JPH0342288B2 - - Google Patents
Info
- Publication number
- JPH0342288B2 JPH0342288B2 JP15680382A JP15680382A JPH0342288B2 JP H0342288 B2 JPH0342288 B2 JP H0342288B2 JP 15680382 A JP15680382 A JP 15680382A JP 15680382 A JP15680382 A JP 15680382A JP H0342288 B2 JPH0342288 B2 JP H0342288B2
- Authority
- JP
- Japan
- Prior art keywords
- phenol
- mol
- trivalent
- reaction
- reaction mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 73
- 239000004417 polycarbonate Substances 0.000 claims description 44
- 229920000515 polycarbonate Polymers 0.000 claims description 44
- 239000011541 reaction mixture Substances 0.000 claims description 43
- 239000007864 aqueous solution Substances 0.000 claims description 34
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 claims description 32
- 239000008346 aqueous phase Substances 0.000 claims description 21
- 239000003960 organic solvent Substances 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 239000012074 organic phase Substances 0.000 claims description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 78
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 78
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 61
- 238000003756 stirring Methods 0.000 description 32
- 238000006243 chemical reaction Methods 0.000 description 31
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 30
- 235000011121 sodium hydroxide Nutrition 0.000 description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 26
- 238000005406 washing Methods 0.000 description 23
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 21
- 229960001553 phloroglucinol Drugs 0.000 description 21
- 238000000034 method Methods 0.000 description 15
- 229920000642 polymer Polymers 0.000 description 14
- 238000000746 purification Methods 0.000 description 14
- 229930185605 Bisphenol Natural products 0.000 description 13
- 150000002989 phenols Chemical class 0.000 description 13
- 238000011156 evaluation Methods 0.000 description 10
- 239000012071 phase Substances 0.000 description 10
- 238000006068 polycondensation reaction Methods 0.000 description 10
- 239000003513 alkali Substances 0.000 description 8
- KICYRZIVKKYRFS-UHFFFAOYSA-N 2-(3,5-dihydroxyphenyl)benzene-1,3,5-triol Chemical compound OC1=CC(O)=CC(C=2C(=CC(O)=CC=2O)O)=C1 KICYRZIVKKYRFS-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- WXNRYSGJLQFHBR-UHFFFAOYSA-N bis(2,4-dihydroxyphenyl)methanone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=C(O)C=C1O WXNRYSGJLQFHBR-UHFFFAOYSA-N 0.000 description 5
- 238000000071 blow moulding Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 238000002835 absorbance Methods 0.000 description 4
- -1 carbonyl halide Chemical class 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000011002 quantification Methods 0.000 description 4
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000006085 branching agent Substances 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 238000010128 melt processing Methods 0.000 description 3
- 229920005668 polycarbonate resin Polymers 0.000 description 3
- 239000004431 polycarbonate resin Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000001294 propane Substances 0.000 description 3
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- 238000007259 addition reaction Methods 0.000 description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- MIHINWMALJZIBX-UHFFFAOYSA-N cyclohexa-2,4-dien-1-ol Chemical compound OC1CC=CC=C1 MIHINWMALJZIBX-UHFFFAOYSA-N 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 150000002367 halogens Chemical group 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- YGKOYVNJPRSSRX-UHFFFAOYSA-M (4-dodecylphenyl)methyl-trimethylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCC1=CC=C(C[N+](C)(C)C)C=C1 YGKOYVNJPRSSRX-UHFFFAOYSA-M 0.000 description 1
- UKDOTCFNLHHKOF-FGRDZWBJSA-N (z)-1-chloroprop-1-ene;(z)-1,2-dichloroethene Chemical group C\C=C/Cl.Cl\C=C/Cl UKDOTCFNLHHKOF-FGRDZWBJSA-N 0.000 description 1
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- MAQOZOILPAMFSW-UHFFFAOYSA-N 2,6-bis[(2-hydroxy-5-methylphenyl)methyl]-4-methylphenol Chemical compound CC1=CC=C(O)C(CC=2C(=C(CC=3C(=CC=C(C)C=3)O)C=C(C)C=2)O)=C1 MAQOZOILPAMFSW-UHFFFAOYSA-N 0.000 description 1
- RXNYJUSEXLAVNQ-UHFFFAOYSA-N 4,4'-Dihydroxybenzophenone Chemical compound C1=CC(O)=CC=C1C(=O)C1=CC=C(O)C=C1 RXNYJUSEXLAVNQ-UHFFFAOYSA-N 0.000 description 1
- VWGKEVWFBOUAND-UHFFFAOYSA-N 4,4'-thiodiphenol Chemical compound C1=CC(O)=CC=C1SC1=CC=C(O)C=C1 VWGKEVWFBOUAND-UHFFFAOYSA-N 0.000 description 1
- NZGQHKSLKRFZFL-UHFFFAOYSA-N 4-(4-hydroxyphenoxy)phenol Chemical compound C1=CC(O)=CC=C1OC1=CC=C(O)C=C1 NZGQHKSLKRFZFL-UHFFFAOYSA-N 0.000 description 1
- RQCACQIALULDSK-UHFFFAOYSA-N 4-(4-hydroxyphenyl)sulfinylphenol Chemical compound C1=CC(O)=CC=C1S(=O)C1=CC=C(O)C=C1 RQCACQIALULDSK-UHFFFAOYSA-N 0.000 description 1
- BRPSWMCDEYMRPE-UHFFFAOYSA-N 4-[1,1-bis(4-hydroxyphenyl)ethyl]phenol Chemical compound C=1C=C(O)C=CC=1C(C=1C=CC(O)=CC=1)(C)C1=CC=C(O)C=C1 BRPSWMCDEYMRPE-UHFFFAOYSA-N 0.000 description 1
- RQTDWDATSAVLOR-UHFFFAOYSA-N 4-[3,5-bis(4-hydroxyphenyl)phenyl]phenol Chemical compound C1=CC(O)=CC=C1C1=CC(C=2C=CC(O)=CC=2)=CC(C=2C=CC(O)=CC=2)=C1 RQTDWDATSAVLOR-UHFFFAOYSA-N 0.000 description 1
- LIDWAYDGZUAJEG-UHFFFAOYSA-N 4-[bis(4-hydroxyphenyl)-phenylmethyl]phenol Chemical compound C1=CC(O)=CC=C1C(C=1C=CC(O)=CC=1)(C=1C=CC(O)=CC=1)C1=CC=CC=C1 LIDWAYDGZUAJEG-UHFFFAOYSA-N 0.000 description 1
- BOCLKUCIZOXUEY-UHFFFAOYSA-N 4-[tris(4-hydroxyphenyl)methyl]phenol Chemical compound C1=CC(O)=CC=C1C(C=1C=CC(O)=CC=1)(C=1C=CC(O)=CC=1)C1=CC=C(O)C=C1 BOCLKUCIZOXUEY-UHFFFAOYSA-N 0.000 description 1
- 235000010893 Bischofia javanica Nutrition 0.000 description 1
- 240000005220 Bischofia javanica Species 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 238000012695 Interfacial polymerization Methods 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 1
- QLRKASHXFNIPLZ-UHFFFAOYSA-M benzyl-dimethyl-phenylazanium;chloride Chemical compound [Cl-].C=1C=CC=CC=1[N+](C)(C)CC1=CC=CC=C1 QLRKASHXFNIPLZ-UHFFFAOYSA-M 0.000 description 1
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical group C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- FZFAMSAMCHXGEF-UHFFFAOYSA-N chloro formate Chemical compound ClOC=O FZFAMSAMCHXGEF-UHFFFAOYSA-N 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 229940117389 dichlorobenzene Drugs 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- CHTGZWZVEFPJEQ-UHFFFAOYSA-N dodecyl-[2-(2-methylphenyl)propan-2-yl]azanium hydroxide Chemical compound [OH-].CC1=C(C([NH2+]CCCCCCCCCCCC)(C)C)C=CC=C1 CHTGZWZVEFPJEQ-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 229910001410 inorganic ion Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical group 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Landscapes
- Polyesters Or Polycarbonates (AREA)
Description
ãçºæã®è©³çŽ°ãªèª¬æã
æ¬çºæã¯åå²ããªã«ãŒãããŒãã®è£œé æ¹æ³ã«é¢
ãããããã«è©³ããã¯ãïŒäŸ¡ããšããŒã«ãšãã¹ã²
ã³ãšããåæãããäœååéã®ç·ç¶ããªã«ãŒãã
ãŒãã«ãïŒäŸ¡ä»¥äžã®å€äŸ¡ããšããŒã«ãšïŒäŸ¡ããšã
ãŒã«ãæ·»å ããŠåå¿ããããã€ãã§ïŒäŸ¡ããšããŒ
ã«ãå ããŠéååå¿ãå®çµããããããšãç¹åŸŽãš
ããåå²ããè³éŠæããªã«ãŒãããŒãã補é ãã
æ¹æ³ã«é¢ããã
ãããããã«è©³ããã¯ãïŒäŸ¡ããšããŒã«ãšãã¹ã²
ã³ãšããåæãããäœååéã®ç·ç¶ããªã«ãŒãã
ãŒãã«ãïŒäŸ¡ä»¥äžã®å€äŸ¡ããšããŒã«ãšïŒäŸ¡ããšã
ãŒã«ãæ·»å ããŠåå¿ããããã€ãã§ïŒäŸ¡ããšããŒ
ã«ãå ããŠéååå¿ãå®çµããããããšãç¹åŸŽãš
ããåå²ããè³éŠæããªã«ãŒãããŒãã補é ãã
æ¹æ³ã«é¢ããã
ãšã³ãžãã¢ãªã³ã°ãã©ã¹ããã¯ã¹ãšããŠåºãçš
ããããŠããããªã«ãŒãããŒãæš¹èã®å€ãã¯ãïŒ
䟡ããšããŒã«ãšãã¹ã²ã³ãšãåå¿ããããŠçæã
ãçŽéç¶éåäœã§ãããããã®çŽéç¶éåäœã¯æº¶
èå å·¥æ¡ä»¶äžã§ã¯ããŠãŒãã³æµåæåã瀺ããå¹
蟌æ圢ãæŒåºæ圢ãè¡ãªãéã«ã¯èªéã«ãããã¬
ãçããããã倧åã®è£œåãäœãããšãå°é£ã§ã
ãããã®ããã«ããããæ圢çšéã«ã¯æº¶èå å·¥æ¡
件äžã§éããŠãŒãã³æµåæ§ã瀺ãã溶èæã«ãã¬
ãçãé£ãåå²ããªã«ãŒãããŒããèŠæ±ãããã
ããããŠããããªã«ãŒãããŒãæš¹èã®å€ãã¯ãïŒ
䟡ããšããŒã«ãšãã¹ã²ã³ãšãåå¿ããããŠçæã
ãçŽéç¶éåäœã§ãããããã®çŽéç¶éåäœã¯æº¶
èå å·¥æ¡ä»¶äžã§ã¯ããŠãŒãã³æµåæåã瀺ããå¹
蟌æ圢ãæŒåºæ圢ãè¡ãªãéã«ã¯èªéã«ãããã¬
ãçããããã倧åã®è£œåãäœãããšãå°é£ã§ã
ãããã®ããã«ããããæ圢çšéã«ã¯æº¶èå å·¥æ¡
件äžã§éããŠãŒãã³æµåæ§ã瀺ãã溶èæã«ãã¬
ãçãé£ãåå²ããªã«ãŒãããŒããèŠæ±ãããã
ãã®éããŠãŒãã³æµåæ§ã¯ã次åŒ
ïŒïŒ«ã»PN
ïŒããã§ãã¯æº¶èæš¹èã®æµåéïŒc.c.ïŒsecïŒã
ã¯å®æ°ãã¯å§åïŒKgïŒcm2ïŒãã¯æ§é ç²æ§æ
æ°ã§ãããïŒ ããæ±ããããæ§é ç²æ§ææ°ïŒ®ã®å€ã§è©äŸ¡ã§ã
ããã¯ïŒã®ãšãã«ã¯ããŠãŒãã³æµåã瀺ããïŒ
ãã倧ãããªãã»ã©éããŠãŒãã³æµåæ§ã倧ãã
ãªãããšã瀺ãã
ã¯å®æ°ãã¯å§åïŒKgïŒcm2ïŒãã¯æ§é ç²æ§æ
æ°ã§ãããïŒ ããæ±ããããæ§é ç²æ§ææ°ïŒ®ã®å€ã§è©äŸ¡ã§ã
ããã¯ïŒã®ãšãã«ã¯ããŠãŒãã³æµåã瀺ããïŒ
ãã倧ãããªãã»ã©éããŠãŒãã³æµåæ§ã倧ãã
ãªãããšã瀺ãã
æ¬çºæè
ã¯ãäžèšã®æ§é ç²æ§ææ°ïŒ®ãšå¹èŸŒæ
圢ãæŒåºæ圢æã®ãã¬ãšã®é¢ä¿ã調ã¹ãçµæã
ã1.2ã1.3ã®ç·ç¶æ§ã®åŒ·ãããªã«ãŒãããŒãã«æ¯
ããã1.4ã3.5ã®åå²ããããªã«ãŒãããŒãæš¹
èããããã®æ圢æã«ããã¬ãçãé£ãã倧åæ
圢åã«å®¹æã«æ圢ãããããšãæãããšãªã€ãã
圢ãæŒåºæ圢æã®ãã¬ãšã®é¢ä¿ã調ã¹ãçµæã
ã1.2ã1.3ã®ç·ç¶æ§ã®åŒ·ãããªã«ãŒãããŒãã«æ¯
ããã1.4ã3.5ã®åå²ããããªã«ãŒãããŒãæš¹
èããããã®æ圢æã«ããã¬ãçãé£ãã倧åæ
圢åã«å®¹æã«æ圢ãããããšãæãããšãªã€ãã
åŸã€ãŠãæ¬çºæã®ç®çã¯å¹èŸŒæ圢ãæŒåºæ圢ç
ã«åªããæ圢æ§ã瀺ããæ§é ç²æ§ææ°ïŒ®ã1.4ã
3.5ã®åå²ããããªã«ãŒãããŒãæš¹èã®è£œé æ¹æ³
ãæäŸããããšã«ããã
ã«åªããæ圢æ§ã瀺ããæ§é ç²æ§ææ°ïŒ®ã1.4ã
3.5ã®åå²ããããªã«ãŒãããŒãæš¹èã®è£œé æ¹æ³
ãæäŸããããšã«ããã
åŸæ¥ãããåå²å€ãšããŠïŒäŸ¡ä»¥äžã®å€äŸ¡ããšã
ãŒã«ãçšããåå²ããªã«ãŒãããŒãã®è£œé æ³ã¯
çš®ã ç¥ãããŠãããããã®åå²åãéãããšç¶²ç¶
åããææ©æº¶å€ã«äžæº¶ãšãªãããŸãïŒäŸ¡ä»¥äžã®å€
䟡ããšããŒã«ã®åå¿æ§ã¯ïŒäŸ¡ããšããŒã«ã®ããã«
æ¯ã¹ãŠäœããªã©ã®çç±ã§ãé«åçã§ïŒ®ã®é«ãåå²
ããªã«ãŒãããŒããåŸãããšã¯å®¹æã§ãªããšãã
åé¡ããããäŸãã°ãè±åœç¹èš±ç¬¬923863å·æ现æž
ã«ã¯ãïŒäŸ¡ããšããŒã«ãšããã²ã³åã«ã«ããã«ãš
ã®åå¿äžã«ããšããŒã«ãšãã«ã ã¢ã«ãããã®åå¿
ã§åŸãããããªããããã·ååç©ãæ·»å ããæ¹æ³
ãé瀺ãããŠããããããããã®æ¹æ³ã§ã¯æº¶å€äž
溶ç©ãçããããããã§ãªããŠãç±ç¡¬åæ§çæç©
ãšãªãããšããããå®å®ããŠåå²ããªã«ãŒãããŒ
ãã補é ããããšãé£ããã
ãŒã«ãçšããåå²ããªã«ãŒãããŒãã®è£œé æ³ã¯
çš®ã ç¥ãããŠãããããã®åå²åãéãããšç¶²ç¶
åããææ©æº¶å€ã«äžæº¶ãšãªãããŸãïŒäŸ¡ä»¥äžã®å€
䟡ããšããŒã«ã®åå¿æ§ã¯ïŒäŸ¡ããšããŒã«ã®ããã«
æ¯ã¹ãŠäœããªã©ã®çç±ã§ãé«åçã§ïŒ®ã®é«ãåå²
ããªã«ãŒãããŒããåŸãããšã¯å®¹æã§ãªããšãã
åé¡ããããäŸãã°ãè±åœç¹èš±ç¬¬923863å·æ现æž
ã«ã¯ãïŒäŸ¡ããšããŒã«ãšããã²ã³åã«ã«ããã«ãš
ã®åå¿äžã«ããšããŒã«ãšãã«ã ã¢ã«ãããã®åå¿
ã§åŸãããããªããããã·ååç©ãæ·»å ããæ¹æ³
ãé瀺ãããŠããããããããã®æ¹æ³ã§ã¯æº¶å€äž
溶ç©ãçããããããã§ãªããŠãç±ç¡¬åæ§çæç©
ãšãªãããšããããå®å®ããŠåå²ããªã«ãŒãããŒ
ãã補é ããããšãé£ããã
ãã®æ¹è¯æ³ãšããŠãäŸãã°ç¹å
¬æ44â17149å·
å ¬å ±ã«ïŒäŸ¡ããšããŒã«ã«å¯ŸããŠïŒäŸ¡ããšããŒã«ç
ã®å€å®èœååç©ããã¹ã²ã³å¹èŸŒã¿åã«å ãããã¹
ã²ã³ã®å¹èŸŒé床ãåå¿æž©åºŠãå¶åŸ¡ããŠéåããæ¹
æ³ãé瀺ãããŠãããããã®æ¹æ³ã¯æ¡ä»¶èšå®ãè€
éãªã®ã§å·¥æ¥çå®æœãé£ããããã€æº¶æ¶²éåã察
象ãšããŠãããäžæ¹çé¢éåã«ããæ¹æ³ãšããŠ
ã¯ãç¹å ¬æ47â23918å·å ¬å ±ãç¹å ¬æ49â16277å·
å ¬å ±ã«ïŒäŸ¡ä»¥äžã®å€äŸ¡ããšããŒã«ãšïŒäŸ¡ããšããŒ
ã«ãšã®åæçååšäžã«ãïŒäŸ¡ããšããŒã«ãšãã¹ã²
ã³çã®çé žèªå°äœãåå¿ããããæ¹æ³ïŒç¹å ¬æ53
â28193å·å ¬å ±ã«ïŒäŸ¡ããšããŒã«ãšïŒäŸ¡ããšããŒ
ã«ã®åæååšäžã«ãã¹ã²ã³åããŠäœååéããªã«
ãŒãããŒããçæããã€ãã§è§ŠåªãšïŒäŸ¡ä»¥äžã®å€
䟡ããšããŒã«ãå ããæ¹æ³ãé瀺ãããŠãããã
ãããã®æ¹æ³ã§ã¯ãšãã«ãã¹ããšããŒã«ã«æ¯ã¹ãŠ
åå¿æ§ã®äœãïŒäŸ¡ä»¥äžã®å€äŸ¡ããšããŒã«ãçšãã
éã«ã¯ãæ¬çºæã®ç®çãšãããããªïŒ®ã®é«ãããª
ã«ãŒãããŒãã¯åŸãããªãã
å ¬å ±ã«ïŒäŸ¡ããšããŒã«ã«å¯ŸããŠïŒäŸ¡ããšããŒã«ç
ã®å€å®èœååç©ããã¹ã²ã³å¹èŸŒã¿åã«å ãããã¹
ã²ã³ã®å¹èŸŒé床ãåå¿æž©åºŠãå¶åŸ¡ããŠéåããæ¹
æ³ãé瀺ãããŠãããããã®æ¹æ³ã¯æ¡ä»¶èšå®ãè€
éãªã®ã§å·¥æ¥çå®æœãé£ããããã€æº¶æ¶²éåã察
象ãšããŠãããäžæ¹çé¢éåã«ããæ¹æ³ãšããŠ
ã¯ãç¹å ¬æ47â23918å·å ¬å ±ãç¹å ¬æ49â16277å·
å ¬å ±ã«ïŒäŸ¡ä»¥äžã®å€äŸ¡ããšããŒã«ãšïŒäŸ¡ããšããŒ
ã«ãšã®åæçååšäžã«ãïŒäŸ¡ããšããŒã«ãšãã¹ã²
ã³çã®çé žèªå°äœãåå¿ããããæ¹æ³ïŒç¹å ¬æ53
â28193å·å ¬å ±ã«ïŒäŸ¡ããšããŒã«ãšïŒäŸ¡ããšããŒ
ã«ã®åæååšäžã«ãã¹ã²ã³åããŠäœååéããªã«
ãŒãããŒããçæããã€ãã§è§ŠåªãšïŒäŸ¡ä»¥äžã®å€
䟡ããšããŒã«ãå ããæ¹æ³ãé瀺ãããŠãããã
ãããã®æ¹æ³ã§ã¯ãšãã«ãã¹ããšããŒã«ã«æ¯ã¹ãŠ
åå¿æ§ã®äœãïŒäŸ¡ä»¥äžã®å€äŸ¡ããšããŒã«ãçšãã
éã«ã¯ãæ¬çºæã®ç®çãšãããããªïŒ®ã®é«ãããª
ã«ãŒãããŒãã¯åŸãããªãã
ãŸãããã®åå¿çµäºåŸã®ããªããŒæº¶æ¶²ïŒææ©
çžïŒã«ã¯ãåå¿ã«äœ¿çšããã¢ã«ã«ãªãïŒäŸ¡ããšã
ãŒã«çãåå¿ã®å¯çæç©ã§ããé£å¡©ãçé žãœãŒã
çãå«ãã 氎溶液ãå°ããªæº¶æ»Žãšãªã€ãŠå®å®ã«å
æ£ããŠãããæ°ŽæŽçã«ãã€ãŠããããåé€ã粟補
ããå¿ èŠããããããã®ç²Ÿè£œæ§ãæªãæ¬ ç¹ãã
ããããã«ãæåŸã«è¿°ã¹ãæ¹æ³ã§ã¯åå²å€ã¯ïŒäŸ¡
以äžã®å€äŸ¡ããšããŒã«ã«éãããŠããã
çžïŒã«ã¯ãåå¿ã«äœ¿çšããã¢ã«ã«ãªãïŒäŸ¡ããšã
ãŒã«çãåå¿ã®å¯çæç©ã§ããé£å¡©ãçé žãœãŒã
çãå«ãã 氎溶液ãå°ããªæº¶æ»Žãšãªã€ãŠå®å®ã«å
æ£ããŠãããæ°ŽæŽçã«ãã€ãŠããããåé€ã粟補
ããå¿ èŠããããããã®ç²Ÿè£œæ§ãæªãæ¬ ç¹ãã
ããããã«ãæåŸã«è¿°ã¹ãæ¹æ³ã§ã¯åå²å€ã¯ïŒäŸ¡
以äžã®å€äŸ¡ããšããŒã«ã«éãããŠããã
æ¬çºæè
ã¯ãäžè¿°ã®åŠãåŸæ¥æ¹æ³ã®è«žæ¬ é¥ãå
æããŠæ¬çºæã®ç®çãéæãã¹ãéæç 究ããçµ
æãäž¡æ«ç«¯ã«åå¿åºãæããäœååéã®ç·ç¶ããª
ã«ãŒãããŒãããŸãåæããããã«ïŒäŸ¡ä»¥äžã®å€
䟡ããšããŒã«ãšïŒäŸ¡ããšããŒã«ãšãæ·»å ããŠåå¿
ããã次ãã§ïŒäŸ¡ããšããŒã«ãæ·»å åå¿ãããŠé«
ååéåããããšã«ãã€ãŠã溶å€äžæº¶åã®æããª
ããé«åçã§ãé«ãå€ãæããåå²ããªã«ãŒã
ããŒããå®å®ããŠåŸãããšãã§ããããšãèŠãåº
ããæ¬çºæã«å°éããã
æããŠæ¬çºæã®ç®çãéæãã¹ãéæç 究ããçµ
æãäž¡æ«ç«¯ã«åå¿åºãæããäœååéã®ç·ç¶ããª
ã«ãŒãããŒãããŸãåæããããã«ïŒäŸ¡ä»¥äžã®å€
䟡ããšããŒã«ãšïŒäŸ¡ããšããŒã«ãšãæ·»å ããŠåå¿
ããã次ãã§ïŒäŸ¡ããšããŒã«ãæ·»å åå¿ãããŠé«
ååéåããããšã«ãã€ãŠã溶å€äžæº¶åã®æããª
ããé«åçã§ãé«ãå€ãæããåå²ããªã«ãŒã
ããŒããå®å®ããŠåŸãããšãã§ããããšãèŠãåº
ããæ¬çºæã«å°éããã
ããªãã¡ãæ¬çºæã¯ïŒäŸ¡ããšããŒã«ã®ã¢ã«ã«ãª
氎溶液ãšãã¹ã²ã³ãšãææ©æº¶åªã®ååšäžã«åå¿ã
ãããŠåŸãããäœååéã®ç·ç¶ããªã«ãŒãããŒã
ã«ããŸãïŒäŸ¡ä»¥äžã®å€äŸ¡ããšããŒã«ãšïŒäŸ¡ããšã
ãŒã«ãšãå ããŠåå¿ããããã€ãã§ïŒäŸ¡ããšããŒ
ã«ãå ããŠåå¿ããããããšãããªããïŒäŸ¡ä»¥äž
ã®å€äŸ¡ããšããŒã«ã®éãïŒäŸ¡ããšããŒã«ã®å šéã«
åºããŠ0.1ã2.0ã¢ã«ïŒ ãå ±åããïŒäŸ¡ããšããŒã«
ãïŒäŸ¡ä»¥äžã®å€äŸ¡ããšããŒã«ã®æ°Žé žåºïŒååœãïŒ
ãïŒã¢ã«ããã³åå¿æ··å液ãæ§æããææ©çžãšæ°Ž
çžã®äœç©æ¯ãïŒïŒ0.1ãïŒïŒ1.3ã§ããããšãç¹åŸŽ
ãšããåå²ããªã«ãŒãããŒãã®è£œé æ¹æ³ã§ããã
氎溶液ãšãã¹ã²ã³ãšãææ©æº¶åªã®ååšäžã«åå¿ã
ãããŠåŸãããäœååéã®ç·ç¶ããªã«ãŒãããŒã
ã«ããŸãïŒäŸ¡ä»¥äžã®å€äŸ¡ããšããŒã«ãšïŒäŸ¡ããšã
ãŒã«ãšãå ããŠåå¿ããããã€ãã§ïŒäŸ¡ããšããŒ
ã«ãå ããŠåå¿ããããããšãããªããïŒäŸ¡ä»¥äž
ã®å€äŸ¡ããšããŒã«ã®éãïŒäŸ¡ããšããŒã«ã®å šéã«
åºããŠ0.1ã2.0ã¢ã«ïŒ ãå ±åããïŒäŸ¡ããšããŒã«
ãïŒäŸ¡ä»¥äžã®å€äŸ¡ããšããŒã«ã®æ°Žé žåºïŒååœãïŒ
ãïŒã¢ã«ããã³åå¿æ··å液ãæ§æããææ©çžãšæ°Ž
çžã®äœç©æ¯ãïŒïŒ0.1ãïŒïŒ1.3ã§ããããšãç¹åŸŽ
ãšããåå²ããªã«ãŒãããŒãã®è£œé æ¹æ³ã§ããã
æ¬çºæã®è£œé æ¹æ³ã«ããã°ãæ®ã«åŸæ¥ã®æ¹æ³ã§
ã¯åå¿ãé£ãã€ããïŒå以äžã®æ°Žé žåºãæããã
ã³ãŒã³ç°ããã®ååæ§é å ã«å°ããšãïŒåæãã
ïŒäŸ¡ä»¥äžã®å€äŸ¡ããšããŒã«ãåå²å€ãšããŠçšããŠ
ããé«åçã§ããã溶å€äžæº¶åã®å±éºæ§ããªãã
ã®é«ãåå²ããªã«ãŒãããŒãã補é ããããšã
ã§ãããããããçæããåå²ããªã«ãŒãããŒã
ã®ææ©æº¶åªæº¶æ¶²ã®æ°ŽæŽã«ãã粟補æ§ãããã®ã§ç
ç£æ§ã«åªããå©ç¹ããããæŽã«ãŸããæ¬çºæã®è£œ
é æ¹æ³ã§åŸãããåå²ããªã«ãŒãããŒãã¯é«ãé
ããŠãŒãã³æµåæ§ã瀺ãã溶èå å·¥æã«ãã¬ãç
ãé£ãã®ã§ãå¹èŸŒæ圢ãæŒåºæ圢ã«å¥œé©ã«çšãã
ãã倧åæ圢åã«å å·¥ã§ããå©ç¹ãæããã
ã¯åå¿ãé£ãã€ããïŒå以äžã®æ°Žé žåºãæããã
ã³ãŒã³ç°ããã®ååæ§é å ã«å°ããšãïŒåæãã
ïŒäŸ¡ä»¥äžã®å€äŸ¡ããšããŒã«ãåå²å€ãšããŠçšããŠ
ããé«åçã§ããã溶å€äžæº¶åã®å±éºæ§ããªãã
ã®é«ãåå²ããªã«ãŒãããŒãã補é ããããšã
ã§ãããããããçæããåå²ããªã«ãŒãããŒã
ã®ææ©æº¶åªæº¶æ¶²ã®æ°ŽæŽã«ãã粟補æ§ãããã®ã§ç
ç£æ§ã«åªããå©ç¹ããããæŽã«ãŸããæ¬çºæã®è£œ
é æ¹æ³ã§åŸãããåå²ããªã«ãŒãããŒãã¯é«ãé
ããŠãŒãã³æµåæ§ã瀺ãã溶èå å·¥æã«ãã¬ãç
ãé£ãã®ã§ãå¹èŸŒæ圢ãæŒåºæ圢ã«å¥œé©ã«çšãã
ãã倧åæ圢åã«å å·¥ã§ããå©ç¹ãæããã
æ¬çºæã®è£œé æ¹æ³ã®ãããç¹é·ã¯ãäž¡æ«ç«¯ã«å
å¿åºãæããäœååéã®ç·ç¶ããªã«ãŒãããŒããž
ã®ïŒäŸ¡ä»¥äžã®å€äŸ¡ããšããŒã«ã®ä»å åå¿ãšé«åå
éåãžã®éçž®ååå¿ãåããŠè¡ãªãããšã«ãã€ãŠ
åããŠåŸããããã®ã§ãããåå¿ã®è©³çŽ°ã詳ãã
ã§ãªãããã«ããããã®ç¹é·ã®çºçŸçç±ã®è©³çŽ°ã¯
æ確ã§ãªãããã€ãã®ããã«æšèããããããªã
ã¡ãäœååéã®ç·ç¶ããªã«ãŒãããŒããžã®ïŒäŸ¡ä»¥
äžã®å€äŸ¡ããšããŒã«ã®ä»å åå¿ãç¹å®ã®æ¡ä»¶äžã§
è¡ãªãããã«ãïŒäŸ¡ä»¥äžã®å€äŸ¡ããšããŒã«ã®åå¿
çãé«ããªãããŸãïŒäŸ¡ããšããŒã«ãšåæã«åå¿
ããããããã«åå²åããã網ç¶åãé£ããªãã®
ã§ã溶å€ã®äžæº¶åã®å±éºæ§ãªããã®é«ãåå²ã
ãªã«ãŒãããŒããåŸããããšæšå¯ãããããŸãã
ãã®åŸã§ïŒäŸ¡ããšããŒã«ãå ããŠåå¿ãå®çµãã
ããããšã«ãã€ãŠãæªåå¿ã®ã¯ããããŒã¡ãŒãã
ãªããªããäžã€æªåå¿ã®ïŒäŸ¡ããšããŒã«ãïŒäŸ¡ä»¥
äžã®å€äŸ¡ããšããŒã«ãéåžžã«å°ãªããªãã®ã§ãå
å²ããªã«ãŒãããŒã溶液ã®æ°ŽæŽç²Ÿè£œãåªãããšè
ããããã
å¿åºãæããäœååéã®ç·ç¶ããªã«ãŒãããŒããž
ã®ïŒäŸ¡ä»¥äžã®å€äŸ¡ããšããŒã«ã®ä»å åå¿ãšé«åå
éåãžã®éçž®ååå¿ãåããŠè¡ãªãããšã«ãã€ãŠ
åããŠåŸããããã®ã§ãããåå¿ã®è©³çŽ°ã詳ãã
ã§ãªãããã«ããããã®ç¹é·ã®çºçŸçç±ã®è©³çŽ°ã¯
æ確ã§ãªãããã€ãã®ããã«æšèããããããªã
ã¡ãäœååéã®ç·ç¶ããªã«ãŒãããŒããžã®ïŒäŸ¡ä»¥
äžã®å€äŸ¡ããšããŒã«ã®ä»å åå¿ãç¹å®ã®æ¡ä»¶äžã§
è¡ãªãããã«ãïŒäŸ¡ä»¥äžã®å€äŸ¡ããšããŒã«ã®åå¿
çãé«ããªãããŸãïŒäŸ¡ããšããŒã«ãšåæã«åå¿
ããããããã«åå²åããã網ç¶åãé£ããªãã®
ã§ã溶å€ã®äžæº¶åã®å±éºæ§ãªããã®é«ãåå²ã
ãªã«ãŒãããŒããåŸããããšæšå¯ãããããŸãã
ãã®åŸã§ïŒäŸ¡ããšããŒã«ãå ããŠåå¿ãå®çµãã
ããããšã«ãã€ãŠãæªåå¿ã®ã¯ããããŒã¡ãŒãã
ãªããªããäžã€æªåå¿ã®ïŒäŸ¡ããšããŒã«ãïŒäŸ¡ä»¥
äžã®å€äŸ¡ããšããŒã«ãéåžžã«å°ãªããªãã®ã§ãå
å²ããªã«ãŒãããŒã溶液ã®æ°ŽæŽç²Ÿè£œãåªãããšè
ããããã
æ¬çºæã«çšããããïŒäŸ¡ããšããŒã«ãšããŠã¯ã
ãã¹ããšããŒã«é¡ã奜ãŸããããšãã«ïŒïŒïŒâã
ã¹ïŒ4â²âããããã·ããšãã«ïŒãããã³ã以äžã
ãã¹ããšããŒã«ïŒ¡ãšäºããã奜ãŸããããŸããã¹
ããšããŒã«ïŒ¡ã®äžéšåã¯å šéšãä»ã®ïŒäŸ¡ããšããŒ
ã«ã§çœ®æããŠãããããã¹ããšããŒã«ïŒ¡ä»¥å€ã®ïŒ
䟡ããšããŒã«ãšããŠã¯ãäŸãã°ãã€ããããã³ïŒ
ïŒïŒ4â²âãžããããã·ãžããšãã«ïŒãã¹ïŒïŒâã
ãããã·ããšãã«ïŒã¢ã«ã«ã³ïŒãã¹ïŒïŒâããã
ãã·ããšãã«ïŒã·ã¯ãã¢ã«ã«ã³ïŒãã¹ïŒïŒâãã
ããã·ããšãã«ïŒã¹ã«ãã€ãïŒãã¹ïŒïŒâããã
ãã·ããšãã«ïŒã¹ã«ããã·ãïŒãã¹ïŒïŒâããã
ãã·ããšãã«ïŒã¹ã«ãã³ïŒãã¹ïŒïŒâããããã·
ããšãã«ïŒã±ãã³ïŒãã¹ïŒïŒâããããã·ããšã
ã«ïŒãšãŒãã«ïŒïŒïŒ2â²âãã¹ïŒ3â²ïŒ5â²âãžã¡ãã«
â4â²âããããã·ããšãã«ïŒãããã³åã³ïŒïŒïŒ
âãã¹ïŒ3â²ïŒ5â²âãžããã¢â4â²âããããã·ããš
ãã«ïŒãããã³ã®åŠãããã²ã³åãã¹ããšããŒã«
é¡ãæããããšãã§ããã
ãã¹ããšããŒã«é¡ã奜ãŸããããšãã«ïŒïŒïŒâã
ã¹ïŒ4â²âããããã·ããšãã«ïŒãããã³ã以äžã
ãã¹ããšããŒã«ïŒ¡ãšäºããã奜ãŸããããŸããã¹
ããšããŒã«ïŒ¡ã®äžéšåã¯å šéšãä»ã®ïŒäŸ¡ããšããŒ
ã«ã§çœ®æããŠãããããã¹ããšããŒã«ïŒ¡ä»¥å€ã®ïŒ
䟡ããšããŒã«ãšããŠã¯ãäŸãã°ãã€ããããã³ïŒ
ïŒïŒ4â²âãžããããã·ãžããšãã«ïŒãã¹ïŒïŒâã
ãããã·ããšãã«ïŒã¢ã«ã«ã³ïŒãã¹ïŒïŒâããã
ãã·ããšãã«ïŒã·ã¯ãã¢ã«ã«ã³ïŒãã¹ïŒïŒâãã
ããã·ããšãã«ïŒã¹ã«ãã€ãïŒãã¹ïŒïŒâããã
ãã·ããšãã«ïŒã¹ã«ããã·ãïŒãã¹ïŒïŒâããã
ãã·ããšãã«ïŒã¹ã«ãã³ïŒãã¹ïŒïŒâããããã·
ããšãã«ïŒã±ãã³ïŒãã¹ïŒïŒâããããã·ããšã
ã«ïŒãšãŒãã«ïŒïŒïŒ2â²âãã¹ïŒ3â²ïŒ5â²âãžã¡ãã«
â4â²âããããã·ããšãã«ïŒãããã³åã³ïŒïŒïŒ
âãã¹ïŒ3â²ïŒ5â²âãžããã¢â4â²âããããã·ããš
ãã«ïŒãããã³ã®åŠãããã²ã³åãã¹ããšããŒã«
é¡ãæããããšãã§ããã
ãããã®ïŒäŸ¡ããšããŒã«ã¯ã¢ã«ã«ãªæ°Žæº¶æ¶²ã«æº¶
解åæ£ãããŠäœ¿çšãããããã®å Žåãã¢ã«ã«ãªãš
ããŠã¯èæ§ãœãŒãïŒèæ§ã«ãªãªã©ã®ã¢ã«ã«ãªéå±
æ°Žé žåç©ã奜ãŸããçšãããããã®ã¢ã«ã«ãªæ¿åºŠ
ã¯ïŒã13ééïŒ ã奜ãŸããã溶解åæ£ãããïŒäŸ¡
ããšããŒã«ãšã¢ã«ã«ãªã®ã¢ã«æ¯ã¯ïŒïŒ1.8ãïŒïŒ
3.3ã奜ãŸãããæŽã«å¥œãŸããã¯ïŒïŒ2.2ãïŒïŒ3.1
ã§ããã
解åæ£ãããŠäœ¿çšãããããã®å Žåãã¢ã«ã«ãªãš
ããŠã¯èæ§ãœãŒãïŒèæ§ã«ãªãªã©ã®ã¢ã«ã«ãªéå±
æ°Žé žåç©ã奜ãŸããçšãããããã®ã¢ã«ã«ãªæ¿åºŠ
ã¯ïŒã13ééïŒ ã奜ãŸããã溶解åæ£ãããïŒäŸ¡
ããšããŒã«ãšã¢ã«ã«ãªã®ã¢ã«æ¯ã¯ïŒïŒ1.8ãïŒïŒ
3.3ã奜ãŸãããæŽã«å¥œãŸããã¯ïŒïŒ2.2ãïŒïŒ3.1
ã§ããã
æ¬çºæã«çšããããææ©æº¶åªã¯ãæ°Žã«å¯ŸããŠå®
質çã«äžæº¶ã§ãäžã€åå¿ã«å¯ŸããŠäžæŽ»æ§ã§ããã
ãããåå¿ã«ãã€ãŠçããããªã«ãŒãããŒãã溶
解ããææ©ååç©ã§ããããã®å ·äœäŸãšããŠãå¡©
åã¡ãã¬ã³ïŒããã©ã¯ãã«ãšã¿ã³ïŒïŒïŒïŒâãžã¯
ãã«ãšãã¬ã³ïŒã¯ãããã«ã ïŒåå¡©åççŽ ïŒããª
ã¯ãã«ãšã¿ã³ïŒãžã¯ãã«ãšã¿ã³çã®å¡©çŽ åèèªæ
çåæ°ŽçŽ ïŒã¯ãã«ãã³ãŒã³ïŒãžã¯ãã«ãã³ãŒã³ïŒ
ã¯ãã«ãã«ãšã³çã®å¡©çŽ åè³éŠæçåæ°ŽçŽ ïŒã¢ã»
ãããšãã³ïŒã·ã¯ããããµãã³ïŒã¢ããœãŒã«çã
ãããããšãã§ããããããã¯åç¬ãŸãã¯æ··åç©
ãšããŠçšããããšãã§ããããããã®ãã¡å¡©åã¡
ãã¬ã³ãæã奜ãŸããã
質çã«äžæº¶ã§ãäžã€åå¿ã«å¯ŸããŠäžæŽ»æ§ã§ããã
ãããåå¿ã«ãã€ãŠçããããªã«ãŒãããŒãã溶
解ããææ©ååç©ã§ããããã®å ·äœäŸãšããŠãå¡©
åã¡ãã¬ã³ïŒããã©ã¯ãã«ãšã¿ã³ïŒïŒïŒïŒâãžã¯
ãã«ãšãã¬ã³ïŒã¯ãããã«ã ïŒåå¡©åççŽ ïŒããª
ã¯ãã«ãšã¿ã³ïŒãžã¯ãã«ãšã¿ã³çã®å¡©çŽ åèèªæ
çåæ°ŽçŽ ïŒã¯ãã«ãã³ãŒã³ïŒãžã¯ãã«ãã³ãŒã³ïŒ
ã¯ãã«ãã«ãšã³çã®å¡©çŽ åè³éŠæçåæ°ŽçŽ ïŒã¢ã»
ãããšãã³ïŒã·ã¯ããããµãã³ïŒã¢ããœãŒã«çã
ãããããšãã§ããããããã¯åç¬ãŸãã¯æ··åç©
ãšããŠçšããããšãã§ããããããã®ãã¡å¡©åã¡
ãã¬ã³ãæã奜ãŸããã
æ¬çºæã«ãããŠã¯ãå
ãïŒäŸ¡ããšããŒã«ã®ã¢ã«
ã«ãªæ°Žæº¶æ¶²ãšãã¹ã²ã³ãšãææ©æº¶åªã®ååšäžã§å
å¿ããããŠäœååéã®ç·ç¶ããªã«ãŒãããŒããç
æããããã®éãïŒäŸ¡ããšããŒã«ãšãã¹ã²ã³ã®ã¢
ã«æ¯ã¯ïŒïŒ1.1ãïŒïŒ1.5ã§ãããåå¿ã¯ïŒäŸ¡ããš
ããŒã«ã溶解ããåèšã®ã¢ã«ã«ãªæ°Žæº¶æ¶²ã«ãææ©
溶åªã®ååšäž25â以äžã§ãã¹ã²ã³ãå¹ã蟌ãããš
ã«ãã€ãŠè¡ãªãããšã奜ãŸããããã®åå¿ã«ãã€
ãŠåŸãããç·ç¶ããªã«ãŒãããŒãã¯å¥œãŸããã¯
1.015ã1.200ã®çžå¯Ÿç²åºŠïŒå¡©åã¡ãã¬ã³æº¶åªãçš
ããŠãããªããŒæ¿åºŠ0.7ïœïŒ100mlã§æž¬å®ïŒãæã
ããã®ã§ããã
ã«ãªæ°Žæº¶æ¶²ãšãã¹ã²ã³ãšãææ©æº¶åªã®ååšäžã§å
å¿ããããŠäœååéã®ç·ç¶ããªã«ãŒãããŒããç
æããããã®éãïŒäŸ¡ããšããŒã«ãšãã¹ã²ã³ã®ã¢
ã«æ¯ã¯ïŒïŒ1.1ãïŒïŒ1.5ã§ãããåå¿ã¯ïŒäŸ¡ããš
ããŒã«ã溶解ããåèšã®ã¢ã«ã«ãªæ°Žæº¶æ¶²ã«ãææ©
溶åªã®ååšäž25â以äžã§ãã¹ã²ã³ãå¹ã蟌ãããš
ã«ãã€ãŠè¡ãªãããšã奜ãŸããããã®åå¿ã«ãã€
ãŠåŸãããç·ç¶ããªã«ãŒãããŒãã¯å¥œãŸããã¯
1.015ã1.200ã®çžå¯Ÿç²åºŠïŒå¡©åã¡ãã¬ã³æº¶åªãçš
ããŠãããªããŒæ¿åºŠ0.7ïœïŒ100mlã§æž¬å®ïŒãæã
ããã®ã§ããã
äœååéã®ç·ç¶ããªã«ãŒãããŒãã®çžå¯Ÿç²åºŠã
1.015æªæºã§ã¯æ§é ç²æ§ææ°ã®é«ãåå²ããªã«ãŒ
ãããŒããåŸé£ããäžæ¹1.200ãè¶ ããç¯å²ã§ã¯
åŸã®éçž®ååå¿ã«ãããŠã²ã«åãæãåŸåã«ãªã
ã®ã§å¥œãŸãããªãã
1.015æªæºã§ã¯æ§é ç²æ§ææ°ã®é«ãåå²ããªã«ãŒ
ãããŒããåŸé£ããäžæ¹1.200ãè¶ ããç¯å²ã§ã¯
åŸã®éçž®ååå¿ã«ãããŠã²ã«åãæãåŸåã«ãªã
ã®ã§å¥œãŸãããªãã
ããããŠåŸãããäœååéã®ç·ç¶ããªã«ãŒãã
ãŒãã¯æ¬¡ãã§å€äŸ¡ããšããŒã«ãšåå¿ãããããã
ã®ãã®ã¯äžè¿°ã®ããã«åŸæ¥å ¬ç¥ã®æ¹æ³ã§è¡ãªãã
ãŠããïŒäŸ¡ããšããŒã«ã®å ±åäžã§ãã¹ã²ã³ãšåå¿
ãããã®ã§ã¯ãªããŠãïŒäŸ¡ããšããŒã«ã®ã¿ãšãã¹
ã²ã³ãšã®åå¿ã«ãã€ãŠè£œé ããã®ã§äž¡æ«ç«¯ã«åå¿
åºãæ®ããããšãã§ããæå©ã§ããã
ãŒãã¯æ¬¡ãã§å€äŸ¡ããšããŒã«ãšåå¿ãããããã
ã®ãã®ã¯äžè¿°ã®ããã«åŸæ¥å ¬ç¥ã®æ¹æ³ã§è¡ãªãã
ãŠããïŒäŸ¡ããšããŒã«ã®å ±åäžã§ãã¹ã²ã³ãšåå¿
ãããã®ã§ã¯ãªããŠãïŒäŸ¡ããšããŒã«ã®ã¿ãšãã¹
ã²ã³ãšã®åå¿ã«ãã€ãŠè£œé ããã®ã§äž¡æ«ç«¯ã«åå¿
åºãæ®ããããšãã§ããæå©ã§ããã
æ¬çºæã«ãããŠã¯ã次ãã§äžè¿°ã®äœååéã®ç·
ç¶ããªã«ãŒãããŒããå«ãåå¿æ··å液ãã®ãŸãæ
ã¯æ°Žçžã®äžéšãæãåã€ãæ®æ¶²ã«ãïŒäŸ¡ä»¥äžã®å€
䟡ããšããŒã«ãšïŒäŸ¡ããšããŒã«ããã®ãŸãæã¯å
èšã®ã¢ã«ã«ãªæ°Žæº¶æ¶²ãŸãã¯ææ©æº¶åªã«æº¶è§£ããŠæ·»
å ããåå¿ãããã
ç¶ããªã«ãŒãããŒããå«ãåå¿æ··å液ãã®ãŸãæ
ã¯æ°Žçžã®äžéšãæãåã€ãæ®æ¶²ã«ãïŒäŸ¡ä»¥äžã®å€
䟡ããšããŒã«ãšïŒäŸ¡ããšããŒã«ããã®ãŸãæã¯å
èšã®ã¢ã«ã«ãªæ°Žæº¶æ¶²ãŸãã¯ææ©æº¶åªã«æº¶è§£ããŠæ·»
å ããåå¿ãããã
æ¬çºæã«çšããããïŒäŸ¡ä»¥äžã®å€äŸ¡ããšããŒã«
ãšããŠã¯ãäŸãã°ãããã°ã«ã·ã³ïŒãããã°ã«ã·
ãïŒïŒïŒïŒâãžã¡ãã«âïŒïŒïŒïŒïŒâããªïŒ4â²â
ããããã·ããšãã«ïŒâãããã³âïŒïŒïŒïŒïŒâ
ãžã¡ãã«âïŒïŒïŒïŒïŒâããªïŒ4â²âããããã·ã
ãšãã«ïŒâããã¿ã³ïŒïŒïŒïŒïŒïŒâããªâïŒ4â²âã
ãããã·ããšãã«ïŒâãã³ãŒã³ïŒïŒïŒïŒïŒïŒâã
ãªâïŒ4â²âããããã·ããšãã«ïŒâãšã¿ã³ïŒïŒïŒïŒ
âãã¹âãïŒïŒïŒâãã¹ïŒ4â²âããããã·ããšã
ã«ïŒã·ã¯ãããã·ã«ãâãããã³ïŒïŒïŒïŒâãã¹
âïŒ2â²âããããã·â5â²âã¡ãã«âãã³ãžã«ïŒâïŒ
âã¡ãã«âããšããŒã«ïŒïŒïŒïŒâãã¹âïŒ2â²âã
ãããã·â5â²âã€ãœãããã«âãã³ãžã«ïŒâïŒâ
ã€ãœãããã«ããšããŒã«ïŒãã¹âãïŒâãããã
ã·âïŒâïŒ2â²âããããã·â5â²âã¡ãã«ãã³ãžã«ïŒ
âïŒâã¡ãã«âããšãã«ãã¡ã¿ã³ïŒããã©âïŒïŒ
âããããã·ããšãã«ïŒã¡ã¿ã³ïŒããªâïŒïŒâã
ãããã·ããšãã«ïŒããšãã«ã¡ã¿ã³ïŒããªã¹ããš
ããŒã«ïŒãã¹ïŒïŒïŒïŒâãžããããã·ããšãã«ïŒ
ã±ãã³ïŒïŒïŒïŒâãã¹âïŒ4â²ïŒ4â³âãžããããã·
ããªããšãã«âã¡ãã«ïŒâãã³ãŒã³çãæããã
ããããããã¯ããã²ã³çœ®æåºãæããŠããŠãã
ãããããã¯æ··åããŠçšããŠãå·®æ¯ããªãã
ãšããŠã¯ãäŸãã°ãããã°ã«ã·ã³ïŒãããã°ã«ã·
ãïŒïŒïŒïŒâãžã¡ãã«âïŒïŒïŒïŒïŒâããªïŒ4â²â
ããããã·ããšãã«ïŒâãããã³âïŒïŒïŒïŒïŒâ
ãžã¡ãã«âïŒïŒïŒïŒïŒâããªïŒ4â²âããããã·ã
ãšãã«ïŒâããã¿ã³ïŒïŒïŒïŒïŒïŒâããªâïŒ4â²âã
ãããã·ããšãã«ïŒâãã³ãŒã³ïŒïŒïŒïŒïŒïŒâã
ãªâïŒ4â²âããããã·ããšãã«ïŒâãšã¿ã³ïŒïŒïŒïŒ
âãã¹âãïŒïŒïŒâãã¹ïŒ4â²âããããã·ããšã
ã«ïŒã·ã¯ãããã·ã«ãâãããã³ïŒïŒïŒïŒâãã¹
âïŒ2â²âããããã·â5â²âã¡ãã«âãã³ãžã«ïŒâïŒ
âã¡ãã«âããšããŒã«ïŒïŒïŒïŒâãã¹âïŒ2â²âã
ãããã·â5â²âã€ãœãããã«âãã³ãžã«ïŒâïŒâ
ã€ãœãããã«ããšããŒã«ïŒãã¹âãïŒâãããã
ã·âïŒâïŒ2â²âããããã·â5â²âã¡ãã«ãã³ãžã«ïŒ
âïŒâã¡ãã«âããšãã«ãã¡ã¿ã³ïŒããã©âïŒïŒ
âããããã·ããšãã«ïŒã¡ã¿ã³ïŒããªâïŒïŒâã
ãããã·ããšãã«ïŒããšãã«ã¡ã¿ã³ïŒããªã¹ããš
ããŒã«ïŒãã¹ïŒïŒïŒïŒâãžããããã·ããšãã«ïŒ
ã±ãã³ïŒïŒïŒïŒâãã¹âïŒ4â²ïŒ4â³âãžããããã·
ããªããšãã«âã¡ãã«ïŒâãã³ãŒã³çãæããã
ããããããã¯ããã²ã³çœ®æåºãæããŠããŠãã
ãããããã¯æ··åããŠçšããŠãå·®æ¯ããªãã
ãŸããæ¬çºæã«çšããããïŒäŸ¡ããšããŒã«ãšã
ãŠã¯ãäŸãã°ããšããŒã«ïŒC1ãC4ã®ã¢ã«ãã«çœ®
æåºãæããã¢ã«ãã«ããšããŒã«é¡ãç¹ã«ïœâã¯
ã¬ãŸãŒã«ïŒïœâïœâããã«ããšããŒã«ãæããã
ãããããã¯ããã²ã³ã§çœ®æãããŠããŠãããã
ãŠã¯ãäŸãã°ããšããŒã«ïŒC1ãC4ã®ã¢ã«ãã«çœ®
æåºãæããã¢ã«ãã«ããšããŒã«é¡ãç¹ã«ïœâã¯
ã¬ãŸãŒã«ïŒïœâïœâããã«ããšããŒã«ãæããã
ãããããã¯ããã²ã³ã§çœ®æãããŠããŠãããã
ãããã®ããšããŒã«é¡ã®äœ¿çšéã¯ãåå²ããªã«
ãŒãããŒãã補é ããã®ã«äœ¿çšãããïŒäŸ¡ããšã
ãŒã«ã®å šéãããªãã¡ãäœååéã®ç·ç¶ããªã«ãŒ
ãããŒãã®è£œé ã«äœ¿çšãããéãšæåŸã«äœ¿çšãã
ãéãšã®åèšã«åºã¥ããŠå®ãããããå®æœäŸïŒã
ãã³ïŒã«è¿°ã¹ãããã«ãæåŸã«äœ¿çšãããïŒäŸ¡ã
ãšããŒã«ãšããŠäœååéããªã«ãŒãããŒã補é çŽ
åŸã®åå¿æ··å液ããæãåã€ãæ°Žçžäžã«æº¶è§£ããŠ
ããæªåå¿ïŒäŸ¡ããšããŒã«ãå åœãããå Žåã«
ã¯ãïŒäŸ¡ããšããŒã«ã®å šéã¯äœååéããªã«ãŒã
ããŒãã®è£œé ã«äœ¿çšãããéã«äžèŽããããã
ãŠãïŒäŸ¡ä»¥äžã®å€äŸ¡ããšããŒã«ã®äœ¿çšéã¯ïŒäŸ¡ã
ãšããŒã«ã®å šéã«åºã¥ããŠ0.1ã2.0ã¢ã«ïŒ ã奜ãŸ
ããã¯0.3ã1.5ã¢ã¢ã«ïŒ ã§ããããŸãïŒäŸ¡ããšã
ãŒã«ã®äœ¿çšéã¯ç®çãšããåå²ããªã«ãŒãããŒã
ã®å¹³åååéã«å¯Ÿå¿ããŠæ±ºããããããéåžž0.5
ã10ã¢ã«ïŒ ãæŽã«å¥œãŸããã¯ïŒãïŒã¢ã«ïŒ ã§ã
ããïŒäŸ¡ä»¥äžã®å€äŸ¡ããšããŒã«äœ¿çšéã0.1ã¢ã«
ïŒ æªæºã§ã¯åå²ååå¿ãååã«é²ãŸããç®çãšã
ãæ§é ç²æ§ææ°ïŒ®ã®é«ãåå²ããªã«ãŒãããŒãã¯
åŸãããªãããŸããïŒäŸ¡ä»¥äžã®å€äŸ¡ããšããŒã«ã®
䜿çšéã2.0ã¢ã«ïŒ ãè¶ ãããšãã²ã«åããŠæº¶å€
ã«äžæº¶åããå±éºæ§ãçãããããã§ãïŒäŸ¡ä»¥äž
ã®å€äŸ¡ããšããŒã«ãåå¿ããããéã«å ±åããïŒ
䟡ããšããŒã«ã®éã¯å°ãªãæ¹ããããïŒäŸ¡ããšã
ãŒã«ãïŒäŸ¡ä»¥äžã®å€äŸ¡ããšããŒã«ã®æ°Žé žåºã®ïŒå
åœãïŒã¢ã«ãè¶ ããŠå ±åãããšãïŒäŸ¡ä»¥äžã®å€äŸ¡
ããšããŒã«ã¯äœååéããªã«ãŒãããŒããšåå¿ã
é£ããªããåŸã€ãŠç®çãšããæ§é ç²æ§ææ°ïŒ®ã®é«
ãåå²ããªã«ãŒãããŒãã¯åŸããé£ãã
ãŒãããŒãã補é ããã®ã«äœ¿çšãããïŒäŸ¡ããšã
ãŒã«ã®å šéãããªãã¡ãäœååéã®ç·ç¶ããªã«ãŒ
ãããŒãã®è£œé ã«äœ¿çšãããéãšæåŸã«äœ¿çšãã
ãéãšã®åèšã«åºã¥ããŠå®ãããããå®æœäŸïŒã
ãã³ïŒã«è¿°ã¹ãããã«ãæåŸã«äœ¿çšãããïŒäŸ¡ã
ãšããŒã«ãšããŠäœååéããªã«ãŒãããŒã補é çŽ
åŸã®åå¿æ··å液ããæãåã€ãæ°Žçžäžã«æº¶è§£ããŠ
ããæªåå¿ïŒäŸ¡ããšããŒã«ãå åœãããå Žåã«
ã¯ãïŒäŸ¡ããšããŒã«ã®å šéã¯äœååéããªã«ãŒã
ããŒãã®è£œé ã«äœ¿çšãããéã«äžèŽããããã
ãŠãïŒäŸ¡ä»¥äžã®å€äŸ¡ããšããŒã«ã®äœ¿çšéã¯ïŒäŸ¡ã
ãšããŒã«ã®å šéã«åºã¥ããŠ0.1ã2.0ã¢ã«ïŒ ã奜ãŸ
ããã¯0.3ã1.5ã¢ã¢ã«ïŒ ã§ããããŸãïŒäŸ¡ããšã
ãŒã«ã®äœ¿çšéã¯ç®çãšããåå²ããªã«ãŒãããŒã
ã®å¹³åååéã«å¯Ÿå¿ããŠæ±ºããããããéåžž0.5
ã10ã¢ã«ïŒ ãæŽã«å¥œãŸããã¯ïŒãïŒã¢ã«ïŒ ã§ã
ããïŒäŸ¡ä»¥äžã®å€äŸ¡ããšããŒã«äœ¿çšéã0.1ã¢ã«
ïŒ æªæºã§ã¯åå²ååå¿ãååã«é²ãŸããç®çãšã
ãæ§é ç²æ§ææ°ïŒ®ã®é«ãåå²ããªã«ãŒãããŒãã¯
åŸãããªãããŸããïŒäŸ¡ä»¥äžã®å€äŸ¡ããšããŒã«ã®
䜿çšéã2.0ã¢ã«ïŒ ãè¶ ãããšãã²ã«åããŠæº¶å€
ã«äžæº¶åããå±éºæ§ãçãããããã§ãïŒäŸ¡ä»¥äž
ã®å€äŸ¡ããšããŒã«ãåå¿ããããéã«å ±åããïŒ
䟡ããšããŒã«ã®éã¯å°ãªãæ¹ããããïŒäŸ¡ããšã
ãŒã«ãïŒäŸ¡ä»¥äžã®å€äŸ¡ããšããŒã«ã®æ°Žé žåºã®ïŒå
åœãïŒã¢ã«ãè¶ ããŠå ±åãããšãïŒäŸ¡ä»¥äžã®å€äŸ¡
ããšããŒã«ã¯äœååéããªã«ãŒãããŒããšåå¿ã
é£ããªããåŸã€ãŠç®çãšããæ§é ç²æ§ææ°ïŒ®ã®é«
ãåå²ããªã«ãŒãããŒãã¯åŸããé£ãã
ãã®æ®µéã§ãåå¿æ··å液äžã®ææ©æº¶åªçžãšæ°Žçž
ã®äœç©æ¯ã¯ïŒïŒ0.1ã1.3ã®ç¯å²ã«ããããšãé©åœ
ã§ãããïŒïŒ0.1ã1.2ã®ç¯å²ã奜ãŸããããã®ç
ç±ã¯æãã§ãªããããã®äœç©æ¯ã0.1æªæºã§ã¯ã²
ã«åããããšãå€ãããŸã1.3ãè¶ ãããšïŒäŸ¡ä»¥
äžã®å€äŸ¡ããšããŒã«ãåå¿ãã«ãããªã€ãŠããã
ããç®çãšããã®é«ãåå²ããªã«ãŒãããŒãã
å®å®ããŠè£œé ããããšãé£ããã
ã®äœç©æ¯ã¯ïŒïŒ0.1ã1.3ã®ç¯å²ã«ããããšãé©åœ
ã§ãããïŒïŒ0.1ã1.2ã®ç¯å²ã奜ãŸããããã®ç
ç±ã¯æãã§ãªããããã®äœç©æ¯ã0.1æªæºã§ã¯ã²
ã«åããããšãå€ãããŸã1.3ãè¶ ãããšïŒäŸ¡ä»¥
äžã®å€äŸ¡ããšããŒã«ãåå¿ãã«ãããªã€ãŠããã
ããç®çãšããã®é«ãåå²ããªã«ãŒãããŒãã
å®å®ããŠè£œé ããããšãé£ããã
次ã«ãåå¿æ··å液ã«è§Šåªãæ·»å ããŠãïŒã20å
éåå¿ãè¡ãªããããã§äœ¿çšããã觊åªã¯ã第ïŒ
çŽã¢ãã³ãŸãã¯ç¬¬ïŒçŽã¢ã³ã¢ããŠã å¡©ã§ãã€ãŠã
å ·äœçã«ã¯ããªãšãã«ã¢ãã³ïŒããªã¡ãã«ããã·
ã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ããªãïŒãžã¡ãã«ãã³
ãžã«ããšãã«ã¢ã³ã¢ããŠã ã¯ããªãïŒããªã¡ãã«
ããã·ã«ãã³ãžã«ã¢ã³ã¢ããŠã ããããã·ãçã
äŸç€ºããããšãã§ããããã®å¥œãŸããæ·»å éã¯å
èšã®ïŒäŸ¡ããšããŒã«ã®å šéã«åºã¥ããŠ0.01ãïŒã¢
ã«ïŒ ã§ãããæŽã«å¥œãŸããã¯0.05ã0.5ã¢ã«ïŒ ã§
ããã
éåå¿ãè¡ãªããããã§äœ¿çšããã觊åªã¯ã第ïŒ
çŽã¢ãã³ãŸãã¯ç¬¬ïŒçŽã¢ã³ã¢ããŠã å¡©ã§ãã€ãŠã
å ·äœçã«ã¯ããªãšãã«ã¢ãã³ïŒããªã¡ãã«ããã·
ã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ããªãïŒãžã¡ãã«ãã³
ãžã«ããšãã«ã¢ã³ã¢ããŠã ã¯ããªãïŒããªã¡ãã«
ããã·ã«ãã³ãžã«ã¢ã³ã¢ããŠã ããããã·ãçã
äŸç€ºããããšãã§ããããã®å¥œãŸããæ·»å éã¯å
èšã®ïŒäŸ¡ããšããŒã«ã®å šéã«åºã¥ããŠ0.01ãïŒã¢
ã«ïŒ ã§ãããæŽã«å¥œãŸããã¯0.05ã0.5ã¢ã«ïŒ ã§
ããã
æåŸã«ãåå¿æ··å液ã«ïŒäŸ¡ããšããŒã«ãã¢ã«ã«
ãªæ°Žæº¶æ¶²ã«æº¶è§£ããŠæ·»å ããæ¹æãç¶ç¶ããŠéå
ãå®çµãããããã§äœ¿çšããïŒäŸ¡ããšããŒã«ã®ã¢
ã«ã«ãªæ°Žæº¶æ¶²ã¯ãå®æœäŸïŒããã³ïŒã«è¿°è¿°ã¹ãã
ãã«ãäœååéã®ç·ç¶ããªã«ãŒãããŒãã補é ã
ãçŽåŸã®æ°Žçžã®äžéšã§ãã€ãŠãå·®æ¯ããªãããŸ
ããããã§äœ¿çšããã¢ã«ã«ãªæ°Žæº¶æ¶²äžã®ã¢ã«ã«ãª
ã®æ¿åºŠã¯ïŒã13ééïŒ ã奜ãŸããã䜿çšããïŒäŸ¡
ããšããŒã«ã®éã¯ãåèšã®ïŒäŸ¡ããšããŒã«ã®å šé
ã«åºã¥ããŠïŒã20ã¢ã«ïŒ ãæŽã«å¥œãŸããã¯ïŒã18
ã¢ã«ïŒ ã§ããã
ãªæ°Žæº¶æ¶²ã«æº¶è§£ããŠæ·»å ããæ¹æãç¶ç¶ããŠéå
ãå®çµãããããã§äœ¿çšããïŒäŸ¡ããšããŒã«ã®ã¢
ã«ã«ãªæ°Žæº¶æ¶²ã¯ãå®æœäŸïŒããã³ïŒã«è¿°è¿°ã¹ãã
ãã«ãäœååéã®ç·ç¶ããªã«ãŒãããŒãã補é ã
ãçŽåŸã®æ°Žçžã®äžéšã§ãã€ãŠãå·®æ¯ããªãããŸ
ããããã§äœ¿çšããã¢ã«ã«ãªæ°Žæº¶æ¶²äžã®ã¢ã«ã«ãª
ã®æ¿åºŠã¯ïŒã13ééïŒ ã奜ãŸããã䜿çšããïŒäŸ¡
ããšããŒã«ã®éã¯ãåèšã®ïŒäŸ¡ããšããŒã«ã®å šé
ã«åºã¥ããŠïŒã20ã¢ã«ïŒ ãæŽã«å¥œãŸããã¯ïŒã18
ã¢ã«ïŒ ã§ããã
åå¿çµäºåŸã®åå¿æ··å液ã®æ°Žçžã«ã¯ãã¢ã«ã«ãª
éå±ã®æ°Žé žåç©ïŒçé žå¡©ïŒå¡©åç©ãªã©ã®å¯çæç©
ãå€éã«å«ãŸããŠããã®ã§ãããããå®å šã«é€å»
ããããšã奜ãŸããããã®ããã«ãåå¿æ··å液ã
ãã®ãŸãããŸãã¯ææ©æº¶åªã§åžéããå¡©é žçã®é ž
ãå ãé žæ§ãšããã®ã¡ãå¿ èŠã«å¿ã芪氎æ§ã®æ
ã§éãè¡ãªããæ°Žçžãšææ©çžã«åé¢ããæŽã«æ
æ©çžã¯ç¡æ©ã€ãªã³ãæ€åºãããªããªããŸã§å åã«
æ°ŽæŽç²Ÿè£œããããšã奜ãŸãããæ°ŽæŽç²Ÿè£œã®çµã€ã
ææ©çžããææ©æº¶åªãé€å»ãããšåºäœã®åå²ããª
ã«ãŒãããŒããåŸãããšãã§ããã
éå±ã®æ°Žé žåç©ïŒçé žå¡©ïŒå¡©åç©ãªã©ã®å¯çæç©
ãå€éã«å«ãŸããŠããã®ã§ãããããå®å šã«é€å»
ããããšã奜ãŸããããã®ããã«ãåå¿æ··å液ã
ãã®ãŸãããŸãã¯ææ©æº¶åªã§åžéããå¡©é žçã®é ž
ãå ãé žæ§ãšããã®ã¡ãå¿ èŠã«å¿ã芪氎æ§ã®æ
ã§éãè¡ãªããæ°Žçžãšææ©çžã«åé¢ããæŽã«æ
æ©çžã¯ç¡æ©ã€ãªã³ãæ€åºãããªããªããŸã§å åã«
æ°ŽæŽç²Ÿè£œããããšã奜ãŸãããæ°ŽæŽç²Ÿè£œã®çµã€ã
ææ©çžããææ©æº¶åªãé€å»ãããšåºäœã®åå²ããª
ã«ãŒãããŒããåŸãããšãã§ããã
以äžã«ãå®æœäŸã«ãã€ãŠæ¬çºæãããã«èª¬æã
ãããæ¬çºæã¯ãããã«éå®ããããã®ã§ãªãã
ãªããäŸäžã®ç¹æ§ã¯æ¬¡ã®æ¹æ³ã§æž¬å®ããã
ãããæ¬çºæã¯ãããã«éå®ããããã®ã§ãªãã
ãªããäŸäžã®ç¹æ§ã¯æ¬¡ã®æ¹æ³ã§æž¬å®ããã
äºå也ç¥ããããªã«ãŒãããŒãããæŒåºæ©ïŒãŒ
ãã©ã«ã»ãšã¬ã¯ããªãã¯(æ ª)補ïŒã¢ãã«No.
9T51Y106ïŒã«ãŠ300âã§æŒåºãããã¬ããåã
ãã該ãã¬ããã也ç¥åŸé«ååŒãããŒãã¹ã¿ãŒ
ïŒå³¶æŽ¥è£œäœæ(æ ª)補ïŒã®ã·ãªã³ããŒã«å ¥ãã280ã
300âã®äžå®æž©åºŠã§ã®å ããå§åïŒ20ã300KgïŒ
cm2ïŒïŒç¹ïŒãšå€«ã ã®æº¶èæš¹èã®æµåéïŒc.c.ïŒ
secïŒã枬å®ãã倫ã ã®å€ã䞡察æ°ã°ã©ãã«ãã
ããããŠåŸãããååž°çŽç·ã®åŸé ãããæ±ã
ããæ§é ç²æ§ææ°ïŒ®ã¯å€§ããã»ã©éããŠãŒãã³æµ
åæ§ã倧ãããå¹èŸŒæ圢ãæŒåºæ圢ã«é©ããããš
ãè¡šããã
ãã©ã«ã»ãšã¬ã¯ããªãã¯(æ ª)補ïŒã¢ãã«No.
9T51Y106ïŒã«ãŠ300âã§æŒåºãããã¬ããåã
ãã該ãã¬ããã也ç¥åŸé«ååŒãããŒãã¹ã¿ãŒ
ïŒå³¶æŽ¥è£œäœæ(æ ª)補ïŒã®ã·ãªã³ããŒã«å ¥ãã280ã
300âã®äžå®æž©åºŠã§ã®å ããå§åïŒ20ã300KgïŒ
cm2ïŒïŒç¹ïŒãšå€«ã ã®æº¶èæš¹èã®æµåéïŒc.c.ïŒ
secïŒã枬å®ãã倫ã ã®å€ã䞡察æ°ã°ã©ãã«ãã
ããããŠåŸãããååž°çŽç·ã®åŸé ãããæ±ã
ããæ§é ç²æ§ææ°ïŒ®ã¯å€§ããã»ã©éããŠãŒãã³æµ
åæ§ã倧ãããå¹èŸŒæ圢ãæŒåºæ圢ã«é©ããããš
ãè¡šããã
也ç¥ããè©Šæ0.700ïœãå¡©åã¡ãã¬ã³100mlã«æº¶
解ãããªã¹ãã¯ã«ãç²åºŠèšã«ãŠ20âã§æž¬å®ããã
解ãããªã¹ãã¯ã«ãç²åºŠèšã«ãŠ20âã§æž¬å®ããã
åå¿æ··å液ããæ°ŽçžïŒmlãåé¢ããåžã¢ã«ã«ãª
氎溶液ã«ãŠ200ã1000åã«åžéåŸåå å 床èšïŒæ¥
ç«è£œäœæ(æ ª)補ïŒ200â10åïŒãçšã294nmã®åžå
床ã枬å®ããäžèšåŒ(1)ãããã¹ããšããŒã«ïŒ¡ã®
éãæ±ããã
氎溶液ã«ãŠ200ã1000åã«åžéåŸåå å 床èšïŒæ¥
ç«è£œäœæ(æ ª)補ïŒ200â10åïŒãçšã294nmã®åžå
床ã枬å®ããäžèšåŒ(1)ãããã¹ããšããŒã«ïŒ¡ã®
éãæ±ããã
ãã¹ããšããŒã«ïŒ¡ïŒïœïŒïŒïŒ0.0455A âŠâŠ(1)
ãæªåå¿ãããã°ã«ã·ã³ã®å®éã
åå¿æ··å液ããæ°ŽçžïŒmlãåé¢ããåžã¢ã«ã«ãª
氎溶液ã«ãŠ200åã«åžéåŸãåå å 床èšïŒäžèšãš
åãïŒãçšã348nmã®åžå 床ã枬å®ããäžèšåŒ
(2)ãããããã°ã«ã·ã³ã®éãæ±ããã
氎溶液ã«ãŠ200åã«åžéåŸãåå å 床èšïŒäžèšãš
åãïŒãçšã348nmã®åžå 床ã枬å®ããäžèšåŒ
(2)ãããããã°ã«ã·ã³ã®éãæ±ããã
ãããã°ã«ã·ã³ïŒïœïŒïŒïŒ0.0191A âŠâŠ(2)
ãæªåå¿ãããã°ã«ã·ãã®å®éã
åå¿æ··å液ããæ°ŽçžïŒmlãåé¢ããåžã¢ã«ã«ãª
氎溶液ã«ãŠ200åã«åžéåŸãåå å 床èšïŒäžèšãš
åãïŒãçšã357nmã®åžå 床ã枬å®ããäžèšåŒ
(3)ããããããã°ã«ã·ãã®éãæ±ããã
氎溶液ã«ãŠ200åã«åžéåŸãåå å 床èšïŒäžèšãš
åãïŒãçšã357nmã®åžå 床ã枬å®ããäžèšåŒ
(3)ããããããã°ã«ã·ãã®éãæ±ããã
ãããã°ã«ã·ãïŒïœïŒïŒïŒ0.0303A
ïŒ0.000015 âŠâŠ(3)
ãæªåå¿ãã¹âïŒïŒïŒïŒâãžããããã·ããšã
ã«ïŒã±ãã³ã®å®éã åå¿æ··å液ããæ°ŽçžïŒmlãåé¢ããåžã¢ã«ã«ãª
氎溶液ã«ãŠ200åã«åžéåŸãåå ã 床èšïŒäžèšïŒ
ãçšã323nmã®åžå 床ã枬å®ããäžèšåŒ(4)ãã
ãã¹âïŒïŒïŒïŒâãžããããã·ããšãã«ïŒã±ãã³
ã®éãæ±ããã
ã«ïŒã±ãã³ã®å®éã åå¿æ··å液ããæ°ŽçžïŒmlãåé¢ããåžã¢ã«ã«ãª
氎溶液ã«ãŠ200åã«åžéåŸãåå ã 床èšïŒäžèšïŒ
ãçšã323nmã®åžå 床ã枬å®ããäžèšåŒ(4)ãã
ãã¹âïŒïŒïŒïŒâãžããããã·ããšãã«ïŒã±ãã³
ã®éãæ±ããã
ãã¹âïŒïŒïŒïŒâãžããããã·ããšãã«ïŒã±ãã³
ïŒïœïŒïŒïŒ0.0148AïŒ0.00007 âŠâŠ(4)
ã粟補æ§ã®è©äŸ¡ã
åå¿æ··å液ã«å¡©åã¡ãã¬ã³ãå ããŠãããªã«ãŒ
ãããŒãã®æ¿åºŠãïŒééïŒ ã«ãªãããã«åžéãã
ã®ã¡ãææ©çžãšæ°Žçžã«åé¢ããããã®ææ©çž1.5
ã«0.01Nã®å¡©é ž0.5ãå ããŠååã«æ··åããã®
ã¡é眮åé¢ãããã€ãã«æ°ŽæŽãè¡ãªã€ããããªã
ã¡ãäžèšææ©çžã«1.5ã®çŽæ°Žãå ããŠååã«æ··
åããã®ã¡ãçŽïŒæ±æŽçŽ(æ ª)補ïŒå®æ§çŽNo.
ïŒïŒã§éããŠé眮åé¢ãããæŽã«ãæ°ŽæŽææ°Žäž
ã®å¡©çŽ ã€ãªã³ãç¡é žéã«ãã€ãŠæ€åºãããªããªã
ãŸã§ãåæ§ãªæäœã§æ°ŽæŽãããè¿ããã粟補æ§ã¯
該氎æŽã®åæ°ãå°ãªãã»ã©è¯å¥œã§ããããšãè¡šã
ãã
ãããŒãã®æ¿åºŠãïŒééïŒ ã«ãªãããã«åžéãã
ã®ã¡ãææ©çžãšæ°Žçžã«åé¢ããããã®ææ©çž1.5
ã«0.01Nã®å¡©é ž0.5ãå ããŠååã«æ··åããã®
ã¡é眮åé¢ãããã€ãã«æ°ŽæŽãè¡ãªã€ããããªã
ã¡ãäžèšææ©çžã«1.5ã®çŽæ°Žãå ããŠååã«æ··
åããã®ã¡ãçŽïŒæ±æŽçŽ(æ ª)補ïŒå®æ§çŽNo.
ïŒïŒã§éããŠé眮åé¢ãããæŽã«ãæ°ŽæŽææ°Žäž
ã®å¡©çŽ ã€ãªã³ãç¡é žéã«ãã€ãŠæ€åºãããªããªã
ãŸã§ãåæ§ãªæäœã§æ°ŽæŽãããè¿ããã粟補æ§ã¯
該氎æŽã®åæ°ãå°ãªãã»ã©è¯å¥œã§ããããšãè¡šã
ãã
å®æœäŸ ïŒ
ãã¹ã²ã³å¹èŸŒç®¡ïŒæž©åºŠèšåã³ãããŸãæ©ããšã
ã€ããïŒäžãå£ãã©ã¹ã³ã«ããã¹ããšããŒã«
A114ïœïŒ0.5ã¢ã«ïŒã溶解ãã12.3ïŒ NaOH氎溶
液394mlãšå¡©åã¡ãã¬ã³378mlãå ¥ãããããŸããª
ãã20ã25âã§ãã¹ã²ã³69.3ïœïŒ0.7ã¢ã«ïŒãçŽ
40åãèŠããŠå°å ¥ãããªãªãŽããŒãçæããã
ããåå¿æ··å液äžã®æªåå¿ãã¹ããšããŒã«ïŒ¡ã¯
4.15ïœïŒ0.0182ã¢ã«ïŒã§ãããçæãªãªãŽããŒã®
çžå¯Ÿç²åºŠã¯1.095ã§ãã€ãã
ã€ããïŒäžãå£ãã©ã¹ã³ã«ããã¹ããšããŒã«
A114ïœïŒ0.5ã¢ã«ïŒã溶解ãã12.3ïŒ NaOH氎溶
液394mlãšå¡©åã¡ãã¬ã³378mlãå ¥ãããããŸããª
ãã20ã25âã§ãã¹ã²ã³69.3ïœïŒ0.7ã¢ã«ïŒãçŽ
40åãèŠããŠå°å ¥ãããªãªãŽããŒãçæããã
ããåå¿æ··å液äžã®æªåå¿ãã¹ããšããŒã«ïŒ¡ã¯
4.15ïœïŒ0.0182ã¢ã«ïŒã§ãããçæãªãªãŽããŒã®
çžå¯Ÿç²åºŠã¯1.095ã§ãã€ãã
ãã®ãªãªãŽããŒåå¿æ··å液ã«ïœâïœâããã«ã
ãšããŒã«3.15ïœïŒ0.021ã¢ã«ïŒãšãããã°ã«ã·ã³
0.63ïœïŒ0.005ã¢ã«ïŒã溶解ãã10ïŒ NaOH氎溶
液ïŒmlãå ããïŒåéãããŸããã®ã¡ããªãšãã«
ã¢ãã³0.23ïœïŒ0.0023ã¢ã«ïŒãå ãã10åéãã
ãŸããŠãããã°ã«ã·ã³ãåå¿ãããããç¶ãåŸã
ãã¹ããšããŒã«A22.8ïœïŒ0.1ã¢ã«ïŒã溶解ããïŒ
ïŒ NaOH氎溶液237mlãå ãã40åéãããŸãã
ç¶ããŠéçž®ååå¿ãå®çµããããã
ãšããŒã«3.15ïœïŒ0.021ã¢ã«ïŒãšãããã°ã«ã·ã³
0.63ïœïŒ0.005ã¢ã«ïŒã溶解ãã10ïŒ NaOH氎溶
液ïŒmlãå ããïŒåéãããŸããã®ã¡ããªãšãã«
ã¢ãã³0.23ïœïŒ0.0023ã¢ã«ïŒãå ãã10åéãã
ãŸããŠãããã°ã«ã·ã³ãåå¿ãããããç¶ãåŸã
ãã¹ããšããŒã«A22.8ïœïŒ0.1ã¢ã«ïŒã溶解ããïŒ
ïŒ NaOH氎溶液237mlãå ãã40åéãããŸãã
ç¶ããŠéçž®ååå¿ãå®çµããããã
åå¿çµäºåŸã®æªåå¿ã¯ããã°ã«ã·ã³ã®éã¯0.03
ïœã§ãã€ããåå¿æ··å液ããå¡©åã¡ãã¬ã³çžãå
é¢ãã粟補æ§ã®è©äŸ¡æ¹æ³ã«åŸã€ãŠæ°ŽæŽç²Ÿè£œãããš
ãããæ°ŽæŽã¯ïŒåãèŠããããã®ç²Ÿè£œåŸãå¡©åã¡
ãã¬ã³ãèžçºããŠããªããŒãååãããçæããª
ããŒã®çžå¯Ÿç²åºŠã¯1.444ã§ããããã®æ§é ç²æ§æ
æ°ïŒ®ã¯1.72ã§ãã€ãã
ïœã§ãã€ããåå¿æ··å液ããå¡©åã¡ãã¬ã³çžãå
é¢ãã粟補æ§ã®è©äŸ¡æ¹æ³ã«åŸã€ãŠæ°ŽæŽç²Ÿè£œãããš
ãããæ°ŽæŽã¯ïŒåãèŠããããã®ç²Ÿè£œåŸãå¡©åã¡
ãã¬ã³ãèžçºããŠããªããŒãååãããçæããª
ããŒã®çžå¯Ÿç²åºŠã¯1.444ã§ããããã®æ§é ç²æ§æ
æ°ïŒ®ã¯1.72ã§ãã€ãã
å®æœäŸ ïŒ
ãã¹ã²ã³å¹èŸŒç®¡ïŒæž©åºŠèšåã³ãããŸãæ©ããšã
ã€ããïŒã®äžãå£ãã©ã¹ã³ã«ããã¹ããšããŒã«
A114ïœïŒ0.5ã¢ã«ïŒã溶解ãã12.3ïŒ NaOH氎溶
液394mlãšå¡©åã¡ãã¬ã³378mlãå ¥ãããããŸããª
ãã20ã25âã§ãã¹ã²ã³69.3ïœïŒ0.7ã¢ã«ïŒãçŽ
40åãèŠããŠå°å ¥ãããªãªãŽããŒãçæããã
ããåå¿æ··å液äžã®æªåå¿ãã¹ããšããŒã«ïŒ¡ã¯
4.05ïœïŒ0.0178ã¢ã«ïŒã§ãããçæãªãªãŽããŒã®
çžå¯Ÿç²åºŠã¯1.098ã§ãã€ãããã®ãªãªãŽããŒåå¿
æ··å液ã«ããšããŒã«1.97ïœïŒ0.021ã¢ã«ïŒãšãã
ãã°ã«ã·ã³0.91ïœïŒ0.0072ã¢ã«ïŒã溶解ãã10ïŒ
NaOH氎溶液ïŒmlãå ããïŒåéãããŸããã®
ã¡ããªãšãã«ã¢ãã³0.23ïœïŒ0.0023ã¢ã«ïŒãå
ãã10åéãããŸããŠãããã°ã«ã·ã³ãåå¿ãã
ãããç¶ãåŸããã¹ããšããŒã«A22.8ïœïŒ0.1ã¢
ã«ïŒã溶解ããïŒïŒ NaOH氎溶液237mlãå ãã
çŽ40åéãããŸããç¶ããŠéçž®ååå¿ãå®çµãã
ããã
ã€ããïŒã®äžãå£ãã©ã¹ã³ã«ããã¹ããšããŒã«
A114ïœïŒ0.5ã¢ã«ïŒã溶解ãã12.3ïŒ NaOH氎溶
液394mlãšå¡©åã¡ãã¬ã³378mlãå ¥ãããããŸããª
ãã20ã25âã§ãã¹ã²ã³69.3ïœïŒ0.7ã¢ã«ïŒãçŽ
40åãèŠããŠå°å ¥ãããªãªãŽããŒãçæããã
ããåå¿æ··å液äžã®æªåå¿ãã¹ããšããŒã«ïŒ¡ã¯
4.05ïœïŒ0.0178ã¢ã«ïŒã§ãããçæãªãªãŽããŒã®
çžå¯Ÿç²åºŠã¯1.098ã§ãã€ãããã®ãªãªãŽããŒåå¿
æ··å液ã«ããšããŒã«1.97ïœïŒ0.021ã¢ã«ïŒãšãã
ãã°ã«ã·ã³0.91ïœïŒ0.0072ã¢ã«ïŒã溶解ãã10ïŒ
NaOH氎溶液ïŒmlãå ããïŒåéãããŸããã®
ã¡ããªãšãã«ã¢ãã³0.23ïœïŒ0.0023ã¢ã«ïŒãå
ãã10åéãããŸããŠãããã°ã«ã·ã³ãåå¿ãã
ãããç¶ãåŸããã¹ããšããŒã«A22.8ïœïŒ0.1ã¢
ã«ïŒã溶解ããïŒïŒ NaOH氎溶液237mlãå ãã
çŽ40åéãããŸããç¶ããŠéçž®ååå¿ãå®çµãã
ããã
åå¿çµäºåŸã®æªåå¿ãããã°ã«ã·ã³ã®éã¯0.02
ïœã§ãã€ããåå¿æ··å液ããå¡©åã¡ãã¬ã³çžãå
é¢ãã粟補æ§ã®è©äŸ¡æ¹æ³ã«åŸã€ãŠæ°ŽæŽç²Ÿè£œãããš
ãããæ°ŽæŽã¯ïŒåãèŠãããçæããªããŒã®çžå¯Ÿ
ç²åºŠã¯1.526ã§ããããã®æ§é ç²æ§ææ°ïŒ®ã¯2.04
ã§ãã€ãã
ïœã§ãã€ããåå¿æ··å液ããå¡©åã¡ãã¬ã³çžãå
é¢ãã粟補æ§ã®è©äŸ¡æ¹æ³ã«åŸã€ãŠæ°ŽæŽç²Ÿè£œãããš
ãããæ°ŽæŽã¯ïŒåãèŠãããçæããªããŒã®çžå¯Ÿ
ç²åºŠã¯1.526ã§ããããã®æ§é ç²æ§ææ°ïŒ®ã¯2.04
ã§ãã€ãã
å®æœäŸ ïŒ
ãã¹ã²ã³å¹èŸŒç®¡ïŒæž©åºŠèšåã³ãããŸãæ©ããšã
ã€ããïŒäžãå£ãã©ã¹ã³ã«ããã¹ããšããŒã«
A114ïœïŒ0.5ã¢ã«ïŒã溶解ãã8.6ïŒ NaOH氎溶液
603mlãšå¡©åã¡ãã¬ã³378mlãå ¥ãããããŸããªã
ã20ã25âã§ãã¹ã²ã³56.3ïœïŒ0.57ã¢ã«ïŒãçŽ40
åãèŠããŠå°å ¥ãããªãªãŽããŒãçæããããã
åå¿æ··å液äžã®æªåå¿ãã¹ããšããŒã«ïŒ¡ã¯12.8ïœ
ïŒ0.0561ã¢ã«ïŒã§ãããçæãªãªãŽããŒã®çžå¯Ÿç²
床ã¯1.105ã§ãã€ãã
ã€ããïŒäžãå£ãã©ã¹ã³ã«ããã¹ããšããŒã«
A114ïœïŒ0.5ã¢ã«ïŒã溶解ãã8.6ïŒ NaOH氎溶液
603mlãšå¡©åã¡ãã¬ã³378mlãå ¥ãããããŸããªã
ã20ã25âã§ãã¹ã²ã³56.3ïœïŒ0.57ã¢ã«ïŒãçŽ40
åãèŠããŠå°å ¥ãããªãªãŽããŒãçæããããã
åå¿æ··å液äžã®æªåå¿ãã¹ããšããŒã«ïŒ¡ã¯12.8ïœ
ïŒ0.0561ã¢ã«ïŒã§ãããçæãªãªãŽããŒã®çžå¯Ÿç²
床ã¯1.105ã§ãã€ãã
ãã®ãªãªãŽããŒåå¿æ··å液ããæ°Žçž422mlãå
é¢ããæ®ãã®åå¿æ··å液ïŒãã¹ããšããŒã«A3.83
ïœïŒ0.0168ã¢ã«ïŒå«æïŒã«ïœâïœâããã«ããšã
ãŒã«3.38ïœïŒ0.0225ã¢ã«ïŒãšãããã°ã«ã·ã³0.76
ïœïŒ0.006ã¢ã«ïŒã溶解ãã10ïŒ NaOH氎溶液ïŒ
mlãå ããïŒåéãããŸããã®ã¡ããªãšãã«ã¢ã
ã³0.19ïœïŒ0.0019ã¢ã«ïŒãå ãã10åéãããŸã
ãŠãããã°ã«ã·ã³ãåå¿ãããããç¶ãåŸãäžèš
ã®åé¢ããæ°Žçž422mlãå ãã40åéãããŸãã
ç¶ããŠéçž®ååå¿ãå®çµããããã
é¢ããæ®ãã®åå¿æ··å液ïŒãã¹ããšããŒã«A3.83
ïœïŒ0.0168ã¢ã«ïŒå«æïŒã«ïœâïœâããã«ããšã
ãŒã«3.38ïœïŒ0.0225ã¢ã«ïŒãšãããã°ã«ã·ã³0.76
ïœïŒ0.006ã¢ã«ïŒã溶解ãã10ïŒ NaOH氎溶液ïŒ
mlãå ããïŒåéãããŸããã®ã¡ããªãšãã«ã¢ã
ã³0.19ïœïŒ0.0019ã¢ã«ïŒãå ãã10åéãããŸã
ãŠãããã°ã«ã·ã³ãåå¿ãããããç¶ãåŸãäžèš
ã®åé¢ããæ°Žçž422mlãå ãã40åéãããŸãã
ç¶ããŠéçž®ååå¿ãå®çµããããã
åå¿çµäºåŸã®æªåå¿ãããã°ã«ã·ã³ã®éã¯0.01
ïœã§ãã€ããåå¿æ··å液ããå¡©åã¡ãã¬ã³çžãå
é¢ãã粟補æ§ã®è©äŸ¡æ¹æ³ã«åŸã€ãŠæ°ŽæŽç²Ÿè£œãããš
ãããæ°ŽæŽã¯ïŒåãèŠãããçæããªããŒã®çžå¯Ÿ
ç²åºŠã¯1.556ã§ããããã®æ§é ç²æ§ææ°ïŒ®ã¯2.51
ã§ãã€ãã
ïœã§ãã€ããåå¿æ··å液ããå¡©åã¡ãã¬ã³çžãå
é¢ãã粟補æ§ã®è©äŸ¡æ¹æ³ã«åŸã€ãŠæ°ŽæŽç²Ÿè£œãããš
ãããæ°ŽæŽã¯ïŒåãèŠãããçæããªããŒã®çžå¯Ÿ
ç²åºŠã¯1.556ã§ããããã®æ§é ç²æ§ææ°ïŒ®ã¯2.51
ã§ãã€ãã
å®æœäŸ ïŒ
ãã¹ã²ã³å¹èŸŒç®¡ïŒæž©åºŠèšåã³ãããŸãæ©ããšã
ã€ããïŒäžãå£ãã©ã¹ã³ã«ããã¹ããšããŒã«
A114ïœïŒ0.5ã¢ã«ïŒã溶解ãã8.6ïŒ NaOH氎溶液
603mlãšå¡©åã¡ãã¬ã³378mlãå ¥ãããããŸããªã
ã20ã25âã§ãã¹ã²ã³56.3ïœïŒ0.57ã¢ã«ïŒãçŽ40
åãèŠããŠå°å ¥ãããªãªãŽããŒãçæããããã
åå¿æ··å液äžã®æªåå¿ãã¹ããšããŒã«ïŒ¡ã¯13.3ïœ
ïŒ0.0583ã¢ã«ïŒã§ãããçæãªãªãŽããŒã®çžå¯Ÿç²
床ã¯1.103ã§ãã€ãã
ã€ããïŒäžãå£ãã©ã¹ã³ã«ããã¹ããšããŒã«
A114ïœïŒ0.5ã¢ã«ïŒã溶解ãã8.6ïŒ NaOH氎溶液
603mlãšå¡©åã¡ãã¬ã³378mlãå ¥ãããããŸããªã
ã20ã25âã§ãã¹ã²ã³56.3ïœïŒ0.57ã¢ã«ïŒãçŽ40
åãèŠããŠå°å ¥ãããªãªãŽããŒãçæããããã
åå¿æ··å液äžã®æªåå¿ãã¹ããšããŒã«ïŒ¡ã¯13.3ïœ
ïŒ0.0583ã¢ã«ïŒã§ãããçæãªãªãŽããŒã®çžå¯Ÿç²
床ã¯1.103ã§ãã€ãã
ãã®ãªãªãŽããŒåå¿æ··å液ããæ°Žçž422mlãå
é¢ããæ®ãã®åå¿æ··å液ïŒãã¹ããšããŒã«A3.98
ïœïŒ0.0175ã¢ã«ïŒå«æïŒã«ïœâïœâããã«ããšã
ãŒã«3.38ïœïŒ0.0235ã¢ã«ïŒãšãããã°ã«ã·ã0.35
ïœïŒ0.0015ã¢ã«ïŒã溶解ãã10ïŒ NaOH氎溶液ïŒ
mlãå ããïŒåéãããŸããã®ã¡ããªãšãã«ã¢ã
ã³0.15ïœïŒ0.0015ã¢ã«ïŒãå ãã10åéãããŸã
ãŠãããã°ã«ã·ããåå¿ãããããç¶ãåŸãäžèš
ã®åé¢ããæ°Žçž422mlãå ãã40åéãããŸãã
ç¶ããŠéçž®ååå¿ãå®çµããããã
é¢ããæ®ãã®åå¿æ··å液ïŒãã¹ããšããŒã«A3.98
ïœïŒ0.0175ã¢ã«ïŒå«æïŒã«ïœâïœâããã«ããšã
ãŒã«3.38ïœïŒ0.0235ã¢ã«ïŒãšãããã°ã«ã·ã0.35
ïœïŒ0.0015ã¢ã«ïŒã溶解ãã10ïŒ NaOH氎溶液ïŒ
mlãå ããïŒåéãããŸããã®ã¡ããªãšãã«ã¢ã
ã³0.15ïœïŒ0.0015ã¢ã«ïŒãå ãã10åéãããŸã
ãŠãããã°ã«ã·ããåå¿ãããããç¶ãåŸãäžèš
ã®åé¢ããæ°Žçž422mlãå ãã40åéãããŸãã
ç¶ããŠéçž®ååå¿ãå®çµããããã
åå¿çµäºåŸã®æªåå¿ãããã°ã«ã·ãã®éã¯0.01
ïœã§ãã€ããåå¿æ··å液ããå¡©åã¡ãã¬ã³çžãå
é¢ãã粟補æ§ã®è©äŸ¡æ¹æ³ã«åŸã€ãŠæ°ŽæŽç²Ÿè£œãããš
ãããæ°ŽæŽã¯ïŒåãèŠãããçæããªããŒã®çžå¯Ÿ
ç²åºŠã¯1.388ã§ããããã®æ§é ç²æ§ææ°ïŒ®ã¯1.71
ã§ãã€ãã
ïœã§ãã€ããåå¿æ··å液ããå¡©åã¡ãã¬ã³çžãå
é¢ãã粟補æ§ã®è©äŸ¡æ¹æ³ã«åŸã€ãŠæ°ŽæŽç²Ÿè£œãããš
ãããæ°ŽæŽã¯ïŒåãèŠãããçæããªããŒã®çžå¯Ÿ
ç²åºŠã¯1.388ã§ããããã®æ§é ç²æ§ææ°ïŒ®ã¯1.71
ã§ãã€ãã
å®æœäŸ ïŒ
ãã¹ã²ã³å¹èŸŒç®¡ïŒæž©åºŠèšåã³ãããŸãæ©ããšã
ã€ããïŒäžãå£ãã©ã¹ã³ã«ããã¹ããšããŒã«
A114ïœïŒ0.5ã¢ã«ïŒã溶解ãã12.3ïŒ NaOH氎溶
液394mlãšå¡©åã¡ãã¬ã³378mlãå ¥ãããããŸããª
ãã20ã25âã§ãã¹ã²ã³56.3ïœïŒ0.57ã¢ã«ïŒãçŽ
40åãèŠããŠå°å ¥ãããªãªãŽããŒãçæããã
ããåå¿æ··å液äžã®æªåå¿ãã¹ããšããŒã«ïŒ¡ã¯
4.27ïœïŒ0.0187ã¢ã«ïŒã§ãããçæãªãªãŽããŒã®
çžå¯Ÿç²åºŠã¯1.093ã§ãã€ãã
ã€ããïŒäžãå£ãã©ã¹ã³ã«ããã¹ããšããŒã«
A114ïœïŒ0.5ã¢ã«ïŒã溶解ãã12.3ïŒ NaOH氎溶
液394mlãšå¡©åã¡ãã¬ã³378mlãå ¥ãããããŸããª
ãã20ã25âã§ãã¹ã²ã³56.3ïœïŒ0.57ã¢ã«ïŒãçŽ
40åãèŠããŠå°å ¥ãããªãªãŽããŒãçæããã
ããåå¿æ··å液äžã®æªåå¿ãã¹ããšããŒã«ïŒ¡ã¯
4.27ïœïŒ0.0187ã¢ã«ïŒã§ãããçæãªãªãŽããŒã®
çžå¯Ÿç²åºŠã¯1.093ã§ãã€ãã
ãã®ãªãªãŽããŒåå¿æ··å液ã«ããšããŒã«1.97ïœ
ïŒ0.021ã¢ã«ïŒãšãã¹âïŒïŒïŒïŒâãžããããã·ã
ãšãã«ïŒã±ãã³0.89ïœïŒ0.0036ã¢ã«ïŒã溶解ãã
10ïŒ NaOH氎溶液ïŒmlãå ããïŒåéãããŸã
ãã®ã¡ããªãšãã«ã¢ãã³0.23ïœïŒ0.0023ã¢ã«ïŒã
å ãã10åéãããŸããŠãã¹ïŒïŒïŒïŒâãžããã
ãã·ããšãã«ïŒã±ãã³ãåå¿ãããããç¶ãåŸã
ãã¹ããšããŒã«A22.8ïœïŒ0.1ã¢ã«ïŒã溶解ããïŒ
ïŒ NaOH氎溶液237mlãå ããçŽ40åéãããŸã
ãç¶ããŠéçž®ååå¿ãå®çµããããã
ïŒ0.021ã¢ã«ïŒãšãã¹âïŒïŒïŒïŒâãžããããã·ã
ãšãã«ïŒã±ãã³0.89ïœïŒ0.0036ã¢ã«ïŒã溶解ãã
10ïŒ NaOH氎溶液ïŒmlãå ããïŒåéãããŸã
ãã®ã¡ããªãšãã«ã¢ãã³0.23ïœïŒ0.0023ã¢ã«ïŒã
å ãã10åéãããŸããŠãã¹ïŒïŒïŒïŒâãžããã
ãã·ããšãã«ïŒã±ãã³ãåå¿ãããããç¶ãåŸã
ãã¹ããšããŒã«A22.8ïœïŒ0.1ã¢ã«ïŒã溶解ããïŒ
ïŒ NaOH氎溶液237mlãå ããçŽ40åéãããŸã
ãç¶ããŠéçž®ååå¿ãå®çµããããã
åå¿çµäºåŸã®æªåå¿ãã¹ïŒïŒïŒïŒâãžãããã
ã·ããšãã«ïŒã±ãã³ã¯0.03ïœã§ãã€ããåå¿æ··å
液ããå¡©åã¡ãã¬ã³çžãåé¢ãã粟補æ§ã®è©äŸ¡æ¹
æ³ã«åŸã€ãŠæ°ŽæŽç²Ÿè£œãããšãããæ°ŽæŽåæ°ã¯ïŒå
ãèŠãããçæããªããŒã®çžå¯Ÿç²åºŠã¯1.452ã§ã
ãããã®æ§é ç²æ§ææ°ïŒ®ã¯2.10ã§ãã€ãã
ã·ããšãã«ïŒã±ãã³ã¯0.03ïœã§ãã€ããåå¿æ··å
液ããå¡©åã¡ãã¬ã³çžãåé¢ãã粟補æ§ã®è©äŸ¡æ¹
æ³ã«åŸã€ãŠæ°ŽæŽç²Ÿè£œãããšãããæ°ŽæŽåæ°ã¯ïŒå
ãèŠãããçæããªããŒã®çžå¯Ÿç²åºŠã¯1.452ã§ã
ãããã®æ§é ç²æ§ææ°ïŒ®ã¯2.10ã§ãã€ãã
æ¯èŒäŸ ïŒ
ãã¹ã²ã³å¹èŸŒç®¡ïŒæž©åºŠèšåã³ãããŸãæ©ããšã
ã€ããïŒäžãå£ãã©ã¹ã³ã«ããã¹ããšããŒã«
A114ïœïŒ0.5ã¢ã«ïŒã溶解ãã12.3ïŒ NaOH氎溶
液394mlãšå¡©åã¡ãã¬ã³378mlãå ãããããŸããª
ãã20ã25âã§ãã¹ã²ã³69.3ïœïŒ0.7ã¢ã«ïŒãçŽ
40åãèŠããŠå°å ¥ãããªãªãŽããŒãçæããã
ããåå¿æ··å液äžã®æªåå¿ãã¹ããšããŒã«ïŒ¡ã¯
4.25ïœïŒ0.0186ã¢ã«ïŒã§ãããçæãªãªãŽããŒã®
çžå¯Ÿç²åºŠã¯1.093ã§ãã€ãã
ã€ããïŒäžãå£ãã©ã¹ã³ã«ããã¹ããšããŒã«
A114ïœïŒ0.5ã¢ã«ïŒã溶解ãã12.3ïŒ NaOH氎溶
液394mlãšå¡©åã¡ãã¬ã³378mlãå ãããããŸããª
ãã20ã25âã§ãã¹ã²ã³69.3ïœïŒ0.7ã¢ã«ïŒãçŽ
40åãèŠããŠå°å ¥ãããªãªãŽããŒãçæããã
ããåå¿æ··å液äžã®æªåå¿ãã¹ããšããŒã«ïŒ¡ã¯
4.25ïœïŒ0.0186ã¢ã«ïŒã§ãããçæãªãªãŽããŒã®
çžå¯Ÿç²åºŠã¯1.093ã§ãã€ãã
ãã®ãªãªãŽããŒæ··å液ã«ïœâïœâããã«ããšã
ãŒã«4.05ïœïŒ0.0178ã¢ã«ïŒãå ããïŒåéãããŸ
ããã®ã¡ããªãšãã«ã¢ãã³0.23ïœïŒ0.0023ã¢ã«ïŒ
ãå ãã10åéãããŸããŠåå¿ãããããç¶ã
åŸããã¹ããšããŒã«A22.8ïœïŒ0.1ã¢ã«ïŒã溶解ã
ãïŒïŒ NaOH氎溶液237mlãå ãã40åéãããŸ
ããç¶ããŠéçž®ååå¿ãå®çµããããã
ãŒã«4.05ïœïŒ0.0178ã¢ã«ïŒãå ããïŒåéãããŸ
ããã®ã¡ããªãšãã«ã¢ãã³0.23ïœïŒ0.0023ã¢ã«ïŒ
ãå ãã10åéãããŸããŠåå¿ãããããç¶ã
åŸããã¹ããšããŒã«A22.8ïœïŒ0.1ã¢ã«ïŒã溶解ã
ãïŒïŒ NaOH氎溶液237mlãå ãã40åéãããŸ
ããç¶ããŠéçž®ååå¿ãå®çµããããã
åå¿æ··å液ããå¡©åã¡ãã¬ã³çžãåé¢ãã粟補
æ§ã®è©äŸ¡æ¹æ³ã«åŸã€ãŠæ°ŽæŽç²Ÿè£œãããšãããæ°ŽæŽ
åæ°ã¯ïŒåãèŠãããçæããªããŒã®çžå¯Ÿç²åºŠã¯
1.374ã§ããããã®æ§é ç²æ§ææ°ïŒ®ã¯1.27ã§ãã€
ãã
æ§ã®è©äŸ¡æ¹æ³ã«åŸã€ãŠæ°ŽæŽç²Ÿè£œãããšãããæ°ŽæŽ
åæ°ã¯ïŒåãèŠãããçæããªããŒã®çžå¯Ÿç²åºŠã¯
1.374ã§ããããã®æ§é ç²æ§ææ°ïŒ®ã¯1.27ã§ãã€
ãã
æ¯èŒäŸ ïŒ
ãã¹ã²ã³å¹èŸŒç®¡ïŒæž©åºŠèšåã³ãããŸãæ©ããšã
ã€ããïŒäžãå£ãã©ã¹ã³ã«ããã¹ããšããŒã«
A114ïœïŒ0.5ã¢ã«ïŒãšãããã°ã«ã·ã³0.76ïœ
ïŒ0.006ã¢ã«ïŒã溶解ãã8.6ïŒ NaOH氎溶液611ml
ãšïœâïœâããã«ããšããŒã«3.38ïœïŒ0.0225ã¢
ã«ïŒã溶解ããå¡©åã¡ãã¬ã³378mlãå ¥ãããã
ãŸããªãã20ã25âã§ãã¹ã²ã³56.3ïœïŒ0.57ã¢
ã«ïŒãçŽ40åãèŠãå°å ¥ããã®ã¡ãããªãšãã«ã¢
ãã³0.19ïœïŒ0.0019ã¢ã«ïŒãå ãã50åéãããŸ
ããç¶ãåå¿ããããã
ã€ããïŒäžãå£ãã©ã¹ã³ã«ããã¹ããšããŒã«
A114ïœïŒ0.5ã¢ã«ïŒãšãããã°ã«ã·ã³0.76ïœ
ïŒ0.006ã¢ã«ïŒã溶解ãã8.6ïŒ NaOH氎溶液611ml
ãšïœâïœâããã«ããšããŒã«3.38ïœïŒ0.0225ã¢
ã«ïŒã溶解ããå¡©åã¡ãã¬ã³378mlãå ¥ãããã
ãŸããªãã20ã25âã§ãã¹ã²ã³56.3ïœïŒ0.57ã¢
ã«ïŒãçŽ40åãèŠãå°å ¥ããã®ã¡ãããªãšãã«ã¢
ãã³0.19ïœïŒ0.0019ã¢ã«ïŒãå ãã50åéãããŸ
ããç¶ãåå¿ããããã
åå¿çµäºåŸã®æªåå¿ãããã°ã«ã·ã³ã®éã¯0.75
ã§ããããããã°ã«ã·ã³ã¯ã»ãšãã©åå¿ããŠããª
ãã€ããåå¿æ··å液ããå¡©åã¡ãã¬ã³çžãåé¢
ãã粟補æ§ã®è©äŸ¡æ¹æ³ã«åŸã€ãŠæ°ŽæŽãããšããã
æ°ŽæŽã¯ïŒåãèŠãããçæããªããŒã®çžå¯Ÿç²åºŠã¯
1.419ã§ããããã®æ§é ç²æ§ææ°ïŒ®ã¯1.30ã§ãã€
ãã
ã§ããããããã°ã«ã·ã³ã¯ã»ãšãã©åå¿ããŠããª
ãã€ããåå¿æ··å液ããå¡©åã¡ãã¬ã³çžãåé¢
ãã粟補æ§ã®è©äŸ¡æ¹æ³ã«åŸã€ãŠæ°ŽæŽãããšããã
æ°ŽæŽã¯ïŒåãèŠãããçæããªããŒã®çžå¯Ÿç²åºŠã¯
1.419ã§ããããã®æ§é ç²æ§ææ°ïŒ®ã¯1.30ã§ãã€
ãã
æ¯èŒäŸ ïŒ
ãã¹ã²ã³å¹èŸŒç®¡ïŒæž©åºŠèšåã³ãããŸãæ©ããšã
ã€ããïŒäžãå£ãã©ã¹ã³ã«ããã¹ããšããŒã«
A114ïœïŒ0.5ã¢ã«ïŒã溶解ãã8.6ïŒ NaOH氎溶液
603mlãšå¡©åã¡ãã¬ã³378mlãšãå ¥ãããããŸããª
ãã20ã25âã§ãã¹ã²ã³56.3ïœïŒ0.57ã¢ã«ïŒãçŽ
40åãèŠããŠå°å ¥ãããªãªãŽããŒãçæããã
ããåå¿æ··å液äžã®æªåå¿ãã¹ããšããŒã«ïŒ¡ã¯
12.5ïœïŒ0.0548ã¢ã«ïŒã§ãããçæãªãªãŽããŒã®
çžå¯Ÿç²åºŠã¯1.112ã§ãã€ãã
ã€ããïŒäžãå£ãã©ã¹ã³ã«ããã¹ããšããŒã«
A114ïœïŒ0.5ã¢ã«ïŒã溶解ãã8.6ïŒ NaOH氎溶液
603mlãšå¡©åã¡ãã¬ã³378mlãšãå ¥ãããããŸããª
ãã20ã25âã§ãã¹ã²ã³56.3ïœïŒ0.57ã¢ã«ïŒãçŽ
40åãèŠããŠå°å ¥ãããªãªãŽããŒãçæããã
ããåå¿æ··å液äžã®æªåå¿ãã¹ããšããŒã«ïŒ¡ã¯
12.5ïœïŒ0.0548ã¢ã«ïŒã§ãããçæãªãªãŽããŒã®
çžå¯Ÿç²åºŠã¯1.112ã§ãã€ãã
ãã®ãªãªãŽããŒåå¿æ··å液ããæ°Žçž422mlãå
é¢ããæ®ãã®åå¿æ··å液ïŒãã¹ããšããŒã«A3.73
ïœïŒ0.016ã¢ã«ïŒå«æïŒã«ïœâïœâããã«ããšã
ãŒã«3.38ïœïŒ0.0225ã¢ã«ïŒãšãããã°ã«ã·ã³1.58
ïœïŒ0.0125ã¢ã«ïŒã溶解ãã10ïŒ NaOH氎溶液15
mlãå ããïŒåéãããŸããã®ã¡ããªãšãã«ã¢ã
ã³0.19ïœïŒ0.0019ã¢ã«ïŒãå ãã10åéãããŸã
ãŠãããã°ã«ã·ã³ãåå¿ãããããç¶ãåŸãäžèš
ã®åé¢ããæ°Žçž422mlãå ãããããŸãããšåå¿
éäžã§å¡©åã¡ãã¬ã³ã«äžæº¶ã®ã²ã«ç¶ç©ãçããã
é¢ããæ®ãã®åå¿æ··å液ïŒãã¹ããšããŒã«A3.73
ïœïŒ0.016ã¢ã«ïŒå«æïŒã«ïœâïœâããã«ããšã
ãŒã«3.38ïœïŒ0.0225ã¢ã«ïŒãšãããã°ã«ã·ã³1.58
ïœïŒ0.0125ã¢ã«ïŒã溶解ãã10ïŒ NaOH氎溶液15
mlãå ããïŒåéãããŸããã®ã¡ããªãšãã«ã¢ã
ã³0.19ïœïŒ0.0019ã¢ã«ïŒãå ãã10åéãããŸã
ãŠãããã°ã«ã·ã³ãåå¿ãããããç¶ãåŸãäžèš
ã®åé¢ããæ°Žçž422mlãå ãããããŸãããšåå¿
éäžã§å¡©åã¡ãã¬ã³ã«äžæº¶ã®ã²ã«ç¶ç©ãçããã
æ¯èŒäŸ ïŒ
ãã¹ã²ã³å¹èŸŒç®¡ïŒæž©åºŠèšåã³ãããŸãæ©ããšã
ã€ããïŒäžãå£ãã©ã¹ã³ã«ããã¹ããšããŒã«
A114ïœïŒ0.5ã¢ã«ïŒã溶解ãã8.6ïŒ NaOH氎溶液
603mlãšå¡©åã¡ãã¬ã³378mlãšãå ¥ãããããŸããª
ãã20ã25âã§ãã¹ã²ã³56.3ïœïŒ0.57ã¢ã«ïŒãçŽ
40åãèŠããŠå°å ¥ãããªãªãŽããŒãçæããã
ããåå¿æ··å液äžã®æªåå¿ãã¹ããšããŒã«ïŒ¡ã¯
12.6ïœïŒ0.0551ã¢ã«ïŒã§ãããçæãªãªãŽããŒã®
çžå¯Ÿç²åºŠã¯1.108ã§ãã€ãã
ã€ããïŒäžãå£ãã©ã¹ã³ã«ããã¹ããšããŒã«
A114ïœïŒ0.5ã¢ã«ïŒã溶解ãã8.6ïŒ NaOH氎溶液
603mlãšå¡©åã¡ãã¬ã³378mlãšãå ¥ãããããŸããª
ãã20ã25âã§ãã¹ã²ã³56.3ïœïŒ0.57ã¢ã«ïŒãçŽ
40åãèŠããŠå°å ¥ãããªãªãŽããŒãçæããã
ããåå¿æ··å液äžã®æªåå¿ãã¹ããšããŒã«ïŒ¡ã¯
12.6ïœïŒ0.0551ã¢ã«ïŒã§ãããçæãªãªãŽããŒã®
çžå¯Ÿç²åºŠã¯1.108ã§ãã€ãã
ãã®ãªãªãŽããŒåå¿æ··å液ããæ°Žçž422mlãå
é¢ããæ®ãã®åå¿æ··å液ïŒãã¹ããšããŒã«A3.76
ïœïŒ0.016ã¢ã«ïŒå«æïŒã«ïœâïœâããã«ããšã
ãŒã«3.38ïœïŒ0.0225ã¢ã«ïŒãšãããã°ã«ã·ã³0.76
ïœïŒ0.006ã¢ã«ïŒã溶解ãã10ïŒ NaOH氎溶液ïŒ
mlãšãã¹ããšããŒã«A9.94ïœïŒ0.0435ã¢ã«ïŒã溶
解ãã10ïŒ NaOH氎溶液34.8mlãšãå ããïŒåé
ãããŸããã®ã¡ããªãšãã«ã¢ãã³0.19ïœïŒ0.0019
ã¢ã«ïŒãå ãã10åéãããŸãããç¶ãåŸãäžèš
ã®åé¢ããæ°Žçž422mlãå ããçŽ40åéãããŸã
ãç¶ããŠéçž®ååå¿ãå®çµããããã
é¢ããæ®ãã®åå¿æ··å液ïŒãã¹ããšããŒã«A3.76
ïœïŒ0.016ã¢ã«ïŒå«æïŒã«ïœâïœâããã«ããšã
ãŒã«3.38ïœïŒ0.0225ã¢ã«ïŒãšãããã°ã«ã·ã³0.76
ïœïŒ0.006ã¢ã«ïŒã溶解ãã10ïŒ NaOH氎溶液ïŒ
mlãšãã¹ããšããŒã«A9.94ïœïŒ0.0435ã¢ã«ïŒã溶
解ãã10ïŒ NaOH氎溶液34.8mlãšãå ããïŒåé
ãããŸããã®ã¡ããªãšãã«ã¢ãã³0.19ïœïŒ0.0019
ã¢ã«ïŒãå ãã10åéãããŸãããç¶ãåŸãäžèš
ã®åé¢ããæ°Žçž422mlãå ããçŽ40åéãããŸã
ãç¶ããŠéçž®ååå¿ãå®çµããããã
åå¿çµäºåŸã®æªåå¿ãããã°ã«ã·ã³ã®éã¯0.74
ïœã§ãã€ããåå¿æ··å液ããå¡©åã¡ãã¬ã³çžãå
é¢ãã粟補è©äŸ¡æ¹æ³ã«åŸã€ãŠæ°ŽæŽç²Ÿè£œãããšãã
æ°ŽæŽã¯ïŒåãèŠãããçæããªããŒã®çžå¯Ÿç²åºŠã¯
1.378ïŒæ§é ç²æ§ææ°ïŒ®ã¯1.28ã§ãã€ãã
ïœã§ãã€ããåå¿æ··å液ããå¡©åã¡ãã¬ã³çžãå
é¢ãã粟補è©äŸ¡æ¹æ³ã«åŸã€ãŠæ°ŽæŽç²Ÿè£œãããšãã
æ°ŽæŽã¯ïŒåãèŠãããçæããªããŒã®çžå¯Ÿç²åºŠã¯
1.378ïŒæ§é ç²æ§ææ°ïŒ®ã¯1.28ã§ãã€ãã
æ¯èŒäŸ ïŒ
ãã¹ã²ã³å¹èŸŒç®¡ïŒæž©åºŠèšåã³ãããŸãæ©ããšã
ã€ããïŒäžãå£ãã©ã¹ã³ã«ããã¹ããšããŒã«
A114ïœïŒ0.5ã¢ã«ïŒã溶解ãã12.3ïŒ NaOH氎溶
液394mlãšå¡©åã¡ãã¬ã³378mlãå ¥ãããããŸããª
ãã20ã25âã§ãã¹ã²ã³69.3ïœïŒ0.7ã¢ã«ïŒãçŽ
40åãèŠããŠå°å ¥ãããªãªãŽããŒãçæããã
ããåå¿æ··å液äžã®æªåå¿ãã¹ããšããŒã«ïŒ¡ã¯
4.02ïœïŒ0.0176ã¢ã«ïŒã§ãããçæãªãªãŽããŒã®
çžå¯Ÿç²åºŠã¯1.092ã§ãã€ãã
ã€ããïŒäžãå£ãã©ã¹ã³ã«ããã¹ããšããŒã«
A114ïœïŒ0.5ã¢ã«ïŒã溶解ãã12.3ïŒ NaOH氎溶
液394mlãšå¡©åã¡ãã¬ã³378mlãå ¥ãããããŸããª
ãã20ã25âã§ãã¹ã²ã³69.3ïœïŒ0.7ã¢ã«ïŒãçŽ
40åãèŠããŠå°å ¥ãããªãªãŽããŒãçæããã
ããåå¿æ··å液äžã®æªåå¿ãã¹ããšããŒã«ïŒ¡ã¯
4.02ïœïŒ0.0176ã¢ã«ïŒã§ãããçæãªãªãŽããŒã®
çžå¯Ÿç²åºŠã¯1.092ã§ãã€ãã
ãã®ãªãªãŽããŒæ··å液ã«ïœâïœâããã«ããšã
ãŒã«3.38ïœïŒ0.0225ã¢ã«ïŒãšãããã°ã«ã·ã³0.91
ïœïŒ0.0072ã«ïŒã溶解ãã10ïŒ NaOH氎溶液ïŒml
ãš1.8ïŒ NaOH氎溶液173mlãå ããïŒåéãããŸ
ããã®ã¡ãããªãšãã«ã¢ãã³0.23ïœïŒ0.0023ã¢
ã«ïŒãå ãã10åéãããŸãããç¶ãåŸããã¹ã
ãšããŒã«A22.8ïœïŒ0.1ã¢ã«ïŒã溶解ãã13ïŒ
NaOH氎溶液70mlãå ããçŽ40åéãããŸãã
ç¶ããŠéçž®ååå¿ãå®çµããããã
ãŒã«3.38ïœïŒ0.0225ã¢ã«ïŒãšãããã°ã«ã·ã³0.91
ïœïŒ0.0072ã«ïŒã溶解ãã10ïŒ NaOH氎溶液ïŒml
ãš1.8ïŒ NaOH氎溶液173mlãå ããïŒåéãããŸ
ããã®ã¡ãããªãšãã«ã¢ãã³0.23ïœïŒ0.0023ã¢
ã«ïŒãå ãã10åéãããŸãããç¶ãåŸããã¹ã
ãšããŒã«A22.8ïœïŒ0.1ã¢ã«ïŒã溶解ãã13ïŒ
NaOH氎溶液70mlãå ããçŽ40åéãããŸãã
ç¶ããŠéçž®ååå¿ãå®çµããããã
åå¿çµäºåŸã®æªåå¿ãããã°ã«ã·ã³ã®éã¯0.90
ïœã§ãã€ããåå¿æ··å液ããå¡©åã¡ãã¬ã³çžãå
é¢ãã粟補ã®è©äŸ¡æ¹æ³ã«åŸã€ãŠæ°ŽæŽç²Ÿè£œãããšã
ãæ°ŽæŽã¯ïŒåãèŠãããçæããªããŒã®çžå¯Ÿç²åºŠ
ã¯1.372ã§ããããã®æ§é ç²æ§ææ°ïŒ®ã¯1.29ã§ã
ã€ãã
ïœã§ãã€ããåå¿æ··å液ããå¡©åã¡ãã¬ã³çžãå
é¢ãã粟補ã®è©äŸ¡æ¹æ³ã«åŸã€ãŠæ°ŽæŽç²Ÿè£œãããšã
ãæ°ŽæŽã¯ïŒåãèŠãããçæããªããŒã®çžå¯Ÿç²åºŠ
ã¯1.372ã§ããããã®æ§é ç²æ§ææ°ïŒ®ã¯1.29ã§ã
ã€ãã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ ïŒäŸ¡ããšããŒã«ã®ã¢ã«ã«ãªæ°Žæº¶æ¶²ãšãã¹ã²ã³
ãšãææ©æº¶åªã®ååšäžã«åå¿ããããŠåŸãããäœ
ååéã®ç·ç¶ããªã«ãŒãããŒãã«ããŸãïŒäŸ¡ä»¥äž
ã®å€äŸ¡ããšããŒã«ãšïŒäŸ¡ããšããŒã«ãšãå ããŠå
å¿ããããã€ãã§ïŒäŸ¡ããšããŒã«ãå ããŠåå¿ã
ãããããšãããªããïŒäŸ¡ä»¥äžã®å€äŸ¡ããšããŒã«
ã®éãïŒäŸ¡ããšããŒã«ã®å šéã«åºããŠ0.1ã2.0ã¢
ã«ïŒ ãå ±åããïŒäŸ¡ããšããŒã«ãïŒäŸ¡ä»¥äžã®å€äŸ¡
ããšããŒã«ã®æ°Žé žåºïŒååœãïŒãïŒã¢ã«ããã³å
å¿æ··å液ãæ§æããææ©çžãšæ°Žçžã®äœç©æ¯ãïŒïŒ
0.1ãïŒïŒ1.3ã§ããããšãç¹åŸŽãšããåå²ããªã«
ãŒãããŒãã®è£œé æ¹æ³ã ïŒ ïŒäŸ¡ä»¥äžã®å€äŸ¡ããšããŒã«ããïŒå以äžã®æ°Ž
é žåºãæãããã³ãŒã³ç°ããã®ååæ§é å ã«å°ãª
ããšãïŒåæããïŒäŸ¡ä»¥äžã®å€äŸ¡ããšããŒã«ã§ã
ãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®åå²ããªã«ãŒãã
ãŒãã®è£œé æ¹æ³ã
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15680382A JPS5947228A (ja) | 1982-09-10 | 1982-09-10 | åå²ããªã«âããâãã®è£œé æ¹æ³ |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15680382A JPS5947228A (ja) | 1982-09-10 | 1982-09-10 | åå²ããªã«âããâãã®è£œé æ¹æ³ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5947228A JPS5947228A (ja) | 1984-03-16 |
| JPH0342288B2 true JPH0342288B2 (ja) | 1991-06-26 |
Family
ID=15635660
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15680382A Granted JPS5947228A (ja) | 1982-09-10 | 1982-09-10 | åå²ããªã«âããâãã®è£œé æ¹æ³ |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5947228A (ja) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2010297A6 (es) * | 1988-07-27 | 1989-11-01 | Cables Comunicaciones | Un procedimiento para la preparacion de nuevas copoliesteramidas termotropas aromaticas. |
| JPH0684429B2 (ja) * | 1988-09-06 | 1994-10-26 | åºå ç³æ²¹ååŠæ ªåŒäŒç€Ÿ | åå²ããªã«ãŒãããŒãåã³ãã®è£œé æ¹æ³ |
| JP2628562B2 (ja) * | 1989-08-03 | 1997-07-09 | åºå ç³æ²¹ååŠæ ªåŒäŒç€Ÿ | åå²ç¶ããªã«ãŒãããŒãåã³ãã®è£œé æ¹æ³ |
| JP2628563B2 (ja) * | 1989-08-03 | 1997-07-09 | åºå ç³æ²¹ååŠæ ªåŒäŒç€Ÿ | åå²ç¶ããªã«ãŒãããŒãåã³ãã®è£œé æ³ |
| CN1075083C (zh) * | 1995-02-03 | 2001-11-21 | åºå ç³æ²¹ååŠæ ªåŒäŒç€Ÿ | èç¢³é žé ¯çå¶å€æ¹æ³ |
| DE19943642A1 (de) * | 1999-09-13 | 2001-03-15 | Bayer Ag | BehÀlter |
| US8541537B2 (en) | 2009-10-07 | 2013-09-24 | Teijin Chemicals, Ltd. | Branched polycarbonate resin and process for producing the same |
-
1982
- 1982-09-10 JP JP15680382A patent/JPS5947228A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5947228A (ja) | 1984-03-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4153780A (en) | Process for the preparation of polycarbonate with weatherproof property | |
| JPS6051499B2 (ja) | ããªã«âããâãã¹ã¯ã©ããããã®é«å質ããªã«âããâãã®ååæ³ | |
| JP2659609B2 (ja) | ãã¹ã¯ãããã«ã¡ãŒãããã®èª¿ç¯ãããååéã®ããªã«ãŒãããŒãã®è£œé æ³ | |
| US4413103A (en) | Halogen-containing polycarbonate resin and process for producing same | |
| JP2724217B2 (ja) | ããªã«ãŒãããŒããªãªãŽããŒã®è£œé æ¹æ³ | |
| US4294953A (en) | Process for preparing a branched polycarbonate | |
| JPS5947228A (ja) | åå²ããªã«âããâãã®è£œé æ¹æ³ | |
| JPS6210541B2 (ja) | ||
| JPH0315658B2 (ja) | ||
| JPS5867720A (ja) | ïŒïŒïŒâ²âãžããããã·ãžããšãã«ã¹ã«ãã³ã«åºãããªã«âããâãã®åé¢æ³ | |
| JPH09208684A (ja) | é«æµåæ§ããªã«ãŒãããŒãæš¹èããã³ãã®è£œé æ¹æ³ | |
| JP2002037872A (ja) | ããªã«ãŒãããŒãæš¹èåæããã³ããªã«ãŒãããŒãæš¹èã®è£œé æ³ | |
| WO2001066616A1 (en) | Processes for producing raw polycarbonate resin material and producing polycarbonate resin | |
| JPH0564935B2 (ja) | ||
| JP2681682B2 (ja) | åå²ç¶ããªã«ãŒãããŒãã®è£œé æ¹æ³ | |
| US4308373A (en) | Halogen-containing polycarbonate resin and process for producing same | |
| JPH0469178B2 (ja) | ||
| JP2628562B2 (ja) | åå²ç¶ããªã«ãŒãããŒãåã³ãã®è£œé æ¹æ³ | |
| US6288204B1 (en) | Branched polycarbonate resin and process for producing the same | |
| JP2968402B2 (ja) | ã«ãŒãããŒãåé£çå€ã®è£œé æ³ | |
| JPH10226724A (ja) | æ®çºæ§å¡©çŽ ã®å°ãªãããªã«ãŒãããŒãæš¹èåã³ãã®è£œé æ¹æ³ | |
| JPH04233938A (ja) | ãã¹ã¯ãããã«ã¡âãããåäžã®å·¥çšã§ããªã«âããâãã補é ããæ¹æ³ | |
| US4918155A (en) | Process for production of polycarbonate | |
| JP3785965B2 (ja) | é«æµåæ§ããªã«ãŒãããŒãæš¹èã®è£œé æ¹æ³ | |
| JP3962883B2 (ja) | é«æµåæ§ããªã«ãŒãããŒãæš¹èã®è£œé æ¹æ³ |