PL412559A1 - Ammonium ionic liquids with anion of natural origin and method for producing them and their application as feeding deterrents - Google Patents
Ammonium ionic liquids with anion of natural origin and method for producing them and their application as feeding deterrentsInfo
- Publication number
- PL412559A1 PL412559A1 PL412559A PL41255915A PL412559A1 PL 412559 A1 PL412559 A1 PL 412559A1 PL 412559 A PL412559 A PL 412559A PL 41255915 A PL41255915 A PL 41255915A PL 412559 A1 PL412559 A1 PL 412559A1
- Authority
- PL
- Poland
- Prior art keywords
- ionic liquids
- natural origin
- anion
- ammonium ionic
- ammonium
- Prior art date
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Przedmiotem wynalazku są amoniowe ciecze jonowe z anionem pochodzenia naturalnego i sposób ich wytwarzania oraz zastosowanie jako deterentów pokarmowych. Amoniowe ciecze jonowe o wzorze ogólnym 1, w którym R1 i R2 oznaczają podstawniki alkilowe zawierające 1 - 22 atomów węgla lub podstawnik benzylowy, a A oznacza anion pochodzenia naturalnego, którego źródłem są triglicerydy zawarte w tłuszczach roślinnych lub zwierzęcych. Sposób ich otrzymywania polega na tym, że czwartorzędowy wodorotlenek amoniowy, poddaje się reakcji z tłuszczem pochodzenia naturalnego w stosunku molowym wodorotlenku do tłuszczu równym 3 : 0,8 - 1,3 w środowisku alkoholu drugorzędowego, korzystnie 2 - propanolu, w temperaturze od 25 do 80°C, korzystnie w 80°C, w czasie 1 - 24 godzin, po czym odparowuje się rozpuszczalnik, a powstały układ poddaje się ekstrakcji w układzie rozpuszczalnik organiczny - woda, korzystnie chloroform, dichlorometan, heksan - woda, po czym rozpuszczalnik organiczny odparowuje się, a powstały produkt, nie zawierający zanieczyszczeń, suszy pod obniżonym ciśnieniem w temperaturze od 30 do 80°C w czasie 1 - 24 godzin. Ujawniono również zastosowanie amoniowych cieczy jonowych o wzorze ogólnym 1, jako detergentów pokarmowych.The subject of the invention are ammonium ionic liquids with anion of natural origin and the method of their preparation and use as food detectors. Ammonium ionic liquids of general formula 1, wherein R1 and R2 are alkyl substituents containing 1 - 22 carbon atoms or benzyl substituent, and A is anion of natural origin, whose source is triglycerides contained in vegetable or animal fats. The method of their preparation consists in the fact that the quaternary ammonium hydroxide is reacted with fat of natural origin in a molar ratio of hydroxide to fat of 3: 0.8 - 1.3 in a secondary alcohol environment, preferably 2 - propanol, at a temperature of 25 to 80 ° C, preferably at 80 ° C, for 1 - 24 hours, after which the solvent is evaporated and the resulting system is extracted in an organic solvent - water system, preferably chloroform, dichloromethane, hexane - water, then the organic solvent is evaporated and the resulting product, containing no impurities, dried under reduced pressure at a temperature of 30 to 80 ° C for 1 to 24 hours. Also disclosed is the use of ammonium ionic liquids of general formula 1 as food detergents.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL412559A PL229997B1 (en) | 2015-06-01 | 2015-06-01 | Ammonium ionic liquids with anion of natural origin and method for producing them and their application as feeding deterrents |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL412559A PL229997B1 (en) | 2015-06-01 | 2015-06-01 | Ammonium ionic liquids with anion of natural origin and method for producing them and their application as feeding deterrents |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL412559A1 true PL412559A1 (en) | 2016-12-05 |
| PL229997B1 PL229997B1 (en) | 2018-09-28 |
Family
ID=57405943
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL412559A PL229997B1 (en) | 2015-06-01 | 2015-06-01 | Ammonium ionic liquids with anion of natural origin and method for producing them and their application as feeding deterrents |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL229997B1 (en) |
-
2015
- 2015-06-01 PL PL412559A patent/PL229997B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL229997B1 (en) | 2018-09-28 |
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