WO2009025334A1 - 肥大化ゴムの製造方法、グラフト共重合体、熱可塑性樹脂組成物および成形品 - Google Patents

肥大化ゴムの製造方法、グラフト共重合体、熱可塑性樹脂組成物および成形品 Download PDF

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Publication number
WO2009025334A1
WO2009025334A1 PCT/JP2008/064947 JP2008064947W WO2009025334A1 WO 2009025334 A1 WO2009025334 A1 WO 2009025334A1 JP 2008064947 W JP2008064947 W JP 2008064947W WO 2009025334 A1 WO2009025334 A1 WO 2009025334A1
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Prior art keywords
mass
resin composition
thermoplastic resin
graft copolymer
acid group
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Ceased
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PCT/JP2008/064947
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English (en)
French (fr)
Inventor
Yoshifumi Shikisai
Naoki Konishi
Yasuo Masaki
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Techno UMG Co Ltd
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UMG ABS Ltd
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Publication date
Priority claimed from JP2007214714A external-priority patent/JP2009046602A/ja
Priority claimed from JP2007235285A external-priority patent/JP2009067839A/ja
Priority claimed from JP2007262083A external-priority patent/JP2009091420A/ja
Application filed by UMG ABS Ltd filed Critical UMG ABS Ltd
Priority to KR1020107003344A priority Critical patent/KR101225559B1/ko
Priority to US12/674,138 priority patent/US20110077355A1/en
Priority to EP08827871A priority patent/EP2182010A4/en
Priority to CN2008801037237A priority patent/CN101754982B/zh
Publication of WO2009025334A1 publication Critical patent/WO2009025334A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C1/00—Treatment of rubber latex
    • C08C1/02—Chemical or physical treatment of rubber latex before or during concentration
    • C08C1/065—Increasing the size of dispersed rubber particles
    • C08C1/07—Increasing the size of dispersed rubber particles characterised by the agglomerating agents used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
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    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
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    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
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    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
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    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
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    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2321/00—Characterised by the use of unspecified rubbers
    • C08J2321/02—Latex

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

　ゴム状重合体ラテックス（Ａ）の固形分１００質量部に対して、縮合酸塩（Ｂ）０．１～１０質量部、酸基含有共重合体ラテックス（Ｃ）を固形分で０．１～１０質量部、以上を混合することを特徴とする、肥大化ゴムの製造方法、前記製造方法により得られる肥大化ゴムの存在下で重合することにより得られるグラフト共重合体、前記グラフト共重合体を含む熱可塑性樹脂組成物、及び熱可塑性樹脂組成物を成形してなる成形品。 　酸基含有共重合体ラテックス（Ｃ）：水中にて、酸基含有単量体５～３０質量％および不飽和カルボン酸エステル系単量体９５～７０質量％を含む単量体混合物を重合して得られた酸基含有共重合体のラテックス。
PCT/JP2008/064947 2007-08-21 2008-08-21 肥大化ゴムの製造方法、グラフト共重合体、熱可塑性樹脂組成物および成形品 Ceased WO2009025334A1 (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
KR1020107003344A KR101225559B1 (ko) 2007-08-21 2008-08-21 비대화 고무의 제조 방법, 그라프트 공중합체, 열가소성 수지 조성물 및 성형품
US12/674,138 US20110077355A1 (en) 2007-08-21 2008-08-21 Method Of Producing Enlarged Rubber, Graft Copolymer, Thermoplastic Resin Composition And Molded Article
EP08827871A EP2182010A4 (en) 2007-08-21 2008-08-21 METHOD FOR MANUFACTURING ENHANCED RUBBER, GRAFT COPOLYMER, THERMOPLASTIC RESIN COMPOSITION AND MOLDED ARTICLE
CN2008801037237A CN101754982B (zh) 2007-08-21 2008-08-21 肥大化橡胶的制造方法、接枝共聚物、热塑性树脂组合物以及成型品

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP2007-214714 2007-08-21
JP2007214714A JP2009046602A (ja) 2007-08-21 2007-08-21 肥大化ゴムの製造方法
JP2007-235285 2007-09-11
JP2007235285A JP2009067839A (ja) 2007-09-11 2007-09-11 グラフト共重合体、熱可塑性樹脂組成物および成形品
JP2007262083A JP2009091420A (ja) 2007-10-05 2007-10-05 グラフト共重合体、熱可塑性樹脂組成物および成形品
JP2007-262083 2007-10-05

Publications (1)

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WO2009025334A1 true WO2009025334A1 (ja) 2009-02-26

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US (1) US20110077355A1 (ja)
EP (1) EP2182010A4 (ja)
KR (1) KR101225559B1 (ja)
CN (1) CN101754982B (ja)
WO (1) WO2009025334A1 (ja)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2351791A4 (en) * 2008-11-27 2012-08-22 Umg Abs Ltd RESIN COMPOSITION FOR PLATING AND PLATED RESIN PRODUCT
CN103254365A (zh) * 2013-05-17 2013-08-21 合肥工业大学 一种采用水溶性氧化还原引发剂低温制备asa共聚物胶乳的方法
JP2022138218A (ja) * 2021-03-10 2022-09-26 株式会社カネカ コアシェル型グラフト共重合体粒子、その製造方法、及び樹脂組成物

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US8576184B2 (en) 2010-08-19 2013-11-05 Nokia Corporation Method and apparatus for browsing content files
CN102399403B (zh) * 2011-09-30 2013-03-27 慈溪金岛塑化有限公司 一种abs与asa共聚物合金及其制备方法
TWI455983B (zh) * 2012-12-28 2014-10-11 Chi Mei Corp 橡膠改質甲基丙烯酸酯系樹脂組成物
TWI465509B (zh) * 2012-12-28 2014-12-21 Chi Mei Corp 橡膠改質甲基丙烯酸酯系樹脂組成物
JP7034070B2 (ja) 2015-10-18 2022-03-11 アレジアンス、コーポレイション 水系ヒドロゲルブレンドコーティングおよびエラストマー物品への塗布方法
WO2019164176A1 (ko) 2018-02-26 2019-08-29 (주) 엘지화학 Abs계 그라프트 공중합체의 제조방법 및 열가소성 수지 조성물의 제조방법
KR102282816B1 (ko) 2018-02-26 2021-07-29 주식회사 엘지화학 Abs계 그라프트 공중합체의 제조방법 및 열가소성 수지 조성물의 제조방법
KR102511427B1 (ko) 2019-07-24 2023-03-20 주식회사 엘지화학 아크릴계 공중합체 응집제 및 이를 이용한 그라프트 공중합체의 제조방법
KR102775890B1 (ko) * 2020-09-18 2025-03-06 주식회사 엘지화학 그라프트 공중합체의 제조방법 및 이를 포함하는 열가소성 수지 조성물의 제조방법
KR102888158B1 (ko) * 2021-01-22 2025-11-19 주식회사 엘지화학 열가소성 수지 조성물, 이의 제조방법 및 이를 포함하는 성형품

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