JPH0346812B2 - - Google Patents
Info
- Publication number
- JPH0346812B2 JPH0346812B2 JP6949984A JP6949984A JPH0346812B2 JP H0346812 B2 JPH0346812 B2 JP H0346812B2 JP 6949984 A JP6949984 A JP 6949984A JP 6949984 A JP6949984 A JP 6949984A JP H0346812 B2 JPH0346812 B2 JP H0346812B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- silver
- dye
- image
- heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000126 substance Substances 0.000 claims description 82
- -1 silver halide Chemical class 0.000 claims description 53
- 229910052709 silver Inorganic materials 0.000 claims description 36
- 239000004332 silver Substances 0.000 claims description 36
- 239000000463 material Substances 0.000 claims description 30
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims description 28
- 239000011230 binding agent Substances 0.000 claims description 23
- 238000011161 development Methods 0.000 claims description 23
- 125000000217 alkyl group Chemical group 0.000 claims description 15
- 125000003118 aryl group Chemical group 0.000 claims description 11
- 125000003545 alkoxy group Chemical group 0.000 claims description 7
- 239000003638 chemical reducing agent Substances 0.000 claims description 6
- 125000003282 alkyl amino group Chemical group 0.000 claims description 4
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 4
- 125000005843 halogen group Chemical group 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 125000001769 aryl amino group Chemical group 0.000 claims description 2
- 125000001951 carbamoylamino group Chemical group C(N)(=O)N* 0.000 claims description 2
- 125000005647 linker group Chemical group 0.000 claims description 2
- 125000004442 acylamino group Chemical group 0.000 claims 1
- 239000000975 dye Substances 0.000 description 59
- 238000000034 method Methods 0.000 description 29
- 150000001875 compounds Chemical class 0.000 description 26
- 239000002904 solvent Substances 0.000 description 20
- 125000001424 substituent group Chemical group 0.000 description 20
- 239000002253 acid Substances 0.000 description 19
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 15
- 239000000243 solution Substances 0.000 description 15
- 238000012546 transfer Methods 0.000 description 12
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 11
- 239000006185 dispersion Substances 0.000 description 11
- 229920000642 polymer Polymers 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 108010010803 Gelatin Proteins 0.000 description 10
- 150000003863 ammonium salts Chemical class 0.000 description 10
- 229920000159 gelatin Polymers 0.000 description 10
- 239000008273 gelatin Substances 0.000 description 10
- 235000019322 gelatine Nutrition 0.000 description 10
- 235000011852 gelatine desserts Nutrition 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- 150000003839 salts Chemical class 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 238000009835 boiling Methods 0.000 description 9
- 239000000839 emulsion Substances 0.000 description 9
- IBWXIFXUDGADCV-UHFFFAOYSA-N 2h-benzotriazole;silver Chemical compound [Ag].C1=CC=C2NN=NC2=C1 IBWXIFXUDGADCV-UHFFFAOYSA-N 0.000 description 8
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 8
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 229910052751 metal Chemical group 0.000 description 7
- 239000002184 metal Chemical group 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 6
- 239000005020 polyethylene terephthalate Substances 0.000 description 6
- 229920000139 polyethylene terephthalate Polymers 0.000 description 6
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 6
- 159000000000 sodium salts Chemical class 0.000 description 6
- 238000003786 synthesis reaction Methods 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 206010070834 Sensitisation Diseases 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 239000000470 constituent Substances 0.000 description 5
- 238000011109 contamination Methods 0.000 description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- 238000010992 reflux Methods 0.000 description 5
- 238000011160 research Methods 0.000 description 5
- 230000008313 sensitization Effects 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 239000011593 sulfur Substances 0.000 description 5
- 229910052717 sulfur Inorganic materials 0.000 description 5
- QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 4
- PLYFWZGSBMDRKW-UHFFFAOYSA-N 2h-benzotriazole-4-sulfonic acid;silver Chemical compound [Ag].OS(=O)(=O)C1=CC=CC2=NNN=C12 PLYFWZGSBMDRKW-UHFFFAOYSA-N 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 125000003277 amino group Chemical group 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 125000003754 ethoxycarbonyl group Chemical group C(=O)(OCC)* 0.000 description 4
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 4
- 230000002209 hydrophobic effect Effects 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000011259 mixed solution Substances 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 4
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 150000003378 silver Chemical class 0.000 description 4
- 238000010186 staining Methods 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- ZNZYKNKBJPZETN-WELNAUFTSA-N Dialdehyde 11678 Chemical compound N1C2=CC=CC=C2C2=C1[C@H](C[C@H](/C(=C/O)C(=O)OC)[C@@H](C=C)C=O)NCC2 ZNZYKNKBJPZETN-WELNAUFTSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 3
- 239000012964 benzotriazole Substances 0.000 description 3
- 229910052794 bromium Inorganic materials 0.000 description 3
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 229910052740 iodine Inorganic materials 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 230000001235 sensitizing effect Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 230000003595 spectral effect Effects 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- XBYRMPXUBGMOJC-UHFFFAOYSA-N 1,2-dihydropyrazol-3-one Chemical compound OC=1C=CNN=1 XBYRMPXUBGMOJC-UHFFFAOYSA-N 0.000 description 2
- AFBBKYQYNPNMAT-UHFFFAOYSA-N 1h-1,2,4-triazol-1-ium-3-thiolate Chemical compound SC=1N=CNN=1 AFBBKYQYNPNMAT-UHFFFAOYSA-N 0.000 description 2
- WXTMDXOMEHJXQO-UHFFFAOYSA-N 2,5-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC(O)=CC=C1O WXTMDXOMEHJXQO-UHFFFAOYSA-N 0.000 description 2
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 description 2
- WNZQDUSMALZDQF-UHFFFAOYSA-N 2-benzofuran-1(3H)-one Chemical compound C1=CC=C2C(=O)OCC2=C1 WNZQDUSMALZDQF-UHFFFAOYSA-N 0.000 description 2
- NEAQRZUHTPSBBM-UHFFFAOYSA-N 2-hydroxy-3,3-dimethyl-7-nitro-4h-isoquinolin-1-one Chemical compound C1=C([N+]([O-])=O)C=C2C(=O)N(O)C(C)(C)CC2=C1 NEAQRZUHTPSBBM-UHFFFAOYSA-N 0.000 description 2
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- MLCZOHLVCQVKPI-UHFFFAOYSA-N 4-methyl-2h-benzotriazole;silver Chemical compound [Ag].CC1=CC=CC2=C1N=NN2 MLCZOHLVCQVKPI-UHFFFAOYSA-N 0.000 description 2
- VPKWVNHDLVBJNG-UHFFFAOYSA-N 5-nitro-2H-benzotriazol-4-ol silver Chemical compound [Ag].OC1=C(C=CC=2NN=NC21)[N+](=O)[O-] VPKWVNHDLVBJNG-UHFFFAOYSA-N 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- PCLIMKBDDGJMGD-UHFFFAOYSA-N N-bromosuccinimide Chemical compound BrN1C(=O)CCC1=O PCLIMKBDDGJMGD-UHFFFAOYSA-N 0.000 description 2
- JRNVZBWKYDBUCA-UHFFFAOYSA-N N-chlorosuccinimide Chemical compound ClN1C(=O)CCC1=O JRNVZBWKYDBUCA-UHFFFAOYSA-N 0.000 description 2
- LQZMLBORDGWNPD-UHFFFAOYSA-N N-iodosuccinimide Chemical compound IN1C(=O)CCC1=O LQZMLBORDGWNPD-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- 229910001864 baryta Inorganic materials 0.000 description 2
- XSCHRSMBECNVNS-UHFFFAOYSA-N benzopyrazine Natural products N1=CC=NC2=CC=CC=C21 XSCHRSMBECNVNS-UHFFFAOYSA-N 0.000 description 2
- 150000001565 benzotriazoles Chemical class 0.000 description 2
- UUZYBYIOAZTMGC-UHFFFAOYSA-M benzyl(trimethyl)azanium;bromide Chemical compound [Br-].C[N+](C)(C)CC1=CC=CC=C1 UUZYBYIOAZTMGC-UHFFFAOYSA-M 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 125000004181 carboxyalkyl group Chemical group 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 229920002301 cellulose acetate Polymers 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 125000001240 enamine group Chemical group 0.000 description 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 150000008282 halocarbons Chemical class 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 2
- 125000001841 imino group Chemical group [H]N=* 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- OKJPEAGHQZHRQV-UHFFFAOYSA-N iodoform Chemical compound IC(I)I OKJPEAGHQZHRQV-UHFFFAOYSA-N 0.000 description 2
- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 2
- 125000004170 methylsulfonyl group Chemical group [H]C([H])([H])S(*)(=O)=O 0.000 description 2
- HRRDCWDFRIJIQZ-UHFFFAOYSA-N naphthalene-1,8-dicarboxylic acid Chemical compound C1=CC(C(O)=O)=C2C(C(=O)O)=CC=CC2=C1 HRRDCWDFRIJIQZ-UHFFFAOYSA-N 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical class O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 2
- 229940100890 silver compound Drugs 0.000 description 2
- 150000003379 silver compounds Chemical class 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 125000004964 sulfoalkyl group Chemical group 0.000 description 2
- 229940124530 sulfonamide Drugs 0.000 description 2
- 150000003456 sulfonamides Chemical class 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000001132 ultrasonic dispersion Methods 0.000 description 2
- GVTLFGJNTIRUEG-ZHACJKMWSA-N (e)-n-(3-methoxyphenyl)-3-phenylprop-2-enamide Chemical compound COC1=CC=CC(NC(=O)\C=C\C=2C=CC=CC=2)=C1 GVTLFGJNTIRUEG-ZHACJKMWSA-N 0.000 description 1
- HGRZLIGHKHRTRE-UHFFFAOYSA-N 1,2,3,4-tetrabromobutane Chemical compound BrCC(Br)C(Br)CBr HGRZLIGHKHRTRE-UHFFFAOYSA-N 0.000 description 1
- OWQPOVKKUWUEKE-UHFFFAOYSA-N 1,2,3-benzotriazine Chemical compound N1=NN=CC2=CC=CC=C21 OWQPOVKKUWUEKE-UHFFFAOYSA-N 0.000 description 1
- IZQGCATXOBZJQL-UHFFFAOYSA-N 1,3-benzothiazine-2,4-dione Chemical compound C1=CC=C2SC(=O)NC(=O)C2=C1 IZQGCATXOBZJQL-UHFFFAOYSA-N 0.000 description 1
- STOQYCJHYNCPTL-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione;silver Chemical compound [Ag].C1=CC=C2NC(=S)NC2=C1 STOQYCJHYNCPTL-UHFFFAOYSA-N 0.000 description 1
- GUMZPHOQHLZJOY-UHFFFAOYSA-N 1,3-oxazine-2,4-dione Chemical compound O=C1C=COC(=O)N1 GUMZPHOQHLZJOY-UHFFFAOYSA-N 0.000 description 1
- ODIRBFFBCSTPTO-UHFFFAOYSA-N 1,3-selenazole Chemical compound C1=C[se]C=N1 ODIRBFFBCSTPTO-UHFFFAOYSA-N 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- TXCHYYGSRHDEBU-UHFFFAOYSA-N 1-(2H-benzotriazol-5-yldiazenyl)naphthalen-2-ol silver Chemical compound [Ag].OC1=C(N=NC2=CC=C3NN=NC3=C2)C2=CC=CC=C2C=C1 TXCHYYGSRHDEBU-UHFFFAOYSA-N 0.000 description 1
- WDRZVZVXHZNSFG-UHFFFAOYSA-N 1-ethenylpyridin-1-ium Chemical compound C=C[N+]1=CC=CC=C1 WDRZVZVXHZNSFG-UHFFFAOYSA-N 0.000 description 1
- IQIOOZJZTRAXTO-UHFFFAOYSA-M 1-ethyl-2H-1,3-thiazol-2-ylium bromide Chemical compound [Br-].CCS1=CC=N[CH+]1 IQIOOZJZTRAXTO-UHFFFAOYSA-M 0.000 description 1
- HFZLSTDPRQSZCQ-UHFFFAOYSA-N 1-pyrrolidin-3-ylpyrrolidine Chemical compound C1CCCN1C1CNCC1 HFZLSTDPRQSZCQ-UHFFFAOYSA-N 0.000 description 1
- AVRPFRMDMNDIDH-UHFFFAOYSA-N 1h-quinazolin-2-one Chemical compound C1=CC=CC2=NC(O)=NC=C21 AVRPFRMDMNDIDH-UHFFFAOYSA-N 0.000 description 1
- OGYMWUMPVDTUCW-UHFFFAOYSA-N 2,2-bis(2-ethylhexyl)-3-sulfobutanedioic acid Chemical compound CCCCC(CC)CC(C(O)=O)(C(C(O)=O)S(O)(=O)=O)CC(CC)CCCC OGYMWUMPVDTUCW-UHFFFAOYSA-N 0.000 description 1
- KGLPWQKSKUVKMJ-UHFFFAOYSA-N 2,3-dihydrophthalazine-1,4-dione Chemical compound C1=CC=C2C(=O)NNC(=O)C2=C1 KGLPWQKSKUVKMJ-UHFFFAOYSA-N 0.000 description 1
- CTOQUCNYLFHOAH-UHFFFAOYSA-N 2,3-dihydropyrrolo[2,3-d]triazole-5,6-dithione Chemical compound N1NN=C2C(=S)C(=S)N=C21 CTOQUCNYLFHOAH-UHFFFAOYSA-N 0.000 description 1
- 125000004201 2,4-dichlorophenyl group Chemical group [H]C1=C([H])C(*)=C(Cl)C([H])=C1Cl 0.000 description 1
- PYMWDAQVSJGRIA-UHFFFAOYSA-N 2-(1-bromo-6-methylcyclohexa-2,4-dien-1-yl)acetamide Chemical compound CC1C=CC=CC1(Br)CC(N)=O PYMWDAQVSJGRIA-UHFFFAOYSA-N 0.000 description 1
- DYNQKTWPOTTWGS-UHFFFAOYSA-N 2-(1-bromo-6-methylcyclohexa-2,4-dien-1-yl)sulfonylacetamide Chemical compound CC1C=CC=CC1(Br)S(=O)(=O)CC(N)=O DYNQKTWPOTTWGS-UHFFFAOYSA-N 0.000 description 1
- XXXFZKQPYACQLD-UHFFFAOYSA-N 2-(2-hydroxyethoxy)ethyl acetate Chemical compound CC(=O)OCCOCCO XXXFZKQPYACQLD-UHFFFAOYSA-N 0.000 description 1
- DUIMITDEOYCHER-UHFFFAOYSA-N 2-(2H-benzotriazol-5-yldiazenyl)-4-methoxynaphthalen-1-ol silver Chemical compound N1N=NC2=C1C=CC(=C2)N=NC2=C(C1=CC=CC=C1C(=C2)OC)O.[Ag] DUIMITDEOYCHER-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- YUUNLFNRYZDMQC-UHFFFAOYSA-N 2-(4-hydroxy-2H-benzotriazol-5-yl)acetic acid silver Chemical compound [Ag].OC1=C(C=CC=2NN=NC21)CC(=O)O YUUNLFNRYZDMQC-UHFFFAOYSA-N 0.000 description 1
- PTTPXKJBFFKCEK-UHFFFAOYSA-N 2-Methyl-4-heptanone Chemical compound CC(C)CC(=O)CC(C)C PTTPXKJBFFKCEK-UHFFFAOYSA-N 0.000 description 1
- PVMAFQFVCVBLNU-UHFFFAOYSA-N 2-[(4-hydroxy-2H-benzotriazol-5-yl)oxy]acetic acid silver Chemical compound [Ag].OC1=C(C=CC=2NN=NC21)OCC(=O)O PVMAFQFVCVBLNU-UHFFFAOYSA-N 0.000 description 1
- AYNDSQMEJOTQIT-UHFFFAOYSA-N 2-[(6-nitro-2h-benzotriazol-5-yl)oxy]acetic acid;silver Chemical compound [Ag].C1=C([N+]([O-])=O)C(OCC(=O)O)=CC2=NNN=C21 AYNDSQMEJOTQIT-UHFFFAOYSA-N 0.000 description 1
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 1
- YAQLSKVCTLCIIE-UHFFFAOYSA-N 2-bromobutyric acid Chemical compound CCC(Br)C(O)=O YAQLSKVCTLCIIE-UHFFFAOYSA-N 0.000 description 1
- LDLCZOVUSADOIV-UHFFFAOYSA-N 2-bromoethanol Chemical compound OCCBr LDLCZOVUSADOIV-UHFFFAOYSA-N 0.000 description 1
- MARXMDRWROUXMD-UHFFFAOYSA-N 2-bromoisoindole-1,3-dione Chemical compound C1=CC=C2C(=O)N(Br)C(=O)C2=C1 MARXMDRWROUXMD-UHFFFAOYSA-N 0.000 description 1
- CQJNLNKTOGXYCH-UHFFFAOYSA-N 2-bromophthalazin-1-one Chemical compound C1=CC=C2C(=O)N(Br)N=CC2=C1 CQJNLNKTOGXYCH-UHFFFAOYSA-N 0.000 description 1
- SZTBMYHIYNGYIA-UHFFFAOYSA-M 2-chloroacrylate Chemical compound [O-]C(=O)C(Cl)=C SZTBMYHIYNGYIA-UHFFFAOYSA-M 0.000 description 1
- KSBRTGXRNZVPAT-UHFFFAOYSA-N 2-chlorophthalazin-1-one Chemical compound C1=CC=C2C(=O)N(Cl)N=CC2=C1 KSBRTGXRNZVPAT-UHFFFAOYSA-N 0.000 description 1
- VKNASXZDGZNEDA-UHFFFAOYSA-N 2-cyanoethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCC#N VKNASXZDGZNEDA-UHFFFAOYSA-N 0.000 description 1
- KTWCUGUUDHJVIH-UHFFFAOYSA-N 2-hydroxybenzo[de]isoquinoline-1,3-dione Chemical compound C1=CC(C(N(O)C2=O)=O)=C3C2=CC=CC3=C1 KTWCUGUUDHJVIH-UHFFFAOYSA-N 0.000 description 1
- YZOXPLQWARQVEJ-UHFFFAOYSA-N 2-methylsulfonyl-1,3-benzothiazole Chemical compound C1=CC=C2SC(S(=O)(=O)C)=NC2=C1 YZOXPLQWARQVEJ-UHFFFAOYSA-N 0.000 description 1
- RSEBUVRVKCANEP-UHFFFAOYSA-N 2-pyrroline Chemical compound C1CC=CN1 RSEBUVRVKCANEP-UHFFFAOYSA-N 0.000 description 1
- UGWULZWUXSCWPX-UHFFFAOYSA-N 2-sulfanylideneimidazolidin-4-one Chemical class O=C1CNC(=S)N1 UGWULZWUXSCWPX-UHFFFAOYSA-N 0.000 description 1
- XQITUXIEASXIMZ-UHFFFAOYSA-N 2-sulfooctadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(C(O)=O)S(O)(=O)=O XQITUXIEASXIMZ-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- DNMNQAUVYXEIKX-UHFFFAOYSA-N 2H-benzotriazol-4-ol silver Chemical compound [Ag].Oc1cccc2[nH]nnc12 DNMNQAUVYXEIKX-UHFFFAOYSA-N 0.000 description 1
- VQYCQWZFTSTAIQ-UHFFFAOYSA-N 2H-benzotriazol-5-ol silver Chemical compound [Ag].OC1=CC2=C(NN=N2)C=C1 VQYCQWZFTSTAIQ-UHFFFAOYSA-N 0.000 description 1
- UFIAWLACMHGBIS-UHFFFAOYSA-N 2H-benzotriazole-4,6-diol silver Chemical compound [Ag].OC1=CC(=CC=2NN=NC21)O UFIAWLACMHGBIS-UHFFFAOYSA-N 0.000 description 1
- CMLFRMDBDNHMRA-UHFFFAOYSA-N 2h-1,2-benzoxazine Chemical compound C1=CC=C2C=CNOC2=C1 CMLFRMDBDNHMRA-UHFFFAOYSA-N 0.000 description 1
- HEIRXAZWPOSGIQ-UHFFFAOYSA-N 2h-benzotriazole-4-carboxylic acid;silver Chemical compound [Ag].OC(=O)C1=CC=CC2=NNN=C12 HEIRXAZWPOSGIQ-UHFFFAOYSA-N 0.000 description 1
- UUPDERKICQBDKW-UHFFFAOYSA-N 2h-benzotriazole-4-sulfonamide;silver Chemical compound [Ag].NS(=O)(=O)C1=CC=CC2=NNN=C12 UUPDERKICQBDKW-UHFFFAOYSA-N 0.000 description 1
- HGKDENRPLPWAKJ-UHFFFAOYSA-N 2h-benzotriazole-5,6-dicarboxylic acid;silver Chemical compound [Ag].C1=C(C(O)=O)C(C(=O)O)=CC2=NNN=C21 HGKDENRPLPWAKJ-UHFFFAOYSA-N 0.000 description 1
- ZSZHFJYOWDHCSN-UHFFFAOYSA-N 2h-benzotriazole-5-carboxamide;silver Chemical compound [Ag].C1=C(C(=O)N)C=CC2=NNN=C21 ZSZHFJYOWDHCSN-UHFFFAOYSA-N 0.000 description 1
- VAVIJGPIFNIPSG-UHFFFAOYSA-N 2h-benzotriazole-5-carboxylic acid;silver Chemical compound [Ag].C1=C(C(=O)O)C=CC2=NNN=C21 VAVIJGPIFNIPSG-UHFFFAOYSA-N 0.000 description 1
- MMSSUHGNWNZJRZ-UHFFFAOYSA-N 2h-benzotriazole-5-sulfonic acid;silver Chemical compound [Ag].C1=C(S(=O)(=O)O)C=CC2=NNN=C21 MMSSUHGNWNZJRZ-UHFFFAOYSA-N 0.000 description 1
- YPVPEILJJPUFMZ-UHFFFAOYSA-N 2h-benzotriazole;2-hydroxybenzenesulfonamide;silver Chemical compound [Ag].C1=CC=CC2=NNN=C21.NS(=O)(=O)C1=CC=CC=C1O YPVPEILJJPUFMZ-UHFFFAOYSA-N 0.000 description 1
- UKYRKNJJZACCEC-UHFFFAOYSA-N 2h-benzotriazole;silver;2-sulfamoylbenzenesulfonic acid Chemical compound [Ag].C1=CC=CC2=NNN=C21.NS(=O)(=O)C1=CC=CC=C1S(O)(=O)=O UKYRKNJJZACCEC-UHFFFAOYSA-N 0.000 description 1
- XOHUESSDMRKYEV-UHFFFAOYSA-N 2h-phthalazin-1-one;silver Chemical compound [Ag].C1=CC=C2C(=O)NN=CC2=C1 XOHUESSDMRKYEV-UHFFFAOYSA-N 0.000 description 1
- QGGXUUYCRXZROA-UHFFFAOYSA-N 3,4-bis(methoxycarbonyl)benzenesulfonic acid Chemical compound COC(=O)C1=CC=C(S(O)(=O)=O)C=C1C(=O)OC QGGXUUYCRXZROA-UHFFFAOYSA-N 0.000 description 1
- ZDGHHRPKFCVOJL-UHFFFAOYSA-N 3-hydrazinylbenzenesulfonic acid Chemical compound NNC1=CC=CC(S(O)(=O)=O)=C1 ZDGHHRPKFCVOJL-UHFFFAOYSA-N 0.000 description 1
- OGMRHLUHIHYVRU-UHFFFAOYSA-M 3-methyl-1,3-thiazol-3-ium;bromide Chemical compound [Br-].C[N+]=1C=CSC=1 OGMRHLUHIHYVRU-UHFFFAOYSA-M 0.000 description 1
- GPJUVPHNQFWGKA-UHFFFAOYSA-N 3h-1,3-benzothiazole-2-thione;silver Chemical compound [Ag].C1=CC=C2SC(=S)NC2=C1 GPJUVPHNQFWGKA-UHFFFAOYSA-N 0.000 description 1
- AMHVHKFKFDBCTE-UHFFFAOYSA-N 3h-1,3-benzoxazole-2-thione;silver Chemical compound [Ag].C1=CC=C2OC(S)=NC2=C1 AMHVHKFKFDBCTE-UHFFFAOYSA-N 0.000 description 1
- KVUKKQPCWRVNSK-UHFFFAOYSA-N 4-(4-hydroxy-2H-benzotriazol-5-yl)benzenesulfonic acid silver Chemical compound [Ag].OC1=C(C=CC=2NN=NC21)C2=CC=C(C=C2)S(=O)(=O)O KVUKKQPCWRVNSK-UHFFFAOYSA-N 0.000 description 1
- XPBQQAHIVODAIC-UHFFFAOYSA-N 4-bromobutylbenzene Chemical compound BrCCCCC1=CC=CC=C1 XPBQQAHIVODAIC-UHFFFAOYSA-N 0.000 description 1
- VWVGXRZAWQKZQB-UHFFFAOYSA-N 4-chloro-2h-benzotriazole;silver Chemical compound [Ag].ClC1=CC=CC2=NNN=C12 VWVGXRZAWQKZQB-UHFFFAOYSA-N 0.000 description 1
- GOUHYARYYWKXHS-UHFFFAOYSA-N 4-formylbenzoic acid Chemical compound OC(=O)C1=CC=C(C=O)C=C1 GOUHYARYYWKXHS-UHFFFAOYSA-N 0.000 description 1
- GUVYHKPLQUZCCX-UHFFFAOYSA-N 4-hydroxy-2H-benzotriazole-5-carbonitrile silver Chemical compound [Ag].OC1=C(C=CC=2NN=NC21)C#N GUVYHKPLQUZCCX-UHFFFAOYSA-N 0.000 description 1
- LETYJLSIDFTIJM-UHFFFAOYSA-N 4-hydroxy-2H-benzotriazole-5-carboxylic acid silver Chemical compound [Ag].OC1=C(C=CC=2NN=NC21)C(=O)O LETYJLSIDFTIJM-UHFFFAOYSA-N 0.000 description 1
- YRRCATIIGZMMIW-UHFFFAOYSA-N 4-hydroxy-2H-benzotriazole-5-sulfonic acid silver Chemical compound [Ag].OC1=C(C=CC=2NN=NC21)S(=O)(=O)O YRRCATIIGZMMIW-UHFFFAOYSA-N 0.000 description 1
- FXKQPQOOZSXQAG-UHFFFAOYSA-N 4-methyltriazine Chemical compound CC1=CC=NN=N1 FXKQPQOOZSXQAG-UHFFFAOYSA-N 0.000 description 1
- UTMDJGPRCLQPBT-UHFFFAOYSA-N 4-nitro-1h-1,2,3-benzotriazole Chemical class [O-][N+](=O)C1=CC=CC2=NNN=C12 UTMDJGPRCLQPBT-UHFFFAOYSA-N 0.000 description 1
- XHQIJHOXQWEWNO-UHFFFAOYSA-N 4-nitro-2h-benzotriazole;silver Chemical compound [Ag].[O-][N+](=O)C1=CC=CC2=NNN=C12 XHQIJHOXQWEWNO-UHFFFAOYSA-N 0.000 description 1
- UWAZUCRCJKCIAZ-UHFFFAOYSA-N 5,7-dinitro-2H-benzotriazol-4-ol silver Chemical compound OC1=C(C=C(C=2NN=NC21)[N+](=O)[O-])[N+](=O)[O-].[Ag] UWAZUCRCJKCIAZ-UHFFFAOYSA-N 0.000 description 1
- LCVPUZZJHISVIL-UHFFFAOYSA-N 5-(2-ethoxy-2-oxoethoxy)-2h-benzotriazole-4-carboxylic acid;silver Chemical compound [Ag].OC(=O)C1=C(OCC(=O)OCC)C=CC2=NNN=C21 LCVPUZZJHISVIL-UHFFFAOYSA-N 0.000 description 1
- KOHQEDCONWTWEQ-UHFFFAOYSA-N 5-(2-ethoxy-2-oxoethoxy)-2h-benzotriazole-4-sulfonic acid;silver Chemical compound [Ag].OS(=O)(=O)C1=C(OCC(=O)OCC)C=CC2=NNN=C21 KOHQEDCONWTWEQ-UHFFFAOYSA-N 0.000 description 1
- OGGACJRXFMCVRC-UHFFFAOYSA-N 5-(2-ethoxy-2-oxoethyl)-2h-benzotriazole-4-sulfonic acid;silver Chemical compound [Ag].OS(=O)(=O)C1=C(CC(=O)OCC)C=CC2=NNN=C21 OGGACJRXFMCVRC-UHFFFAOYSA-N 0.000 description 1
- QIUIIIPBGSHQFY-UHFFFAOYSA-N 5-(4-nitrophenyl)-2H-benzotriazol-4-ol silver Chemical compound [Ag].OC1=C(C=CC=2NN=NC21)C2=CC=C(C=C2)[N+](=O)[O-] QIUIIIPBGSHQFY-UHFFFAOYSA-N 0.000 description 1
- XFKMXXDXKIYVKH-UHFFFAOYSA-N 5-(4-nitrophenyl)-2h-benzotriazole-4-carboxylic acid;silver Chemical compound [Ag].C1=CC2=NNN=C2C(C(=O)O)=C1C1=CC=C([N+]([O-])=O)C=C1 XFKMXXDXKIYVKH-UHFFFAOYSA-N 0.000 description 1
- UWBZQBXZSLYATH-UHFFFAOYSA-N 5-(4-nitrophenyl)-2h-benzotriazole-4-sulfonic acid;silver Chemical compound [Ag].C1=CC2=NNN=C2C(S(=O)(=O)O)=C1C1=CC=C([N+]([O-])=O)C=C1 UWBZQBXZSLYATH-UHFFFAOYSA-N 0.000 description 1
- UXYCQFBMYVHWCD-UHFFFAOYSA-N 5-(carboxymethyl)-2h-benzotriazole-4-carboxylic acid;silver Chemical compound [Ag].OC(=O)C1=C(CC(=O)O)C=CC2=NNN=C21 UXYCQFBMYVHWCD-UHFFFAOYSA-N 0.000 description 1
- GEPQDSDPIKTAQZ-UHFFFAOYSA-N 5-acetamido-2h-benzotriazole-4-carboxylic acid;silver Chemical compound [Ag].OC(=O)C1=C(NC(=O)C)C=CC2=NNN=C21 GEPQDSDPIKTAQZ-UHFFFAOYSA-N 0.000 description 1
- HKYVZSAUMXEWSM-UHFFFAOYSA-N 5-acetamido-2h-benzotriazole-4-sulfonic acid;silver Chemical compound [Ag].OS(=O)(=O)C1=C(NC(=O)C)C=CC2=NNN=C21 HKYVZSAUMXEWSM-UHFFFAOYSA-N 0.000 description 1
- VXADKSZHKMWPPQ-UHFFFAOYSA-N 5-amino-2H-benzotriazol-4-ol silver Chemical compound [Ag].OC1=C(C=CC=2NN=NC21)N VXADKSZHKMWPPQ-UHFFFAOYSA-N 0.000 description 1
- HQONCMUTVXCNKO-UHFFFAOYSA-N 5-amino-2h-benzotriazole-4-carboxylic acid;silver Chemical compound [Ag].OC(=O)C1=C(N)C=CC2=NNN=C21 HQONCMUTVXCNKO-UHFFFAOYSA-N 0.000 description 1
- PUUBBNLVXJJRKR-UHFFFAOYSA-N 5-amino-2h-benzotriazole-4-sulfonic acid;silver Chemical compound [Ag].OS(=O)(=O)C1=C(N)C=CC2=NNN=C21 PUUBBNLVXJJRKR-UHFFFAOYSA-N 0.000 description 1
- HGKMUJVZOYHQLE-UHFFFAOYSA-N 5-chloro-2H-benzotriazol-4-ol silver Chemical compound [Ag].OC1=C(C=CC=2NN=NC21)Cl HGKMUJVZOYHQLE-UHFFFAOYSA-N 0.000 description 1
- FKQVBYIFZVIJAB-UHFFFAOYSA-N 5-chloro-2h-benzotriazole-4-carboxylic acid;silver Chemical compound [Ag].OC(=O)C1=C(Cl)C=CC2=NNN=C12 FKQVBYIFZVIJAB-UHFFFAOYSA-N 0.000 description 1
- WXHAFROXDSNSNA-UHFFFAOYSA-N 5-chloro-2h-benzotriazole-4-sulfonic acid;silver Chemical compound [Ag].OS(=O)(=O)C1=C(Cl)C=CC2=NNN=C12 WXHAFROXDSNSNA-UHFFFAOYSA-N 0.000 description 1
- VYLMOMINLRGEMR-UHFFFAOYSA-N 5-chloro-4,6-dinitro-2h-benzotriazole;silver Chemical compound [Ag].[O-][N+](=O)C1=C(Cl)C([N+](=O)[O-])=CC2=NNN=C21 VYLMOMINLRGEMR-UHFFFAOYSA-N 0.000 description 1
- NBWYUUUULKYVMY-UHFFFAOYSA-N 5-chloro-6-nitro-2h-benzotriazole;silver Chemical compound [Ag].C1=C(Cl)C([N+](=O)[O-])=CC2=NNN=C21 NBWYUUUULKYVMY-UHFFFAOYSA-N 0.000 description 1
- NUNXISICBRDBPK-UHFFFAOYSA-N 5-cyano-2h-benzotriazole-4-sulfonic acid;silver Chemical compound [Ag].OS(=O)(=O)C1=C(C#N)C=CC2=NNN=C12 NUNXISICBRDBPK-UHFFFAOYSA-N 0.000 description 1
- IDYWQTUXKZTZLQ-UHFFFAOYSA-N 5-methoxy-2H-benzotriazol-4-ol silver Chemical compound [Ag].OC1=C(C=CC=2NN=NC21)OC IDYWQTUXKZTZLQ-UHFFFAOYSA-N 0.000 description 1
- HLDWGAUXHLROCB-UHFFFAOYSA-N 5-methoxy-2h-benzotriazole-4-carboxylic acid;silver Chemical compound [Ag].OC(=O)C1=C(OC)C=CC2=NNN=C21 HLDWGAUXHLROCB-UHFFFAOYSA-N 0.000 description 1
- RNUNNQMSQDZTGA-UHFFFAOYSA-N 5-methoxy-2h-benzotriazole-4-sulfonic acid;silver Chemical compound [Ag].OS(=O)(=O)C1=C(OC)C=CC2=NNN=C21 RNUNNQMSQDZTGA-UHFFFAOYSA-N 0.000 description 1
- JAVSUZRJEUOVIW-UHFFFAOYSA-N 5-methoxy-4,6-dinitro-2h-benzotriazole;silver Chemical compound [Ag].[O-][N+](=O)C1=C(OC)C([N+]([O-])=O)=CC2=NNN=C21 JAVSUZRJEUOVIW-UHFFFAOYSA-N 0.000 description 1
- FKAXDTZKJSWMMA-UHFFFAOYSA-N 5-methoxy-6-nitro-2h-benzotriazole;silver Chemical compound [Ag].C1=C([N+]([O-])=O)C(OC)=CC2=NNN=C21 FKAXDTZKJSWMMA-UHFFFAOYSA-N 0.000 description 1
- NJPMMJJVLGNCON-UHFFFAOYSA-N 5-methyl-2,3-dihydrotriazolo[4,5-d]pyrimidin-7-one;silver Chemical compound [Ag].O=C1N=C(C)N=C2NNN=C21 NJPMMJJVLGNCON-UHFFFAOYSA-N 0.000 description 1
- FEDXQJCJZHSFJC-UHFFFAOYSA-N 5-methyl-2H-benzotriazol-4-ol silver Chemical compound [Ag].OC1=C(C=CC=2NN=NC21)C FEDXQJCJZHSFJC-UHFFFAOYSA-N 0.000 description 1
- ZOOABFASFMLFTR-UHFFFAOYSA-N 5-methyl-2h-benzotriazole-4-carboxylic acid;silver Chemical compound [Ag].OC(=O)C1=C(C)C=CC2=NNN=C21 ZOOABFASFMLFTR-UHFFFAOYSA-N 0.000 description 1
- UVEGBIASMHQMQJ-UHFFFAOYSA-N 5-methyl-2h-benzotriazole-4-sulfonic acid;silver Chemical compound [Ag].OS(=O)(=O)C1=C(C)C=CC2=NNN=C21 UVEGBIASMHQMQJ-UHFFFAOYSA-N 0.000 description 1
- FDFNTSAWIDKMFP-UHFFFAOYSA-N 5-methyl-6-nitro-2h-benzotriazole;silver Chemical compound [Ag].C1=C([N+]([O-])=O)C(C)=CC2=NNN=C21 FDFNTSAWIDKMFP-UHFFFAOYSA-N 0.000 description 1
- KEACENITOZRSJT-UHFFFAOYSA-N 5-nitro-2h-benzotriazole-4-carboxylic acid;silver Chemical compound [Ag].OC(=O)C1=C([N+]([O-])=O)C=CC2=NNN=C12 KEACENITOZRSJT-UHFFFAOYSA-N 0.000 description 1
- BBGRQUUSRRKFSS-UHFFFAOYSA-N 5-nitro-2h-benzotriazole;silver Chemical compound [Ag].C1=C([N+](=O)[O-])C=CC2=NNN=C21 BBGRQUUSRRKFSS-UHFFFAOYSA-N 0.000 description 1
- RXACCCLYSOFTFW-UHFFFAOYSA-N 5-nitrobenzene-1,3-dicarbaldehyde Chemical compound [O-][N+](=O)C1=CC(C=O)=CC(C=O)=C1 RXACCCLYSOFTFW-UHFFFAOYSA-N 0.000 description 1
- GWXIEDHZMGXUKM-UHFFFAOYSA-N 5-phenyl-2H-benzotriazol-4-ol silver Chemical compound [Ag].OC1=C(C=CC=2NN=NC21)C2=CC=CC=C2 GWXIEDHZMGXUKM-UHFFFAOYSA-N 0.000 description 1
- QRCYCQILRCMCEG-UHFFFAOYSA-N 5-phenyl-2h-benzotriazole-4-carboxylic acid;silver Chemical compound [Ag].C1=CC2=NNN=C2C(C(=O)O)=C1C1=CC=CC=C1 QRCYCQILRCMCEG-UHFFFAOYSA-N 0.000 description 1
- HDGFGYSIIXYKBT-UHFFFAOYSA-N 5-phenyl-2h-benzotriazole-4-sulfonic acid;silver Chemical compound [Ag].C1=CC2=NNN=C2C(S(=O)(=O)O)=C1C1=CC=CC=C1 HDGFGYSIIXYKBT-UHFFFAOYSA-N 0.000 description 1
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 1
- QSHQKZDOLGDGLD-UHFFFAOYSA-N 6-chloro-5-methoxy-2h-benzotriazole-4-sulfonic acid;silver Chemical compound [Ag].OS(=O)(=O)C1=C(OC)C(Cl)=CC2=NNN=C21 QSHQKZDOLGDGLD-UHFFFAOYSA-N 0.000 description 1
- LLKFECWNVQJWQC-UHFFFAOYSA-N 6-chloro-5-nitro-2H-benzotriazol-4-ol silver Chemical compound OC1=C(C(=CC=2NN=NC21)Cl)[N+](=O)[O-].[Ag] LLKFECWNVQJWQC-UHFFFAOYSA-N 0.000 description 1
- ICTRITZRUJGWEW-UHFFFAOYSA-N 6-chloro-7-sulfo-2h-benzotriazole-5-carboxylic acid;silver Chemical compound [Ag].OS(=O)(=O)C1=C(Cl)C(C(=O)O)=CC2=NNN=C21 ICTRITZRUJGWEW-UHFFFAOYSA-N 0.000 description 1
- STZPIDYYPWJEJM-UHFFFAOYSA-N 6-hydroxy-2H-benzotriazole-5-carboxylic acid silver Chemical compound [Ag].C(=O)(O)C1=CC2=C(NN=N2)C=C1O STZPIDYYPWJEJM-UHFFFAOYSA-N 0.000 description 1
- QKBLSRCBFAWSPP-UHFFFAOYSA-N 6-methyl-5-nitro-2H-benzotriazol-4-ol silver Chemical compound OC1=C(C(=CC=2NN=NC21)C)[N+](=O)[O-].[Ag] QKBLSRCBFAWSPP-UHFFFAOYSA-N 0.000 description 1
- JEOQXAQUIVZJNX-UHFFFAOYSA-N 6-nitro-2h-benzotriazol-5-amine;silver Chemical compound [Ag].C1=C([N+]([O-])=O)C(N)=CC2=NNN=C21 JEOQXAQUIVZJNX-UHFFFAOYSA-N 0.000 description 1
- VUKLGFRIKFBJFN-UHFFFAOYSA-N 6-nitro-2h-benzotriazole-4-carbonitrile;silver Chemical compound [Ag].C1=C([N+](=O)[O-])C=C(C#N)C2=NNN=C21 VUKLGFRIKFBJFN-UHFFFAOYSA-N 0.000 description 1
- SLBUGEPSVBECEY-UHFFFAOYSA-N 6-nitro-2h-benzotriazole-4-carboxamide;silver Chemical compound [Ag].NC(=O)C1=CC([N+]([O-])=O)=CC2=NNN=C12 SLBUGEPSVBECEY-UHFFFAOYSA-N 0.000 description 1
- KGULHBNUPVIMGA-UHFFFAOYSA-N 6-nitro-2h-benzotriazole-4-carboxylic acid;silver Chemical compound [Ag].OC(=O)C1=CC([N+]([O-])=O)=CC2=NNN=C12 KGULHBNUPVIMGA-UHFFFAOYSA-N 0.000 description 1
- RHUWUZKMDYIXLX-UHFFFAOYSA-N 6-nitro-2h-benzotriazole-4-sulfonamide;silver Chemical compound [Ag].NS(=O)(=O)C1=CC([N+]([O-])=O)=CC2=NNN=C12 RHUWUZKMDYIXLX-UHFFFAOYSA-N 0.000 description 1
- GCWOEXFAHBQLHJ-UHFFFAOYSA-N 6-nitro-2h-benzotriazole-4-sulfonic acid;silver Chemical compound [Ag].OS(=O)(=O)C1=CC([N+]([O-])=O)=CC2=NNN=C12 GCWOEXFAHBQLHJ-UHFFFAOYSA-N 0.000 description 1
- ZDVKOEIQMMTAHO-UHFFFAOYSA-N 6-nitro-2h-benzotriazole-5-carboxylic acid;silver Chemical compound [Ag].C1=C([N+]([O-])=O)C(C(=O)O)=CC2=NNN=C21 ZDVKOEIQMMTAHO-UHFFFAOYSA-N 0.000 description 1
- DQQIEVWEHGOQJV-UHFFFAOYSA-N 6-nitro-4-phenyl-2h-benzotriazole;silver Chemical compound [Ag].C12=NNN=C2C=C([N+](=O)[O-])C=C1C1=CC=CC=C1 DQQIEVWEHGOQJV-UHFFFAOYSA-N 0.000 description 1
- ANUFXSVWPAUZLZ-UHFFFAOYSA-N 7-hydroxy-2H-benzotriazole-4-sulfonic acid silver Chemical compound [Ag].OC1=CC=C(C=2NN=NC21)S(=O)(=O)O ANUFXSVWPAUZLZ-UHFFFAOYSA-N 0.000 description 1
- SSWWADQTDCUWBN-UHFFFAOYSA-N 7-nitro-2H-benzotriazol-4-ol silver Chemical compound OC1=CC=C(C=2NN=NC21)[N+](=O)[O-].[Ag] SSWWADQTDCUWBN-UHFFFAOYSA-N 0.000 description 1
- PKDNVQWIKHXVGL-UHFFFAOYSA-N 9h-fluorene;n-propylpropan-1-amine Chemical compound CCCNCCC.C1=CC=C2CC3=CC=CC=C3C2=C1 PKDNVQWIKHXVGL-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 241001479434 Agfa Species 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical group N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- AXVCDCGTJGNMKM-UHFFFAOYSA-L C(C=1C(C(=O)[O-])=CC=CC1)(=O)[O-].[Ag+2] Chemical compound C(C=1C(C(=O)[O-])=CC=CC1)(=O)[O-].[Ag+2] AXVCDCGTJGNMKM-UHFFFAOYSA-L 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 239000004709 Chlorinated polyethylene Substances 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920002307 Dextran Polymers 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- MGJKQDOBUOMPEZ-UHFFFAOYSA-N N,N'-dimethylurea Chemical group CNC(=O)NC MGJKQDOBUOMPEZ-UHFFFAOYSA-N 0.000 description 1
- OILIPECUNDBBML-UHFFFAOYSA-N N-(4-hydroxy-2H-benzotriazol-5-yl)acetamide silver Chemical compound [Ag].OC1=C(C=CC=2NN=NC21)NC(C)=O OILIPECUNDBBML-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- 229920002732 Polyanhydride Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 241000978776 Senegalia senegal Species 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 229910021612 Silver iodide Inorganic materials 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 1
- 241001061127 Thione Species 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 1
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 1
- XCFIVNQHHFZRNR-UHFFFAOYSA-N [Ag].Cl[IH]Br Chemical compound [Ag].Cl[IH]Br XCFIVNQHHFZRNR-UHFFFAOYSA-N 0.000 description 1
- HOLVRJRSWZOAJU-UHFFFAOYSA-N [Ag].ICl Chemical compound [Ag].ICl HOLVRJRSWZOAJU-UHFFFAOYSA-N 0.000 description 1
- QOKDACFVNZFJFA-UHFFFAOYSA-N [K].[Ag].N1N=NC2=C1C=CC=C2 Chemical compound [K].[Ag].N1N=NC2=C1C=CC=C2 QOKDACFVNZFJFA-UHFFFAOYSA-N 0.000 description 1
- NZHXEWZGTQSYJM-UHFFFAOYSA-N [bromo(diphenyl)methyl]benzene Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)(Br)C1=CC=CC=C1 NZHXEWZGTQSYJM-UHFFFAOYSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 238000006359 acetalization reaction Methods 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 description 1
- 125000004103 aminoalkyl group Chemical group 0.000 description 1
- HAMNKKUPIHEESI-UHFFFAOYSA-N aminoguanidine Chemical class NNC(N)=N HAMNKKUPIHEESI-UHFFFAOYSA-N 0.000 description 1
- 150000003927 aminopyridines Chemical class 0.000 description 1
- 150000005010 aminoquinolines Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 125000003289 ascorbyl group Chemical class [H]O[C@@]([H])(C([H])([H])O*)[C@@]1([H])OC(=O)C(O*)=C1O* 0.000 description 1
- 150000007656 barbituric acids Chemical class 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- CSKNSYBAZOQPLR-UHFFFAOYSA-N benzenesulfonyl chloride Chemical compound ClS(=O)(=O)C1=CC=CC=C1 CSKNSYBAZOQPLR-UHFFFAOYSA-N 0.000 description 1
- CCGGDOVGIDSGQN-UHFFFAOYSA-N benzo[f][1,2]benzoxazine-1,2-dione Chemical compound C1=CC=CC2=C(C(C(=O)NO3)=O)C3=CC=C21 CCGGDOVGIDSGQN-UHFFFAOYSA-N 0.000 description 1
- JWDQJARMCBHFDK-UHFFFAOYSA-N benzotriazole-1-sulfonic acid Chemical compound C1=CC=C2N(S(=O)(=O)O)N=NC2=C1 JWDQJARMCBHFDK-UHFFFAOYSA-N 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 229920000402 bisphenol A polycarbonate polymer Polymers 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 150000001661 cadmium Chemical class 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- JHRWWRDRBPCWTF-OLQVQODUSA-N captafol Chemical compound C1C=CC[C@H]2C(=O)N(SC(Cl)(Cl)C(Cl)Cl)C(=O)[C@H]21 JHRWWRDRBPCWTF-OLQVQODUSA-N 0.000 description 1
- 125000002837 carbocyclic group Chemical group 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 150000001767 cationic compounds Chemical group 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- WORJEOGGNQDSOE-UHFFFAOYSA-N chloroform;methanol Chemical compound OC.ClC(Cl)Cl WORJEOGGNQDSOE-UHFFFAOYSA-N 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000004440 column chromatography Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- GWZCCUDJHOGOSO-UHFFFAOYSA-N diphenic acid Chemical compound OC(=O)C1=CC=CC=C1C1=CC=CC=C1C(O)=O GWZCCUDJHOGOSO-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 229930004069 diterpene Natural products 0.000 description 1
- 150000004141 diterpene derivatives Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 description 1
- WILQTVNGLALUHI-UHFFFAOYSA-N ethyl 2-(4-hydroxy-2H-benzotriazol-5-yl)acetate silver Chemical compound [Ag].OC1=C(C=CC=2NN=NC21)CC(=O)OCC WILQTVNGLALUHI-UHFFFAOYSA-N 0.000 description 1
- CCPIHSHZRPPEIW-UHFFFAOYSA-N ethyl 2-[(4-hydroxy-2H-benzotriazol-5-yl)oxy]acetate silver Chemical compound [Ag].OC1=C(C=CC=2NN=NC21)OCC(=O)OCC CCPIHSHZRPPEIW-UHFFFAOYSA-N 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- VUFOSBDICLTFMS-UHFFFAOYSA-M ethyl-hexadecyl-dimethylazanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)CC VUFOSBDICLTFMS-UHFFFAOYSA-M 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Chemical compound CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 125000000816 ethylene group Polymers [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 229940083124 ganglion-blocking antiadrenergic secondary and tertiary amines Drugs 0.000 description 1
- 229960005219 gentisic acid Drugs 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- PWSKHLMYTZNYKO-UHFFFAOYSA-N heptane-1,7-diamine Chemical compound NCCCCCCCN PWSKHLMYTZNYKO-UHFFFAOYSA-N 0.000 description 1
- 150000007857 hydrazones Chemical class 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- 229910001502 inorganic halide Inorganic materials 0.000 description 1
- 239000002198 insoluble material Substances 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- XUPFNPFFFUXGMP-UHFFFAOYSA-N isoindole-1,3-dione;silver Chemical compound [Ag].C1=CC=C2C(=O)NC(=O)C2=C1 XUPFNPFFFUXGMP-UHFFFAOYSA-N 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- AZEPWULHRMVZQR-UHFFFAOYSA-M lithium;dodecanoate Chemical compound [Li+].CCCCCCCCCCCC([O-])=O AZEPWULHRMVZQR-UHFFFAOYSA-M 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- CUONGYYJJVDODC-UHFFFAOYSA-N malononitrile Chemical class N#CCC#N CUONGYYJJVDODC-UHFFFAOYSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 1
- OTVPURYEWXIAKH-UHFFFAOYSA-N n,n-dibromobenzenesulfonamide Chemical compound BrN(Br)S(=O)(=O)C1=CC=CC=C1 OTVPURYEWXIAKH-UHFFFAOYSA-N 0.000 description 1
- AIKOWPMUHAOTCV-UHFFFAOYSA-N n-(2h-benzotriazol-5-yl)-4-[[4-(dimethylamino)phenyl]diazenyl]benzamide;silver Chemical compound [Ag].C1=CC(N(C)C)=CC=C1N=NC1=CC=C(C(=O)NC2=CC3=NNN=C3C=C2)C=C1 AIKOWPMUHAOTCV-UHFFFAOYSA-N 0.000 description 1
- YBSCQRRTOGYRQG-UHFFFAOYSA-N n-(2h-benzotriazol-5-yl)acetamide;silver Chemical compound [Ag].C1=C(NC(=O)C)C=CC2=NNN=C21 YBSCQRRTOGYRQG-UHFFFAOYSA-N 0.000 description 1
- UMBBGOALZMAJSF-UHFFFAOYSA-N n-benzylethenamine;hydrochloride Chemical compound [Cl-].C=C[NH2+]CC1=CC=CC=C1 UMBBGOALZMAJSF-UHFFFAOYSA-N 0.000 description 1
- DVNYDODOESWBJY-UHFFFAOYSA-N n-bromo-n-methylbenzenesulfonamide Chemical compound CN(Br)S(=O)(=O)C1=CC=CC=C1 DVNYDODOESWBJY-UHFFFAOYSA-N 0.000 description 1
- FWLGGSWAIHNLLW-UHFFFAOYSA-N n-bromo-n-phenylacetamide Chemical compound CC(=O)N(Br)C1=CC=CC=C1 FWLGGSWAIHNLLW-UHFFFAOYSA-N 0.000 description 1
- VBTQNRFWXBXZQR-UHFFFAOYSA-N n-bromoacetamide Chemical compound CC(=O)NBr VBTQNRFWXBXZQR-UHFFFAOYSA-N 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- BIAGWOZIXODKKS-UHFFFAOYSA-N oxadiazole-4-thiol;silver Chemical compound [Ag].SC1=CON=N1 BIAGWOZIXODKKS-UHFFFAOYSA-N 0.000 description 1
- 150000001475 oxazolidinediones Chemical class 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 238000005691 oxidative coupling reaction Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- FCJSHPDYVMKCHI-UHFFFAOYSA-N phenyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OC1=CC=CC=C1 FCJSHPDYVMKCHI-UHFFFAOYSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- IJAPPYDYQCXOEF-UHFFFAOYSA-N phthalazin-1(2H)-one Chemical compound C1=CC=C2C(=O)NN=CC2=C1 IJAPPYDYQCXOEF-UHFFFAOYSA-N 0.000 description 1
- LFSXCDWNBUNEEM-UHFFFAOYSA-N phthalazine Chemical compound C1=NN=CC2=CC=CC=C21 LFSXCDWNBUNEEM-UHFFFAOYSA-N 0.000 description 1
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical compound C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920003227 poly(N-vinyl carbazole) Polymers 0.000 description 1
- 229920000779 poly(divinylbenzene) Polymers 0.000 description 1
- 229920001483 poly(ethyl methacrylate) polymer Polymers 0.000 description 1
- 229920000205 poly(isobutyl methacrylate) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 229920002776 polycyclohexyl methacrylate Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- ZVJHJDDKYZXRJI-UHFFFAOYSA-N pyrroline Natural products C1CC=NC1 ZVJHJDDKYZXRJI-UHFFFAOYSA-N 0.000 description 1
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 description 1
- GJAWHXHKYYXBSV-UHFFFAOYSA-N quinolinic acid Chemical compound OC(=O)C1=CC=CN=C1C(O)=O GJAWHXHKYYXBSV-UHFFFAOYSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- KIWUVOGUEXMXSV-UHFFFAOYSA-N rhodanine Chemical class O=C1CSC(=S)N1 KIWUVOGUEXMXSV-UHFFFAOYSA-N 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 description 1
- 229940081974 saccharin Drugs 0.000 description 1
- 235000019204 saccharin Nutrition 0.000 description 1
- 239000000901 saccharin and its Na,K and Ca salt Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- AQRYNYUOKMNDDV-UHFFFAOYSA-M silver behenate Chemical compound [Ag+].CCCCCCCCCCCCCCCCCCCCCC([O-])=O AQRYNYUOKMNDDV-UHFFFAOYSA-M 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- 229940045105 silver iodide Drugs 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- NUMJVUZSWZLKTF-XVSDJDOKSA-M silver;(5z,8z,11z,14z)-icosa-5,8,11,14-tetraenoate Chemical compound [Ag+].CCCCC\C=C/C\C=C/C\C=C/C\C=C/CCCC([O-])=O NUMJVUZSWZLKTF-XVSDJDOKSA-M 0.000 description 1
- KZNAFUWGUKKVCW-UHFFFAOYSA-N silver;2-(4-sulfo-2h-benzotriazol-5-yl)acetic acid Chemical compound [Ag].OS(=O)(=O)C1=C(CC(=O)O)C=CC2=NNN=C21 KZNAFUWGUKKVCW-UHFFFAOYSA-N 0.000 description 1
- XNAILVDMCFZEHQ-UHFFFAOYSA-N silver;2-[(4-sulfo-2h-benzotriazol-5-yl)oxy]acetic acid Chemical compound [Ag].OS(=O)(=O)C1=C(OCC(=O)O)C=CC2=NNN=C21 XNAILVDMCFZEHQ-UHFFFAOYSA-N 0.000 description 1
- HMGKNQRMNITOOM-UHFFFAOYSA-M silver;2h-benzotriazole-4-sulfonate Chemical compound [Ag+].[O-]S(=O)(=O)C1=CC=CC2=NNN=C12 HMGKNQRMNITOOM-UHFFFAOYSA-M 0.000 description 1
- SUEXRGWLMCSHTR-UHFFFAOYSA-N silver;3-(1h-1,2,4-triazol-5-yl)benzenethiol Chemical compound [Ag].SC1=CC=CC(C=2NN=CN=2)=C1 SUEXRGWLMCSHTR-UHFFFAOYSA-N 0.000 description 1
- ARIXIMPNXJBOMG-UHFFFAOYSA-N silver;5-(4-sulfophenyl)-2h-benzotriazole-4-sulfonic acid Chemical compound [Ag].C1=CC(S(=O)(=O)O)=CC=C1C1=C(S(O)(=O)=O)C2=NNN=C2C=C1 ARIXIMPNXJBOMG-UHFFFAOYSA-N 0.000 description 1
- KRTGFHQXSLLBOE-UHFFFAOYSA-N silver;7-sulfo-2h-benzotriazole-5-carboxylic acid Chemical compound [Ag].C1=C(C(=O)O)C=C(S(O)(=O)=O)C2=NNN=C21 KRTGFHQXSLLBOE-UHFFFAOYSA-N 0.000 description 1
- CLDWGXZGFUNWKB-UHFFFAOYSA-M silver;benzoate Chemical compound [Ag+].[O-]C(=O)C1=CC=CC=C1 CLDWGXZGFUNWKB-UHFFFAOYSA-M 0.000 description 1
- MNMYRUHURLPFQW-UHFFFAOYSA-M silver;dodecanoate Chemical compound [Ag+].CCCCCCCCCCCC([O-])=O MNMYRUHURLPFQW-UHFFFAOYSA-M 0.000 description 1
- LTYHQUJGIQUHMS-UHFFFAOYSA-M silver;hexadecanoate Chemical compound [Ag+].CCCCCCCCCCCCCCCC([O-])=O LTYHQUJGIQUHMS-UHFFFAOYSA-M 0.000 description 1
- ORYURPRSXLUCSS-UHFFFAOYSA-M silver;octadecanoate Chemical compound [Ag+].CCCCCCCCCCCCCCCCCC([O-])=O ORYURPRSXLUCSS-UHFFFAOYSA-M 0.000 description 1
- OHGHHPYRRURLHR-UHFFFAOYSA-M silver;tetradecanoate Chemical compound [Ag+].CCCCCCCCCCCCCC([O-])=O OHGHHPYRRURLHR-UHFFFAOYSA-M 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical class O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- BUUPQKDIAURBJP-UHFFFAOYSA-N sulfinic acid Chemical compound OS=O BUUPQKDIAURBJP-UHFFFAOYSA-N 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- RKSOPLXZQNSWAS-UHFFFAOYSA-N tert-butyl bromide Chemical compound CC(C)(C)Br RKSOPLXZQNSWAS-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- LIXPXSXEKKHIRR-UHFFFAOYSA-M tetraethylphosphanium;bromide Chemical compound [Br-].CC[P+](CC)(CC)CC LIXPXSXEKKHIRR-UHFFFAOYSA-M 0.000 description 1
- DDFYFBUWEBINLX-UHFFFAOYSA-M tetramethylammonium bromide Chemical compound [Br-].C[N+](C)(C)C DDFYFBUWEBINLX-UHFFFAOYSA-M 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
- 150000001467 thiazolidinediones Chemical class 0.000 description 1
- CBDKQYKMCICBOF-UHFFFAOYSA-N thiazoline Chemical compound C1CN=CS1 CBDKQYKMCICBOF-UHFFFAOYSA-N 0.000 description 1
- 125000004149 thio group Chemical group *S* 0.000 description 1
- 125000005300 thiocarboxy group Chemical group C(=S)(O)* 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- ZEMGGZBWXRYJHK-UHFFFAOYSA-N thiouracil Chemical compound O=C1C=CNC(=S)N1 ZEMGGZBWXRYJHK-UHFFFAOYSA-N 0.000 description 1
- 229950000329 thiouracil Drugs 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- YFDSDPIBEUFTMI-UHFFFAOYSA-N tribromoethanol Chemical compound OCC(Br)(Br)Br YFDSDPIBEUFTMI-UHFFFAOYSA-N 0.000 description 1
- 229950004616 tribromoethanol Drugs 0.000 description 1
- GNMJFQWRASXXMS-UHFFFAOYSA-M trimethyl(phenyl)azanium;bromide Chemical compound [Br-].C[N+](C)(C)C1=CC=CC=C1 GNMJFQWRASXXMS-UHFFFAOYSA-M 0.000 description 1
- ZOPCDOGRWDSSDQ-UHFFFAOYSA-N trinonyl phosphate Chemical compound CCCCCCCCCOP(=O)(OCCCCCCCCC)OCCCCCCCCC ZOPCDOGRWDSSDQ-UHFFFAOYSA-N 0.000 description 1
- JBWKIWSBJXDJDT-UHFFFAOYSA-N triphenylmethyl chloride Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)(Cl)C1=CC=CC=C1 JBWKIWSBJXDJDT-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- INDZTCRIYSRWOH-UHFFFAOYSA-N undec-10-enyl carbamimidothioate;hydroiodide Chemical compound I.NC(=N)SCCCCCCCCCC=C INDZTCRIYSRWOH-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C8/00—Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
- G03C8/40—Development by heat ; Photo-thermographic processes
- G03C8/4013—Development by heat ; Photo-thermographic processes using photothermographic silver salt systems, e.g. dry silver
- G03C8/4033—Transferable dyes or precursors
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Description
ãç£æ¥äžã®å©çšåéã
æ¬çºæã¯æ°èŠãªç±çŸåã«ã©ãŒæå
ææã«é¢ãã
詳ããã¯ç±çŸåæå èŠçŽ äžã«ãããŠåœ¢æãããæ¡
æ£æ§è²çŽ ã®åæ§ååžãååå±€ã«ç±è»¢åããããšã«
ããç»åãåŸãç±çŸåã«ã©ãŒæå ææã«é¢ããã
ã®ã§ãããããã«è©³ããã¯èŠªæ°Žæ§ãã€ã³ããŒå±€äž
ã§è²çŽ äŸäžç©è³ªãéæ¡æ£åãããããã«å¯Ÿãè²çŽ
äŸäžç©è³ªãæ¡æ£æ§ã®ããããŒã³ã¿ã®è²çŽ ã圢æã
ãããšã«ãããç±è»¢åæã«è²çŽ äŸäžç©è³ªãšæ¡æ£æ§
è²çŽ ã®åé¢æ§ãé«ããããç±çŸåã«ã©ãŒæå ææ
ã«é¢ããã ãåŸæ¥æè¡ã åŸæ¥ããç¥ãããŠããæå æ§ããã²ã³åéãçš
ããã«ã©ãŒåçæ³ã¯ãæå æ§ãé調æ§ãªãã³ã«ç»
åä¿åæ§çã«ãããŠããã®ä»ã®ã«ã©ãŒåçæ³ã«å
ããã®ã§ãããæãåºãå®çšåãããŠããããã
ããªããããã®æ¹æ³ã«ãããŠã¯çŸåãæŒçœãå®
çãæ°ŽæŽãªã©ã®å·¥çšã«æ¹¿åŒåŠçæ³ãçšãããã
ã«ãåŠçã«æéãšæéããããããŸãåŠçè¬åã«
ãã人äœãžã®å ¬å®³ãæžå¿µããããããããã¯åŠç
宀ãäœæ¥è ã«å¯ŸããåŠçè¬åã«ããæ±æãå¿é ã
ããããããã«ã¯å»æ¶²åŠçã®æéãã³ã¹ããªã©å€
ãã®åé¡ç¹ãååšããŠããã åŸã€ãŠã也åŒåŠçãå¯èœãªã«ã©ãŒç»åã®åœ¢ææ¹
æ³ã®éçºãèŠæãããŠããã çŸåå·¥çšãç±åŠçã§è¡ãªãããšãç¹åŸŽãšããé»
çœç±çŸåæå ææã¯ä»¥åããç¥ãããŠãããäŸã
ã°ç¹å ¬æ43â4921å·ããã³å43â4924å·ã«ãã®èš
èŒããããææ©éå¡©ãããã²ã³åéããã³çŸåå€
ãããªãæå ææãé瀺ãããŠãããããã«ãã®
é»çœç±çŸåæå ææãå¿çšããã«ã©ãŒç±çŸåæå
ææãæ°å€ãç¥ãããŠããã äŸãã°ç±³åœç¹èš±ç¬¬3531286å·ãå第3761270å·ã
å第3764328å·ããªãµãŒãã»ãã€ã¹ã¯ããŒãžã€ãŒ
ïŒä»¥äžRDãšããïŒNo.15108å·ãåNo.15127ãåNo.
12044ããã³åNo.16479çã«ã¯ç±çŸåæå ææäžã«
åççšã«ãã©ãŒãšçºè²çŸåäžè¬ãå«æããããã®
ã«ã€ããŠãç±³åœç¹èš±ç¬¬3180731å·ãRDNo.13443ã
ãã³åNo.14347çã«ã¯ããã€ã³è²çŽ ãçšãããã®
ã«ã€ããŠãç±³åœç¹èš±ç¬¬4235957å·ãRDNo.14433ã
åNo.14448ãåNo.15227ãåNo.15776ãåNo.18137ã
ãã³åNo.19419çã«ã¯ãéè²çŽ æŒçœæ³ãå¿çšãã
ãã®ã«ã€ããŠãç±³åœç¹èš±ç¬¬4124398å·ãå第
4124387å·ããã³å第4123273å·ã«ã¯ç±çŸåæå æ
æã®ç±æŒçœæ¹æ³ã«ã€ããŠè¿°ã¹ãããŠããã ããã«ãç±çŸåã«ããæ¡æ£æ§è²çŽ ãæŸåºããã
ãã®è²çŽ ãååå±€ã«è»¢åãããããšã«ããéç»å
ãšè²çŽ ãšãåé¢ããŠã«ã©ãŒç»åãåŸãåŠãç±çŸå
ã«ã©ãŒæå ææãç¹éæ57â179840å·ããã³å57
â186744å·ã«èšèŒãããŠããã ãŸãæŽã«ãæ¬åºé¡äººã«ããç¹é¡æ57â122596å·
ã«ã¯ãç±çŸåã«ããæè¯æ§è²çŽ ãæŸåºãããåå
å±€ã«è»¢åããããæ¹æ³ãèšèŒãããŠããã ããããªãããã«ã©ãŒç±çŸåæå ææã«é¢ãã
ãããã®ææ¡ã¯ãåæã«åœ¢æãããé»çœéç»åã
æŒçœãŸãã¯å®çããããšãå°é£ã§ãã€ããããã
ãã¯å šãäžå¯èœã§ãã€ãããå¯èœã§ãã€ãŠã湿åŒ
åŠçãªã©ãå¿ èŠãšãããã®ã§ããã ãŸãæŽã«ã湿åŒåŠçãå¿ èŠãšããè²çŽ ãç±ã«ã
ãæ¡æ£è»¢åããããšã«ããååå±€ã«ã«ã©ãŒç»åã
åŸãããšãã§ãããããã®å Žåãè²çŽ ã®æ¡æ£ãšå
æã«è²çŽ äŸäžç©è³ªãååå±€ã«è»¢åããŠããŸãåå
å±€ãæ±æãããšããåé¡ç¹ãããã ãã®ããšã¯è²çŽ äŸäžç©è³ªãæ¡æ£æ§è²çŽ ãããã¯
æè¯æ§è²çŽ ãçæãããããªè²çŽ æŸåºæ§ç©è³ªã§ã
ãå Žåã«ã¯ãè²çŽ äŸäžç©è³ªèªäœãæè²ååç©ã§ã
ãããã«ãç¹ã«æ±æãã²ã©ãããŸãè²çŽ æŸåºæã«
圢æãããè²ç»å以å€ã«äžå¿ èŠãªè²çŽ ã転åããŠ
ããã®ã§ããã®ããã®æ±æããããªã©å€§ããªåé¡
ããããããã«å¯Ÿãè²çŽ äŸäžç©è³ªãããããéåžž
ã®åççšã«ãã©ãŒã®ãããªç¡è²ãããã¯çœè²ã®è²
çŽ åœ¢æç©è³ªã§ããå Žåã«ãç»åä¿åæã®ååå±€ã®
é»ã°ã¿æ±æãšãªãããã«åé¡ãšãªãã ãã®ããšã¯ãè²çŽ äŸäžç©è³ªãè²çŽ æŸåºç©è³ªã§ã
ãå Žåã«ã¯ãè²çŽ 圢ææ§ç©è³ªã§ããå Žåãšæ¯èŒã
ãŠã該ååç©èªäœãæè²ã§ããããã«ååå±€ãæ¿
ããæ±æããŠããŸããšããæ¬ ç¹ãæããããšãæ
å³ããã ããã«å¥ã®åé¡ç¹ãšããŠè²çŽ äŸäžç©è³ªãè²çŽ æŸ
åºæ§ç©è³ªã§ããå Žåã«ã¯ãè²çŽ 圢ææ§ç©è³ªã§ãã
å Žåãšæ¯èŒããŠã該ååç©ãæè²ã§ãããããã«
éåžžã«æžæããŠããŸããšããæ¬ ç¹ãæããã 以äžã®èŠ³ç¹ãããç±çŸåæå ææãšããŠçšãã
ããè²çŽ äŸäžç©è³ªãšããŠã¯ãè²çŽ æŸåºæ§ç©è³ªãã
è²çŽ 圢ææ§ç©è³ªã®æ¹ã奜ãŸããã ãŸãè²çŽ äŸäžç©è³ªãè²çŽ 圢ææ§ç©è³ªã§ããå Žå
ã«ãäŸãã°ããããç°ãªãæ³¢é·åã«åå å¢æãã
æå å±€ãéå±€ããæå ææã®å Žåãè²çŽ äŸäžç©è³ª
ãå±€éãæ¡æ£ãåŸããã®ã§ããéãã¯è²æ¿ããã
ããã¯çºè²äžè¯ãåŒãèµ·ããšããåé¡ç¹ãããã
ããã§ä»¥äžã®ãããªèŠ³ç¹ããè²çŽ äŸäžç©è³ªãç±çŸ
åæã«ååå±€ãããã¯ä»å±€ãžæ¡æ£ããããšã¯çµ¶å¯Ÿ
ã«èš±ãããªãããšã§ãããåŸã€ãŠç±çŸåã«ã©ãŒæ
å ææã«çšããããè²çŽ äŸäžç©è³ªã¯ååã«éæ¡æ£
åãããååç©ã§ãªããã°ãªããªãã è²çŽ äŸäžç©è³ªãè²çŽ 圢ææ§ç©è³ªã§ããå Žåã«
ã¯ãé¢è±ãããäžå¿ èŠãªæŽ»æ§ç¹çœ®æåºãååå±€ã«
転åããããšã«ãã€ãŠååå±€ã«æ±æãçºçãã
ãããããã¯ç»åä¿åæã®æ±æã®åå ãšããªãã®
ã§éæ¡æ£åãããŠããããšã奜ãŸããããšã¯èšã
ãŸã§ããªãããšã§ããã 以äžã®ãããªèæ¯äžã§ã奜ãŸããè²çŽ äŸäžç©è³ª
ã«ã€ããŠéæç 究ãéããçµæãæ¬çºæè ã¯å ã«
ç¹é¡æ58â33364å·æ现æžã«ãããŠæ°Žæº¶æ§åºãæ
ãããã€è©²è²çŽ äŸäžç©è³ªãç±çŸåã«ããæ¡æ£æ§ã®
氎溶æ§åºãæããªãè²çŽ ã圢æãåŸãååç©ãæ
æ¡ãããæ¬çºæè ã¯æŽã«ç 究ãéããçµæãäžèš
ã®å ææ¡ã«ä¿ãååç©ã®ãã¡ç¹ã«ããŒã³ã¿è²çŽ ã
äžããååç©ã§ã¯ç»åã®æ¿åºŠãäžãããšã«ããªæ¿
床ãå¢ããšããæ¬ ç¹ãããããšãèŠãã ãããã
ãæ¬ ç¹ã解決ãã¹ãç 究ãéããçµæãæ¬çºæã
å®æããã«è³ã€ããã®ã§ããã ãçºæã®ç®çã æ¬çºæã®ç®çã¯ãç±è»¢åæã«è²çŽ 圢ææ§ç©è³ªæ®
åºãšåœ¢æãããæ¡æ£æ§è²çŽ ã®åé¢æ§ãé«ãããã
ç±çŸåã«ã©ãŒæå ææãæäŸããããšã«ããã æ¬çºæã®ä»ã®ç®çã¯ãé«æ¿åºŠã®è»¢åç»åãåŸã
ãããããã«ããªãå°ãªãããŒã³ã¿ã®è»¢åç»åã
åŸãããšãã§ããè²çŽ äŸäžç©è³ªãæäŸããããšã«
ããã ãçºæã®æ§æã æ¬çºæè çã¯äžèšç®çãéæãã¹ãéæç 究ã®
çµæãæ¯æäœäžã«ãå°ãªããšãæå æ§ããã²ã³å
éãææ©éå¡©ãéå å€ãç±çŸåã«ããè²çŽ ã圢æ
ãåŸãè²çŽ äŸäžç©è³ªããã³èŠªæ°Žæ§ãã€ã³ããŒãå«
æããå°ãªããšãïŒå±€ã®åçæ§æå±€ãæããç±çŸ
åã«ã©ãŒæå ææã«ãããŠã該è²çŽ äŸäžç©è³ªãäž
èšäžè¬åŒããåã¯ããã§è¡šããããããŒã³ã¿
è²çŽ äŸäžç©è³ªã§ããããšã«ãã€ãŠãäžèšç®çãé
æãããããšãèŠãåºããæ¬çºæãå®æããã åŒäžãR1ã¯ã¢ã«ãã«åºå¥œãŸããã¯ççŽ æ°ïŒå
以äžã®ã¢ã«ãã«åºãã¢ãªãŒã«åºå¥œãŸããã¯ããšã
ã«åºãã¢ã«ãã«ã¢ããåºå¥œãŸããã¯ççŽ æ°ïŒå以
äžã®ã¢ã«ãã«ã¢ããåºãã¢ãªãŒã«ã¢ããåºå¥œãŸã
ãã¯ããšãã«åºãã¢ãªãŒã«åºå¥œãŸããã¯ççŽ æ°ïŒ
å以äžã®ã¢ã·ã«åºããŠã¬ã€ãåºïŒã¢ã«ãã«åºåã¯
ã¢ãªãŒã«åºã§çœ®æãããŠããŠãããïŒåã¯ã·ã¢ã
åºãè¡šãããR2ã¯ããã²ã³ååãæ°ŽçŽ ååãã¢
ã«ãã«åºå¥œãŸããã¯ççŽ æ°ïŒå以äžã®ã¢ã«ãã«åº
åã¯ã¢ã«ã³ãã·åºå¥œãŸããã¯ççŽ æ°ïŒå以äžã®ã¢
ã«ã³ãã·åºãè¡šãããã¯èŠªæ°Žæ§åºãè¡šããã
ã¯ïŒå以äžã®èŠªæ°Žæ§åºã§çœ®æãããåºå¥œãŸããã¯
ïŒå以äžã®ã¹ã«ãåºåã¯ã«ã«ããã·åºã§çœ®æãã
ãã€ççŽ æ°ïŒå以äžã®ã¢ã«ãã«éãæããåºãè¡š
ãããã¯ïŒäŸ¡ã®çµååºå¥œãŸããã¯âCOâãâ
SO2âãâNHâãââãââã
詳ããã¯ç±çŸåæå èŠçŽ äžã«ãããŠåœ¢æãããæ¡
æ£æ§è²çŽ ã®åæ§ååžãååå±€ã«ç±è»¢åããããšã«
ããç»åãåŸãç±çŸåã«ã©ãŒæå ææã«é¢ããã
ã®ã§ãããããã«è©³ããã¯èŠªæ°Žæ§ãã€ã³ããŒå±€äž
ã§è²çŽ äŸäžç©è³ªãéæ¡æ£åãããããã«å¯Ÿãè²çŽ
äŸäžç©è³ªãæ¡æ£æ§ã®ããããŒã³ã¿ã®è²çŽ ã圢æã
ãããšã«ãããç±è»¢åæã«è²çŽ äŸäžç©è³ªãšæ¡æ£æ§
è²çŽ ã®åé¢æ§ãé«ããããç±çŸåã«ã©ãŒæå ææ
ã«é¢ããã ãåŸæ¥æè¡ã åŸæ¥ããç¥ãããŠããæå æ§ããã²ã³åéãçš
ããã«ã©ãŒåçæ³ã¯ãæå æ§ãé調æ§ãªãã³ã«ç»
åä¿åæ§çã«ãããŠããã®ä»ã®ã«ã©ãŒåçæ³ã«å
ããã®ã§ãããæãåºãå®çšåãããŠããããã
ããªããããã®æ¹æ³ã«ãããŠã¯çŸåãæŒçœãå®
çãæ°ŽæŽãªã©ã®å·¥çšã«æ¹¿åŒåŠçæ³ãçšãããã
ã«ãåŠçã«æéãšæéããããããŸãåŠçè¬åã«
ãã人äœãžã®å ¬å®³ãæžå¿µããããããããã¯åŠç
宀ãäœæ¥è ã«å¯ŸããåŠçè¬åã«ããæ±æãå¿é ã
ããããããã«ã¯å»æ¶²åŠçã®æéãã³ã¹ããªã©å€
ãã®åé¡ç¹ãååšããŠããã åŸã€ãŠã也åŒåŠçãå¯èœãªã«ã©ãŒç»åã®åœ¢ææ¹
æ³ã®éçºãèŠæãããŠããã çŸåå·¥çšãç±åŠçã§è¡ãªãããšãç¹åŸŽãšããé»
çœç±çŸåæå ææã¯ä»¥åããç¥ãããŠãããäŸã
ã°ç¹å ¬æ43â4921å·ããã³å43â4924å·ã«ãã®èš
èŒããããææ©éå¡©ãããã²ã³åéããã³çŸåå€
ãããªãæå ææãé瀺ãããŠãããããã«ãã®
é»çœç±çŸåæå ææãå¿çšããã«ã©ãŒç±çŸåæå
ææãæ°å€ãç¥ãããŠããã äŸãã°ç±³åœç¹èš±ç¬¬3531286å·ãå第3761270å·ã
å第3764328å·ããªãµãŒãã»ãã€ã¹ã¯ããŒãžã€ãŒ
ïŒä»¥äžRDãšããïŒNo.15108å·ãåNo.15127ãåNo.
12044ããã³åNo.16479çã«ã¯ç±çŸåæå ææäžã«
åççšã«ãã©ãŒãšçºè²çŸåäžè¬ãå«æããããã®
ã«ã€ããŠãç±³åœç¹èš±ç¬¬3180731å·ãRDNo.13443ã
ãã³åNo.14347çã«ã¯ããã€ã³è²çŽ ãçšãããã®
ã«ã€ããŠãç±³åœç¹èš±ç¬¬4235957å·ãRDNo.14433ã
åNo.14448ãåNo.15227ãåNo.15776ãåNo.18137ã
ãã³åNo.19419çã«ã¯ãéè²çŽ æŒçœæ³ãå¿çšãã
ãã®ã«ã€ããŠãç±³åœç¹èš±ç¬¬4124398å·ãå第
4124387å·ããã³å第4123273å·ã«ã¯ç±çŸåæå æ
æã®ç±æŒçœæ¹æ³ã«ã€ããŠè¿°ã¹ãããŠããã ããã«ãç±çŸåã«ããæ¡æ£æ§è²çŽ ãæŸåºããã
ãã®è²çŽ ãååå±€ã«è»¢åãããããšã«ããéç»å
ãšè²çŽ ãšãåé¢ããŠã«ã©ãŒç»åãåŸãåŠãç±çŸå
ã«ã©ãŒæå ææãç¹éæ57â179840å·ããã³å57
â186744å·ã«èšèŒãããŠããã ãŸãæŽã«ãæ¬åºé¡äººã«ããç¹é¡æ57â122596å·
ã«ã¯ãç±çŸåã«ããæè¯æ§è²çŽ ãæŸåºãããåå
å±€ã«è»¢åããããæ¹æ³ãèšèŒãããŠããã ããããªãããã«ã©ãŒç±çŸåæå ææã«é¢ãã
ãããã®ææ¡ã¯ãåæã«åœ¢æãããé»çœéç»åã
æŒçœãŸãã¯å®çããããšãå°é£ã§ãã€ããããã
ãã¯å šãäžå¯èœã§ãã€ãããå¯èœã§ãã€ãŠã湿åŒ
åŠçãªã©ãå¿ èŠãšãããã®ã§ããã ãŸãæŽã«ã湿åŒåŠçãå¿ èŠãšããè²çŽ ãç±ã«ã
ãæ¡æ£è»¢åããããšã«ããååå±€ã«ã«ã©ãŒç»åã
åŸãããšãã§ãããããã®å Žåãè²çŽ ã®æ¡æ£ãšå
æã«è²çŽ äŸäžç©è³ªãååå±€ã«è»¢åããŠããŸãåå
å±€ãæ±æãããšããåé¡ç¹ãããã ãã®ããšã¯è²çŽ äŸäžç©è³ªãæ¡æ£æ§è²çŽ ãããã¯
æè¯æ§è²çŽ ãçæãããããªè²çŽ æŸåºæ§ç©è³ªã§ã
ãå Žåã«ã¯ãè²çŽ äŸäžç©è³ªèªäœãæè²ååç©ã§ã
ãããã«ãç¹ã«æ±æãã²ã©ãããŸãè²çŽ æŸåºæã«
圢æãããè²ç»å以å€ã«äžå¿ èŠãªè²çŽ ã転åããŠ
ããã®ã§ããã®ããã®æ±æããããªã©å€§ããªåé¡
ããããããã«å¯Ÿãè²çŽ äŸäžç©è³ªãããããéåžž
ã®åççšã«ãã©ãŒã®ãããªç¡è²ãããã¯çœè²ã®è²
çŽ åœ¢æç©è³ªã§ããå Žåã«ãç»åä¿åæã®ååå±€ã®
é»ã°ã¿æ±æãšãªãããã«åé¡ãšãªãã ãã®ããšã¯ãè²çŽ äŸäžç©è³ªãè²çŽ æŸåºç©è³ªã§ã
ãå Žåã«ã¯ãè²çŽ 圢ææ§ç©è³ªã§ããå Žåãšæ¯èŒã
ãŠã該ååç©èªäœãæè²ã§ããããã«ååå±€ãæ¿
ããæ±æããŠããŸããšããæ¬ ç¹ãæããããšãæ
å³ããã ããã«å¥ã®åé¡ç¹ãšããŠè²çŽ äŸäžç©è³ªãè²çŽ æŸ
åºæ§ç©è³ªã§ããå Žåã«ã¯ãè²çŽ 圢ææ§ç©è³ªã§ãã
å Žåãšæ¯èŒããŠã該ååç©ãæè²ã§ãããããã«
éåžžã«æžæããŠããŸããšããæ¬ ç¹ãæããã 以äžã®èŠ³ç¹ãããç±çŸåæå ææãšããŠçšãã
ããè²çŽ äŸäžç©è³ªãšããŠã¯ãè²çŽ æŸåºæ§ç©è³ªãã
è²çŽ 圢ææ§ç©è³ªã®æ¹ã奜ãŸããã ãŸãè²çŽ äŸäžç©è³ªãè²çŽ 圢ææ§ç©è³ªã§ããå Žå
ã«ãäŸãã°ããããç°ãªãæ³¢é·åã«åå å¢æãã
æå å±€ãéå±€ããæå ææã®å Žåãè²çŽ äŸäžç©è³ª
ãå±€éãæ¡æ£ãåŸããã®ã§ããéãã¯è²æ¿ããã
ããã¯çºè²äžè¯ãåŒãèµ·ããšããåé¡ç¹ãããã
ããã§ä»¥äžã®ãããªèŠ³ç¹ããè²çŽ äŸäžç©è³ªãç±çŸ
åæã«ååå±€ãããã¯ä»å±€ãžæ¡æ£ããããšã¯çµ¶å¯Ÿ
ã«èš±ãããªãããšã§ãããåŸã€ãŠç±çŸåã«ã©ãŒæ
å ææã«çšããããè²çŽ äŸäžç©è³ªã¯ååã«éæ¡æ£
åãããååç©ã§ãªããã°ãªããªãã è²çŽ äŸäžç©è³ªãè²çŽ 圢ææ§ç©è³ªã§ããå Žåã«
ã¯ãé¢è±ãããäžå¿ èŠãªæŽ»æ§ç¹çœ®æåºãååå±€ã«
転åããããšã«ãã€ãŠååå±€ã«æ±æãçºçãã
ãããããã¯ç»åä¿åæã®æ±æã®åå ãšããªãã®
ã§éæ¡æ£åãããŠããããšã奜ãŸããããšã¯èšã
ãŸã§ããªãããšã§ããã 以äžã®ãããªèæ¯äžã§ã奜ãŸããè²çŽ äŸäžç©è³ª
ã«ã€ããŠéæç 究ãéããçµæãæ¬çºæè ã¯å ã«
ç¹é¡æ58â33364å·æ现æžã«ãããŠæ°Žæº¶æ§åºãæ
ãããã€è©²è²çŽ äŸäžç©è³ªãç±çŸåã«ããæ¡æ£æ§ã®
氎溶æ§åºãæããªãè²çŽ ã圢æãåŸãååç©ãæ
æ¡ãããæ¬çºæè ã¯æŽã«ç 究ãéããçµæãäžèš
ã®å ææ¡ã«ä¿ãååç©ã®ãã¡ç¹ã«ããŒã³ã¿è²çŽ ã
äžããååç©ã§ã¯ç»åã®æ¿åºŠãäžãããšã«ããªæ¿
床ãå¢ããšããæ¬ ç¹ãããããšãèŠãã ãããã
ãæ¬ ç¹ã解決ãã¹ãç 究ãéããçµæãæ¬çºæã
å®æããã«è³ã€ããã®ã§ããã ãçºæã®ç®çã æ¬çºæã®ç®çã¯ãç±è»¢åæã«è²çŽ 圢ææ§ç©è³ªæ®
åºãšåœ¢æãããæ¡æ£æ§è²çŽ ã®åé¢æ§ãé«ãããã
ç±çŸåã«ã©ãŒæå ææãæäŸããããšã«ããã æ¬çºæã®ä»ã®ç®çã¯ãé«æ¿åºŠã®è»¢åç»åãåŸã
ãããããã«ããªãå°ãªãããŒã³ã¿ã®è»¢åç»åã
åŸãããšãã§ããè²çŽ äŸäžç©è³ªãæäŸããããšã«
ããã ãçºæã®æ§æã æ¬çºæè çã¯äžèšç®çãéæãã¹ãéæç 究ã®
çµæãæ¯æäœäžã«ãå°ãªããšãæå æ§ããã²ã³å
éãææ©éå¡©ãéå å€ãç±çŸåã«ããè²çŽ ã圢æ
ãåŸãè²çŽ äŸäžç©è³ªããã³èŠªæ°Žæ§ãã€ã³ããŒãå«
æããå°ãªããšãïŒå±€ã®åçæ§æå±€ãæããç±çŸ
åã«ã©ãŒæå ææã«ãããŠã該è²çŽ äŸäžç©è³ªãäž
èšäžè¬åŒããåã¯ããã§è¡šããããããŒã³ã¿
è²çŽ äŸäžç©è³ªã§ããããšã«ãã€ãŠãäžèšç®çãé
æãããããšãèŠãåºããæ¬çºæãå®æããã åŒäžãR1ã¯ã¢ã«ãã«åºå¥œãŸããã¯ççŽ æ°ïŒå
以äžã®ã¢ã«ãã«åºãã¢ãªãŒã«åºå¥œãŸããã¯ããšã
ã«åºãã¢ã«ãã«ã¢ããåºå¥œãŸããã¯ççŽ æ°ïŒå以
äžã®ã¢ã«ãã«ã¢ããåºãã¢ãªãŒã«ã¢ããåºå¥œãŸã
ãã¯ããšãã«åºãã¢ãªãŒã«åºå¥œãŸããã¯ççŽ æ°ïŒ
å以äžã®ã¢ã·ã«åºããŠã¬ã€ãåºïŒã¢ã«ãã«åºåã¯
ã¢ãªãŒã«åºã§çœ®æãããŠããŠãããïŒåã¯ã·ã¢ã
åºãè¡šãããR2ã¯ããã²ã³ååãæ°ŽçŽ ååãã¢
ã«ãã«åºå¥œãŸããã¯ççŽ æ°ïŒå以äžã®ã¢ã«ãã«åº
åã¯ã¢ã«ã³ãã·åºå¥œãŸããã¯ççŽ æ°ïŒå以äžã®ã¢
ã«ã³ãã·åºãè¡šãããã¯èŠªæ°Žæ§åºãè¡šããã
ã¯ïŒå以äžã®èŠªæ°Žæ§åºã§çœ®æãããåºå¥œãŸããã¯
ïŒå以äžã®ã¹ã«ãåºåã¯ã«ã«ããã·åºã§çœ®æãã
ãã€ççŽ æ°ïŒå以äžã®ã¢ã«ãã«éãæããåºãè¡š
ãããã¯ïŒäŸ¡ã®çµååºå¥œãŸããã¯âCOâãâ
SO2âãâNHâãââãââã
ãåŒãâ
NHSO2âã
ãåŒã
ãåŒãçãè¡šãããïœã¯ïŒãïŒã®æŽæ°ãè¡š
ãããïœã¯ïŒåã¯ïŒãè¡šãããïœã¯ïŒåã¯ïŒãè¡š
ãããïœåã³ïœã¯ïŒãïŒåã¯ïŒãè¡šããïŒãã ã
ïœãïœã¯å ±ã«ïŒã§ã¯ãªãïŒãïœã¯ïŒïŒïœïŒïŒã®æïŒ
åã¯ïŒïŒïœïŒïŒã®æïŒãè¡šããã äžèšïŒ¹ã§è¡šãããã芪氎æ§åºåã³ïŒžã§è¡šããã
ãåºã«çœ®æããã芪氎æ§åºãšããŠã¯ãäŸãã°ã¹ã«
ãåºãã¹ã«ãã¢ã¢ã€ã«åºãã¹ã«ãã€ãåºãã¹ã«ã
ãšãåºãããªã¹ã«ãåºããžãªãã¹ã«ãåºãããã
ãã·ã¹ã«ããã«ãªãã·åºãããããã·ã¹ã«ããã«
ããªåºãã«ã«ããã·åºãããªã«ã«ããã·åºãã«ã«
ããã·ã€ããé žåºãããã©ãŸã³é žåºãã«ã«ããã
ã©ãŸã³é žåºãããããã·ã é žåºãã«ã«ããããã
ã·ã é žåºããããããµã é žåºãã«ã«ããããããµ
ã é žåºãã¹ã«ãã€ã³ã€ããé žåºãã¹ã«ãã³ã€ãã
é žåºãã¹ã«ãã€ãããã©ãŸã³é žåºãã¹ã«ãããã
ã©ãŸã³é žåºãã¹ã«ãã€ãããããã·ã é žåºãã¹ã«
ããããããã·ã é žåºããããã®åºã§å¡©ãäœãåŸ
ããã®ã¯ãããã®åºã®å¡©ïŒäŸãã°ã¢ã«ã«ãªéå±
å¡©ãã¢ã³ã¢ããŠã å¡©çïŒçãæããããç¹ã«å¥œãŸ
ããã¯ã¹ã«ãåºåã³ã«ã«ããã·åºã§ããã 以äžãæ¬çºæã«ã€ããŠè©³è¿°ããã åèšäžè¬åŒããåã¯ããã§è¡šããããããŒ
ã³ã¿è²çŽ äŸäžç©è³ªã¯èŠªæ°Žæ§åºãæããååç©ã§ã
ã€ãŠãç±çŸåã«éããŠæ¡æ£æ§ã®èŠªæ°Žæ§åºãæããª
ãè²çŽ ã圢æãåŸãååç©ã§ããã äžèšã®ç±çŸåã«éããŠåœ¢æãããæ¡æ£æ§è²çŽ ã®
âæ¡æ£æ§âãšã¯ãåèšè²çŽ äŸäžç©è³ªãã圢æãã
ãããŒã³ã¿è²çŽ ãã該è²çŽ äŸäžç©è³ªãå«æããå±€
ããç©éé¢ä¿ã«ããé£æ¥å±€ã«ç§»åãåŸãæ§è³ªãæ
å³ãããã®ç§»åã®æ æ§ã«ã€ããŠã¯ãäŸãã°çæã
ããè²çŽ èªäœãæ¡æ£æ§ååç©ã§ããå Žåã«ã¯ãã
ã®æ¡æ£æ§ã«åºã¥ããŠåè¿°ã®ç§»åãè¡ãªããããŸã
ä»ã®äŸãšããŠã¯åœ¢æãããè²çŽ ãè²çŽ ã®æº¶å€ã«æº¶
解ããããŸãã¯ç±æº¶å€ã«ãã€ãŠå ç±æº¶è§£ãããŠç§»
åãè¡ãªãããå Žåçãå«ãŸãããããã«åœ¢æã
ããè²çŽ èªäœãæè¯æ§ã§ãã€ãŠã圢æãããè²çŽ
ãæè¯ããŠé£æ¥å±€ãžç§»åããæ æ§ãå«ãŸããã ããã§ãäžèšâæè¯æ§âãšã¯äžè¬ã«çšããããŠ
ããã液äœç¶æ ãçµãããšãªãåºäœããæ°äœã«å€
åããæ§è³ªã ãã§ãªããåºäœã溶èããŠæ¶²äœã«ãª
ãããã®æ¶²äœããæŽã«æ°äœã«å€åããæ§è³ªããå«
ããã®ã§ããã æ¬çºæã«çšããããäžè¬åŒããåã¯ããã§
è¡šããããããŒã³ã¿ã®è²çŽ äŸäžç©è³ªã¯ããŒã³ã¿ã«
ãã©ãŒæ¯æ žã§ããïŒâãã©ãŸãã³ã®ïŒäœïŒä»¥äžã
掻æ§ç¹ãšèšãïŒã§çºè²çŸåäž»è¬ã®é žåäœãšåå¿
ããããŒã³ã¿è²çŽ ã圢æããããããã®éããŒã³
ã¿ã«ãã©ãŒæ¯æ žããååéãå°ããïŒå¥œãŸããã¯
ååé400以äžïŒãã€èŠªæ°Žæ§åºãå«ãŸãªãå Žåã«
ã¯èŠªæ°Žæ§ãã€ã³ããŒäžã§ã®æ¡æ£æ§ã«å¯ããšããæ§
質ãæããããŸã掻æ§ç¹ã®çœ®æåºã«ã¹ã«ãåºåã¯
ã«ã«ããã·åºã®åŠã芪氎æ§åºãå«ãã åºãååšã
ãããšã«ããè²çŽ äŸäžç©è³ªã¯çŸåæäžååãããŠ
ããããã®æŽ»æ§ç¹ã®çœ®æåºã¯è²çŽ 圢æã®éé¢è±ã
ãã®ã§åœ¢æè²çŽ ã«ã¯äžéœåãšãªããªãã詳现ã¯åŸ
è¿°ããã äžèšäžè¬åŒããåã¯ããã§è¡šããããããŒ
ã³ã¿ã®è²çŽ äŸäžç©è³ªã®ãã¡ã§ç¹ã«å¥œãŸãããã®ã¯
äžèšäžè¬åŒããã§ç€ºãããè²çŽ äŸäžç©è³ªã§ã
ãã äžè¬åŒãã åŒäžãR1ãR2ãããïœãïœåã³ïœã¯äžè¬
åŒããã§å®çŸ©ããããã®ãšåã å矩ã§ããã 以äžã«ãæ¬çºæã«çšããããäžè¬åŒããåã¯
ããã§è¡šããããããŒã³ã¿ã®è²çŽ äŸäžç©è³ªã®ä»£
è¡šçå ·äœäŸãèšèŒãããããããã«éå®ãããã
ã®ã§ã¯ãªãã æ¬çºæã®ããŒã³ã¿è²çŽ äŸäžç©è³ªã¯åç¬ã§çšããŠ
ãããããïŒä»¥äžã䜵çšããŠãããã æ¬çºæã«çšããããè²çŽ äŸäžç©è³ªã¯äžè¬çã«ã¯
ïŒâãã©ãŸãã³ããŒã³ã¿ã«ãã©ãŒãšèŠªæ°Žæ§åºãæ
ã€ãèèªæåã¯è³éŠæã®ãžã¢ã«ããããšãåå¿ã
ããŠåŸããåã¯ïŒâãã©ãŸãã³ããŒã³ã¿ã«ãã©ãŒ
ãšèèªæåã¯è³éŠæãžã¢ã«ããããšãåå¿ãããŠ
åŸãããååç©ã«æ°Žæº¶æ§åºãæã€ã眮æåºãå°å ¥
ããããšã«ãã€ãŠåŸãããã 次ã«å ·äœçãªåæäŸã瀺ãã åæäŸ ïŒ è²çŽ äŸäžç©è³ª(3)ã®åæ 8.65ïœã®ïŒâããšãã«âïŒãã¢ã»ãã«ã¢ããâ
ïŒâãã©ãŸãã³ãš1.8ïœã®ïŒâãããâã€ãœãã¿
ã«ã¢ã«ããããšã100mlãšã¿ããŒã«ã«å ããïŒæ
éå ç±éæµããåŸããšã¿ããŒã«ãé€å»ãããåŸã
ããåºäœã100mlã®ã¢ã»ãã³ã«å ããããã«ãã
ç²æ«ïŒïœãšæ¿å¡©é žïŒmlãå ããŠå®€æž©ã§ïŒæéæ¹æ
ããããã«ïŒæéå ç±éæµããåŸãå·åŽäžã§çé ž
ãããªãŠã ãå ãPHãçŽ6.0ãšããããã®åå¿æ¶²
ãæ¿Ÿéããæ¿çž®ããæåºããçµæ¶ãæ¿Ÿéãã¢ãã³
äžéäœãåŸãã 2.8ïœã®ïŒâã¹ã«ãã¹ãã¢ãªã³é žãã¢ã»ããã
ãªã«ïŒ12mlïŒãšããªãžã³ïŒïŒmlïŒã®æ··å溶液ã«å
ããããã«ïŒmlã®ãã³ãŒã³ã¹ã«ããã«ã¯ãã©ã€ã
ãå ããïŒæééæµããåŸ30âã«å·åŽããäžèšã¢
ãã³äžéäœïŒ7.3ïœïŒã®ã¢ã»ããããªã«ïŒ20mlïŒ
溶液ã滎äžããã滎äžåŸïŒæééæµããåŸãæ¿Ÿé
ã濟液ãæ¿çž®åŸ200mlã®ã¡ã¿ããŒã«ãå ãåã³æ¿Ÿ
éã濟液ãæ¿çž®åŸé£œåé£å¡©æ°ŽïŒ200mlïŒãå ãã
æåºããæ²æŸ±ãæ¿Ÿéããåã³200mlã®ã¡ã¿ããŒã«
ã«å ãæ¿Ÿéãã濟液ãæ¿çž®ããŠäžçŽç©ãå«ãã ç®
çç©ãåŸãããããã¯ãããã«ã âã¡ã¿ããŒã«
ïŒïŒïŒïŒïŒãå±é溶åªãšããŠã«ã©ã ã¯ãããã°ã©
ãã€ãŒã«ãã粟補ããŠç®çç©4.2ïœãåŸãã åæäŸ ïŒ è²çŽ äŸäžç©è³ªïŒ14ïŒã®åæ 18.5ïœã®ïŒâïŒïŒ®âããã«ãã«ââã¡ãã«ïŒ
ã¢ããâïŒâã¹ã«ãã¢ããªã³ã200mlã®ãã«ãšã³
ãš40mlã®ããªãžã³æ··å液ã«åæ£ãã3.5mlã®ïŒå¡©
åãªã³ã®ãã«ãšã³ïŒ100mlïŒæº¶æ¶²ã滎äžãã1.5æ
é120âã§åå¿ãããããã®åå¿æ¶²ãå·åŽãã7.5
ïœã®ãã¬ãã¿ã«ã¢ã«ãããé žã®ãã«ãšã³ïŒ50mlïŒ
溶液ã滎äžãã滎äžåŸïŒæé120âã§åå¿ãããã
åå¿æ¶²ãæ¿Ÿéãæ²æŸ±ã200mlã®ã¡ã¿ããŒã«ã«å ã
å ç±æº¶è§£ããåŸäžæº¶ç©ãæ¿Ÿéã§é€ããåŸãã¡ã¿ã
ãŒã«æº¶æ¶²ãæ¿çž®ãããç¶ããŠ200mlã®ãšã¿ããŒã«
ãå ã溶解ããããã«21.6ïœã®ïŒâããšãã«âïŒ
âã¢ã»ãã«ã¢ããâïŒâãã©ãŸãã³ãå ããïŒæ
ééæµããåŸãæ¿çž®ãåæäŸïŒãšåæ§ã®æ¹æ³ã§ç²Ÿ
補ããŠç®çç©24.5ïœãåŸãã äžèšã®åææ¹æ³ã«ãã補é ãããæ¬çºæã«çšã
ãããè²çŽ äŸäžç©è³ªã¯ãåèšäžè¬åŒããã§è¡šã
ãããããã«çæ°Žæ§åºãæããã«ãã©ãŒååã®æŽ»
æ§ç¹ã«é¢è±å¯èœãªåºãšããŠèŠªæ°Žæ§åºãŸãã¯èŠªæ°Žæ§
åºãæããåºã眮æããããååç©ã§ãããåŸã€
ãŠè©²ååç©ãå«ãŸãã芪氎æ§ãã€ã³ããŒäžã§ã¯ã
ãã®èŠªåæ§ã®ããã«éæ¡æ£åãããããç±çŸåã«
éããŠã¯ãé žåã«ããªã³ã°åå¿ã«ãã掻æ§ç¹ã®èŠª
æ°Žæ§åºãé¢è±ããããããããŠèŠªæ°Žæ§åºã倱ã€ã
è²çŽ ã¯ããã¯ã芪氎æ§ãã€ã³ããŒïŒåŸè¿°ããïŒãš
ã®èŠªåæ§ã倱ããå®å šã«çæ°Žæ§ãšãªãããã芪å
æ§ã®åŒ·ãååå±€ãžãšæ¡æ£ããŠãããååå±€äžã«è²
çŽ ç»åã圢æãããããäžæ¹ãç±çŸåã«éããŠäž
èšæŽ»æ§ç¹ããé¢è±ããã芪氎æ§ãå«ãæåã¯ãäŸ
ç¶ãšããŠèŠªæ°Žæ§ãã€ã³ããŒã«å¯ŸããŠèŠªåæ§ãæã
ãã®ã§èŠªæ°Žæ§ãã€ã³ããŒäžã«æ®çããååå±€ã«æ¡
æ£ããŠããããšã¯ãªããããããå¹æã¯ååå±€ã
çæ°Žæ§ç©è³ªã«ãã€ãŠæ§æãããŠããå Žåã«ç¹ã«å€§
ããã åŸã€ãŠæ¬çºæã«ããã°ãç±çŸåã«éããè²çŽ äŸ
äžç©è³ªæ®åºãšæ¡æ£æ§è²çŽ ãšã®åé¢æ§ãèããæ¹è¯
ãããååå±€ã®æ±æã®çºçã¯å®å šã«é²æ¢ãããä¿
åã«ããæ±ããçºçããããšãè³ã€ãŠå°ãªããªã€
ãããŸãå€å±€æ§æã®å Žåãè²æ¿ãã®ãªãè²çŽ ç»å
ãåŸãããã ããã«ãŸããæ¬çºæã«çšããããè²çŽ äŸäžç©è³ª
ã«ãããŠã¯è©²ååç©ã®éæ¡æ£æ§ãé«ããããã«ã«
ãã©ãŒæ®åºã®æŽ»æ§ç¹ã«ãã©ã¹ãåºãå°å ¥ãããã®
ãã©ã¹ãåºã«åèšã®èŠªæ°Žæ§åºãããããããšã¯é
åžžã«å¥œãŸããããšã§ããã ããªãã¡ãè²çŽ äŸäžç©è³ªã«ãã©ã¹ãåºãæãã
ãããšã«ãããç±çŸå以åã«ããã芪氎æ§ãã€ã³
ããŒäžã§ã®è²çŽ äŸäžç©è³ªã®éæ¡æ£æ§ãããé«ãã
ããšãã§ããããã§ããããŸãç±çŸåã«éããŠã¯
ã«ãã©ãŒååã®æŽ»æ§ç¹ããé¢è±ãã芪氎æ§åºãæ
ãããã©ã¹ãåºæåã¯ã芪氎æ§åºãšçžä¿ã€ãŠèŠªæ°Ž
æ§ãã€ã³ããŒäžã§ã®äžååããã匷åºã«ããããš
ãã§ããã®ã§ãæ¬çºæã®åèšå¹æãããé«ããã
ãšãå¯èœã«ãããã ããã«ã¯æ¬çºæã«çšããããè²çŽ äŸäžç©è³ªã¯ã
ç¡è²ãçœè²ã«è¿ãã®ã§ãå±€ãçè²ãããããšããª
ãæå¹æ床ãæãªãããšããªãã äžèšæ¬çºæã«çšããããè²çŽ äŸäžç©è³ªã¯ãç±çŸ
åæå çµæãå¡åžæ¡ä»¶ãåŠçæ¹æ³çã«ããç°ãªã
ãã倧äœææ©éå¡©ïŒã¢ã«ã«å¯ŸããŠ0.01ã¢ã«ã10ã¢
ã«ã®ç¯å²ã§çšãããã奜ãŸããã¯0.1ã¢ã«ã2.0ã¢
ã«ã§ããã æ¬çºæã«çšããããè²çŽ äŸäžç©è³ªã¯ç±çŸåæå
å±€ãŸãã¯ä»ã®åçæ§æå±€ã«å«æãããŠçšãããã
ããäŸãã°ç±çŸåæå å±€äžã«å«æããããã«ã¯ã
ã«ãã©ãŒã®åæ£æ³ã«é¢ããç±³åœç¹èš±ç¬¬2322027å·
ã«èšèŒãããŠããããã«é«æ²žç¹æº¶åªã«æº¶è§£ããŠå«
æãããããšãã§ãããããã«äžèšã®åŠãåæ£æ¹
æ³ã«ãããŠãäžèšé«æ²žç¹æº¶åªã«å¿ èŠã«å¿ããŠäœæ²ž
ç¹æº¶åªã䜵çšããŠè²çŽ äŸäžç©è³ªã溶解ããŠç±çŸå
æå å±€ã«å«æãããããšãã§ããã äžèšã®é«æ²žç¹æº¶åªãšããŠã¯ãäŸãã°ãžâïœâã
ãã«ãã¿ã¬ãŒããããªã¯ã¬ãžã«ãã¹ããšãŒãããž
âãªã¯ãã«ãã¿ã¬ãŒããïœâããã«ããšããŒã«ç
ãããããŸãäœæ²žç¹æº¶åªãšããŠã¯ãäŸãã°é ¢é žã¡
ãã«ãããããªã³é žããã«ãã·ã¯ããããµããŒ
ã«ããžãšãã¬ã³ã°ãªã³ãŒã«ã¢ãã¢ã»ããŒããªã©ã
ç¥ãããŠããããããã®æº¶åªã¯åç¬ã§çšããŠãã
æ··åããŠçšããŠãããããã®ããã«æº¶åªã«æº¶è§£ã
ããè²çŽ äŸäžç©è³ªã¯ãã¢ã«ãã«ãã³ãŒã³ã¹ã«ãã³
é žããã³ã¢ã«ãã«ããã¿ã¬ã³ã¹ã«ãã³é žã®åŠãã¢
ããªã³ç³»çé¢æŽ»æ§å€ããã³ïŒãŸãã¯ãœã«ãã¿ã³ã¢
ãã©ãŠãªã³é žãšã¹ãã«ã®åŠããããªã³ç³»çé¢æŽ»æ§
å€ãå«ããŒã©ãã³çã®èŠªæ°Žæ§ãã€ã³ããŒãå«æã
ã氎溶液ãšæ··åããã³ãã€ããã«ãŸãã¯è¶ é³æ³¢å
æ£è£ 眮çã§ä¹³ååæ£ããç±çŸåæå å±€ã«æ·»å ãã
ããããšãã§ããã äžèšé«æ²žç¹æº¶åªã¯ãè²çŽ äŸäžç©è³ªãå®å šã«æº¶è§£
ããããéã§çšãããããã奜ãŸããã¯è²çŽ äŸäž
ç©è³ªïŒéšã«å¯ŸããŠ0.05ã100éšã®ç¯å²ã§çšããã
ãšãã§ããã äžèšä»¥å€ã®å¥œãŸããåæ£æ¹æ³ãšããŠã¯ãã€ãã·
ã€ãŒåæ£ãããã該ãã€ãã·ã€ãŒåæ£ãšã¯ãåäž
ååäžã«èŠªæ°Žæ§æåãšçæ°Žæ§æåãšãæããè²çŽ
äŸäžç©è³ªãã¢ã«ã«ãªæ°Žæº¶æ¶²ã«æº¶è§£ãåæ£ããããš
ãããããã®æº¶è§£ãåæ£ã«ããããæ°Žãšçžæº¶æ§ã
æããææ©æº¶åªãæ·»å ããããå ç±ãæ¹æïŒãã¢
ãžãã€ã¶ãŒãè¶ é³æ³¢åæ£ãªã©ïŒãããããããã¯
çé¢æŽ»æ§å€ã®å©ããããããªã©ããŠããããã¢ã«
ã«ãªæ°Žæº¶æ¶²ã®ã¢ã«ã«ãªãšããŠã¯ãç¡æ©å¡©åºãæ°Žãš
çžæº¶æ§ã®ããææ©å¡©åºãçšããããšãã§ããè²çŽ
äŸäžç©è³ªã溶解ãåæ£ããåŸãå¿ èŠã«å¿ããŠPHã
調æŽããããšãã§ããããã®å Žåã®PH調æŽå€ã«ã¯
æ°Žãšçžæº¶æ§ã®ããææ©åã¯ç¡æ©é žãçšããããšã
ã§ãããåæ£å©å€ãšããŠã®çé¢æŽ»æ§å€ã¯ãã¢ããª
ã³ç³»ããããªã³ç³»æŽ»æ§å€çã§è¯ãããã¢ããªã³ç³»
掻æ§å€ã奜ãŸããã ãªãäžèšãã€ãã·ã€ãŒåæ£ã¯ãã¢ã°ãã¢ãŒåæ£
ãšåŒã°ããããšããããè±åœç¹èš±ç¬¬45555å·ãå
第465823å·ãå第29897å·çã«èšèŒãããŠããæ
è¡å 容ãåèã«ããããšãã§ããã æ¬çºæã«çšããããè²çŽ äŸäžç©è³ªã¯ãç±çŸåæ
å å±€ã«åŸè¿°ã®èŠªæ°Žæ§ãã€ã³ããŒãçšããŠããã®èŠª
æ°Žæ§ãã€ã³ããŒäžã«äžè¿°ã®ããã«ãã€ãã·ã€ãŒå
æ£åã¯ãªã€ã«ãããã¯ãåæ£ãããããã®ã§ã
ããåŸã€ãŠåŸæ¥ã®ããã«ããŒã«ãã«ãŸãã¯ãµã³ã
ãã«çã䜿çšããŠç£šç ããå¿ èŠããªãã®ã§çæé
ã®äœæ¥ã§åŸ®çŽ°ãã€å®å®ã«ç±çŸåæå å±€äžã«åæ£ã
ãããããšãã§ãããã€è²çŽ ç»åã®è»¢åæ¿åºŠãæ¹
è¯ããããšãã§ããã ãŸããæ¬çºæã§ã¯åŸè¿°ã®ããã«ç±çŸåæå å±€ã®
ãã€ã³ããŒãšããŠã芪氎æ§ãã€ã³ããŒã䜿çšãã
ã®ã§è©²ç±çŸåæå å±€ãæ¯æäœäžã«å¡åžããå Žåã«
ã¯éææ©æº¶åªããªãã¡æ°Žç³»ã«ãŠå¡åžããããšãã§
ãããŸãç¹ã«ãã€ã³ããŒãšããŠãŒã©ãã³ãçšãã
å Žåã«ã¯ãã®ã»ããæ§ãå©çšã§ããã®ã§ç¡å ¬å®³
ã§ããããå¿ ãããæ°Žå¹³å¡åžãå¿ èŠãšããªãã®ã§
æå ææ補é äžã®äœæ¥å·¥çšãç°¡æåãããã æ¬çºæã®ç±çŸåæå å±€ã«ã¯åèšã®è²çŽ äŸäžç©è³ª
ãšåæ§ã«æå æ§ããã²ã³åéãå«æããã æ¬çºæã«çšããããæå æ§ããã²ã³åéãšããŠ
ã¯ãå¡©åéãèåéãæ²åéãå¡©èåéãå¡©æ²å
éãæ²èåéãå¡©æ²èåéãŸãã¯ãããã®æ··åç©
çããããããã該æå æ§ããã²ã³åéã¯ãåç
æè¡åéã§å ¬ç¥ã®ã·ã³ã°ã«ãžãšããæ³ãããã«ãž
ãšããæ³çã®ä»»æã®æ¹æ³ã§èª¿è£œããããšãã§ãã
ããæ¬çºæã«æŒããŠã¯éåžžã®ããã²ã³åéãŒã©ã
ã³ä¹³å€ã®èª¿è£œæ¹æ³ã«åŸã€ãŠèª¿è£œããæå æ§ããã²
ã³åéä¹³å€ã奜ãŸããçµæãäžããã 該æå æ§ããã²ã³åéä¹³å€ã¯ãåçæè¡åéã§
å ¬ç¥ã®ä»»æã®æ¹æ³ã§ååŠçã«å¢æããŠãè¯ããã
ããå¢ææ³ãšããŠã¯ãéå¢æãã€ãªãŠå¢æãéâ
ã€ãªãŠå¢æãéå å¢æçåçš®ã®æ¹æ³ããããã
ãã äžèšæå æ§ä¹³å€äžã®ããã²ã³åéã¯ãç²ç²åã§
ãã€ãŠã埮ç²åã§ãã€ãŠãè¯ããã奜ãŸããç²å
ãµã€ãºã¯ããã®åŸãçŽ1.5ÎŒïœãçŽ0.001ÎŒïœã§ã
ããããã«å¥œãŸããã¯çŽ0.5ÎŒïœãçŽ0.01ÎŒïœã§ã
ãã äžèšã®ããã«èª¿è£œãããæå æ§ããã²ã³åéä¹³
å€ãæ¬çºæã®æå ææã®æ§æå±€ã§ããç±çŸåæ§æ
å å±€ã«æã奜ãŸããé©çšããããšãã§ããã æ¬çºæã«ãããŠãä»ã®æå æ§ããã²ã³åéã®èª¿
補æ³ãšããŠãæå æ§é塩圢ææåãææ©éå¡©ãšå ±
åãããææ©éå¡©ã®äžéšã«æå æ§ããã²ã³åéã
圢æãããããšãã§ããããã®èª¿è£œæ³ã«çšããã
ãæå æ§é塩圢ææåãšããŠã¯ãç¡æ©ããã²ã³å
ç©ãäŸãã°ãMXnã§è¡šããããããã²ã³åç©
ïŒããã§ãïŒã¯ïŒšååãNH4åºãŸãã¯éå±ååã
è¡šãããã¯ClãBrãŸãã¯ïŒ©ãïœã¯ïŒãååã
NH4åºã®æã¯ïŒ©ãïŒãéå±ååã®æã¯ããã®å
å䟡ã瀺ããéå±ååãšããŠã¯ããªããŠã ããã
ãªãŠã ãã«ãªãŠã ãã«ããžãŠã ãã»ã·ãŠã ãé ã
éãããªãªãŠã ããã°ãã·ãŠã ãã«ã«ã·ãŠã ãã¹
ããã³ããŠã ãããªãŠã ãäºéãã«ãããŠã ãæ°Ž
éãã¢ã«ãããŠã ãã€ã³ãžãŠã ãã©ã³ã¿ã³ãã«ã
ããŠã ãã¿ãªãŠã ãã²ã«ãããŠã ãé«ãéãã¢ã³
ãã¢ã³ããã¹ãã¹ãã¯ãã ãã¢ãªããã³ãã¿ã³ã°
ã¹ãã³ããã³ã¬ã³ãã¬ããŠã ãéãã³ãã«ããã
ãã±ã«ãããžãŠã ããã©ãžãŠã ããªã¹ããŠã ãã€
ãªãžãŠã ãçœéãã»ãªãŠã çãããããããïŒãå«
ããã²ã³éå±é¯äœïŒäŸãã°K2PtCl6ãK2PtBr6ã
HAuCl4ãïŒNH4ïŒ2IrCl6ãïŒNH4ïŒ3IrCl6ã
ïŒNH4ïŒ2RuCl6ãïŒNH4ïŒ3RuCl6ãïŒNH4ïŒ3RhCl6ã
ïŒNH4ïŒ3RhBr6çïŒããªããŠã ãã©ã€ãïŒäŸãã°ã
ãã©ã¡ãã«ã¢ã³ã¢ããŠã ãããã€ããããªã¡ãã«
ããšãã«ã¢ã³ã¢ããŠã ãããã€ããã»ãã«ãšãã«
ãžã¡ãã«ã¢ã³ã¢ããŠã ãããã€ããïŒâã¡ãã«ã
ã¢ãŸãªãŠã ãããã€ããããªã¡ãã«ãã³ãžã«ã¢ã³
ã¢ããŠã ãããã€ãã®ãããªïŒçŽã¢ã³ã¢ããŠã ã
ã©ã€ããããã©ãšãã«ããªã¹ããªããŠã ãããã€
ãã®ãããªïŒçŽããªã¹ããªããŠã ãã©ã€ãããã³
ãžã«ãšãã«ã¡ãã«ãããã€ããïŒâãšãã«ãã¢ãŸ
ãªãŠã ãããã€ãã®ãããªïŒçŽã¹ã«ãããŠã ãã©
ã€ãçïŒãããã²ã³åçåæ°ŽçŽ ïŒäŸãã°ãšãŒãã
ã«ã ãããã¢ãã«ã åèåççŽ ãïŒâããã âïŒ
âã¡ãã«ãããã³çïŒãâããã²ã³ååç©ïŒïŒ®
âã¯ããã³ãã¯é žã€ãããâããã ã³ãã¯é žã€
ãããâããã ãã¿ã«é žã€ãããâããã ã¢
ã»ãã¢ãããâãšãŒãã³ãã¯é žã€ãããâã
ãã ãã¿ã©ãžãã³ãâã¯ãããã¿ã©ãžãã³ã
âããã¢ã¢ã»ãã¢ããªããïŒïŒ®âãžããã¢ãã³
ãŒã³ã¹ã«ãã³ã¢ãããâããã¢ââã¡ãã«ã
ã³ãŒã³ã¹ã«ãã³ã¢ãããïŒïŒïŒâãžããã¢âïŒïŒ
ïŒâãžã¡ãã«ããã³ãã€ã³çïŒããã®ä»ã®å«ãã
ã²ã³ååç©ïŒäŸãã°å¡©åããªããšãã«ã¡ãã«ãè
åããªããšãã«ã¡ãã«ãïŒâããã é ªé žãïŒâã
ãã ãšã¿ããŒã«çïŒãªã©ããããããšãã§ããã ãããæå æ§ããã²ã³åéããã³æå æ§é塩圢
ææåã¯ãçš®ã ã®æ¹æ³ã«ãããŠçµåããŠäœ¿çšã§
ãã䜿çšéã¯ææ©éå¡©ïŒã¢ã«ã«å¯ŸããŠ0.001ã¢ã«
ã2.0ã¢ã«ã§ããã奜ãŸããã¯0.01ã¢ã«ã0.5ã¢ã«
ã§ããã ãŸããæ¬çºæã®ç±çŸåã«ã©ãŒæå ææã¯éè²
å ãç·è²å ãèµ€è²å ã«æå æ§ãæããåå±€ãããª
ãã¡ç±çŸåéæå å±€ãç±çŸåç·æå å±€ãç±çŸåèµ€
æå å±€ãšããŠå€å±€æ§æãšããããšãã§ããããã
ã®åã çšããããéææ§ããã²ã³åéä¹³å€ãç·æ
æ§ããã²ã³åéä¹³å€ãèµ€ææ§ããã²ã³åéä¹³å€
ã¯ãåèšããã²ã³åéä¹³å€ã«åçš®ã®åå å¢æè²çŽ
ãå ããããšã«ãã€ãŠåŸãããšãã§ããã æ¬çºæã«çšãããã代衚çãªåå å¢æè²çŽ ãšã
ãŠã¯ãäŸãã°ã·ã¢ãã³ãã¡ãã·ã¢ãã³ãã³ã³ãã¬
ãã¯ã¹ïŒïŒæ žåã¯ïŒæ žã®ïŒã·ã¢ãã³ãããããŒã©
âã·ã¢ãã³ãã¹ããªã«ãããã·ã¢ãã³ããªããœã
ãŒã«çãããããããã·ã¢ãã³é¡ã®è²çŽ ã®ãã¡ã§
ãã¢ãŸãªã³ããªããµãŸãªã³ããããªã³ãããªãžã³
ãªããµãŸãŒã«ããã¢ãŸãŒã«ãã»ã¬ããŸãŒã«ãã€ã
ããŸãŒã«ã®æ§ãªå¡©åºæ§æ žãæãããã®ãããã奜
ãŸããããã®æ§ãªæ žã«ã¯ã¢ã«ãã«åºãã¢ã«ãã¬ã³
åºãããããã·ã¢ã«ãã«åºãã¹ã«ãã¢ã«ãã«åºã
ã«ã«ããã·ã¢ã«ãã«åºãã¢ããã¢ã«ãã«åºãŸãã¯
çž®åççŽ ç°åŒãŸãã¯è€çŽ ç°è²ç°ãäœãäºã®åºæ¥ã
ãšããã³åºãæããŠããŠãããããŸã察称圢ã§ã
é察称圢ã§ãããããŸãã¡ãã³éãããªã¡ãã³é
ã«ã¢ã«ãã«åºãããšãã«åºããšããã³åºãããã
ç°çœ®æåºãæããŠããŠãããã ã¡ãã·ã¢ãã³è²çŽ ã¯äžèšå¡©åºæ§æ žã®ä»ã«äŸãã°
ããªããã³ãã€ã³æ žãããŒããã³æ žããªããµãŸãª
ãžã³ãžãªã³æ žããã¢ãŸãªãžã³ãžãªã³æ žããã«ãã
ãŒã«é žæ žããã¢ãŸãªã³ããªã³æ žãããããããªã«
æ žããã©ãŸãã³æ žã®æ§ãªé žæ§æ žãæããŠããŠãã
ãããããã®é žæ§æ žã¯æŽã«ã¢ã«ãã«åºãã¢ã«ãã¬
ã³åºãããšãã«åºãã«ã«ããã·ã¢ã«ãã«åºãã¹ã«
ãã¢ã«ãã«åºãããããã·ã¢ã«ãã«åºãã¢ã«ã³ã
ã·ã¢ã«ãã«åºãã¢ã«ãã«ã¢ãã³åºåã¯ãããç°åŒ
æ žã§çœ®æãããŠããŠããããåå¿ èŠãªãã°ããã
ã®è²çŽ ãçµåãããŠäœ¿çšããŠããããæŽã«ã¢ã¹ã³
ã«ãã³é žèªå°äœãã¢ã¶ã€ã³ãã³ã«ãããŠã å¡©ãæ
æ©ã¹ã«ãã³é žçäŸãã°ç±³åœç¹èš±ç¬¬2933390å·ãå
第2937089å·ã®æ现æžçã«èšèŒãããŠããæ§ãªå¯
èŠå ãåžåããªãè¶ å¢ææ§æ·»å å€ã䜵çšããããš
ãã§ããã ãããè²çŽ ã®æ·»å éã¯ããã²ã³åéãŸãã¯ãã
ã²ã³åé圢ææåïŒã¢ã«åœãïŒÃ10-4ã¢ã«ãïŒã¢
ã«ã§ãããæŽã«å¥œãŸããã¯ãïŒÃ10-4ã¢ã«ãïŒÃ
10-1ã¢ã«ã§ããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã«çšããããæ
æ©éå¡©ãšããŠã¯ãç¹å ¬æ43â4924å·ãå44â
26582å·ãå45â18416å·ãå45â12700å·ãå45
â22185å·ããã³ç¹éæ49â52626å·ãå52â
31728å·ãå52â13731å·ãå52â141222å·ãå53
â36224å·ãå53â37610å·åå ¬å ±ãç±³åœç¹èš±ç¬¬
3330633å·ãå第4168980å·çã®æ现æžã«èšèŒãã
ãŠããèèªæã«ã«ãã³é žã®éå¡©ãäŸãã°ã©ãŠãªã³
é žéãããªã¹ãã³é žéããã«ããã³é žéãã¹ãã¢
ãªã³é žéãã¢ã©ããã³é žéãããã³é žéçããŸã
è³éŠæã«ã«ãã³é žéãäŸãã°å®æ¯éŠé žéããã¿ã«
é žéçããŸãã€ããåºãæããéå¡©ãäŸãã°ãã³
ãŸããªã¢ãŸãŒã«éããµãã«ãªã³éããã¿ã©ãžãã³
éããã¿ã«ã€ããéçãã¡ã«ã«ããåºãŸãã¯ããª
ã³åºãæããååç©ã®éå¡©ãäŸãã°ïŒâã¡ã«ã«ã
ããã³ãŸâãªããµãŸãŒã«éãã¡ã«ã«ãããªããµãž
ã¢ãŸãŒã«éãã¡ã«ã«ãããã³ãŸãã¢ãŸãŒã«éãïŒ
âã¡ã«ã«ãããã³ãŸã€ãããŸãŒã«éãïŒâã¡ã«ã«
ããâããšãã«âïŒïŒïŒïŒïŒâããªã¢ãŸãŒã«éã
ãŸããã®ä»ãšããŠïŒâããããã·âïŒâã¡ãã«â
ïŒïŒïŒïŒ3aïŒïŒâããã©ã¶ã€ã³ãã³éãïŒâã¡
ãã«âïŒâããããã·âïŒïŒïŒïŒïŒïŒïŒïŒïŒâã
ã³ã¿ã¶ã€ã³ãã³éçããããããã ãŸãRD16966ãå16907ãè±åœç¹èš±ç¬¬1590956
å·ãå第1590957å·æ现æžã«èšèŒã®æ§ãªéååç©
ãçšããããšãã§ãããäžã§ãäŸãã°ãã³ãŸããª
ã¢ãŸãŒã«éã®éå¡©ã®æ§ãªã€ããåºãæããéå¡©ã
奜ãŸããããã³ãŸããªã¢ãŸãŒã«ã®éå¡©ãšããŠã¯ã
äŸãã°ã¡ãã«ãã³ãŸããªã¢ãŸãŒã«éã®ãããªã¢ã«
ãã«çœ®æãã³ãŸããªã¢ãŸãŒã«éãäŸãã°ããã â
ãã³ãŸããªã¢ãŸãŒã«éãã¯ãã«ãã³ãŸããªã¢ãŸãŒ
ã«éã®ãããªããã²ã³çœ®æãã³ãŸããªã¢ãŸãŒã«
éãäŸãã°ïŒâã¢ã»ãã¢ãããã³ãŸããªã¢ãŸãŒã«
éã®ãããªã¢ãã眮æãã³ãŸããªã¢ãŸãŒã«éããŸ
ãè±åœç¹èš±ç¬¬1590956å·ãå第1590957å·åæ现æž
ã«èšèŒã®ååç©ãäŸãã°ïŒ®âãïŒâã¯ããâïŒâ
âïŒïŒïŒïŒâãžã¯ããâïŒâããããã·ããšã
ã«ïŒã€ããâïŒâãªããœâïŒâã¡ãã«âïŒïŒïŒâ
ã·ã¯ããããµãžãšã³âïŒâã€ã«ãâïŒâã«ã«ãã¢
ã€ã«ãã³ãŸããªã¢ãŸãŒã«éå¡©ãïŒâãã³ãŸããªã¢
ãŸãŒã«âïŒâã€ã«ã¢ãŸâïŒâã¡ããã·âïŒâãã
ããŒã«éå¡©ãïŒâãã³ãŸããªã¢ãŸãŒã«âïŒâã€ã«
ã¢ãŸâïŒâããããŒã«éå¡©ãâãã³ãŸããªã¢ãŸ
ãŒã«âïŒâã€ã«âïŒâïŒïŒâãžã¡ãã«ã¢ããããš
ãã«ã¢ãŸïŒãã³ãŸã¢ããéå¡©çããããããã ãŸãäžèšäžè¬åŒããã§è¡šããããããããã³
ãŸããªã¢ãŸãŒã«é¡ããã³äžèšäžè¬åŒããã§è¡šã
ããããã³ãŸããªã¢ãŸãŒã«é¡ãæå©ã«äœ¿çšã§ã
ãã äžè¬åŒãã åŒäžãR3ã¯ãããåºãè¡šãããR4ããã³R5ã¯
åäžã§ãç°ãªã€ãŠããŠããããåã ããã²ã³åå
ïŒäŸãã°å¡©çŽ ãèçŽ ãæ²çŽ ïŒãããããã·åºãã¹ã«
ãåºãããã¯ãã®å¡©ïŒäŸãã°ãããªãŠã å¡©ãã«ãª
ãŠã å¡©ãã¢ã³ã¢ããŠã å¡©ïŒãã«ã«ããã·åºããã
ã¯ãã®å¡©ïŒäŸãã°ãããªãŠã å¡©ãã«ãªãŠã å¡©ãã¢
ã³ã¢ããŠã å¡©ïŒããããåºãã·ã¢ãåºããŸãã¯ã
ããã眮æåºãæããŠãããã«ã«ãã¢ã€ã«åºãã¹
ã«ãã¢ã¢ã€ã«åºãã¢ã«ãã«åºïŒäŸãã°ã¡ãã«åºã
ãšãã«åºããããã«åºïŒãã¢ã«ã³ãã·åºïŒäŸãã°
ã¡ããã·åºããšããã·åºïŒãã¢ãªãŒã«åºïŒäŸãã°
ããšãã«åºïŒãããã¯ã¢ããåºãè¡šãããïœã¯ïŒ
ãïŒãïœã¯ïŒãŸãã¯ïŒãè¡šããããŸãåèšã«ã«ã
ã¢ã€ã«åºã®çœ®æåºãšããŠã¯ãäŸãã°ã¡ãã«åºããš
ãã«åºãã¢ã»ãã«åºçããããããšãã§ããã¹ã«
ãã¢ã¢ã€ã«åºã®çœ®æåºãšããŠã¯ãäŸãã°ã¡ãã«
åºããšãã«åºãã¢ã»ãã«åºçããããããšãã§
ããã¢ã«ãã«åºã®çœ®æåºãšããŠã¯ãäŸãã°ã«ã«ã
ãã·åºããšããã·ã«ã«ããã«åºçããã¢ãªãŒã«åº
ã®çœ®æåºãšããŠã¯ãäŸãã°ã¹ã«ãåºããããåºç
ããã¢ã«ã³ãã·åºã®çœ®æåºãšããŠã¯ãäŸãã°ã«ã«
ããã·åºããšããã·ã«ã«ããã«åºããããã³ã¢ã
ãåºã®çœ®æåºãšããŠã¯ãäŸãã°ã¢ã»ãã«åºãã¡ã¿
ã³ã¹ã«ããã«åºãããããã·åºãåã ãããããš
ãã§ããã åèšäžè¬åŒããã§è¡šããããååç©ã¯å°ãªã
ãšãäžã€ã®ãããåºãæãããã³ãŸããªã¢ãŸãŒã«
èªå°äœã®éå¡©ã§ããããã®å ·äœäŸãšããŠã¯ä»¥äžã®
ååç©ããããããšãã§ããã äŸãã°ïŒâããããã³ãŸããªã¢ãŸãŒã«éãïŒâ
ããããã³ãŸããªã¢ãŸãŒã«éãïŒâãããâïŒâ
ã¯ãã«ãã³ãŸããªã¢ãŸãŒã«éãïŒâãããâïŒâ
ã¡ãã«ãã³ãŸããªã¢ãŸãŒã«éãïŒâãããâïŒâ
ã¡ããã·ãã³ãŸããªã¢ãŸãŒã«éãïŒâãããâïŒ
âããšãã«ãã³ãŸããªã¢ãŸãŒã«éãïŒâãããã
ã·âïŒâããããã³ãŸããªã¢ãŸãŒã«éãïŒâãã
ããã·âïŒâããããã³ãŸããªã¢ãŸãŒã«éãïŒâ
ããããã·âïŒïŒïŒâãžããããã³ãŸããªã¢ãŸãŒ
ã«éãïŒâããããã·âïŒâãããâïŒâã¯ãã«
ãã³ãŸããªã¢ãŸãŒã«éãïŒâããããã·âïŒâã
ããâïŒâã¡ãã«ãã³ãŸããªã¢ãŸãŒã«éãïŒâã¹
ã«ãâïŒâããããã³ãŸããªã¢ãŸãŒã«éãïŒâã«
ã«ããã·âïŒâããããã³ãŸããªã¢ãŸãŒã«éãïŒ
âã«ã«ããã·âïŒâããããã³ãŸããªã¢ãŸãŒã«
éãïŒâã«ã«ãã¢ã€ã«âïŒâããããã³ãŸããªã¢
ãŸãŒã«éãïŒâã¹ã«ãã¢ã¢ã€ã«âïŒâããããã³
ãŸããªã¢ãŸãŒã«éãïŒâã«ã«ããã·ã¡ãã«âïŒâ
ããããã³ãŸããªã¢ãŸãŒã«éãïŒâããããã·ã«
ã«ããã«ã¡ããã·âïŒâããããã³ãŸããªã¢ãŸãŒ
ã«éãïŒâãããâïŒâã·ã¢ããã³ãŸããªã¢ãŸãŒ
ã«éãïŒâã¢ããâïŒâããããã³ãŸããªã¢ãŸãŒ
ã«éãïŒâãããâïŒâïŒïœâãããããšãã«ïŒ
ãã³ãŸããªã¢ãŸãŒã«éãïŒïŒïŒâãžãããâïŒâ
ã¡ãã«ãã³ãŸããªã¢ãŸãŒã«éãïŒïŒïŒâãžããã
âïŒâã¯ãã«ãã³ãŸããªã¢ãŸãŒã«éãïŒïŒïŒâãž
ãããâïŒâã¡ããã·ãã³ãŸããªã¢ãŸãŒã«éãªã©
ããããããšãã§ããã äžè¬åŒãã åŒäžãR6ã¯ããããã·åºãã¹ã«ãåºãããã¯
ãã®å¡©ïŒäŸãã°ãããªãŠã å¡©ãã«ãªãŠã å¡©ãã¢ã³
ã¢ããŠã å¡©ïŒãã«ã«ããã·åºãããã¯ãã®å¡©ïŒäŸ
ãã°ããããªãŠã å¡©ãã«ãªãŠã å¡©ãã¢ã³ã¢ããŠã
å¡©ïŒã眮æåºãæããŠãããã«ã«ãã¢ã€ã«åºãã
ã³çœ®æåºãæããŠãããã¹ã«ãã¢ã¢ã€ã«åºãè¡šã
ããR7ã¯ããã²ã³ååïŒäŸãã°å¡©çŽ ãèçŽ ãæ²
çŽ ïŒãããããã·åºãã¹ã«ãåºãããã¯ãã®å¡©
ïŒäŸãã°ãããªãŠã å¡©ãã«ãªãŠã å¡©ãã¢ã³ã¢ããŠ
ã å¡©ïŒãã«ã«ããã·åºãããã¯ãã®å¡©ïŒäŸãã°ã
ããªãŠã å¡©ãã«ãªãŠã å¡©ãã¢ã³ã¢ããŠã å¡©ïŒãã
ããåºãã·ã¢ãåºããŸãã¯ãããã眮æåºãæã
ãŠãããã¢ã«ãã«åºïŒäŸãã°ã¡ãã«åºããšãã«
åºããããã«åºïŒãã¢ãªãŒã«åºïŒäŸãã°ããšãã«
åºïŒãã¢ã«ã³ãã·åºïŒäŸãã°ã¡ããã·åºããšãã
ã·åºïŒãããã¯ã¢ããåºãè¡šãããïœã¯ïŒãŸãã¯
ïŒãïœã¯ïŒãïŒã®æŽæ°ãè¡šããã ãŸããåèšR6ã«ãããã«ã«ãã¢ã€ã«åºã®çœ®æ
åºãšããŠã¯ãäŸãã°ã¡ãã«åºããšãã«åºãã¢ã»ã
ã«åºçããããããšãã§ããã¹ã«ãã¢ã¢ã€ã«åºã®
眮æåºãšããŠã¯ãäŸãã°ã¡ãã«åºããšãã«åºãã¢
ã»ãã«åºçããããããšãã§ãããããã«åèš
R7ã«ãããã¢ã«ãã«åºã®çœ®æåºãšããŠã¯ãäŸã
ã°ã«ã«ããã·åºããšããã·ã«ã«ããã«åºçããã¢
ãªãŒã«åºã®çœ®æåºãšããŠã¯ãäŸãã°ã¹ã«ãåºãã
ããåºçãã¢ã«ã³ãã·åºã®çœ®æåºãšããŠã¯ãäŸã
ã°ã«ã«ããã·åºããšããã·ã«ã«ããã«åºçããã
ãã³ã¢ããåºã®çœ®æåºãšããŠã¯ãäŸãã°ã¢ã»ãã«
åºãã¡ã¿ã³ã¹ã«ããã«åºãããããã·åºçãåã
ãããããšãã§ããã åèšäžè¬åŒããã§è¡šããããææ©éå¡©ã®å ·äœ
äŸãšããŠã¯ä»¥äžã®ååç©ããããããšãã§ããã äŸãã°ïŒâããããã·ãã³ãŸããªã¢ãŸãŒã«éã
ïŒâããããã·ãã³ãŸããªã¢ãŸãŒã«éãïŒâã¹ã«
ããã³ãŸããªã¢ãŸãŒã«éãïŒâã¹ã«ããã³ãŸããª
ã¢ãŸãŒã«éããã³ãŸããªã¢ãŸãŒã«éâïŒâã¹ã«ã
ã³é žãããªãŠã ããã³ãŸããªã¢ãŸãŒã«éâïŒâã¹
ã«ãã³é žãããªãŠã ããã³ãŸããªã¢ãŸãŒã«éâïŒ
âã¹ã«ãã³é žã«ãªãŠã ããã³ãŸããªã¢ãŸãŒã«éâ
ïŒâã¹ã«ãã³é žã«ãªãŠã ããã³ãŸããªã¢ãŸãŒã«é
âïŒâã¹ã«ãã³é žã¢ã³ã¢ããŠã ããã³ãŸããªã¢ãŸ
ãŒã«éâïŒâã¹ã«ãã³é žã¢ã³ã¢ããŠã ãïŒâã«ã«
ããã·ãã³ãŸããªã¢ãŸãŒã«éãïŒâã«ã«ããã·ã
ã³ãŸããªã¢ãŸãŒã«éããã³ãŸããªã¢ãŸãŒã«éâïŒ
âã«ã«ãã³é žãããªãŠã ããã³ãŸããªã¢ãŸãŒã«é
âïŒâã«ã«ãã³é žãããªãŠã ããã³ãŸããªã¢ãŸãŒ
ã«éâïŒâã«ã«ãã³é žã«ãªãŠã ããã³ãŸããªã¢ãŸ
ãŒã«éâïŒâã«ã«ãã³é žã«ãªãŠã ããã³ãŸããªã¢
ãŸãŒã«éâïŒâã«ã«ãã³é žã¢ã³ã¢ããŠã ããã³ãŸ
ããªã¢ãŸãŒã«éâïŒâã«ã«ãã³é žã¢ã³ã¢ããŠã ã
ïŒâã«ã«ãã¢ã€ã«ãã³ãŸããªã¢ãŸãŒã«éãïŒâã¹
ã«ãã¢ã¢ã€ã«ãã³ãŸããªã¢ãŸãŒã«éãïŒâã«ã«ã
ãã·âïŒâããããã·ãã³ãŸããªã¢ãŸãŒã«éãïŒ
âã«ã«ããã·âïŒâã¹ã«ããã³ãŸããªã¢ãŸãŒã«
éãïŒâããããã·âïŒâã¹ã«ããã³ãŸããªã¢ãŸ
ãŒã«éãïŒâããããã·âïŒâã¹ã«ããã³ãŸããª
ã¢ãŸãŒã«éãïŒïŒïŒâãžã«ã«ããã·ãã³ãŸããªã¢
ãŸãŒã«éãïŒïŒïŒâãžããããã·ãã³ãŸããªã¢ãŸ
ãŒã«éãïŒâããããã·âïŒâã¯ãã«ãã³ãŸããª
ã¢ãŸãŒã«éãïŒâããããã·âïŒâã¡ãã«ãã³ãŸ
ããªã¢ãŸãŒã«éãïŒâããããã·âïŒâã¡ããã·
ãã³ãŸããªã¢ãŸãŒã«éãïŒâããããã·âïŒâã
ãããã³ãŸããªã¢ãŸãŒã«éãïŒâããããã·âïŒ
âã·ã¢ããã³ãŸããªã¢ãŸãŒã«éãïŒâããããã·
âïŒâã¢ãããã³ãŸããªã¢ãŸãŒã«éãïŒâããã
ãã·âïŒâã¢ã»ãã¢ãããã³ãŸããªã¢ãŸãŒã«éã
ïŒâããããã·âïŒâãã³ãŒã³ã¹ã«ãã³ã¢ããã
ã³ãŸããªã¢ãŸãŒã«éãïŒâããããã·âïŒâãã
ããã·ã«ã«ããã«ã¡ããã·ãã³ãŸããªã¢ãŸãŒã«
éãïŒâããããã·âïŒâãšããã·ã«ã«ããã«ã¡
ããã·ãã³ãŸããªã¢ãŸãŒã«éãïŒâããããã·â
ïŒâã«ã«ããã·ã¡ãã«ãã³ãŸããªã¢ãŸãŒã«éãïŒ
âããããã·âïŒâãšããã·ã«ã«ããã«ã¡ãã«ã
ã³ãŸããªã¢ãŸãŒã«éãïŒâããããã·âïŒâããš
ãã«ãã³ãŸããªã¢ãŸãŒã«éãïŒâããããã·âïŒ
âïŒïœâãããããšãã«ïŒãã³ãŸããªã¢ãŸãŒã«éã
ïŒâããããã·âïŒâïŒïœâã¹ã«ãããšãã«ïŒã
ã³ãŸããªã¢ãŸãŒã«éãïŒâã¹ã«ãâïŒâã¯ãã«ã
ã³ãŸããªã¢ãŸãŒã«éãïŒâã¹ã«ãâïŒâã¡ãã«ã
ã³ãŸããªã¢ãŸãŒã«éãïŒâã¹ã«ãâïŒâã¡ããã·
ãã³ãŸããªã¢ãŸãŒã«éãïŒâã¹ã«ãâïŒâã·ã¢ã
ãã³ãŸããªã¢ãŸãŒã«éãïŒâã¹ã«ãâïŒâã¢ãã
ãã³ãŸããªã¢ãŸãŒã«éãïŒâã¹ã«ãâïŒâã¢ã»ã
ã¢ãããã³ãŸããªã¢ãŸãŒã«éãïŒâã¹ã«ãâïŒâ
ãã³ãŒã³ã¹ã«ãã³ã¢ãããã³ãŸããªã¢ãŸãŒã«éã
ïŒâã¹ã«ãâïŒâããããã·ã«ã«ããã«ã¡ããã·
ãã³ãŸããªã¢ãŸãŒã«éãïŒâã¹ã«ãâïŒâãšãã
ã·ã«ã«ããã«ã¡ããã·ãã³ãŸããªã¢ãŸãŒã«éãïŒ
âããããã·âïŒâã«ã«ããã·ãã³ãŸããªã¢ãŸãŒ
ã«éãïŒâã¹ã«ãâïŒâã«ã«ããã·ã¡ãã«ãã³ãŸ
ããªã¢ãŸãŒã«éãïŒâã¹ã«ãâïŒâãšããã·ã«ã«
ããã«ã¡ãã«ãã³ãŸããªã¢ãŸãŒã«éãïŒâã¹ã«ã
âïŒâããšãã«ãã³ãŸããªã¢ãŸãŒã«éãïŒâã¹ã«
ãâïŒâïŒïœâãããããšãã«ïŒãã³ãŸããªã¢ãŸ
ãŒã«éãïŒâã¹ã«ãâïŒâïŒïœâã¹ã«ãããšãã«ïŒ
ãã³ãŸããªã¢ãŸãŒã«éãïŒâã¹ã«ãâïŒâã¡ãã
ã·âïŒâã¯ãã«ãã³ãŸããªã¢ãŸãŒã«éãïŒâã¹ã«
ãâïŒâã¯ãã«âïŒâã«ã«ããã·ãã³ãŸããªã¢ãŸ
ãŒã«éãïŒâã«ã«ããã·âïŒâã¯ãã«ãã³ãŸããª
ã¢ãŸãŒã«éãïŒâã«ã«ããã·âïŒâã¡ãã«ãã³ãŸ
ããªã¢ãŸãŒã«éãïŒâã«ã«ããã·âïŒâãããã
ã³ãŸããªã¢ãŸãŒã«éãïŒâã«ã«ããã·âïŒâã¢ã
ããã³ãŸããªã¢ãŸãŒã«éãïŒâã«ã«ããã·âïŒâ
ã¡ããã·ãã³ãŸããªã¢ãŸãŒã«éãïŒâã«ã«ããã·
âïŒâã¢ã»ãã¢ãããã³ãŸããªã¢ãŸãŒã«éãïŒâ
ã«ã«ããã·âïŒâãšããã·ã«ã«ããã«ã¡ããã·ã
ã³ãŸããªã¢ãŸãŒã«éãïŒâã«ã«ããã·âïŒâã«ã«
ããã·ã¡ãã«ãã³ãŸããªã¢ãŸãŒã«éãïŒâã«ã«ã
ãã·âïŒâããšãã«ãã³ãŸããªã¢ãŸãŒã«éãïŒâ
ã«ã«ããã·âïŒâïŒïœâãããããšãã«ïŒãã³ãŸ
ããªã¢ãŸãŒã«éãïŒâã«ã«ããã·âïŒâã¡ãã«â
ïŒâã¹ã«ããã³ãŸããªã¢ãŸãŒã«éãªã©ããããã
ãšãã§ããããããã®ååç©ã¯åç¬ã§çšããŠãã
ïŒçš®é¡ä»¥äžãçµåããŠçšããŠãããã æ¬çºæã«çšããããææ©éå¡©ã®èª¿è£œæ³ã«ã€ããŠ
ã«åŸã«è¿°ã¹ããã該ææ©éå¡©ã¯åé¢ãããã®ãé©
åœãªæ段ã«ãããã€ã³ããŒäžã«åæ£ããŠäœ¿çšã«äŸ
ããŠããããããŸãé©åœãªãã€ã³ããŒäžã§éå¡©ã
調補ããåé¢ããã«ãã®ãŸãŸäœ¿çšã«äŸããŠãã
ãã 該ææ©éå¡©ã®äœ¿çšéã¯ãæ¯æäœïŒïœåœã0.05ïœ
ã10.0ïœã§ããã奜ãŸããã¯0.2ïœã20ïœã§ããã ãŸããæ¬çºæã®ç±çŸåã«ã©ãŒæå ææã«çšãã
ããéå å€ãšããŠã¯ãäŸãã°ç±³åœç¹èš±ç¬¬3531286
å·ãå第3761270å·ãå第3764328å·åæ现æžããŸ
ãRD12146ãRD15108ãRD15127ããã³ç¹éæ
56â27132å·å ¬å ±çã«èšèŒã®ïœâããšãã¬ã³ãžã¢
ãã³ç³»ããã³ïœâã¢ããããšããŒã«ç³»çŸåäž»è¬ã
ããªã¹ããªãã¢ããããšããŒã«ç³»ããã³ã¹ã«ãã³
ã¢ããããšããŒã«ç³»çŸåäž»è¬ããŸãããã©ãŸã³å
çºè²çŸåäž»è¬çã®å ¬ç¥ã®çºè²çŸåäž»è¬åã¯ãã®ã
ãªã«ãŒãµãŒããããããããç¹ã«å¥œãŸããã®ã¯ç¹
éæ56â146133å·å ¬å ±ããã³æ¬åºé¡äººã«ããç¹é¡
æ57â225928å·æ现æžã«èšèŒã®ïœâïŒïŒ®ïŒïŒ®âãž
ã¢ã«ãã«ã¢ããããšãã«ïŒã¹ã«ãã¢ãã³é žçŸåäž»
è¬ã§ããã ãããéå å€ã¯åç¬ãæãã¯ïŒçš®ä»¥äžçµåããŠ
çšããããšãã§ãããéå å€ã®äœ¿çšéã¯ã䜿çšã
ããææ©éå¡©ã®çš®é¡ãæå æ§éå¡©ã®çš®é¡ããã³ã
ã®ä»ã®æ·»å å€ã®çš®é¡ãªã©ã«äŸåããããéåžžã¯æ
æ©éå¡©ïŒã¢ã«ã«å¯ŸããŠ0.05ã¢ã«ã10ã¢ã«ã®ç¯å²ã§
ããã奜ãŸããã¯0.1ã¢ã«ãïŒã¢ã«ã§ããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã«ã¯ãäžèšåæ
å以å€ã«å¿ èŠã«å¿ãå皮添å å€ãæ·»å ããããšã
ã§ãããäŸãã°çŸåä¿é²å€ãšããŠã¯ãç±³åœç¹èš±ç¬¬
3220840å·ãå第3531285å·ãå第4012260å·ãå
第4060420å·ãå第4088496å·ãå第4207392å·å
æ现æžãŸãã¯RD15733ãå15734ãå15776çã«
èšèŒãããã¢ã«ã«ãªæŸåºå€ãç¹å ¬æ45â12700å·
èšèŒã®ææ©é žãç±³åœç¹èš±ç¬¬3667959å·èšèŒã®âCO
âãâSO2âãâSOâåºãæããéæ°Žæ§æ¥µæ§æº¶åª
ååç©ãç±³åœç¹èš±ç¬¬3438776å·èšèŒã®ã¡ã«ãããª
ãŒããŒãç±³åœç¹èš±ç¬¬3666477å·ãç¹éæ51â19525
å·ã«èšèŒã®ããªã¢ã«ãã¬ã³ã°ãªã³ãŒã«é¡çãã
ãããŸãè²èª¿å€ãšããŠã¯ãäŸãã°ç¹éæ46â4928
å·ãå46â6077å·ãå49â5019å·ãå49â5020
å·ãå49â91215å·ãå49â107727å·ãå50â
2524å·ãå50â67132å·ãå50â67641å·ãå50â
114217å·ãå52â33722å·ãå52â99813å·ãå53
â1020å·ãå53â55115å·ãå53â76020å·ãå53
â125014å·ãå54â156523å·ãå54â156524å·ã
å54â156525å·ãå54â156526å·ãå56â4060
å·ãå55â4061å·ãå55â32015å·çã®å ¬å ±ãªã
ã³ã«è¥¿ç¬ç¹èš±ç¬¬2140406å·ãå第2147063å·ãå第
2220618å·ãç±³åœç¹èš±ç¬¬3080254å·ãå第3847612
å·ãå第3782941å·ãå第3994732å·ãå第
4123282å·ãå第4201582å·çã®åæ现æžã«èšèŒã
ããŠããååç©ã§ãããã¿ã©ãžãã³ããã¿ã«ã€ã·
ãããã©ãŸãã³ããããŸãªãã³ãâããããã·
ããã¿ã«ã€ããããã³ããªããµãžã³ãããããªã
ãµãžã³ãžãªã³ãïŒïŒïŒâãžãããâãã¿ã©ãžã³ãž
ãªã³ãïŒïŒïŒâãžãããâïŒïŒïŒâãªããµãžã³â
ïŒïŒïŒâãžãªã³ããªãã·ããªãžã³ãã¢ããããªãž
ã³ãããããã·ãããªã³ãã¢ãããããªã³ãã€ãœ
ã«ã«ãã¹ããªã«ãã¹ã«ãã³ã¢ããã2HâïŒïŒïŒ
âãã³ãŸãã¢ãžã³âïŒïŒïŒâïŒ3HïŒãžãªã³ããã³
ãŸããªã¢ãžã³ãã¡ã«ã«ããããªã¢ãŸãŒã«ããžã¡ã«
ã«ããããã©ã¶ãã³ã¿ã¬ã³ããã¿ã«é žãããã¿ã«
é žããã¿ã«ã¢ãã³é žçãããããããã®ïŒã€ãŸã
ã¯ïŒã€ä»¥äžãšã€ãããŸãŒã«ååç©ãšã®æ··åç©ãŸã
ãã¿ã«é žãããã¿ã«é žçã®é žãŸãã¯é žç¡æ°Žç©ã®å°
ãªããšãïŒã€ããã³ãã¿ã©ãžã³ååç©ã®æ··åç©ã
ããã«ã¯ãã¿ã©ãžã³ãšãã¬ã€ã³é žãã€ã¿ã³ã³é žã
ãããªã³é žãã²ã³ããžã³é žçã®çµåãçãããã
ããšãã§ããããŸãæ¬åºé¡äººã«ããç¹é¡æ57â
73215å·ãå57â76838å·æ现æžã«èšèŒããããïŒ
âã¢ããâïŒâã¡ã«ã«ããâïŒïŒïŒïŒïŒâããªã¢
ãŸãŒã«é¡ãïŒâã¢ã·ã«ã¢ããâïŒâã¡ã«ã«ããâ
ïŒïŒïŒïŒïŒâããªã¢ãŸãŒã«é¡ãæå¹ã§ããã ãŸãããã«ã«ããªé²æ¢å€ãšããŠã¯ãäŸãã°ç¹å ¬
æ47â11113å·ãç¹éæ49â90118å·ãå49â
10724å·ãå49â97613å·ãå50â101019å·ãå49
â130720å·ãå50â123331å·ãå51â47419å·ã
å51â57435å·ãå51â78227å·ãå51â104338
å·ãå53â19825å·ãå53â20923å·ãå51â
50725å·ãå51â3223å·ãå51â42529å·ãå51â
81124å·ãå54â51821å·ãå55â93149å·çã®å ¬
å ±ããªãã³ã«è±åœç¹èš±ç¬¬1455271å·ãç±³åœç¹èš±ç¬¬
3885968å·ãå第3700457å·ãå第4137079å·ãå
第4138265å·ã西ç¬ç¹èš±ç¬¬2617907å·çãšåæ现æž
ã«èšèŒãããŠããååç©ã§ãã第ïŒæ°Žéå¡©ãæã
ã¯é žåå€ïŒäŸãã°ïŒ®âããã²ãã¢ã»ãã¢ããã
âããã²ãã³ãã¯é žã€ãããéå¡©çŽ é žããã³ãã®
å¡©é¡ãç¡æ©éé žåç©ãéç¡«é žå¡©çïŒãæãã¯é žã
ãã³ãã®å¡©ïŒäŸãã°ã¹ã«ãã€ã³é žãã©ãŠãªã³é žãª
ããŠã ãããžã³ããžãã«ãã³é žãããªã¹ã«ãã³é ž
çïŒãæãã¯ã€ãªãŠå«æååç©ïŒäŸãã°ã¡ã«ã«ã
ãååç©æŸåºæ§ååç©ãããªãŠã©ã·ã«ããžã¹ã«ã
ã€ããã€ãªãŠåäœãã¡ã«ã«ããâïŒïŒïŒïŒïŒâã
ãªã¢ãŸãŒã«ããã¢ãŸãªã³ããªã³ãããªã¹ã«ãã€ã
ååç©çïŒããã®ä»ããªããµãŸãªã³ãïŒïŒïŒïŒïŒ
âããªã¢ãŸãŒã«ããã¿ã«ã€ããçã®ååç©ããã
ãããã ãŸãå®å®å€ãšããŠç¹ã«åŠçåŸã®ããªã³ãã¢ãŠã
é²æ¢å€ãåæã«çšããŠããããäŸãã°ç¹éæ48â
45228å·ãå50â119624å·ãå50â120328å·ãå
53â46020å·å ¬å ±çã«èšèŒã®ããã²ã³åçåæ°ŽçŽ
é¡ãå ·äœçã«ã¯ããã©ããã ãã¿ã³ãããªããã
ãšã¿ããŒã«ãïŒâããã¢âïŒâããªã«ã¢ã»ãã¢ã
ããïŒâããã¢âïŒâããªã«ã¹ã«ããã«ã¢ã»ãã¢
ãããïŒâããªããã¢ã¡ãã«ã¹ã«ããã«ãã³ãŸã
ã¢ãŸãŒã«ãïŒïŒïŒâãã¹ïŒããªããã¢ã¡ãã«ïŒâ
ïŒâã¡ãã«ããªã¢ãžã³ãªã©ããããããã ãŸãç¹å ¬æ46â5393å·ãç¹éæ50â54329å·ã
å50â77034å·åå ¬å ±èšèŒã®ããã«å«ã€ãªãŠåå
ç©ãçšããŠåŸåŠçãè¡ãªã€ãŠãããã ããã«ã¯ãç±³åœç¹èš±ç¬¬3301678å·ãå第3506444
å·ãå第3824103å·ãå第3844788å·åæ现æžã«èš
èŒã®ã€ãœããŠãããŠã ç³»ã¹ã¿ãã©ã€ã¶ãŒããªã«ãŒ
ãµãŒããŸãç±³åœç¹èš±ç¬¬3669670å·ãå第4012260
å·ãå第4060420å·æ现æžçã«èšèŒãããã¢ã¯ã
ããŒã¿ãŒã¹ã¿ãã©ã€ã¶ãŒãã¬ã«ãŒãµãŒçãå«æã
ãŠãããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã«ã¯ãããã«äž
èšæå以å€ã«å¿ èŠã«å¿ããŠãåå å¢æææããã¬
ãŒã·ãšã³é²æ¢ææãè¢å å¢çœå€ã硬èå€ã垯é»é²
æ¢å€ãå¯å¡å€ã延å±å€çåçš®ã®æ·»å å€ãå¡åžå©å€
çãæ·»å ãããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã«ã¯ãã€ã³ããŒ
ãšããŠã¯èŠªæ°Žæ§ã®ãã€ã³ããŒãçšããããããç
æ°Žæ§ãã€ã³ããŒãäžéšäœµçšãããŠããããæ¬çºæ
ã«çšãã芪氎æ§ãã€ã³ããŒãšã¯ãæ°Žãããã¯ãæ°Ž
ãšææ©æº¶åªïŒæ°Žãšä»»æã«æ··åã§ãã溶åªïŒã®æ··å
液ã«å¯æº¶ã§ãããã®ããããäŸãã°ãŒã©ãã³ããŒ
ã©ãã³èªå°äœã®åŠãèçœè³ªãã»ã«ããŒã¹èªå°äœã
ããã¹ãã©ã³ã®åŠãããªãµãã«ã©ã€ããã¢ã©ãã¢
ãŽã çã®åŠã倩ç¶ç©è³ªããã³æå¹ãªããªããŒãšã
ãŠãããªããã«ã¢ã»ã¿ãŒã«ïŒå¥œãŸããã¯ã¢ã»ã¿ãŒ
ã«å床ã20ïŒ ä»¥äžãäŸãã°ããªããã«ããã©ãŒ
ã«ïŒãããªã¢ã¯ãªã«ã¢ãããããªããã«ãããªã
ã³ããšãã«ã»ã«ããŒã¹ãããªããã«ã¢ã«ã³ãŒã«
ïŒã±ã³åçã75ïŒ ä»¥äžã®ãã®ã奜ãŸããïŒçã奜
ãŸãããããããã®ã¿ã«éå®ããããã®ã§ã¯ãª
ãããŸãå¿ èŠãªãã°ïŒçš®ä»¥äžæ··å䜿çšããŠãã
ãããã€ã³ããŒã®éã¯åæå å±€ãããææ©éå¡©ïŒ
éšã«å¯ŸããŠééæ¯ã§ïŒïŒ10ã10ã奜ãŸããã¯ïŒïŒ
ïŒãïŒéšã§ããã æ¬çºæã®åèšåæåãå«ãå±€ããã³ãã®ä»ã®å±€
ã¯åºç¯å²ã®åçš®æ¯æäœäžã«å¡åžããããæ¬çºæã«
䜿çšãããæ¯æäœãšããŠã¯ãã»ã«ããŒã¹ãã€ãã¬
ãŒããã€ã«ã ãã»ã«ããŒã¹ãšã¹ãã«ãã€ã«ã ãã
ãªããã«ã¢ã»ã¿ãŒã«ãã€ã«ã ãããªãšãã¬ã³ãã€
ã«ã ãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããã€ã«ã ãã
ãªã«ãŒãããŒããã€ã«ã çã®ãã©ã¹ããã¯ãã€ã«
ã ããã³ã¬ã©ã¹ãçŽãã¢ã«ãããŠã çã®éå±çã
ãããããããŸããã©ã€ã¿çŽãã¬ã·ã³ã³ãŒãã€ã
çŽãèæ°Žæ§çŽãçšããããšãã§ããã æ¬çºæã®æå ææã¯åºæ¬çã«ã¯åäžå±€äžã«(1)æ
å æ§ããã²ã³åéã(2)ææ©éå¡©ã(3)芪氎æ§ãã€ã³
ããŒã(4)æ¬çºæã®è²çŽ äŸäžç©è³ªã(5)éå å€ãå«æ
ãããããããããã¯å¿ ãããåäžã®åçæ§æå±€
äžã«å«æãããå¿ èŠã¯ãªããäŸãã°äžã€ã®æå å±€
ãäºå±€ã«åããæ¬çºæã®è²çŽ äŸäžç©è³ªãåèš(1)ã
(2)ã(3)ããã³(5)ã®æåãå«æããäžã€ã®æå å±€ã«
é£æ¥ããä»ã®æå å±€ã«å«æããããçãçžäºã«å
å¿å¯èœãªç¶æ ã§ããã°ïŒä»¥äžã®åçæ§æå±€ã«åã
ãŠå«æããããŠãããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã¯æè²æ§ãç°ã«
ããïŒä»¥äžã®æå å±€ãæããŠããŠãããããäžå¡
ãå±€ãäžå¡ãå±€ããããã³ã°å±€ãäžéå±€ãæãã¯
ãã€ã«ã¿ãŒå±€çåçš®ã®åçæ§æå±€ãæããŠããŠã
ããã 該ç±çŸåã«ã©ãŒæå ææã¯ç»åæ§é²å ããã³ç±
åŠçã«ãã€ãŠè²çŽ ç»åã圢æããããšãã§ãã
ããè²çŽ ç»åã®ããã®ç»åååå±€ãžãäŸãã°ã¡ã¿
ããŒã«ã®æ§ãªæº¶å€ããŸãã¯äŸãã°ã¡ãã«ã¢ã³ã»ãŒ
ãã®æ§ãªç±ã§æº¶èããç±æº¶å€ãçšããŠç±è»¢åããŠ
ããããšãã§ããããŸãè±åœç¹èš±ç¬¬1590957å·æ
现æžã«èšèŒã®æ§ãªç±è»¢åæ¹åŒãçšããããšãå¯èœ
ã§ããã æ¬çºæã®æå ææïŒä»¥äžãæ¬çºæã®æå èŠçŽ ãš
ãããïŒã¯ãåæ§é²å ããåŸãç±çŸåããããšã«
ãã€ãŠãç±è»¢åæ§è²çŽ ã®åæ§ååžã該è²çŽ äŸäžç©
質ãã圢æããã該åæ§ååžã®å°ãªããšãäžéš
ããæ¬çºæã®æå èŠçŽ ãšç©éé¢ä¿ã«ããååå±€ã«
ç±è»¢åããã«ã©ãŒç±æ¡æ£è»¢åæ¹æ³ã«é©çšãããå Ž
åãååå±€ã«åœ¢æãããç»åæ¿åºŠãæ¹è¯ãããé«
ãæ¿åºŠã®ç»åãäžããã ååå±€ã¯ãç±çŸåã«ããæŸåºä¹è³åœ¢æãããè²
çŽ ãå容ããæ©èœãæããã°ãããè²çŽ æ¡æ£è»¢å
åæå ææã«çšããããåªæå€ãç¹éæ57â
207250å·çã«èšèŒãããã¬ã©ã¹è»¢ç§»æž©åºŠã40â以
äž250â以äžã®èç±æ§ææ©é«ååç©è³ªã§åœ¢æãã
ãããšã奜ãŸããã åèšåªæå€ã®å ·äœçãªäŸãšããŠã¯ãå«çªçŽ äº
çŽãäžçŽã¢ãã³é¡ãå«çªçŽ è€çŽ ç°ååç©ãããã
ã®åçŽã«ããªã³æ§ååç©ãç±³åœç¹èš±ç¬¬2548564å·ã
å2484430å·ãå3148061å·ãå3756814å·ã«é瀺
ãããŠããããã«ããªãžã³ããªããŒããã³ããã«
ããªãžããŠã ã«ããªã³ããªããŒãç±³åœç¹èš±ç¬¬
2675316å·ã«é瀺ãããŠãããžã¢ã«ãã«ã¢ããåº
ãå«ãããªããŒãç±³åœç¹èš±ç¬¬2882156å·ã«é瀺ã
ããŠããã¢ããã°ã¢ããžã³èªå°äœãç±³åœç¹èš±ç¬¬
3625694å·ãå3859096å·ãè±åœç¹èš±ç¬¬1277453å·ã
å2011012å·ã«é瀺ãããŠãããŒã©ãã³ãªã©ãšæ¶
æ©å¯èœãªåªæå€ãç±³åœç¹èš±ç¬¬3958995å·ãå
2721852å·ãå2798063å·ã«é瀺ãããŠããæ°Žæ§ãŸ
ã«ååªæå€ãç¹éæ50â61228å·ã«é瀺ãããŠã
ãæ°Žäžæº¶æ§åªæå€ãç±³åœç¹èš±ç¬¬3788855å·ã西ç¬
ç¹èš±åºé¡ïŒOLSïŒç¬¬2843320å·ãç¹éæ53â
30328å·ãå52â155528å·ãå53â125å·ãå53â
1024å·ãå54â74430å·ãå54â124726å·ãå55
â22766å·ãç±³åœç¹èš±ç¬¬3642482å·ãå3488706å·ã
å3557066å·ãå3271147å·ãå3271148å·ãç¹å ¬
æ55â29418å·ãå56â36414å·ãå57â12139å·ã
RD12045ïŒ1974幎ïŒã«é瀺ãããŠããåçš®åªæå€
ããããããšãã§ããã ç¹ã«æçšãªåªæå€ã¯ã¢ã³ã¢ããŠã å¡©ãå«ãããª
ããŒã§ãç±³åœç¹èš±ç¬¬3709690å·ã«èšèŒãããŠããã
äŸãã°ã¢ã³ã¢ããŠã å¡©ãå«ãããªããŒãšããŠã¯ã
ããªã¹ãã¬ã³âã³âïŒïŒ®ïŒïŒ®âããªâïœâãã
ã·ã«ââããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€
ãã§ãã¹ãã¬ã³ãšããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯
ãã©ã€ãã®æ¯çã¯ãïŒïŒïŒãïŒïŒïŒã奜ãŸããã¯
ïŒïŒïŒã§ããã å žåçãªè²çŽ æ¡æ£è»¢åçšã®ååå±€ã¯ã¢ã³ã¢ããŠ
ã å¡©ãå«ãããªããŒããŒã©ãã³ãšæ··åããŠæ¯æäœ
äžã«å¡åžããããšã«ããåŸããããè²çŽ ã®ç±çŸå
æå å±€ããååå±€ãžã®è»¢åã«ã¯ã転å溶åªãçšã
ãããšãã§ããããã®è»¢å溶åªã«ã¯ãã¡ã¿ããŒ
ã«ãé ¢é žãšãã«ããžã€ãœããã«ã±ãã³çã®äœæ²žç¹
溶åªããã³ããªâïœâã¯ã¬ãžã«ããªã¹ããšãŒãã
ããªâïœâããã«ãã¹ããšãŒãããžâïœâããã«
ãã¿ã¬ãŒãçã®é«æ²žç¹æº¶åªãçšããé«æ²žç¹æº¶åªã®
å Žåã«ã¯ãé©åœãªä¹³åå€ãçšããŠãŒã©ãã³äžã«ä¹³
åãååå±€ã«æ·»å ããããšãã§ããã åèšèç±æ§ææ©é«ååç©è³ªã®äŸãšããŠã¯ãåå
é2000ã85000ã®ããªã¹ãã¬ã³ãççŽ æ°ïŒä»¥äžã®
眮æåºããã€ããªã¹ãã¬ã³èªå°äœãããªããã«ã·
ã¯ããããµã³ãããªãžããã«ãã³ãŒã³ãããªãã
ã«ãããªãã³ãããªããã«ã«ã«ããŸã«ãããªã¢ãª
ã«ãã³ãŒã³ãããªããã«ã¢ã«ã³ãŒã«ãããªããã«
ãã«ããŒã«ããã³ããªããã«ããã©ãŒã«ãªã©ã®ã
ãªã¢ã»ã¿ãŒã«é¡ãããªå¡©åããã«ãå¡©çŽ åããªãš
ãã¬ã³ãããªäžå¡©åãµã€åãšãã¬ã³ãããªã¢ã¯ãª
ããããªã«ãããªâïŒïŒ®âãžã¡ãã«ã¢ãªã«ã¢ã
ããïœâã·ã¢ãããšãã«åºããã³ã¿ã¯ããããšã
ã«åºããã³ïŒïŒïŒâãžã¯ããããšãã«åºããã€ã
ãªã¢ã¯ãªã¬ãŒããããªã¢ã¯ãªã«ã¯ããã¢ã¯ãªã¬ãŒ
ããããªã¡ãã«ã¡ã¿ã¯ãªã¬ãŒããããªãšãã«ã¡ã¿
ã¯ãªã¬ãŒããããªãããã«ã¡ã¿ã¯ãªã¬ãŒããããª
ã€ãœãããã«ã¡ã¿ã¯ãªã¬ãŒããããªã€ãœããã«ã¡
ã¿ã¯ãªã¬ãŒããããªâtertâããã«ã¡ã¿ã¯ãªã¬ãŒ
ããããªã·ã¯ãããã·ã«ã¡ã¿ã¯ãªã¬ãŒããããªãš
ãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒããããªâïŒâ
ã·ã¢ãâãšãã«ã¡ã¿ã¯ãªã¬ãŒããããªãšãã¬ã³ã
ã¬ãã¿ã¬ãŒããªã©ã®ããªãšã¹ãã«é¡ãããªã¹ã«ã
ã³ããã¹ããšããŒã«ïŒ¡ããªã«ãŒãããŒãçã®ããª
ã«ãŒãããŒãé¡ãããªã¢ã³ããã©ã€ããããªã¢ã
ãé¡äžŠã³ã«ã»ã«ããŒã¹ã¢ã»ããŒãé¡ãããããã
ãããŸããPolymer Handbook 2nd cd.ïŒJ.
BrandrupãE.H.Immergutç·šïŒJohn Wiley ïŒ
Sonsåºçãã«èšèŒãããŠããã¬ã©ã¹è»¢ç§»æž©åºŠ
40â以äžã®åæããªããŒãæçšã§ããããããã®
é«ååç©è³ªã¯ãåç¬ã§çšããããŠãããŸãè€æ°ä»¥
äžãçµã¿åããŠå ±éåäœãšããŠçšããŠãããã ç¹ã«æçšãªããªããŒãšããŠã¯ãããªã¢ã»ããŒ
ãããžã¢ã»ããŒããªã©ã®ã»ã«ããŒã¹ã¢ã»ããŒãã
ããã¿ã¡ãã¬ã³ãžã¢ãã³ãšã®ãã¬ãã¿ã«é žããã«
ãªã¬ã³ãžãããã«ã¢ãã³ãšã¢ãžãã³é žããããµã¡
ãã¬ã³ãžã¢ãã³ãšãžããšã³é žããããµã¡ãã¬ã³ãž
ã¢ãã³ãšã€ãœãã¿ã«é žãªã©ã®çµã¿åãã«ããããª
ã¢ããããžãšãã¬ã³ã°ãªã³ãŒã«ãšãžããšãã«ã«ã«
ãã³é žããã¹âïœâã«ã«ããã·ããšããã·ãã¿ã³
ãšãšãã¬ã³ã°ãªã³ãŒã«ãªã©ã®çµã¿åãã«ããããª
ãšã¹ãã«ãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããããªã«
ãŒãããŒãããããããããããã®ããªããŒã¯æ¹
質ããããã®ã§ãã€ãŠããããããšãã°ãã·ã¯ã
ãããµã³ãžã¡ã¿ããŒã«ãã€ãœãã¿ã«é žãã¡ããã·
ããªãšãã¬ã³âã°ãªã³ãŒã«ãïŒïŒïŒâãžã«ã«ãã¡
ããã·âïŒâãã³ãŒã³ã¹ã«ãã³é žãªã©ãæ¹è³ªå€ãš
ããŠçšããããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããæå¹ã§
ããã äžèšã®ããªããŒã¯é©åœãªæº¶å€ã«æº¶ãããŠæ¯æäœ
äžã«å¡åžããŠååå±€ãšãããããããã¯äžèšããª
ããŒããæããã€ã«ã ç¶ååå±€ãæ¯æäœã«ã©ãã
ãŒãããŠçšãããããããŸãã¯æ¯æäœäžã«å¡åžã
ãããšãªããäžèšããªããŒããæãéšæïŒäŸãã°
ãã€ã«ã ïŒåç¬ã§ååå±€ãæ§æããããšïŒåå
å±€ã»æ¯æäœå ŒçšåïŒãã§ããã ããã«ååå±€ãšããŠã¯éææ¯æäœäžã®ååå±€ã®
äžã«ãŒã©ãã³åæ£ããäºé žåãã¿ã³çãå«ãäžé
æåå±€ïŒåå°æ§å±€ïŒãèšããŠæ§æããããšãã§ã
ãããã®äžéæåå±€ã¯ã転åè²ç»åãååå±€ã®é
ææ¯æäœåŽããèŠãããšã«ããåå°åã®è²åãåŸ
ãããã ãå®æœäŸã 以äžã«æ¬çºæã®å®æœäŸã瀺ãããæ¬çºæã®å®æœ
æ æ§ã¯ãããã«éããããã®ã§ã¯ãªãã ïŒïŒâã¹ã«ããã³ãŸããªã¢ãŸãŒã«éå¡©ã®èª¿è£œïŒ 20ïœã®ïŒâã¹ã«ããã³ãŸããªã¢ãŸãŒã«åã³ïŒïœ
ã®æ°Žé žåãããªãŠã ããšã¿ããŒã«âæ°ŽïŒïŒïŒïŒïŒ
æ··å液300mlã«å ã溶解ããããã®æº¶æ¶²ã«ïŒèŠå®
ã®ç¡é žé溶液20mlã滎äžããããã®éïŒèŠå®ã®æ°Ž
é žåãããªãŠã 溶液ãåæã«æ»ŽäžãPHãïŒãïŒã«
ç¶æããããã®æº¶æ¶²ãïŒæé宀枩ã§æ¹æããåŸã
æ°Žã§400mlã«ä»äžããŠïŒâã¹ã«ããã³ãŸããªã¢ãŸ
ãŒã«é溶液ã調補ããã å®æœäŸ ïŒ äŸç€ºè²çŽ äŸäžç©è³ª(1)4.1ïœãšïŒïŒ ã®ãžïŒïŒâãš
ãã«ããã·ã«ïŒâïŒâã¹ã«ãã³ãã¯é žæ°Žæº¶æ¶²1.6
mlãæ°Ž2.8mlãã¡ã¿ããŒã«ïŒmlãæ··åããããã«
ïŒmlã®ïŒèŠå®æ°Žé žåãããªãŠã 溶液ãå ããåŸã
ïŒïŒ ã®ãŒã©ãã³æ°Žæº¶æ¶²17.5mlãå ããããã®åæ£
液ãïŒïŒ ã®ã¯ãšã³é žã§äžåããåŸãæ°Žã§30mlã«ä»
äžããã äžèšã®ïŒâã¹ã«ããã³ãŸããªã¢ãŸãŒã«é溶液ïŒ
mlãè²çŽ äŸäžç©è³ªã®åæ£æ¶²ïŒmlãæ··åããããã«
ããªããã«ãããªãã³ïŒååé30000ïŒ730mgãã
ã³ã¿ãšãªã¹ãªããŒã«520mgãããªãšãã¬ã³ã°ãªã³
ãŒã«ïŒååé400ïŒ310mgãæ°ŽïŒmlåã³äžèšçŸåå€
200mgãå ããåŸãïŒïŒ ã¯ãšã³é žã§PHã5.5ãšã
ãããã®åæ£æ¶²ã«å¹³åç²åŸ0.05ÎŒmã®æ²èåéã
éã«æç®ããŠïŒÃ10-4ã¢ã«æ·»å ããããªãšãã¬ã³
ãã¬ãã¿ã¬ãŒãæ¯æäœäžã«æ¹¿æœ€èåã65ÎŒmãšãª
ãæ§ã«ã¯ã€ã€ãŒããŒã«ãŠå¡åžããã äžèšå¡åžç©ã也ç¥ããŠåŸãããè©Šæã«å¯ŸããŠã¹
ããããŠãšããžãéããŠã30000CMSïŒã«ã³ã
ã©ã»ã¡ãŒã¿ãŒã»ç§ïŒã®é²å ãäžããã 次ãã§äžèšé²å æžã¿è©Šæã®å¡åžé¢ã«ããã©ã€ã¿
çŽäžã«å¡©åããã«ãå¡åžããååçŽãéããŠãè¡š
é¢æž©åºŠã160âã®éå±è£œããŒããããã¯ã§60ç§é
å§çå ç±ãã次ãã§ååçŽãå¥ããååçŽã«è»¢å
ããè²çŽ åæ¿åºŠïŒééæ¿åºŠïŒã枬å®ããããã®çµ
æãåŸèšç¬¬ïŒè¡šã«ç€ºãã å®æœäŸ ïŒ ããªããã«ãããªãã³ãããªããã«ã¢ã«ã³ãŒã«
ïŒéå床400ïŒã«ä»£ãã以å€ã¯å®æœäŸïŒãšåãåŠæ³
ã§äœæããè©Šæãçšæããå®æœäŸïŒãšåãé²å ã
çŸåãè¡ãªã€ãããã®çµæãåãã第ïŒè¡šã«ç€º
ãã å®æœäŸ ïŒ ç±æº¶å€ã®ããªãšãã¬ã³ã°ãªã³ãŒã«ããžã¡ãã«ãŠ
ã¬ã¢ïŒ310mgïŒã«ä»£ãã以å€ã¯å®æœäŸïŒãšåãåŠ
æ³ã§äœæããè©Šæãçšæããå®æœäŸïŒãšåãé²
å ãçŸåãè¡ãªã€ãããã®çµæãåãã第ïŒè¡šã«
瀺ãã å®æœäŸ ïŒ è²çŽ äŸäžç©è³ªãšããŠäŸç€ºè²çŽ äŸäžç©è³ª(1)ã®ä»£ã
ãã«äŸç€ºè²çŽ äŸäžç©è³ª(3)ãçšãã以å€ã¯å®æœäŸïŒ
ãšåãåŠæ³ã§äœæããè©Šæãçšæããå®æœäŸïŒãš
åãé²å ãçŸåãè¡ãªã€ãããã®çµæãåãã第
ïŒè¡šã«ç€ºãã å®æœäŸ ïŒ è²çŽ äŸäžç©è³ªãšããŠäŸç€ºè²çŽ äŸäžç©è³ª(1)ã®ä»£ã
ãã«äŸç€ºè²çŽ äŸäžè³ªïŒ13ïŒãçšãã以å€ã¯å®æœäŸ
ïŒãšåãåŠæ³ã§äœæããè©Šæãçšæããå®æœäŸïŒ
ãšåãé²å ãçŸåãè¡ãªã€ãããã®çµæãåãã
第ïŒè¡šã«ç€ºãã å®æœäŸ ïŒ å®æœäŸïŒã®è©Šæãå®æœäŸïŒãšåãé²å ãäžãã
åŸãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããããªãååå±€
ãéãåãããŠè¡šé¢æž©åºŠã160âã®éå±ããŒãã
ããã¯ã§60ç§éå§çå ç±ãã次ãã§ååå±€ãå¥ã
ãã転åããæ¿åºŠãééæ¿åºŠã§æž¬å®ããããã®çµ
æãåãã第ïŒè¡šã«ç€ºãã æ¯èŒäŸ ïŒããã³ïŒ è²çŽ äŸäžç©è³ªãšããŠäžèšè²çŽ äŸäžç©è³ª(A)ããã³
(B)ãçšãã以å€ã¯å®æœäŸïŒãšåãåŠæ³ã§äœæãã
ïŒçš®ã®è©Šæãçšæããå®æœäŸïŒãšåãé²å ãçŸå
ãè¡ãªã€ãããã®çµæãåãã第ïŒè¡šã«ç€ºãã
ãããïœåã³ïœã¯ïŒãïŒåã¯ïŒãè¡šããïŒãã ã
ïœãïœã¯å ±ã«ïŒã§ã¯ãªãïŒãïœã¯ïŒïŒïœïŒïŒã®æïŒ
åã¯ïŒïŒïœïŒïŒã®æïŒãè¡šããã äžèšïŒ¹ã§è¡šãããã芪氎æ§åºåã³ïŒžã§è¡šããã
ãåºã«çœ®æããã芪氎æ§åºãšããŠã¯ãäŸãã°ã¹ã«
ãåºãã¹ã«ãã¢ã¢ã€ã«åºãã¹ã«ãã€ãåºãã¹ã«ã
ãšãåºãããªã¹ã«ãåºããžãªãã¹ã«ãåºãããã
ãã·ã¹ã«ããã«ãªãã·åºãããããã·ã¹ã«ããã«
ããªåºãã«ã«ããã·åºãããªã«ã«ããã·åºãã«ã«
ããã·ã€ããé žåºãããã©ãŸã³é žåºãã«ã«ããã
ã©ãŸã³é žåºãããããã·ã é žåºãã«ã«ããããã
ã·ã é žåºããããããµã é žåºãã«ã«ããããããµ
ã é žåºãã¹ã«ãã€ã³ã€ããé žåºãã¹ã«ãã³ã€ãã
é žåºãã¹ã«ãã€ãããã©ãŸã³é žåºãã¹ã«ãããã
ã©ãŸã³é žåºãã¹ã«ãã€ãããããã·ã é žåºãã¹ã«
ããããããã·ã é žåºããããã®åºã§å¡©ãäœãåŸ
ããã®ã¯ãããã®åºã®å¡©ïŒäŸãã°ã¢ã«ã«ãªéå±
å¡©ãã¢ã³ã¢ããŠã å¡©çïŒçãæããããç¹ã«å¥œãŸ
ããã¯ã¹ã«ãåºåã³ã«ã«ããã·åºã§ããã 以äžãæ¬çºæã«ã€ããŠè©³è¿°ããã åèšäžè¬åŒããåã¯ããã§è¡šããããããŒ
ã³ã¿è²çŽ äŸäžç©è³ªã¯èŠªæ°Žæ§åºãæããååç©ã§ã
ã€ãŠãç±çŸåã«éããŠæ¡æ£æ§ã®èŠªæ°Žæ§åºãæããª
ãè²çŽ ã圢æãåŸãååç©ã§ããã äžèšã®ç±çŸåã«éããŠåœ¢æãããæ¡æ£æ§è²çŽ ã®
âæ¡æ£æ§âãšã¯ãåèšè²çŽ äŸäžç©è³ªãã圢æãã
ãããŒã³ã¿è²çŽ ãã該è²çŽ äŸäžç©è³ªãå«æããå±€
ããç©éé¢ä¿ã«ããé£æ¥å±€ã«ç§»åãåŸãæ§è³ªãæ
å³ãããã®ç§»åã®æ æ§ã«ã€ããŠã¯ãäŸãã°çæã
ããè²çŽ èªäœãæ¡æ£æ§ååç©ã§ããå Žåã«ã¯ãã
ã®æ¡æ£æ§ã«åºã¥ããŠåè¿°ã®ç§»åãè¡ãªããããŸã
ä»ã®äŸãšããŠã¯åœ¢æãããè²çŽ ãè²çŽ ã®æº¶å€ã«æº¶
解ããããŸãã¯ç±æº¶å€ã«ãã€ãŠå ç±æº¶è§£ãããŠç§»
åãè¡ãªãããå Žåçãå«ãŸãããããã«åœ¢æã
ããè²çŽ èªäœãæè¯æ§ã§ãã€ãŠã圢æãããè²çŽ
ãæè¯ããŠé£æ¥å±€ãžç§»åããæ æ§ãå«ãŸããã ããã§ãäžèšâæè¯æ§âãšã¯äžè¬ã«çšããããŠ
ããã液äœç¶æ ãçµãããšãªãåºäœããæ°äœã«å€
åããæ§è³ªã ãã§ãªããåºäœã溶èããŠæ¶²äœã«ãª
ãããã®æ¶²äœããæŽã«æ°äœã«å€åããæ§è³ªããå«
ããã®ã§ããã æ¬çºæã«çšããããäžè¬åŒããåã¯ããã§
è¡šããããããŒã³ã¿ã®è²çŽ äŸäžç©è³ªã¯ããŒã³ã¿ã«
ãã©ãŒæ¯æ žã§ããïŒâãã©ãŸãã³ã®ïŒäœïŒä»¥äžã
掻æ§ç¹ãšèšãïŒã§çºè²çŸåäž»è¬ã®é žåäœãšåå¿
ããããŒã³ã¿è²çŽ ã圢æããããããã®éããŒã³
ã¿ã«ãã©ãŒæ¯æ žããååéãå°ããïŒå¥œãŸããã¯
ååé400以äžïŒãã€èŠªæ°Žæ§åºãå«ãŸãªãå Žåã«
ã¯èŠªæ°Žæ§ãã€ã³ããŒäžã§ã®æ¡æ£æ§ã«å¯ããšããæ§
質ãæããããŸã掻æ§ç¹ã®çœ®æåºã«ã¹ã«ãåºåã¯
ã«ã«ããã·åºã®åŠã芪氎æ§åºãå«ãã åºãååšã
ãããšã«ããè²çŽ äŸäžç©è³ªã¯çŸåæäžååãããŠ
ããããã®æŽ»æ§ç¹ã®çœ®æåºã¯è²çŽ 圢æã®éé¢è±ã
ãã®ã§åœ¢æè²çŽ ã«ã¯äžéœåãšãªããªãã詳现ã¯åŸ
è¿°ããã äžèšäžè¬åŒããåã¯ããã§è¡šããããããŒ
ã³ã¿ã®è²çŽ äŸäžç©è³ªã®ãã¡ã§ç¹ã«å¥œãŸãããã®ã¯
äžèšäžè¬åŒããã§ç€ºãããè²çŽ äŸäžç©è³ªã§ã
ãã äžè¬åŒãã åŒäžãR1ãR2ãããïœãïœåã³ïœã¯äžè¬
åŒããã§å®çŸ©ããããã®ãšåã å矩ã§ããã 以äžã«ãæ¬çºæã«çšããããäžè¬åŒããåã¯
ããã§è¡šããããããŒã³ã¿ã®è²çŽ äŸäžç©è³ªã®ä»£
è¡šçå ·äœäŸãèšèŒãããããããã«éå®ãããã
ã®ã§ã¯ãªãã æ¬çºæã®ããŒã³ã¿è²çŽ äŸäžç©è³ªã¯åç¬ã§çšããŠ
ãããããïŒä»¥äžã䜵çšããŠãããã æ¬çºæã«çšããããè²çŽ äŸäžç©è³ªã¯äžè¬çã«ã¯
ïŒâãã©ãŸãã³ããŒã³ã¿ã«ãã©ãŒãšèŠªæ°Žæ§åºãæ
ã€ãèèªæåã¯è³éŠæã®ãžã¢ã«ããããšãåå¿ã
ããŠåŸããåã¯ïŒâãã©ãŸãã³ããŒã³ã¿ã«ãã©ãŒ
ãšèèªæåã¯è³éŠæãžã¢ã«ããããšãåå¿ãããŠ
åŸãããååç©ã«æ°Žæº¶æ§åºãæã€ã眮æåºãå°å ¥
ããããšã«ãã€ãŠåŸãããã 次ã«å ·äœçãªåæäŸã瀺ãã åæäŸ ïŒ è²çŽ äŸäžç©è³ª(3)ã®åæ 8.65ïœã®ïŒâããšãã«âïŒãã¢ã»ãã«ã¢ããâ
ïŒâãã©ãŸãã³ãš1.8ïœã®ïŒâãããâã€ãœãã¿
ã«ã¢ã«ããããšã100mlãšã¿ããŒã«ã«å ããïŒæ
éå ç±éæµããåŸããšã¿ããŒã«ãé€å»ãããåŸã
ããåºäœã100mlã®ã¢ã»ãã³ã«å ããããã«ãã
ç²æ«ïŒïœãšæ¿å¡©é žïŒmlãå ããŠå®€æž©ã§ïŒæéæ¹æ
ããããã«ïŒæéå ç±éæµããåŸãå·åŽäžã§çé ž
ãããªãŠã ãå ãPHãçŽ6.0ãšããããã®åå¿æ¶²
ãæ¿Ÿéããæ¿çž®ããæåºããçµæ¶ãæ¿Ÿéãã¢ãã³
äžéäœãåŸãã 2.8ïœã®ïŒâã¹ã«ãã¹ãã¢ãªã³é žãã¢ã»ããã
ãªã«ïŒ12mlïŒãšããªãžã³ïŒïŒmlïŒã®æ··å溶液ã«å
ããããã«ïŒmlã®ãã³ãŒã³ã¹ã«ããã«ã¯ãã©ã€ã
ãå ããïŒæééæµããåŸ30âã«å·åŽããäžèšã¢
ãã³äžéäœïŒ7.3ïœïŒã®ã¢ã»ããããªã«ïŒ20mlïŒ
溶液ã滎äžããã滎äžåŸïŒæééæµããåŸãæ¿Ÿé
ã濟液ãæ¿çž®åŸ200mlã®ã¡ã¿ããŒã«ãå ãåã³æ¿Ÿ
éã濟液ãæ¿çž®åŸé£œåé£å¡©æ°ŽïŒ200mlïŒãå ãã
æåºããæ²æŸ±ãæ¿Ÿéããåã³200mlã®ã¡ã¿ããŒã«
ã«å ãæ¿Ÿéãã濟液ãæ¿çž®ããŠäžçŽç©ãå«ãã ç®
çç©ãåŸãããããã¯ãããã«ã âã¡ã¿ããŒã«
ïŒïŒïŒïŒïŒãå±é溶åªãšããŠã«ã©ã ã¯ãããã°ã©
ãã€ãŒã«ãã粟補ããŠç®çç©4.2ïœãåŸãã åæäŸ ïŒ è²çŽ äŸäžç©è³ªïŒ14ïŒã®åæ 18.5ïœã®ïŒâïŒïŒ®âããã«ãã«ââã¡ãã«ïŒ
ã¢ããâïŒâã¹ã«ãã¢ããªã³ã200mlã®ãã«ãšã³
ãš40mlã®ããªãžã³æ··å液ã«åæ£ãã3.5mlã®ïŒå¡©
åãªã³ã®ãã«ãšã³ïŒ100mlïŒæº¶æ¶²ã滎äžãã1.5æ
é120âã§åå¿ãããããã®åå¿æ¶²ãå·åŽãã7.5
ïœã®ãã¬ãã¿ã«ã¢ã«ãããé žã®ãã«ãšã³ïŒ50mlïŒ
溶液ã滎äžãã滎äžåŸïŒæé120âã§åå¿ãããã
åå¿æ¶²ãæ¿Ÿéãæ²æŸ±ã200mlã®ã¡ã¿ããŒã«ã«å ã
å ç±æº¶è§£ããåŸäžæº¶ç©ãæ¿Ÿéã§é€ããåŸãã¡ã¿ã
ãŒã«æº¶æ¶²ãæ¿çž®ãããç¶ããŠ200mlã®ãšã¿ããŒã«
ãå ã溶解ããããã«21.6ïœã®ïŒâããšãã«âïŒ
âã¢ã»ãã«ã¢ããâïŒâãã©ãŸãã³ãå ããïŒæ
ééæµããåŸãæ¿çž®ãåæäŸïŒãšåæ§ã®æ¹æ³ã§ç²Ÿ
補ããŠç®çç©24.5ïœãåŸãã äžèšã®åææ¹æ³ã«ãã補é ãããæ¬çºæã«çšã
ãããè²çŽ äŸäžç©è³ªã¯ãåèšäžè¬åŒããã§è¡šã
ãããããã«çæ°Žæ§åºãæããã«ãã©ãŒååã®æŽ»
æ§ç¹ã«é¢è±å¯èœãªåºãšããŠèŠªæ°Žæ§åºãŸãã¯èŠªæ°Žæ§
åºãæããåºã眮æããããååç©ã§ãããåŸã€
ãŠè©²ååç©ãå«ãŸãã芪氎æ§ãã€ã³ããŒäžã§ã¯ã
ãã®èŠªåæ§ã®ããã«éæ¡æ£åãããããç±çŸåã«
éããŠã¯ãé žåã«ããªã³ã°åå¿ã«ãã掻æ§ç¹ã®èŠª
æ°Žæ§åºãé¢è±ããããããããŠèŠªæ°Žæ§åºã倱ã€ã
è²çŽ ã¯ããã¯ã芪氎æ§ãã€ã³ããŒïŒåŸè¿°ããïŒãš
ã®èŠªåæ§ã倱ããå®å šã«çæ°Žæ§ãšãªãããã芪å
æ§ã®åŒ·ãååå±€ãžãšæ¡æ£ããŠãããååå±€äžã«è²
çŽ ç»åã圢æãããããäžæ¹ãç±çŸåã«éããŠäž
èšæŽ»æ§ç¹ããé¢è±ããã芪氎æ§ãå«ãæåã¯ãäŸ
ç¶ãšããŠèŠªæ°Žæ§ãã€ã³ããŒã«å¯ŸããŠèŠªåæ§ãæã
ãã®ã§èŠªæ°Žæ§ãã€ã³ããŒäžã«æ®çããååå±€ã«æ¡
æ£ããŠããããšã¯ãªããããããå¹æã¯ååå±€ã
çæ°Žæ§ç©è³ªã«ãã€ãŠæ§æãããŠããå Žåã«ç¹ã«å€§
ããã åŸã€ãŠæ¬çºæã«ããã°ãç±çŸåã«éããè²çŽ äŸ
äžç©è³ªæ®åºãšæ¡æ£æ§è²çŽ ãšã®åé¢æ§ãèããæ¹è¯
ãããååå±€ã®æ±æã®çºçã¯å®å šã«é²æ¢ãããä¿
åã«ããæ±ããçºçããããšãè³ã€ãŠå°ãªããªã€
ãããŸãå€å±€æ§æã®å Žåãè²æ¿ãã®ãªãè²çŽ ç»å
ãåŸãããã ããã«ãŸããæ¬çºæã«çšããããè²çŽ äŸäžç©è³ª
ã«ãããŠã¯è©²ååç©ã®éæ¡æ£æ§ãé«ããããã«ã«
ãã©ãŒæ®åºã®æŽ»æ§ç¹ã«ãã©ã¹ãåºãå°å ¥ãããã®
ãã©ã¹ãåºã«åèšã®èŠªæ°Žæ§åºãããããããšã¯é
åžžã«å¥œãŸããããšã§ããã ããªãã¡ãè²çŽ äŸäžç©è³ªã«ãã©ã¹ãåºãæãã
ãããšã«ãããç±çŸå以åã«ããã芪氎æ§ãã€ã³
ããŒäžã§ã®è²çŽ äŸäžç©è³ªã®éæ¡æ£æ§ãããé«ãã
ããšãã§ããããã§ããããŸãç±çŸåã«éããŠã¯
ã«ãã©ãŒååã®æŽ»æ§ç¹ããé¢è±ãã芪氎æ§åºãæ
ãããã©ã¹ãåºæåã¯ã芪氎æ§åºãšçžä¿ã€ãŠèŠªæ°Ž
æ§ãã€ã³ããŒäžã§ã®äžååããã匷åºã«ããããš
ãã§ããã®ã§ãæ¬çºæã®åèšå¹æãããé«ããã
ãšãå¯èœã«ãããã ããã«ã¯æ¬çºæã«çšããããè²çŽ äŸäžç©è³ªã¯ã
ç¡è²ãçœè²ã«è¿ãã®ã§ãå±€ãçè²ãããããšããª
ãæå¹æ床ãæãªãããšããªãã äžèšæ¬çºæã«çšããããè²çŽ äŸäžç©è³ªã¯ãç±çŸ
åæå çµæãå¡åžæ¡ä»¶ãåŠçæ¹æ³çã«ããç°ãªã
ãã倧äœææ©éå¡©ïŒã¢ã«ã«å¯ŸããŠ0.01ã¢ã«ã10ã¢
ã«ã®ç¯å²ã§çšãããã奜ãŸããã¯0.1ã¢ã«ã2.0ã¢
ã«ã§ããã æ¬çºæã«çšããããè²çŽ äŸäžç©è³ªã¯ç±çŸåæå
å±€ãŸãã¯ä»ã®åçæ§æå±€ã«å«æãããŠçšãããã
ããäŸãã°ç±çŸåæå å±€äžã«å«æããããã«ã¯ã
ã«ãã©ãŒã®åæ£æ³ã«é¢ããç±³åœç¹èš±ç¬¬2322027å·
ã«èšèŒãããŠããããã«é«æ²žç¹æº¶åªã«æº¶è§£ããŠå«
æãããããšãã§ãããããã«äžèšã®åŠãåæ£æ¹
æ³ã«ãããŠãäžèšé«æ²žç¹æº¶åªã«å¿ èŠã«å¿ããŠäœæ²ž
ç¹æº¶åªã䜵çšããŠè²çŽ äŸäžç©è³ªã溶解ããŠç±çŸå
æå å±€ã«å«æãããããšãã§ããã äžèšã®é«æ²žç¹æº¶åªãšããŠã¯ãäŸãã°ãžâïœâã
ãã«ãã¿ã¬ãŒããããªã¯ã¬ãžã«ãã¹ããšãŒãããž
âãªã¯ãã«ãã¿ã¬ãŒããïœâããã«ããšããŒã«ç
ãããããŸãäœæ²žç¹æº¶åªãšããŠã¯ãäŸãã°é ¢é žã¡
ãã«ãããããªã³é žããã«ãã·ã¯ããããµããŒ
ã«ããžãšãã¬ã³ã°ãªã³ãŒã«ã¢ãã¢ã»ããŒããªã©ã
ç¥ãããŠããããããã®æº¶åªã¯åç¬ã§çšããŠãã
æ··åããŠçšããŠãããããã®ããã«æº¶åªã«æº¶è§£ã
ããè²çŽ äŸäžç©è³ªã¯ãã¢ã«ãã«ãã³ãŒã³ã¹ã«ãã³
é žããã³ã¢ã«ãã«ããã¿ã¬ã³ã¹ã«ãã³é žã®åŠãã¢
ããªã³ç³»çé¢æŽ»æ§å€ããã³ïŒãŸãã¯ãœã«ãã¿ã³ã¢
ãã©ãŠãªã³é žãšã¹ãã«ã®åŠããããªã³ç³»çé¢æŽ»æ§
å€ãå«ããŒã©ãã³çã®èŠªæ°Žæ§ãã€ã³ããŒãå«æã
ã氎溶液ãšæ··åããã³ãã€ããã«ãŸãã¯è¶ é³æ³¢å
æ£è£ 眮çã§ä¹³ååæ£ããç±çŸåæå å±€ã«æ·»å ãã
ããããšãã§ããã äžèšé«æ²žç¹æº¶åªã¯ãè²çŽ äŸäžç©è³ªãå®å šã«æº¶è§£
ããããéã§çšãããããã奜ãŸããã¯è²çŽ äŸäž
ç©è³ªïŒéšã«å¯ŸããŠ0.05ã100éšã®ç¯å²ã§çšããã
ãšãã§ããã äžèšä»¥å€ã®å¥œãŸããåæ£æ¹æ³ãšããŠã¯ãã€ãã·
ã€ãŒåæ£ãããã該ãã€ãã·ã€ãŒåæ£ãšã¯ãåäž
ååäžã«èŠªæ°Žæ§æåãšçæ°Žæ§æåãšãæããè²çŽ
äŸäžç©è³ªãã¢ã«ã«ãªæ°Žæº¶æ¶²ã«æº¶è§£ãåæ£ããããš
ãããããã®æº¶è§£ãåæ£ã«ããããæ°Žãšçžæº¶æ§ã
æããææ©æº¶åªãæ·»å ããããå ç±ãæ¹æïŒãã¢
ãžãã€ã¶ãŒãè¶ é³æ³¢åæ£ãªã©ïŒãããããããã¯
çé¢æŽ»æ§å€ã®å©ããããããªã©ããŠããããã¢ã«
ã«ãªæ°Žæº¶æ¶²ã®ã¢ã«ã«ãªãšããŠã¯ãç¡æ©å¡©åºãæ°Žãš
çžæº¶æ§ã®ããææ©å¡©åºãçšããããšãã§ããè²çŽ
äŸäžç©è³ªã溶解ãåæ£ããåŸãå¿ èŠã«å¿ããŠPHã
調æŽããããšãã§ããããã®å Žåã®PH調æŽå€ã«ã¯
æ°Žãšçžæº¶æ§ã®ããææ©åã¯ç¡æ©é žãçšããããšã
ã§ãããåæ£å©å€ãšããŠã®çé¢æŽ»æ§å€ã¯ãã¢ããª
ã³ç³»ããããªã³ç³»æŽ»æ§å€çã§è¯ãããã¢ããªã³ç³»
掻æ§å€ã奜ãŸããã ãªãäžèšãã€ãã·ã€ãŒåæ£ã¯ãã¢ã°ãã¢ãŒåæ£
ãšåŒã°ããããšããããè±åœç¹èš±ç¬¬45555å·ãå
第465823å·ãå第29897å·çã«èšèŒãããŠããæ
è¡å 容ãåèã«ããããšãã§ããã æ¬çºæã«çšããããè²çŽ äŸäžç©è³ªã¯ãç±çŸåæ
å å±€ã«åŸè¿°ã®èŠªæ°Žæ§ãã€ã³ããŒãçšããŠããã®èŠª
æ°Žæ§ãã€ã³ããŒäžã«äžè¿°ã®ããã«ãã€ãã·ã€ãŒå
æ£åã¯ãªã€ã«ãããã¯ãåæ£ãããããã®ã§ã
ããåŸã€ãŠåŸæ¥ã®ããã«ããŒã«ãã«ãŸãã¯ãµã³ã
ãã«çã䜿çšããŠç£šç ããå¿ èŠããªãã®ã§çæé
ã®äœæ¥ã§åŸ®çŽ°ãã€å®å®ã«ç±çŸåæå å±€äžã«åæ£ã
ãããããšãã§ãããã€è²çŽ ç»åã®è»¢åæ¿åºŠãæ¹
è¯ããããšãã§ããã ãŸããæ¬çºæã§ã¯åŸè¿°ã®ããã«ç±çŸåæå å±€ã®
ãã€ã³ããŒãšããŠã芪氎æ§ãã€ã³ããŒã䜿çšãã
ã®ã§è©²ç±çŸåæå å±€ãæ¯æäœäžã«å¡åžããå Žåã«
ã¯éææ©æº¶åªããªãã¡æ°Žç³»ã«ãŠå¡åžããããšãã§
ãããŸãç¹ã«ãã€ã³ããŒãšããŠãŒã©ãã³ãçšãã
å Žåã«ã¯ãã®ã»ããæ§ãå©çšã§ããã®ã§ç¡å ¬å®³
ã§ããããå¿ ãããæ°Žå¹³å¡åžãå¿ èŠãšããªãã®ã§
æå ææ補é äžã®äœæ¥å·¥çšãç°¡æåãããã æ¬çºæã®ç±çŸåæå å±€ã«ã¯åèšã®è²çŽ äŸäžç©è³ª
ãšåæ§ã«æå æ§ããã²ã³åéãå«æããã æ¬çºæã«çšããããæå æ§ããã²ã³åéãšããŠ
ã¯ãå¡©åéãèåéãæ²åéãå¡©èåéãå¡©æ²å
éãæ²èåéãå¡©æ²èåéãŸãã¯ãããã®æ··åç©
çããããããã該æå æ§ããã²ã³åéã¯ãåç
æè¡åéã§å ¬ç¥ã®ã·ã³ã°ã«ãžãšããæ³ãããã«ãž
ãšããæ³çã®ä»»æã®æ¹æ³ã§èª¿è£œããããšãã§ãã
ããæ¬çºæã«æŒããŠã¯éåžžã®ããã²ã³åéãŒã©ã
ã³ä¹³å€ã®èª¿è£œæ¹æ³ã«åŸã€ãŠèª¿è£œããæå æ§ããã²
ã³åéä¹³å€ã奜ãŸããçµæãäžããã 該æå æ§ããã²ã³åéä¹³å€ã¯ãåçæè¡åéã§
å ¬ç¥ã®ä»»æã®æ¹æ³ã§ååŠçã«å¢æããŠãè¯ããã
ããå¢ææ³ãšããŠã¯ãéå¢æãã€ãªãŠå¢æãéâ
ã€ãªãŠå¢æãéå å¢æçåçš®ã®æ¹æ³ããããã
ãã äžèšæå æ§ä¹³å€äžã®ããã²ã³åéã¯ãç²ç²åã§
ãã€ãŠã埮ç²åã§ãã€ãŠãè¯ããã奜ãŸããç²å
ãµã€ãºã¯ããã®åŸãçŽ1.5ÎŒïœãçŽ0.001ÎŒïœã§ã
ããããã«å¥œãŸããã¯çŽ0.5ÎŒïœãçŽ0.01ÎŒïœã§ã
ãã äžèšã®ããã«èª¿è£œãããæå æ§ããã²ã³åéä¹³
å€ãæ¬çºæã®æå ææã®æ§æå±€ã§ããç±çŸåæ§æ
å å±€ã«æã奜ãŸããé©çšããããšãã§ããã æ¬çºæã«ãããŠãä»ã®æå æ§ããã²ã³åéã®èª¿
補æ³ãšããŠãæå æ§é塩圢ææåãææ©éå¡©ãšå ±
åãããææ©éå¡©ã®äžéšã«æå æ§ããã²ã³åéã
圢æãããããšãã§ããããã®èª¿è£œæ³ã«çšããã
ãæå æ§é塩圢ææåãšããŠã¯ãç¡æ©ããã²ã³å
ç©ãäŸãã°ãMXnã§è¡šããããããã²ã³åç©
ïŒããã§ãïŒã¯ïŒšååãNH4åºãŸãã¯éå±ååã
è¡šãããã¯ClãBrãŸãã¯ïŒ©ãïœã¯ïŒãååã
NH4åºã®æã¯ïŒ©ãïŒãéå±ååã®æã¯ããã®å
å䟡ã瀺ããéå±ååãšããŠã¯ããªããŠã ããã
ãªãŠã ãã«ãªãŠã ãã«ããžãŠã ãã»ã·ãŠã ãé ã
éãããªãªãŠã ããã°ãã·ãŠã ãã«ã«ã·ãŠã ãã¹
ããã³ããŠã ãããªãŠã ãäºéãã«ãããŠã ãæ°Ž
éãã¢ã«ãããŠã ãã€ã³ãžãŠã ãã©ã³ã¿ã³ãã«ã
ããŠã ãã¿ãªãŠã ãã²ã«ãããŠã ãé«ãéãã¢ã³
ãã¢ã³ããã¹ãã¹ãã¯ãã ãã¢ãªããã³ãã¿ã³ã°
ã¹ãã³ããã³ã¬ã³ãã¬ããŠã ãéãã³ãã«ããã
ãã±ã«ãããžãŠã ããã©ãžãŠã ããªã¹ããŠã ãã€
ãªãžãŠã ãçœéãã»ãªãŠã çãããããããïŒãå«
ããã²ã³éå±é¯äœïŒäŸãã°K2PtCl6ãK2PtBr6ã
HAuCl4ãïŒNH4ïŒ2IrCl6ãïŒNH4ïŒ3IrCl6ã
ïŒNH4ïŒ2RuCl6ãïŒNH4ïŒ3RuCl6ãïŒNH4ïŒ3RhCl6ã
ïŒNH4ïŒ3RhBr6çïŒããªããŠã ãã©ã€ãïŒäŸãã°ã
ãã©ã¡ãã«ã¢ã³ã¢ããŠã ãããã€ããããªã¡ãã«
ããšãã«ã¢ã³ã¢ããŠã ãããã€ããã»ãã«ãšãã«
ãžã¡ãã«ã¢ã³ã¢ããŠã ãããã€ããïŒâã¡ãã«ã
ã¢ãŸãªãŠã ãããã€ããããªã¡ãã«ãã³ãžã«ã¢ã³
ã¢ããŠã ãããã€ãã®ãããªïŒçŽã¢ã³ã¢ããŠã ã
ã©ã€ããããã©ãšãã«ããªã¹ããªããŠã ãããã€
ãã®ãããªïŒçŽããªã¹ããªããŠã ãã©ã€ãããã³
ãžã«ãšãã«ã¡ãã«ãããã€ããïŒâãšãã«ãã¢ãŸ
ãªãŠã ãããã€ãã®ãããªïŒçŽã¹ã«ãããŠã ãã©
ã€ãçïŒãããã²ã³åçåæ°ŽçŽ ïŒäŸãã°ãšãŒãã
ã«ã ãããã¢ãã«ã åèåççŽ ãïŒâããã âïŒ
âã¡ãã«ãããã³çïŒãâããã²ã³ååç©ïŒïŒ®
âã¯ããã³ãã¯é žã€ãããâããã ã³ãã¯é žã€
ãããâããã ãã¿ã«é žã€ãããâããã ã¢
ã»ãã¢ãããâãšãŒãã³ãã¯é žã€ãããâã
ãã ãã¿ã©ãžãã³ãâã¯ãããã¿ã©ãžãã³ã
âããã¢ã¢ã»ãã¢ããªããïŒïŒ®âãžããã¢ãã³
ãŒã³ã¹ã«ãã³ã¢ãããâããã¢ââã¡ãã«ã
ã³ãŒã³ã¹ã«ãã³ã¢ãããïŒïŒïŒâãžããã¢âïŒïŒ
ïŒâãžã¡ãã«ããã³ãã€ã³çïŒããã®ä»ã®å«ãã
ã²ã³ååç©ïŒäŸãã°å¡©åããªããšãã«ã¡ãã«ãè
åããªããšãã«ã¡ãã«ãïŒâããã é ªé žãïŒâã
ãã ãšã¿ããŒã«çïŒãªã©ããããããšãã§ããã ãããæå æ§ããã²ã³åéããã³æå æ§é塩圢
ææåã¯ãçš®ã ã®æ¹æ³ã«ãããŠçµåããŠäœ¿çšã§
ãã䜿çšéã¯ææ©éå¡©ïŒã¢ã«ã«å¯ŸããŠ0.001ã¢ã«
ã2.0ã¢ã«ã§ããã奜ãŸããã¯0.01ã¢ã«ã0.5ã¢ã«
ã§ããã ãŸããæ¬çºæã®ç±çŸåã«ã©ãŒæå ææã¯éè²
å ãç·è²å ãèµ€è²å ã«æå æ§ãæããåå±€ãããª
ãã¡ç±çŸåéæå å±€ãç±çŸåç·æå å±€ãç±çŸåèµ€
æå å±€ãšããŠå€å±€æ§æãšããããšãã§ããããã
ã®åã çšããããéææ§ããã²ã³åéä¹³å€ãç·æ
æ§ããã²ã³åéä¹³å€ãèµ€ææ§ããã²ã³åéä¹³å€
ã¯ãåèšããã²ã³åéä¹³å€ã«åçš®ã®åå å¢æè²çŽ
ãå ããããšã«ãã€ãŠåŸãããšãã§ããã æ¬çºæã«çšãããã代衚çãªåå å¢æè²çŽ ãšã
ãŠã¯ãäŸãã°ã·ã¢ãã³ãã¡ãã·ã¢ãã³ãã³ã³ãã¬
ãã¯ã¹ïŒïŒæ žåã¯ïŒæ žã®ïŒã·ã¢ãã³ãããããŒã©
âã·ã¢ãã³ãã¹ããªã«ãããã·ã¢ãã³ããªããœã
ãŒã«çãããããããã·ã¢ãã³é¡ã®è²çŽ ã®ãã¡ã§
ãã¢ãŸãªã³ããªããµãŸãªã³ããããªã³ãããªãžã³
ãªããµãŸãŒã«ããã¢ãŸãŒã«ãã»ã¬ããŸãŒã«ãã€ã
ããŸãŒã«ã®æ§ãªå¡©åºæ§æ žãæãããã®ãããã奜
ãŸããããã®æ§ãªæ žã«ã¯ã¢ã«ãã«åºãã¢ã«ãã¬ã³
åºãããããã·ã¢ã«ãã«åºãã¹ã«ãã¢ã«ãã«åºã
ã«ã«ããã·ã¢ã«ãã«åºãã¢ããã¢ã«ãã«åºãŸãã¯
çž®åççŽ ç°åŒãŸãã¯è€çŽ ç°è²ç°ãäœãäºã®åºæ¥ã
ãšããã³åºãæããŠããŠãããããŸã察称圢ã§ã
é察称圢ã§ãããããŸãã¡ãã³éãããªã¡ãã³é
ã«ã¢ã«ãã«åºãããšãã«åºããšããã³åºãããã
ç°çœ®æåºãæããŠããŠãããã ã¡ãã·ã¢ãã³è²çŽ ã¯äžèšå¡©åºæ§æ žã®ä»ã«äŸãã°
ããªããã³ãã€ã³æ žãããŒããã³æ žããªããµãŸãª
ãžã³ãžãªã³æ žããã¢ãŸãªãžã³ãžãªã³æ žããã«ãã
ãŒã«é žæ žããã¢ãŸãªã³ããªã³æ žãããããããªã«
æ žããã©ãŸãã³æ žã®æ§ãªé žæ§æ žãæããŠããŠãã
ãããããã®é žæ§æ žã¯æŽã«ã¢ã«ãã«åºãã¢ã«ãã¬
ã³åºãããšãã«åºãã«ã«ããã·ã¢ã«ãã«åºãã¹ã«
ãã¢ã«ãã«åºãããããã·ã¢ã«ãã«åºãã¢ã«ã³ã
ã·ã¢ã«ãã«åºãã¢ã«ãã«ã¢ãã³åºåã¯ãããç°åŒ
æ žã§çœ®æãããŠããŠããããåå¿ èŠãªãã°ããã
ã®è²çŽ ãçµåãããŠäœ¿çšããŠããããæŽã«ã¢ã¹ã³
ã«ãã³é žèªå°äœãã¢ã¶ã€ã³ãã³ã«ãããŠã å¡©ãæ
æ©ã¹ã«ãã³é žçäŸãã°ç±³åœç¹èš±ç¬¬2933390å·ãå
第2937089å·ã®æ现æžçã«èšèŒãããŠããæ§ãªå¯
èŠå ãåžåããªãè¶ å¢ææ§æ·»å å€ã䜵çšããããš
ãã§ããã ãããè²çŽ ã®æ·»å éã¯ããã²ã³åéãŸãã¯ãã
ã²ã³åé圢ææåïŒã¢ã«åœãïŒÃ10-4ã¢ã«ãïŒã¢
ã«ã§ãããæŽã«å¥œãŸããã¯ãïŒÃ10-4ã¢ã«ãïŒÃ
10-1ã¢ã«ã§ããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã«çšããããæ
æ©éå¡©ãšããŠã¯ãç¹å ¬æ43â4924å·ãå44â
26582å·ãå45â18416å·ãå45â12700å·ãå45
â22185å·ããã³ç¹éæ49â52626å·ãå52â
31728å·ãå52â13731å·ãå52â141222å·ãå53
â36224å·ãå53â37610å·åå ¬å ±ãç±³åœç¹èš±ç¬¬
3330633å·ãå第4168980å·çã®æ现æžã«èšèŒãã
ãŠããèèªæã«ã«ãã³é žã®éå¡©ãäŸãã°ã©ãŠãªã³
é žéãããªã¹ãã³é žéããã«ããã³é žéãã¹ãã¢
ãªã³é žéãã¢ã©ããã³é žéãããã³é žéçããŸã
è³éŠæã«ã«ãã³é žéãäŸãã°å®æ¯éŠé žéããã¿ã«
é žéçããŸãã€ããåºãæããéå¡©ãäŸãã°ãã³
ãŸããªã¢ãŸãŒã«éããµãã«ãªã³éããã¿ã©ãžãã³
éããã¿ã«ã€ããéçãã¡ã«ã«ããåºãŸãã¯ããª
ã³åºãæããååç©ã®éå¡©ãäŸãã°ïŒâã¡ã«ã«ã
ããã³ãŸâãªããµãŸãŒã«éãã¡ã«ã«ãããªããµãž
ã¢ãŸãŒã«éãã¡ã«ã«ãããã³ãŸãã¢ãŸãŒã«éãïŒ
âã¡ã«ã«ãããã³ãŸã€ãããŸãŒã«éãïŒâã¡ã«ã«
ããâããšãã«âïŒïŒïŒïŒïŒâããªã¢ãŸãŒã«éã
ãŸããã®ä»ãšããŠïŒâããããã·âïŒâã¡ãã«â
ïŒïŒïŒïŒ3aïŒïŒâããã©ã¶ã€ã³ãã³éãïŒâã¡
ãã«âïŒâããããã·âïŒïŒïŒïŒïŒïŒïŒïŒïŒâã
ã³ã¿ã¶ã€ã³ãã³éçããããããã ãŸãRD16966ãå16907ãè±åœç¹èš±ç¬¬1590956
å·ãå第1590957å·æ现æžã«èšèŒã®æ§ãªéååç©
ãçšããããšãã§ãããäžã§ãäŸãã°ãã³ãŸããª
ã¢ãŸãŒã«éã®éå¡©ã®æ§ãªã€ããåºãæããéå¡©ã
奜ãŸããããã³ãŸããªã¢ãŸãŒã«ã®éå¡©ãšããŠã¯ã
äŸãã°ã¡ãã«ãã³ãŸããªã¢ãŸãŒã«éã®ãããªã¢ã«
ãã«çœ®æãã³ãŸããªã¢ãŸãŒã«éãäŸãã°ããã â
ãã³ãŸããªã¢ãŸãŒã«éãã¯ãã«ãã³ãŸããªã¢ãŸãŒ
ã«éã®ãããªããã²ã³çœ®æãã³ãŸããªã¢ãŸãŒã«
éãäŸãã°ïŒâã¢ã»ãã¢ãããã³ãŸããªã¢ãŸãŒã«
éã®ãããªã¢ãã眮æãã³ãŸããªã¢ãŸãŒã«éããŸ
ãè±åœç¹èš±ç¬¬1590956å·ãå第1590957å·åæ现æž
ã«èšèŒã®ååç©ãäŸãã°ïŒ®âãïŒâã¯ããâïŒâ
âïŒïŒïŒïŒâãžã¯ããâïŒâããããã·ããšã
ã«ïŒã€ããâïŒâãªããœâïŒâã¡ãã«âïŒïŒïŒâ
ã·ã¯ããããµãžãšã³âïŒâã€ã«ãâïŒâã«ã«ãã¢
ã€ã«ãã³ãŸããªã¢ãŸãŒã«éå¡©ãïŒâãã³ãŸããªã¢
ãŸãŒã«âïŒâã€ã«ã¢ãŸâïŒâã¡ããã·âïŒâãã
ããŒã«éå¡©ãïŒâãã³ãŸããªã¢ãŸãŒã«âïŒâã€ã«
ã¢ãŸâïŒâããããŒã«éå¡©ãâãã³ãŸããªã¢ãŸ
ãŒã«âïŒâã€ã«âïŒâïŒïŒâãžã¡ãã«ã¢ããããš
ãã«ã¢ãŸïŒãã³ãŸã¢ããéå¡©çããããããã ãŸãäžèšäžè¬åŒããã§è¡šããããããããã³
ãŸããªã¢ãŸãŒã«é¡ããã³äžèšäžè¬åŒããã§è¡šã
ããããã³ãŸããªã¢ãŸãŒã«é¡ãæå©ã«äœ¿çšã§ã
ãã äžè¬åŒãã åŒäžãR3ã¯ãããåºãè¡šãããR4ããã³R5ã¯
åäžã§ãç°ãªã€ãŠããŠããããåã ããã²ã³åå
ïŒäŸãã°å¡©çŽ ãèçŽ ãæ²çŽ ïŒãããããã·åºãã¹ã«
ãåºãããã¯ãã®å¡©ïŒäŸãã°ãããªãŠã å¡©ãã«ãª
ãŠã å¡©ãã¢ã³ã¢ããŠã å¡©ïŒãã«ã«ããã·åºããã
ã¯ãã®å¡©ïŒäŸãã°ãããªãŠã å¡©ãã«ãªãŠã å¡©ãã¢
ã³ã¢ããŠã å¡©ïŒããããåºãã·ã¢ãåºããŸãã¯ã
ããã眮æåºãæããŠãããã«ã«ãã¢ã€ã«åºãã¹
ã«ãã¢ã¢ã€ã«åºãã¢ã«ãã«åºïŒäŸãã°ã¡ãã«åºã
ãšãã«åºããããã«åºïŒãã¢ã«ã³ãã·åºïŒäŸãã°
ã¡ããã·åºããšããã·åºïŒãã¢ãªãŒã«åºïŒäŸãã°
ããšãã«åºïŒãããã¯ã¢ããåºãè¡šãããïœã¯ïŒ
ãïŒãïœã¯ïŒãŸãã¯ïŒãè¡šããããŸãåèšã«ã«ã
ã¢ã€ã«åºã®çœ®æåºãšããŠã¯ãäŸãã°ã¡ãã«åºããš
ãã«åºãã¢ã»ãã«åºçããããããšãã§ããã¹ã«
ãã¢ã¢ã€ã«åºã®çœ®æåºãšããŠã¯ãäŸãã°ã¡ãã«
åºããšãã«åºãã¢ã»ãã«åºçããããããšãã§
ããã¢ã«ãã«åºã®çœ®æåºãšããŠã¯ãäŸãã°ã«ã«ã
ãã·åºããšããã·ã«ã«ããã«åºçããã¢ãªãŒã«åº
ã®çœ®æåºãšããŠã¯ãäŸãã°ã¹ã«ãåºããããåºç
ããã¢ã«ã³ãã·åºã®çœ®æåºãšããŠã¯ãäŸãã°ã«ã«
ããã·åºããšããã·ã«ã«ããã«åºããããã³ã¢ã
ãåºã®çœ®æåºãšããŠã¯ãäŸãã°ã¢ã»ãã«åºãã¡ã¿
ã³ã¹ã«ããã«åºãããããã·åºãåã ãããããš
ãã§ããã åèšäžè¬åŒããã§è¡šããããååç©ã¯å°ãªã
ãšãäžã€ã®ãããåºãæãããã³ãŸããªã¢ãŸãŒã«
èªå°äœã®éå¡©ã§ããããã®å ·äœäŸãšããŠã¯ä»¥äžã®
ååç©ããããããšãã§ããã äŸãã°ïŒâããããã³ãŸããªã¢ãŸãŒã«éãïŒâ
ããããã³ãŸããªã¢ãŸãŒã«éãïŒâãããâïŒâ
ã¯ãã«ãã³ãŸããªã¢ãŸãŒã«éãïŒâãããâïŒâ
ã¡ãã«ãã³ãŸããªã¢ãŸãŒã«éãïŒâãããâïŒâ
ã¡ããã·ãã³ãŸããªã¢ãŸãŒã«éãïŒâãããâïŒ
âããšãã«ãã³ãŸããªã¢ãŸãŒã«éãïŒâãããã
ã·âïŒâããããã³ãŸããªã¢ãŸãŒã«éãïŒâãã
ããã·âïŒâããããã³ãŸããªã¢ãŸãŒã«éãïŒâ
ããããã·âïŒïŒïŒâãžããããã³ãŸããªã¢ãŸãŒ
ã«éãïŒâããããã·âïŒâãããâïŒâã¯ãã«
ãã³ãŸããªã¢ãŸãŒã«éãïŒâããããã·âïŒâã
ããâïŒâã¡ãã«ãã³ãŸããªã¢ãŸãŒã«éãïŒâã¹
ã«ãâïŒâããããã³ãŸããªã¢ãŸãŒã«éãïŒâã«
ã«ããã·âïŒâããããã³ãŸããªã¢ãŸãŒã«éãïŒ
âã«ã«ããã·âïŒâããããã³ãŸããªã¢ãŸãŒã«
éãïŒâã«ã«ãã¢ã€ã«âïŒâããããã³ãŸããªã¢
ãŸãŒã«éãïŒâã¹ã«ãã¢ã¢ã€ã«âïŒâããããã³
ãŸããªã¢ãŸãŒã«éãïŒâã«ã«ããã·ã¡ãã«âïŒâ
ããããã³ãŸããªã¢ãŸãŒã«éãïŒâããããã·ã«
ã«ããã«ã¡ããã·âïŒâããããã³ãŸããªã¢ãŸãŒ
ã«éãïŒâãããâïŒâã·ã¢ããã³ãŸããªã¢ãŸãŒ
ã«éãïŒâã¢ããâïŒâããããã³ãŸããªã¢ãŸãŒ
ã«éãïŒâãããâïŒâïŒïœâãããããšãã«ïŒ
ãã³ãŸããªã¢ãŸãŒã«éãïŒïŒïŒâãžãããâïŒâ
ã¡ãã«ãã³ãŸããªã¢ãŸãŒã«éãïŒïŒïŒâãžããã
âïŒâã¯ãã«ãã³ãŸããªã¢ãŸãŒã«éãïŒïŒïŒâãž
ãããâïŒâã¡ããã·ãã³ãŸããªã¢ãŸãŒã«éãªã©
ããããããšãã§ããã äžè¬åŒãã åŒäžãR6ã¯ããããã·åºãã¹ã«ãåºãããã¯
ãã®å¡©ïŒäŸãã°ãããªãŠã å¡©ãã«ãªãŠã å¡©ãã¢ã³
ã¢ããŠã å¡©ïŒãã«ã«ããã·åºãããã¯ãã®å¡©ïŒäŸ
ãã°ããããªãŠã å¡©ãã«ãªãŠã å¡©ãã¢ã³ã¢ããŠã
å¡©ïŒã眮æåºãæããŠãããã«ã«ãã¢ã€ã«åºãã
ã³çœ®æåºãæããŠãããã¹ã«ãã¢ã¢ã€ã«åºãè¡šã
ããR7ã¯ããã²ã³ååïŒäŸãã°å¡©çŽ ãèçŽ ãæ²
çŽ ïŒãããããã·åºãã¹ã«ãåºãããã¯ãã®å¡©
ïŒäŸãã°ãããªãŠã å¡©ãã«ãªãŠã å¡©ãã¢ã³ã¢ããŠ
ã å¡©ïŒãã«ã«ããã·åºãããã¯ãã®å¡©ïŒäŸãã°ã
ããªãŠã å¡©ãã«ãªãŠã å¡©ãã¢ã³ã¢ããŠã å¡©ïŒãã
ããåºãã·ã¢ãåºããŸãã¯ãããã眮æåºãæã
ãŠãããã¢ã«ãã«åºïŒäŸãã°ã¡ãã«åºããšãã«
åºããããã«åºïŒãã¢ãªãŒã«åºïŒäŸãã°ããšãã«
åºïŒãã¢ã«ã³ãã·åºïŒäŸãã°ã¡ããã·åºããšãã
ã·åºïŒãããã¯ã¢ããåºãè¡šãããïœã¯ïŒãŸãã¯
ïŒãïœã¯ïŒãïŒã®æŽæ°ãè¡šããã ãŸããåèšR6ã«ãããã«ã«ãã¢ã€ã«åºã®çœ®æ
åºãšããŠã¯ãäŸãã°ã¡ãã«åºããšãã«åºãã¢ã»ã
ã«åºçããããããšãã§ããã¹ã«ãã¢ã¢ã€ã«åºã®
眮æåºãšããŠã¯ãäŸãã°ã¡ãã«åºããšãã«åºãã¢
ã»ãã«åºçããããããšãã§ãããããã«åèš
R7ã«ãããã¢ã«ãã«åºã®çœ®æåºãšããŠã¯ãäŸã
ã°ã«ã«ããã·åºããšããã·ã«ã«ããã«åºçããã¢
ãªãŒã«åºã®çœ®æåºãšããŠã¯ãäŸãã°ã¹ã«ãåºãã
ããåºçãã¢ã«ã³ãã·åºã®çœ®æåºãšããŠã¯ãäŸã
ã°ã«ã«ããã·åºããšããã·ã«ã«ããã«åºçããã
ãã³ã¢ããåºã®çœ®æåºãšããŠã¯ãäŸãã°ã¢ã»ãã«
åºãã¡ã¿ã³ã¹ã«ããã«åºãããããã·åºçãåã
ãããããšãã§ããã åèšäžè¬åŒããã§è¡šããããææ©éå¡©ã®å ·äœ
äŸãšããŠã¯ä»¥äžã®ååç©ããããããšãã§ããã äŸãã°ïŒâããããã·ãã³ãŸããªã¢ãŸãŒã«éã
ïŒâããããã·ãã³ãŸããªã¢ãŸãŒã«éãïŒâã¹ã«
ããã³ãŸããªã¢ãŸãŒã«éãïŒâã¹ã«ããã³ãŸããª
ã¢ãŸãŒã«éããã³ãŸããªã¢ãŸãŒã«éâïŒâã¹ã«ã
ã³é žãããªãŠã ããã³ãŸããªã¢ãŸãŒã«éâïŒâã¹
ã«ãã³é žãããªãŠã ããã³ãŸããªã¢ãŸãŒã«éâïŒ
âã¹ã«ãã³é žã«ãªãŠã ããã³ãŸããªã¢ãŸãŒã«éâ
ïŒâã¹ã«ãã³é žã«ãªãŠã ããã³ãŸããªã¢ãŸãŒã«é
âïŒâã¹ã«ãã³é žã¢ã³ã¢ããŠã ããã³ãŸããªã¢ãŸ
ãŒã«éâïŒâã¹ã«ãã³é žã¢ã³ã¢ããŠã ãïŒâã«ã«
ããã·ãã³ãŸããªã¢ãŸãŒã«éãïŒâã«ã«ããã·ã
ã³ãŸããªã¢ãŸãŒã«éããã³ãŸããªã¢ãŸãŒã«éâïŒ
âã«ã«ãã³é žãããªãŠã ããã³ãŸããªã¢ãŸãŒã«é
âïŒâã«ã«ãã³é žãããªãŠã ããã³ãŸããªã¢ãŸãŒ
ã«éâïŒâã«ã«ãã³é žã«ãªãŠã ããã³ãŸããªã¢ãŸ
ãŒã«éâïŒâã«ã«ãã³é žã«ãªãŠã ããã³ãŸããªã¢
ãŸãŒã«éâïŒâã«ã«ãã³é žã¢ã³ã¢ããŠã ããã³ãŸ
ããªã¢ãŸãŒã«éâïŒâã«ã«ãã³é žã¢ã³ã¢ããŠã ã
ïŒâã«ã«ãã¢ã€ã«ãã³ãŸããªã¢ãŸãŒã«éãïŒâã¹
ã«ãã¢ã¢ã€ã«ãã³ãŸããªã¢ãŸãŒã«éãïŒâã«ã«ã
ãã·âïŒâããããã·ãã³ãŸããªã¢ãŸãŒã«éãïŒ
âã«ã«ããã·âïŒâã¹ã«ããã³ãŸããªã¢ãŸãŒã«
éãïŒâããããã·âïŒâã¹ã«ããã³ãŸããªã¢ãŸ
ãŒã«éãïŒâããããã·âïŒâã¹ã«ããã³ãŸããª
ã¢ãŸãŒã«éãïŒïŒïŒâãžã«ã«ããã·ãã³ãŸããªã¢
ãŸãŒã«éãïŒïŒïŒâãžããããã·ãã³ãŸããªã¢ãŸ
ãŒã«éãïŒâããããã·âïŒâã¯ãã«ãã³ãŸããª
ã¢ãŸãŒã«éãïŒâããããã·âïŒâã¡ãã«ãã³ãŸ
ããªã¢ãŸãŒã«éãïŒâããããã·âïŒâã¡ããã·
ãã³ãŸããªã¢ãŸãŒã«éãïŒâããããã·âïŒâã
ãããã³ãŸããªã¢ãŸãŒã«éãïŒâããããã·âïŒ
âã·ã¢ããã³ãŸããªã¢ãŸãŒã«éãïŒâããããã·
âïŒâã¢ãããã³ãŸããªã¢ãŸãŒã«éãïŒâããã
ãã·âïŒâã¢ã»ãã¢ãããã³ãŸããªã¢ãŸãŒã«éã
ïŒâããããã·âïŒâãã³ãŒã³ã¹ã«ãã³ã¢ããã
ã³ãŸããªã¢ãŸãŒã«éãïŒâããããã·âïŒâãã
ããã·ã«ã«ããã«ã¡ããã·ãã³ãŸããªã¢ãŸãŒã«
éãïŒâããããã·âïŒâãšããã·ã«ã«ããã«ã¡
ããã·ãã³ãŸããªã¢ãŸãŒã«éãïŒâããããã·â
ïŒâã«ã«ããã·ã¡ãã«ãã³ãŸããªã¢ãŸãŒã«éãïŒ
âããããã·âïŒâãšããã·ã«ã«ããã«ã¡ãã«ã
ã³ãŸããªã¢ãŸãŒã«éãïŒâããããã·âïŒâããš
ãã«ãã³ãŸããªã¢ãŸãŒã«éãïŒâããããã·âïŒ
âïŒïœâãããããšãã«ïŒãã³ãŸããªã¢ãŸãŒã«éã
ïŒâããããã·âïŒâïŒïœâã¹ã«ãããšãã«ïŒã
ã³ãŸããªã¢ãŸãŒã«éãïŒâã¹ã«ãâïŒâã¯ãã«ã
ã³ãŸããªã¢ãŸãŒã«éãïŒâã¹ã«ãâïŒâã¡ãã«ã
ã³ãŸããªã¢ãŸãŒã«éãïŒâã¹ã«ãâïŒâã¡ããã·
ãã³ãŸããªã¢ãŸãŒã«éãïŒâã¹ã«ãâïŒâã·ã¢ã
ãã³ãŸããªã¢ãŸãŒã«éãïŒâã¹ã«ãâïŒâã¢ãã
ãã³ãŸããªã¢ãŸãŒã«éãïŒâã¹ã«ãâïŒâã¢ã»ã
ã¢ãããã³ãŸããªã¢ãŸãŒã«éãïŒâã¹ã«ãâïŒâ
ãã³ãŒã³ã¹ã«ãã³ã¢ãããã³ãŸããªã¢ãŸãŒã«éã
ïŒâã¹ã«ãâïŒâããããã·ã«ã«ããã«ã¡ããã·
ãã³ãŸããªã¢ãŸãŒã«éãïŒâã¹ã«ãâïŒâãšãã
ã·ã«ã«ããã«ã¡ããã·ãã³ãŸããªã¢ãŸãŒã«éãïŒ
âããããã·âïŒâã«ã«ããã·ãã³ãŸããªã¢ãŸãŒ
ã«éãïŒâã¹ã«ãâïŒâã«ã«ããã·ã¡ãã«ãã³ãŸ
ããªã¢ãŸãŒã«éãïŒâã¹ã«ãâïŒâãšããã·ã«ã«
ããã«ã¡ãã«ãã³ãŸããªã¢ãŸãŒã«éãïŒâã¹ã«ã
âïŒâããšãã«ãã³ãŸããªã¢ãŸãŒã«éãïŒâã¹ã«
ãâïŒâïŒïœâãããããšãã«ïŒãã³ãŸããªã¢ãŸ
ãŒã«éãïŒâã¹ã«ãâïŒâïŒïœâã¹ã«ãããšãã«ïŒ
ãã³ãŸããªã¢ãŸãŒã«éãïŒâã¹ã«ãâïŒâã¡ãã
ã·âïŒâã¯ãã«ãã³ãŸããªã¢ãŸãŒã«éãïŒâã¹ã«
ãâïŒâã¯ãã«âïŒâã«ã«ããã·ãã³ãŸããªã¢ãŸ
ãŒã«éãïŒâã«ã«ããã·âïŒâã¯ãã«ãã³ãŸããª
ã¢ãŸãŒã«éãïŒâã«ã«ããã·âïŒâã¡ãã«ãã³ãŸ
ããªã¢ãŸãŒã«éãïŒâã«ã«ããã·âïŒâãããã
ã³ãŸããªã¢ãŸãŒã«éãïŒâã«ã«ããã·âïŒâã¢ã
ããã³ãŸããªã¢ãŸãŒã«éãïŒâã«ã«ããã·âïŒâ
ã¡ããã·ãã³ãŸããªã¢ãŸãŒã«éãïŒâã«ã«ããã·
âïŒâã¢ã»ãã¢ãããã³ãŸããªã¢ãŸãŒã«éãïŒâ
ã«ã«ããã·âïŒâãšããã·ã«ã«ããã«ã¡ããã·ã
ã³ãŸããªã¢ãŸãŒã«éãïŒâã«ã«ããã·âïŒâã«ã«
ããã·ã¡ãã«ãã³ãŸããªã¢ãŸãŒã«éãïŒâã«ã«ã
ãã·âïŒâããšãã«ãã³ãŸããªã¢ãŸãŒã«éãïŒâ
ã«ã«ããã·âïŒâïŒïœâãããããšãã«ïŒãã³ãŸ
ããªã¢ãŸãŒã«éãïŒâã«ã«ããã·âïŒâã¡ãã«â
ïŒâã¹ã«ããã³ãŸããªã¢ãŸãŒã«éãªã©ããããã
ãšãã§ããããããã®ååç©ã¯åç¬ã§çšããŠãã
ïŒçš®é¡ä»¥äžãçµåããŠçšããŠãããã æ¬çºæã«çšããããææ©éå¡©ã®èª¿è£œæ³ã«ã€ããŠ
ã«åŸã«è¿°ã¹ããã該ææ©éå¡©ã¯åé¢ãããã®ãé©
åœãªæ段ã«ãããã€ã³ããŒäžã«åæ£ããŠäœ¿çšã«äŸ
ããŠããããããŸãé©åœãªãã€ã³ããŒäžã§éå¡©ã
調補ããåé¢ããã«ãã®ãŸãŸäœ¿çšã«äŸããŠãã
ãã 該ææ©éå¡©ã®äœ¿çšéã¯ãæ¯æäœïŒïœåœã0.05ïœ
ã10.0ïœã§ããã奜ãŸããã¯0.2ïœã20ïœã§ããã ãŸããæ¬çºæã®ç±çŸåã«ã©ãŒæå ææã«çšãã
ããéå å€ãšããŠã¯ãäŸãã°ç±³åœç¹èš±ç¬¬3531286
å·ãå第3761270å·ãå第3764328å·åæ现æžããŸ
ãRD12146ãRD15108ãRD15127ããã³ç¹éæ
56â27132å·å ¬å ±çã«èšèŒã®ïœâããšãã¬ã³ãžã¢
ãã³ç³»ããã³ïœâã¢ããããšããŒã«ç³»çŸåäž»è¬ã
ããªã¹ããªãã¢ããããšããŒã«ç³»ããã³ã¹ã«ãã³
ã¢ããããšããŒã«ç³»çŸåäž»è¬ããŸãããã©ãŸã³å
çºè²çŸåäž»è¬çã®å ¬ç¥ã®çºè²çŸåäž»è¬åã¯ãã®ã
ãªã«ãŒãµãŒããããããããç¹ã«å¥œãŸããã®ã¯ç¹
éæ56â146133å·å ¬å ±ããã³æ¬åºé¡äººã«ããç¹é¡
æ57â225928å·æ现æžã«èšèŒã®ïœâïŒïŒ®ïŒïŒ®âãž
ã¢ã«ãã«ã¢ããããšãã«ïŒã¹ã«ãã¢ãã³é žçŸåäž»
è¬ã§ããã ãããéå å€ã¯åç¬ãæãã¯ïŒçš®ä»¥äžçµåããŠ
çšããããšãã§ãããéå å€ã®äœ¿çšéã¯ã䜿çšã
ããææ©éå¡©ã®çš®é¡ãæå æ§éå¡©ã®çš®é¡ããã³ã
ã®ä»ã®æ·»å å€ã®çš®é¡ãªã©ã«äŸåããããéåžžã¯æ
æ©éå¡©ïŒã¢ã«ã«å¯ŸããŠ0.05ã¢ã«ã10ã¢ã«ã®ç¯å²ã§
ããã奜ãŸããã¯0.1ã¢ã«ãïŒã¢ã«ã§ããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã«ã¯ãäžèšåæ
å以å€ã«å¿ èŠã«å¿ãå皮添å å€ãæ·»å ããããšã
ã§ãããäŸãã°çŸåä¿é²å€ãšããŠã¯ãç±³åœç¹èš±ç¬¬
3220840å·ãå第3531285å·ãå第4012260å·ãå
第4060420å·ãå第4088496å·ãå第4207392å·å
æ现æžãŸãã¯RD15733ãå15734ãå15776çã«
èšèŒãããã¢ã«ã«ãªæŸåºå€ãç¹å ¬æ45â12700å·
èšèŒã®ææ©é žãç±³åœç¹èš±ç¬¬3667959å·èšèŒã®âCO
âãâSO2âãâSOâåºãæããéæ°Žæ§æ¥µæ§æº¶åª
ååç©ãç±³åœç¹èš±ç¬¬3438776å·èšèŒã®ã¡ã«ãããª
ãŒããŒãç±³åœç¹èš±ç¬¬3666477å·ãç¹éæ51â19525
å·ã«èšèŒã®ããªã¢ã«ãã¬ã³ã°ãªã³ãŒã«é¡çãã
ãããŸãè²èª¿å€ãšããŠã¯ãäŸãã°ç¹éæ46â4928
å·ãå46â6077å·ãå49â5019å·ãå49â5020
å·ãå49â91215å·ãå49â107727å·ãå50â
2524å·ãå50â67132å·ãå50â67641å·ãå50â
114217å·ãå52â33722å·ãå52â99813å·ãå53
â1020å·ãå53â55115å·ãå53â76020å·ãå53
â125014å·ãå54â156523å·ãå54â156524å·ã
å54â156525å·ãå54â156526å·ãå56â4060
å·ãå55â4061å·ãå55â32015å·çã®å ¬å ±ãªã
ã³ã«è¥¿ç¬ç¹èš±ç¬¬2140406å·ãå第2147063å·ãå第
2220618å·ãç±³åœç¹èš±ç¬¬3080254å·ãå第3847612
å·ãå第3782941å·ãå第3994732å·ãå第
4123282å·ãå第4201582å·çã®åæ现æžã«èšèŒã
ããŠããååç©ã§ãããã¿ã©ãžãã³ããã¿ã«ã€ã·
ãããã©ãŸãã³ããããŸãªãã³ãâããããã·
ããã¿ã«ã€ããããã³ããªããµãžã³ãããããªã
ãµãžã³ãžãªã³ãïŒïŒïŒâãžãããâãã¿ã©ãžã³ãž
ãªã³ãïŒïŒïŒâãžãããâïŒïŒïŒâãªããµãžã³â
ïŒïŒïŒâãžãªã³ããªãã·ããªãžã³ãã¢ããããªãž
ã³ãããããã·ãããªã³ãã¢ãããããªã³ãã€ãœ
ã«ã«ãã¹ããªã«ãã¹ã«ãã³ã¢ããã2HâïŒïŒïŒ
âãã³ãŸãã¢ãžã³âïŒïŒïŒâïŒ3HïŒãžãªã³ããã³
ãŸããªã¢ãžã³ãã¡ã«ã«ããããªã¢ãŸãŒã«ããžã¡ã«
ã«ããããã©ã¶ãã³ã¿ã¬ã³ããã¿ã«é žãããã¿ã«
é žããã¿ã«ã¢ãã³é žçãããããããã®ïŒã€ãŸã
ã¯ïŒã€ä»¥äžãšã€ãããŸãŒã«ååç©ãšã®æ··åç©ãŸã
ãã¿ã«é žãããã¿ã«é žçã®é žãŸãã¯é žç¡æ°Žç©ã®å°
ãªããšãïŒã€ããã³ãã¿ã©ãžã³ååç©ã®æ··åç©ã
ããã«ã¯ãã¿ã©ãžã³ãšãã¬ã€ã³é žãã€ã¿ã³ã³é žã
ãããªã³é žãã²ã³ããžã³é žçã®çµåãçãããã
ããšãã§ããããŸãæ¬åºé¡äººã«ããç¹é¡æ57â
73215å·ãå57â76838å·æ现æžã«èšèŒããããïŒ
âã¢ããâïŒâã¡ã«ã«ããâïŒïŒïŒïŒïŒâããªã¢
ãŸãŒã«é¡ãïŒâã¢ã·ã«ã¢ããâïŒâã¡ã«ã«ããâ
ïŒïŒïŒïŒïŒâããªã¢ãŸãŒã«é¡ãæå¹ã§ããã ãŸãããã«ã«ããªé²æ¢å€ãšããŠã¯ãäŸãã°ç¹å ¬
æ47â11113å·ãç¹éæ49â90118å·ãå49â
10724å·ãå49â97613å·ãå50â101019å·ãå49
â130720å·ãå50â123331å·ãå51â47419å·ã
å51â57435å·ãå51â78227å·ãå51â104338
å·ãå53â19825å·ãå53â20923å·ãå51â
50725å·ãå51â3223å·ãå51â42529å·ãå51â
81124å·ãå54â51821å·ãå55â93149å·çã®å ¬
å ±ããªãã³ã«è±åœç¹èš±ç¬¬1455271å·ãç±³åœç¹èš±ç¬¬
3885968å·ãå第3700457å·ãå第4137079å·ãå
第4138265å·ã西ç¬ç¹èš±ç¬¬2617907å·çãšåæ现æž
ã«èšèŒãããŠããååç©ã§ãã第ïŒæ°Žéå¡©ãæã
ã¯é žåå€ïŒäŸãã°ïŒ®âããã²ãã¢ã»ãã¢ããã
âããã²ãã³ãã¯é žã€ãããéå¡©çŽ é žããã³ãã®
å¡©é¡ãç¡æ©éé žåç©ãéç¡«é žå¡©çïŒãæãã¯é žã
ãã³ãã®å¡©ïŒäŸãã°ã¹ã«ãã€ã³é žãã©ãŠãªã³é žãª
ããŠã ãããžã³ããžãã«ãã³é žãããªã¹ã«ãã³é ž
çïŒãæãã¯ã€ãªãŠå«æååç©ïŒäŸãã°ã¡ã«ã«ã
ãååç©æŸåºæ§ååç©ãããªãŠã©ã·ã«ããžã¹ã«ã
ã€ããã€ãªãŠåäœãã¡ã«ã«ããâïŒïŒïŒïŒïŒâã
ãªã¢ãŸãŒã«ããã¢ãŸãªã³ããªã³ãããªã¹ã«ãã€ã
ååç©çïŒããã®ä»ããªããµãŸãªã³ãïŒïŒïŒïŒïŒ
âããªã¢ãŸãŒã«ããã¿ã«ã€ããçã®ååç©ããã
ãããã ãŸãå®å®å€ãšããŠç¹ã«åŠçåŸã®ããªã³ãã¢ãŠã
é²æ¢å€ãåæã«çšããŠããããäŸãã°ç¹éæ48â
45228å·ãå50â119624å·ãå50â120328å·ãå
53â46020å·å ¬å ±çã«èšèŒã®ããã²ã³åçåæ°ŽçŽ
é¡ãå ·äœçã«ã¯ããã©ããã ãã¿ã³ãããªããã
ãšã¿ããŒã«ãïŒâããã¢âïŒâããªã«ã¢ã»ãã¢ã
ããïŒâããã¢âïŒâããªã«ã¹ã«ããã«ã¢ã»ãã¢
ãããïŒâããªããã¢ã¡ãã«ã¹ã«ããã«ãã³ãŸã
ã¢ãŸãŒã«ãïŒïŒïŒâãã¹ïŒããªããã¢ã¡ãã«ïŒâ
ïŒâã¡ãã«ããªã¢ãžã³ãªã©ããããããã ãŸãç¹å ¬æ46â5393å·ãç¹éæ50â54329å·ã
å50â77034å·åå ¬å ±èšèŒã®ããã«å«ã€ãªãŠåå
ç©ãçšããŠåŸåŠçãè¡ãªã€ãŠãããã ããã«ã¯ãç±³åœç¹èš±ç¬¬3301678å·ãå第3506444
å·ãå第3824103å·ãå第3844788å·åæ现æžã«èš
èŒã®ã€ãœããŠãããŠã ç³»ã¹ã¿ãã©ã€ã¶ãŒããªã«ãŒ
ãµãŒããŸãç±³åœç¹èš±ç¬¬3669670å·ãå第4012260
å·ãå第4060420å·æ现æžçã«èšèŒãããã¢ã¯ã
ããŒã¿ãŒã¹ã¿ãã©ã€ã¶ãŒãã¬ã«ãŒãµãŒçãå«æã
ãŠãããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã«ã¯ãããã«äž
èšæå以å€ã«å¿ èŠã«å¿ããŠãåå å¢æææããã¬
ãŒã·ãšã³é²æ¢ææãè¢å å¢çœå€ã硬èå€ã垯é»é²
æ¢å€ãå¯å¡å€ã延å±å€çåçš®ã®æ·»å å€ãå¡åžå©å€
çãæ·»å ãããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã«ã¯ãã€ã³ããŒ
ãšããŠã¯èŠªæ°Žæ§ã®ãã€ã³ããŒãçšããããããç
æ°Žæ§ãã€ã³ããŒãäžéšäœµçšãããŠããããæ¬çºæ
ã«çšãã芪氎æ§ãã€ã³ããŒãšã¯ãæ°Žãããã¯ãæ°Ž
ãšææ©æº¶åªïŒæ°Žãšä»»æã«æ··åã§ãã溶åªïŒã®æ··å
液ã«å¯æº¶ã§ãããã®ããããäŸãã°ãŒã©ãã³ããŒ
ã©ãã³èªå°äœã®åŠãèçœè³ªãã»ã«ããŒã¹èªå°äœã
ããã¹ãã©ã³ã®åŠãããªãµãã«ã©ã€ããã¢ã©ãã¢
ãŽã çã®åŠã倩ç¶ç©è³ªããã³æå¹ãªããªããŒãšã
ãŠãããªããã«ã¢ã»ã¿ãŒã«ïŒå¥œãŸããã¯ã¢ã»ã¿ãŒ
ã«å床ã20ïŒ ä»¥äžãäŸãã°ããªããã«ããã©ãŒ
ã«ïŒãããªã¢ã¯ãªã«ã¢ãããããªããã«ãããªã
ã³ããšãã«ã»ã«ããŒã¹ãããªããã«ã¢ã«ã³ãŒã«
ïŒã±ã³åçã75ïŒ ä»¥äžã®ãã®ã奜ãŸããïŒçã奜
ãŸãããããããã®ã¿ã«éå®ããããã®ã§ã¯ãª
ãããŸãå¿ èŠãªãã°ïŒçš®ä»¥äžæ··å䜿çšããŠãã
ãããã€ã³ããŒã®éã¯åæå å±€ãããææ©éå¡©ïŒ
éšã«å¯ŸããŠééæ¯ã§ïŒïŒ10ã10ã奜ãŸããã¯ïŒïŒ
ïŒãïŒéšã§ããã æ¬çºæã®åèšåæåãå«ãå±€ããã³ãã®ä»ã®å±€
ã¯åºç¯å²ã®åçš®æ¯æäœäžã«å¡åžããããæ¬çºæã«
䜿çšãããæ¯æäœãšããŠã¯ãã»ã«ããŒã¹ãã€ãã¬
ãŒããã€ã«ã ãã»ã«ããŒã¹ãšã¹ãã«ãã€ã«ã ãã
ãªããã«ã¢ã»ã¿ãŒã«ãã€ã«ã ãããªãšãã¬ã³ãã€
ã«ã ãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããã€ã«ã ãã
ãªã«ãŒãããŒããã€ã«ã çã®ãã©ã¹ããã¯ãã€ã«
ã ããã³ã¬ã©ã¹ãçŽãã¢ã«ãããŠã çã®éå±çã
ãããããããŸããã©ã€ã¿çŽãã¬ã·ã³ã³ãŒãã€ã
çŽãèæ°Žæ§çŽãçšããããšãã§ããã æ¬çºæã®æå ææã¯åºæ¬çã«ã¯åäžå±€äžã«(1)æ
å æ§ããã²ã³åéã(2)ææ©éå¡©ã(3)芪氎æ§ãã€ã³
ããŒã(4)æ¬çºæã®è²çŽ äŸäžç©è³ªã(5)éå å€ãå«æ
ãããããããããã¯å¿ ãããåäžã®åçæ§æå±€
äžã«å«æãããå¿ èŠã¯ãªããäŸãã°äžã€ã®æå å±€
ãäºå±€ã«åããæ¬çºæã®è²çŽ äŸäžç©è³ªãåèš(1)ã
(2)ã(3)ããã³(5)ã®æåãå«æããäžã€ã®æå å±€ã«
é£æ¥ããä»ã®æå å±€ã«å«æããããçãçžäºã«å
å¿å¯èœãªç¶æ ã§ããã°ïŒä»¥äžã®åçæ§æå±€ã«åã
ãŠå«æããããŠãããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã¯æè²æ§ãç°ã«
ããïŒä»¥äžã®æå å±€ãæããŠããŠãããããäžå¡
ãå±€ãäžå¡ãå±€ããããã³ã°å±€ãäžéå±€ãæãã¯
ãã€ã«ã¿ãŒå±€çåçš®ã®åçæ§æå±€ãæããŠããŠã
ããã 該ç±çŸåã«ã©ãŒæå ææã¯ç»åæ§é²å ããã³ç±
åŠçã«ãã€ãŠè²çŽ ç»åã圢æããããšãã§ãã
ããè²çŽ ç»åã®ããã®ç»åååå±€ãžãäŸãã°ã¡ã¿
ããŒã«ã®æ§ãªæº¶å€ããŸãã¯äŸãã°ã¡ãã«ã¢ã³ã»ãŒ
ãã®æ§ãªç±ã§æº¶èããç±æº¶å€ãçšããŠç±è»¢åããŠ
ããããšãã§ããããŸãè±åœç¹èš±ç¬¬1590957å·æ
现æžã«èšèŒã®æ§ãªç±è»¢åæ¹åŒãçšããããšãå¯èœ
ã§ããã æ¬çºæã®æå ææïŒä»¥äžãæ¬çºæã®æå èŠçŽ ãš
ãããïŒã¯ãåæ§é²å ããåŸãç±çŸåããããšã«
ãã€ãŠãç±è»¢åæ§è²çŽ ã®åæ§ååžã該è²çŽ äŸäžç©
質ãã圢æããã該åæ§ååžã®å°ãªããšãäžéš
ããæ¬çºæã®æå èŠçŽ ãšç©éé¢ä¿ã«ããååå±€ã«
ç±è»¢åããã«ã©ãŒç±æ¡æ£è»¢åæ¹æ³ã«é©çšãããå Ž
åãååå±€ã«åœ¢æãããç»åæ¿åºŠãæ¹è¯ãããé«
ãæ¿åºŠã®ç»åãäžããã ååå±€ã¯ãç±çŸåã«ããæŸåºä¹è³åœ¢æãããè²
çŽ ãå容ããæ©èœãæããã°ãããè²çŽ æ¡æ£è»¢å
åæå ææã«çšããããåªæå€ãç¹éæ57â
207250å·çã«èšèŒãããã¬ã©ã¹è»¢ç§»æž©åºŠã40â以
äž250â以äžã®èç±æ§ææ©é«ååç©è³ªã§åœ¢æãã
ãããšã奜ãŸããã åèšåªæå€ã®å ·äœçãªäŸãšããŠã¯ãå«çªçŽ äº
çŽãäžçŽã¢ãã³é¡ãå«çªçŽ è€çŽ ç°ååç©ãããã
ã®åçŽã«ããªã³æ§ååç©ãç±³åœç¹èš±ç¬¬2548564å·ã
å2484430å·ãå3148061å·ãå3756814å·ã«é瀺
ãããŠããããã«ããªãžã³ããªããŒããã³ããã«
ããªãžããŠã ã«ããªã³ããªããŒãç±³åœç¹èš±ç¬¬
2675316å·ã«é瀺ãããŠãããžã¢ã«ãã«ã¢ããåº
ãå«ãããªããŒãç±³åœç¹èš±ç¬¬2882156å·ã«é瀺ã
ããŠããã¢ããã°ã¢ããžã³èªå°äœãç±³åœç¹èš±ç¬¬
3625694å·ãå3859096å·ãè±åœç¹èš±ç¬¬1277453å·ã
å2011012å·ã«é瀺ãããŠãããŒã©ãã³ãªã©ãšæ¶
æ©å¯èœãªåªæå€ãç±³åœç¹èš±ç¬¬3958995å·ãå
2721852å·ãå2798063å·ã«é瀺ãããŠããæ°Žæ§ãŸ
ã«ååªæå€ãç¹éæ50â61228å·ã«é瀺ãããŠã
ãæ°Žäžæº¶æ§åªæå€ãç±³åœç¹èš±ç¬¬3788855å·ã西ç¬
ç¹èš±åºé¡ïŒOLSïŒç¬¬2843320å·ãç¹éæ53â
30328å·ãå52â155528å·ãå53â125å·ãå53â
1024å·ãå54â74430å·ãå54â124726å·ãå55
â22766å·ãç±³åœç¹èš±ç¬¬3642482å·ãå3488706å·ã
å3557066å·ãå3271147å·ãå3271148å·ãç¹å ¬
æ55â29418å·ãå56â36414å·ãå57â12139å·ã
RD12045ïŒ1974幎ïŒã«é瀺ãããŠããåçš®åªæå€
ããããããšãã§ããã ç¹ã«æçšãªåªæå€ã¯ã¢ã³ã¢ããŠã å¡©ãå«ãããª
ããŒã§ãç±³åœç¹èš±ç¬¬3709690å·ã«èšèŒãããŠããã
äŸãã°ã¢ã³ã¢ããŠã å¡©ãå«ãããªããŒãšããŠã¯ã
ããªã¹ãã¬ã³âã³âïŒïŒ®ïŒïŒ®âããªâïœâãã
ã·ã«ââããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€
ãã§ãã¹ãã¬ã³ãšããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯
ãã©ã€ãã®æ¯çã¯ãïŒïŒïŒãïŒïŒïŒã奜ãŸããã¯
ïŒïŒïŒã§ããã å žåçãªè²çŽ æ¡æ£è»¢åçšã®ååå±€ã¯ã¢ã³ã¢ããŠ
ã å¡©ãå«ãããªããŒããŒã©ãã³ãšæ··åããŠæ¯æäœ
äžã«å¡åžããããšã«ããåŸããããè²çŽ ã®ç±çŸå
æå å±€ããååå±€ãžã®è»¢åã«ã¯ã転å溶åªãçšã
ãããšãã§ããããã®è»¢å溶åªã«ã¯ãã¡ã¿ããŒ
ã«ãé ¢é žãšãã«ããžã€ãœããã«ã±ãã³çã®äœæ²žç¹
溶åªããã³ããªâïœâã¯ã¬ãžã«ããªã¹ããšãŒãã
ããªâïœâããã«ãã¹ããšãŒãããžâïœâããã«
ãã¿ã¬ãŒãçã®é«æ²žç¹æº¶åªãçšããé«æ²žç¹æº¶åªã®
å Žåã«ã¯ãé©åœãªä¹³åå€ãçšããŠãŒã©ãã³äžã«ä¹³
åãååå±€ã«æ·»å ããããšãã§ããã åèšèç±æ§ææ©é«ååç©è³ªã®äŸãšããŠã¯ãåå
é2000ã85000ã®ããªã¹ãã¬ã³ãççŽ æ°ïŒä»¥äžã®
眮æåºããã€ããªã¹ãã¬ã³èªå°äœãããªããã«ã·
ã¯ããããµã³ãããªãžããã«ãã³ãŒã³ãããªãã
ã«ãããªãã³ãããªããã«ã«ã«ããŸã«ãããªã¢ãª
ã«ãã³ãŒã³ãããªããã«ã¢ã«ã³ãŒã«ãããªããã«
ãã«ããŒã«ããã³ããªããã«ããã©ãŒã«ãªã©ã®ã
ãªã¢ã»ã¿ãŒã«é¡ãããªå¡©åããã«ãå¡©çŽ åããªãš
ãã¬ã³ãããªäžå¡©åãµã€åãšãã¬ã³ãããªã¢ã¯ãª
ããããªã«ãããªâïŒïŒ®âãžã¡ãã«ã¢ãªã«ã¢ã
ããïœâã·ã¢ãããšãã«åºããã³ã¿ã¯ããããšã
ã«åºããã³ïŒïŒïŒâãžã¯ããããšãã«åºããã€ã
ãªã¢ã¯ãªã¬ãŒããããªã¢ã¯ãªã«ã¯ããã¢ã¯ãªã¬ãŒ
ããããªã¡ãã«ã¡ã¿ã¯ãªã¬ãŒããããªãšãã«ã¡ã¿
ã¯ãªã¬ãŒããããªãããã«ã¡ã¿ã¯ãªã¬ãŒããããª
ã€ãœãããã«ã¡ã¿ã¯ãªã¬ãŒããããªã€ãœããã«ã¡
ã¿ã¯ãªã¬ãŒããããªâtertâããã«ã¡ã¿ã¯ãªã¬ãŒ
ããããªã·ã¯ãããã·ã«ã¡ã¿ã¯ãªã¬ãŒããããªãš
ãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒããããªâïŒâ
ã·ã¢ãâãšãã«ã¡ã¿ã¯ãªã¬ãŒããããªãšãã¬ã³ã
ã¬ãã¿ã¬ãŒããªã©ã®ããªãšã¹ãã«é¡ãããªã¹ã«ã
ã³ããã¹ããšããŒã«ïŒ¡ããªã«ãŒãããŒãçã®ããª
ã«ãŒãããŒãé¡ãããªã¢ã³ããã©ã€ããããªã¢ã
ãé¡äžŠã³ã«ã»ã«ããŒã¹ã¢ã»ããŒãé¡ãããããã
ãããŸããPolymer Handbook 2nd cd.ïŒJ.
BrandrupãE.H.Immergutç·šïŒJohn Wiley ïŒ
Sonsåºçãã«èšèŒãããŠããã¬ã©ã¹è»¢ç§»æž©åºŠ
40â以äžã®åæããªããŒãæçšã§ããããããã®
é«ååç©è³ªã¯ãåç¬ã§çšããããŠãããŸãè€æ°ä»¥
äžãçµã¿åããŠå ±éåäœãšããŠçšããŠãããã ç¹ã«æçšãªããªããŒãšããŠã¯ãããªã¢ã»ããŒ
ãããžã¢ã»ããŒããªã©ã®ã»ã«ããŒã¹ã¢ã»ããŒãã
ããã¿ã¡ãã¬ã³ãžã¢ãã³ãšã®ãã¬ãã¿ã«é žããã«
ãªã¬ã³ãžãããã«ã¢ãã³ãšã¢ãžãã³é žããããµã¡
ãã¬ã³ãžã¢ãã³ãšãžããšã³é žããããµã¡ãã¬ã³ãž
ã¢ãã³ãšã€ãœãã¿ã«é žãªã©ã®çµã¿åãã«ããããª
ã¢ããããžãšãã¬ã³ã°ãªã³ãŒã«ãšãžããšãã«ã«ã«
ãã³é žããã¹âïœâã«ã«ããã·ããšããã·ãã¿ã³
ãšãšãã¬ã³ã°ãªã³ãŒã«ãªã©ã®çµã¿åãã«ããããª
ãšã¹ãã«ãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããããªã«
ãŒãããŒãããããããããããã®ããªããŒã¯æ¹
質ããããã®ã§ãã€ãŠããããããšãã°ãã·ã¯ã
ãããµã³ãžã¡ã¿ããŒã«ãã€ãœãã¿ã«é žãã¡ããã·
ããªãšãã¬ã³âã°ãªã³ãŒã«ãïŒïŒïŒâãžã«ã«ãã¡
ããã·âïŒâãã³ãŒã³ã¹ã«ãã³é žãªã©ãæ¹è³ªå€ãš
ããŠçšããããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããæå¹ã§
ããã äžèšã®ããªããŒã¯é©åœãªæº¶å€ã«æº¶ãããŠæ¯æäœ
äžã«å¡åžããŠååå±€ãšãããããããã¯äžèšããª
ããŒããæããã€ã«ã ç¶ååå±€ãæ¯æäœã«ã©ãã
ãŒãããŠçšãããããããŸãã¯æ¯æäœäžã«å¡åžã
ãããšãªããäžèšããªããŒããæãéšæïŒäŸãã°
ãã€ã«ã ïŒåç¬ã§ååå±€ãæ§æããããšïŒåå
å±€ã»æ¯æäœå ŒçšåïŒãã§ããã ããã«ååå±€ãšããŠã¯éææ¯æäœäžã®ååå±€ã®
äžã«ãŒã©ãã³åæ£ããäºé žåãã¿ã³çãå«ãäžé
æåå±€ïŒåå°æ§å±€ïŒãèšããŠæ§æããããšãã§ã
ãããã®äžéæåå±€ã¯ã転åè²ç»åãååå±€ã®é
ææ¯æäœåŽããèŠãããšã«ããåå°åã®è²åãåŸ
ãããã ãå®æœäŸã 以äžã«æ¬çºæã®å®æœäŸã瀺ãããæ¬çºæã®å®æœ
æ æ§ã¯ãããã«éããããã®ã§ã¯ãªãã ïŒïŒâã¹ã«ããã³ãŸããªã¢ãŸãŒã«éå¡©ã®èª¿è£œïŒ 20ïœã®ïŒâã¹ã«ããã³ãŸããªã¢ãŸãŒã«åã³ïŒïœ
ã®æ°Žé žåãããªãŠã ããšã¿ããŒã«âæ°ŽïŒïŒïŒïŒïŒ
æ··å液300mlã«å ã溶解ããããã®æº¶æ¶²ã«ïŒèŠå®
ã®ç¡é žé溶液20mlã滎äžããããã®éïŒèŠå®ã®æ°Ž
é žåãããªãŠã 溶液ãåæã«æ»ŽäžãPHãïŒãïŒã«
ç¶æããããã®æº¶æ¶²ãïŒæé宀枩ã§æ¹æããåŸã
æ°Žã§400mlã«ä»äžããŠïŒâã¹ã«ããã³ãŸããªã¢ãŸ
ãŒã«é溶液ã調補ããã å®æœäŸ ïŒ äŸç€ºè²çŽ äŸäžç©è³ª(1)4.1ïœãšïŒïŒ ã®ãžïŒïŒâãš
ãã«ããã·ã«ïŒâïŒâã¹ã«ãã³ãã¯é žæ°Žæº¶æ¶²1.6
mlãæ°Ž2.8mlãã¡ã¿ããŒã«ïŒmlãæ··åããããã«
ïŒmlã®ïŒèŠå®æ°Žé žåãããªãŠã 溶液ãå ããåŸã
ïŒïŒ ã®ãŒã©ãã³æ°Žæº¶æ¶²17.5mlãå ããããã®åæ£
液ãïŒïŒ ã®ã¯ãšã³é žã§äžåããåŸãæ°Žã§30mlã«ä»
äžããã äžèšã®ïŒâã¹ã«ããã³ãŸããªã¢ãŸãŒã«é溶液ïŒ
mlãè²çŽ äŸäžç©è³ªã®åæ£æ¶²ïŒmlãæ··åããããã«
ããªããã«ãããªãã³ïŒååé30000ïŒ730mgãã
ã³ã¿ãšãªã¹ãªããŒã«520mgãããªãšãã¬ã³ã°ãªã³
ãŒã«ïŒååé400ïŒ310mgãæ°ŽïŒmlåã³äžèšçŸåå€
200mgãå ããåŸãïŒïŒ ã¯ãšã³é žã§PHã5.5ãšã
ãããã®åæ£æ¶²ã«å¹³åç²åŸ0.05ÎŒmã®æ²èåéã
éã«æç®ããŠïŒÃ10-4ã¢ã«æ·»å ããããªãšãã¬ã³
ãã¬ãã¿ã¬ãŒãæ¯æäœäžã«æ¹¿æœ€èåã65ÎŒmãšãª
ãæ§ã«ã¯ã€ã€ãŒããŒã«ãŠå¡åžããã äžèšå¡åžç©ã也ç¥ããŠåŸãããè©Šæã«å¯ŸããŠã¹
ããããŠãšããžãéããŠã30000CMSïŒã«ã³ã
ã©ã»ã¡ãŒã¿ãŒã»ç§ïŒã®é²å ãäžããã 次ãã§äžèšé²å æžã¿è©Šæã®å¡åžé¢ã«ããã©ã€ã¿
çŽäžã«å¡©åããã«ãå¡åžããååçŽãéããŠãè¡š
é¢æž©åºŠã160âã®éå±è£œããŒããããã¯ã§60ç§é
å§çå ç±ãã次ãã§ååçŽãå¥ããååçŽã«è»¢å
ããè²çŽ åæ¿åºŠïŒééæ¿åºŠïŒã枬å®ããããã®çµ
æãåŸèšç¬¬ïŒè¡šã«ç€ºãã å®æœäŸ ïŒ ããªããã«ãããªãã³ãããªããã«ã¢ã«ã³ãŒã«
ïŒéå床400ïŒã«ä»£ãã以å€ã¯å®æœäŸïŒãšåãåŠæ³
ã§äœæããè©Šæãçšæããå®æœäŸïŒãšåãé²å ã
çŸåãè¡ãªã€ãããã®çµæãåãã第ïŒè¡šã«ç€º
ãã å®æœäŸ ïŒ ç±æº¶å€ã®ããªãšãã¬ã³ã°ãªã³ãŒã«ããžã¡ãã«ãŠ
ã¬ã¢ïŒ310mgïŒã«ä»£ãã以å€ã¯å®æœäŸïŒãšåãåŠ
æ³ã§äœæããè©Šæãçšæããå®æœäŸïŒãšåãé²
å ãçŸåãè¡ãªã€ãããã®çµæãåãã第ïŒè¡šã«
瀺ãã å®æœäŸ ïŒ è²çŽ äŸäžç©è³ªãšããŠäŸç€ºè²çŽ äŸäžç©è³ª(1)ã®ä»£ã
ãã«äŸç€ºè²çŽ äŸäžç©è³ª(3)ãçšãã以å€ã¯å®æœäŸïŒ
ãšåãåŠæ³ã§äœæããè©Šæãçšæããå®æœäŸïŒãš
åãé²å ãçŸåãè¡ãªã€ãããã®çµæãåãã第
ïŒè¡šã«ç€ºãã å®æœäŸ ïŒ è²çŽ äŸäžç©è³ªãšããŠäŸç€ºè²çŽ äŸäžç©è³ª(1)ã®ä»£ã
ãã«äŸç€ºè²çŽ äŸäžè³ªïŒ13ïŒãçšãã以å€ã¯å®æœäŸ
ïŒãšåãåŠæ³ã§äœæããè©Šæãçšæããå®æœäŸïŒ
ãšåãé²å ãçŸåãè¡ãªã€ãããã®çµæãåãã
第ïŒè¡šã«ç€ºãã å®æœäŸ ïŒ å®æœäŸïŒã®è©Šæãå®æœäŸïŒãšåãé²å ãäžãã
åŸãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããããªãååå±€
ãéãåãããŠè¡šé¢æž©åºŠã160âã®éå±ããŒãã
ããã¯ã§60ç§éå§çå ç±ãã次ãã§ååå±€ãå¥ã
ãã転åããæ¿åºŠãééæ¿åºŠã§æž¬å®ããããã®çµ
æãåãã第ïŒè¡šã«ç€ºãã æ¯èŒäŸ ïŒããã³ïŒ è²çŽ äŸäžç©è³ªãšããŠäžèšè²çŽ äŸäžç©è³ª(A)ããã³
(B)ãçšãã以å€ã¯å®æœäŸïŒãšåãåŠæ³ã§äœæãã
ïŒçš®ã®è©Šæãçšæããå®æœäŸïŒãšåãé²å ãçŸå
ãè¡ãªã€ãããã®çµæãåãã第ïŒè¡šã«ç€ºãã
ãè¡šã
ãè¡šã
äžèšç¬¬ïŒè¡šã®çµæãããæãããªããã«ãæ¬çº
æã®ããŒã³ã¿è²çŽ äŸäžç©è³ªãçšããæå èŠçŽ ã¯ã
æ倧æ¿åºŠïŒDmaxïŒã倧ããããããã«ããª
ïŒDminïŒãå°ãããšããåªããå¹æãçºæ®ãã
ããšããããã
æã®ããŒã³ã¿è²çŽ äŸäžç©è³ªãçšããæå èŠçŽ ã¯ã
æ倧æ¿åºŠïŒDmaxïŒã倧ããããããã«ããª
ïŒDminïŒãå°ãããšããåªããå¹æãçºæ®ãã
ããšããããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ æ¯æäœäžã«ãå°ãªããšãæå æ§ããã²ã³å
éãææ©éå¡©ãéå å€ãç±çŸåã«ããè²çŽ ã圢æ
ãåŸãè²çŽ äŸäžç©è³ªããã³èŠªæ°Žæ§ãã€ã³ããŒãå«
æããå°ãªããšãïŒå±€ã®åçæ§æå±€ãæããç±çŸ
åã«ã©ãŒæå ææã«ãããŠã該è²çŽ äŸäžç©è³ªãäž
èšäžè¬åŒããåã¯ããã§è¡šããããããŒã³ã¿
è²çŽ äŸäžç©è³ªã§ããããšãç¹åŸŽãšããç±çŸåã«ã©
ãŒæå ææã ãåŒäžR1ã¯ã¢ã«ãã«åºãã¢ãªãŒã«åºãã¢ã«ãã«
ã¢ããåºãã¢ãªãŒã«ã¢ããåºãã¢ã·ã«ã¢ããåºã
ãŠã¬ã€ãåºåã¯ã·ã¢ãåºãè¡šãããR2ã¯ããã²
ã³ååãæ°ŽçŽ ååãã¢ã«ãã«åºåã¯ã¢ã«ã³ãã·åº
ãè¡šãããã¯èŠªæ°Žæ§åºãè¡šãããã¯ïŒå以äž
ã®èŠªæ°Žæ§åºã§çœ®æãããåºãè¡šãããã¯ïŒäŸ¡ã®
çµååºãè¡šãããïœã¯ïŒãïŒã®æŽæ°ãè¡šãããïœ
ã¯ïŒåã¯ïŒãè¡šãããïœã¯ïŒåã¯ïŒãè¡šãããïœ
åã³ïœã¯ïŒãïŒåã¯ïŒãè¡šããïŒãã ãïœãïœã¯
å ±ã«ïŒã§ã¯ãªãïŒãïœã¯ïŒïŒïœïŒïŒã®æïŒåã¯ïŒ
ïŒïœïŒïŒã®æïŒãè¡šãããã
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6949984A JPS60212762A (ja) | 1984-04-06 | 1984-04-06 | ç±çŸåã«ã©âæå ææ |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6949984A JPS60212762A (ja) | 1984-04-06 | 1984-04-06 | ç±çŸåã«ã©âæå ææ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60212762A JPS60212762A (ja) | 1985-10-25 |
| JPH0346812B2 true JPH0346812B2 (ja) | 1991-07-17 |
Family
ID=13404470
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6949984A Granted JPS60212762A (ja) | 1984-04-06 | 1984-04-06 | ç±çŸåã«ã©âæå ææ |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60212762A (ja) |
-
1984
- 1984-04-06 JP JP6949984A patent/JPS60212762A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS60212762A (ja) | 1985-10-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0136142B1 (en) | Thermally developable, light-sensitive material | |
| US4770981A (en) | Heat-development-type color light-sensitive material | |
| JPH0554667B2 (ja) | ||
| JPS60133449A (ja) | ç±çŸåã«ã©âæå ææ | |
| JPH027052B2 (ja) | ||
| JPH0477892B2 (ja) | ||
| JPH0346812B2 (ja) | ||
| JPH0527849B2 (ja) | ||
| JPH0587819B2 (ja) | ||
| JPH0413702B2 (ja) | ||
| JPH0245179B2 (ja) | ||
| JPH0548900B2 (ja) | ||
| JPH023169B2 (ja) | ||
| JPS60123840A (ja) | ç±çŸåã«ã©âæå ææ | |
| JPH0376736B2 (ja) | ||
| JPH0146054B2 (ja) | ||
| JPS60173548A (ja) | ç±çŸåã«ã©âæå ææ | |
| JPS60203942A (ja) | ç±çŸåã«ã©âæå ææ | |
| JPH0533778B2 (ja) | ||
| JPS60115934A (ja) | ç±çŸåã«ã©âæå ææ | |
| JPH0345819B2 (ja) | ||
| JPH0530259B2 (ja) | ||
| JPH029336B2 (ja) | ||
| JPH0554665B2 (ja) | ||
| JPH0511401A (ja) | ç±çŸåã«ã©ãŒæå ææ |