JPH0475491B2 - - Google Patents
Info
- Publication number
- JPH0475491B2 JPH0475491B2 JP7559283A JP7559283A JPH0475491B2 JP H0475491 B2 JPH0475491 B2 JP H0475491B2 JP 7559283 A JP7559283 A JP 7559283A JP 7559283 A JP7559283 A JP 7559283A JP H0475491 B2 JPH0475491 B2 JP H0475491B2
- Authority
- JP
- Japan
- Prior art keywords
- silver halide
- group
- fogging agent
- present
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 silver halide Chemical class 0.000 claims description 89
- 229910052709 silver Inorganic materials 0.000 claims description 65
- 239000004332 silver Substances 0.000 claims description 65
- 239000003795 chemical substances by application Substances 0.000 claims description 60
- 239000000839 emulsion Substances 0.000 claims description 51
- 239000000463 material Substances 0.000 claims description 32
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 239000000084 colloidal system Substances 0.000 claims description 6
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 6
- 229910052717 sulfur Inorganic materials 0.000 claims description 6
- 125000004434 sulfur atom Chemical group 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 4
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 3
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 56
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 33
- 238000011161 development Methods 0.000 description 27
- 238000000034 method Methods 0.000 description 25
- 150000001875 compounds Chemical class 0.000 description 23
- 108010010803 Gelatin Proteins 0.000 description 16
- 239000000975 dye Substances 0.000 description 16
- 229920000159 gelatin Polymers 0.000 description 16
- 239000008273 gelatin Substances 0.000 description 16
- 235000019322 gelatine Nutrition 0.000 description 16
- 235000011852 gelatine desserts Nutrition 0.000 description 16
- OAKJQQAXSVQMHS-UHFFFAOYSA-N hydrazine Substances NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 15
- 239000000243 solution Substances 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 239000000203 mixture Substances 0.000 description 11
- 238000012545 processing Methods 0.000 description 11
- 230000000694 effects Effects 0.000 description 10
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 9
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 9
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 8
- 238000003786 synthesis reaction Methods 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 125000003545 alkoxy group Chemical group 0.000 description 6
- 239000011241 protective layer Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 5
- 238000009792 diffusion process Methods 0.000 description 5
- 125000005843 halogen group Chemical group 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 238000012546 transfer Methods 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 125000004093 cyano group Chemical group *C#N 0.000 description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 4
- 125000001424 substituent group Chemical group 0.000 description 4
- LRUDIIUSNGCQKF-UHFFFAOYSA-N 5-methyl-1H-benzotriazole Chemical compound C1=C(C)C=CC2=NNN=C21 LRUDIIUSNGCQKF-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 239000012190 activator Substances 0.000 description 3
- 229960005070 ascorbic acid Drugs 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 150000002540 isothiocyanates Chemical class 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- 239000004848 polyfunctional curative Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 2
- VOZKAJLKRJDJLL-UHFFFAOYSA-N 2,4-diaminotoluene Chemical compound CC1=CC=C(N)C=C1N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 2
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 2
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 2
- ZVNPWFOVUDMGRP-UHFFFAOYSA-N 4-methylaminophenol sulfate Chemical compound OS(O)(=O)=O.CNC1=CC=C(O)C=C1.CNC1=CC=C(O)C=C1 ZVNPWFOVUDMGRP-UHFFFAOYSA-N 0.000 description 2
- KMVPXBDOWDXXEN-UHFFFAOYSA-N 4-nitrophenylhydrazine Chemical compound NNC1=CC=C([N+]([O-])=O)C=C1 KMVPXBDOWDXXEN-UHFFFAOYSA-N 0.000 description 2
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- LJTFFORYSFGNCT-UHFFFAOYSA-N Thiocarbohydrazide Chemical class NNC(=S)NN LJTFFORYSFGNCT-UHFFFAOYSA-N 0.000 description 2
- XCFIVNQHHFZRNR-UHFFFAOYSA-N [Ag].Cl[IH]Br Chemical compound [Ag].Cl[IH]Br XCFIVNQHHFZRNR-UHFFFAOYSA-N 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- 235000010323 ascorbic acid Nutrition 0.000 description 2
- 239000011668 ascorbic acid Substances 0.000 description 2
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical class C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 229920002301 cellulose acetate Polymers 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 235000019253 formic acid Nutrition 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- 150000002429 hydrazines Chemical class 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000012046 mixed solvent Substances 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- CMCWWLVWPDLCRM-UHFFFAOYSA-N phenidone Chemical compound N1C(=O)CCN1C1=CC=CC=C1 CMCWWLVWPDLCRM-UHFFFAOYSA-N 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920002401 polyacrylamide Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 238000003672 processing method Methods 0.000 description 2
- JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical compound O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 description 2
- 238000012552 review Methods 0.000 description 2
- KIWUVOGUEXMXSV-UHFFFAOYSA-N rhodanine Chemical compound O=C1CSC(=S)N1 KIWUVOGUEXMXSV-UHFFFAOYSA-N 0.000 description 2
- DUIOPKIIICUYRZ-UHFFFAOYSA-N semicarbazide Chemical compound NNC(N)=O DUIOPKIIICUYRZ-UHFFFAOYSA-N 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 2
- 235000010265 sodium sulphite Nutrition 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229940124530 sulfonamide Drugs 0.000 description 2
- 150000003456 sulfonamides Chemical class 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- HMHWNJGOHUYVMD-UHFFFAOYSA-N (4-methylanilino)azanium;chloride Chemical compound Cl.CC1=CC=C(NN)C=C1 HMHWNJGOHUYVMD-UHFFFAOYSA-N 0.000 description 1
- VNPBXWLZWAMGEO-UHFFFAOYSA-N 1,1-diethyl-2-(2-methylphenyl)hydrazine Chemical compound CCN(CC)NC1=CC=CC=C1C VNPBXWLZWAMGEO-UHFFFAOYSA-N 0.000 description 1
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 1
- ULOCHOLAPFZTGB-UHFFFAOYSA-N 1,3-benzothiazol-3-ium;bromide Chemical compound [Br-].C1=CC=C2SC=[NH+]C2=C1 ULOCHOLAPFZTGB-UHFFFAOYSA-N 0.000 description 1
- SLYRGJDSFOCAAI-UHFFFAOYSA-N 1,3-thiazolidin-2-one Chemical compound O=C1NCCS1 SLYRGJDSFOCAAI-UHFFFAOYSA-N 0.000 description 1
- ZRHUHDUEXWHZMA-UHFFFAOYSA-N 1,4-dihydropyrazol-5-one Chemical compound O=C1CC=NN1 ZRHUHDUEXWHZMA-UHFFFAOYSA-N 0.000 description 1
- GGZHVNZHFYCSEV-UHFFFAOYSA-N 1-Phenyl-5-mercaptotetrazole Chemical compound SC1=NN=NN1C1=CC=CC=C1 GGZHVNZHFYCSEV-UHFFFAOYSA-N 0.000 description 1
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- GUOSQNAUYHMCRU-UHFFFAOYSA-N 11-Aminoundecanoic acid Chemical compound NCCCCCCCCCCC(O)=O GUOSQNAUYHMCRU-UHFFFAOYSA-N 0.000 description 1
- JAAIPIWKKXCNOC-UHFFFAOYSA-N 1h-tetrazol-1-ium-5-thiolate Chemical compound SC1=NN=NN1 JAAIPIWKKXCNOC-UHFFFAOYSA-N 0.000 description 1
- CLDZVCMRASJQFO-UHFFFAOYSA-N 2,5-bis(2,4,4-trimethylpentan-2-yl)benzene-1,4-diol Chemical compound CC(C)(C)CC(C)(C)C1=CC(O)=C(C(C)(C)CC(C)(C)C)C=C1O CLDZVCMRASJQFO-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- QTLHLXYADXCVCF-UHFFFAOYSA-N 2-(4-amino-n-ethyl-3-methylanilino)ethanol Chemical compound OCCN(CC)C1=CC=C(N)C(C)=C1 QTLHLXYADXCVCF-UHFFFAOYSA-N 0.000 description 1
- JHKKTXXMAQLGJB-UHFFFAOYSA-N 2-(methylamino)phenol Chemical compound CNC1=CC=CC=C1O JHKKTXXMAQLGJB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- HCMQCNNTMBBVLX-UHFFFAOYSA-N 2-aminobenzenesulfonyl chloride Chemical compound NC1=CC=CC=C1S(Cl)(=O)=O HCMQCNNTMBBVLX-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- UGWULZWUXSCWPX-UHFFFAOYSA-N 2-sulfanylideneimidazolidin-4-one Chemical compound O=C1CNC(=S)N1 UGWULZWUXSCWPX-UHFFFAOYSA-N 0.000 description 1
- RVBUGGBMJDPOST-UHFFFAOYSA-N 2-thiobarbituric acid Chemical compound O=C1CC(=O)NC(=S)N1 RVBUGGBMJDPOST-UHFFFAOYSA-N 0.000 description 1
- KFAGFICBFWGIAW-UHFFFAOYSA-M 3-(2-methyl-1,3-benzothiazol-3-ium-3-yl)propanal;bromide Chemical compound [Br-].C1=CC=C2[N+](CCC=O)=C(C)SC2=C1 KFAGFICBFWGIAW-UHFFFAOYSA-M 0.000 description 1
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 1
- UVBJXPUIEFOBSW-UHFFFAOYSA-M 3-(2-propyl-1,3-benzothiazol-3-ium-3-yl)propanal;bromide Chemical compound [Br-].C1=CC=C2[N+](CCC=O)=C(CCC)SC2=C1 UVBJXPUIEFOBSW-UHFFFAOYSA-M 0.000 description 1
- DBBHXKHGVFHHSB-UHFFFAOYSA-M 3-methyl-4-phenyl-1,2-dihydropyrido[2,1-b][1,3]benzoselenazol-10-ium;bromide Chemical compound [Br-].C1=2[se]C3=CC=CC=C3[N+]=2CCC(C)=C1C1=CC=CC=C1 DBBHXKHGVFHHSB-UHFFFAOYSA-M 0.000 description 1
- VBNUEXVIMODPSF-UHFFFAOYSA-M 3-methyl-4-phenyl-1,2-dihydropyrido[2,1-b][1,3]benzothiazol-10-ium;bromide Chemical compound [Br-].C1=2SC3=CC=CC=C3[N+]=2CCC(C)=C1C1=CC=CC=C1 VBNUEXVIMODPSF-UHFFFAOYSA-M 0.000 description 1
- XRZDIHADHZSFBB-UHFFFAOYSA-N 3-oxo-n,3-diphenylpropanamide Chemical compound C=1C=CC=CC=1NC(=O)CC(=O)C1=CC=CC=C1 XRZDIHADHZSFBB-UHFFFAOYSA-N 0.000 description 1
- SJSJAWHHGDPBOC-UHFFFAOYSA-N 4,4-dimethyl-1-phenylpyrazolidin-3-one Chemical compound N1C(=O)C(C)(C)CN1C1=CC=CC=C1 SJSJAWHHGDPBOC-UHFFFAOYSA-N 0.000 description 1
- DCKXKFYYFIZDGN-UHFFFAOYSA-M 4-(2-benzyl-1,3-benzoselenazol-3-ium-3-yl)butan-2-one;bromide Chemical compound [Br-].[se]1C2=CC=CC=C2[N+](CCC(=O)C)=C1CC1=CC=CC=C1 DCKXKFYYFIZDGN-UHFFFAOYSA-M 0.000 description 1
- DSVIHYOAKPVFEH-UHFFFAOYSA-N 4-(hydroxymethyl)-4-methyl-1-phenylpyrazolidin-3-one Chemical compound N1C(=O)C(C)(CO)CN1C1=CC=CC=C1 DSVIHYOAKPVFEH-UHFFFAOYSA-N 0.000 description 1
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 1
- TXPBPZVDLVXJKZ-UHFFFAOYSA-N 4-hydrazinylaniline Chemical compound NNC1=CC=C(N)C=C1 TXPBPZVDLVXJKZ-UHFFFAOYSA-N 0.000 description 1
- HWAOQCPYJVJUCR-UHFFFAOYSA-M 4-methyl-n-[3-(2-methyl-1,3-benzothiazol-3-ium-3-yl)propylideneamino]aniline;bromide Chemical compound [Br-].CC=1SC2=CC=CC=C2[N+]=1CCC=NNC1=CC=C(C)C=C1 HWAOQCPYJVJUCR-UHFFFAOYSA-M 0.000 description 1
- QNGVNLMMEQUVQK-UHFFFAOYSA-N 4-n,4-n-diethylbenzene-1,4-diamine Chemical compound CCN(CC)C1=CC=C(N)C=C1 QNGVNLMMEQUVQK-UHFFFAOYSA-N 0.000 description 1
- BTJIUGUIPKRLHP-UHFFFAOYSA-N 4-nitrophenol Chemical compound OC1=CC=C([N+]([O-])=O)C=C1 BTJIUGUIPKRLHP-UHFFFAOYSA-N 0.000 description 1
- UJTTUOLQLCQZEA-UHFFFAOYSA-N 9h-fluoren-9-ylmethyl n-(4-hydroxybutyl)carbamate Chemical compound C1=CC=C2C(COC(=O)NCCCCO)C3=CC=CC=C3C2=C1 UJTTUOLQLCQZEA-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 102000009027 Albumins Human genes 0.000 description 1
- 108010088751 Albumins Proteins 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229920002307 Dextran Polymers 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- 239000002211 L-ascorbic acid Substances 0.000 description 1
- 235000000069 L-ascorbic acid Nutrition 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 241000978776 Senegalia senegal Species 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- 239000004280 Sodium formate Substances 0.000 description 1
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 1
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 1
- 241001061127 Thione Species 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 1
- DQDAKTWBGHIMSE-UHFFFAOYSA-M [Br-].CC1=CC=2SC3=C([N+]2CC1)C=CC=C3 Chemical compound [Br-].CC1=CC=2SC3=C([N+]2CC1)C=CC=C3 DQDAKTWBGHIMSE-UHFFFAOYSA-M 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 108091005647 acylated proteins Proteins 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- BIVUUOPIAYRCAP-UHFFFAOYSA-N aminoazanium;chloride Chemical compound Cl.NN BIVUUOPIAYRCAP-UHFFFAOYSA-N 0.000 description 1
- 229960004050 aminobenzoic acid Drugs 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- XNSQZBOCSSMHSZ-UHFFFAOYSA-K azane;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxymethyl)amino]acetate;iron(3+) Chemical compound [NH4+].[Fe+3].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O XNSQZBOCSSMHSZ-UHFFFAOYSA-K 0.000 description 1
- HNYOPLTXPVRDBG-UHFFFAOYSA-N barbituric acid Chemical compound O=C1CC(=O)NC(=O)N1 HNYOPLTXPVRDBG-UHFFFAOYSA-N 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- WZTQWXKHLAJTRC-UHFFFAOYSA-N benzyl 2-amino-6,7-dihydro-4h-[1,3]thiazolo[5,4-c]pyridine-5-carboxylate Chemical compound C1C=2SC(N)=NC=2CCN1C(=O)OCC1=CC=CC=C1 WZTQWXKHLAJTRC-UHFFFAOYSA-N 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 229920005557 bromobutyl Polymers 0.000 description 1
- 125000002837 carbocyclic group Chemical group 0.000 description 1
- 125000004181 carboxyalkyl group Chemical group 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- ZUIVNYGZFPOXFW-UHFFFAOYSA-N chembl1717603 Chemical compound N1=C(C)C=C(O)N2N=CN=C21 ZUIVNYGZFPOXFW-UHFFFAOYSA-N 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 125000000068 chlorophenyl group Chemical group 0.000 description 1
- MOCKWYUCPREFCZ-UHFFFAOYSA-N chondroitin sulfate E (GalNAc4,6diS-GlcA), precursor 5a Chemical compound NNC(=O)NC1=CC=CC=C1 MOCKWYUCPREFCZ-UHFFFAOYSA-N 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000000586 desensitisation Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- RAFNCPHFRHZCPS-UHFFFAOYSA-N di(imidazol-1-yl)methanethione Chemical compound C1=CN=CN1C(=S)N1C=CN=C1 RAFNCPHFRHZCPS-UHFFFAOYSA-N 0.000 description 1
- KYQODXQIAJFKPH-UHFFFAOYSA-N diazanium;2-[2-[bis(carboxymethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [NH4+].[NH4+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O KYQODXQIAJFKPH-UHFFFAOYSA-N 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- MQRJBSHKWOFOGF-UHFFFAOYSA-L disodium;carbonate;hydrate Chemical class O.[Na+].[Na+].[O-]C([O-])=O MQRJBSHKWOFOGF-UHFFFAOYSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- AFOSIXZFDONLBT-UHFFFAOYSA-N divinyl sulfone Chemical compound C=CS(=O)(=O)C=C AFOSIXZFDONLBT-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- WBJINCZRORDGAQ-UHFFFAOYSA-N formic acid ethyl ester Natural products CCOC=O WBJINCZRORDGAQ-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000000717 hydrazino group Chemical group [H]N([*])N([H])[H] 0.000 description 1
- GZDLDWLKRNZZAG-UHFFFAOYSA-N hydrazinylmethanesulfonic acid Chemical class NNCS(O)(=O)=O GZDLDWLKRNZZAG-UHFFFAOYSA-N 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- LOCAIGRSOJUCTB-UHFFFAOYSA-N indazol-3-one Chemical compound C1=CC=C2C(=O)N=NC2=C1 LOCAIGRSOJUCTB-UHFFFAOYSA-N 0.000 description 1
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 description 1
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- NONOKGVFTBWRLD-UHFFFAOYSA-N isocyanatosulfanylimino(oxo)methane Chemical compound O=C=NSN=C=O NONOKGVFTBWRLD-UHFFFAOYSA-N 0.000 description 1
- FZWBNHMXJMCXLU-BLAUPYHCSA-N isomaltotriose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@@H](OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O)O1 FZWBNHMXJMCXLU-BLAUPYHCSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 125000005647 linker group Chemical group 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 150000002731 mercury compounds Chemical class 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- UKVIEHSSVKSQBA-UHFFFAOYSA-N methane;palladium Chemical compound C.[Pd] UKVIEHSSVKSQBA-UHFFFAOYSA-N 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- NQMRYBIKMRVZLB-UHFFFAOYSA-N methylamine hydrochloride Chemical compound [Cl-].[NH3+]C NQMRYBIKMRVZLB-UHFFFAOYSA-N 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- UICBCXONCUFSOI-UHFFFAOYSA-N n'-phenylacetohydrazide Chemical compound CC(=O)NNC1=CC=CC=C1 UICBCXONCUFSOI-UHFFFAOYSA-N 0.000 description 1
- CKLPECFHCLIYKN-UHFFFAOYSA-N n'-phenylbenzohydrazide Chemical compound C=1C=CC=CC=1C(=O)NNC1=CC=CC=C1 CKLPECFHCLIYKN-UHFFFAOYSA-N 0.000 description 1
- UQPFSVMPYHXOFG-UHFFFAOYSA-N n'-phenylmethanesulfonohydrazide Chemical compound CS(=O)(=O)NNC1=CC=CC=C1 UQPFSVMPYHXOFG-UHFFFAOYSA-N 0.000 description 1
- JIJNOXGGMCEUMF-UHFFFAOYSA-N n-(4-aminoanilino)formamide Chemical compound NC1=CC=C(NNC=O)C=C1 JIJNOXGGMCEUMF-UHFFFAOYSA-N 0.000 description 1
- OOZGXMAMKUQKGJ-UHFFFAOYSA-N n-(4-nitroanilino)formamide Chemical compound [O-][N+](=O)C1=CC=C(NNC=O)C=C1 OOZGXMAMKUQKGJ-UHFFFAOYSA-N 0.000 description 1
- FWTFCJFGBSEGFO-UHFFFAOYSA-N n-(methylideneamino)aniline Chemical compound C=NNC1=CC=CC=C1 FWTFCJFGBSEGFO-UHFFFAOYSA-N 0.000 description 1
- TZGSEIYJFWNURA-UHFFFAOYSA-N n-[2-(2-amino-n-ethyl-3-methylanilino)ethyl]methanesulfonamide Chemical compound CS(=O)(=O)NCCN(CC)C1=CC=CC(C)=C1N TZGSEIYJFWNURA-UHFFFAOYSA-N 0.000 description 1
- WLKXTJOYOZTROF-UHFFFAOYSA-M n-[3-(2-methyl-1,3-benzothiazol-3-ium-3-yl)propylideneamino]aniline;bromide Chemical compound [Br-].CC=1SC2=CC=CC=C2[N+]=1CCC=NNC1=CC=CC=C1 WLKXTJOYOZTROF-UHFFFAOYSA-M 0.000 description 1
- PJOHYBFGXHXFGV-UHFFFAOYSA-N n-[4-(2-acetylhydrazinyl)phenyl]acetamide Chemical compound CC(=O)NNC1=CC=C(NC(C)=O)C=C1 PJOHYBFGXHXFGV-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- XBCIOBSQHJYVBQ-UHFFFAOYSA-N naphthalen-1-ylhydrazine Chemical compound C1=CC=C2C(NN)=CC=CC2=C1 XBCIOBSQHJYVBQ-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- COWNFYYYZFRNOY-UHFFFAOYSA-N oxazolidinedione Chemical compound O=C1COC(=O)N1 COWNFYYYZFRNOY-UHFFFAOYSA-N 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- JOVOSQBPPZZESK-UHFFFAOYSA-N phenylhydrazine hydrochloride Chemical compound Cl.NNC1=CC=CC=C1 JOVOSQBPPZZESK-UHFFFAOYSA-N 0.000 description 1
- 229940038531 phenylhydrazine hydrochloride Drugs 0.000 description 1
- MRFDIIXYTDNCAZ-UHFFFAOYSA-N phthalic acid;terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1.OC(=O)C1=CC=CC=C1C(O)=O MRFDIIXYTDNCAZ-UHFFFAOYSA-N 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002717 polyvinylpyridine Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 1
- 235000019252 potassium sulphite Nutrition 0.000 description 1
- UVWWZGPJRBROMK-UHFFFAOYSA-M potassium;2,5-dihydroxy-4-octadecan-2-ylbenzenesulfonate Chemical compound [K+].CCCCCCCCCCCCCCCCC(C)C1=CC(O)=C(S([O-])(=O)=O)C=C1O UVWWZGPJRBROMK-UHFFFAOYSA-M 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- NDGRWYRVNANFNB-UHFFFAOYSA-N pyrazolidin-3-one Chemical class O=C1CCNN1 NDGRWYRVNANFNB-UHFFFAOYSA-N 0.000 description 1
- MCSKRVKAXABJLX-UHFFFAOYSA-N pyrazolo[3,4-d]triazole Chemical compound N1=NN=C2N=NC=C21 MCSKRVKAXABJLX-UHFFFAOYSA-N 0.000 description 1
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000003349 semicarbazides Chemical class 0.000 description 1
- 230000001235 sensitizing effect Effects 0.000 description 1
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 1
- 235000019254 sodium formate Nutrition 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- FGDMJJQHQDFUCP-UHFFFAOYSA-M sodium;2-propan-2-ylnaphthalene-1-sulfonate Chemical compound [Na+].C1=CC=CC2=C(S([O-])(=O)=O)C(C(C)C)=CC=C21 FGDMJJQHQDFUCP-UHFFFAOYSA-M 0.000 description 1
- 239000012089 stop solution Substances 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 125000004964 sulfoalkyl group Chemical group 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- CBDKQYKMCICBOF-UHFFFAOYSA-N thiazoline Chemical compound C1CN=CS1 CBDKQYKMCICBOF-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 150000003583 thiosemicarbazides Chemical class 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 150000003752 zinc compounds Chemical class 0.000 description 1
- 150000003754 zirconium Chemical class 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/485—Direct positive emulsions
- G03C1/48538—Direct positive emulsions non-prefogged, i.e. fogged after imagewise exposure
- G03C1/48546—Direct positive emulsions non-prefogged, i.e. fogged after imagewise exposure characterised by the nucleating/fogging agent
- G03C1/48561—Direct positive emulsions non-prefogged, i.e. fogged after imagewise exposure characterised by the nucleating/fogging agent hydrazine compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
ç£æ¥äžã®å©çšåé
æ¬çºæã¯ãå
éšæœååããã²ã³åéä¹³å€ãçšã
ãçŽæ¥ããžããã²ã³åéåçæå ææã«é¢ããæŽ
ã«è©³ããã¯ãã«ããªå¹æã®åªããã«ããªå€ãå«æ
ãããã€ä¿åå®å®æ§ã«ãåªããå éšæœååããã²
ã³åéä¹³å€å±€ãçšããçŽæ¥ããžããã²ã³åéåç
æå ææã«é¢ããã åŸæ¥æè¡ ããã²ã³åéåçæå ææãçšããŠå転çŸååŠ
çãŸãã¯ãã¬åçåãå¿ èŠãšããã«ãçŽæ¥ããžç»
åã圢æã§ããããšã¯ããç¥ãããŠããã åŸæ¥ç¥ãããŠãããçŽæ¥ããžåããã²ã³åéå
çæå ææãçšããŠããžç»åã圢æããããã«çš
ããããæ¹æ³ã¯ãç¹æ®ãªãã®ãé€ããå®çšçæçš
ããèæ ®ãããšãäž»ãšããŠïŒã€ã®ã¿ã€ãã«åãã
ããšãã§ããã ïŒã€ã®ã¿ã€ãã¯ããããããã«ãã©ããããã
ã²ã³åéä¹³å€ãçšãããœã©ãªãŒãŒã·ãšã³ãããã¯
ããŒã·ãšã«å¹æçãå©çšããŠé²å éšã®ã«ããªæ ž
ïŒæœåïŒãç Žå£ããããšã«ãã€ãŠçŸååŸããžç»å
ãåŸããã®ã§ããã ããïŒã€ã®ã¿ã€ãã¯ãã«ãã©ãããŠããªãå éš
æœååããã²ã³åéä¹³å€ãçšããç»åé²å åŸã«ã
ãªåŠçãæœããåŸã§åã³ïŒãŸãåã¯ã«ããªåŠçã
æœããªããè¡šé¢çŸåãè¡ãããžç»åãåŸããã®ã§
ããã ããã§ãã«ããªåŠçã¯ãå šé¢é²å ãäžããããš
ã§ãããããã«ããªå€ãçšããŠããããã匷åãª
çŸå液ãçšããŠãããããç±åŠççã«ãã€ãŠãã
ãããéåžžã¯ã«ããªå€ãçšããŠè¡ãããŠããããª
ãå éšæœååããã²ã³åéä¹³å€ãšã¯äž»ãšããŠãã
ã²ã³åéç²åã®å éšã«æå æ žãæããé²å ã«ãã€
ãŠç²åå éšã«æœåã圢æããããããªããã²ã³å
éä¹³å€ãããã ãã®åŸè ã®ã¿ã€ãã®ããã²ã³åéä¹³å€ã«ããçŽ
æ¥ããžç»åãåŸãæ¹æ³ã¯ãåè ã®ã¿ã€ãã®æ¹æ³ã«
æ¯èŒããŠãäžè¬çã«æ床ãé«ããé«æ床ãèŠæ±ã
ããå¿çšã«é©ããŠãããæ¬çºæã¯ãããã«é¢ãã
ãã®ã§ããã ãã®æè¡åéã«ãããŠã¯çš®ã ã®æè¡ããããŸã§
ã«ç¥ãããŠãããäŸãã°ãç±³åœç¹èš±ç¬¬2592250å·ã
å第2456957å·ãå第2497875å·ãå第2588982å·ã
è±åœç¹èš±ç¬¬1151363å·ãç¹å ¬æ43â29405å·ãç¹é
æ47â9434å·ãå47â9677å·ãå47â32813å·ã
å47â32814å·ãå48â9727å·ãå48â9717å·å ¬
å ±ãç±³åœç¹èš±ç¬¬3761266å·ãå3796577å·ãç¹éæ
50â8524å·ãå50â38525å·çããã®äž»ãªãã®ã§
ããã ãããå ¬ç¥ã®æ¹æ³ãçšããŠãçŽæ¥ããžåãšããŠ
ã¯æ¯èŒçé«æ床ã®åçæå ææãäœãããšãã§ã
ãã ãŸããçŽæ¥ããžç»åã®åœ¢ææ©æ§ã®è©³çŽ°ã«ã€ããŠ
ã¯ãäŸãã°ããŒã¹ããã³ãžãšãŒã ã¹å ±èãã¶ã»ã»
ãªãªãŒã»ãªãã»ã¶ã»ããªãã°ã©ãã€ãã¯ã»ããã»
ã¹ãïŒThe Theory of the Photographic
ProcessïŒç¬¬ïŒç161é ã«è«ããããŠããåŠã
ãå éšæœåã«ããæžæäœçšããªã©ã«ããããžç»å
ã®åœ¢æãããéçšãããçšåºŠç解ããããšãã§ã
ãã ã€ãŸããæåã®ç»åé²å ã«ãã€ãŠããã²ã³åé
ç²åã®å éšã«çããããããå éšæœåã«èµ·å ãã
è¡šé¢æžæäœçšã«ãããéç»åéšã®æªé²å ããã²ã³
åéç²åã®è¡šé¢ã®ã¿ã«éžæçã«ã«ããªæ žãçæã
ãã次ãã§éåžžã®çŸåã«ãã€ãŠæªé²å éšã«åçå
ã圢æãããã®ãšæãããã ãã®ãããªéžæçãªã«ããªäœçšã瀺ãæçšãªã«
ããªå€ãšããŠã¯ããã©ãžã³ååç©ãããªã«ã«ããž
ãèªå°äœãç¥ãããŠããã äŸãã°ãç±³åœç¹èš±ç¬¬2563785å·ãå第2588982å·
ã«èšèŒãããŠããããã©ãžã³ååç©ãç±³åœç¹èš±ç¬¬
2604700å·ã«èšèŒãããŠãããããã«ããã©ãžã³
ã¹ã«ããªã³é žããããã¯è±åœç¹èš±ç¬¬1403018å·ã«
èšèŒãããŠããã¹ã«ããªã¡ãã«ããã©ãžã³é¡ãã«
ããªå€ãšããŠäœ¿çšãããŠããããŸãç¹å ¬æ41â
17184å·ã«ã¯ããã©ãžãããŸãã¯ããã©ãžã³åå
ç©ãçšããŠã«ã©ãŒããžç»åãåŸãããããšãèšèŒ
ãããŠããã ããããªããããããã®ååç©ãã«ããªå€ãšã
ãŠäœ¿çšããŠçŽæ¥ããžç»åã圢æããæ¹æ³ãçš®ã ã®
åçåéã«å¿çšããããã«ã¯æŽã«æ¹è¯ããªããã°
ãªããªãæè¡ç課é¡ãæ®ãããŠããã äŸãã°ããã®ãããªã«ããªçŸåã«ãããŠã¯ãçŸ
ååå¿ã«å è¡ããŠã«ããªå€ã«ããã«ããªåå¿ãèµ·
ããªããã°ãªããªãã®ã§ãéåžžã®æœåéã®çŸåã«
æ¯èŒããŠçŸåãéå§ããããŸã§ã®èªå°æãé·ãã
åŸã€ãŠãã®çŸåã¯ããªãé 延ãããããã®ããã
ç¹ã«å€å±€ã«ã©ãŒåçæå ææã«é©çšããå Žåã«å±€
éã«ç¹æ§ã®äžåäžãåŒãèµ·ãæãçã®åé¡ãååš
ããããŸããåŸæ¥ã®ã«ããªå€ã§ã¯æçµçã«åŸãã
ãæ倧æ¿åºŠãæ¯èŒçäœãã åŸã€ãŠãåŸæ¥ã®ã«ããªå€ã§ã¯ãæ¯èŒççæéå
ã«ææã®ã«ããªå¹æãåŸãããã«ã¯æ¯èŒçé«æ¿åºŠ
ã®ã«ããªå€ãå¿ èŠãšããããããã®ãããªé«æ¿åºŠ
ã§ã«ããªå€ã䜿çšããå Žåãçš®ã ã®æ¬ ç¹ãèŠãåº
ããããäŸãã°ãã«ããªå€ãä¹³å€äžã«å«æããã
å Žåã«ã¯çŸå液äžãžå€éã®ã«ããªå€ã溶åºãã奜
ãŸãããªãçŸåã®äžåäžãããããããšãç¥ãã
ãŠãããæŽã«ã«ããªå€ã®å解ã«ãã€ãŠçããçªçŽ
ã¬ã¹ã®æ°æ³¡ãæå ææã®ãã€ã³ããŒäžã«æç²ãã
ããšãç»åã®å質ãèãããæãªãããšã«ãªãã
ãŸãé«æ¿åºŠã®ã«ããªå€ãçšããŠçŸåãè¡ãªãå Ž
åãã«ããªå€ã«ããæ±æã«ããèæ¯éšåã«å€è²ã
ã²ãèµ·ãåŸåãããããŸããçºè²çŸåãè¡ãå Ž
åãã«ããªå€ãçºè²å€ãšç«¶åããŠãçºè²çŸåäž»è¬
ã®é žåäœãšåå¿ãããããé«æ¿åºŠã®ã«ããªå€ãçš
ãããšçºè²æææ¿åºŠãèããäœäžããããã ãã®ãããªåé¡ç¹ã解決ããããã«ãããã²ã³
åéç²åã®è¡šé¢ã«åžçããã«ããªå€ãšããŠãäŸã
ã°ç±³åœç¹èš±ç¬¬4030925å·ãå第4031127å·ã«ããã¢
ã·ã«ããã©ãžãããšãã«ããªå°¿çŽ ååç©ãææ¡ã
ããŠãããå°éã®æ·»å éã«ãã€ãŠè¯å¥œãªã«ããªå¹
æãéæããããšãã§ãããŸãçŸååŠç枩床äŸå
æ§ãå°ãªããšèšãç¹æ§ãæããŠããããšãé瀺ã
ããŠãããããããªãããäžèšã®ååç©ãä¹³å€ã«
å«æãããå Žåãä¹³å€æ¶²ãªãã³ã«æå ææã®ä¿å
æ§ãèãããå£åããããããšãèªãããããã
ãªãã¡ãæå ææãæ¯èŒçé«æž©ãããã¯é«æ¹¿ã®ç°
å¢äžã§ä¿åãããšãæå°æ¿åºŠãèãããå¢å€§ãã
æ倧æ¿åºŠãäœäžãããã®çµæãããžç»åã®å質ã
èãããæãããããšã«ãªãã ãŸãç±³åœç¹èš±ç¬¬4139387å·ã«ããã°ãããªã«ã«
ãããã©ãžãååç©ãæå¹ãªã«ããªäœçšãæãã
氎溶æ§ãæ¯èŒçé«ãããšãé瀺ãããŠããããã
ããªãããã®ååç©ã以äžã®åŠãå®çšäžã®æ¬ ç¹ã
ããããšãèªãããããããªãã¡åŸãããããžç»
åã®ãã€ã©ã€ãéšãã€ãŸãåçç¹æ§æ²ç·äžã®èéš
ã®é調ãèãããè»èª¿åããããããæè¬è¶³åã
ãæªããªããšããåŸåã®ããããšãèŠãåºãã
ãããã®ãããªç¹æ§ã¯ãäŸãã°æåãç·ç»ãªã©ã®
ãããªèæ¯éšåãšã®ã³ã³ãã©ã¹ããé«ãã茪éã®
é®®æãªåçåãäœæããå Žåã«ã¯æ¥µããŠäžå©ã§ã
ãã äžèšã®ä»ã«ãçš®ã ã®ã«ããªå€ãææ¡ãããŠãã
ããããããã«ããªå€ãšããŠã®æ§èœãäžè¶³ããŠã
ãããä¿åäžã®ç±æ¹¿æ°çã«ããæ§èœãå£åãããª
ã©ã®æ¬ ç¹ããããæŽã«æ¹è¯ãããã«ããªå€ã®éçº
ãæãŸããŠããã çºæã®ç®ç æ¬çºæã®ç¬¬ïŒã®ç®çã¯ãä¿åå®å®æ§ã®è¯å¥œãªçŽ
æ¥ããžããã²ã³åéåçæå ææãæäŸããããš
ã«ããããŸãæ¬çºæã®ç¬¬ïŒã®ç®çã¯ãç¹æ§æ²ç·ã®
足åãã®ããé®®æãªç»åã®åŸãããçŽæ¥ããžãã
ã²ã³åéåçæå ææãæäŸããããšã«ããã ããã«æ¬çºæã®ç¬¬ïŒã®ç®çã¯ãã«ããªå¹æã«åª
ããçŸåã®äžåäžæ§ãããã¯æ±æã®çºçããªãã
ãã€çŸååŠç枩床ãããã¯çµæä¿åã«ããå€åã
å°ãªãã°ããã§ãªãå®å®æ§ã®è¯å¥œãªããžç»åã圢
æãåŸãåŠãæ°èŠãªã«ããªå€ãªãã³ã«è©²ã«ããªå€
ãå«æããããçŽæ¥ããžããã²ã³åéåçæå æ
æãæäŸããããšã«ããã çºæã®æ§æ æ¬çºæè çã¯äžèšèª²é¡ã«å¯Ÿãæ€èšãéããçµæ
äžèšã®ç®çã¯ãå éšæœååããã²ã³åéç²åãå«
ãå°ãªããšãïŒå±€ã®æå æ§ããã²ã³åéä¹³å€å±€ã
æ¯æäœäžã«æãã該乳å€å±€ããã³ïŒãŸãã¯ãã®ä»
ã®èŠªæ°Žæ§ã³ãã€ãå±€ã®å°ãªããšãïŒå±€äžã«ã«ããª
å€ãå«æããããã²ã³åéåçæå ææã«ãã
ãŠãäžèšã«ããªå€ãäžèšäžè¬åŒã§ç€ºãããçŽæ¥ã
ãžããã²ã³åéåçæå ææã«ããéæãåŸãã
ãšãèŠãåºããã äžè¬åŒ åŒäžãR1ãR2ããã³R3ã¯åäžã§ãç°ãªã€ãŠã
ãŠããããåã æ°ŽçŽ ååãã¢ã«ãã«åºãã·ã¯ãã¢
ã«ãã«åºãŸãã¯ã¢ãªãŒã«åºãè¡šãããã¯ããšã
ã¬ã³åºã
ãçŽæ¥ããžããã²ã³åéåçæå ææã«é¢ããæŽ
ã«è©³ããã¯ãã«ããªå¹æã®åªããã«ããªå€ãå«æ
ãããã€ä¿åå®å®æ§ã«ãåªããå éšæœååããã²
ã³åéä¹³å€å±€ãçšããçŽæ¥ããžããã²ã³åéåç
æå ææã«é¢ããã åŸæ¥æè¡ ããã²ã³åéåçæå ææãçšããŠå転çŸååŠ
çãŸãã¯ãã¬åçåãå¿ èŠãšããã«ãçŽæ¥ããžç»
åã圢æã§ããããšã¯ããç¥ãããŠããã åŸæ¥ç¥ãããŠãããçŽæ¥ããžåããã²ã³åéå
çæå ææãçšããŠããžç»åã圢æããããã«çš
ããããæ¹æ³ã¯ãç¹æ®ãªãã®ãé€ããå®çšçæçš
ããèæ ®ãããšãäž»ãšããŠïŒã€ã®ã¿ã€ãã«åãã
ããšãã§ããã ïŒã€ã®ã¿ã€ãã¯ããããããã«ãã©ããããã
ã²ã³åéä¹³å€ãçšãããœã©ãªãŒãŒã·ãšã³ãããã¯
ããŒã·ãšã«å¹æçãå©çšããŠé²å éšã®ã«ããªæ ž
ïŒæœåïŒãç Žå£ããããšã«ãã€ãŠçŸååŸããžç»å
ãåŸããã®ã§ããã ããïŒã€ã®ã¿ã€ãã¯ãã«ãã©ãããŠããªãå éš
æœååããã²ã³åéä¹³å€ãçšããç»åé²å åŸã«ã
ãªåŠçãæœããåŸã§åã³ïŒãŸãåã¯ã«ããªåŠçã
æœããªããè¡šé¢çŸåãè¡ãããžç»åãåŸããã®ã§
ããã ããã§ãã«ããªåŠçã¯ãå šé¢é²å ãäžããããš
ã§ãããããã«ããªå€ãçšããŠããããã匷åãª
çŸå液ãçšããŠãããããç±åŠççã«ãã€ãŠãã
ãããéåžžã¯ã«ããªå€ãçšããŠè¡ãããŠããããª
ãå éšæœååããã²ã³åéä¹³å€ãšã¯äž»ãšããŠãã
ã²ã³åéç²åã®å éšã«æå æ žãæããé²å ã«ãã€
ãŠç²åå éšã«æœåã圢æããããããªããã²ã³å
éä¹³å€ãããã ãã®åŸè ã®ã¿ã€ãã®ããã²ã³åéä¹³å€ã«ããçŽ
æ¥ããžç»åãåŸãæ¹æ³ã¯ãåè ã®ã¿ã€ãã®æ¹æ³ã«
æ¯èŒããŠãäžè¬çã«æ床ãé«ããé«æ床ãèŠæ±ã
ããå¿çšã«é©ããŠãããæ¬çºæã¯ãããã«é¢ãã
ãã®ã§ããã ãã®æè¡åéã«ãããŠã¯çš®ã ã®æè¡ããããŸã§
ã«ç¥ãããŠãããäŸãã°ãç±³åœç¹èš±ç¬¬2592250å·ã
å第2456957å·ãå第2497875å·ãå第2588982å·ã
è±åœç¹èš±ç¬¬1151363å·ãç¹å ¬æ43â29405å·ãç¹é
æ47â9434å·ãå47â9677å·ãå47â32813å·ã
å47â32814å·ãå48â9727å·ãå48â9717å·å ¬
å ±ãç±³åœç¹èš±ç¬¬3761266å·ãå3796577å·ãç¹éæ
50â8524å·ãå50â38525å·çããã®äž»ãªãã®ã§
ããã ãããå ¬ç¥ã®æ¹æ³ãçšããŠãçŽæ¥ããžåãšããŠ
ã¯æ¯èŒçé«æ床ã®åçæå ææãäœãããšãã§ã
ãã ãŸããçŽæ¥ããžç»åã®åœ¢ææ©æ§ã®è©³çŽ°ã«ã€ããŠ
ã¯ãäŸãã°ããŒã¹ããã³ãžãšãŒã ã¹å ±èãã¶ã»ã»
ãªãªãŒã»ãªãã»ã¶ã»ããªãã°ã©ãã€ãã¯ã»ããã»
ã¹ãïŒThe Theory of the Photographic
ProcessïŒç¬¬ïŒç161é ã«è«ããããŠããåŠã
ãå éšæœåã«ããæžæäœçšããªã©ã«ããããžç»å
ã®åœ¢æãããéçšãããçšåºŠç解ããããšãã§ã
ãã ã€ãŸããæåã®ç»åé²å ã«ãã€ãŠããã²ã³åé
ç²åã®å éšã«çããããããå éšæœåã«èµ·å ãã
è¡šé¢æžæäœçšã«ãããéç»åéšã®æªé²å ããã²ã³
åéç²åã®è¡šé¢ã®ã¿ã«éžæçã«ã«ããªæ žãçæã
ãã次ãã§éåžžã®çŸåã«ãã€ãŠæªé²å éšã«åçå
ã圢æãããã®ãšæãããã ãã®ãããªéžæçãªã«ããªäœçšã瀺ãæçšãªã«
ããªå€ãšããŠã¯ããã©ãžã³ååç©ãããªã«ã«ããž
ãèªå°äœãç¥ãããŠããã äŸãã°ãç±³åœç¹èš±ç¬¬2563785å·ãå第2588982å·
ã«èšèŒãããŠããããã©ãžã³ååç©ãç±³åœç¹èš±ç¬¬
2604700å·ã«èšèŒãããŠãããããã«ããã©ãžã³
ã¹ã«ããªã³é žããããã¯è±åœç¹èš±ç¬¬1403018å·ã«
èšèŒãããŠããã¹ã«ããªã¡ãã«ããã©ãžã³é¡ãã«
ããªå€ãšããŠäœ¿çšãããŠããããŸãç¹å ¬æ41â
17184å·ã«ã¯ããã©ãžãããŸãã¯ããã©ãžã³åå
ç©ãçšããŠã«ã©ãŒããžç»åãåŸãããããšãèšèŒ
ãããŠããã ããããªããããããã®ååç©ãã«ããªå€ãšã
ãŠäœ¿çšããŠçŽæ¥ããžç»åã圢æããæ¹æ³ãçš®ã ã®
åçåéã«å¿çšããããã«ã¯æŽã«æ¹è¯ããªããã°
ãªããªãæè¡ç課é¡ãæ®ãããŠããã äŸãã°ããã®ãããªã«ããªçŸåã«ãããŠã¯ãçŸ
ååå¿ã«å è¡ããŠã«ããªå€ã«ããã«ããªåå¿ãèµ·
ããªããã°ãªããªãã®ã§ãéåžžã®æœåéã®çŸåã«
æ¯èŒããŠçŸåãéå§ããããŸã§ã®èªå°æãé·ãã
åŸã€ãŠãã®çŸåã¯ããªãé 延ãããããã®ããã
ç¹ã«å€å±€ã«ã©ãŒåçæå ææã«é©çšããå Žåã«å±€
éã«ç¹æ§ã®äžåäžãåŒãèµ·ãæãçã®åé¡ãååš
ããããŸããåŸæ¥ã®ã«ããªå€ã§ã¯æçµçã«åŸãã
ãæ倧æ¿åºŠãæ¯èŒçäœãã åŸã€ãŠãåŸæ¥ã®ã«ããªå€ã§ã¯ãæ¯èŒççæéå
ã«ææã®ã«ããªå¹æãåŸãããã«ã¯æ¯èŒçé«æ¿åºŠ
ã®ã«ããªå€ãå¿ èŠãšããããããã®ãããªé«æ¿åºŠ
ã§ã«ããªå€ã䜿çšããå Žåãçš®ã ã®æ¬ ç¹ãèŠãåº
ããããäŸãã°ãã«ããªå€ãä¹³å€äžã«å«æããã
å Žåã«ã¯çŸå液äžãžå€éã®ã«ããªå€ã溶åºãã奜
ãŸãããªãçŸåã®äžåäžãããããããšãç¥ãã
ãŠãããæŽã«ã«ããªå€ã®å解ã«ãã€ãŠçããçªçŽ
ã¬ã¹ã®æ°æ³¡ãæå ææã®ãã€ã³ããŒäžã«æç²ãã
ããšãç»åã®å質ãèãããæãªãããšã«ãªãã
ãŸãé«æ¿åºŠã®ã«ããªå€ãçšããŠçŸåãè¡ãªãå Ž
åãã«ããªå€ã«ããæ±æã«ããèæ¯éšåã«å€è²ã
ã²ãèµ·ãåŸåãããããŸããçºè²çŸåãè¡ãå Ž
åãã«ããªå€ãçºè²å€ãšç«¶åããŠãçºè²çŸåäž»è¬
ã®é žåäœãšåå¿ãããããé«æ¿åºŠã®ã«ããªå€ãçš
ãããšçºè²æææ¿åºŠãèããäœäžããããã ãã®ãããªåé¡ç¹ã解決ããããã«ãããã²ã³
åéç²åã®è¡šé¢ã«åžçããã«ããªå€ãšããŠãäŸã
ã°ç±³åœç¹èš±ç¬¬4030925å·ãå第4031127å·ã«ããã¢
ã·ã«ããã©ãžãããšãã«ããªå°¿çŽ ååç©ãææ¡ã
ããŠãããå°éã®æ·»å éã«ãã€ãŠè¯å¥œãªã«ããªå¹
æãéæããããšãã§ãããŸãçŸååŠç枩床äŸå
æ§ãå°ãªããšèšãç¹æ§ãæããŠããããšãé瀺ã
ããŠãããããããªãããäžèšã®ååç©ãä¹³å€ã«
å«æãããå Žåãä¹³å€æ¶²ãªãã³ã«æå ææã®ä¿å
æ§ãèãããå£åããããããšãèªãããããã
ãªãã¡ãæå ææãæ¯èŒçé«æž©ãããã¯é«æ¹¿ã®ç°
å¢äžã§ä¿åãããšãæå°æ¿åºŠãèãããå¢å€§ãã
æ倧æ¿åºŠãäœäžãããã®çµæãããžç»åã®å質ã
èãããæãããããšã«ãªãã ãŸãç±³åœç¹èš±ç¬¬4139387å·ã«ããã°ãããªã«ã«
ãããã©ãžãååç©ãæå¹ãªã«ããªäœçšãæãã
氎溶æ§ãæ¯èŒçé«ãããšãé瀺ãããŠããããã
ããªãããã®ååç©ã以äžã®åŠãå®çšäžã®æ¬ ç¹ã
ããããšãèªãããããããªãã¡åŸãããããžç»
åã®ãã€ã©ã€ãéšãã€ãŸãåçç¹æ§æ²ç·äžã®èéš
ã®é調ãèãããè»èª¿åããããããæè¬è¶³åã
ãæªããªããšããåŸåã®ããããšãèŠãåºãã
ãããã®ãããªç¹æ§ã¯ãäŸãã°æåãç·ç»ãªã©ã®
ãããªèæ¯éšåãšã®ã³ã³ãã©ã¹ããé«ãã茪éã®
é®®æãªåçåãäœæããå Žåã«ã¯æ¥µããŠäžå©ã§ã
ãã äžèšã®ä»ã«ãçš®ã ã®ã«ããªå€ãææ¡ãããŠãã
ããããããã«ããªå€ãšããŠã®æ§èœãäžè¶³ããŠã
ãããä¿åäžã®ç±æ¹¿æ°çã«ããæ§èœãå£åãããª
ã©ã®æ¬ ç¹ããããæŽã«æ¹è¯ãããã«ããªå€ã®éçº
ãæãŸããŠããã çºæã®ç®ç æ¬çºæã®ç¬¬ïŒã®ç®çã¯ãä¿åå®å®æ§ã®è¯å¥œãªçŽ
æ¥ããžããã²ã³åéåçæå ææãæäŸããããš
ã«ããããŸãæ¬çºæã®ç¬¬ïŒã®ç®çã¯ãç¹æ§æ²ç·ã®
足åãã®ããé®®æãªç»åã®åŸãããçŽæ¥ããžãã
ã²ã³åéåçæå ææãæäŸããããšã«ããã ããã«æ¬çºæã®ç¬¬ïŒã®ç®çã¯ãã«ããªå¹æã«åª
ããçŸåã®äžåäžæ§ãããã¯æ±æã®çºçããªãã
ãã€çŸååŠç枩床ãããã¯çµæä¿åã«ããå€åã
å°ãªãã°ããã§ãªãå®å®æ§ã®è¯å¥œãªããžç»åã圢
æãåŸãåŠãæ°èŠãªã«ããªå€ãªãã³ã«è©²ã«ããªå€
ãå«æããããçŽæ¥ããžããã²ã³åéåçæå æ
æãæäŸããããšã«ããã çºæã®æ§æ æ¬çºæè çã¯äžèšèª²é¡ã«å¯Ÿãæ€èšãéããçµæ
äžèšã®ç®çã¯ãå éšæœååããã²ã³åéç²åãå«
ãå°ãªããšãïŒå±€ã®æå æ§ããã²ã³åéä¹³å€å±€ã
æ¯æäœäžã«æãã該乳å€å±€ããã³ïŒãŸãã¯ãã®ä»
ã®èŠªæ°Žæ§ã³ãã€ãå±€ã®å°ãªããšãïŒå±€äžã«ã«ããª
å€ãå«æããããã²ã³åéåçæå ææã«ãã
ãŠãäžèšã«ããªå€ãäžèšäžè¬åŒã§ç€ºãããçŽæ¥ã
ãžããã²ã³åéåçæå ææã«ããéæãåŸãã
ãšãèŠãåºããã äžè¬åŒ åŒäžãR1ãR2ããã³R3ã¯åäžã§ãç°ãªã€ãŠã
ãŠããããåã æ°ŽçŽ ååãã¢ã«ãã«åºãã·ã¯ãã¢
ã«ãã«åºãŸãã¯ã¢ãªãŒã«åºãè¡šãããã¯ããšã
ã¬ã³åºã
ãåŒãåºãŸã
ã¯
ãåŒãåºãè¡šããã
ã¯é
žçŽ ååãŸãã¯ç¡«é»ååãè¡šãããã¯ïŒžã
é žçŽ ååã®ãšãã¯ç¡«é»ååãè¡šããããç¡«é»å
åã®ãšãã¯é žçŽ ååãè¡šããã 以äžãæ¬çºæãæŽã«è©³çŽ°ã«èª¬æããã äžèšäžè¬åŒã«ãããŠãR1ãR2ããã³R3ã§è¡šã
ãããã¢ã«ãã«åºãšããŠã¯ãäŸãã°ççŽ ååæ°ã
ïŒã18ã®çŽéç¶ãŸãã¯åå²ç¶ã®ã¢ã«ãã«åºãã
ãããããã®åºã«ããã²ã³ååãã¢ã«ã³ãã·åºã
ã«ã«ããã·ã«åºãããšãã«åºãã·ã¢ãåºçã«ãã
眮æãããŠããŠããããäŸãã°ã¡ãã«åºããšãã«
åºãïœâããã«åºãã€ãœãããã«åºããªã¯ãã«
åºãããã·ã«åºãããªãã«ãªãã¡ãã«åºãÏâã
ãã¢ããã«åºãβâã¡ããã·ãšãã«åºãã«ã«ãã
ã·ãšãã«åºããã³ãžã«åºãããšããã«åºçãæã
ãããšãã§ããããŸãåèšR1ãR2ããã³R3ã§è¡š
ããããã·ã¯ãã¢ã«ãã«åºã¯çœ®æãããŠããŠãã
ãã眮æåºãšããŠã¯ã¢ã«ã³ãã·åºãã«ã«ããã·ã«
åºãããšãã«åºãã·ã¢ãåºãããã²ã³ååçãæ
ããããšãã§ããå ·äœäŸãšããŠã¯ã·ã¯ããããã«
åºãã·ã¯ãããã·ã«åºãïŒâã¯ããã·ã¯ãããã·
ã«åºçãæããããšãã§ãããããã«åèšR1ã
R2ããã³R3ãè¡šããã¢ãªãŒã«åºãšããŠã¯ãäŸã
ã°ããšãã«åºããããã«åºçããããããããã¯
æŽã«ã¢ã«ãã«åºãã¢ã«ã³ãã·åºãããã²ã³ååã
ã¢ããåºãã·ã¢ãåºãã«ã«ããã·ã«åºçã«ãã眮
æãããŠããŠããããäŸãã°ããšãã«åºãããªã«
åºãã¡ããã·ããšãã«åºãã¯ããããšãã«åºãã
ããã«ããšãã«åºãã¢ã»ãã«ã¢ããããšãã«åºã
ã«ã«ããã·ããšãã«åºçãæããããšãã§ããã
次ã«åèšïŒ¡ãè¡šããããšãã¬ã³åºã
é žçŽ ååã®ãšãã¯ç¡«é»ååãè¡šããããç¡«é»å
åã®ãšãã¯é žçŽ ååãè¡šããã 以äžãæ¬çºæãæŽã«è©³çŽ°ã«èª¬æããã äžèšäžè¬åŒã«ãããŠãR1ãR2ããã³R3ã§è¡šã
ãããã¢ã«ãã«åºãšããŠã¯ãäŸãã°ççŽ ååæ°ã
ïŒã18ã®çŽéç¶ãŸãã¯åå²ç¶ã®ã¢ã«ãã«åºãã
ãããããã®åºã«ããã²ã³ååãã¢ã«ã³ãã·åºã
ã«ã«ããã·ã«åºãããšãã«åºãã·ã¢ãåºçã«ãã
眮æãããŠããŠããããäŸãã°ã¡ãã«åºããšãã«
åºãïœâããã«åºãã€ãœãããã«åºããªã¯ãã«
åºãããã·ã«åºãããªãã«ãªãã¡ãã«åºãÏâã
ãã¢ããã«åºãβâã¡ããã·ãšãã«åºãã«ã«ãã
ã·ãšãã«åºããã³ãžã«åºãããšããã«åºçãæã
ãããšãã§ããããŸãåèšR1ãR2ããã³R3ã§è¡š
ããããã·ã¯ãã¢ã«ãã«åºã¯çœ®æãããŠããŠãã
ãã眮æåºãšããŠã¯ã¢ã«ã³ãã·åºãã«ã«ããã·ã«
åºãããšãã«åºãã·ã¢ãåºãããã²ã³ååçãæ
ããããšãã§ããå ·äœäŸãšããŠã¯ã·ã¯ããããã«
åºãã·ã¯ãããã·ã«åºãïŒâã¯ããã·ã¯ãããã·
ã«åºçãæããããšãã§ãããããã«åèšR1ã
R2ããã³R3ãè¡šããã¢ãªãŒã«åºãšããŠã¯ãäŸã
ã°ããšãã«åºããããã«åºçããããããããã¯
æŽã«ã¢ã«ãã«åºãã¢ã«ã³ãã·åºãããã²ã³ååã
ã¢ããåºãã·ã¢ãåºãã«ã«ããã·ã«åºçã«ãã眮
æãããŠããŠããããäŸãã°ããšãã«åºãããªã«
åºãã¡ããã·ããšãã«åºãã¯ããããšãã«åºãã
ããã«ããšãã«åºãã¢ã»ãã«ã¢ããããšãã«åºã
ã«ã«ããã·ããšãã«åºçãæããããšãã§ããã
次ã«åèšïŒ¡ãè¡šããããšãã¬ã³åºã
ãåŒãåºãŸãã¯
ãåŒãåºã®ãã³ãŒã³ç°
ã«ã¯çœ®æåºããã€ãŠãããããããã®çœ®æåºãšã
ãŠã¯ãäŸãã°ããã²ã³ååïŒå¥œãŸããã¯å¡©çŽ å
åïŒãã¢ã«ãã«åºïŒå¥œãŸããã¯äœçŽã¢ã«ãã«åºã
äŸãã°ã¡ãã«ããšãã«ãïœâããã«çã®ååºïŒã
ã¢ã«ã³ãã·åºïŒå¥œãŸããã¯äœçŽã¢ã«ã³ãã·åºãäŸ
ãã°ã¡ããã·åºããšããã·åºçïŒçãæããããš
ãã§ããã 以äžã«åèšäžè¬åŒã§è¡šããããæ¬çºæã«ä¿ãã
ã«ããªå€ã®ä»£è¡šçå ·äœäŸãæããããæ¬çºæã¯ã
ãã«ããéå®ããããã®ã§ã¯ãªãã ïŒäŸç€ºååç©ïŒ æ¬çºæã®äžè¬åŒã§ç€ºãããååç©ã¯ãäžè¬åŒã«
次ã®æ¹æ³ã«ããåæããããšãã§ããã ããªãã¡ãïŒâãããããšãã«ããã©ãžã³ã«ã«
ã«ãã³é žïŒãããã¯é žå¡©åç©ãŸãã¯é žç¡æ°Žç©ïŒã
åå¿ãããŠïŒâã¢ã·ã«âïŒâïŒïŒâãããããšã
ã«ïŒããã©ãžã³ãåŸããããããšã¿ããŒã«ã溶åª
ãšããŠè§ŠåªãçšããŠæ°ŽçŽ æ·»å ãè¡ããïŒâã¢ãã
èªå°äœã«éå ãããæ¬çºæã«ä¿ããã«ããªå€ã¯äž
èšã«ããåŸãããïŒâã¢ããããšãã«ããã©ãžã³
ãïŒâã¢ã·ã«âïŒâïŒïŒâããªã€ãœã·ã¢ããŒãã
ãšãã«ïŒããã©ãžã³ã«èªå°ããææã®ã»ãã«ã«ã
ãžãé¡ãšãšã¿ããŒã«æ°Žç³»ã®æº¶åªäžãå ç±éæµãã
ããšã«ãã€ãŠåæããããšãã§ããã äžèšã¢ããåºãããªã€ãœã·ã¢ããŒããžå€æãã
æ¹æ³ãšãã¯å¹Ÿã€ãã®æ¹æ³ãããããïŒïŒ1â²âããª
ã«ã«ããã«ãžã€ãããŸãŒã«ã䜿çšãããšæž©åãªæ¡
件ã§åå¿ãé²ã¿æå©ã§ãããåèšã®ã»ãã«ã«ããž
ãé¡ã¯ããã©ãžã³ãšã€ãœã·ã¢ããŒããã容æã«å
æããããšãã§ããã ãŸãæ¬çºæã«ä¿ããã«ããªå€ããåèšã«ã«ãã¢
ããããšãã«åºãŸãã¯ã¹ã«ãã¢ããããšãã«åºã
é£çµåºãšããŠæããååç©ã§ãããšãã¯ãåèšã®
ïŒâã¢ã·ã«âïŒâïŒïŒâã¢ããããšãã«ïŒããã©
ãžã³ãã¢ããå®æ¯éŠé žã¯ããªããããã¯ã¢ããã
ã³ãŒã³ã¹ã«ããã«ã¯ããªããçšããŠããããã察
å¿ããïŒâã¢ã·ã«âïŒâïŒã¢ããããšãã«ã¢ãã
ããšãã«ïŒããã©ãžã³ãšãªããæŽã«ãããã€ãœã
ãªã·ã¢ããŒãã«èªå°ããŠã»ãã«ã«ããžããšåå¿ã
ãããŠåŸãããšãã§ããããŸãä»ã®æ¹æ³ãšããŠ
ã¯ããã³ãŒã³ãžã«ã«ãã³é žïŒãã¬ãã¿ã«é žïŒçã®
ã«ã«ãã³é žã®äžæ¹ãïœâãããããšããŒã«çã§ãš
ã¹ãã«åããŠä¿è·ããŠãããæ®äœã®ã«ã«ãã³é žã
é žã¯ããªãã«èªå°ããé žã¢ãžããã¯ã«ããŠã¹
ïŒCurtiusïŒè»¢ç§»ãçµãŠã€ãœã·ã¢ããŒãã«èªå°ãã
ããªã»ãã«ã«ããžãèªå°äœãšå ã«åå¿ãããæåŸ
ã«ïŒâã¢ããããšãã«ããã©ãžããšçž®åãããã
ãšã«ãã€ãŠãåæããããšãã§ããã 次ã«æ¬çºæã«ä¿ããã«ããªå€ã®å ·äœçåææ³ã
äŸèšããã åæäŸ ïŒ ïŒäŸç€ºååç©(1)ã®åæïŒ (ã€) ïŒâãã«ãã«âïŒâïŒïŒâãããããšãã«ïŒ
ããã©ãžã³äžéäœã®åæã ïŒâãããããšãã«ããã©ãžã³19.2ïœãã®é žã
ããªãŠã 8.5ïœããšã¿ããŒã«80mlãã®é žãšãã«400
mlãã®é ž60mlã®æ··å溶液äžã§ïŒæéå ç±ãéæµã
ãããã®åŸæº¶åªãæžå§æ¿çž®ããæåºããçµæ¶ã
åãããšã¿ããŒã«ã§æŽã€ãŠä¹Ÿç¥ããããç®çç©ã®
åé13.1ïœãèç¹182ã184âã (ã) ïŒâãã«ãã«âïŒâïŒïŒâã¢ããããšãã«ïŒ
ããã©ãžã³äžéäœã®åæã ïŒâãã«ãã«âïŒâïŒïŒâãããããšãã«ïŒã
ãã©ãžã³ïŒïœããšã¿ããŒã«200mlãšé ¢é žãšãã«200
mlã®æ··å溶åªã«æžæ¿ãããã©ãžãŠã âççŽ 1.0ïœ
ãå ããŠåžžå§äžã§æ°ŽçŽ æ·»å ãããåå¿æ¶²ãé
ãã液ãæžå§äžæ¿çž®ããçæããçµæ¶ãå
ãããšã¿ããŒã«ïŒïœâãããµã³æ··å溶åªã§æŽã€ãŠ
也ç¥ããããç®çç©ã®åé3.8ïœãèç¹120ã123
âã (ã) ïœâïŒïŒâãã«ãã«ããã©ãžãããšãã«ïŒã€
ãœããªã·ã¢ããŒãäžéäœã®åæã ïŒâãã«ãã«âïŒâïŒïŒâã¢ããããšãã«ïŒã
ãã©ãžã³2.2ïœãã¢ã»ãã³200mlã«æº¶ãããâ50â
ã«å·åŽãããããã«ïŒïŒ1â²âããªã«ã«ããã«ãžã€
ãããŸãŒã«2.7ïœãã¢ã»ãã³60mlã«æº¶ããããã®
ã30åéã«æ»Žäžããã次ãã§å®€æž©ãŸã§ãã€ããæ»
ããïŒæéæ¹æããã30â以äžã§æžå§äžã溶åªã
èžçºä¹Ÿåºããæ®æ»ã«ãšãŒãã«100mlãå ãããã
ããã€ã¶ãããæžæ¿æ¶²ãéããæ°Ž150mlã§æŽæµ
ããæŽã«ãšãŒãã«50mlã§æŽæµããŠãç®çç©1.8ïœ
ãåŸããèç¹173ã177âã (ã) äŸç€ºååç©(1)ã®åæ å¡©é žã»ãã«ã«ããžã1.11ïœããšã¿ããŒã«30mlã
æ°Ž10mlã®æ··å溶液ã«æº¶ãããããªãšãã«ã¢ãã³
1.01ïœãå ããããã®æº¶æ¶²ã«çªçŽ æ°æµäžãïœâ
ïŒïŒâãã«ãã«ããã©ãžãããšãã«ïŒã€ãœããªã·
ã¢ããŒã1.8ïœãå ããïŒæéå ç±éæµãããæŸ
å·åŸãåå¿æ¶²ãéããæ°Ž20mlã§æŽãã次ãã§ãš
ã¿ããŒã«20mlã§æŽæµããç®çç©0.95ïœãåŸããè
ç¹204ã205âïŒå解ïŒã åæäŸ ïŒ ïŒäŸç€ºååç©(2)ã®åæïŒ ïŒâããšãã«ã»ãã«ã«ããžã1.51ïœããšã¿ããŒ
ã«40mlãæ°ŽïŒmlã®æ··å液ã«åæ£ããããããã«çª
çŽ æ°æµäžãïœâïŒïŒâãã«ãã«ããã©ãžãããšã
ã«ïŒã€ãœããªã·ã¢ããŒã1.95ïœãæ·»å ããïŒæé
å ç±ãéæµããããæŸå·åŸãåå¿æ¶²ãéãããš
ã¿ããŒã«30mlã§æŽæµããŠç®çç©1.40ïœãåŸããè
ç¹196ã198âïŒå解ïŒã æ¬çºæã«ä¿ããã«ããªå€ã¯ãçŽæ¥ããžããã²ã³
åéåçæå ææã®å éšæœååããã²ã³åéç²å
ãæãã氎芪æ§ã³ãã€ãå±€ãããªãå°ããšãïŒã€
ã®ä¹³å€å±€äžã«å«æãããã®ã奜ãŸãããã該乳å€
å±€ãšæ¯æäœäžåãåŽã«ãã芪氎æ§ã³ãã€ãå±€ãäŸ
ãã°ä¿è·å±€ãäžéå±€ããã€ã«ã¿ãŒå±€ããã¬ãŒã·ãš
ã³é²æ¢å±€çã«å«æãããŠãããã該ã«ããªå€ã®äœ¿
çšéã¯ãçšããããããã²ã³åéä¹³å€ã®ç¹æ§ãã«
ããªå€ã®çš®é¡ãçŸåæ¡ä»¶ã«ãã€ãŠåºãç¯å²ã«å€å
ãåŸãããå éšæœååããã²ã³åéä¹³å€å±€ãæã
ãåçæå ææãç»åé²å åŸãè¡šé¢çŸå液ã§çŸå
åŠçããŠããžç»åãåŸãããã ãã®ãã¶ããäœçš
ãäžããéã§ããã°ãããçŸååŠçåŸå åãªæ倧
æ¿åºŠïŒäŸãã°1.5以äžïŒãäžããéã§ããããšã
æãŸãããéåžžã¯ãå éšæœååããã²ã³åéïŒã¢
ã«ã«å¯Ÿããã«ããªå€ã10-6ã¢ã«ã10-2ã¢ã«çšåºŠã
奜ãŸãããæŽã«å¥œãŸããã¯10-6ã¢ã«ã10-3ã¢ã«ã®
ç¯å²ã§ãããã«ããªå€ãäžèšä¹³å€å±€ã«å«æããã
ãå Žåã®ã«ããªå€ã®æº¶å€ãšããŠã¯ãéåžžãæ°Žãšæ··
åãåŸãææ©æº¶å€ã奜ãŸãããäŸãã°ã¡ã¿ããŒ
ã«ããšã¿ããŒã«ãã¢ã»ãã³ããžã¡ãã«ããªã«ã ã¢
ãããããã©ããããã©ã³çãåç¬ãããã¯æ··å
ããŠçšããã æ¬çºæã«ããã°ãæ¬çºæã«ä¿ããã«ããªå€ã¯ã
åèšã®ããã«å éšæœååããã²ã³åéç²åãå«æ
ããä¹³å€å±€ã®ã¿ãªããã該乳å€å±€ãšé£æ¥ãã芪氎
æ§ã³ãã€ãå±€ãäŸãã°äžéå±€ãä¿è·å±€ããã€ã«ã¿
ãŒå±€ãŸãã¯ãã¬ãŒã·ãšã³é²æ¢å±€çã«å«æãããã
ããšãã§ãããäžèšã®åŠãé£æ¥å±€ã«å«æãããã«
ããªå€ã¯ãçŸååŠçæã«è©²å±€ããåŠç液ãšå ±ã«æµ
ãåºãã該局ãšçžæ¥ããå éšæœååããã²ã³åé
ç²åãå«æããä¹³å€å±€ã«æµžå ¥ããäžèšããã²ã³å
éç²åè¡šé¢ã«åžçãããŠæ¬çºæã®å¹æãçºæ®ãã
ãã®ãšæšå¯ãããããŸãæ¬çºæã«ä¿ããã«ããªå€
ã¯ïŒçš®ä»¥äžäœµçšããããšãã§ãããã䜵çšããã
å Žåã«ã¯åäžã®èŠªæ°Žæ§ã³ãã€ãå±€äžã«å«æããã
ãããšã奜ãŸããããå¥åã®å±€ã«ããããå«æã
ããããšãã§ããã ãŸããæ¬çºæã«ä¿ããã«ããªå€ãã«ã©ãŒæ¡æ£è»¢
åæ³ã«é©çšãããå Žåã«ãã€ãŠã¯ããã®ååå±€ãŸ
ãã¯ã·ãŒãäžã«æ··å ¥ããããããšãã§ããããã®
å Žåã®è©²ã«ããªå€ã®å«æéã¯åèšããã²ã³åéä¹³
å€å±€äžã«å«æããããå Žåã«æºããéã§ããã æ¬çºæã«ä¿ããã«ããªå€ã¯ãåŸæ¥å ¬ç¥ã®ã«ããª
å€ãšäœµçšããããšãã§ããã äžèšã®åŸæ¥å ¬ç¥ã®æçšãªã«ããªå€ã®å ·äœäŸã瀺
ãã°ãããã©ãžã³å¡©é žå¡©ãããšãã«ããã©ãžã³å¡©
é žå¡©ãïŒâã¡ãã«ããšãã«ããã©ãžã³å¡©é žå¡©ãïŒ
âãã«ãã«âïŒâïŒïŒâã¡ãã«ããšãã«ïŒããã©
ãžã³ãïŒâã¢ã»ãã«âïŒâããšãã«ããã©ãžã³ã
ïŒâã¢ã»ãã«âïŒâïŒïŒâã¢ã»ãã¢ããããšãã«ïŒ
ããã©ãžã³ãïŒâã¡ãã«ã¹ã«ããªãã«âïŒâããš
ãã«ããã©ãžã³ãïŒâãã³ãŸã€ã«âïŒâããšãã«
ããã©ãžã³ãïŒâã¡ãã«ã¹ã«ããªãã«âïŒâïŒïŒ
âããšãã«ã¹ã«ããªã³ã¢ããããšãã«ïŒããã©ãž
ã³ãããªã«ã ã¢ã«ãããããšãã«ããã©ãŸã³çã®
ããã©ãžã³ååç©ïŒïŒâïŒïŒâãã«ãã«ãšãã«ïŒâ
ïŒâã¡ãã«ãã³ãŸãã¢ãŸãªãŠã ãããã€ããïŒâ
ïŒïŒâãã«ãã«ãšãã«ïŒâïŒâãããã«ãã³ãŸãã¢
ãŸãªãŠã ãããã€ããïŒâïŒïŒâã¢ã»ãã«ãšãã«ïŒ
âïŒâãã³ãžã«ãã³ãŸã»ã¬ããŸãªãŠã ãããã€
ããïŒâïŒïŒâã¢ã»ãã«ãšãã«âïŒâãã³ãžã«â
ïŒâããšãã«âãã³ãŸãªããµãŸãªãŠã ãããã€
ããïŒâã¡ãã«âïŒâïŒâïŒããšãã«ããã©ãŸ
ãïŒãããã«ïŒœãã³ãŸãã¢ãŸãªãŠã ãããã€ãã
ïŒâã¡ãã«âïŒâïŒâïŒïœâããªã«ããã©ãŸãïŒ
ãããã«ïŒœãã³ãŸãã¢ãŸãªãŠã ãããã€ããïŒâ
ã¡ãã«âïŒâïŒâïŒïœâã¹ã«ããªããšãã«ããã©
ãŸãïŒãããã«ïŒœãã³ãŸãã¢ãŸãªãŠã ãããã€
ããïŒâã¡ãã«âïŒâïŒâïŒïœâã¹ã«ããªããšã
ã«ããã©ãŸãïŒãã³ãã«ïŒœãã³ãŸãã¢ãŸãªãŠã ãš
ãŒãããïŒïŒïŒâãžãããâïŒâã¡ãã«âïŒâã
ãšãã«ããªãïŒïŒïŒâïœïŒãã³ãŸãã¢ãŸãªãŠã
ãããã€ããïŒïŒïŒâãžãããâïŒâã¡ãã«âïŒ
âããšãã«ããªãïŒïŒïŒâïœïŒœâïŒâããšãã«
ãã³ãŸãªããµãŸãªãŠã ãããã€ããïŒïŒ4â²âãšã
ã¬ã³ãã¹ïŒïŒïŒïŒâãžãããâïŒâã¡ãã«ããªã
ïŒïŒïŒâïœïŒœãã³ãŸãã¢ãŸãªãŠã ãããã€ãïŒã
ïŒïŒïŒâãžãããâïŒâã¡ãã«âïŒâããšãã«ã
ãªãïŒïŒïŒâïœïŒœãã³ãŸã»ã¬ããŸãªãŠã ããã
ã€ãçã®ïŒ®â眮æ第ïŒçŽã·ã¯ãã¢ã³ã¢ããŠã å¡©ïŒ
ïŒâïŒâãšãã«ãããïŒïŒïŒïŒâïœïŒãã¢ãŸãª
ã³âïŒâã€ãªãã³ãšããªãã³ïŒœâïŒâïŒïŒâããšã
ã«ã«ã«ããŸã€ã«ïŒã¡ãã«âïŒâïŒïŒâã¹ã«ãã¢ã¢
ã€ã«ããšãã«ïŒâïŒâããªããã³ãã€ã³ãïŒâïŒïŒ
âãšãã«âïŒâãã³ãŸãã¢ãŸãªããªãã³ïŒâïŒâ
ïŒâïŒïŒâããªã«ãã«ããã©ãžãïŒããšãã«ïŒœã
ãŒããã³ãïŒâïŒâïŒïŒâããªã«ãã«ããã©ãž
ãïŒããšãã«ïŒœâããšãã«ããªå°¿çŽ ãïŒïŒïŒâã
ã¹ïŒ»ïŒâïŒïŒâããªã«ãã«ããã©ãžãïŒããšãã«ïŒœ
ããªå°¿çŽ ãªã©ãæããããã æ¬çºæã®çŽæ¥ããžããã²ã³åéåçæå ææ
ïŒä»¥äžãæ¬çºæã®æå ææãšåŒã¶ïŒã¯åæ§é²å åŸã
ã«ããªå€ã®ååšäžã«çŸååŠçããããšã«ãã€ãŠçŽ
æ¥ããžç»åã圢æããããæ¬çºæã®æå ææã®çŸ
ååŠçæ¹æ³ã¯ä»»æã®çŸååŠçæ¹æ³ãæ¡çšããã
ãã奜ãŸããã¯è¡šé¢çŸååŠçæ¹æ³ã§ããããã®è¡š
é¢çŸååŠçæ¹æ³ãšã¯ããã²ã³åé溶å€ãå®è³ªçã«
å«ãŸãªãçŸå液ã§åŠçããããšãæå³ããã æ¬çºæã«ãããŠçŸå液ãšããŠäœ¿çšããããšã®ã§
ããéåžžã®ããã²ã³åéçŸåå€ã«ã¯ããã€ããã
ãã³ã®åŠãããªããããã·ãã³ãŒã³é¡ãã¢ããã
ãšããŒã«é¡ãïŒâãã©ãŸãªãã³é¡ãã¢ã¹ã³ã«ãã³
é žãšãã®èªå°äœãã¬ãã¯ãã³é¡ãããšãã¬ã³ãžã¢
ãã³é¡çãããã¯ãã®æ··åç©ãå«ãŸãããå ·äœç
ã«ã¯ãã€ããããã³ãã¢ããããšããŒã«ãâã¡
ãã«ã¢ããããšããŒã«ãïŒâããšãã«âïŒâãã©
ãŸãªãã³ãïŒâããšãã«âïŒïŒïŒâãžã¡ãã«âïŒ
âãã©ãŸãªãã³ãïŒâããšãã«âïŒâã¡ãã«âïŒ
âããããã·ã¡ãã«âïŒâãã©ãŸãªãã³ãã¢ã¹ã³
ã«ãã³é žãïŒïŒ®âãžãšãã«âïœâããšãã¬ã³ãž
ã¢ãã³ããžãšãã«ã¢ããâïœâãã«ã€ãžã³ãïŒâ
ã¢ããâïŒâã¡ãã«ââãšãã«ââïŒÎ²âã¡
ã¿ã³ã¹ã«ããªã³ã¢ãããšãã«ïŒã¢ããªã³ãïŒâã¢
ããâïŒâã¡ãã«ââãšãã«ââïŒÎ²âãã
ããã·ãšãã«ïŒã¢ããªã³çãæãããããããã
ã®çŸåå€ã¯ãããããä¹³å€äžã«å«ãŸããŠãããé«
PH氎溶液浞挬äžã«ããã²ã³åéã«äœçšããããã
ã«ããããšãã§ããã æ¬çºæã«ãããŠäœ¿çšãããçŸå液ã¯ãæŽã«ç¹å®
ã®ã«ããªé²æ¢å€åã³çŸåæå¶å€ãå«æããããšã
ã§ãããããã¯ãããã®çŸå液添å å€ãããã²ã³
åéåçæå ææã®å±€èäžã«ä»»æã«çµã¿å ¥ããã
ãšãå¯èœã§ãããéåžžæçšãªã«ããªé²æ¢å€ã«ã¯ã
äŸãã°ïŒâã¡ãã«ãã³ãŸããªã¢ãŸãŒã«ã®ãããªã
ã³ãŸããªã¢ãŸãŒã«é¡ïŒãã³ãŸãã¢ãŸãŒã«é¡ïŒïŒâ
ããšãã«âïŒâã¡ã«ã«ããããã©ãŸãŒã«ã®ãããª
è€çŽ ç°åŒããªã³é¡ïŒè³éŠæåã³èèªæã®ã¡ã«ã«ã
ãååç©çãå«ãŸããããŸããçŸå液äžã«ã¯ãçŸ
åä¿é²å€äŸãã°ããªã¢ã«ãã¬ã³ãªããµã€ãèªå°äœ
ã第ïŒçŽã¢ã³ã¢ããŠã å¡©ååç©ãªã©ãå«æããã
ããšãã§ããã æ¬çºæã®æå ææã¯å°ãªããšãäžå±€ã®å éšæœå
åããã²ã³åéä¹³å€ãããªãã æ¬çºæã«ãããå éšæœååããã²ã³åéä¹³å€ã¯
ããã²ã³åéç²åã®å éšã«äž»ãšããŠæœåã圢æ
ããæå æ žã®å€§éšåãç²åã®å éšã«æããããã²
ã³åéç²åãæããä¹³å€ã§ãã€ãŠãä»»æã®ããã²
ã³åéãäŸãã°èåéãå¡©åéãå¡©èåéãæ²è
åéãå¡©æ²èåéçãå å«ãããã ç¹ã«å¥œãŸããã¯ãã®ä¹³å€ã¯éæãªæ¯æäœã«å¡åž
ããè©Šæã®äžéšãçŽïŒç§ãŸã§ã®ããå®ããããæ
éã«ããã€ãŠå 匷床ã¹ã±ãŒã«ã«é²å ãå®è³ªçã«ã
ãã²ã³åé溶å€ãå«æããªãç²åã®è¡šé¢åã®ã¿ã
çŸåããäžèšã®è¡šé¢çŸå液ãçšããŠ20âã§ïŒå
éçŸåããå Žåã«ãåäžã®ä¹³å€è©Šæã®å¥ã®äžéšã
åããé²å ããç²åã®å éšã®åãçŸåããäžèšã®
å éšçŸå液ã§20âã§ïŒåéçŸåããå Žåã«åŸã
ããæ倧æ¿åºŠã®1/5ãã倧ãããªãæ倧æ¿åºŠã瀺
ããã®ã§ããã奜ãŸããã¯ãè¡šé¢çŸå液ãçšã
ãŠåŸãããæ倧æ¿åºŠã¯å éšçŸå液ã§åŸãããæ
倧æ¿åºŠã®1/10ãã倧ãããªããã®ã§ããã ïŒè¡šé¢çŸåæ¶²ïŒ¡ïŒ ã¡ããŒã« 2.5ïœ ïŒ¬âã¢ã¹ã³ã«ãã³é ž 10ïœ NaBO2ã»4H2O 35ïœ KBr ïŒïœ æ°Žãå ããŠ ïŒ ïŒå éšçŸåæ¶²ïŒ¢ïŒ ã¡ããŒã« 2.0ïœ äºç¡«é žãœãŒãïŒç¡æ°ŽïŒ 90.0ïœ ãã€ããããã³ 8.0ïœ çé žãœãŒããŒæ°Žå¡© 52.5ïœ KBr 5.0ïœ KI 0.5ïœ æ°Žãå ããŠ ïŒ ãŸããæ¬çºæã«ä¿ãå éšæœååããã²ã³åéä¹³
å€ã¯ãçš®ã ã®æ¹æ³ã§èª¿è£œããããã®ãå«ãŸããã
äŸãã°ç±³åœç¹èš±ç¬¬2592250å·ã«èšèŒãããŠããã³
ã³ããŒãžãšã³åããã²ã³åéä¹³å€ããŸãã¯ç±³åœç¹
蚱第3206316å·ãå第3317322å·ããã³å第
3567778å·ã«èšèŒãããŠããå éšååŠå¢æããã
ããã²ã³åéç²åãæããããã²ã³åéä¹³å€ããŸ
ãã¯ç±³åœç¹èš±ç¬¬3271157å·ãå第3447927å·ããã³
å第3331291å·ã«èšèŒãããŠããå€äŸ¡éå±ã€ãªã³
ãå èµããŠããããã²ã³åéç²åãæããããã²
ã³åéä¹³å€ããŸãã¯ç±³åœç¹èš±ç¬¬3761276å·ã«èšèŒ
ãããŠããããŒãå€ãå«æããããã²ã³åéç²å
ã®ç²åè¡šé¢ã匱ãååŠå¢æããããã²ã³åéä¹³
å€ããŸãã¯ç¹éæ50â8524å·ãå50â38525å·ã
ãã³å53â2408å·ã«èšèŒãããŠããç©å±€æ§é ãæ
ããç²åãããªãããã²ã³åéä¹³å€ããã®ä»ç¹é
æ52â156614å·ããã³ç¹éæ55â127549å·ã«èšèŒ
ãããŠããããã²ã³åéä¹³å€ãªã©ã§ããã æŽã«ãæ¬çºæã«ä¿ãå éšæœååããã²ã³åéä¹³
å€ã«ã¯ãéåžžçšããããå®å®å€ãäŸãã°ã¢ã¶ã€ã³
ãã³ç°ãæã€ååç©ããã³ã¡ã«ã«ããåºãæãã
å«çªçŽ ãããç°ååç©ïŒä»£è¡šçãªãã®ãšããŠãã
ããïŒâããããã·âïŒâã¡ãã«âïŒïŒïŒïŒ3aïŒ
ïŒâããã©ã¶ã€ã³ãã³ããã³ïŒâããšãã«âïŒâ
ã¡ã«ã«ããããã©ãŸãŒã«ãæããããïŒçããã
ã²ã³åéïŒã¢ã«ã«å¯ŸãïŒmgã10ïœå«æãããããš
ã«ãããããäœãæå°æ¿åºŠãæã€ãããå®å®ãªçµ
æãäžããããšãã§ããã ãã®ä»æ¬çºæã«ãããŠãã«ããªé²æ¢å€ãŸãã¯å®
å®å€ãšããŠãäŸãã°æ°Žéååç©ãããªã¢ãŸãŒã«ç³»
ååç©ãã¢ã¶ã€ã³ãã³ç³»ååç©ããã³ãŸãã¢ãŸãª
ãŠã ç³»ååç©ãäºéååç©çã䜿çšãåŸãã æ¬çºæã«ä¿ãå éšæœååããã²ã³åéä¹³å€ã«
ã¯ãåçš®ã®åççšæ·»å å€ãå ããããšã¯ä»»æã§ã
ãã äŸãã°ãæ¬çºæã«ãããŠäœ¿çšãåŸãå åŠå¢æå€
ã«ã¯ãã·ã¢ãã³é¡ãã¡ãã·ã¢ã³é¡ãäžæ žãŸãã¯å
æ žã¡ãã·ã¢ãã³é¡ãäžæ žãŸãã¯åæ žã·ã¢ãã³é¡ã
ã¹ããªã«é¡ããã¢ããŒã©ã·ã¢ãã³é¡ãããã·ã¢ã
ã³é¡ããªããœããŒã«é¡ããã³ãããªããœããŒã«é¡
ãå«ãŸãããããã®å åŠå¢æå€ã¯å«çªçŽ è€çŽ ç°æ ž
ãšããŠã®æ§é ã®äžéšã«ãã¢ãŸãªã³ããã¢ãŸãŒã«ç
ã®å¡©åºæ§åºãŸãã¯ããŒããã³ãããªããã³ãã€
ã³ããªããµãŸãªãžã³ãžãªã³ããã«ãããŒã«é žãã
ãªãã«ãããŒã«é žããã©ãŸãã³çã®æ žãå«ããã®
ã奜ãŸããããããæ žã¯ã¢ã«ãã«ãããããã·ã¢
ã«ãã«ãã¹ã«ãã¢ã«ãã«ãã«ã«ããã·ã¢ã«ãã«ã
ããã²ã³ãããšãã«ãã·ã¢ããã¢ã«ã³ãã·çœ®æã
ãããšãã§ãããŸãççŽ ç°ãŸãã¯è€çŽ ç°ãšçž®åã
ãããšã¯ä»»æã§ããã æ¬çºæã«ä¿ãå éšæœååããã²ã³åéä¹³å€ã¯è¶
è²å¢æããããšãã§ãããè¶ è²å¢æã®æ¹æ³ã«ã€ã
ãŠã¯ãäŸãã°ãè¶ è²å¢æã®æ©æ§ã®ç·èª¬ãã¬ããŠ
ãŒã»ãªãã»ã¹ãŒããŒã»ã³ã·ã¿ã€ãŒãŒã·ãšã³
ïŒReview of SupersensitizationïŒããªãã°ã©ã
ã€ãã¯ã»ãµã€ãšã³ã¹ã»ã¢ã³ãã»ãšã³ãžãã€ãªã³ã°
ïŒPhotographic Science and EngineeringïŒ
Vol.18ã第4418é ïŒ1974ïŒå¹Žã«èšèŒãããŠããã ãã®ä»æ¬çºæã«ãããŠãç®çã«å¿ããŠçšããã
ãæ·»å å€ã¯ã湿最å€ãšããŠã¯ãäŸãã°ããžããã
ãã·ã¢ã«ã«ã³çãæããããããã«èç©æ§æ¹è¯å€
ãšããŠã¯ãäŸãã°ãã¢ã«ãã«ã¢ã¯ãªã¬ãŒãããã
ã¯ã¢ã«ãã«ã¡ã¿ã¯ãªã¬ãŒããšã¢ã¯ãªã«é žãããã¯
ã¡ã¿ã¢ã¯ãªã«é žãšã®å ±éåäœãã¹ãã¬ã³âãã¬ã€
ã³é žå ±éåäœãã¹ãã¬ã³ç¡æ°Žãã¬ã€ã³é žããŒãã¢
ã«ãã«ãšã¹ãã«å ±éåäœçã®ä¹³åéåã«ãã€ãŠåŸ
ãããæ°Žåæ£æ§ã®åŸ®ç²åç¶é«ååç©è³ªçãé©åœã§
ãããå¡åžå©å€ãšããŠã¯ãäŸãã°ããµããã³ãã
ãªãšãã¬ã³ã°ãªã³ãŒã«ã©ãŠãªã«ãšãŒãã«çãå«ãŸ
ããããã®ä»åççšæ·»å å€ãšããŠããŒã©ãã³å¯å¡
å€ãçé¢æŽ»æ§å€ã玫å€ç·åžåå€ãPH調æŽå€ãé žå
é²æ¢å€ã垯é»é²æ¢å€ãå¢ç²å€ãç²ç¶æ§åäžå€ãæ
æãã¢ã«ãã³ããå¢çœå€ãçŸåé床調ç¯å€ããã
ãå€çã䜿çšããããšã¯ä»»æã§ããã äžè¿°ã®åŠã調補ãããããã²ã³åéä¹³å€ã¯ãå¿
èŠã«å¿ããŠäžåŒå±€ããã¬ãŒã·ãšã³é²æ¢å±€ããã€ã«
ã¿ãŒå±€çãä»ããŠæ¯æäœã«å¡åžããçŽæ¥ããžãã
ã²ã³åéåçæå ææãåŸãã æ¬çºæã®æå ææã¯ãã«ã©ãŒçšãšããŠçšããã
ãšãã§ãããã®å Žåã«ã¯åèšä¹³å€äžã«ã·ã¢ã³ãã
ãŒã³ã¿ããã³ã€ãšããŒã®è²çŽ 圢æã«ãã©ãŒãŸãã¯
DIRååç©çã®è²çŽ ç»å圢æç©è³ªãå«ãŸããããš
ã奜ãŸãããäžèšã€ãšããŒè²çŽ 圢æã«ãã©ãŒãšã
ãŠã¯ããã³ãŸã€ã«ã¢ã»ãã¢ããªãåããããã€ã«
ã¢ã»ãã¢ããªãåæãã¯ã«ãããªã³ã°äœã®ççŽ å
åãã«ãããªã³ã°åå¿æã«é¢èª¬ããããšãã§ãã
眮æåºãããããã¹ããªãããªãåºã§çœ®æãããŠ
ããïŒåœéåã€ãšããŒã«ãã©ãŒçãæçšã§ããã
ãŸãããŒã³ã¿è²çŽ 圢æã«ãã©ãŒãšããŠã¯ãã©ãŸã
ã³ç³»ããã©ãŸãããªã¢ãŸãŒã«ç³»ããã©ãŸãªããã³
ãã€ãããŸãŒã«ç³»ãã€ã³ããŸãã³ç³»æãã¯ã¹ããª
ãããªãåºãæããïŒåœéåããŒã³ã¿ã«ãã©ãŒã
æçšã§ãããæŽã«ã·ã¢ã³è²çŽ 圢æã«ãã©ãŒãšããŠ
ã¯ããšããŒã«ç³»ãããããŒã«ç³»ããã©ãŸãããŸã
ã³ç³»ãæãã¯ã¹ããªãããªãåºãæããïŒåœéå
ã·ã¢ã³ã«ãã©ãŒãæçšã§ããã æ¬çºæã«ãããŠã¯ãè²çŽ ç»åã®çæ³¢é·ã®æŽ»æ§å
ç·ã«ãã耪è²ãé²æ¢ãããã玫å€ç·åžåå€ãäŸã
ã°ãã¢ãŸãªãã³ããã³ãŸããªã¢ãŸãŒã«ãã¢ã¯ãªã
ãããªã«ããã³ãŸããšãã³ç³»ååç©ãçšããããš
ã¯æçšã§ãããç¹ã«ãããã³ã³PSãå320ãå
326ãå327ãå328ïŒããããããã¬ã€ã®ãŒç€Ÿè£œïŒ
ã®åçšãããã¯äœµçšãæå©ã§ããã æ¬çºæã®æå ææã®æ¯æäœãšããŠã¯ä»»æã®ãã®
ãçšãããããã代衚çãªæ¯æäœãšããŠã¯ãå¿ èŠ
ã«å¿ããŠäžåŒå å·¥ããããªãšãã¬ã³ãã¬ãã¿ã¬ãŒ
ããã€ã«ã ãããªã«ãŒãããŒããã€ã«ã ãããªã¹
ãã¬ã³ãã€ã«ã ãããªãããã¬ã³ãã€ã«ã ãã»ã«
ããŒãºã¢ã»ããŒããã€ã«ã ãã¬ã©ã¹ããã©ã€ã¿
çŽãããªãšãã¬ã³ã©ãããŒãçŽçãå«ãŸããã æ¬çºæã®æå ææã«ã¯ãŒã©ãã³ã®ä»ã«ç®çã«å¿
ããŠé©åœãªãŒã©ãã³èªå°äœãå«ãŸããããšãã§ã
ãããã®é©åœãªãŒã©ãã³èªå°äœãšããŠã¯ãäŸãã°
ã¢ã·ã«åãŒã©ãã³ãã°ã¢ããžã«åãŒã©ãã³ãã«ã«
ããã«åãŒã©ãã³ãã·ã¢ããšã¿ããŒã«åãŒã©ã
ã³ããšã¹ãã«åãŒã©ãã³çãæããããšãã§ã
ãã ãŸããæ¬çºæã«ãããŠã¯ãèªåã«å¿ããŠä»ã®èŠª
æ°Žæ§ãã€ã³ããŒãå«ãŸããããšãã§ãããã®é©åœ
ãªãã€ã³ããŒãšããŠã¯ãŒã©ãã³ã®ã»ããã³ãã€ã
ç¶ã¢ã«ããã³ãå¯å€©ãã¢ã©ãã€ãŽã ãããã¹ãã©
ã³ãã¢ã«ã®ã³é žãã¢ã»ãã«å«æ10ã20ïŒ ã«ãŸã§å
æ°Žå解ãããã»ã«ããŒãºã¢ã»ããŒãã®åŠãã»ã«ã
ãŒãºèªå°äœãããªã¢ã¯ãªã«ã¢ãããã€ããåããª
ã¢ã¯ãªã«ã¢ãããã«ãŒã€ã³ãããã«ã¢ã«ã³ãŒã«â
ããã«ã¢ããã¢ã»ããŒãã³ããªããŒã®åŠããŠã¬ã¿
ã³ã«ã«ãã³é žåºãŸãã¯ãã·ã¢ãã¢ã»ãã«åºãå«ã
ããã«ã¢ã«ã³ãŒã«ããªããŒãããªããã«ã¢ã«ã³ãŒ
ã«ãããªããã«ãããªãã³ãå æ°Žå解ããªããã«
ã¢ã»ããŒããèçœè³ªãŸãã¯é£œåã¢ã·ã«åèçœè³ªãš
ããã«åºãæããã¢ãããŒãšã®éåã§åŸãããã
ãªããŒãããªããã«ããªãžã³ãããªããã«ã¢ã
ã³ãããªã¢ãããšãã«ã¡ã¿ã¢ã¯ãªã¬ãŒããããªãš
ãã¬ã³ã¢ãã³çãå«ãŸããä¹³å€å±€ãããã¯äžé
å±€ãä¿è·å±€ããã€ã«ã¿ãŒå±€ãè£åŒå±€çã®ããã²ã³
åéåçæå æææ§æå±€ã«ç®çã«å¿ããŠæ·»å ãã
ããšãã§ãããããã«äžèšèŠªæ°Žæ§ãã€ã³ããŒã«ã¯
ç®çã«å¿ããŠé©åœãªå¯å¡æ§ã最æ»å€çãå«æãã
ããããšãã§ããã ãŸããæ¬çºæã«ä¿ãäžèšæ§æå±€ã¯ä»»æã®é©åœãª
硬èå€ã§ç¡¬åããããããšãã§ããããããã®ç¡¬
èå€ãšããŠã¯ãã¯ãã å¡©ããžã«ã³ããŠã å¡©ãããª
ã«ã ã¢ã«ããããã ã³ããã²ã³é žã®åŠãã¢ã«ãã
ãç³»ãããããªã¢ãžã³ç³»ãããªãšããã·ååç©ã
ãšãã¬ã³ã€ãã³ç³»ãããã«ã¹ã«ããªã³ç³»ãã¢ã¯ãª
ãã€ã«ç³»ç¡¬èå€çãæããããã ãŸããæ¬çºæã®æå ææã¯ãæ¯æäœäžã«ä¹³å€
å±€ããã€ã«ã¿ãŒå±€ãäžéå±€ãä¿è·å±€ãäžåŒå±€ãè£
åŒå±€ããã¬ãŒã·ãšã³é²æ¢å±€çã®çš®ã ã®åçæ§æå±€
ãå€æ°èšçœ®ãããšãå¯èœã§ããã æ¬çºæã®æå ææã¯ãåèšã®ã«ã©ãŒçšã®ã»ãã
çœé»äžè¬çšãã¬ã€çšãåœã«ã©ãŒçšãå°å·çšãèµ€
å€çšããã€ã¯ãçšãéè²çŽ æŒçœçšãã«ã©ãŒæ¡æ£è»¢
ååççšçãçš®ã ã®çšéã«é©çšããããšãã§ã
ãã äžã§ãæ¡æ£è»¢ååççšãšããŠã¯ãDRRååç©
ãçšããæ¹åŒã®ãã®ã«ç¹ã«æå¹ã§ããã該DRR
ååç©ïŒè²çŽ æŸåºæ§ã¬ããã¯ã¹ååç©ãDye
Releasing Redox CompoundïŒãšã¯ãäŸãã°ã
ã©ã¹ãä»ã®ããšããŒã«ïŒåã¯ããããŒã«ïŒãªã«ã
åã¯ãã©äœã«ã¹ã«ãã³ã¢ãããä»ããŠè²çŽ ãçµå
ããããã®ããããã¯ã€ã³ããŒã«ã®ïŒäœã«ã¹ã«ã
ã³ã¢ãããä»ããŠè²çŽ ãçµåããããã®çã§ãã€
ãŠããããã¯çŸåæã«ããšããã³èªå°äœã®é žåäœ
ãšåå¿ããŠãã¯ãã¹é žåãåããã€ãã§å æ°Žå解
ãããŠæ¡æ£æ§ã®è²çŽ ãæŸåºããæ§è³ªãæããåå
ç©ãèšããïŒç¹éæ48â33826å·ãå51â104343
å·ãå54â130122å·ãå57â85055å·å ¬å ±çãå
ç §ïŒãããã®ååç©ã䜿çšããçŸåæã«æŸåºãã
ãè²çŽ ãååéšã§åããããã§ç»åãããããæ¹
åŒã«ãããŠã¯ãéçŸåã®èµ·ããåæã§ã®ã¿è²çŽ ç»
åãåŸãããããšã«ãªããã€ãŸãé垞䜿çšããã
è¡šé¢æœåããã€ãããã²ã³åéä¹³å€ã§ã¯ããã¬å
ãåŸãããæ¬çºæã§ç€ºããããããªå éšæœååçŽ
æ¥ããžä¹³å€ã§ã¯ããžåãåŸãããšãã§ããã 以äžãå®æœäŸããããŠæ¬çºæãäŸèšŒããããæ¬
çºæã®å®æœã®æ æ§ãããã«ãã€ãŠéå®ããããã®
ã§ã¯ãªãã å®æœäŸ ïŒ ç±³åœç¹èš±ç¬¬2592250å·æ现æžã®å®æœäŸïŒã«èšèŒ
ã®æ¹æ³ã«åŸã€ãŠã³ã³ããŒãžãšã³æ³ã«ããå éšæœå
åã®å¡©æ²èåéä¹³å€ã調補ãããå¥ã«ããŒã³ã¿ã«
ãã©âïŒâïŒïŒïŒïŒïŒïŒâããªã¯ããããšãã«ïŒâ
ïŒâïŒïŒâã¯ããâïŒâãªã¯ã¿ãã·ã«ã¹ã¯ã·ã³ã€
ããã¢ããªãïŒïŒâãã©ãŸãã³40ïœãïŒïŒïŒâãž
âtertâãªã¯ãã«ãã€ããããã³ïŒïœããžãªã¯ã
ã«ãã¿ã¬ãŒã75ïœãé ¢é žãšãã«30ïœãæ··å溶解
ããã€ãœãããã«ããã¿ã¬ã³ã¹ã«ãã³é žãœãŒãã
å«ããŒã©ãã³æ°Žæº¶æ¶²ã«å ãä¹³ååæ£ããããã®å
æ£æ¶²ãäºãäžèšã®å¢æè²çŽ ïŒè²çŽ ïŒããã³ïŒïŒã«
ãã€ãŠåå å¢æããåèšä¹³å€ïŒïŒå¡©æ²èåé
0.35ã¢ã«å«æïŒã«å ããæŽã«ïŒâããããã·âïŒ
âã¡ãã«âïŒïŒïŒïŒ3aïŒïŒâããã©ã¶ã€ã³ãã³
ïŒïœãïŒïŒïŒâãžããããã·âïŒâsecâãªã¯ã¿
ãã·ã«ãã³ãŒã³ã¹ã«ãã³é žã«ãªãŠã ïŒïœãå ããŠ
ä¹³å€ã調補ããã äžèšã«ãã調補ãããä¹³å€ã«äžèšç¬¬ïŒè¡šã«ç€ºã
ãããããªæ¬çºæã«ä¿ããã«ããªå€ãªãã³ã«äžèš
ã®æ¯èŒçšã®ã«ããªå€ãã¡ã¿ããŒã«æº¶æ¶²ãšããŠå
ãããã®ä¹³å€ãã¬ãžã³ã³ãŒãããçŽæ¯æäœäžã«å¡
åžã也ç¥ããã äžèšã®å¡åžè©Šæãããããã枩床23âãçžå¯Ÿæ¹¿
床55ïŒ ã§ïŒæ¥ä¿åïŒæ¡ä»¶âïŒãšããïŒã枩床55âã
ç¡èª¿æ¹¿ã§ïŒæ¥ä¿åïŒæ¡ä»¶âïŒãšããïŒãããã³æž©
床40âãçžå¯Ÿæ¹¿åºŠ80ïŒ ã§ïŒæ¥ä¿åïŒæ¡ä»¶âïŒïŒã
ãåŸãåæ§é²å ãäžããŠããã以äžã®åŠçæ¹æ³ã«
åŸãçŸååŠçãè¡ã€ãã åŠçïŒ çºè²çŸåïŒïŒå30ç§ïŒâåæ¢ïŒ30ç§ïŒâæŒçœå®ç
ïŒïŒå30ç§ïŒâæ°ŽæŽïŒïŒå30ç§ïŒåŠç枩床ã¯ååŠç
ã¹ãããå ±ã«30âã§ãããäžèšã«ååŠç液ã®çµæ
ã瀺ããã çºè²çŸåæ¶²ïŒ çé žã«ãªãŠã 25ïœ èåã«ãªãŠã ïŒïœ ãã³ãžã«ã¢ã«ã³ãŒã« 10ïœ äºç¡«é žã«ãªãŠã 2.5ïœ ïŒâã¡ãã«ãã³ãŸããªã¢ãŸãŒã« 10mg ïŒâã¢ããâïŒâã¡ãã«ââãšãã«â
Nâ²âïŒÎ²âã¡ã¿ã³ã¹ã«ãã³ã¢ãããšãã«ïŒã¢
ããªã³ç¡«é žå¡© 4.5ïœ PHïŒæ°Žé žåã«ãªãŠã ã§èª¿æŽïŒ 12.0 æ°Žãå ããŠïŒã«ä»äžããã åæ¢æ¶²ïŒ é ¢é žãããªãŠã 6.7ïœ é ¢é ž 18.5ïœ äºç¡«é žãããªãŠã 4.5ïœ PH 4.1 æ°Žã§ïŒã«ä»äžããã æŒçœå®çæ¶²ïŒ ããªç¡«é žã¢ã³ã¢ããŠã 110ïœ äºç¡«é žæ°ŽçŽ ãããªãŠã 10ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žéã¢ã³ã¢ããŠã
60ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žïŒã¢ã³ã¢ããŠã
ïŒïœ ãã¹ã»ããªå°¿çŽ ïŒïœ PHïŒã¢ã³ã¢ãã¢æ°Žã§èª¿æŽïŒ 6.5 æ°Žã§ïŒã«ä»äžããã åŸãããçµæãäžèšç¬¬ïŒè¡šã«ç€ºãã
ãŠã¯ãäŸãã°ããã²ã³ååïŒå¥œãŸããã¯å¡©çŽ å
åïŒãã¢ã«ãã«åºïŒå¥œãŸããã¯äœçŽã¢ã«ãã«åºã
äŸãã°ã¡ãã«ããšãã«ãïœâããã«çã®ååºïŒã
ã¢ã«ã³ãã·åºïŒå¥œãŸããã¯äœçŽã¢ã«ã³ãã·åºãäŸ
ãã°ã¡ããã·åºããšããã·åºçïŒçãæããããš
ãã§ããã 以äžã«åèšäžè¬åŒã§è¡šããããæ¬çºæã«ä¿ãã
ã«ããªå€ã®ä»£è¡šçå ·äœäŸãæããããæ¬çºæã¯ã
ãã«ããéå®ããããã®ã§ã¯ãªãã ïŒäŸç€ºååç©ïŒ æ¬çºæã®äžè¬åŒã§ç€ºãããååç©ã¯ãäžè¬åŒã«
次ã®æ¹æ³ã«ããåæããããšãã§ããã ããªãã¡ãïŒâãããããšãã«ããã©ãžã³ã«ã«
ã«ãã³é žïŒãããã¯é žå¡©åç©ãŸãã¯é žç¡æ°Žç©ïŒã
åå¿ãããŠïŒâã¢ã·ã«âïŒâïŒïŒâãããããšã
ã«ïŒããã©ãžã³ãåŸããããããšã¿ããŒã«ã溶åª
ãšããŠè§ŠåªãçšããŠæ°ŽçŽ æ·»å ãè¡ããïŒâã¢ãã
èªå°äœã«éå ãããæ¬çºæã«ä¿ããã«ããªå€ã¯äž
èšã«ããåŸãããïŒâã¢ããããšãã«ããã©ãžã³
ãïŒâã¢ã·ã«âïŒâïŒïŒâããªã€ãœã·ã¢ããŒãã
ãšãã«ïŒããã©ãžã³ã«èªå°ããææã®ã»ãã«ã«ã
ãžãé¡ãšãšã¿ããŒã«æ°Žç³»ã®æº¶åªäžãå ç±éæµãã
ããšã«ãã€ãŠåæããããšãã§ããã äžèšã¢ããåºãããªã€ãœã·ã¢ããŒããžå€æãã
æ¹æ³ãšãã¯å¹Ÿã€ãã®æ¹æ³ãããããïŒïŒ1â²âããª
ã«ã«ããã«ãžã€ãããŸãŒã«ã䜿çšãããšæž©åãªæ¡
件ã§åå¿ãé²ã¿æå©ã§ãããåèšã®ã»ãã«ã«ããž
ãé¡ã¯ããã©ãžã³ãšã€ãœã·ã¢ããŒããã容æã«å
æããããšãã§ããã ãŸãæ¬çºæã«ä¿ããã«ããªå€ããåèšã«ã«ãã¢
ããããšãã«åºãŸãã¯ã¹ã«ãã¢ããããšãã«åºã
é£çµåºãšããŠæããååç©ã§ãããšãã¯ãåèšã®
ïŒâã¢ã·ã«âïŒâïŒïŒâã¢ããããšãã«ïŒããã©
ãžã³ãã¢ããå®æ¯éŠé žã¯ããªããããã¯ã¢ããã
ã³ãŒã³ã¹ã«ããã«ã¯ããªããçšããŠããããã察
å¿ããïŒâã¢ã·ã«âïŒâïŒã¢ããããšãã«ã¢ãã
ããšãã«ïŒããã©ãžã³ãšãªããæŽã«ãããã€ãœã
ãªã·ã¢ããŒãã«èªå°ããŠã»ãã«ã«ããžããšåå¿ã
ãããŠåŸãããšãã§ããããŸãä»ã®æ¹æ³ãšããŠ
ã¯ããã³ãŒã³ãžã«ã«ãã³é žïŒãã¬ãã¿ã«é žïŒçã®
ã«ã«ãã³é žã®äžæ¹ãïœâãããããšããŒã«çã§ãš
ã¹ãã«åããŠä¿è·ããŠãããæ®äœã®ã«ã«ãã³é žã
é žã¯ããªãã«èªå°ããé žã¢ãžããã¯ã«ããŠã¹
ïŒCurtiusïŒè»¢ç§»ãçµãŠã€ãœã·ã¢ããŒãã«èªå°ãã
ããªã»ãã«ã«ããžãèªå°äœãšå ã«åå¿ãããæåŸ
ã«ïŒâã¢ããããšãã«ããã©ãžããšçž®åãããã
ãšã«ãã€ãŠãåæããããšãã§ããã 次ã«æ¬çºæã«ä¿ããã«ããªå€ã®å ·äœçåææ³ã
äŸèšããã åæäŸ ïŒ ïŒäŸç€ºååç©(1)ã®åæïŒ (ã€) ïŒâãã«ãã«âïŒâïŒïŒâãããããšãã«ïŒ
ããã©ãžã³äžéäœã®åæã ïŒâãããããšãã«ããã©ãžã³19.2ïœãã®é žã
ããªãŠã 8.5ïœããšã¿ããŒã«80mlãã®é žãšãã«400
mlãã®é ž60mlã®æ··å溶液äžã§ïŒæéå ç±ãéæµã
ãããã®åŸæº¶åªãæžå§æ¿çž®ããæåºããçµæ¶ã
åãããšã¿ããŒã«ã§æŽã€ãŠä¹Ÿç¥ããããç®çç©ã®
åé13.1ïœãèç¹182ã184âã (ã) ïŒâãã«ãã«âïŒâïŒïŒâã¢ããããšãã«ïŒ
ããã©ãžã³äžéäœã®åæã ïŒâãã«ãã«âïŒâïŒïŒâãããããšãã«ïŒã
ãã©ãžã³ïŒïœããšã¿ããŒã«200mlãšé ¢é žãšãã«200
mlã®æ··å溶åªã«æžæ¿ãããã©ãžãŠã âççŽ 1.0ïœ
ãå ããŠåžžå§äžã§æ°ŽçŽ æ·»å ãããåå¿æ¶²ãé
ãã液ãæžå§äžæ¿çž®ããçæããçµæ¶ãå
ãããšã¿ããŒã«ïŒïœâãããµã³æ··å溶åªã§æŽã€ãŠ
也ç¥ããããç®çç©ã®åé3.8ïœãèç¹120ã123
âã (ã) ïœâïŒïŒâãã«ãã«ããã©ãžãããšãã«ïŒã€
ãœããªã·ã¢ããŒãäžéäœã®åæã ïŒâãã«ãã«âïŒâïŒïŒâã¢ããããšãã«ïŒã
ãã©ãžã³2.2ïœãã¢ã»ãã³200mlã«æº¶ãããâ50â
ã«å·åŽãããããã«ïŒïŒ1â²âããªã«ã«ããã«ãžã€
ãããŸãŒã«2.7ïœãã¢ã»ãã³60mlã«æº¶ããããã®
ã30åéã«æ»Žäžããã次ãã§å®€æž©ãŸã§ãã€ããæ»
ããïŒæéæ¹æããã30â以äžã§æžå§äžã溶åªã
èžçºä¹Ÿåºããæ®æ»ã«ãšãŒãã«100mlãå ãããã
ããã€ã¶ãããæžæ¿æ¶²ãéããæ°Ž150mlã§æŽæµ
ããæŽã«ãšãŒãã«50mlã§æŽæµããŠãç®çç©1.8ïœ
ãåŸããèç¹173ã177âã (ã) äŸç€ºååç©(1)ã®åæ å¡©é žã»ãã«ã«ããžã1.11ïœããšã¿ããŒã«30mlã
æ°Ž10mlã®æ··å溶液ã«æº¶ãããããªãšãã«ã¢ãã³
1.01ïœãå ããããã®æº¶æ¶²ã«çªçŽ æ°æµäžãïœâ
ïŒïŒâãã«ãã«ããã©ãžãããšãã«ïŒã€ãœããªã·
ã¢ããŒã1.8ïœãå ããïŒæéå ç±éæµãããæŸ
å·åŸãåå¿æ¶²ãéããæ°Ž20mlã§æŽãã次ãã§ãš
ã¿ããŒã«20mlã§æŽæµããç®çç©0.95ïœãåŸããè
ç¹204ã205âïŒå解ïŒã åæäŸ ïŒ ïŒäŸç€ºååç©(2)ã®åæïŒ ïŒâããšãã«ã»ãã«ã«ããžã1.51ïœããšã¿ããŒ
ã«40mlãæ°ŽïŒmlã®æ··å液ã«åæ£ããããããã«çª
çŽ æ°æµäžãïœâïŒïŒâãã«ãã«ããã©ãžãããšã
ã«ïŒã€ãœããªã·ã¢ããŒã1.95ïœãæ·»å ããïŒæé
å ç±ãéæµããããæŸå·åŸãåå¿æ¶²ãéãããš
ã¿ããŒã«30mlã§æŽæµããŠç®çç©1.40ïœãåŸããè
ç¹196ã198âïŒå解ïŒã æ¬çºæã«ä¿ããã«ããªå€ã¯ãçŽæ¥ããžããã²ã³
åéåçæå ææã®å éšæœååããã²ã³åéç²å
ãæãã氎芪æ§ã³ãã€ãå±€ãããªãå°ããšãïŒã€
ã®ä¹³å€å±€äžã«å«æãããã®ã奜ãŸãããã該乳å€
å±€ãšæ¯æäœäžåãåŽã«ãã芪氎æ§ã³ãã€ãå±€ãäŸ
ãã°ä¿è·å±€ãäžéå±€ããã€ã«ã¿ãŒå±€ããã¬ãŒã·ãš
ã³é²æ¢å±€çã«å«æãããŠãããã該ã«ããªå€ã®äœ¿
çšéã¯ãçšããããããã²ã³åéä¹³å€ã®ç¹æ§ãã«
ããªå€ã®çš®é¡ãçŸåæ¡ä»¶ã«ãã€ãŠåºãç¯å²ã«å€å
ãåŸãããå éšæœååããã²ã³åéä¹³å€å±€ãæã
ãåçæå ææãç»åé²å åŸãè¡šé¢çŸå液ã§çŸå
åŠçããŠããžç»åãåŸãããã ãã®ãã¶ããäœçš
ãäžããéã§ããã°ãããçŸååŠçåŸå åãªæ倧
æ¿åºŠïŒäŸãã°1.5以äžïŒãäžããéã§ããããšã
æãŸãããéåžžã¯ãå éšæœååããã²ã³åéïŒã¢
ã«ã«å¯Ÿããã«ããªå€ã10-6ã¢ã«ã10-2ã¢ã«çšåºŠã
奜ãŸãããæŽã«å¥œãŸããã¯10-6ã¢ã«ã10-3ã¢ã«ã®
ç¯å²ã§ãããã«ããªå€ãäžèšä¹³å€å±€ã«å«æããã
ãå Žåã®ã«ããªå€ã®æº¶å€ãšããŠã¯ãéåžžãæ°Žãšæ··
åãåŸãææ©æº¶å€ã奜ãŸãããäŸãã°ã¡ã¿ããŒ
ã«ããšã¿ããŒã«ãã¢ã»ãã³ããžã¡ãã«ããªã«ã ã¢
ãããããã©ããããã©ã³çãåç¬ãããã¯æ··å
ããŠçšããã æ¬çºæã«ããã°ãæ¬çºæã«ä¿ããã«ããªå€ã¯ã
åèšã®ããã«å éšæœååããã²ã³åéç²åãå«æ
ããä¹³å€å±€ã®ã¿ãªããã該乳å€å±€ãšé£æ¥ãã芪氎
æ§ã³ãã€ãå±€ãäŸãã°äžéå±€ãä¿è·å±€ããã€ã«ã¿
ãŒå±€ãŸãã¯ãã¬ãŒã·ãšã³é²æ¢å±€çã«å«æãããã
ããšãã§ãããäžèšã®åŠãé£æ¥å±€ã«å«æãããã«
ããªå€ã¯ãçŸååŠçæã«è©²å±€ããåŠç液ãšå ±ã«æµ
ãåºãã該局ãšçžæ¥ããå éšæœååããã²ã³åé
ç²åãå«æããä¹³å€å±€ã«æµžå ¥ããäžèšããã²ã³å
éç²åè¡šé¢ã«åžçãããŠæ¬çºæã®å¹æãçºæ®ãã
ãã®ãšæšå¯ãããããŸãæ¬çºæã«ä¿ããã«ããªå€
ã¯ïŒçš®ä»¥äžäœµçšããããšãã§ãããã䜵çšããã
å Žåã«ã¯åäžã®èŠªæ°Žæ§ã³ãã€ãå±€äžã«å«æããã
ãããšã奜ãŸããããå¥åã®å±€ã«ããããå«æã
ããããšãã§ããã ãŸããæ¬çºæã«ä¿ããã«ããªå€ãã«ã©ãŒæ¡æ£è»¢
åæ³ã«é©çšãããå Žåã«ãã€ãŠã¯ããã®ååå±€ãŸ
ãã¯ã·ãŒãäžã«æ··å ¥ããããããšãã§ããããã®
å Žåã®è©²ã«ããªå€ã®å«æéã¯åèšããã²ã³åéä¹³
å€å±€äžã«å«æããããå Žåã«æºããéã§ããã æ¬çºæã«ä¿ããã«ããªå€ã¯ãåŸæ¥å ¬ç¥ã®ã«ããª
å€ãšäœµçšããããšãã§ããã äžèšã®åŸæ¥å ¬ç¥ã®æçšãªã«ããªå€ã®å ·äœäŸã瀺
ãã°ãããã©ãžã³å¡©é žå¡©ãããšãã«ããã©ãžã³å¡©
é žå¡©ãïŒâã¡ãã«ããšãã«ããã©ãžã³å¡©é žå¡©ãïŒ
âãã«ãã«âïŒâïŒïŒâã¡ãã«ããšãã«ïŒããã©
ãžã³ãïŒâã¢ã»ãã«âïŒâããšãã«ããã©ãžã³ã
ïŒâã¢ã»ãã«âïŒâïŒïŒâã¢ã»ãã¢ããããšãã«ïŒ
ããã©ãžã³ãïŒâã¡ãã«ã¹ã«ããªãã«âïŒâããš
ãã«ããã©ãžã³ãïŒâãã³ãŸã€ã«âïŒâããšãã«
ããã©ãžã³ãïŒâã¡ãã«ã¹ã«ããªãã«âïŒâïŒïŒ
âããšãã«ã¹ã«ããªã³ã¢ããããšãã«ïŒããã©ãž
ã³ãããªã«ã ã¢ã«ãããããšãã«ããã©ãŸã³çã®
ããã©ãžã³ååç©ïŒïŒâïŒïŒâãã«ãã«ãšãã«ïŒâ
ïŒâã¡ãã«ãã³ãŸãã¢ãŸãªãŠã ãããã€ããïŒâ
ïŒïŒâãã«ãã«ãšãã«ïŒâïŒâãããã«ãã³ãŸãã¢
ãŸãªãŠã ãããã€ããïŒâïŒïŒâã¢ã»ãã«ãšãã«ïŒ
âïŒâãã³ãžã«ãã³ãŸã»ã¬ããŸãªãŠã ãããã€
ããïŒâïŒïŒâã¢ã»ãã«ãšãã«âïŒâãã³ãžã«â
ïŒâããšãã«âãã³ãŸãªããµãŸãªãŠã ãããã€
ããïŒâã¡ãã«âïŒâïŒâïŒããšãã«ããã©ãŸ
ãïŒãããã«ïŒœãã³ãŸãã¢ãŸãªãŠã ãããã€ãã
ïŒâã¡ãã«âïŒâïŒâïŒïœâããªã«ããã©ãŸãïŒ
ãããã«ïŒœãã³ãŸãã¢ãŸãªãŠã ãããã€ããïŒâ
ã¡ãã«âïŒâïŒâïŒïœâã¹ã«ããªããšãã«ããã©
ãŸãïŒãããã«ïŒœãã³ãŸãã¢ãŸãªãŠã ãããã€
ããïŒâã¡ãã«âïŒâïŒâïŒïœâã¹ã«ããªããšã
ã«ããã©ãŸãïŒãã³ãã«ïŒœãã³ãŸãã¢ãŸãªãŠã ãš
ãŒãããïŒïŒïŒâãžãããâïŒâã¡ãã«âïŒâã
ãšãã«ããªãïŒïŒïŒâïœïŒãã³ãŸãã¢ãŸãªãŠã
ãããã€ããïŒïŒïŒâãžãããâïŒâã¡ãã«âïŒ
âããšãã«ããªãïŒïŒïŒâïœïŒœâïŒâããšãã«
ãã³ãŸãªããµãŸãªãŠã ãããã€ããïŒïŒ4â²âãšã
ã¬ã³ãã¹ïŒïŒïŒïŒâãžãããâïŒâã¡ãã«ããªã
ïŒïŒïŒâïœïŒœãã³ãŸãã¢ãŸãªãŠã ãããã€ãïŒã
ïŒïŒïŒâãžãããâïŒâã¡ãã«âïŒâããšãã«ã
ãªãïŒïŒïŒâïœïŒœãã³ãŸã»ã¬ããŸãªãŠã ããã
ã€ãçã®ïŒ®â眮æ第ïŒçŽã·ã¯ãã¢ã³ã¢ããŠã å¡©ïŒ
ïŒâïŒâãšãã«ãããïŒïŒïŒïŒâïœïŒãã¢ãŸãª
ã³âïŒâã€ãªãã³ãšããªãã³ïŒœâïŒâïŒïŒâããšã
ã«ã«ã«ããŸã€ã«ïŒã¡ãã«âïŒâïŒïŒâã¹ã«ãã¢ã¢
ã€ã«ããšãã«ïŒâïŒâããªããã³ãã€ã³ãïŒâïŒïŒ
âãšãã«âïŒâãã³ãŸãã¢ãŸãªããªãã³ïŒâïŒâ
ïŒâïŒïŒâããªã«ãã«ããã©ãžãïŒããšãã«ïŒœã
ãŒããã³ãïŒâïŒâïŒïŒâããªã«ãã«ããã©ãž
ãïŒããšãã«ïŒœâããšãã«ããªå°¿çŽ ãïŒïŒïŒâã
ã¹ïŒ»ïŒâïŒïŒâããªã«ãã«ããã©ãžãïŒããšãã«ïŒœ
ããªå°¿çŽ ãªã©ãæããããã æ¬çºæã®çŽæ¥ããžããã²ã³åéåçæå ææ
ïŒä»¥äžãæ¬çºæã®æå ææãšåŒã¶ïŒã¯åæ§é²å åŸã
ã«ããªå€ã®ååšäžã«çŸååŠçããããšã«ãã€ãŠçŽ
æ¥ããžç»åã圢æããããæ¬çºæã®æå ææã®çŸ
ååŠçæ¹æ³ã¯ä»»æã®çŸååŠçæ¹æ³ãæ¡çšããã
ãã奜ãŸããã¯è¡šé¢çŸååŠçæ¹æ³ã§ããããã®è¡š
é¢çŸååŠçæ¹æ³ãšã¯ããã²ã³åé溶å€ãå®è³ªçã«
å«ãŸãªãçŸå液ã§åŠçããããšãæå³ããã æ¬çºæã«ãããŠçŸå液ãšããŠäœ¿çšããããšã®ã§
ããéåžžã®ããã²ã³åéçŸåå€ã«ã¯ããã€ããã
ãã³ã®åŠãããªããããã·ãã³ãŒã³é¡ãã¢ããã
ãšããŒã«é¡ãïŒâãã©ãŸãªãã³é¡ãã¢ã¹ã³ã«ãã³
é žãšãã®èªå°äœãã¬ãã¯ãã³é¡ãããšãã¬ã³ãžã¢
ãã³é¡çãããã¯ãã®æ··åç©ãå«ãŸãããå ·äœç
ã«ã¯ãã€ããããã³ãã¢ããããšããŒã«ãâã¡
ãã«ã¢ããããšããŒã«ãïŒâããšãã«âïŒâãã©
ãŸãªãã³ãïŒâããšãã«âïŒïŒïŒâãžã¡ãã«âïŒ
âãã©ãŸãªãã³ãïŒâããšãã«âïŒâã¡ãã«âïŒ
âããããã·ã¡ãã«âïŒâãã©ãŸãªãã³ãã¢ã¹ã³
ã«ãã³é žãïŒïŒ®âãžãšãã«âïœâããšãã¬ã³ãž
ã¢ãã³ããžãšãã«ã¢ããâïœâãã«ã€ãžã³ãïŒâ
ã¢ããâïŒâã¡ãã«ââãšãã«ââïŒÎ²âã¡
ã¿ã³ã¹ã«ããªã³ã¢ãããšãã«ïŒã¢ããªã³ãïŒâã¢
ããâïŒâã¡ãã«ââãšãã«ââïŒÎ²âãã
ããã·ãšãã«ïŒã¢ããªã³çãæãããããããã
ã®çŸåå€ã¯ãããããä¹³å€äžã«å«ãŸããŠãããé«
PH氎溶液浞挬äžã«ããã²ã³åéã«äœçšããããã
ã«ããããšãã§ããã æ¬çºæã«ãããŠäœ¿çšãããçŸå液ã¯ãæŽã«ç¹å®
ã®ã«ããªé²æ¢å€åã³çŸåæå¶å€ãå«æããããšã
ã§ãããããã¯ãããã®çŸå液添å å€ãããã²ã³
åéåçæå ææã®å±€èäžã«ä»»æã«çµã¿å ¥ããã
ãšãå¯èœã§ãããéåžžæçšãªã«ããªé²æ¢å€ã«ã¯ã
äŸãã°ïŒâã¡ãã«ãã³ãŸããªã¢ãŸãŒã«ã®ãããªã
ã³ãŸããªã¢ãŸãŒã«é¡ïŒãã³ãŸãã¢ãŸãŒã«é¡ïŒïŒâ
ããšãã«âïŒâã¡ã«ã«ããããã©ãŸãŒã«ã®ãããª
è€çŽ ç°åŒããªã³é¡ïŒè³éŠæåã³èèªæã®ã¡ã«ã«ã
ãååç©çãå«ãŸããããŸããçŸå液äžã«ã¯ãçŸ
åä¿é²å€äŸãã°ããªã¢ã«ãã¬ã³ãªããµã€ãèªå°äœ
ã第ïŒçŽã¢ã³ã¢ããŠã å¡©ååç©ãªã©ãå«æããã
ããšãã§ããã æ¬çºæã®æå ææã¯å°ãªããšãäžå±€ã®å éšæœå
åããã²ã³åéä¹³å€ãããªãã æ¬çºæã«ãããå éšæœååããã²ã³åéä¹³å€ã¯
ããã²ã³åéç²åã®å éšã«äž»ãšããŠæœåã圢æ
ããæå æ žã®å€§éšåãç²åã®å éšã«æããããã²
ã³åéç²åãæããä¹³å€ã§ãã€ãŠãä»»æã®ããã²
ã³åéãäŸãã°èåéãå¡©åéãå¡©èåéãæ²è
åéãå¡©æ²èåéçãå å«ãããã ç¹ã«å¥œãŸããã¯ãã®ä¹³å€ã¯éæãªæ¯æäœã«å¡åž
ããè©Šæã®äžéšãçŽïŒç§ãŸã§ã®ããå®ããããæ
éã«ããã€ãŠå 匷床ã¹ã±ãŒã«ã«é²å ãå®è³ªçã«ã
ãã²ã³åé溶å€ãå«æããªãç²åã®è¡šé¢åã®ã¿ã
çŸåããäžèšã®è¡šé¢çŸå液ãçšããŠ20âã§ïŒå
éçŸåããå Žåã«ãåäžã®ä¹³å€è©Šæã®å¥ã®äžéšã
åããé²å ããç²åã®å éšã®åãçŸåããäžèšã®
å éšçŸå液ã§20âã§ïŒåéçŸåããå Žåã«åŸã
ããæ倧æ¿åºŠã®1/5ãã倧ãããªãæ倧æ¿åºŠã瀺
ããã®ã§ããã奜ãŸããã¯ãè¡šé¢çŸå液ãçšã
ãŠåŸãããæ倧æ¿åºŠã¯å éšçŸå液ã§åŸãããæ
倧æ¿åºŠã®1/10ãã倧ãããªããã®ã§ããã ïŒè¡šé¢çŸåæ¶²ïŒ¡ïŒ ã¡ããŒã« 2.5ïœ ïŒ¬âã¢ã¹ã³ã«ãã³é ž 10ïœ NaBO2ã»4H2O 35ïœ KBr ïŒïœ æ°Žãå ããŠ ïŒ ïŒå éšçŸåæ¶²ïŒ¢ïŒ ã¡ããŒã« 2.0ïœ äºç¡«é žãœãŒãïŒç¡æ°ŽïŒ 90.0ïœ ãã€ããããã³ 8.0ïœ çé žãœãŒããŒæ°Žå¡© 52.5ïœ KBr 5.0ïœ KI 0.5ïœ æ°Žãå ããŠ ïŒ ãŸããæ¬çºæã«ä¿ãå éšæœååããã²ã³åéä¹³
å€ã¯ãçš®ã ã®æ¹æ³ã§èª¿è£œããããã®ãå«ãŸããã
äŸãã°ç±³åœç¹èš±ç¬¬2592250å·ã«èšèŒãããŠããã³
ã³ããŒãžãšã³åããã²ã³åéä¹³å€ããŸãã¯ç±³åœç¹
蚱第3206316å·ãå第3317322å·ããã³å第
3567778å·ã«èšèŒãããŠããå éšååŠå¢æããã
ããã²ã³åéç²åãæããããã²ã³åéä¹³å€ããŸ
ãã¯ç±³åœç¹èš±ç¬¬3271157å·ãå第3447927å·ããã³
å第3331291å·ã«èšèŒãããŠããå€äŸ¡éå±ã€ãªã³
ãå èµããŠããããã²ã³åéç²åãæããããã²
ã³åéä¹³å€ããŸãã¯ç±³åœç¹èš±ç¬¬3761276å·ã«èšèŒ
ãããŠããããŒãå€ãå«æããããã²ã³åéç²å
ã®ç²åè¡šé¢ã匱ãååŠå¢æããããã²ã³åéä¹³
å€ããŸãã¯ç¹éæ50â8524å·ãå50â38525å·ã
ãã³å53â2408å·ã«èšèŒãããŠããç©å±€æ§é ãæ
ããç²åãããªãããã²ã³åéä¹³å€ããã®ä»ç¹é
æ52â156614å·ããã³ç¹éæ55â127549å·ã«èšèŒ
ãããŠããããã²ã³åéä¹³å€ãªã©ã§ããã æŽã«ãæ¬çºæã«ä¿ãå éšæœååããã²ã³åéä¹³
å€ã«ã¯ãéåžžçšããããå®å®å€ãäŸãã°ã¢ã¶ã€ã³
ãã³ç°ãæã€ååç©ããã³ã¡ã«ã«ããåºãæãã
å«çªçŽ ãããç°ååç©ïŒä»£è¡šçãªãã®ãšããŠãã
ããïŒâããããã·âïŒâã¡ãã«âïŒïŒïŒïŒ3aïŒ
ïŒâããã©ã¶ã€ã³ãã³ããã³ïŒâããšãã«âïŒâ
ã¡ã«ã«ããããã©ãŸãŒã«ãæããããïŒçããã
ã²ã³åéïŒã¢ã«ã«å¯ŸãïŒmgã10ïœå«æãããããš
ã«ãããããäœãæå°æ¿åºŠãæã€ãããå®å®ãªçµ
æãäžããããšãã§ããã ãã®ä»æ¬çºæã«ãããŠãã«ããªé²æ¢å€ãŸãã¯å®
å®å€ãšããŠãäŸãã°æ°Žéååç©ãããªã¢ãŸãŒã«ç³»
ååç©ãã¢ã¶ã€ã³ãã³ç³»ååç©ããã³ãŸãã¢ãŸãª
ãŠã ç³»ååç©ãäºéååç©çã䜿çšãåŸãã æ¬çºæã«ä¿ãå éšæœååããã²ã³åéä¹³å€ã«
ã¯ãåçš®ã®åççšæ·»å å€ãå ããããšã¯ä»»æã§ã
ãã äŸãã°ãæ¬çºæã«ãããŠäœ¿çšãåŸãå åŠå¢æå€
ã«ã¯ãã·ã¢ãã³é¡ãã¡ãã·ã¢ã³é¡ãäžæ žãŸãã¯å
æ žã¡ãã·ã¢ãã³é¡ãäžæ žãŸãã¯åæ žã·ã¢ãã³é¡ã
ã¹ããªã«é¡ããã¢ããŒã©ã·ã¢ãã³é¡ãããã·ã¢ã
ã³é¡ããªããœããŒã«é¡ããã³ãããªããœããŒã«é¡
ãå«ãŸãããããã®å åŠå¢æå€ã¯å«çªçŽ è€çŽ ç°æ ž
ãšããŠã®æ§é ã®äžéšã«ãã¢ãŸãªã³ããã¢ãŸãŒã«ç
ã®å¡©åºæ§åºãŸãã¯ããŒããã³ãããªããã³ãã€
ã³ããªããµãŸãªãžã³ãžãªã³ããã«ãããŒã«é žãã
ãªãã«ãããŒã«é žããã©ãŸãã³çã®æ žãå«ããã®
ã奜ãŸããããããæ žã¯ã¢ã«ãã«ãããããã·ã¢
ã«ãã«ãã¹ã«ãã¢ã«ãã«ãã«ã«ããã·ã¢ã«ãã«ã
ããã²ã³ãããšãã«ãã·ã¢ããã¢ã«ã³ãã·çœ®æã
ãããšãã§ãããŸãççŽ ç°ãŸãã¯è€çŽ ç°ãšçž®åã
ãããšã¯ä»»æã§ããã æ¬çºæã«ä¿ãå éšæœååããã²ã³åéä¹³å€ã¯è¶
è²å¢æããããšãã§ãããè¶ è²å¢æã®æ¹æ³ã«ã€ã
ãŠã¯ãäŸãã°ãè¶ è²å¢æã®æ©æ§ã®ç·èª¬ãã¬ããŠ
ãŒã»ãªãã»ã¹ãŒããŒã»ã³ã·ã¿ã€ãŒãŒã·ãšã³
ïŒReview of SupersensitizationïŒããªãã°ã©ã
ã€ãã¯ã»ãµã€ãšã³ã¹ã»ã¢ã³ãã»ãšã³ãžãã€ãªã³ã°
ïŒPhotographic Science and EngineeringïŒ
Vol.18ã第4418é ïŒ1974ïŒå¹Žã«èšèŒãããŠããã ãã®ä»æ¬çºæã«ãããŠãç®çã«å¿ããŠçšããã
ãæ·»å å€ã¯ã湿最å€ãšããŠã¯ãäŸãã°ããžããã
ãã·ã¢ã«ã«ã³çãæããããããã«èç©æ§æ¹è¯å€
ãšããŠã¯ãäŸãã°ãã¢ã«ãã«ã¢ã¯ãªã¬ãŒãããã
ã¯ã¢ã«ãã«ã¡ã¿ã¯ãªã¬ãŒããšã¢ã¯ãªã«é žãããã¯
ã¡ã¿ã¢ã¯ãªã«é žãšã®å ±éåäœãã¹ãã¬ã³âãã¬ã€
ã³é žå ±éåäœãã¹ãã¬ã³ç¡æ°Žãã¬ã€ã³é žããŒãã¢
ã«ãã«ãšã¹ãã«å ±éåäœçã®ä¹³åéåã«ãã€ãŠåŸ
ãããæ°Žåæ£æ§ã®åŸ®ç²åç¶é«ååç©è³ªçãé©åœã§
ãããå¡åžå©å€ãšããŠã¯ãäŸãã°ããµããã³ãã
ãªãšãã¬ã³ã°ãªã³ãŒã«ã©ãŠãªã«ãšãŒãã«çãå«ãŸ
ããããã®ä»åççšæ·»å å€ãšããŠããŒã©ãã³å¯å¡
å€ãçé¢æŽ»æ§å€ã玫å€ç·åžåå€ãPH調æŽå€ãé žå
é²æ¢å€ã垯é»é²æ¢å€ãå¢ç²å€ãç²ç¶æ§åäžå€ãæ
æãã¢ã«ãã³ããå¢çœå€ãçŸåé床調ç¯å€ããã
ãå€çã䜿çšããããšã¯ä»»æã§ããã äžè¿°ã®åŠã調補ãããããã²ã³åéä¹³å€ã¯ãå¿
èŠã«å¿ããŠäžåŒå±€ããã¬ãŒã·ãšã³é²æ¢å±€ããã€ã«
ã¿ãŒå±€çãä»ããŠæ¯æäœã«å¡åžããçŽæ¥ããžãã
ã²ã³åéåçæå ææãåŸãã æ¬çºæã®æå ææã¯ãã«ã©ãŒçšãšããŠçšããã
ãšãã§ãããã®å Žåã«ã¯åèšä¹³å€äžã«ã·ã¢ã³ãã
ãŒã³ã¿ããã³ã€ãšããŒã®è²çŽ 圢æã«ãã©ãŒãŸãã¯
DIRååç©çã®è²çŽ ç»å圢æç©è³ªãå«ãŸããããš
ã奜ãŸãããäžèšã€ãšããŒè²çŽ 圢æã«ãã©ãŒãšã
ãŠã¯ããã³ãŸã€ã«ã¢ã»ãã¢ããªãåããããã€ã«
ã¢ã»ãã¢ããªãåæãã¯ã«ãããªã³ã°äœã®ççŽ å
åãã«ãããªã³ã°åå¿æã«é¢èª¬ããããšãã§ãã
眮æåºãããããã¹ããªãããªãåºã§çœ®æãããŠ
ããïŒåœéåã€ãšããŒã«ãã©ãŒçãæçšã§ããã
ãŸãããŒã³ã¿è²çŽ 圢æã«ãã©ãŒãšããŠã¯ãã©ãŸã
ã³ç³»ããã©ãŸãããªã¢ãŸãŒã«ç³»ããã©ãŸãªããã³
ãã€ãããŸãŒã«ç³»ãã€ã³ããŸãã³ç³»æãã¯ã¹ããª
ãããªãåºãæããïŒåœéåããŒã³ã¿ã«ãã©ãŒã
æçšã§ãããæŽã«ã·ã¢ã³è²çŽ 圢æã«ãã©ãŒãšããŠ
ã¯ããšããŒã«ç³»ãããããŒã«ç³»ããã©ãŸãããŸã
ã³ç³»ãæãã¯ã¹ããªãããªãåºãæããïŒåœéå
ã·ã¢ã³ã«ãã©ãŒãæçšã§ããã æ¬çºæã«ãããŠã¯ãè²çŽ ç»åã®çæ³¢é·ã®æŽ»æ§å
ç·ã«ãã耪è²ãé²æ¢ãããã玫å€ç·åžåå€ãäŸã
ã°ãã¢ãŸãªãã³ããã³ãŸããªã¢ãŸãŒã«ãã¢ã¯ãªã
ãããªã«ããã³ãŸããšãã³ç³»ååç©ãçšããããš
ã¯æçšã§ãããç¹ã«ãããã³ã³PSãå320ãå
326ãå327ãå328ïŒããããããã¬ã€ã®ãŒç€Ÿè£œïŒ
ã®åçšãããã¯äœµçšãæå©ã§ããã æ¬çºæã®æå ææã®æ¯æäœãšããŠã¯ä»»æã®ãã®
ãçšãããããã代衚çãªæ¯æäœãšããŠã¯ãå¿ èŠ
ã«å¿ããŠäžåŒå å·¥ããããªãšãã¬ã³ãã¬ãã¿ã¬ãŒ
ããã€ã«ã ãããªã«ãŒãããŒããã€ã«ã ãããªã¹
ãã¬ã³ãã€ã«ã ãããªãããã¬ã³ãã€ã«ã ãã»ã«
ããŒãºã¢ã»ããŒããã€ã«ã ãã¬ã©ã¹ããã©ã€ã¿
çŽãããªãšãã¬ã³ã©ãããŒãçŽçãå«ãŸããã æ¬çºæã®æå ææã«ã¯ãŒã©ãã³ã®ä»ã«ç®çã«å¿
ããŠé©åœãªãŒã©ãã³èªå°äœãå«ãŸããããšãã§ã
ãããã®é©åœãªãŒã©ãã³èªå°äœãšããŠã¯ãäŸãã°
ã¢ã·ã«åãŒã©ãã³ãã°ã¢ããžã«åãŒã©ãã³ãã«ã«
ããã«åãŒã©ãã³ãã·ã¢ããšã¿ããŒã«åãŒã©ã
ã³ããšã¹ãã«åãŒã©ãã³çãæããããšãã§ã
ãã ãŸããæ¬çºæã«ãããŠã¯ãèªåã«å¿ããŠä»ã®èŠª
æ°Žæ§ãã€ã³ããŒãå«ãŸããããšãã§ãããã®é©åœ
ãªãã€ã³ããŒãšããŠã¯ãŒã©ãã³ã®ã»ããã³ãã€ã
ç¶ã¢ã«ããã³ãå¯å€©ãã¢ã©ãã€ãŽã ãããã¹ãã©
ã³ãã¢ã«ã®ã³é žãã¢ã»ãã«å«æ10ã20ïŒ ã«ãŸã§å
æ°Žå解ãããã»ã«ããŒãºã¢ã»ããŒãã®åŠãã»ã«ã
ãŒãºèªå°äœãããªã¢ã¯ãªã«ã¢ãããã€ããåããª
ã¢ã¯ãªã«ã¢ãããã«ãŒã€ã³ãããã«ã¢ã«ã³ãŒã«â
ããã«ã¢ããã¢ã»ããŒãã³ããªããŒã®åŠããŠã¬ã¿
ã³ã«ã«ãã³é žåºãŸãã¯ãã·ã¢ãã¢ã»ãã«åºãå«ã
ããã«ã¢ã«ã³ãŒã«ããªããŒãããªããã«ã¢ã«ã³ãŒ
ã«ãããªããã«ãããªãã³ãå æ°Žå解ããªããã«
ã¢ã»ããŒããèçœè³ªãŸãã¯é£œåã¢ã·ã«åèçœè³ªãš
ããã«åºãæããã¢ãããŒãšã®éåã§åŸãããã
ãªããŒãããªããã«ããªãžã³ãããªããã«ã¢ã
ã³ãããªã¢ãããšãã«ã¡ã¿ã¢ã¯ãªã¬ãŒããããªãš
ãã¬ã³ã¢ãã³çãå«ãŸããä¹³å€å±€ãããã¯äžé
å±€ãä¿è·å±€ããã€ã«ã¿ãŒå±€ãè£åŒå±€çã®ããã²ã³
åéåçæå æææ§æå±€ã«ç®çã«å¿ããŠæ·»å ãã
ããšãã§ãããããã«äžèšèŠªæ°Žæ§ãã€ã³ããŒã«ã¯
ç®çã«å¿ããŠé©åœãªå¯å¡æ§ã最æ»å€çãå«æãã
ããããšãã§ããã ãŸããæ¬çºæã«ä¿ãäžèšæ§æå±€ã¯ä»»æã®é©åœãª
硬èå€ã§ç¡¬åããããããšãã§ããããããã®ç¡¬
èå€ãšããŠã¯ãã¯ãã å¡©ããžã«ã³ããŠã å¡©ãããª
ã«ã ã¢ã«ããããã ã³ããã²ã³é žã®åŠãã¢ã«ãã
ãç³»ãããããªã¢ãžã³ç³»ãããªãšããã·ååç©ã
ãšãã¬ã³ã€ãã³ç³»ãããã«ã¹ã«ããªã³ç³»ãã¢ã¯ãª
ãã€ã«ç³»ç¡¬èå€çãæããããã ãŸããæ¬çºæã®æå ææã¯ãæ¯æäœäžã«ä¹³å€
å±€ããã€ã«ã¿ãŒå±€ãäžéå±€ãä¿è·å±€ãäžåŒå±€ãè£
åŒå±€ããã¬ãŒã·ãšã³é²æ¢å±€çã®çš®ã ã®åçæ§æå±€
ãå€æ°èšçœ®ãããšãå¯èœã§ããã æ¬çºæã®æå ææã¯ãåèšã®ã«ã©ãŒçšã®ã»ãã
çœé»äžè¬çšãã¬ã€çšãåœã«ã©ãŒçšãå°å·çšãèµ€
å€çšããã€ã¯ãçšãéè²çŽ æŒçœçšãã«ã©ãŒæ¡æ£è»¢
ååççšçãçš®ã ã®çšéã«é©çšããããšãã§ã
ãã äžã§ãæ¡æ£è»¢ååççšãšããŠã¯ãDRRååç©
ãçšããæ¹åŒã®ãã®ã«ç¹ã«æå¹ã§ããã該DRR
ååç©ïŒè²çŽ æŸåºæ§ã¬ããã¯ã¹ååç©ãDye
Releasing Redox CompoundïŒãšã¯ãäŸãã°ã
ã©ã¹ãä»ã®ããšããŒã«ïŒåã¯ããããŒã«ïŒãªã«ã
åã¯ãã©äœã«ã¹ã«ãã³ã¢ãããä»ããŠè²çŽ ãçµå
ããããã®ããããã¯ã€ã³ããŒã«ã®ïŒäœã«ã¹ã«ã
ã³ã¢ãããä»ããŠè²çŽ ãçµåããããã®çã§ãã€
ãŠããããã¯çŸåæã«ããšããã³èªå°äœã®é žåäœ
ãšåå¿ããŠãã¯ãã¹é žåãåããã€ãã§å æ°Žå解
ãããŠæ¡æ£æ§ã®è²çŽ ãæŸåºããæ§è³ªãæããåå
ç©ãèšããïŒç¹éæ48â33826å·ãå51â104343
å·ãå54â130122å·ãå57â85055å·å ¬å ±çãå
ç §ïŒãããã®ååç©ã䜿çšããçŸåæã«æŸåºãã
ãè²çŽ ãååéšã§åããããã§ç»åãããããæ¹
åŒã«ãããŠã¯ãéçŸåã®èµ·ããåæã§ã®ã¿è²çŽ ç»
åãåŸãããããšã«ãªããã€ãŸãé垞䜿çšããã
è¡šé¢æœåããã€ãããã²ã³åéä¹³å€ã§ã¯ããã¬å
ãåŸãããæ¬çºæã§ç€ºããããããªå éšæœååçŽ
æ¥ããžä¹³å€ã§ã¯ããžåãåŸãããšãã§ããã 以äžãå®æœäŸããããŠæ¬çºæãäŸèšŒããããæ¬
çºæã®å®æœã®æ æ§ãããã«ãã€ãŠéå®ããããã®
ã§ã¯ãªãã å®æœäŸ ïŒ ç±³åœç¹èš±ç¬¬2592250å·æ现æžã®å®æœäŸïŒã«èšèŒ
ã®æ¹æ³ã«åŸã€ãŠã³ã³ããŒãžãšã³æ³ã«ããå éšæœå
åã®å¡©æ²èåéä¹³å€ã調補ãããå¥ã«ããŒã³ã¿ã«
ãã©âïŒâïŒïŒïŒïŒïŒïŒâããªã¯ããããšãã«ïŒâ
ïŒâïŒïŒâã¯ããâïŒâãªã¯ã¿ãã·ã«ã¹ã¯ã·ã³ã€
ããã¢ããªãïŒïŒâãã©ãŸãã³40ïœãïŒïŒïŒâãž
âtertâãªã¯ãã«ãã€ããããã³ïŒïœããžãªã¯ã
ã«ãã¿ã¬ãŒã75ïœãé ¢é žãšãã«30ïœãæ··å溶解
ããã€ãœãããã«ããã¿ã¬ã³ã¹ã«ãã³é žãœãŒãã
å«ããŒã©ãã³æ°Žæº¶æ¶²ã«å ãä¹³ååæ£ããããã®å
æ£æ¶²ãäºãäžèšã®å¢æè²çŽ ïŒè²çŽ ïŒããã³ïŒïŒã«
ãã€ãŠåå å¢æããåèšä¹³å€ïŒïŒå¡©æ²èåé
0.35ã¢ã«å«æïŒã«å ããæŽã«ïŒâããããã·âïŒ
âã¡ãã«âïŒïŒïŒïŒ3aïŒïŒâããã©ã¶ã€ã³ãã³
ïŒïœãïŒïŒïŒâãžããããã·âïŒâsecâãªã¯ã¿
ãã·ã«ãã³ãŒã³ã¹ã«ãã³é žã«ãªãŠã ïŒïœãå ããŠ
ä¹³å€ã調補ããã äžèšã«ãã調補ãããä¹³å€ã«äžèšç¬¬ïŒè¡šã«ç€ºã
ãããããªæ¬çºæã«ä¿ããã«ããªå€ãªãã³ã«äžèš
ã®æ¯èŒçšã®ã«ããªå€ãã¡ã¿ããŒã«æº¶æ¶²ãšããŠå
ãããã®ä¹³å€ãã¬ãžã³ã³ãŒãããçŽæ¯æäœäžã«å¡
åžã也ç¥ããã äžèšã®å¡åžè©Šæãããããã枩床23âãçžå¯Ÿæ¹¿
床55ïŒ ã§ïŒæ¥ä¿åïŒæ¡ä»¶âïŒãšããïŒã枩床55âã
ç¡èª¿æ¹¿ã§ïŒæ¥ä¿åïŒæ¡ä»¶âïŒãšããïŒãããã³æž©
床40âãçžå¯Ÿæ¹¿åºŠ80ïŒ ã§ïŒæ¥ä¿åïŒæ¡ä»¶âïŒïŒã
ãåŸãåæ§é²å ãäžããŠããã以äžã®åŠçæ¹æ³ã«
åŸãçŸååŠçãè¡ã€ãã åŠçïŒ çºè²çŸåïŒïŒå30ç§ïŒâåæ¢ïŒ30ç§ïŒâæŒçœå®ç
ïŒïŒå30ç§ïŒâæ°ŽæŽïŒïŒå30ç§ïŒåŠç枩床ã¯ååŠç
ã¹ãããå ±ã«30âã§ãããäžèšã«ååŠç液ã®çµæ
ã瀺ããã çºè²çŸåæ¶²ïŒ çé žã«ãªãŠã 25ïœ èåã«ãªãŠã ïŒïœ ãã³ãžã«ã¢ã«ã³ãŒã« 10ïœ äºç¡«é žã«ãªãŠã 2.5ïœ ïŒâã¡ãã«ãã³ãŸããªã¢ãŸãŒã« 10mg ïŒâã¢ããâïŒâã¡ãã«ââãšãã«â
Nâ²âïŒÎ²âã¡ã¿ã³ã¹ã«ãã³ã¢ãããšãã«ïŒã¢
ããªã³ç¡«é žå¡© 4.5ïœ PHïŒæ°Žé žåã«ãªãŠã ã§èª¿æŽïŒ 12.0 æ°Žãå ããŠïŒã«ä»äžããã åæ¢æ¶²ïŒ é ¢é žãããªãŠã 6.7ïœ é ¢é ž 18.5ïœ äºç¡«é žãããªãŠã 4.5ïœ PH 4.1 æ°Žã§ïŒã«ä»äžããã æŒçœå®çæ¶²ïŒ ããªç¡«é žã¢ã³ã¢ããŠã 110ïœ äºç¡«é žæ°ŽçŽ ãããªãŠã 10ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žéã¢ã³ã¢ããŠã
60ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žïŒã¢ã³ã¢ããŠã
ïŒïœ ãã¹ã»ããªå°¿çŽ ïŒïœ PHïŒã¢ã³ã¢ãã¢æ°Žã§èª¿æŽïŒ 6.5 æ°Žã§ïŒã«ä»äžããã åŸãããçµæãäžèšç¬¬ïŒè¡šã«ç€ºãã
ãè¡šã
ãè¡šã
äžèšè¡šã«ãããŠ
γ1ïŒç¹æ§æ²ç·äžã®æ¿åºŠ0.5ããã³1.5ã®ïŒç¹ãçµã¶
çŽç·ã®åŸæè§ã®æ£æ¥å€ã§çŽç·éšÎ³ãè¡šãããŠã
ãã γ2ïŒæå°æ¿åºŠïŒ0.05ããã³æå°æ¿åºŠïŒ0.35ã®ïŒç¹
ãçµã¶çŽç·ã®åŸæé¢ã®æ£æ¥å€ã§ç¹æ§æ²ç·äžã®è
éšÎ³ãè¡šãããŠããã äžèšè¡šã瀺ãããã«æ¬çºæã®ã«ããªå€ãçšãã
è©Šæã§ã¯è¯å¥œãªããžç»åãåŸããããŸãé«æž©ãé«
湿ã«ãããä¿åæ¡ä»¶äžã«ãããŠãåªããå®å®æ§ã
瀺ãããšãããã€ããããªãã¡ãæ¯èŒçšã«ããªå€
âããã³ïŒ¢ãçšããæ¬çºæå€ã®è©Šæã§ã¯é«æž©ä¿
åïŒæ¡ä»¶âïŒïŒã«éããŠæå°æ¿åºŠã®å¢å ãèãã
ãããŸãé«æ¹¿ä¿åïŒæ¡ä»¶âïŒïŒã®å Žåã«ã¯æ倧æ¿
床ã®äœäžãèãããèµ·ãããŸãæ¯èŒçšã«ããªå€â
ãçšããå Žåã«ã¯ç¹æ§æ²ç·ã®èéšã®é調ïŒÎ³2ïŒ
ãè»èª¿ã§ãããé«æž©ãé«æ¹¿äžã§ä¿åãããšãã¯æŽ
ã«è»èª¿åãèããã足åããæªããªã€ãŠãããäž
æ¹ãæ¬çºæã«ããè©Šæã¯ãäžèšã®ããã«ä¿åå®å®
æ§ã«åªããããã足åããããé®®æãªç»åãåŸã
ããšãã§ããã å®æœäŸ ïŒ äžéæåããããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããã€
ã«ã æ¯æäœäžã«ãäžèšã®å±€ãé 次å¡åžããŠæ¡æ£è»¢
åæ³çšæå ã·ãŒããäœè£œããã (1) äžèšããŒã³ã¿è²çŽ ç»å圢æååç©ãå«æãã
ãŒã©ãã³å±€ã (2) ç·ææ§å éšæœååçŽæ¥ããžèåéä¹³å€å±€ã ç±³åœç¹èš±ç¬¬3761276å·ã®å®æœäŸïŒã«èšèŒããã
ä¹³å€ïŒ£ãšåæ§ã®æ¹æ³ã§èª¿è£œããã¹ãã¯ãã«å¢æã
ããå éšæœååä¹³å€ã«ïŒïŒïŒâãžããããã·âïŒ
âsecâãªã¯ã¿ãã·ã«ãã³ãŒã³ã¹ã«ãã³é žã«ãªãŠ
ã ããã³äžèšç¬¬ïŒè¡šã«ç€ºããæ¬çºæã«ä¿ããã«ã
ãªå€ïŒäŸç€ºååç©ïŒïŒãæ·»å ãå«æããããå±€ã (3) ãŒã©ãã³ä¿è·å±€ 次ãã§ãäžèšã®æå ã·ãŒãã®å±€ïŒã«æ·»å ããã«
ããªå€ãå€ããŠãäŸç€ºååç©(1)ã®ä»£ãã«äŸç€ºåå
ç©(2)ãçšãããŸãæ¯èŒçšã«ããªå€ãšããŠåèšæ¯èŒ
çšã«ããªå€âããã³äžèšã®æ¯èŒçšã«ããªå€â
ãçšãããã以å€ã¯äžèšå±€ïŒã®çµæãšåããã®ã
䜿çšããŠä¹³å€ã調補ããåèšæå ã·ãŒããšåæ§ã«
æ¯æäœäžã«ïŒå±€å¡åžããŠè©Šæãäœè£œããã åŒç¶ããŠäžéæãªçŽæ¯æäœäžã«ãäžèšã®å±€ãé
次å¡åžããããŠè²çŽ ç»åååã·ãŒããäœè£œããã (1) ã¹ãã¬ã³ãšïŒ®ïŒïŒ®âãžã¡ãã«ââãã³ãžã«
ââïœâïŒã¡ã¿ã¯ãã€ã«ã¢ããããšãã«ïŒã¡
ãã«ã¢ã³ã¢ããŠã ã¯ããªããšãžããã«ãã³ãŒã³
ã®å ±éåäœããŒã©ãã³ããã³ïŒâããšãã«âïŒ
âããããã·ã¡ãã«âïŒâã¡ãã«âïŒâãã©ãŸ
ãªãžãã³ãããªãååå±€ (2) 玫å€ç·åžåå€ãå«æãããŒã©ãã³äžéå±€ (3) ãŒã©ãã³ä¿è·å±€ äžèšã«ãã調補ãããåæå ã·ãŒãã«åæ§é²å
ãäžããäžèšçµæã®ã¢ã¯ãããŒã¿æº¶æ¶²äžã«15ç§é
浞挬ãã次ã«äžå¯Ÿã®å å§ããŒã©ã®éãéããŠäžèš
ã®ååã·ãŒããšããããéãåãããåŠçã¯18
âã24âããã³33âã®ïŒæ®µéã§è¡ã€ãã ïŒã¢ã¯ãããŒã¿æº¶æ¶²çµæïŒ æ°Žé žåã«ãªãŠã 56.2ïœ ïŒâã¡ãã«ãã³ãŸããªã¢ãŸãŒã« 7.2ïœ 11âã¢ãããŠã³ãã³ã«ã³é ž 2.0ïœ èåã«ãªãŠã 2.0ïœ æ°Žã§ïŒã«ä»äžããã äžèšã¢ã¯ãããŒã¿æº¶æ¶²ã«ããåŠçãïŒåéç¶ã
ãåŸãæå ã·ãŒããšååã·ãŒããšãå¥é¢ãããšã
ãååå±€ã«ããŒã³ã¿è²çŽ ç»åãåŸããããäžèšç¬¬
ïŒè¡šã«åŸãããè²åã®æ倧æ¿åºŠãšæå°æ¿åºŠãšã瀺
ãã
çŽç·ã®åŸæè§ã®æ£æ¥å€ã§çŽç·éšÎ³ãè¡šãããŠã
ãã γ2ïŒæå°æ¿åºŠïŒ0.05ããã³æå°æ¿åºŠïŒ0.35ã®ïŒç¹
ãçµã¶çŽç·ã®åŸæé¢ã®æ£æ¥å€ã§ç¹æ§æ²ç·äžã®è
éšÎ³ãè¡šãããŠããã äžèšè¡šã瀺ãããã«æ¬çºæã®ã«ããªå€ãçšãã
è©Šæã§ã¯è¯å¥œãªããžç»åãåŸããããŸãé«æž©ãé«
湿ã«ãããä¿åæ¡ä»¶äžã«ãããŠãåªããå®å®æ§ã
瀺ãããšãããã€ããããªãã¡ãæ¯èŒçšã«ããªå€
âããã³ïŒ¢ãçšããæ¬çºæå€ã®è©Šæã§ã¯é«æž©ä¿
åïŒæ¡ä»¶âïŒïŒã«éããŠæå°æ¿åºŠã®å¢å ãèãã
ãããŸãé«æ¹¿ä¿åïŒæ¡ä»¶âïŒïŒã®å Žåã«ã¯æ倧æ¿
床ã®äœäžãèãããèµ·ãããŸãæ¯èŒçšã«ããªå€â
ãçšããå Žåã«ã¯ç¹æ§æ²ç·ã®èéšã®é調ïŒÎ³2ïŒ
ãè»èª¿ã§ãããé«æž©ãé«æ¹¿äžã§ä¿åãããšãã¯æŽ
ã«è»èª¿åãèããã足åããæªããªã€ãŠãããäž
æ¹ãæ¬çºæã«ããè©Šæã¯ãäžèšã®ããã«ä¿åå®å®
æ§ã«åªããããã足åããããé®®æãªç»åãåŸã
ããšãã§ããã å®æœäŸ ïŒ äžéæåããããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããã€
ã«ã æ¯æäœäžã«ãäžèšã®å±€ãé 次å¡åžããŠæ¡æ£è»¢
åæ³çšæå ã·ãŒããäœè£œããã (1) äžèšããŒã³ã¿è²çŽ ç»å圢æååç©ãå«æãã
ãŒã©ãã³å±€ã (2) ç·ææ§å éšæœååçŽæ¥ããžèåéä¹³å€å±€ã ç±³åœç¹èš±ç¬¬3761276å·ã®å®æœäŸïŒã«èšèŒããã
ä¹³å€ïŒ£ãšåæ§ã®æ¹æ³ã§èª¿è£œããã¹ãã¯ãã«å¢æã
ããå éšæœååä¹³å€ã«ïŒïŒïŒâãžããããã·âïŒ
âsecâãªã¯ã¿ãã·ã«ãã³ãŒã³ã¹ã«ãã³é žã«ãªãŠ
ã ããã³äžèšç¬¬ïŒè¡šã«ç€ºããæ¬çºæã«ä¿ããã«ã
ãªå€ïŒäŸç€ºååç©ïŒïŒãæ·»å ãå«æããããå±€ã (3) ãŒã©ãã³ä¿è·å±€ 次ãã§ãäžèšã®æå ã·ãŒãã®å±€ïŒã«æ·»å ããã«
ããªå€ãå€ããŠãäŸç€ºååç©(1)ã®ä»£ãã«äŸç€ºåå
ç©(2)ãçšãããŸãæ¯èŒçšã«ããªå€ãšããŠåèšæ¯èŒ
çšã«ããªå€âããã³äžèšã®æ¯èŒçšã«ããªå€â
ãçšãããã以å€ã¯äžèšå±€ïŒã®çµæãšåããã®ã
䜿çšããŠä¹³å€ã調補ããåèšæå ã·ãŒããšåæ§ã«
æ¯æäœäžã«ïŒå±€å¡åžããŠè©Šæãäœè£œããã åŒç¶ããŠäžéæãªçŽæ¯æäœäžã«ãäžèšã®å±€ãé
次å¡åžããããŠè²çŽ ç»åååã·ãŒããäœè£œããã (1) ã¹ãã¬ã³ãšïŒ®ïŒïŒ®âãžã¡ãã«ââãã³ãžã«
ââïœâïŒã¡ã¿ã¯ãã€ã«ã¢ããããšãã«ïŒã¡
ãã«ã¢ã³ã¢ããŠã ã¯ããªããšãžããã«ãã³ãŒã³
ã®å ±éåäœããŒã©ãã³ããã³ïŒâããšãã«âïŒ
âããããã·ã¡ãã«âïŒâã¡ãã«âïŒâãã©ãŸ
ãªãžãã³ãããªãååå±€ (2) 玫å€ç·åžåå€ãå«æãããŒã©ãã³äžéå±€ (3) ãŒã©ãã³ä¿è·å±€ äžèšã«ãã調補ãããåæå ã·ãŒãã«åæ§é²å
ãäžããäžèšçµæã®ã¢ã¯ãããŒã¿æº¶æ¶²äžã«15ç§é
浞挬ãã次ã«äžå¯Ÿã®å å§ããŒã©ã®éãéããŠäžèš
ã®ååã·ãŒããšããããéãåãããåŠçã¯18
âã24âããã³33âã®ïŒæ®µéã§è¡ã€ãã ïŒã¢ã¯ãããŒã¿æº¶æ¶²çµæïŒ æ°Žé žåã«ãªãŠã 56.2ïœ ïŒâã¡ãã«ãã³ãŸããªã¢ãŸãŒã« 7.2ïœ 11âã¢ãããŠã³ãã³ã«ã³é ž 2.0ïœ èåã«ãªãŠã 2.0ïœ æ°Žã§ïŒã«ä»äžããã äžèšã¢ã¯ãããŒã¿æº¶æ¶²ã«ããåŠçãïŒåéç¶ã
ãåŸãæå ã·ãŒããšååã·ãŒããšãå¥é¢ãããšã
ãååå±€ã«ããŒã³ã¿è²çŽ ç»åãåŸããããäžèšç¬¬
ïŒè¡šã«åŸãããè²åã®æ倧æ¿åºŠãšæå°æ¿åºŠãšã瀺
ãã
ãè¡šã
ãè¡šã
äžèšã®çµæãããæ¬çºæã«ä¿ããã«ããªå€ã¯æ¡
æ£è»¢åæ³çšã®æå ææã«çšããããå Žåã«ãè¯å¥œ
ãªããžç»åãäžããŸãä¿åå®å®æ§ã«ãåªããŠãã
ããšãæããã«ãªã€ããããªãã¡ãæ¬çºæã«ãã
ã«ããªå€ãçšãããšãæ¯èŒçšã«ããªå€âãçšã
ãå Žåãšæ¯èŒããŠãé«æž©é«æ¹¿äžã§ã®çµæä¿åã«ã
ããå€åïŒæ倧æ¿åºŠã®äœäžããã³æ倧æ¿åºŠã®å¢
倧ïŒãå°ããããŸãæ¯èŒçšã«ããªå€âãçšãã
å Žåãšæ¯èŒãããšãåŠç枩床ã«ããæ倧æ¿åºŠã®å€
åãèãããå°ããããã€äžèšã«ããªå€âãçš
ããå Žåã®æ³¡ã®çºçããã³çŸåããã¯å šãèªãã
ããªãã€ãã çºæã®å¹æ æ¬çºæã«ä¿ããã«ããªå€ãå«æããçŽæ¥ããžã
ãã²ã³åéåçæå ææã¯ãé®®æã§ãã€æ倧æ¿åºŠ
ã®åªããããžç»åãåŸãããšãã§ããããã«é«
æž©ãé«æ¹¿äžã§ã®ä¿åã«éããŠãå®å®ã§ããã®äžåŠ
ç枩床ãå€åãããŠãç»åæ¿åºŠãå€åããããšã
èããå°ãªãã
æ£è»¢åæ³çšã®æå ææã«çšããããå Žåã«ãè¯å¥œ
ãªããžç»åãäžããŸãä¿åå®å®æ§ã«ãåªããŠãã
ããšãæããã«ãªã€ããããªãã¡ãæ¬çºæã«ãã
ã«ããªå€ãçšãããšãæ¯èŒçšã«ããªå€âãçšã
ãå Žåãšæ¯èŒããŠãé«æž©é«æ¹¿äžã§ã®çµæä¿åã«ã
ããå€åïŒæ倧æ¿åºŠã®äœäžããã³æ倧æ¿åºŠã®å¢
倧ïŒãå°ããããŸãæ¯èŒçšã«ããªå€âãçšãã
å Žåãšæ¯èŒãããšãåŠç枩床ã«ããæ倧æ¿åºŠã®å€
åãèãããå°ããããã€äžèšã«ããªå€âãçš
ããå Žåã®æ³¡ã®çºçããã³çŸåããã¯å šãèªãã
ããªãã€ãã çºæã®å¹æ æ¬çºæã«ä¿ããã«ããªå€ãå«æããçŽæ¥ããžã
ãã²ã³åéåçæå ææã¯ãé®®æã§ãã€æ倧æ¿åºŠ
ã®åªããããžç»åãåŸãããšãã§ããããã«é«
æž©ãé«æ¹¿äžã§ã®ä¿åã«éããŠãå®å®ã§ããã®äžåŠ
ç枩床ãå€åãããŠãç»åæ¿åºŠãå€åããããšã
èããå°ãªãã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ å éšæœååããã²ã³åéç²åãå«ãå°ãªããš
ãïŒå±€ã®æå æ§ããã²ã³åéä¹³å€å±€ãæ¯æäœäžã«
æãã該乳å€å±€ããã³ïŒãŸãã¯ãã®ä»ã®èŠªæ°Žæ§ã³
ãã€ãå±€ã®å°ãªããšãïŒå±€äžã«ã«ããªå€ãå«æã
ãçŽæ¥ããžããã²ã³åéåçæå ææã«ãããŠã
äžèšã«ããªå€ãäžèšäžè¬åŒã§ç€ºãããããšãç¹åŸŽ
ãšããçŽæ¥ããžããã²ã³åéåçæå ææã äžè¬åŒ åŒäžãR1ãR2ããã³R3ã¯åäžã§ãç°ãªã€ãŠ
ããŠããããåã æ°ŽçŽ ååãã¢ã«ãã«åºãã·ã¯ã
ã¢ã«ãã«åºãŸãã¯ã¢ãªãŒã«åºãè¡šãããã¯ããš
ãã¬ã³åºããåŒãåºãŸ ãã¯ãåŒãåºãè¡šããã ã¯é žçŽ ååãŸãã¯ç¡«é»ååãè¡šãããã¯ïŒžã
é žçŽ ååã®ãšãã¯ç¡«é»ååãè¡šããããç¡«é»å
åã®ãšãã¯é žçŽ ååãè¡šããã
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7559283A JPS59200231A (ja) | 1983-04-27 | 1983-04-27 | çŽæ¥ããžããã²ã³åéåçæå ææ |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7559283A JPS59200231A (ja) | 1983-04-27 | 1983-04-27 | çŽæ¥ããžããã²ã³åéåçæå ææ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59200231A JPS59200231A (ja) | 1984-11-13 |
| JPH0475491B2 true JPH0475491B2 (ja) | 1992-12-01 |
Family
ID=13580620
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7559283A Granted JPS59200231A (ja) | 1983-04-27 | 1983-04-27 | çŽæ¥ããžããã²ã³åéåçæå ææ |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59200231A (ja) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62160438A (ja) * | 1986-01-09 | 1987-07-16 | Fuji Photo Film Co Ltd | ããã²ã³åéåçæå ææ |
| JP2683796B2 (ja) * | 1988-03-03 | 1997-12-03 | ã³ãã«æ ªåŒäŒç€Ÿ | é«ã³ã³ãã©ã¹ããªç»åãåŸãããšãã§ããããã²ã³åéåçæå ææ |
-
1983
- 1983-04-27 JP JP7559283A patent/JPS59200231A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS59200231A (ja) | 1984-11-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2724590B2 (ja) | ããã²ã³åéåçæå ææ | |
| US4863838A (en) | Direct positive type light-sensitive silver halide photographic materials | |
| JPH07113744B2 (ja) | ããã²ã³åéåçæå ææ | |
| JP2515156B2 (ja) | ããã²ã³åéåçæå ææ | |
| JPH0511301B2 (ja) | ||
| JP2899625B2 (ja) | ããã²ã³åéåçæå ææ | |
| JPH0693082B2 (ja) | ããã²ã³åéåçæå ææ | |
| JPH0786666B2 (ja) | ããã²ã³åéåçæå ææ | |
| JPH0475491B2 (ja) | ||
| JPS583535B2 (ja) | çŽæ¥ããžç»åã®åœ¢ææ¹æ³ | |
| JPH0786664B2 (ja) | ããã²ã³åéåçæå ææ | |
| JPS5828570B2 (ja) | çŽæ¥ããžç»åã®åœ¢ææ¹æ³ | |
| JPH0310930B2 (ja) | ||
| JPH0473770B2 (ja) | ||
| JPH0546935B2 (ja) | ||
| JPS5814666B2 (ja) | çŽæ¥ããžããã²ã³åéåçæå ææ | |
| JP2515151B2 (ja) | ããã²ã³åéåçæå ææ | |
| JP2654684B2 (ja) | ããã²ã³åéåçæå ææ | |
| JPH0816771B2 (ja) | ããã²ã³åéåçæå ææ | |
| JPH0475490B2 (ja) | ||
| JPH0738071B2 (ja) | ããã²ã³åéåçæå ææ | |
| JPS6325650B2 (ja) | ||
| JPS59201049A (ja) | ããžåç»åã®åœ¢ææ¹æ³ | |
| JPH02220042A (ja) | ããã²ã³åéåçæå ææ | |
| JPS59201045A (ja) | ããã²ã³åéåçèŠçŽ |