NL8201149A - Polyvinylchloride-mengsels. - Google Patents

Polyvinylchloride-mengsels. Download PDF

Info

Publication number: NL8201149A
Authority: NL; Netherlands
Prior art keywords: parts; impact strength; polyvinyl chloride; strength improver; mixture according
Prior art date: 1980-10-23

Application number

NL8201149A

Other languages

English (en)

Dutch (nl)

Original Assignee

Kureha Chemical Ind Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1980-10-23

Filing date

1982-03-19

Publication date

1983-10-17

1982-03-19 Application filed by Kureha Chemical Ind Co Ltd filed Critical Kureha Chemical Ind Co Ltd

1983-10-17 Publication of NL8201149A publication Critical patent/NL8201149A/nl

Links

239000000203 mixture Substances 0.000 title claims description 64
229920000915 polyvinyl chloride Polymers 0.000 title claims description 46
239000004800 polyvinyl chloride Substances 0.000 title claims description 45
229920000642 polymer Polymers 0.000 claims description 45
239000000178 monomer Substances 0.000 claims description 43
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims description 39
229920000126 latex Polymers 0.000 claims description 37
239000004816 latex Substances 0.000 claims description 36
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 28
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 27
229920002554 vinyl polymer Polymers 0.000 claims description 25
-1 alkyl methacrylate Chemical compound 0.000 claims description 21
150000001993 dienes Chemical class 0.000 claims description 21
239000004971 Cross linker Substances 0.000 claims description 18
238000002845 discoloration Methods 0.000 claims description 14
125000005250 alkyl acrylate group Chemical group 0.000 claims description 13
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 12
150000002825 nitriles Chemical class 0.000 claims description 10
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 5
230000009477 glass transition Effects 0.000 claims description 5
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 3
XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 32
238000006116 polymerization reaction Methods 0.000 description 29
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 26
239000010410 layer Substances 0.000 description 22
229920009204 Methacrylate-butadiene-styrene Polymers 0.000 description 16
230000000052 comparative effect Effects 0.000 description 13
239000002245 particle Substances 0.000 description 12
229920001577 copolymer Polymers 0.000 description 11
238000005452 bending Methods 0.000 description 9
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 7
FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 7
229940048086 sodium pyrophosphate Drugs 0.000 description 7
235000019818 tetrasodium diphosphate Nutrition 0.000 description 7
239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 7
159000000000 sodium salts Chemical class 0.000 description 6
230000002087 whitening effect Effects 0.000 description 5
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
229920001971 elastomer Polymers 0.000 description 4
239000000047 product Substances 0.000 description 4
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
239000003995 emulsifying agent Substances 0.000 description 3
238000007720 emulsion polymerization reaction Methods 0.000 description 3
239000003623 enhancer Substances 0.000 description 3
239000003999 initiator Substances 0.000 description 3
238000004898 kneading Methods 0.000 description 3
SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
239000005977 Ethylene Substances 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
125000000217 alkyl group Chemical group 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
230000001112 coagulating effect Effects 0.000 description 2
239000007771 core particle Substances 0.000 description 2
230000007423 decrease Effects 0.000 description 2
230000000694 effects Effects 0.000 description 2
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
238000000034 method Methods 0.000 description 2
238000002156 mixing Methods 0.000 description 2
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
230000000379 polymerizing effect Effects 0.000 description 2
230000005855 radiation Effects 0.000 description 2
150000003440 styrenes Chemical class 0.000 description 2
229920001567 vinyl ester resin Polymers 0.000 description 2
WVAFEFUPWRPQSY-UHFFFAOYSA-N 1,2,3-tris(ethenyl)benzene Chemical compound C=CC1=CC=CC(C=C)=C1C=C WVAFEFUPWRPQSY-UHFFFAOYSA-N 0.000 description 1
KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
WGGLDBIZIQMEGH-UHFFFAOYSA-N 1-bromo-4-ethenylbenzene Chemical compound BrC1=CC=C(C=C)C=C1 WGGLDBIZIQMEGH-UHFFFAOYSA-N 0.000 description 1
IYDMICQAKLQHLA-UHFFFAOYSA-N 1-phenylnaphthalene Chemical compound C1=CC=CC=C1C1=CC=CC2=CC=CC=C12 IYDMICQAKLQHLA-UHFFFAOYSA-N 0.000 description 1
BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
JJBFVQSGPLGDNX-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)propyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)COC(=O)C(C)=C JJBFVQSGPLGDNX-UHFFFAOYSA-N 0.000 description 1
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 1
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
PMZXJPLGCUVUDN-UHFFFAOYSA-N 4-ethenyl-1,2-dimethylbenzene Chemical compound CC1=CC=C(C=C)C=C1C PMZXJPLGCUVUDN-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
229920001875 Ebonite Polymers 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 1
206010047289 Ventricular extrasystoles Diseases 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
238000003916 acid precipitation Methods 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
239000012190 activator Substances 0.000 description 1
239000000654 additive Substances 0.000 description 1
238000005054 agglomeration Methods 0.000 description 1
230000002776 aggregation Effects 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
230000005540 biological transmission Effects 0.000 description 1
230000002051 biphasic effect Effects 0.000 description 1
JZQAAQZDDMEFGZ-UHFFFAOYSA-N bis(ethenyl) hexanedioate Chemical compound C=COC(=O)CCCCC(=O)OC=C JZQAAQZDDMEFGZ-UHFFFAOYSA-N 0.000 description 1
ZPOLOEWJWXZUSP-WAYWQWQTSA-N bis(prop-2-enyl) (z)-but-2-enedioate Chemical compound C=CCOC(=O)\C=C/C(=O)OCC=C ZPOLOEWJWXZUSP-WAYWQWQTSA-N 0.000 description 1
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
SPTHWAJJMLCAQF-UHFFFAOYSA-M ctk4f8481 Chemical compound [O-]O.CC(C)C1=CC=CC=C1C(C)C SPTHWAJJMLCAQF-UHFFFAOYSA-M 0.000 description 1
HGQSXVKHVMGQRG-UHFFFAOYSA-N dioctyltin Chemical compound CCCCCCCC[Sn]CCCCCCCC HGQSXVKHVMGQRG-UHFFFAOYSA-N 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000001035 drying Methods 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
VXNZUUAINFGPBY-UHFFFAOYSA-N ethyl ethylene Natural products CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
229940071106 ethylenediaminetetraacetate Drugs 0.000 description 1
229920000578 graft copolymer Polymers 0.000 description 1
125000001475 halogen functional group Chemical group 0.000 description 1
239000012760 heat stabilizer Substances 0.000 description 1
239000011229 interlayer Substances 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
239000000463 material Substances 0.000 description 1
229940096992 potassium oleate Drugs 0.000 description 1
MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
238000005096 rolling process Methods 0.000 description 1
238000005185 salting out Methods 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
238000010186 staining Methods 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
150000005846 sugar alcohols Polymers 0.000 description 1
239000000725 suspension Substances 0.000 description 1
229920003002 synthetic resin Polymers 0.000 description 1
239000000057 synthetic resin Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/20—Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Graft Or Block Polymers (AREA)
Compositions Of Macromolecular Compounds (AREA)
Paints Or Removers (AREA)

NL8201149A 1980-10-23 1982-03-19 Polyvinylchloride-mengsels. NL8201149A (nl)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
JP55148729A JPS592704B2 (ja)	1980-10-23	1980-10-23	塩化ビニル系樹脂組成物
JP14872980		1980-10-23

Publications (1)

Publication Number	Publication Date
NL8201149A true NL8201149A (nl)	1983-10-17

Family

ID=15459297

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NL8201149A NL8201149A (nl)	1980-10-23	1982-03-19	Polyvinylchloride-mengsels.

Country Status (10)

Country	Link
US (1)	US4352910A (de)
EP (1)	EP0050848B1 (de)
JP (1)	JPS592704B2 (de)
KR (1)	KR860001212B1 (de)
AU (1)	AU546182B2 (de)
BR (1)	BR8106824A (de)
CA (1)	CA1180484A (de)
DE (1)	DE3170754D1 (de)
MX (1)	MX160493A (de)
NL (1)	NL8201149A (de)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA1201547A (en) *	1982-07-13	1986-03-04	Akira Takaki	Graft copolymer useful as reinforcements for vinyl chloride polymers and process for preparing the same
JPS5933342A (ja) *	1982-08-18	1984-02-23	Mitsubishi Rayon Co Ltd	塩化ビニル系樹脂組成物
JPS5951931A (ja) *	1982-09-16	1984-03-26	Sumitomo Chem Co Ltd	塩化ビニル系樹脂組成物
JPS5998151A (ja) *	1982-11-08	1984-06-06	Mitsubishi Rayon Co Ltd	塩化ビニル系樹脂組成物
JPS5998153A (ja) *	1982-11-09	1984-06-06	Mitsubishi Rayon Co Ltd	塩化ビニル系樹脂組成物
DE3300526A1 (de) *	1983-01-10	1984-07-12	Röhm GmbH, 6100 Darmstadt	Schlagzaehmodifizierungsmittel
JPS60208349A (ja) *	1984-04-03	1985-10-19	Kanegafuchi Chem Ind Co Ltd	耐衝撃性難燃性樹脂組成物の製造方法
JPS60217252A (ja) *	1984-04-12	1985-10-30	Kanegafuchi Chem Ind Co Ltd	耐衝撃性に優れた塩化ビニル樹脂組成物
JPS60235854A (ja) *	1984-05-08	1985-11-22	Kanegafuchi Chem Ind Co Ltd	耐溶剤性に優れた塩化ビニル系樹脂組成物
US4602064A (en) *	1984-11-30	1986-07-22	The Dow Chemical Company	Grafted rubber concentrates for use in impact resistant polymers
JPH062792B2 (ja) *	1985-05-10	1994-01-12	三菱レイヨン株式会社	熱可塑性樹脂用滑剤
JPH01313551A (ja) *	1988-06-14	1989-12-19	Mitsubishi Rayon Co Ltd	ポリ塩化ビニル系樹脂組成物
US5047474A (en) *	1989-08-03	1991-09-10	Rohm And Haas Company	Polymeric modifier compositions
JPH02191652A (ja) *	1989-12-22	1990-07-27	Kanegafuchi Chem Ind Co Ltd	耐溶剤性に優れた塩化ビニル系樹脂組成物
DE4101969A1 (de) *	1991-01-24	1992-07-30	Basf Ag	Schlagfeste polyvinylhalogenidformmasse mit hoher transparenz
AU3941593A (en) *	1992-04-15	1993-11-18	B.F. Goodrich Company, The	Multilayer core-shell polymer compositions as toughener for thermosets and thermoplastics
DE69923267T2 (de)	1998-09-09	2006-03-30	Rohm And Haas Co.	Verbesserte MBS schlagzähe Modifiziermittel
KR100454023B1 (ko)	2000-10-27	2004-10-20	주식회사 엘지화학	내백화성이 우수한 메틸메타크릴레이트-부타디엔-스티렌의그라프트 공중합체 제조방법
KR100417062B1 (ko) *	2001-01-11	2004-02-05	주식회사 엘지화학	바이모달 입자분포로 이루어진 아크릴계 고무라텍스의제조방법
RU2212421C2 (ru) *	2001-09-03	2003-09-20	Государственное унитарное предприятие Республики Татарстан Завод "СТРОЙПЛАСТ" при Государственном внебюджетном жилищном фонде	Композиция на основе пвх для профильных изделий
US8048524B2 (en)	2003-12-30	2011-11-01	Lg Chem, Ltd.	Polymer latex having excellent impact-resistance and powder flow property and method for preparing the same
KR100708965B1 (ko)	2004-09-01	2007-04-18	주식회사 엘지화학	우수한 내충격성과 내후성을 갖는 아크릴-공액디엔계 복합고무성 충격보강제 및 이의 제조방법
EP1866352A4 (de) *	2005-08-19	2009-03-25	Lg Chemical Ltd	Schlagfestigkeitsmodifikatoren für polyvinylchloridharz und herstellungsverfahren dafür
TWI385187B (zh) *	2006-08-29	2013-02-11	Mitsubishi Rayon Co	熱可塑性樹脂組成物及成型品
KR100997278B1 (ko) *	2007-01-16	2010-11-29	주식회사 엘지화학	투명 열가소성 폴리우레탄 수지용 그라프트 공중합체, 이의제조방법 및 이를 포함하는 폴리우레탄 수지 조성물
US9260603B2 (en) *	2013-03-15	2016-02-16	Sabic Global Technologies B.V.	Polymer compositions, method of manufacture, and articles formed therefrom
CN109971086A (zh)	2019-02-14	2019-07-05	山东东临新材料股份有限公司	一种pvc易加工不透明高抗冲mbs及其制备方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
NL130337C (de) *	1967-08-19
US3644249A (en) *	1968-07-10	1972-02-22	Mitsubishi Rayon Co	Polyvinyl chloride resin composition having excellent transparency, surface gloss and impact strength
US3886232A (en) *	1971-10-07	1975-05-27	Kureha Chemical Ind Co Ltd	Process for producing vinyl chloride resin composition
BE790738A (fr) *	1972-10-06	1973-04-30	Denki Kagaku Kogyo Kk	Composition comprenant une resine chlorovinylique et un nouveaucopolymere greffe, et son procede de preparation
US3959895A (en) *	1974-06-27	1976-06-01	Monsanto Company	Polyvinyl chloride polyblend molding
US4133788A (en) *	1978-01-23	1979-01-09	Borg-Warner Corporation	Polymer latex which is cross-linked with a dialkyl tin diacrylate in the preparation of grafted copolymers

1980
- 1980-10-23 JP JP55148729A patent/JPS592704B2/ja not_active Expired
1981
- 1981-10-20 US US06/313,198 patent/US4352910A/en not_active Expired - Lifetime
- 1981-10-22 AU AU76732/81A patent/AU546182B2/en not_active Ceased
- 1981-10-22 KR KR1019810004010A patent/KR860001212B1/ko not_active Expired
- 1981-10-22 BR BR8106824A patent/BR8106824A/pt not_active IP Right Cessation
- 1981-10-22 EP EP81108757A patent/EP0050848B1/de not_active Expired
- 1981-10-22 MX MX189762A patent/MX160493A/es unknown
- 1981-10-22 DE DE8181108757T patent/DE3170754D1/de not_active Expired
- 1981-10-22 CA CA000388519A patent/CA1180484A/en not_active Expired
1982
- 1982-03-19 NL NL8201149A patent/NL8201149A/nl not_active Application Discontinuation

Also Published As

Publication number	Publication date
JPS5773036A (en)	1982-05-07
KR830007733A (ko)	1983-11-07
EP0050848A2 (de)	1982-05-05
EP0050848B1 (de)	1985-05-29
EP0050848A3 (en)	1982-09-01
KR860001212B1 (ko)	1986-08-27
AU7673281A (en)	1982-04-29
BR8106824A (pt)	1982-07-06
CA1180484A (en)	1985-01-02
DE3170754D1 (en)	1985-07-04
US4352910A (en)	1982-10-05
JPS592704B2 (ja)	1984-01-20
AU546182B2 (en)	1985-08-22
MX160493A (es)	1990-03-12

Legal Events

Date	Code	Title
1985-01-01	A85	Still pending on 85-01-01
1989-01-02	BA	A request for search or an international-type search has been filed
1989-01-02	BB	A search report has been drawn up
1989-02-01	BC	A request for examination has been filed
1993-11-01	BV	The patent application has lapsed

Publication	Publication Date	Title
NL8201149A (nl)	1983-10-17	Polyvinylchloride-mengsels.
US3833686A (en)	1974-09-03	Sequentially produced alkyl acrylate polymers blended with poly(vinyl halides)
US3678133A (en)	1972-07-18	Modified vinyl halide polymers
KR102080102B1 (ko)	2020-04-24	열가소성 수지 조성물, 이의 제조방법 및 이를 포함하는 성형품
AU758859B2 (en)	2003-04-03	Resin composition containing multilayered graft polymer
EP1778785B1 (de)	2012-09-19	Transparente thermoplastische harzzusammensetzungen und herstellungsverfahren dafür
JP2021517929A (ja)	2021-07-29	熱可塑性樹脂組成物
KR20090084574A (ko)	2009-08-05	고광택, 고경도 투명 열가소성 수지 조성물
JPH0576500B2 (de)	1993-10-22
US8008397B2 (en)	2011-08-30	Impact strength modifiers for polyvinyl chloride resin and method of preparing them
EP0278788B1 (de)	1994-05-04	Kunstharzmischungen auf PVC-Basis und zu ihrer Herstellung verwendbare Pfropfcopolymere
US4594387A (en)	1986-06-10	Thermoplastic resin composition having toughness and high thermal deformation resistance
AU6946001A (en)	2002-01-21	Transparent impact-resistant thermoplastic resin composition
US5610235A (en)	1997-03-11	High gloss graft copolymer blend containing emulsion graft copolymer and bulk graft copolymer
JPS61127755A (ja)	1986-06-16	熱可塑性樹脂組成物
US3652727A (en)	1972-03-28	Vinyl chloride series resin compositions
JP2000204220A (ja)	2000-07-25	メタクリル系樹脂用改質剤
JPH0781062B2 (ja)	1995-08-30	耐衝撃性メタクリル樹脂組成物
JP3438833B2 (ja)	2003-08-18	耐衝撃性熱可塑性樹脂の製造法
JP2002226655A (ja)	2002-08-14	ゴム変性スチレン系樹脂組成物
KR20190076137A (ko)	2019-07-02	그라프트 공중합체의 제조방법 및 열가소성 수지 조성물
JPS61236850A (ja)	1986-10-22	熱可塑性樹脂組成物
JPH0143779B2 (de)	1989-09-22
KR100461524B1 (ko)	2005-04-06	내스팀성이우수한열가소성수지조성물
JP2616073B2 (ja)	1997-06-04	耐衝撃性熱可塑性樹脂組成物及び成形品