JPH0342453B2 - - Google Patents
Info
- Publication number
- JPH0342453B2 JPH0342453B2 JP17593983A JP17593983A JPH0342453B2 JP H0342453 B2 JPH0342453 B2 JP H0342453B2 JP 17593983 A JP17593983 A JP 17593983A JP 17593983 A JP17593983 A JP 17593983A JP H0342453 B2 JPH0342453 B2 JP H0342453B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- emulsion
- silver halide
- dye
- silver
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000839 emulsion Substances 0.000 claims description 100
- -1 silver halide Chemical class 0.000 claims description 91
- 229910052709 silver Inorganic materials 0.000 claims description 55
- 239000004332 silver Substances 0.000 claims description 55
- 125000000217 alkyl group Chemical group 0.000 claims description 16
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 claims description 9
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 9
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 8
- 125000001424 substituent group Chemical group 0.000 claims description 8
- 125000004453 alkoxycarbonyl group Chemical group 0.000 claims description 7
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 7
- 125000005843 halogen group Chemical group 0.000 claims description 7
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims description 6
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 6
- 241000270666 Testudines Species 0.000 claims description 5
- 125000002252 acyl group Chemical group 0.000 claims description 5
- 125000004423 acyloxy group Chemical group 0.000 claims description 5
- 125000003545 alkoxy group Chemical group 0.000 claims description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 150000001450 anions Chemical class 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 239000000975 dye Substances 0.000 description 61
- 238000000034 method Methods 0.000 description 38
- 241000270708 Testudinidae Species 0.000 description 37
- 239000000463 material Substances 0.000 description 32
- 125000004432 carbon atom Chemical group C* 0.000 description 30
- 150000001875 compounds Chemical class 0.000 description 29
- 230000001235 sensitizing effect Effects 0.000 description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 21
- 230000035945 sensitivity Effects 0.000 description 20
- 238000012545 processing Methods 0.000 description 17
- 108010010803 Gelatin Proteins 0.000 description 14
- 229920000159 gelatin Polymers 0.000 description 14
- 239000008273 gelatin Substances 0.000 description 14
- 235000019322 gelatine Nutrition 0.000 description 14
- 235000011852 gelatine desserts Nutrition 0.000 description 14
- 238000011161 development Methods 0.000 description 13
- 206010070834 Sensitisation Diseases 0.000 description 11
- 230000008313 sensitization Effects 0.000 description 11
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- 238000012546 transfer Methods 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 238000011282 treatment Methods 0.000 description 9
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 239000000084 colloidal system Substances 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- 230000003595 spectral effect Effects 0.000 description 8
- 238000009792 diffusion process Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 6
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 5
- 125000001309 chloro group Chemical group Cl* 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 5
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 5
- 229940001482 sodium sulfite Drugs 0.000 description 5
- 235000010265 sodium sulphite Nutrition 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- 239000011593 sulfur Substances 0.000 description 4
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 3
- KPVMVJXYXFUVLR-UHFFFAOYSA-N 12-ethyltetradecan-1-amine Chemical compound CCC(CC)CCCCCCCCCCCN KPVMVJXYXFUVLR-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 235000010724 Wisteria floribunda Nutrition 0.000 description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 229910000510 noble metal Inorganic materials 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 125000001501 propionyl group Chemical group O=C([*])C([H])([H])C([H])([H])[H] 0.000 description 3
- 125000000547 substituted alkyl group Chemical group 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 229910052724 xenon Inorganic materials 0.000 description 3
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 3
- JZODKRWQWUWGCD-UHFFFAOYSA-N 2,5-di-tert-butylbenzene-1,4-diol Chemical compound CC(C)(C)C1=CC(O)=C(C(C)(C)C)C=C1O JZODKRWQWUWGCD-UHFFFAOYSA-N 0.000 description 2
- DSVIHYOAKPVFEH-UHFFFAOYSA-N 4-(hydroxymethyl)-4-methyl-1-phenylpyrazolidin-3-one Chemical compound N1C(=O)C(C)(CO)CN1C1=CC=CC=C1 DSVIHYOAKPVFEH-UHFFFAOYSA-N 0.000 description 2
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- KXDAEFPNCMNJSK-UHFFFAOYSA-N Benzamide Chemical compound NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- 229920002284 Cellulose triacetate Polymers 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- SMEGJBVQLJJKKX-HOTMZDKISA-N [(2R,3S,4S,5R,6R)-5-acetyloxy-3,4,6-trihydroxyoxan-2-yl]methyl acetate Chemical compound CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)O)OC(=O)C)O)O SMEGJBVQLJJKKX-HOTMZDKISA-N 0.000 description 2
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 2
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229960000583 acetic acid Drugs 0.000 description 2
- 229940081735 acetylcellulose Drugs 0.000 description 2
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 125000005907 alkyl ester group Chemical group 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 125000004104 aryloxy group Chemical group 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- JEHKKBHWRAXMCH-UHFFFAOYSA-N benzenesulfinic acid Chemical compound O[S@@](=O)C1=CC=CC=C1 JEHKKBHWRAXMCH-UHFFFAOYSA-N 0.000 description 2
- 150000001556 benzimidazoles Chemical class 0.000 description 2
- 150000001565 benzotriazoles Chemical class 0.000 description 2
- 125000001584 benzyloxycarbonyl group Chemical group C(=O)(OCC1=CC=CC=C1)* 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 229920002301 cellulose acetate Polymers 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 125000003754 ethoxycarbonyl group Chemical group C(=O)(OCC)* 0.000 description 2
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 125000001153 fluoro group Chemical group F* 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical class OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- 239000012362 glacial acetic acid Substances 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 description 2
- 125000004170 methylsulfonyl group Chemical group [H]C([H])([H])S(*)(=O)=O 0.000 description 2
- 125000002950 monocyclic group Chemical group 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 230000003472 neutralizing effect Effects 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- NDGRWYRVNANFNB-UHFFFAOYSA-N pyrazolidin-3-one Chemical class O=C1CCNN1 NDGRWYRVNANFNB-UHFFFAOYSA-N 0.000 description 2
- 230000005070 ripening Effects 0.000 description 2
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- KSYNLCYTMRMCGG-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate;dihydrate Chemical compound O.O.[Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O KSYNLCYTMRMCGG-UHFFFAOYSA-J 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- CNHDIAIOKMXOLK-UHFFFAOYSA-N toluquinol Chemical compound CC1=CC(O)=CC=C1O CNHDIAIOKMXOLK-UHFFFAOYSA-N 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 1
- KTTLEIOEBUVYMY-KTKRTIGZSA-N (z)-2-chlorooctadec-9-enoic acid Chemical compound CCCCCCCC\C=C/CCCCCCC(Cl)C(O)=O KTTLEIOEBUVYMY-KTKRTIGZSA-N 0.000 description 1
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 1
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical class C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 1
- BCMCBBGGLRIHSE-UHFFFAOYSA-N 1,3-benzoxazole Chemical group C1=CC=C2OC=NC2=C1 BCMCBBGGLRIHSE-UHFFFAOYSA-N 0.000 description 1
- ZRHUHDUEXWHZMA-UHFFFAOYSA-N 1,4-dihydropyrazol-5-one Chemical compound O=C1CC=NN1 ZRHUHDUEXWHZMA-UHFFFAOYSA-N 0.000 description 1
- GGZHVNZHFYCSEV-UHFFFAOYSA-N 1-Phenyl-5-mercaptotetrazole Chemical compound SC1=NN=NN1C1=CC=CC=C1 GGZHVNZHFYCSEV-UHFFFAOYSA-N 0.000 description 1
- FYBFGAFWCBMEDG-UHFFFAOYSA-N 1-[3,5-di(prop-2-enoyl)-1,3,5-triazinan-1-yl]prop-2-en-1-one Chemical compound C=CC(=O)N1CN(C(=O)C=C)CN(C(=O)C=C)C1 FYBFGAFWCBMEDG-UHFFFAOYSA-N 0.000 description 1
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 1
- YGDWUQFZMXWDKE-UHFFFAOYSA-N 1-oxido-1,3-thiazole Chemical group [O-]S1=CN=C=C1 YGDWUQFZMXWDKE-UHFFFAOYSA-N 0.000 description 1
- JAAIPIWKKXCNOC-UHFFFAOYSA-N 1h-tetrazol-1-ium-5-thiolate Chemical class SC1=NN=NN1 JAAIPIWKKXCNOC-UHFFFAOYSA-N 0.000 description 1
- IKQCSJBQLWJEPU-UHFFFAOYSA-N 2,5-dihydroxybenzenesulfonic acid Chemical compound OC1=CC=C(O)C(S(O)(=O)=O)=C1 IKQCSJBQLWJEPU-UHFFFAOYSA-N 0.000 description 1
- QVLXDGDLLZYJAM-UHFFFAOYSA-N 2,5-dioctylbenzene-1,4-diol Chemical compound CCCCCCCCC1=CC(O)=C(CCCCCCCC)C=C1O QVLXDGDLLZYJAM-UHFFFAOYSA-N 0.000 description 1
- YKUDHBLDJYZZQS-UHFFFAOYSA-N 2,6-dichloro-1h-1,3,5-triazin-4-one Chemical compound OC1=NC(Cl)=NC(Cl)=N1 YKUDHBLDJYZZQS-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- LOIUBRXCXMKWFZ-UHFFFAOYSA-J 2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate;iron(4+) Chemical compound [Fe+4].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O LOIUBRXCXMKWFZ-UHFFFAOYSA-J 0.000 description 1
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 1
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N 2-propanol Substances CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- VJWBUPGLRCFWEZ-UHFFFAOYSA-N 3,5-dichloro-1-hydroxy-2,4-dihydrotriazine;sodium Chemical compound [Na].ON1NN(Cl)CC(Cl)=C1 VJWBUPGLRCFWEZ-UHFFFAOYSA-N 0.000 description 1
- GCABLKFGYPIVFC-UHFFFAOYSA-N 3-(1-benzofuran-2-yl)-3-oxopropanenitrile Chemical compound C1=CC=C2OC(C(CC#N)=O)=CC2=C1 GCABLKFGYPIVFC-UHFFFAOYSA-N 0.000 description 1
- OWIRCRREDNEXTA-UHFFFAOYSA-N 3-nitro-1h-indazole Chemical class C1=CC=C2C([N+](=O)[O-])=NNC2=C1 OWIRCRREDNEXTA-UHFFFAOYSA-N 0.000 description 1
- XRZDIHADHZSFBB-UHFFFAOYSA-N 3-oxo-n,3-diphenylpropanamide Chemical class C=1C=CC=CC=1NC(=O)CC(=O)C1=CC=CC=C1 XRZDIHADHZSFBB-UHFFFAOYSA-N 0.000 description 1
- OCVLSHAVSIYKLI-UHFFFAOYSA-N 3h-1,3-thiazole-2-thione Chemical class SC1=NC=CS1 OCVLSHAVSIYKLI-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- ZVNPWFOVUDMGRP-UHFFFAOYSA-N 4-methylaminophenol sulfate Chemical compound OS(O)(=O)=O.CNC1=CC=C(O)C=C1.CNC1=CC=C(O)C=C1 ZVNPWFOVUDMGRP-UHFFFAOYSA-N 0.000 description 1
- 125000000590 4-methylphenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 1
- LRUDIIUSNGCQKF-UHFFFAOYSA-N 5-methyl-1H-benzotriazole Chemical compound C1=C(C)C=CC2=NNN=C21 LRUDIIUSNGCQKF-UHFFFAOYSA-N 0.000 description 1
- GIQKIFWTIQDQMM-UHFFFAOYSA-N 5h-1,3-oxazole-2-thione Chemical compound S=C1OCC=N1 GIQKIFWTIQDQMM-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- LEVWYRKDKASIDU-QWWZWVQMSA-N D-cystine Chemical compound OC(=O)[C@H](N)CSSC[C@@H](N)C(O)=O LEVWYRKDKASIDU-QWWZWVQMSA-N 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- NVXLIZQNSVLKPO-UHFFFAOYSA-N Glucosereductone Chemical compound O=CC(O)C=O NVXLIZQNSVLKPO-UHFFFAOYSA-N 0.000 description 1
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 1
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical class OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 description 1
- 229910000806 Latten Inorganic materials 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 241001061127 Thione Species 0.000 description 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 150000003926 acrylamides Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000005904 alkaline hydrolysis reaction Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 125000005599 alkyl carboxylate group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000001351 alkyl iodides Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- HTKFORQRBXIQHD-UHFFFAOYSA-N allylthiourea Chemical compound NC(=S)NCC=C HTKFORQRBXIQHD-UHFFFAOYSA-N 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 229940101006 anhydrous sodium sulfite Drugs 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 125000003289 ascorbyl group Chemical class [H]O[C@@]([H])(C([H])([H])O*)[C@@]1([H])OC(=O)C(O*)=C1O* 0.000 description 1
- 150000003851 azoles Chemical class 0.000 description 1
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 1
- 229910001864 baryta Inorganic materials 0.000 description 1
- 150000008366 benzophenones Chemical group 0.000 description 1
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical class C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 1
- 125000000051 benzyloxy group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])O* 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 1
- COPHVUDURPSYBO-UHFFFAOYSA-N butyl dioctyl phosphate Chemical compound CCCCCCCCOP(=O)(OCCCC)OCCCCCCCC COPHVUDURPSYBO-UHFFFAOYSA-N 0.000 description 1
- 150000001661 cadmium Chemical class 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- ZUIVNYGZFPOXFW-UHFFFAOYSA-N chembl1717603 Chemical compound N1=C(C)C=C(O)N2N=CN=C21 ZUIVNYGZFPOXFW-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- WYYQVWLEPYFFLP-UHFFFAOYSA-K chromium(3+);triacetate Chemical compound [Cr+3].CC([O-])=O.CC([O-])=O.CC([O-])=O WYYQVWLEPYFFLP-UHFFFAOYSA-K 0.000 description 1
- 229930016911 cinnamic acid Natural products 0.000 description 1
- 235000013985 cinnamic acid Nutrition 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 229960003067 cystine Drugs 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000011033 desalting Methods 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 150000001990 dicarboxylic acid derivatives Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 150000004683 dihydrates Chemical class 0.000 description 1
- ASMQGLCHMVWBQR-UHFFFAOYSA-M diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)([O-])OC1=CC=CC=C1 ASMQGLCHMVWBQR-UHFFFAOYSA-M 0.000 description 1
- MQRJBSHKWOFOGF-UHFFFAOYSA-L disodium;carbonate;hydrate Chemical compound O.[Na+].[Na+].[O-]C([O-])=O MQRJBSHKWOFOGF-UHFFFAOYSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 1
- 150000002429 hydrazines Chemical class 0.000 description 1
- 150000007857 hydrazones Chemical class 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 229920001477 hydrophilic polymer Polymers 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- NWVVVBRKAWDGAB-UHFFFAOYSA-N hydroquinone methyl ether Natural products COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 1
- AKCUHGBLDXXTOM-UHFFFAOYSA-N hydroxy-oxo-phenyl-sulfanylidene-$l^{6}-sulfane Chemical class SS(=O)(=O)C1=CC=CC=C1 AKCUHGBLDXXTOM-UHFFFAOYSA-N 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- PTFYQSWHBLOXRZ-UHFFFAOYSA-N imidazo[4,5-e]indazole Chemical compound C1=CC2=NC=NC2=C2C=NN=C21 PTFYQSWHBLOXRZ-UHFFFAOYSA-N 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 229940079865 intestinal antiinfectives imidazole derivative Drugs 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- 150000002503 iridium Chemical class 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- PJUIMOJAAPLTRJ-UHFFFAOYSA-N monothioglycerol Chemical compound OCC(O)CS PJUIMOJAAPLTRJ-UHFFFAOYSA-N 0.000 description 1
- 125000006518 morpholino carbonyl group Chemical group [H]C1([H])OC([H])([H])C([H])([H])N(C(*)=O)C1([H])[H] 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000005691 oxidative coupling reaction Methods 0.000 description 1
- 125000003854 p-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Cl 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 150000004686 pentahydrates Chemical class 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 125000006678 phenoxycarbonyl group Chemical group 0.000 description 1
- 150000004986 phenylenediamines Chemical class 0.000 description 1
- HKOOXMFOFWEVGF-UHFFFAOYSA-N phenylhydrazine Chemical compound NNC1=CC=CC=C1 HKOOXMFOFWEVGF-UHFFFAOYSA-N 0.000 description 1
- 229940067157 phenylhydrazine Drugs 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- NFIYTPYOYDDLGO-UHFFFAOYSA-N phosphoric acid;sodium Chemical group [Na].OP(O)(O)=O NFIYTPYOYDDLGO-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920000172 poly(styrenesulfonic acid) Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001451 polypropylene glycol Chemical class 0.000 description 1
- 229940005642 polystyrene sulfonic acid Drugs 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- ZNNZYHKDIALBAK-UHFFFAOYSA-M potassium thiocyanate Chemical compound [K+].[S-]C#N ZNNZYHKDIALBAK-UHFFFAOYSA-M 0.000 description 1
- 229940116357 potassium thiocyanate Drugs 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 description 1
- HBCQSNAFLVXVAY-UHFFFAOYSA-N pyrimidine-2-thiol Chemical class SC1=NC=CC=N1 HBCQSNAFLVXVAY-UHFFFAOYSA-N 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 238000001454 recorded image Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 150000003283 rhodium Chemical class 0.000 description 1
- 238000006798 ring closing metathesis reaction Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 235000017709 saponins Nutrition 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 1
- XOQRNNDIPPJGLV-UHFFFAOYSA-M sodium;2,5-dihydroxy-4-pentadecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCCCCC1=CC(O)=C(S([O-])(=O)=O)C=C1O XOQRNNDIPPJGLV-UHFFFAOYSA-M 0.000 description 1
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000001119 stannous chloride Substances 0.000 description 1
- 235000011150 stannous chloride Nutrition 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 150000003431 steroids Chemical class 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical class [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 description 1
- 125000004964 sulfoalkyl group Chemical group 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 125000001174 sulfone group Chemical group 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 150000003475 thallium Chemical class 0.000 description 1
- JJJPTTANZGDADF-UHFFFAOYSA-N thiadiazole-4-thiol Chemical class SC1=CSN=N1 JJJPTTANZGDADF-UHFFFAOYSA-N 0.000 description 1
- 125000005323 thioketone group Chemical group 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
- 150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/08—Sensitivity-increasing substances
- G03C1/10—Organic substances
- G03C1/12—Methine and polymethine dyes
- G03C1/14—Methine and polymethine dyes with an odd number of CH groups
- G03C1/18—Methine and polymethine dyes with an odd number of CH groups with three CH groups
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
Description
ãçºæã®è©³çŽ°ãªèª¬æã
æ¬çºæã¯åå
å¢æ®ãããããã²ã³åéåçä¹³å€
ã«é¢ãããã®ã§ãããæŽã«è©³çŽ°ã«ã¯ãç·è²æ³¢é·å
ã®åå æ床ãç¹ã«é«ããããããã²ã³åéåçä¹³
å€ã«é¢ãããã®ã§ããã
ã«é¢ãããã®ã§ãããæŽã«è©³çŽ°ã«ã¯ãç·è²æ³¢é·å
ã®åå æ床ãç¹ã«é«ããããããã²ã³åéåçä¹³
å€ã«é¢ãããã®ã§ããã
æå
ææã®è£œé ã«æŒãŠãããã²ã³åéåçä¹³å€
ã®æå æ³¢é·åãæ¡åŒµããããšãå³ã¡åå å¢æãæœ
ãããšã¯ããç¥ãããŠããããã®åå å¢ææè¡ã®
äžã§ãç¹ã«ãç·è²æ³¢é·åã®å¢æã¯ã人éã®èŠæ床
ã®æ¥µå€§ãçŽ545nïœã«ããã人éã®çŒãç·è²æ³¢é·
åã®å ã«éæã«æããããäºå®ãšé¢é£ããŠéèŠã§
ããã
ã®æå æ³¢é·åãæ¡åŒµããããšãå³ã¡åå å¢æãæœ
ãããšã¯ããç¥ãããŠããããã®åå å¢ææè¡ã®
äžã§ãç¹ã«ãç·è²æ³¢é·åã®å¢æã¯ã人éã®èŠæ床
ã®æ¥µå€§ãçŽ545nïœã«ããã人éã®çŒãç·è²æ³¢é·
åã®å ã«éæã«æããããäºå®ãšé¢é£ããŠéèŠã§
ããã
ããã²ã³åéã®ç·æ床ãäžæãããæ段ãšã
ãŠãããçš®ã®ãã³ãŸã€ãããŸãã«ã«ãã·ã¢ãã³è²
çŽ ã®æ·»å ã極ããŠæå¹ã§ããããšã¯è¯ãç¥ãããŠ
ããããã®å Žåããã²ã³åéåçä¹³å€äžã«å ãã
ããè²çŽ ã¯ä¹³å€äžã®ããã²ã³åéç²åã«åžçãã
ããã²ã³åéã«åºå®ã®åžå垯ã«æŽã«é·æ³¢é·ã®åžå
垯ãä»å ãããå³ã¡ãè²çŽ ã«ããåå å¢æãåŸã
ããã
ãŠãããçš®ã®ãã³ãŸã€ãããŸãã«ã«ãã·ã¢ãã³è²
çŽ ã®æ·»å ã極ããŠæå¹ã§ããããšã¯è¯ãç¥ãããŠ
ããããã®å Žåããã²ã³åéåçä¹³å€äžã«å ãã
ããè²çŽ ã¯ä¹³å€äžã®ããã²ã³åéç²åã«åžçãã
ããã²ã³åéã«åºå®ã®åžå垯ã«æŽã«é·æ³¢é·ã®åžå
垯ãä»å ãããå³ã¡ãè²çŽ ã«ããåå å¢æãåŸã
ããã
ãããã®ããšã¯ãäŸãã°ãç±³åœç¹èš±2912329å·
æ现æžãå2739149å·æ现æžãè±åœç¹èš±654690å·
æ现æžãå815172å·æ现æžãªã©ã«èšèŒãããŠã
ãã
æ现æžãå2739149å·æ现æžãè±åœç¹èš±654690å·
æ现æžãå815172å·æ现æžãªã©ã«èšèŒãããŠã
ãã
ããããªãããåŸæ¥ç¥ãããŠãããã³ãŸã€ãã
ãŸãã«ã«ãã·ã¢ãã³è²çŽ ã§ã¯ä¹³å€å¡åžåŸã®é«æž©äž
ãŸãã¯é«æž©é«æ¹¿äžã«ãããã«ããªã®å¢å ãããã¯
ä¹³å€å¡åžåŸã®çµæå®å®æ§ãæªããæ床ã®äœäžã倧
ããã€ãããã³ãŸã€ãããŸãã«ã«ãã·ã¢ãã³è²çŽ
ã®ãããã®çæâå³ã¡é«æž©äžãããã¯é«æž©é«æ¹¿äž
ã§ã®ã«ããªã®å¢å ãããã¯çµæã«ããæ床ã®äœäž
âã®æ¹è¯ã¯ãæå ææ補é æè¡ã«ãããéèŠãªèª²
é¡ã®äžã€ã«ãªã€ãŠããã
ãŸãã«ã«ãã·ã¢ãã³è²çŽ ã§ã¯ä¹³å€å¡åžåŸã®é«æž©äž
ãŸãã¯é«æž©é«æ¹¿äžã«ãããã«ããªã®å¢å ãããã¯
ä¹³å€å¡åžåŸã®çµæå®å®æ§ãæªããæ床ã®äœäžã倧
ããã€ãããã³ãŸã€ãããŸãã«ã«ãã·ã¢ãã³è²çŽ
ã®ãããã®çæâå³ã¡é«æž©äžãããã¯é«æž©é«æ¹¿äž
ã§ã®ã«ããªã®å¢å ãããã¯çµæã«ããæ床ã®äœäž
âã®æ¹è¯ã¯ãæå ææ補é æè¡ã«ãããéèŠãªèª²
é¡ã®äžã€ã«ãªã€ãŠããã
æ¬çºæã®ç®çã¯é«æž©äžãããã¯é«æž©é«æ¹¿äžã«ã
ãããã«ããªã®å¢å ãæããããã«ã¯çµæã«ãã
æ床äœäžãæå°éã«æããçµæå®å®æ§ã®è¯ããã
ã²ã³åéåçä¹³å€ãæäŸããããšã§ããã
ãããã«ããªã®å¢å ãæããããã«ã¯çµæã«ãã
æ床äœäžãæå°éã«æããçµæå®å®æ§ã®è¯ããã
ã²ã³åéåçä¹³å€ãæäŸããããšã§ããã
æ¬çºæã®äžèšã®è«žç®çã¯ãåŒâïŒCH2ïŒlïŒCF2ïŒn
ïŒïœããã³ïœã¯ïŒãŸãã¯ïŒããïŒãŸã§ã®æŽæ°ã
è¡šãããäœãïœïŒïœïŒïŒã§ããïŒã§è¡šããããã
ãçŽ çœ®æã¢ã«ãã«åºãã€ãããŸãŒã«ç°ã®çªçŽ åå
ã®å°ããšãïŒã€ã«çµåããäžèšäžè¬åŒïŒïŒã§è¡š
ãããããã³ãŸã€ãããŸãã«ã«ãã·ã¢ãã³è²çŽ ã®
å°ããšãäžçš®ä»¥äžå«æããããšãç¹åŸŽãšãããã
ã²ã³åéåçä¹³å€ã調補ããããšã«ããéæãã
ãããšãèŠåºãããã
ïŒïœããã³ïœã¯ïŒãŸãã¯ïŒããïŒãŸã§ã®æŽæ°ã
è¡šãããäœãïœïŒïœïŒïŒã§ããïŒã§è¡šããããã
ãçŽ çœ®æã¢ã«ãã«åºãã€ãããŸãŒã«ç°ã®çªçŽ åå
ã®å°ããšãïŒã€ã«çµåããäžèšäžè¬åŒïŒïŒã§è¡š
ãããããã³ãŸã€ãããŸãã«ã«ãã·ã¢ãã³è²çŽ ã®
å°ããšãäžçš®ä»¥äžå«æããããšãç¹åŸŽãšãããã
ã²ã³åéåçä¹³å€ã調補ããããšã«ããéæãã
ãããšãèŠåºãããã
äžè¬åŒïŒïŒ
â â â äºã®ç² 0215 â â â
åŒäžïœã¯ïŒãŸãã¯ïŒããïŒã®æŽæ°ãïœã¯ïŒãã
ïŒã®æŽæ°ãè¡šãããäœãïœïŒïœïŒïŒã§ãããR1ã
R2ãR3ã¯ããããåäžãŸãã¯ç°ãªã€ãŠããŠãã
ããâïŒCH2ïŒjïŒCF2ïŒkåºã眮æãããã¯ç¡çœ®æ
ã®ã¢ã«ãã«åºãè¡šãããäœããR1ãR2ãR3ã®ã
ã¡ãå°ããšãïŒã€ã¯é žçœ®æåºïŒäŸãã°ãã¹ã«ã
åºãã«ã«ããã·ã«åºãªã©ïŒãæããã¢ã«ãã«åºã§
ãããïœã¯ïŒãŸãã¯ïŒããïŒã®æŽæ°ãè¡šããïœã¯
ïŒãŸãã¯ïŒããïŒã®æŽæ°ãè¡šãããäœããïœïŒïœ
ïŒïŒã§ãããV1ãV2ãV3ãV4ã¯ããããåäžã
ããã¯ç°ã€ãŠããŠããããæ°ŽçŽ ååãããã²ã³å
åã眮æã¢ã«ãã«åºãããã¯ç¡çœ®æã¢ã«ãã«åºã
ã¢ã«ã³ãã·åºãã¢ã·ã«åºãã¢ã·ã«ãªãã·åºãã¢ã«
ã³ãã·ã«ã«ããã«åºãã«ã«ãã¢ã€ã«åºãã¹ã«ãã¢
ã¢ã€ã«åºãã·ã¢ãåºããŸãã¯ããªãã«ãªãã¡ãã«
åºãè¡šãããã¯ã¢ããªã³ãè¡šãããïœã¯ïŒãŸã
ã¯ïŒãè¡šãããè²çŽ ãååå å¡©ã圢æãããšãã¯
ïŒã§ããã
ïŒã®æŽæ°ãè¡šãããäœãïœïŒïœïŒïŒã§ãããR1ã
R2ãR3ã¯ããããåäžãŸãã¯ç°ãªã€ãŠããŠãã
ããâïŒCH2ïŒjïŒCF2ïŒkåºã眮æãããã¯ç¡çœ®æ
ã®ã¢ã«ãã«åºãè¡šãããäœããR1ãR2ãR3ã®ã
ã¡ãå°ããšãïŒã€ã¯é žçœ®æåºïŒäŸãã°ãã¹ã«ã
åºãã«ã«ããã·ã«åºãªã©ïŒãæããã¢ã«ãã«åºã§
ãããïœã¯ïŒãŸãã¯ïŒããïŒã®æŽæ°ãè¡šããïœã¯
ïŒãŸãã¯ïŒããïŒã®æŽæ°ãè¡šãããäœããïœïŒïœ
ïŒïŒã§ãããV1ãV2ãV3ãV4ã¯ããããåäžã
ããã¯ç°ã€ãŠããŠããããæ°ŽçŽ ååãããã²ã³å
åã眮æã¢ã«ãã«åºãããã¯ç¡çœ®æã¢ã«ãã«åºã
ã¢ã«ã³ãã·åºãã¢ã·ã«åºãã¢ã·ã«ãªãã·åºãã¢ã«
ã³ãã·ã«ã«ããã«åºãã«ã«ãã¢ã€ã«åºãã¹ã«ãã¢
ã¢ã€ã«åºãã·ã¢ãåºããŸãã¯ããªãã«ãªãã¡ãã«
åºãè¡šãããã¯ã¢ããªã³ãè¡šãããïœã¯ïŒãŸã
ã¯ïŒãè¡šãããè²çŽ ãååå å¡©ã圢æãããšãã¯
ïŒã§ããã
äžè¬åŒïŒïŒã¯å
±é³Žæ§é ã®äžæ¥µéç¶æ
ã瀺ãã
ã«ãããããã€ãŒãžããã®ä»ã®ã€ãããŸãŒã«ç°
çªçŽ ååã«ãã極éç¶æ ã§è¡šãããŠãåäžç©è³ªã
æå³ããã
ã«ãããããã€ãŒãžããã®ä»ã®ã€ãããŸãŒã«ç°
çªçŽ ååã«ãã極éç¶æ ã§è¡šãããŠãåäžç©è³ªã
æå³ããã
æ¬çºæã«çšããããå¢æè²çŽ ã®äžè¬åŒïŒïŒã«
ãããŠãå眮æåºã§å¥œãŸããã¯äžèšã®çœ®æåºãçš
ããããã
ãããŠãå眮æåºã§å¥œãŸããã¯äžèšã®çœ®æåºãçš
ããããã
å³ã¡ãR1ãR2ãR3ã¯ããããåäžãŸãã¯ç°ãª
ã€ãŠããŠããããâïŒCH2ïŒjïŒCF2ïŒkåºïŒããã§
ïœã¯ïœãšåäžãŸãã¯ç°ã€ãŠããŠãããïŒãŸãã¯ïŒ
ããïŒãŸã§ã®æŽæ°ãè¡šãããäœããïœïŒïœïŒïŒã§
ãããïŒ ççŽ æ°ïŒä»¥äžã®ç¡çœ®æã¢ã«ãã«åºïŒäŸãã°ã¡ã
ã«åºããšãã«åºããããã«åºãããã«åºããã³ã
ã«åºãããã«ã¡ãã«åºãã·ã¯ãããã·ã«åºãªã©ïŒ
ãŸãã¯çœ®æã¢ã«ãã«åºïœçœ®æåºãšããŠäŸãã°ãã«
ã«ããã·ã«åºãã¹ã«ãåºãã·ã¢ãåºãããã²ã³å
åïŒäŸãã°ããçŽ ååãå¡©çŽ ååãèçŽ ååã§ã
ããïŒããããã·åºãççŽ æ°ïŒä»¥äžã®ã¢ã«ã³ãã·
ã«ã«ããã«åºïŒäŸãã°ã¡ããã·ã«ã«ããã«åºããš
ããã·ã«ã«ããã«åºãããšããã·ã«ã«ããã«åºã
ãã³ãžã«ãªãã·ã«ã«ããã«åºãªã©ïŒãççŽ æ°ïŒä»¥
äžã®ã¢ã«ã³ãã·åºãïŒäŸãã°ã¡ããã·åºããšãã
ã·åºããã³ãžã«ãªãã·åºãããšããã«ãªãã·åºãª
ã©ïŒççŽ æ°10以äžã®åç°åŒã®ã¢ãªãŒã«ãªãã·åº
ïŒäŸãã°ããšããã·åºãïœâããªã«ãªãã·åºãªã©ïŒ
ççŽ æ°ïŒä»¥äžã®ã¢ã·ã«ãªãã·åºïŒäŸãã°ã¢ã»ãã«
ãªãã·åºãããããªãã«ãªãã·åºãªã©ïŒãççŽ æ°
ïŒä»¥äžã®ã¢ã·ã«åºïŒäŸãã°ã¢ã»ãã«åºãããããª
ãã«åºããã³ãŸã€ã«åºãã¡ã·ã«åºãªã©ïŒã«ã«ãã¢
ã€ã«åºïŒäŸãã°ã«ã«ãã¢ã€ã«åºãïŒïŒ®âãžã¡ã
ã«ã«ã«ãã¢ã€ã«åºãã¢ã«ããªãã«ã«ããã«åºãã
ããªãžãã«ã«ããã«åºãªã©ïŒãã¹ã«ãã¢ã¢ã€ã«åº
ïŒäŸãã°ã¹ã«ãã¢ã¢ã€ã«åºãïŒïŒ®âãžã¡ãã«ã¹
ã«ãã¢ã¢ã€ã«åºãã¢ã«ããªãã¹ã«ããã«åºããã
ãªãžãã¹ã«ããã«åºãªã©ïŒççŽ æ°10以äžã®ã¢ãªãŒ
ã«åºïŒäŸãã°ããšãã«åºãïŒâã¯ãã«ããšãã«
åºãïŒâã¡ãã«ããšãã«åºãαâãããã«åºãª
ã©ïŒãªã©ã§çœ®æãããççŽ æ°ïŒä»¥äžã®ã¢ã«ãã«
åºïœã奜ãŸãããäœãR1ãR2ãR3ã®ãã¡å°ããš
ãïŒã€ã¯ã¹ã«ãåºããŸãã¯ã«ã«ããã·ã«åºãæã
ãççŽ æ°ïŒä»¥äžã®ã¢ã«ãã«åºã§ããã
ã€ãŠããŠããããâïŒCH2ïŒjïŒCF2ïŒkåºïŒããã§
ïœã¯ïœãšåäžãŸãã¯ç°ã€ãŠããŠãããïŒãŸãã¯ïŒ
ããïŒãŸã§ã®æŽæ°ãè¡šãããäœããïœïŒïœïŒïŒã§
ãããïŒ ççŽ æ°ïŒä»¥äžã®ç¡çœ®æã¢ã«ãã«åºïŒäŸãã°ã¡ã
ã«åºããšãã«åºããããã«åºãããã«åºããã³ã
ã«åºãããã«ã¡ãã«åºãã·ã¯ãããã·ã«åºãªã©ïŒ
ãŸãã¯çœ®æã¢ã«ãã«åºïœçœ®æåºãšããŠäŸãã°ãã«
ã«ããã·ã«åºãã¹ã«ãåºãã·ã¢ãåºãããã²ã³å
åïŒäŸãã°ããçŽ ååãå¡©çŽ ååãèçŽ ååã§ã
ããïŒããããã·åºãççŽ æ°ïŒä»¥äžã®ã¢ã«ã³ãã·
ã«ã«ããã«åºïŒäŸãã°ã¡ããã·ã«ã«ããã«åºããš
ããã·ã«ã«ããã«åºãããšããã·ã«ã«ããã«åºã
ãã³ãžã«ãªãã·ã«ã«ããã«åºãªã©ïŒãççŽ æ°ïŒä»¥
äžã®ã¢ã«ã³ãã·åºãïŒäŸãã°ã¡ããã·åºããšãã
ã·åºããã³ãžã«ãªãã·åºãããšããã«ãªãã·åºãª
ã©ïŒççŽ æ°10以äžã®åç°åŒã®ã¢ãªãŒã«ãªãã·åº
ïŒäŸãã°ããšããã·åºãïœâããªã«ãªãã·åºãªã©ïŒ
ççŽ æ°ïŒä»¥äžã®ã¢ã·ã«ãªãã·åºïŒäŸãã°ã¢ã»ãã«
ãªãã·åºãããããªãã«ãªãã·åºãªã©ïŒãççŽ æ°
ïŒä»¥äžã®ã¢ã·ã«åºïŒäŸãã°ã¢ã»ãã«åºãããããª
ãã«åºããã³ãŸã€ã«åºãã¡ã·ã«åºãªã©ïŒã«ã«ãã¢
ã€ã«åºïŒäŸãã°ã«ã«ãã¢ã€ã«åºãïŒïŒ®âãžã¡ã
ã«ã«ã«ãã¢ã€ã«åºãã¢ã«ããªãã«ã«ããã«åºãã
ããªãžãã«ã«ããã«åºãªã©ïŒãã¹ã«ãã¢ã¢ã€ã«åº
ïŒäŸãã°ã¹ã«ãã¢ã¢ã€ã«åºãïŒïŒ®âãžã¡ãã«ã¹
ã«ãã¢ã¢ã€ã«åºãã¢ã«ããªãã¹ã«ããã«åºããã
ãªãžãã¹ã«ããã«åºãªã©ïŒççŽ æ°10以äžã®ã¢ãªãŒ
ã«åºïŒäŸãã°ããšãã«åºãïŒâã¯ãã«ããšãã«
åºãïŒâã¡ãã«ããšãã«åºãαâãããã«åºãª
ã©ïŒãªã©ã§çœ®æãããççŽ æ°ïŒä»¥äžã®ã¢ã«ãã«
åºïœã奜ãŸãããäœãR1ãR2ãR3ã®ãã¡å°ããš
ãïŒã€ã¯ã¹ã«ãåºããŸãã¯ã«ã«ããã·ã«åºãæã
ãççŽ æ°ïŒä»¥äžã®ã¢ã«ãã«åºã§ããã
V1ãV2ãV3ãV4ã¯ããããåäžãããã¯ç°ã€
ãŠããŠãããããããããæ°ŽçŽ ååãããã²ã³å
åïŒäŸãã°ããçŽ ååãå¡©çŽ ååãèçŽ ååãª
ã©ïŒççŽ æ°ïŒä»¥äžã®ã¢ã«ãã«åºïŒäŸãã°ã¡ãã«
åºããšãã«åºãããã«ã¡ãã«åºãã·ã¯ãããã·ã«
åºãªã©ïŒççŽ æ°ïŒä»¥äžã®ã¢ã·ã«åºïŒäŸãã°ã¢ã»ã
ã«åºãããããªãã«åºããã³ãŸã€ã«åºãã¡ã·ã«åº
ãªã©ïŒççŽ æ°ïŒä»¥äžã®ã¢ã·ã«ãªãã·åºïŒäŸãã°ã¢
ã»ããã·åºãïŒãççŽ æ°ïŒä»¥äžã®ã¢ã«ã³ãã·ã«ã«ã
ãã«åºïŒäŸãã°ã¡ããã·ã«ã«ããã«åºïŒãšããã·
ã«ã«ããã«åºããã³ãžã«ãªãã·ã«ã«ããã«åºãª
ã©ïŒççŽ æ°ïŒä»¥äžã®ã«ã«ãã¢ã€ã«åºïŒäŸãã°ã«ã«
ãã¢ã€ã«åºãïŒïŒ®âãžã¡ãã«ã«ã«ãã¢ã€ã«åºã
ã¢ãªããªãã«ã«ããã«åºããããªãžãã«ã«ããã«
åºãªã©ïŒççŽ æ°ïŒä»¥äžã®ã¹ã«ãã¢ã¢ã€ã«åºïŒäŸã
ã°ã¹ã«ãã¢ã¢ã€ã«åºãïŒïŒ®âãžã¡ãã«ã¹ã«ãã¢
ã¢ã€ã«åºãã¢ã«ããªãã¹ã«ããã«åºããããªãžã
ã¹ã«ããã«åºãªã©ïŒã·ã¢ãåºãããªãã«ãªãã¡ã
ã«åºãããããã·åºã奜ãŸããã
ãŠããŠãããããããããæ°ŽçŽ ååãããã²ã³å
åïŒäŸãã°ããçŽ ååãå¡©çŽ ååãèçŽ ååãª
ã©ïŒççŽ æ°ïŒä»¥äžã®ã¢ã«ãã«åºïŒäŸãã°ã¡ãã«
åºããšãã«åºãããã«ã¡ãã«åºãã·ã¯ãããã·ã«
åºãªã©ïŒççŽ æ°ïŒä»¥äžã®ã¢ã·ã«åºïŒäŸãã°ã¢ã»ã
ã«åºãããããªãã«åºããã³ãŸã€ã«åºãã¡ã·ã«åº
ãªã©ïŒççŽ æ°ïŒä»¥äžã®ã¢ã·ã«ãªãã·åºïŒäŸãã°ã¢
ã»ããã·åºãïŒãççŽ æ°ïŒä»¥äžã®ã¢ã«ã³ãã·ã«ã«ã
ãã«åºïŒäŸãã°ã¡ããã·ã«ã«ããã«åºïŒãšããã·
ã«ã«ããã«åºããã³ãžã«ãªãã·ã«ã«ããã«åºãª
ã©ïŒççŽ æ°ïŒä»¥äžã®ã«ã«ãã¢ã€ã«åºïŒäŸãã°ã«ã«
ãã¢ã€ã«åºãïŒïŒ®âãžã¡ãã«ã«ã«ãã¢ã€ã«åºã
ã¢ãªããªãã«ã«ããã«åºããããªãžãã«ã«ããã«
åºãªã©ïŒççŽ æ°ïŒä»¥äžã®ã¹ã«ãã¢ã¢ã€ã«åºïŒäŸã
ã°ã¹ã«ãã¢ã¢ã€ã«åºãïŒïŒ®âãžã¡ãã«ã¹ã«ãã¢
ã¢ã€ã«åºãã¢ã«ããªãã¹ã«ããã«åºããããªãžã
ã¹ã«ããã«åºãªã©ïŒã·ã¢ãåºãããªãã«ãªãã¡ã
ã«åºãããããã·åºã奜ãŸããã
æ¬çºæã«çšããããå¢æè²çŽ ã®äžè¬åŒïŒïŒã«
ãããŠãïœãšïœã¯ïŒâ§ïœïŒïœïŒïŒãç¹ã«å¥œãŸã
ãããŸãå眮æåºã§ç¹ã«å¥œãŸããã¯äžèšã®çœ®æåº
ãçšãããããå³ã¡ãR1ãR2ãR3ã¯ããããå
äžãŸãã¯ç°ã€ãŠããŠããããâïŒCH2ïŒjïŒCF2ïŒk
åºïŒããã§ïœã¯ïœãšåäžãŸãã¯ç°ã€ãŠããŠããã
ïŒãŸãã¯ïŒããïŒãŸã§ã®æŽæ°ãè¡šãããäœããïœ
ïŒïœïŒïŒã§ããã奜ãŸããã¯ïŒâ§ïœïŒïœïŒïŒã§ã
ããïŒ ççŽ æ°ïŒä»¥äžã®ç¡çœ®æã¢ã«ãã«åºïŒäŸãã°ã¡ã
ã«åºããšãã«åºããããã«åºãããã«åºããã³ã
ã«åºãããã«ã¡ãã«åºãã·ã¯ãããã·ã«åºãªã©ïŒ
ãŸãã¯ççŽ æ°12以äžã®çœ®æã¢ã«ãã«åºïœçœ®æåºãš
ããŠäŸãã°ã«ã«ããã·åºãã¹ã«ãåºãã·ã¢ãåºã
ããã²ã³ååãããããã·åºãççŽ æ°ïŒä»¥äžã®ã¢
ã«ã³ãã·ã«ã«ããã«åºãççŽ æ°ïŒä»¥äžã®ã¢ã«ã³ã
ã·åºãççŽ æ°10以äžã®åç°åŒã®ã¢ãªãŒã«ãªãã·
åºãççŽ æ°ïŒä»¥äžã®ã¢ã·ã«ãªãã·åºãççŽ æ°ïŒä»¥
äžã®ã¢ã·ã«åºãã¹ã«ãã¢ã¢ã€ã«åºãççŽ æ°10以äž
ã®ã¢ãªãŒã«åºãªã©ã§çœ®æãããççŽ æ°ïŒä»¥äžã®ã¢
ã«ãã«åºïœãç¹ã«å¥œãŸãããäœããR1ãR2ãR3
ã®ãã¡ãå°ããšãïŒã€ã¯ã¹ã«ãåºãŸãã¯ã«ã«ãã
ã·ã«åºãæããççŽ æ°ïŒä»¥äžã®ã¢ã«ãã«åºã§ã
ãã
ãããŠãïœãšïœã¯ïŒâ§ïœïŒïœïŒïŒãç¹ã«å¥œãŸã
ãããŸãå眮æåºã§ç¹ã«å¥œãŸããã¯äžèšã®çœ®æåº
ãçšãããããå³ã¡ãR1ãR2ãR3ã¯ããããå
äžãŸãã¯ç°ã€ãŠããŠããããâïŒCH2ïŒjïŒCF2ïŒk
åºïŒããã§ïœã¯ïœãšåäžãŸãã¯ç°ã€ãŠããŠããã
ïŒãŸãã¯ïŒããïŒãŸã§ã®æŽæ°ãè¡šãããäœããïœ
ïŒïœïŒïŒã§ããã奜ãŸããã¯ïŒâ§ïœïŒïœïŒïŒã§ã
ããïŒ ççŽ æ°ïŒä»¥äžã®ç¡çœ®æã¢ã«ãã«åºïŒäŸãã°ã¡ã
ã«åºããšãã«åºããããã«åºãããã«åºããã³ã
ã«åºãããã«ã¡ãã«åºãã·ã¯ãããã·ã«åºãªã©ïŒ
ãŸãã¯ççŽ æ°12以äžã®çœ®æã¢ã«ãã«åºïœçœ®æåºãš
ããŠäŸãã°ã«ã«ããã·åºãã¹ã«ãåºãã·ã¢ãåºã
ããã²ã³ååãããããã·åºãççŽ æ°ïŒä»¥äžã®ã¢
ã«ã³ãã·ã«ã«ããã«åºãççŽ æ°ïŒä»¥äžã®ã¢ã«ã³ã
ã·åºãççŽ æ°10以äžã®åç°åŒã®ã¢ãªãŒã«ãªãã·
åºãççŽ æ°ïŒä»¥äžã®ã¢ã·ã«ãªãã·åºãççŽ æ°ïŒä»¥
äžã®ã¢ã·ã«åºãã¹ã«ãã¢ã¢ã€ã«åºãççŽ æ°10以äž
ã®ã¢ãªãŒã«åºãªã©ã§çœ®æãããççŽ æ°ïŒä»¥äžã®ã¢
ã«ãã«åºïœãç¹ã«å¥œãŸãããäœããR1ãR2ãR3
ã®ãã¡ãå°ããšãïŒã€ã¯ã¹ã«ãåºãŸãã¯ã«ã«ãã
ã·ã«åºãæããççŽ æ°ïŒä»¥äžã®ã¢ã«ãã«åºã§ã
ãã
V1ãV2ãV3ãV4ã¯ããããåäžãããã¯ç°ã€
ãŠããŠããããããããæ°ŽçŽ ååãããã²ã³å
åãççŽ æ°ïŒä»¥äžã®ã¢ã«ãã«åºïŒäŸãã°ã¡ãã«
åºããšãã«åºãããã«ã¡ãã«åºãªã©ïŒççŽ æ°ïŒä»¥
äžã®ã¢ã·ã«åºïŒäŸãã°ã¢ã»ãã«åºãããããªãã«
åºããã³ãŸã€ã«åºããªã©ïŒççŽ æ°ïŒä»¥äžã®ã¢ã«ã³
ãã·ã«ã«ããã«åºãççŽ æ°ïŒä»¥äžã®ã«ã«ãã¢ã€ã«
åºïŒäŸãã°ã«ã«ãã¢ã€ã«åºãïŒïŒ®âãžã¡ãã«ã«
ã«ãã¢ã€ã«åºãã¢ã«ããªãã«ã«ãã¢ã€ã«åºããª
ã©ïŒççŽ æ°ïŒä»¥äžã®ã¹ã«ãã¢ã¢ã€ã«åºïŒäŸãã°ã¹
ã«ãã¢ã¢ã€ã«åºãïŒïŒ®âãžã¡ãã«ã¹ã«ãã¢ã¢ã€
ã«åºãã¢ã«ããã«ã¹ã«ããã«åºããããªãžãã¹ã«
ããã«åºããªã©ïŒã·ã¢ãåºãããªãã«ãªãã¡ãã«
åºãããããã·åºãç¹ã«å¥œãŸããã
ãŠããŠããããããããæ°ŽçŽ ååãããã²ã³å
åãççŽ æ°ïŒä»¥äžã®ã¢ã«ãã«åºïŒäŸãã°ã¡ãã«
åºããšãã«åºãããã«ã¡ãã«åºãªã©ïŒççŽ æ°ïŒä»¥
äžã®ã¢ã·ã«åºïŒäŸãã°ã¢ã»ãã«åºãããããªãã«
åºããã³ãŸã€ã«åºããªã©ïŒççŽ æ°ïŒä»¥äžã®ã¢ã«ã³
ãã·ã«ã«ããã«åºãççŽ æ°ïŒä»¥äžã®ã«ã«ãã¢ã€ã«
åºïŒäŸãã°ã«ã«ãã¢ã€ã«åºãïŒïŒ®âãžã¡ãã«ã«
ã«ãã¢ã€ã«åºãã¢ã«ããªãã«ã«ãã¢ã€ã«åºããª
ã©ïŒççŽ æ°ïŒä»¥äžã®ã¹ã«ãã¢ã¢ã€ã«åºïŒäŸãã°ã¹
ã«ãã¢ã¢ã€ã«åºãïŒïŒ®âãžã¡ãã«ã¹ã«ãã¢ã¢ã€
ã«åºãã¢ã«ããã«ã¹ã«ããã«åºããããªãžãã¹ã«
ããã«åºããªã©ïŒã·ã¢ãåºãããªãã«ãªãã¡ãã«
åºãããããã·åºãç¹ã«å¥œãŸããã
æ¬çºæã®äžè¬åŒïŒïŒã«ãã€ãŠè¡šããããè²çŽ
ã®å ·äœäŸãäŸç€ºããããããããã®ã¿ã«éå®ãã
ããã®ã§ã¯ãªãã
ã®å ·äœäŸãäŸç€ºããããããããã®ã¿ã«éå®ãã
ããã®ã§ã¯ãªãã
â â â äºã®ç² 0216 â â â
â â â äºã®ç² 0217 â â â
â â â äºã®ç² 0218 â â â
â â â äºã®ç² 0219 â â â
â â â äºã®ç² 0220 â â â
â â â äºã®ç² 0221 â â â
â â â äºã®ç² 0222 â â â
â â â äºã®ç² 0223 â â â
â â â äºã®ç² 0224 â â â
â â â äºã®ç² 0225 â â â
â â â äºã®ç² 0226 â â â
â â â äºã®ç² 0227 â â â
â â â äºã®ç² 0228 â â â
â â â äºã®ç² 0229 â â â
â â â äºã®ç² 0230 â â â
â â â äºã®ç² 0231 â â â
â â â äºã®ç² 0232 â â â
â â â äºã®ç² 0233 â â â
â â â äºã®ç² 0234 â â â
â â â äºã®ç² 0235 â â â
â â â äºã®ç² 0236 â â â
â â â äºã®ç² 0237 â â â
â â â äºã®ç² 0238 â â â
â â â äºã®ç² 0239 â â â
â â â äºã®ç² 0240 â â â
â â â äºã®ç² 0241 â â â
â â â äºã®ç² 0242 â â â
â â â äºã®ç² 0243 â â â
æ¬çºæã®äžè¬åŒïŒïŒã®ååç©ã¯ãJ.Org.
Chem.ã26ã4021ïŒ1961ïŒïŒJ.Amer.Chem.Soc.ã
773149ïŒ1955ïŒïŒJ.Amer.Chem.Soc.ã78ã4999
ïŒ1956ïŒçã«èšèŒãããæ¹æ³ã«æºããŠåæããã
ã¹ã«ãã³é žã®ããçŽ åã¢ã«ãã«ãšã¹ãã«é¡ããã
çŽ åã¢ã«ãã«ã¢ãã³é¡ãããçŽ åã¢ã«ãã«ãšãŠå
ç©çãçšããŠã次ã®æç®ã®èšèŒã«åºã¥ããŠå®¹æã«
åæããããšãã§ãããããªãã¡ãç±³åœç¹èš±
2912329å·æ现æžãå2739149å·æ现æžãè±åœç¹èš±
654690å·æ现æžãå815172å·æ现æžã
Chem.ã26ã4021ïŒ1961ïŒïŒJ.Amer.Chem.Soc.ã
773149ïŒ1955ïŒïŒJ.Amer.Chem.Soc.ã78ã4999
ïŒ1956ïŒçã«èšèŒãããæ¹æ³ã«æºããŠåæããã
ã¹ã«ãã³é žã®ããçŽ åã¢ã«ãã«ãšã¹ãã«é¡ããã
çŽ åã¢ã«ãã«ã¢ãã³é¡ãããçŽ åã¢ã«ãã«ãšãŠå
ç©çãçšããŠã次ã®æç®ã®èšèŒã«åºã¥ããŠå®¹æã«
åæããããšãã§ãããããªãã¡ãç±³åœç¹èš±
2912329å·æ现æžãå2739149å·æ现æžãè±åœç¹èš±
654690å·æ现æžãå815172å·æ现æžã
äžè¬åŒããã«ãã€ãŠç€ºãããååç©ã¯ããã
ã²ã³åéïŒã¢ã«åœãïŒÃ10-7ã¢ã«ãïŒÃ10-3ã¢
ã«ã奜ãŸããã¯ïŒÃ10-6ã¢ã«ãïŒÃ10-3ã¢ã«ãç¹
ã«å¥œãŸããã¯ïŒÃ10-5ã¢ã«ãïŒÃ10-3ã¢ã«ã®å²å
ã§ããã²ã³åéåçä¹³å€äžã«å«æãããã
ã²ã³åéïŒã¢ã«åœãïŒÃ10-7ã¢ã«ãïŒÃ10-3ã¢
ã«ã奜ãŸããã¯ïŒÃ10-6ã¢ã«ãïŒÃ10-3ã¢ã«ãç¹
ã«å¥œãŸããã¯ïŒÃ10-5ã¢ã«ãïŒÃ10-3ã¢ã«ã®å²å
ã§ããã²ã³åéåçä¹³å€äžã«å«æãããã
æ¬çºæã«çšããããå¢æè²çŽ ã¯ãçŽæ¥ã«ä¹³å€äž
ãžåæ£ããããšãã§ããããŸãããããã¯é©åœãª
溶åªãäŸãã°ãã¡ãã«ã¢ã«ã³ãŒã«ããšãã«ã¢ã«ã³
ãŒã«ããããã«ã¢ã«ã³ãŒã«ãã¡ãã«ã»ã«ãœã«ãã
ç¹éæ48â9715ãç±³åœç¹èš±3756830å·ã«èšèŒã®ã
ãã²ã³åã¢ã«ã³ãŒã«ãã¢ã»ãã³ãæ°Žãããªãžã³ãª
ã©ãããã¯ããããã®æ··å溶åªãªã©ã®äžã«æº¶è§£ã
ã溶液ã®åœ¢ã§ãä¹³å€ãžæ·»å ããããšãã§ãããã
ã®ä»ã®æ·»å æ³ãšããŠç¹å ¬æ46â24485å·ãç±³åœç¹
èš±3822135å·ãå3660101å·ãå2912343å·ãå
2996287å·ãå3429835å·ãå3658546å·ã«èšèŒã®
æ¹æ³ãçšããããšãã§ããããŸããã€ãç¹èš±åºé¡
2104283å·ã«èšèŒã®æ¹æ³ãç±³åœç¹èš±3649286å·ã«èš
èŒã®æ¹æ³ãçšããããšãã§ããã
ãžåæ£ããããšãã§ããããŸãããããã¯é©åœãª
溶åªãäŸãã°ãã¡ãã«ã¢ã«ã³ãŒã«ããšãã«ã¢ã«ã³
ãŒã«ããããã«ã¢ã«ã³ãŒã«ãã¡ãã«ã»ã«ãœã«ãã
ç¹éæ48â9715ãç±³åœç¹èš±3756830å·ã«èšèŒã®ã
ãã²ã³åã¢ã«ã³ãŒã«ãã¢ã»ãã³ãæ°Žãããªãžã³ãª
ã©ãããã¯ããããã®æ··å溶åªãªã©ã®äžã«æº¶è§£ã
ã溶液ã®åœ¢ã§ãä¹³å€ãžæ·»å ããããšãã§ãããã
ã®ä»ã®æ·»å æ³ãšããŠç¹å ¬æ46â24485å·ãç±³åœç¹
èš±3822135å·ãå3660101å·ãå2912343å·ãå
2996287å·ãå3429835å·ãå3658546å·ã«èšèŒã®
æ¹æ³ãçšããããšãã§ããããŸããã€ãç¹èš±åºé¡
2104283å·ã«èšèŒã®æ¹æ³ãç±³åœç¹èš±3649286å·ã«èš
èŒã®æ¹æ³ãçšããããšãã§ããã
ãŸãäžèšå¢æè²çŽ ã¯é©åœãªæ¯æäœäžã«å¡åžãã
ãåã«ããã²ã³åéåçä¹³å€äžã«äžæ§ã«åæ£ããŠ
ããããå¿è«ããã²ã³åéä¹³å€ã®èª¿è£œã®ã©ã®éçš
ã«ãåæ£ããããšãã§ããã
ãåã«ããã²ã³åéåçä¹³å€äžã«äžæ§ã«åæ£ããŠ
ããããå¿è«ããã²ã³åéä¹³å€ã®èª¿è£œã®ã©ã®éçš
ã«ãåæ£ããããšãã§ããã
æ¬çºæã®åçä¹³å€ã«ã¯ããã²ã³åéãšããŠãè
åéãæ²èåéãæ²å¡©èåéãå¡©èåéããã³å¡©
åéã®ããããçšããŠãããã奜ãŸããããã²ã³
åéã¯èåéãå¡©èåéãæ²èåéããŸãã¯æ²å¡©
èåéã§ããã
åéãæ²èåéãæ²å¡©èåéãå¡©èåéããã³å¡©
åéã®ããããçšããŠãããã奜ãŸããããã²ã³
åéã¯èåéãå¡©èåéãæ²èåéããŸãã¯æ²å¡©
èåéã§ããã
åçä¹³å€äžã®ããã²ã³åéç²åã¯ãç«æ¹äœãå
«
é¢äœã®ãããªèŠåçïŒregularïŒãªçµæ¶äœãæã
ããã®ã§ãããããŸãçç¶ãæ¿ç¶ãªã©ã®ãããªå€
åçïŒirregularïŒãªçµæ¶åœ¢ããã€ãã®ãããã
ã¯ãããã®çµæ¶åœ¢ã®è€å圢ããã€ãã®ã§ãããã
çš®ã ã®çµæ¶åœ¢ã®ç²åã®æ··åããæã€ãŠãããã
é¢äœã®ãããªèŠåçïŒregularïŒãªçµæ¶äœãæã
ããã®ã§ãããããŸãçç¶ãæ¿ç¶ãªã©ã®ãããªå€
åçïŒirregularïŒãªçµæ¶åœ¢ããã€ãã®ãããã
ã¯ãããã®çµæ¶åœ¢ã®è€å圢ããã€ãã®ã§ãããã
çš®ã ã®çµæ¶åœ¢ã®ç²åã®æ··åããæã€ãŠãããã
ããã²ã³åéç²åã¯å
éšãšè¡šå±€ãšãç°ãªãçžã
ãã€ãŠããŠããåäžãªçžããæã€ãŠããŠãããã
ãŸãæœåãäž»ãšããŠè¡šé¢ã«åœ¢æããããããªç²å
ïŒäŸãã°ãã¬åä¹³å€ïŒã§ããããç²åå éšã«äž»ãš
ããŠåœ¢æããããããªç²åïŒäŸãã°ãå éšæœåå
ä¹³å€ãäºããã¶ãããçŽæ¥å転åä¹³å€ïŒã§ãã€ãŠ
ãããã
ãã€ãŠããŠããåäžãªçžããæã€ãŠããŠãããã
ãŸãæœåãäž»ãšããŠè¡šé¢ã«åœ¢æããããããªç²å
ïŒäŸãã°ãã¬åä¹³å€ïŒã§ããããç²åå éšã«äž»ãš
ããŠåœ¢æããããããªç²åïŒäŸãã°ãå éšæœåå
ä¹³å€ãäºããã¶ãããçŽæ¥å転åä¹³å€ïŒã§ãã€ãŠ
ãããã
æ¬çºæã«çšããããåçä¹³å€ã¯P.Glafkidesè
Chimie et Physique PhotographiqueïŒPaul
Montel瀟åã1967幎ïŒãG.F.Duffinè
Photographic Emulsion ChemistryïŒThe Focal
Pressåã1966幎ïŒãV.L.Zelikman et alè
Making and Coating and Coating
Photographic EmulsionïŒThe Focal Pressåã
1964幎ïŒãªã©ã«èšèŒãããæ¹æ³ãçšããŠèª¿è£œãã
ããšãã§ãããããªãã¡ãé žæ§æ³ãäžæ§æ³ãã¢ã³
ã¢ãã¢æ³çã®ãããã§ãããããŸãå¯æº¶æ§éå¡©ãš
å¯æº¶æ§ããã²ã³å¡©ãåå¿ããã圢åŒãšããŠã¯çåŽ
æ··åæ³ãåææ··åæ³ããããã®çµåããªã©ã®ãã
ããçšããŠãããã
Chimie et Physique PhotographiqueïŒPaul
Montel瀟åã1967幎ïŒãG.F.Duffinè
Photographic Emulsion ChemistryïŒThe Focal
Pressåã1966幎ïŒãV.L.Zelikman et alè
Making and Coating and Coating
Photographic EmulsionïŒThe Focal Pressåã
1964幎ïŒãªã©ã«èšèŒãããæ¹æ³ãçšããŠèª¿è£œãã
ããšãã§ãããããªãã¡ãé žæ§æ³ãäžæ§æ³ãã¢ã³
ã¢ãã¢æ³çã®ãããã§ãããããŸãå¯æº¶æ§éå¡©ãš
å¯æº¶æ§ããã²ã³å¡©ãåå¿ããã圢åŒãšããŠã¯çåŽ
æ··åæ³ãåææ··åæ³ããããã®çµåããªã©ã®ãã
ããçšããŠãããã
ç²åãéã€ãªã³éå°ã®äžã«ãããŠåœ¢æãããæ¹
æ³ïŒããããéæ··åæ³ïŒãçšããããšãã§ããã
åææ··åæ³ã®äžã€ã®åœ¢åŒãšããŠããã²ã³åéã®ç
æããã液çžäžã®pAgãäžå®ã«ä¿ã€æ¹æ³ãããªã
ã¡ããããã³ã³ãããŒã«ãã»ããã«ãžãšããæ³ã
çšããããšãã§ããã
æ³ïŒããããéæ··åæ³ïŒãçšããããšãã§ããã
åææ··åæ³ã®äžã€ã®åœ¢åŒãšããŠããã²ã³åéã®ç
æããã液çžäžã®pAgãäžå®ã«ä¿ã€æ¹æ³ãããªã
ã¡ããããã³ã³ãããŒã«ãã»ããã«ãžãšããæ³ã
çšããããšãã§ããã
ãã®æ¹æ³ã«ãããšãçµæ¶åœ¢ãèŠåçã§ç²åãµã€
ãºãåäžã«è¿ãããã²ã³åéä¹³å€ãããããã
ãºãåäžã«è¿ãããã²ã³åéä¹³å€ãããããã
å¥ã
ã«åœ¢æããïŒçš®ä»¥äžã®ããã²ã³åéä¹³å€ã
æ··åããŠçšããŠãããã
æ··åããŠçšããŠãããã
ãŸããã®ããã²ã³åéç²åã®åœ¢ææã«ã¯ç²åã®
æé·ãã³ã³ãããŒã«ããããã«ããã²ã³åé溶å€
ãšããŠäŸãã°ã¢ã³ã¢ãã¢ãããã³ã«ãªãããã³ã¢
ã³ã¢ã³ãããªãšãŒãã«ååç©ïŒäŸãã°ç±³åœç¹èš±ç¬¬
3271157å·ãå第3574628å·ãå第3704130å·ãå
4297439å·ãå第4276374å·ããªã©ïŒããªã³ååç©
ïŒäŸãã°ç¹éæ53â144319å·ãå第53â82408å·ã
å第55â77737å·ãªã©ïŒãã¢ãã³ååç©ïŒäŸãã°ç¹
éæ54â100717å·ãªã©ïŒãªã©ãçšããããšãã§ã
ãã
æé·ãã³ã³ãããŒã«ããããã«ããã²ã³åé溶å€
ãšããŠäŸãã°ã¢ã³ã¢ãã¢ãããã³ã«ãªãããã³ã¢
ã³ã¢ã³ãããªãšãŒãã«ååç©ïŒäŸãã°ç±³åœç¹èš±ç¬¬
3271157å·ãå第3574628å·ãå第3704130å·ãå
4297439å·ãå第4276374å·ããªã©ïŒããªã³ååç©
ïŒäŸãã°ç¹éæ53â144319å·ãå第53â82408å·ã
å第55â77737å·ãªã©ïŒãã¢ãã³ååç©ïŒäŸãã°ç¹
éæ54â100717å·ãªã©ïŒãªã©ãçšããããšãã§ã
ãã
ããã²ã³åéç²å圢æãŸãã¯ç©ççæã®éçšã«
ãããŠãã«ãããŠã å¡©ãäºéå¡©ãã¿ãªãŠã å¡©ãã€
ãªãžãŠã å¡©ãŸãã¯ãã®é¯å¡©ãããžãŠã å¡©ãŸãã¯ã
ã®é¯å¡©ãéå¡©ãŸãã¯éé¯å¡©ãªã©ãå ±åãããŠãã
ãã
ãããŠãã«ãããŠã å¡©ãäºéå¡©ãã¿ãªãŠã å¡©ãã€
ãªãžãŠã å¡©ãŸãã¯ãã®é¯å¡©ãããžãŠã å¡©ãŸãã¯ã
ã®é¯å¡©ãéå¡©ãŸãã¯éé¯å¡©ãªã©ãå ±åãããŠãã
ãã
ãŸããæ¬çºæã«çšããããå
éšæœååä¹³å€ãšã
ãŠã¯äŸãã°ç±³åœç¹èš±2592250å·ãå3206313å·ãå
3447927å·ãå3761276å·ãåã³å3935014å·çã«
èšèŒãããã³ã³ããŒãžãšã³åä¹³å€ãã³ã¢ïŒã·ãšã«
åä¹³å€ãç°çš®éå±ãå èµãããä¹³å€çãæããã
ãšãã§ããã
ãŠã¯äŸãã°ç±³åœç¹èš±2592250å·ãå3206313å·ãå
3447927å·ãå3761276å·ãåã³å3935014å·çã«
èšèŒãããã³ã³ããŒãžãšã³åä¹³å€ãã³ã¢ïŒã·ãšã«
åä¹³å€ãç°çš®éå±ãå èµãããä¹³å€çãæããã
ãšãã§ããã
ããã²ã³åéä¹³å€ã¯ãéåžžã¯ååŠå¢æãããã
ååŠå¢æã®ããã«ã¯ãäŸãã°H.Frieserç·šDie
Grundlagen der Photographishen Prozesse
mit SilberhalogenidenïŒAkademische
VerlagsgesellschaftïŒ1968ïŒ675ã734é ã«èšèŒ
ã®æ¹æ³ãçšããããšãã§ããã
ååŠå¢æã®ããã«ã¯ãäŸãã°H.Frieserç·šDie
Grundlagen der Photographishen Prozesse
mit SilberhalogenidenïŒAkademische
VerlagsgesellschaftïŒ1968ïŒ675ã734é ã«èšèŒ
ã®æ¹æ³ãçšããããšãã§ããã
ããªãã¡ã掻æ§ãŒã©ãã³ãéãšåå¿ãåŸãç¡«é»
ãå«ãååç©ïŒäŸãã°ãããªç¡«é žå¡©ãããªå°¿çŽ
é¡ãã¡ã«ã«ããååç©é¡ãããŒããã³é¡ïŒãçšã
ãç¡«é»å¢ææ³ïŒéå æ§ç©è³ªïŒäŸãã°ã第äžãã
å¡©ãã¢ãã³é¡ãããã©ãžã³èªå°äœããã«ã ã¢ããž
ã³ã¹ã«ãã€ã³é žãã·ã©ã³ååç©ïŒãçšããéå å¢
ææ³ïŒè²Žéå±ååç©ïŒäŸãã°ãéé¯å¡©ã®ã»ãã
PtãIrãPdãªã©ã®åšæåŸè¡šæã®éå±ã®é¯å¡©ïŒ
ãçšãã貎éå±å¢ææ³ãªã©ãåç¬ãŸãã¯çµåããŠ
çšããããšãã§ããã
ãå«ãååç©ïŒäŸãã°ãããªç¡«é žå¡©ãããªå°¿çŽ
é¡ãã¡ã«ã«ããååç©é¡ãããŒããã³é¡ïŒãçšã
ãç¡«é»å¢ææ³ïŒéå æ§ç©è³ªïŒäŸãã°ã第äžãã
å¡©ãã¢ãã³é¡ãããã©ãžã³èªå°äœããã«ã ã¢ããž
ã³ã¹ã«ãã€ã³é žãã·ã©ã³ååç©ïŒãçšããéå å¢
ææ³ïŒè²Žéå±ååç©ïŒäŸãã°ãéé¯å¡©ã®ã»ãã
PtãIrãPdãªã©ã®åšæåŸè¡šæã®éå±ã®é¯å¡©ïŒ
ãçšãã貎éå±å¢ææ³ãªã©ãåç¬ãŸãã¯çµåããŠ
çšããããšãã§ããã
ãããã®å
·äœäŸã¯ãç¡«é»å¢ææ³ã«ã€ããŠã¯ç±³åœ
ç¹èš±ç¬¬1574944å·ãå第2410689å·ãå第2278947
å·ãå第2728668å·ãå第3656955å·çãéå å¢æ
æ³ã«ã€ããŠã¯ç±³åœç¹èš±ç¬¬2983609å·ãå第2419974
å·ãå第4054458å·çã貎éå±å¢ææ³ã«ã€ããŠã¯
ç±³åœç¹èš±ç¬¬2399083å·ãå第2448060å·ãè±åœç¹èš±
第618061å·çã®åæ现æžã«èšèŒãããŠããã
ç¹èš±ç¬¬1574944å·ãå第2410689å·ãå第2278947
å·ãå第2728668å·ãå第3656955å·çãéå å¢æ
æ³ã«ã€ããŠã¯ç±³åœç¹èš±ç¬¬2983609å·ãå第2419974
å·ãå第4054458å·çã貎éå±å¢ææ³ã«ã€ããŠã¯
ç±³åœç¹èš±ç¬¬2399083å·ãå第2448060å·ãè±åœç¹èš±
第618061å·çã®åæ现æžã«èšèŒãããŠããã
æŽã«å
·äœçãªååŠå¢æå€ãšããŠã¯ãã¢ãªã«ããª
ã«ã«ããããããªå°¿çŽ ããœãžãŠã ã»ããªãµã«ããš
ãŒããã·ã¹ãã³ãªã©ã®ç¡«é»å¢æå€ïŒãã¿ã·ãŠã ã¯
ãããªãŒã¬ã€ãããªã©ã¹ã»ããªãµã«ããšãŒããã
ã¿ã·ãŠã ã¯ãããã©ããŒããªã©ã®è²Žéå±å¢æå€ïŒ
å¡©åã¹ãºãããšãã«ããã©ãžã³ãã¬ãã¯ãã³ãªã©
ã®éå å¢æå€çãå«ãã§ãããããªãªãã·ãšãã¬
ã³ååç©ãããªãªãã·ãããã¬ã³ååç©ãïŒçŽã¢
ã³ã¢ããŠã åºããã€ååç©ãªã©ã®å¢æå€ãå«ãã§
ããã
ã«ã«ããããããªå°¿çŽ ããœãžãŠã ã»ããªãµã«ããš
ãŒããã·ã¹ãã³ãªã©ã®ç¡«é»å¢æå€ïŒãã¿ã·ãŠã ã¯
ãããªãŒã¬ã€ãããªã©ã¹ã»ããªãµã«ããšãŒããã
ã¿ã·ãŠã ã¯ãããã©ããŒããªã©ã®è²Žéå±å¢æå€ïŒ
å¡©åã¹ãºãããšãã«ããã©ãžã³ãã¬ãã¯ãã³ãªã©
ã®éå å¢æå€çãå«ãã§ãããããªãªãã·ãšãã¬
ã³ååç©ãããªãªãã·ãããã¬ã³ååç©ãïŒçŽã¢
ã³ã¢ããŠã åºããã€ååç©ãªã©ã®å¢æå€ãå«ãã§
ããã
æ¬çºæã«çšããããåçä¹³å€ã«ã¯ãæå
ææã®
補é å·¥çšãä¿åäžãããã¯åçåŠçäžã®ã«ããªã
é²æ¢ãããããã¯åçæ§èœãå®å®åãããç®ç
ã§ãçš®ã ã®ååç©ãå«æãããããšãã§ãããã
ãªãã¡ã¢ãŸãŒã«é¡ããšãã°ãã³ãŸãã¢ãŸãªãŠã
å¡©ããããã€ã³ããŸãŒã«é¡ãããªã¢ãŸãŒã«é¡ãã
ã³ãŸããªã¢ãŸãŒã«é¡ããã³ãºã€ãããŸãŒã«é¡ïŒç¹
ã«ãããâãŸãã¯ããã²ã³çœ®æäœïŒïŒãããç°ã¡
ã«ã«ããååç©é¡ããšãã°ã¡ã«ã«ãããã¢ãŸãŒã«
é¡ãã¡ã«ã«ãããã³ãŸãã¢ãŸãŒã«é¡ãã¡ã«ã«ãã
ãã³ãºã€ãããŸãŒã«é¡ãã¡ã«ã«ãããã¢ãžã¢ãŸãŒ
ã«é¡ãã¡ã«ã«ããããã©ãŸãŒã«é¡ïŒç¹ã«ïŒâããš
ãã«âïŒâã¡ã«ã«ããããã©ãŸãŒã«ïŒãã¡ã«ã«ã
ãããªããžã³é¡ïŒã«ã«ããã·ã«åºãã¹ã«ãã³åºãª
ã©ã®æ°Žæº¶æ§ãæããäžèšã®ãããç°ã¡ã«ã«ããå
åç©é¡ïŒããªã±ãååç©ããšãã°ãªããµãŸãªã³ã
ãªã³ïŒã¢ã¶ã€ã³ãã³é¡ããšãã°ããã©ã¢ã¶ã€ã³ã
ã³é¡ïŒç¹ã«ïŒâããããã·çœ®æïŒïŒãïŒã3aã
ïŒïŒããã©ã¢ã¶ã€ã³ãã³é¡ïŒïŒãã³ãŒã³ããªã¹ã«
ãã³é žé¡ïŒãã³ãŒã³ã¹ã«ãã€ã³é žïŒãªã©ã®ãããª
ã«ããªé²æ¢å€ãŸãã¯å®å®å€ãšã«ç¥ãããå€ãã®å
åç©ãå ããããšãã§ããã
補é å·¥çšãä¿åäžãããã¯åçåŠçäžã®ã«ããªã
é²æ¢ãããããã¯åçæ§èœãå®å®åãããç®ç
ã§ãçš®ã ã®ååç©ãå«æãããããšãã§ãããã
ãªãã¡ã¢ãŸãŒã«é¡ããšãã°ãã³ãŸãã¢ãŸãªãŠã
å¡©ããããã€ã³ããŸãŒã«é¡ãããªã¢ãŸãŒã«é¡ãã
ã³ãŸããªã¢ãŸãŒã«é¡ããã³ãºã€ãããŸãŒã«é¡ïŒç¹
ã«ãããâãŸãã¯ããã²ã³çœ®æäœïŒïŒãããç°ã¡
ã«ã«ããååç©é¡ããšãã°ã¡ã«ã«ãããã¢ãŸãŒã«
é¡ãã¡ã«ã«ãããã³ãŸãã¢ãŸãŒã«é¡ãã¡ã«ã«ãã
ãã³ãºã€ãããŸãŒã«é¡ãã¡ã«ã«ãããã¢ãžã¢ãŸãŒ
ã«é¡ãã¡ã«ã«ããããã©ãŸãŒã«é¡ïŒç¹ã«ïŒâããš
ãã«âïŒâã¡ã«ã«ããããã©ãŸãŒã«ïŒãã¡ã«ã«ã
ãããªããžã³é¡ïŒã«ã«ããã·ã«åºãã¹ã«ãã³åºãª
ã©ã®æ°Žæº¶æ§ãæããäžèšã®ãããç°ã¡ã«ã«ããå
åç©é¡ïŒããªã±ãååç©ããšãã°ãªããµãŸãªã³ã
ãªã³ïŒã¢ã¶ã€ã³ãã³é¡ããšãã°ããã©ã¢ã¶ã€ã³ã
ã³é¡ïŒç¹ã«ïŒâããããã·çœ®æïŒïŒãïŒã3aã
ïŒïŒããã©ã¢ã¶ã€ã³ãã³é¡ïŒïŒãã³ãŒã³ããªã¹ã«
ãã³é žé¡ïŒãã³ãŒã³ã¹ã«ãã€ã³é žïŒãªã©ã®ãããª
ã«ããªé²æ¢å€ãŸãã¯å®å®å€ãšã«ç¥ãããå€ãã®å
åç©ãå ããããšãã§ããã
æ¬çºæã®ããã²ã³åéåçä¹³å€ã¯ã·ã¢ã³ã»ã«ã
ã©ãŒãããŒã³ãã»ã«ãã©ãŒãã€ãšããŒã»ã«ãã©ãŒ
ãªã©ã®ã«ã©ãŒã»ã«ãã©ãŒåã³ã«ãã©ãŒãåæ£ãã
ååç©ãå«ãããšãã§ããã
ã©ãŒãããŒã³ãã»ã«ãã©ãŒãã€ãšããŒã»ã«ãã©ãŒ
ãªã©ã®ã«ã©ãŒã»ã«ãã©ãŒåã³ã«ãã©ãŒãåæ£ãã
ååç©ãå«ãããšãã§ããã
ããªãã¡çºè²çŸååŠçã«ãããŠè³éŠæïŒçŽã¢ã
ã³çŸåè¬ïŒäŸãã°ãããšãã¬ã³ãžã¢ãã³èªå°äœ
ããã¢ããããšããŒã«èªå°äœãªã©ïŒãšã®é žåã«ã
ããªã³ã°ã«ãã€ãŠçºè²ãããååç©ãå«ãã§ãã
ããäŸãã°ãããŒã³ã¿ã«ãã©ãŒãšããŠãïŒâãã©
ãŸãã³ã«ãã©ãŒããã©ãŸããã³ãã€ãããŸãŒã«ã«
ãã©ãŒãã·ã¢ãã¢ã»ãã«ã¯ããã³ã«ãã©ãŒãéé
ã¢ã·ã«ã¢ã»ããããªã«ã«ãã©ãŒçããããã€ãšã
ãŒã«ãã©ãŒãšããŠãã¢ã·ã«ã¢ã»ãã¢ããã«ãã©ãŒ
ïŒäŸãã°ãã³ãŸã€ã«ã¢ã»ãã¢ããªãé¡ããããã€
ã«ã¢ã»ãã¢ããªãé¡ïŒãçããããã·ã¢ã³ã«ãã©
ãŒãšããŠãããããŒã«ã«ãã©ãŒãããã³ããšããŒ
ã«ã«ãã©ãŒãçãããããããã®ã«ãã©ãŒã¯åå
äžã«ãã©ã¹ãåºãšãã°ããçæ°Žåºãæããéæ¡æ£
ã®ãã®ãæãŸãããã«ãã©ãŒã¯éã€ãªã³ã«å¯ŸãïŒ
åœéæ§ãããã¯ïŒåœéæ§ã®ã©ã¡ãã§ãããããŸã
è²è£æ£ã®å¹æããã€ã«ã©ãŒãã«ãã©ãŒããããã¯
çŸåã«ãšããªã€ãŠçŸåæå¶å€ãæŸåºããã«ãã©ãŒ
ïŒããããDIRã«ãã©ãŒïŒã§ãã€ãŠãããã
ã³çŸåè¬ïŒäŸãã°ãããšãã¬ã³ãžã¢ãã³èªå°äœ
ããã¢ããããšããŒã«èªå°äœãªã©ïŒãšã®é žåã«ã
ããªã³ã°ã«ãã€ãŠçºè²ãããååç©ãå«ãã§ãã
ããäŸãã°ãããŒã³ã¿ã«ãã©ãŒãšããŠãïŒâãã©
ãŸãã³ã«ãã©ãŒããã©ãŸããã³ãã€ãããŸãŒã«ã«
ãã©ãŒãã·ã¢ãã¢ã»ãã«ã¯ããã³ã«ãã©ãŒãéé
ã¢ã·ã«ã¢ã»ããããªã«ã«ãã©ãŒçããããã€ãšã
ãŒã«ãã©ãŒãšããŠãã¢ã·ã«ã¢ã»ãã¢ããã«ãã©ãŒ
ïŒäŸãã°ãã³ãŸã€ã«ã¢ã»ãã¢ããªãé¡ããããã€
ã«ã¢ã»ãã¢ããªãé¡ïŒãçããããã·ã¢ã³ã«ãã©
ãŒãšããŠãããããŒã«ã«ãã©ãŒãããã³ããšããŒ
ã«ã«ãã©ãŒãçãããããããã®ã«ãã©ãŒã¯åå
äžã«ãã©ã¹ãåºãšãã°ããçæ°Žåºãæããéæ¡æ£
ã®ãã®ãæãŸãããã«ãã©ãŒã¯éã€ãªã³ã«å¯ŸãïŒ
åœéæ§ãããã¯ïŒåœéæ§ã®ã©ã¡ãã§ãããããŸã
è²è£æ£ã®å¹æããã€ã«ã©ãŒãã«ãã©ãŒããããã¯
çŸåã«ãšããªã€ãŠçŸåæå¶å€ãæŸåºããã«ãã©ãŒ
ïŒããããDIRã«ãã©ãŒïŒã§ãã€ãŠãããã
ãŸãDIRã«ãã©ãŒä»¥å€ã«ããã«ãããªã³ã°åå¿
ã®çæç©ãç¡è²ã§ãã€ãŠçŸåæå¶å€ãæŸåºããç¡
åè²DIRã«ãããªã³ã°ååç©ãå«ãã§ãããã
ã®çæç©ãç¡è²ã§ãã€ãŠçŸåæå¶å€ãæŸåºããç¡
åè²DIRã«ãããªã³ã°ååç©ãå«ãã§ãããã
ã«ã©ãŒã«ãã©ãŒäžãšãã«ããŒã³ã¿ã»ã«ãã©ãŒã
å«ãŸããŠãããããŒã³ã¿çºè²ã«ãã©ãŒã®å ·äœäŸ
ã¯ãç±³åœç¹èš±ç¬¬2600788å·ãå2983608å·ãå
3062653å·ãå3127269å·ãå3311476å·ãå
3419391å·ãå3519429å·ãå3558319å·ãå
3582322å·ãå3615506å·ãå3834908å·ãå
3891445å·ã西ç¬ç¹èš±1810464å·ã西ç¬ç¹èš±åºé¡
ïŒOLSïŒ2408665å·ãå2417945å·ãå2418959å·ã
å2424467å·ãç¹å ¬æ40â6031å·ãç¹éæ52â
58922å·ãå49â129538å·ãå49â74027å·ãå50
â159336å·ãå52â42121å·ãå49â74028å·ãå
50â60233å·ãå51â26541å·ãå53â55122å·ã
ç¹é¡æ54â136497å·ãç¹é¡æ54â163167å·ãç¹é¡
æ54â163168å·ãªã©ã«èšèŒã®ãã®ã§ããã
å«ãŸããŠãããããŒã³ã¿çºè²ã«ãã©ãŒã®å ·äœäŸ
ã¯ãç±³åœç¹èš±ç¬¬2600788å·ãå2983608å·ãå
3062653å·ãå3127269å·ãå3311476å·ãå
3419391å·ãå3519429å·ãå3558319å·ãå
3582322å·ãå3615506å·ãå3834908å·ãå
3891445å·ã西ç¬ç¹èš±1810464å·ã西ç¬ç¹èš±åºé¡
ïŒOLSïŒ2408665å·ãå2417945å·ãå2418959å·ã
å2424467å·ãç¹å ¬æ40â6031å·ãç¹éæ52â
58922å·ãå49â129538å·ãå49â74027å·ãå50
â159336å·ãå52â42121å·ãå49â74028å·ãå
50â60233å·ãå51â26541å·ãå53â55122å·ã
ç¹é¡æ54â136497å·ãç¹é¡æ54â163167å·ãç¹é¡
æ54â163168å·ãªã©ã«èšèŒã®ãã®ã§ããã
é»è²çºè²ã«ãã©ãŒã®å
·äœäŸã¯ç±³åœç¹èš±2875057
å·ãå3265506å·ãå3408194å·ãå355155å·ãå
3582322å·ãå3725072å·ãå3891445å·ã西ç¬ç¹
èš±1547868å·ã西ç¬åºé¡å ¬é2219917å·ãå
2261361å·ãå2414006å·ãè±åœç¹èš±1425020å·ã
ç¹å ¬æ51â10783å·ãç¹éæ47â26133å·ãå48â
73147å·ãå51â102636å·ãå50â6341å·ãå50
â123342å·ãå50â130442å·ãå51â21827å·ã
å50â87650å·ãå52â82424å·ãå52â115219å·
ãªã©ã«èšèŒããããã®ã§ããã
å·ãå3265506å·ãå3408194å·ãå355155å·ãå
3582322å·ãå3725072å·ãå3891445å·ã西ç¬ç¹
èš±1547868å·ã西ç¬åºé¡å ¬é2219917å·ãå
2261361å·ãå2414006å·ãè±åœç¹èš±1425020å·ã
ç¹å ¬æ51â10783å·ãç¹éæ47â26133å·ãå48â
73147å·ãå51â102636å·ãå50â6341å·ãå50
â123342å·ãå50â130442å·ãå51â21827å·ã
å50â87650å·ãå52â82424å·ãå52â115219å·
ãªã©ã«èšèŒããããã®ã§ããã
ã·ã¢ã³ã«ãã©ãŒã®å
·äœäŸã¯ç±³åœç¹èš±2369929å·ã
å2434272å·ãå2474293å·ãå2521908å·ãå
2895826å·ãå3034892å·ãå3311476å·ãå
3458315å·ãå3476563å·ãå3583971å·ãå
3591383å·ãå3767411å·ãå4004929å·ã西ç¬ç¹
èš±åºé¡ïŒOLSïŒ2414830å·ãå2454329å·ãç¹é
æ48â59838å·ãå51â26034å·ãå48â5055å·ã
å51â146828å·ãå52â69624å·ãå52â90932å·
ã«èšèŒã®ãã®ã§ããã
å2434272å·ãå2474293å·ãå2521908å·ãå
2895826å·ãå3034892å·ãå3311476å·ãå
3458315å·ãå3476563å·ãå3583971å·ãå
3591383å·ãå3767411å·ãå4004929å·ã西ç¬ç¹
èš±åºé¡ïŒOLSïŒ2414830å·ãå2454329å·ãç¹é
æ48â59838å·ãå51â26034å·ãå48â5055å·ã
å51â146828å·ãå52â69624å·ãå52â90932å·
ã«èšèŒã®ãã®ã§ããã
ã«ã©ãŒãã»ã«ãã©ãŒãšããŠã¯äŸãã°ç±³åœç¹èš±
3476560å·ãç¹å ¬æ44â2016å·ãå38â22335å·ã
å42â11304å·ãå44â32461å·ãç¹éæ51â
26034å·æ现æžãå52â42121å·æ现æžã西ç¬ç¹èš±
åºé¡ïŒOLSïŒ2418959å·ã«èšèŒã®ãã®ã䜿çšã§ã
ãã
3476560å·ãç¹å ¬æ44â2016å·ãå38â22335å·ã
å42â11304å·ãå44â32461å·ãç¹éæ51â
26034å·æ现æžãå52â42121å·æ现æžã西ç¬ç¹èš±
åºé¡ïŒOLSïŒ2418959å·ã«èšèŒã®ãã®ã䜿çšã§ã
ãã
DIRã«ãã©ãŒãšããŠã¯ãããšãã°ç±³åœç¹èš±
3227554å·ãå3617291å·ãå3701783å·ãå
3790384å·ãå3632345å·ã西ç¬ç¹èš±åºé¡ïŒOLSïŒ
2414006å·ãå2454301å·ãå2454329å·ãè±åœç¹
èš±953454å·ãç¹éæ52â69624å·ãå49â122335
å·ãç¹å ¬æ51â16141å·ã«èšèŒããããã®ã䜿çš
ã§ããã
3227554å·ãå3617291å·ãå3701783å·ãå
3790384å·ãå3632345å·ã西ç¬ç¹èš±åºé¡ïŒOLSïŒ
2414006å·ãå2454301å·ãå2454329å·ãè±åœç¹
èš±953454å·ãç¹éæ52â69624å·ãå49â122335
å·ãç¹å ¬æ51â16141å·ã«èšèŒããããã®ã䜿çš
ã§ããã
DIRã«ãã©ãŒä»¥å€ã«ãçŸåã«ãšããªã€ãŠçŸåæ
å¶å€ãæŸåºããååç©ããæå ææäžã«å«ãã§ã
ãããäŸãã°ç±³åœç¹èš±3297445å·ãå3379529å·ã
西ç¬ç¹èš±åºé¡ïŒOLSïŒ2417914å·ãç¹éæ52â
15271å·ãç¹éæ53â9116å·ã«èšèŒã®ãã®ã䜿çš
ã§ããã
å¶å€ãæŸåºããååç©ããæå ææäžã«å«ãã§ã
ãããäŸãã°ç±³åœç¹èš±3297445å·ãå3379529å·ã
西ç¬ç¹èš±åºé¡ïŒOLSïŒ2417914å·ãç¹éæ52â
15271å·ãç¹éæ53â9116å·ã«èšèŒã®ãã®ã䜿çš
ã§ããã
ã«ãã©ãŒãããã²ã³åéä¹³å€å±€ã«å°å
¥ããã«ã¯
å ¬ç¥ã®æ¹æ³ããšãã°ç±³åœç¹èš±2322027å·ã«èšèŒã®
æ¹æ³ãªã©ãçšãããããããšãã°ãã¿ãŒã«é žã¢ã«
ãã«ãšã¹ãã«ïŒãžããã«ãã¿ã¬ãŒãããžãªã¯ãã«
ãã¿ã¬ãŒããªã©ïŒããªã³é žãšã¹ãã«ïŒãžããšãã«
ããªã¹ããšãŒããããªããšãã«ããªã¹ããšãŒãã
ããªã¯ã¬ãžã«ããªã·ããšãŒãããžãªã¯ãã«ããã«
ããªã¹ããšãŒãïŒããªã©ããŸãã¯æ²žç¹çŽ30âä¹è³
150âã®ææ©æº¶åªãããšãã°é ¢é žãšãã«ãé ¢é žã
ãã«ã®ããšãäœçŽã¢ã«ãã«ã¢ã»ããŒããããããª
ã³é žãšãã«ãïŒçŽããã«ã¢ã«ã³ãŒã«ãçã«æº¶è§£ã
ãã®ã¡ã芪氎æ§ã³ãã€ãã«åæ£ããããäžèšã®é«
沞ç¹ææ©æº¶åªãšäœæ²žç¹ææ©æº¶åªãšãæ··åããŠçšã
ãŠãããã
å ¬ç¥ã®æ¹æ³ããšãã°ç±³åœç¹èš±2322027å·ã«èšèŒã®
æ¹æ³ãªã©ãçšãããããããšãã°ãã¿ãŒã«é žã¢ã«
ãã«ãšã¹ãã«ïŒãžããã«ãã¿ã¬ãŒãããžãªã¯ãã«
ãã¿ã¬ãŒããªã©ïŒããªã³é žãšã¹ãã«ïŒãžããšãã«
ããªã¹ããšãŒããããªããšãã«ããªã¹ããšãŒãã
ããªã¯ã¬ãžã«ããªã·ããšãŒãããžãªã¯ãã«ããã«
ããªã¹ããšãŒãïŒããªã©ããŸãã¯æ²žç¹çŽ30âä¹è³
150âã®ææ©æº¶åªãããšãã°é ¢é žãšãã«ãé ¢é žã
ãã«ã®ããšãäœçŽã¢ã«ãã«ã¢ã»ããŒããããããª
ã³é žãšãã«ãïŒçŽããã«ã¢ã«ã³ãŒã«ãçã«æº¶è§£ã
ãã®ã¡ã芪氎æ§ã³ãã€ãã«åæ£ããããäžèšã®é«
沞ç¹ææ©æº¶åªãšäœæ²žç¹ææ©æº¶åªãšãæ··åããŠçšã
ãŠãããã
æ¬çºæã®åçä¹³å€ã«ã¯æ床äžæãã³ã³ãã©ã¹ã
äžæããŸãã¯çŸåä¿é²ã®ç®çã§ãäŸãã°ããªã¢ã«
ãã¬ã³ãªãã·ããŸãã¯ãã®ãšãŒãã«ããšã¹ãã«ã
ã¢ãã³ãªã©ã®èªå°äœãããªãšãŒãã«ååç©ãããª
ã¢ã«ããªãªã³é¡ãåçŽã¢ã³ã¢ããŠã å¡©ååç©ããŠ
ã¬ã¿ã³èªå°äœãå°¿çŽ èªå°äœãã€ãããŸãŒã«èªå°
äœãïŒâãã©ãŸãªãã³é¡çãå«ãã§ãããã
äžæããŸãã¯çŸåä¿é²ã®ç®çã§ãäŸãã°ããªã¢ã«
ãã¬ã³ãªãã·ããŸãã¯ãã®ãšãŒãã«ããšã¹ãã«ã
ã¢ãã³ãªã©ã®èªå°äœãããªãšãŒãã«ååç©ãããª
ã¢ã«ããªãªã³é¡ãåçŽã¢ã³ã¢ããŠã å¡©ååç©ããŠ
ã¬ã¿ã³èªå°äœãå°¿çŽ èªå°äœãã€ãããŸãŒã«èªå°
äœãïŒâãã©ãŸãªãã³é¡çãå«ãã§ãããã
æ¬çºæã®ããã²ã³åéåçä¹³å€ã«ã¯ãã€ã«ã¿ãŒ
ææãšããŠããããã¯ã€ã©ãžãšãŒã·ãšã³é²æ¢ãã®
ä»çš®ã ã®ç®çã§ã氎溶æ§ææïŒäŸãã°ãªããœããŒ
ã«ææïŒãããªããœããŒã«ææåã³ã¡ãã·ã¢ãã³
ææïŒãå«æããŠãããã
ææãšããŠããããã¯ã€ã©ãžãšãŒã·ãšã³é²æ¢ãã®
ä»çš®ã ã®ç®çã§ã氎溶æ§ææïŒäŸãã°ãªããœããŒ
ã«ææïŒãããªããœããŒã«ææåã³ã¡ãã·ã¢ãã³
ææïŒãå«æããŠãããã
æ¬çºæã®åçä¹³å€ã«å¡åžå©å€ã垯é»é²æ¢ãã¹ã
ãªæ§æ¹è¯ãä¹³ååæ£ãæ¥çé²æ¢ããã³åçç¹æ§æ¹
è¯ïŒããšãã°çŸåä¿é²ã硬調åãå¢æïŒãªã©çš®ã
ã®ç®çã§çš®ã ã®çé¢æŽ»æ§å€ãå«ãã§ãããã
ãªæ§æ¹è¯ãä¹³ååæ£ãæ¥çé²æ¢ããã³åçç¹æ§æ¹
è¯ïŒããšãã°çŸåä¿é²ã硬調åãå¢æïŒãªã©çš®ã
ã®ç®çã§çš®ã ã®çé¢æŽ»æ§å€ãå«ãã§ãããã
ããšãã°ãµããã³ïŒã¹ããã€ãç³»ïŒãã¢ã«ãã¬
ã³ãªããµã€ãèªå°äœïŒäŸãã°ããªãšãã¬ã³ã°ãªã³
ãŒã«ãããªãšãã¬ã³ã°ãªã³ãŒã«ã¢ã«ãã«ãšãŒãã«
é¡ãã°ãªã·ããŒã«èªå°äœãå€äŸ¡ã¢ã«ã³ãŒã«ã®èèª
é žãšã¹ãã«é¡ãç³ã®ã¢ã«ãã«ãšã¹ãã«é¡ãªã©ã®é
ã€ãªã³æ§çé¢æŽ»æ§å€ïŒã¢ã«ãã«ã«ã«ãã³é žå¡©ãã¢
ã«ãã«ã¹ã«ããªã³é žå¡©ãã¢ã«ãã«ãã³ãŒã³ã¹ã«ã
ãªã³é žå¡©ãã¢ã«ãã«ç¡«é žãšã¹ãã«é¡ããªã©ã®äž¡æ§
çé¢æŽ»æ§å€ïŒã¢ã«ãã«ã¢ãã³å¡©é¡ãèèªæããã
ã¯è³éŠæ第ïŒçŽã¢ã³ã¢ããŠã å¡©é¡ãããªãžããŠ
ã ãã€ãããŸãªãŠã ãªã©ã®è€çŽ ç°ç¬¬ïŒçŽã¢ã³ã¢ã
ãŠã å¡©é¡ããªã©ã®ã«ããªã³çé¢æŽ»æ§å€ãçšããã
ãšãã§ããã
ã³ãªããµã€ãèªå°äœïŒäŸãã°ããªãšãã¬ã³ã°ãªã³
ãŒã«ãããªãšãã¬ã³ã°ãªã³ãŒã«ã¢ã«ãã«ãšãŒãã«
é¡ãã°ãªã·ããŒã«èªå°äœãå€äŸ¡ã¢ã«ã³ãŒã«ã®èèª
é žãšã¹ãã«é¡ãç³ã®ã¢ã«ãã«ãšã¹ãã«é¡ãªã©ã®é
ã€ãªã³æ§çé¢æŽ»æ§å€ïŒã¢ã«ãã«ã«ã«ãã³é žå¡©ãã¢
ã«ãã«ã¹ã«ããªã³é žå¡©ãã¢ã«ãã«ãã³ãŒã³ã¹ã«ã
ãªã³é žå¡©ãã¢ã«ãã«ç¡«é žãšã¹ãã«é¡ããªã©ã®äž¡æ§
çé¢æŽ»æ§å€ïŒã¢ã«ãã«ã¢ãã³å¡©é¡ãèèªæããã
ã¯è³éŠæ第ïŒçŽã¢ã³ã¢ããŠã å¡©é¡ãããªãžããŠ
ã ãã€ãããŸãªãŠã ãªã©ã®è€çŽ ç°ç¬¬ïŒçŽã¢ã³ã¢ã
ãŠã å¡©é¡ããªã©ã®ã«ããªã³çé¢æŽ»æ§å€ãçšããã
ãšãã§ããã
æ¬çºæãå®æœããã«éããŠäžèšã®å
¬ç¥ã®éè²é²
æ¢å€ã䜵çšããããšãã§ãããŸãæ¬çºæã«çšãã
è²åå®å®å€ã¯åç¬ãŸãã¯ïŒçš®ä»¥äžäœµçšããããšã
ã§ãããå ¬ç¥ã®éè²é²æ¢å€ãšããŠã¯ããã€ããã
ãã³èªå°äœã没é£åé žèªå°äœãïœâã¢ã«ã³ãã·ã
ãšããŒã«é¡ãïœâãªãã·ããšããŒã«èªå°äœåã³ã
ã¹ããšããŒã«é¡çãããã
æ¢å€ã䜵çšããããšãã§ãããŸãæ¬çºæã«çšãã
è²åå®å®å€ã¯åç¬ãŸãã¯ïŒçš®ä»¥äžäœµçšããããšã
ã§ãããå ¬ç¥ã®éè²é²æ¢å€ãšããŠã¯ããã€ããã
ãã³èªå°äœã没é£åé žèªå°äœãïœâã¢ã«ã³ãã·ã
ãšããŒã«é¡ãïœâãªãã·ããšããŒã«èªå°äœåã³ã
ã¹ããšããŒã«é¡çãããã
æ¬çºæãçšããŠäœãããåçæå
ææã«ã¯åç
ä¹³å€å±€ãã®ä»ã®èŠªæ°Žæ§ã³ãã€ãå±€ã«å¯žåºŠå®å®æ§ã®
æ¹è¯ãªã©ã®ç®çã§ãæ°Žäžæº¶ãŸãã¯é£æº¶æ§åæããª
ããŒã®åæ£ç©ãå«ãããšãã§ãããããšãã°ã¢ã«
ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããã¢ã«ã³ãã·ã¢ã«ãã«
ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããã°ãªã·ãžã«ïŒã¡ã¿ïŒã¢ã¯
ãªã¬ãŒããïŒã¡ã¿ïŒã¢ã¯ãªã«ã¢ãããããã«ãšã¹
ãã«ïŒããšãã°é ¢é žããã«ïŒãã¢ã¯ãªããããªã«ã
ãªã¬ãã€ã³ãã¹ãã¬ã³ãªã©ã®åç¬ãããã¯çµå
ãããŸãã¯ããããšã¢ã¯ãªã«é žãã¡ã¿ã¢ã¯ãªã«
é žãαïŒÎ²âäžé£œåãžã«ã«ãã³é žãããããã·ã¢
ã«ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããã¹ã«ããªã¢ã«ãã«
ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããã¹ãã¬ã³ã¹ã«ããªã³é žãª
ã©ãšã®çµåããåéäœæåãšããããªããŒãçšã
ãããšãã§ããã
ä¹³å€å±€ãã®ä»ã®èŠªæ°Žæ§ã³ãã€ãå±€ã«å¯žåºŠå®å®æ§ã®
æ¹è¯ãªã©ã®ç®çã§ãæ°Žäžæº¶ãŸãã¯é£æº¶æ§åæããª
ããŒã®åæ£ç©ãå«ãããšãã§ãããããšãã°ã¢ã«
ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããã¢ã«ã³ãã·ã¢ã«ãã«
ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããã°ãªã·ãžã«ïŒã¡ã¿ïŒã¢ã¯
ãªã¬ãŒããïŒã¡ã¿ïŒã¢ã¯ãªã«ã¢ãããããã«ãšã¹
ãã«ïŒããšãã°é ¢é žããã«ïŒãã¢ã¯ãªããããªã«ã
ãªã¬ãã€ã³ãã¹ãã¬ã³ãªã©ã®åç¬ãããã¯çµå
ãããŸãã¯ããããšã¢ã¯ãªã«é žãã¡ã¿ã¢ã¯ãªã«
é žãαïŒÎ²âäžé£œåãžã«ã«ãã³é žãããããã·ã¢
ã«ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããã¹ã«ããªã¢ã«ãã«
ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããã¹ãã¬ã³ã¹ã«ããªã³é žãª
ã©ãšã®çµåããåéäœæåãšããããªããŒãçšã
ãããšãã§ããã
æ¬çºæã®åçä¹³å€ã«ã¯ç¡æ©ãŸãã¯ææ©ã®ç¡¬èå€
ãå«æããŠãããäŸãã°ã¯ãã å¡©ïŒã¯ãã æã°
ããé ¢é žã¯ãã ãªã©ïŒãã¢ã«ãããé¡ïŒãã«ã ã¢
ã«ããããã°ãªãªããµãŒã«ãã°ã«ã¿ãŒã«ã¢ã«ãã
ããªã©ïŒã掻æ§ããã«ååç©ïŒïŒïŒïŒïŒïŒâããª
ã¢ã¯ãªãã€ã«âãããµãããâïœâããªã¢ãžã³ã
ïŒïŒïŒâããã«ã¹ã«ããã«âïŒâãããããŒã«ãª
ã©ïŒã掻æ§ããã²ã³ååç©ïŒïŒïŒïŒâãžã¯ãã«â
ïŒâããããã·âïœâããªã¢ãžã³ãªã©ïŒããªã©ã
åç¬ãŸãã¯çµåãããŠçšããããšãã§ããã
ãå«æããŠãããäŸãã°ã¯ãã å¡©ïŒã¯ãã æã°
ããé ¢é žã¯ãã ãªã©ïŒãã¢ã«ãããé¡ïŒãã«ã ã¢
ã«ããããã°ãªãªããµãŒã«ãã°ã«ã¿ãŒã«ã¢ã«ãã
ããªã©ïŒã掻æ§ããã«ååç©ïŒïŒïŒïŒïŒïŒâããª
ã¢ã¯ãªãã€ã«âãããµãããâïœâããªã¢ãžã³ã
ïŒïŒïŒâããã«ã¹ã«ããã«âïŒâãããããŒã«ãª
ã©ïŒã掻æ§ããã²ã³ååç©ïŒïŒïŒïŒâãžã¯ãã«â
ïŒâããããã·âïœâããªã¢ãžã³ãªã©ïŒããªã©ã
åç¬ãŸãã¯çµåãããŠçšããããšãã§ããã
æ¬çºæãçšããŠäœãããæå
ææã¯è²ã«ããªé²
æ¢å€ãšããŠããã€ããããã³èªå°äœãã¢ããããš
ããŒã«èªå°äœã没é£åé žèªå°äœãã¢ã¹ã³ã«ãã³é ž
èªå°äœãªã©ãå«æããŠãããã
æ¢å€ãšããŠããã€ããããã³èªå°äœãã¢ããããš
ããŒã«èªå°äœã没é£åé žèªå°äœãã¢ã¹ã³ã«ãã³é ž
èªå°äœãªã©ãå«æããŠãããã
æ¬çºæãçšããŠäœãããæå
ææã«ã¯èŠªæ°Žæ§ã³
ãã€ãå±€ã«çŽ«å€ç·åžåå€ãå«ãã§ãããããšãã°
ã¢ãªãŒã«åºã§çœ®æããããã³ãŸããªã¢ãŸãŒã«åå
ç©ïŒâãã¢ãŸãªãã³ååç©ããã³ãŸããšãã³åå
ç©ãæ¡ç®é žãšã¹ãã«ååç©ããã¿ãžãšã³ååç©ã
ãã³ãŸãªããµãŸãŒã«ååç©ãããã«çŽ«å€ç·åžåæ§
ããªããŒãªã©ãçšããããšãã§ããããããã®çŽ«
å€ç·åžåå€ã¯äžèšèŠªæ°Žæ§ã³ãã€ãå±€äžã«åºå®ãã
ãŠãããã
ãã€ãå±€ã«çŽ«å€ç·åžåå€ãå«ãã§ãããããšãã°
ã¢ãªãŒã«åºã§çœ®æããããã³ãŸããªã¢ãŸãŒã«åå
ç©ïŒâãã¢ãŸãªãã³ååç©ããã³ãŸããšãã³åå
ç©ãæ¡ç®é žãšã¹ãã«ååç©ããã¿ãžãšã³ååç©ã
ãã³ãŸãªããµãŸãŒã«ååç©ãããã«çŽ«å€ç·åžåæ§
ããªããŒãªã©ãçšããããšãã§ããããããã®çŽ«
å€ç·åžåå€ã¯äžèšèŠªæ°Žæ§ã³ãã€ãå±€äžã«åºå®ãã
ãŠãããã
æ¬çºæãçšããŠäœãããæå
ææã«ãããŠã芪
æ°Žæ§ã³ãã€ãå±€ã«ææã玫å€ç·åžåå€ãªã©ãå«æ
ãããå Žåã«ããããã¯ã«ããªã³æ§ããªããŒãªã©
ã«ãã€ãŠåªæãããŠãããã
æ°Žæ§ã³ãã€ãå±€ã«ææã玫å€ç·åžåå€ãªã©ãå«æ
ãããå Žåã«ããããã¯ã«ããªã³æ§ããªããŒãªã©
ã«ãã€ãŠåªæãããŠãããã
以äžãè¿°ã¹ãçš®ã
ã®æ·»å å€ã«é¢ããŠãå
·äœçã«
ã¯ãResearch Disclosure Vol.176ïŒ1978ãXIIïŒ
RDâ17643ãªã©ã«èšèŒãããŠããã
ã¯ãResearch Disclosure Vol.176ïŒ1978ãXIIïŒ
RDâ17643ãªã©ã«èšèŒãããŠããã
æ¬çºæã«çšããããããã²ã³åéåçä¹³å€ã«ã¯
ä¿è·ã³ãã€ããšããŠãŒã©ãã³ã®ã»ãã«ãã¿ã«åãŒ
ã©ãã³ãããã³åãŒã©ãã³ã®ãããªã¢ã·ã«åãŒã©
ãã³ãããããã·ãšãã«ã»ã«ããŒãºããã«ã«ãã
ã·ã¡ãã«ã»ã«ããŒã¹ã®ãããªã»ã«ããŒãºååç©ïŒ
ããã¹ããªã³ã®ãããªå¯æº¶æ§ã§ãã·ãïŒããªãã
ã«ã¢ã«ã³ãŒã«ãããªããã«ãããªãã³ãããªã¢ã¯
ãªã«ã¢ãããããªã¹ãã¬ã³ã¹ã«ãã³é žã®ãããªèŠª
æ°Žæ§ããªããŒã寞床å®å®åã®ããã®å¯å¡å€ãã©ã
ãã¯ã¹ããªããŒããããå€ãå ããããããå®æ
ïŒfinishedïŒä¹³å€ã¯ãé©åãªæ¯æäœãäŸãã°ãã©
ã€ã¿çŽãã¬ãžã³ã³ãŒãçŽãåæçŽãããªã¢ã»ããŒ
ããã€ã«ã ãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããã€ã«
ã ããã®ä»ã®ãã©ã¹ããã¯ããŒã¹ãŸãã¯ã¬ã©ã¹æ¿
ã®äžã«å¡åžãããã
ä¿è·ã³ãã€ããšããŠãŒã©ãã³ã®ã»ãã«ãã¿ã«åãŒ
ã©ãã³ãããã³åãŒã©ãã³ã®ãããªã¢ã·ã«åãŒã©
ãã³ãããããã·ãšãã«ã»ã«ããŒãºããã«ã«ãã
ã·ã¡ãã«ã»ã«ããŒã¹ã®ãããªã»ã«ããŒãºååç©ïŒ
ããã¹ããªã³ã®ãããªå¯æº¶æ§ã§ãã·ãïŒããªãã
ã«ã¢ã«ã³ãŒã«ãããªããã«ãããªãã³ãããªã¢ã¯
ãªã«ã¢ãããããªã¹ãã¬ã³ã¹ã«ãã³é žã®ãããªèŠª
æ°Žæ§ããªããŒã寞床å®å®åã®ããã®å¯å¡å€ãã©ã
ãã¯ã¹ããªããŒããããå€ãå ããããããå®æ
ïŒfinishedïŒä¹³å€ã¯ãé©åãªæ¯æäœãäŸãã°ãã©
ã€ã¿çŽãã¬ãžã³ã³ãŒãçŽãåæçŽãããªã¢ã»ããŒ
ããã€ã«ã ãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããã€ã«
ã ããã®ä»ã®ãã©ã¹ããã¯ããŒã¹ãŸãã¯ã¬ã©ã¹æ¿
ã®äžã«å¡åžãããã
åçåãåŸãããã®é²å
ã¯éåžžã®æ¹æ³ãçšããŠ
è¡ãªãã°ãããããªãã¡ãèªç¶å ïŒæ¥å ïŒãã¿ã³
ã°ã¹ãã³é»ç¯ãè¢å ç¯ãæ°Žéç¯ããã»ãã³ã¢ãŒã¯
ç¯ãççŽ ã¢ãŒã¯ç¯ãããšãã³ãã©ãã·ãŠç¯ãé°æ¥µ
ç·ç®¡ãã©ã€ã³ã°ã¹ããããªã©å ¬ç¥ã®å€çš®ã®å æºã
ãããã§ãçšããããšãã§ãããé²å æéã¯éåžž
ã«ã¡ã©ã§çšããããïŒïŒ1000ç§ããïŒç§ã®é²å æ
éã¯ãã¡ãããïŒïŒ1000ç§ããçãé²å ãããšã
ã°ãã»ãã³éå ç¯ãé°æ¥µç·ç®¡ãçšããïŒïŒ104ã
ïŒïŒ106ç§ã®é²å ãçšããããšãã§ããããïŒç§
ããé·ãé²å ãçšããããšãã§ãããå¿ èŠã«å¿ã
ãŠè²ãã€ã«ã¿ãŒã§é²å ã«çšããããå ã®åå çµæ
ã調ç¯ããããšãã§ãããé²å ã«ã¬ãŒã¶ãŒå ãçš
ããããšãã§ããããŸãé»åç·ãç·ãγç·ãα
ç·ãªã©ã«ãã€ãŠå±èµ·ãããè¢å äœããæŸåºããå
ã«ãã€ãŠé²å ãããŠãããã
è¡ãªãã°ãããããªãã¡ãèªç¶å ïŒæ¥å ïŒãã¿ã³
ã°ã¹ãã³é»ç¯ãè¢å ç¯ãæ°Žéç¯ããã»ãã³ã¢ãŒã¯
ç¯ãççŽ ã¢ãŒã¯ç¯ãããšãã³ãã©ãã·ãŠç¯ãé°æ¥µ
ç·ç®¡ãã©ã€ã³ã°ã¹ããããªã©å ¬ç¥ã®å€çš®ã®å æºã
ãããã§ãçšããããšãã§ãããé²å æéã¯éåžž
ã«ã¡ã©ã§çšããããïŒïŒ1000ç§ããïŒç§ã®é²å æ
éã¯ãã¡ãããïŒïŒ1000ç§ããçãé²å ãããšã
ã°ãã»ãã³éå ç¯ãé°æ¥µç·ç®¡ãçšããïŒïŒ104ã
ïŒïŒ106ç§ã®é²å ãçšããããšãã§ããããïŒç§
ããé·ãé²å ãçšããããšãã§ãããå¿ èŠã«å¿ã
ãŠè²ãã€ã«ã¿ãŒã§é²å ã«çšããããå ã®åå çµæ
ã調ç¯ããããšãã§ãããé²å ã«ã¬ãŒã¶ãŒå ãçš
ããããšãã§ããããŸãé»åç·ãç·ãγç·ãα
ç·ãªã©ã«ãã€ãŠå±èµ·ãããè¢å äœããæŸåºããå
ã«ãã€ãŠé²å ãããŠãããã
æ¬çºæã®åå
å¢æè²çŽ ã¯ãçš®ã
ã®ã«ã©ãŒåã³çœ
é»ææçšã®ããã²ã³åéåçä¹³å€ã®å¢æã«çšãã
ãããçšããããä¹³å€ã¯ãäŸãã°ãã«ã©ãŒããžçš
ä¹³å€ãã«ã©ãŒããŒããŒçšä¹³å€ãã«ã©ãŒãã¬çšä¹³
å€ãã«ã©ãŒå転çšä¹³å€ïŒã«ãã©ãŒãå«ãå Žåãã
ããå«ãŸã¬å ŽåãããïŒã補ççšåçæå ææ
ïŒäŸãã°ãªã¹ãã€ã«ã ãªã©ïŒçšä¹³å€ãé°æ¥µç·ç®¡ã
ã€ã¹ãã¬ã€çšæå ææã«çšããããä¹³å€ïŒžç·èšé²
çšæå ææïŒç¹ã«ã¹ã¯ãªãŒã³ãçšããçŽæ¥åã³é
æ¥æ®åœ±çšææïŒã«çšããããä¹³å€ãã³ãã€ãã»ã
ã©ã³ã¹ãã¢ãŒã»ããã»ã¹ïŒColloid transfer
processïŒïŒäŸãã°ç±³åœç¹èš±2716059å·ã«èšèŒãã
ãŠããïŒã«çšããããä¹³å€ãéå¡©æ¡æ£è»¢åããã»
ã¹ïŒSilver Salt diffusion transfer processïŒ
ïŒäŸãã°ãç±³åœç¹èš±2352014å·ãå2543181å·ãå
3020155å·ãå2861885å·ãªã©ã«èšèŒãããŠããïŒ
ã«çšããããä¹³å€ãã«ã©ãŒæ¡æ£è»¢åããã»ã¹ïŒç±³
åœç¹èš±3087817å·ãå3185567å·ãå2983606å·ã
å3253915å·ãå3227550å·ãå3227551å·ãå
3227552å·ãå3415644å·ãå3415645å·ãå
3415646å·ãªã©ã«èšèŒãããŠããïŒã«çšããä¹³å€ã
ãã€ã»ãã©ã³ã¹ãã¢ãŒã»ããã»ã¹ïŒimbibitio
transfer processïŒïŒç±³åœç¹èš±2882156å·ãªã©ã«èš
èŒãããŠããïŒã«çšããä¹³å€ãéè²çŽ æŒçœæ³
ãFriedmanã®âHistory of Color
PhotographyâAmerican Photographic
Pablishers Co.1944ããšãã«ç¬¬24ç« ïŒã
âBritish Journal of Photographyâvol111ãïœ
â308ã309Apr.7ã1964ãªã©ã«èšèŒãããŠããã
ã«çšããä¹³å€ãããªã³ãã¢ãŠãåãèšé²ããææ
ïŒäŸãã°ãç±³åœç¹èš±2369449å·ããã«ã®ãŒç¹èš±
704976å·ãªã©ã«èšèŒãããŠããïŒã«çšããããä¹³
å€ãå çŸååçŒåºãïŒDirect Print imageïŒæ
å ææïŒäŸãã°ãç±³åœç¹èš±3033682å·ãå3287137
å·ãªã©ã«èšèŒãããŠããïŒã«çšããä¹³å€ãç±çŸå
çšæå ææïŒäŸãã°ãç±³åœç¹èš±3152904å·ãå
3312550å·ãå3148122å·ãè±åœç¹èš±1140046å·ãª
ã©ã«èšèŒãããŠããïŒã«çšããä¹³å€ãç©ççŸåçš
æå ææïŒäŸãã°ãè±åœç¹èš±920277å·ãå
1131238å·ãªã©ã«èšèŒãããŠããïŒã«çšããä¹³å€
çã§ããã
é»ææçšã®ããã²ã³åéåçä¹³å€ã®å¢æã«çšãã
ãããçšããããä¹³å€ã¯ãäŸãã°ãã«ã©ãŒããžçš
ä¹³å€ãã«ã©ãŒããŒããŒçšä¹³å€ãã«ã©ãŒãã¬çšä¹³
å€ãã«ã©ãŒå転çšä¹³å€ïŒã«ãã©ãŒãå«ãå Žåãã
ããå«ãŸã¬å ŽåãããïŒã補ççšåçæå ææ
ïŒäŸãã°ãªã¹ãã€ã«ã ãªã©ïŒçšä¹³å€ãé°æ¥µç·ç®¡ã
ã€ã¹ãã¬ã€çšæå ææã«çšããããä¹³å€ïŒžç·èšé²
çšæå ææïŒç¹ã«ã¹ã¯ãªãŒã³ãçšããçŽæ¥åã³é
æ¥æ®åœ±çšææïŒã«çšããããä¹³å€ãã³ãã€ãã»ã
ã©ã³ã¹ãã¢ãŒã»ããã»ã¹ïŒColloid transfer
processïŒïŒäŸãã°ç±³åœç¹èš±2716059å·ã«èšèŒãã
ãŠããïŒã«çšããããä¹³å€ãéå¡©æ¡æ£è»¢åããã»
ã¹ïŒSilver Salt diffusion transfer processïŒ
ïŒäŸãã°ãç±³åœç¹èš±2352014å·ãå2543181å·ãå
3020155å·ãå2861885å·ãªã©ã«èšèŒãããŠããïŒ
ã«çšããããä¹³å€ãã«ã©ãŒæ¡æ£è»¢åããã»ã¹ïŒç±³
åœç¹èš±3087817å·ãå3185567å·ãå2983606å·ã
å3253915å·ãå3227550å·ãå3227551å·ãå
3227552å·ãå3415644å·ãå3415645å·ãå
3415646å·ãªã©ã«èšèŒãããŠããïŒã«çšããä¹³å€ã
ãã€ã»ãã©ã³ã¹ãã¢ãŒã»ããã»ã¹ïŒimbibitio
transfer processïŒïŒç±³åœç¹èš±2882156å·ãªã©ã«èš
èŒãããŠããïŒã«çšããä¹³å€ãéè²çŽ æŒçœæ³
ãFriedmanã®âHistory of Color
PhotographyâAmerican Photographic
Pablishers Co.1944ããšãã«ç¬¬24ç« ïŒã
âBritish Journal of Photographyâvol111ãïœ
â308ã309Apr.7ã1964ãªã©ã«èšèŒãããŠããã
ã«çšããä¹³å€ãããªã³ãã¢ãŠãåãèšé²ããææ
ïŒäŸãã°ãç±³åœç¹èš±2369449å·ããã«ã®ãŒç¹èš±
704976å·ãªã©ã«èšèŒãããŠããïŒã«çšããããä¹³
å€ãå çŸååçŒåºãïŒDirect Print imageïŒæ
å ææïŒäŸãã°ãç±³åœç¹èš±3033682å·ãå3287137
å·ãªã©ã«èšèŒãããŠããïŒã«çšããä¹³å€ãç±çŸå
çšæå ææïŒäŸãã°ãç±³åœç¹èš±3152904å·ãå
3312550å·ãå3148122å·ãè±åœç¹èš±1140046å·ãª
ã©ã«èšèŒãããŠããïŒã«çšããä¹³å€ãç©ççŸåçš
æå ææïŒäŸãã°ãè±åœç¹èš±920277å·ãå
1131238å·ãªã©ã«èšèŒãããŠããïŒã«çšããä¹³å€
çã§ããã
æ¬çºæãçšããŠäœãããæå
ææã®åçåŠçã«
ã¯ãäŸãã°ãªãµãŒãã»ãã€ã¹ã¯ããŒãžã€ãŒ
ïŒResearch DisclosureïŒ176å·ç¬¬28ã30é ïŒRD
â17643ïŒã«èšèŒãããŠãããããªãå ¬ç¥ã®æ¹æ³
åã³å ¬ç¥ã®åŠç液ã®ãããããé©çšããããšãã§
ããããã®åçåŠçã¯ãç®çã«å¿ããŠãé²ç»åã
圢æããåçåŠçïŒé»çœåçåŠçïŒããããã¯è²
çŽ åã圢æããåçåŠçïŒã«ã©ãŒåçåŠçïŒã®ã
ãããŠãã€ãŠããããåŠç枩床ã¯æ®é18âãã50
âã®éã«éžã°ãããã18âããäœã枩床ãŸãã¯50
âãè¶ãã枩床ãšããŠãããã
ã¯ãäŸãã°ãªãµãŒãã»ãã€ã¹ã¯ããŒãžã€ãŒ
ïŒResearch DisclosureïŒ176å·ç¬¬28ã30é ïŒRD
â17643ïŒã«èšèŒãããŠãããããªãå ¬ç¥ã®æ¹æ³
åã³å ¬ç¥ã®åŠç液ã®ãããããé©çšããããšãã§
ããããã®åçåŠçã¯ãç®çã«å¿ããŠãé²ç»åã
圢æããåçåŠçïŒé»çœåçåŠçïŒããããã¯è²
çŽ åã圢æããåçåŠçïŒã«ã©ãŒåçåŠçïŒã®ã
ãããŠãã€ãŠããããåŠç枩床ã¯æ®é18âãã50
âã®éã«éžã°ãããã18âããäœã枩床ãŸãã¯50
âãè¶ãã枩床ãšããŠãããã
次ã«ãæ¬çºæã®åçä¹³å€ã¯ã以äžã«è¿°ã¹ããã
ãªã«ã©ãŒæ¡æ£è»¢åããã»ã¹ã«çšããããŠãããã
ããã§çšããããä¹³å€ãšããŠã¯ãè¡šé¢æœåã圢æ
ãããã¬åä¹³å€ã§ããçŽæ¥å転åä¹³å€ã§ã䜿çšã§
ãããåŸè ã®ä¹³å€ãšããŠã¯ãå éšæœååä¹³å€ãäº
ãã«ããããçŽæ¥å転åä¹³å€ãããããªãã§ãã
å éšæœååããã²ã³åéä¹³å€ãæå©ã«äœ¿çšã§ãã
ãã®åã®ä¹³å€ãšããŠã¯äŸãã°ç±³åœç¹èš±2592250å·ã
å3206313å·ãå3447927å·ãå3761276å·ãåã³
å3935014å·çã«èšèŒãããã³ã³ããŒãžãšã³åä¹³
å€ãã³ã¢ïŒã·ãšã«åä¹³å€ãç°çš®éå±ãå èµããã
ä¹³å€çãæããããšãã§ããã
ãªã«ã©ãŒæ¡æ£è»¢åããã»ã¹ã«çšããããŠãããã
ããã§çšããããä¹³å€ãšããŠã¯ãè¡šé¢æœåã圢æ
ãããã¬åä¹³å€ã§ããçŽæ¥å転åä¹³å€ã§ã䜿çšã§
ãããåŸè ã®ä¹³å€ãšããŠã¯ãå éšæœååä¹³å€ãäº
ãã«ããããçŽæ¥å転åä¹³å€ãããããªãã§ãã
å éšæœååããã²ã³åéä¹³å€ãæå©ã«äœ¿çšã§ãã
ãã®åã®ä¹³å€ãšããŠã¯äŸãã°ç±³åœç¹èš±2592250å·ã
å3206313å·ãå3447927å·ãå3761276å·ãåã³
å3935014å·çã«èšèŒãããã³ã³ããŒãžãšã³åä¹³
å€ãã³ã¢ïŒã·ãšã«åä¹³å€ãç°çš®éå±ãå èµããã
ä¹³å€çãæããããšãã§ããã
ãã®åã®ä¹³å€ã®ã«ãã©ã·å€ãšããŠã¯ãç±³åœç¹èš±
2588982å·ãå2563785å·ã«èšèŒãããããã©ãžã³
é¡ïŒå3227552å·ã«èšèŒãããããã©ãžãé¡ãšã
ãã©ãŸã³é¡ïŒè±åœç¹èš±1283835å·ãç¹å ¬æ49â
38164å·ãç±³åœç¹èš±3734738å·ãå3719494å·ãå
3615615å·ã«èšèŒãããåçŽå¡©ååç©ïŒç±³åœç¹èš±
3718470å·ã«èšèŒãããããã¶ããäœçšã®ãã
ïŒnucleatingïŒçœ®æåºãè²çŽ ååäžã«æããå¢æ
è²çŽ ïŒç±³åœç¹èš±4030925å·ãå4031127å·ã«èšèŒã
ããã¢ã·ã«ããã©ãžãããšãã«ããªå°¿çŽ ç³»ååç©
ã代衚çãªãã®ã§ããã
2588982å·ãå2563785å·ã«èšèŒãããããã©ãžã³
é¡ïŒå3227552å·ã«èšèŒãããããã©ãžãé¡ãšã
ãã©ãŸã³é¡ïŒè±åœç¹èš±1283835å·ãç¹å ¬æ49â
38164å·ãç±³åœç¹èš±3734738å·ãå3719494å·ãå
3615615å·ã«èšèŒãããåçŽå¡©ååç©ïŒç±³åœç¹èš±
3718470å·ã«èšèŒãããããã¶ããäœçšã®ãã
ïŒnucleatingïŒçœ®æåºãè²çŽ ååäžã«æããå¢æ
è²çŽ ïŒç±³åœç¹èš±4030925å·ãå4031127å·ã«èšèŒã
ããã¢ã·ã«ããã©ãžãããšãã«ããªå°¿çŽ ç³»ååç©
ã代衚çãªãã®ã§ããã
æ¬çºæã«äœ¿çšãããè²çŽ åäŸäžååç©ãšããŠå
çš®ååç©ãå©çšããããšãåºæ¥ãããã«ãã©âå
ã³è²çŽ æŸåºã¬ããã¯ã¹ååç©ãç¹ã«æçšã§ããã
çš®ååç©ãå©çšããããšãåºæ¥ãããã«ãã©âå
ã³è²çŽ æŸåºã¬ããã¯ã¹ååç©ãç¹ã«æçšã§ããã
è²çŽ æŸåºã¬ããã¯ã¹ååç©ã®ãã¡ãé
žåãåã
ãååç©ãã¢ã«ã«ãªå æ°Žå解ããŠè²çŽ ãæŸåºãã
ãã®ãšããŠã¯ãäžèšã®æç®ã«èšèŒã®ãã®ãæãã
ããšãã§ããã
ãååç©ãã¢ã«ã«ãªå æ°Žå解ããŠè²çŽ ãæŸåºãã
ãã®ãšããŠã¯ãäžèšã®æç®ã«èšèŒã®ãã®ãæãã
ããšãã§ããã
ç±³åœç¹èš±4053312å·ãå4055428å·ãå4076529
å·ãå4152153å·ãå4135929å·ãç¹éæ53â
149328å·ãå51â104343å·ãå53â46730å·ãå
54â130122å·ãå53â3819å·ãç¹é¡æ54â89128
å·ãå54â90806å·ãå54â91187å·ãç ãã®ãã¡ãã€ãšããŒè²çŽ ãæŸåºãããã®ïŒ ç±³åœç¹èš±4013633å·ãç¹éæ53â149328å·ãå
51â114930å·ãç¹é¡æ54â148237å·ããªãµãŒãã»
ãã€ã¹ã¯ããŒãžã€ãŒïŒResearch DisclosureïŒ
17630ïŒâ78ïŒãå16475ïŒâ77ïŒç ããŒã³ã¿è²çŽ ãæŸåºãããã®ïŒ ç±³åœç¹èš±3954476å·ãå3931144å·ãå3932308
å·ãç¹éæ53â23628å·ãå52â106727å·ãå54
â65034å·ãç¹é¡æ53â69488å·ãå53â76162å·ã
å53â96445å·ãå54â149777å·ãå54â146655
å·ãå54â42848å·ã西ç¬ç¹èš±åºé¡ïŒOLSïŒ
2847371å·ãç ã·ã¢ã³è²çŽ ãæŸåºãããã®ïŒ ç±³åœç¹èš±3942987å·ãå3929760å·ãå4013635
å·ãç¹éæ51â109928å·ãå53â149328å·ãå52
â8827å·ãå53â143323å·ãå53â47823å·ãç¹
é¡æ54â146654å·ãç ãŸããé žåãåããªãã€ãæ¹ã®ååç©ãéç°ã
ããªã©ããŠè²çŽ ãæŸåºããã¬ããã¯ã¹ååç©ãšã
ãŠã¯ãäžèšã®æç®ã«èšèŒã®ãã®ãæããããšãã§
ããã
å·ãå4152153å·ãå4135929å·ãç¹éæ53â
149328å·ãå51â104343å·ãå53â46730å·ãå
54â130122å·ãå53â3819å·ãç¹é¡æ54â89128
å·ãå54â90806å·ãå54â91187å·ãç ãã®ãã¡ãã€ãšããŒè²çŽ ãæŸåºãããã®ïŒ ç±³åœç¹èš±4013633å·ãç¹éæ53â149328å·ãå
51â114930å·ãç¹é¡æ54â148237å·ããªãµãŒãã»
ãã€ã¹ã¯ããŒãžã€ãŒïŒResearch DisclosureïŒ
17630ïŒâ78ïŒãå16475ïŒâ77ïŒç ããŒã³ã¿è²çŽ ãæŸåºãããã®ïŒ ç±³åœç¹èš±3954476å·ãå3931144å·ãå3932308
å·ãç¹éæ53â23628å·ãå52â106727å·ãå54
â65034å·ãç¹é¡æ53â69488å·ãå53â76162å·ã
å53â96445å·ãå54â149777å·ãå54â146655
å·ãå54â42848å·ã西ç¬ç¹èš±åºé¡ïŒOLSïŒ
2847371å·ãç ã·ã¢ã³è²çŽ ãæŸåºãããã®ïŒ ç±³åœç¹èš±3942987å·ãå3929760å·ãå4013635
å·ãç¹éæ51â109928å·ãå53â149328å·ãå52
â8827å·ãå53â143323å·ãå53â47823å·ãç¹
é¡æ54â146654å·ãç ãŸããé žåãåããªãã€ãæ¹ã®ååç©ãéç°ã
ããªã©ããŠè²çŽ ãæŸåºããã¬ããã¯ã¹ååç©ãšã
ãŠã¯ãäžèšã®æç®ã«èšèŒã®ãã®ãæããããšãã§
ããã
ç±³åœç¹èš±4139379å·ãå3980479å·ã西ç¬ç¹èš±åº
é¡ïŒOLSïŒ2402900å·ãå2448811å·ãçã
é¡ïŒOLSïŒ2402900å·ãå2448811å·ãçã
ã«ã©ãŒæ¡æ£è»¢åããã»ã¹çšã®ææã«ã¯ãæŽã«ã
éåžžçšããããŠããææãã«ãã©ãŒãã©ããã¯
ã¹ãçé¢æŽ»æ§å€ãããã²ã³åéçŸåè¬ïŒãã€ãã
ããã³é¡ããã©ãŸãªãžãã³é¡ãªã©ïŒãåŠççµæç©
ïŒã¢ã«ã«ãªå€ãé žåé²æ¢å€ãéã€ãªã³æ¿åºŠèª¿ç¯å€
ãªã©ïŒãªã©ãçšããããšãã§ããã
éåžžçšããããŠããææãã«ãã©ãŒãã©ããã¯
ã¹ãçé¢æŽ»æ§å€ãããã²ã³åéçŸåè¬ïŒãã€ãã
ããã³é¡ããã©ãŸãªãžãã³é¡ãªã©ïŒãåŠççµæç©
ïŒã¢ã«ã«ãªå€ãé žåé²æ¢å€ãéã€ãªã³æ¿åºŠèª¿ç¯å€
ãªã©ïŒãªã©ãçšããããšãã§ããã
ãŸããè²çŽ æŸåºã¬ããã¯ã¹ååç©ã¯ãæ
äœã§ã
ã芪氎æ§ã³ãã€ãäžã«éåžžã®çš®ã ã®æ¹æ³ã«ãŠåæ£
ããããšãã§ããã
ã芪氎æ§ã³ãã€ãäžã«éåžžã®çš®ã ã®æ¹æ³ã«ãŠåæ£
ããããšãã§ããã
è²çŽ æŸåºã¬ããã¯ã¹ååç©ãçšããŠãã«ã©ãŒæ¡
æ£è»¢åç»åãåŸãããã®ããã»ã¹ã«ã€ããŠã¯ã
Photographic Science and Engineeringèªã
vol20ãNo.ïŒïŒãp115ã164ãJulyïŒAugust1976
ã«èšèŒãããŠããã
æ£è»¢åç»åãåŸãããã®ããã»ã¹ã«ã€ããŠã¯ã
Photographic Science and Engineeringèªã
vol20ãNo.ïŒïŒãp115ã164ãJulyïŒAugust1976
ã«èšèŒãããŠããã
äžèšããã»ã¹ã«ãããŠãè²çŽ æŸåºã¬ããã¯ã¹å
åç©ãã¯ãã¹é žåã§ãããã®ã§ããéããã©ã®ã
ããªããã²ã³åéçŸåè¬ã§ã䜿çšããããšãã§ã
ãããã®ãããªçŸåè¬ã¯ãã¢ã«ã«ãªæ§åŠççµæç©
ã®äžã«å«ãŸããŠãããããåçèŠçŽ ã®é©åœãªå±€ã«
å«ãŸããŠãããã
åç©ãã¯ãã¹é žåã§ãããã®ã§ããéããã©ã®ã
ããªããã²ã³åéçŸåè¬ã§ã䜿çšããããšãã§ã
ãããã®ãããªçŸåè¬ã¯ãã¢ã«ã«ãªæ§åŠççµæç©
ã®äžã«å«ãŸããŠãããããåçèŠçŽ ã®é©åœãªå±€ã«
å«ãŸããŠãããã
æ¬çºæã®ã«ã©ãŒæ¡æ£è»¢åæ³çšã®æå
ææã«äœ¿çš
ãããåªæå±€ãäžåå±€ãäžåé床調ç¯å±€ïŒã¿ã€ã
ã³ã°å±€ïŒãåŠççµæç©çã«ã€ããŠã¯ãäŸãã°ç¹é
æ52â64533å·ã«èšèŒã®ãã®ãé©çšã§ããã
ãããåªæå±€ãäžåå±€ãäžåé床調ç¯å±€ïŒã¿ã€ã
ã³ã°å±€ïŒãåŠççµæç©çã«ã€ããŠã¯ãäŸãã°ç¹é
æ52â64533å·ã«èšèŒã®ãã®ãé©çšã§ããã
æ¬çºæã®ã«ã©ãŒæ¡æ£è»¢åæ³çšã®æå
ææã¯ãé²
å ã®åãäžãåŸãéããŠçµå§äžäœåãããã¢ãã·
ãŒãåãã€ã«ã ãŠãããïŒæå èŠçŽ ãååèŠçŽ ã
åŠçèŠçŽ ãçµåã€ããã®ïŒã§ãã€ãŠãææã§çŸå
å¯èœãªãã®ã奜ãŸããããã®ãããªãã€ã«ã ãŠã
ããã«ã€ããŠã¯ãåæ²ã®Photographic Science
and Engineeringèªåã³Nebletteâ²s Handbook
of Photography and Reprography MaterialsïŒ
Process and SystemsïŒSeventh Ed.ïŒ1977ïŒã®
12ç« ãçã«èšèŒãããŠããã
å ã®åãäžãåŸãéããŠçµå§äžäœåãããã¢ãã·
ãŒãåãã€ã«ã ãŠãããïŒæå èŠçŽ ãååèŠçŽ ã
åŠçèŠçŽ ãçµåã€ããã®ïŒã§ãã€ãŠãææã§çŸå
å¯èœãªãã®ã奜ãŸããããã®ãããªãã€ã«ã ãŠã
ããã«ã€ããŠã¯ãåæ²ã®Photographic Science
and Engineeringèªåã³Nebletteâ²s Handbook
of Photography and Reprography MaterialsïŒ
Process and SystemsïŒSeventh Ed.ïŒ1977ïŒã®
12ç« ãçã«èšèŒãããŠããã
次ã«æ¬çºæã«çšããããå
·äœäŸã瀺ããããã
ãããã®å ·äœäŸã®ã¿ã«éå®ããããã®ã§ã¯ãªãã
ãããã®å ·äœäŸã®ã¿ã«éå®ããããã®ã§ã¯ãªãã
å®æœäŸ ïŒ
ããã«ãžãšããæ³ã«ããããã²ã³åéç²åãæ²
柱ãããç©ççæãè±å¡©åŠçåŸãæŽã«ååŠçæã
ããŠæ²èåéïŒãšãŒãå«æé7.5ã¢ã«ïŒ ïŒä¹³å€ã
åŸãããã®ä¹³å€ã«å«ãŸããããã²ã³åéç²åã®å¹³
åçŽåŸã¯0.7ãã¯ãã³ã§ãã€ãããã®ä¹³å€ïŒKgäž
ã«ã¯0.55ã¢ã«ã®ããã²ã³åéãå«æãããã
柱ãããç©ççæãè±å¡©åŠçåŸãæŽã«ååŠçæã
ããŠæ²èåéïŒãšãŒãå«æé7.5ã¢ã«ïŒ ïŒä¹³å€ã
åŸãããã®ä¹³å€ã«å«ãŸããããã²ã³åéç²åã®å¹³
åçŽåŸã¯0.7ãã¯ãã³ã§ãã€ãããã®ä¹³å€ïŒKgäž
ã«ã¯0.55ã¢ã«ã®ããã²ã³åéãå«æãããã
ãã®ä¹³å€ã®ïŒKgããããã«ç§€åã40âã«å æž©ã
ãŠæº¶è§£ãããå¢æè²çŽ ã®ã¡ã¿ããŒã«æº¶æ¶²ãããã
ãæå®éæ·»å ããæ··åæ¹æãããæŽã«ïŒâããã
ãã·âïŒâã¡ãã«âïŒïŒïŒïŒ3aïŒïŒâããã©ã¶
ã€ã³ãã³1.0ééïŒ æ°Žæº¶æ¶²ã®10mlãå ããïŒâã
ãããã·âïŒïŒïŒâãžã¯ããããªã¢ãžã³ãããªãŠ
ã å¡©1.0ééïŒ æ°Žæº¶æ¶²ã®10mlãå ããããã«ãã
ã·ã«ãã³ãŒã³ã¹ã«ãã³é žãããªãŠã å¡©1.0ééïŒ
氎溶液ã®10mlãå ããŠæ¹æããããã®å®æä¹³å€ã
ã»ã«ããŒãºããªã¢ã»ããŒããã€ã«ã ããŒã¹äžã«ä¹Ÿ
ç¥èåãïŒãã¯ãã³ã«ãªãããã«å¡åžä¹Ÿç¥ããæ
å ææã®è©ŠæãåŸãããã®ãã€ã«ã è©Šæãè²æž©åºŠ
5400ãã®å æºããã€æå èšãçšããŠãå æºã«ãã
ããå¯å£«åçãã€ã«ã 瀟補ã®é»è²ãã€ã«ã¿ãŒ
ïŒSCâ50ïŒãšã€ãŒã¹ããã³ã³ããã¯ç€Ÿè£œã®éè²ã
ã€ã«ã¿ãŒïŒã©ããã³47BïŒãã€ããŠå æ¥é²å ãè¡
ã€ãã
ãŠæº¶è§£ãããå¢æè²çŽ ã®ã¡ã¿ããŒã«æº¶æ¶²ãããã
ãæå®éæ·»å ããæ··åæ¹æãããæŽã«ïŒâããã
ãã·âïŒâã¡ãã«âïŒïŒïŒïŒ3aïŒïŒâããã©ã¶
ã€ã³ãã³1.0ééïŒ æ°Žæº¶æ¶²ã®10mlãå ããïŒâã
ãããã·âïŒïŒïŒâãžã¯ããããªã¢ãžã³ãããªãŠ
ã å¡©1.0ééïŒ æ°Žæº¶æ¶²ã®10mlãå ããããã«ãã
ã·ã«ãã³ãŒã³ã¹ã«ãã³é žãããªãŠã å¡©1.0ééïŒ
氎溶液ã®10mlãå ããŠæ¹æããããã®å®æä¹³å€ã
ã»ã«ããŒãºããªã¢ã»ããŒããã€ã«ã ããŒã¹äžã«ä¹Ÿ
ç¥èåãïŒãã¯ãã³ã«ãªãããã«å¡åžä¹Ÿç¥ããæ
å ææã®è©ŠæãåŸãããã®ãã€ã«ã è©Šæãè²æž©åºŠ
5400ãã®å æºããã€æå èšãçšããŠãå æºã«ãã
ããå¯å£«åçãã€ã«ã 瀟補ã®é»è²ãã€ã«ã¿ãŒ
ïŒSCâ50ïŒãšã€ãŒã¹ããã³ã³ããã¯ç€Ÿè£œã®éè²ã
ã€ã«ã¿ãŒïŒã©ããã³47BïŒãã€ããŠå æ¥é²å ãè¡
ã€ãã
é²å
åŸäžèšçµæã®çŸå液ãçšããŠ20âã§ïŒåé
çŸåããåæ¢ãå®ç济ãè¡ããæŽã«æ°ŽæŽããæå®
ã®é»çœåããã€ã¹ããªããã¹ãåŸãããããå¯å£«
åçãã€ã«ã 瀟補ã®ïŒ°åæ¿åºŠèšãçšããŠãæ¿åºŠæž¬
å®ãè¡ããæ床ãšã«ããªãåŸããæ床ã決å®ãã
å åŠæ¿åºŠã®åºæºç¹ã¯ãã«ããªïŒ0.20ãã®ç¹ã§ãã€
ãã
çŸåããåæ¢ãå®ç济ãè¡ããæŽã«æ°ŽæŽããæå®
ã®é»çœåããã€ã¹ããªããã¹ãåŸãããããå¯å£«
åçãã€ã«ã 瀟補ã®ïŒ°åæ¿åºŠèšãçšããŠãæ¿åºŠæž¬
å®ãè¡ããæ床ãšã«ããªãåŸããæ床ã決å®ãã
å åŠæ¿åºŠã®åºæºç¹ã¯ãã«ããªïŒ0.20ãã®ç¹ã§ãã€
ãã
çŸå液ã®çµæ
æ°Ž âŠâŠ700ml
ã¡ããŒã« âŠâŠ2.0ïœ
ç¡æ°Žäºç¡«é
žãããªãŠã âŠâŠ100.0ïœ
ãã€ããããã³ âŠâŠ5.0ïœ
ç¡Œç ïŒïŒæ°Žå¡©ïŒ âŠâŠ1.5ïœ
æ°Žãå ã㊠âŠâŠïŒ
åŸãããçµæãçžå¯Ÿçãªå€ãšããŠç¬¬ïŒè¡šã«ç€º
ãããããã®çµæã¯æ¬çºæã®å¢æè²çŽ ãé«æ床ã§
ã«ããªã®å°ãªãåªããææã®äœããããšã瀺ããŠ
ããã
ãããããã®çµæã¯æ¬çºæã®å¢æè²çŽ ãé«æ床ã§
ã«ããªã®å°ãªãåªããææã®äœããããšã瀺ããŠ
ããã
æ¯èŒã«çšããå¢æè²çŽ ã®ååŠæ§é
â â â äºã®ç² 0244 â â â
â â â äºã®ç² 0245 â â â
â â â äºã®ç² 0010 â â â
æ¯èŒçšè²çŽ âã¯ç±³åœç¹èš±2912329å·æ现æžã§ã
æ¯èŒçšè²çŽ âã¯ç±³åœç¹èš±2739149å·æ现æžã§ç¥
ãããã€ããã«ã«ãã·ã¢ãã³è²çŽ ã§ãããããã
æ¯èŒçšè²çŽ ãšæ¯ã¹ãŠãæ¬çºæã®å¢æè²çŽ ã¯åå æ
床ïŒé»è²ãã€ã«ã¿ãŒã«ããæ床ïŒé«ããåªããå¢
æè²çŽ ã§ããããšããããã
æ¯èŒçšè²çŽ âã¯ç±³åœç¹èš±2739149å·æ现æžã§ç¥
ãããã€ããã«ã«ãã·ã¢ãã³è²çŽ ã§ãããããã
æ¯èŒçšè²çŽ ãšæ¯ã¹ãŠãæ¬çºæã®å¢æè²çŽ ã¯åå æ
床ïŒé»è²ãã€ã«ã¿ãŒã«ããæ床ïŒé«ããåªããå¢
æè²çŽ ã§ããããšããããã
å®æœäŸ ïŒ
å®æœäŸ ïŒã§çšãããšåãããã²ã³åéä¹³å€ã
çšããå®æœäŸ ïŒãšåæ§ã®æ¹æ³ã§å¢æè²çŽ ãå«æ
ãããå¡åžã也ç¥ããŠæå ææã®è©ŠæãåŸããã
ã®ãã€ã«ã è©ŠæãïŒã€ã¯çžå¯Ÿæ¹¿åºŠ75ïŒ ã枩床50â
ã®ããšã§ïŒæ¥éæŸçœ®ãããä»ã®ïŒã€ã¯ãçžå¯Ÿæž©åºŠ
20ïŒ ã枩床50âã®ããšã§ïŒæ¥éæŸçœ®ããåŸãå®æœ
äŸ ïŒãšåæ§ã®æ¹æ³ã§é²å ããçŸååŠçããŠãæ
床ãšã«ããªã®å€åã枬å®ãããåŸãããçµæãçž
察çãªå€ãšããŠç¬¬ïŒè¡šã«ç€ºãã
çšããå®æœäŸ ïŒãšåæ§ã®æ¹æ³ã§å¢æè²çŽ ãå«æ
ãããå¡åžã也ç¥ããŠæå ææã®è©ŠæãåŸããã
ã®ãã€ã«ã è©ŠæãïŒã€ã¯çžå¯Ÿæ¹¿åºŠ75ïŒ ã枩床50â
ã®ããšã§ïŒæ¥éæŸçœ®ãããä»ã®ïŒã€ã¯ãçžå¯Ÿæž©åºŠ
20ïŒ ã枩床50âã®ããšã§ïŒæ¥éæŸçœ®ããåŸãå®æœ
äŸ ïŒãšåæ§ã®æ¹æ³ã§é²å ããçŸååŠçããŠãæ
床ãšã«ããªã®å€åã枬å®ãããåŸãããçµæãçž
察çãªå€ãšããŠç¬¬ïŒè¡šã«ç€ºãã
â â â äºã®ç² 0011 â â â
第ïŒè¡šã«ç€ºãããçµæããæãããªããã«ãæ¬
çºæã®å¢æè²çŽ ã¯ãé«æž©äžïŒ20ïŒ RHã50âã§ã
ã«ããªã®å¢å ãå°ãªãããŸããé«æž©ãé«æ¹¿äžïŒ75
ïŒ RHã50âïŒã§ãæ床äœäžãå°ãªãããšããã
ãã
çºæã®å¢æè²çŽ ã¯ãé«æž©äžïŒ20ïŒ RHã50âã§ã
ã«ããªã®å¢å ãå°ãªãããŸããé«æž©ãé«æ¹¿äžïŒ75
ïŒ RHã50âïŒã§ãæ床äœäžãå°ãªãããšããã
ãã
å®æœäŸ ïŒ
å®æœäŸ ïŒã§çšãããšåãããã²ã³åéä¹³å€ã
çšããå®æœäŸ ïŒãšåæ§ã®æ¹æ³ã§å¢æè²çŽ ãå«æ
ããå¡åžã也ç¥ããŠæå ææã®è©ŠæãåŸãããã®
ãã€ã«ã è©ŠæãïŒã€ã¯ãå¡åžåŸïŒã±æéãçžå¯Ÿæ¹¿
床60ïŒ ã枩床20âã®æ¡ä»¶äžã«æŸçœ®ããåŸãå®æœäŸ
ïŒãšåæ§ã®æ¹æ³ã§é²å ãçŸååŠçããŠãæ床ãš
ã«ããªã®å€åã枬å®ãããåŸãããçµæãçžå¯Ÿç
ãªå€ãšããŠç¬¬ïŒè¡šã«ç€ºãã
çšããå®æœäŸ ïŒãšåæ§ã®æ¹æ³ã§å¢æè²çŽ ãå«æ
ããå¡åžã也ç¥ããŠæå ææã®è©ŠæãåŸãããã®
ãã€ã«ã è©ŠæãïŒã€ã¯ãå¡åžåŸïŒã±æéãçžå¯Ÿæ¹¿
床60ïŒ ã枩床20âã®æ¡ä»¶äžã«æŸçœ®ããåŸãå®æœäŸ
ïŒãšåæ§ã®æ¹æ³ã§é²å ãçŸååŠçããŠãæ床ãš
ã«ããªã®å€åã枬å®ãããåŸãããçµæãçžå¯Ÿç
ãªå€ãšããŠç¬¬ïŒè¡šã«ç€ºãã
â â â äºã®ç² 0012 â â â
æ¯èŒçšè²çŽ âã¯ãç±³åœç¹èš±2912329å·æ现æž
ã§ç¥ãããŠããã€ããã«ã«ãã·ã¢ãã³è²çŽ ãæ¯èŒ
çšè²çŽ âã¯ãæ¬çºæã®è²çŽ âïŒãšé¡äŒŒïŒïŒäœâ
眮æåºãâCH2CF2CF3ãšâCH2CH2CH3ã®å·®ïŒ
ã®ååŠæ§é ããã€ãã€ããã«ã«ãã·ã¢ãã³è²çŽ ã§
ããããããæ¯èŒçšè²çŽ ã¯ãçµæã«ãã€ãŠã«ããª
ãå¢ããšãšãã«ããã®æ床äœäžãå€ããä»æ¹ãæ¬
çºæã®å¢æè²çŽ ã¯çµæã«ããæ床äœäžãå°ãªãã«
ããªã®å¢å ã¯å šããªããããã¯ãæ¬çºæã®å¢æè²
çŽ ãçšããããšã«ãããããçµæå®å®æ§ã«åªãã
æå ææãæäŸã§ããããšãè¡šãããŠããã
ã§ç¥ãããŠããã€ããã«ã«ãã·ã¢ãã³è²çŽ ãæ¯èŒ
çšè²çŽ âã¯ãæ¬çºæã®è²çŽ âïŒãšé¡äŒŒïŒïŒäœâ
眮æåºãâCH2CF2CF3ãšâCH2CH2CH3ã®å·®ïŒ
ã®ååŠæ§é ããã€ãã€ããã«ã«ãã·ã¢ãã³è²çŽ ã§
ããããããæ¯èŒçšè²çŽ ã¯ãçµæã«ãã€ãŠã«ããª
ãå¢ããšãšãã«ããã®æ床äœäžãå€ããä»æ¹ãæ¬
çºæã®å¢æè²çŽ ã¯çµæã«ããæ床äœäžãå°ãªãã«
ããªã®å¢å ã¯å šããªããããã¯ãæ¬çºæã®å¢æè²
çŽ ãçšããããšã«ãããããçµæå®å®æ§ã«åªãã
æå ææãæäŸã§ããããšãè¡šãããŠããã
å®æœäŸ ïŒ
éãšç¡«é»ã§ååŠå¢æããæ²èåéä¹³å€ïŒå¹³åç²
åãµã€ãº1.0ÎŒããšãŒãå«éïŒã¢ã«ïŒ ãéé80ïœïŒ
Kgä¹³å€ããŒã©ãã³é60ïœïŒKgä¹³å€ïŒã«ãå¢æè²çŽ
ã®ã¡ã¿ããŒã«æº¶æ¶²ãæå®éå ããåå å¢æãè¡ã€
ãã
åãµã€ãº1.0ÎŒããšãŒãå«éïŒã¢ã«ïŒ ãéé80ïœïŒ
Kgä¹³å€ããŒã©ãã³é60ïœïŒKgä¹³å€ïŒã«ãå¢æè²çŽ
ã®ã¡ã¿ããŒã«æº¶æ¶²ãæå®éå ããåå å¢æãè¡ã€
ãã
ãã®ä¹³å€ããããŒã³ã¿ã«ãã©ãŒïŒâïŒïŒïŒïŒïŒ
ïŒâããªã¯ããããšãã«ïŒâïŒâïœïŒâïŒïŒïŒïŒâ
ãžâïœâã¢ããããšããã·ã¢ã»ã¿ããïŒãã³ãºã¢
ããïœâïŒâãã©ãŸãã³ã®ä¹³åç©ãšå ±ã«ã»ã«ããŒ
ã¹ããªã¢ã»ããŒããã€ã«ã äžã«å¡åžïŒå¡åžéé
1.1ïœïŒm2ïŒãã也ç¥ãããã
ïŒâããªã¯ããããšãã«ïŒâïŒâïœïŒâïŒïŒïŒïŒâ
ãžâïœâã¢ããããšããã·ã¢ã»ã¿ããïŒãã³ãºã¢
ããïœâïŒâãã©ãŸãã³ã®ä¹³åç©ãšå ±ã«ã»ã«ããŒ
ã¹ããªã¢ã»ããŒããã€ã«ã äžã«å¡åžïŒå¡åžéé
1.1ïœïŒm2ïŒãã也ç¥ãããã
åŸãããè©Šæã第ïŒè¡šã«ç€ºãçžå¯Ÿæ¹¿åºŠã枩床ã®
ããšã§ïŒæ¥éæŸçœ®ããåŸãè²æž©åºŠ4800ãã®å æºã
ãã€æå èšãçšããŠããã«ãŒãã€ã«ã¿ãŒãšäžæ§ç°
è²ã®ã»ã³ã·ãã¡ããªãŒçšãŠãšããžãéããŠé²å
ããçŸååŠçããŠåŸãããæé«æ¿åºŠã®å€åã枬å®
ããã
ããšã§ïŒæ¥éæŸçœ®ããåŸãè²æž©åºŠ4800ãã®å æºã
ãã€æå èšãçšããŠããã«ãŒãã€ã«ã¿ãŒãšäžæ§ç°
è²ã®ã»ã³ã·ãã¡ããªãŒçšãŠãšããžãéããŠé²å
ããçŸååŠçããŠåŸãããæé«æ¿åºŠã®å€åã枬å®
ããã
ããã§çšããåŠçå·¥çšåã³åŠç液ã¯ä»¥äžã®éã
ã§ããã
ã§ããã
åŠçå·¥çš
å·¥ çš æé(å) æž© 床
第ïŒçŸå ïŒ 38â
æ°Ž æŽ ïŒ ã
å 転 ïŒ ã
çºè²çŸå ïŒ ã
調 æŽ ïŒ ã
æŒ çœ ïŒ ã
å® ç ïŒ ã
æ°Ž æŽ ïŒ ã
å® å® ïŒ åžž æž©
也 ç¥
ïŒç¬¬ïŒçŸå济ïŒ
æ°Ž 700ml
ããã©ããªãªã³é
žãããªãŠã ïŒïœ
äºç¡«é
žãããªãŠã 20ïœ
ãã€ããããã³ã»ã¢ãã¹ã«ããªããŒã 30ïœ
çé
žãããªãŠã ïŒïŒæ°Žå¡©ïŒ 30ïœ
ïŒâããšãã«ã»ïŒâã¡ãã«ã»ïŒâããããã·ã¡ã
ã«âïŒãã©ãŸãªãã³ ïŒïœ èåã«ãªãŠã 2.5ïœ ããªã·ã¢ã³é žã«ãªãŠã 1.2ïœ ãšãŠåã«ãªãŠã ïŒ0.1ïŒ æº¶æ¶²ïŒ ïŒml æ°Žãå ã㊠1000ml ïŒåè»¢æµŽïŒ æ°Ž 700ml ãããªãã»ïŒ®ã»ïŒ®ã»ïŒ®âããªã¡ãã¬ã³ãã¹ãã³é ž
6Naå¡© ïŒïœ å¡©å第ïŒã¹ãºïŒïŒæ°Žå¡©ïŒ ïŒïœ ïœâã¢ããããšããŒã« 0.1ïœ æ°Žé žåãããªãŠã ïŒïœ æ°·é ¢é ž 15ml æ°Žãå ã㊠1000ml ïŒçºè²çŸåæµŽïŒ æ°Ž 700ml ããã©ããªãªã³é žãããªãŠã ïŒïœ äºç¡«é žãããªãŠã ïŒïœ 第ïŒãªã³é žãããªãŠã ïŒ12æ°Žå¡©ïŒ 36ïœ èåã«ãªãŠã ïŒïœ æ²åã«ãªãŠã ïŒ0.1ïŒ æº¶æ¶²ïŒ 90ml æ°Žé žåãããªãŠã ïŒïœ ã·ãã©ãžã³é ž 1.5ïœ ïŒ®âãšãã«ââïŒÎ²âã¹ã«ãã¢ãããšãã«ïŒâïŒ
âã¡ãã«ã¢ããã¢ããªã³ç¡«é žå¡© 11ïœ ãšãã¬ã³ãžã¢ãã³ ïŒïœ æ°Žãå ã㊠1000ml ïŒèª¿æŽæµŽïŒ æ°Ž 700ml äºç¡«é žãããªãŠã 12ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žãããªãŠã ïŒïŒæ°Ž
å¡©ïŒ ïŒïœ ããªã°ãªã»ãªã³ 0.4ml æ°·é ¢é ž ïŒml æ°Žãå ã㊠1000ml ïŒæŒçœæµŽïŒ æ°Ž 800ml ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žãããªãŠã ïŒïŒæ°Ž
å¡©ïŒ 2.0ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žéïŒïŒã¢ã³ã¢ããŠ
ã ïŒïŒæ°Žå¡©ïŒ 120.0ïœ èåã«ãªãŠã 100.0ïœ æ°Žãå ã㊠1.0 ïŒå®çæµŽïŒ æ°Ž 800ml ããªç¡«é žã¢ã³ã¢ããŠã 80.0ml äºç¡«é žãããªãŠã 5.0ïœ éäºç¡«é žãããªãŠã 5.0ïœ æ°Žãå ã㊠1.0 ïŒå®å®æµŽïŒ æ°Ž 800ml ãã«ããªã³ïŒ37ééïŒ ïŒ 5.0ml å¯å£«ãã©ã€ãŠãšã« 5.0ml æ°Žãå ã㊠1.0ml åŸãããçµæã第ïŒè¡šã«ç€ºãã
ã«âïŒãã©ãŸãªãã³ ïŒïœ èåã«ãªãŠã 2.5ïœ ããªã·ã¢ã³é žã«ãªãŠã 1.2ïœ ãšãŠåã«ãªãŠã ïŒ0.1ïŒ æº¶æ¶²ïŒ ïŒml æ°Žãå ã㊠1000ml ïŒåè»¢æµŽïŒ æ°Ž 700ml ãããªãã»ïŒ®ã»ïŒ®ã»ïŒ®âããªã¡ãã¬ã³ãã¹ãã³é ž
6Naå¡© ïŒïœ å¡©å第ïŒã¹ãºïŒïŒæ°Žå¡©ïŒ ïŒïœ ïœâã¢ããããšããŒã« 0.1ïœ æ°Žé žåãããªãŠã ïŒïœ æ°·é ¢é ž 15ml æ°Žãå ã㊠1000ml ïŒçºè²çŸåæµŽïŒ æ°Ž 700ml ããã©ããªãªã³é žãããªãŠã ïŒïœ äºç¡«é žãããªãŠã ïŒïœ 第ïŒãªã³é žãããªãŠã ïŒ12æ°Žå¡©ïŒ 36ïœ èåã«ãªãŠã ïŒïœ æ²åã«ãªãŠã ïŒ0.1ïŒ æº¶æ¶²ïŒ 90ml æ°Žé žåãããªãŠã ïŒïœ ã·ãã©ãžã³é ž 1.5ïœ ïŒ®âãšãã«ââïŒÎ²âã¹ã«ãã¢ãããšãã«ïŒâïŒ
âã¡ãã«ã¢ããã¢ããªã³ç¡«é žå¡© 11ïœ ãšãã¬ã³ãžã¢ãã³ ïŒïœ æ°Žãå ã㊠1000ml ïŒèª¿æŽæµŽïŒ æ°Ž 700ml äºç¡«é žãããªãŠã 12ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žãããªãŠã ïŒïŒæ°Ž
å¡©ïŒ ïŒïœ ããªã°ãªã»ãªã³ 0.4ml æ°·é ¢é ž ïŒml æ°Žãå ã㊠1000ml ïŒæŒçœæµŽïŒ æ°Ž 800ml ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žãããªãŠã ïŒïŒæ°Ž
å¡©ïŒ 2.0ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žéïŒïŒã¢ã³ã¢ããŠ
ã ïŒïŒæ°Žå¡©ïŒ 120.0ïœ èåã«ãªãŠã 100.0ïœ æ°Žãå ã㊠1.0 ïŒå®çæµŽïŒ æ°Ž 800ml ããªç¡«é žã¢ã³ã¢ããŠã 80.0ml äºç¡«é žãããªãŠã 5.0ïœ éäºç¡«é žãããªãŠã 5.0ïœ æ°Žãå ã㊠1.0 ïŒå®å®æµŽïŒ æ°Ž 800ml ãã«ããªã³ïŒ37ééïŒ ïŒ 5.0ml å¯å£«ãã©ã€ãŠãšã« 5.0ml æ°Žãå ã㊠1.0ml åŸãããçµæã第ïŒè¡šã«ç€ºãã
â â â äºã®ç² 0013 â â â
第ïŒè¡šã®çµæãããæ¬çºæã®å¢æè²çŽ No.ïŒãïŒ
ã¯é«æž©äžïŒ55âã30ïŒ ãïŒæ¥ïŒã§ããé«æž©é«æ¹¿äž
ïŒ60âã60ïŒ ãïŒæ¥ïŒã§ãæé«æ¿åºŠã®äœäžãå°ã
ãããšããããã
ã¯é«æž©äžïŒ55âã30ïŒ ãïŒæ¥ïŒã§ããé«æž©é«æ¹¿äž
ïŒ60âã60ïŒ ãïŒæ¥ïŒã§ãæé«æ¿åºŠã®äœäžãå°ã
ãããšããããã
å®æœäŸ ïŒ
å®æœäŸïŒã§çšãããšåãè©ŠæãçšããŠãå®æœäŸ
ïŒãšåæ§ã®é²å ãè¡ã€ãåŸã第ïŒè¡šã«ç€ºãçžå¯Ÿæ¹¿
床ã枩床ã®ããšã§ïŒæ¥éæŸçœ®ããããã®è©Šæãå®
æœäŸïŒãšåæ§ã®çŸååŠçããŠåŸããããã€ã©ã€ã
éšïŒæ¿åºŠ0.2ïŒã®æ床å€åã第ïŒè¡šã«ç€ºãã
ïŒãšåæ§ã®é²å ãè¡ã€ãåŸã第ïŒè¡šã«ç€ºãçžå¯Ÿæ¹¿
床ã枩床ã®ããšã§ïŒæ¥éæŸçœ®ããããã®è©Šæãå®
æœäŸïŒãšåæ§ã®çŸååŠçããŠåŸããããã€ã©ã€ã
éšïŒæ¿åºŠ0.2ïŒã®æ床å€åã第ïŒè¡šã«ç€ºãã
â â â äºã®ç² 0014 â â â
第ïŒè¡šã®çµæãããæ¬çºæã®å¢æè²çŽ No.ïŒãïŒ
ã¯ãé«æž©äžïŒ50âã30ïŒ ãïŒæ¥ïŒã§ãé«æž©é«æ¹¿äž
ïŒ45âã80ïŒ ãïŒæ¥ïŒã§ãããã€ã©ã€ãéšã®æ床
äœäžãå°ããããšããããã
ã¯ãé«æž©äžïŒ50âã30ïŒ ãïŒæ¥ïŒã§ãé«æž©é«æ¹¿äž
ïŒ45âã80ïŒ ãïŒæ¥ïŒã§ãããã€ã©ã€ãéšã®æ床
äœäžãå°ããããšããããã
å®æœäŸ ïŒ
ããªãšãã¬ã³ãã¬ãã¿ã¬ãŒãéææ¯æäœäžã«æ¬¡
ã®é ã«åå±€ãå¡åžããŠæå èŠçŽ ïŒãïŒãã€ãã€
ãã
ã®é ã«åå±€ãå¡åžããŠæå èŠçŽ ïŒãïŒãã€ãã€
ãã
(1) ç±³åœç¹èš±ç¬¬3898088å·ã«èšèŒãããŠããå
±é
åäœã§äžèšç¹°ãè¿ãåäœãäžèšã®å²åã§å«ãé
åäœïŒ3.0ïœïŒm2ïŒ â â â äºã®ç² 0250 â â â ããã³ãŒã©ãã³ïŒ3.0ïœïŒm2ïŒãå«ãåªæå±€ã
åäœã§äžèšç¹°ãè¿ãåäœãäžèšã®å²åã§å«ãé
åäœïŒ3.0ïœïŒm2ïŒ â â â äºã®ç² 0250 â â â ããã³ãŒã©ãã³ïŒ3.0ïœïŒm2ïŒãå«ãåªæå±€ã
(2) é
žåãã¿ã³20ïœïŒm2ããã³ãŒã©ãã³2.0ïœïŒ
m2ãå«ãçœè²åå°å±€ã
m2ãå«ãçœè²åå°å±€ã
(3) ã«ãŒãã³ãã©ãã¯2.7ïœïŒm2ããã³ãŒã©ãã³
2.7ïœïŒm2ãå«ãé®å å±€ã
2.7ïœïŒm2ãå«ãé®å å±€ã
(4) äžèšã®ã·ã¢ã³DRRååç©ïŒ0.5ïœïŒm2ïŒããž
ãšãã«ã©ãŠãªã«ã¢ããïŒ0.25ïœïŒm2ïŒããã³ãŒ
ã©ãã³ïŒ1.14ïœïŒm2ãå«ãå±€ã
ãšãã«ã©ãŠãªã«ã¢ããïŒ0.25ïœïŒm2ïŒããã³ãŒ
ã©ãã³ïŒ1.14ïœïŒm2ãå«ãå±€ã
â â â äºã®ç² 0251 â â â
(5) å
éšæœååä¹³å€ïŒéã®éã§1.9ïœïŒm2ïŒèµ€æ
æ§å¢æè²çŽ ãåŸè¿°ã®ã«ãã©ã·å€ãïŒ0.07mgïŒ
m2ïŒãïŒâãã³ã¿ãã·ã«âãã€ããããã³âïŒ
âã¹ã«ãã³é žãããªãŠã ïŒ0.13ïœïŒm2ïŒãå«æ
ããèµ€ææ§ã®å éšæœååçŽæ¥ããžèåéä¹³å€
å±€ã
æ§å¢æè²çŽ ãåŸè¿°ã®ã«ãã©ã·å€ãïŒ0.07mgïŒ
m2ïŒãïŒâãã³ã¿ãã·ã«âãã€ããããã³âïŒ
âã¹ã«ãã³é žãããªãŠã ïŒ0.13ïœïŒm2ïŒãå«æ
ããèµ€ææ§ã®å éšæœååçŽæ¥ããžèåéä¹³å€
å±€ã
(6) ãŒã©ãã³ïŒ2.6ïœïŒm2ïŒãšïŒïŒïŒâãžãªã¯ã
ã«ãã€ããããã³ïŒ1.0ïœïŒm2ïŒãå«ãå±€ã
ã«ãã€ããããã³ïŒ1.0ïœïŒm2ïŒãå«ãå±€ã
(7) äžèšã®ããŒã³ã¿DRRååç©ïŒ0.45ïœïŒm2ïŒã
ãžãšãã«ã©ãŠãªã«ã¢ããïŒ0.10ïœïŒm2ïŒãïŒïŒ
ïŒâãžâïœâããã«ãã€ããããã³ïŒ0.0074
ïœïŒm2ïŒãããã³ãŒã©ãã³ïŒ0.76ïœïŒm2ïŒãå«
ãå±€ã
ãžãšãã«ã©ãŠãªã«ã¢ããïŒ0.10ïœïŒm2ïŒãïŒïŒ
ïŒâãžâïœâããã«ãã€ããããã³ïŒ0.0074
ïœïŒm2ïŒãããã³ãŒã©ãã³ïŒ0.76ïœïŒm2ïŒãå«
ãå±€ã
â â â äºã®ç² 0252 â â â
(8) å
éšæœååä¹³å€ïŒéã®éã§1.4ïœïŒm2ïŒã«ã
æå èŠçŽ ïŒã§ã¯ç·ææ§å¢æè²çŽ ïŒæ¯èŒçšè²çŽ â
ïŒãæ·»å ããæå èŠçŽ ïŒã§ã¯åäžã®ä¹³å€ã«ç·
ææ§å¢æè²çŽ ïŒè²çŽ â23ïŒãæ·»å ããæå èŠçŽ
ïŒã§ã¯åäžã®ä¹³å€ã«ç·ææ§å¢æè²çŽ ïŒè²çŽ â
24ïŒãæ·»å ããã
æå èŠçŽ ïŒã§ã¯ç·ææ§å¢æè²çŽ ïŒæ¯èŒçšè²çŽ â
ïŒãæ·»å ããæå èŠçŽ ïŒã§ã¯åäžã®ä¹³å€ã«ç·
ææ§å¢æè²çŽ ïŒè²çŽ â23ïŒãæ·»å ããæå èŠçŽ
ïŒã§ã¯åäžã®ä¹³å€ã«ç·ææ§å¢æè²çŽ ïŒè²çŽ â
24ïŒãæ·»å ããã
â â â äºã®ç² 0253 â â â
æ¯èŒçšè²çŽ âã¯è±åœç¹èš±654690å·ãå
815172å·ãæ现æžã§ç¥ããã代衚çãªã€ããã«
ã«ãã·ã¢ãã³è²çŽ ã§ããã
815172å·ãæ现æžã§ç¥ããã代衚çãªã€ããã«
ã«ãã·ã¢ãã³è²çŽ ã§ããã
ç·ææ§å¢æè²çŽ 以å€ã¯ãå
±éã«åŸè¿°ã®ã«ãã©
ã·å€ã0.05mgïŒm2åã³ïŒâãã³ã¿ãã·ã«âãã€
ãããã·ãã³âïŒâã¹ã«ãã³é žãããªãŠã
ïŒ0.11ïœïŒm2ïŒãå«ãç·ææ§å éšæœååçŽæ¥ã
ãžèåéä¹³å€å±€ã
ã·å€ã0.05mgïŒm2åã³ïŒâãã³ã¿ãã·ã«âãã€
ãããã·ãã³âïŒâã¹ã«ãã³é žãããªãŠã
ïŒ0.11ïœïŒm2ïŒãå«ãç·ææ§å éšæœååçŽæ¥ã
ãžèåéä¹³å€å±€ã
(9) åèšã®(6)ãšåæ§ã®å±€ã
(10) äžèšã®ã€ãšããŒDRRååç©ïŒ0.78ïœïŒm2ïŒã
ãžãšãã«ã©ãŠãªã«ã¢ããïŒ0.16ïœïŒm2ïŒãïŒïŒ
ïŒâãžâïœâããã«ãã€ããããã³ïŒ0.012
ïœïŒm2ïŒããã³ãŒã©ãã³ïŒ0.78ïœïŒm2ïŒãå«ã
å±€ã
ãžãšãã«ã©ãŠãªã«ã¢ããïŒ0.16ïœïŒm2ïŒãïŒïŒ
ïŒâãžâïœâããã«ãã€ããããã³ïŒ0.012
ïœïŒm2ïŒããã³ãŒã©ãã³ïŒ0.78ïœïŒm2ïŒãå«ã
å±€ã
â â â äºã®ç² 0254 â â â
(11) å
éšæœååä¹³å€ïŒéã®éã§2.2ïœïŒm2ïŒãé
ææ§å¢æè²çŽ ãåŸè¿°ã®ã«ãã©ã·å€ã0.08mgïŒm2
åã³ïŒâãã³ã¿ãã·ã«ãã€ããããã³âïŒâã¹
ã«ãã³é žãããªãŠã ïŒ0.094ïœïŒm2ïŒãå«ãé
ææ§å éšæœååçŽæ¥ããžèåéä¹³å€ã®å±€ã
ææ§å¢æè²çŽ ãåŸè¿°ã®ã«ãã©ã·å€ã0.08mgïŒm2
åã³ïŒâãã³ã¿ãã·ã«ãã€ããããã³âïŒâã¹
ã«ãã³é žãããªãŠã ïŒ0.094ïœïŒm2ïŒãå«ãé
ææ§å éšæœååçŽæ¥ããžèåéä¹³å€ã®å±€ã
(12) ãŒã©ãã³ïŒ0.94ïœïŒm2ïŒãå«ãå±€ã
â â â äºã®ç² 0255 â â â
äžèšæå
èŠçŽ ïŒãïŒã次ã«ç€ºãåèŠçŽ ãšçµã¿å
ãããŠåŠçãè¡ã€ãã
ãããŠåŠçãè¡ã€ãã
åŠç液
ïŒâããšãã«âïŒâã¡ãã«âïŒâããããã·ã¡ã
ã«âïŒâãã©ãŸãªãžãã³ 10ïœ ã¡ãã«ãã€ããããã³ 0.18ïœ ïŒâã¡ãã«ãã³ãããªã¢ãŸãŒã« 4.0ïœ äºç¡«é žãããªãŠã ïŒç¡æ°ŽïŒ 1.0ïœ ã«ã«ããã·ã¡ãã«ã»ã«ããŒã¹Naå¡© 40.0ïœ ã«ãŒãã³ãã©ã㯠150ïœ æ°Žé žåã«ãªãŠã ïŒ28ïŒ æ°Žæº¶æ¶²ïŒ 200c.c. H2O 550c.c. äžèšçµæã®åŠç液ã0.8ïœãã€ãå§åã§ç Žå£å¯
èœãªå®¹åšãã«å å¡«ããã
ã«âïŒâãã©ãŸãªãžãã³ 10ïœ ã¡ãã«ãã€ããããã³ 0.18ïœ ïŒâã¡ãã«ãã³ãããªã¢ãŸãŒã« 4.0ïœ äºç¡«é žãããªãŠã ïŒç¡æ°ŽïŒ 1.0ïœ ã«ã«ããã·ã¡ãã«ã»ã«ããŒã¹Naå¡© 40.0ïœ ã«ãŒãã³ãã©ã㯠150ïœ æ°Žé žåã«ãªãŠã ïŒ28ïŒ æ°Žæº¶æ¶²ïŒ 200c.c. H2O 550c.c. äžèšçµæã®åŠç液ã0.8ïœãã€ãå§åã§ç Žå£å¯
èœãªå®¹åšãã«å å¡«ããã
ã«ããŒã·ãŒã
ããªãšãã¬ã³ãã¬ãã¿ã¬ãŒãæ¯æäœäžã«é
žæ§ã
ãªããŒå±€ïŒäžåå±€ïŒãšããŠããªã¢ã¯ãªã«é žïŒ10é
éïŒ æ°Žæº¶æ¶²ã§ç²åºŠçŽ1000cpïŒ15ïœïŒããã³m2ã
ã®äžã«äžåã¿ã€ãã³ã°å±€ãšããŠã¢ã»ãã«ã»ã«ããŒ
ã¹ïŒ100ïœã®ã¢ã»ãã«ã»ã«ããŒã¹ãå æ°Žå解ããŠ
39.4ïœã¢ã»ãã«åºãçæããïŒ3.8ïœïŒm2ããã³
ã¹ãã¬ã³ãšç¡æ°Žãã¬ã€ã³é žã®ã³ããªããŒïŒçµæ
ïŒã¢ã«ïŒæ¯ãã¹ãã¬ã³ïŒç¡æ°Žãã¬ã€ã³é žïŒçŽ60ïŒ
40ãååéçŽïŒäžïŒ0.2ïœïŒm2ãå¡åžããã«ããŒ
ã·ãŒããäœæãããæå èŠçŽ ïŒãïŒãå¡åžåŸïŒã±
æé40âã«æŸçœ®ããè²æž©åºŠ5400ãã®å æºããã€æ
å èšãçšããŠå æ¥é²å ãè¡ãªã以äžã«ç€ºãåŠçã
è¡ãªã€ãã
ãªããŒå±€ïŒäžåå±€ïŒãšããŠããªã¢ã¯ãªã«é žïŒ10é
éïŒ æ°Žæº¶æ¶²ã§ç²åºŠçŽ1000cpïŒ15ïœïŒããã³m2ã
ã®äžã«äžåã¿ã€ãã³ã°å±€ãšããŠã¢ã»ãã«ã»ã«ããŒ
ã¹ïŒ100ïœã®ã¢ã»ãã«ã»ã«ããŒã¹ãå æ°Žå解ããŠ
39.4ïœã¢ã»ãã«åºãçæããïŒ3.8ïœïŒm2ããã³
ã¹ãã¬ã³ãšç¡æ°Žãã¬ã€ã³é žã®ã³ããªããŒïŒçµæ
ïŒã¢ã«ïŒæ¯ãã¹ãã¬ã³ïŒç¡æ°Žãã¬ã€ã³é žïŒçŽ60ïŒ
40ãååéçŽïŒäžïŒ0.2ïœïŒm2ãå¡åžããã«ããŒ
ã·ãŒããäœæãããæå èŠçŽ ïŒãïŒãå¡åžåŸïŒã±
æé40âã«æŸçœ®ããè²æž©åºŠ5400ãã®å æºããã€æ
å èšãçšããŠå æ¥é²å ãè¡ãªã以äžã«ç€ºãåŠçã
è¡ãªã€ãã
åŠçå·¥çš
äžèšã«ããŒã·ãŒããšåèšæå
ã·ãŒããéãåã
ããã«ããŒã·ãŒãã®åŽããã«ã©ãŒãã¹ããã€ãŒã
ãé²å ããã®ã¡ãäž¡ã·ãŒãã®éã«ãäžèšåŠç液ã
75ÎŒã®åã¿ã«ãªãããã«å±éããïŒå±éã¯å å§ã
ãŒã©ãŒã®å©ãããããŠè¡ã€ãïŒãåŠçã¯ã25âã§
è¡ã€ããåŠçåŸãæå ã·ãŒãã®éææ¯æäœãéã
ãŠãååå±€ã«çæããç»åã®ç·æ¿åºŠããã¯ãã¹å
å°æ¿åºŠèšã«ãã€ãŠåŠçïŒæéåŸã«æž¬å®ããã
ããã«ããŒã·ãŒãã®åŽããã«ã©ãŒãã¹ããã€ãŒã
ãé²å ããã®ã¡ãäž¡ã·ãŒãã®éã«ãäžèšåŠç液ã
75ÎŒã®åã¿ã«ãªãããã«å±éããïŒå±éã¯å å§ã
ãŒã©ãŒã®å©ãããããŠè¡ã€ãïŒãåŠçã¯ã25âã§
è¡ã€ããåŠçåŸãæå ã·ãŒãã®éææ¯æäœãéã
ãŠãååå±€ã«çæããç»åã®ç·æ¿åºŠããã¯ãã¹å
å°æ¿åºŠèšã«ãã€ãŠåŠçïŒæéåŸã«æž¬å®ããã
ãã®çµæã第ïŒè¡šã«ç€ºãã
â â â äºã®ç² 0015 â â â
äžè¡šããæ¯èŒçšè²çŽ ãšæ¯ã¹ãŠæ¬çºæã®å¢æè²çŽ
ã¯çµæã§ã®æ床ã®äœäžãéåžžã«å°ããããšããã
ãã
ã¯çµæã§ã®æ床ã®äœäžãéåžžã«å°ããããšããã
ãã
æ¬çºæã®å¥œãŸããå®æœæ
æ§ã次ã«æããã
ïŒ çšããããããã²ã³åéåçä¹³å€ãæ²èåé
ä¹³å€ã§ããç¹èš±è«æ±ã®ããã²ã³åéåçä¹³å€ã
ä¹³å€ã§ããç¹èš±è«æ±ã®ããã²ã³åéåçä¹³å€ã
ïŒ çšããããããã²ã³åéåçä¹³å€ãèåéä¹³
å€ã§ããç¹èš±è«æ±ã®ç¯å²ã®ããã²ã³åéåçä¹³
å€ã
å€ã§ããç¹èš±è«æ±ã®ç¯å²ã®ããã²ã³åéåçä¹³
å€ã
ïŒ ç¹èš±è«æ±ã®ç¯å²ã«ãããŠããã²ã³åéåçä¹³
å€äžã«ã«ã©ãŒã«ãã©ãŒãå«æããã«ã©ãŒåçæ
å ææã
å€äžã«ã«ã©ãŒã«ãã©ãŒãå«æããã«ã©ãŒåçæ
å ææã
ïŒ å®æœæ
æ§ïŒã«ãããŠã«ã©ãŒã«ãã©ãŒãããŒã³
ã¿ã«ãã©ãŒã§ããåçæå ææã
ã¿ã«ãã©ãŒã§ããåçæå ææã
ïŒ ç¹èš±è«æ±ã®ç¯å²ã«ãããŠäžè¬åŒããã®V2ã
V4ãããªãã«ãªãã¡ãã«åºãå¡©çŽ ååãã·ã¢
ãåºãV1ãV3ãå¡©çŽ ååã§ããå Žåã
V4ãããªãã«ãªãã¡ãã«åºãå¡©çŽ ååãã·ã¢
ãåºãV1ãV3ãå¡©çŽ ååã§ããå Žåã
ïŒ å®æœæ
æ§ïŒã«ãããŠãV2ãV4ã®ããããäž
æ¹ãããªãã«ãªãã¡ãã«åºãã·ã¢ãåºãä»ã®äž
æ¹ãå¡©çŽ ååã§ããå Žåã
æ¹ãããªãã«ãªãã¡ãã«åºãã·ã¢ãåºãä»ã®äž
æ¹ãå¡©çŽ ååã§ããå Žåã
ïŒ éææ§ä¹³å€å±€ãç·ææ§ä¹³å€å±€ãèµ€ææ§ä¹³å€å±€
ã®å°ãªããšãïŒå±€ãããªãã«ã©ãŒåçæå ææ
ã«ãããŠãç·ææ§ä¹³å€å±€ãäžèšå®æœæ æ§ïŒã§ã
ãããã²ã³åéåçæå ææã
ã®å°ãªããšãïŒå±€ãããªãã«ã©ãŒåçæå ææ
ã«ãããŠãç·ææ§ä¹³å€å±€ãäžèšå®æœæ æ§ïŒã§ã
ãããã²ã³åéåçæå ææã
ïŒ å®æœæ
æ§âïŒã«ãããŠç·ææ§ä¹³å€å±€ãå®æœæ
æ§âïŒã§ããããã²ã³åéåçæå ææã
æ§âïŒã§ããããã²ã³åéåçæå ææã
ïŒ å®æœæ
æ§âïŒã«ãããŠãç·ææ§ä¹³å€å±€ãå
éš
æœååããã²ã³åéåçæå ææã
æœååããã²ã³åéåçæå ææã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ äžè¬åŒïŒïŒã§ç€ºããããã³ãŸã€ãããŸãã«
ã«ãã·ã¢ãã³è²çŽ ãå°ãªããšãäžçš®ä»¥äžå«æãã
ããšãç¹åŸŽãšããããã²ã³åéåçä¹³å€ã äžè¬åŒïŒïŒ â â â äºã®ç² 0214 â â â ïŒåŒäžãR1ãR2ãR3ã¯ããããåäžã§ãç°ãªã€
ãŠããŠããããâïŒCH2ïŒjïŒCF2ïŒkåºïŒããã§ïœ
ã¯ïŒãïŒãŸãã¯ïŒããïœã¯ïŒãŸãã¯ïŒãïŒã®æŽæ°
ãããããè¡šãããïœïŒïœïŒïŒã§ãããïŒãç¡çœ®æ
ã¢ã«ãã«åºãŸãã¯ã«ã«ããã·ã«åºãã¹ã«ãåºãã·
ã¢ãåºãããã²ã³ååãããããã·åºãã¢ã«ã³ã
ã·ã«ã«ããã«åºãã¢ã«ã³ãã·åºãã«ã«ãã¢ã€ã«
åºãã¹ã«ãã¢ã¢ã€ã«åºãããã¯ããšãã«åºã§çœ®æ
ãããã¢ã«ãã«åºãè¡šãããäœããR1ãR2åã³
R3ã®ãã¡å°ãªããšãïŒã€ã¯é žçœ®æåºãæããã¢
ã«ãã«åºã§ããã V1ãV2ãV3ãV4ã¯ããããåäžã§ãç°ãªã€ãŠ
ããŠããããæ°ŽçŽ ååãããã²ã³ååã眮æã¢ã«
ãã«åºãããã¯ç¡çœ®æã¢ã«ãã«åºãã¢ã«ã³ãã·
åºãã¢ã·ã«åºãã¢ã·ã«ãªãã·åºãã¢ã«ã³ãã·ã«ã«
ããã«åºãã«ã«ãã¢ã€ã«åºãã¹ã«ãã¢ã¢ã€ã«åºã
ã·ã¢ãåºãŸãã¯ããªãã«ãªãã¡ãã«åºãè¡šããã ã¯ã¢ããªã³ãè¡šãããïœã¯ïŒãŸãã¯ïŒãè¡šã
ããè²çŽ ãååå å¡©ã圢æãããšãã¯ïŒã§ããã ïœã¯ïŒãïŒãŸãã¯ïŒããïœã¯ïŒãŸãã¯ïŒãïŒã®
æŽæ°ãããããè¡šãããïœïŒïœïŒïŒã§ãããïŒ
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17593983A JPS6067934A (ja) | 1983-09-22 | 1983-09-22 | ããã²ã³åéåçä¹³å€ |
| DE3402480A DE3402480C2 (de) | 1983-01-25 | 1984-01-25 | Farbphotographische Silberhalogenidemulsion und farbphotographisches, lichtempfindliches Material, enthaltend diese Emulsion |
| US06/573,760 US4555481A (en) | 1983-01-25 | 1984-01-25 | Silver halide photographic emulsions containing benzimidazolocarbocyanine dye having fluoroalkyl group at the nitrogen atom of benzimidazole |
| GB08401890A GB2138156B (en) | 1983-01-25 | 1984-01-25 | Silver halide photographic emulsions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17593983A JPS6067934A (ja) | 1983-09-22 | 1983-09-22 | ããã²ã³åéåçä¹³å€ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6067934A JPS6067934A (ja) | 1985-04-18 |
| JPH0342453B2 true JPH0342453B2 (ja) | 1991-06-27 |
Family
ID=16004896
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP17593983A Granted JPS6067934A (ja) | 1983-01-25 | 1983-09-22 | ããã²ã³åéåçä¹³å€ |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6067934A (ja) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6330840A (ja) * | 1986-07-24 | 1988-02-09 | Konica Corp | ããã²ã³åéåçæå ææ |
| JPH0713731B2 (ja) * | 1987-02-23 | 1995-02-15 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | ããã²ã³åéã«ã©âåçæå ææ |
| JP2008023939A (ja) * | 2006-07-25 | 2008-02-07 | Toshiba Hokuto Electronics Corp | ãµãŒãã«ããã |
-
1983
- 1983-09-22 JP JP17593983A patent/JPS6067934A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6067934A (ja) | 1985-04-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH0431102B2 (ja) | ||
| US4764455A (en) | Color image-forming process | |
| JPH051930B2 (ja) | ||
| US4510235A (en) | Silver halide photographic emulsions | |
| JP2542805B2 (ja) | ããã²ã³åéåçä¹³å€ | |
| US4555482A (en) | Silver halide photographic emulsion | |
| JPH0456967B2 (ja) | ||
| JPS61285445A (ja) | ããã²ã³åéåçæå ææ | |
| US4555481A (en) | Silver halide photographic emulsions containing benzimidazolocarbocyanine dye having fluoroalkyl group at the nitrogen atom of benzimidazole | |
| US4659646A (en) | Silver salt diffusion transfer photographic material | |
| US4607005A (en) | Silver halide photographic emulsions | |
| JPS6136213B2 (ja) | ||
| JPH0363056B2 (ja) | ||
| JPH0342453B2 (ja) | ||
| JPH0454935B2 (ja) | ||
| JPH061350B2 (ja) | ããã²ã³åéåçæå ææ | |
| JP3934183B2 (ja) | ã¹ãã¬ããã·ã¢ãã³ååç©åã³è©²ååç©ãå«ãããã²ã³åéä¹³å€ | |
| JPH0810319B2 (ja) | å éšæœååããã²ã³åéåçä¹³å€ | |
| JP3483049B2 (ja) | ããã²ã³åéåçæå ææ | |
| JP3790940B2 (ja) | ããã²ã³åéæå ææ | |
| US5523197A (en) | Multilayer direct-positive photographic material and process for preparing the same | |
| JPH0786665B2 (ja) | ããã²ã³åéåçæå ææ | |
| JP2890277B2 (ja) | ããã²ã³åéåçæå ææ | |
| JPS59200229A (ja) | ããã²ã³åéåçä¹³å€ | |
| US5863714A (en) | Silver halide light-sensitive material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |