæ¶åœ¢ïŒç¡¬ãïŒã
ãªã«ãŒãããŒãã®ååšãç¹è²ã§ããã 圢æ åŠçãªèŠ³ç¹ããèšãã°ãããªãšã¹ãã«ïŒã
ãªã«ãŒãããŒãã¯ãïŒã€ã®ç°ãªã空éçãªåé¢
çžãå³ã¡é£ç¶çãªç¡å®åœ¢ããªãšã¹ãã«ãããªãåº
ååã³çµæ¶åœ¢åã¯ç¡å®åœ¢ïŒçµæ¶åœ¢ããªã«ãŒãããŒ
ããããªãåºåãæããã æ¬çºæã«ããããªãšã¹ãã«ïŒããªã«ãŒãããŒã
ã¯ãããããå€çžã§ãããæ ã«ã察æ¯ãããåäž
çžããªãšã¹ãã«ïŒããªã«ãŒãããŒãããé«ãç±æª
枩床ãæããã åäžçžããªãšã¹ãã«ïŒããªã«ãŒãããŒãã¯ãäŸ
ãã°ç±³åœç¹èš±ç¬¬3151615å·ã«èšè¿°ãããŠãããã
ããã¯çš®ã ã®æ¹æ³ã«ããã奜ãŸããã¯ããªã«ãŒã
ããŒãã®è£œé ããå ¬ç¥ã®âããªãžã³âæ³ã«ãã€ãŠ
補é ãããã äŸãã°ããªã«ãŒãããŒãïŒããªã«ããã©ã¯ãã³
ã®ïŒçžéåäœã®è£œé ã¯ãåŸæ¥ããªã«ããã©ã¯ãã³
ã®ãã¹ã¯ãã«ããŒã¡ãŒãåã³ããªã«ãŒãããŒããª
ãªãŽããŒãçšããããšã«ãã€ãŠã ãè¡ãªãããŠã
ãïŒåç §ä»åœç¹èš±ç¬¬2235965å·ïŒããã®ããšã¯ãïŒ
çžéåäœãšããŠåå®ãããªãç¬åœç¹èš±ç¬¬1162559
å·ã®ããªãšã¹ãã«ïŒããªã«ãŒãããŒãã«å¯ŸããŠã
çå®ã§ããã æ¬çºæã«ãããããªãšã¹ãã«ãžãªãŒã«ãã¹âãž
ããšããŒã«ã«ãŒãããŒãã®äœ¿çšã¯ã察å¿ãããã·
ã¯ãã«ããŒã¡ãŒãã®äœ¿çšãšæ¯èŒããŠãå æ°Žå解ã«
察ããéææ§ãå³ã¡è¯å¥œãªè²¯èµå®å®æ§åã³æ確ãª
ïŒå®èœåå¿æ§ãšããå©ç¹ãäžããã ç¹ã«æ¬çºæã«ããããªãšã¹ãã«ïŒããªã«ãŒãã
ãŒãã¯ããã®çµæ¶åœ¢ããªã«ãŒãããŒãçžã®ããã«
é«ç±æªæž©åºŠãæããã æ¬çºæã«ããããªãšã¹ãã«ïŒããªã«ãŒãããŒã
ã®ç°ãªãçžã¯ç€ºå·®ç±åæã«ãã€ãŠæ€ç¥ããããšã
ã§ãããå³ã¡äŸãã°ããªãšã¹ãã«çžã¯ïŒ20âã®å€
圢枩床ãæãåã³ããªã«ãŒãããŒãçžã®ç¡å®åœ¢æ
åã¯çŽ100ã150âã®å€åœ¢æž©åºŠãæãäžã€ããªã«ãŒ
ãããŒãçžã®çµæ¶åœ¢æåã¯çŽ170ã250âã®çµæ¶è
ç¹ãæããã æ¬çºæã®æ¹æ³ã§è£œé ããäžã€ç±å¯å¡æ§æš¹èãšã
ãŠåŠçã§ããé«ååéã®ã»ã°ã¡ã³ãåããªãšã¹ã
ã«ïŒããªã«ãŒãããŒãã¯ããã®ç±ã«å¯Ÿããç¹å¥ãª
æ§è³ªã«å ããŠãè¯å¥œãªéææ§ãé«åŒŸæ§åã³ïŒ400
ïŒ ã®éã ã€ãç Žæ䌞匵ã瀺ãã äžèšããªãšã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«
ã«ãŒãããŒãããæ¬çºæã®ããªãšã¹ãã«ïŒããªã«
ãŒãããŒãã補é ããã®ã«é©åœãªãžããšããŒã«
ã¯ãããªãšã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«ã«
ãŒãããŒãã®è£œé ã«é¢ããŠãã§ã«èšåãããã®ã
ç¹ã«åŒã®ãã®ãäŸãã°ïŒïŒ4â²âãžããããã·â
ãžããšãã«ããã¹âïŒïŒâããããã·ããšãã«ïŒ
âã¡ã¿ã³ãïŒïŒïŒâãã¹âïŒïŒâããããã·ããš
ãã«ïŒâïŒâã¡ãã«ãã¿ã³ãαïŒÎ±âãã¹âïŒïŒ
âããããã·ããšãã«ïŒâïœâãžã€ãœãããã«ã
ã³ãŒã³ãïŒïŒïŒâãã¹âïŒïŒâã¯ãã«âïŒâãã
ããã·ããšãã«ïŒâãããã³ããã¹âïŒãããã
ã·ããšãã«ïŒã¹ã«ãã€ãåã³ïŒïŒïŒâãã¹â
ïŒïŒïŒïŒâãžã¡ãã«âïŒâããããã·ããšãã«ïŒ
âãããã³ãé©åœã§ããã æ¬çºæã«ããããªãšã¹ãã«ïŒããªã«ãŒãããŒã
ã®è£œé ã«ã¯ãïŒïŒïŒâãã¹âïŒïŒâããããã·ã
ãšãã«ïŒâãããã³ãïŒïŒïŒâãã¹âïŒïŒïŒïŒâ
ãžã¯ãã«âïŒâããããã·ããšãã«ïŒâããã
ã³ãïŒïŒïŒâãã¹âïŒïŒïŒïŒâãžããã âïŒâã
ãããã·ããšãã«ïŒâãããã³åã³ïŒïŒïŒâãã¹
âïŒïŒâããããã·ããšãã«ïŒâã·ã¯ããããµã³
ãä»ã®ãžããšããŒã«ãšããŠå¥œé©ã«äœ¿çšã§ãããã
ãããšä»ã®ãžããšããŒã«ã®æãŸããæ··åç©ã䜿çš
ã§ããã åŠçäžã«è¯å¥œãªæµåæ§ãæããåå²ãããçæ
ç©ã¯ãïŒå®èœæ§åã¯ïŒå®èœæ§ä»¥äžã®ååç©ãç¹ã«
ïŒååã¯ãã以äžã®ããšããŒã«æ§æ°Žé žåºãæãã
ååç©ãå°éã§ã奜ãŸããã¯ïŒçšãããžããšããŒ
ã«ã«å¯ŸããŠïŒçŽ0.05ãçŽïŒã¢ã«ïŒ ã§æ··å ¥ããããš
ã«ãã€ãŠè£œé ãããã é©åœãªïŒå®èœæ§åã¯ïŒå®èœæ§ä»¥äžã®ååç©ã¯ã
ãããã°ãªã·ããŒã«ãïŒïŒïŒâãžã¡ãã«âïŒïŒ
ïŒïŒïŒâããªâïŒïŒâããããã·ããšãã«ïŒâã
ããâïŒâãšã³ãïŒïŒïŒâãžã¡ãã«âïŒïŒïŒïŒïŒ
âããªâïŒïŒâããããã·ããšãã«ïŒâããã¿
ã³ãïŒïŒïŒïŒïŒâããªâïŒïŒâããããã·ããšã
ã«ïŒâãã³ãŒã³ãïŒïŒïŒïŒïŒâããªïŒïŒâããã
ãã·ããšãã«ïŒâãšã¿ã³ãããªâïŒïŒâãããã
ã·ããšãã«ïŒâããšãã«ã¡ã¿ã³ãïŒïŒïŒâãã¹â
ïŒïŒïŒâïŒïŒïŒ4â²âãžããããã·ãžããšãã«ïŒ
ã·ã¯ãããã·ã«ïŒœâãããã³ãïŒïŒïŒâãã¹â
ïŒïŒâããããã·ããšãã«âã€ãœãããã«ïŒâã
ãšããŒã«ãïŒïŒïŒâãã¹âïŒ2â²âããããã·â
5â²âã¡ãã«ãã³ãžã«ïŒâïŒâã¡ãã«ããšããŒã«ã
ïŒïŒïŒâãžããããã·å®æ¯éŠé žãïŒâïŒïŒâãã
ããã·ããšãã«ïŒâïŒâïŒïŒïŒïŒâãžããããã·
ããšãã«ïŒâãããã³ãïŒïŒïŒâãã¹âïŒïŒïŒ
4â³âãžããããã·ããªããšãã«âã¡ãã«ïŒâãã³
ãŒã³åã³ïŒïŒïŒâãã¹âïŒïŒâããããã·ããšã
ã«ïŒâïŒâãªããœâïŒïŒïŒâãžãããã€ã³ããŒã«
䞊ã³ã«ïŒïŒïŒâãã¹âïŒïŒâã¡ãã«âïŒâããã
ãã·ããšãã«ïŒâïŒâãªããœâïŒïŒïŒâãžããã
ã€ã³ããŒã«ã§ããã ããªãšã¹ãã«ïŒããªã«ãŒãããŒãã®éé·ã¯ãé
åæ¢å€äŸãã°åå®èœæ§ããšããŒã«ãäŸãã°ããšã
ãŒã«ãïŒïŒïŒâãžã¡ãã«ããšããŒã«ãïœâããã
ããšããŒã«ãåã¯ïœâtertâããã«ããšããŒã«ã
æ·»å ããããšã«ãã€ãŠèª¿ç¯ã§ããããã®äœ¿çšéã¯
çšãããžããšããŒã«ïŒã¢ã«åœãçŽ0.1ãçŽ10ã¢ã«
ïŒ ã§ãã€ãŠããã ç±å¯å¡æ§æš¹èãšããŠåŠçããããšã®ã§ããé«å
åéã®ã»ã°ã¡ã³ãåããªãšã¹ãã«ïŒããªã«ãŒãã
ãŒãã¯ïŒçžçé¢éçž®åæ³ã«ãã€ãŠè£œé ããããã
ã®ããã«ãäžè¿°ã®ä»ã®ããšããŒã«åã¯ãã®æ··åç©
ãã¢ã«ã«ãªæ°Žæº¶æ¶²ã«æº¶è§£ããã次ãã§äžèšããªãš
ã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«ã«ãŒãããŒ
ããç¹ã«åŒã®ãã®åã¯ãã®æ··åç©ããåæ§ã«æ°Ž
ãšæ··åããªãäžæŽ»æ§ãªææ©æº¶å€ã«æº¶è§£ãããã®æº¶
液ãæ·»å ããã次ãã§æ··åç©ã«ãã¹ã²ã³ã枩床çŽ
ïŒã80âã奜ãŸããã¯çŽ15ã40âåã³PHå€çŽïŒã
14ã®ããšã«éå ¥ããããã¹ã²ã³ã®éã¯çšãããžã
ãšããŒã«ãå·åŽæ段åã³åå¿æž©åºŠã«äŸåãããã
äžè¬ã«ãžããšããŒã«ïŒã¢ã«åœãçŽ1.1ã3.0ã¢ã«ã§
ããããã¹ã²ã³åã®åŸããžããšããŒã«ïŒã¢ã«åœã
çŽ0.2ã10ã¢ã«ïŒ ã®ïŒçŽèèªæã¢ãã³ãæ·»å ãã
ããšã«ãã€ãŠéçž®åãè¡ãªãããã®æ¹æ³ã§ã¯ãçŽ
ïŒã90åéã®ãã¹ã²ã³åæéãå¿ èŠã§ãããçŽïŒ
åãïŒæéã®éçž®åæéãå¿ èŠã§ããã åŸã€ãŠæ¬çºæã¯ãäžæŽ»æ§ãªææ©æº¶å€åã³ã¢ã«ã«
ãªæ°Žæº¶æ¶²ãããªã液äœæ··åç©äžã«ãããŠäžèšããª
ãšã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«ã«ãŒãããŒ
ããç¹ã«åŒã®ãã®ãä»ã®ãžããšããŒã«ãç¹ã«åŒ
ã®ãã®åã³ãã¹ã²ã³ãšæž©åºŠçŽïŒã80âã奜ãŸã
ãã¯çŽ15ã40âåã³PHå€çŽïŒã14ã®ããšã«åå¿ã
ããåã³ãã¹ã²ã³ã®æ·»å åŸãžããšããŒã«ã®ã¢ã«é
ã«å¯ŸããŠçŽ0.2ã10ã¢ã«ïŒ ã®ïŒçŽã¢ãã³ãæ·»å ã
ãããšã«ãã€ãŠéçž®ååå¿ãè¡ãªããããªãšã¹ã
ã«ãžãªãŒã«ãã¹âãžããšããŒã«ã«ãŒãããŒã察ä»
ã®ãžããšããŒã«ã®ééæ¯ãããªãšã¹ãã«ïŒããªã«
ãŒãããŒãäžã®ããªã«ãŒãããŒãã®å²ååã³ããª
ãšã¹ãã«ã®å²åã«ãã€ãŠæ±ºå®ãããããªãšã¹ã
ã«ïŒããªã«ãŒãããŒãã®è£œé æ³ã«é¢ããã åŸãããããªãšã¹ãã«ïŒããªã«ãŒãããŒãã®æ
æ©æº¶åªäžæº¶æ¶²ããïŒçžçé¢æ³ã§è£œé ãããç±å¯å¡
æ§ããªã«ãŒãããŒãã®æº¶æ¶²ãšåæ§ã«åŠçããå³ã¡
ããªãšã¹ãã«ïŒããªã«ãŒãããŒããåŸåŠçã«äŸã
ããç¹ã«ããããïœïŒå ¬ç¥ã®æ¹æ³ã§ãäŸãã°ã¡ã¿
ããŒã«åã¯ãšã¿ããŒã«ã§ã®æ²æŸ±ã«ããåé¢ãã次
ãã§ä¹Ÿç¥ããåã¯åªæåã«äŸãåã¯ææ©æº¶å€ã«æº¶
解ããŠã²ã«åããããæãã¯ïœïŒåé¢äžã«ãäŸã
ã°æ®çºç©ãé€å»ããæŒãåºãæ©ã§ãã§ã«åªæåã«
äŸããæãã¯ïœïŒåé¢åã«ïŒçžçé¢æ³ã«ããããª
ãšã¹ãã«ïŒããªã«ãŒãããŒãã®è£œé ã«çšãããã
溶åªäžã§ã²ã«åããããã æ¬çºæã«ããããªãšã¹ãã«ïŒããªã«ãŒãããŒã
ã®è£œé ã«é©åœãªäžæŽ»æ§ææ©æº¶å€ã¯ãæ°Žãšæ··åããª
ãèèªæå¡©çŽ åçåæ°ŽçŽ ãäŸãã°å¡©åã¡ãã¬ã³ã
ã¯ãããã«ã åã³ïŒïŒïŒâãžã¯ãã«ãšã¿ã³ãåã¯
å¡©çŽ åè³éŠæååç©ãäŸãã°ã¯ãã«ãã³ãŒã³ããž
ã¯ãã«ãã³ãŒã³åã³ã¯ãã«ãã«ãšã³æãã¯ããã
ã®æº¶å€ã®æ··åç©ã§ããã æ¬çºæã®æ¹æ³ã«é©åœãªã¢ã«ã«ãªæ°Žæº¶æ¶²ã¯ãLi
ïŒOHïŒ2ïŒNaOHïŒKOHïŒCaïŒOHïŒ2åã³ïŒåã¯
BaïŒOHïŒ2ã®æ°Žæº¶æ¶²ã§ããã æ¬çºæã®æ¹æ³ã«é©åœãªïŒçŽèèªæã¢ãã³ã¯ãç
çŽ æ°çŽïŒã15ã®ãã®ãå³ã¡äŸãã°ããªã¡ãã«ã¢ã
ã³ãããªãšãã«ã¢ãã³ãïœâããªãããã«ã¢ãã³
åã³ïœâããªããã«ã¢ãã³ã§ãããçšãããžããš
ããŒã«ã«äŸåããŠçŽ0.2ãïŒã¢ã«ïŒ ã§å€åãåã³
ããã©ã¡ãã«çœ®æãžããšããŒã«ãçšããå Žåã«ã¯
çšãããžããšããŒã«ã®å šéïŒïŒããªãšã¹ãã«ãžãª
ãŒã«ãã¹âãžããšããŒã«ã«ãŒãããŒãåã³ä»ã®ãž
ããšããŒã«ã®åèšïŒã«å¯ŸããŠçŽïŒã10ã¢ã«ïŒ ã§å€
åããã æ¬çºæã®æ¹æ³ã§è£œé ãããããªãšã¹ãã«ïŒããª
ã«ãŒãããŒãã¯æ¬¡ã®æ¹æ³ã§åé¢ããããšãã§ã
ãïŒ ïœ ææ©æº¶åªãããæ¿åºŠãŸã§çå»ããé«æ¿åºŠïŒçŽ
30ã40ééïŒ ïŒã®éåäœæº¶æ¶²ã補é ããç¶ããŠ
æ®ãã®æº¶åªããã€ããèžçºãããŠããªãšã¹ã
ã«ïŒããªã«ãŒãããŒããã²ã«åãããã ïœ æ²æŸ±ã«é©åœãªæº¶åªã®ææ©æº¶åªãäŸãã°ã¡ã¿ã
ãŒã«ããšã¿ããŒã«ãã€ãœãããããŒã«ãã¢ã»ã
ã³ãèèªæçåæ°ŽçŽ åã³èèªæçåæ°ŽçŽ ãçšã
ãããšã«ããããªãšã¹ãã«ïŒããªã«ãŒãããŒã
ãææ©æº¶åªã§æ²æŸ±ãããã ïœ è±æ®çºç©æŒåºæ©äžã«ãããŠããªãšã¹ãã«ïŒã
ãªã«ãŒãããŒããããªã«ãŒãããŒãã«å¯ŸããŠå ¬
ç¥ã®æ¡ä»¶äžã«çŽ160ã240âã§åé¢ããåªæåã
é©çšããã æ¬çºæã®æ¹æ³ã§è£œé ããããããªãšã¹ãã«ïŒã
ãªã«ãŒãããŒãã¯ãåé¢ããã«ïŒçžåå¿æ··åç©ã®
åŠçææ©çžäžã«ãããŠåã¯äºããåé¢ããããªãš
ã¹ãã«ïŒããªã«ãŒãããŒãã®å¥ã®ææ©æº¶åªæ¶²æ¶²äž
ã«ãããŠãé«æ¿åºŠéåäœæº¶æ¶²ãå·åŽåããããšã«
ãã€ãŠã²ã«åãããããããã²ã«åæéã¯ããªãš
ã¹ãã«åã¯ããªã«ãŒãããŒãã®å²åã«äŸåããã
çŽïŒã40âã§çŽïŒåéã12æéã§ããã ã²ã«åããçæç©ã¯ç²æ«ç²ç¶ã®æ··åç©ãšããã
ãã«åŠçã§ããåŸãããããªãšã¹ãã«ïŒããªã«ãŒ
ãããŒãã50âã§çŽ48æéåã³100âã§24æéç
空äžã«ä¹Ÿç¥ããã åé¢ããããªãšã¹ãã«ïŒããªã«ãŒãããŒãã®å¥
眮ã²ã«åã«é©åœãªæº¶åªã¯ãææ©æº¶åªãäŸãã°å¡©å
ã¡ãã¬ã³ããã³ãŒã³ããã«ãšã³åã¯ãã·ã¬ã³ã§ã
ãã åé¢ããããªãšã¹ãã«ïŒããªã«ãŒãããŒãã®ç±
åŠçã¯çŽ40ã170âã§çŽïŒåéã24æéè¡ãªãã
ãã åé¢ããããªãšã¹ãã«ïŒããªã«ãŒãããŒãã«çŽ
130ã240âã®æž©åºŠã§çŽ0.5ã30åéåªæåãäœçš
ãããéåäœKgåœãçŽ0.2ã0.7KWhã®åªæåãé©
çšãããã äžèšããªãšã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«
ã«ãŒãããŒããšãžããšããŒã«åã³ãã¹ã²ã³ãšã®ïŒ
çžçé¢æ³ã«ããæ¬çºæã®åå¿ã¯å®éçã«é²è¡ã
ããåŸã€ãŠããªãšã¹ãã«ãžãªãŒã«ãã¹âãžããšã
ãŒã«ã«ãŒãããŒã察ä»ã®ãžããšããŒã«ã®åå¿ç©æ¯
ã¯åæãã¹ãããªãšã¹ãã«ïŒããªã«ãŒãããŒãã®
ããªã«ãŒãããŒãæååã³ããªãšã¹ãã«æåã«ã
ã€ãŠæ±ºå®ãããã æ¬çºæã®æ¹æ³ã§è£œé ãããããªãšã¹ãã«ïŒããª
ã«ãŒãããŒãäžã®ããªã«ãŒãããŒãã®å²åã¯ãæ
åŸ ããæ§è³ªã«å¿ããŠçŽ30ã95ã奜ãŸããã¯çŽ35ã
80ééïŒ ã§ãããããã«ç¡¬åºŠåã³ç±æªæž©åºŠãåã³
匟æ§åã³ç Žæ䌞é·ã¯ãããããããªã«ãŒãããŒã
ã®å²åã®å¢å ãšäŸã«å¢å ããåã³æžå°ããã æ¬çºæã«ããããªãšã¹ãã«ïŒããªã«ãŒãããŒã
äžã®ããªã«ãŒãããŒãã®å²åã¯ãäžåŒ åŒäžãã¯ããªãšã¹ãã«ïŒããªã«ãŒãããŒã
äžã®ãžããšãã¬ãŒãåºãè¡šãã ã®è³éŠæããªã«ãŒãããŒãæ§é åäœãç¹ã«åŒïœ åŒäžãåã³Y1ãY4ã¯åŒãšå矩ã§ãã ã®è³éŠæããªã«ãŒãããŒãæ§é åäœã®ééã«ãã
éãšããŠç解ãã¹ãã§ããã æ¬çºæã«ããããªãšã¹ãã«ïŒããªã«ãŒãããŒã
ã®ããªãšã¹ãã«ã®å²åã¯ã察å¿ããŠç°¡ç¥ååŒ â
âïŒããªãšã¹ãã«ïŒââ ã®ããªãšã¹ãã«ïŒãžãªãŒã«ã®ïŒçš®ã®ããªãšã¹ãã«
ãžãªãŒã¬ãŒããããã¯åäœã®ééã«ããéãšããŠ
ç解ãã¹ãã§ããã åŸã€ãŠæ¬çºæã¯ãåŒãç¹ã«åŒïœã®è³éŠæã
ãªã«ãŒãããŒãæ§é åäœçŽ30ã95ééïŒ ã奜ãŸã
ãã¯çŽ35ã80ééïŒ åã³äžè¿°ã®ããªãšã¹ãã«ãžãª
ãŒã¬ãŒããããã¯åäœçŽ70ãïŒééïŒ ã奜ãŸãã
ã¯çŽ65ã20ééïŒ ãããªãããªãšã¹ãã«ïŒããªã«
ãŒãããŒãã«é¢ããã æ¬çºæã«ããããªãšã¹ãã«ïŒããªã«ãŒãããŒã
ã¯ãäŸãã°åŒïœ åŒäžãã¯ïŒšåã¯CH3ã§ãã ã®ããªã«ãŒãããŒãæ§é åäœçŽ30ãçŽ95ééïŒ ã
奜ãŸããã¯çŽ35ã80ééïŒ ãåã³ããªãšã¹ãã«ãž
ãªãŒã¬ãŒããããã¯åäœçŽ70ãçŽïŒééïŒ ã奜ãŸ
ããã¯çŽ65ãçŽ20ééïŒ ãããªããã®ã§ããã æ¬çºæã«ããããªãšã¹ãã«ïŒããªã«ãŒãããŒã
ã¯ãå æ£ä¹±å 床èšãçšããå æ£ä¹±æ³ã§æ±ºå®ãããš
ããçŽ25000ã200000ã奜ãŸããã¯çŽ70000ã
150000ã®å¹³åååéïœïŒééå¹³åïŒãæãã¹ã
ã§ãããæ¬çºæã«ããããªãšã¹ãã«ïŒããªã«ãŒã
ããŒãã®çžå¯Ÿæº¶æ¶²ç²åºŠÎ·relïŒCH2Cl2100mläž0.5ïœ
ã§25âäžã«æž¬å®ïŒã¯ãçŽ1.3ã3.0ã奜ãŸããã¯çŽ
1.4ã2.6ã§ããã æ¬çºæã®æ¹æ³ã§è£œé ããäžã€ç±å¯å¡æ§æš¹èãšã
ãŠåŠçããããšã®ã§ããé«ååéã®ã»ã°ã¡ã³ãå
ããªãšã¹ãã«ïŒããªã«ãŒãããŒãã¯ã瀺差ç±åæ
ã§æž¬å®ãããšãããªãšã¹ãã«æåãç¡å®åœ¢ã§ååš
ãäžã€çŽâ100âãïŒ100âã奜ãŸããã¯çŽâ80â
ãïŒ20âã®å€åœ¢æž©åºŠãæãããåã³ããªã«ãŒãã
ãŒãæåãéšåçã«çµæ¶åœ¢ã§ååšãäžã€çµæ¶ããª
ã«ãŒãããŒãéšåãå°ãªããšã160âã奜ãŸãã
ã¯çŽ165ã250âã®çµæ¶èç¹ãæãããåã³ç¡å®åœ¢
ããªã«ãŒãããŒãéšåã®å€åœ¢æž©åºŠãçŽ80â以äžã
奜ãŸããã¯çŽ100â以äžã§ãããããšãç¹è²ã§ã
ãã ããªãšã¹ãã«æåã®å€åœ¢æž©åºŠåã³ããªã«ãŒãã
ãŒãæåã®å€åœ¢æž©åºŠåã³çµæ¶èç¹ã«ãããäžè¿°ã®
å·®ã¯ãããªãšã¹ãã«æååã³ããªã«ãŒãããŒãæ
åéã®çžåé¢ã®ååšã«å¯ŸããŠç¹åŸŽçã§ãããå°ã
ãšãïŒã8calïŒïœéåäœã®æž¬å®ããã溶èãšã³ã¿
ã«ããŒã§æ€ç¥ããããšã®ã§ããæ¬çºæã®ããªãšã¹
ãã«ïŒããªã«ãŒãããŒãã®ããªã«ãŒãããŒãæå
ã®éšåççµæ¶å床ã¯ã延䌞åã³ç¶ã40ã170âã§
ã®ç±åŠçïŒïŒåéã25æéïŒã«ããæãã¯å€è»žã¹
ã¯ãªãŠãŒæŒåºãæ©ã§ã®ç±å¯å¡æ§åŠçã«ãããåªæ
åã®äœçšã«ããæŽã«50ïŒ ã ãå¢å ãããããšãã§
ããããã®ãšãçæç©ã®ç±æªæž©åºŠã¯äžæããèŠã
ãã¯éæããåéæãªããäžéæã«å€åããã éšåçã«çµæ¶åœ¢ã®åŒŸæ§ããªãšã¹ãã«ïŒããªã«ãŒ
ãããŒãã¯ãçµæ¶ããªã«ãŒãããŒãéšåã®çµæ¶è
ç¹ä»¥äžåã¯ãã®ä»è¿ã®çŽ130ãæé«250âã®æž©åºŠã§
ç±å¯å¡æ§æš¹èãšããŠåŠçããããšãã§ããããã®
å Žåçµæ¶å床ã®å®è³ªçãªéšåãä¿æããããç¡å®
圢ã§éæãªçæç©ã¯ãçµæ¶åœ¢ããªã«ãŒãããŒãéš
åã®çµæ¶èç¹ä»¥äžã®åŠç枩床ã§åŸãããã å³ã¡æ¬çºæã«ããããªãšã¹ãã«ïŒããªã«ãŒãã
ãŒãã®ããªã«ãŒãããŒãéšåã®çµæ¶åœ¢å²åã¯ãå€
ããããšãã§ãããŸãããªãšã¹ãã«ïŒããªã«ãŒã
ããŒãã«äœ¿çšäžã®é«ç±æªæž©åºŠãä»äžããããã«çŽ
ïŒã8calïŒïœéåäœã奜ãŸããã¯çŽ2.5ã5.5calïŒ
ïœéåäœã®æº¶èãšã³ã¿ã«ããŒãäžããã®ã«ååã§
ããã æ¬çºæã«åŸãããªãšã¹ãã«ïŒããªã«ãŒãããŒã
ãç±åŠçãªãã«ãã²ã«åãªãã«åã³åªæåã®é©çš
ãªãã«åŠçãäžã€åé¢ããå Žåãåäžçžã®ããªãš
ã¹ãã«ïŒããªã«ãŒãããŒããå³ã¡ç€ºå·®ç±åæã§æž¬
å®ã§ããå€åœ¢æž©åºŠãïŒã€ã ãæããçæç©ãåŸã
ããã æ¬çºæã«ããããªãšã¹ãã«ïŒããªã«ãŒãããŒã
ã®UVå ã«å¯Ÿããå®å®æ§åã³å æ°Žå解ã«å¯Ÿããå®
å®æ§ã¯ãç±å¯å¡æ§ããªã«ãŒãããŒãã«éåžžã®UV
å®å®å€ãäŸãã°çœ®æãããâãã³ãŸããšãã³âå
ã¯âãã³ãºããªã¢ãŸãŒã«âã«ãããå æ°Žå解ã«å¯Ÿ
ããå®å®æ§ãä»äžããè¬å€ãäŸãã°ã¢ãã«ã«ããž
ã€ããåã³äžã§ãããªã«ã«ããžã€ããåç §ã
W.NewmanãJ.PeterïŒH.Holtschmidt and W.
KallertïŒProceeding of the 4th Rubber
Technology ConferenceïŒLondonïŒïŒæ22ã25
æ¥ã1962幎ã738ã751é ãäŸãã°ããªãšã¹ã
ã«ïŒããªã«ãŒãããŒãã®ééã«å¯ŸããŠ0.2ãïŒé
éïŒ ã®è¬å€ã«ãããåã³ç±å¯å¡æ§ããªãšã¹ãã«å
ã³ç±å¯å¡æ§ããªã«ãŒãããŒãã®ååŠã«ãããŠå ¬ç¥
ã®èåé²æ¢å€ã«ããæ¹è¯ããããšãã§ããã æŽã«äŸãã°ã«ãŒãã³ãã©ãã¯ãçªè»åãã«ãªãª
ã³ãç²åãCaF2ïŒCaCO3ãé žåã¢ã«ãããŠã å
ã³éåžžã®ã¬ã©ã¹ç¹ç¶ã®åŠãç©è³ªãæ圢çµæç©ã®å š
ééã«å¯ŸããŠçŽïŒã40ééïŒ ã®éã§æ·»å ã§ããå
ã³ç¡æ©é¡æãå å¡«å€åã³æ žåå€ãšããŠæ·»å ã§ãã
ãã®çµææ¬çºæã«ããçæç©ãæ¹è³ªããããšãã§
ããã é£çæ§çæç©ãæåŸ ããå Žåã«ã¯ãç±å¯å¡æ§ã
ãªãšã¹ãã«åã³ç±å¯å¡æ§ããªã«ãŒãããŒãã®ååŠ
ã«ãããŠå ¬ç¥ã®é£çå€ãäŸãã°äžé žåã¢ã³ãã¢
ã³ãããã©ããã ãã¿ã«é žç¡æ°Žç©ããããµããã
ã·ã¯ãããã«ã³ãããã©ã¯ãã«ãããã¯ããã©ã
ãã ãã¹ããšããŒã«ïŒ¡åã¯ããªã¹âïŒïŒïŒïŒâãž
ã¯ãã«ãããã«ïŒãã¹ããšãŒããããªãšã¹ãã«ïŒ
ããªã«ãŒãããŒãã®ééã«å¯ŸããŠçŽïŒã15ééïŒ
æ··åããããšãã§ãããæ¬çºæã«ããããªã«ãŒã
ããŒãã®ããªã«ãŒãããŒãéšåã«çµ±èšçã«æ··å ¥ã
ããããã©ã¯ãã«åã³ããã©ããã ãã¹ããšããŒ
ã«ãé£çæ§ã瀺ãã æŽã«ãç±å¯å¡æ§ããªãšã¹ãã«åã³ç±å¯å¡æ§ããª
ã«ãŒãããŒãã®ååŠã«ãããŠå ¬ç¥ã®åŠçå©å€ãäŸ
ãã°é¢åå€ãå¹æçã«äœ¿çšã§ããã æ¬çºæã«ãã€ãŠè£œé ãããããªãšã¹ãã«ïŒããª
ã«ãŒãããŒãã¯ã硬床åã³åŒŸæ§ãç¹ã«å·æææ§ã®
çµåããæåŸ ãããã¹ãŠã®äºäŸã«ãããŠãäŸãã°
èªåè»ã®è»äœã«ãèªåè»ã®äœå§ã¿ã€ã€ã®è£œé ã«ã
ããŒã¹ãã·ãŒãä»ã³ããŠãŒãã®å€ç®ã«åã³æè»ãª
é§åããŒãªãŒã«æå©ã«äœ¿çšã§ããã 次ã®åèäŸã«ç€ºãå¹³åååéã¯æ°å¹³åååé
ïœã§ãããOHæ°ã®æž¬å®ã«ãã€ãŠæ±ºå®ãããã å®æœäŸ1aã1fã®çžå¯Ÿæº¶æ¶²ç²åºŠÎ·relã¯ãå¡©åã¡ã
ã¬ã³100mläžã®ããªãšã¹ãã«ïŒããªã«ãŒãããŒã
0.5ïœã®æº¶æ¶²ã®25âã«ãããç²åºŠãšããŠå®çŸ©ãã
ãã åŒåŒµã匷床åã³ç Žææ䌞匵ã¯DIN第53455å·ã
察å¿ããŠASTM第â638å·ã«åŸã€ãŠæž¬å®ããã
ã²ã«ã¯ãããã°ãã€ãŒã«ããæ€èšã¯ãããã©ãã
ããã©ã³åã³ã¹ãã©ã²ã«ã«ã©ã ïŒåé¢ç¯å²1.5Ã
105â«ïŒïŒÃ105â«ïŒïŒÃ104â«åã³ïŒÃ103â«ïŒã
çšããŠå®€æž©ã§è¡ãªã€ãã決å®ã«å¯ŸããŠã¯ããã¹ã
ãšããŒã«ïŒ¡ããªã«ãŒãããŒãã®è£æ£æ²ç·ãçšã
ããå æ£ä¹±æ³ã«ãã€ãŠæ±ºå®ããïœãšæ¯ã¹ãŠã倧
ããªåå·®ã¯èŠåºãããªãã€ãã 瀺差ç±åæã¯ãE.I.ããŠãã³ç€Ÿè£œã®âDu Pont
900åâãçšããŠè¡ãªã€ããå€åœ¢æž©åºŠã解éãã
å Žåãæ¥ç·æ³ã«åŸã€ãŠè»å枩床ç¯å²ã®å¡ãäžç¹ã
éžã³ãåã³çµæ¶èç¹ã®å Žåã溶èæ²ç·ã®åžç±ããŒ
ã¯ã®å¡ãäžç¹ãéžæããã åèäŸïŒã«ç€ºãã·ãŠã¿ãŠãã€ã³ã¬ãŒææ°ïŒ»Î·ïŒœ
ã¯25âãããã©ããããã©ã³äžã§æž¬å®ããdlïŒïœ
ã§è¡šç€ºãããã·ãŠã¿ãŠãã€ã³ã¬ãŒææ°ã®å®çŸ©ã«é¢
ããŠã¯ãH.G.ãšãªã¢ã¹ïŒEliasïŒèã
âMakromolekušleâïŒHušthig ïŒ Wepfâ
Verlag Basle 265é ãåç §ã®ããšã åèäŸ ïŒ ããªãšã¹ãã«ãžãªãŒã«ãã¹âçé žã¢ãã¢ãªãŒã«
ãšã¹ãã«ã®è£œé å¹³åååéïœïŒ800ãæãããããµã³âïŒïŒ
ïŒâãžãªãŒã«åã³ã¢ãžãã³é žããã®ããªãšã¹ãã«
ãžãªãŒã«800éééšãçé žãžããšãã«856éééšå
ã³ãããªãŠã ããšãã¬ãŒã0.05éééšããçªçŽ äž
ã«æªæããªãã15mmHgã®ç空ã§3.5æé150âã«
å ç±ããããã®æéäžåå¿æ··åç©ããããšããŒã«
187éééšãçå»ããã次ãã§éå°ã®çé žãžããš
ãã«ãæ¿¡å£èžçºæ©ã§200âïŒ0.1mmïœäžã«é€å»ã
ããç¡è²ã®ç²çš ãªæ²¹ãåŸãã ηããã©ããããã©ã³ïŒ0.072 OHæ°ïŒïŒ åæïŒèšç®å€ïŒïŒ£ïŒ66.5ïŒ ïŒïŒšïŒ8.2ïŒ å®éšå€ïŒïŒ£ïŒ63.3ïŒ ïŒïŒšïŒ8.3ïŒ åèäŸ 6a ãã¹ããšããŒã«A18.5ééïŒ åã³ãã¹ããšããŒ
ã«ïŒ¡åã³çé žãžããšãã«ã®åå¿çæç©ãå«æã
ãããªãšã¹ãã«ãžãªãŒã«ãã¹âïŒãã¹ããšããŒ
ã«ïŒ¡ïŒã«ãŒãããŒãã®è£œé åèäŸïŒã«åŸããããµã³âïŒïŒïŒâãžãªãŒã«å
ã³ã¢ãžãã³é žãã補é ãããå¹³åååéïœïŒ
1900ã®ããªãšã¹ãã«ãžãªãŒã«ã§ãã€ãŠãããã«ç
é žãžããšãã«çŽ26.3éééšïŒå šéã«å¯ŸããŠæ®åå«
é5.9ééïŒ ïŒãæ··åãã該ããªãšã¹ãã«ãžãªãŒ
ã«ã®ãã¹çé žã¢ãã¢ãªãŒã«ãšã¹ãã«446.3éééš
ïŒ0.2ã¢ã«ïŒãïŒïŒïŒâãã¹âïŒïŒâããããã·ã
ãšãã«ïŒâãããã³ïŒãã¹ããšããŒã«ïŒ¡ïŒ191.7
éééšåã³è§Šåª0.2éééšïŒãã¹ããšããŒã«ïŒ¡ã®
ãããªãŠã ãã¹âããšãã¬ãŒãïŒãã¹ããšããŒã«
ïŒïŒïŒ100ïŒãçªçŽ äžã«æªæããªãã0.05mm
ïœã§ïŒæé150âã«å ç±ããããã®æéäžãããš
ããŒã«57.3éééšãçå»ããã åèäŸ 6b ãã¹ããšããŒã«A18.7ééïŒ åã³ãã¹ããšããŒ
ã«ïŒ¡åã³çé žãžããšãã«ã®åå¿çæç©ãå«æã
ãããªãšã¹ãã«ãžãªãŒã«ãã¹âïŒãã¹ããšããŒ
ã«ïŒ¡ïŒã«ãŒãããŒãã®è£œé åèäŸïŒã«åŸããããµã³âïŒïŒïŒâãžãªãŒã«å
ã³ã¢ãžãã³é žãã補é ãããå¹³åååéïœïŒ
800ã®ããªãšã¹ãã«ãžãªãŒã«ã§ãã€ãŠãããã«ç
é žãžããšãã«çŽ27.0éééšïŒå šéã«å¯ŸããŠæ®åå«
é4.3ééïŒ ïŒãæ··åãã該ããªãšã¹ãã«ãžãªãŒ
ã«ã®ãã¹çé žã¢ãã¢ãªãŒã«ãšã¹ãã«627éééšã
ïŒïŒïŒâãã¹âïŒïŒâããããã·ããšãã«ïŒâã
ããã³ïŒãã¹ããšããŒã«ïŒ¡ïŒ431.5éééšåã³è§Š
åª0.43éééšïŒãã¹ããšããŒã«ïŒ¡ã®ãããªãŠã ã
ã¹âããšãã¬ãŒãïŒãã¹ããšããŒã«ïŒ¡ïŒïŒïŒ100ïŒ
ãçªçŽ äžã«æªæããªãã0.5mmïœã§ïŒæé125â
ã«æ¬¡ãã§ïŒæé150âã«å ç±ããããã®æéäžã
ããšããŒã«123éééšãçå»ããã åèäŸ 6c ãã¹ããšããŒã«A26.1ééïŒ åã³ãã¹ããšããŒ
ã«ïŒ¡åã³çé žãžããšãã«ã®åå¿çæç©ãå«æã
ãããªãšã¹ãã«ãžãªãŒã«ãã¹âïŒãã¹ããšããŒ
ã«ïŒ¡ïŒã«ãŒãããŒãã®è£œé åèäŸïŒã«åŸãã¢ã«æ¯65ïŒ35ã®ãããµã³âïŒïŒ
ïŒâãžãªãŒã«ïŒããªãã³ãã«ã°ãªãŒã«åã³ã¢ãžã
ã³é žãã補é ãããå¹³åååéïœïŒ1828ã®ããª
ãšã¹ãã«ãžãªãŒã«ã§ãã€ãŠãããã«çé žãžããšã
ã«çŽ164.5éééšïŒå šéã«å¯ŸããŠæ®åå«é8.8éé
ïŒ ïŒãæ··åãã該ããªãšã¹ãã«ãžãªãŒã«ã®ãã¹ç
é žã¢ãã¢ãªãŒã«ãšã¹ãã«1870éééšãïŒïŒïŒâã
ã¹âïŒïŒâããããã·ããšãã«ïŒâãããã³ïŒã
ã¹ããšããŒã«ïŒ¡ïŒ986éééšåã³è§Šåª1.5éééš
ïŒãã¹ããšããŒã«ïŒ¡ã®ãããªãŠã ãã¹âããšãã¬
ãŒãïŒãã¹ããšããŒã«ïŒ¡ïŒïŒïŒ100ïŒãçªçŽ äžã«
æªæããªãã0.25mmïœã§æåã«ïŒæé125âã«
次ãã§ïŒæé150âã«å ç±ããããã®æéäžãã
ãšããŒã«246éééšãçå»ããã åèäŸ 6d ãã¹ããšããŒã«A15.6ééïŒ åã³ãã¹ããšããŒ
ã«ïŒ¡åã³çé žãžããšãã«ã®åå¿çæç©ãå«æã
ãããªãšã¹ãã«ãžãªãŒã«ãã¹âïŒãã¹ããšããŒ
ã«ïŒ¡ïŒã«ãŒãããŒãã®è£œé åèäŸïŒã«åŸãã¢ã«æ¯65ïŒ35ã®ãããµã³âïŒïŒ
ïŒâãžãªãŒã«ïŒããªãã³ãã«ã°ãªã³ãŒã«åã³ã¢ãž
ãã³é žãã補é ãããå¹³åååéïœïŒ1828ã®ã
ãªãšã¹ãã«ãžãªãŒã«ã§ãã€ãŠãããã«çé žãžããš
ãã«çŽ12.8éééšïŒå šéã«å¯ŸããŠæ®åå«é4.1é
éïŒ ïŒãæ··åãã該ããªãšã¹ãã«ãžãªãŒã«ã®ãã¹
çé žã¢ãã¢ãªãŒã«ãšã¹ãã«313éééšãïŒïŒïŒâ
ãã¹âïŒïŒâããããã·ããšãã«ïŒâãããã³
ïŒãã¹ããšããŒã«ïŒ¡ïŒ120.5éééšåã³ãããªãŠã
ããšãã¬ãŒã0.02éééšãçªçŽ äžã«æªæããªãã
0.06mmïœã§æåã«ïŒæé125âã«æ¬¡ãã§ïŒæé
150âã«å ç±ããããã®æéäžãããšããŒã«31.5
éééšãçå»ããã åèäŸ 6e ãã¹ããšããŒã«A16.8ééïŒ åã³ãã¹ããšããŒ
ã«ïŒ¡åã³çé žãžããšãã«ã®åå¿çæç©ãå«æã
ãããªãšã¹ãã«ãžãªãŒã«ãã¹âïŒãã¹ããšããŒ
ã«ïŒ¡ïŒã«ãŒãããŒãã®è£œé åèäŸïŒã«åŸãããªãã³ãã«ã°ãªã³ãŒã«åã³ã¢
ãžãã³é žãã補é ãããå¹³åååéïœïŒ2000ã®
ããªãšã¹ãã«ãžãªãŒã«ã§ãã€ãŠãããã«çé žãžã
ãšãã«çŽ18.1éééšïŒå šéã«å¯ŸããŠæ®åå«é5.2
ééïŒ ïŒãæ··åãã該ããªãšã¹ãã«ãžãªãŒã«ã®ã
ã¹çé žã¢ãã¢ãªãŒã«ãšã¹ãã«348.1éééšãïŒïŒ
ïŒâãã¹âïŒïŒâããããã·ããšãã«ïŒâããã
ã³ïŒãã¹ããšããŒã«ïŒ¡ïŒ139.5éééšåã³è§Šåª
0.14éééšïŒãã¹ããšããŒã«ïŒ¡ã®ãããªãŠã ãã¹
âããšãã¬ãŒãïŒãã¹ããšããŒã«ïŒ¡ïŒïŒïŒ100ïŒ
ãçªçŽ äžã«æªæããªãã0.5mmïœã§æåã«ïŒæ
é125âã«æ¬¡ãã§ïŒæé150âã«å ç±ããããã®æ
éäžãããšããŒã«37.6éééšãçå»ããã åèäŸ 6f ïŒïŒïŒâãã¹âïŒïŒïŒïŒâãžã¡ãã«âïŒâãã
ããã·ããšãã«ïŒâãããã³åã³ïŒïŒïŒâãã¹
âïŒïŒïŒïŒâãžã¡ãã«âïŒâããããã·ããšã
ã«ïŒâãããã³åã³çé žãžããšãã«ã®åå¿çæ
ç©ã14.8ééïŒ ã®éã§å«æããåŒïœã®ããªãš
ã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«ã«ãŒãããŒ
ãã®è£œé åèäŸïŒã«åŸããããµã³âïŒïŒïŒâãžãªãŒã«å
ã³ã¢ãžãã³é žãã補é ãããå¹³åååéïœïŒ
800ã®ããªãšã¹ãã«ãžãªãŒã«ã§ãã€ãŠãããã«ç
é žãžããšãã«çŽïŒéééšïŒå šéã«å¯ŸããŠæ®åå«é
ïŒééïŒ ïŒãæ··åãã該ããªãšã¹ãã«ãžãªãŒã«ã®
ãã¹çé žã¢ãã¢ãªãŒã«ãšã¹ãã«303éééšãïŒïŒ
ïŒâãã¹âïŒïŒâããããã·ããšãã«ïŒâããã
ã³232.2éééšåã³è§Šåª0.22éééšïŒãã¹ããšã
ãŒã«ïŒ¡ã®ãããªãŠã ãã¹âããšãã¬ãŒãïŒãã¹ã
ãšããŒã«ïŒ¡ïŒïŒïŒ100ïŒãçªçŽ äžã«æªæããªãã
0.1mmïœã§æåã«ïŒæé125âã«æ¬¡ãã§4.5æé
150âã«å ç±ããããã®æéäžãããšããŒã«49é
ééšãçå»ããã å®æœäŸ 1a 50ééïŒ ã®ããªãšã¹ãã«éšåãæããããªãšã¹
ãã«ïŒããªã«ãŒãããŒãã®è£œé 45ïŒ NaOH70éééšåã³èžçæ°Ž1300éééšã«
溶解ãããã¹ããšããŒã«A40.2éééšåã³ïœâ
tertâããã«ããšããŒã«0.885éééšã®æº¶æ¶²ã«ãå¡©
åã¡ãã¬ã³1725éšã«æº¶è§£ããåèäŸ6aããã®ç²
çš ãªæ²¹151.5éééšãæ·»å ããã次ãã§çªçŽ äžã«
æªæããªãããã¹ã²ã³58.3éééšã20ã25âã§30
åéã«äºãéå ¥ããããã®æéäžãPHå€ã13ã®äž
å®å€ãšãªãããã«45ïŒ NaOH111éééšãåæã«
滎ã ã«æ·»å ããããã¹ã²ã³ã®éå ¥åŸãïŒïŒ ã®ããª
ãšãã«ã¢ãã³æº¶æ¶²39.8éééšãæ·»å ããæ··åç©ã
ïŒæéæªæãããææ©çžãåé¢ããïŒïŒ çé žåã³
æåŸã«èžçæ°ŽãçšããŠé»è§£è³ªããªããªããŸã§é£ç¶
çã«æŽæµãããæ°Žãåé¢ããåŸãææ©çžã次ã®æ¹
æ³ã§åŠçããã 1a.1 CH2Cl2ãããæ¿åºŠãŸã§çå»ããããšã«ããã
åã¯ã¯ãã«ãã³ãŒã³ãææ©çžã«æ·»å ãåã³å šå¡©å
ã¡ãã¬ã³ãçå»ããããšã«ãããé«æ¿åºŠïŒçŽ30ã
40ééïŒ ïŒã®éåäœæº¶æ¶²ãåŸãã次ãã§æ®ãã®å¡©
åã¡ãã¬ã³åã¯ã¯ãã«ãã³ãŒã³ããã€ããèžçºã
ããããšã«ãã€ãŠããªãšã¹ãã«ïŒããªã«ãŒãããŒ
ããã²ã«åããã次ãã§ãããæŽã«ç²æ«ç²åæ··å
ç©ã«åŠçãããåŸãããããªãšã¹ãã«ïŒããªã«ãŒ
ãããŒãã50âã§48æéåã³100âã§24æéç空
äžã«ä¹Ÿç¥ããã 1a.2 溶åªãçå»ããæ®æž£ã15mmïœåã³çŽ80ã110
âã®ç空也ç¥æ©äžã§ä¹Ÿç¥ããç¶ããŠç²ç ããããš
ã«ãã埮ç²ç ãããåºäœçæç©ãåŸãã 1a.3 äŸãã°ã¡ã¿ããŒã«ããšã¿ããŒã«ãã€ãœãããã
ãŒã«ãã¢ã»ãã³ãèèªæçåæ°ŽçŽ åã³èç°æçå
æ°ŽçŽ ãçšããŠããªãšã¹ãã«ïŒããªã«ãŒãããŒãã
ææ©çžããæ²æ®¿ãããç¶ããŠæ²æ®¿ã80ã110âå
ã³15mmïœã®ç空也ç¥åšäžã§ä¹Ÿç¥ããã 1a.4 ææ©çžãèžçºåŒæŒåºæ©äžã§æ¿çž®ããç¶ããŠããª
ã«ãŒãããŒãã®æŒåºãã«å ¬ç¥ãªæ¡ä»¶äžã«çŽ160ã
240âã§æŒåºããã å®æœäŸ1a.1ã1a.4ã§åŸãããªãšã¹ãã«ïŒããªã«
ãŒãããŒãã®çžå¯Ÿç²åºŠÎ·ã¯1.46ã§ãã€ã
ïŒCH2Cl2äž25âåã³ïœïŒïŒïœïŒã§æž¬å®ïŒãã²ã«
ã¯ãããã°ã©ãã€ãŒã«ããã°ãããªãšã¹ãã«ïŒã
ãªã«ãŒãããŒãã¯56000ã§æé«å€ã瀺ããããã
ã¯ããªãšã¹ãã«ã50ééïŒ å«æãåã³ããªã«ãŒã
ããŒãéšåã50ééïŒ å«æãããå¡©åã¡ãã¬ã³ã
ã泚é ãããã€ã«ã ã®æ©æ¢°çæ§è³ªã¯æ¬¡ã®éãã§ã
ã€ãïŒ åŒåŒµã匷床22.7ïŒMPaïŒïŒDIN第53455å·âASTM
第â638å·ã«ããïŒ ç Žæ䌞匵413ïŒ ïŒDIN第53455å·âASTM第â
638å·ã«ããïŒ ç²ç¶ããªãšã¹ãã«ïŒããªã«ãŒãããŒãã®ç€ºå·®ç±
åæã«ããã°ãããªã¹ãã«æåã¯â28âã®ã¬ã©ã¹
転移枩床ïŒå€åœ¢æž©åºŠïŒãæããç¡å®åœ¢ããªã«ãŒã
ããŒãéšåã¯125âã®ã¬ã©ã¹è»¢ç§»æž©åºŠïŒå€åœ¢æž©åºŠïŒ
ãæããåã³çµæ¶åœ¢ããªã«ãŒãããŒãéšåã¯çŽ
190âã®çµæ¶èç¹ãæãããçµæ¶ããªã«ãŒãããŒ
ãéšåã®æº¶èãšã³ã¿ã«ããŒã¯2.5ã5.5calïŒïœéå
äœã§ãã€ãã å®æœäŸ 1b 45ééïŒ ã®ããªãšã¹ãã«éšåãæããããªãšã¹
ãã«ïŒããªã«ãŒãããŒãã®è£œé èžçæ°Ž1300éééšåã³45ïŒ æ°Žé žåãããªãŠã 溶
液77éééšã«æº¶è§£ããïŒïŒïŒâãã¹âïŒïŒâãã
ããã·ããšãã«ïŒâãããã³ïŒãããšããŒã«ïŒ¡ïŒ
20.3éééšåã³ïœâtertâããã«ããšããŒã«1.3é
ééšã®æº¶æ¶²ã«ãå¡©åã¡ãã¬ã³1725éééšã«æº¶è§£ã
ãåèäŸ6bããã®ç²çš ãªæ²¹171.6éééšãæ·»å ã
ãããã®æ··åç©ãçªçŽ é°å²æ°äžã«æªæããªãã45
åéã«äºã€ãŠãã¹ã²ã³85.6éééšãéå ¥ããåæ
ã«45ïŒ æ°Žé žåãããªãŠã 溶液195éšã滎ã ã«æ·»å
ããŠPHã13ã®äžå®å€ã«ä¿ã€ãããã¹ã²ã³ãéå ¥ã
ãåŸãããªãšãã«ã¢ãã³0.44éééšãæ·»å ããã
ãã®æ··åç©ã¯ããç²çš ã«ãªã€ããïŒæåŸãææ©çž
ãåé¢ããããªã¹ãã«ïŒããªãŒããããå®æœäŸ
1aïŒ1a.1ã1a.4ïŒã®åŠãåé¢ããã ããªãšã¹ã
ã«ïŒããªã«ãŒãããŒãã®çžå¯Ÿç²åºŠÎ·relã¯1.82
ïŒCH2C12äžïŒã§ãã€ãã ã²ã«ã¯ãããã°ã©ãã€ãŒã«ããã°ãéåäœã¯
93000ã®æé«å€ã瀺ããã 45ééïŒ ã®ããªãšã¹ãã«ãå«æãäžã€55ééïŒ
ã®ããªã«ãŒãããŒãéšåãæããå¡©åã¡ãã¬ã³ã
ã泚é ãããã€ã«ã ã®æ©æ¢°çæ§è³ªã¯æ¬¡ã®éãã§ã
ã€ãïŒ åŒåŒµã匷床 61.5MPa ç Žæ䌞匵 265ïŒ å®æœäŸ 1c 50ééïŒ ã®ããªãšã¹ãã«éšåãæããããªãšã¹
ãã«ïŒããªã«ãŒãããŒãã®è£œé èžçæ°Ž1300éééšåã³45ïŒ æ°Žé žåãããªãŠã 溶
液70éééšã«æº¶è§£ããïŒïŒïŒâãã¹âïŒïŒâãã
ããã·ããšãã«ïŒâãããã³ïŒãã¹ããšããŒã«
ïŒ28.5éééšåã³ïœâtertâããã«ããšããŒã«
0.89éééšã®æº¶æ¶²ã«ãå¡©åã¡ãã¬ã³1725éééšã«
溶解ããåèäŸ6cããã®ç²çš ãªæ²¹163.2éééšã
æ·»å ããããã®æ··åç©ãçªçŽ é°å²æ°äžã«æªæããª
ãã40åéã«äºã€ãŠãã¹ã²ã³58.3éééšãéå ¥
ããåæã«45ïŒ æ°Žé žåãããªãŠã 溶液131éšã
滎ã ã«æ·»å ããŠPHã13ã®äžå®å€ã«ä¿ã€ãããã¹ã²
ã³ãéå ¥ããåŸãããªãšãã«ã¢ãã³0.4éééšã
æ·»å ããããã®æ··åç©ã¯ããç²çš ã«ãªã€ããïŒæ
éåŸãææ©çžãåé¢ããããªãšã¹ãã«ïŒããªã«ãŒ
ãããŒããå®æœäŸ1aïŒ1a.1ã1a.4ïŒã®åŠãåé¢ã
ãã ããªãšã¹ãã«ïŒããªã«ãŒãããŒãã®çžå¯Ÿç²åºŠ
ηrelã¯1.62ïŒCH2Cl2äžïŒã§ãã€ãã ã²ã«ã¯ãããã°ã©ãã€ãŒã«ããã°ãéåäœã¯
51000ã®æé«å€ã瀺ããã 50ééïŒ ã®ããªãšã¹ãã«ãå«æãäžã€50ééïŒ
ã®ããªã«ãŒãããŒãéšåãæããå¡©åã¡ãã¬ã³ã
ã泚é ãããã€ã«ã ã®æ©æ¢°çæ§è³ªã¯æ¬¡ã®éãã§ã
ã€ãïŒ åŒåŒµã匷床 17.8MPa ç Žæ䌞匵 293ïŒ ç²ç¶ããªãšã¹ãã«ïŒããªã«ãŒãããŒãã®ç€ºå·®ç±
åæã«ããã°ãããªãšã¹ãã«æåã¯â24âã®ã¬ã©
ã¹è»¢ç§»æž©åºŠïŒå€åœ¢æž©åºŠïŒãæããç¡å®åœ¢ããªã«ãŒ
ãããŒãéšåã¯130âã®ã¬ã©ã¹è»¢ç§»æž©åºŠïŒå€åœ¢æž©
床ïŒãæããåã³çµæ¶åœ¢ããªã«ãŒãããŒãéšåã¯
çŽ185âã®çµæ¶èç¹ãæãããçµæ¶ããªã«ãŒãã
ãŒãéšåã®æº¶èãšã³ã¿ã«ããŒã¯2.5ã5.5calïŒïœé
åäœã§ãã€ãã å®æœäŸ 1d 45ééïŒ ã®ããªãšã¹ãã«éšåãæããããªãšã¹
ãã«ïŒããªã«ãŒãããŒãã®è£œé èžçæ°Ž1300éééšåã³45ïŒ æ°Žé žåãããªãŠã 溶
液77éééšã«æº¶è§£ããïŒïŒïŒâãã¹âïŒïŒâãã
ããã·ããšãã«ïŒâãããã³ïŒãã¹ããšããŒã«
ïŒ59.8éééšåã³ïœâtertâããã«ããšããŒã«
0.98éééšã®æº¶æ¶²ã«ãå¡©åã¡ãã¬ã³1725éééšã«
溶解ããåèäŸ6dããã®ç²çš ãªæ²¹130.6éééšã
æ·»å ããããã®æ··åç©ã«ïŒïŒïŒâãã¹âïŒ4â²ïŒ
4â³âãžããããã·ããªããšãã«ã¡ãã«ïŒâãã³ãŒ
ã³0.58éééšåã³ïŒïŒ NaOH溶液ïŒéééšãæ·»å
ããããã®æ··åç©ãçªçŽ é°å²æ°äžã«æªæããªãã
30åéã«äºã€ãŠãã¹ã²ã³64.3éééšãéå ¥ããå
æã«45ïŒ æ°Žé žåãããªãŠã 溶液146éšã滎ã ã«æ·»
å ããŠPHã13ã®äžå®å€ã«ä¿ã€ãããã¹ã²ã³ãéå ¥
ããåŸãããªãšãã«ã¢ãã³0.4éééšãæ·»å ããã
ãã®æ··åç©ã¯ããç²çš ã«ãªã€ããïŒæéåŸãææ©
çžãåé¢ããããªãšã¹ãã«ïŒããªã«ãŒãããŒãã
å®æœäŸ1aïŒ1a.1ã1a.4ïŒã®åŠãåé¢ããã ããªãšã¹ãã«ïŒããªã«ãŒãããŒãã®çžå¯Ÿç²åºŠ
ηrelã¯1.56ïŒCH2Cl2äžïŒã§ãã€ãã ã²ã«ã¯ãããã°ã©ãã€ãŒã«ããã°ãéåäœã¯
49000ã®æé«å€ã瀺ããã 50ééïŒ ã®ããªãšã¹ãã«ãå«æãäžã€50ééïŒ
ã®ããªã«ãŒãããŒãéšåãæããå¡©åã¡ãã¬ã³ã
ã泚é ãããã€ã«ã ã®æ©æ¢°çæ§è³ªã¯æ¬¡ã®éãã§ã
ã€ãïŒ åŒåŒµã匷床 17.5MPa ç Žæ䌞匵 228ïŒ ç²ç¶ããªãšã¹ãã«ïŒããªã«ãŒãããŒãã®ç€ºå·®ç±
åæã«ããã°ãããªãšã¹ãã«æåã¯â19âã®ã¬ã©
ã¹è»¢ç§»æž©åºŠïŒå€åœ¢æž©åºŠïŒãæããç¡å®åœ¢ããªã«ãŒ
ãããŒãéšåã¯125âã®ã¬ã©ã¹è»¢ç§»æž©åºŠïŒå€åœ¢æž©
床ïŒãæããåã³çµæ¶åœ¢ããªã«ãŒãããŒãéšåã¯
çŽ185âã®çµæ¶èç¹ãæãããçµæ¶ããªã«ãŒãã
ãŒãéšåã®æº¶èãšã³ã¿ã«ããŒã¯2.5ã5.5calïŒïœé
åäœã§ãã€ãã å®æœäŸ 1f 50ééïŒ ã®ããªãšã¹ãã«éšåãæããïŒïŒïŒâ
ãã¹âïŒïŒïŒïŒâãžã¡ãã«âïŒâããããã·ã
ãšãã«ïŒâãããã³ããã®ããªãšã¹ãã«ïŒããª
ã«ãŒãããŒãã®è£œé èžçæ°Ž1300éééšåã³45ïŒ æ°Žé žåãããªãŠã 溶
液66éééšã®æº¶æ¶²ã«ãå¡©åã¡ãã¬ã³1725éééšã«
溶解ããåèäŸ6fããã®ç²çš ãªæ²¹197.1éééšå
ã³ããªããã«ã¢ãã³0.61éééšïŒïŒãã¹ããšããŒ
ã«åäœïŒã¢ã«åœãïŒã¢ã«ïŒ ïŒãæ·»å ããããã®æ··
åç©ãçªçŽ é°å²æ°äžã«æªæããªãã30åéã«äºã€
ãŠãã¹ã²ã³98éééšãéå ¥ããåæã«45ïŒ æ°Žé žå
ãããªãŠã 溶液225éšã滎ã ã«æ·»å ããŠPHã13ã®
äžå®å€ã«ä¿ã€ãããã¹ã²ã³ãéå ¥ããåŸãããªã
ãã«ã¢ãã³5.5éééšïŒïŒãã¹ããšããŒã«åäœïŒ
ã¢ã«åœãïŒã¢ã«ïŒ ïŒãæ·»å ããŠåå¿ãå®çµãã
ãããã®æ··åç©ã¯ããç²çš ã«ãªã€ããïŒæéåŸã
ææ©çžãåé¢ããããªãšã¹ãã«ïŒããªã«ãŒãããŒ
ããå®æœäŸ1aïŒ1a.1ã1a.4ïŒã®åŠãåé¢ããã ããªãšã¹ãã«ïŒããªã«ãŒãããŒãã®çžå¯Ÿç²åºŠ
ηrelã¯1.58ïŒCH2Cl2äžïŒã§ãã€ãã äŸç€ºã®ç®çã§æ¬çºæã詳现ã«èšè¿°ããŠãããã
ã©ããã®ãããªè©³çŽ°ã¯ç®çã®ããã ãã§ãããäž
ã€æ¬çºæã®ç²Ÿç¥åã³ç¹èš±è«æ±ã®ç¯å²ãé¢ãããŠæ¹
å€ãè¡ãªãããªãããšãç解ãã¹ãã§ããã
åã¯ã¡ãã«ã瀺ã ã®ãžããšããŒã«ãšåå¿ãããŠç°¡ç¥ååŒ ïŒ»åŒäžãâïŒããªãšã¹ãã«ïŒâã¯èèªæãžãªãŒ
ã«ãšèèªæãžã«ã«ãã³é žãããªãããªãšã¹ãã«ãž
ãªãŒã«ã®ïŒäŸ¡ã®åºãè¡šãããåã³Y1ãY4ã¯äž
è¿°ãšå矩ã§ãã ã®ããªãšã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«ã«ãŒ
ãããŒãã補é ããã äžèšæ¹æ³ã«ããããªãšã¹ãã«ãžãªãŒã«ãã¹âãž
ããšããŒã«ã«ãŒãããŒãã¯ãå³ã¡äŸãã°äžèšã®ã
ã®ã§ããïŒ äžåŒã«ãããŠãâïŒããªãšã¹ãã«ïŒâã¯åè¿°ã
ãããªãšã¹ãã«ãžãªãŒã«ã®ïŒäŸ¡ã®åºã§ããã  ããªãšã¹ãã«ïŒããªã«ãŒãããŒãã®è£œé æ³ äžèšããªãšã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«
ã«ãŒãããŒãã¯ãå ¬ç¥ã®ïŒçžçé¢éçž®åæ³ã«ãã
ããªã«ãŒãããŒãã®è£œé ã«ãããåºçºãã¹âããš
ããŒã«ãšããŠäœ¿çšã§ãããåŸã€ãŠçš®ã ã®æ§é ã®ã
ãªãšã¹ãã«ïŒããªã«ãŒãããŒããåŸãããã æ¬çºæã«ããããªãšã¹ãã«ïŒããªã«ãŒãããŒã
ã®è£œé æ³ã¯ãããªã«ãŒãããŒãã®è£œé ã«å ¬ç¥ã®ïŒ
çžçé¢éçž®åæ³ã«åŸããããªãšã¹ãã«ãžãªãŒã«ã
ã¹âãžããšããŒã«ã«ãŒãããŒããä»ã®ãžããšããŒ
ã«ãç¹ã«åŒã®ãã®ãåã³ãã¹ã²ã³ãšPHçŽïŒã14
åã³æž©åºŠçŽïŒã80âã奜ãŸããã¯çŽ15ã40âäžã«
åå¿ãããããšãç¹è²ã§ãããæ¬çºæã«ãã€ãŠåŸ
ãããããªãšã¹ãã«ïŒããªã«ãŒãããŒãã¯ãç¡å®
圢ïŒåŒŸæ§ïŒããªãšã¹ãã«çžåã³çµæ¶åœ¢ïŒç¡¬ãïŒã
ãªã«ãŒãããŒãçžåã¯ç¡å®åœ¢ïŒçµæ¶åœ¢ïŒç¡¬ãïŒã
ãªã«ãŒãããŒãã®ååšãç¹è²ã§ããã 圢æ åŠçãªèŠ³ç¹ããèšãã°ãããªãšã¹ãã«ïŒã
ãªã«ãŒãããŒãã¯ãïŒã€ã®ç°ãªã空éçãªåé¢
çžãå³ã¡é£ç¶çãªç¡å®åœ¢ããªãšã¹ãã«ãããªãåº
ååã³çµæ¶åœ¢åã¯ç¡å®åœ¢ïŒçµæ¶åœ¢ããªã«ãŒãããŒ
ããããªãåºåãæããã æ¬çºæã«ããããªãšã¹ãã«ïŒããªã«ãŒãããŒã
ã¯ãããããå€çžã§ãããæ ã«ã察æ¯ãããåäž
çžããªãšã¹ãã«ïŒããªã«ãŒãããŒãããé«ãç±æª
枩床ãæããã åäžçžããªãšã¹ãã«ïŒããªã«ãŒãããŒãã¯ãäŸ
ãã°ç±³åœç¹èš±ç¬¬3151615å·ã«èšè¿°ãããŠãããã
ããã¯çš®ã ã®æ¹æ³ã«ããã奜ãŸããã¯ããªã«ãŒã
ããŒãã®è£œé ããå ¬ç¥ã®âããªãžã³âæ³ã«ãã€ãŠ
補é ãããã äŸãã°ããªã«ãŒãããŒãïŒããªã«ããã©ã¯ãã³
ã®ïŒçžéåäœã®è£œé ã¯ãåŸæ¥ããªã«ããã©ã¯ãã³
ã®ãã¹ã¯ãã«ããŒã¡ãŒãåã³ããªã«ãŒãããŒããª
ãªãŽããŒãçšããããšã«ãã€ãŠã ãè¡ãªãããŠã
ãïŒåç §ä»åœç¹èš±ç¬¬2235965å·ïŒããã®ããšã¯ãïŒ
çžéåäœãšããŠåå®ãããªãç¬åœç¹èš±ç¬¬1162559
å·ã®ããªãšã¹ãã«ïŒããªã«ãŒãããŒãã«å¯ŸããŠã
çå®ã§ããã æ¬çºæã«ãããããªãšã¹ãã«ãžãªãŒã«ãã¹âãž
ããšããŒã«ã«ãŒãããŒãã®äœ¿çšã¯ã察å¿ãããã·
ã¯ãã«ããŒã¡ãŒãã®äœ¿çšãšæ¯èŒããŠãå æ°Žå解ã«
察ããéææ§ãå³ã¡è¯å¥œãªè²¯èµå®å®æ§åã³æ確ãª
ïŒå®èœåå¿æ§ãšããå©ç¹ãäžããã ç¹ã«æ¬çºæã«ããããªãšã¹ãã«ïŒããªã«ãŒãã
ãŒãã¯ããã®çµæ¶åœ¢ããªã«ãŒãããŒãçžã®ããã«
é«ç±æªæž©åºŠãæããã æ¬çºæã«ããããªãšã¹ãã«ïŒããªã«ãŒãããŒã
ã®ç°ãªãçžã¯ç€ºå·®ç±åæã«ãã€ãŠæ€ç¥ããããšã
ã§ãããå³ã¡äŸãã°ããªãšã¹ãã«çžã¯ïŒ20âã®å€
圢枩床ãæãåã³ããªã«ãŒãããŒãçžã®ç¡å®åœ¢æ
åã¯çŽ100ã150âã®å€åœ¢æž©åºŠãæãäžã€ããªã«ãŒ
ãããŒãçžã®çµæ¶åœ¢æåã¯çŽ170ã250âã®çµæ¶è
ç¹ãæããã æ¬çºæã®æ¹æ³ã§è£œé ããäžã€ç±å¯å¡æ§æš¹èãšã
ãŠåŠçã§ããé«ååéã®ã»ã°ã¡ã³ãåããªãšã¹ã
ã«ïŒããªã«ãŒãããŒãã¯ããã®ç±ã«å¯Ÿããç¹å¥ãª
æ§è³ªã«å ããŠãè¯å¥œãªéææ§ãé«åŒŸæ§åã³ïŒ400
ïŒ ã®éã ã€ãç Žæ䌞匵ã瀺ãã äžèšããªãšã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«
ã«ãŒãããŒãããæ¬çºæã®ããªãšã¹ãã«ïŒããªã«
ãŒãããŒãã補é ããã®ã«é©åœãªãžããšããŒã«
ã¯ãããªãšã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«ã«
ãŒãããŒãã®è£œé ã«é¢ããŠãã§ã«èšåãããã®ã
ç¹ã«åŒã®ãã®ãäŸãã°ïŒïŒ4â²âãžããããã·â
ãžããšãã«ããã¹âïŒïŒâããããã·ããšãã«ïŒ
âã¡ã¿ã³ãïŒïŒïŒâãã¹âïŒïŒâããããã·ããš
ãã«ïŒâïŒâã¡ãã«ãã¿ã³ãαïŒÎ±âãã¹âïŒïŒ
âããããã·ããšãã«ïŒâïœâãžã€ãœãããã«ã
ã³ãŒã³ãïŒïŒïŒâãã¹âïŒïŒâã¯ãã«âïŒâãã
ããã·ããšãã«ïŒâãããã³ããã¹âïŒãããã
ã·ããšãã«ïŒã¹ã«ãã€ãåã³ïŒïŒïŒâãã¹â
ïŒïŒïŒïŒâãžã¡ãã«âïŒâããããã·ããšãã«ïŒ
âãããã³ãé©åœã§ããã æ¬çºæã«ããããªãšã¹ãã«ïŒããªã«ãŒãããŒã
ã®è£œé ã«ã¯ãïŒïŒïŒâãã¹âïŒïŒâããããã·ã
ãšãã«ïŒâãããã³ãïŒïŒïŒâãã¹âïŒïŒïŒïŒâ
ãžã¯ãã«âïŒâããããã·ããšãã«ïŒâããã
ã³ãïŒïŒïŒâãã¹âïŒïŒïŒïŒâãžããã âïŒâã
ãããã·ããšãã«ïŒâãããã³åã³ïŒïŒïŒâãã¹
âïŒïŒâããããã·ããšãã«ïŒâã·ã¯ããããµã³
ãä»ã®ãžããšããŒã«ãšããŠå¥œé©ã«äœ¿çšã§ãããã
ãããšä»ã®ãžããšããŒã«ã®æãŸããæ··åç©ã䜿çš
ã§ããã åŠçäžã«è¯å¥œãªæµåæ§ãæããåå²ãããçæ
ç©ã¯ãïŒå®èœæ§åã¯ïŒå®èœæ§ä»¥äžã®ååç©ãç¹ã«
ïŒååã¯ãã以äžã®ããšããŒã«æ§æ°Žé žåºãæãã
ååç©ãå°éã§ã奜ãŸããã¯ïŒçšãããžããšããŒ
ã«ã«å¯ŸããŠïŒçŽ0.05ãçŽïŒã¢ã«ïŒ ã§æ··å ¥ããããš
ã«ãã€ãŠè£œé ãããã é©åœãªïŒå®èœæ§åã¯ïŒå®èœæ§ä»¥äžã®ååç©ã¯ã
ãããã°ãªã·ããŒã«ãïŒïŒïŒâãžã¡ãã«âïŒïŒ
ïŒïŒïŒâããªâïŒïŒâããããã·ããšãã«ïŒâã
ããâïŒâãšã³ãïŒïŒïŒâãžã¡ãã«âïŒïŒïŒïŒïŒ
âããªâïŒïŒâããããã·ããšãã«ïŒâããã¿
ã³ãïŒïŒïŒïŒïŒâããªâïŒïŒâããããã·ããšã
ã«ïŒâãã³ãŒã³ãïŒïŒïŒïŒïŒâããªïŒïŒâããã
ãã·ããšãã«ïŒâãšã¿ã³ãããªâïŒïŒâãããã
ã·ããšãã«ïŒâããšãã«ã¡ã¿ã³ãïŒïŒïŒâãã¹â
ïŒïŒïŒâïŒïŒïŒ4â²âãžããããã·ãžããšãã«ïŒ
ã·ã¯ãããã·ã«ïŒœâãããã³ãïŒïŒïŒâãã¹â
ïŒïŒâããããã·ããšãã«âã€ãœãããã«ïŒâã
ãšããŒã«ãïŒïŒïŒâãã¹âïŒ2â²âããããã·â
5â²âã¡ãã«ãã³ãžã«ïŒâïŒâã¡ãã«ããšããŒã«ã
ïŒïŒïŒâãžããããã·å®æ¯éŠé žãïŒâïŒïŒâãã
ããã·ããšãã«ïŒâïŒâïŒïŒïŒïŒâãžããããã·
ããšãã«ïŒâãããã³ãïŒïŒïŒâãã¹âïŒïŒïŒ
4â³âãžããããã·ããªããšãã«âã¡ãã«ïŒâãã³
ãŒã³åã³ïŒïŒïŒâãã¹âïŒïŒâããããã·ããšã
ã«ïŒâïŒâãªããœâïŒïŒïŒâãžãããã€ã³ããŒã«
䞊ã³ã«ïŒïŒïŒâãã¹âïŒïŒâã¡ãã«âïŒâããã
ãã·ããšãã«ïŒâïŒâãªããœâïŒïŒïŒâãžããã
ã€ã³ããŒã«ã§ããã ããªãšã¹ãã«ïŒããªã«ãŒãããŒãã®éé·ã¯ãé
åæ¢å€äŸãã°åå®èœæ§ããšããŒã«ãäŸãã°ããšã
ãŒã«ãïŒïŒïŒâãžã¡ãã«ããšããŒã«ãïœâããã
ããšããŒã«ãåã¯ïœâtertâããã«ããšããŒã«ã
æ·»å ããããšã«ãã€ãŠèª¿ç¯ã§ããããã®äœ¿çšéã¯
çšãããžããšããŒã«ïŒã¢ã«åœãçŽ0.1ãçŽ10ã¢ã«
ïŒ ã§ãã€ãŠããã ç±å¯å¡æ§æš¹èãšããŠåŠçããããšã®ã§ããé«å
åéã®ã»ã°ã¡ã³ãåããªãšã¹ãã«ïŒããªã«ãŒãã
ãŒãã¯ïŒçžçé¢éçž®åæ³ã«ãã€ãŠè£œé ããããã
ã®ããã«ãäžè¿°ã®ä»ã®ããšããŒã«åã¯ãã®æ··åç©
ãã¢ã«ã«ãªæ°Žæº¶æ¶²ã«æº¶è§£ããã次ãã§äžèšããªãš
ã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«ã«ãŒãããŒ
ããç¹ã«åŒã®ãã®åã¯ãã®æ··åç©ããåæ§ã«æ°Ž
ãšæ··åããªãäžæŽ»æ§ãªææ©æº¶å€ã«æº¶è§£ãããã®æº¶
液ãæ·»å ããã次ãã§æ··åç©ã«ãã¹ã²ã³ã枩床çŽ
ïŒã80âã奜ãŸããã¯çŽ15ã40âåã³PHå€çŽïŒã
14ã®ããšã«éå ¥ããããã¹ã²ã³ã®éã¯çšãããžã
ãšããŒã«ãå·åŽæ段åã³åå¿æž©åºŠã«äŸåãããã
äžè¬ã«ãžããšããŒã«ïŒã¢ã«åœãçŽ1.1ã3.0ã¢ã«ã§
ããããã¹ã²ã³åã®åŸããžããšããŒã«ïŒã¢ã«åœã
çŽ0.2ã10ã¢ã«ïŒ ã®ïŒçŽèèªæã¢ãã³ãæ·»å ãã
ããšã«ãã€ãŠéçž®åãè¡ãªãããã®æ¹æ³ã§ã¯ãçŽ
ïŒã90åéã®ãã¹ã²ã³åæéãå¿ èŠã§ãããçŽïŒ
åãïŒæéã®éçž®åæéãå¿ èŠã§ããã åŸã€ãŠæ¬çºæã¯ãäžæŽ»æ§ãªææ©æº¶å€åã³ã¢ã«ã«
ãªæ°Žæº¶æ¶²ãããªã液äœæ··åç©äžã«ãããŠäžèšããª
ãšã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«ã«ãŒãããŒ
ããç¹ã«åŒã®ãã®ãä»ã®ãžããšããŒã«ãç¹ã«åŒ
ã®ãã®åã³ãã¹ã²ã³ãšæž©åºŠçŽïŒã80âã奜ãŸã
ãã¯çŽ15ã40âåã³PHå€çŽïŒã14ã®ããšã«åå¿ã
ããåã³ãã¹ã²ã³ã®æ·»å åŸãžããšããŒã«ã®ã¢ã«é
ã«å¯ŸããŠçŽ0.2ã10ã¢ã«ïŒ ã®ïŒçŽã¢ãã³ãæ·»å ã
ãããšã«ãã€ãŠéçž®ååå¿ãè¡ãªããããªãšã¹ã
ã«ãžãªãŒã«ãã¹âãžããšããŒã«ã«ãŒãããŒã察ä»
ã®ãžããšããŒã«ã®ééæ¯ãããªãšã¹ãã«ïŒããªã«
ãŒãããŒãäžã®ããªã«ãŒãããŒãã®å²ååã³ããª
ãšã¹ãã«ã®å²åã«ãã€ãŠæ±ºå®ãããããªãšã¹ã
ã«ïŒããªã«ãŒãããŒãã®è£œé æ³ã«é¢ããã åŸãããããªãšã¹ãã«ïŒããªã«ãŒãããŒãã®æ
æ©æº¶åªäžæº¶æ¶²ããïŒçžçé¢æ³ã§è£œé ãããç±å¯å¡
æ§ããªã«ãŒãããŒãã®æº¶æ¶²ãšåæ§ã«åŠçããå³ã¡
ããªãšã¹ãã«ïŒããªã«ãŒãããŒããåŸåŠçã«äŸã
ããç¹ã«ããããïœïŒå ¬ç¥ã®æ¹æ³ã§ãäŸãã°ã¡ã¿
ããŒã«åã¯ãšã¿ããŒã«ã§ã®æ²æŸ±ã«ããåé¢ãã次
ãã§ä¹Ÿç¥ããåã¯åªæåã«äŸãåã¯ææ©æº¶å€ã«æº¶
解ããŠã²ã«åããããæãã¯ïœïŒåé¢äžã«ãäŸã
ã°æ®çºç©ãé€å»ããæŒãåºãæ©ã§ãã§ã«åªæåã«
äŸããæãã¯ïœïŒåé¢åã«ïŒçžçé¢æ³ã«ããããª
ãšã¹ãã«ïŒããªã«ãŒãããŒãã®è£œé ã«çšãããã
溶åªäžã§ã²ã«åããããã æ¬çºæã«ããããªãšã¹ãã«ïŒããªã«ãŒãããŒã
ã®è£œé ã«é©åœãªäžæŽ»æ§ææ©æº¶å€ã¯ãæ°Žãšæ··åããª
ãèèªæå¡©çŽ åçåæ°ŽçŽ ãäŸãã°å¡©åã¡ãã¬ã³ã
ã¯ãããã«ã åã³ïŒïŒïŒâãžã¯ãã«ãšã¿ã³ãåã¯
å¡©çŽ åè³éŠæååç©ãäŸãã°ã¯ãã«ãã³ãŒã³ããž
ã¯ãã«ãã³ãŒã³åã³ã¯ãã«ãã«ãšã³æãã¯ããã
ã®æº¶å€ã®æ··åç©ã§ããã æ¬çºæã®æ¹æ³ã«é©åœãªã¢ã«ã«ãªæ°Žæº¶æ¶²ã¯ãLi
ïŒOHïŒ2ïŒNaOHïŒKOHïŒCaïŒOHïŒ2åã³ïŒåã¯
BaïŒOHïŒ2ã®æ°Žæº¶æ¶²ã§ããã æ¬çºæã®æ¹æ³ã«é©åœãªïŒçŽèèªæã¢ãã³ã¯ãç
çŽ æ°çŽïŒã15ã®ãã®ãå³ã¡äŸãã°ããªã¡ãã«ã¢ã
ã³ãããªãšãã«ã¢ãã³ãïœâããªãããã«ã¢ãã³
åã³ïœâããªããã«ã¢ãã³ã§ãããçšãããžããš
ããŒã«ã«äŸåããŠçŽ0.2ãïŒã¢ã«ïŒ ã§å€åãåã³
ããã©ã¡ãã«çœ®æãžããšããŒã«ãçšããå Žåã«ã¯
çšãããžããšããŒã«ã®å šéïŒïŒããªãšã¹ãã«ãžãª
ãŒã«ãã¹âãžããšããŒã«ã«ãŒãããŒãåã³ä»ã®ãž
ããšããŒã«ã®åèšïŒã«å¯ŸããŠçŽïŒã10ã¢ã«ïŒ ã§å€
åããã æ¬çºæã®æ¹æ³ã§è£œé ãããããªãšã¹ãã«ïŒããª
ã«ãŒãããŒãã¯æ¬¡ã®æ¹æ³ã§åé¢ããããšãã§ã
ãïŒ ïœ ææ©æº¶åªãããæ¿åºŠãŸã§çå»ããé«æ¿åºŠïŒçŽ
30ã40ééïŒ ïŒã®éåäœæº¶æ¶²ã補é ããç¶ããŠ
æ®ãã®æº¶åªããã€ããèžçºãããŠããªãšã¹ã
ã«ïŒããªã«ãŒãããŒããã²ã«åãããã ïœ æ²æŸ±ã«é©åœãªæº¶åªã®ææ©æº¶åªãäŸãã°ã¡ã¿ã
ãŒã«ããšã¿ããŒã«ãã€ãœãããããŒã«ãã¢ã»ã
ã³ãèèªæçåæ°ŽçŽ åã³èèªæçåæ°ŽçŽ ãçšã
ãããšã«ããããªãšã¹ãã«ïŒããªã«ãŒãããŒã
ãææ©æº¶åªã§æ²æŸ±ãããã ïœ è±æ®çºç©æŒåºæ©äžã«ãããŠããªãšã¹ãã«ïŒã
ãªã«ãŒãããŒããããªã«ãŒãããŒãã«å¯ŸããŠå ¬
ç¥ã®æ¡ä»¶äžã«çŽ160ã240âã§åé¢ããåªæåã
é©çšããã æ¬çºæã®æ¹æ³ã§è£œé ããããããªãšã¹ãã«ïŒã
ãªã«ãŒãããŒãã¯ãåé¢ããã«ïŒçžåå¿æ··åç©ã®
åŠçææ©çžäžã«ãããŠåã¯äºããåé¢ããããªãš
ã¹ãã«ïŒããªã«ãŒãããŒãã®å¥ã®ææ©æº¶åªæ¶²æ¶²äž
ã«ãããŠãé«æ¿åºŠéåäœæº¶æ¶²ãå·åŽåããããšã«
ãã€ãŠã²ã«åãããããããã²ã«åæéã¯ããªãš
ã¹ãã«åã¯ããªã«ãŒãããŒãã®å²åã«äŸåããã
çŽïŒã40âã§çŽïŒåéã12æéã§ããã ã²ã«åããçæç©ã¯ç²æ«ç²ç¶ã®æ··åç©ãšããã
ãã«åŠçã§ããåŸãããããªãšã¹ãã«ïŒããªã«ãŒ
ãããŒãã50âã§çŽ48æéåã³100âã§24æéç
空äžã«ä¹Ÿç¥ããã åé¢ããããªãšã¹ãã«ïŒããªã«ãŒãããŒãã®å¥
眮ã²ã«åã«é©åœãªæº¶åªã¯ãææ©æº¶åªãäŸãã°å¡©å
ã¡ãã¬ã³ããã³ãŒã³ããã«ãšã³åã¯ãã·ã¬ã³ã§ã
ãã åé¢ããããªãšã¹ãã«ïŒããªã«ãŒãããŒãã®ç±
åŠçã¯çŽ40ã170âã§çŽïŒåéã24æéè¡ãªãã
ãã åé¢ããããªãšã¹ãã«ïŒããªã«ãŒãããŒãã«çŽ
130ã240âã®æž©åºŠã§çŽ0.5ã30åéåªæåãäœçš
ãããéåäœKgåœãçŽ0.2ã0.7KWhã®åªæåãé©
çšãããã äžèšããªãšã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«
ã«ãŒãããŒããšãžããšããŒã«åã³ãã¹ã²ã³ãšã®ïŒ
çžçé¢æ³ã«ããæ¬çºæã®åå¿ã¯å®éçã«é²è¡ã
ããåŸã€ãŠããªãšã¹ãã«ãžãªãŒã«ãã¹âãžããšã
ãŒã«ã«ãŒãããŒã察ä»ã®ãžããšããŒã«ã®åå¿ç©æ¯
ã¯åæãã¹ãããªãšã¹ãã«ïŒããªã«ãŒãããŒãã®
ããªã«ãŒãããŒãæååã³ããªãšã¹ãã«æåã«ã
ã€ãŠæ±ºå®ãããã æ¬çºæã®æ¹æ³ã§è£œé ãããããªãšã¹ãã«ïŒããª
ã«ãŒãããŒãäžã®ããªã«ãŒãããŒãã®å²åã¯ãæ
åŸ ããæ§è³ªã«å¿ããŠçŽ30ã95ã奜ãŸããã¯çŽ35ã
80ééïŒ ã§ãããããã«ç¡¬åºŠåã³ç±æªæž©åºŠãåã³
匟æ§åã³ç Žæ䌞é·ã¯ãããããããªã«ãŒãããŒã
ã®å²åã®å¢å ãšäŸã«å¢å ããåã³æžå°ããã æ¬çºæã«ããããªãšã¹ãã«ïŒããªã«ãŒãããŒã
äžã®ããªã«ãŒãããŒãã®å²åã¯ãäžåŒ åŒäžãã¯ããªãšã¹ãã«ïŒããªã«ãŒãããŒã
äžã®ãžããšãã¬ãŒãåºãè¡šãã ã®è³éŠæããªã«ãŒãããŒãæ§é åäœãç¹ã«åŒïœ åŒäžãåã³Y1ãY4ã¯åŒãšå矩ã§ãã ã®è³éŠæããªã«ãŒãããŒãæ§é åäœã®ééã«ãã
éãšããŠç解ãã¹ãã§ããã æ¬çºæã«ããããªãšã¹ãã«ïŒããªã«ãŒãããŒã
ã®ããªãšã¹ãã«ã®å²åã¯ã察å¿ããŠç°¡ç¥ååŒ â
âïŒããªãšã¹ãã«ïŒââ ã®ããªãšã¹ãã«ïŒãžãªãŒã«ã®ïŒçš®ã®ããªãšã¹ãã«
ãžãªãŒã¬ãŒããããã¯åäœã®ééã«ããéãšããŠ
ç解ãã¹ãã§ããã åŸã€ãŠæ¬çºæã¯ãåŒãç¹ã«åŒïœã®è³éŠæã
ãªã«ãŒãããŒãæ§é åäœçŽ30ã95ééïŒ ã奜ãŸã
ãã¯çŽ35ã80ééïŒ åã³äžè¿°ã®ããªãšã¹ãã«ãžãª
ãŒã¬ãŒããããã¯åäœçŽ70ãïŒééïŒ ã奜ãŸãã
ã¯çŽ65ã20ééïŒ ãããªãããªãšã¹ãã«ïŒããªã«
ãŒãããŒãã«é¢ããã æ¬çºæã«ããããªãšã¹ãã«ïŒããªã«ãŒãããŒã
ã¯ãäŸãã°åŒïœ åŒäžãã¯ïŒšåã¯CH3ã§ãã ã®ããªã«ãŒãããŒãæ§é åäœçŽ30ãçŽ95ééïŒ ã
奜ãŸããã¯çŽ35ã80ééïŒ ãåã³ããªãšã¹ãã«ãž
ãªãŒã¬ãŒããããã¯åäœçŽ70ãçŽïŒééïŒ ã奜ãŸ
ããã¯çŽ65ãçŽ20ééïŒ ãããªããã®ã§ããã æ¬çºæã«ããããªãšã¹ãã«ïŒããªã«ãŒãããŒã
ã¯ãå æ£ä¹±å 床èšãçšããå æ£ä¹±æ³ã§æ±ºå®ãããš
ããçŽ25000ã200000ã奜ãŸããã¯çŽ70000ã
150000ã®å¹³åååéïœïŒééå¹³åïŒãæãã¹ã
ã§ãããæ¬çºæã«ããããªãšã¹ãã«ïŒããªã«ãŒã
ããŒãã®çžå¯Ÿæº¶æ¶²ç²åºŠÎ·relïŒCH2Cl2100mläž0.5ïœ
ã§25âäžã«æž¬å®ïŒã¯ãçŽ1.3ã3.0ã奜ãŸããã¯çŽ
1.4ã2.6ã§ããã æ¬çºæã®æ¹æ³ã§è£œé ããäžã€ç±å¯å¡æ§æš¹èãšã
ãŠåŠçããããšã®ã§ããé«ååéã®ã»ã°ã¡ã³ãå
ããªãšã¹ãã«ïŒããªã«ãŒãããŒãã¯ã瀺差ç±åæ
ã§æž¬å®ãããšãããªãšã¹ãã«æåãç¡å®åœ¢ã§ååš
ãäžã€çŽâ100âãïŒ100âã奜ãŸããã¯çŽâ80â
ãïŒ20âã®å€åœ¢æž©åºŠãæãããåã³ããªã«ãŒãã
ãŒãæåãéšåçã«çµæ¶åœ¢ã§ååšãäžã€çµæ¶ããª
ã«ãŒãããŒãéšåãå°ãªããšã160âã奜ãŸãã
ã¯çŽ165ã250âã®çµæ¶èç¹ãæãããåã³ç¡å®åœ¢
ããªã«ãŒãããŒãéšåã®å€åœ¢æž©åºŠãçŽ80â以äžã
奜ãŸããã¯çŽ100â以äžã§ãããããšãç¹è²ã§ã
ãã ããªãšã¹ãã«æåã®å€åœ¢æž©åºŠåã³ããªã«ãŒãã
ãŒãæåã®å€åœ¢æž©åºŠåã³çµæ¶èç¹ã«ãããäžè¿°ã®
å·®ã¯ãããªãšã¹ãã«æååã³ããªã«ãŒãããŒãæ
åéã®çžåé¢ã®ååšã«å¯ŸããŠç¹åŸŽçã§ãããå°ã
ãšãïŒã8calïŒïœéåäœã®æž¬å®ããã溶èãšã³ã¿
ã«ããŒã§æ€ç¥ããããšã®ã§ããæ¬çºæã®ããªãšã¹
ãã«ïŒããªã«ãŒãããŒãã®ããªã«ãŒãããŒãæå
ã®éšåççµæ¶å床ã¯ã延䌞åã³ç¶ã40ã170âã§
ã®ç±åŠçïŒïŒåéã25æéïŒã«ããæãã¯å€è»žã¹
ã¯ãªãŠãŒæŒåºãæ©ã§ã®ç±å¯å¡æ§åŠçã«ãããåªæ
åã®äœçšã«ããæŽã«50ïŒ ã ãå¢å ãããããšãã§
ããããã®ãšãçæç©ã®ç±æªæž©åºŠã¯äžæããèŠã
ãã¯éæããåéæãªããäžéæã«å€åããã éšåçã«çµæ¶åœ¢ã®åŒŸæ§ããªãšã¹ãã«ïŒããªã«ãŒ
ãããŒãã¯ãçµæ¶ããªã«ãŒãããŒãéšåã®çµæ¶è
ç¹ä»¥äžåã¯ãã®ä»è¿ã®çŽ130ãæé«250âã®æž©åºŠã§
ç±å¯å¡æ§æš¹èãšããŠåŠçããããšãã§ããããã®
å Žåçµæ¶å床ã®å®è³ªçãªéšåãä¿æããããç¡å®
圢ã§éæãªçæç©ã¯ãçµæ¶åœ¢ããªã«ãŒãããŒãéš
åã®çµæ¶èç¹ä»¥äžã®åŠç枩床ã§åŸãããã å³ã¡æ¬çºæã«ããããªãšã¹ãã«ïŒããªã«ãŒãã
ãŒãã®ããªã«ãŒãããŒãéšåã®çµæ¶åœ¢å²åã¯ãå€
ããããšãã§ãããŸãããªãšã¹ãã«ïŒããªã«ãŒã
ããŒãã«äœ¿çšäžã®é«ç±æªæž©åºŠãä»äžããããã«çŽ
ïŒã8calïŒïœéåäœã奜ãŸããã¯çŽ2.5ã5.5calïŒ
ïœéåäœã®æº¶èãšã³ã¿ã«ããŒãäžããã®ã«ååã§
ããã æ¬çºæã«åŸãããªãšã¹ãã«ïŒããªã«ãŒãããŒã
ãç±åŠçãªãã«ãã²ã«åãªãã«åã³åªæåã®é©çš
ãªãã«åŠçãäžã€åé¢ããå Žåãåäžçžã®ããªãš
ã¹ãã«ïŒããªã«ãŒãããŒããå³ã¡ç€ºå·®ç±åæã§æž¬
å®ã§ããå€åœ¢æž©åºŠãïŒã€ã ãæããçæç©ãåŸã
ããã æ¬çºæã«ããããªãšã¹ãã«ïŒããªã«ãŒãããŒã
ã®UVå ã«å¯Ÿããå®å®æ§åã³å æ°Žå解ã«å¯Ÿããå®
å®æ§ã¯ãç±å¯å¡æ§ããªã«ãŒãããŒãã«éåžžã®UV
å®å®å€ãäŸãã°çœ®æãããâãã³ãŸããšãã³âå
ã¯âãã³ãºããªã¢ãŸãŒã«âã«ãããå æ°Žå解ã«å¯Ÿ
ããå®å®æ§ãä»äžããè¬å€ãäŸãã°ã¢ãã«ã«ããž
ã€ããåã³äžã§ãããªã«ã«ããžã€ããåç §ã
W.NewmanãJ.PeterïŒH.Holtschmidt and W.
KallertïŒProceeding of the 4th Rubber
Technology ConferenceïŒLondonïŒïŒæ22ã25
æ¥ã1962幎ã738ã751é ãäŸãã°ããªãšã¹ã
ã«ïŒããªã«ãŒãããŒãã®ééã«å¯ŸããŠ0.2ãïŒé
éïŒ ã®è¬å€ã«ãããåã³ç±å¯å¡æ§ããªãšã¹ãã«å
ã³ç±å¯å¡æ§ããªã«ãŒãããŒãã®ååŠã«ãããŠå ¬ç¥
ã®èåé²æ¢å€ã«ããæ¹è¯ããããšãã§ããã æŽã«äŸãã°ã«ãŒãã³ãã©ãã¯ãçªè»åãã«ãªãª
ã³ãç²åãCaF2ïŒCaCO3ãé žåã¢ã«ãããŠã å
ã³éåžžã®ã¬ã©ã¹ç¹ç¶ã®åŠãç©è³ªãæ圢çµæç©ã®å š
ééã«å¯ŸããŠçŽïŒã40ééïŒ ã®éã§æ·»å ã§ããå
ã³ç¡æ©é¡æãå å¡«å€åã³æ žåå€ãšããŠæ·»å ã§ãã
ãã®çµææ¬çºæã«ããçæç©ãæ¹è³ªããããšãã§
ããã é£çæ§çæç©ãæåŸ ããå Žåã«ã¯ãç±å¯å¡æ§ã
ãªãšã¹ãã«åã³ç±å¯å¡æ§ããªã«ãŒãããŒãã®ååŠ
ã«ãããŠå ¬ç¥ã®é£çå€ãäŸãã°äžé žåã¢ã³ãã¢
ã³ãããã©ããã ãã¿ã«é žç¡æ°Žç©ããããµããã
ã·ã¯ãããã«ã³ãããã©ã¯ãã«ãããã¯ããã©ã
ãã ãã¹ããšããŒã«ïŒ¡åã¯ããªã¹âïŒïŒïŒïŒâãž
ã¯ãã«ãããã«ïŒãã¹ããšãŒããããªãšã¹ãã«ïŒ
ããªã«ãŒãããŒãã®ééã«å¯ŸããŠçŽïŒã15ééïŒ
æ··åããããšãã§ãããæ¬çºæã«ããããªã«ãŒã
ããŒãã®ããªã«ãŒãããŒãéšåã«çµ±èšçã«æ··å ¥ã
ããããã©ã¯ãã«åã³ããã©ããã ãã¹ããšããŒ
ã«ãé£çæ§ã瀺ãã æŽã«ãç±å¯å¡æ§ããªãšã¹ãã«åã³ç±å¯å¡æ§ããª
ã«ãŒãããŒãã®ååŠã«ãããŠå ¬ç¥ã®åŠçå©å€ãäŸ
ãã°é¢åå€ãå¹æçã«äœ¿çšã§ããã æ¬çºæã«ãã€ãŠè£œé ãããããªãšã¹ãã«ïŒããª
ã«ãŒãããŒãã¯ã硬床åã³åŒŸæ§ãç¹ã«å·æææ§ã®
çµåããæåŸ ãããã¹ãŠã®äºäŸã«ãããŠãäŸãã°
èªåè»ã®è»äœã«ãèªåè»ã®äœå§ã¿ã€ã€ã®è£œé ã«ã
ããŒã¹ãã·ãŒãä»ã³ããŠãŒãã®å€ç®ã«åã³æè»ãª
é§åããŒãªãŒã«æå©ã«äœ¿çšã§ããã 次ã®åèäŸã«ç€ºãå¹³åååéã¯æ°å¹³åååé
ïœã§ãããOHæ°ã®æž¬å®ã«ãã€ãŠæ±ºå®ãããã å®æœäŸ1aã1fã®çžå¯Ÿæº¶æ¶²ç²åºŠÎ·relã¯ãå¡©åã¡ã
ã¬ã³100mläžã®ããªãšã¹ãã«ïŒããªã«ãŒãããŒã
0.5ïœã®æº¶æ¶²ã®25âã«ãããç²åºŠãšããŠå®çŸ©ãã
ãã åŒåŒµã匷床åã³ç Žææ䌞匵ã¯DIN第53455å·ã
察å¿ããŠASTM第â638å·ã«åŸã€ãŠæž¬å®ããã
ã²ã«ã¯ãããã°ãã€ãŒã«ããæ€èšã¯ãããã©ãã
ããã©ã³åã³ã¹ãã©ã²ã«ã«ã©ã ïŒåé¢ç¯å²1.5Ã
105â«ïŒïŒÃ105â«ïŒïŒÃ104â«åã³ïŒÃ103â«ïŒã
çšããŠå®€æž©ã§è¡ãªã€ãã決å®ã«å¯ŸããŠã¯ããã¹ã
ãšããŒã«ïŒ¡ããªã«ãŒãããŒãã®è£æ£æ²ç·ãçšã
ããå æ£ä¹±æ³ã«ãã€ãŠæ±ºå®ããïœãšæ¯ã¹ãŠã倧
ããªåå·®ã¯èŠåºãããªãã€ãã 瀺差ç±åæã¯ãE.I.ããŠãã³ç€Ÿè£œã®âDu Pont
900åâãçšããŠè¡ãªã€ããå€åœ¢æž©åºŠã解éãã
å Žåãæ¥ç·æ³ã«åŸã€ãŠè»å枩床ç¯å²ã®å¡ãäžç¹ã
éžã³ãåã³çµæ¶èç¹ã®å Žåã溶èæ²ç·ã®åžç±ããŒ
ã¯ã®å¡ãäžç¹ãéžæããã åèäŸïŒã«ç€ºãã·ãŠã¿ãŠãã€ã³ã¬ãŒææ°ïŒ»Î·ïŒœ
ã¯25âãããã©ããããã©ã³äžã§æž¬å®ããdlïŒïœ
ã§è¡šç€ºãããã·ãŠã¿ãŠãã€ã³ã¬ãŒææ°ã®å®çŸ©ã«é¢
ããŠã¯ãH.G.ãšãªã¢ã¹ïŒEliasïŒèã
âMakromolekušleâïŒHušthig ïŒ Wepfâ
Verlag Basle 265é ãåç §ã®ããšã åèäŸ ïŒ ããªãšã¹ãã«ãžãªãŒã«ãã¹âçé žã¢ãã¢ãªãŒã«
ãšã¹ãã«ã®è£œé å¹³åååéïœïŒ800ãæãããããµã³âïŒïŒ
ïŒâãžãªãŒã«åã³ã¢ãžãã³é žããã®ããªãšã¹ãã«
ãžãªãŒã«800éééšãçé žãžããšãã«856éééšå
ã³ãããªãŠã ããšãã¬ãŒã0.05éééšããçªçŽ äž
ã«æªæããªãã15mmHgã®ç空ã§3.5æé150âã«
å ç±ããããã®æéäžåå¿æ··åç©ããããšããŒã«
187éééšãçå»ããã次ãã§éå°ã®çé žãžããš
ãã«ãæ¿¡å£èžçºæ©ã§200âïŒ0.1mmïœäžã«é€å»ã
ããç¡è²ã®ç²çš ãªæ²¹ãåŸãã ηããã©ããããã©ã³ïŒ0.072 OHæ°ïŒïŒ åæïŒèšç®å€ïŒïŒ£ïŒ66.5ïŒ ïŒïŒšïŒ8.2ïŒ å®éšå€ïŒïŒ£ïŒ63.3ïŒ ïŒïŒšïŒ8.3ïŒ åèäŸ 6a ãã¹ããšããŒã«A18.5ééïŒ åã³ãã¹ããšããŒ
ã«ïŒ¡åã³çé žãžããšãã«ã®åå¿çæç©ãå«æã
ãããªãšã¹ãã«ãžãªãŒã«ãã¹âïŒãã¹ããšããŒ
ã«ïŒ¡ïŒã«ãŒãããŒãã®è£œé åèäŸïŒã«åŸããããµã³âïŒïŒïŒâãžãªãŒã«å
ã³ã¢ãžãã³é žãã補é ãããå¹³åååéïœïŒ
1900ã®ããªãšã¹ãã«ãžãªãŒã«ã§ãã€ãŠãããã«ç
é žãžããšãã«çŽ26.3éééšïŒå šéã«å¯ŸããŠæ®åå«
é5.9ééïŒ ïŒãæ··åãã該ããªãšã¹ãã«ãžãªãŒ
ã«ã®ãã¹çé žã¢ãã¢ãªãŒã«ãšã¹ãã«446.3éééš
ïŒ0.2ã¢ã«ïŒãïŒïŒïŒâãã¹âïŒïŒâããããã·ã
ãšãã«ïŒâãããã³ïŒãã¹ããšããŒã«ïŒ¡ïŒ191.7
éééšåã³è§Šåª0.2éééšïŒãã¹ããšããŒã«ïŒ¡ã®
ãããªãŠã ãã¹âããšãã¬ãŒãïŒãã¹ããšããŒã«
ïŒïŒïŒ100ïŒãçªçŽ äžã«æªæããªãã0.05mm
ïœã§ïŒæé150âã«å ç±ããããã®æéäžãããš
ããŒã«57.3éééšãçå»ããã åèäŸ 6b ãã¹ããšããŒã«A18.7ééïŒ åã³ãã¹ããšããŒ
ã«ïŒ¡åã³çé žãžããšãã«ã®åå¿çæç©ãå«æã
ãããªãšã¹ãã«ãžãªãŒã«ãã¹âïŒãã¹ããšããŒ
ã«ïŒ¡ïŒã«ãŒãããŒãã®è£œé åèäŸïŒã«åŸããããµã³âïŒïŒïŒâãžãªãŒã«å
ã³ã¢ãžãã³é žãã補é ãããå¹³åååéïœïŒ
800ã®ããªãšã¹ãã«ãžãªãŒã«ã§ãã€ãŠãããã«ç
é žãžããšãã«çŽ27.0éééšïŒå šéã«å¯ŸããŠæ®åå«
é4.3ééïŒ ïŒãæ··åãã該ããªãšã¹ãã«ãžãªãŒ
ã«ã®ãã¹çé žã¢ãã¢ãªãŒã«ãšã¹ãã«627éééšã
ïŒïŒïŒâãã¹âïŒïŒâããããã·ããšãã«ïŒâã
ããã³ïŒãã¹ããšããŒã«ïŒ¡ïŒ431.5éééšåã³è§Š
åª0.43éééšïŒãã¹ããšããŒã«ïŒ¡ã®ãããªãŠã ã
ã¹âããšãã¬ãŒãïŒãã¹ããšããŒã«ïŒ¡ïŒïŒïŒ100ïŒ
ãçªçŽ äžã«æªæããªãã0.5mmïœã§ïŒæé125â
ã«æ¬¡ãã§ïŒæé150âã«å ç±ããããã®æéäžã
ããšããŒã«123éééšãçå»ããã åèäŸ 6c ãã¹ããšããŒã«A26.1ééïŒ åã³ãã¹ããšããŒ
ã«ïŒ¡åã³çé žãžããšãã«ã®åå¿çæç©ãå«æã
ãããªãšã¹ãã«ãžãªãŒã«ãã¹âïŒãã¹ããšããŒ
ã«ïŒ¡ïŒã«ãŒãããŒãã®è£œé åèäŸïŒã«åŸãã¢ã«æ¯65ïŒ35ã®ãããµã³âïŒïŒ
ïŒâãžãªãŒã«ïŒããªãã³ãã«ã°ãªãŒã«åã³ã¢ãžã
ã³é žãã補é ãããå¹³åååéïœïŒ1828ã®ããª
ãšã¹ãã«ãžãªãŒã«ã§ãã€ãŠãããã«çé žãžããšã
ã«çŽ164.5éééšïŒå šéã«å¯ŸããŠæ®åå«é8.8éé
ïŒ ïŒãæ··åãã該ããªãšã¹ãã«ãžãªãŒã«ã®ãã¹ç
é žã¢ãã¢ãªãŒã«ãšã¹ãã«1870éééšãïŒïŒïŒâã
ã¹âïŒïŒâããããã·ããšãã«ïŒâãããã³ïŒã
ã¹ããšããŒã«ïŒ¡ïŒ986éééšåã³è§Šåª1.5éééš
ïŒãã¹ããšããŒã«ïŒ¡ã®ãããªãŠã ãã¹âããšãã¬
ãŒãïŒãã¹ããšããŒã«ïŒ¡ïŒïŒïŒ100ïŒãçªçŽ äžã«
æªæããªãã0.25mmïœã§æåã«ïŒæé125âã«
次ãã§ïŒæé150âã«å ç±ããããã®æéäžãã
ãšããŒã«246éééšãçå»ããã åèäŸ 6d ãã¹ããšããŒã«A15.6ééïŒ åã³ãã¹ããšããŒ
ã«ïŒ¡åã³çé žãžããšãã«ã®åå¿çæç©ãå«æã
ãããªãšã¹ãã«ãžãªãŒã«ãã¹âïŒãã¹ããšããŒ
ã«ïŒ¡ïŒã«ãŒãããŒãã®è£œé åèäŸïŒã«åŸãã¢ã«æ¯65ïŒ35ã®ãããµã³âïŒïŒ
ïŒâãžãªãŒã«ïŒããªãã³ãã«ã°ãªã³ãŒã«åã³ã¢ãž
ãã³é žãã補é ãããå¹³åååéïœïŒ1828ã®ã
ãªãšã¹ãã«ãžãªãŒã«ã§ãã€ãŠãããã«çé žãžããš
ãã«çŽ12.8éééšïŒå šéã«å¯ŸããŠæ®åå«é4.1é
éïŒ ïŒãæ··åãã該ããªãšã¹ãã«ãžãªãŒã«ã®ãã¹
çé žã¢ãã¢ãªãŒã«ãšã¹ãã«313éééšãïŒïŒïŒâ
ãã¹âïŒïŒâããããã·ããšãã«ïŒâãããã³
ïŒãã¹ããšããŒã«ïŒ¡ïŒ120.5éééšåã³ãããªãŠã
ããšãã¬ãŒã0.02éééšãçªçŽ äžã«æªæããªãã
0.06mmïœã§æåã«ïŒæé125âã«æ¬¡ãã§ïŒæé
150âã«å ç±ããããã®æéäžãããšããŒã«31.5
éééšãçå»ããã åèäŸ 6e ãã¹ããšããŒã«A16.8ééïŒ åã³ãã¹ããšããŒ
ã«ïŒ¡åã³çé žãžããšãã«ã®åå¿çæç©ãå«æã
ãããªãšã¹ãã«ãžãªãŒã«ãã¹âïŒãã¹ããšããŒ
ã«ïŒ¡ïŒã«ãŒãããŒãã®è£œé åèäŸïŒã«åŸãããªãã³ãã«ã°ãªã³ãŒã«åã³ã¢
ãžãã³é žãã補é ãããå¹³åååéïœïŒ2000ã®
ããªãšã¹ãã«ãžãªãŒã«ã§ãã€ãŠãããã«çé žãžã
ãšãã«çŽ18.1éééšïŒå šéã«å¯ŸããŠæ®åå«é5.2
ééïŒ ïŒãæ··åãã該ããªãšã¹ãã«ãžãªãŒã«ã®ã
ã¹çé žã¢ãã¢ãªãŒã«ãšã¹ãã«348.1éééšãïŒïŒ
ïŒâãã¹âïŒïŒâããããã·ããšãã«ïŒâããã
ã³ïŒãã¹ããšããŒã«ïŒ¡ïŒ139.5éééšåã³è§Šåª
0.14éééšïŒãã¹ããšããŒã«ïŒ¡ã®ãããªãŠã ãã¹
âããšãã¬ãŒãïŒãã¹ããšããŒã«ïŒ¡ïŒïŒïŒ100ïŒ
ãçªçŽ äžã«æªæããªãã0.5mmïœã§æåã«ïŒæ
é125âã«æ¬¡ãã§ïŒæé150âã«å ç±ããããã®æ
éäžãããšããŒã«37.6éééšãçå»ããã åèäŸ 6f ïŒïŒïŒâãã¹âïŒïŒïŒïŒâãžã¡ãã«âïŒâãã
ããã·ããšãã«ïŒâãããã³åã³ïŒïŒïŒâãã¹
âïŒïŒïŒïŒâãžã¡ãã«âïŒâããããã·ããšã
ã«ïŒâãããã³åã³çé žãžããšãã«ã®åå¿çæ
ç©ã14.8ééïŒ ã®éã§å«æããåŒïœã®ããªãš
ã¹ãã«ãžãªãŒã«ãã¹âãžããšããŒã«ã«ãŒãããŒ
ãã®è£œé åèäŸïŒã«åŸããããµã³âïŒïŒïŒâãžãªãŒã«å
ã³ã¢ãžãã³é žãã補é ãããå¹³åååéïœïŒ
800ã®ããªãšã¹ãã«ãžãªãŒã«ã§ãã€ãŠãããã«ç
é žãžããšãã«çŽïŒéééšïŒå šéã«å¯ŸããŠæ®åå«é
ïŒééïŒ ïŒãæ··åãã該ããªãšã¹ãã«ãžãªãŒã«ã®
ãã¹çé žã¢ãã¢ãªãŒã«ãšã¹ãã«303éééšãïŒïŒ
ïŒâãã¹âïŒïŒâããããã·ããšãã«ïŒâããã
ã³232.2éééšåã³è§Šåª0.22éééšïŒãã¹ããšã
ãŒã«ïŒ¡ã®ãããªãŠã ãã¹âããšãã¬ãŒãïŒãã¹ã
ãšããŒã«ïŒ¡ïŒïŒïŒ100ïŒãçªçŽ äžã«æªæããªãã
0.1mmïœã§æåã«ïŒæé125âã«æ¬¡ãã§4.5æé
150âã«å ç±ããããã®æéäžãããšããŒã«49é
ééšãçå»ããã å®æœäŸ 1a 50ééïŒ ã®ããªãšã¹ãã«éšåãæããããªãšã¹
ãã«ïŒããªã«ãŒãããŒãã®è£œé 45ïŒ NaOH70éééšåã³èžçæ°Ž1300éééšã«
溶解ãããã¹ããšããŒã«A40.2éééšåã³ïœâ
tertâããã«ããšããŒã«0.885éééšã®æº¶æ¶²ã«ãå¡©
åã¡ãã¬ã³1725éšã«æº¶è§£ããåèäŸ6aããã®ç²
çš ãªæ²¹151.5éééšãæ·»å ããã次ãã§çªçŽ äžã«
æªæããªãããã¹ã²ã³58.3éééšã20ã25âã§30
åéã«äºãéå ¥ããããã®æéäžãPHå€ã13ã®äž
å®å€ãšãªãããã«45ïŒ NaOH111éééšãåæã«
滎ã ã«æ·»å ããããã¹ã²ã³ã®éå ¥åŸãïŒïŒ ã®ããª
ãšãã«ã¢ãã³æº¶æ¶²39.8éééšãæ·»å ããæ··åç©ã
ïŒæéæªæãããææ©çžãåé¢ããïŒïŒ çé žåã³
æåŸã«èžçæ°ŽãçšããŠé»è§£è³ªããªããªããŸã§é£ç¶
çã«æŽæµãããæ°Žãåé¢ããåŸãææ©çžã次ã®æ¹
æ³ã§åŠçããã 1a.1 CH2Cl2ãããæ¿åºŠãŸã§çå»ããããšã«ããã
åã¯ã¯ãã«ãã³ãŒã³ãææ©çžã«æ·»å ãåã³å šå¡©å
ã¡ãã¬ã³ãçå»ããããšã«ãããé«æ¿åºŠïŒçŽ30ã
40ééïŒ ïŒã®éåäœæº¶æ¶²ãåŸãã次ãã§æ®ãã®å¡©
åã¡ãã¬ã³åã¯ã¯ãã«ãã³ãŒã³ããã€ããèžçºã
ããããšã«ãã€ãŠããªãšã¹ãã«ïŒããªã«ãŒãããŒ
ããã²ã«åããã次ãã§ãããæŽã«ç²æ«ç²åæ··å
ç©ã«åŠçãããåŸãããããªãšã¹ãã«ïŒããªã«ãŒ
ãããŒãã50âã§48æéåã³100âã§24æéç空
äžã«ä¹Ÿç¥ããã 1a.2 溶åªãçå»ããæ®æž£ã15mmïœåã³çŽ80ã110
âã®ç空也ç¥æ©äžã§ä¹Ÿç¥ããç¶ããŠç²ç ããããš
ã«ãã埮ç²ç ãããåºäœçæç©ãåŸãã 1a.3 äŸãã°ã¡ã¿ããŒã«ããšã¿ããŒã«ãã€ãœãããã
ãŒã«ãã¢ã»ãã³ãèèªæçåæ°ŽçŽ åã³èç°æçå
æ°ŽçŽ ãçšããŠããªãšã¹ãã«ïŒããªã«ãŒãããŒãã
ææ©çžããæ²æ®¿ãããç¶ããŠæ²æ®¿ã80ã110âå
ã³15mmïœã®ç空也ç¥åšäžã§ä¹Ÿç¥ããã 1a.4 ææ©çžãèžçºåŒæŒåºæ©äžã§æ¿çž®ããç¶ããŠããª
ã«ãŒãããŒãã®æŒåºãã«å ¬ç¥ãªæ¡ä»¶äžã«çŽ160ã
240âã§æŒåºããã å®æœäŸ1a.1ã1a.4ã§åŸãããªãšã¹ãã«ïŒããªã«
ãŒãããŒãã®çžå¯Ÿç²åºŠÎ·ã¯1.46ã§ãã€ã
ïŒCH2Cl2äž25âåã³ïœïŒïŒïœïŒã§æž¬å®ïŒãã²ã«
ã¯ãããã°ã©ãã€ãŒã«ããã°ãããªãšã¹ãã«ïŒã
ãªã«ãŒãããŒãã¯56000ã§æé«å€ã瀺ããããã
ã¯ããªãšã¹ãã«ã50ééïŒ å«æãåã³ããªã«ãŒã
ããŒãéšåã50ééïŒ å«æãããå¡©åã¡ãã¬ã³ã
ã泚é ãããã€ã«ã ã®æ©æ¢°çæ§è³ªã¯æ¬¡ã®éãã§ã
ã€ãïŒ åŒåŒµã匷床22.7ïŒMPaïŒïŒDIN第53455å·âASTM
第â638å·ã«ããïŒ ç Žæ䌞匵413ïŒ ïŒDIN第53455å·âASTM第â
638å·ã«ããïŒ ç²ç¶ããªãšã¹ãã«ïŒããªã«ãŒãããŒãã®ç€ºå·®ç±
åæã«ããã°ãããªã¹ãã«æåã¯â28âã®ã¬ã©ã¹
転移枩床ïŒå€åœ¢æž©åºŠïŒãæããç¡å®åœ¢ããªã«ãŒã
ããŒãéšåã¯125âã®ã¬ã©ã¹è»¢ç§»æž©åºŠïŒå€åœ¢æž©åºŠïŒ
ãæããåã³çµæ¶åœ¢ããªã«ãŒãããŒãéšåã¯çŽ
190âã®çµæ¶èç¹ãæãããçµæ¶ããªã«ãŒãããŒ
ãéšåã®æº¶èãšã³ã¿ã«ããŒã¯2.5ã5.5calïŒïœéå
äœã§ãã€ãã å®æœäŸ 1b 45ééïŒ ã®ããªãšã¹ãã«éšåãæããããªãšã¹
ãã«ïŒããªã«ãŒãããŒãã®è£œé èžçæ°Ž1300éééšåã³45ïŒ æ°Žé žåãããªãŠã 溶
液77éééšã«æº¶è§£ããïŒïŒïŒâãã¹âïŒïŒâãã
ããã·ããšãã«ïŒâãããã³ïŒãããšããŒã«ïŒ¡ïŒ
20.3éééšåã³ïœâtertâããã«ããšããŒã«1.3é
ééšã®æº¶æ¶²ã«ãå¡©åã¡ãã¬ã³1725éééšã«æº¶è§£ã
ãåèäŸ6bããã®ç²çš ãªæ²¹171.6éééšãæ·»å ã
ãããã®æ··åç©ãçªçŽ é°å²æ°äžã«æªæããªãã45
åéã«äºã€ãŠãã¹ã²ã³85.6éééšãéå ¥ããåæ
ã«45ïŒ æ°Žé žåãããªãŠã 溶液195éšã滎ã ã«æ·»å
ããŠPHã13ã®äžå®å€ã«ä¿ã€ãããã¹ã²ã³ãéå ¥ã
ãåŸãããªãšãã«ã¢ãã³0.44éééšãæ·»å ããã
ãã®æ··åç©ã¯ããç²çš ã«ãªã€ããïŒæåŸãææ©çž
ãåé¢ããããªã¹ãã«ïŒããªãŒããããå®æœäŸ
1aïŒ1a.1ã1a.4ïŒã®åŠãåé¢ããã ããªãšã¹ã
ã«ïŒããªã«ãŒãããŒãã®çžå¯Ÿç²åºŠÎ·relã¯1.82
ïŒCH2C12äžïŒã§ãã€ãã ã²ã«ã¯ãããã°ã©ãã€ãŒã«ããã°ãéåäœã¯
93000ã®æé«å€ã瀺ããã 45ééïŒ ã®ããªãšã¹ãã«ãå«æãäžã€55ééïŒ
ã®ããªã«ãŒãããŒãéšåãæããå¡©åã¡ãã¬ã³ã
ã泚é ãããã€ã«ã ã®æ©æ¢°çæ§è³ªã¯æ¬¡ã®éãã§ã
ã€ãïŒ åŒåŒµã匷床 61.5MPa ç Žæ䌞匵 265ïŒ å®æœäŸ 1c 50ééïŒ ã®ããªãšã¹ãã«éšåãæããããªãšã¹
ãã«ïŒããªã«ãŒãããŒãã®è£œé èžçæ°Ž1300éééšåã³45ïŒ æ°Žé žåãããªãŠã 溶
液70éééšã«æº¶è§£ããïŒïŒïŒâãã¹âïŒïŒâãã
ããã·ããšãã«ïŒâãããã³ïŒãã¹ããšããŒã«
ïŒ28.5éééšåã³ïœâtertâããã«ããšããŒã«
0.89éééšã®æº¶æ¶²ã«ãå¡©åã¡ãã¬ã³1725éééšã«
溶解ããåèäŸ6cããã®ç²çš ãªæ²¹163.2éééšã
æ·»å ããããã®æ··åç©ãçªçŽ é°å²æ°äžã«æªæããª
ãã40åéã«äºã€ãŠãã¹ã²ã³58.3éééšãéå ¥
ããåæã«45ïŒ æ°Žé žåãããªãŠã 溶液131éšã
滎ã ã«æ·»å ããŠPHã13ã®äžå®å€ã«ä¿ã€ãããã¹ã²
ã³ãéå ¥ããåŸãããªãšãã«ã¢ãã³0.4éééšã
æ·»å ããããã®æ··åç©ã¯ããç²çš ã«ãªã€ããïŒæ
éåŸãææ©çžãåé¢ããããªãšã¹ãã«ïŒããªã«ãŒ
ãããŒããå®æœäŸ1aïŒ1a.1ã1a.4ïŒã®åŠãåé¢ã
ãã ããªãšã¹ãã«ïŒããªã«ãŒãããŒãã®çžå¯Ÿç²åºŠ
ηrelã¯1.62ïŒCH2Cl2äžïŒã§ãã€ãã ã²ã«ã¯ãããã°ã©ãã€ãŒã«ããã°ãéåäœã¯
51000ã®æé«å€ã瀺ããã 50ééïŒ ã®ããªãšã¹ãã«ãå«æãäžã€50ééïŒ
ã®ããªã«ãŒãããŒãéšåãæããå¡©åã¡ãã¬ã³ã
ã泚é ãããã€ã«ã ã®æ©æ¢°çæ§è³ªã¯æ¬¡ã®éãã§ã
ã€ãïŒ åŒåŒµã匷床 17.8MPa ç Žæ䌞匵 293ïŒ ç²ç¶ããªãšã¹ãã«ïŒããªã«ãŒãããŒãã®ç€ºå·®ç±
åæã«ããã°ãããªãšã¹ãã«æåã¯â24âã®ã¬ã©
ã¹è»¢ç§»æž©åºŠïŒå€åœ¢æž©åºŠïŒãæããç¡å®åœ¢ããªã«ãŒ
ãããŒãéšåã¯130âã®ã¬ã©ã¹è»¢ç§»æž©åºŠïŒå€åœ¢æž©
床ïŒãæããåã³çµæ¶åœ¢ããªã«ãŒãããŒãéšåã¯
çŽ185âã®çµæ¶èç¹ãæãããçµæ¶ããªã«ãŒãã
ãŒãéšåã®æº¶èãšã³ã¿ã«ããŒã¯2.5ã5.5calïŒïœé
åäœã§ãã€ãã å®æœäŸ 1d 45ééïŒ ã®ããªãšã¹ãã«éšåãæããããªãšã¹
ãã«ïŒããªã«ãŒãããŒãã®è£œé èžçæ°Ž1300éééšåã³45ïŒ æ°Žé žåãããªãŠã 溶
液77éééšã«æº¶è§£ããïŒïŒïŒâãã¹âïŒïŒâãã
ããã·ããšãã«ïŒâãããã³ïŒãã¹ããšããŒã«
ïŒ59.8éééšåã³ïœâtertâããã«ããšããŒã«
0.98éééšã®æº¶æ¶²ã«ãå¡©åã¡ãã¬ã³1725éééšã«
溶解ããåèäŸ6dããã®ç²çš ãªæ²¹130.6éééšã
æ·»å ããããã®æ··åç©ã«ïŒïŒïŒâãã¹âïŒ4â²ïŒ
4â³âãžããããã·ããªããšãã«ã¡ãã«ïŒâãã³ãŒ
ã³0.58éééšåã³ïŒïŒ NaOH溶液ïŒéééšãæ·»å
ããããã®æ··åç©ãçªçŽ é°å²æ°äžã«æªæããªãã
30åéã«äºã€ãŠãã¹ã²ã³64.3éééšãéå ¥ããå
æã«45ïŒ æ°Žé žåãããªãŠã 溶液146éšã滎ã ã«æ·»
å ããŠPHã13ã®äžå®å€ã«ä¿ã€ãããã¹ã²ã³ãéå ¥
ããåŸãããªãšãã«ã¢ãã³0.4éééšãæ·»å ããã
ãã®æ··åç©ã¯ããç²çš ã«ãªã€ããïŒæéåŸãææ©
çžãåé¢ããããªãšã¹ãã«ïŒããªã«ãŒãããŒãã
å®æœäŸ1aïŒ1a.1ã1a.4ïŒã®åŠãåé¢ããã ããªãšã¹ãã«ïŒããªã«ãŒãããŒãã®çžå¯Ÿç²åºŠ
ηrelã¯1.56ïŒCH2Cl2äžïŒã§ãã€ãã ã²ã«ã¯ãããã°ã©ãã€ãŒã«ããã°ãéåäœã¯
49000ã®æé«å€ã瀺ããã 50ééïŒ ã®ããªãšã¹ãã«ãå«æãäžã€50ééïŒ
ã®ããªã«ãŒãããŒãéšåãæããå¡©åã¡ãã¬ã³ã
ã泚é ãããã€ã«ã ã®æ©æ¢°çæ§è³ªã¯æ¬¡ã®éãã§ã
ã€ãïŒ åŒåŒµã匷床 17.5MPa ç Žæ䌞匵 228ïŒ ç²ç¶ããªãšã¹ãã«ïŒããªã«ãŒãããŒãã®ç€ºå·®ç±
åæã«ããã°ãããªãšã¹ãã«æåã¯â19âã®ã¬ã©
ã¹è»¢ç§»æž©åºŠïŒå€åœ¢æž©åºŠïŒãæããç¡å®åœ¢ããªã«ãŒ
ãããŒãéšåã¯125âã®ã¬ã©ã¹è»¢ç§»æž©åºŠïŒå€åœ¢æž©
床ïŒãæããåã³çµæ¶åœ¢ããªã«ãŒãããŒãéšåã¯
çŽ185âã®çµæ¶èç¹ãæãããçµæ¶ããªã«ãŒãã
ãŒãéšåã®æº¶èãšã³ã¿ã«ããŒã¯2.5ã5.5calïŒïœé
åäœã§ãã€ãã å®æœäŸ 1f 50ééïŒ ã®ããªãšã¹ãã«éšåãæããïŒïŒïŒâ
ãã¹âïŒïŒïŒïŒâãžã¡ãã«âïŒâããããã·ã
ãšãã«ïŒâãããã³ããã®ããªãšã¹ãã«ïŒããª
ã«ãŒãããŒãã®è£œé èžçæ°Ž1300éééšåã³45ïŒ æ°Žé žåãããªãŠã 溶
液66éééšã®æº¶æ¶²ã«ãå¡©åã¡ãã¬ã³1725éééšã«
溶解ããåèäŸ6fããã®ç²çš ãªæ²¹197.1éééšå
ã³ããªããã«ã¢ãã³0.61éééšïŒïŒãã¹ããšããŒ
ã«åäœïŒã¢ã«åœãïŒã¢ã«ïŒ ïŒãæ·»å ããããã®æ··
åç©ãçªçŽ é°å²æ°äžã«æªæããªãã30åéã«äºã€
ãŠãã¹ã²ã³98éééšãéå ¥ããåæã«45ïŒ æ°Žé žå
ãããªãŠã 溶液225éšã滎ã ã«æ·»å ããŠPHã13ã®
äžå®å€ã«ä¿ã€ãããã¹ã²ã³ãéå ¥ããåŸãããªã
ãã«ã¢ãã³5.5éééšïŒïŒãã¹ããšããŒã«åäœïŒ
ã¢ã«åœãïŒã¢ã«ïŒ ïŒãæ·»å ããŠåå¿ãå®çµãã
ãããã®æ··åç©ã¯ããç²çš ã«ãªã€ããïŒæéåŸã
ææ©çžãåé¢ããããªãšã¹ãã«ïŒããªã«ãŒãããŒ
ããå®æœäŸ1aïŒ1a.1ã1a.4ïŒã®åŠãåé¢ããã ããªãšã¹ãã«ïŒããªã«ãŒãããŒãã®çžå¯Ÿç²åºŠ
ηrelã¯1.58ïŒCH2Cl2äžïŒã§ãã€ãã äŸç€ºã®ç®çã§æ¬çºæã詳现ã«èšè¿°ããŠãããã
ã©ããã®ãããªè©³çŽ°ã¯ç®çã®ããã ãã§ãããäž
ã€æ¬çºæã®ç²Ÿç¥åã³ç¹èš±è«æ±ã®ç¯å²ãé¢ãããŠæ¹
å€ãè¡ãªãããªãããšãç解ãã¹ãã§ããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ äžæŽ»æ§ãªææ©æº¶å€åã³ã¢ã«ã«ãªæ°Žæ§æº¶æ¶²ãå«
ãã§ãªã液äœæ··åç©äžã«ãããŠãäžèšåŒ åŒäžãâïŒããªãšã¹ãã«ïŒâã¯èèªæãžãªãŒ
ã«ãšèèªæãžã«ã«ãã³é žãããªãããªãšã¹ãã«ãž
ãªãŒã«ã®ïŒäŸ¡ã®åºãè¡šãããã¯âCH2âåã¯
ãåŒãã瀺ããY1ãY4ã¯åäžã§ãç°ãªã€ãŠ ãããäžã€æ°ŽçŽ åã¯ã¡ãã«ã瀺ã ã®ãééå¹³åååéã750ãªãã20000ã®ããªãšã¹
ãã«ãžãªãŒã«ãã¹âãžããšããŒã«ã«ãŒãããŒã
ããäžèšåŒ åŒäžãã¯âCH2âåã¯ãåŒãã瀺ãã Y1ãY4ã¯åãã§ãç°ãªã€ãŠãããäžã€æ°ŽçŽ åã¯
ã¡ãã«ã瀺ã ã®ãžããšããŒã«åã³ãã¹ã²ã³ãšïŒã80âã®æž©åºŠå
ã³ïŒã14ã®PHå€ã§åå¿ãããããšãå«ãã§ãªãã
ãªãšã¹ãã«ïŒããªã«ãŒãããŒãã®è£œé ã«éããã
ã¹ã²ã³ã®æ·»å åŸãžããšããŒã«ã®ã¢ã«æ¿åºŠéã«å¯Ÿã
ãŠ0.2ã10ã¢ã«ïŒ ã®ïŒçŽã¢ãã³ãæ·»å ããããšã«
ãã€ãŠéçž®åãè¡ãªããããªãšã¹ãã«ãžãªãŒã«ã
ã¹âãžããšããŒã«ã«ãŒãããŒã察ãžããšããŒã«ã®
ééæ¯ãåŸãããããªãšã¹ãã«ïŒããªã«ãŒãããŒ
ãäžã®ããªã«ãŒãããŒãåã³ããªãšã¹ãã«ã®æãŸ
ããå²åã«ãã€ãŠæ±ºå®ããã該ããªãšã¹ãã«ïŒã
ãªã«ãŒãããŒãã®è£œé æ³ã ïŒ ïŒçŽã¢ãã³ãã¢ãã³åååœãïŒã15ã®ççŽ æ°
ãæããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¹æ³ã ïŒ ïŒå®èœæ§åã¯ïŒããå€ãå®èœæ§ã®ååç©ã
0.05ãïŒã¢ã«ïŒ çšããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒãïŒé
ã®ããããã«èšèŒã®æ¹æ³ã
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2726376.9 | 1977-06-10 | ||
| DE19772726376 DE2726376A1 (de) | 1977-06-10 | 1977-06-10 | Verfahren zur herstellung von kohlensaeure-bis-diphenolestern von polyesterdiolen und ihre verwendung zur herstellung von hochmolekularen, segmentierten, thermoplastisch verarbeitbaren polyester- polycarbonaten |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63236642A Division JPH01126326A (ja) | 1977-06-10 | 1988-09-22 | ããªãšã¹ãã«ïŒããªã«ãŒãããŒãåã³ãã®åŠçæ³ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6211725A JPS6211725A (ja) | 1987-01-20 |
| JPH0129498B2 true JPH0129498B2 (ja) | 1989-06-12 |
Family
ID=6011294
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6840078A Granted JPS544988A (en) | 1977-06-10 | 1978-06-08 | Polyester diol biss diphenol carbonate and preparation thereof |
| JP61169971A Granted JPS6211725A (ja) | 1977-06-10 | 1986-07-21 | ããªãšã¹ãã«ïŒããªã«ãŒãããŒãã®è£œé æ³ |
| JP63236642A Pending JPH01126326A (ja) | 1977-06-10 | 1988-09-22 | ããªãšã¹ãã«ïŒããªã«ãŒãããŒãåã³ãã®åŠçæ³ |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6840078A Granted JPS544988A (en) | 1977-06-10 | 1978-06-08 | Polyester diol biss diphenol carbonate and preparation thereof |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63236642A Pending JPH01126326A (ja) | 1977-06-10 | 1988-09-22 | ããªãšã¹ãã«ïŒããªã«ãŒãããŒãåã³ãã®åŠçæ³ |
Country Status (5)
| Country | Link |
|---|---|
| JP (3) | JPS544988A (ja) |
| DE (1) | DE2726376A1 (ja) |
| FR (1) | FR2393823B1 (ja) |
| GB (1) | GB1586326A (ja) |
| IT (1) | IT1104730B (ja) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2930787A1 (de) | 1979-07-28 | 1981-02-12 | Bayer Ag | Vernetzbare polycarbonat-elastomere, ein verfahren zu ihrer herstellung und ihre verwendung fuer medizinische verpackungen nach erfolgter vernetzung |
| CA1214588A (en) * | 1981-11-09 | 1986-11-25 | Union Carbide Corporation | Process for preparing polyesters or poly(estercarbonates) in the presence of a processing aid |
| DE4208360A1 (de) * | 1992-03-16 | 1993-09-23 | Bayer Ag | Kompostierbare thermoplastische blockcopolyester fuer verpackungsmaterialien |
| JP2019200053A (ja) | 2018-05-14 | 2019-11-21 | ã ãµã·ãæ©åšæ ªåŒäŒç€Ÿ | 液é¢èšãããã³é«äœæ¶²é¢èŠå ±è£ 眮 |
| CN120813627A (zh) * | 2023-03-30 | 2025-10-17 | äžè±ååŠæ ªåŒäŒç€Ÿ | èç¢³é žé ¯æ èç»åç©åå ¶æåå |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3161615A (en) * | 1957-02-05 | 1964-12-15 | Gen Electric | Resinous copolymeric polycarbonate of a mixture of dihydric phenols |
| GB1139413A (en) * | 1965-02-03 | 1969-01-08 | Ici Fibres Ltd | Polyester/polycarbonate block copolymers |
| DE2651639A1 (de) * | 1976-11-12 | 1978-05-24 | Bayer Ag | Verfahren zur herstellung von kohlensaeureestern von polyesterpolyolen |
-
1977
- 1977-06-10 DE DE19772726376 patent/DE2726376A1/de active Granted
-
1978
- 1978-05-19 GB GB20711/78A patent/GB1586326A/en not_active Expired
- 1978-06-08 IT IT49767/78A patent/IT1104730B/it active
- 1978-06-08 JP JP6840078A patent/JPS544988A/ja active Granted
- 1978-06-09 FR FR7817349A patent/FR2393823B1/fr not_active Expired
-
1986
- 1986-07-21 JP JP61169971A patent/JPS6211725A/ja active Granted
-
1988
- 1988-09-22 JP JP63236642A patent/JPH01126326A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6211725A (ja) | 1987-01-20 |
| DE2726376A1 (de) | 1978-12-21 |
| DE2726376C2 (ja) | 1990-02-01 |
| IT1104730B (it) | 1985-10-28 |
| FR2393823A1 (ja) | 1979-01-05 |
| JPS6320852B2 (ja) | 1988-04-30 |
| JPH01126326A (ja) | 1989-05-18 |
| FR2393823B1 (ja) | 1985-01-11 |
| IT7849767A0 (it) | 1978-06-08 |
| GB1586326A (en) | 1981-03-18 |
| JPS544988A (en) | 1979-01-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4297455A (en) | Process for the preparation of carbonic acid aryl esters of polyester-diols lengthened via carbonate groups and their use for the preparation of polyester-diol bis-diphenol carbonates and polyester/polycarbonates | |
| CN1980978B (zh) | å ·ææŽå¥œæµåšèœåçå ±èç¢³é žé ¯ | |
| US4216298A (en) | Process for the preparation of carbonic acid bis-diphenol esters of polyester-diols and their use for the preparation of high-molecular segmented polyester/polycarbonates which can be processed as thermoplastics | |
| US4169868A (en) | Process for the preparation of new high-molecular segmented polyester-polycarbonates which can be processed by thermoplastic methods and new polyester-polycarbonates obtained according to the process | |
| US4281101A (en) | Process for the preparation of aliphatic-aromatic polycarbonates with diphenol carbonate end groups and their use for the preparation of high-molecular, segmented, aliphatic-aromatic polycarbonate elastomers which can be processed as thermoplastics | |
| US4333809A (en) | Cross-linkable polycarbonate elastomers, a process for their preparation and use for packaging medicines | |
| US4217437A (en) | Process for the preparation of carbonic acid bis-diphenol esters of polyalkylene oxide-diols lengthened via carbonate groups and their use for the preparation of high-molecular, segmented polyether/polycarbonates which can be processed as thermoplastics | |
| US4191705A (en) | Process for the preparation of carbonic acid esters of polyester-polyols | |
| JPH02245023A (ja) | æåãç±å¯å¡æ§ããªã«ãŒãããŒãåã³ãã®è£œé æ³ | |
| JPS6219451B2 (ja) | ||
| US5191001A (en) | Process for the production of solventless polycarbonate | |
| JPH0231099B2 (ja) | ||
| JPS62223222A (ja) | ç±å¯å¡æ§ããªãšã¹ãã«âã«ãŒãããŒãæš¹è | |
| US4430492A (en) | High-molecular, segmented, thermoplastically processable, aromatic polycarbonates containing co-condensed dimeric fatty acid esters, their preparation and their use | |
| JPS629130B2 (ja) | ||
| JPS6320852B2 (ja) | ||
| JP2002516620A (ja) | ããªã«ãŒãããŒãé¡ | |
| DE2636784A1 (de) | Verfahren zur herstellung von kohlensaeure-bis-diphenolestern von polyalkylenoxiddiolen und ihre verwendung zur herstellung von hochmolekularen, segmentierten, thermoplastisch verarbeitbaren polyaether-polycarbonaten | |
| JP2824161B2 (ja) | ããªãšã¹ãã«åã³ããªãšã¹ãã«ã«ãŒãããŒã | |
| JP3039757B2 (ja) | äœãã¬ã©ã¹è»¢ç§»æž©åºŠã®ã³ããªãšã¹ãã«ã«ãŒãããŒã | |
| JPH0713137B2 (ja) | æš¹èã®æ¶æ©æ¹æ³ | |
| US4168368A (en) | Polycarbonates incorporating 2-methylepichlorohydrin | |
| JPH09136962A (ja) | ããªïŒã¢ãªãŒã«ã·ãããµã³ïŒçµæç©ã®è£œæ³ | |
| JP2003506508A (ja) | æåãäºé žã®æ®åºãå«ãããªãšã¹ãã«ã«ãŒãããŒã |