JPH0251492B2 - - Google Patents
Info
- Publication number
- JPH0251492B2 JPH0251492B2 JP8152383A JP8152383A JPH0251492B2 JP H0251492 B2 JPH0251492 B2 JP H0251492B2 JP 8152383 A JP8152383 A JP 8152383A JP 8152383 A JP8152383 A JP 8152383A JP H0251492 B2 JPH0251492 B2 JP H0251492B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- formula
- color
- layer
- substituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 silver halide Chemical class 0.000 claims description 58
- 125000000217 alkyl group Chemical group 0.000 claims description 23
- 239000000463 material Substances 0.000 claims description 23
- 229910052709 silver Inorganic materials 0.000 claims description 19
- 239000004332 silver Substances 0.000 claims description 19
- 229920000642 polymer Polymers 0.000 claims description 14
- 125000003118 aryl group Chemical group 0.000 claims description 13
- 125000005843 halogen group Chemical group 0.000 claims description 13
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 12
- 229920001577 copolymer Polymers 0.000 claims description 11
- 125000003545 alkoxy group Chemical group 0.000 claims description 9
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- 125000002252 acyl group Chemical group 0.000 claims description 5
- 125000004453 alkoxycarbonyl group Chemical group 0.000 claims description 5
- 125000005161 aryl oxy carbonyl group Chemical group 0.000 claims description 5
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 claims description 5
- 125000006367 bivalent amino carbonyl group Chemical group [H]N([*:1])C([*:2])=O 0.000 claims description 4
- 125000000623 heterocyclic group Chemical group 0.000 claims description 4
- 125000004442 acylamino group Chemical group 0.000 claims description 3
- 125000004414 alkyl thio group Chemical group 0.000 claims description 3
- 125000003277 amino group Chemical group 0.000 claims description 3
- 125000005110 aryl thio group Chemical group 0.000 claims description 3
- 125000001951 carbamoylamino group Chemical group C(N)(=O)N* 0.000 claims description 3
- 125000004149 thio group Chemical group *S* 0.000 claims description 3
- 125000004466 alkoxycarbonylamino group Chemical group 0.000 claims description 2
- 125000004422 alkyl sulphonamide group Chemical group 0.000 claims description 2
- 125000004421 aryl sulphonamide group Chemical group 0.000 claims description 2
- 125000001424 substituent group Chemical group 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 55
- 239000000839 emulsion Substances 0.000 description 38
- 108010010803 Gelatin Proteins 0.000 description 23
- 229920000159 gelatin Polymers 0.000 description 23
- 239000008273 gelatin Substances 0.000 description 23
- 235000019322 gelatine Nutrition 0.000 description 23
- 235000011852 gelatine desserts Nutrition 0.000 description 23
- 238000011161 development Methods 0.000 description 20
- 125000004432 carbon atom Chemical group C* 0.000 description 19
- 150000001875 compounds Chemical class 0.000 description 17
- 239000003795 chemical substances by application Substances 0.000 description 16
- 239000000203 mixture Substances 0.000 description 16
- 238000000034 method Methods 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 12
- 239000000975 dye Substances 0.000 description 12
- 239000000178 monomer Substances 0.000 description 11
- 239000002253 acid Substances 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 229940124530 sulfonamide Drugs 0.000 description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 8
- 239000003112 inhibitor Substances 0.000 description 8
- 238000003756 stirring Methods 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 239000013078 crystal Substances 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- 238000012546 transfer Methods 0.000 description 7
- 238000011282 treatment Methods 0.000 description 7
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 6
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 6
- 238000009792 diffusion process Methods 0.000 description 6
- 229910052740 iodine Inorganic materials 0.000 description 6
- 239000011630 iodine Substances 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 6
- 238000003786 synthesis reaction Methods 0.000 description 6
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 5
- 150000007513 acids Chemical class 0.000 description 5
- 238000004061 bleaching Methods 0.000 description 5
- 239000007844 bleaching agent Substances 0.000 description 5
- 230000003449 preventive effect Effects 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 150000003456 sulfonamides Chemical class 0.000 description 5
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 4
- OJGMBLNIHDZDGS-UHFFFAOYSA-N N-Ethylaniline Chemical compound CCNC1=CC=CC=C1 OJGMBLNIHDZDGS-UHFFFAOYSA-N 0.000 description 4
- FZERHIULMFGESH-UHFFFAOYSA-N N-phenylacetamide Chemical compound CC(=O)NC1=CC=CC=C1 FZERHIULMFGESH-UHFFFAOYSA-N 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical class OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 4
- 238000004040 coloring Methods 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 4
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 4
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000005457 ice water Substances 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 238000010186 staining Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 2
- XLLIQLLCWZCATF-UHFFFAOYSA-N 2-methoxyethyl acetate Chemical compound COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 2
- ZNBNBTIDJSKEAM-UHFFFAOYSA-N 4-[7-hydroxy-2-[5-[5-[6-hydroxy-6-(hydroxymethyl)-3,5-dimethyloxan-2-yl]-3-methyloxolan-2-yl]-5-methyloxolan-2-yl]-2,8-dimethyl-1,10-dioxaspiro[4.5]decan-9-yl]-2-methyl-3-propanoyloxypentanoic acid Chemical compound C1C(O)C(C)C(C(C)C(OC(=O)CC)C(C)C(O)=O)OC11OC(C)(C2OC(C)(CC2)C2C(CC(O2)C2C(CC(C)C(O)(CO)O2)C)C)CC1 ZNBNBTIDJSKEAM-UHFFFAOYSA-N 0.000 description 2
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 229910021607 Silver chloride Inorganic materials 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 229960001413 acetanilide Drugs 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 2
- 125000004104 aryloxy group Chemical group 0.000 description 2
- 235000019445 benzyl alcohol Nutrition 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 229910000378 hydroxylammonium sulfate Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 2
- 238000005691 oxidative coupling reaction Methods 0.000 description 2
- 150000004986 phenylenediamines Chemical class 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 2
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 2
- 235000010265 sodium sulphite Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- YBBRCQOCSYXUOC-UHFFFAOYSA-N sulfuryl dichloride Chemical compound ClS(Cl)(=O)=O YBBRCQOCSYXUOC-UHFFFAOYSA-N 0.000 description 2
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 2
- GVEYRUKUJCHJSR-UHFFFAOYSA-N (4-azaniumyl-3-methylphenyl)-ethyl-(2-hydroxyethyl)azanium;sulfate Chemical compound OS(O)(=O)=O.OCCN(CC)C1=CC=C(N)C(C)=C1 GVEYRUKUJCHJSR-UHFFFAOYSA-N 0.000 description 1
- 125000006569 (C5-C6) heterocyclic group Chemical group 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 1
- BCMCBBGGLRIHSE-UHFFFAOYSA-N 1,3-benzoxazole Chemical group C1=CC=C2OC=NC2=C1 BCMCBBGGLRIHSE-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- ZRHUHDUEXWHZMA-UHFFFAOYSA-N 1,4-dihydropyrazol-5-one Chemical compound O=C1CC=NN1 ZRHUHDUEXWHZMA-UHFFFAOYSA-N 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- YGDWUQFZMXWDKE-UHFFFAOYSA-N 1-oxido-1,3-thiazole Chemical group [O-]S1=CN=C=C1 YGDWUQFZMXWDKE-UHFFFAOYSA-N 0.000 description 1
- KPVMVJXYXFUVLR-UHFFFAOYSA-N 12-ethyltetradecan-1-amine Chemical compound CCC(CC)CCCCCCCCCCCN KPVMVJXYXFUVLR-UHFFFAOYSA-N 0.000 description 1
- CLDZVCMRASJQFO-UHFFFAOYSA-N 2,5-bis(2,4,4-trimethylpentan-2-yl)benzene-1,4-diol Chemical compound CC(C)(C)CC(C)(C)C1=CC(O)=C(C(C)(C)CC(C)(C)C)C=C1O CLDZVCMRASJQFO-UHFFFAOYSA-N 0.000 description 1
- QVLXDGDLLZYJAM-UHFFFAOYSA-N 2,5-dioctylbenzene-1,4-diol Chemical compound CCCCCCCCC1=CC(O)=C(CCCCCCCC)C=C1O QVLXDGDLLZYJAM-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- QTLHLXYADXCVCF-UHFFFAOYSA-N 2-(4-amino-n-ethyl-3-methylanilino)ethanol Chemical compound OCCN(CC)C1=CC=C(N)C(C)=C1 QTLHLXYADXCVCF-UHFFFAOYSA-N 0.000 description 1
- WFXLRLQSHRNHCE-UHFFFAOYSA-N 2-(4-amino-n-ethylanilino)ethanol Chemical compound OCCN(CC)C1=CC=C(N)C=C1 WFXLRLQSHRNHCE-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- XKBYRCKCIRVXLC-UHFFFAOYSA-N 2-[2,4-bis(2-methylbutan-2-yl)phenoxy]propanamide Chemical group CCC(C)(C)C1=CC=C(OC(C)C(N)=O)C(C(C)(C)CC)=C1 XKBYRCKCIRVXLC-UHFFFAOYSA-N 0.000 description 1
- SZTBMYHIYNGYIA-UHFFFAOYSA-N 2-chloroacrylic acid Chemical compound OC(=O)C(Cl)=C SZTBMYHIYNGYIA-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- IQUPABOKLQSFBK-UHFFFAOYSA-N 2-nitrophenol Chemical compound OC1=CC=CC=C1[N+]([O-])=O IQUPABOKLQSFBK-UHFFFAOYSA-N 0.000 description 1
- SEEZWGFVHCMHJF-UHFFFAOYSA-N 2-nitrosophenol Chemical class OC1=CC=CC=C1N=O SEEZWGFVHCMHJF-UHFFFAOYSA-N 0.000 description 1
- ZAWQXWZJKKICSZ-UHFFFAOYSA-N 3,3-dimethyl-2-methylidenebutanamide Chemical compound CC(C)(C)C(=C)C(N)=O ZAWQXWZJKKICSZ-UHFFFAOYSA-N 0.000 description 1
- 125000004189 3,4-dichlorophenyl group Chemical group [H]C1=C([H])C(Cl)=C(Cl)C([H])=C1* 0.000 description 1
- BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 description 1
- XRZDIHADHZSFBB-UHFFFAOYSA-N 3-oxo-n,3-diphenylpropanamide Chemical class C=1C=CC=CC=1NC(=O)CC(=O)C1=CC=CC=C1 XRZDIHADHZSFBB-UHFFFAOYSA-N 0.000 description 1
- YLNKRLLYLJYWEN-UHFFFAOYSA-N 4-(2,2-dibutoxyethoxy)-4-oxobutanoic acid Chemical compound CCCCOC(OCCCC)COC(=O)CCC(O)=O YLNKRLLYLJYWEN-UHFFFAOYSA-N 0.000 description 1
- XBTWVJKPQPQTDW-UHFFFAOYSA-N 4-n,4-n-diethyl-2-methylbenzene-1,4-diamine Chemical compound CCN(CC)C1=CC=C(N)C(C)=C1 XBTWVJKPQPQTDW-UHFFFAOYSA-N 0.000 description 1
- QNGVNLMMEQUVQK-UHFFFAOYSA-N 4-n,4-n-diethylbenzene-1,4-diamine Chemical compound CCN(CC)C1=CC=C(N)C=C1 QNGVNLMMEQUVQK-UHFFFAOYSA-N 0.000 description 1
- FFAJEKUNEVVYCW-UHFFFAOYSA-N 4-n-ethyl-4-n-(2-methoxyethyl)-2-methylbenzene-1,4-diamine Chemical compound COCCN(CC)C1=CC=C(N)C(C)=C1 FFAJEKUNEVVYCW-UHFFFAOYSA-N 0.000 description 1
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 229920002284 Cellulose triacetate Polymers 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 125000000738 acetamido group Chemical group [H]C([H])([H])C(=O)N([H])[*] 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- 150000001253 acrylic acids Chemical class 0.000 description 1
- 238000012644 addition polymerization Methods 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 238000007112 amidation reaction Methods 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 description 1
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 125000003289 ascorbyl group Chemical class [H]O[C@@]([H])(C([H])([H])O*)[C@@]1([H])OC(=O)C(O*)=C1O* 0.000 description 1
- XNSQZBOCSSMHSZ-UHFFFAOYSA-K azane;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxymethyl)amino]acetate;iron(3+) Chemical compound [NH4+].[Fe+3].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O XNSQZBOCSSMHSZ-UHFFFAOYSA-K 0.000 description 1
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 1
- 229910001864 baryta Inorganic materials 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 125000000043 benzamido group Chemical group [H]N([*])C(=O)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- KHBQMWCZKVMBLN-IDEBNGHGSA-N benzenesulfonamide Chemical group NS(=O)(=O)[13C]1=[13CH][13CH]=[13CH][13CH]=[13CH]1 KHBQMWCZKVMBLN-IDEBNGHGSA-N 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 150000008366 benzophenones Chemical group 0.000 description 1
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 150000001649 bromium compounds Chemical class 0.000 description 1
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 1
- XZOWIJDBQIHMFC-UHFFFAOYSA-N butanamide Chemical compound CCCC(N)=O.CCCC(N)=O XZOWIJDBQIHMFC-UHFFFAOYSA-N 0.000 description 1
- 125000006630 butoxycarbonylamino group Chemical group 0.000 description 1
- COPHVUDURPSYBO-UHFFFAOYSA-N butyl dioctyl phosphate Chemical compound CCCCCCCCOP(=O)(OCCCC)OCCCCCCCC COPHVUDURPSYBO-UHFFFAOYSA-N 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 235000013985 cinnamic acid Nutrition 0.000 description 1
- 229930016911 cinnamic acid Natural products 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 description 1
- XWVQUJDBOICHGH-UHFFFAOYSA-N dioctyl nonanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCC(=O)OCCCCCCCC XWVQUJDBOICHGH-UHFFFAOYSA-N 0.000 description 1
- ASMQGLCHMVWBQR-UHFFFAOYSA-M diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)([O-])OC1=CC=CC=C1 ASMQGLCHMVWBQR-UHFFFAOYSA-M 0.000 description 1
- 125000004914 dipropylamino group Chemical group C(CC)N(CCC)* 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000005670 ethenylalkyl group Chemical group 0.000 description 1
- 125000003754 ethoxycarbonyl group Chemical group C(=O)(OCC)* 0.000 description 1
- 125000006627 ethoxycarbonylamino group Chemical group 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 125000004672 ethylcarbonyl group Chemical group [H]C([H])([H])C([H])([H])C(*)=O 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- YAGKRVSRTSUGEY-UHFFFAOYSA-N ferricyanide Chemical compound [Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] YAGKRVSRTSUGEY-UHFFFAOYSA-N 0.000 description 1
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical class OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 1
- 229940093915 gynecological organic acid Drugs 0.000 description 1
- 150000004820 halides Chemical group 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 description 1
- 229920001477 hydrophilic polymer Polymers 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- PTFYQSWHBLOXRZ-UHFFFAOYSA-N imidazo[4,5-e]indazole Chemical compound C1=CC2=NC=NC2=C2C=NN=C21 PTFYQSWHBLOXRZ-UHFFFAOYSA-N 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000004694 iodide salts Chemical class 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- HNQIVZYLYMDVSB-UHFFFAOYSA-N methanesulfonimidic acid Chemical group CS(N)(=O)=O HNQIVZYLYMDVSB-UHFFFAOYSA-N 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- 125000002816 methylsulfanyl group Chemical group [H]C([H])([H])S[*] 0.000 description 1
- 125000006606 n-butoxy group Chemical group 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 150000002832 nitroso derivatives Chemical class 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- QWOKKHXWFDAJCZ-UHFFFAOYSA-N octane-1-sulfonamide Chemical group CCCCCCCCS(N)(=O)=O QWOKKHXWFDAJCZ-UHFFFAOYSA-N 0.000 description 1
- NZIDBRBFGPQCRY-UHFFFAOYSA-N octyl 2-methylprop-2-enoate Chemical compound CCCCCCCCOC(=O)C(C)=C NZIDBRBFGPQCRY-UHFFFAOYSA-N 0.000 description 1
- VECVSKFWRQYTAL-UHFFFAOYSA-N octyl benzoate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1 VECVSKFWRQYTAL-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000001037 p-tolyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 1
- 239000006179 pH buffering agent Substances 0.000 description 1
- 229960003330 pentetic acid Drugs 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pentâ4âenâ2âone Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- CMCWWLVWPDLCRM-UHFFFAOYSA-N phenidone Chemical compound N1C(=O)CCN1C1=CC=CC=C1 CMCWWLVWPDLCRM-UHFFFAOYSA-N 0.000 description 1
- 125000003356 phenylsulfanyl group Chemical group [*]SC1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 125000003170 phenylsulfonyl group Chemical group C1(=CC=CC=C1)S(=O)(=O)* 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 150000003142 primary aromatic amines Chemical class 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical compound O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 150000004053 quinones Chemical class 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000012279 sodium borohydride Substances 0.000 description 1
- 229910000033 sodium borohydride Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- UWSAIOMORQUEHN-UHFFFAOYSA-L sodium;2-[2-[carboxylatomethyl(carboxymethyl)amino]ethyl-(carboxymethyl)amino]acetate;iron(5+) Chemical compound [Na+].[Fe+5].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O UWSAIOMORQUEHN-UHFFFAOYSA-L 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- LMYRWZFENFIFIT-UHFFFAOYSA-N toluene-4-sulfonamide Chemical group CC1=CC=C(S(N)(=O)=O)C=C1 LMYRWZFENFIFIT-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- NJPOTNJJCSJJPJ-UHFFFAOYSA-N tributyl benzene-1,3,5-tricarboxylate Chemical compound CCCCOC(=O)C1=CC(C(=O)OCCCC)=CC(C(=O)OCCCC)=C1 NJPOTNJJCSJJPJ-UHFFFAOYSA-N 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- 150000003639 trimesic acids Chemical class 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/392—Additives
- G03C7/39208—Organic compounds
- G03C7/39212—Carbocyclic
- G03C7/39216—Carbocyclic with OH groups
Landscapes
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Description
æ¬çºæã¯è²æ±æãé²æ¢ããã«ã©ãŒåçæå
ææ
ã«é¢ãããã®ã§ãããç¹ã«ã¹ã«ãã³ã¢ããããšã
ãŒã«èªå°äœãè²æ±æé²æ¢å€ãšããŠå«ãããã²ã³å
éã«ã©ãŒåçæå ææã«é¢ãããã®ã§ããã ããã²ã³åéåçæå ä¹³å€äžäžã«è²åœ¢æã«ãã©
ãŒãå«æãããã©ããšãã¬ã³ãžã¢ãã³ãªã©ã®çºè²
çŸåè¬ãçšããŠçŸåããã¿ã€ãã®å€å±€ã«ã©ãŒåç
æå æã«ãããŠãçŸåæã«çæããçºè²çŸåè¬é ž
åäœããé£æ¥ã®ç»å圢æå±€ã«ç§»è¡ããŠäžéœåãªè²
çŽ ã圢æãããããããè²æ¿ãïŒæ··è²ïŒãçŸåã
çããããšã¯è¯ãç¥ãããŠããããŸãçºè²çŸåæ
ã«çŸåäž»è¬ã®ç©ºæ°é žåãä¹³å€ã«ããªãªã©ã«ãã€ãŠ
äžéœåãªãè²ã«ããªãçŸè±¡ãèµ·ããããšãç¥ãã
ãŠããã以äžã«ãããŠã¯ããã®ãè²æ¿ãããšãè²
ã«ããªããç·ç§°ããŠãè²æ±æããšåŒã¶ããšã«ã
ãã è²æ±æãé²æ¢ããããã«ãåŸæ¥çš®ã ã®ãã€ãã
ããã³ãçšããæ¹æ³ãææ¡ãããŠãããäŸãã°ã
ã¢ãçŽéã¢ã«ãã«ãã€ããããã³ãçšããããšã«
ã€ããŠã¯ãç±³åœç¹èš±2728659å·ãç¹éæ49â
106329å·ãªã©ã«ããŸãã¢ãåæã¢ã«ãã«ãã€ãã
ããã³ãçšããããšã«ã€ããŠã¯ãç±³åœç¹èš±
3700453å·ã西ç¬ç¹èš±å ¬é2149789å·ãç¹éæ50â
156438å·ãå49â106329å·ã«èšèŒãããŠãããäž
æ¹ãžçŽéã¢ã«ãã«ãã€ããããã³ã«ã€ããŠã¯ãç±³
åœç¹èš±2728659å·ãå2732300å·ãè±åœç¹èš±752146
å·ãå1086208å·ããã±ãã«ã«ã¢ãã¹ãã©ã¯ãã
èª58å·»6367hãªã©ã«ããŸããžåæã¢ã«ãã«ãã€ã
ãããã³ã«ã€ããŠã¯ãç±³åœç¹èš±3700453å·ãå
2732300å·ãè±åœç¹èš±1086208å·ãåæ²ãã±ãã«
ã«ã»ã¢ãã¹ãã©ã¯ããèªãç¹éæ50â156438å·ã
ç¹å ¬æ50â21249å·ãå56â40818å·ãªã©ã«èšèŒã
ããã ãã®ä»ãã¢ã«ãã«ãã€ããããã³ãè²æ±æé²æ¢
å€ãšããŠçšããããšã«ã€ããŠã¯ãè±åœç¹èš±558258
å·ãå557750å·ïŒå¯Ÿå¿ç±³åœç¹èš±2360290å·ïŒãå
557802å·ãå731301å·ïŒå¯Ÿå¿ç±³åœç¹èš±2701197
å·ïŒãç±³åœç¹èš±2336327å·ãå2403721å·ãå
3582333å·ã西ç¬ç¹èš±å ¬é2505016å·ïŒå¯Ÿå¿ç¹éæ
50â110337å·ïŒãç¹å ¬æ56â40816å·ã«ãèšèŒãã
ãã ã«ã©ãŒæ¡æ£è»¢ååçææã«ãããŠãéåžžã®ã«ã©
ãŒåçæå æãšåæ§ãè²æ¿ããçŸè±¡ãèµ·ããããš
ãç¥ãããŠããããããé²æ¢ããããã«äžèšãã€
ããããã³é¡ãå¿çšãããŠãããæ¡æ£è»¢åææã®
è²æ¿ãé²æ¢å€ã«çšãããã€ããããã³ãšããŠã¯ç¹
éæ58â21249å·ã«èšèŒãããã ã¹ã«ãã³ã¢ããããšããŒã«é¡ãæ¡æ£è»¢åææã®
è²æ¿ãé²æ¢å€ãšããŠçšããããšã«ã€ããŠã¯ããªãµ
ãŒãã»ãã€ã¹ã¯ããŒãžã€ãèª15162ïŒ1973幎ïŒ83
é ãç¹éæ55â72158å·ãç¹éæ57â24941å·ïŒå¯Ÿ
å¿ç±³åœç¹èš±4366226å·ïŒã«èšèŒãããã æè¿ã®ã«ã©ãŒåçæå ææã®è£œé æè¡åéã§
ã¯ãããé«å質ã®ã«ã©ãŒåçãåŸãããã«ãåç
æ床ãäœäžãããããšãªãè²æ±æããããäžå±€å¹
ççã«é²æ¢ã§ããé®®é床ãåäžãããããã«èå±€
åãããææã«ãæ·»å å¯èœã§ãé·æä¿ååŸãæ§èœ
ã®å€åããããããæŽã«çºè²çŸè±¡ã«ãã€ãŠåœ¢æã
ããè²çŽ ç»åã®å å ç¢æ§ã®æ¹è¯ã«ãå¯äžããæ°ã
ãè²æ±æé²æ¢å€ã®éçºã匷ãæãŸããŠããã æ¬çºæã®ç¬¬äžã®ç®çã¯æ°èŠãªè²æ±ææ¢å€ãæäŸ
ããããšã«ãããæ¬çºæ第äºã®ç®çã¯çºè²çŸåè¬
åã¯é»è·ç§»ååé»è²çŸåè¬ã®é žåäœãå¹çè¯ãé€
å»ããæ°èŠè²æ±æé²æ¢å€ãæäŸããããšã«ããã
æ¬çºæã®ç¬¬äžã®ç®çã¯èå±€åãããææãæ§æã
ãããšãå¯èœãªæ°èŠè²æ±æé²æ¢å€ãæäŸããããš
ã«ãããæ¬çºæã®ç¬¬åã®ç®çã¯é·æä¿ååŸãæ§èœ
ã®å€åãããããªãæ°èŠè²æ±æé²æ¢å€ãæäŸãã
ããšã«ãããæŽã«æ¬çºæã®ããäžã€ã®ç®çã¯ãã
ã®æ°èŠãªè²æ±æé²æ¢å€ãå«ãã«ã©ãŒåçæå ææ
ãæäŸããããšã«ããã äžèšã®è«žç®çã¯ãäžèšã®äžè¬åŒïŒïŒã§è¡šãã
ãç¹°ãè¿ãåäœåã³ïŒåã¯äžè¬åŒïŒïŒã§è¡šãã
ããç¹°ãè¿ãåäœãå«ãéåäœè¥ããã¯å ±éåäœ
ãããã²ã³åéã«ã©ãŒåçæå ææã«å«æããã
ãããšã«ããéæãããã åŒäžããã¯ããããâSO2âåã¯âCOâ
ãè¡šããããã®ãã¡ã®å°ãªããšãäžæ¹ã¯â
SO2âã§ããã R1ã¯æ°ŽçŽ ååãããã²ã³ååïŒåŒçŽ ãå¡©çŽ ã
èçŽ ãªã©ïŒããããã眮æåã¯ç¡çœ®æã®ãã¢ã«ã
ã«åºïŒããã²ã³ååãªã©ã§çœ®æãããŠããŠãã
ããççŽ æ°ïŒã20ã®ãã®ã奜ãŸãããäŸãã°ã¡ã
ã«åºãïœâããã«åºãã·ã¯ãããã·ã«åºãïœâã
ã³ã¿ãã·ã«åºãªã©ïŒãã¢ã«ã³ãã·åºïŒããã²ã³å
åãªã©ã§çœ®æãããŠããŠããããççŽ æ°ïŒã20ã®
ãã®ã奜ãŸãããäŸãã°ã¡ããã·åºãïœâããã
ã·åºãªã©ïŒãã¢ãªãŒã«ã¹ã«ãã³ã¢ããåºïŒã¢ãªãŒ
ã«åºã¯ã¢ã«ãã«åºãã¢ã«ã³ãã·åºãªã©ã«ããæŽã«
眮æãããŠããŠããããççŽ æ°ã®åèšïŒã30ã®ã
ã®ã奜ãŸãããäŸãã°ïŒâïŒïœâããã·ããã·ïŒ
ãã³ãŒã³ã¹ã«ãã³ã¢ããåºãïœâããªã«ã¹ã«ãã³
ã¢ããåºãªã©ïŒãã¢ã«ãã«ã¹ã«ãã³ã¢ããåºïŒã¢
ã«ãã«åºã¯ããã²ã³ååãæ°Žé žåºã§çœ®æãããŠã
ãŠããããççŽ æ°ïŒã20ã®ãã®ã奜ãŸãããäŸã
ã°ãã¡ã¿ã³ã¹ã«ãã³ã¢ããåºãïœâãªã¯ã¿ã³ã¹ã«
ãã³ã¢ããåºãªã©ïŒãã¢ã·ã«ã¢ããåºïŒã¢ã«ã³ã
ã·åºãã¢ãªãŒããã·åºãã¢ã«ãã«åºãªã©ã§æŽã«çœ®
æãããŠããŠããããççŽ æ°ã®åèšïŒã30ã®ãã®
ã奜ãŸãããäŸãã°ã¢ã»ãã«ã¢ããåºããã³ãŸã€
ã«ã¢ããåºãαâïŒïŒïŒïŒâãžâïœâã¢ãã«ããš
ããã·ïŒãããã³ã¢ããåºãªã©ïŒãã¢ã«ãã«ããª
åºïŒããã²ã³ååãªã©ã§çœ®æãããŠããŠãããã
ççŽ æ°ïŒã20ã®ãã®ã奜ãŸãããäŸãã°ãã¡ãã«
ããªåºããããµãã·ã«ããªåºãªã©ïŒãã¢ãªãŒã«ã
ãªåºïŒã¢ãªãŒã«åºã¯ã¢ã«ãã«åºãã¢ã«ã³ãã·åºãª
ã©ã§æŽã«çœ®æãããŠããŠããããäŸãã°ãããšã
ã«ããªåºãïŒâãããã·ããšãã«ããªåºãªã©ïŒã
ãããç°ããªåºïŒïŒãïŒå¡ã®ãããç°ã奜ãŸã
ãããããç°ã¯ã¢ã«ãã«åºãã¢ãªãŒã«åºãªã©ã§æŽ
ã«çœ®æãããŠããŠããããççŽ æ°ã®åèšïŒã20ã®
ãã®ã奜ãŸãããäŸãã°ïŒâããšãã«ããã©ãŸãŒ
ã«âïŒâã€ã«ããªåºãªã©ïŒãã¢ã«ã³ãã·ã«ã«ãã
ã«åºïŒã¢ã«ãã«åºã¯ããã²ã³ååãªã©ã§çœ®æãã
ãŠããŠããããççŽ æ°ïŒã20ã®ãã®ã奜ãŸããã
äŸãã°ãã¡ããã·ã«ã«ããã«åºããšããã·ã«ã«ã
ãã«åºãªã©ïŒãã¢ãªãŒããã·ã«ã«ããã«åºïŒã¢ãª
ãŒã«åºã¯ã¢ã«ãã«åºãã¢ã«ã³ãã·åºãªã©ã§æŽã«çœ®
æãããŠããŠããããççŽ æ°ã®åèšïŒã30ã®ãã®
ã奜ãŸãããäŸãã°ãããšããã·ã«ã«ããã«åºãª
ã©ïŒãã¹ã«ãã¢ã¢ã€ã«ã¢ããåºïŒã¹ã«ãã¢ã¢ã€ã«
åºã¯ã¢ã«ãã«åºãã¢ãªãŒã«åºãªã©ã§æŽã«çœ®æãã
ãŠããŠããããççŽ æ°ã®åèšïŒã20ã®ãã®ã奜ãŸ
ãããäŸãã°ãïŒïŒ®âãžãããã«ïŒã¹ã«ãã¢ã¢
ã€ã«ã¢ããåºãªã©ïŒãã¢ã«ã³ãã·ã«ã«ããã«ã¢ã
ãåºïŒççŽ æ°ïŒã20ã®ãã®ã奜ãŸãããäŸãã°ãš
ããã·ã«ã«ããã«ã¢ããåºããããã·ã«ã«ããã«
ã¢ããåºãªã©ïŒãã«ã«ãã¢ã€ã«ã¢ããåºïŒã«ã«ã
ã¢ã€ã«åºã¯ã¢ã«ãã«åºãã¢ãªãŒã«åºãªã©ã«ãã€ãŠ
æŽã«çœ®æãããŠããŠãããã奜ãŸããã¯ççŽ æ°ã¯
åèšïŒã20ãäŸãã°ïŒ®âããšãã«ã«ã«ãã¢ã€ã«ã¢
ããåºãªã©ïŒãã¢ã·ã«åºãïŒå¥œãŸããççŽ æ°ã¯ïŒã
20ãäŸãã°ã¢ã»ãã«åºããšãã«ã«ã«ããã«åºãª
ã©ïŒãã¹ã«ããã«åºïŒå¥œãŸããççŽ æ°ã¯ïŒã30ã
äŸãã°ãã³ãŒã³ã¹ã«ããã«åºãªã©ïŒãã«ã«ãã¢ã€
ã«åºïŒã¢ã«ãã«åºãã¢ãªãŒã«åºãªã©ã§çœ®æãããŠ
ããŠãããã奜ãŸããççŽ æ°ïŒã20ãäŸãã°ïŒ®â
ããšãã«ã«ã«ãã¢ã€ã«åºãïŒïŒ®âãžãªã¯ãã«ã«
ã«ãã¢ã€ã«åºãªã©ïŒãããããã R2ãR3ã¯ããããã眮æåã¯ç¡çœ®æã®ãã¢ãª
ãŒã«åºïŒã¢ãªãŒã«åºã¯ããã²ã³ååãã¢ã«ãã«
åºãã¢ã«ã³ãã·åºãªã©ã«ãã€ãŠæŽã«çœ®æãããŠã
ãŠããããççŽ æ°ã®åèšïŒã30ã®ãã®ã奜ãŸã
ããäŸãã°ïŒâïŒïœâããã·ããã·ïŒããšãã«
åºãïœâããªã«åºãïŒïŒïŒâãžã¯ãã«ããšãã«
åºãïŒâããã·ã«ããšãã«åºãªã©ïŒãã¢ã«ãã«åº
ïŒã¢ã«ãã«åºã¯ããã²ã³ååãæ°Žé žåºãã¢ãªãŒã
ãã·åºãã¢ã«ã³ãã·åºãªã©ã«ãã€ãŠçœ®æãããŠã
ãŠããããççŽ æ°ã®åèšïŒã30ã®ãã®ã奜ãŸã
ããäŸãã°ã¡ãã«åºãããªãã«ãªãã¡ãã«åºãïœ
âãããµãã·ã«åºãïŒâïŒïœâãã³ã¿ãã·ã«ããš
ããã·ïŒãããã«åºãªã©ïŒãã¢ããåºïŒã¢ããåº
ã¯ã¢ã«ãã«åºãã¢ãªãŒã«åºãªã©ã«ãã眮æãããŠ
ããŠããããççŽ æ°ã®åèšïŒã30ã®ãã®ã奜ãŸã
ããäŸãã°ãžã¡ãã«ã¢ããåºããžãããã«ã¢ãã
åºãªã©ïŒãè¡šãããR2ãR3ã¯åãã§ãç°ãªã€ãŠ
ããŠãããã R4ã¯ã
ã«é¢ãããã®ã§ãããç¹ã«ã¹ã«ãã³ã¢ããããšã
ãŒã«èªå°äœãè²æ±æé²æ¢å€ãšããŠå«ãããã²ã³å
éã«ã©ãŒåçæå ææã«é¢ãããã®ã§ããã ããã²ã³åéåçæå ä¹³å€äžäžã«è²åœ¢æã«ãã©
ãŒãå«æãããã©ããšãã¬ã³ãžã¢ãã³ãªã©ã®çºè²
çŸåè¬ãçšããŠçŸåããã¿ã€ãã®å€å±€ã«ã©ãŒåç
æå æã«ãããŠãçŸåæã«çæããçºè²çŸåè¬é ž
åäœããé£æ¥ã®ç»å圢æå±€ã«ç§»è¡ããŠäžéœåãªè²
çŽ ã圢æãããããããè²æ¿ãïŒæ··è²ïŒãçŸåã
çããããšã¯è¯ãç¥ãããŠããããŸãçºè²çŸåæ
ã«çŸåäž»è¬ã®ç©ºæ°é žåãä¹³å€ã«ããªãªã©ã«ãã€ãŠ
äžéœåãªãè²ã«ããªãçŸè±¡ãèµ·ããããšãç¥ãã
ãŠããã以äžã«ãããŠã¯ããã®ãè²æ¿ãããšãè²
ã«ããªããç·ç§°ããŠãè²æ±æããšåŒã¶ããšã«ã
ãã è²æ±æãé²æ¢ããããã«ãåŸæ¥çš®ã ã®ãã€ãã
ããã³ãçšããæ¹æ³ãææ¡ãããŠãããäŸãã°ã
ã¢ãçŽéã¢ã«ãã«ãã€ããããã³ãçšããããšã«
ã€ããŠã¯ãç±³åœç¹èš±2728659å·ãç¹éæ49â
106329å·ãªã©ã«ããŸãã¢ãåæã¢ã«ãã«ãã€ãã
ããã³ãçšããããšã«ã€ããŠã¯ãç±³åœç¹èš±
3700453å·ã西ç¬ç¹èš±å ¬é2149789å·ãç¹éæ50â
156438å·ãå49â106329å·ã«èšèŒãããŠãããäž
æ¹ãžçŽéã¢ã«ãã«ãã€ããããã³ã«ã€ããŠã¯ãç±³
åœç¹èš±2728659å·ãå2732300å·ãè±åœç¹èš±752146
å·ãå1086208å·ããã±ãã«ã«ã¢ãã¹ãã©ã¯ãã
èª58å·»6367hãªã©ã«ããŸããžåæã¢ã«ãã«ãã€ã
ãããã³ã«ã€ããŠã¯ãç±³åœç¹èš±3700453å·ãå
2732300å·ãè±åœç¹èš±1086208å·ãåæ²ãã±ãã«
ã«ã»ã¢ãã¹ãã©ã¯ããèªãç¹éæ50â156438å·ã
ç¹å ¬æ50â21249å·ãå56â40818å·ãªã©ã«èšèŒã
ããã ãã®ä»ãã¢ã«ãã«ãã€ããããã³ãè²æ±æé²æ¢
å€ãšããŠçšããããšã«ã€ããŠã¯ãè±åœç¹èš±558258
å·ãå557750å·ïŒå¯Ÿå¿ç±³åœç¹èš±2360290å·ïŒãå
557802å·ãå731301å·ïŒå¯Ÿå¿ç±³åœç¹èš±2701197
å·ïŒãç±³åœç¹èš±2336327å·ãå2403721å·ãå
3582333å·ã西ç¬ç¹èš±å ¬é2505016å·ïŒå¯Ÿå¿ç¹éæ
50â110337å·ïŒãç¹å ¬æ56â40816å·ã«ãèšèŒãã
ãã ã«ã©ãŒæ¡æ£è»¢ååçææã«ãããŠãéåžžã®ã«ã©
ãŒåçæå æãšåæ§ãè²æ¿ããçŸè±¡ãèµ·ããããš
ãç¥ãããŠããããããé²æ¢ããããã«äžèšãã€
ããããã³é¡ãå¿çšãããŠãããæ¡æ£è»¢åææã®
è²æ¿ãé²æ¢å€ã«çšãããã€ããããã³ãšããŠã¯ç¹
éæ58â21249å·ã«èšèŒãããã ã¹ã«ãã³ã¢ããããšããŒã«é¡ãæ¡æ£è»¢åææã®
è²æ¿ãé²æ¢å€ãšããŠçšããããšã«ã€ããŠã¯ããªãµ
ãŒãã»ãã€ã¹ã¯ããŒãžã€ãèª15162ïŒ1973幎ïŒ83
é ãç¹éæ55â72158å·ãç¹éæ57â24941å·ïŒå¯Ÿ
å¿ç±³åœç¹èš±4366226å·ïŒã«èšèŒãããã æè¿ã®ã«ã©ãŒåçæå ææã®è£œé æè¡åéã§
ã¯ãããé«å質ã®ã«ã©ãŒåçãåŸãããã«ãåç
æ床ãäœäžãããããšãªãè²æ±æããããäžå±€å¹
ççã«é²æ¢ã§ããé®®é床ãåäžãããããã«èå±€
åãããææã«ãæ·»å å¯èœã§ãé·æä¿ååŸãæ§èœ
ã®å€åããããããæŽã«çºè²çŸè±¡ã«ãã€ãŠåœ¢æã
ããè²çŽ ç»åã®å å ç¢æ§ã®æ¹è¯ã«ãå¯äžããæ°ã
ãè²æ±æé²æ¢å€ã®éçºã匷ãæãŸããŠããã æ¬çºæã®ç¬¬äžã®ç®çã¯æ°èŠãªè²æ±ææ¢å€ãæäŸ
ããããšã«ãããæ¬çºæ第äºã®ç®çã¯çºè²çŸåè¬
åã¯é»è·ç§»ååé»è²çŸåè¬ã®é žåäœãå¹çè¯ãé€
å»ããæ°èŠè²æ±æé²æ¢å€ãæäŸããããšã«ããã
æ¬çºæã®ç¬¬äžã®ç®çã¯èå±€åãããææãæ§æã
ãããšãå¯èœãªæ°èŠè²æ±æé²æ¢å€ãæäŸããããš
ã«ãããæ¬çºæã®ç¬¬åã®ç®çã¯é·æä¿ååŸãæ§èœ
ã®å€åãããããªãæ°èŠè²æ±æé²æ¢å€ãæäŸãã
ããšã«ãããæŽã«æ¬çºæã®ããäžã€ã®ç®çã¯ãã
ã®æ°èŠãªè²æ±æé²æ¢å€ãå«ãã«ã©ãŒåçæå ææ
ãæäŸããããšã«ããã äžèšã®è«žç®çã¯ãäžèšã®äžè¬åŒïŒïŒã§è¡šãã
ãç¹°ãè¿ãåäœåã³ïŒåã¯äžè¬åŒïŒïŒã§è¡šãã
ããç¹°ãè¿ãåäœãå«ãéåäœè¥ããã¯å ±éåäœ
ãããã²ã³åéã«ã©ãŒåçæå ææã«å«æããã
ãããšã«ããéæãããã åŒäžããã¯ããããâSO2âåã¯âCOâ
ãè¡šããããã®ãã¡ã®å°ãªããšãäžæ¹ã¯â
SO2âã§ããã R1ã¯æ°ŽçŽ ååãããã²ã³ååïŒåŒçŽ ãå¡©çŽ ã
èçŽ ãªã©ïŒããããã眮æåã¯ç¡çœ®æã®ãã¢ã«ã
ã«åºïŒããã²ã³ååãªã©ã§çœ®æãããŠããŠãã
ããççŽ æ°ïŒã20ã®ãã®ã奜ãŸãããäŸãã°ã¡ã
ã«åºãïœâããã«åºãã·ã¯ãããã·ã«åºãïœâã
ã³ã¿ãã·ã«åºãªã©ïŒãã¢ã«ã³ãã·åºïŒããã²ã³å
åãªã©ã§çœ®æãããŠããŠããããççŽ æ°ïŒã20ã®
ãã®ã奜ãŸãããäŸãã°ã¡ããã·åºãïœâããã
ã·åºãªã©ïŒãã¢ãªãŒã«ã¹ã«ãã³ã¢ããåºïŒã¢ãªãŒ
ã«åºã¯ã¢ã«ãã«åºãã¢ã«ã³ãã·åºãªã©ã«ããæŽã«
眮æãããŠããŠããããççŽ æ°ã®åèšïŒã30ã®ã
ã®ã奜ãŸãããäŸãã°ïŒâïŒïœâããã·ããã·ïŒ
ãã³ãŒã³ã¹ã«ãã³ã¢ããåºãïœâããªã«ã¹ã«ãã³
ã¢ããåºãªã©ïŒãã¢ã«ãã«ã¹ã«ãã³ã¢ããåºïŒã¢
ã«ãã«åºã¯ããã²ã³ååãæ°Žé žåºã§çœ®æãããŠã
ãŠããããççŽ æ°ïŒã20ã®ãã®ã奜ãŸãããäŸã
ã°ãã¡ã¿ã³ã¹ã«ãã³ã¢ããåºãïœâãªã¯ã¿ã³ã¹ã«
ãã³ã¢ããåºãªã©ïŒãã¢ã·ã«ã¢ããåºïŒã¢ã«ã³ã
ã·åºãã¢ãªãŒããã·åºãã¢ã«ãã«åºãªã©ã§æŽã«çœ®
æãããŠããŠããããççŽ æ°ã®åèšïŒã30ã®ãã®
ã奜ãŸãããäŸãã°ã¢ã»ãã«ã¢ããåºããã³ãŸã€
ã«ã¢ããåºãαâïŒïŒïŒïŒâãžâïœâã¢ãã«ããš
ããã·ïŒãããã³ã¢ããåºãªã©ïŒãã¢ã«ãã«ããª
åºïŒããã²ã³ååãªã©ã§çœ®æãããŠããŠãããã
ççŽ æ°ïŒã20ã®ãã®ã奜ãŸãããäŸãã°ãã¡ãã«
ããªåºããããµãã·ã«ããªåºãªã©ïŒãã¢ãªãŒã«ã
ãªåºïŒã¢ãªãŒã«åºã¯ã¢ã«ãã«åºãã¢ã«ã³ãã·åºãª
ã©ã§æŽã«çœ®æãããŠããŠããããäŸãã°ãããšã
ã«ããªåºãïŒâãããã·ããšãã«ããªåºãªã©ïŒã
ãããç°ããªåºïŒïŒãïŒå¡ã®ãããç°ã奜ãŸã
ãããããç°ã¯ã¢ã«ãã«åºãã¢ãªãŒã«åºãªã©ã§æŽ
ã«çœ®æãããŠããŠããããççŽ æ°ã®åèšïŒã20ã®
ãã®ã奜ãŸãããäŸãã°ïŒâããšãã«ããã©ãŸãŒ
ã«âïŒâã€ã«ããªåºãªã©ïŒãã¢ã«ã³ãã·ã«ã«ãã
ã«åºïŒã¢ã«ãã«åºã¯ããã²ã³ååãªã©ã§çœ®æãã
ãŠããŠããããççŽ æ°ïŒã20ã®ãã®ã奜ãŸããã
äŸãã°ãã¡ããã·ã«ã«ããã«åºããšããã·ã«ã«ã
ãã«åºãªã©ïŒãã¢ãªãŒããã·ã«ã«ããã«åºïŒã¢ãª
ãŒã«åºã¯ã¢ã«ãã«åºãã¢ã«ã³ãã·åºãªã©ã§æŽã«çœ®
æãããŠããŠããããççŽ æ°ã®åèšïŒã30ã®ãã®
ã奜ãŸãããäŸãã°ãããšããã·ã«ã«ããã«åºãª
ã©ïŒãã¹ã«ãã¢ã¢ã€ã«ã¢ããåºïŒã¹ã«ãã¢ã¢ã€ã«
åºã¯ã¢ã«ãã«åºãã¢ãªãŒã«åºãªã©ã§æŽã«çœ®æãã
ãŠããŠããããççŽ æ°ã®åèšïŒã20ã®ãã®ã奜ãŸ
ãããäŸãã°ãïŒïŒ®âãžãããã«ïŒã¹ã«ãã¢ã¢
ã€ã«ã¢ããåºãªã©ïŒãã¢ã«ã³ãã·ã«ã«ããã«ã¢ã
ãåºïŒççŽ æ°ïŒã20ã®ãã®ã奜ãŸãããäŸãã°ãš
ããã·ã«ã«ããã«ã¢ããåºããããã·ã«ã«ããã«
ã¢ããåºãªã©ïŒãã«ã«ãã¢ã€ã«ã¢ããåºïŒã«ã«ã
ã¢ã€ã«åºã¯ã¢ã«ãã«åºãã¢ãªãŒã«åºãªã©ã«ãã€ãŠ
æŽã«çœ®æãããŠããŠãããã奜ãŸããã¯ççŽ æ°ã¯
åèšïŒã20ãäŸãã°ïŒ®âããšãã«ã«ã«ãã¢ã€ã«ã¢
ããåºãªã©ïŒãã¢ã·ã«åºãïŒå¥œãŸããççŽ æ°ã¯ïŒã
20ãäŸãã°ã¢ã»ãã«åºããšãã«ã«ã«ããã«åºãª
ã©ïŒãã¹ã«ããã«åºïŒå¥œãŸããççŽ æ°ã¯ïŒã30ã
äŸãã°ãã³ãŒã³ã¹ã«ããã«åºãªã©ïŒãã«ã«ãã¢ã€
ã«åºïŒã¢ã«ãã«åºãã¢ãªãŒã«åºãªã©ã§çœ®æãããŠ
ããŠãããã奜ãŸããççŽ æ°ïŒã20ãäŸãã°ïŒ®â
ããšãã«ã«ã«ãã¢ã€ã«åºãïŒïŒ®âãžãªã¯ãã«ã«
ã«ãã¢ã€ã«åºãªã©ïŒãããããã R2ãR3ã¯ããããã眮æåã¯ç¡çœ®æã®ãã¢ãª
ãŒã«åºïŒã¢ãªãŒã«åºã¯ããã²ã³ååãã¢ã«ãã«
åºãã¢ã«ã³ãã·åºãªã©ã«ãã€ãŠæŽã«çœ®æãããŠã
ãŠããããççŽ æ°ã®åèšïŒã30ã®ãã®ã奜ãŸã
ããäŸãã°ïŒâïŒïœâããã·ããã·ïŒããšãã«
åºãïœâããªã«åºãïŒïŒïŒâãžã¯ãã«ããšãã«
åºãïŒâããã·ã«ããšãã«åºãªã©ïŒãã¢ã«ãã«åº
ïŒã¢ã«ãã«åºã¯ããã²ã³ååãæ°Žé žåºãã¢ãªãŒã
ãã·åºãã¢ã«ã³ãã·åºãªã©ã«ãã€ãŠçœ®æãããŠã
ãŠããããççŽ æ°ã®åèšïŒã30ã®ãã®ã奜ãŸã
ããäŸãã°ã¡ãã«åºãããªãã«ãªãã¡ãã«åºãïœ
âãããµãã·ã«åºãïŒâïŒïœâãã³ã¿ãã·ã«ããš
ããã·ïŒãããã«åºãªã©ïŒãã¢ããåºïŒã¢ããåº
ã¯ã¢ã«ãã«åºãã¢ãªãŒã«åºãªã©ã«ãã眮æãããŠ
ããŠããããççŽ æ°ã®åèšïŒã30ã®ãã®ã奜ãŸã
ããäŸãã°ãžã¡ãã«ã¢ããåºããžãããã«ã¢ãã
åºãªã©ïŒãè¡šãããR2ãR3ã¯åãã§ãç°ãªã€ãŠ
ããŠãããã R4ã¯ã
ãåŒã
ãåŒã
ãåŒã
ãåŒã
ãåŒãâCH2CH2O
âã
ãåŒã
ãåŒã
âNHCH2CH2NHCOâãè¡šããã
R5ã¯ã
ãåŒã
ãåŒã
ãåŒã
ãåŒã
âCH2CH2CH2NHCOâãâNHSO2âã
ãåŒã
ãåŒãè¡šããã
R6ã¯æ°ŽçŽ ååãããã²ã³ååïŒåŒçŽ ãå¡©çŽ ã
èçŽ ãªã©ïŒãã¢ã«ãã«åºïŒå¥œãŸããã¯ççŽ æ°ïŒã
ïŒã®ãã®ãäŸãã°ã¡ãã«åºããšãã«åºãªã©ïŒãè¡š
ããã ïœã¯ïŒåã¯ïŒã§ããã äžè¬åŒïŒïŒåã¯ïŒïŒã«ãããããšããŒã«ç°
äžã®çœ®æåºã¯ããããç°äžã®ãããã®äœçœ®ã«çœ®æ
ããŠããŠãããã äžè¬åŒïŒïŒåã¯ïŒïŒã§è¡šãããããã®ã®äž
ã§ããäžè¬åŒïŒïŒã§è¡šãããããã®ã奜ãŸã
ãã åèšäžè¬åŒïŒïŒã§è¡šããããç¹°ãè¿ãåäœã®
äžã§ã次ã®äžè¬åŒã§è¡šãããããã®ã奜ãŸããã ãããäžè¬åŒïŒïŒãïŒïŒã«ããããã
R1ãR6ãïœã¯äžè¬åŒïŒïŒã«ãããŠå®çŸ©ããã
ã®ãšåãã§ããã åèšäžè¬åŒïŒïŒãïŒïŒã«ãããŠãR1ã¯ã
ïŒïŒåã³ïŒïŒã®å Žåã«ã¯æ°ŽçŽ ååãããã²ã³
ååãã¢ã«ãã«åºãã¢ã«ã³ãã·åºãã¢ã«ãã«ããª
åºãã¢ã«ã³ãã·ã«ã«ããã«åºãã¢ãªãŒã«ããªåºã
ãããç°ããªåºãã¢ãªãŒããã·ã«ã«ããã«åºãã¢
ã·ã«åºãã¹ã«ããã«åºãã«ã«ãã¢ã€ã«åºã§ããã
ãšã奜ãŸãããïŒïŒãïŒïŒã®å Žåã«ã¯ãR1ã¯
æ°ŽçŽ ååãããã²ã³ååãã¢ã«ãã«åºãã¢ã·ã«ã¢
ããåºãã¢ã«ã³ãã·ã«ã«ããã«åºãã¢ãªãŒããã·
ã«ã«ããã«åºãã¹ã«ããã«åºãã¹ã«ãã¢ã¢ã€ã«ã¢
ããåºãã«ã«ãã¢ã€ã«ã¢ããåºãã¢ã·ã«åºãã«ã«
ãã¢ã€ã«åºã§ããããšã奜ãŸãããç¹ã«ã«ã©ãŒçŸ
åã«ãããçºè²çŸåäž»è¬ãšã®é žåã«ãããªã³ã°ã«
ããçºè²ãèµ·ãããªãåºïŒã¢ã«ãã«åºãã¢ã«ã³ã
ã·ã«ã«ããã«åºãã¹ã«ããã«åºãã¢ãªãŒããã·ã«
ã«ããã«åºãã¢ã·ã«åºãã«ã«ãã¢ã€ã«åºïŒã§ãã
ããšã奜ãŸããã åèšäžè¬åŒïŒïŒãïŒïŒã§è¡šããããç¹°ãè¿
ãåäœã®äžã§ãäžè¬åŒïŒïŒãïŒïŒã§è¡šããã
ããã®ã奜ãŸããã åèšäžè¬åŒïŒïŒãïŒïŒã«ãããR2ãR3ãš
ããŠã¯ã¢ãªãŒã«åºãã¢ã«ãã«åºã§ããå Žåãç¹ã«
奜ãŸããã äžè¬åŒïŒïŒãïŒïŒã«ãããããšããŠã¯
å ±ã«âSO2âã§ããå Žåãç¹ã«å¥œãŸããã äžè¬åŒïŒïŒãïŒïŒã®äžã§æã奜ãŸãããã®
ã¯äžè¬åŒïŒïŒåã¯ïŒïŒã§ããã æ¬çºæã§çšããéåäœè¥ããã¯å ±éåäœã¯ãå
èšäžè¬åŒïŒïŒåã¯ïŒïŒã®ç¹°ãè¿ãåäœã®ã¿ã
ããªããã®ã§ãã€ãŠããããäžè¬åŒïŒïŒãš
ïŒïŒã®åæ¹ã®ç¹°ãè¿ãåäœãããªãå ±éåäœã§
ãã€ãŠãããããŸãäžè¬åŒïŒïŒåã³ïŒåã¯
ïŒïŒã®ç¹°ãè¿ãåäœãšäžè¬åŒïŒïŒåã¯ïŒïŒ
以å€ã®ç¹°ãè¿ãåäœãå«æããå ±éåäœã§ãã€ãŠ
ãããããããéåäœè¥ããã¯å ±éåäœã¯äžè¬
ã«ãäžè¬åŒïŒïŒåã¯ïŒïŒã®ç¹°ãè¿ãåäœãèª
å°ãããåéäœã®åç¬éåãäžè¬åŒïŒïŒåã³
ïŒïŒã®ç¹°ãè¿ãåäœãèªå°ãããåéäœã©ãã
ã®å ±éåããŸãã¯ãããã®åéäœãšä»å éåãã
ãä»ã®ãšãã¬ã³æ§äžé£œååéäœãšã®å ±éåã«ãã€
ãŠåŸãããã äžè¬åŒïŒïŒåã¯ïŒïŒã®ç¹°ãè¿ãåäœãèªå°
ãããåéäœã®å ·äœäŸã以äžã«æããããæ¬çºæ
ã¯ããã«éå®ããããã®ã§ã¯ãªãã äžè¬åŒïŒïŒåã¯ïŒïŒã®ç¹°ãè¿ãåäœãèªå°
ãããåéäœãšä»å éåãããä»ã®ãšãã¬ã³æ§äž
飜ååéäœãšããŠã¯ãéå枩床ïŒäžè¬çã«ã¯50â
ã95âãæãŸããã¯70âã90âïŒã§æ¶²äœã§ããå š
ãŠã®æ°Žäžæº¶æ§åéäœãååçã«äœ¿çšã§ãããå ·äœ
çã«ã¯äŸãã°ãã¢ã¯ãªã«é žãαâã¯ããã¢ã¯ãªã«
é žãαâã¢ã«ã¢ã¯ãªã«é žïŒã¡ã¿ã¢ã¯ãªã«é žãªã©ïŒ
ãªã©ã®ã¢ã¯ãªã«é žé¡ããèªå°ããããšã¹ãã«ãã
ãã¯ã¢ããïŒäŸãã°ïœâããã«ã¢ã¯ãªã«ã¢ããã
ã¡ãã«ã¢ã¯ãªã¬ãŒããã¡ãã«ã¡ã¿ã¢ã¯ãªã¬ãŒãã
ãšãã«ã¢ã¯ãªã¬ãŒããïœâãããã«ã¢ã¯ãªã¬ãŒ
ããïœâããã«ã¢ã¯ãªã¬ãŒããïœâããã«ã¡ã¿ã¢
ã¯ãªã¬ãŒããïŒâãšãã«ããã·ã«ã¢ã¯ãªã¬ãŒãã
ïœâããã·ã«ã¢ã¯ãªã¬ãŒãããªã¯ãã«ã¡ã¿ã¢ã¯ãª
ã¬ãŒããªã©ïŒãããã«ãšã¹ãã«é¡ïŒäŸãã°ããã«
ã¢ã»ããŒããã¢ã¯ãªããããªã«ãªã©ïŒãè³éŠæã
ãã«ååç©ïŒäŸãã°ã¹ãã¬ã³ãããã«ãã«ãšã³ã
ãžããã«ãã³ãŒã³ãªã©ïŒãããã«ã¢ã«ãã«ãšãŒã
ã«é¡ïŒäŸãã°ããã«ãã«ãšãŒãã«ããã¬ã€ã³é žãš
ã¹ãã«ãªã©ïŒãªã©ãããã æ¬çºæã«ããéåäœè¥ããã¯å ±éåäœã®çµæäŸ
ã以äžã«ç€ºãããæ¬çºæã¯ãããã«éå®ãããã
ã®ã§ã¯ãªãã äžè¬åŒïŒïŒåã¯ïŒïŒã®ç¹°è¿ãåäœãèªå°ã
ããåéäœã¯äžè¬ã«ãã¹ã«ãã³ã¢ãã眮æããã
ã¢ããããšããŒã«ãšãé žãã©ã€ãæ®åºãæã€ãšã
ã¬ã³æ§äžé£œååéäœãšã®ã¢ããååå¿ã«ããåæ
ããããšãã§ããã 次ã«ãæ¬çºæã«çšããåéäœã®åæäŸã瀺ãã åæäŸ ïŒ äŸç€ºååç©(1)ã®åæ 80mlã®ããªãžã³äžã«ã¢ããªã³(A)ïŒ15.4ïœïŒã溶
解ãæ¹æãããããžåºäœã®ã¹ã«ããã«ã¯ããªã(B)
ïŒ36.1ïœïŒãæ·»å ãããè¥å¹²ã®çºç±ã芳å¯ãããã
ãã®æ··åç©ãéæµæž©åºŠã§ïŒæéå ç±ããåŸã10å
éæŸå·ããã次ãã§æ¿å¡©é ž100mlãå«ãæ°·æ°Ž500ml
ãæ¹æããªãããã®äžãžè©²æ··åç©ãåŸã ã«æ³šã
ã ãæåºããçµæ¶ãåããæ°ŽæŽã也ç¥ããŠé»è²
çµæ¶(C)47ïœãåŸãã 200mlã®ã€ãœãããããŒã«äžã«ãããããšããŒ
ã«(C)ïŒ47ïœïŒãéå éïŒ25ïœïŒãå ¥ããæ¹æããª
ããå ç±ããŠéæµããããããã§æ¿å¡©é ž10mlã
åŸã ã«æ»Žäžãã30åæ¹æããåŸãæŸå·ããŠé ¢é žãš
ãã«300mlãïŒïŒ éæ¹æ°Ž300mlãå ããŠåºåœ¢åã
åãããé ¢é žãšãã«å±€ãå液ããæ°ŽæŽããåŸæ¿çž®
ããŠé»è€è²ã®ç²çµæ¶ãåŸãã掻æ§çåŠçåŸã¡ã¿ã
ãŒã«ããåçµæ¶ããŠæ·¡è¶è²çµæ¶(D)39ïœãåŸãã 80mlã®ããªãžã³äžã«ã¢ããªã³(D)ïŒ22.4ïœïŒãšã
ãããã³ãŒã³ïŒïŒmlïŒã溶解ã»æ¹æããããã«ã¹
ã«ããã«ã¯ããªã(E)ïŒ10.1ïœïŒãæ·»å ããããã®
æ··åç©ã60âã§ïŒæéå ç±ããåŸã10åéæŸå·ã
ãã次ãã§ãæ¿å¡©é ž100mlãå«ãæ°·æ°Ž500mlãæ¹æ
ããªãããã®äžãžè©²æ··åç©ãåŸã ã«æ³šãã ãæåº
ããçµæ¶ãåããæ°ŽæŽã也ç¥åŸç²Ÿè£œããŠæ·¡è€è²
çµæ¶(F)19ïœãåŸãã C32H42N2O6OsãšããŠã® èšç®å€ ïŒ62.51 ïŒ6.88 ïŒ4.56 å®æž¬å€ ïŒ62.30 ïŒ6.69 ïŒ4.48 次ã«ãæ¬çºæã«çšããéåäœåã¯å ±éåäœã®å
æäŸã瀺ãã åæäŸ ïŒ äŸç€ºååç©(ã)ã®åæ äŸç€ºååç©ïŒ22ïŒ30ïœãšããã«ã¢ã¯ãªã¬ãŒã10
ïœããžãªããµã³200mläžã«æº¶è§£ãããç³»ã70âã«
ææž©ããåŸãã¢ãŸãã¹ã€ãœé ªé žã¡ãã«0.4ïœãå
ãããïŒæéæ¹æåŸããã«ã¢ãŸãã¹ã€ãœé ªé žã¡ã
ã«0.4ïœãå ãããïŒæéæ¹æåŸæŽã«ã¢ãŸãã¹ã€
ãœé ªé žã¡ãã«0.4ïœãå ãã100âã«ææž©ããŠïŒæ
éæ¹æãããæŸå·åŸæ°·æ°ŽïŒã«ç³»ã滎äžããŠãã
åã也ç¥ããããšã§çœè²ã®ããªããŒ37ïœãåŸ
ãã æ¬çºæã®éåäœåã¯å ±éåäœãšè²æ¿ãé²æ¢å€ãš
ããŠäžéå±€ã«çšããå Žåã«ã¯ãäžè¬åŒïŒïŒåã¯
ïŒïŒã§ããããããç¹°è¿ãåäœã®ã¹ã«ãã³ã¢ã
ãããšããŒã«æ®åºã®åœéãïŒå±€åœã1.0Ã10-3ã
1.0Ã10-5ã¢ã«ïŒm2ã§çšããã®ã奜ãŸããããŸã
è²ã«ããªé²æ¢å€ãšããŠä¹³å€å±€ã«çšããå Žåã«ã¯ã
äžå±€åœã1.0Ã10-4ã1.0Ã10-6ã¢ã«ïŒm2ã§çšãã
ã®ã奜ãŸãããããã«éå®ããããã®ã§ã¯ãªãã
ããã«ãè²æ¿ãé²æ¢ãšè²ã«ããªé²æ¢ãšãå ŒããŠäž
éå±€ãä¹³å€å±€äž¡æ¹ã®å±€ã«å ããããšãå¯èœã§ã
ãã æ¬çºæã®éåäœåã¯å ±éåäœã¯é«æ¿åºŠã®ã¹ã«ã
ã³ã¢ããããšããŒã«æ®åºãå«ãããšãã§ãããŒã©
ãã³æ°Žæº¶æ¶²ã®ç²åºŠå¢å ãå°ãªããããèå±€åãã
ãææãæ§æããã®ã«é©ããã æ¬çºæã®éåäœåã¯å ±éåäœã¯ã奜ãŸããã¯æ°Ž
ã«åæ£ããããããããããªããŒã©ããã¯ã¹ã®åœ¢
æ ã§ãå¡åžæ¶²ïŒå€ãã®å ŽåãŒã©ãã³æ°Žæº¶æ¶²ïŒäžã«
æ·»å ãããå¡åžãããã æ¬çºæã®ååç©ã®ä¹³å€å±€ãäžéå±€ãªã©ã®æ§æå±€
ã«å°å ¥ããã«ã¯ã«ãã©ãŒãä¹³å€å±€ã«å°å ¥ããã«é
ããŠäœ¿ãããå ¬ç¥ã®æ¹æ³ãå¿çšããããšãã§ã
ããããšãã°ãã¿ãŒã«é žã¢ã«ãã«ãšã¹ãã«ïŒãžã
ãã«ãã¿ã¬ãŒãããžãªã¯ãã«ãã¿ã¬ãŒããªã©ïŒã
ãªã³é žãšã¹ãã«ïŒãžããšãã«ããªã¹ããšãŒããã
ãªããšãã«ããªã¹ããšãŒããããªã¯ã¬ãžã«ããªã¹
ããšãŒãããžãªã¯ãã«ããã«ããªã¹ããšãŒãïŒã
ã¯ãšã³é žãšã¹ãã«ïŒããšãã°ã¢ã»ãã«ã¯ãšã³é žã
ãªããã«ïŒãå®æ¯éŠé žãšã¹ãã«ïŒããšãã°å®æ¯éŠ
é žãªã¯ãã«ïŒãã¢ã«ãã«ã¢ããïŒããšãã°ãžãšã
ã«ã©ãŠãªã«ã¢ããïŒãèèªé žãšã¹ãã«é¡ïŒããšã
ã°ãžãããã·ãšãã«ãµã¯ã·ããŒãããžãªã¯ãã«ã¢
ãŒã¬ãŒãïŒãããªã¡ã·ã³é žãšã¹ãã«é¡ïŒããšãã°
ããªã¡ã·ã³é žããªããã«ïŒãªã©ããŸãã¯æ²žç¹çŽ30
âä¹è³150âã®ææ©æº¶åªãããšãã°é ¢é žãšãã«ã
é ¢é žããã«ã®ããšãäœçŽã¢ã«ãã«ã¢ã»ããŒããã
ãããªã³é žãšãã«ãïŒçŽããã«ã¢ã«ã³ãŒã«ãã¡ã
ã«ã€ãœããã«ã±ãã³ãβâãšããã·ãšãã«ã¢ã»ã
ãŒããã¡ãã«ã»ããŸã«ãã¢ã»ããŒãçã®æº¶è§£ãã
ã®ã¡ã芪氎æ§ã³ãã€ãã«åæ£ããããäžèšã®é«æ²ž
ç¹ææ©æº¶åªãšäœæ²žç¹ææ©æº¶åªãšãæ··åããŠçšããŠ
ãããã æ¬çºæã®è²æ±æé²æ¢å€ã¯ãçºè²çŸååŠçã«ãã
ãŠè³éŠæïŒçŽã¢ãã³çŸåè¬ïŒäŸãã°ããšãã¬ã³ãž
ã¢ãã³èªå°äœãã¢ããããšããŒã«èªå°äœãªã©ïŒãš
è²åœ¢æã«ãã©ãŒãšã®é žåã«ãããªã³ã°ã«ãã€ãŠè²
åã圢æããã¿ã€ãã®ããã²ã³åéã«ã©ãŒåçæ
å ææïŒäŸãã°ã«ã©ãŒããŒããŒãã«ã©ãŒãã¬ãã€
ã«ã ãã«ã©ãŒãªããŒãµã«ãã€ã«ã ãªã©ïŒã®è²æ±æ
é²æ¢ã«èå¹ã瀺ãã ãã®ã¿ã€ãã®ã«ã©ãŒåçæå ææã«çšãããã
è²åœ¢æã«ãã©ãŒãšããŠã¯ãäŸãã°ããŒã³ã¿ã«ãã©
ãŒãšããŠïŒâãã©ãŸãã³ã«ãã©ãŒããã©ãŸããã³
ãã€ãããŸãŒã«ã«ãã©ãŒãã·ã¢ãã¢ã»ãã«ã¯ãã
ã³ã«ãã©ãŒãééã¢ã·ã«ã¢ã»ããããªã«ã«ãã©ãŒ
çããããã€ãšããŒã«ãã©ãŒãšããŠãã¢ã·ã«ã¢ã»
ãã¢ããã«ãã©ãŒïŒäŸãã°ãã³ãŸã€ã«ã¢ã»ãã¢ã
ãªãé¡ããããã€ã«ã¢ã»ãã¢ããªãé¡ïŒãçãã
ããã·ã¢ã³ã«ãã©ãŒãšããŠãããããŒã«ã«ãã©
ãŒãããã³ããšããŒã«ã«ãã©ãŒãçãããããã
ãã®ã«ãã©ãŒã¯ååäžã«ãã©ã¹ãåºãšãã°ããç
æ°Žæ§åºãå°å ¥ããããããªããŒéã«çµåãããã
ããŠéæ¡æ£åããããšãã§ãã奜ãŸãã䜿çšãã
ãã ã«ãã©ãŒã¯éã€ãªã³ã«å¯ŸãïŒåœéæ§ãããã¯ïŒ
åœéæ§ã®ã©ã¡ãã§ãããããŸãè²è£æ£ã®å¹æãã
ã€ã«ã©ãŒãã«ãã©ãŒããããã¯çŸåã«ãšããªã€ãŠ
çŸåæå¶å€ãæŸåºããã«ãã©ãŒïŒããããDIRã«
ãã©ãŒïŒã§ãã€ãŠãããã ããŒã³ã¿çºè²ã«ãã©ãŒã®å ·äœäŸã¯ãç±³åœç¹èš±
2600788å·ãå2983608å·ãå3062653å·ãå
3127269å·ãå3311476å·ãå3419391å·ãå
3519429å·ãå3558319å·ãå3582322å·ãå
3615506å·ãå3834908å·ãå3891445å·ã西ç¬ç¹
èš±1810464å·ã西ç¬ç¹èš±åºé¡ïŒOLSïŒ2408665å·ã
å2417945å·ãå2418959å·ãå2424467å·ãç¹å ¬
æ40â6031å·ãç¹éæ51â20826å·ãå52â58922
å·ãå49â129538å·ãå49â74027å·ãå50â
159336å·ãå52â42121å·ãå49â74028å·ãå50
â60233å·ãå51â26541å·ãå53â55122å·ãªã©
ã«èšèŒã®ãã®ã§ããã é»è²çºè²ã«ãã©ãŒã®å ·äœäŸã¯ç±³åœç¹èš±2875057
å·ãå3265506å·ãå3408194å·ãå3551155å·ã
å3582322å·ãå3725072å·ãå3891445å·ã西ç¬
ç¹èš±1547868å·ã西ç¬åºé¡å ¬é2219917å·ãå
2261361å·ãå2414006å·ãè±åœç¹èš±1425020å·ã
ç¹å ¬æ51â10783å·ãç¹éæ47â26133å·ãå48â
73147å·ãå51â102636å·ãå50â6341å·ãå50
â123342å·ãå50â130442å·ãå51â21827å·ã
å50â87650å·ãå52â82424å·ãå52â115219å·
ãªã©ã«èšèŒããããã®ã§ããã ã·ã¢ã³ã«ãã©ãŒã®å ·äœäŸã¯ç±³åœç¹èš±2369929å·ã
å2434272å·ãå2474293å·ãå2521908å·ãå
2895826å·ãå3034892å·ãå3311476å·ãå
3458315å·ãå3476563å·ãå3583971å·ãå
3591383å·ãå3767411å·ãå4004929å·ã西ç¬ç¹
èš±åºé¡ïŒOLSïŒ2414830å·ãå2454329å·ãç¹é
æ48â59838å·ãå51â26034å·ãå48â5055å·ã
å51â146828å·ãå52â69624å·ãå52â90932å·
ã«èšèŒã®ãã®ã§ããã ã«ã©ãŒãã»ã«ãã©ãŒãšããŠã¯äŸãã°ç±³åœç¹èš±
3476560å·ãå2521908å·ãå3034892å·ãç¹å ¬æ
44â2016å·ãå38â22335å·ãå42â11304å·ãå
44â32461å·ãç¹éæ51â26034å·æ现æžãå52â
42121å·æ现æžã西ç¬ç¹èš±åºé¡ïŒOLSïŒ2418959
å·ã«èšèŒã®ãã®ã䜿çšã§ããã DIRã«ãã©ãŒãšããŠã¯ãããšãã°ç±³åœç¹èš±
3227554å·ãå3617291å·ãå3701783å·ãå
3790384å·ãå3632345å·ã西ç¬ç¹èš±åºé¡ïŒOLSïŒ
2414006å·ãå2454301å·ãå2454329å·ãè±åœç¹
èš±953454å·ãç¹éæ52â69624å·ãå49â122335
å·ãç¹å ¬æ51â16141å·ã«èšèŒããããã®ã䜿çš
ã§ããã æ¬çºæã®è²æ±æé²æ¢å€ã¯ãŸãããããæ¡æ£è»¢å
åã®ããã²ã³åéã«ã©ãŒåçæå ææã®è²æ±æã
é²æ¢ããã®ã«æçšã§ãããã®åã®ææã«çšããã
ãè²çŽ å圢æååç©ãšããŠã¯äŸãã°è²çŽ çŸåè¬ã
è²çŽ æŸåºã¬ããã¯ã¹ååç©ãDDRã«ãã©ãŒãªã©
ããããå ·äœçã«ã¯äŸãã°ç±³åœç¹èš±4053312å·ã
å4055428å·ãå4076529å·ãå4152153å·ãå
4135929å·ãç¹éæ53â149328å·ãå51â104343
å·ãå53â46730å·ãå54â130122å·ãå53â
3819å·ãç¹é¡æ54â89128å·ãå54â90806å·ãå
54â91187å·ãçã«èšèŒã®ååç©ãçšããããšã
ã§ããã æ¬çºæã®ååç©ã¯ãå ¬ç¥ã®è²æ±æé²æ¢å€ãäŸã
ã°ãã€ããããã³èªå°äœãã¢ããããšããŒã«èªå°
äœã没é£åé žèªå°äœãã¢ã¹ã³ã«ãã³é žèªå°äœãªã©
ãšäœµçšããŠãããã ãã®å ·äœäŸã¯ç±³åœç¹èš±2360290å·ãå2336327
å·ãå2403721å·ãå2418613å·ãå2675314å·ã
å2701197å·ãå2704713å·ãå2728659å·ãå
2732300å·ãå2735365å·ãç¹éæ50â92988å·ã
å50â92989å·ãå50â93928å·ãå50â110337
å·ãå52â146235å·ãç¹å ¬æ50â23813å·çã«èš
èŒãããŠããã æ¬çºæã®æå ææã«ã¯èŠªæ°Žæ§ã³ãã€ãå±€ã«çŽ«å€
ç·åžåå€ãå«ãã§ãããããšãã°ã¢ãªãŒã«åºã§çœ®
æããããã³ãŸããªã¢ãŸãŒã«ååç©ãïŒâãã¢ãŸ
ãªãã³ååç©ããã³ãŸããšãã³ååç©ãæ¡ç®é žãš
ã¹ãã«ååç©ããã¿ãžãšã³ååç©ããã³ãŸãªããµ
ãŸãŒã«ååç©ãããã«çŽ«å€ç·åžåæ§ã®ããªããŒãª
ã©ãçšããããšãã§ããããããã®çŽ«å€ç·åžåå€
ã¯ãäžèšèŠªæ°Žæ§ã³ãã€ãå±€äžã«åºå®ãããŠãã
ãã ãã®ä»ãæ¬çºæã®ã«ã©ãŒææã«çšããããšã®ã§
ããåçããã²ã³åéä¹³å€ããã³ãã®èª¿è£œæ³ãªã
ã³ã«åçæ·»å å€ïŒãŸãã¯åççšçŽ æïŒãªã©ã«ã€ã
ãŠã¯ããResearch DisclosureãèªãNo.176ïŒ1978
幎11æïŒ22ã31é ã«èšèŒããããä¹³å€ã®èª¿è£œãšã¿
ã€ããããä¹³å€ã®æ°ŽæŽãããååŠå¢æãããã«ããªé²æ¢
å€ããã³å®å®å€ããã硬èå€ãããæ¯æäœãããå¯å¡å€
ããã³æœ€æ»å€ãããå¡åžå©å€ããããããå€ãããå¢æ
å€ãããåå å¢æå€ãããæ·»å æ¹æ³ãããåžåããã³ã
ã€ã«ã¿ãŒææãããå¡åžæ¹æ³ããªã©ãé©çšããã
ãšãã§ããã ã«ã©ãŒç»å圢æã®ããã«ã¯ãã¬ããžæ³ïŒäŸãã°
âJournal of the Society of Motion Picture
and Television Engineersâ61å·»ïŒ1953幎ïŒã
667ã701é ã«èšèŒãããŠããïŒãé»çœçŸåäž»è¬ã
å«ãçŸå液ã§çŸåããŠãã¬éåãã€ãããã€ãã§
å°ãªããšãäžåã®äžæ§ãªé²å ãŸãã¯ä»ã®é©åœãªã«
ããªåŠçãè¡ãªããåŒãç¶ããŠçºè²çŸåãè¡ãªã
ããšã«ããè²çŽ éœç»åãåŸãã«ã©ãŒå転æ³ãè²çŽ
ãå«ãåçä¹³å€å±€ããé²å åŸçŸåããŠéç»åãã€
ããããããæŒçœè§ŠåªãšããŠè²çŽ ãæŒçœããéè²
çŽ æŒçœæ³ãªã©ãçšããããã ã«ã©ãŒçŸå液ã¯ãäžè¬ã«çºè²çŸåäž»è¬ãå«ãã¢
ã«ã«ãªæ§æ°Žæº¶æ¶²ããæããçºè²çŸåäž»è¬ã¯å ¬ç¥ã®
äžçŽè³éŠæã¢ãã³çŸåå€ãäŸãã°ããšãã¬ã³ãžã¢
ãã³é¡ïŒäŸãã°ïŒâã¢ããâïŒïŒ®âãžãšãã«ã¢
ããªã³ãïŒâã¡ãã«âïŒâã¢ããâïŒïŒ®âãžãš
ãã«ã¢ããªã³ãïŒâã¢ããââãšãã«ââβ
âããããã·ãšãã«ã¢ããªã³ãïŒâã¡ãã«âïŒâ
ã¢ããââãšãã«ââβâããããã·ãšãã«
ã¢ããªã³ãïŒâã¡ãã«âïŒâã¢ããââãšãã«
ââβâã¡ã¿ã³ã¹ã«ãã¢ãããšãã«ã¢ããªã³ã
ïŒâã¢ããâïŒâã¡ãã«ââãšãã«ââβâ
ã¡ããã·ãšãã«ã¢ããªã³ãªã©ïŒãçšããããšã§ã
ãã ãã®ä»L.F.A.MasonèPhotographic
Processing ChemistryïŒFocal Pressåã1966幎ïŒ
ã®226ã229é ãç±³åœç¹èš±2193015å·ãå2592364
å·ãç¹éæ48â64933å·ãªã©ã«èšèŒã®ãã®ãçšã
ãŠããã ã«ã©ãŒçŸå液ã¯ãã®ã»ãã¢ã«ã«ãªéå±ã®äºç¡«é ž
å¡©ãçé žå¡©ãããŠé žå¡©ããã³ãªã³é žå¡©ã®åŠãPHã
ç·©è¡å€ãèåç©ãæ²åç©ããã³ææ©ã«ããªé²æ¢å€
ã®åŠãçŸåæå¶å€ãªããã«ããªé²æ¢å€ãªã©ãå«ã
ããšãã§ããããŸãå¿ èŠã«å¿ããŠã硬氎è»åå€ã
ããããã·ã«ã¢ãã³ã®åŠãä¿æå€ããã³ãžã«ã¢ã«
ã³ãŒã«ããžãšãã¬ã³ã°ãªã³ãŒã«ã®åŠãææ©æº¶å€ã
ããªãšãã¬ã³ã°ãªã³ãŒã«ãåçŽã¢ã³ã¢ããŠã å¡©ã
ã¢ãã³é¡ã®åŠãçŸåä¿é²å€ãè²çŽ 圢æã«ãã©ãŒã
競äºã«ãã©ãŒããããªãŠã ãããã€ãã©ã€ãã®åŠ
ããã¶ããå€ãïŒâããšãã«âïŒâãã©ãŸãªãã³
ã®åŠãè£å©çŸåè¬ãç²æ§ä»äžå€ãç±³åœç¹èš±
4083723å·ã«èšèŒã®ããªã«ã«ãã³é žç³»ãã¬ãŒãå€ã
西ç¬å ¬éïŒOLSïŒ2622950å·ã«èšèŒã®é žåé²æ¢å€
ãªã©ãå«ãã§ãããã çºè²çŸååŸã®åçä¹³å€å±€ã¯éåžžãæŒçœåŠçãã
ããæŒçœåŠçã¯å®çåŠçãšåæã«è¡ãªãããŠãã
ãããåå¥ã«è¡ãªãããŠããããæŒçœå€ãšããŠã¯
éïŒïŒãã³ãã«ãïŒïŒãã¯ãã ïŒïŒãé ïŒïŒ
ãªã©ã®å€äŸ¡éå±ã®ååç©ãéé žé¡ãããã³é¡ãã
ãããœååç©ãªã©ãçšãããããããšãã°ããšãª
ã·ã¢ã³åç©ãéã¯ãã é žå¡©ãéïŒïŒãŸãã¯ã³ã
ã«ãïŒïŒã®ææ©é¯å¡©ãããšãã°ãšãã¬ã³ãžã¢ã
ã³åé ¢é žããããªãããªé ¢é žãïŒïŒïŒâãžã¢ãã
âïŒâãããããŒã«åé ¢é žãªã©ã®ã¢ããããªã«ã«
ãã³é žé¡ãããã¯ã¯ãšã³é žãé ç³é žããªã³ãŽé žãª
ã©ã®ææ©é žã®é¯å¡©ïŒéç¡«é žå¡©ãéãã³ã¬ã³é žå¡©ïŒ
ããããœããšããŒã«ãªã©ãçšããããšãã§ããã
ãããã®ãã¡ããšãªã·ã¢ã³åã«ãªããšãã¬ã³ãžã¢
ãã³åé ¢é žéïŒïŒãããªãŠã ããã³ãšãã¬ã³ãž
ã¢ãã³åé ¢é žéïŒïŒã¢ã³ã¢ããŠã ã¯ç¹ã«æçšã§
ããããšãã¬ã³ãžã¢ãã³åé ¢é žéïŒïŒé¯å¡©ã¯ç¬
ç«ã®æŒçœæ¶²ã«ãããŠããäžæµŽæŒçœå®ç液ã«ãããŠ
ãæçšã§ããã æŒçœãŸãã¯æŒçœå®ç液ã«ã¯ãç±³åœç¹èš±3042520
å·ãå3241966å·ãç¹å ¬æ45â8506å·ãç¹å ¬æ45
â8836å·ãªã©ã«èšèŒã®æŒçœä¿é²å€ãç¹éæ53â
65732å·ã«èšèŒã®ããªãŒã«ååç©ã®ä»ãçš®ã ã®æ·»
å å€ãå ããããšãã§ããã æ¬çºæãæ¡æ£è»¢åæ³ã«çšããå Žåã¯ç²æ§çŸå液
ã§åŠçããããšãã§ããã ãã®ç²æ§çŸå液ã¯ããã²ã³åéä¹³å€ã®çŸåãšæ¡
æ£è»¢åè²çŽ åã®åœ¢æãšã«å¿ èŠãªåŠçæåãå«æã
ã液ç¶çµæç©ã§ãã€ãŠã溶åªã®äž»äœã¯æ°Žã§ããã
ä»ã«ã¡ã¿ããŒã«ãã¡ãã«ã»ããœã«ãã®åŠã芪氎æ§
溶åªãå«ãããšããããåŠççµæç©ã¯ãä¹³å€å±€ã®
çŸåãèµ·ãããã«å¿ èŠãªPHãç¶æããçŸåãšè²çŽ
å圢æã®è«žéçšäžã«çæããé žïŒäŸãã°èåæ°ŽçŽ
é žçã®ããã²ã³åæ°ŽçŽ é žãé ¢é žçã®ã«ã«ãã³é ž
çïŒãäžåããã«è¶³ããéã®ã¢ã«ã«ãªãå«æããŠ
ãããã¢ã«ã«ãªãšããŠã¯æ°Žé žåãªããŠã ãæ°Žé žå
ãããªãŠã ãæ°Žé žåã«ãªãŠã ãæ°Žé žåã«ã«ã·ãŠã
åæ£ç©ãæ°Žé žåããã©ã¡ãã«ã¢ã³ã¢ããŠã ãçé ž
ãããªãŠã ããªã³é žïŒãããªãŠã ããžãšãã«ã¢ã
ã³çã®ã¢ã«ã«ãªéå±ãããã¯ã¢ã«ã«ãªåé¡éå±
å¡©ãåã¯ã¢ãã³é¡ã䜿çšããã奜ãŸããã¯å®€æž©ã«
ãããŠçŽ12以äžã®PHããã€ãç¹ã«PH14以äžãšãªã
ãããªæ¿åºŠã®èæ§ã¢ã«ã«ãªãå«æãããããšãæ
ãŸãããããã«å¥œãŸããã¯åŠççµæç©ã¯é«ååé
ã®ããªããã«ã¢ã«ã³ãŒã«ãããããã·ãšãã«ã»ã«
ããŒãºããããªãŠã ã«ã«ããã·ã¡ãã«ã»ã«ããŒãº
ã®åŠã芪氎æ§ããªããŒãå«æããŠããããããã®
ããªããŒã¯åŠççµæç©ã«å®€æž©ã§ïŒãã€ã¹ä»¥äžã奜
ãŸããã¯æ°çŸïŒ500ã600ïŒä¹è³1000ãã€ã¹çšåºŠã®
ç²åºŠãäžããããã«çšãããšããã 以äžã«å®æœäŸãæ²ãæ¬çºæãæŽã«è©³çŽ°ã«èª¬æã
ãã å®æœäŸ ïŒ ãã€ã«ã  ããªãšãã¬ã³ã§äž¡é¢è¢«èŠããããã©ã€ã¿çŽæ¯æ
äœäžã«ã第ïŒå±€ãšããŠã€ãšããŒã«ãã©ãŒÎ±âãã
ãã€ã«âαïŒïŒïŒïŒâãžãªããœâïŒïŒ5â²âãžã¡ã
ã«ãªããµãŸãªãžã³âïŒâã€ã«ïŒâïŒâã¯ããâïŒ
âãαâïŒïŒïŒïŒâãžâtertâãã³ãã«ããšãã
ã·ïŒãã¿ã³ã¢ãããã¢ã»ãã¢ããªããå«æããé
ææ§å¡©èåéä¹³å€å±€ã3.0ÎŒã®åãã«å¡åžïŒã«ãã©
ãŒå¡åžé0.646Ã10-3ã¢ã«ïŒm2ãå¡åžéé3.88Ã
10-3ã¢ã«ïŒm2ãèåé70ã¢ã«ïŒ ãå¡©åé30ã¢ã«
ïŒ ïŒãããã®äžã«ç¬¬ïŒå±€ãšããŠãŒã©ãã³å±€ã1.5ÎŒ
ã®åãã«å¡åžããã æŽã«ç¬¬ïŒå±€ãšããŠããŒã³ã¿ã«ãã©ãŒïŒâïŒïŒïŒ
ïŒïŒïŒâããªã¯ããããšãã«ïŒâïŒâïœïŒâã¯ã
ãâïŒïŒâããã©ãã«ã³ã¢ããïŒã¢ããªãïœâïŒ
âãã©ãŸãã³ãå«æãããŒã©ãã³å±€ã3.1ÎŒã®åã
ã«å¡åžããïŒã«ãã©ãŒå¡åžé0.500Ã10-3ã¢ã«ïŒ
m2 ãã€ã«ã  äžèšãã€ã«ã ã«æŒããŠã第ïŒå±€ã«ïŒïŒïŒâãž
ãªã¯ãã«ãã€ããããã³ãå«ã以å€ã¯ãã€ã«ã 
ãšåãïŒãã€ããããã³å¡åžé1.59Ã10-4ã¢ã«ïŒ
m2ïŒã«ããŠãã€ã«ã ãäœè£œããã ãŸãã次ã®ãããªãã€ã«ã ããäœè£œããã ãã€ã«ã  äžèšãã€ã«ã ã«æŒããŠç¬¬ïŒå±€ã«äŸç€ºååç©(ã€)
ã0.09ïœïŒm2ïŒã¹ã«ãã³ã¢ããããšããŒã«æ®åºãš
ããŠ1.59Ã10-4ã¢ã«ïŒm2ïŒå«ã以å€ã¯ãã€ã«ã 
ãšåãã ãã€ã«ã  äžèšãã€ã«ã ã«æŒããŠç¬¬ïŒå±€ã«äŸç€ºååç©(ã)
ã0.106ïœïŒm2ïŒã¹ã«ãã³ã¢ããããšãŒã«æ®åºãš
ããŠ1.59Ã10-4ã¢ã«ïŒm2ïŒå«ã以å€ã¯ãã€ã«ã 
ãšåãã ãã€ã«ã  äžèšãã€ã«ã ã«æŒããŠç¬¬ïŒå±€ã«äŸç€ºååç©(ã)
ã0.053ïœïŒm2ïŒã¹ã«ãã³ã¢ããããšããŒã«æ®åº
ãšããŠ8.0Ã10-5ã¢ã«ïŒm2ïŒå«ã以å€ã¯ãã€ã«ã
ãšåãã ãã®æ§ã«ããŠäœè£œãããã€ã«ã ããé£ç¶ç
ã«ã°ã¬ã€æ¿åºŠãç°ãªããŠãšããžãä»ããŠé²å ãã
次ã®åŠçãè¡ãªã€ãã åŠçå·¥çš ã«ã©ãŒçŸååŠç ïŒå30ç§ 33â æŒçœå®çåŠç ïŒå30ç§ 33â æ°Ž æŽ ïŒå 28ã35â ã«ã©ãŒçŸå液 ãã³ãžã«ã¢ã«ã³ãŒã« 15ml ãžãšãã¬ã³ããªã¢ãã³ïŒé ¢é ž ïŒïœ KBr 0.4ïœ Na2SO3 ïŒïœ Na2CO3 30ïœ ããããã·ã«ã¢ãã³ç¡«é žå¡© ïŒïœ ïŒâã¢ããâïŒâã¡ãã«ââβâïŒã¡ã¿ã³ã¹
ã«ãã³ã¢ããïŒãšãã«ã¢ããªã³ã»ïŒïŒ
2H2SO4ã»H2O 4.5ïœ æ°Žã§1000mlã«ãã PH10.1 æŒçœå®ç液 ããªç¡«é žã¢ã³ã¢ããŠã ïŒ70wtïŒ ïŒ 150ml Na2SO3 ïŒïœ NaãFeïŒEDTAïŒã 40ïœ EDTA ïŒïœ æ°Žã§1000mlã«ãã PH6.8 åã çŸåããããµã³ãã«ãã°ãªãŒã³ãã€ã«ã¿ãŒ
ãçšããŠæ¿åºŠæž¬å®ããïŒããŒã³ã¿çºè²æ¿åºŠïŒãã€
ãšããŒæ倧çºè²æ¿åºŠã«æŒããããŒã³ã¿æ¿åºŠãšã€ãš
ããŒæäœçºè²æ¿åºŠã®ããŒã³ã¿æ¿åºŠãšã®å·®ãæ±ã
ãŠãã€ãšããŒçºè²éšã®ããŒã³ã¿æ··è²ã調ã¹ãã çµæã次衚ã«ç€ºãã
èçŽ ãªã©ïŒãã¢ã«ãã«åºïŒå¥œãŸããã¯ççŽ æ°ïŒã
ïŒã®ãã®ãäŸãã°ã¡ãã«åºããšãã«åºãªã©ïŒãè¡š
ããã ïœã¯ïŒåã¯ïŒã§ããã äžè¬åŒïŒïŒåã¯ïŒïŒã«ãããããšããŒã«ç°
äžã®çœ®æåºã¯ããããç°äžã®ãããã®äœçœ®ã«çœ®æ
ããŠããŠãããã äžè¬åŒïŒïŒåã¯ïŒïŒã§è¡šãããããã®ã®äž
ã§ããäžè¬åŒïŒïŒã§è¡šãããããã®ã奜ãŸã
ãã åèšäžè¬åŒïŒïŒã§è¡šããããç¹°ãè¿ãåäœã®
äžã§ã次ã®äžè¬åŒã§è¡šãããããã®ã奜ãŸããã ãããäžè¬åŒïŒïŒãïŒïŒã«ããããã
R1ãR6ãïœã¯äžè¬åŒïŒïŒã«ãããŠå®çŸ©ããã
ã®ãšåãã§ããã åèšäžè¬åŒïŒïŒãïŒïŒã«ãããŠãR1ã¯ã
ïŒïŒåã³ïŒïŒã®å Žåã«ã¯æ°ŽçŽ ååãããã²ã³
ååãã¢ã«ãã«åºãã¢ã«ã³ãã·åºãã¢ã«ãã«ããª
åºãã¢ã«ã³ãã·ã«ã«ããã«åºãã¢ãªãŒã«ããªåºã
ãããç°ããªåºãã¢ãªãŒããã·ã«ã«ããã«åºãã¢
ã·ã«åºãã¹ã«ããã«åºãã«ã«ãã¢ã€ã«åºã§ããã
ãšã奜ãŸãããïŒïŒãïŒïŒã®å Žåã«ã¯ãR1ã¯
æ°ŽçŽ ååãããã²ã³ååãã¢ã«ãã«åºãã¢ã·ã«ã¢
ããåºãã¢ã«ã³ãã·ã«ã«ããã«åºãã¢ãªãŒããã·
ã«ã«ããã«åºãã¹ã«ããã«åºãã¹ã«ãã¢ã¢ã€ã«ã¢
ããåºãã«ã«ãã¢ã€ã«ã¢ããåºãã¢ã·ã«åºãã«ã«
ãã¢ã€ã«åºã§ããããšã奜ãŸãããç¹ã«ã«ã©ãŒçŸ
åã«ãããçºè²çŸåäž»è¬ãšã®é žåã«ãããªã³ã°ã«
ããçºè²ãèµ·ãããªãåºïŒã¢ã«ãã«åºãã¢ã«ã³ã
ã·ã«ã«ããã«åºãã¹ã«ããã«åºãã¢ãªãŒããã·ã«
ã«ããã«åºãã¢ã·ã«åºãã«ã«ãã¢ã€ã«åºïŒã§ãã
ããšã奜ãŸããã åèšäžè¬åŒïŒïŒãïŒïŒã§è¡šããããç¹°ãè¿
ãåäœã®äžã§ãäžè¬åŒïŒïŒãïŒïŒã§è¡šããã
ããã®ã奜ãŸããã åèšäžè¬åŒïŒïŒãïŒïŒã«ãããR2ãR3ãš
ããŠã¯ã¢ãªãŒã«åºãã¢ã«ãã«åºã§ããå Žåãç¹ã«
奜ãŸããã äžè¬åŒïŒïŒãïŒïŒã«ãããããšããŠã¯
å ±ã«âSO2âã§ããå Žåãç¹ã«å¥œãŸããã äžè¬åŒïŒïŒãïŒïŒã®äžã§æã奜ãŸãããã®
ã¯äžè¬åŒïŒïŒåã¯ïŒïŒã§ããã æ¬çºæã§çšããéåäœè¥ããã¯å ±éåäœã¯ãå
èšäžè¬åŒïŒïŒåã¯ïŒïŒã®ç¹°ãè¿ãåäœã®ã¿ã
ããªããã®ã§ãã€ãŠããããäžè¬åŒïŒïŒãš
ïŒïŒã®åæ¹ã®ç¹°ãè¿ãåäœãããªãå ±éåäœã§
ãã€ãŠãããããŸãäžè¬åŒïŒïŒåã³ïŒåã¯
ïŒïŒã®ç¹°ãè¿ãåäœãšäžè¬åŒïŒïŒåã¯ïŒïŒ
以å€ã®ç¹°ãè¿ãåäœãå«æããå ±éåäœã§ãã€ãŠ
ãããããããéåäœè¥ããã¯å ±éåäœã¯äžè¬
ã«ãäžè¬åŒïŒïŒåã¯ïŒïŒã®ç¹°ãè¿ãåäœãèª
å°ãããåéäœã®åç¬éåãäžè¬åŒïŒïŒåã³
ïŒïŒã®ç¹°ãè¿ãåäœãèªå°ãããåéäœã©ãã
ã®å ±éåããŸãã¯ãããã®åéäœãšä»å éåãã
ãä»ã®ãšãã¬ã³æ§äžé£œååéäœãšã®å ±éåã«ãã€
ãŠåŸãããã äžè¬åŒïŒïŒåã¯ïŒïŒã®ç¹°ãè¿ãåäœãèªå°
ãããåéäœã®å ·äœäŸã以äžã«æããããæ¬çºæ
ã¯ããã«éå®ããããã®ã§ã¯ãªãã äžè¬åŒïŒïŒåã¯ïŒïŒã®ç¹°ãè¿ãåäœãèªå°
ãããåéäœãšä»å éåãããä»ã®ãšãã¬ã³æ§äž
飜ååéäœãšããŠã¯ãéå枩床ïŒäžè¬çã«ã¯50â
ã95âãæãŸããã¯70âã90âïŒã§æ¶²äœã§ããå š
ãŠã®æ°Žäžæº¶æ§åéäœãååçã«äœ¿çšã§ãããå ·äœ
çã«ã¯äŸãã°ãã¢ã¯ãªã«é žãαâã¯ããã¢ã¯ãªã«
é žãαâã¢ã«ã¢ã¯ãªã«é žïŒã¡ã¿ã¢ã¯ãªã«é žãªã©ïŒ
ãªã©ã®ã¢ã¯ãªã«é žé¡ããèªå°ããããšã¹ãã«ãã
ãã¯ã¢ããïŒäŸãã°ïœâããã«ã¢ã¯ãªã«ã¢ããã
ã¡ãã«ã¢ã¯ãªã¬ãŒããã¡ãã«ã¡ã¿ã¢ã¯ãªã¬ãŒãã
ãšãã«ã¢ã¯ãªã¬ãŒããïœâãããã«ã¢ã¯ãªã¬ãŒ
ããïœâããã«ã¢ã¯ãªã¬ãŒããïœâããã«ã¡ã¿ã¢
ã¯ãªã¬ãŒããïŒâãšãã«ããã·ã«ã¢ã¯ãªã¬ãŒãã
ïœâããã·ã«ã¢ã¯ãªã¬ãŒãããªã¯ãã«ã¡ã¿ã¢ã¯ãª
ã¬ãŒããªã©ïŒãããã«ãšã¹ãã«é¡ïŒäŸãã°ããã«
ã¢ã»ããŒããã¢ã¯ãªããããªã«ãªã©ïŒãè³éŠæã
ãã«ååç©ïŒäŸãã°ã¹ãã¬ã³ãããã«ãã«ãšã³ã
ãžããã«ãã³ãŒã³ãªã©ïŒãããã«ã¢ã«ãã«ãšãŒã
ã«é¡ïŒäŸãã°ããã«ãã«ãšãŒãã«ããã¬ã€ã³é žãš
ã¹ãã«ãªã©ïŒãªã©ãããã æ¬çºæã«ããéåäœè¥ããã¯å ±éåäœã®çµæäŸ
ã以äžã«ç€ºãããæ¬çºæã¯ãããã«éå®ãããã
ã®ã§ã¯ãªãã äžè¬åŒïŒïŒåã¯ïŒïŒã®ç¹°è¿ãåäœãèªå°ã
ããåéäœã¯äžè¬ã«ãã¹ã«ãã³ã¢ãã眮æããã
ã¢ããããšããŒã«ãšãé žãã©ã€ãæ®åºãæã€ãšã
ã¬ã³æ§äžé£œååéäœãšã®ã¢ããååå¿ã«ããåæ
ããããšãã§ããã 次ã«ãæ¬çºæã«çšããåéäœã®åæäŸã瀺ãã åæäŸ ïŒ äŸç€ºååç©(1)ã®åæ 80mlã®ããªãžã³äžã«ã¢ããªã³(A)ïŒ15.4ïœïŒã溶
解ãæ¹æãããããžåºäœã®ã¹ã«ããã«ã¯ããªã(B)
ïŒ36.1ïœïŒãæ·»å ãããè¥å¹²ã®çºç±ã芳å¯ãããã
ãã®æ··åç©ãéæµæž©åºŠã§ïŒæéå ç±ããåŸã10å
éæŸå·ããã次ãã§æ¿å¡©é ž100mlãå«ãæ°·æ°Ž500ml
ãæ¹æããªãããã®äžãžè©²æ··åç©ãåŸã ã«æ³šã
ã ãæåºããçµæ¶ãåããæ°ŽæŽã也ç¥ããŠé»è²
çµæ¶(C)47ïœãåŸãã 200mlã®ã€ãœãããããŒã«äžã«ãããããšããŒ
ã«(C)ïŒ47ïœïŒãéå éïŒ25ïœïŒãå ¥ããæ¹æããª
ããå ç±ããŠéæµããããããã§æ¿å¡©é ž10mlã
åŸã ã«æ»Žäžãã30åæ¹æããåŸãæŸå·ããŠé ¢é žãš
ãã«300mlãïŒïŒ éæ¹æ°Ž300mlãå ããŠåºåœ¢åã
åãããé ¢é žãšãã«å±€ãå液ããæ°ŽæŽããåŸæ¿çž®
ããŠé»è€è²ã®ç²çµæ¶ãåŸãã掻æ§çåŠçåŸã¡ã¿ã
ãŒã«ããåçµæ¶ããŠæ·¡è¶è²çµæ¶(D)39ïœãåŸãã 80mlã®ããªãžã³äžã«ã¢ããªã³(D)ïŒ22.4ïœïŒãšã
ãããã³ãŒã³ïŒïŒmlïŒã溶解ã»æ¹æããããã«ã¹
ã«ããã«ã¯ããªã(E)ïŒ10.1ïœïŒãæ·»å ããããã®
æ··åç©ã60âã§ïŒæéå ç±ããåŸã10åéæŸå·ã
ãã次ãã§ãæ¿å¡©é ž100mlãå«ãæ°·æ°Ž500mlãæ¹æ
ããªãããã®äžãžè©²æ··åç©ãåŸã ã«æ³šãã ãæåº
ããçµæ¶ãåããæ°ŽæŽã也ç¥åŸç²Ÿè£œããŠæ·¡è€è²
çµæ¶(F)19ïœãåŸãã C32H42N2O6OsãšããŠã® èšç®å€ ïŒ62.51 ïŒ6.88 ïŒ4.56 å®æž¬å€ ïŒ62.30 ïŒ6.69 ïŒ4.48 次ã«ãæ¬çºæã«çšããéåäœåã¯å ±éåäœã®å
æäŸã瀺ãã åæäŸ ïŒ äŸç€ºååç©(ã)ã®åæ äŸç€ºååç©ïŒ22ïŒ30ïœãšããã«ã¢ã¯ãªã¬ãŒã10
ïœããžãªããµã³200mläžã«æº¶è§£ãããç³»ã70âã«
ææž©ããåŸãã¢ãŸãã¹ã€ãœé ªé žã¡ãã«0.4ïœãå
ãããïŒæéæ¹æåŸããã«ã¢ãŸãã¹ã€ãœé ªé žã¡ã
ã«0.4ïœãå ãããïŒæéæ¹æåŸæŽã«ã¢ãŸãã¹ã€
ãœé ªé žã¡ãã«0.4ïœãå ãã100âã«ææž©ããŠïŒæ
éæ¹æãããæŸå·åŸæ°·æ°ŽïŒã«ç³»ã滎äžããŠãã
åã也ç¥ããããšã§çœè²ã®ããªããŒ37ïœãåŸ
ãã æ¬çºæã®éåäœåã¯å ±éåäœãšè²æ¿ãé²æ¢å€ãš
ããŠäžéå±€ã«çšããå Žåã«ã¯ãäžè¬åŒïŒïŒåã¯
ïŒïŒã§ããããããç¹°è¿ãåäœã®ã¹ã«ãã³ã¢ã
ãããšããŒã«æ®åºã®åœéãïŒå±€åœã1.0Ã10-3ã
1.0Ã10-5ã¢ã«ïŒm2ã§çšããã®ã奜ãŸããããŸã
è²ã«ããªé²æ¢å€ãšããŠä¹³å€å±€ã«çšããå Žåã«ã¯ã
äžå±€åœã1.0Ã10-4ã1.0Ã10-6ã¢ã«ïŒm2ã§çšãã
ã®ã奜ãŸãããããã«éå®ããããã®ã§ã¯ãªãã
ããã«ãè²æ¿ãé²æ¢ãšè²ã«ããªé²æ¢ãšãå ŒããŠäž
éå±€ãä¹³å€å±€äž¡æ¹ã®å±€ã«å ããããšãå¯èœã§ã
ãã æ¬çºæã®éåäœåã¯å ±éåäœã¯é«æ¿åºŠã®ã¹ã«ã
ã³ã¢ããããšããŒã«æ®åºãå«ãããšãã§ãããŒã©
ãã³æ°Žæº¶æ¶²ã®ç²åºŠå¢å ãå°ãªããããèå±€åãã
ãææãæ§æããã®ã«é©ããã æ¬çºæã®éåäœåã¯å ±éåäœã¯ã奜ãŸããã¯æ°Ž
ã«åæ£ããããããããããªããŒã©ããã¯ã¹ã®åœ¢
æ ã§ãå¡åžæ¶²ïŒå€ãã®å ŽåãŒã©ãã³æ°Žæº¶æ¶²ïŒäžã«
æ·»å ãããå¡åžãããã æ¬çºæã®ååç©ã®ä¹³å€å±€ãäžéå±€ãªã©ã®æ§æå±€
ã«å°å ¥ããã«ã¯ã«ãã©ãŒãä¹³å€å±€ã«å°å ¥ããã«é
ããŠäœ¿ãããå ¬ç¥ã®æ¹æ³ãå¿çšããããšãã§ã
ããããšãã°ãã¿ãŒã«é žã¢ã«ãã«ãšã¹ãã«ïŒãžã
ãã«ãã¿ã¬ãŒãããžãªã¯ãã«ãã¿ã¬ãŒããªã©ïŒã
ãªã³é žãšã¹ãã«ïŒãžããšãã«ããªã¹ããšãŒããã
ãªããšãã«ããªã¹ããšãŒããããªã¯ã¬ãžã«ããªã¹
ããšãŒãããžãªã¯ãã«ããã«ããªã¹ããšãŒãïŒã
ã¯ãšã³é žãšã¹ãã«ïŒããšãã°ã¢ã»ãã«ã¯ãšã³é žã
ãªããã«ïŒãå®æ¯éŠé žãšã¹ãã«ïŒããšãã°å®æ¯éŠ
é žãªã¯ãã«ïŒãã¢ã«ãã«ã¢ããïŒããšãã°ãžãšã
ã«ã©ãŠãªã«ã¢ããïŒãèèªé žãšã¹ãã«é¡ïŒããšã
ã°ãžãããã·ãšãã«ãµã¯ã·ããŒãããžãªã¯ãã«ã¢
ãŒã¬ãŒãïŒãããªã¡ã·ã³é žãšã¹ãã«é¡ïŒããšãã°
ããªã¡ã·ã³é žããªããã«ïŒãªã©ããŸãã¯æ²žç¹çŽ30
âä¹è³150âã®ææ©æº¶åªãããšãã°é ¢é žãšãã«ã
é ¢é žããã«ã®ããšãäœçŽã¢ã«ãã«ã¢ã»ããŒããã
ãããªã³é žãšãã«ãïŒçŽããã«ã¢ã«ã³ãŒã«ãã¡ã
ã«ã€ãœããã«ã±ãã³ãβâãšããã·ãšãã«ã¢ã»ã
ãŒããã¡ãã«ã»ããŸã«ãã¢ã»ããŒãçã®æº¶è§£ãã
ã®ã¡ã芪氎æ§ã³ãã€ãã«åæ£ããããäžèšã®é«æ²ž
ç¹ææ©æº¶åªãšäœæ²žç¹ææ©æº¶åªãšãæ··åããŠçšããŠ
ãããã æ¬çºæã®è²æ±æé²æ¢å€ã¯ãçºè²çŸååŠçã«ãã
ãŠè³éŠæïŒçŽã¢ãã³çŸåè¬ïŒäŸãã°ããšãã¬ã³ãž
ã¢ãã³èªå°äœãã¢ããããšããŒã«èªå°äœãªã©ïŒãš
è²åœ¢æã«ãã©ãŒãšã®é žåã«ãããªã³ã°ã«ãã€ãŠè²
åã圢æããã¿ã€ãã®ããã²ã³åéã«ã©ãŒåçæ
å ææïŒäŸãã°ã«ã©ãŒããŒããŒãã«ã©ãŒãã¬ãã€
ã«ã ãã«ã©ãŒãªããŒãµã«ãã€ã«ã ãªã©ïŒã®è²æ±æ
é²æ¢ã«èå¹ã瀺ãã ãã®ã¿ã€ãã®ã«ã©ãŒåçæå ææã«çšãããã
è²åœ¢æã«ãã©ãŒãšããŠã¯ãäŸãã°ããŒã³ã¿ã«ãã©
ãŒãšããŠïŒâãã©ãŸãã³ã«ãã©ãŒããã©ãŸããã³
ãã€ãããŸãŒã«ã«ãã©ãŒãã·ã¢ãã¢ã»ãã«ã¯ãã
ã³ã«ãã©ãŒãééã¢ã·ã«ã¢ã»ããããªã«ã«ãã©ãŒ
çããããã€ãšããŒã«ãã©ãŒãšããŠãã¢ã·ã«ã¢ã»
ãã¢ããã«ãã©ãŒïŒäŸãã°ãã³ãŸã€ã«ã¢ã»ãã¢ã
ãªãé¡ããããã€ã«ã¢ã»ãã¢ããªãé¡ïŒãçãã
ããã·ã¢ã³ã«ãã©ãŒãšããŠãããããŒã«ã«ãã©
ãŒãããã³ããšããŒã«ã«ãã©ãŒãçãããããã
ãã®ã«ãã©ãŒã¯ååäžã«ãã©ã¹ãåºãšãã°ããç
æ°Žæ§åºãå°å ¥ããããããªããŒéã«çµåãããã
ããŠéæ¡æ£åããããšãã§ãã奜ãŸãã䜿çšãã
ãã ã«ãã©ãŒã¯éã€ãªã³ã«å¯ŸãïŒåœéæ§ãããã¯ïŒ
åœéæ§ã®ã©ã¡ãã§ãããããŸãè²è£æ£ã®å¹æãã
ã€ã«ã©ãŒãã«ãã©ãŒããããã¯çŸåã«ãšããªã€ãŠ
çŸåæå¶å€ãæŸåºããã«ãã©ãŒïŒããããDIRã«
ãã©ãŒïŒã§ãã€ãŠãããã ããŒã³ã¿çºè²ã«ãã©ãŒã®å ·äœäŸã¯ãç±³åœç¹èš±
2600788å·ãå2983608å·ãå3062653å·ãå
3127269å·ãå3311476å·ãå3419391å·ãå
3519429å·ãå3558319å·ãå3582322å·ãå
3615506å·ãå3834908å·ãå3891445å·ã西ç¬ç¹
èš±1810464å·ã西ç¬ç¹èš±åºé¡ïŒOLSïŒ2408665å·ã
å2417945å·ãå2418959å·ãå2424467å·ãç¹å ¬
æ40â6031å·ãç¹éæ51â20826å·ãå52â58922
å·ãå49â129538å·ãå49â74027å·ãå50â
159336å·ãå52â42121å·ãå49â74028å·ãå50
â60233å·ãå51â26541å·ãå53â55122å·ãªã©
ã«èšèŒã®ãã®ã§ããã é»è²çºè²ã«ãã©ãŒã®å ·äœäŸã¯ç±³åœç¹èš±2875057
å·ãå3265506å·ãå3408194å·ãå3551155å·ã
å3582322å·ãå3725072å·ãå3891445å·ã西ç¬
ç¹èš±1547868å·ã西ç¬åºé¡å ¬é2219917å·ãå
2261361å·ãå2414006å·ãè±åœç¹èš±1425020å·ã
ç¹å ¬æ51â10783å·ãç¹éæ47â26133å·ãå48â
73147å·ãå51â102636å·ãå50â6341å·ãå50
â123342å·ãå50â130442å·ãå51â21827å·ã
å50â87650å·ãå52â82424å·ãå52â115219å·
ãªã©ã«èšèŒããããã®ã§ããã ã·ã¢ã³ã«ãã©ãŒã®å ·äœäŸã¯ç±³åœç¹èš±2369929å·ã
å2434272å·ãå2474293å·ãå2521908å·ãå
2895826å·ãå3034892å·ãå3311476å·ãå
3458315å·ãå3476563å·ãå3583971å·ãå
3591383å·ãå3767411å·ãå4004929å·ã西ç¬ç¹
èš±åºé¡ïŒOLSïŒ2414830å·ãå2454329å·ãç¹é
æ48â59838å·ãå51â26034å·ãå48â5055å·ã
å51â146828å·ãå52â69624å·ãå52â90932å·
ã«èšèŒã®ãã®ã§ããã ã«ã©ãŒãã»ã«ãã©ãŒãšããŠã¯äŸãã°ç±³åœç¹èš±
3476560å·ãå2521908å·ãå3034892å·ãç¹å ¬æ
44â2016å·ãå38â22335å·ãå42â11304å·ãå
44â32461å·ãç¹éæ51â26034å·æ现æžãå52â
42121å·æ现æžã西ç¬ç¹èš±åºé¡ïŒOLSïŒ2418959
å·ã«èšèŒã®ãã®ã䜿çšã§ããã DIRã«ãã©ãŒãšããŠã¯ãããšãã°ç±³åœç¹èš±
3227554å·ãå3617291å·ãå3701783å·ãå
3790384å·ãå3632345å·ã西ç¬ç¹èš±åºé¡ïŒOLSïŒ
2414006å·ãå2454301å·ãå2454329å·ãè±åœç¹
èš±953454å·ãç¹éæ52â69624å·ãå49â122335
å·ãç¹å ¬æ51â16141å·ã«èšèŒããããã®ã䜿çš
ã§ããã æ¬çºæã®è²æ±æé²æ¢å€ã¯ãŸãããããæ¡æ£è»¢å
åã®ããã²ã³åéã«ã©ãŒåçæå ææã®è²æ±æã
é²æ¢ããã®ã«æçšã§ãããã®åã®ææã«çšããã
ãè²çŽ å圢æååç©ãšããŠã¯äŸãã°è²çŽ çŸåè¬ã
è²çŽ æŸåºã¬ããã¯ã¹ååç©ãDDRã«ãã©ãŒãªã©
ããããå ·äœçã«ã¯äŸãã°ç±³åœç¹èš±4053312å·ã
å4055428å·ãå4076529å·ãå4152153å·ãå
4135929å·ãç¹éæ53â149328å·ãå51â104343
å·ãå53â46730å·ãå54â130122å·ãå53â
3819å·ãç¹é¡æ54â89128å·ãå54â90806å·ãå
54â91187å·ãçã«èšèŒã®ååç©ãçšããããšã
ã§ããã æ¬çºæã®ååç©ã¯ãå ¬ç¥ã®è²æ±æé²æ¢å€ãäŸã
ã°ãã€ããããã³èªå°äœãã¢ããããšããŒã«èªå°
äœã没é£åé žèªå°äœãã¢ã¹ã³ã«ãã³é žèªå°äœãªã©
ãšäœµçšããŠãããã ãã®å ·äœäŸã¯ç±³åœç¹èš±2360290å·ãå2336327
å·ãå2403721å·ãå2418613å·ãå2675314å·ã
å2701197å·ãå2704713å·ãå2728659å·ãå
2732300å·ãå2735365å·ãç¹éæ50â92988å·ã
å50â92989å·ãå50â93928å·ãå50â110337
å·ãå52â146235å·ãç¹å ¬æ50â23813å·çã«èš
èŒãããŠããã æ¬çºæã®æå ææã«ã¯èŠªæ°Žæ§ã³ãã€ãå±€ã«çŽ«å€
ç·åžåå€ãå«ãã§ãããããšãã°ã¢ãªãŒã«åºã§çœ®
æããããã³ãŸããªã¢ãŸãŒã«ååç©ãïŒâãã¢ãŸ
ãªãã³ååç©ããã³ãŸããšãã³ååç©ãæ¡ç®é žãš
ã¹ãã«ååç©ããã¿ãžãšã³ååç©ããã³ãŸãªããµ
ãŸãŒã«ååç©ãããã«çŽ«å€ç·åžåæ§ã®ããªããŒãª
ã©ãçšããããšãã§ããããããã®çŽ«å€ç·åžåå€
ã¯ãäžèšèŠªæ°Žæ§ã³ãã€ãå±€äžã«åºå®ãããŠãã
ãã ãã®ä»ãæ¬çºæã®ã«ã©ãŒææã«çšããããšã®ã§
ããåçããã²ã³åéä¹³å€ããã³ãã®èª¿è£œæ³ãªã
ã³ã«åçæ·»å å€ïŒãŸãã¯åççšçŽ æïŒãªã©ã«ã€ã
ãŠã¯ããResearch DisclosureãèªãNo.176ïŒ1978
幎11æïŒ22ã31é ã«èšèŒããããä¹³å€ã®èª¿è£œãšã¿
ã€ããããä¹³å€ã®æ°ŽæŽãããååŠå¢æãããã«ããªé²æ¢
å€ããã³å®å®å€ããã硬èå€ãããæ¯æäœãããå¯å¡å€
ããã³æœ€æ»å€ãããå¡åžå©å€ããããããå€ãããå¢æ
å€ãããåå å¢æå€ãããæ·»å æ¹æ³ãããåžåããã³ã
ã€ã«ã¿ãŒææãããå¡åžæ¹æ³ããªã©ãé©çšããã
ãšãã§ããã ã«ã©ãŒç»å圢æã®ããã«ã¯ãã¬ããžæ³ïŒäŸãã°
âJournal of the Society of Motion Picture
and Television Engineersâ61å·»ïŒ1953幎ïŒã
667ã701é ã«èšèŒãããŠããïŒãé»çœçŸåäž»è¬ã
å«ãçŸå液ã§çŸåããŠãã¬éåãã€ãããã€ãã§
å°ãªããšãäžåã®äžæ§ãªé²å ãŸãã¯ä»ã®é©åœãªã«
ããªåŠçãè¡ãªããåŒãç¶ããŠçºè²çŸåãè¡ãªã
ããšã«ããè²çŽ éœç»åãåŸãã«ã©ãŒå転æ³ãè²çŽ
ãå«ãåçä¹³å€å±€ããé²å åŸçŸåããŠéç»åãã€
ããããããæŒçœè§ŠåªãšããŠè²çŽ ãæŒçœããéè²
çŽ æŒçœæ³ãªã©ãçšããããã ã«ã©ãŒçŸå液ã¯ãäžè¬ã«çºè²çŸåäž»è¬ãå«ãã¢
ã«ã«ãªæ§æ°Žæº¶æ¶²ããæããçºè²çŸåäž»è¬ã¯å ¬ç¥ã®
äžçŽè³éŠæã¢ãã³çŸåå€ãäŸãã°ããšãã¬ã³ãžã¢
ãã³é¡ïŒäŸãã°ïŒâã¢ããâïŒïŒ®âãžãšãã«ã¢
ããªã³ãïŒâã¡ãã«âïŒâã¢ããâïŒïŒ®âãžãš
ãã«ã¢ããªã³ãïŒâã¢ããââãšãã«ââβ
âããããã·ãšãã«ã¢ããªã³ãïŒâã¡ãã«âïŒâ
ã¢ããââãšãã«ââβâããããã·ãšãã«
ã¢ããªã³ãïŒâã¡ãã«âïŒâã¢ããââãšãã«
ââβâã¡ã¿ã³ã¹ã«ãã¢ãããšãã«ã¢ããªã³ã
ïŒâã¢ããâïŒâã¡ãã«ââãšãã«ââβâ
ã¡ããã·ãšãã«ã¢ããªã³ãªã©ïŒãçšããããšã§ã
ãã ãã®ä»L.F.A.MasonèPhotographic
Processing ChemistryïŒFocal Pressåã1966幎ïŒ
ã®226ã229é ãç±³åœç¹èš±2193015å·ãå2592364
å·ãç¹éæ48â64933å·ãªã©ã«èšèŒã®ãã®ãçšã
ãŠããã ã«ã©ãŒçŸå液ã¯ãã®ã»ãã¢ã«ã«ãªéå±ã®äºç¡«é ž
å¡©ãçé žå¡©ãããŠé žå¡©ããã³ãªã³é žå¡©ã®åŠãPHã
ç·©è¡å€ãèåç©ãæ²åç©ããã³ææ©ã«ããªé²æ¢å€
ã®åŠãçŸåæå¶å€ãªããã«ããªé²æ¢å€ãªã©ãå«ã
ããšãã§ããããŸãå¿ èŠã«å¿ããŠã硬氎è»åå€ã
ããããã·ã«ã¢ãã³ã®åŠãä¿æå€ããã³ãžã«ã¢ã«
ã³ãŒã«ããžãšãã¬ã³ã°ãªã³ãŒã«ã®åŠãææ©æº¶å€ã
ããªãšãã¬ã³ã°ãªã³ãŒã«ãåçŽã¢ã³ã¢ããŠã å¡©ã
ã¢ãã³é¡ã®åŠãçŸåä¿é²å€ãè²çŽ 圢æã«ãã©ãŒã
競äºã«ãã©ãŒããããªãŠã ãããã€ãã©ã€ãã®åŠ
ããã¶ããå€ãïŒâããšãã«âïŒâãã©ãŸãªãã³
ã®åŠãè£å©çŸåè¬ãç²æ§ä»äžå€ãç±³åœç¹èš±
4083723å·ã«èšèŒã®ããªã«ã«ãã³é žç³»ãã¬ãŒãå€ã
西ç¬å ¬éïŒOLSïŒ2622950å·ã«èšèŒã®é žåé²æ¢å€
ãªã©ãå«ãã§ãããã çºè²çŸååŸã®åçä¹³å€å±€ã¯éåžžãæŒçœåŠçãã
ããæŒçœåŠçã¯å®çåŠçãšåæã«è¡ãªãããŠãã
ãããåå¥ã«è¡ãªãããŠããããæŒçœå€ãšããŠã¯
éïŒïŒãã³ãã«ãïŒïŒãã¯ãã ïŒïŒãé ïŒïŒ
ãªã©ã®å€äŸ¡éå±ã®ååç©ãéé žé¡ãããã³é¡ãã
ãããœååç©ãªã©ãçšãããããããšãã°ããšãª
ã·ã¢ã³åç©ãéã¯ãã é žå¡©ãéïŒïŒãŸãã¯ã³ã
ã«ãïŒïŒã®ææ©é¯å¡©ãããšãã°ãšãã¬ã³ãžã¢ã
ã³åé ¢é žããããªãããªé ¢é žãïŒïŒïŒâãžã¢ãã
âïŒâãããããŒã«åé ¢é žãªã©ã®ã¢ããããªã«ã«
ãã³é žé¡ãããã¯ã¯ãšã³é žãé ç³é žããªã³ãŽé žãª
ã©ã®ææ©é žã®é¯å¡©ïŒéç¡«é žå¡©ãéãã³ã¬ã³é žå¡©ïŒ
ããããœããšããŒã«ãªã©ãçšããããšãã§ããã
ãããã®ãã¡ããšãªã·ã¢ã³åã«ãªããšãã¬ã³ãžã¢
ãã³åé ¢é žéïŒïŒãããªãŠã ããã³ãšãã¬ã³ãž
ã¢ãã³åé ¢é žéïŒïŒã¢ã³ã¢ããŠã ã¯ç¹ã«æçšã§
ããããšãã¬ã³ãžã¢ãã³åé ¢é žéïŒïŒé¯å¡©ã¯ç¬
ç«ã®æŒçœæ¶²ã«ãããŠããäžæµŽæŒçœå®ç液ã«ãããŠ
ãæçšã§ããã æŒçœãŸãã¯æŒçœå®ç液ã«ã¯ãç±³åœç¹èš±3042520
å·ãå3241966å·ãç¹å ¬æ45â8506å·ãç¹å ¬æ45
â8836å·ãªã©ã«èšèŒã®æŒçœä¿é²å€ãç¹éæ53â
65732å·ã«èšèŒã®ããªãŒã«ååç©ã®ä»ãçš®ã ã®æ·»
å å€ãå ããããšãã§ããã æ¬çºæãæ¡æ£è»¢åæ³ã«çšããå Žåã¯ç²æ§çŸå液
ã§åŠçããããšãã§ããã ãã®ç²æ§çŸå液ã¯ããã²ã³åéä¹³å€ã®çŸåãšæ¡
æ£è»¢åè²çŽ åã®åœ¢æãšã«å¿ èŠãªåŠçæåãå«æã
ã液ç¶çµæç©ã§ãã€ãŠã溶åªã®äž»äœã¯æ°Žã§ããã
ä»ã«ã¡ã¿ããŒã«ãã¡ãã«ã»ããœã«ãã®åŠã芪氎æ§
溶åªãå«ãããšããããåŠççµæç©ã¯ãä¹³å€å±€ã®
çŸåãèµ·ãããã«å¿ èŠãªPHãç¶æããçŸåãšè²çŽ
å圢æã®è«žéçšäžã«çæããé žïŒäŸãã°èåæ°ŽçŽ
é žçã®ããã²ã³åæ°ŽçŽ é žãé ¢é žçã®ã«ã«ãã³é ž
çïŒãäžåããã«è¶³ããéã®ã¢ã«ã«ãªãå«æããŠ
ãããã¢ã«ã«ãªãšããŠã¯æ°Žé žåãªããŠã ãæ°Žé žå
ãããªãŠã ãæ°Žé žåã«ãªãŠã ãæ°Žé žåã«ã«ã·ãŠã
åæ£ç©ãæ°Žé žåããã©ã¡ãã«ã¢ã³ã¢ããŠã ãçé ž
ãããªãŠã ããªã³é žïŒãããªãŠã ããžãšãã«ã¢ã
ã³çã®ã¢ã«ã«ãªéå±ãããã¯ã¢ã«ã«ãªåé¡éå±
å¡©ãåã¯ã¢ãã³é¡ã䜿çšããã奜ãŸããã¯å®€æž©ã«
ãããŠçŽ12以äžã®PHããã€ãç¹ã«PH14以äžãšãªã
ãããªæ¿åºŠã®èæ§ã¢ã«ã«ãªãå«æãããããšãæ
ãŸãããããã«å¥œãŸããã¯åŠççµæç©ã¯é«ååé
ã®ããªããã«ã¢ã«ã³ãŒã«ãããããã·ãšãã«ã»ã«
ããŒãºããããªãŠã ã«ã«ããã·ã¡ãã«ã»ã«ããŒãº
ã®åŠã芪氎æ§ããªããŒãå«æããŠããããããã®
ããªããŒã¯åŠççµæç©ã«å®€æž©ã§ïŒãã€ã¹ä»¥äžã奜
ãŸããã¯æ°çŸïŒ500ã600ïŒä¹è³1000ãã€ã¹çšåºŠã®
ç²åºŠãäžããããã«çšãããšããã 以äžã«å®æœäŸãæ²ãæ¬çºæãæŽã«è©³çŽ°ã«èª¬æã
ãã å®æœäŸ ïŒ ãã€ã«ã  ããªãšãã¬ã³ã§äž¡é¢è¢«èŠããããã©ã€ã¿çŽæ¯æ
äœäžã«ã第ïŒå±€ãšããŠã€ãšããŒã«ãã©ãŒÎ±âãã
ãã€ã«âαïŒïŒïŒïŒâãžãªããœâïŒïŒ5â²âãžã¡ã
ã«ãªããµãŸãªãžã³âïŒâã€ã«ïŒâïŒâã¯ããâïŒ
âãαâïŒïŒïŒïŒâãžâtertâãã³ãã«ããšãã
ã·ïŒãã¿ã³ã¢ãããã¢ã»ãã¢ããªããå«æããé
ææ§å¡©èåéä¹³å€å±€ã3.0ÎŒã®åãã«å¡åžïŒã«ãã©
ãŒå¡åžé0.646Ã10-3ã¢ã«ïŒm2ãå¡åžéé3.88Ã
10-3ã¢ã«ïŒm2ãèåé70ã¢ã«ïŒ ãå¡©åé30ã¢ã«
ïŒ ïŒãããã®äžã«ç¬¬ïŒå±€ãšããŠãŒã©ãã³å±€ã1.5ÎŒ
ã®åãã«å¡åžããã æŽã«ç¬¬ïŒå±€ãšããŠããŒã³ã¿ã«ãã©ãŒïŒâïŒïŒïŒ
ïŒïŒïŒâããªã¯ããããšãã«ïŒâïŒâïœïŒâã¯ã
ãâïŒïŒâããã©ãã«ã³ã¢ããïŒã¢ããªãïœâïŒ
âãã©ãŸãã³ãå«æãããŒã©ãã³å±€ã3.1ÎŒã®åã
ã«å¡åžããïŒã«ãã©ãŒå¡åžé0.500Ã10-3ã¢ã«ïŒ
m2 ãã€ã«ã  äžèšãã€ã«ã ã«æŒããŠã第ïŒå±€ã«ïŒïŒïŒâãž
ãªã¯ãã«ãã€ããããã³ãå«ã以å€ã¯ãã€ã«ã 
ãšåãïŒãã€ããããã³å¡åžé1.59Ã10-4ã¢ã«ïŒ
m2ïŒã«ããŠãã€ã«ã ãäœè£œããã ãŸãã次ã®ãããªãã€ã«ã ããäœè£œããã ãã€ã«ã  äžèšãã€ã«ã ã«æŒããŠç¬¬ïŒå±€ã«äŸç€ºååç©(ã€)
ã0.09ïœïŒm2ïŒã¹ã«ãã³ã¢ããããšããŒã«æ®åºãš
ããŠ1.59Ã10-4ã¢ã«ïŒm2ïŒå«ã以å€ã¯ãã€ã«ã 
ãšåãã ãã€ã«ã  äžèšãã€ã«ã ã«æŒããŠç¬¬ïŒå±€ã«äŸç€ºååç©(ã)
ã0.106ïœïŒm2ïŒã¹ã«ãã³ã¢ããããšãŒã«æ®åºãš
ããŠ1.59Ã10-4ã¢ã«ïŒm2ïŒå«ã以å€ã¯ãã€ã«ã 
ãšåãã ãã€ã«ã  äžèšãã€ã«ã ã«æŒããŠç¬¬ïŒå±€ã«äŸç€ºååç©(ã)
ã0.053ïœïŒm2ïŒã¹ã«ãã³ã¢ããããšããŒã«æ®åº
ãšããŠ8.0Ã10-5ã¢ã«ïŒm2ïŒå«ã以å€ã¯ãã€ã«ã
ãšåãã ãã®æ§ã«ããŠäœè£œãããã€ã«ã ããé£ç¶ç
ã«ã°ã¬ã€æ¿åºŠãç°ãªããŠãšããžãä»ããŠé²å ãã
次ã®åŠçãè¡ãªã€ãã åŠçå·¥çš ã«ã©ãŒçŸååŠç ïŒå30ç§ 33â æŒçœå®çåŠç ïŒå30ç§ 33â æ°Ž æŽ ïŒå 28ã35â ã«ã©ãŒçŸå液 ãã³ãžã«ã¢ã«ã³ãŒã« 15ml ãžãšãã¬ã³ããªã¢ãã³ïŒé ¢é ž ïŒïœ KBr 0.4ïœ Na2SO3 ïŒïœ Na2CO3 30ïœ ããããã·ã«ã¢ãã³ç¡«é žå¡© ïŒïœ ïŒâã¢ããâïŒâã¡ãã«ââβâïŒã¡ã¿ã³ã¹
ã«ãã³ã¢ããïŒãšãã«ã¢ããªã³ã»ïŒïŒ
2H2SO4ã»H2O 4.5ïœ æ°Žã§1000mlã«ãã PH10.1 æŒçœå®ç液 ããªç¡«é žã¢ã³ã¢ããŠã ïŒ70wtïŒ ïŒ 150ml Na2SO3 ïŒïœ NaãFeïŒEDTAïŒã 40ïœ EDTA ïŒïœ æ°Žã§1000mlã«ãã PH6.8 åã çŸåããããµã³ãã«ãã°ãªãŒã³ãã€ã«ã¿ãŒ
ãçšããŠæ¿åºŠæž¬å®ããïŒããŒã³ã¿çºè²æ¿åºŠïŒãã€
ãšããŒæ倧çºè²æ¿åºŠã«æŒããããŒã³ã¿æ¿åºŠãšã€ãš
ããŒæäœçºè²æ¿åºŠã®ããŒã³ã¿æ¿åºŠãšã®å·®ãæ±ã
ãŠãã€ãšããŒçºè²éšã®ããŒã³ã¿æ··è²ã調ã¹ãã çµæã次衚ã«ç€ºãã
ãè¡šã
æ··è²ã¯æ°å€ã®å°ããæ¹ãå°ãªãããšã瀺ããåŸ
ã€ãŠæ¬çºæã®ååç©ã¯æ··è²ïŒè²ã«ããªïŒãé²æ¢ã
ãæ§èœã«åªããå°ãªãæ·»å éã§å åãªå¹æã瀺ã
ããšãæããã§ããã å®æœäŸ ïŒ ãã€ã«ã ã®äœè£œ ããªãšãã¬ã³ã§äž¡é¢è¢«èŠãããã©ã€ã¿çŽæ¯æäœ
äžã«ã€ãšããŒã«ãã©ãŒÎ±âãããã€ã«âαïŒïŒïŒ
ïŒâãžãªããœâïŒïŒ5â²âãžã¡ãã«ãªããµãŸãªãžã³
âïŒâã€ã«ïŒâïŒâã¯ããâïŒâãαâïŒïŒïŒïŒ
âãžâïœâãã³ãã«ããšããã·ïŒããã³ã¢ããã
ã¢ã»ãã¢ããªããå«æããéææ§å¡©èåéä¹³å€å±€
ã3ÎŒã®ä¹Ÿç¥èåã«å¡åžïŒã«ãã©ãŒå¡åžé0.646Ã
10-3ã¢ã«ïŒm2ãå¡åžéé3.88Ã10-3ã¢ã«ïŒm2ããª
ãå¡©èåéã®ããã²ã³çµæã¯èåé70ã¢ã«ïŒ ãå¡©
åé30ã¢ã«ïŒ ã§ããïŒãããã®äžã«ãŒã©ãã³å±€ã
1ÎŒã®ä¹Ÿç¥èåã«å¡åžããã ãã€ã«ã ã äžèšã€ãšããŒã«ãã©ãŒã«å ããŠæ¬çºæã®ååç©
(ã€)ã(ã)ã(ã)ã(ã)ãåã 0.02Ã10-3ã¢ã«*ïŒm2ã
æ·»
å ãã以å€ã¯ãã€ã«ã ãšåãã«ããŠãã€ã«ã 
ããäœè£œãããïŒïŒã¹ã«ãã³ã¢ããããšããŒã«
æ®åºãšããŠèšç®ïŒ äžèšåãã€ã«ã ãé£ç¶çã«ã°ã¬ã€æ¿åºŠã®å€ãã
ãŠãšããžãä»ããŠé²å ããå®æœäŸïŒã§ç€ºããåŠç
ã«æŒããŠã«ã©ãŒçŸåã38âã§ïŒåéè¡ãªã€ã以å€
ã¯å®æœäŸïŒãšåãåŠçãè¡ãªã€ããåŠçåŸã€ãšã
ãŒæ¿åºŠã枬å®ããæ倧æ¿åºŠïŒDmaxïŒãæäœæ¿åºŠ
ïŒDminïŒã調ã¹ãã çµæã次衚ã«ç€ºãã
ã€ãŠæ¬çºæã®ååç©ã¯æ··è²ïŒè²ã«ããªïŒãé²æ¢ã
ãæ§èœã«åªããå°ãªãæ·»å éã§å åãªå¹æã瀺ã
ããšãæããã§ããã å®æœäŸ ïŒ ãã€ã«ã ã®äœè£œ ããªãšãã¬ã³ã§äž¡é¢è¢«èŠãããã©ã€ã¿çŽæ¯æäœ
äžã«ã€ãšããŒã«ãã©ãŒÎ±âãããã€ã«âαïŒïŒïŒ
ïŒâãžãªããœâïŒïŒ5â²âãžã¡ãã«ãªããµãŸãªãžã³
âïŒâã€ã«ïŒâïŒâã¯ããâïŒâãαâïŒïŒïŒïŒ
âãžâïœâãã³ãã«ããšããã·ïŒããã³ã¢ããã
ã¢ã»ãã¢ããªããå«æããéææ§å¡©èåéä¹³å€å±€
ã3ÎŒã®ä¹Ÿç¥èåã«å¡åžïŒã«ãã©ãŒå¡åžé0.646Ã
10-3ã¢ã«ïŒm2ãå¡åžéé3.88Ã10-3ã¢ã«ïŒm2ããª
ãå¡©èåéã®ããã²ã³çµæã¯èåé70ã¢ã«ïŒ ãå¡©
åé30ã¢ã«ïŒ ã§ããïŒãããã®äžã«ãŒã©ãã³å±€ã
1ÎŒã®ä¹Ÿç¥èåã«å¡åžããã ãã€ã«ã ã äžèšã€ãšããŒã«ãã©ãŒã«å ããŠæ¬çºæã®ååç©
(ã€)ã(ã)ã(ã)ã(ã)ãåã 0.02Ã10-3ã¢ã«*ïŒm2ã
æ·»
å ãã以å€ã¯ãã€ã«ã ãšåãã«ããŠãã€ã«ã 
ããäœè£œãããïŒïŒã¹ã«ãã³ã¢ããããšããŒã«
æ®åºãšããŠèšç®ïŒ äžèšåãã€ã«ã ãé£ç¶çã«ã°ã¬ã€æ¿åºŠã®å€ãã
ãŠãšããžãä»ããŠé²å ããå®æœäŸïŒã§ç€ºããåŠç
ã«æŒããŠã«ã©ãŒçŸåã38âã§ïŒåéè¡ãªã€ã以å€
ã¯å®æœäŸïŒãšåãåŠçãè¡ãªã€ããåŠçåŸã€ãšã
ãŒæ¿åºŠã枬å®ããæ倧æ¿åºŠïŒDmaxïŒãæäœæ¿åºŠ
ïŒDminïŒã調ã¹ãã çµæã次衚ã«ç€ºãã
ãè¡šã
æ¬çºæã®ååç©ãçšãããã€ã«ã ãã¯ãã€
ã«ã ã«æ¯ã¹æäœæ¿åºŠãäœããè²ã«ããªãæ¹è¯ã
ããŠããããšãå€ãã åèšã®ãã€ã«ã ãïŒé²å åïŒãçžå¯Ÿæ¹¿åºŠ50
ïŒ ã枩床50âã®æ¡ä»¶ã§ïŒæ¥éä¿åããåŸã«ãåèš
ãšåæ§ã®é²å ã»åŠçãè¡ãªã€ããšããããã€ã«ã
ã§ã¯æ倧æ¿åºŠã®äœäžåã³æäœæ¿åºŠã®å¢å ã芳å¯
ãããã®ã«å¯Ÿãããã€ã«ã ãã§ã¯æ倧æ¿åºŠå
ã³æäœæ¿åºŠã®å€åãåæ¹ãšãããå°ãªãã€ãã å®æœäŸ ïŒ ã»ã«ããŒã¹ããªã¢ã»ããŒããã€ã«ã æ¯æäœäžã«
äžèšã«ç€ºããšããã®å±€ãèšããŠå€å±€ã«ã©ãŒïŒã
ã¬ïŒæå ææãäœã€ãã ïŒç¬¬ïŒå±€ ãã¬ãŒã·ãšã³é²æ¢å±€ïŒïŒä¹Ÿç¥èå2.0ÎŒïŒ ïŒç¬¬ïŒå±€ äœæèµ€æä¹³å€å±€ïŒ äžèšã·ã¢ã³ã«ãã©ãŒã®ä¹³åç©(1)ïŒã·ã¢ã³ã«ãã©
ãŒ70ïœããŒã©ãã³100ïœãå«ãïŒã400ïœãåãã·
ã¢ã³ã«ãã©ãŒãšäžèšDIRååç©ãå«ãä¹³åç©(2)
ïŒã·ã¢ã³ã«ãã©ãŒ70ïœãDIRååç©10ïœããŒã©ã
ã³100ïœãå«ãïŒã200ïœãäžèšã«ã©ãŒãã·ã¢ã³ã«
ãã©ãŒã®ïŒïŒ 氎溶液ã200c.c.ãããããäœæ床赀
ææ§æ²èåéä¹³å€ïŒããã²ã³åé100ïœããŒã©ã
ã³70ïœãå«ãããšãŒãå«é5.0ã¢ã«ïŒ ïŒïŒKgã«æ··
åãã也ç¥èå3.5ÎŒã«ãªãæ§ã«å¡åžããã ïŒç¬¬ïŒå±€ é«æèµ€æä¹³å€å±€ïŒ 第ïŒå±€ã§çšããä¹³åç©(1)ã220ïœãä¹³åç©(2)ã
30ïœãã«ã©ãŒãã·ã¢ã³ã«ãã©ãŒæ°Žæº¶æ¶²ïŒïŒïŒ ïŒã
200c.c.ãããããé«æ床赀ææ§æ²èåéä¹³å€ïŒã
ãã²ã³åé100ïœããŒã©ãã³70ïœãå«ããšãŒãå«
éïŒã¢ã«ïŒ ïŒïŒKgã«æ··åãã也ç¥èå2.2ÎŒã«ãªã
ããã«å¡åžããã ïŒç¬¬ïŒå±€ ãŒã©ãã³äžéå±€ïŒ ïŒïŒïŒâãžâïœâãªã¯ãã«ãã€ããããã³50ïœ
ããžããã«ãã¿ã¬ãŒã100c.c.åã³é ¢é žãšãã«100c.c.
ã«æº¶è§£ãã10ïŒ ãŒã©ãã³æ°Žæº¶æ¶²ïŒKgãšæ¹æä¹³åã
ãŠåŸãä¹³åç©700ïœã10ïŒ ãŒã©ãã³æ°Žæº¶æ¶²ïŒKgãš
æ··åãã也ç¥èå1.2ÎŒã«ãªãããã«å¡åžããã ïŒç¬¬ïŒå±€ äœæç·æä¹³å€å±€ïŒ äžèšããŒã³ã¿ã«ãã©ãŒ50ïœãšäžèšã«ã©ãŒãããŒ
ã³ã¿ã«ãã©ãŒ10ïœãå«ãä¹³åç©(3)ïŒãŒã©ãã³100
ïœãå«ãïŒã320ïœãåãããŒã³ã¿ã«ãã©ãŒ50ïœã
åãã«ã©ãŒãããŒã³ã¿ã«ãã©ãŒ10ïœåã³äžèšDIR
ååç©15ïœãå«ãä¹³åç©(4)ïŒãŒã©ãã³100ïœãå«
ãïŒã180ïœãããããäœæ床ç·ææ§æ²èåéä¹³
å€ïŒããã²ã³åé100ïœããŒã©ãã³70ïœãå«ãã
ãšãŒãå«éïŒã¢ã«ïŒ ïŒïŒKgã«æ··åãã也ç¥èå
3.2ÎŒã«ãªãããã«å¡åžããã ïŒç¬¬ïŒå±€ é«æç·æä¹³å€å±€ïŒ 第ïŒå±€ã§çšããä¹³åç©(3)ã150ïœãä¹³åç©(4)ã
30ïœãããããé«æ床ç·ææ§æ²èåéä¹³å€ïŒãã
ã²ã³åé100ïœããŒã©ãã³70ïœãå«ãããšãŒãå«
éïŒã¢ã«ïŒ ïŒïŒKgã«æ··åãã也ç¥èå2.2ÎŒã«ãªã
ããã«å¡åžããã ïŒç¬¬ïŒå±€ ãŒã©ãã³äžéå±€ïŒ ä¹Ÿç¥èå0.9ÎŒã«ãªãããã«ãŒã©ãã³æ°Žæº¶æ¶²ãå¡
åžããã ïŒç¬¬ïŒå±€ é»è²ãã€ã«ã¿ãŒå±€ïŒ é»è²ã³ãã€ãéãå«ããŒã©ãã³æ¶²ã也ç¥èå
1ÎŒã«ãªãããã«å¡åžããã ïŒç¬¬ïŒå±€ äœæéæä¹³å€å±€ïŒ äžèšã€ãšããŒã«ãã©ãŒã®ä¹³åç©(5)ïŒã€ãšããŒã«
ãã©ãŒ100ïœããŒã©ãã³100ïœãå«ãïŒãäœæ床é
ææ§æ²èåéä¹³å€ïŒããã²ã³åé100ïœããŒã©ã
ã³70ïœãå«ãããšãŒãå«éïŒã¢ã«ïŒ ïŒïŒKgã«150
ïœæ·»å ããŠæ··åãã也ç¥èå3.0ÎŒã«ãªãããã«å¡
åžããã ïŒç¬¬10å±€ é«æéæä¹³å€å±€ïŒ 第ïŒå±€ã§çšããä¹³åå€(5)ã300ïœãé«æ床éæ
æ§æ²èåéä¹³å€ïŒããã²ã³åé100ïœããŒã©ãã³
70ïœãå«ãããšãŒãå«éïŒã¢ã«ïŒ ïŒïŒKgã«æ··å
ãã也ç¥èå2.5ÎŒã«ãªãããã«å¡åžããã ïŒç¬¬11å±€ 第ïŒä¿è·å±€ïŒ ïŒä¹Ÿç¥èå1ÎŒïŒ ïŒç¬¬12å±€ ãŒã©ãã³ä¿è·å±€ïŒ ïŒä¹Ÿç¥èå1.5ÎŒïŒ ãã®ããã«ããäœè£œãããã€ã«ã è©Šæããã€ã«
ã ãšããã äžèšã«ãããŠã第ïŒå±€ã®ä¹³åç©ãšããŠãïŒïŒïŒ
âãžâïœâãªã¯ãã«ãã€ããããã³ã«ä»£ããŠæ¬çº
æã®ååç©(ã€)*ãçšãã以å€ã¯åæ§ã«ããŠãã€ã«
ã ãäœè£œãããïŒïŒã¹ã«ãã³ã¢ããããšããŒã«
æ®åºã«æç®ããŠ1.59Ã10-4ã¢ã«ïŒm2䜿çšïŒ ãããã®è©Šæã«é£ç¶çã«ã°ã¬ã€æ¿åºŠã®å€ãããŠ
ãšããžãä»ããŠèµ€å é²å ãã次ã®åŠãåŠçãè¡ãª
ã€ãã ïŒ ã«ã©ãŒçŸå ïŒå15ç§ ïŒ å 济 30ç§ ïŒ æŒ çœ ïŒå20ç§ ïŒ å® ç ïŒå20ç§ ïŒ æ°Ž æŽ ïŒå15ç§ ïŒ å® å® 30ç§ åå·¥çšã«çšããåŠç液çµæã¯äžèšã®éãã§ãã€
ãã ã«ã©ãŒçŸå液 ãããªãããªé ¢é žäžãããªãŠã å¡© 1.9ïœ äºç¡«é žãããªãŠã 4.0ïœ çé žã«ãªãŠã 30.0ïœ èåã«ãªãŠã 1.4ïœ æ²åã«ãªãŠã 1.3mg ããããã·ã«ã¢ãã³ç¡«é žå¡© 2.4ïœ ïŒâïŒïŒ®âãšãã«ââβâããããã·ãšãã«
ã¢ããïŒâïŒâã¡ãã«ã¢ããªã³ç¡«é žå¡© 4.5ïœ æ°Žãå ã㊠1.0 PH10.0 æŒçœæ¶² ãšãã¬ã³ãžã¢ãã³åé ¢é žç¬¬äºéã¢ã³ã¢ããŠã å¡©
100.0ïœ ãšãã¬ã³ãžã¢ãã³åé ¢é žäºãããªãŠã å¡© 8.0ïœ èåã¢ã³ã¢ããŠã 150.0ïœ æ°Žãå ã㊠1.0 PH6.0 å®ç液 ããã©ããªãªã³é žãããªãŠã 2.0ïœ äºç¡«é žãããªãŠã 4.0ïœ ããªç¡«é žã¢ã³ã¢ããŠã 氎溶液ïŒ70ïŒ ïŒ 175.0ml éäºç¡«é žãããªãŠã 4.6ïœ æ°Žãå ã㊠1.0 PH6.6 å®å®æ¶² ãã«ããªã³ïŒ40ïŒ ïŒ 8.0ml æ°Žãå ã㊠1.0 çŸåãããã€ã«ã ããç·ãã€ã«ã¿ãŒãçšã
ãŠæ¿åºŠæž¬å®ããæ倧çºè²æ¿åºŠãšæäœçºè²æ¿åºŠïŒç·
æå±€ïŒã調ã¹ããšãããæ¬çºæã®ååç©ãçšãã
ãã€ã«ã ã®ããŒã³ã¿çºè²æ¿åºŠã¯ãã€ã«ã ãã
ãäœããæ··è²ãããé²æ¢ãããŠããããšãããã€
ãã
ã«ã ã«æ¯ã¹æäœæ¿åºŠãäœããè²ã«ããªãæ¹è¯ã
ããŠããããšãå€ãã åèšã®ãã€ã«ã ãïŒé²å åïŒãçžå¯Ÿæ¹¿åºŠ50
ïŒ ã枩床50âã®æ¡ä»¶ã§ïŒæ¥éä¿åããåŸã«ãåèš
ãšåæ§ã®é²å ã»åŠçãè¡ãªã€ããšããããã€ã«ã
ã§ã¯æ倧æ¿åºŠã®äœäžåã³æäœæ¿åºŠã®å¢å ã芳å¯
ãããã®ã«å¯Ÿãããã€ã«ã ãã§ã¯æ倧æ¿åºŠå
ã³æäœæ¿åºŠã®å€åãåæ¹ãšãããå°ãªãã€ãã å®æœäŸ ïŒ ã»ã«ããŒã¹ããªã¢ã»ããŒããã€ã«ã æ¯æäœäžã«
äžèšã«ç€ºããšããã®å±€ãèšããŠå€å±€ã«ã©ãŒïŒã
ã¬ïŒæå ææãäœã€ãã ïŒç¬¬ïŒå±€ ãã¬ãŒã·ãšã³é²æ¢å±€ïŒïŒä¹Ÿç¥èå2.0ÎŒïŒ ïŒç¬¬ïŒå±€ äœæèµ€æä¹³å€å±€ïŒ äžèšã·ã¢ã³ã«ãã©ãŒã®ä¹³åç©(1)ïŒã·ã¢ã³ã«ãã©
ãŒ70ïœããŒã©ãã³100ïœãå«ãïŒã400ïœãåãã·
ã¢ã³ã«ãã©ãŒãšäžèšDIRååç©ãå«ãä¹³åç©(2)
ïŒã·ã¢ã³ã«ãã©ãŒ70ïœãDIRååç©10ïœããŒã©ã
ã³100ïœãå«ãïŒã200ïœãäžèšã«ã©ãŒãã·ã¢ã³ã«
ãã©ãŒã®ïŒïŒ 氎溶液ã200c.c.ãããããäœæ床赀
ææ§æ²èåéä¹³å€ïŒããã²ã³åé100ïœããŒã©ã
ã³70ïœãå«ãããšãŒãå«é5.0ã¢ã«ïŒ ïŒïŒKgã«æ··
åãã也ç¥èå3.5ÎŒã«ãªãæ§ã«å¡åžããã ïŒç¬¬ïŒå±€ é«æèµ€æä¹³å€å±€ïŒ 第ïŒå±€ã§çšããä¹³åç©(1)ã220ïœãä¹³åç©(2)ã
30ïœãã«ã©ãŒãã·ã¢ã³ã«ãã©ãŒæ°Žæº¶æ¶²ïŒïŒïŒ ïŒã
200c.c.ãããããé«æ床赀ææ§æ²èåéä¹³å€ïŒã
ãã²ã³åé100ïœããŒã©ãã³70ïœãå«ããšãŒãå«
éïŒã¢ã«ïŒ ïŒïŒKgã«æ··åãã也ç¥èå2.2ÎŒã«ãªã
ããã«å¡åžããã ïŒç¬¬ïŒå±€ ãŒã©ãã³äžéå±€ïŒ ïŒïŒïŒâãžâïœâãªã¯ãã«ãã€ããããã³50ïœ
ããžããã«ãã¿ã¬ãŒã100c.c.åã³é ¢é žãšãã«100c.c.
ã«æº¶è§£ãã10ïŒ ãŒã©ãã³æ°Žæº¶æ¶²ïŒKgãšæ¹æä¹³åã
ãŠåŸãä¹³åç©700ïœã10ïŒ ãŒã©ãã³æ°Žæº¶æ¶²ïŒKgãš
æ··åãã也ç¥èå1.2ÎŒã«ãªãããã«å¡åžããã ïŒç¬¬ïŒå±€ äœæç·æä¹³å€å±€ïŒ äžèšããŒã³ã¿ã«ãã©ãŒ50ïœãšäžèšã«ã©ãŒãããŒ
ã³ã¿ã«ãã©ãŒ10ïœãå«ãä¹³åç©(3)ïŒãŒã©ãã³100
ïœãå«ãïŒã320ïœãåãããŒã³ã¿ã«ãã©ãŒ50ïœã
åãã«ã©ãŒãããŒã³ã¿ã«ãã©ãŒ10ïœåã³äžèšDIR
ååç©15ïœãå«ãä¹³åç©(4)ïŒãŒã©ãã³100ïœãå«
ãïŒã180ïœãããããäœæ床ç·ææ§æ²èåéä¹³
å€ïŒããã²ã³åé100ïœããŒã©ãã³70ïœãå«ãã
ãšãŒãå«éïŒã¢ã«ïŒ ïŒïŒKgã«æ··åãã也ç¥èå
3.2ÎŒã«ãªãããã«å¡åžããã ïŒç¬¬ïŒå±€ é«æç·æä¹³å€å±€ïŒ 第ïŒå±€ã§çšããä¹³åç©(3)ã150ïœãä¹³åç©(4)ã
30ïœãããããé«æ床ç·ææ§æ²èåéä¹³å€ïŒãã
ã²ã³åé100ïœããŒã©ãã³70ïœãå«ãããšãŒãå«
éïŒã¢ã«ïŒ ïŒïŒKgã«æ··åãã也ç¥èå2.2ÎŒã«ãªã
ããã«å¡åžããã ïŒç¬¬ïŒå±€ ãŒã©ãã³äžéå±€ïŒ ä¹Ÿç¥èå0.9ÎŒã«ãªãããã«ãŒã©ãã³æ°Žæº¶æ¶²ãå¡
åžããã ïŒç¬¬ïŒå±€ é»è²ãã€ã«ã¿ãŒå±€ïŒ é»è²ã³ãã€ãéãå«ããŒã©ãã³æ¶²ã也ç¥èå
1ÎŒã«ãªãããã«å¡åžããã ïŒç¬¬ïŒå±€ äœæéæä¹³å€å±€ïŒ äžèšã€ãšããŒã«ãã©ãŒã®ä¹³åç©(5)ïŒã€ãšããŒã«
ãã©ãŒ100ïœããŒã©ãã³100ïœãå«ãïŒãäœæ床é
ææ§æ²èåéä¹³å€ïŒããã²ã³åé100ïœããŒã©ã
ã³70ïœãå«ãããšãŒãå«éïŒã¢ã«ïŒ ïŒïŒKgã«150
ïœæ·»å ããŠæ··åãã也ç¥èå3.0ÎŒã«ãªãããã«å¡
åžããã ïŒç¬¬10å±€ é«æéæä¹³å€å±€ïŒ 第ïŒå±€ã§çšããä¹³åå€(5)ã300ïœãé«æ床éæ
æ§æ²èåéä¹³å€ïŒããã²ã³åé100ïœããŒã©ãã³
70ïœãå«ãããšãŒãå«éïŒã¢ã«ïŒ ïŒïŒKgã«æ··å
ãã也ç¥èå2.5ÎŒã«ãªãããã«å¡åžããã ïŒç¬¬11å±€ 第ïŒä¿è·å±€ïŒ ïŒä¹Ÿç¥èå1ÎŒïŒ ïŒç¬¬12å±€ ãŒã©ãã³ä¿è·å±€ïŒ ïŒä¹Ÿç¥èå1.5ÎŒïŒ ãã®ããã«ããäœè£œãããã€ã«ã è©Šæããã€ã«
ã ãšããã äžèšã«ãããŠã第ïŒå±€ã®ä¹³åç©ãšããŠãïŒïŒïŒ
âãžâïœâãªã¯ãã«ãã€ããããã³ã«ä»£ããŠæ¬çº
æã®ååç©(ã€)*ãçšãã以å€ã¯åæ§ã«ããŠãã€ã«
ã ãäœè£œãããïŒïŒã¹ã«ãã³ã¢ããããšããŒã«
æ®åºã«æç®ããŠ1.59Ã10-4ã¢ã«ïŒm2䜿çšïŒ ãããã®è©Šæã«é£ç¶çã«ã°ã¬ã€æ¿åºŠã®å€ãããŠ
ãšããžãä»ããŠèµ€å é²å ãã次ã®åŠãåŠçãè¡ãª
ã€ãã ïŒ ã«ã©ãŒçŸå ïŒå15ç§ ïŒ å 济 30ç§ ïŒ æŒ çœ ïŒå20ç§ ïŒ å® ç ïŒå20ç§ ïŒ æ°Ž æŽ ïŒå15ç§ ïŒ å® å® 30ç§ åå·¥çšã«çšããåŠç液çµæã¯äžèšã®éãã§ãã€
ãã ã«ã©ãŒçŸå液 ãããªãããªé ¢é žäžãããªãŠã å¡© 1.9ïœ äºç¡«é žãããªãŠã 4.0ïœ çé žã«ãªãŠã 30.0ïœ èåã«ãªãŠã 1.4ïœ æ²åã«ãªãŠã 1.3mg ããããã·ã«ã¢ãã³ç¡«é žå¡© 2.4ïœ ïŒâïŒïŒ®âãšãã«ââβâããããã·ãšãã«
ã¢ããïŒâïŒâã¡ãã«ã¢ããªã³ç¡«é žå¡© 4.5ïœ æ°Žãå ã㊠1.0 PH10.0 æŒçœæ¶² ãšãã¬ã³ãžã¢ãã³åé ¢é žç¬¬äºéã¢ã³ã¢ããŠã å¡©
100.0ïœ ãšãã¬ã³ãžã¢ãã³åé ¢é žäºãããªãŠã å¡© 8.0ïœ èåã¢ã³ã¢ããŠã 150.0ïœ æ°Žãå ã㊠1.0 PH6.0 å®ç液 ããã©ããªãªã³é žãããªãŠã 2.0ïœ äºç¡«é žãããªãŠã 4.0ïœ ããªç¡«é žã¢ã³ã¢ããŠã 氎溶液ïŒ70ïŒ ïŒ 175.0ml éäºç¡«é žãããªãŠã 4.6ïœ æ°Žãå ã㊠1.0 PH6.6 å®å®æ¶² ãã«ããªã³ïŒ40ïŒ ïŒ 8.0ml æ°Žãå ã㊠1.0 çŸåãããã€ã«ã ããç·ãã€ã«ã¿ãŒãçšã
ãŠæ¿åºŠæž¬å®ããæ倧çºè²æ¿åºŠãšæäœçºè²æ¿åºŠïŒç·
æå±€ïŒã調ã¹ããšãããæ¬çºæã®ååç©ãçšãã
ãã€ã«ã ã®ããŒã³ã¿çºè²æ¿åºŠã¯ãã€ã«ã ãã
ãäœããæ··è²ãããé²æ¢ãããŠããããšãããã€
ãã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ äžèšäžè¬åŒïŒïŒã§è¡šããããç¹°ãè¿ãåäœ
åã³ïŒåã¯äžè¬åŒïŒïŒã§è¡šããããç¹°ãè¿ãå
äœãå«ãéåäœè¥ããã¯å ±éåäœãå«æããããš
ãç¹åŸŽãšããããã²ã³åéã«ã©ãŒåçæå ææã äœãåŒäžããã¯ããããâCOâåã¯â
SO2âãè¡šãããå°ãªããšãäžæ¹ã¯âSO2âã§ã
ããR1ã¯æ°ŽçŽ ååãããã²ã³ååããããã眮
æåã¯ç¡çœ®æã®ãã¢ã«ãã«åºãã¢ã«ã³ãã·åºãã¢
ãªãŒã«ã¹ã«ãã³ã¢ããåºãã¢ã«ãã«ã¹ã«ãã³ã¢ã
ãåºãã¢ã·ã«ã¢ããåºãã¢ã«ãã«ããªåºãã¢ãªãŒ
ã«ããªåºããããç°ããªåºãã¢ã«ã³ãã·ã«ã«ãã
ã«åºãã¢ãªãŒããã·ã«ã«ããã«åºãã¹ã«ãã¢ã¢ã€
ã«ã¢ããåºãã¢ã«ã³ãã·ã«ã«ããã«ã¢ããåºãã«
ã«ãã¢ã€ã«ã¢ããåºãã¢ã·ã«åºãã¹ã«ããã«åºã
ã«ã«ãã¢ã€ã«åºãè¡šãããR2ãR3ã¯ããããã
眮æåã¯ç¡çœ®æã®ãã¢ãªãŒã«åºãã¢ã«ãã«åºãã¢
ããåºãè¡šãããåãã§ãç°ãªã€ãŠããŠãããã
R4ã¯ããåŒã ãåŒã ãåŒã ãåŒã ãåŒãâCH2CH2O âã ãåŒã ãåŒã âNHCH2CH2NHCOâãè¡šããã R5ã¯ããåŒã ãåŒã ãåŒã ãåŒã âCH2CH2CH2NHCOâãâNHSO2âã ãåŒã ãåŒãè¡šããã R6ã¯æ°ŽçŽ ååãããã²ã³ååãã¢ã«ãã«åºã
è¡šãããïœã¯ïŒåã¯ïŒãè¡šãããäžè¬åŒïŒïŒã
ïŒïŒã«ãããããšããŒã«ç°äžã®çœ®æåºã¯ããã
ããç°äžã®ãããã®äœçœ®ã«çœ®æããŠãããã ïŒ åèšäžè¬åŒïŒïŒåã¯ïŒïŒã«ãããã
ãå ±ã«âSO2âã§ããããšãç¹åŸŽãšããç¹èš±è«æ±
ã®ç¯å²ã®ç¬¬ïŒé èšèŒã®ã«ã©ãŒåçæå ææã
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8152383A JPS59206833A (ja) | 1983-05-10 | 1983-05-10 | ã«ã©âåçæå ææ |
| US07/018,737 US4717651A (en) | 1983-04-15 | 1987-02-24 | Color photographic light-sensitive material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8152383A JPS59206833A (ja) | 1983-05-10 | 1983-05-10 | ã«ã©âåçæå ææ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59206833A JPS59206833A (ja) | 1984-11-22 |
| JPH0251492B2 true JPH0251492B2 (ja) | 1990-11-07 |
Family
ID=13748692
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8152383A Granted JPS59206833A (ja) | 1983-04-15 | 1983-05-10 | ã«ã©âåçæå ææ |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59206833A (ja) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61169844A (ja) * | 1985-01-23 | 1986-07-31 | Fuji Photo Film Co Ltd | ã«ã©âåçæå ææ |
| IT1199805B (it) * | 1986-12-18 | 1989-01-05 | Minnesota Mining & Mfg | Elementi fotografici a colori agl alogenuri d'argento |
| JP2559245B2 (ja) * | 1987-10-14 | 1996-12-04 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | ããã²ã³åéåçæå ææ |
| JP2533782B2 (ja) * | 1987-11-20 | 1996-09-11 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | ããã²ã³åéã«ã©âåçæå ææ |
| JP2640236B2 (ja) * | 1987-12-11 | 1997-08-13 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | ããã²ã³åéã«ã©ãŒåçæå ææ |
-
1983
- 1983-05-10 JP JP8152383A patent/JPS59206833A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS59206833A (ja) | 1984-11-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH0349092B2 (ja) | ||
| JPS6116063B2 (ja) | ||
| JPH0318175B2 (ja) | ||
| JPH0549975B2 (ja) | ||
| JPS6333694B2 (ja) | ||
| JPH07107601B2 (ja) | ããã²ã³åéã«ã©ãŒåçæå ææ | |
| JPS6245545B2 (ja) | ||
| JPS6291947A (ja) | ããã²ã³åéã«ã©âåçæå ææ | |
| JPH0257295B2 (ja) | ||
| JPS5814668B2 (ja) | ã·ã€ã·ã³ãšãŠã²ã³ãŸãŠã€ã¯ | |
| JPH0332773B2 (ja) | ||
| JPS6326377B2 (ja) | ||
| JPS61189536A (ja) | ããã²ã³åéã«ã©âåçæå ææ | |
| JPH0247734B2 (ja) | ||
| JPS6237777B2 (ja) | ||
| JPH0347489B2 (ja) | ||
| US4336327A (en) | Silver halide emulsion containing yellow coupler | |
| JPS6113748B2 (ja) | ||
| JPH0251492B2 (ja) | ||
| JPS6023855A (ja) | ã«ã©âåçæå ææ | |
| JPH0417413B2 (ja) | ||
| JPH0566576B2 (ja) | ||
| JPS61169845A (ja) | ããã²ã³åéã«ã©âåçæå ææ | |
| JPS5950977B2 (ja) | ã«ã©âåçæå ææ | |
| JPS59204039A (ja) | ã«ã©âåçæå ææ |