PL450223A1 - Method of oxidizing limonene in the presence of a catalyst - Google Patents

Method of oxidizing limonene in the presence of a catalyst

Info

Publication number
PL450223A1
PL450223A1 PL450223A PL45022324A PL450223A1 PL 450223 A1 PL450223 A1 PL 450223A1 PL 450223 A PL450223 A PL 450223A PL 45022324 A PL45022324 A PL 45022324A PL 450223 A1 PL450223 A1 PL 450223A1
Authority
PL
Poland
Prior art keywords
catalyst
limonene
oxidizing
sparger
oxygen
Prior art date
Application number
PL450223A
Other languages
Polish (pl)
Inventor
Agnieszka Wróblewska
Sylwia Gajewska
Joanna Siemak
Beata Michalkiewicz
Original Assignee
Zachodniopomorski Uniwersytet Technologiczny W Szczecinie
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zachodniopomorski Uniwersytet Technologiczny W Szczecinie filed Critical Zachodniopomorski Uniwersytet Technologiczny W Szczecinie
Priority to PL450223A priority Critical patent/PL450223A1/en
Publication of PL450223A1 publication Critical patent/PL450223A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/06—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the liquid phase
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Przedmiotem zgłoszenia jest sposób utleniania limonenu w obecności katalizatora, polegający na mieszaniu limonenu z katalizatorem w ilości od 0,5% wag. do 5% wag. w stosunku do limonenu pod ciśnieniem atmosferycznym, z intensywnością mieszania 500 obr./minutę, w atmosferze tlenu podawanego z butli przez bełkotkę stosując przepływ tlenu 40 ml/minutę, w czasie od 15 minut do 360 minut, który charakteryzuje się tym, że jako katalizator stosuje się wysuszone i rozdrobnione pestki awokado, przy czym proces prowadzi się w temperaturze 70°C - 100°C. Stosuje się pestki awokado wysuszone i rozdrobnione do wielkości ziaren nie większych niż 0,43 mm. Do reaktora szklanego wprowadza się w pierwszej kolejności limonen, później katalizator, na samym końcu doprowadza się tlen przez bełkotkę.The subject of the application is a method for oxidizing limonene in the presence of a catalyst, consisting of mixing limonene with a catalyst in an amount from 0.5% by weight to 5% by weight of limonene at atmospheric pressure, with a stirring intensity of 500 rpm, in an atmosphere of oxygen supplied from a cylinder through a sparger using an oxygen flow of 40 ml/minute, for a time of 15 minutes to 360 minutes, characterized in that dried and crushed avocado pits are used as the catalyst, with the process being carried out at a temperature of 70°C - 100°C. Dried avocado pits are used, crushed to a grain size of no more than 0.43 mm. Limonene is first introduced into the glass reactor, then the catalyst, and finally oxygen is introduced through a sparger.

PL450223A 2024-11-07 2024-11-07 Method of oxidizing limonene in the presence of a catalyst PL450223A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL450223A PL450223A1 (en) 2024-11-07 2024-11-07 Method of oxidizing limonene in the presence of a catalyst

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL450223A PL450223A1 (en) 2024-11-07 2024-11-07 Method of oxidizing limonene in the presence of a catalyst

Publications (1)

Publication Number Publication Date
PL450223A1 true PL450223A1 (en) 2026-05-11

Family

ID=99717240

Family Applications (1)

Application Number Title Priority Date Filing Date
PL450223A PL450223A1 (en) 2024-11-07 2024-11-07 Method of oxidizing limonene in the presence of a catalyst

Country Status (1)

Country Link
PL (1) PL450223A1 (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL416571A1 (en) * 2016-03-22 2017-09-25 Zachodniopomorski Uniwersytet Technologiczny W Szczecinie Method for oxidation of limonene
PL420101A1 (en) * 2017-01-03 2018-07-16 Zachodniopomorski Uniwersytet Technologiczny W Szczecinie Method for oxidation of limonene

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL416571A1 (en) * 2016-03-22 2017-09-25 Zachodniopomorski Uniwersytet Technologiczny W Szczecinie Method for oxidation of limonene
PL420101A1 (en) * 2017-01-03 2018-07-16 Zachodniopomorski Uniwersytet Technologiczny W Szczecinie Method for oxidation of limonene

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