JPS6123928B2 - - Google Patents

Info

Publication number: JPS6123928B2
Authority: JP; Japan
Prior art keywords: polymer; monomer; polymerization; polymers; reaction
Prior art date: 1980-12-26
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP18375080A

Other languages

English (en)

Japanese (ja)

Other versions

JPS57108104A (en

Inventor

Shunji Uchio

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Olympus Corp

Original Assignee

Olympus Optical Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1980-12-26

Filing date

1980-12-26

Publication date

1986-06-09

1980-12-26 Application filed by Olympus Optical Co Ltd filed Critical Olympus Optical Co Ltd

1980-12-26 Priority to JP18375080A priority Critical patent/JPS57108104A/ja

1982-07-06 Publication of JPS57108104A publication Critical patent/JPS57108104A/ja

1986-06-09 Publication of JPS6123928B2 publication Critical patent/JPS6123928B2/ja

Status Granted legal-status Critical Current

Links

229920000642 polymer Polymers 0.000 claims description 74
239000000178 monomer Substances 0.000 claims description 60
238000006116 polymerization reaction Methods 0.000 claims description 30
238000006243 chemical reaction Methods 0.000 claims description 20
229920003023 plastic Polymers 0.000 claims description 20
230000003287 optical effect Effects 0.000 claims description 19
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 14
239000004033 plastic Substances 0.000 claims description 13
230000005540 biological transmission Effects 0.000 claims description 4
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 3
239000006188 syrup Substances 0.000 description 13
235000020357 syrup Nutrition 0.000 description 13
239000000203 mixture Substances 0.000 description 12
239000000463 material Substances 0.000 description 10
238000004519 manufacturing process Methods 0.000 description 9
FZYCEURIEDTWNS-UHFFFAOYSA-N prop-1-en-2-ylbenzene Chemical compound CC(=C)C1=CC=CC=C1.CC(=C)C1=CC=CC=C1 FZYCEURIEDTWNS-UHFFFAOYSA-N 0.000 description 9
238000005266 casting Methods 0.000 description 8
238000004132 cross linking Methods 0.000 description 8
239000002904 solvent Substances 0.000 description 8
238000002834 transmittance Methods 0.000 description 8
239000011521 glass Substances 0.000 description 7
238000000034 method Methods 0.000 description 7
DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 6
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 6
239000004342 Benzoyl peroxide Substances 0.000 description 5
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 5
235000019400 benzoyl peroxide Nutrition 0.000 description 5
ROLAGNYPWIVYTG-UHFFFAOYSA-N 1,2-bis(4-methoxyphenyl)ethanamine;hydrochloride Chemical compound Cl.C1=CC(OC)=CC=C1CC(N)C1=CC=C(OC)C=C1 ROLAGNYPWIVYTG-UHFFFAOYSA-N 0.000 description 4
239000012986 chain transfer agent Substances 0.000 description 4
238000005498 polishing Methods 0.000 description 4
229920003229 poly(methyl methacrylate) Polymers 0.000 description 4
239000004926 polymethyl methacrylate Substances 0.000 description 4
239000011347 resin Substances 0.000 description 4
229920005989 resin Polymers 0.000 description 4
238000003756 stirring Methods 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
SYFOAKAXGNMQAX-UHFFFAOYSA-N bis(prop-2-enyl) carbonate;2-(2-hydroxyethoxy)ethanol Chemical compound OCCOCCO.C=CCOC(=O)OCC=C SYFOAKAXGNMQAX-UHFFFAOYSA-N 0.000 description 3
239000006185 dispersion Substances 0.000 description 3
238000002474 experimental method Methods 0.000 description 3
238000001746 injection moulding Methods 0.000 description 3
239000002994 raw material Substances 0.000 description 3
239000004641 Diallyl-phthalate Substances 0.000 description 2
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
239000004793 Polystyrene Substances 0.000 description 2
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
238000010521 absorption reaction Methods 0.000 description 2
QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 2
WQAQPCDUOCURKW-UHFFFAOYSA-N butanethiol Chemical compound CCCCS WQAQPCDUOCURKW-UHFFFAOYSA-N 0.000 description 2
238000000748 compression moulding Methods 0.000 description 2
238000005520 cutting process Methods 0.000 description 2
239000000539 dimer Substances 0.000 description 2
230000000694 effects Effects 0.000 description 2
238000005516 engineering process Methods 0.000 description 2
238000005187 foaming Methods 0.000 description 2
238000000227 grinding Methods 0.000 description 2
229920001519 homopolymer Polymers 0.000 description 2
239000003999 initiator Substances 0.000 description 2
238000000465 moulding Methods 0.000 description 2
230000000704 physical effect Effects 0.000 description 2
229920000515 polycarbonate Polymers 0.000 description 2
239000004417 polycarbonate Substances 0.000 description 2
229920002223 polystyrene Polymers 0.000 description 2
238000012545 processing Methods 0.000 description 2
230000035484 reaction time Effects 0.000 description 2
238000012360 testing method Methods 0.000 description 2
ZOKCNEIWFQCSCM-UHFFFAOYSA-N (2-methyl-4-phenylpent-4-en-2-yl)benzene Chemical compound C=1C=CC=CC=1C(C)(C)CC(=C)C1=CC=CC=C1 ZOKCNEIWFQCSCM-UHFFFAOYSA-N 0.000 description 1
JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
239000004925 Acrylic resin Substances 0.000 description 1
229920000178 Acrylic resin Polymers 0.000 description 1
229910052582 BN Inorganic materials 0.000 description 1
PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
229910000997 High-speed steel Inorganic materials 0.000 description 1
238000000862 absorption spectrum Methods 0.000 description 1
230000009471 action Effects 0.000 description 1
230000004913 activation Effects 0.000 description 1
238000012644 addition polymerization Methods 0.000 description 1
ZDNFTNPFYCKVTB-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,4-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=C(C(=O)OCC=C)C=C1 ZDNFTNPFYCKVTB-UHFFFAOYSA-N 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
230000008602 contraction Effects 0.000 description 1
238000001816 cooling Methods 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
229920006037 cross link polymer Polymers 0.000 description 1
230000003111 delayed effect Effects 0.000 description 1
238000013461 design Methods 0.000 description 1
238000011161 development Methods 0.000 description 1
WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
238000010894 electron beam technology Methods 0.000 description 1
230000005251 gamma ray Effects 0.000 description 1
239000000499 gel Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
239000005457 ice water Substances 0.000 description 1
230000006872 improvement Effects 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
239000011630 iodine Substances 0.000 description 1
GHXZPUGJZVBLGC-UHFFFAOYSA-N iodoethene Chemical compound IC=C GHXZPUGJZVBLGC-UHFFFAOYSA-N 0.000 description 1
239000007788 liquid Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
239000000155 melt Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
239000005304 optical glass Substances 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
238000012805 post-processing Methods 0.000 description 1
QROGIFZRVHSFLM-UHFFFAOYSA-N prop-1-enylbenzene Chemical class CC=CC1=CC=CC=C1 QROGIFZRVHSFLM-UHFFFAOYSA-N 0.000 description 1
238000012827 research and development Methods 0.000 description 1
238000007151 ring opening polymerisation reaction Methods 0.000 description 1
238000001228 spectrum Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
229920005992 thermoplastic resin Polymers 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1
238000012546 transfer Methods 0.000 description 1
238000006276 transfer reaction Methods 0.000 description 1
UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
-1 vinyl acetate-polyethylene Chemical group 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1

Landscapes

Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Polymerisation Methods In General (AREA)

JP18375080A 1980-12-26 1980-12-26 Production of transparent plastic with increased conversion in prepolymerization Granted JPS57108104A (en)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP18375080A JPS57108104A (en)	1980-12-26	1980-12-26	Production of transparent plastic with increased conversion in prepolymerization

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP18375080A JPS57108104A (en)	1980-12-26	1980-12-26	Production of transparent plastic with increased conversion in prepolymerization

Publications (2)

Publication Number	Publication Date
JPS57108104A JPS57108104A (en)	1982-07-06
JPS6123928B2 true JPS6123928B2 (fr)	1986-06-09

Family

ID=16141315

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP18375080A Granted JPS57108104A (en)	1980-12-26	1980-12-26	Production of transparent plastic with increased conversion in prepolymerization

Country Status (1)

Country	Link
JP (1)	JPS57108104A (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2555294B2 (ja) *	1989-06-30	1996-11-20	日本合成ゴム株式会社	紙塗被組成物

1980
- 1980-12-26 JP JP18375080A patent/JPS57108104A/ja active Granted

Also Published As

Publication number	Publication date
JPS57108104A (en)	1982-07-06

Publication	Publication Date	Title
EP0071475B1 (fr)	1985-10-16	Lentille en matière plastique
JPS5845445B2 (ja)	1983-10-11	透明プラスチック成形体の製法
JPS61223008A (ja)	1986-10-03	ジエチレングリコールビス（アリルカーボネート）を含むモノマー組成物の予備重合法
CN1582308A (zh)	2005-02-16	具有优良的光学特性的固化性组合物
JPS6123928B2 (fr)	1986-06-09
JPH0430410B2 (fr)	1992-05-21
JPH0239761B2 (fr)	1990-09-07
JPS58198510A (ja)	1983-11-18	透明プラスチツクとその製造方法
US4725397A (en)	1988-02-16	Thermosetting preform having superior transparency and process for producing molded articles from said preform
JPS58217511A (ja)	1983-12-17	透明プラスチツクの製造方法
JP2001124903A (ja)	2001-05-11	光硬化性樹脂製レンズ
JPS5818601A (ja)	1983-02-03	合成樹脂レンズ
JPS58217510A (ja)	1983-12-17	予備重合率を高めた透明プラスチツクスの製造方法
JPS60144701A (ja)	1985-07-31	高屈折率プラスチツクレンズ
JPS58164608A (ja)	1983-09-29	プラスチツクレンズ用樹脂
JPS58201812A (ja)	1983-11-24	透明プラスチツク
JPS58179210A (ja)	1983-10-20	透明プラスチツク
JPH0312281B2 (fr)	1991-02-19
JPH0679083B2 (ja)	1994-10-05	光学材料
JPS5815513A (ja)	1983-01-28	光学用の共重合樹脂組成物
JPS58168609A (ja)	1983-10-05	プラスチツクレンズ用樹脂
JP4108191B2 (ja)	2008-06-25	合成樹脂製レンズ
JPH0312282B2 (fr)	1991-02-19
JPS63122714A (ja)	1988-05-26	重合性単量体組成物
JPS63193826A (ja)	1988-08-11	光学素子の製造方法