ATE364640T1 - Verfahren zur herstellung von flüssigem poly- alpha-olefin, metallocen dafür und diese enthaltende schmiermittel - Google Patents
Verfahren zur herstellung von flüssigem poly- alpha-olefin, metallocen dafür und diese enthaltende schmiermittelInfo
- Publication number
- ATE364640T1 ATE364640T1 AT01961955T AT01961955T ATE364640T1 AT E364640 T1 ATE364640 T1 AT E364640T1 AT 01961955 T AT01961955 T AT 01961955T AT 01961955 T AT01961955 T AT 01961955T AT E364640 T1 ATE364640 T1 AT E364640T1
- Authority
- AT
- Austria
- Prior art keywords
- low
- metallocene
- olefin
- alpha
- homo
- Prior art date
Links
- 229920013639 polyalphaolefin Polymers 0.000 title abstract 5
- 239000007788 liquid Substances 0.000 title abstract 4
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000000314 lubricant Substances 0.000 title 1
- 229920001577 copolymer Polymers 0.000 abstract 3
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 abstract 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 230000009477 glass transition Effects 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052740 iodine Inorganic materials 0.000 abstract 1
- 239000011630 iodine Substances 0.000 abstract 1
- 239000010687 lubricating oil Substances 0.000 abstract 1
- 239000012968 metallocene catalyst Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000004034 viscosity adjusting agent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M143/00—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
- C10M143/08—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing aliphatic monomer having more than 4 carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/14—Monomers containing five or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/14—Monomers containing five or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/14—Monomers containing five or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/026—Butene
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Lubricants (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/637,791 US6858767B1 (en) | 2000-08-11 | 2000-08-11 | Process for producing liquid polyalphaolefin polymer, metallocene catalyst therefor, the resulting polymer and lubricant containing same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE364640T1 true ATE364640T1 (de) | 2007-07-15 |
Family
ID=24557387
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT01961955T ATE364640T1 (de) | 2000-08-11 | 2001-08-08 | Verfahren zur herstellung von flüssigem poly- alpha-olefin, metallocen dafür und diese enthaltende schmiermittel |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6858767B1 (de) |
| EP (1) | EP1309633B1 (de) |
| JP (2) | JP4074191B2 (de) |
| AT (1) | ATE364640T1 (de) |
| AU (1) | AU2001283177A1 (de) |
| BR (1) | BR0113185B1 (de) |
| CA (1) | CA2416894C (de) |
| DE (1) | DE60128926T2 (de) |
| MX (1) | MXPA03001289A (de) |
| WO (1) | WO2002014384A2 (de) |
Families Citing this family (92)
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|---|---|---|---|---|
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| US6887305B2 (en) | 2002-05-29 | 2005-05-03 | Exxonmobil Chemical Patents Inc. | Release agent and uses for same |
| US6706828B2 (en) | 2002-06-04 | 2004-03-16 | Crompton Corporation | Process for the oligomerization of α-olefins having low unsaturation |
| US8003725B2 (en) | 2002-08-12 | 2011-08-23 | Exxonmobil Chemical Patents Inc. | Plasticized hetero-phase polyolefin blends |
| US7271209B2 (en) | 2002-08-12 | 2007-09-18 | Exxonmobil Chemical Patents Inc. | Fibers and nonwovens from plasticized polyolefin compositions |
| US7998579B2 (en) | 2002-08-12 | 2011-08-16 | Exxonmobil Chemical Patents Inc. | Polypropylene based fibers and nonwovens |
| CN100345896C (zh) | 2002-08-12 | 2007-10-31 | 埃克森美孚化学专利公司 | 增塑聚烯烃组合物 |
| US7531594B2 (en) * | 2002-08-12 | 2009-05-12 | Exxonmobil Chemical Patents Inc. | Articles from plasticized polyolefin compositions |
| US7662885B2 (en) | 2002-08-12 | 2010-02-16 | Exxonmobil Chemical Patents Inc. | Method to make an article comprising polymer concentrate |
| JP4728643B2 (ja) * | 2002-10-02 | 2011-07-20 | ダウ グローバル テクノロジーズ エルエルシー | 液状およびゲル状の低分子量エチレンポリマー類 |
| US8192813B2 (en) | 2003-08-12 | 2012-06-05 | Exxonmobil Chemical Patents, Inc. | Crosslinked polyethylene articles and processes to produce same |
| JP2005200453A (ja) * | 2004-01-13 | 2005-07-28 | Mitsui Chemicals Inc | α−オレフィン(共)重合体の製造方法 |
| JP2005200448A (ja) * | 2004-01-13 | 2005-07-28 | Mitsui Chemicals Inc | 潤滑油添加剤および潤滑油組成物 |
| JP2005200447A (ja) * | 2004-01-13 | 2005-07-28 | Mitsui Chemicals Inc | 潤滑油添加剤および潤滑油組成物 |
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| US7285608B2 (en) | 2004-04-21 | 2007-10-23 | Novolen Technology Holdings C.V. | Metallocene ligands, metallocene compounds and metallocene catalysts, their synthesis and their use for the polymerization of olefins |
| PL1805231T3 (pl) | 2004-10-18 | 2010-08-31 | Basell Poliolefine Italia Srl | (Ko)polimery butenu-1 o niskiej izotaktyczności |
| JP5027665B2 (ja) * | 2004-10-21 | 2012-09-19 | バーゼル・ポリオレフィン・ゲーエムベーハー | 1−ブテンポリマー及びこの調製方法 |
| EP1802669B1 (de) * | 2004-10-21 | 2011-03-09 | Basell Polyolefine GmbH | 1-buten-polymer und herstellungsverfahren dafür |
| GB2420348B (en) * | 2004-10-28 | 2009-11-18 | Exxonmobil Chem Patents Inc | Syndiotactic rich polyolefins |
| US8389615B2 (en) | 2004-12-17 | 2013-03-05 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions comprising vinylaromatic block copolymer, polypropylene, plastomer, and low molecular weight polyolefin |
| US8399390B2 (en) * | 2005-06-29 | 2013-03-19 | Exxonmobil Chemical Patents Inc. | HVI-PAO in industrial lubricant and grease compositions |
| WO2007011530A2 (en) | 2005-07-15 | 2007-01-25 | Exxonmobil Chemical Patents, Inc. | Elastomeric compositions |
| US8748361B2 (en) * | 2005-07-19 | 2014-06-10 | Exxonmobil Chemical Patents Inc. | Polyalpha-olefin compositions and processes to produce the same |
| WO2007011462A1 (en) * | 2005-07-19 | 2007-01-25 | Exxonmobil Chemical Patents Inc. | Lubricants from mixed alpha-olefin feeds |
| CA2615895C (en) * | 2005-07-19 | 2012-10-30 | Exxonmobil Chemical Patents Inc. | Lubricants from mixed alpha-olefin feeds |
| US7989670B2 (en) * | 2005-07-19 | 2011-08-02 | Exxonmobil Chemical Patents Inc. | Process to produce high viscosity fluids |
| US8834705B2 (en) | 2006-06-06 | 2014-09-16 | Exxonmobil Research And Engineering Company | Gear oil compositions |
| US8299007B2 (en) | 2006-06-06 | 2012-10-30 | Exxonmobil Research And Engineering Company | Base stock lubricant blends |
| US8535514B2 (en) * | 2006-06-06 | 2013-09-17 | Exxonmobil Research And Engineering Company | High viscosity metallocene catalyst PAO novel base stock lubricant blends |
| US8501675B2 (en) | 2006-06-06 | 2013-08-06 | Exxonmobil Research And Engineering Company | High viscosity novel base stock lubricant viscosity blends |
| US8921290B2 (en) | 2006-06-06 | 2014-12-30 | Exxonmobil Research And Engineering Company | Gear oil compositions |
| US8188170B2 (en) | 2006-06-20 | 2012-05-29 | Chemtura Corporation | Polymers with low gel content and enhanced gas-fading |
| JP5613416B2 (ja) * | 2006-07-19 | 2014-10-22 | エクソンモービル・ケミカル・パテンツ・インク | 高粘度流体の生成プロセス |
| JP5555490B2 (ja) | 2006-07-19 | 2014-07-23 | エクソンモービル・ケミカル・パテンツ・インク | メタロセン触媒を用いたポリオレフィンの製造方法 |
| US8080699B2 (en) * | 2009-08-28 | 2011-12-20 | Chemtura Corporation | Two-stage process and system for forming high viscosity polyalphaolefins |
| US7601255B2 (en) | 2006-09-06 | 2009-10-13 | Chemtura Corporation | Process for removal of residual catalyst components |
| US8513478B2 (en) * | 2007-08-01 | 2013-08-20 | Exxonmobil Chemical Patents Inc. | Process to produce polyalphaolefins |
| CA2693908C (en) * | 2007-08-07 | 2012-05-29 | Exxonmobil Chemical Patents Inc. | Plasticized polyolefin compositions |
| US8227392B2 (en) | 2008-01-25 | 2012-07-24 | Exxonmobil Research And Engineering Company | Base stocks and lubricant blends containing poly-alpha olefins |
| WO2009097069A1 (en) * | 2008-01-31 | 2009-08-06 | Exxonmobil Chemical Patents Inc. | Improved utilization of linear alpha olefins in the production of metallocene catalyzed poly-alpha olefins |
| US7943807B2 (en) * | 2008-02-06 | 2011-05-17 | Chemtura Corporation | Controlling branch level and viscosity of polyalphaolefins with propene addition |
| US8865959B2 (en) * | 2008-03-18 | 2014-10-21 | Exxonmobil Chemical Patents Inc. | Process for synthetic lubricant production |
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| US8394746B2 (en) * | 2008-08-22 | 2013-03-12 | Exxonmobil Research And Engineering Company | Low sulfur and low metal additive formulations for high performance industrial oils |
| JP5319992B2 (ja) * | 2008-09-08 | 2013-10-16 | 三井化学株式会社 | ギヤ油用潤滑油組成物 |
| JP2010077336A (ja) * | 2008-09-29 | 2010-04-08 | Mitsui Chemicals Inc | α−オレフィン(共)重合体の製造方法 |
| US8247358B2 (en) * | 2008-10-03 | 2012-08-21 | Exxonmobil Research And Engineering Company | HVI-PAO bi-modal lubricant compositions |
| US8114946B2 (en) * | 2008-12-18 | 2012-02-14 | Chevron Phillips Chemical Company Lp | Process for producing broader molecular weight distribution polymers with a reverse comonomer distribution and low levels of long chain branches |
| US8389625B2 (en) | 2008-12-23 | 2013-03-05 | Exxonmobil Research And Engineering Company | Production of synthetic hydrocarbon fluids, plasticizers and synthetic lubricant base stocks from renewable feedstocks |
| CN103555403A (zh) * | 2009-01-23 | 2014-02-05 | 出光兴产株式会社 | 齿轮用润滑油 |
| CN102388072A (zh) * | 2009-04-10 | 2012-03-21 | 出光兴产株式会社 | α烯烃低聚物及其制造方法 |
| KR101753549B1 (ko) | 2009-06-16 | 2017-07-03 | 셰브론 필립스 케미컬 컴퍼니 엘피 | 메탈로센-ssa 촉매시스템을 이용한 알파 올레핀 올리고머화 및 윤활제 블렌드 제조를 위한 생성된 폴리알파올레핀의 용도 |
| US8969636B2 (en) * | 2009-07-29 | 2015-03-03 | The United States Of America As Represented By The Secretary Of The Navy | Homogeneous metallocene ziegler-natta catalysts for the oligomerization of olefins in aliphatic-hydrocarbon solvents |
| US8067652B2 (en) * | 2009-08-13 | 2011-11-29 | Chemtura Corporation | Processes for controlling the viscosity of polyalphaolefins |
| US8716201B2 (en) * | 2009-10-02 | 2014-05-06 | Exxonmobil Research And Engineering Company | Alkylated naphtylene base stock lubricant formulations |
| US20110082323A1 (en) * | 2009-10-06 | 2011-04-07 | Chevron Phillips Chemical Company Lp | Oligomerization of olefin waxes using metallocene-based catalyst systems |
| CN102666806B (zh) * | 2009-12-24 | 2015-09-16 | 埃克森美孚化学专利公司 | 用于生产新型合成基础油料的方法 |
| US8642523B2 (en) * | 2010-02-01 | 2014-02-04 | Exxonmobil Research And Engineering Company | Method for improving the fuel efficiency of engine oil compositions for large low and medium speed engines by reducing the traction coefficient |
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| US8598103B2 (en) * | 2010-02-01 | 2013-12-03 | Exxonmobil Research And Engineering Company | Method for improving the fuel efficiency of engine oil compositions for large low, medium and high speed engines by reducing the traction coefficient |
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| US8748362B2 (en) * | 2010-02-01 | 2014-06-10 | Exxonmobile Research And Engineering Company | Method for improving the fuel efficiency of engine oil compositions for large low and medium speed gas engines by reducing the traction coefficient |
| EP2609125B1 (de) | 2010-08-25 | 2019-12-04 | ExxonMobil Chemical Patents Inc. | Funktionalisierbare synthetische kohlenwasserstoffflüssigkeiten und integriertes herstellungsverfahren dafür |
| US9815915B2 (en) * | 2010-09-03 | 2017-11-14 | Exxonmobil Chemical Patents Inc. | Production of liquid polyolefins |
| US20120165580A1 (en) * | 2010-09-03 | 2012-06-28 | Bahler Kenneth A | Process For Production of Polyolefins |
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| US20140323665A1 (en) | 2011-03-30 | 2014-10-30 | Exxonmobil Chemical Patents Inc. | Polyalphaolefins by Oligomerization and Isomerization |
| EP2735574A1 (de) * | 2011-05-19 | 2014-05-28 | Idemitsu Kosan Co., Ltd | 1-octen-, 1-decen- und ternäres 1-dodecen-copolymer und schmiermittelzusammensetzung damit |
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| ES2524905T3 (es) * | 2012-11-28 | 2014-12-15 | Saudi Basic Industries Corporation | Proceso para la oligomerización de etileno |
| US20140274849A1 (en) * | 2013-03-14 | 2014-09-18 | Exxonmobil Research And Engineering Company | Lubricating composition providing high wear resistance |
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| WO2015181280A1 (en) * | 2014-05-30 | 2015-12-03 | Total Research & Technology Feluy | Use of a metallocene catalyst to produce a polyalpha-olefin |
| FR3021664B1 (fr) | 2014-05-30 | 2020-12-04 | Total Marketing Services | Polyolefines lubrifiantes de basse viscosite |
| EP3192856B1 (de) | 2014-09-10 | 2020-12-23 | Mitsui Chemicals, Inc. | Schmiermittelzusammensetzung |
| US9732300B2 (en) | 2015-07-23 | 2017-08-15 | Chevron Phillipa Chemical Company LP | Liquid propylene oligomers and methods of making same |
| US10731096B2 (en) | 2015-08-21 | 2020-08-04 | Exxonmobil Chemical Patents Inc. | Lubricant base stock blends |
| US10059898B2 (en) | 2015-08-21 | 2018-08-28 | Exxonmobil Chemical Patents Inc. | High-viscosity metallocene polyalpha-olefins with high electrohydrodynamic performance |
| US10611980B2 (en) | 2015-10-15 | 2020-04-07 | Exxonmobil Chemical Patents Inc. | Lubricant containing high-viscosity metallocene polyalpha-olefins |
| US10351488B2 (en) | 2016-08-02 | 2019-07-16 | Exxonmobil Chemical Patents Inc. | Unsaturated polyalpha-olefin materials |
| CN109844017B (zh) | 2016-09-06 | 2022-02-08 | 道达尔研究技术弗吕公司 | 包括由茂金属催化的高粘度聚-α-烯烃添加剂的改进的单乙烯基芳族聚合物组合物 |
| DE102016220263A1 (de) | 2016-10-17 | 2018-04-19 | Clariant Plastics & Coatings Ltd | Haftklebstoffe |
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| EP3569678B1 (de) | 2017-01-16 | 2023-10-18 | Mitsui Chemicals, Inc. | Schmierölzusammensetzung für kraftfahrzeuggetriebe |
| WO2019173427A1 (en) | 2018-03-06 | 2019-09-12 | Valvoline Licensing And Intellectual Property Llc | Traction fluid composition |
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-
2000
- 2000-08-11 US US09/637,791 patent/US6858767B1/en not_active Expired - Lifetime
-
2001
- 2001-08-08 DE DE60128926T patent/DE60128926T2/de not_active Expired - Lifetime
- 2001-08-08 CA CA2416894A patent/CA2416894C/en not_active Expired - Fee Related
- 2001-08-08 EP EP01961955A patent/EP1309633B1/de not_active Expired - Lifetime
- 2001-08-08 MX MXPA03001289A patent/MXPA03001289A/es active IP Right Grant
- 2001-08-08 JP JP2002519521A patent/JP4074191B2/ja not_active Expired - Fee Related
- 2001-08-08 WO PCT/US2001/024815 patent/WO2002014384A2/en not_active Ceased
- 2001-08-08 BR BRPI0113185-0A patent/BR0113185B1/pt not_active IP Right Cessation
- 2001-08-08 AU AU2001283177A patent/AU2001283177A1/en not_active Abandoned
- 2001-08-08 AT AT01961955T patent/ATE364640T1/de not_active IP Right Cessation
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2006
- 2006-05-10 JP JP2006131521A patent/JP5420816B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| MXPA03001289A (es) | 2003-06-30 |
| EP1309633B1 (de) | 2007-06-13 |
| AU2001283177A1 (en) | 2002-02-25 |
| DE60128926T2 (de) | 2008-02-14 |
| JP4074191B2 (ja) | 2008-04-09 |
| JP5420816B2 (ja) | 2014-02-19 |
| EP1309633A2 (de) | 2003-05-14 |
| JP2004506758A (ja) | 2004-03-04 |
| CA2416894A1 (en) | 2002-02-21 |
| US6858767B1 (en) | 2005-02-22 |
| WO2002014384A2 (en) | 2002-02-21 |
| BR0113185A (pt) | 2003-09-16 |
| CA2416894C (en) | 2010-05-25 |
| BR0113185B1 (pt) | 2011-05-03 |
| WO2002014384A3 (en) | 2002-05-23 |
| JP2006206925A (ja) | 2006-08-10 |
| DE60128926D1 (de) | 2007-07-26 |
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