PL417897A1 - New type phases of restricted solid solutions doped with d- and f-electron metal ions and method for producing the type phases of restricted solid solutions doped with d- and f-electron metal ions - Google Patents
New type phases of restricted solid solutions doped with d- and f-electron metal ions and method for producing the type phases of restricted solid solutions doped with d- and f-electron metal ionsInfo
- Publication number
- PL417897A1 PL417897A1 PL417897A PL41789716A PL417897A1 PL 417897 A1 PL417897 A1 PL 417897A1 PL 417897 A PL417897 A PL 417897A PL 41789716 A PL41789716 A PL 41789716A PL 417897 A1 PL417897 A1 PL 417897A1
- Authority
- PL
- Poland
- Prior art keywords
- metal ions
- solid solutions
- electron metal
- mol
- type phases
- Prior art date
Links
- 229910000678 Elektron (alloy) Inorganic materials 0.000 title abstract 6
- 150000002500 ions Chemical class 0.000 title abstract 4
- 239000006104 solid solution Substances 0.000 title abstract 4
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 229910052748 manganese Inorganic materials 0.000 abstract 3
- 239000011572 manganese Substances 0.000 abstract 3
- 239000013078 crystal Substances 0.000 abstract 2
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 abstract 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052779 Neodymium Inorganic materials 0.000 abstract 1
- BIOOACNPATUQFW-UHFFFAOYSA-N calcium;dioxido(dioxo)molybdenum Chemical compound [Ca+2].[O-][Mo]([O-])(=O)=O BIOOACNPATUQFW-UHFFFAOYSA-N 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- KYYSIVCCYWZZLR-UHFFFAOYSA-N cobalt(2+);dioxido(dioxo)molybdenum Chemical compound [Co+2].[O-][Mo]([O-])(=O)=O KYYSIVCCYWZZLR-UHFFFAOYSA-N 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000000265 homogenisation Methods 0.000 abstract 1
- QYZFLCQIQOHNTP-UHFFFAOYSA-N manganese(ii) molybdate Chemical compound [Mn+2].[O-][Mo]([O-])(=O)=O QYZFLCQIQOHNTP-UHFFFAOYSA-N 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 abstract 1
Landscapes
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Przedmiotem zgłoszenia są nowe fazy typu ograniczonych roztworów stałych dotowanych jonami d- i f-elektronowego metalu, które charakteryzują się tym, że metal d-elektronowy stanowi mangan lub kobalt, metal f-elektronowy stanowi neodym o ogólnym wzorze Ca0,9934-3xM0,0066 xNd2x(MoO4)1-3x(WO4)3x, gdzie 0 < x ? 0,25, M oznacza Mn lub Co, a oznacza wakancje w sieci krystalicznej. Zgłoszenie zawiera też sposób wytwarzania faz typu ograniczonych roztworów stałych dotowanych jonami d- i f-elektronowego metalu według wynalazku, polegający na mieszaniu, ujednorodnianiu, wygrzewaniu i chłodzeniu, charakteryzuje się tym, że molibdenian(VI) wapnia w ilości większej niż lub równej 49,00% molowego, a mniejszej niż 100,00% molowego miesza się z wolframianem(VI) neodymu(III) w ilości większej niż 0% molowego a mniejszej niż lub równej 50,00% molowego oraz molibdenianem(VI) manganu(II) lub molibdenianem(VI) kobaltu(II) w ilości równej 1,00% molowego, po czym mieszaniny praży się w temperaturze od 900 do 1170°C, następnie chłodzi otrzymując produkt o ogólnym wzorze, Ca0,9934-3xM0,0066 xNd2x(MoO4)1-3x(WO4)3x, gdzie 0 < x ? 0,25, M oznacza Mn lub Co, a oznacza wakancje w sieci krystalicznej.The subject of the application are new phases of the type of limited solid solutions subsidized with d- and f-electron metal ions, which are characterized in that the d-electron metal is manganese or cobalt, the f-electron metal is a neodymium with the general formula Ca0.9934-3xM0.0066 xNd2x (MoO4) 1-3x (WO4) 3x, where 0 <x? 0.25, M is Mn or Co, and means vacancies in the crystal lattice. The application also contains a method for producing phases of the type of limited solid solutions subsidized with d- and f-electron metal ions according to the invention, consisting in mixing, homogenization, heating and cooling, characterized in that calcium molybdate in an amount greater than or equal to 49, 00 mol% and less than 100.00 mol% is mixed with neodymium (III) tungstate in an amount greater than 0 mol% and less than or equal to 50.00 mol% and manganese (II) molybdate or cobalt (II) molybdate in an amount equal to 1.00 mol%, after which the mixtures are calcined at 900 to 1170 ° C, then cooled to give the product of the general formula, Ca0.9934-3xM0.0066 xNd2x (MoO4) 1-3x (WO4) 3x, where 0 <x? 0.25, M is Mn or Co, and means vacancies in the crystal lattice.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL417897A PL231517B1 (en) | 2016-07-11 | 2016-07-11 | New type phases of restricted solid solutions doped with d- and f-electron metal ions and method for producing the type phases of restricted solid solutions doped with d- and f-electron metal ions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL417897A PL231517B1 (en) | 2016-07-11 | 2016-07-11 | New type phases of restricted solid solutions doped with d- and f-electron metal ions and method for producing the type phases of restricted solid solutions doped with d- and f-electron metal ions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL417897A1 true PL417897A1 (en) | 2018-01-15 |
| PL231517B1 PL231517B1 (en) | 2019-03-29 |
Family
ID=60937392
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL417897A PL231517B1 (en) | 2016-07-11 | 2016-07-11 | New type phases of restricted solid solutions doped with d- and f-electron metal ions and method for producing the type phases of restricted solid solutions doped with d- and f-electron metal ions |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL231517B1 (en) |
-
2016
- 2016-07-11 PL PL417897A patent/PL231517B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL231517B1 (en) | 2019-03-29 |
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