JPH11505871A - 耐衝撃性が改良された（メタ）アクリルポリマー - Google Patents

耐衝撃性が改良された（メタ）アクリルポリマー

Info

Publication number: JPH11505871A
Authority: JP; Japan
Prior art keywords: shell; core; meth; acrylic polymer; polymer
Prior art date: 1995-05-24
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Withdrawn

Application number

JP8535387A

Other languages

English (en)

Japanese (ja)

Other versions

JPH11505871A5 (2

Inventor

ミュアーフレイザー，イアン

マークトレッドゴールド，ジョナサン

Original Assignee

インペリアルケミカルインダストリーズパブリックリミティドカンパニー

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1995-05-24

Filing date

1996-05-23

Publication date

1999-05-25

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=8221204&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=JPH11505871(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1996-05-23 Application filed by インペリアルケミカルインダストリーズパブリックリミティドカンパニー filed Critical インペリアルケミカルインダストリーズパブリックリミティドカンパニー

1999-05-25 Publication of JPH11505871A publication Critical patent/JPH11505871A/ja

2004-07-08 Publication of JPH11505871A5 publication Critical patent/JPH11505871A5/ja

Status Withdrawn legal-status Critical Current

Links

229920000058 polyacrylate Polymers 0.000 title claims abstract description 53
239000002245 particle Substances 0.000 claims abstract description 83
239000011258 core-shell material Substances 0.000 claims abstract description 67
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 46
229920000642 polymer Polymers 0.000 claims abstract description 42
239000000178 monomer Substances 0.000 claims abstract description 23
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 16
239000003431 cross linking reagent Substances 0.000 claims abstract description 15
230000009477 glass transition Effects 0.000 claims abstract description 10
238000000034 method Methods 0.000 claims abstract description 9
150000001875 compounds Chemical class 0.000 claims abstract description 7
239000004609 Impact Modifier Substances 0.000 claims abstract description 6
229920001519 homopolymer Polymers 0.000 claims abstract description 6
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 6
229920002554 vinyl polymer Polymers 0.000 claims abstract description 6
239000000203 mixture Substances 0.000 claims description 40
229920001577 copolymer Polymers 0.000 claims description 23
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical group CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 20
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical group COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 14
-1 alkyl methacrylates Chemical class 0.000 claims description 9
238000009472 formulation Methods 0.000 claims description 8
239000011159 matrix material Substances 0.000 claims description 7
238000000465 moulding Methods 0.000 claims description 4
239000003795 chemical substances by application Substances 0.000 claims description 3
229920001296 polysiloxane Polymers 0.000 claims description 3
GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 claims description 2
238000002156 mixing Methods 0.000 claims description 2
125000004178 (C1-C4) alkyl group Chemical group 0.000 claims 1
125000005250 alkyl acrylate group Chemical group 0.000 claims 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 12
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 9
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 8
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 8
238000012360 testing method Methods 0.000 description 8
FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 6
238000006116 polymerization reaction Methods 0.000 description 5
239000004971 Cross linker Substances 0.000 description 4
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 4
239000008367 deionised water Substances 0.000 description 4
229910021641 deionized water Inorganic materials 0.000 description 4
239000003999 initiator Substances 0.000 description 4
229920003229 poly(methyl methacrylate) Polymers 0.000 description 4
239000004926 polymethyl methacrylate Substances 0.000 description 4
USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
230000015271 coagulation Effects 0.000 description 3
238000005345 coagulation Methods 0.000 description 3
239000011521 glass Substances 0.000 description 3
239000004816 latex Substances 0.000 description 3
229920000126 latex Polymers 0.000 description 3
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
238000010899 nucleation Methods 0.000 description 3
239000000376 reactant Substances 0.000 description 3
239000010420 shell particle Substances 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
239000000654 additive Substances 0.000 description 2
238000005119 centrifugation Methods 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
238000002347 injection Methods 0.000 description 2
239000007924 injection Substances 0.000 description 2
230000003287 optical effect Effects 0.000 description 2
230000036314 physical performance Effects 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 2
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
241000042032 Petrocephalus catostoma Species 0.000 description 1
PCSMJKASWLYICJ-UHFFFAOYSA-N Succinic aldehyde Chemical compound O=CCCC=O PCSMJKASWLYICJ-UHFFFAOYSA-N 0.000 description 1
IAXXETNIOYFMLW-COPLHBTASA-N [(1s,3s,4s)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate Chemical compound C1C[C@]2(C)[C@@H](OC(=O)C(=C)C)C[C@H]1C2(C)C IAXXETNIOYFMLW-COPLHBTASA-N 0.000 description 1
150000001252 acrylic acid derivatives Chemical class 0.000 description 1
125000005399 allylmethacrylate group Chemical group 0.000 description 1
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 description 1
238000001035 drying Methods 0.000 description 1
238000007720 emulsion polymerization reaction Methods 0.000 description 1
SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
239000007863 gel particle Substances 0.000 description 1
VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
239000010931 gold Substances 0.000 description 1
229910052737 gold Inorganic materials 0.000 description 1
239000012760 heat stabilizer Substances 0.000 description 1
KETWBQOXTBGBBN-UHFFFAOYSA-N hex-1-enylbenzene Chemical compound CCCCC=CC1=CC=CC=C1 KETWBQOXTBGBBN-UHFFFAOYSA-N 0.000 description 1
150000004687 hexahydrates Chemical class 0.000 description 1
230000001771 impaired effect Effects 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
238000001746 injection moulding Methods 0.000 description 1
229940119545 isobornyl methacrylate Drugs 0.000 description 1
239000002932 luster Substances 0.000 description 1
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
238000003921 particle size analysis Methods 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
238000010926 purge Methods 0.000 description 1
238000009877 rendering Methods 0.000 description 1
239000011347 resin Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
241000894007 species Species 0.000 description 1
238000003756 stirring Methods 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2998—Coated including synthetic resin or polymer

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Graft Or Block Polymers (AREA)
Compositions Of Macromolecular Compounds (AREA)
Manufacture Of Macromolecular Shaped Articles (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

JP8535387A 1995-05-24 1996-05-23 耐衝撃性が改良された（メタ）アクリルポリマー Withdrawn JPH11505871A (ja)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
GB95303525.0		1995-05-24
EP95303525A EP0745622A1 (en)	1995-05-24	1995-05-24	Impact modified (meth)acrylic polymers
PCT/EP1996/002216 WO1996037531A1 (en)	1995-05-24	1996-05-23	Impact modified (meth)acrylic polymers

Related Child Applications (1)

Application Number	Title	Priority Date	Filing Date
JP2007200754A Division JP2007321158A (ja)	1995-05-24	2007-08-01	耐衝撃性が改良された（メタ）アクリルポリマー

Publications (2)

Publication Number	Publication Date
JPH11505871A true JPH11505871A (ja)	1999-05-25
JPH11505871A5 JPH11505871A5 (2)	2004-07-08

Family

ID=8221204

Family Applications (3)

Application Number	Title	Priority Date	Filing Date
JP8535387A Withdrawn JPH11505871A (ja)	1995-05-24	1996-05-23	耐衝撃性が改良された（メタ）アクリルポリマー
JP2007200754A Withdrawn JP2007321158A (ja)	1995-05-24	2007-08-01	耐衝撃性が改良された（メタ）アクリルポリマー
JP2009165726A Expired - Lifetime JP5410868B2 (ja)	1995-05-24	2009-07-14	耐衝撃性が改良された（メタ）アクリルポリマー

Family Applications After (2)

Application Number	Title	Priority Date	Filing Date
JP2007200754A Withdrawn JP2007321158A (ja)	1995-05-24	2007-08-01	耐衝撃性が改良された（メタ）アクリルポリマー
JP2009165726A Expired - Lifetime JP5410868B2 (ja)	1995-05-24	2009-07-14	耐衝撃性が改良された（メタ）アクリルポリマー

Country Status (13)

Country	Link
US (1)	US6172135B1 (2)
EP (2)	EP0745622A1 (2)
JP (3)	JPH11505871A (2)
CN (1)	CN1137168C (2)
AT (1)	ATE191491T1 (2)
CA (1)	CA2220411C (2)
DE (1)	DE69607613T3 (2)
DK (1)	DK0828772T4 (2)
ES (1)	ES2145453T5 (2)
MY (1)	MY134601A (2)
PT (1)	PT828772E (2)
TW (1)	TW442502B (2)
WO (1)	WO1996037531A1 (2)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2004508438A (ja) *	2000-09-04	2004-03-18	レーム　ゲゼルシヤフト　ミツト　ベシユレンクテル　ハフツング　ウント　コンパニー　コマンディートゲゼルシャフト	改善された耐衝撃性を有するポリメチルメタクリレート成形材料
JP2006510758A (ja) *	2002-12-19	2006-03-30	レームゲゼルシャフトミツトベシュレンクテルハフツングウントコンパニーコマンディートゲゼルシャフト	ポリ（メタ）アクリレート成形材料の耐衝撃性改良用のコア・シェル粒子
WO2013094759A1 (ja) *	2011-12-21	2013-06-27	三菱レイヨン株式会社	重合体粉体、硬化性樹脂組成物及びその硬化物
WO2024203994A1 (ja) *	2023-03-30	2024-10-03	株式会社カネカ	重合体微粒子、樹脂用改質剤および樹脂組成物

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6649104B2 (en)	1997-07-31	2003-11-18	Sumitomo Chemical Company, Limited	Acrylic resin film and laminated film comprising the same
JP3664575B2 (ja) *	1997-08-19	2005-06-29	株式会社カネカ	メタクリル酸エステル系樹脂組成物及びそれを成形してなるフィルム
WO1999032533A1 (en) *	1997-12-19	1999-07-01	Matsumoto Yushi-Seiyaku Co., Ltd.	Synthetic organic particles, process for the production of the same, and use thereof
KR20010007235A (ko)	1999-06-17	2001-01-26	마크 에스. 아들러	내후성, 감소된 광택 및 고충격을 제공하는 캡스톡 조성물및 그 제조방법
DE10003509A1 (de) *	2000-01-27	2001-08-02	Basf Ag	Verfahren zur Herstellung schlagzäher Kunststoffe
KR100428638B1 (ko) *	2001-09-13	2004-04-30	주식회사 엘지화학	고분자 라텍스 수지 분체의 제조방법
US7294399B2 (en) *	2002-04-02	2007-11-13	Arkema France	Weather-resistant, high-impact strength acrylic compositions
DE10243062A1 (de) *	2002-09-16	2004-03-25	Röhm GmbH & Co. KG	Heißwasserwechseltestbeständiges Sanitärmaterial aus PMMA-Formmasse oder schlagzäher PMMA-Formmasse
DE10260089A1 (de)	2002-12-19	2004-07-01	Röhm GmbH & Co. KG	Verfahren zur Herstellung von wässrigen Dispersionen
KR100544904B1 (ko) *	2002-12-24	2006-01-24	주식회사 엘지화학	다층구조를 갖는 충격보강제와 이의 제조방법 및 이를 포함하는 열가소성 수지
KR100789108B1 (ko) *	2003-12-30	2007-12-26	주식회사 엘지화학	내충격성 및 흐름성이 우수한 고분자 라텍스 및 이의 제조방법
DE102004035937A1 (de) *	2004-07-23	2006-02-16	Röhm GmbH & Co. KG	Plastisole mit verringerter Wasseraufnahme
GB0508255D0 (en)	2005-04-25	2005-06-01	Lucite Int Uk Ltd	Acrylic blends
US8034441B2 (en) †	2005-07-08	2011-10-11	Arkema France	Multilayer composition
KR100836731B1 (ko) *	2005-10-13	2008-06-10	주식회사 엘지화학	아크릴-실리콘계 고무 복합 중합체, 이의 제조방법 및 용도
KR101010089B1 (ko) *	2006-02-22	2011-01-24	가부시키가이샤 닛폰 쇼쿠바이	수지 조성물 및 필름
GB0711017D0 (en)	2007-06-08	2007-07-18	Lucite Int Uk Ltd	Polymer Composition
KR100994055B1 (ko) *	2008-01-16	2010-11-11	주식회사 엘지화학	열가소성 폴리에스테르 수지용 충격 보강제 및 이를 포함한열가소성 폴리에스테르 수지 조성물
FR2931822B1 (fr)	2008-05-30	2012-11-02	Arkema France	Methacrylate de methyle derive de la biomasse, procede de fabrication, utilisations et polymeres correspondants.
EP2218738A1 (de)	2009-01-22	2010-08-18	Bayer MaterialScience AG	Wässrige Polymerdispersion
ES2523047T3 (es) *	2009-07-07	2014-11-20	Evonik Röhm Gmbh	Composiciones de moldeo de materiales sintéticos, piezas moldeadas y procedimientos de producción
KR101215754B1 (ko) *	2009-12-22	2012-12-26	주식회사 엘지화학	내충격성 및 색상이 우수한 수지 및 그의 제조방법
KR101185688B1 (ko)	2010-01-15	2012-09-25	주식회사 엘지화학	가공성이 우수한 아크릴계 충격 보강제 제조 방법과 이를 포함하는 폴리염화비닐 조성물
WO2012044929A2 (en) *	2010-09-30	2012-04-05	Lubrizol Advanced Materials, Inc.	Structured acrylate copolymer for use in multi-phase systems
KR101333578B1 (ko) *	2010-12-29	2013-11-27	제일모직주식회사	내후성이 우수한 다층구조 충격보강제, 그 제조방법 및 이를 포함한 열가소성 수지 조성물
EP2691235A1 (en) *	2011-03-28	2014-02-05	Evonik Röhm GmbH	Plastic mouldings for use as windows for cars or utility vehicles
EP2978785B1 (de)	2013-03-25	2017-03-08	Evonik Röhm GmbH	Schlagzäh ausgerüstetes pmma mit verbesserten optischen eigenschaften
JP6511059B2 (ja) *	2013-09-16	2019-05-08	コエルクス・エッセ・エッレ・エッレＣｏｅＬｕｘＳ．ｒ．ｌ．	ポリマーマトリクスとナノ粒子を含む複合材料、その製造方法及び使用
ES2648920T3 (es) *	2013-11-26	2018-01-08	Ineos Styrolution Group Gmbh	Masas de moldeo termoplásticas con envuelta de injerto adaptada
US10358552B2 (en)	2014-09-24	2019-07-23	Evonik Röhm Gmbh	Impact-resistant molding material having an improved characteristics profile
FR3046605B1 (fr) *	2016-01-11	2019-09-06	Arkema France	Composition liquide comprenant un polymere a phases multiples, son procede de preparation et son utilisation
EP3443037B1 (en) *	2016-04-12	2022-02-16	SABIC Global Technologies B.V.	Polymer composition comprising poly(methyl methacrylate) and an impact modifier composition
AU2019204505C1 (en) *	2018-07-19	2023-10-26	Rohm And Haas Company	Process for preparing an aqueous dispersion of multistage polymer particles
CN114502637A (zh) *	2019-10-18	2022-05-13	陶氏环球技术有限责任公司	聚烯烃丙烯酸聚合物对苯乙烯聚合物的抗冲改性

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3793402A (en) †	1971-11-05	1974-02-19	F Owens	Low haze impact resistant compositions containing a multi-stage,sequentially produced polymer
JPS5936645B2 (ja) *	1975-05-06	1984-09-05	三菱レイヨン株式会社	多層構造重合体組成物の製造法
GB2039496B (en)	1979-01-12	1982-11-10	Du Pont	Cored acrylic polymers
JPS6017406B2 (ja) *	1981-06-03	1985-05-02	旭化成株式会社	多層構造アクリル系樹脂成形材料の製造方法
DE3300526A1 (de) *	1983-01-10	1984-07-12	Röhm GmbH, 6100 Darmstadt	Schlagzaehmodifizierungsmittel
DE3842796A1 (de) †	1988-12-20	1990-06-21	Roehm Gmbh	Klare schlagzaehe acrylat-formmasse
GB2233979B (en) †	1989-07-03	1993-07-14	Asahi Chemical Ind	Thermoplastic acrylic resin composition
JPH0768318B2 (ja) *	1989-12-27	1995-07-26	旭化成工業株式会社	多層構造アクリル系重合体
DE4114641A1 (de)	1991-05-04	1992-11-05	Basf Ag	Emulsionspfropfcopolymerisate
DE4136993A1 (de) †	1991-11-11	1993-05-13	Basf Ag	Transparente, schlagzaehmodifizierte pmma-formmassen mit verbesserter tieftemperatur-schlagzaehigkeit und hoher bewitterungsstabilitaet
DE4300596A1 (de)	1993-01-13	1994-07-14	Basf Ag	Formmassen auf der Basis von Polymethylmethacrylat mit verbesserter Kerbschlagzähigkeit
DE4325823A1 (de) †	1993-07-31	1995-04-27	Basf Ag	Thermoplastische Formmassen aus einem Copolymerisat auf der Basis von Alkylestern der Methacrylsäure und einem fünfstufigen Emulsionspfropfcopolymerisat

1995
- 1995-05-24 EP EP95303525A patent/EP0745622A1/en not_active Withdrawn
1996
- 1996-05-23 PT PT96917408T patent/PT828772E/pt unknown
- 1996-05-23 ES ES96917408T patent/ES2145453T5/es not_active Expired - Lifetime
- 1996-05-23 AT AT96917408T patent/ATE191491T1/de active
- 1996-05-23 DE DE69607613T patent/DE69607613T3/de not_active Expired - Lifetime
- 1996-05-23 EP EP96917408A patent/EP0828772B2/en not_active Expired - Lifetime
- 1996-05-23 CA CA002220411A patent/CA2220411C/en not_active Expired - Lifetime
- 1996-05-23 WO PCT/EP1996/002216 patent/WO1996037531A1/en not_active Ceased
- 1996-05-23 DK DK96917408T patent/DK0828772T4/da active
- 1996-05-23 CN CNB961941138A patent/CN1137168C/zh not_active Expired - Lifetime
- 1996-05-23 JP JP8535387A patent/JPH11505871A/ja not_active Withdrawn
- 1996-05-23 US US08/952,425 patent/US6172135B1/en not_active Expired - Lifetime
- 1996-05-24 MY MYPI96001979A patent/MY134601A/en unknown
- 1996-06-08 TW TW085106905A patent/TW442502B/zh not_active IP Right Cessation
2007
- 2007-08-01 JP JP2007200754A patent/JP2007321158A/ja not_active Withdrawn
2009
- 2009-07-14 JP JP2009165726A patent/JP5410868B2/ja not_active Expired - Lifetime

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2004508438A (ja) *	2000-09-04	2004-03-18	レーム　ゲゼルシヤフト　ミツト　ベシユレンクテル　ハフツング　ウント　コンパニー　コマンディートゲゼルシャフト	改善された耐衝撃性を有するポリメチルメタクリレート成形材料
JP2006510758A (ja) *	2002-12-19	2006-03-30	レームゲゼルシャフトミツトベシュレンクテルハフツングウントコンパニーコマンディートゲゼルシャフト	ポリ（メタ）アクリレート成形材料の耐衝撃性改良用のコア・シェル粒子
WO2013094759A1 (ja) *	2011-12-21	2013-06-27	三菱レイヨン株式会社	重合体粉体、硬化性樹脂組成物及びその硬化物
JPWO2013094759A1 (ja) *	2011-12-21	2015-04-27	三菱レイヨン株式会社	重合体粉体、硬化性樹脂組成物及びその硬化物
US9193812B2 (en)	2011-12-21	2015-11-24	Mitsubishi Rayon Co., Ltd.	Polymer powder, curable resin composition and cured material thereof
US9522997B2 (en)	2011-12-21	2016-12-20	Mitsubishi Rayon Co., Ltd.	Polymer powder, curable resin composition and cured material thereof
WO2024203994A1 (ja) *	2023-03-30	2024-10-03	株式会社カネカ	重合体微粒子、樹脂用改質剤および樹脂組成物

Also Published As

Publication number	Publication date
JP2007321158A (ja)	2007-12-13
DE69607613D1 (de)	2000-05-11
DK0828772T4 (da)	2003-12-15
MY134601A (en)	2007-12-31
EP0828772B1 (en)	2000-04-05
EP0745622A1 (en)	1996-12-04
DK0828772T3 (da)	2000-08-14
DE69607613T2 (de)	2000-08-17
ES2145453T3 (es)	2000-07-01
PT828772E (pt)	2000-07-31
DE69607613T3 (de)	2004-04-01
JP2009270115A (ja)	2009-11-19
US6172135B1 (en)	2001-01-09
CN1137168C (zh)	2004-02-04
WO1996037531A1 (en)	1996-11-28
EP0828772B2 (en)	2003-08-20
JP5410868B2 (ja)	2014-02-05
CA2220411A1 (en)	1996-11-28
CN1185165A (zh)	1998-06-17
TW442502B (en)	2001-06-23
CA2220411C (en)	2008-07-22
EP0828772A1 (en)	1998-03-18
ES2145453T5 (es)	2004-06-16
ATE191491T1 (de)	2000-04-15

Legal Events

Date	Code	Title	Description
2005-07-19	A131	Notification of reasons for refusal	Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20050719
2005-08-01	A977	Report on retrieval	Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20050628
2005-11-10	A601	Written request for extension of time	Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20051019
2005-12-05	A602	Written permission of extension of time	Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20051205
2006-02-09	A521	Request for written amendment filed	Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20060119
2007-04-03	A02	Decision of refusal	Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20070403
2007-07-03	A521	Request for written amendment filed	Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20070702
2007-10-10	A911	Transfer to examiner for re-examination before appeal (zenchi)	Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20071011
2008-01-26	A761	Written withdrawal of application	Free format text: JAPANESE INTERMEDIATE CODE: A761 Effective date: 20080125

Publication	Publication Date	Title
JPH11505871A (ja)	1999-05-25	耐衝撃性が改良された（メタ）アクリルポリマー
JP4718475B2 (ja)	2011-07-06	ポリマー混合物および射出成形品のためのその使用
TW548284B (en)	2003-08-21	PMMA moulding compositions with better impact strength
JPS603101B2 (ja)	1985-01-25	改良された耐衝撃性を有するポリアルキレンテレフタレート組成物
JP2007321158A5 (2)	2008-06-05
RU2007131956A (ru)	2009-02-27	Ударопрочная поли(мет)акрилатная формовочная масса с высокой теплостойкостью
JPH01190746A (ja)	1989-07-31	耐衝撃性樹脂組成物
EP0231933B1 (en)	1993-05-26	Thermoplastic resin compositions having excellent impact resistance, weather resistance and moldability, and process for preparing the same
JPS6036177B2 (ja)	1985-08-19	ポリブレンド組成物
AU6687700A (en)	2001-01-09	Modified impact resistant polymethacrylate moulding material with improved flowability
CN1150230C (zh)	2004-05-19	阻光性和抗冲击强度改善的耐气候树脂组合物
JPH03199213A (ja)	1991-08-30	多層構造アクリル系重合体
JPH0699611B2 (ja)	1994-12-07	重合体アロイ
EP0129376A1 (en)	1984-12-27	Thermoplastic composition of copolymers
JP2796595B2 (ja)	1998-09-10	多層構造重合体および樹脂組成物
JPH0873685A (ja)	1996-03-19	熱可塑性成形材料
CA1047680A (en)	1979-01-30	Lenses for exterior vehicle lamps
JPH0245547A (ja)	1990-02-15	透明耐衝撃性樹脂組成物
JP3025333B2 (ja)	2000-03-27	熱可塑性樹脂組成物
JPH04185663A (ja)	1992-07-02	高衝撃高剛性ａａｓ系樹脂組成物
JPS6296511A (ja)	1987-05-06	艶消し性熱可塑性樹脂組成物及びその製造方法
JPH1149922A (ja)	1999-02-23	アクリル系樹脂組成物
JPH02129266A (ja)	1990-05-17	コアシェルポリマー及びこれを含む組成物
KR20040050146A (ko)	2004-06-16	이형성이 우수한 열가소성 수지조성물
JPH10298375A (ja)	1998-11-10	ゴム変性耐熱性スチレン系樹脂組成物