BRPI0606159A2 - hidrogenação de glicerol em fase vapor - Google Patents
hidrogenação de glicerol em fase vaporInfo
- Publication number
- BRPI0606159A2 BRPI0606159A2 BRPI0606159-1A BRPI0606159A BRPI0606159A2 BR PI0606159 A2 BRPI0606159 A2 BR PI0606159A2 BR PI0606159 A BRPI0606159 A BR PI0606159A BR PI0606159 A2 BRPI0606159 A2 BR PI0606159A2
- Authority
- BR
- Brazil
- Prior art keywords
- hydrogenation
- vapor phase
- glycerol
- phase glycerol
- glycerol hydrogenation
- Prior art date
Links
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 title abstract 15
- 238000005984 hydrogenation reaction Methods 0.000 title abstract 4
- 239000012808 vapor phase Substances 0.000 title abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 238000004326 stimulated echo acquisition mode for imaging Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/02—Monohydroxylic acyclic alcohols
- C07C31/10—Monohydroxylic acyclic alcohols containing three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/18—Polyhydroxylic acyclic alcohols
- C07C31/20—Dihydroxylic alcohols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
HIDROGENAçãO DE GLICEROL EM FASE VAPOR. Processo para a hidrogenação de glicerol, no qual uma alimentação compreendendo glicerol é colocada em contato com um jato de gás contendo hidrogênio e submetida à hidrogenação na fase de vapor na presença de um catalisador numa temperatura de cerca de 160°C até cerca de 260°C, uma pressão de cerca de 10 até cerca de 30 bar, uma proporção de hidrogênio para glicerol de 400:1 até cerca de 600:1 e um tempo de residência de cerca de 0,01 até cerca de 2,5 segundos.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0514593.3 | 2005-07-15 | ||
| GBGB0514593.3A GB0514593D0 (en) | 2005-07-15 | 2005-07-15 | Process |
| PCT/GB2006/050181 WO2007010299A1 (en) | 2005-07-15 | 2006-06-30 | Process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0606159A2 true BRPI0606159A2 (pt) | 2009-06-13 |
| BRPI0606159B1 BRPI0606159B1 (pt) | 2015-08-11 |
Family
ID=34897311
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0606159-1A BRPI0606159B1 (pt) | 2005-07-15 | 2006-06-30 | Hidrogenação de glicerol em fase vapor |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US7355083B2 (pt) |
| EP (1) | EP1836147B1 (pt) |
| JP (1) | JP5149796B2 (pt) |
| KR (1) | KR101325084B1 (pt) |
| CN (1) | CN101006036B (pt) |
| AR (1) | AR058013A1 (pt) |
| AU (1) | AU2006252177B2 (pt) |
| BR (1) | BRPI0606159B1 (pt) |
| CA (1) | CA2569622C (pt) |
| DK (1) | DK1836147T3 (pt) |
| EA (1) | EA010314B1 (pt) |
| ES (1) | ES2298101T3 (pt) |
| GB (1) | GB0514593D0 (pt) |
| MY (1) | MY142306A (pt) |
| NZ (1) | NZ551994A (pt) |
| PL (1) | PL1836147T3 (pt) |
| TW (1) | TWI394740B (pt) |
| WO (1) | WO2007010299A1 (pt) |
| ZA (1) | ZA200700897B (pt) |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5377975B2 (ja) * | 2005-12-21 | 2013-12-25 | ヴァイレント エナジー システムズ インク. | 触媒、および含酸素化合物の製造方法 |
| EP2565176B1 (en) | 2006-05-08 | 2015-08-19 | Virent, Inc. | Methods for generating polyols |
| US7619119B2 (en) | 2006-06-07 | 2009-11-17 | The Procter & Gamble Company | Processes for converting glycerol to amino alcohols |
| US7619118B2 (en) | 2006-06-07 | 2009-11-17 | The Procter & Gamble Company | Process for the conversion of glycerol to propylene glycol and amino alcohols |
| GB0614823D0 (en) | 2006-07-26 | 2006-09-06 | Davy Process Techn Ltd | Process |
| DE102006050751A1 (de) | 2006-10-27 | 2008-05-08 | Clariant International Limited | Verfahren zur Herstellung von 1,2-Propandiol durch Hydrogenolyse von Glycerin |
| AU2007353527B2 (en) * | 2006-12-20 | 2012-12-20 | Virent, Inc. | Reactor system for producing gaseous products |
| DE102007003188B3 (de) | 2007-01-22 | 2008-06-05 | Clariant International Ltd. | Verfahren zur Herstellung von 1,2-Propandiol durch Hydrogenolyse von Glycerin |
| US8053615B2 (en) * | 2007-03-08 | 2011-11-08 | Virent Energy Systems, Inc. | Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons |
| BRPI0701993A2 (pt) * | 2007-03-30 | 2008-11-18 | Petroleo Brasileiro Sa | mÉtodo para reciclagem e aproveitamento da glicerina obtida da produÇço do biodiesel |
| JP5302543B2 (ja) * | 2008-01-21 | 2013-10-02 | 花王株式会社 | 多価アルコールの水素化分解物の製造方法 |
| EP2138478B1 (en) | 2007-04-17 | 2019-07-24 | Kao Corporation | Process for producing hydrogenolysis products of polyhydric alcohols |
| US8507736B2 (en) * | 2007-05-18 | 2013-08-13 | Biofuel-Solution I Malmo Ab | Gas phase process for monoalcohol production from glycerol |
| KR100870369B1 (ko) | 2007-08-29 | 2008-11-25 | 지에스칼텍스 주식회사 | 프로판디올 제조용 촉매의 제조 방법 및 이를 이용한프로판디올의 제조 방법 |
| CN101848884B (zh) * | 2007-08-31 | 2013-05-01 | 巴斯夫欧洲公司 | 通过在至少三个连续的反应器中将甘油氢化制备1,2-丙二醇的方法 |
| PL2200958T3 (pl) * | 2007-08-31 | 2016-04-29 | Basf Se | Sposób wytwarzania 1,2-propanodiolu drogą uwodorniania glicerolu w dwustopniowej kaskadzie reaktorów |
| WO2009027502A2 (de) * | 2007-08-31 | 2009-03-05 | Basf Se | Verfahren zur herstellung von 1,2-propandiol durch niederdruck-hydrierung von glycerin |
| WO2009057584A1 (ja) | 2007-10-31 | 2009-05-07 | Mitsui Chemicals, Inc. | プロピレングリコールの製造方法 |
| GB0724232D0 (en) * | 2007-12-12 | 2008-01-23 | Davy Process Techn Ltd | Process |
| CN101456791B (zh) | 2007-12-13 | 2012-07-04 | 中国科学院兰州化学物理研究所 | 利用生物基甘油生产1,2-丙二醇的方法 |
| JP5305669B2 (ja) * | 2008-01-21 | 2013-10-02 | 花王株式会社 | 多価アルコールの水素化分解物の製造方法 |
| JP5612806B2 (ja) * | 2008-01-30 | 2014-10-22 | 花王株式会社 | 多価アルコールの水素化分解物の製造方法 |
| AR072446A1 (es) * | 2008-03-02 | 2010-09-01 | Dow Global Technologies Inc | Proceso de hidrogenacion mejorado |
| US20090246430A1 (en) | 2008-03-28 | 2009-10-01 | The Coca-Cola Company | Bio-based polyethylene terephthalate polymer and method of making same |
| MY150295A (en) * | 2008-04-30 | 2013-12-31 | Mitsui Chemicals Inc | Method of producing propylene glycol |
| DE102008027601A1 (de) | 2008-06-10 | 2009-12-17 | Clariant International Limited | Verfahren zur Herstellung von 1,2-Propandiol durch Hydrogenolyse von Glycerin |
| BRPI0803898A2 (pt) * | 2008-07-30 | 2010-11-09 | Univ Rio De Janeiro | processo catalìtico para a transformação de glicerina em insumos para o setor petroquìmico |
| WO2010016462A1 (ja) * | 2008-08-04 | 2010-02-11 | チッソ株式会社 | グリセリンからのグリコール及び1-プロパノールの製造方法 |
| EP2331486A2 (en) * | 2008-08-27 | 2011-06-15 | Virent Energy Systems Inc. | Synthesis of liquid fuels from biomass |
| US8071820B2 (en) * | 2008-12-23 | 2011-12-06 | Uop Llc | Method for converting glycerol to propanol |
| KR101050058B1 (ko) * | 2008-12-31 | 2011-07-19 | 서울대학교산학협력단 | 프로판디올 제조용 촉매의 제조 방법 및 그를 이용한 프로판디올의 제조 방법 |
| US20100189790A1 (en) | 2009-01-23 | 2010-07-29 | Teva Pharmaceutical Industries, Ltd. | Delayed release rasagiline formulation |
| SG173818A1 (en) | 2009-02-25 | 2011-09-29 | Grace W R & Co | Process for making 1, 2-propane diol from hydrogenation of glycerol |
| EP2403894B1 (en) | 2009-03-03 | 2016-06-01 | The Coca-Cola Company | Bio-based polyethylene terephthalate packaging and method of making thereof |
| WO2010150278A2 (en) | 2009-06-15 | 2010-12-29 | Ganapati Dadasaheb Yadav; | Hydrogenolysis of polyhydroxy alcohols using metal incorporated manganese oxide octahedral molecular sieve as a catalyst |
| KR20120098584A (ko) * | 2009-06-30 | 2012-09-05 | 바이렌트, 아이엔씨. | 당분 및 당알코올을 변환하기 위한 공정 및 반응기 시스템 |
| WO2011009936A2 (en) | 2009-07-24 | 2011-01-27 | Basf Se | Process for the preparation of 1,2-propanediol from glycerol |
| BRPI1000430A2 (pt) | 2010-02-24 | 2011-10-25 | Petroleo Brasileiro Sa | produção de propilenoglicol a partir de glicerina |
| DE102010015006A1 (de) | 2010-04-14 | 2011-11-24 | Tu Darmstadt | Katalysator zur Hydrierung von wässrigen mehrwertigen Alkohollösungen |
| CN103687835B (zh) * | 2011-03-10 | 2015-11-25 | Gtc科技美国有限责任公司 | 用于将甘油转化为丙二醇的方法 |
| CN102924233B (zh) * | 2012-10-20 | 2015-04-15 | 青岛科技大学 | 一种甘油氢解制备丙二醇的方法 |
| AR095195A1 (es) | 2013-03-15 | 2015-09-30 | W R Grace & Co -Conn | Proceso para la producción selectiva de propanoles por hidrogenación de glicerol |
| CN107673952A (zh) * | 2017-09-26 | 2018-02-09 | 龙岩卓越生物基材料有限公司 | 利用生物甘油制备1,2‑丙二醇及正丙醇的方法 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE524101C (de) * | 1926-01-13 | 1931-05-11 | I G Farbenindustrie Akt Ges | Verfahren zur UEberfuehrung von hoeherwertigen Alkoholen in niedrigerwertige |
| BR8204165A (pt) | 1981-07-22 | 1983-07-12 | Du Pont | Processo para hidrogenolise de pentitois e misturas de pentitois com outros glicois hexitois e misturas de hexitois com outros poliois e poliois para etileno glicol |
| US4642394A (en) | 1985-07-16 | 1987-02-10 | Celanese Corporation | Production of propanediols |
| GB8917862D0 (en) * | 1989-08-04 | 1989-09-20 | Davy Mckee London | Process |
| EP0510238A1 (en) | 1991-04-26 | 1992-10-28 | NOVAMONT S.p.A. | Process for producing lower poliols and mixtures thereof |
| IT1249956B (it) | 1991-07-10 | 1995-03-30 | Menon S R L | Procedimento di idrogenazione catalitica della glicerina |
| IT1249955B (it) | 1991-07-10 | 1995-03-30 | Menon S R L | Procedimento di idrogenazione della glicerina |
| IT1256802B (it) | 1992-01-31 | 1995-12-15 | Novamont Spa | Catalizzatore di idrogenazione, procedimento per la sua preparazione ed impiego, particolarmente per l'drogenazione e/o idrogenolisi di carboidrati e polioli. |
| DE4238492C2 (de) | 1992-11-14 | 1995-06-14 | Degussa | Verfahren zur Herstellung von 1,2- und 1,3-Propandiol |
| DE4302464A1 (de) * | 1993-01-29 | 1994-08-04 | Henkel Kgaa | Herstellung von 1,2-Propandiol aus Glycerin |
| DE4442124A1 (de) | 1994-11-26 | 1996-05-30 | Basf Ag | Verfahren zur Herstellung von Propandiol-1,2 |
| WO1997000841A1 (en) | 1995-06-20 | 1997-01-09 | Kao Corporation | Method for producing alcohol |
| TW476746B (en) | 1997-07-23 | 2002-02-21 | Shell Int Research | Hydrogenolysis of glycerol |
| US6291725B1 (en) | 2000-03-03 | 2001-09-18 | Board Of Trustees Operating Michigan State University | Catalysts and process for hydrogenolysis of sugar alcohols to polyols |
| DE60101743T2 (de) | 2000-06-20 | 2004-12-09 | E.I. Du Pont De Nemours And Co., Wilmington | Katalytische dehydroxylation von diolen und polyolen |
| US6841085B2 (en) | 2001-10-23 | 2005-01-11 | Battelle Memorial Institute | Hydrogenolysis of 6-carbon sugars and other organic compounds |
| JP2003261550A (ja) | 2002-03-06 | 2003-09-19 | Sumitomo Chem Co Ltd | プロピレンオキサイド及びプロピルアルコールの製造方法 |
| ES2501391T3 (es) | 2004-03-25 | 2014-10-01 | Galen J. Suppes | Procedimiento para producir una composición anticongelante que contiene alcoholes inferiores y glicerol a través de alcohólisis de un glicérido |
-
2005
- 2005-07-15 GB GBGB0514593.3A patent/GB0514593D0/en not_active Ceased
-
2006
- 2006-06-30 EP EP06744361A patent/EP1836147B1/en not_active Not-in-force
- 2006-06-30 BR BRPI0606159-1A patent/BRPI0606159B1/pt not_active IP Right Cessation
- 2006-06-30 AU AU2006252177A patent/AU2006252177B2/en not_active Ceased
- 2006-06-30 ZA ZA200700897A patent/ZA200700897B/en unknown
- 2006-06-30 DK DK06744361.4T patent/DK1836147T3/da active
- 2006-06-30 JP JP2008520964A patent/JP5149796B2/ja not_active Expired - Fee Related
- 2006-06-30 WO PCT/GB2006/050181 patent/WO2007010299A1/en not_active Ceased
- 2006-06-30 EA EA200700445A patent/EA010314B1/ru not_active IP Right Cessation
- 2006-06-30 KR KR1020077000311A patent/KR101325084B1/ko not_active Expired - Fee Related
- 2006-06-30 NZ NZ551994A patent/NZ551994A/en not_active IP Right Cessation
- 2006-06-30 CA CA2569622A patent/CA2569622C/en not_active Expired - Fee Related
- 2006-06-30 CN CN2006800006177A patent/CN101006036B/zh not_active Expired - Fee Related
- 2006-06-30 PL PL06744361T patent/PL1836147T3/pl unknown
- 2006-06-30 ES ES06744361T patent/ES2298101T3/es active Active
- 2006-07-07 MY MYPI20063248A patent/MY142306A/en unknown
- 2006-07-13 AR ARP060103005A patent/AR058013A1/es not_active Application Discontinuation
- 2006-07-14 TW TW095125853A patent/TWI394740B/zh not_active IP Right Cessation
-
2007
- 2007-01-30 US US11/668,884 patent/US7355083B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| TWI394740B (zh) | 2013-05-01 |
| KR20080025357A (ko) | 2008-03-20 |
| ES2298101T1 (es) | 2008-05-16 |
| CN101006036A (zh) | 2007-07-25 |
| PL1836147T3 (pl) | 2013-06-28 |
| AU2006252177A2 (en) | 2008-08-07 |
| ZA200700897B (en) | 2008-07-30 |
| MY142306A (en) | 2010-11-15 |
| AR058013A1 (es) | 2008-01-23 |
| CA2569622A1 (en) | 2007-01-15 |
| CA2569622C (en) | 2013-08-27 |
| EP1836147A1 (en) | 2007-09-26 |
| EA010314B1 (ru) | 2008-08-29 |
| TW200708500A (en) | 2007-03-01 |
| EA200700445A1 (ru) | 2007-06-29 |
| GB0514593D0 (en) | 2005-08-24 |
| DK1836147T3 (da) | 2013-04-22 |
| JP2009501203A (ja) | 2009-01-15 |
| JP5149796B2 (ja) | 2013-02-20 |
| ES2298101T3 (es) | 2013-04-17 |
| US20070149830A1 (en) | 2007-06-28 |
| AU2006252177A1 (en) | 2007-02-01 |
| WO2007010299A1 (en) | 2007-01-25 |
| BRPI0606159B1 (pt) | 2015-08-11 |
| EP1836147B1 (en) | 2013-02-20 |
| CN101006036B (zh) | 2011-09-07 |
| US7355083B2 (en) | 2008-04-08 |
| KR101325084B1 (ko) | 2013-11-06 |
| AU2006252177B2 (en) | 2011-06-23 |
| NZ551994A (en) | 2010-05-28 |
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Legal Events
| Date | Code | Title | Description |
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| B06G | Technical and formal requirements: other requirements [chapter 6.7 patent gazette] |
Free format text: SOLICITA-SE A REGULARIZACAO DA PROCURACAO, UMA VEZ QUE BASEADO NO ARTIGO 216 1O DA LPI, O DOCUMENTO DE PROCURACAO DEVE SER APRESENTADO EM SUA FORMA AUTENTICADA; OU SEGUNDO PARECER DA PROCURADORIA NO 074/93, DEVE CONSTAR UMA DECLARACAO DE VERACIDADE, A QUAL DEVE SER ASSINADA POR UMA PESSOA DEVIDAMENTE AUTORIZADA A REPRESENTAR O INTERESSADO, DEVENDO A MESMA CONSTAR NO INSTRUMENTO DE PROCURACAO, OU NO SEU SUBSTABELECIMENTO. |
|
| B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 30/06/2006, OBSERVADAS AS CONDICOES LEGAIS. |
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| B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time | ||
| B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |