JPH0573010B2 - - Google Patents
Info
- Publication number
- JPH0573010B2 JPH0573010B2 JP24301284A JP24301284A JPH0573010B2 JP H0573010 B2 JPH0573010 B2 JP H0573010B2 JP 24301284 A JP24301284 A JP 24301284A JP 24301284 A JP24301284 A JP 24301284A JP H0573010 B2 JPH0573010 B2 JP H0573010B2
- Authority
- JP
- Japan
- Prior art keywords
- coupler
- acid
- silver halide
- color
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- -1 silver halide Chemical class 0.000 claims description 49
- 229910052709 silver Inorganic materials 0.000 claims description 32
- 239000004332 silver Substances 0.000 claims description 32
- 125000000217 alkyl group Chemical group 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 14
- 239000000839 emulsion Substances 0.000 claims description 13
- 125000003118 aryl group Chemical group 0.000 claims description 9
- UDFSJHJKINSRFV-UHFFFAOYSA-N N1N=CN2N=CC=C21 Chemical compound N1N=CN2N=CC=C21 UDFSJHJKINSRFV-UHFFFAOYSA-N 0.000 claims description 7
- 125000005842 heteroatom Chemical group 0.000 claims description 4
- 125000002947 alkylene group Chemical group 0.000 claims description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 22
- 239000000975 dye Substances 0.000 description 22
- 239000000243 solution Substances 0.000 description 20
- 238000011161 development Methods 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 239000010410 layer Substances 0.000 description 14
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 238000000034 method Methods 0.000 description 12
- 239000000203 mixture Substances 0.000 description 12
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 10
- 108010010803 Gelatin Proteins 0.000 description 8
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 8
- 239000002253 acid Substances 0.000 description 8
- 239000008273 gelatin Substances 0.000 description 8
- 229920000159 gelatin Polymers 0.000 description 8
- 235000019322 gelatine Nutrition 0.000 description 8
- 235000011852 gelatine desserts Nutrition 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 238000010168 coupling process Methods 0.000 description 7
- 238000005859 coupling reaction Methods 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- 125000001424 substituent group Chemical group 0.000 description 7
- 238000003786 synthesis reaction Methods 0.000 description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000004061 bleaching Methods 0.000 description 6
- 230000008878 coupling Effects 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 229960000583 acetic acid Drugs 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 238000004040 coloring Methods 0.000 description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 5
- 150000007524 organic acids Chemical class 0.000 description 5
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 4
- 239000006096 absorbing agent Substances 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 125000003545 alkoxy group Chemical group 0.000 description 4
- 125000004414 alkyl thio group Chemical group 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000007844 bleaching agent Substances 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical class OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- 239000012362 glacial acetic acid Substances 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- 150000002367 halogens Chemical class 0.000 description 4
- 125000000623 heterocyclic group Chemical group 0.000 description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- 230000001235 sensitizing effect Effects 0.000 description 4
- 235000011121 sodium hydroxide Nutrition 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 3
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 125000004453 alkoxycarbonyl group Chemical group 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 125000004093 cyano group Chemical group *C#N 0.000 description 3
- 125000004663 dialkyl amino group Chemical group 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229940093915 gynecological organic acid Drugs 0.000 description 3
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 description 3
- 235000005985 organic acids Nutrition 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 229910000027 potassium carbonate Inorganic materials 0.000 description 3
- 235000011181 potassium carbonates Nutrition 0.000 description 3
- JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical compound O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- 230000035945 sensitivity Effects 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 235000017550 sodium carbonate Nutrition 0.000 description 3
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 3
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 3
- ZKGIQGUWLGYKMA-UHFFFAOYSA-N 1,2-bis(ethenylsulfonyl)ethane Chemical compound C=CS(=O)(=O)CCS(=O)(=O)C=C ZKGIQGUWLGYKMA-UHFFFAOYSA-N 0.000 description 2
- CLDZVCMRASJQFO-UHFFFAOYSA-N 2,5-bis(2,4,4-trimethylpentan-2-yl)benzene-1,4-diol Chemical compound CC(C)(C)CC(C)(C)C1=CC(O)=C(C(C)(C)CC(C)(C)C)C=C1O CLDZVCMRASJQFO-UHFFFAOYSA-N 0.000 description 2
- XNCSCQSQSGDGES-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]propyl-(carboxymethyl)amino]acetic acid Chemical compound OC(=O)CN(CC(O)=O)C(C)CN(CC(O)=O)CC(O)=O XNCSCQSQSGDGES-UHFFFAOYSA-N 0.000 description 2
- RNMCCPMYXUKHAZ-UHFFFAOYSA-N 2-[3,3-diamino-1,2,2-tris(carboxymethyl)cyclohexyl]acetic acid Chemical compound NC1(N)CCCC(CC(O)=O)(CC(O)=O)C1(CC(O)=O)CC(O)=O RNMCCPMYXUKHAZ-UHFFFAOYSA-N 0.000 description 2
- XLLIQLLCWZCATF-UHFFFAOYSA-N 2-methoxyethyl acetate Chemical compound COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 2
- KWYJDIUEHHCHCZ-UHFFFAOYSA-N 3-[2-[bis(2-carboxyethyl)amino]ethyl-(2-carboxyethyl)amino]propanoic acid Chemical compound OC(=O)CCN(CCC(O)=O)CCN(CCC(O)=O)CCC(O)=O KWYJDIUEHHCHCZ-UHFFFAOYSA-N 0.000 description 2
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical compound [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- JRNVZBWKYDBUCA-UHFFFAOYSA-N N-chlorosuccinimide Chemical compound ClN1C(=O)CCC1=O JRNVZBWKYDBUCA-UHFFFAOYSA-N 0.000 description 2
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical compound CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- AUJUKHGWOKKPAN-UHFFFAOYSA-J [Na+].[Na+].[Na+].[Na+].CC(CN(CC([O-])=O)CC([O-])=O)N(CC([O-])=O)CC([O-])=O Chemical compound [Na+].[Na+].[Na+].[Na+].CC(CN(CC([O-])=O)CC([O-])=O)N(CC([O-])=O)CC([O-])=O AUJUKHGWOKKPAN-UHFFFAOYSA-J 0.000 description 2
- LRSAWRZHGQQHBJ-UHFFFAOYSA-N acetic acid;benzene-1,2-diamine Chemical compound CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O.NC1=CC=CC=C1N LRSAWRZHGQQHBJ-UHFFFAOYSA-N 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
- DEFVIWRASFVYLL-UHFFFAOYSA-N ethylene glycol bis(2-aminoethyl)tetraacetic acid Chemical compound OC(=O)CN(CC(O)=O)CCOCCOCCN(CC(O)=O)CC(O)=O DEFVIWRASFVYLL-UHFFFAOYSA-N 0.000 description 2
- 238000005562 fading Methods 0.000 description 2
- NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 description 2
- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- LQPLDXQVILYOOL-UHFFFAOYSA-I pentasodium;2-[bis[2-[bis(carboxylatomethyl)amino]ethyl]amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC(=O)[O-])CCN(CC([O-])=O)CC([O-])=O LQPLDXQVILYOOL-UHFFFAOYSA-I 0.000 description 2
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 2
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 2
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 2
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 2
- 229940001584 sodium metabisulfite Drugs 0.000 description 2
- 235000010262 sodium metabisulphite Nutrition 0.000 description 2
- DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 125000004434 sulfur atom Chemical group 0.000 description 2
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 2
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 description 2
- 229910052724 xenon Inorganic materials 0.000 description 2
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 2
- NKJOXAZJBOMXID-UHFFFAOYSA-N 1,1'-Oxybisoctane Chemical compound CCCCCCCCOCCCCCCCC NKJOXAZJBOMXID-UHFFFAOYSA-N 0.000 description 1
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 1
- AOSFMYBATFLTAQ-UHFFFAOYSA-N 1-amino-3-(benzimidazol-1-yl)propan-2-ol Chemical compound C1=CC=C2N(CC(O)CN)C=NC2=C1 AOSFMYBATFLTAQ-UHFFFAOYSA-N 0.000 description 1
- HRBLHUVHOWWBEN-UHFFFAOYSA-N 1-n,4-n-diethylbenzene-1,4-diamine;hydrochloride Chemical compound Cl.CCNC1=CC=C(NCC)C=C1 HRBLHUVHOWWBEN-UHFFFAOYSA-N 0.000 description 1
- NEPWWHQLHRGVQL-UHFFFAOYSA-N 1-n,4-n-dimethylbenzene-1,4-diamine;hydron;chloride Chemical compound Cl.CNC1=CC=C(NC)C=C1 NEPWWHQLHRGVQL-UHFFFAOYSA-N 0.000 description 1
- YGDWUQFZMXWDKE-UHFFFAOYSA-N 1-oxido-1,3-thiazole Chemical class [O-]S1=CN=C=C1 YGDWUQFZMXWDKE-UHFFFAOYSA-N 0.000 description 1
- KPVMVJXYXFUVLR-UHFFFAOYSA-N 12-ethyltetradecan-1-amine Chemical compound CCC(CC)CCCCCCCCCCCN KPVMVJXYXFUVLR-UHFFFAOYSA-N 0.000 description 1
- RDMIJQCFPQDYQN-UHFFFAOYSA-N 2-(2,4,4-trimethylpentan-2-yl)benzene-1,4-diol Chemical compound CC(C)(C)CC(C)(C)C1=CC(O)=CC=C1O RDMIJQCFPQDYQN-UHFFFAOYSA-N 0.000 description 1
- ALQQNXBDAKRPOQ-UHFFFAOYSA-N 2-(2-ethyl-2-phenylhydrazinyl)ethanol Chemical compound OCCNN(CC)C1=CC=CC=C1 ALQQNXBDAKRPOQ-UHFFFAOYSA-N 0.000 description 1
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 1
- JKRNNIGZNCVVHA-UHFFFAOYSA-N 2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate;trimethylazanium Chemical compound C[NH+](C)C.C[NH+](C)C.C[NH+](C)C.C[NH+](C)C.[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O JKRNNIGZNCVVHA-UHFFFAOYSA-N 0.000 description 1
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- ZZXILYOBAFPJNS-UHFFFAOYSA-N 2-octylbenzene-1,4-diol Chemical compound CCCCCCCCC1=CC(O)=CC=C1O ZZXILYOBAFPJNS-UHFFFAOYSA-N 0.000 description 1
- XRZDIHADHZSFBB-UHFFFAOYSA-N 3-oxo-n,3-diphenylpropanamide Chemical compound C=1C=CC=CC=1NC(=O)CC(=O)C1=CC=CC=C1 XRZDIHADHZSFBB-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- YLNKRLLYLJYWEN-UHFFFAOYSA-N 4-(2,2-dibutoxyethoxy)-4-oxobutanoic acid Chemical compound CCCCOC(OCCCC)COC(=O)CCC(O)=O YLNKRLLYLJYWEN-UHFFFAOYSA-N 0.000 description 1
- MTOCKMVNXPZCJW-UHFFFAOYSA-N 4-n-dodecyl-4-n-ethyl-2-methylbenzene-1,4-diamine Chemical compound CCCCCCCCCCCCN(CC)C1=CC=C(N)C(C)=C1 MTOCKMVNXPZCJW-UHFFFAOYSA-N 0.000 description 1
- IJJSFSXLZYFTKV-UHFFFAOYSA-N 4-n-methylbenzene-1,4-diamine;hydrochloride Chemical compound Cl.CNC1=CC=C(N)C=C1 IJJSFSXLZYFTKV-UHFFFAOYSA-N 0.000 description 1
- NSPMIYGKQJPBQR-UHFFFAOYSA-N 4H-1,2,4-triazole Chemical compound C=1N=CNN=1 NSPMIYGKQJPBQR-UHFFFAOYSA-N 0.000 description 1
- 125000002373 5 membered heterocyclic group Chemical group 0.000 description 1
- 229940100484 5-chloro-2-methyl-4-isothiazolin-3-one Drugs 0.000 description 1
- 125000004070 6 membered heterocyclic group Chemical group 0.000 description 1
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical class C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- DGMHWANKRGEVMI-UHFFFAOYSA-N CC1=CC=C(C=C1)S(=O)(=O)O.COCCN(C1=CC(=CC=C1)C)CC Chemical compound CC1=CC=C(C=C1)S(=O)(=O)O.COCCN(C1=CC(=CC=C1)C)CC DGMHWANKRGEVMI-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical group C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 229910021612 Silver iodide Inorganic materials 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 1
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical group C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 1
- XCFIVNQHHFZRNR-UHFFFAOYSA-N [Ag].Cl[IH]Br Chemical compound [Ag].Cl[IH]Br XCFIVNQHHFZRNR-UHFFFAOYSA-N 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 125000004442 acylamino group Chemical group 0.000 description 1
- 125000004423 acyloxy group Chemical group 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 229910001508 alkali metal halide Inorganic materials 0.000 description 1
- 150000008045 alkali metal halides Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 125000004390 alkyl sulfonyl group Chemical group 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 229940101006 anhydrous sodium sulfite Drugs 0.000 description 1
- 125000004391 aryl sulfonyl group Chemical group 0.000 description 1
- 125000005110 aryl thio group Chemical group 0.000 description 1
- 125000004104 aryloxy group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- XNSQZBOCSSMHSZ-UHFFFAOYSA-K azane;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxymethyl)amino]acetate;iron(3+) Chemical compound [NH4+].[Fe+3].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O XNSQZBOCSSMHSZ-UHFFFAOYSA-K 0.000 description 1
- ZFSFDELZPURLKD-UHFFFAOYSA-N azanium;hydroxide;hydrate Chemical compound N.O.O ZFSFDELZPURLKD-UHFFFAOYSA-N 0.000 description 1
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 1
- 229910001864 baryta Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- 150000001565 benzotriazoles Chemical group 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 229960002645 boric acid Drugs 0.000 description 1
- 235000010338 boric acid Nutrition 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- SXDBWCPKPHAZSM-UHFFFAOYSA-M bromate Inorganic materials [O-]Br(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-M 0.000 description 1
- SXDBWCPKPHAZSM-UHFFFAOYSA-N bromic acid Chemical compound OBr(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-N 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 1
- COPHVUDURPSYBO-UHFFFAOYSA-N butyl dioctyl phosphate Chemical compound CCCCCCCCOP(=O)(OCCCC)OCCCCCCCC COPHVUDURPSYBO-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 description 1
- 229940114081 cinnamate Drugs 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004440 column chromatography Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- XWVQUJDBOICHGH-UHFFFAOYSA-N dioctyl nonanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCC(=O)OCCCCCCCC XWVQUJDBOICHGH-UHFFFAOYSA-N 0.000 description 1
- ASMQGLCHMVWBQR-UHFFFAOYSA-M diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)([O-])OC1=CC=CC=C1 ASMQGLCHMVWBQR-UHFFFAOYSA-M 0.000 description 1
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 description 1
- PCAXGMRPPOMODZ-UHFFFAOYSA-N disulfurous acid, diammonium salt Chemical compound [NH4+].[NH4+].[O-]S(=O)S([O-])(=O)=O PCAXGMRPPOMODZ-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical class OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 150000003840 hydrochlorides Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 1
- LOCAIGRSOJUCTB-UHFFFAOYSA-N indazol-3-one Chemical class C1=CC=C2C(=O)N=NC2=C1 LOCAIGRSOJUCTB-UHFFFAOYSA-N 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000002650 laminated plastic Substances 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- CLJDCQWROXMJAZ-UHFFFAOYSA-N n-[2-(4-amino-n-ethyl-3-methylanilino)ethyl]methanesulfonamide;sulfuric acid Chemical compound OS(O)(=O)=O.CS(=O)(=O)NCCN(CC)C1=CC=C(N)C(C)=C1 CLJDCQWROXMJAZ-UHFFFAOYSA-N 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000004780 naphthols Chemical class 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- VECVSKFWRQYTAL-UHFFFAOYSA-N octyl benzoate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1 VECVSKFWRQYTAL-UHFFFAOYSA-N 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 150000003891 oxalate salts Chemical class 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 150000004989 p-phenylenediamines Chemical class 0.000 description 1
- 239000006179 pH buffering agent Substances 0.000 description 1
- 229960003330 pentetic acid Drugs 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- DJEHXEMURTVAOE-UHFFFAOYSA-M potassium bisulfite Chemical compound [K+].OS([O-])=O DJEHXEMURTVAOE-UHFFFAOYSA-M 0.000 description 1
- 229940099427 potassium bisulfite Drugs 0.000 description 1
- 235000010259 potassium hydrogen sulphite Nutrition 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- RWPGFSMJFRPDDP-UHFFFAOYSA-L potassium metabisulfite Chemical compound [K+].[K+].[O-]S(=O)S([O-])(=O)=O RWPGFSMJFRPDDP-UHFFFAOYSA-L 0.000 description 1
- 229940043349 potassium metabisulfite Drugs 0.000 description 1
- 235000010263 potassium metabisulphite Nutrition 0.000 description 1
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 1
- 235000019252 potassium sulphite Nutrition 0.000 description 1
- 150000003142 primary aromatic amines Chemical class 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- MCSKRVKAXABJLX-UHFFFAOYSA-N pyrazolo[3,4-d]triazole Chemical class N1=NN=C2N=NC=C21 MCSKRVKAXABJLX-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- 229940045105 silver iodide Drugs 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- XUXNAKZDHHEHPC-UHFFFAOYSA-M sodium bromate Chemical compound [Na+].[O-]Br(=O)=O XUXNAKZDHHEHPC-UHFFFAOYSA-M 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 150000003456 sulfonamides Chemical class 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 125000005031 thiocyano group Chemical group S(C#N)* 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- NJPOTNJJCSJJPJ-UHFFFAOYSA-N tributyl benzene-1,3,5-tricarboxylate Chemical compound CCCCOC(=O)C1=CC(C(=O)OCCCC)=CC(C(=O)OCCCC)=C1 NJPOTNJJCSJJPJ-UHFFFAOYSA-N 0.000 description 1
- 150000003639 trimesic acids Chemical class 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/32—Colour coupling substances
- G03C7/36—Couplers containing compounds with active methylene groups
- G03C7/38—Couplers containing compounds with active methylene groups in rings
- G03C7/381—Heterocyclic compounds
- G03C7/382—Heterocyclic compounds with two heterocyclic rings
- G03C7/3825—Heterocyclic compounds with two heterocyclic rings the nuclei containing only nitrogen as hetero atoms
- G03C7/3835—Heterocyclic compounds with two heterocyclic rings the nuclei containing only nitrogen as hetero atoms four nitrogen atoms
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Description
ïŒç£æ¥äžã®å©çšåéïŒ
æ¬çºæã¯é«çºè²æ§ã§ãä¿åæ§ç¹ã«èå
æ§ã®æ¹è¯
ãããããŒã³ã¿è²çŽ ç»åã圢æãããšããã®ããŒ
ã³ã¿ã«ãã©ãŒãå«æããããã²ã³åéã«ã©ãŒåç
æå ææã«é¢ãããæŽã«è©³ããã¯æ°èŠãª1Hâã
ã©ãŸããïŒïŒïŒâãââããªã¢ãŸãŒã«ç³»ããŒ
ã³ã¿ã«ãã©ãŒãå«æããããã²ã³åéã«ã©ãŒåç
æå ææã«é¢ããã ïŒåŸæ¥æè¡ïŒ éåžžããã²ã³åéã«ã©ãŒåçæå ææã«ãããŠ
ã¯ãæå ãããããã²ã³åéç²åãè³éŠæ第ïŒçŽ
ã¢ãã³ç³»çºè²çŸåäž»è¬ã«ããéå ãããã®éçæ
ãããåèšçºè²çŸåäž»è¬ã®é žåäœãšã€ãšããŒãã
ãŒã³ã¿ããã³ã·ã¢ã³ã®åè²çŽ ã圢æããã«ãã©ãŒ
ãšã®ã«ãããªã³ã°ã«ããè²çŽ ç»åãåŸãããšãã§
ããã åèšããŒã³ã¿è²çŽ ã圢æããããã«ãåŸæ¥ãã
å®çšã«äŸãããŠããã«ãã©ãŒã¯ãã©ãŸãã³åã«ã
ã©ãŒã§ããããããã¯å¥œãŸãããªãå¯åžåãæã
ããšå ±ã«ä¿åæ§ãç¹ã«ãã«ããªã³ã¬ã¹ã«å¯Ÿããè
æ§ïŒãã«ããªã³èæ§ïŒã«ä¹ãããšããæ¬ ç¹ãæã
ãŠããã äžèšæ¬ ç¹ãæ¹è¯ããããã«ããããŸã§çš®ã ã®
1Hâãã©ãŸããïŒïŒïŒâãââããªã¢ãŸãŒã«
ç³»ããŒã³ã¿ã«ãã©ãŒãææ¡ãããŠãããäŸãã°ç±³
åœç¹èš±3725067å·ãè±åœç¹èš±1252418å·ãå
1334515å·ã«èšèŒãããŠããããããã®ç¹èš±ã«èš
èŒã®ååç©ãå¿è«å¯åžåãšããç¹ã§ã¯ãã©ãŸãã³
ç³»ããŒã³ã¿ã«ãã©ãŒã«åªãããã«ããªã³èæ§ã®æ¹
è¯ã¯äžååã§ããããŸãçºè²æ§ç»åã®èå æ§ãšã
ãç¹ã§ã®æ¹è¯ã¯ã»ãšãã©ãªãããŠããªãã
Research Disclosure 12443èšèŒã®ååç©ãçºè²
æ§ãšããç¹ã§å šãå®çšã«äŸãåŸãªããç¹éæ58â
42045å·ã«èšèŒã®1Hâãã©ãŸããïŒïŒïŒâãâ
âããªã¢ãŸãŒã«åããŒã³ã¿ã«ãã©ãŒã¯ãã«ããª
ã³èæ§ã®æ¹è¯ããã³çºè²æ§ãšããç¹ã§ã¯èããæ¹
è¯ãããŠãããããã¯ãèå æ§ã®æ¹è¯ã¯ã»ãšãã©
ãªãããŠããªãã ãŸãç¹éæ59â99437å·ãå59â125732å·ã«èš
èŒã®ã«ãã©ãŒãçºè²æ§ã®æ¹è¯ã¯ãªãããŠãããã
èšèŒã«ãã©ãŒã«åºã¥ãè²çŽ ç»åã®èå æ§ãšããç¹
ã§ã¯çžå€ããæ¹è¯ã®ããšãèŠãããªãã åŸè ã¯åã«äœµçšããæ·»å å€ã«ãã€ãŠç»åã®èå
æ§ãæ¹åãããŠããã«éããªãããã åè æ现æž
èšèŒååç©äŸ19ã®ã«ãã©ãŒã¯ãããã«èå æ§ã¯æ¹
è¯ãããŠãããååãšã¯èšããªãã ããªãã¡ããããŸã§å¯åžåããªããã«ããªã³è
æ§ãé«ããšããããšã§æ³šç®ãããŠãã1Hâãã©
ãŸããïŒïŒïŒâãââããªã¢ãŸãŒã«ç³»ããŒã³
ã¿ã«ãã©ãŒãè²çŽ ç»åã®èå æ§ã«ã€ããŠã¯ãã»ãš
ãã©æ¹è¯ããªãããŠããŠããªããšèšããã ïŒçºæã®ç®çïŒ æ¬çºæã®ç®çã¯ãèå æ§ããã³ãã«ããªã³èæ§
ãããããããçºè²æ§ã®é«ãããã²ã³åéã«ã©ãŒ
åçæå ææãæäŸããããšã«ããã ïŒçºæã®æ§æïŒ åèšããæ¬çºæã®ç®çã¯æ¯æäœäžã«å°ããšãäž
å±€ã®ããã²ã³åéä¹³å€å±€ãæããããã²ã³åéã«
ã©ãŒåçæå ææã«ãããŠãåèšããã²ã³åéä¹³
å€å±€äžã«ãïŒäœãïŒçŽã¢ã«ãã«ãã¢ãªãŒã«åã³ã
ããç°ããéžã°ããåºã§ããã€ïŒäœã次ã®äžè¬åŒ
ã§ç€ºãããåºã§çœ®æããã1Hâãã©ãŸããïŒïŒ
ïŒâãââããªã¢ãŸãŒã«ç³»ããŒã³ã¿ã«ãã©ãŒ
ã®å°ããšãïŒã€ãå«æãããŠããããšãç¹åŸŽãšã
ãããã²ã³åéã«ã©ãŒåçæå ææã«ãã€ãŠéæ
ãããã äžè¬åŒ âR1âSO2âR2 åŒäžãR1ã¯ïŒçŽåã¯ïŒçŽã¢ã«ãã¬ã³ãR2ã¯ã¢
ã«ãã«åã¯ã¢ãªãŒã«ãè¡šããã 次ã«æ¬çºæã詳现ã«èª¬æããã æ¬çºæè ãã¯ããã®ç¹ã®æ¹è¯ãç®æããŠéæç
究ãããããŠããçµæãç»åã®èå æ§ããã³ãã«
ããªã³èæ§ããããããããé«ãçºè²æ§ã瀺ã
1Hâãã©ãŸããïŒïŒïŒâãââããªã¢ãŸãŒã«
ç³»ããŒã³ã¿ã«ãã©ãŒãèŠãåºãã«å°ã€ãã ããªãã¡1Hâãã©ãŸããïŒïŒïŒâãââã
ãªã¢ãŸãŒã«ã«æŒããŠïŒäœãåèšäžè¬åŒã§ç€ºããã
åºã§çœ®æãããæèå æ§ã®å€§å·Ÿãªåäžãšå ±ã«ãé«
ãçºè²æ§ãéæããããšãåºæ¥ãã ãŸãïŒäœãåèšäžè¬åŒã§ç€ºãããåºã§çœ®æãã
ããšå ±ã«çºè²çŸåäž»è¬ã®é žåäœãšã®ã«ãããªã³ã°
äœã§ããïŒäœãæ°ŽçŽ åå以å€ã®é¢è±åºã§çœ®æãã
ãæãèå æ§ãçºè²æ§ã«æŒããŠæŽã«å¥œãŸããæ§èœ
ãçºçŸããã R1ã§ç€ºãããã¢ã«ãã¬ã³ã¯ã¢ã«ãã«ãã¢ãªãŒ
ã«ïŒäŸãã°ããšãã«ïŒãããã²ã³ãã·ã¢ããæŽã«
ã¢ã«ã³ãã·ã«ã«ããã«ãã¢ã·ã«ãã«ã«ãã¢ã€ã«ç
ã§ç€ºãããã«ã«ããã«ã§çµåãã眮æåºãæŽã«ã¯
ããããã¢ã«ã³ãã·ãã¢ã«ãã«ããªããžã¢ã«ãã«
ã¢ããçã®ãããååã§çµåãã眮æåºã§çœ®æã
ããŠããŠãããã R2ã§ç€ºãããã¢ã«ãã«ã¯ãïŒçŽã¢ã«ãã«ãæŽ
ã«ã¯åå²ã®ïŒçŽãïŒçµã¢ã«ãã«ã瀺ããïŒçŽã¢ã«
ãã«ã¯æ ¹å ççŽ ã«æ°ŽçŽ ãïŒåçµåããŠããã¢ã«ã
ã«ãè¡šãããïŒçŽã¢ã«ãã«ã¯æ ¹å ççŽ ã«æ°ŽçŽ ãïŒ
åçµåããŠããã¢ã«ãã«ãè¡šãããïŒçŽã¢ã«ãã«
ã¯æ ¹å ççŽ ã«æ°ŽçŽ ãå šãçµåããŠããã¢ã«ãã«ã
è¡šããã R2ã§ç€ºãããã¢ã«ãã«ã¯ã¢ãªãŒã«ããããç°ã
ããã²ã³ãã·ã¢ããæŽã«ã¢ã«ã³ãã·ã«ã«ããã«ã
ã¢ã·ã«ãã«ã«ãã¢ã€ã«çã§ç€ºãããã«ã«ããã«ã§
çµåãã眮æåºãæŽã«ã¯ããããã¢ã«ã³ã·ããã¢
ã«ãã«ããªããžã¢ã«ãã«ã¢ããçã®ãããååã§
çµåãã眮æåºã§çœ®æãããŠããŠãããã ãªãããããç°åºã1Hâãã©ãŸããïŒïŒïŒâ
ãââããªã¢ãŸãŒã«âïŒâã€ã«ç³»ååç©ã®æ
ãã¹åã®1Hâãã©ãŸããïŒïŒïŒâãââããª
ã¢ãŸãŒã«ç³»ååç©ã圢æãããå¿è«æ¬çºæã«å å«
ãããããŒã³ã¿ã«ãã©ãŒã§ããã R2ã§ç€ºãããã¢ãªãŒã«ãšããŠã¯ããšãã«ãã
ããã«çãæãããããããã¯ã¢ã«ãã«ãããã²
ã³ãã·ã¢ããæŽã«ã¢ã«ã³ãã·ã«ã«ããã«ãã¢ã
ã«ãã«ã«ãã¢ã€ã«çã§ç€ºãããã«ã«ããã«ã§çµå
ãã眮æåºãæŽã«ã¯ããããã¢ã«ã³ãã·ãã¢ã«ã
ã«ããªããžã¢ã«ãã«ã¢ããçã®ãããååã§çµå
ãã眮æåºã§çœ®æãããŠããŠãããã ïŒäœã«ãããªã³ã°äœã«çµåããæ°ŽçŽ åå以å€ã®
é¢è±åºãšããŠã¯ããã²ã³ãæŽã«ã¯é žçŽ ååãçªçŽ
ååãŸãã¯ã€ãªãŠååã§ã«ãããªã³ã°äœã«çµåã
ãŠããææ©åºãæããããã é žçŽ ååã§ã«ãããªã³ã°äœã«çµåããŠããé¢è±
åºãšããŠã¯ã¢ã«ã³ãã·ãã¢ãªãŒã«ãªãã·ãã¢ã·ã«
ãªãã·ããããç°ãªãã·ãªã©ãæããããçªçŽ å
åã§ã«ãããªã³ã°äœã«çµåããŠããé¢è±åºãšããŠ
ã¯ã¢ã·ã«ã¢ããããžã¢ã·ã«ã¢ãããã¹ã«ãã³ã¢ã
ãããã³ãã®çªçŽ ååãå«ãïŒå¡ãŸãã¯ïŒå¡ã®è€
çŽ ç°åºãªã©ãæããããæŽã«ã€ãªãŠååã§ã«ãã
ãªã³ã°äœã«çµåããŠããé¢è±åºãšããŠã¯ããªã·ã¢
ããã¢ã«ãã«ããªãã¢ãªãŒã«ããªããããç°ã
ãªãã¢ãªãŒã«ã¹ã«ããã«ãã¢ã«ãã«ã¹ã«ããã«ãª
ã©ãæããããã æ¬çºæã®ãã¡ãæŽã«å¥œãŸããã¯æ¬¡ã®äžè¬åŒã§ç€º
ãããã
ãããããŒã³ã¿è²çŽ ç»åã圢æãããšããã®ããŒ
ã³ã¿ã«ãã©ãŒãå«æããããã²ã³åéã«ã©ãŒåç
æå ææã«é¢ãããæŽã«è©³ããã¯æ°èŠãª1Hâã
ã©ãŸããïŒïŒïŒâãââããªã¢ãŸãŒã«ç³»ããŒ
ã³ã¿ã«ãã©ãŒãå«æããããã²ã³åéã«ã©ãŒåç
æå ææã«é¢ããã ïŒåŸæ¥æè¡ïŒ éåžžããã²ã³åéã«ã©ãŒåçæå ææã«ãããŠ
ã¯ãæå ãããããã²ã³åéç²åãè³éŠæ第ïŒçŽ
ã¢ãã³ç³»çºè²çŸåäž»è¬ã«ããéå ãããã®éçæ
ãããåèšçºè²çŸåäž»è¬ã®é žåäœãšã€ãšããŒãã
ãŒã³ã¿ããã³ã·ã¢ã³ã®åè²çŽ ã圢æããã«ãã©ãŒ
ãšã®ã«ãããªã³ã°ã«ããè²çŽ ç»åãåŸãããšãã§
ããã åèšããŒã³ã¿è²çŽ ã圢æããããã«ãåŸæ¥ãã
å®çšã«äŸãããŠããã«ãã©ãŒã¯ãã©ãŸãã³åã«ã
ã©ãŒã§ããããããã¯å¥œãŸãããªãå¯åžåãæã
ããšå ±ã«ä¿åæ§ãç¹ã«ãã«ããªã³ã¬ã¹ã«å¯Ÿããè
æ§ïŒãã«ããªã³èæ§ïŒã«ä¹ãããšããæ¬ ç¹ãæã
ãŠããã äžèšæ¬ ç¹ãæ¹è¯ããããã«ããããŸã§çš®ã ã®
1Hâãã©ãŸããïŒïŒïŒâãââããªã¢ãŸãŒã«
ç³»ããŒã³ã¿ã«ãã©ãŒãææ¡ãããŠãããäŸãã°ç±³
åœç¹èš±3725067å·ãè±åœç¹èš±1252418å·ãå
1334515å·ã«èšèŒãããŠããããããã®ç¹èš±ã«èš
èŒã®ååç©ãå¿è«å¯åžåãšããç¹ã§ã¯ãã©ãŸãã³
ç³»ããŒã³ã¿ã«ãã©ãŒã«åªãããã«ããªã³èæ§ã®æ¹
è¯ã¯äžååã§ããããŸãçºè²æ§ç»åã®èå æ§ãšã
ãç¹ã§ã®æ¹è¯ã¯ã»ãšãã©ãªãããŠããªãã
Research Disclosure 12443èšèŒã®ååç©ãçºè²
æ§ãšããç¹ã§å šãå®çšã«äŸãåŸãªããç¹éæ58â
42045å·ã«èšèŒã®1Hâãã©ãŸããïŒïŒïŒâãâ
âããªã¢ãŸãŒã«åããŒã³ã¿ã«ãã©ãŒã¯ãã«ããª
ã³èæ§ã®æ¹è¯ããã³çºè²æ§ãšããç¹ã§ã¯èããæ¹
è¯ãããŠãããããã¯ãèå æ§ã®æ¹è¯ã¯ã»ãšãã©
ãªãããŠããªãã ãŸãç¹éæ59â99437å·ãå59â125732å·ã«èš
èŒã®ã«ãã©ãŒãçºè²æ§ã®æ¹è¯ã¯ãªãããŠãããã
èšèŒã«ãã©ãŒã«åºã¥ãè²çŽ ç»åã®èå æ§ãšããç¹
ã§ã¯çžå€ããæ¹è¯ã®ããšãèŠãããªãã åŸè ã¯åã«äœµçšããæ·»å å€ã«ãã€ãŠç»åã®èå
æ§ãæ¹åãããŠããã«éããªãããã åè æ现æž
èšèŒååç©äŸ19ã®ã«ãã©ãŒã¯ãããã«èå æ§ã¯æ¹
è¯ãããŠãããååãšã¯èšããªãã ããªãã¡ããããŸã§å¯åžåããªããã«ããªã³è
æ§ãé«ããšããããšã§æ³šç®ãããŠãã1Hâãã©
ãŸããïŒïŒïŒâãââããªã¢ãŸãŒã«ç³»ããŒã³
ã¿ã«ãã©ãŒãè²çŽ ç»åã®èå æ§ã«ã€ããŠã¯ãã»ãš
ãã©æ¹è¯ããªãããŠããŠããªããšèšããã ïŒçºæã®ç®çïŒ æ¬çºæã®ç®çã¯ãèå æ§ããã³ãã«ããªã³èæ§
ãããããããçºè²æ§ã®é«ãããã²ã³åéã«ã©ãŒ
åçæå ææãæäŸããããšã«ããã ïŒçºæã®æ§æïŒ åèšããæ¬çºæã®ç®çã¯æ¯æäœäžã«å°ããšãäž
å±€ã®ããã²ã³åéä¹³å€å±€ãæããããã²ã³åéã«
ã©ãŒåçæå ææã«ãããŠãåèšããã²ã³åéä¹³
å€å±€äžã«ãïŒäœãïŒçŽã¢ã«ãã«ãã¢ãªãŒã«åã³ã
ããç°ããéžã°ããåºã§ããã€ïŒäœã次ã®äžè¬åŒ
ã§ç€ºãããåºã§çœ®æããã1Hâãã©ãŸããïŒïŒ
ïŒâãââããªã¢ãŸãŒã«ç³»ããŒã³ã¿ã«ãã©ãŒ
ã®å°ããšãïŒã€ãå«æãããŠããããšãç¹åŸŽãšã
ãããã²ã³åéã«ã©ãŒåçæå ææã«ãã€ãŠéæ
ãããã äžè¬åŒ âR1âSO2âR2 åŒäžãR1ã¯ïŒçŽåã¯ïŒçŽã¢ã«ãã¬ã³ãR2ã¯ã¢
ã«ãã«åã¯ã¢ãªãŒã«ãè¡šããã 次ã«æ¬çºæã詳现ã«èª¬æããã æ¬çºæè ãã¯ããã®ç¹ã®æ¹è¯ãç®æããŠéæç
究ãããããŠããçµæãç»åã®èå æ§ããã³ãã«
ããªã³èæ§ããããããããé«ãçºè²æ§ã瀺ã
1Hâãã©ãŸããïŒïŒïŒâãââããªã¢ãŸãŒã«
ç³»ããŒã³ã¿ã«ãã©ãŒãèŠãåºãã«å°ã€ãã ããªãã¡1Hâãã©ãŸããïŒïŒïŒâãââã
ãªã¢ãŸãŒã«ã«æŒããŠïŒäœãåèšäžè¬åŒã§ç€ºããã
åºã§çœ®æãããæèå æ§ã®å€§å·Ÿãªåäžãšå ±ã«ãé«
ãçºè²æ§ãéæããããšãåºæ¥ãã ãŸãïŒäœãåèšäžè¬åŒã§ç€ºãããåºã§çœ®æãã
ããšå ±ã«çºè²çŸåäž»è¬ã®é žåäœãšã®ã«ãããªã³ã°
äœã§ããïŒäœãæ°ŽçŽ åå以å€ã®é¢è±åºã§çœ®æãã
ãæãèå æ§ãçºè²æ§ã«æŒããŠæŽã«å¥œãŸããæ§èœ
ãçºçŸããã R1ã§ç€ºãããã¢ã«ãã¬ã³ã¯ã¢ã«ãã«ãã¢ãªãŒ
ã«ïŒäŸãã°ããšãã«ïŒãããã²ã³ãã·ã¢ããæŽã«
ã¢ã«ã³ãã·ã«ã«ããã«ãã¢ã·ã«ãã«ã«ãã¢ã€ã«ç
ã§ç€ºãããã«ã«ããã«ã§çµåãã眮æåºãæŽã«ã¯
ããããã¢ã«ã³ãã·ãã¢ã«ãã«ããªããžã¢ã«ãã«
ã¢ããçã®ãããååã§çµåãã眮æåºã§çœ®æã
ããŠããŠãããã R2ã§ç€ºãããã¢ã«ãã«ã¯ãïŒçŽã¢ã«ãã«ãæŽ
ã«ã¯åå²ã®ïŒçŽãïŒçµã¢ã«ãã«ã瀺ããïŒçŽã¢ã«
ãã«ã¯æ ¹å ççŽ ã«æ°ŽçŽ ãïŒåçµåããŠããã¢ã«ã
ã«ãè¡šãããïŒçŽã¢ã«ãã«ã¯æ ¹å ççŽ ã«æ°ŽçŽ ãïŒ
åçµåããŠããã¢ã«ãã«ãè¡šãããïŒçŽã¢ã«ãã«
ã¯æ ¹å ççŽ ã«æ°ŽçŽ ãå šãçµåããŠããã¢ã«ãã«ã
è¡šããã R2ã§ç€ºãããã¢ã«ãã«ã¯ã¢ãªãŒã«ããããç°ã
ããã²ã³ãã·ã¢ããæŽã«ã¢ã«ã³ãã·ã«ã«ããã«ã
ã¢ã·ã«ãã«ã«ãã¢ã€ã«çã§ç€ºãããã«ã«ããã«ã§
çµåãã眮æåºãæŽã«ã¯ããããã¢ã«ã³ã·ããã¢
ã«ãã«ããªããžã¢ã«ãã«ã¢ããçã®ãããååã§
çµåãã眮æåºã§çœ®æãããŠããŠãããã ãªãããããç°åºã1Hâãã©ãŸããïŒïŒïŒâ
ãââããªã¢ãŸãŒã«âïŒâã€ã«ç³»ååç©ã®æ
ãã¹åã®1Hâãã©ãŸããïŒïŒïŒâãââããª
ã¢ãŸãŒã«ç³»ååç©ã圢æãããå¿è«æ¬çºæã«å å«
ãããããŒã³ã¿ã«ãã©ãŒã§ããã R2ã§ç€ºãããã¢ãªãŒã«ãšããŠã¯ããšãã«ãã
ããã«çãæãããããããã¯ã¢ã«ãã«ãããã²
ã³ãã·ã¢ããæŽã«ã¢ã«ã³ãã·ã«ã«ããã«ãã¢ã
ã«ãã«ã«ãã¢ã€ã«çã§ç€ºãããã«ã«ããã«ã§çµå
ãã眮æåºãæŽã«ã¯ããããã¢ã«ã³ãã·ãã¢ã«ã
ã«ããªããžã¢ã«ãã«ã¢ããçã®ãããååã§çµå
ãã眮æåºã§çœ®æãããŠããŠãããã ïŒäœã«ãããªã³ã°äœã«çµåããæ°ŽçŽ åå以å€ã®
é¢è±åºãšããŠã¯ããã²ã³ãæŽã«ã¯é žçŽ ååãçªçŽ
ååãŸãã¯ã€ãªãŠååã§ã«ãããªã³ã°äœã«çµåã
ãŠããææ©åºãæããããã é žçŽ ååã§ã«ãããªã³ã°äœã«çµåããŠããé¢è±
åºãšããŠã¯ã¢ã«ã³ãã·ãã¢ãªãŒã«ãªãã·ãã¢ã·ã«
ãªãã·ããããç°ãªãã·ãªã©ãæããããçªçŽ å
åã§ã«ãããªã³ã°äœã«çµåããŠããé¢è±åºãšããŠ
ã¯ã¢ã·ã«ã¢ããããžã¢ã·ã«ã¢ãããã¹ã«ãã³ã¢ã
ãããã³ãã®çªçŽ ååãå«ãïŒå¡ãŸãã¯ïŒå¡ã®è€
çŽ ç°åºãªã©ãæããããæŽã«ã€ãªãŠååã§ã«ãã
ãªã³ã°äœã«çµåããŠããé¢è±åºãšããŠã¯ããªã·ã¢
ããã¢ã«ãã«ããªãã¢ãªãŒã«ããªããããç°ã
ãªãã¢ãªãŒã«ã¹ã«ããã«ãã¢ã«ãã«ã¹ã«ããã«ãª
ã©ãæããããã æ¬çºæã®ãã¡ãæŽã«å¥œãŸããã¯æ¬¡ã®äžè¬åŒã§ç€º
ãããã
ãåŒã
R1ïŒR2ã®å®çŸ©ã¯æ¢ã«èšèŒãããŠãããã¯çº
è²çŸåäž»è¬ã®é žåäœãšã«ãããªã³ã°ããŠé¢è±åºã
è¡šãããããã«ã€ããŠãå ã«èšèŒããã ã¯ã¢ã«ãã«ãã¢ãªãŒã«ããããç°ãè¡šããã ã¢ãªãŒã«ãšããŠã¯å¥œãŸããã¯çœ®æãªããã¯ç¡çœ®
æã®ããšãã«ãè¡šããããããç°ãšããŠã¯å ·äœç
ã«ã¯ãã©ã³ç°ãããªããšã³ç°ãªã©ãæããããã 以äžã«æ¬çºæã«åºã¥ãå ·äœäŸã以äžã«ç€ºããã
æ¬çºæã¯ãããã«éå®ããããã®ã§ã¯ãªãã ãªããæ¬çºæã«ä¿ãã1Hâãã©ãŸããïŒïŒïŒ
âãââããªã¢ãŸãŒã«ç³»ããŒã³ã¿ã«ãã©ãŒã¯
éæ¡æ£æ§ã§ããããšãæãŸãããååéã¯450ã
è¶ãããã®ã奜ãŸããã
è²çŸåäž»è¬ã®é žåäœãšã«ãããªã³ã°ããŠé¢è±åºã
è¡šãããããã«ã€ããŠãå ã«èšèŒããã ã¯ã¢ã«ãã«ãã¢ãªãŒã«ããããç°ãè¡šããã ã¢ãªãŒã«ãšããŠã¯å¥œãŸããã¯çœ®æãªããã¯ç¡çœ®
æã®ããšãã«ãè¡šããããããç°ãšããŠã¯å ·äœç
ã«ã¯ãã©ã³ç°ãããªããšã³ç°ãªã©ãæããããã 以äžã«æ¬çºæã«åºã¥ãå ·äœäŸã以äžã«ç€ºããã
æ¬çºæã¯ãããã«éå®ããããã®ã§ã¯ãªãã ãªããæ¬çºæã«ä¿ãã1Hâãã©ãŸããïŒïŒïŒ
âãââããªã¢ãŸãŒã«ç³»ããŒã³ã¿ã«ãã©ãŒã¯
éæ¡æ£æ§ã§ããããšãæãŸãããååéã¯450ã
è¶ãããã®ã奜ãŸããã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
次ã«åææ³ãèšèŒããããR2âSO2âR1â
COOHãåæããåŸã®1Hâãã©ãŸããïŒïŒïŒâ
ãââããªã¢ãŸãŒã«ã®åæã¯Research
Disclosure 12443ããã³Journal of the
Chemical Society Perkin ïŒ 1977ïŒ2047ã
2052ãåèã«è¡ããæŽã«ïŒäœé¢è±åºã®å°å ¥ã¯ç±³åœ
ç¹èš±3725067å·ããã³ç¹éæ59â99437å·ãåèã«
ããã R2âSO2âR1âCOOHã¯ããããã察å¿ãã
R2ââR1âCOOHãç¹éæ47â24321å·èšèŒã®
æ¹æ³ã«åŸãéé žåæ°ŽçŽ ã«ãŠé žåããããšã«ããåŸ
ãã ååç©äŸ(1)ã®åæ åå¿ã¹ããŒã ãèšããšä»¥äžã®ããã«ãªãã
COOHãåæããåŸã®1Hâãã©ãŸããïŒïŒïŒâ
ãââããªã¢ãŸãŒã«ã®åæã¯Research
Disclosure 12443ããã³Journal of the
Chemical Society Perkin ïŒ 1977ïŒ2047ã
2052ãåèã«è¡ããæŽã«ïŒäœé¢è±åºã®å°å ¥ã¯ç±³åœ
ç¹èš±3725067å·ããã³ç¹éæ59â99437å·ãåèã«
ããã R2âSO2âR1âCOOHã¯ããããã察å¿ãã
R2ââR1âCOOHãç¹éæ47â24321å·èšèŒã®
æ¹æ³ã«åŸãéé žåæ°ŽçŽ ã«ãŠé žåããããšã«ããåŸ
ãã ååç©äŸ(1)ã®åæ åå¿ã¹ããŒã ãèšããšä»¥äžã®ããã«ãªãã
ãåã
ãåã
ãåã
ïŒïŒã®åæ
ïŒïŒãã®ãã®ã¯Journal of the Chemical
Society Perkin ïŒ1977ïŒ2047ã2052ã«èšèŒ
ãããŠãããããã®æ¹æ³ã«ã®ã€ãšã€ãŠåæããã ïŒïŒã®åæ 92ïœã®ïŒïŒãïŒã®ã¢ã»ããããªã«ã«åæ£
ããããªãšãã«ã¢ãã³60ïœãå ãç ®æ²žéæµäžã«ã
222ïœã®é žãããªãã«ã¯ããªãã§é žã¯ããªããšã
ããã®ã滎äžããããã®åŸ30åéæµãããå·åŽåŸ
çæããçµæ¶ãåããããæ°ŽæŽã也ç¥ããã80
ïŒ ã®åçã§ç®çãåŸãããã ïŒïŒã®åæ 1.5ã®ãã«ãšã³äžã«193ïœã®ïŒïŒããã³53.5
ïœã®ãªãã·å¡©åãªã³ãå ãïŒæéç ®æ²žéæµããã
ãã®åŸãã«ãšã³ãçå»ããæ®æž£ã«1.5ã®ã¢ã»ã
ãããªã«ããã³80ïœã®ããªãžã³ãå ãã1.5æé
ç ®æ²žéæµãããã¢ã»ããããªã«ãçå»ããæ°Žãå
ãçæããçµæ¶ãåãããæ°ŽæŽã也ç¥åŸã¢ã»ã
ãããªã«åçµæ¶ããŠç®çç©ïŒïŒãåŸãã ïŒïŒã®åæ 130ïœã®ïŒïŒãæ°·é ¢é žïŒãæ¿ç¡«é ž100mlãæ°Ž
20mlã®æ··æ¶²ã«å ã10æéç ®æ²žéæµãããæŸå·åŸæ°Ž
ïŒãèæ§ãœãŒã180ïœãããªãèæ§ãœãŒã氎溶
液ãæªæäžæ³šå ãããæåºããçµæ¶ãåããå
åæ°ŽæŽããã也ç¥ããŠç®çç©ïŒïŒãåŸãã ååç©äŸ(1)ã®åæ 20ïœã®ïŒïŒãã¯ãããã«ã ã«æº¶è§£ããåœéã®
âã¯ãã«ã¹ã¯ã·ã³ã€ãããå ãã宀枩ã«ãŠïŒæ
éåå¿ãããããã®åŸåå¿æ¶²ãåžã¢ã«ã«ãªæŽæµ
ããæŽã«ååæ°ŽæŽãããã¯ãããã«ã ãçå»ãæ®
枣ã«ã€ããŠããã³ãŒã³ïŒã¢ã»ãã³ãã·ãªã«ã²ã«ã
æ äœãšããã«ã©ã ã¯ããããè¡ã粟補ãããç®ç
ç©ã®ç¢ºèªã¯æ žç£æ°å ±é³Žã¹ãã¯ãã«ããã³ãã¹ã¹ã
ã¯ãã«ã«ãŠè¡ã€ãã åèš(1)以å€ã®1Hâãã©ãŸããïŒïŒïŒâãâ
âããªã¢ãŸãŒã«æ žã¯äŸ(1)ã®æ¹æ³ã«æºããŠåæã
ãã (5)ïŒ(17)ïŒ(19)ã®é¢è±åºã®å°å ¥ã¯ãã¯ãç±³åœç¹
èš±3725067å·ããã³ç¹éæ59â99437å·ãåèã«ã
ãã æ¬çºæãçšããŠäœãããããã²ã³åéã«ã©ãŒå
çæå ææã«ã¯åŸæ¥ããçšããããŠããè²çŽ 圢æ
ã«ãã©ãŒãå«ãã§ããŠãããã é»è²çºè²ã«ãã©ãŒãšããŠã¯ãå ¬ç¥ã®ééã±ãã¡
ãã¬ã³ç³»ã«ãã©ãŒãçšããããšãã§ãããããã
ã®ãã¡ããã³ãŸã€ã«ã¢ã»ãã¢ããªãç³»ããã³ãã
ãã€ã«ã¢ã»ãã¢ããªãç³»ååç©ã¯æå©ã§ãããçš
ãåŸãé»è²çºè²ã«ãã©ãŒã®å ·äœäŸã¯ãç±³åœç¹èš±
2875057å·ãå3265506å·ãå3408194å·ãå
3551155å·ãå3582322å·ãå3725072å·ãå
3891445å·ã西ç¬ç¹èš±1547868å·ã西ç¬åºé¡å ¬é
2219917å·ãå2261361å·ãå2414006å·ãè±åœç¹
èš±1425020å·ãç¹å ¬æ51â10783å·ãç¹éæ47â
26133å·ãå48â73147å·ãå51â102036å·ãå50
â6341å·ãå50â123342å·ãå50â130442å·ãå
51â21827å·ãå50â87650å·ãå52â82424å·ã
å52â115219å·ãªã©ã«èšèŒããããã®ã§ããã ã·ã¢ã³çºè²ã«ãã©ãŒãšããŠã¯ãããšããŒã«ç³»å
åç©ãããããŒã«ç³»ååç©ãªã©ãçšããããšãã§
ããããã®å ·äœäŸã¯ç±³åœç¹èš±2369929å·ãå
2434272å·ãå2474293å·ãå2521908å·ãå
2895826å·ãå3034892å·ãå3311476å·ãå
3458315å·ãå3476563å·ãå3583971å·ãå
3591383å·ãå3767411å·ãå4004929å·ã西ç¬ç¹
èš±åºé¡ïŒOLSïŒ2414830å·ãå2454329å·ãç¹é
æ48â59838å·ãå51â26034å·ãå48â5055å·ã
å51â146828å·ãå52â69624å·ãå52â90932å·
ã«èšèŒã®ãã®ã§ããã ããŒã³ã¿çºè²ã«ãã©ãŒãšããŠã¯ãæ¬çºæã®ã«ã
ã©ãŒãåç¬ã§ãŸãã¯ïŒçš®ä»¥äžäœµçšããŠãããã€ã
ããªããæŽã«åŸæ¥å ¬ç¥ã®ãã©ãŸãã³ç³»ååç©ãã€
ã³ããŸãã³ç³»ååç©ãã·ã¢ãã¢ã»ãã«ç³»ååç©ã
ãã©ãŸãªããã³ãã€ãããŸãŒã«ç³»ååç©ããã©ãŸ
ãããªã¢ãŸãŒã«ç³»ååç©ãªã©ãé©å®äœµçšããŠãã
ãŸããªããããããªããå°ãªããšãäžã€ã¯æ¬çºæ
ã®ã«ãã©ãŒã§ããã ãŸãè²è£æ£å¹æãæããã«ã©ãŒãã«ãã©ãŒãæŽ
ã«ã¯ç»è³ªåäžã®ããçŸåæå¶å€æŸåºã«ãã©ãŒïŒã
ãããDIRã«ãã©ãŒïŒãå¿ èŠã«å¿ããŠæ¬çºæã«ã
ã©ãŒãšå ±ã«çšããããšãåºæ¥ãã æ¬çºæã®ããŒã³ã¿ã«ãã©ãŒããã³ãããšä¿ãå
ã«ãã©ãŒãããã²ã³åéä¹³å€å±€ã«å°å ¥ããã«ã¯å ¬
ç¥ã®æ¹æ³ãäŸãã°ç±³åœç¹èš±2322027å·ã«èšèŒã®æ¹
æ³ãªã©ãçšããããã ããšãã°ãã¿ãŒã«é žã¢ã«ãã«ãšã¹ãã«ïŒãžãã
ã«ãã¿ã¬ãŒãããžãªã¯ãã«ãã¿ã¬ãŒããªã©ïŒããª
ã³é žãšã¹ãã«ïŒãžããšãã«ããªã¹ããšãŒããããª
ããšãã«ããªã¹ããšãŒããããªã¯ã¬ãžã«ããªã¹ã
ãšãŒãããžãªã¯ãã«ããã«ããªã¹ããšãŒãïŒãã¯
ãšã³é žãšã¹ãã«ïŒããšãã°ã¢ã»ãã«ã¯ãšã³é žããª
ããã«ïŒãå®æ¯éŠé žãšã¹ãã«ïŒããšãã°å®æ¯éŠé ž
ãªã¯ãã«ïŒãã¢ã«ãã«ã¢ããïŒããšãã°ãžãšãã«
ã©ãŠãªã«ã¢ããïŒãèèªé žãšã¹ãã«é¡ïŒããšãã°
ãžãããã·ãšãã«ãµã¯ã·ããŒãããžãªã¯ãã«ã¢ãŒ
ã¬ãŒãïŒãããªã¡ã·ã³é žãšã¹ãã«é¡ïŒããšãã°ã
ãªã¡ã·ã³é žããªããã«ïŒãªã©ããŸãã¯æ²žç¹çŽ30â
ä¹è³150âã®ææ©æº¶åªãããšãã°é ¢é žãšãã«ãé ¢
é žããã«ã®ããšãäœçŽã¢ã«ãã«ã¢ã»ããŒãããã
ããªã³é žãšãã«ãïŒçŽããã«ã¢ã«ã³ãŒã«ãã¡ãã«
ã€ãœããã«ã±ãã³ãβâãšããã·ãšãã«ã¢ã»ããŒ
ããã¡ãã«ã»ããœã«ãã¢ã»ããŒãçã«æº¶è§£ããã®
ã¡ã芪氎æ§ã³ãã€ãã«åæ£ããããäžèšã®é«æ²žç¹
ææ©æº¶åªãšäœæ²žç¹ææ©æº¶åªãšãæ··åããŠçšããŠã
ããã ãŸãç¹å ¬æ51â39853å·ãç¹éæ51â59943å·ã«
èšèŒãããŠããéåç©ã«ããåæ£æ³ã䜿çšããã
ãšãã§ããã æ¬çºæã®ããŒã³ã¿ã«ãã©ãŒãããã²ã³åéä¹³å€
å±€ã«æ·»å ããå Žåãéåžžããã²ã³åéïŒã¢ã«åœã
0.005ãïŒã¢ã«ã奜ãŸããã¯0.03ã0.5ã¢ã«ã®ç¯å²
ã§æ·»å ãããã æ¬çºæã®ããŒã³ã¿ã«ãã©ãŒãã圢æãããè²çŽ
ç»åèªèº«åŒ·ãèå æ§ã瀺ããã耪è²é²æ¢å€ã䜵çš
ãããæŽã«ã¯çŽ«å€ç·åžåå€ãå«æããå±€ãäžå±€ã«
èšãããšããããšã«ãã€ãŠæŽã«èå æ§ã¯åäžã
ãã 耪è²é²æ¢å€ãšããŠã¯ãããšãã°ç±³åœç¹èš±
2360290å·ãå2418613å·ãå2673314å·ãå
2701197å·ãå2704713å·ãå2728659å·ãå
2732300å·ãå2735765å·ãå2710801å·ãå
2816028å·ãè±åœç¹èš±1363921å·çã«èšèŒãããã
ã€ããããã³èªå°äœãç±³åœç¹èš±3457079å·ãå
3069262å·çã«èšèŒããã没é£åé žèªå°äœãç±³åœ
ç¹èš±2735765å·ãå3698909å·ãç¹å ¬æ49â20977
å·ãå52â6623å·ã«èšèŒãããïœâã¢ã«ã³ãã·ã
ãšããŒã«é¡ãç±³åœç¹èš±3432300å·ãå3573050å·ã
å3574627å·ãå3764337å·ãç¹éæ52â35633å·ã
å52â147434å·ãå52â152225å·ã«èšèŒãããïœ
âãªãã·ããšããŒã«èªå°äœãç±³åœç¹èš±3700455å·
ã«èšèŒã®ãã¹ããšããŒã«é¡çãããã 玫å€ç·åžåå€ãšããŠã¯ãäŸãã°ã¢ãªãŒã«åºã§çœ®
æããããã³ãŸããªã¢ãŸãŒã«ååç©ïŒäŸãã°ç±³åœ
ç¹èš±3533794å·ã«èšèŒã®ãã®ïŒãïŒâãã¢ãŸãªãã³
ååç©ïŒäŸãã°ç±³åœç¹èš±3314794å·ãå3352681å·
ã«èšèŒã®ãã®ïŒããã³ãŸããšãã³ååç©ïŒäŸãã°
ç¹éæ46â2784å·ã«èšèŒã®ãã®ïŒãã±ã€ãé žãšã¹
ãã«ååç©ïŒäŸãã°ç±³åœç¹èš±3705805å·ãå
3707375å·ã«èšèŒã®ãã®ïŒããã¿ãžãšã³ååç©ïŒäŸ
ãã°ç±³åœç¹èš±4045229å·ã«èšèŒã®ãã®ïŒããããã¯
ãã³ãŸãªãã·ããŒã«ååç©ïŒäŸãã°ç±³åœç¹èš±
3700455å·ã«èšèŒã®ãã®ïŒãçšããããšãã§ããã
ããã«ç±³åœç¹èš±3499762å·ãç¹éæ54â48535å·ã«
èšèŒã®ãã®ãçšããããšãã§ããã æ¬çºæã«äœ¿çšãããããã²ã³åéä¹³å€ã«çšãã
ããããã²ã³åéãšããŠã¯ãèåéãå¡©åéãæ²
èåéãå¡©èåéãå¡©æ²èåéçã®éåžžã®ããã²
ã³åéä¹³å€ã«äœ¿çšãããä»»æã®ãã®ãå«ãŸããã
æ¬çºæã«äœ¿çšãããããã²ã³åéã¯å¿ èŠãªæå æ³¢
é·åã«æå æ§ãä»äžããããã«ãé©åœãªå¢æè²çŽ
ã®éžæã«ããåå å¢æããªããããçšããããè²
çŽ ã«ã¯ã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ãã³è²çŽ ãè€åã·
ã¢ãã³è²çŽ ãè€åã¡ãã·ã¢ãã³è²çŽ ãããããŒã©
ãŒã·ã¢ãã³è²çŽ ãããã·ã¢ãã³è²çŽ ãã¹ããªã«è²
çŽ ããã³ãããªããœããŒã«è²çŽ ãå å«ãããã æçšãªå¢æè²çŽ ãšããŠã¯ãäŸãã°ãã€ãç¹èš±
929080å·ãç±³åœç¹èš±2231658å·ãå2493748å·ãå
2503776å·ãå2519001å·ãå2912329å·ãå
3656959å·ãå3672897å·ãå3694217å·ãå
4025349å·ãå4046572å·ãè±åœç¹èš±1242588å·ã
ç¹å ¬æ44â14030å·ãå52â24844å·ã«èšèŒããã
ãã®ãæããããšãåºæ¥ãã ãããã®å¢æè²çŽ ã¯åç¬ã«çšããŠãããããã
ããã®çµåããçšããŠããããå¢æè²çŽ ã®çµåã
ã¯ãç¹ã«åŒ·è²å¢æã®ç®çã§ãã°ãã°çšããããã
ãã®ä»£è¡šäŸã¯ãç±³åœç¹èš±2688545å·ãå2977229
å·ãå3397060å·ãå3522052å·ãå3527641å·ã
å3617293å·ãå3628964å·ãå3666480å·ãå
3672898å·ãå3679428å·ãå3703377å·ãå
3769301å·ãå3814609å·ãå3837862å·ãå
4026707å·ãè±åœç¹èš±1344281å·ãå1507803å·ã
ç¹å ¬æ43â4936å·ãå53â12375å·ãç¹éæ52â
110618å·ãå52â109925å·ã«èšèŒãããŠããã ãŸãæ¬çºæã«äœ¿çšãããããã²ã³åéä¹³å€ã¯ã
çš®ã ã®å ¬ç¥ã®åççšæ·»å å€ãå«æãããããšãåº
æ¥ããäŸãã°Research Disclosure 17643ã«èšèŒ
ãããŠãããåŠãåççšæ·»å å€ã§ããã æ¬çºæããã²ã³åéåçæå ææã®æ¯æäœãšã
ãŠã¯ããã©ã¹ããã¯ãã€ã«ã ããã©ã¹ããã¯ã©ã
ããŒãçŽããã©ã€ã¿çŽãåæçŽçåŸæ¥ç¥ãããã
ã®ã䜿çšç®çã«å¿ããŠé©å®éžæããã°ããã ãŸãæ¬çºæã®ããã²ã³åéã«ã©ãŒåçæå ææ
ã¯åœæ¥çã«æŒããŠçšããããä»»æã®æ§æãæ¡ãã
ãšãã§ããã ããããŠæ§æãããæ¬çºæã®ããã²ã³åéã«ã©
ãŒåçæå ææã¯ãé²å ããåŸçºè²çŸååŠçãšã
ãŠçš®ã ã®åçåŠçæ¹æ³ãçšããããã æ¬çºæã«ãããŠçºè²çŸå液ã«äœ¿çšãããè³éŠæ
第ïŒçŽã¢ãã³çºè²çŸåäž»è¬ã¯çš®ã ã®ã«ã©ãŒåçã
ãã»ã¹ã«ãããŠåºç¯å²ã«äœ¿çšãããŠããå ¬ç¥ã®ã
ã®ãå å«ãããããããã®çŸåå€ã¯ã¢ããããšã
ãŒã«ç³»ããã³ïœâããšãã¬ã³ãžã¢ãã³ç³»èªå°äœã
å«ãŸããããããã®ååç©ã¯éé¢ç¶æ ããå®å®ã®
ããäžè¬ã«å¡©ã®åœ¢ãäŸãã°å¡©é žå¡©ãŸãã¯ç¡«é žå¡©ã®
圢ã§äœ¿çšãããããŸããããã®ååç©ã¯ãäžè¬ã«
çºè²çŸå液ïŒã«ã€ããŠçŽ0.1ïœãçŽ30ïœã®æ¿åºŠã
奜ãŸããã¯çºè²çŸå液ïŒã«ã€ããŠçŽïŒïœãçŽ
1.5ïœã®æ¿åºŠã§äœ¿çšããã ã¢ããããšããŒã«ç³»çŸåå€ãšããŠã¯ãäŸãã°ïœ
âã¢ããããšããŒã«ãïœâã¢ããããšããŒã«ãïŒ
âã¢ããâïŒâãªãã·ãã«ãšã³ãïŒâã¢ããâïŒ
âãªãã·ãã«ãšã³ãïŒâãªãã·âïŒâã¢ããâ
ïŒïŒïŒâãžã¡ãã«ãã³ãŒã³ãªã©ãå«ãŸããã ç¹ã«æçšãªç¬¬ïŒçŽè³éŠæã¢ããç³»çºè²çŸåå€ã¯
ïŒNâ²âãžã¢ã«ãã«âïœâããšãã¬ã³ãžã¢ãã³
ç³»ååç©ã§ãããã¢ã«ãã«åºããã³ããšãã«åºã¯
ä»»æã®çœ®æåºã§çœ®æãããŠããŠãããããã®äžã§
ãç¹ã«æçšãªååç©äŸãšããŠã¯ãïŒNâ²âãžãš
ãã«âïœâããšãã¬ã³ãžã¢ãã³å¡©é žå¡©ãâã¡ã
ã«âïœâããšãã¬ã³ãžã¢ãã³å¡©é žå¡©ãïŒNâ²â
ãžã¡ãã«âïœâããšãã¬ã³ãžã¢ãã³å¡©é žå¡©ãïŒâ
ã¢ããâïŒâïŒïŒ®âãšãã«ââããã·ã«ã¢ããïŒ
âãã«ãšã³ãâãšãã«ââβâã¡ã¿ã³ã¹ã«ã
ã³ã¢ãããšãã«âïŒâã¡ãã«âïŒâã¢ããã¢ããª
ã³ç¡«é žå¡©ãâãšãã«ââβâããããã·ãšã
ã«ã¢ããã¢ããªã³ãïŒâã¢ããâïŒâã¡ãã«â
ïŒNâ²âãžãšãã«ã¢ããªã³ãïŒâã¢ããââ
ïŒïŒâã¡ããã·ãšãã«ïŒââãšãã«âïŒâã¡ãã«
ã¢ããªã³âïœâãã«ãšã³ã¹ã«ãããŒããªã©ãæã
ãããšãã§ããã æ¬çºæã®åŠçã«ãããŠäœ¿çšãããçºè²çŸå液ã«
ã¯ãåèšç¬¬ïŒçŽè³éŠæã¢ãã³ç³»çºè²çŸåå€ã«å ã
ãŠæŽã«çºè²çŸå液ã«éåžžæ·»å ãããŠããçš®ã ã®æ
åãäŸãã°æ°Žé žåãããªãŠã ãçé žãããªãŠã ã
çé žã«ãªãŠã ãªã©ã®ã¢ã«ã«ãªå€ãã¢ã«ã«ãªéå±äº
ç¡«é žå¡©ãã¢ã«ã«ãªéå±éäºç¡«é žå¡©ãã¢ã«ã«ãªéå±
ããªã·ã¢ã³é žå¡©ãã¢ã«ã«ãªéå±ããã²ã³åç©ãã
ã³ãžã«ã¢ã«ã³ãŒã«ãæ°Žè»åå€ããã³æ¿ååå€ãªã©
ãä»»æã«å«æããããããšãã§ããããã®çºè²çŸ
å液ã®PHå€ã¯ãéåžžïŒä»¥äžã§ãããæãäžè¬çã«
ã¯çŽ10ãçŽ13ã§ããã æ¬çºæã«ãããŠã¯ãçºè²çŸååŠçããåŸãå®ç
èœãæããåŠç液ã§åŠçãããã該å®çèœãæã
ãåŠç液ãå®ç液ã§ããå Žåããã®åã«æŒçœåŠç
ãè¡ãããã該æŒçœå·¥çšã«çšããæŒçœæ¶²ãããã¯
æŒçœå®ç液ã«ãããŠäœ¿çšãããæŒçœå€ãšããŠã¯æ
æ©é žã®éå±é¯å¡©ãçšãããã該éå±é¯å¡©ã¯ãçŸå
ã«ãã€ãŠçæããéå±éãé žåããŠããã²ã³åé
ã«ããããšåæã«çºè²å€ã®æªçºè²éšãçºè²ããã
äœçšãæãããã®ã§ããã®æ§é ã¯ã¢ããããªã«ã«
ãã³é žãŸãã¯èé žãã¯ãšã³é žçã®ææ©é žã§éãã³
ãã«ããé çã®éå±ã€ãªã³ãé äœãããã®ã§ã
ãããã®ãããªææ©é žã®éå±é¯å¡©ã圢æãããã
ã«çšããããæã奜ãŸããææ©é žãšããŠã¯ãããª
ã«ã«ãã³é žãŸãã¯ã¢ããããªã«ã«ãã³é žãæãã
ããããããã®ããªã«ã«ãã³é žãŸãã¯ã¢ããããª
ã«ã«ãã³é žã¯ã¢ã«ã«ãªéå±å¡©ãã¢ã³ã¢ããŠã å¡©ã
ããã¯æ°Žæº¶æ§ã¢ãã³å¡©ã§ãã€ãŠãããã ãããã®å ·äœç代衚äŸãšããŠã¯ã次ã®ãã®ãæ
ããããšãã§ããã ãïŒã ãšãã¬ã³ãžã¢ãã³ããã©é ¢é ž ãïŒã ãžãšãã¬ã³ããªã¢ãã³ãã³ã¿é ¢é ž ãïŒã ãšãã¬ã³ãžã¢ãã³ââïŒÎ²âãªãã·ãš
ãã«ïŒâïŒNâ²ïŒNâ²âããªé ¢é ž ãïŒã ãããã¬ã³ãžã¢ãã³ããã©é ¢é ž ãïŒã ãããªãããªé ¢é ž ãïŒã ã·ã¯ããããµã³ãžã¢ãã³ããã©é ¢é ž ãïŒã ã€ãããžé ¢é ž ãïŒã ãžããããã·ãšãã«ã°ãªã·ã³ã¯ãšã³é ž
ïŒãŸãã¯é ç³é žïŒ
Society Perkin ïŒ1977ïŒ2047ã2052ã«èšèŒ
ãããŠãããããã®æ¹æ³ã«ã®ã€ãšã€ãŠåæããã ïŒïŒã®åæ 92ïœã®ïŒïŒãïŒã®ã¢ã»ããããªã«ã«åæ£
ããããªãšãã«ã¢ãã³60ïœãå ãç ®æ²žéæµäžã«ã
222ïœã®é žãããªãã«ã¯ããªãã§é žã¯ããªããšã
ããã®ã滎äžããããã®åŸ30åéæµãããå·åŽåŸ
çæããçµæ¶ãåããããæ°ŽæŽã也ç¥ããã80
ïŒ ã®åçã§ç®çãåŸãããã ïŒïŒã®åæ 1.5ã®ãã«ãšã³äžã«193ïœã®ïŒïŒããã³53.5
ïœã®ãªãã·å¡©åãªã³ãå ãïŒæéç ®æ²žéæµããã
ãã®åŸãã«ãšã³ãçå»ããæ®æž£ã«1.5ã®ã¢ã»ã
ãããªã«ããã³80ïœã®ããªãžã³ãå ãã1.5æé
ç ®æ²žéæµãããã¢ã»ããããªã«ãçå»ããæ°Žãå
ãçæããçµæ¶ãåãããæ°ŽæŽã也ç¥åŸã¢ã»ã
ãããªã«åçµæ¶ããŠç®çç©ïŒïŒãåŸãã ïŒïŒã®åæ 130ïœã®ïŒïŒãæ°·é ¢é žïŒãæ¿ç¡«é ž100mlãæ°Ž
20mlã®æ··æ¶²ã«å ã10æéç ®æ²žéæµãããæŸå·åŸæ°Ž
ïŒãèæ§ãœãŒã180ïœãããªãèæ§ãœãŒã氎溶
液ãæªæäžæ³šå ãããæåºããçµæ¶ãåããå
åæ°ŽæŽããã也ç¥ããŠç®çç©ïŒïŒãåŸãã ååç©äŸ(1)ã®åæ 20ïœã®ïŒïŒãã¯ãããã«ã ã«æº¶è§£ããåœéã®
âã¯ãã«ã¹ã¯ã·ã³ã€ãããå ãã宀枩ã«ãŠïŒæ
éåå¿ãããããã®åŸåå¿æ¶²ãåžã¢ã«ã«ãªæŽæµ
ããæŽã«ååæ°ŽæŽãããã¯ãããã«ã ãçå»ãæ®
枣ã«ã€ããŠããã³ãŒã³ïŒã¢ã»ãã³ãã·ãªã«ã²ã«ã
æ äœãšããã«ã©ã ã¯ããããè¡ã粟補ãããç®ç
ç©ã®ç¢ºèªã¯æ žç£æ°å ±é³Žã¹ãã¯ãã«ããã³ãã¹ã¹ã
ã¯ãã«ã«ãŠè¡ã€ãã åèš(1)以å€ã®1Hâãã©ãŸããïŒïŒïŒâãâ
âããªã¢ãŸãŒã«æ žã¯äŸ(1)ã®æ¹æ³ã«æºããŠåæã
ãã (5)ïŒ(17)ïŒ(19)ã®é¢è±åºã®å°å ¥ã¯ãã¯ãç±³åœç¹
èš±3725067å·ããã³ç¹éæ59â99437å·ãåèã«ã
ãã æ¬çºæãçšããŠäœãããããã²ã³åéã«ã©ãŒå
çæå ææã«ã¯åŸæ¥ããçšããããŠããè²çŽ 圢æ
ã«ãã©ãŒãå«ãã§ããŠãããã é»è²çºè²ã«ãã©ãŒãšããŠã¯ãå ¬ç¥ã®ééã±ãã¡
ãã¬ã³ç³»ã«ãã©ãŒãçšããããšãã§ãããããã
ã®ãã¡ããã³ãŸã€ã«ã¢ã»ãã¢ããªãç³»ããã³ãã
ãã€ã«ã¢ã»ãã¢ããªãç³»ååç©ã¯æå©ã§ãããçš
ãåŸãé»è²çºè²ã«ãã©ãŒã®å ·äœäŸã¯ãç±³åœç¹èš±
2875057å·ãå3265506å·ãå3408194å·ãå
3551155å·ãå3582322å·ãå3725072å·ãå
3891445å·ã西ç¬ç¹èš±1547868å·ã西ç¬åºé¡å ¬é
2219917å·ãå2261361å·ãå2414006å·ãè±åœç¹
èš±1425020å·ãç¹å ¬æ51â10783å·ãç¹éæ47â
26133å·ãå48â73147å·ãå51â102036å·ãå50
â6341å·ãå50â123342å·ãå50â130442å·ãå
51â21827å·ãå50â87650å·ãå52â82424å·ã
å52â115219å·ãªã©ã«èšèŒããããã®ã§ããã ã·ã¢ã³çºè²ã«ãã©ãŒãšããŠã¯ãããšããŒã«ç³»å
åç©ãããããŒã«ç³»ååç©ãªã©ãçšããããšãã§
ããããã®å ·äœäŸã¯ç±³åœç¹èš±2369929å·ãå
2434272å·ãå2474293å·ãå2521908å·ãå
2895826å·ãå3034892å·ãå3311476å·ãå
3458315å·ãå3476563å·ãå3583971å·ãå
3591383å·ãå3767411å·ãå4004929å·ã西ç¬ç¹
èš±åºé¡ïŒOLSïŒ2414830å·ãå2454329å·ãç¹é
æ48â59838å·ãå51â26034å·ãå48â5055å·ã
å51â146828å·ãå52â69624å·ãå52â90932å·
ã«èšèŒã®ãã®ã§ããã ããŒã³ã¿çºè²ã«ãã©ãŒãšããŠã¯ãæ¬çºæã®ã«ã
ã©ãŒãåç¬ã§ãŸãã¯ïŒçš®ä»¥äžäœµçšããŠãããã€ã
ããªããæŽã«åŸæ¥å ¬ç¥ã®ãã©ãŸãã³ç³»ååç©ãã€
ã³ããŸãã³ç³»ååç©ãã·ã¢ãã¢ã»ãã«ç³»ååç©ã
ãã©ãŸãªããã³ãã€ãããŸãŒã«ç³»ååç©ããã©ãŸ
ãããªã¢ãŸãŒã«ç³»ååç©ãªã©ãé©å®äœµçšããŠãã
ãŸããªããããããªããå°ãªããšãäžã€ã¯æ¬çºæ
ã®ã«ãã©ãŒã§ããã ãŸãè²è£æ£å¹æãæããã«ã©ãŒãã«ãã©ãŒãæŽ
ã«ã¯ç»è³ªåäžã®ããçŸåæå¶å€æŸåºã«ãã©ãŒïŒã
ãããDIRã«ãã©ãŒïŒãå¿ èŠã«å¿ããŠæ¬çºæã«ã
ã©ãŒãšå ±ã«çšããããšãåºæ¥ãã æ¬çºæã®ããŒã³ã¿ã«ãã©ãŒããã³ãããšä¿ãå
ã«ãã©ãŒãããã²ã³åéä¹³å€å±€ã«å°å ¥ããã«ã¯å ¬
ç¥ã®æ¹æ³ãäŸãã°ç±³åœç¹èš±2322027å·ã«èšèŒã®æ¹
æ³ãªã©ãçšããããã ããšãã°ãã¿ãŒã«é žã¢ã«ãã«ãšã¹ãã«ïŒãžãã
ã«ãã¿ã¬ãŒãããžãªã¯ãã«ãã¿ã¬ãŒããªã©ïŒããª
ã³é žãšã¹ãã«ïŒãžããšãã«ããªã¹ããšãŒããããª
ããšãã«ããªã¹ããšãŒããããªã¯ã¬ãžã«ããªã¹ã
ãšãŒãããžãªã¯ãã«ããã«ããªã¹ããšãŒãïŒãã¯
ãšã³é žãšã¹ãã«ïŒããšãã°ã¢ã»ãã«ã¯ãšã³é žããª
ããã«ïŒãå®æ¯éŠé žãšã¹ãã«ïŒããšãã°å®æ¯éŠé ž
ãªã¯ãã«ïŒãã¢ã«ãã«ã¢ããïŒããšãã°ãžãšãã«
ã©ãŠãªã«ã¢ããïŒãèèªé žãšã¹ãã«é¡ïŒããšãã°
ãžãããã·ãšãã«ãµã¯ã·ããŒãããžãªã¯ãã«ã¢ãŒ
ã¬ãŒãïŒãããªã¡ã·ã³é žãšã¹ãã«é¡ïŒããšãã°ã
ãªã¡ã·ã³é žããªããã«ïŒãªã©ããŸãã¯æ²žç¹çŽ30â
ä¹è³150âã®ææ©æº¶åªãããšãã°é ¢é žãšãã«ãé ¢
é žããã«ã®ããšãäœçŽã¢ã«ãã«ã¢ã»ããŒãããã
ããªã³é žãšãã«ãïŒçŽããã«ã¢ã«ã³ãŒã«ãã¡ãã«
ã€ãœããã«ã±ãã³ãβâãšããã·ãšãã«ã¢ã»ããŒ
ããã¡ãã«ã»ããœã«ãã¢ã»ããŒãçã«æº¶è§£ããã®
ã¡ã芪氎æ§ã³ãã€ãã«åæ£ããããäžèšã®é«æ²žç¹
ææ©æº¶åªãšäœæ²žç¹ææ©æº¶åªãšãæ··åããŠçšããŠã
ããã ãŸãç¹å ¬æ51â39853å·ãç¹éæ51â59943å·ã«
èšèŒãããŠããéåç©ã«ããåæ£æ³ã䜿çšããã
ãšãã§ããã æ¬çºæã®ããŒã³ã¿ã«ãã©ãŒãããã²ã³åéä¹³å€
å±€ã«æ·»å ããå Žåãéåžžããã²ã³åéïŒã¢ã«åœã
0.005ãïŒã¢ã«ã奜ãŸããã¯0.03ã0.5ã¢ã«ã®ç¯å²
ã§æ·»å ãããã æ¬çºæã®ããŒã³ã¿ã«ãã©ãŒãã圢æãããè²çŽ
ç»åèªèº«åŒ·ãèå æ§ã瀺ããã耪è²é²æ¢å€ã䜵çš
ãããæŽã«ã¯çŽ«å€ç·åžåå€ãå«æããå±€ãäžå±€ã«
èšãããšããããšã«ãã€ãŠæŽã«èå æ§ã¯åäžã
ãã 耪è²é²æ¢å€ãšããŠã¯ãããšãã°ç±³åœç¹èš±
2360290å·ãå2418613å·ãå2673314å·ãå
2701197å·ãå2704713å·ãå2728659å·ãå
2732300å·ãå2735765å·ãå2710801å·ãå
2816028å·ãè±åœç¹èš±1363921å·çã«èšèŒãããã
ã€ããããã³èªå°äœãç±³åœç¹èš±3457079å·ãå
3069262å·çã«èšèŒããã没é£åé žèªå°äœãç±³åœ
ç¹èš±2735765å·ãå3698909å·ãç¹å ¬æ49â20977
å·ãå52â6623å·ã«èšèŒãããïœâã¢ã«ã³ãã·ã
ãšããŒã«é¡ãç±³åœç¹èš±3432300å·ãå3573050å·ã
å3574627å·ãå3764337å·ãç¹éæ52â35633å·ã
å52â147434å·ãå52â152225å·ã«èšèŒãããïœ
âãªãã·ããšããŒã«èªå°äœãç±³åœç¹èš±3700455å·
ã«èšèŒã®ãã¹ããšããŒã«é¡çãããã 玫å€ç·åžåå€ãšããŠã¯ãäŸãã°ã¢ãªãŒã«åºã§çœ®
æããããã³ãŸããªã¢ãŸãŒã«ååç©ïŒäŸãã°ç±³åœ
ç¹èš±3533794å·ã«èšèŒã®ãã®ïŒãïŒâãã¢ãŸãªãã³
ååç©ïŒäŸãã°ç±³åœç¹èš±3314794å·ãå3352681å·
ã«èšèŒã®ãã®ïŒããã³ãŸããšãã³ååç©ïŒäŸãã°
ç¹éæ46â2784å·ã«èšèŒã®ãã®ïŒãã±ã€ãé žãšã¹
ãã«ååç©ïŒäŸãã°ç±³åœç¹èš±3705805å·ãå
3707375å·ã«èšèŒã®ãã®ïŒããã¿ãžãšã³ååç©ïŒäŸ
ãã°ç±³åœç¹èš±4045229å·ã«èšèŒã®ãã®ïŒããããã¯
ãã³ãŸãªãã·ããŒã«ååç©ïŒäŸãã°ç±³åœç¹èš±
3700455å·ã«èšèŒã®ãã®ïŒãçšããããšãã§ããã
ããã«ç±³åœç¹èš±3499762å·ãç¹éæ54â48535å·ã«
èšèŒã®ãã®ãçšããããšãã§ããã æ¬çºæã«äœ¿çšãããããã²ã³åéä¹³å€ã«çšãã
ããããã²ã³åéãšããŠã¯ãèåéãå¡©åéãæ²
èåéãå¡©èåéãå¡©æ²èåéçã®éåžžã®ããã²
ã³åéä¹³å€ã«äœ¿çšãããä»»æã®ãã®ãå«ãŸããã
æ¬çºæã«äœ¿çšãããããã²ã³åéã¯å¿ èŠãªæå æ³¢
é·åã«æå æ§ãä»äžããããã«ãé©åœãªå¢æè²çŽ
ã®éžæã«ããåå å¢æããªããããçšããããè²
çŽ ã«ã¯ã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ãã³è²çŽ ãè€åã·
ã¢ãã³è²çŽ ãè€åã¡ãã·ã¢ãã³è²çŽ ãããããŒã©
ãŒã·ã¢ãã³è²çŽ ãããã·ã¢ãã³è²çŽ ãã¹ããªã«è²
çŽ ããã³ãããªããœããŒã«è²çŽ ãå å«ãããã æçšãªå¢æè²çŽ ãšããŠã¯ãäŸãã°ãã€ãç¹èš±
929080å·ãç±³åœç¹èš±2231658å·ãå2493748å·ãå
2503776å·ãå2519001å·ãå2912329å·ãå
3656959å·ãå3672897å·ãå3694217å·ãå
4025349å·ãå4046572å·ãè±åœç¹èš±1242588å·ã
ç¹å ¬æ44â14030å·ãå52â24844å·ã«èšèŒããã
ãã®ãæããããšãåºæ¥ãã ãããã®å¢æè²çŽ ã¯åç¬ã«çšããŠãããããã
ããã®çµåããçšããŠããããå¢æè²çŽ ã®çµåã
ã¯ãç¹ã«åŒ·è²å¢æã®ç®çã§ãã°ãã°çšããããã
ãã®ä»£è¡šäŸã¯ãç±³åœç¹èš±2688545å·ãå2977229
å·ãå3397060å·ãå3522052å·ãå3527641å·ã
å3617293å·ãå3628964å·ãå3666480å·ãå
3672898å·ãå3679428å·ãå3703377å·ãå
3769301å·ãå3814609å·ãå3837862å·ãå
4026707å·ãè±åœç¹èš±1344281å·ãå1507803å·ã
ç¹å ¬æ43â4936å·ãå53â12375å·ãç¹éæ52â
110618å·ãå52â109925å·ã«èšèŒãããŠããã ãŸãæ¬çºæã«äœ¿çšãããããã²ã³åéä¹³å€ã¯ã
çš®ã ã®å ¬ç¥ã®åççšæ·»å å€ãå«æãããããšãåº
æ¥ããäŸãã°Research Disclosure 17643ã«èšèŒ
ãããŠãããåŠãåççšæ·»å å€ã§ããã æ¬çºæããã²ã³åéåçæå ææã®æ¯æäœãšã
ãŠã¯ããã©ã¹ããã¯ãã€ã«ã ããã©ã¹ããã¯ã©ã
ããŒãçŽããã©ã€ã¿çŽãåæçŽçåŸæ¥ç¥ãããã
ã®ã䜿çšç®çã«å¿ããŠé©å®éžæããã°ããã ãŸãæ¬çºæã®ããã²ã³åéã«ã©ãŒåçæå ææ
ã¯åœæ¥çã«æŒããŠçšããããä»»æã®æ§æãæ¡ãã
ãšãã§ããã ããããŠæ§æãããæ¬çºæã®ããã²ã³åéã«ã©
ãŒåçæå ææã¯ãé²å ããåŸçºè²çŸååŠçãšã
ãŠçš®ã ã®åçåŠçæ¹æ³ãçšããããã æ¬çºæã«ãããŠçºè²çŸå液ã«äœ¿çšãããè³éŠæ
第ïŒçŽã¢ãã³çºè²çŸåäž»è¬ã¯çš®ã ã®ã«ã©ãŒåçã
ãã»ã¹ã«ãããŠåºç¯å²ã«äœ¿çšãããŠããå ¬ç¥ã®ã
ã®ãå å«ãããããããã®çŸåå€ã¯ã¢ããããšã
ãŒã«ç³»ããã³ïœâããšãã¬ã³ãžã¢ãã³ç³»èªå°äœã
å«ãŸããããããã®ååç©ã¯éé¢ç¶æ ããå®å®ã®
ããäžè¬ã«å¡©ã®åœ¢ãäŸãã°å¡©é žå¡©ãŸãã¯ç¡«é žå¡©ã®
圢ã§äœ¿çšãããããŸããããã®ååç©ã¯ãäžè¬ã«
çºè²çŸå液ïŒã«ã€ããŠçŽ0.1ïœãçŽ30ïœã®æ¿åºŠã
奜ãŸããã¯çºè²çŸå液ïŒã«ã€ããŠçŽïŒïœãçŽ
1.5ïœã®æ¿åºŠã§äœ¿çšããã ã¢ããããšããŒã«ç³»çŸåå€ãšããŠã¯ãäŸãã°ïœ
âã¢ããããšããŒã«ãïœâã¢ããããšããŒã«ãïŒ
âã¢ããâïŒâãªãã·ãã«ãšã³ãïŒâã¢ããâïŒ
âãªãã·ãã«ãšã³ãïŒâãªãã·âïŒâã¢ããâ
ïŒïŒïŒâãžã¡ãã«ãã³ãŒã³ãªã©ãå«ãŸããã ç¹ã«æçšãªç¬¬ïŒçŽè³éŠæã¢ããç³»çºè²çŸåå€ã¯
ïŒNâ²âãžã¢ã«ãã«âïœâããšãã¬ã³ãžã¢ãã³
ç³»ååç©ã§ãããã¢ã«ãã«åºããã³ããšãã«åºã¯
ä»»æã®çœ®æåºã§çœ®æãããŠããŠãããããã®äžã§
ãç¹ã«æçšãªååç©äŸãšããŠã¯ãïŒNâ²âãžãš
ãã«âïœâããšãã¬ã³ãžã¢ãã³å¡©é žå¡©ãâã¡ã
ã«âïœâããšãã¬ã³ãžã¢ãã³å¡©é žå¡©ãïŒNâ²â
ãžã¡ãã«âïœâããšãã¬ã³ãžã¢ãã³å¡©é žå¡©ãïŒâ
ã¢ããâïŒâïŒïŒ®âãšãã«ââããã·ã«ã¢ããïŒ
âãã«ãšã³ãâãšãã«ââβâã¡ã¿ã³ã¹ã«ã
ã³ã¢ãããšãã«âïŒâã¡ãã«âïŒâã¢ããã¢ããª
ã³ç¡«é žå¡©ãâãšãã«ââβâããããã·ãšã
ã«ã¢ããã¢ããªã³ãïŒâã¢ããâïŒâã¡ãã«â
ïŒNâ²âãžãšãã«ã¢ããªã³ãïŒâã¢ããââ
ïŒïŒâã¡ããã·ãšãã«ïŒââãšãã«âïŒâã¡ãã«
ã¢ããªã³âïœâãã«ãšã³ã¹ã«ãããŒããªã©ãæã
ãããšãã§ããã æ¬çºæã®åŠçã«ãããŠäœ¿çšãããçºè²çŸå液ã«
ã¯ãåèšç¬¬ïŒçŽè³éŠæã¢ãã³ç³»çºè²çŸåå€ã«å ã
ãŠæŽã«çºè²çŸå液ã«éåžžæ·»å ãããŠããçš®ã ã®æ
åãäŸãã°æ°Žé žåãããªãŠã ãçé žãããªãŠã ã
çé žã«ãªãŠã ãªã©ã®ã¢ã«ã«ãªå€ãã¢ã«ã«ãªéå±äº
ç¡«é žå¡©ãã¢ã«ã«ãªéå±éäºç¡«é žå¡©ãã¢ã«ã«ãªéå±
ããªã·ã¢ã³é žå¡©ãã¢ã«ã«ãªéå±ããã²ã³åç©ãã
ã³ãžã«ã¢ã«ã³ãŒã«ãæ°Žè»åå€ããã³æ¿ååå€ãªã©
ãä»»æã«å«æããããããšãã§ããããã®çºè²çŸ
å液ã®PHå€ã¯ãéåžžïŒä»¥äžã§ãããæãäžè¬çã«
ã¯çŽ10ãçŽ13ã§ããã æ¬çºæã«ãããŠã¯ãçºè²çŸååŠçããåŸãå®ç
èœãæããåŠç液ã§åŠçãããã該å®çèœãæã
ãåŠç液ãå®ç液ã§ããå Žåããã®åã«æŒçœåŠç
ãè¡ãããã該æŒçœå·¥çšã«çšããæŒçœæ¶²ãããã¯
æŒçœå®ç液ã«ãããŠäœ¿çšãããæŒçœå€ãšããŠã¯æ
æ©é žã®éå±é¯å¡©ãçšãããã該éå±é¯å¡©ã¯ãçŸå
ã«ãã€ãŠçæããéå±éãé žåããŠããã²ã³åé
ã«ããããšåæã«çºè²å€ã®æªçºè²éšãçºè²ããã
äœçšãæãããã®ã§ããã®æ§é ã¯ã¢ããããªã«ã«
ãã³é žãŸãã¯èé žãã¯ãšã³é žçã®ææ©é žã§éãã³
ãã«ããé çã®éå±ã€ãªã³ãé äœãããã®ã§ã
ãããã®ãããªææ©é žã®éå±é¯å¡©ã圢æãããã
ã«çšããããæã奜ãŸããææ©é žãšããŠã¯ãããª
ã«ã«ãã³é žãŸãã¯ã¢ããããªã«ã«ãã³é žãæãã
ããããããã®ããªã«ã«ãã³é žãŸãã¯ã¢ããããª
ã«ã«ãã³é žã¯ã¢ã«ã«ãªéå±å¡©ãã¢ã³ã¢ããŠã å¡©ã
ããã¯æ°Žæº¶æ§ã¢ãã³å¡©ã§ãã€ãŠãããã ãããã®å ·äœç代衚äŸãšããŠã¯ã次ã®ãã®ãæ
ããããšãã§ããã ãïŒã ãšãã¬ã³ãžã¢ãã³ããã©é ¢é ž ãïŒã ãžãšãã¬ã³ããªã¢ãã³ãã³ã¿é ¢é ž ãïŒã ãšãã¬ã³ãžã¢ãã³ââïŒÎ²âãªãã·ãš
ãã«ïŒâïŒNâ²ïŒNâ²âããªé ¢é ž ãïŒã ãããã¬ã³ãžã¢ãã³ããã©é ¢é ž ãïŒã ãããªãããªé ¢é ž ãïŒã ã·ã¯ããããµã³ãžã¢ãã³ããã©é ¢é ž ãïŒã ã€ãããžé ¢é ž ãïŒã ãžããããã·ãšãã«ã°ãªã·ã³ã¯ãšã³é ž
ïŒãŸãã¯é ç³é žïŒ
ãïŒã ãšãã«ãšãŒãã«ãžã¢ãã³ããã©é
¢é
ž
ã10ã ã°ãªã³ãŒã«ãšãŒãã«ãžã¢ãã³ããã©é
¢é
ž
ã11ã ãšãã¬ã³ãžã¢ãã³ããã©ããããªã³é
ž
ã12ã ããšãã¬ã³ãžã¢ãã³ããã©é
¢é
ž
ã13ã ãšãã¬ã³ãžã¢ãã³ããã©é
¢é
žãžãããªãŠã
å¡© ã14ã ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žããã©ïŒããª
ã¡ãã«ã¢ã³ã¢ããŠã ïŒå¡© ã15ã ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žããã©ãããª
ãŠã å¡© ã16ã ãžãšãã¬ã³ããªã¢ãã³ãã³ã¿é ¢é žãã³ã¿ã
ããªãŠã å¡© ã17ã ãšãã¬ã³ãžã¢ãã³ââïŒÎ²âãªãã·ãšã
ã«ïŒâïŒNâ²ïŒNâ²âããªé ¢é žãããªãŠã å¡© ã18ã ãããã¬ã³ãžã¢ãã³ããã©é ¢é žãããªãŠã
å¡© ã19ã ãããªãããªé ¢é žãããªãŠã å¡© ã20ã ã·ã¯ããããµã³ãžã¢ãã³ããã©é ¢é žãããª
ãŠã å¡© 䜿çšãããæŒçœæ¶²ã¯ãåèšã®åŠãææ©é žã®éå±
é¯å¡©ãæŒçœå€ãšããŠå«æãããšå ±ã«ãçš®ã ã®æ·»å
å€ãå«ãããšãã§ãããæ·»å å€ãšããŠã¯ããšãã«
ã¢ã«ã«ãªãã©ã€ããŸãã¯ã¢ã³ã¢ããŠã ãã©ã€ãã
äŸãã°èåã«ãªãŠã ãèåãããªãŠã ãå¡©åãã
ãªãŠã ãèåã¢ã³ã¢ããŠã çã®åããã²ã³åå€ã
éå±å¡©ããã¬ãŒãå€ãå«æãããããšãæãŸã
ãããŸãç¡Œé žå¡©ãèé žå¡©ãé ¢é žå¡©ãçé žå¡©ãçé ž
å¡©çã®PHç·©è¡å€ãã¢ã«ãã«ã¢ãã³é¡ãããªãšãã¬
ã³ãªããµã€ãé¡çã®éåžžæŒçœæ¶²ã«æ·»å ããããšã
ç¥ãããŠãããã®ãé©å®æ·»å ããããšãã§ããã æŽã«å®ç液ããã³æŒçœå®ç液ã¯ãäºç¡«é žã¢ã³ã¢
ããŠã ãäºç¡«é žã«ãªãŠã ãéäºç¡«é žã¢ã³ã¢ããŠ
ã ãéäºç¡«é žã«ãªãŠã ãéäºç¡«é žãããªãŠã ãã¡
ã¿éäºç¡«é žã¢ã³ã¢ããŠã ãã¡ã¿éäºç¡«é žã«ãªãŠ
ã ãã¡ã¿éäºç¡«é žãããªãŠã çã®äºç¡«é žå¡©ãç¡Œ
é žãç¡Œç ãæ°Žé žåãããªãŠã ãæ°Žé žåã«ãªãŠã ã
çé žãããªãŠã ãçé žã«ãªãŠã ãéçé žãããªãŠ
ã ãéçé žã«ãªãŠã ãé ¢é žãé ¢é žãããªãŠã ãæ°Ž
é žåã¢ã³ã¢ããŠã çã®åçš®ã®å¡©ããæãPHç·©è¡å€
ãåç¬ãããã¯ïŒçš®ä»¥äžå«ãããšãã§ããã æŒçœå®ç液ïŒæµŽïŒã«æŒçœå®çè£å å€ãè£å ããª
ããæ¬çºæã®åŠçãè¡ãå Žåã該æŒçœå®ç液
ïŒæµŽïŒã«ããªç¡«é žå¡©ãããªã·ã¢ã³é žå¡©ãŸãã¯äºç¡«
é žå¡©çãå«æããããŠããããã該æŒçœå®çè£å
液ã«ãããã®å¡©é¡ãå«æããããŠåŠç济ã«è£å ã
ãŠãããã æ¬çºæã«ãããŠã¯æŒçœå®ç液ã®æŽ»æ§åºŠãé«ãã
ããã«æŒçœå®ç济äžããã³æŒçœå®çè£å 液ã®è²¯èµ
ã¿ã³ã¯å ã§ææã«ãã空æ°ã®å¹ã蟌ã¿ããŸãã¯é ž
çŽ ã®å¹ã蟌ã¿ãè¡ã€ãŠãããããããã¯é©åœãªé ž
åå€ãäŸãã°éé žåæ°ŽçŽ ãèçŽ é žå¡©ãéç¡«é žå¡©ç
ãé©å®æ·»å ããŠãããã ïŒå®æœäŸïŒ 次ã«å®æœäŸã«ãã€ãŠæ¬çºæã説æããããæ¬çº
æã¯ãããã«éå®ããããã®ã§ã¯ãªãã ãå®æœäŸ ïŒã 第ïŒè¡šã«ç€ºããããªæ¬çºæã®ããŒã³ã¿ã«ãã©ãŒ
ããã³æ¯èŒã®ã«ãã©ãŒãåã éïŒã¢ã«ã«å¯ŸããŠ
0.1ã¢ã«ã¥ã€åããã«ãã©ãŒééã®ïŒåéã®ããª
ã¯ã¬ãžã«ãã¹ããšãŒãããã³ïŒåéã®é ¢é žãšãã«
ãå ã60âã«å æž©ããŠå®å šã«æº¶è§£ããããã®æº¶æ¶²
ãã¢ã«ã«ããŒã«ïŒ¢ïŒã¢ã«ãã«ããã¿ã¬ã³ã¹ã«ãã
ãŒããããŠãã³ç€Ÿè£œïŒã®ïŒïŒ 氎溶液120mlãå«ã
ïŒïŒ ãŒã©ãã³æ°Žæº¶æ¶²1200mlãšæ··åããè¶ é³æ³¢åæ£
æ©ã«ãŠä¹³ååæ£ãä¹³åç©ãåŸãããããã®ã¡ãã
ã®åæ£æ¶²ãç·ææ§æ²èåéä¹³å€ïŒæ²åéïŒã¢ã«ïŒ
å«æïŒïŒKgã«æ·»å ãã硬èå€ãšããŠïŒïŒïŒâãã¹
ïŒããã«ã¹ã«ããã«ïŒãšã¿ã³ã®ïŒïŒ 溶液ïŒæ°ŽïŒã¡
ã¿ããŒã«ïŒïŒïŒïŒïŒ120mlãå ããäžåŒãããã
éæãªããªãšã¹ãã«ããŒã¹äžã«å¡åžä¹Ÿç¥ãè©Šæã
äœæãããïŒå¡åžéé20mgïŒ100cm2ïŒ ãã®ããã«ããŠåŸãããè©Šæãåžžæ³ã«åŸã€ãŠãŠ
ãšããžé²å ãè¡ã€ãåŸã以äžã®çŸååŠçãè¡ã€ã
çµæã第ïŒè¡šã«ç€ºãã ãçŸååŠçå·¥çšã çºè²çŸå液 38â ïŒå15ç§ æŒ çœ æ¶² 38â ïŒå20ç§ æ°Ž æŽ 38â ïŒå15ç§ å® ç 液 38â ïŒå20ç§ æ°Ž æŽ 38â ïŒå15ç§ å® å® æ¶² 38â ïŒå30ç§ ä¹Ÿ ç¥ 47â±55â 16å30ç§ ååŠçå·¥çšã«ãããŠã䜿çšããåŠç液çµæã¯äž
èšã®åŠãã§ããã ãçºè²çŸå液çµæã
å¡© ã14ã ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žããã©ïŒããª
ã¡ãã«ã¢ã³ã¢ããŠã ïŒå¡© ã15ã ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žããã©ãããª
ãŠã å¡© ã16ã ãžãšãã¬ã³ããªã¢ãã³ãã³ã¿é ¢é žãã³ã¿ã
ããªãŠã å¡© ã17ã ãšãã¬ã³ãžã¢ãã³ââïŒÎ²âãªãã·ãšã
ã«ïŒâïŒNâ²ïŒNâ²âããªé ¢é žãããªãŠã å¡© ã18ã ãããã¬ã³ãžã¢ãã³ããã©é ¢é žãããªãŠã
å¡© ã19ã ãããªãããªé ¢é žãããªãŠã å¡© ã20ã ã·ã¯ããããµã³ãžã¢ãã³ããã©é ¢é žãããª
ãŠã å¡© 䜿çšãããæŒçœæ¶²ã¯ãåèšã®åŠãææ©é žã®éå±
é¯å¡©ãæŒçœå€ãšããŠå«æãããšå ±ã«ãçš®ã ã®æ·»å
å€ãå«ãããšãã§ãããæ·»å å€ãšããŠã¯ããšãã«
ã¢ã«ã«ãªãã©ã€ããŸãã¯ã¢ã³ã¢ããŠã ãã©ã€ãã
äŸãã°èåã«ãªãŠã ãèåãããªãŠã ãå¡©åãã
ãªãŠã ãèåã¢ã³ã¢ããŠã çã®åããã²ã³åå€ã
éå±å¡©ããã¬ãŒãå€ãå«æãããããšãæãŸã
ãããŸãç¡Œé žå¡©ãèé žå¡©ãé ¢é žå¡©ãçé žå¡©ãçé ž
å¡©çã®PHç·©è¡å€ãã¢ã«ãã«ã¢ãã³é¡ãããªãšãã¬
ã³ãªããµã€ãé¡çã®éåžžæŒçœæ¶²ã«æ·»å ããããšã
ç¥ãããŠãããã®ãé©å®æ·»å ããããšãã§ããã æŽã«å®ç液ããã³æŒçœå®ç液ã¯ãäºç¡«é žã¢ã³ã¢
ããŠã ãäºç¡«é žã«ãªãŠã ãéäºç¡«é žã¢ã³ã¢ããŠ
ã ãéäºç¡«é žã«ãªãŠã ãéäºç¡«é žãããªãŠã ãã¡
ã¿éäºç¡«é žã¢ã³ã¢ããŠã ãã¡ã¿éäºç¡«é žã«ãªãŠ
ã ãã¡ã¿éäºç¡«é žãããªãŠã çã®äºç¡«é žå¡©ãç¡Œ
é žãç¡Œç ãæ°Žé žåãããªãŠã ãæ°Žé žåã«ãªãŠã ã
çé žãããªãŠã ãçé žã«ãªãŠã ãéçé žãããªãŠ
ã ãéçé žã«ãªãŠã ãé ¢é žãé ¢é žãããªãŠã ãæ°Ž
é žåã¢ã³ã¢ããŠã çã®åçš®ã®å¡©ããæãPHç·©è¡å€
ãåç¬ãããã¯ïŒçš®ä»¥äžå«ãããšãã§ããã æŒçœå®ç液ïŒæµŽïŒã«æŒçœå®çè£å å€ãè£å ããª
ããæ¬çºæã®åŠçãè¡ãå Žåã該æŒçœå®ç液
ïŒæµŽïŒã«ããªç¡«é žå¡©ãããªã·ã¢ã³é žå¡©ãŸãã¯äºç¡«
é žå¡©çãå«æããããŠããããã該æŒçœå®çè£å
液ã«ãããã®å¡©é¡ãå«æããããŠåŠç济ã«è£å ã
ãŠãããã æ¬çºæã«ãããŠã¯æŒçœå®ç液ã®æŽ»æ§åºŠãé«ãã
ããã«æŒçœå®ç济äžããã³æŒçœå®çè£å 液ã®è²¯èµ
ã¿ã³ã¯å ã§ææã«ãã空æ°ã®å¹ã蟌ã¿ããŸãã¯é ž
çŽ ã®å¹ã蟌ã¿ãè¡ã€ãŠãããããããã¯é©åœãªé ž
åå€ãäŸãã°éé žåæ°ŽçŽ ãèçŽ é žå¡©ãéç¡«é žå¡©ç
ãé©å®æ·»å ããŠãããã ïŒå®æœäŸïŒ 次ã«å®æœäŸã«ãã€ãŠæ¬çºæã説æããããæ¬çº
æã¯ãããã«éå®ããããã®ã§ã¯ãªãã ãå®æœäŸ ïŒã 第ïŒè¡šã«ç€ºããããªæ¬çºæã®ããŒã³ã¿ã«ãã©ãŒ
ããã³æ¯èŒã®ã«ãã©ãŒãåã éïŒã¢ã«ã«å¯ŸããŠ
0.1ã¢ã«ã¥ã€åããã«ãã©ãŒééã®ïŒåéã®ããª
ã¯ã¬ãžã«ãã¹ããšãŒãããã³ïŒåéã®é ¢é žãšãã«
ãå ã60âã«å æž©ããŠå®å šã«æº¶è§£ããããã®æº¶æ¶²
ãã¢ã«ã«ããŒã«ïŒ¢ïŒã¢ã«ãã«ããã¿ã¬ã³ã¹ã«ãã
ãŒããããŠãã³ç€Ÿè£œïŒã®ïŒïŒ 氎溶液120mlãå«ã
ïŒïŒ ãŒã©ãã³æ°Žæº¶æ¶²1200mlãšæ··åããè¶ é³æ³¢åæ£
æ©ã«ãŠä¹³ååæ£ãä¹³åç©ãåŸãããããã®ã¡ãã
ã®åæ£æ¶²ãç·ææ§æ²èåéä¹³å€ïŒæ²åéïŒã¢ã«ïŒ
å«æïŒïŒKgã«æ·»å ãã硬èå€ãšããŠïŒïŒïŒâãã¹
ïŒããã«ã¹ã«ããã«ïŒãšã¿ã³ã®ïŒïŒ 溶液ïŒæ°ŽïŒã¡
ã¿ããŒã«ïŒïŒïŒïŒïŒ120mlãå ããäžåŒãããã
éæãªããªãšã¹ãã«ããŒã¹äžã«å¡åžä¹Ÿç¥ãè©Šæã
äœæãããïŒå¡åžéé20mgïŒ100cm2ïŒ ãã®ããã«ããŠåŸãããè©Šæãåžžæ³ã«åŸã€ãŠãŠ
ãšããžé²å ãè¡ã€ãåŸã以äžã®çŸååŠçãè¡ã€ã
çµæã第ïŒè¡šã«ç€ºãã ãçŸååŠçå·¥çšã çºè²çŸå液 38â ïŒå15ç§ æŒ çœ æ¶² 38â ïŒå20ç§ æ°Ž æŽ 38â ïŒå15ç§ å® ç 液 38â ïŒå20ç§ æ°Ž æŽ 38â ïŒå15ç§ å® å® æ¶² 38â ïŒå30ç§ ä¹Ÿ ç¥ 47â±55â 16å30ç§ ååŠçå·¥çšã«ãããŠã䜿çšããåŠç液çµæã¯äž
èšã®åŠãã§ããã ãçºè²çŸå液çµæã
ãšãã¬ã³ãžã¢ãã³ããã©é
¢é
žéã¢ã³ã¢ããŠã å¡©
100ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é ž 10ïœ èåã¢ã³ã¢ããŠã 150ïœ æ°·é ¢é ž 40ml èçŽ é žãããªãŠã 10ïœ æ°Žãå ããŠïŒãšããã¢ã³ã¢ãã¢æ°ŽãŸãã¯æ°·é ¢
é žãçšããŠPH3.5ã«èª¿æŽããã ãå®ç液çµæã ããªç¡«é žã¢ã³ã¢ããŠã 180ïœ ç¡æ°Žäºç¡«é žãããªãŠã 12ïœ ã¡ã¿éäºç¡«é žãããªãŠã 2.5ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žïŒãããªãŠã
0.5ïœ çé žãããªãŠã 10ïœ æ°Žãå ããŠïŒãšããã ãå®å®å液çµæã ãã«ããªã³ïŒ37ïŒ æ°Žæº¶æ¶²ïŒ ïŒml ã³ãããã¯ã¹ïŒå°è¥¿å åçå·¥æ¥(æ ª)è£œïŒ ïŒml æ°Žãå ããŠïŒãšããã
100ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é ž 10ïœ èåã¢ã³ã¢ããŠã 150ïœ æ°·é ¢é ž 40ml èçŽ é žãããªãŠã 10ïœ æ°Žãå ããŠïŒãšããã¢ã³ã¢ãã¢æ°ŽãŸãã¯æ°·é ¢
é žãçšããŠPH3.5ã«èª¿æŽããã ãå®ç液çµæã ããªç¡«é žã¢ã³ã¢ããŠã 180ïœ ç¡æ°Žäºç¡«é žãããªãŠã 12ïœ ã¡ã¿éäºç¡«é žãããªãŠã 2.5ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žïŒãããªãŠã
0.5ïœ çé žãããªãŠã 10ïœ æ°Žãå ããŠïŒãšããã ãå®å®å液çµæã ãã«ããªã³ïŒ37ïŒ æ°Žæº¶æ¶²ïŒ ïŒml ã³ãããã¯ã¹ïŒå°è¥¿å åçå·¥æ¥(æ ª)è£œïŒ ïŒml æ°Žãå ããŠïŒãšããã
ãè¡šã
ãè¡šã
ãè¡šã
ïŒ æ¯æ床ã¯ã«ããªæ¿åºŠ0.1ã®æ¿åºŠãäžããé²å
éã®éæ°ã§æ¯èŒã«ãã©ãŒïŒãçšããè©Šæ11ã
100ãšããã ïŒ 30âã62ïŒ RHã«èª¿æž©ã調湿ããã0.9ïŒ ãã«
ããªã³æ°Žæº¶æ¶²ãïŒc.c.å ããå¯é容åšã«è©ŠæãïŒ
æ¥éæå ¥ããåŸãçºè²çŸåãè¡ãã æ¯èŒãšããŠãã«ããªã³æªåŠçã®è©Šæãå ±ã«çŸ
åããã ããªã³èæ§ïŒãã«ããªã³åŠçè©Šæã®çºè²æ¿åºŠ
ïŒãã«ããªã³æªåŠçè©Šæã®çºè²æ¿åºŠÃ100ïŒïŒ ïŒ ïŒ çºè²çŸååŠçåŸã®è©Šæããã»ãã³ããšãŒãã¡
ãŒã¿ãŒã«ïŒæ¥éç §å°ããåæ¿åºŠïŒ€ïŒ1.0ã®ãšã
ãã®åŠçåŸã®è²çŽ æ®æž©ïŒ ã瀺ããã èå æ§ïŒãã»ãã³ããšãŒãã¡ãŒã¿ãŒïŒæ¥éç §
å°åŸã®æ¿åºŠïŒ1.0Ã100 æ¯èŒã«ãã©ãŒïŒ
éã®éæ°ã§æ¯èŒã«ãã©ãŒïŒãçšããè©Šæ11ã
100ãšããã ïŒ 30âã62ïŒ RHã«èª¿æž©ã調湿ããã0.9ïŒ ãã«
ããªã³æ°Žæº¶æ¶²ãïŒc.c.å ããå¯é容åšã«è©ŠæãïŒ
æ¥éæå ¥ããåŸãçºè²çŸåãè¡ãã æ¯èŒãšããŠãã«ããªã³æªåŠçã®è©Šæãå ±ã«çŸ
åããã ããªã³èæ§ïŒãã«ããªã³åŠçè©Šæã®çºè²æ¿åºŠ
ïŒãã«ããªã³æªåŠçè©Šæã®çºè²æ¿åºŠÃ100ïŒïŒ ïŒ ïŒ çºè²çŸååŠçåŸã®è©Šæããã»ãã³ããšãŒãã¡
ãŒã¿ãŒã«ïŒæ¥éç §å°ããåæ¿åºŠïŒ€ïŒ1.0ã®ãšã
ãã®åŠçåŸã®è²çŽ æ®æž©ïŒ ã瀺ããã èå æ§ïŒãã»ãã³ããšãŒãã¡ãŒã¿ãŒïŒæ¥éç §
å°åŸã®æ¿åºŠïŒ1.0Ã100 æ¯èŒã«ãã©ãŒïŒ
ãåã
æ¯èŒã«ãã©ãŒïŒ
ãåã
æ¯èŒã«ãã©ãŒïŒ
ãåã
æ¯èŒã«ãã©ãŒïŒ
å®æœäŸâïŒã«æŒããè©Šæ11ã19ãåæ§ã«ãŠãšã
ãžé²å ãè¡ã€ãåŸã以äžã®çŸååŠçãè¡ã€ãã çµæã¯ç¬¬ïŒè¡šã«ç€ºãã æ¯æ床ãèå æ§ã®æž¬å®ã¯å®æœäŸïŒãšåäžæ¹æ³ã§
è¡ã€ãã ãçŸååŠçå·¥çšã çºè²çŸå 38â ïŒå30ç§ æŒçœå®ç 33â ïŒå30ç§ å®å®ååŠçïŒåã¯æ°ŽæŽåŠç 25ã30â ïŒå 也 ç¥ 75ã80â çŽïŒå ååŠçå·¥çšã«ãããŠã䜿çšããåŠç液çµæã¯äž
èšã®åŠãã§ããã
ãžé²å ãè¡ã€ãåŸã以äžã®çŸååŠçãè¡ã€ãã çµæã¯ç¬¬ïŒè¡šã«ç€ºãã æ¯æ床ãèå æ§ã®æž¬å®ã¯å®æœäŸïŒãšåäžæ¹æ³ã§
è¡ã€ãã ãçŸååŠçå·¥çšã çºè²çŸå 38â ïŒå30ç§ æŒçœå®ç 33â ïŒå30ç§ å®å®ååŠçïŒåã¯æ°ŽæŽåŠç 25ã30â ïŒå 也 ç¥ 75ã80â çŽïŒå ååŠçå·¥çšã«ãããŠã䜿çšããåŠç液çµæã¯äž
èšã®åŠãã§ããã
ãšãã¬ã³ãžã¢ãã³ããã©é
¢é
žç¬¬ïŒéã¢ã³ã¢ããŠ
ã ïŒæ°Žå¡© 60ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é ž ïŒïœ ããªç¡«é žã¢ã³ã¢ããŠã ïŒ70ïŒ æº¶æ¶²ïŒ 100ml äºç¡«é žã¢ã³ã¢ããŠã ïŒ40ïŒ æº¶æ¶²ïŒ 27.5ml çé žã«ãªãŠã ãŸãã¯æ°·é ¢é žã§PH7.1ã«èª¿æŽãæ°Ž
ãå ããŠå šéãïŒãšããã ãå®å®å液ã ïŒâã¯ããâïŒâã¡ãã«âïŒâã€ãœãã¢ãŸãªã³
âïŒâãªã³ 1.0ïœ ãšãã¬ã³ã°ãªã³ãŒã« 10ïœ
ã ïŒæ°Žå¡© 60ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é ž ïŒïœ ããªç¡«é žã¢ã³ã¢ããŠã ïŒ70ïŒ æº¶æ¶²ïŒ 100ml äºç¡«é žã¢ã³ã¢ããŠã ïŒ40ïŒ æº¶æ¶²ïŒ 27.5ml çé žã«ãªãŠã ãŸãã¯æ°·é ¢é žã§PH7.1ã«èª¿æŽãæ°Ž
ãå ããŠå šéãïŒãšããã ãå®å®å液ã ïŒâã¯ããâïŒâã¡ãã«âïŒâã€ãœãã¢ãŸãªã³
âïŒâãªã³ 1.0ïœ ãšãã¬ã³ã°ãªã³ãŒã« 10ïœ
ãè¡šã
次ã®åå±€ãã¢ãã¿ãŒãŒåã®é
žåãã¿ã³ãå«æã
ãããªãšãã¬ã³æš¹èã³ãŒãçŽäžã«é çªã«å¡èšãã
ããšã«ããããã²ã³åéã«ã©ãŒåçæå ææã調
補ããã 以äžã®æ·»å éã¯100cm2åœãã®ãã®ã瀺ãã (1) 20mgã®ãŒã©ãã³ãééãšããŠïŒmgã®éææ§å¡©
èåéä¹³å€ããããŠïŒmgã®ïŒ¹âã«ãã©ãŒïŒãã
ã³0.1mgã®ïŒïŒïŒâãžâïœâãªã¯ãã«ãã€ãã
ããã³ã溶解ããïŒmgã®ãžâãªã¯ãã«ãã¿ã¬ãŒ
ãã«ãã©ãŒæº¶åªãå«ãå±€ã (2) 12mgã®ãŒã©ãã³ã0.5mgã®ïŒïŒïŒâãžâïœâ
ãªã¯ãã«ãã€ããããã³ããã³ïŒmgã®çŽ«å€ç·åž
åå€ïŒã溶解ããïŒmgã®ãžããã«ãã¿ã¬ãŒã玫
å€ç·åžåå€æº¶åªãå«ãäžéå±€ã (3) 18mgã®ãŒã©ãã³ãééãšããŠïŒmgã®ç·ææ§å¡©
èåéä¹³å€ããããŠïŒmgã®ïŒâã«ãã©ãŒïŒãšïŒ
mgã®é žåé²æ¢å€ïŒããã³0.2mgã®ïŒïŒïŒâãžâ
ïœâãªã¯ãã«ãã€ããããã³ã溶解ãã2.5mg
ã®ãžãªã¯ãã«ãã¿ã¬ãŒãã«ãã©ãŒæº¶åªãå«ã
å±€ã (4) (2)ãšåãçµæç©ãå«ãäžéå±€ã (5) 16mgã®ãŒã©ãã³ãééãšããŠïŒmgã®èµ€ææ§å¡©
èåéä¹³å€ããããŠ3.5mgã®ïŒ£âã«ãã©ãŒïŒã
ãã³0.1mgã®ïŒïŒïŒâãžâïœâãªã¯ãã«ãã€ã
ãããã³ã溶解ãã2.0mgã®ããªã¯ã¬ãžã«ãã¹
ããšãŒãã«ãã©ãŒæº¶åªãå«ãå±€ã (6) ïŒmgã®ãŒã©ãã³ãå«æããŠãããŒã©ãã³ä¿è·
å±€ã (1)ãã(6)ã®åå±€ã«ã¯å¡åžå©å€ãæ·»å ããæŽã«(4)
ããã³(6)ã®å±€ã«ã¯ãŒã©ãã³æ¶æ©å€ãæ·»å ããã (2)ïŒ(4)ã®çŽ«å€ç·åžåå€ãšããŠã¯ãäžèšæ§é ã®
UVâïŒãšUVâïŒãæ··åããŠçšããã (3)ã®é žåé²æ¢å€ãšããŠããžâïœâãã³ãã«ãã€
ããããã³âãžâãªã¯ãã«ãšãŒãã«ãçšããã äžèšã®å€å±€æå ææã¯å®æœäŸâïŒãšåæ§ãªåŠç
ããããåå±€ã«çšããããâã«ãã©ãŒãïŒâã«
ãã©ãŒãâã«ãã©ãŒãšãã®çµæãè¡šïŒã«ç€ºãã åè©Šæã¯çœè²é²å ãããåŸã®ããŒã³ã¿æ¿åºŠã«ã€
ããŠæž¬å®ããã æ¯æ床ãèå æ§ã®æž¬å®ã¯å®æœäŸïŒãšåäžæ¹æ³ã§
è¡ã€ãã è¡šïŒããæ¬çºæã«ãã©ãŒã®è²çŽ ç»åã®èå æ§ã
ç§ããŠããããšã¯æããã§ããããŸã玫å€ç·åžå
å€ã䜿çšããããšã«ãã€ãŠæŽã«åäžããããšãæ
ããã§ãããïŒ çŽ«å€ç·åžåå€ UVâïŒ
ãããªãšãã¬ã³æš¹èã³ãŒãçŽäžã«é çªã«å¡èšãã
ããšã«ããããã²ã³åéã«ã©ãŒåçæå ææã調
補ããã 以äžã®æ·»å éã¯100cm2åœãã®ãã®ã瀺ãã (1) 20mgã®ãŒã©ãã³ãééãšããŠïŒmgã®éææ§å¡©
èåéä¹³å€ããããŠïŒmgã®ïŒ¹âã«ãã©ãŒïŒãã
ã³0.1mgã®ïŒïŒïŒâãžâïœâãªã¯ãã«ãã€ãã
ããã³ã溶解ããïŒmgã®ãžâãªã¯ãã«ãã¿ã¬ãŒ
ãã«ãã©ãŒæº¶åªãå«ãå±€ã (2) 12mgã®ãŒã©ãã³ã0.5mgã®ïŒïŒïŒâãžâïœâ
ãªã¯ãã«ãã€ããããã³ããã³ïŒmgã®çŽ«å€ç·åž
åå€ïŒã溶解ããïŒmgã®ãžããã«ãã¿ã¬ãŒã玫
å€ç·åžåå€æº¶åªãå«ãäžéå±€ã (3) 18mgã®ãŒã©ãã³ãééãšããŠïŒmgã®ç·ææ§å¡©
èåéä¹³å€ããããŠïŒmgã®ïŒâã«ãã©ãŒïŒãšïŒ
mgã®é žåé²æ¢å€ïŒããã³0.2mgã®ïŒïŒïŒâãžâ
ïœâãªã¯ãã«ãã€ããããã³ã溶解ãã2.5mg
ã®ãžãªã¯ãã«ãã¿ã¬ãŒãã«ãã©ãŒæº¶åªãå«ã
å±€ã (4) (2)ãšåãçµæç©ãå«ãäžéå±€ã (5) 16mgã®ãŒã©ãã³ãééãšããŠïŒmgã®èµ€ææ§å¡©
èåéä¹³å€ããããŠ3.5mgã®ïŒ£âã«ãã©ãŒïŒã
ãã³0.1mgã®ïŒïŒïŒâãžâïœâãªã¯ãã«ãã€ã
ãããã³ã溶解ãã2.0mgã®ããªã¯ã¬ãžã«ãã¹
ããšãŒãã«ãã©ãŒæº¶åªãå«ãå±€ã (6) ïŒmgã®ãŒã©ãã³ãå«æããŠãããŒã©ãã³ä¿è·
å±€ã (1)ãã(6)ã®åå±€ã«ã¯å¡åžå©å€ãæ·»å ããæŽã«(4)
ããã³(6)ã®å±€ã«ã¯ãŒã©ãã³æ¶æ©å€ãæ·»å ããã (2)ïŒ(4)ã®çŽ«å€ç·åžåå€ãšããŠã¯ãäžèšæ§é ã®
UVâïŒãšUVâïŒãæ··åããŠçšããã (3)ã®é žåé²æ¢å€ãšããŠããžâïœâãã³ãã«ãã€
ããããã³âãžâãªã¯ãã«ãšãŒãã«ãçšããã äžèšã®å€å±€æå ææã¯å®æœäŸâïŒãšåæ§ãªåŠç
ããããåå±€ã«çšããããâã«ãã©ãŒãïŒâã«
ãã©ãŒãâã«ãã©ãŒãšãã®çµæãè¡šïŒã«ç€ºãã åè©Šæã¯çœè²é²å ãããåŸã®ããŒã³ã¿æ¿åºŠã«ã€
ããŠæž¬å®ããã æ¯æ床ãèå æ§ã®æž¬å®ã¯å®æœäŸïŒãšåäžæ¹æ³ã§
è¡ã€ãã è¡šïŒããæ¬çºæã«ãã©ãŒã®è²çŽ ç»åã®èå æ§ã
ç§ããŠããããšã¯æããã§ããããŸã玫å€ç·åžå
å€ã䜿çšããããšã«ãã€ãŠæŽã«åäžããããšãæ
ããã§ãããïŒ çŽ«å€ç·åžåå€ UVâïŒ
ãåã
UVâïŒ
ãåãïŒ
âã«ãã©ãŒ
âïŒ
ãåã
âïŒ
ãåãïŒ
âã«ãã©ãŒ
âïŒ
ãåã
âïŒ
ãåã
âïŒ
ãåã
âïŒ
ãåã
ãè¡šã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ æ¯æäœäžã«å°ããšãäžå±€ã®ããã²ã³åéä¹³å€
å±€ãæããããã²ã³åéã«ã©ãŒåçæå ææã«ã
ããŠãåèšããã²ã³åéä¹³å€å±€äžã«ãïŒäœãïŒçŽ
ã¢ã«ãã«ãã¢ãªãŒã«åã³ãããç°ããéžã°ããåº
ã§ããã€ïŒäœã次ã®äžè¬åŒã§ç€ºãããåºã§çœ®æã
ãã1Hâãã©ãŸããïŒïŒïŒâãââããªã¢ãŸ
ãŒã«ç³»ããŒã³ã¿ã«ãã©ãŒã®å°ããšãïŒã€ãå«æã
ããŠããããšãç¹åŸŽãšããããã²ã³åéã«ã©ãŒå
çæå ææã äžè¬åŒ âR1âSO2âR2 ãåŒäžãR1ã¯ïŒçŽåã¯ïŒçŽã¢ã«ãã¬ã³ãR2ã¯
ã¢ã«ãã«åã¯ã¢ãªãŒã«ãè¡šãããã
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24301284A JPS61120152A (ja) | 1984-11-15 | 1984-11-15 | ããã²ã³åéã«ã©âåçæå ææ |
| AU47439/85A AU4743985A (en) | 1984-09-14 | 1985-09-13 | Silver halide photographic material with magenta coupler |
| DE8585306569T DE3574787D1 (de) | 1984-09-14 | 1985-09-16 | Farbphotographisches silberhalogenidmaterial. |
| EP19850306569 EP0178789B1 (en) | 1984-09-14 | 1985-09-16 | Silver halide color photograhic material |
| US07/161,321 US4840886A (en) | 1984-09-14 | 1988-02-26 | Silver halide color photographic material containing a 1h-pyrazole (3,2-C)-s-triazole derived magenta coupler |
| AU37011/89A AU3701189A (en) | 1984-09-14 | 1989-06-23 | Silver halide color photographic material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24301284A JPS61120152A (ja) | 1984-11-15 | 1984-11-15 | ããã²ã³åéã«ã©âåçæå ææ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61120152A JPS61120152A (ja) | 1986-06-07 |
| JPH0573010B2 true JPH0573010B2 (ja) | 1993-10-13 |
Family
ID=17097570
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP24301284A Granted JPS61120152A (ja) | 1984-09-14 | 1984-11-15 | ããã²ã³åéã«ã©âåçæå ææ |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61120152A (ja) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH071385B2 (ja) * | 1986-06-13 | 1995-01-11 | ã³ãã«æ ªåŒäŒç€Ÿ | çä¿åæ§ã«åªããããã²ã³åéã«ã©âåçæå ææ |
| JPH0640212B2 (ja) * | 1986-09-05 | 1994-05-25 | ã³ãã«æ ªåŒäŒç€Ÿ | ããã²ã³åéã«ã©âåçæå ææ |
| JP2786446B2 (ja) * | 1987-03-09 | 1998-08-13 | ã€ãŒã¹ããã³ ã³ãã㯠ã«ã³ãã㌠| åçããã²ã³åéçµæç© |
| US5656418A (en) | 1994-09-12 | 1997-08-12 | Fuji Photo Film Co., Ltd. | Silver halide color photographic material |
-
1984
- 1984-11-15 JP JP24301284A patent/JPS61120152A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61120152A (ja) | 1986-06-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4665015A (en) | Silver halide color photographic material containing a magenta coupler | |
| US4607002A (en) | Silver halide color photo-sensitive material | |
| US4752556A (en) | Method for processing of silver halide color photo graphic materials | |
| US4840886A (en) | Silver halide color photographic material containing a 1h-pyrazole (3,2-C)-s-triazole derived magenta coupler | |
| JPH0643611A (ja) | åççšã«ãã©ãŒåã³ããã²ã³åéã«ã©ãŒåçæå ææ | |
| US5118812A (en) | Pyrazoloazole series couplers | |
| US4675280A (en) | Silver halide color photographic material containing a 1H-pyrazolo [3,2-C]-S | |
| JPH0562729B2 (ja) | ||
| EP0183445B1 (en) | Silver halide color photo-sensitive material | |
| JPH07122741B2 (ja) | ããã²ã³åéã«ã©âåççšã«ãã©âãããã²ã³åéã«ã©âåçæå ææåã³ã«ã©âç»å圢ææ¹æ³ | |
| JPH043860B2 (ja) | ||
| JPH04190348A (ja) | ããã²ã³åéã«ã©ãŒåçæå ææ | |
| JP2631160B2 (ja) | ã·ã¢ã³ã«ãã©ãŒãã·ã¢ã³ç»å圢ææ¹æ³åã³ããã²ã³åéã«ã©ãŒåçæå ææ | |
| JPH0573010B2 (ja) | ||
| JPH03174153A (ja) | ã«ã©ãŒç»å圢ææ¹æ³ | |
| JPH0380296B2 (ja) | ||
| JPH04190347A (ja) | æ°èŠãªè²çŽ 圢æã«ãã©ãŒããã³è©²ã«ãã©ãŒãå«æããããã²ã³åéã«ã©ãŒåçæå ææ | |
| JPS61120148A (ja) | ããã²ã³åéã«ã©âåçæå ææ | |
| JPS61120150A (ja) | ããã²ã³åéã«ã©âåçæå ææ | |
| JPH0554935B2 (ja) | ||
| EP0347235A2 (en) | Photosensitive silver halide color photographic material | |
| JPH0566574B2 (ja) | ||
| JP2618533B2 (ja) | ããã²ã³åéã«ã©ãŒåçæå ææåã³ããã²ã³åéã«ã©ãŒç»å圢ææ¹æ³ | |
| JPS61144647A (ja) | ããã²ã³åéã«ã©âåçæå ææ | |
| JPH0677142B2 (ja) | ããã²ã³åéã«ã©ãŒåçæå ææ |