ES2289972T1 - Placa de impresion litografica fotosensible positiva. - Google Patents
Placa de impresion litografica fotosensible positiva. Download PDFInfo
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- ES2289972T1 ES2289972T1 ES05024849T ES05024849T ES2289972T1 ES 2289972 T1 ES2289972 T1 ES 2289972T1 ES 05024849 T ES05024849 T ES 05024849T ES 05024849 T ES05024849 T ES 05024849T ES 2289972 T1 ES2289972 T1 ES 2289972T1
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- light
- resin
- printing plate
- dye
- Prior art date
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- 239000000203 mixture Substances 0.000 claims abstract 19
- 229920005989 resin Polymers 0.000 claims abstract 12
- 239000011347 resin Substances 0.000 claims abstract 12
- 239000003513 alkali Substances 0.000 claims abstract 11
- -1 quinolinium compound Chemical class 0.000 claims abstract 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract 6
- 229920003986 novolac Polymers 0.000 claims abstract 6
- 229920001665 Poly-4-vinylphenol Polymers 0.000 claims abstract 3
- 229920001577 copolymer Polymers 0.000 claims abstract 3
- 229920003987 resole Polymers 0.000 claims abstract 3
- 150000003839 salts Chemical class 0.000 claims abstract 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 10
- 125000001424 substituent group Chemical group 0.000 claims 7
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 claims 4
- 229920001342 Bakelite® Polymers 0.000 claims 4
- 239000004637 bakelite Substances 0.000 claims 4
- 229930003836 cresol Natural products 0.000 claims 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims 3
- 150000001875 compounds Chemical class 0.000 claims 3
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 claims 2
- NKTOLZVEWDHZMU-UHFFFAOYSA-N 2,5-xylenol Chemical compound CC1=CC=C(C)C(O)=C1 NKTOLZVEWDHZMU-UHFFFAOYSA-N 0.000 claims 2
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 claims 2
- TUAMRELNJMMDMT-UHFFFAOYSA-N 3,5-xylenol Chemical compound CC1=CC(C)=CC(O)=C1 TUAMRELNJMMDMT-UHFFFAOYSA-N 0.000 claims 2
- HMNKTRSOROOSPP-UHFFFAOYSA-N 3-Ethylphenol Chemical compound CCC1=CC=CC(O)=C1 HMNKTRSOROOSPP-UHFFFAOYSA-N 0.000 claims 2
- HXDOZKJGKXYMEW-UHFFFAOYSA-N 4-ethylphenol Chemical compound CCC1=CC=C(O)C=C1 HXDOZKJGKXYMEW-UHFFFAOYSA-N 0.000 claims 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical class OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 239000003086 colorant Substances 0.000 claims 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 claims 2
- 125000005843 halogen group Chemical group 0.000 claims 2
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 claims 2
- QWVGKYWNOKOFNN-UHFFFAOYSA-N o-cresol Chemical compound CC1=CC=CC=C1O QWVGKYWNOKOFNN-UHFFFAOYSA-N 0.000 claims 2
- GJYCVCVHRSWLNY-UHFFFAOYSA-N ortho-butylphenol Natural products CCCCC1=CC=CC=C1O GJYCVCVHRSWLNY-UHFFFAOYSA-N 0.000 claims 2
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 claims 2
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 claims 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims 2
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims 1
- QAQSNXHKHKONNS-UHFFFAOYSA-N 1-ethyl-2-hydroxy-4-methyl-6-oxopyridine-3-carboxamide Chemical compound CCN1C(O)=C(C(N)=O)C(C)=CC1=O QAQSNXHKHKONNS-UHFFFAOYSA-N 0.000 claims 1
- QTQLUUDYDWDXNA-UHFFFAOYSA-N 1-ethyl-4-(1-ethylpyridin-1-ium-4-yl)pyridin-1-ium Chemical compound C1=C[N+](CC)=CC=C1C1=CC=[N+](CC)C=C1 QTQLUUDYDWDXNA-UHFFFAOYSA-N 0.000 claims 1
- LCNWZISUNVZUOV-UHFFFAOYSA-N 1-ethyl-4-methylquinolin-1-ium Chemical compound C1=CC=C2[N+](CC)=CC=C(C)C2=C1 LCNWZISUNVZUOV-UHFFFAOYSA-N 0.000 claims 1
- IXQGCWUGDFDQMF-UHFFFAOYSA-N 2-Ethylphenol Chemical compound CCC1=CC=CC=C1O IXQGCWUGDFDQMF-UHFFFAOYSA-N 0.000 claims 1
- LCHYEKKJCUJAKN-UHFFFAOYSA-N 2-propylphenol Chemical compound CCCC1=CC=CC=C1O LCHYEKKJCUJAKN-UHFFFAOYSA-N 0.000 claims 1
- WJQOZHYUIDYNHM-UHFFFAOYSA-N 2-tert-Butylphenol Chemical compound CC(C)(C)C1=CC=CC=C1O WJQOZHYUIDYNHM-UHFFFAOYSA-N 0.000 claims 1
- OGRZMXBJGTZUGN-UHFFFAOYSA-N 3-ethyl-2-methyl-1,3-benzothiazol-3-ium Chemical compound C1=CC=C2[N+](CC)=C(C)SC2=C1 OGRZMXBJGTZUGN-UHFFFAOYSA-N 0.000 claims 1
- 229930185605 Bisphenol Natural products 0.000 claims 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims 1
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 150000001299 aldehydes Chemical class 0.000 claims 1
- 125000003545 alkoxy group Chemical group 0.000 claims 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims 1
- 125000004429 atom Chemical group 0.000 claims 1
- 229950011260 betanaphthol Drugs 0.000 claims 1
- 229940106691 bisphenol a Drugs 0.000 claims 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 1
- 229960002798 cetrimide Drugs 0.000 claims 1
- 238000004040 coloring Methods 0.000 claims 1
- 125000000623 heterocyclic group Chemical group 0.000 claims 1
- SMWDFEZZVXVKRB-UHFFFAOYSA-O hydron;quinoline Chemical compound [NH+]1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-O 0.000 claims 1
- 150000002576 ketones Chemical class 0.000 claims 1
- 150000002605 large molecules Chemical class 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
- 229940079877 pyrogallol Drugs 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 125000000542 sulfonic acid group Chemical group 0.000 claims 1
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 claims 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41C—PROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
- B41C1/00—Forme preparation
- B41C1/10—Forme preparation for lithographic printing; Master sheets for transferring a lithographic image to the forme
- B41C1/1008—Forme preparation for lithographic printing; Master sheets for transferring a lithographic image to the forme by removal or destruction of lithographic material on the lithographic support, e.g. by laser or spark ablation; by the use of materials rendered soluble or insoluble by heat exposure, e.g. by heat produced from a light to heat transforming system; by on-the-press exposure or on-the-press development, e.g. by the fountain of photolithographic materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N1/00—Printing plates or foils; Materials therefor
- B41N1/04—Printing plates or foils; Materials therefor metallic
- B41N1/08—Printing plates or foils; Materials therefor metallic for lithographic printing
- B41N1/083—Printing plates or foils; Materials therefor metallic for lithographic printing made of aluminium or aluminium alloys or having such surface layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41C—PROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
- B41C2210/00—Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation
- B41C2210/02—Positive working, i.e. the exposed (imaged) areas are removed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41C—PROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
- B41C2210/00—Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation
- B41C2210/06—Developable by an alkaline solution
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41C—PROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
- B41C2210/00—Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation
- B41C2210/22—Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation characterised by organic non-macromolecular additives, e.g. dyes, UV-absorbers, plasticisers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41C—PROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
- B41C2210/00—Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation
- B41C2210/24—Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation characterised by a macromolecular compound or binder obtained by reactions involving carbon-to-carbon unsaturated bonds, e.g. acrylics, vinyl polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41C—PROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
- B41C2210/00—Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation
- B41C2210/26—Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation characterised by a macromolecular compound or binder obtained by reactions not involving carbon-to-carbon unsaturated bonds
- B41C2210/262—Phenolic condensation polymers, e.g. novolacs, resols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/46—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography characterised by the light-to-heat converting means; characterised by the heat or radiation filtering or absorbing means or layers
- B41M5/465—Infrared radiation-absorbing materials, e.g. dyes, metals, silicates, C black
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/1053—Imaging affecting physical property or radiation sensitive material, or producing nonplanar or printing surface - process, composition, or product: radiation sensitive composition or product or process of making binder containing
- Y10S430/1055—Radiation sensitive composition or product or process of making
- Y10S430/106—Binder containing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/1053—Imaging affecting physical property or radiation sensitive material, or producing nonplanar or printing surface - process, composition, or product: radiation sensitive composition or product or process of making binder containing
- Y10S430/1055—Radiation sensitive composition or product or process of making
- Y10S430/127—Spectral sensitizer containing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/145—Infrared
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Thermal Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Photosensitive Polymer And Photoresist Processing (AREA)
- Materials For Photolithography (AREA)
- Exposure And Positioning Against Photoresist Photosensitive Materials (AREA)
- Manufacture Or Reproduction Of Printing Formes (AREA)
- Printing Plates And Materials Therefor (AREA)
Abstract
Una placa de impresión litográfica fotosensible positiva que puede hacerse funcionar bajo luz blanca que contiene luz ultravioleta, comprendiendo dicha placa de impresión sobre un soporte una composición fotosensible positiva que muestra, tras exposición por escaneado a la luz en el intervalo de longitud de onda de 650 a 1100 nm, una diferencia en solubilidad en un revelador de álcali entre una porción expuesta y una porción no expuesta, caracterizada porque dicha composición comprende: (i) un colorante que absorbe dicha luz, (ii) una resina soluble en álcali que es una resina novolaca, una resina resol, una resina polivinilfenol o un copolímero de un derivado de ácido acrílico, y (iii) un agente que suprime solubilidad que es capaz de rebajar la disolución en un revelador alcalino de una mezcla que comprende el colorante y la resina soluble en álcali, con la condición de que la composición no comprenda una sal de onio y el agente que suprime solubilidad no se selecciona entre elgrupo constituido por un compuesto de quinolinio, un compuesto de benzotiazolio, un compuesto de piridinio y un compuesto de imidazolina.
Claims (4)
1. Una placa de impresión litográfica
fotosensible positiva que puede hacerse funcionar bajo luz blanca
que contiene luz ultravioleta, comprendiendo dicha placa de
impresión sobre un soporte una composición fotosensible positiva que
muestra, tras exposición por escaneado a la luz en el intervalo de
longitud de onda de 650 a 1100 nm, una diferencia en solubilidad en
un revelador de álcali entre una porción expuesta y una porción no
expuesta, caracterizada porque dicha composición
comprende:
- (i)
- un colorante que absorbe dicha luz,
- (ii)
- una resina soluble en álcali que es una resina novolaca, una resina resol, una resina polivinilfenol o un copolímero de un derivado de ácido acrílico, y
- (iii)
- un agente que suprime solubilidad que es capaz de rebajar la disolución en un revelador alcalino de una mezcla que comprende el colorante y la resina soluble en álcali,
con la condición de que la composición no
comprenda una sal de onio y el agente que suprime solubilidad no se
selecciona entre el grupo constituido por un compuesto de
quinolinio, un compuesto de benzotiazolio, un compuesto de piridinio
y un compuesto de imidazolina.
2. Una placa de impresión litográfica
fotosensible positiva que puede hacerse funcionar bajo luz blanca
que contiene luz ultravioleta, comprendiendo dicha placa de
impresión sobre un soporte una composición fotosensible positiva que
muestra, tras exposición por escaneado a la luz en el intervalo de
longitud de onda de 650 a 1100 nm, una diferencia en solubilidad en
un revelador de álcali entre una porción expuesta y una porción no
expuesta, caracterizada porque dicha composición
comprende:
- (i)
- un colorante que absorbe dicha luz
- (ii)
- una novolaca que es un policondensado catalizado por ácido de al menos un hidrocarburo aromático seleccionado entre el grupo constituido por fenol, m-cresol, o-cresol, p-cresol, 2,5-xilenol, 3,5-xilenol, resorcinol, pirogalol, bisfenol, bisfenol-A, trisfenol, o-etilfenol, m-etilfenol, p-etilfenol, propilfenol, n-butilfenol, t-butilfenol, 1-naftol y 2-naftol, con al menos un aldehído o cetona; y
- (iii)
- un agente que suprime solubilidad que es capaz de rebajar la disolución en un revelador alcalino de una mezcla que comprende el colorante y la novolaca,
con la condición de que la composición no
comprenda una sal de onio y que la novolaca no es LB6564, una
novolaca de fenol/cresol comercializada por Bakelite.
3. Una placa de impresión litográfica
fotosensible positiva que puede hacerse funcionar bajo luz blanca
que contiene luz ultravioleta, comprendiendo dicha placa de
impresión sobre un soporte una composición fotosensible positiva que
muestra, tras exposición por escaneado a la luz en el intervalo de
longitud de onda de 650 a 1100 nm, una diferencia en solubilidad en
un revelador de álcali entre una porción expuesta y una porción no
expuesta, caracterizada porque dicha composición
comprende
- (i)
- un colorante, que absorbe dicha luz, en una cantidad de 0,1 a 30 por ciento en peso con relación a la composición,
- (ii)
- una resina soluble en álcali que es una resina novolaca, una resina resol, una resina polivinilfenol o un copolímero de un derivado de ácido acrílico, y
- (iii)
- un agente que suprime solubilidad que es capaz de rebajar la disolución en un revelador alcalino de una mezcla que comprende el colorante y la resina soluble en álcali, con la condición de que la composición no es ninguna de las siguientes:
- -
- 86 partes en peso de resina novolaca de fenol/cresol comercializada por Bakelite bajo el nombre LB6564 y
- -
- 10 partes en peso del siguiente compuesto:
- -
- y 4 partes en peso de Colorante B, representado por la siguiente fórmula:
- ó
- -
- 90 partes en peso de una resina novolaca de fenol/cresol comercializada por Bakelite bajo el nombre LB6564 y
- -
- 4 partes en peso de Colorante B, anteriormente definido y
- -
- 6 partes en peso de uno de los siguientes compuestos: bromuro de 1-etil-4-metil-quinolinio, Monazolina C, bromuro de 3-etil-2-[3-etil-2(3H)-benzotiazolilideno)-2-metil-1-propenil]-benzotiazolio, yoduro de 3-etil-2-metil-benzotiazolio, bromuro de cetilpiridinio, dibromuro de etil-viologen o cetrimida;
- ó
- -
- 90 partes en peso de una resina novolaca de fenol/cresol comercializada por Bakelite bajo el nombre LB6564 y
- -
- 10 partes en peso del siguiente colorante:
4. Una placa de impresión litográfica
fotosensible positiva que puede hacerse funcionar bajo luz blanca
que contiene luz ultravioleta, comprendiendo dicha placa de
impresión sobre un soporte una composición fotosensible positiva que
muestra, tras exposición por escaneado a la luz en el intervalo de
longitud de onda de 650 a 1300 nm, mediante un cambio que no es un
cambio químico, una diferencia en solubilidad en un revelador de
álcali entre una porción expuesta y una porción no expuesta,
caracterizada porque dicha composición comprende
- (i)
- un colorante de cianina que absorbe dicha luz y que se representa por la siguiente fórmula (I):
- en la que cada R^{1} y R^{2} es un grupo alquilo C_{1-8} que puede tener un substituyente, en el que el substituyente es un grupo fenilo, un grupo fenoxi, un grupo alcoxi, un grupo ácido sulfónico, o un grupo carboxilo; Q^{1} es un grupo heptametino que puede tener un substituyente, en el que el substituyente es un grupo alquilo C_{1-8}, un átomo de halógeno o un grupo amino, y en el que el grupo heptametino contiene un anillo ciclohexeno que tiene un substituyente, formado por unión mutua de substituyentes sobre dos átomos de carbono metino del grupo heptametino, en el que el substituyente es un grupo alquilo C_{1-6} o un átomo de halógeno; cada m^{1} y m^{2} es 0 ó 1; cada Z^{1} y Z^{2} es un grupo de átomos que se requiere para formar un anillo heterocíclico que contiene nitrógeno; y X^{-} es un contraión; y
- (ii)
- un compuesto de peso molecular elevado, con la condición de que el colorante no está representado por la estructura siguiente (Colorante B).
Applications Claiming Priority (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20701396 | 1996-08-06 | ||
| JP8-207013 | 1996-08-06 | ||
| JP20701396 | 1996-08-06 | ||
| JP30272296 | 1996-11-14 | ||
| JP8-302722 | 1996-11-14 | ||
| JP30272296 | 1996-11-14 | ||
| JP926497 | 1997-01-22 | ||
| JP9-9264 | 1997-01-22 | ||
| JP926497 | 1997-01-22 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2289972T1 true ES2289972T1 (es) | 2008-02-16 |
| ES2289972T3 ES2289972T3 (es) | 2012-01-09 |
Family
ID=27278408
Family Applications (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES04016020.2T Expired - Lifetime ES2536563T5 (es) | 1996-08-06 | 1997-08-05 | Método para fabricar una plancha de impresión litográfica fotosensible positiva |
| ES06022316T Expired - Lifetime ES2289977T3 (es) | 1996-08-06 | 1997-08-05 | Plancha de impresión litográfica fotosensible positiva. |
| ES05024849T Expired - Lifetime ES2289972T3 (es) | 1996-08-06 | 1997-08-05 | Plancha de impresión litográfica fotosensible positiva. |
| ES97113521T Expired - Lifetime ES2232844T3 (es) | 1996-08-06 | 1997-08-05 | Procedimiento para la fabricacion de placas de impresion litografica positivas y fotosensibles. |
Family Applications Before (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES04016020.2T Expired - Lifetime ES2536563T5 (es) | 1996-08-06 | 1997-08-05 | Método para fabricar una plancha de impresión litográfica fotosensible positiva |
| ES06022316T Expired - Lifetime ES2289977T3 (es) | 1996-08-06 | 1997-08-05 | Plancha de impresión litográfica fotosensible positiva. |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES97113521T Expired - Lifetime ES2232844T3 (es) | 1996-08-06 | 1997-08-05 | Procedimiento para la fabricacion de placas de impresion litografica positivas y fotosensibles. |
Country Status (8)
| Country | Link |
|---|---|
| US (3) | US6326122B1 (es) |
| EP (4) | EP0823327B1 (es) |
| JP (3) | JP3814961B2 (es) |
| AT (3) | ATE528133T1 (es) |
| DE (3) | DE06022316T1 (es) |
| DK (3) | DK1464487T4 (es) |
| ES (4) | ES2536563T5 (es) |
| PT (3) | PT1464487E (es) |
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