PL417368A1 - New type phase of restricted solid solution in the triple system of vanadium, ytterbium and yttrium oxides and method for producing new type phase of restricted solid solution in the triple system of vanadium, ytterbium and yttrium oxides - Google Patents
New type phase of restricted solid solution in the triple system of vanadium, ytterbium and yttrium oxides and method for producing new type phase of restricted solid solution in the triple system of vanadium, ytterbium and yttrium oxidesInfo
- Publication number
- PL417368A1 PL417368A1 PL417368A PL41736816A PL417368A1 PL 417368 A1 PL417368 A1 PL 417368A1 PL 417368 A PL417368 A PL 417368A PL 41736816 A PL41736816 A PL 41736816A PL 417368 A1 PL417368 A1 PL 417368A1
- Authority
- PL
- Poland
- Prior art keywords
- yttrium
- vanadium
- mol
- ytterbium
- solid solution
- Prior art date
Links
- RUDFQVOCFDJEEF-UHFFFAOYSA-N oxygen(2-);yttrium(3+) Chemical class [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 title abstract 6
- 239000006104 solid solution Substances 0.000 title abstract 4
- 229910052720 vanadium Inorganic materials 0.000 title abstract 4
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 229910052769 Ytterbium Inorganic materials 0.000 title 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 title 2
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 title 2
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 abstract 3
- FIXNOXLJNSSSLJ-UHFFFAOYSA-N ytterbium(III) oxide Inorganic materials O=[Yb]O[Yb]=O FIXNOXLJNSSSLJ-UHFFFAOYSA-N 0.000 abstract 3
- 229910052727 yttrium Inorganic materials 0.000 abstract 3
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 abstract 3
- 239000003153 chemical reaction reagent Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- UZLYXNNZYFBAQO-UHFFFAOYSA-N oxygen(2-);ytterbium(3+) Chemical compound [O-2].[O-2].[O-2].[Yb+3].[Yb+3] UZLYXNNZYFBAQO-UHFFFAOYSA-N 0.000 abstract 2
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 abstract 2
- CBPUGRVPJJEDMD-UHFFFAOYSA-N [O-2].[V+5].[O-2].[Y+3] Chemical compound [O-2].[V+5].[O-2].[Y+3] CBPUGRVPJJEDMD-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 abstract 1
- 150000003748 yttrium compounds Chemical class 0.000 abstract 1
Landscapes
- Luminescent Compositions (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Abstract
Przedmiotem zgłoszenia jest nowa faza typu ograniczonego roztworu stałego w potrójnym układzie tlenków wanadu, iterbu i itru, o ogólnym wzorze Yb8-xYxV2O17, gdzie 0<x?4, w którym układ potrójny tlenków oznacza układ tlenek wanadu(V)-tlenek itru(III)-tlenek iterbu(III). Zgłoszenie obejmuje też sposób wytwarzania faz typu ograniczonego roztworu stałego w potrójnym układzie tlenków wanadu, iterbu i itru, polegający na tym, że związki itru i iterbu miesza się, ujednorodnia, wygrzewa i chłodzi, charakteryzuje się tym, że miesza się związki Yb8V2O17 i Y8V2O17 w stosunku molowym takim, że suma zawartości tych związków w procentach molowych jest zawsze równa 100,00, przy czym zawartość Y8V2O17 jest zawsze mniejsza lub równa 50,00% molowych. Otrzymaną mieszaninę reagentów ujednorodnia się przez ucieranie, a następnie wygrzewa w temperaturach od 1000 do 1600°C, korzystnie, w co najmniej trzech etapach po 24 godziny każdy, przy czym po każdym etapie próbki ochładza się wolno do temperatury pokojowej i rozciera, otrzymując produkt o ogólnym wzorze Yb8-xYxV2O17, gdzie x mieści się w przedziale 0<x?4. Zgłoszenie zawiera tez inny sposób wytwarzania faz, który charakteryzuje się tym, że miesza się tlenek wanadu(V) w ilości 20,00% molowych, tlenek itru(III) w ilości większej od 0,00% molowych, a mniejszej lub równej 40,00% molowych oraz tlenek iterbu(III) w ilości większej lub równej 40,00% molowych a mniejszej od 100,00% molowych, przy czym suma zawartości Y2O3 i Yb2O3 wynosi zawsze 80,00% molowych. Otrzymaną mieszaninę reagentów ujednorodnia się przez ucieranie, a następnie wygrzewa w temperaturach od 550 do 1600°C, korzystnie w co najmniej pięciu etapach, po 24 godziny każdy, przy czym po każdym etapie próbki ochładza się wolno do temperatury pokojowej i rozciera, otrzymując produkt o ogólnym wzorze Yb8-xYxV2O17, gdzie x mieści się w przedziale 0<x?4.The subject of the application is a new phase of a limited solid solution type in the triple system of vanadium, yttrium and yttrium oxides, with the general formula Yb8-xYxV2O17, where 0 <x? 4, in which the triple system of oxides is the vanadium (V) oxide-yttrium oxide system (III ) ytterbium (III) oxide. The application also includes a method for producing limited solid solution phases in a triple system of vanadium, yttrium and yttrium oxides, in which yttrium and yttrium compounds are mixed, homogenised, annealed and cooled, characterized by mixing Yb8V2O17 and Y8V2O17 in molar ratio such that the sum of the content of these compounds in molar percentages is always equal to 100.00, with the Y8V2O17 content always being less than or equal to 50.00 mol%. The resulting reagent mixture is homogenised and then annealed at temperatures from 1000 to 1600 ° C, preferably in at least three steps of 24 hours each, after which each sample is slowly cooled to room temperature and triturated to give the product general formula Yb8-xYxV2O17, where x is in the range 0 <x → 4. The application also contains another method of producing phases, which is characterized in that vanadium (V) oxide is mixed in an amount of 20.00 mol%, yttrium (III) oxide in an amount greater than 0.00 mol%, and less than or equal to 40, 00 mol% and ytterbium (III) oxide in an amount greater than or equal to 40.00 mol% and less than 100.00 mol%, with the sum of Y2O3 and Yb2O3 content always 80.00 mol%. The resulting reagent mixture is homogenized by grinding and then heated at temperatures from 550 to 1600 ° C, preferably in at least five stages, 24 hours each, with each sample slowly cooled to room temperature and ground to obtain a product with general formula Yb8-xYxV2O17, where x is in the range 0 <x → 4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL417368A PL235461B1 (en) | 2016-06-02 | 2016-06-02 | New type phase of restricted solid solution in the triple system of vanadium, ytterbium and yttrium oxides and method for producing new type phase of restricted solid solution in the triple system of vanadium, ytterbium and yttrium oxides |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL417368A PL235461B1 (en) | 2016-06-02 | 2016-06-02 | New type phase of restricted solid solution in the triple system of vanadium, ytterbium and yttrium oxides and method for producing new type phase of restricted solid solution in the triple system of vanadium, ytterbium and yttrium oxides |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL417368A1 true PL417368A1 (en) | 2017-12-04 |
| PL235461B1 PL235461B1 (en) | 2020-08-10 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL417368A PL235461B1 (en) | 2016-06-02 | 2016-06-02 | New type phase of restricted solid solution in the triple system of vanadium, ytterbium and yttrium oxides and method for producing new type phase of restricted solid solution in the triple system of vanadium, ytterbium and yttrium oxides |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL235461B1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL424228A1 (en) * | 2018-01-10 | 2019-07-15 | Zachodniopomorski Uniwersytet Technologiczny W Szczecinie | Restricted solid solution in the triple system of transition metal oxides, containing vanadium, ytterbium, yttrium and oxygen and method for producing restricted solid solution |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL249736B1 (en) * | 2024-05-27 | 2026-06-08 | Univ West Pomeranian Szczecin Tech | Substitutional solid solution with limited solubility of components in a binary system of yttrium and samarium vanadates(V) and methods of its preparation |
| PL249766B1 (en) * | 2024-08-29 | 2026-06-15 | Univ West Pomeranian Szczecin Tech | A substitutional solid solution with a limited homogeneity range in a ternary system of vanadium, samarium and yttrium oxides and methods of its preparation |
-
2016
- 2016-06-02 PL PL417368A patent/PL235461B1/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL424228A1 (en) * | 2018-01-10 | 2019-07-15 | Zachodniopomorski Uniwersytet Technologiczny W Szczecinie | Restricted solid solution in the triple system of transition metal oxides, containing vanadium, ytterbium, yttrium and oxygen and method for producing restricted solid solution |
Also Published As
| Publication number | Publication date |
|---|---|
| PL235461B1 (en) | 2020-08-10 |
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