JPS6351176B2 - - Google Patents
Info
- Publication number
- JPS6351176B2 JPS6351176B2 JP58219664A JP21966483A JPS6351176B2 JP S6351176 B2 JPS6351176 B2 JP S6351176B2 JP 58219664 A JP58219664 A JP 58219664A JP 21966483 A JP21966483 A JP 21966483A JP S6351176 B2 JPS6351176 B2 JP S6351176B2
- Authority
- JP
- Japan
- Prior art keywords
- phenylene
- polymer
- azomethine
- methyl
- ring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000642 polymer Polymers 0.000 claims description 77
- 229920001577 copolymer Polymers 0.000 claims description 61
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 43
- -1 promo Chemical group 0.000 claims description 42
- 239000000155 melt Substances 0.000 claims description 35
- 238000002844 melting Methods 0.000 claims description 28
- 230000008018 melting Effects 0.000 claims description 28
- 229910052757 nitrogen Inorganic materials 0.000 claims description 27
- 230000003287 optical effect Effects 0.000 claims description 26
- 239000002994 raw material Substances 0.000 claims description 18
- 150000004985 diamines Chemical class 0.000 claims description 16
- 125000004122 cyclic group Chemical group 0.000 claims description 12
- ZNZYKNKBJPZETN-WELNAUFTSA-N Dialdehyde 11678 Chemical compound N1C2=CC=CC=C2C2=C1[C@H](C[C@H](/C(=C/O)C(=O)OC)[C@@H](C=C)C=O)NCC2 ZNZYKNKBJPZETN-WELNAUFTSA-N 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- 125000004959 2,6-naphthylene group Chemical group [H]C1=C([H])C2=C([H])C([*:1])=C([H])C([H])=C2C([H])=C1[*:2] 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 6
- 125000003367 polycyclic group Chemical group 0.000 claims description 6
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 claims description 5
- 125000004429 atom Chemical group 0.000 claims description 4
- 125000002837 carbocyclic group Chemical group 0.000 claims description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- 125000005594 diketone group Chemical group 0.000 claims description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 3
- 125000004958 1,4-naphthylene group Chemical group 0.000 claims description 2
- 125000005407 trans-1,4-cyclohexylene group Chemical group [H]C1([H])C([H])([H])[C@]([H])([*:2])C([H])([H])C([H])([H])[C@@]1([H])[*:1] 0.000 claims description 2
- 230000001747 exhibiting effect Effects 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 239000000835 fiber Substances 0.000 description 99
- 238000010438 heat treatment Methods 0.000 description 32
- 238000000034 method Methods 0.000 description 31
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 22
- 229920000343 polyazomethine Polymers 0.000 description 21
- 239000011541 reaction mixture Substances 0.000 description 21
- 239000000243 solution Substances 0.000 description 19
- 238000006243 chemical reaction Methods 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 15
- 239000002904 solvent Substances 0.000 description 15
- KUCOHFSKRZZVRO-UHFFFAOYSA-N terephthalaldehyde Chemical compound O=CC1=CC=C(C=O)C=C1 KUCOHFSKRZZVRO-UHFFFAOYSA-N 0.000 description 15
- 238000012360 testing method Methods 0.000 description 15
- 238000006116 polymerization reaction Methods 0.000 description 14
- 238000009987 spinning Methods 0.000 description 13
- 239000000203 mixture Substances 0.000 description 11
- 239000000047 product Substances 0.000 description 11
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 10
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 10
- 229920001971 elastomer Polymers 0.000 description 10
- 239000005060 rubber Substances 0.000 description 10
- 238000003756 stirring Methods 0.000 description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 9
- GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 description 9
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 8
- OBCSAIDCZQSFQH-UHFFFAOYSA-N 2-methyl-1,4-phenylenediamine Chemical compound CC1=CC(N)=CC=C1N OBCSAIDCZQSFQH-UHFFFAOYSA-N 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 238000007429 general method Methods 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 238000011282 treatment Methods 0.000 description 7
- GWIWIPGOKVSQKR-UHFFFAOYSA-N 2-chloroterephthalaldehyde Chemical compound ClC1=CC(C=O)=CC=C1C=O GWIWIPGOKVSQKR-UHFFFAOYSA-N 0.000 description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 6
- 230000005540 biological transmission Effects 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- MNHWRUCVFATHDL-UHFFFAOYSA-N 2-methylterephthalaldehyde Chemical compound CC1=CC(C=O)=CC=C1C=O MNHWRUCVFATHDL-UHFFFAOYSA-N 0.000 description 5
- VVYWUQOTMZEJRJ-UHFFFAOYSA-N 4-n-methylbenzene-1,4-diamine Chemical compound CNC1=CC=C(N)C=C1 VVYWUQOTMZEJRJ-UHFFFAOYSA-N 0.000 description 5
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Substances CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 5
- 239000006227 byproduct Substances 0.000 description 5
- 230000004907 flux Effects 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 5
- SKLUWKYNZNXSLX-UHFFFAOYSA-N 4-Acetamidobenzaldehyde Chemical compound CC(=O)NC1=CC=C(C=O)C=C1 SKLUWKYNZNXSLX-UHFFFAOYSA-N 0.000 description 4
- UHNUHZHQLCGZDA-UHFFFAOYSA-N 4-[2-(4-aminophenyl)ethyl]aniline Chemical compound C1=CC(N)=CC=C1CCC1=CC=C(N)C=C1 UHNUHZHQLCGZDA-UHFFFAOYSA-N 0.000 description 4
- NZXKMTOTHHFKJB-UHFFFAOYSA-N 4-[2-(4-formylphenoxy)ethoxy]benzaldehyde Chemical compound C1=CC(C=O)=CC=C1OCCOC1=CC=C(C=O)C=C1 NZXKMTOTHHFKJB-UHFFFAOYSA-N 0.000 description 4
- QGMGHALXLXKCBD-UHFFFAOYSA-N 4-amino-n-(2-aminophenyl)benzamide Chemical compound C1=CC(N)=CC=C1C(=O)NC1=CC=CC=C1N QGMGHALXLXKCBD-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 4
- 230000014759 maintenance of location Effects 0.000 description 4
- VATYWCRQDJIRAI-UHFFFAOYSA-N p-aminobenzaldehyde Chemical compound NC1=CC=C(C=O)C=C1 VATYWCRQDJIRAI-UHFFFAOYSA-N 0.000 description 4
- 239000000376 reactant Substances 0.000 description 4
- 238000004804 winding Methods 0.000 description 4
- SKBBQSLSGRSQAJ-UHFFFAOYSA-N 1-(4-acetylphenyl)ethanone Chemical compound CC(=O)C1=CC=C(C(C)=O)C=C1 SKBBQSLSGRSQAJ-UHFFFAOYSA-N 0.000 description 3
- MGLZGLAFFOMWPB-UHFFFAOYSA-N 2-chloro-1,4-phenylenediamine Chemical compound NC1=CC=C(N)C(Cl)=C1 MGLZGLAFFOMWPB-UHFFFAOYSA-N 0.000 description 3
- 229910010082 LiAlH Inorganic materials 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
- HKVFISRIUUGTIB-UHFFFAOYSA-O azanium;cerium;nitrate Chemical compound [NH4+].[Ce].[O-][N+]([O-])=O HKVFISRIUUGTIB-UHFFFAOYSA-O 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000002074 melt spinning Methods 0.000 description 3
- CHMBIJAOCISYEW-UHFFFAOYSA-N n-(4-aminophenyl)acetamide Chemical compound CC(=O)NC1=CC=C(N)C=C1 CHMBIJAOCISYEW-UHFFFAOYSA-N 0.000 description 3
- 239000012299 nitrogen atmosphere Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000003825 pressing Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- XBCGIUJJUZHWMC-UHFFFAOYSA-N 2,5-dichloroterephthalaldehyde Chemical compound ClC1=CC(C=O)=C(Cl)C=C1C=O XBCGIUJJUZHWMC-UHFFFAOYSA-N 0.000 description 2
- HQCHAOKWWKLXQH-UHFFFAOYSA-N 2,6-Dichloro-para-phenylenediamine Chemical compound NC1=CC(Cl)=C(N)C(Cl)=C1 HQCHAOKWWKLXQH-UHFFFAOYSA-N 0.000 description 2
- NUIURNJTPRWVAP-UHFFFAOYSA-N 3,3'-Dimethylbenzidine Chemical group C1=C(N)C(C)=CC(C=2C=C(C)C(N)=CC=2)=C1 NUIURNJTPRWVAP-UHFFFAOYSA-N 0.000 description 2
- GXZZHLULZRMUQC-UHFFFAOYSA-N 4-(4-formylphenoxy)benzaldehyde Chemical compound C1=CC(C=O)=CC=C1OC1=CC=C(C=O)C=C1 GXZZHLULZRMUQC-UHFFFAOYSA-N 0.000 description 2
- FEHLIYXNTWAEBQ-UHFFFAOYSA-N 4-(4-formylphenyl)benzaldehyde Chemical group C1=CC(C=O)=CC=C1C1=CC=C(C=O)C=C1 FEHLIYXNTWAEBQ-UHFFFAOYSA-N 0.000 description 2
- HLBLWEWZXPIGSM-UHFFFAOYSA-N 4-Aminophenyl ether Chemical compound C1=CC(N)=CC=C1OC1=CC=C(N)C=C1 HLBLWEWZXPIGSM-UHFFFAOYSA-N 0.000 description 2
- HSBOCPVKJMBWTF-UHFFFAOYSA-N 4-[1-(4-aminophenyl)ethyl]aniline Chemical compound C=1C=C(N)C=CC=1C(C)C1=CC=C(N)C=C1 HSBOCPVKJMBWTF-UHFFFAOYSA-N 0.000 description 2
- MCPYGRMFFWRENO-UHFFFAOYSA-N 4-[12-(4-amino-3-methylphenoxy)dodecoxy]-2-methylaniline Chemical compound C1=C(N)C(C)=CC(OCCCCCCCCCCCCOC=2C=C(C)C(N)=CC=2)=C1 MCPYGRMFFWRENO-UHFFFAOYSA-N 0.000 description 2
- MHVJXCOFNBISKG-UHFFFAOYSA-N 4-[4-(4-amino-3-methylphenoxy)butoxy]-2-methylaniline Chemical compound C1=C(N)C(C)=CC(OCCCCOC=2C=C(C)C(N)=CC=2)=C1 MHVJXCOFNBISKG-UHFFFAOYSA-N 0.000 description 2
- SMJFFCXQIQIRSV-UHFFFAOYSA-N 4-amino-3-methylbenzaldehyde Chemical compound CC1=CC(C=O)=CC=C1N SMJFFCXQIQIRSV-UHFFFAOYSA-N 0.000 description 2
- GOUHYARYYWKXHS-UHFFFAOYSA-N 4-formylbenzoic acid Chemical compound OC(=O)C1=CC=C(C=O)C=C1 GOUHYARYYWKXHS-UHFFFAOYSA-N 0.000 description 2
- 229940044174 4-phenylenediamine Drugs 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 2
- 229960000583 acetic acid Drugs 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- IZALUMVGBVKPJD-UHFFFAOYSA-N benzene-1,3-dicarbaldehyde Chemical compound O=CC1=CC=CC(C=O)=C1 IZALUMVGBVKPJD-UHFFFAOYSA-N 0.000 description 2
- VEFXTGTZJOWDOF-UHFFFAOYSA-N benzene;hydrate Chemical compound O.C1=CC=CC=C1 VEFXTGTZJOWDOF-UHFFFAOYSA-N 0.000 description 2
- PASDCCFISLVPSO-UHFFFAOYSA-N benzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1 PASDCCFISLVPSO-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000007810 chemical reaction solvent Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- VKIRRGRTJUUZHS-UHFFFAOYSA-N cyclohexane-1,4-diamine Chemical compound NC1CCC(N)CC1 VKIRRGRTJUUZHS-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 2
- 239000012362 glacial acetic acid Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 2
- 229910052808 lithium carbonate Inorganic materials 0.000 description 2
- GPSDUZXPYCFOSQ-UHFFFAOYSA-N m-toluic acid Chemical compound CC1=CC=CC(C(O)=O)=C1 GPSDUZXPYCFOSQ-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 150000004986 phenylenediamines Chemical class 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 description 1
- NMNYZCYUYMFSQA-UHFFFAOYSA-N (4-aminophenyl)-(4-aminophenyl)imino-oxidoazanium Chemical compound C1=CC(N)=CC=C1N=[N+]([O-])C1=CC=C(N)C=C1 NMNYZCYUYMFSQA-UHFFFAOYSA-N 0.000 description 1
- 229910000667 (NH4)2Ce(NO3)6 Inorganic materials 0.000 description 1
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 1
- ZJJATABWMGVVRZ-UHFFFAOYSA-N 1,12-dibromododecane Chemical compound BrCCCCCCCCCCCCBr ZJJATABWMGVVRZ-UHFFFAOYSA-N 0.000 description 1
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 1
- ULTHEAFYOOPTTB-UHFFFAOYSA-N 1,4-dibromobutane Chemical compound BrCCCCBr ULTHEAFYOOPTTB-UHFFFAOYSA-N 0.000 description 1
- LVQFKRXRTXCQCZ-UHFFFAOYSA-N 1-(2-acetylphenyl)ethanone Chemical compound CC(=O)C1=CC=CC=C1C(C)=O LVQFKRXRTXCQCZ-UHFFFAOYSA-N 0.000 description 1
- YSTSBXDVNKYPTR-UHFFFAOYSA-N 1-[4-(4-acetylphenyl)phenyl]ethanone Chemical group C1=CC(C(=O)C)=CC=C1C1=CC=C(C(C)=O)C=C1 YSTSBXDVNKYPTR-UHFFFAOYSA-N 0.000 description 1
- VSUKSWCSOBXUFG-UHFFFAOYSA-N 2,5-dibromoterephthalaldehyde Chemical compound BrC1=CC(C=O)=C(Br)C=C1C=O VSUKSWCSOBXUFG-UHFFFAOYSA-N 0.000 description 1
- YSIIHTHHMPYKFP-UHFFFAOYSA-N 2,5-dimethoxyterephthalaldehyde Chemical compound COC1=CC(C=O)=C(OC)C=C1C=O YSIIHTHHMPYKFP-UHFFFAOYSA-N 0.000 description 1
- FXWFZIRWWNPPOV-UHFFFAOYSA-N 2-aminobenzaldehyde Chemical compound NC1=CC=CC=C1C=O FXWFZIRWWNPPOV-UHFFFAOYSA-N 0.000 description 1
- YVNJOTVKIMMVLW-UHFFFAOYSA-N 2-bromoterephthalaldehyde Chemical compound BrC1=CC(C=O)=CC=C1C=O YVNJOTVKIMMVLW-UHFFFAOYSA-N 0.000 description 1
- DFIOBSJHIZBUCE-UHFFFAOYSA-N 2-hydroxyterephthalaldehyde Chemical compound OC1=CC(C=O)=CC=C1C=O DFIOBSJHIZBUCE-UHFFFAOYSA-N 0.000 description 1
- FRTOGSDNMUZZKR-UHFFFAOYSA-N 2-methoxyterephthalaldehyde Chemical compound COC1=CC(C=O)=CC=C1C=O FRTOGSDNMUZZKR-UHFFFAOYSA-N 0.000 description 1
- WOZUXQYPADNGNY-UHFFFAOYSA-N 2-methyl-4-[4-(3-methyl-4-nitrophenoxy)butoxy]-1-nitrobenzene Chemical compound C1=C([N+]([O-])=O)C(C)=CC(OCCCCOC=2C=C(C)C(=CC=2)[N+]([O-])=O)=C1 WOZUXQYPADNGNY-UHFFFAOYSA-N 0.000 description 1
- KDQPMQNHVQVVMR-UHFFFAOYSA-N 2-methyl-4-nitrophenol Chemical compound CC1=CC([N+]([O-])=O)=CC=C1O KDQPMQNHVQVVMR-UHFFFAOYSA-N 0.000 description 1
- NTNUPCREDHXJEL-UHFFFAOYSA-N 2-methylbenzene-1,4-dicarbonyl chloride Chemical compound CC1=CC(C(Cl)=O)=CC=C1C(Cl)=O NTNUPCREDHXJEL-UHFFFAOYSA-N 0.000 description 1
- ICNFHJVPAJKPHW-UHFFFAOYSA-N 4,4'-Thiodianiline Chemical compound C1=CC(N)=CC=C1SC1=CC=C(N)C=C1 ICNFHJVPAJKPHW-UHFFFAOYSA-N 0.000 description 1
- KQIKKETXZQDHGE-FOCLMDBBSA-N 4,4'-diaminoazobenzene Chemical compound C1=CC(N)=CC=C1\N=N\C1=CC=C(N)C=C1 KQIKKETXZQDHGE-FOCLMDBBSA-N 0.000 description 1
- YBRVSVVVWCFQMG-UHFFFAOYSA-N 4,4'-diaminodiphenylmethane Chemical compound C1=CC(N)=CC=C1CC1=CC=C(N)C=C1 YBRVSVVVWCFQMG-UHFFFAOYSA-N 0.000 description 1
- NEQFBGHQPUXOFH-UHFFFAOYSA-N 4-(4-carboxyphenyl)benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1C1=CC=C(C(O)=O)C=C1 NEQFBGHQPUXOFH-UHFFFAOYSA-N 0.000 description 1
- ICDOLJWVDBMASK-UHFFFAOYSA-N 4-[(4-formylphenyl)methyl]benzaldehyde Chemical compound C1=CC(C=O)=CC=C1CC1=CC=C(C=O)C=C1 ICDOLJWVDBMASK-UHFFFAOYSA-N 0.000 description 1
- NCAJMNHLAZAVRZ-OWOJBTEDSA-N 4-[(e)-2-(4-formylphenyl)ethenyl]benzaldehyde Chemical compound C1=CC(C=O)=CC=C1\C=C\C1=CC=C(C=O)C=C1 NCAJMNHLAZAVRZ-OWOJBTEDSA-N 0.000 description 1
- SNDLGRIONHJZFH-UHFFFAOYSA-N 4-[1-(4-formylphenyl)ethyl]benzaldehyde Chemical compound C=1C=C(C=O)C=CC=1C(C)C1=CC=C(C=O)C=C1 SNDLGRIONHJZFH-UHFFFAOYSA-N 0.000 description 1
- HHDFKOSSEXYTJN-UHFFFAOYSA-N 4-[2-(4-aminophenoxy)ethoxy]aniline Chemical compound C1=CC(N)=CC=C1OCCOC1=CC=C(N)C=C1 HHDFKOSSEXYTJN-UHFFFAOYSA-N 0.000 description 1
- VAXBLYWAVAIJJJ-UHFFFAOYSA-N 4-[2-(4-carboxyphenoxy)ethoxy]benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1OCCOC1=CC=C(C(O)=O)C=C1 VAXBLYWAVAIJJJ-UHFFFAOYSA-N 0.000 description 1
- BMIUMBLWVWZIHD-UHFFFAOYSA-N 4-[3-(4-aminophenyl)propyl]aniline Chemical compound C1=CC(N)=CC=C1CCCC1=CC=C(N)C=C1 BMIUMBLWVWZIHD-UHFFFAOYSA-N 0.000 description 1
- PZBWQICCJHUJGP-UHFFFAOYSA-N 4-[4-(4-aminophenyl)butyl]aniline Chemical compound C1=CC(N)=CC=C1CCCCC1=CC=C(N)C=C1 PZBWQICCJHUJGP-UHFFFAOYSA-N 0.000 description 1
- ZBHHWKBPSJWDBX-UHFFFAOYSA-N 4-amino-2-methylbenzaldehyde Chemical compound CC1=CC(N)=CC=C1C=O ZBHHWKBPSJWDBX-UHFFFAOYSA-N 0.000 description 1
- FNTUAAGLCQIYTB-UHFFFAOYSA-N 4-amino-3-chlorobenzaldehyde Chemical compound NC1=CC=C(C=O)C=C1Cl FNTUAAGLCQIYTB-UHFFFAOYSA-N 0.000 description 1
- FHQLDUVZIQIJHK-UHFFFAOYSA-N 4-amino-3-fluorobenzaldehyde Chemical compound NC1=CC=C(C=O)C=C1F FHQLDUVZIQIJHK-UHFFFAOYSA-N 0.000 description 1
- WPBZMCGPFHZRHJ-UHFFFAOYSA-N 4-aminobenzohydrazide Chemical compound NNC(=O)C1=CC=C(N)C=C1 WPBZMCGPFHZRHJ-UHFFFAOYSA-N 0.000 description 1
- RWGGISRILXKSCH-UHFFFAOYSA-N 4-n-bromobenzene-1,4-diamine Chemical compound NC1=CC=C(NBr)C=C1 RWGGISRILXKSCH-UHFFFAOYSA-N 0.000 description 1
- YOJKEVXNAVNUGW-UHFFFAOYSA-N 4-n-chlorobenzene-1,4-diamine Chemical compound NC1=CC=C(NCl)C=C1 YOJKEVXNAVNUGW-UHFFFAOYSA-N 0.000 description 1
- AZSDEGXYYBHUKM-UHFFFAOYSA-N 4-n-fluorobenzene-1,4-diamine Chemical compound NC1=CC=C(NF)C=C1 AZSDEGXYYBHUKM-UHFFFAOYSA-N 0.000 description 1
- IHWPTLPROWODBQ-UHFFFAOYSA-N 4-n-methoxybenzene-1,4-diamine Chemical compound CONC1=CC=C(N)C=C1 IHWPTLPROWODBQ-UHFFFAOYSA-N 0.000 description 1
- ZETHHMPKDUSZQQ-UHFFFAOYSA-N Betulafolienepentol Natural products C1C=C(C)CCC(C(C)CCC=C(C)C)C2C(OC)OC(OC)C2=C1 ZETHHMPKDUSZQQ-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- DBAKFASWICGISY-DASCVMRKSA-N Dexchlorpheniramine maleate Chemical compound OC(=O)\C=C/C(O)=O.C1([C@H](CCN(C)C)C=2N=CC=CC=2)=CC=C(Cl)C=C1 DBAKFASWICGISY-DASCVMRKSA-N 0.000 description 1
- 229920002430 Fibre-reinforced plastic Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 1
- XQVWYOYUZDUNRW-UHFFFAOYSA-N N-Phenyl-1-naphthylamine Chemical compound C=1C=CC2=CC=CC=C2C=1NC1=CC=CC=C1 XQVWYOYUZDUNRW-UHFFFAOYSA-N 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 102000002508 Peptide Elongation Factors Human genes 0.000 description 1
- 108010068204 Peptide Elongation Factors Proteins 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 241001632427 Radiola Species 0.000 description 1
- PCSMJKASWLYICJ-UHFFFAOYSA-N Succinic aldehyde Chemical compound O=CCCC=O PCSMJKASWLYICJ-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- DUIZMPHEHYRGGV-UHFFFAOYSA-N [4-[2-[4-(hydroxymethyl)phenoxy]ethoxy]phenyl]methanol Chemical compound C1=CC(CO)=CC=C1OCCOC1=CC=C(CO)C=C1 DUIZMPHEHYRGGV-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000012675 alcoholic extract Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 230000003321 amplification Effects 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- HFACYLZERDEVSX-UHFFFAOYSA-N benzidine Chemical group C1=CC(N)=CC=C1C1=CC=C(N)C=C1 HFACYLZERDEVSX-UHFFFAOYSA-N 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000009529 body temperature measurement Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000011088 calibration curve Methods 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007123 defense Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- HEOKFDGOFROELJ-UHFFFAOYSA-N diacetal Natural products COc1ccc(C=C/c2cc(O)cc(OC3OC(COC(=O)c4cc(O)c(O)c(O)c4)C(O)C(O)C3O)c2)cc1O HEOKFDGOFROELJ-UHFFFAOYSA-N 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 125000004989 dicarbonyl group Chemical group 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 235000012438 extruded product Nutrition 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000011151 fibre-reinforced plastic Substances 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- VQUHVWVGRKTIBH-UHFFFAOYSA-N hydron;2-methylbenzene-1,4-diamine;dichloride Chemical compound Cl.Cl.CC1=CC(N)=CC=C1N VQUHVWVGRKTIBH-UHFFFAOYSA-N 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000005305 interferometry Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229940098779 methanesulfonic acid Drugs 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- ZTQDYDIRBKMMQB-UHFFFAOYSA-N n-(4-aminophenyl)nitramide Chemical compound NC1=CC=C(N[N+]([O-])=O)C=C1 ZTQDYDIRBKMMQB-UHFFFAOYSA-N 0.000 description 1
- XUFLAVKRRLBIMV-UHFFFAOYSA-N naphthalene-1,4-dicarbaldehyde Chemical compound C1=CC=C2C(C=O)=CC=C(C=O)C2=C1 XUFLAVKRRLBIMV-UHFFFAOYSA-N 0.000 description 1
- KQSABULTKYLFEV-UHFFFAOYSA-N naphthalene-1,5-diamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1N KQSABULTKYLFEV-UHFFFAOYSA-N 0.000 description 1
- YAELIZGEEWGECG-UHFFFAOYSA-N naphthalene-1,5-dicarbaldehyde Chemical compound C1=CC=C2C(C=O)=CC=CC2=C1C=O YAELIZGEEWGECG-UHFFFAOYSA-N 0.000 description 1
- GOGZBMRXLADNEV-UHFFFAOYSA-N naphthalene-2,6-diamine Chemical compound C1=C(N)C=CC2=CC(N)=CC=C21 GOGZBMRXLADNEV-UHFFFAOYSA-N 0.000 description 1
- IQDQMRZGMILNMQ-UHFFFAOYSA-N naphthalene-2,6-dicarbaldehyde Chemical compound C1=C(C=O)C=CC2=CC(C=O)=CC=C21 IQDQMRZGMILNMQ-UHFFFAOYSA-N 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 150000002828 nitro derivatives Chemical class 0.000 description 1
- 238000003199 nucleic acid amplification method Methods 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920005594 polymer fiber Polymers 0.000 description 1
- 238000000710 polymer precipitation Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- GVWYIGSUECJNRM-UHFFFAOYSA-N pyridine-2,5-dicarbaldehyde Chemical compound O=CC1=CC=C(C=O)N=C1 GVWYIGSUECJNRM-UHFFFAOYSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000010058 rubber compounding Methods 0.000 description 1
- 150000003839 salts Chemical group 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- MHSKRLJMQQNJNC-UHFFFAOYSA-N terephthalamide Chemical compound NC(=O)C1=CC=C(C(N)=O)C=C1 MHSKRLJMQQNJNC-UHFFFAOYSA-N 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000012719 thermal polymerization Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
- C08G12/04—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
- C08G12/06—Amines
- C08G12/08—Amines aromatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00Â -Â C08G71/00
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Artificial Filaments (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Description
ãçºæã®è©³çŽ°ãªèª¬æã
åæããªã¢ããã®ããŒãïŒåã¯æº¶æ¶²ïŒãäŸãã°
ã¯ãªãŒã¬ãã¯ïŒKwolekïŒã®ç±³åœç¹èš±ç¬¬3671542
å·ã®ããŒãã«å¯ŸããŠã¯å åŠçç°æ¹æ§ãç¥ãããŠã
ããããªãªã¬ãã€ã³æº¶èç©ã«å¯ŸããŠåœæ¥çã«ãã
ãŠæ¶²æ¶çæåãå ±åãããŠããã æç®ã«ã¯ããªã¢ãŸã¡ãã³ãåã¯ããªïŒã·ããå¡©
åºïŒããåºãèšèŒãããŠããããäŸãã°ããšã³ãµã€
ã¯ãããã€ã¢ã»ãªãŽã»ããªããŒã»ãµã€ãšã³ã¹ã»ã¢
ã³ãã»ãã¯ãããžãŒïŒEncyclopedia of
Polymer Science and TechnologyïŒã第10å·»
659ã670é ïŒ1960幎ïŒããžãŒã»ãšãã»ãã¬ãªãª
ïŒG.F.Dâ²AlelioïŒè ç±³åœããŠãŒãšãŒã¯ãã€ã³ã¿
ãŒãµã€ãšã³ã¹ã»ãããªãã·ã€ãŒãºïŒInterscience
PublishersïŒçºè¡åç §ãããŸãç±³åœç¹èš±ç¬¬3526611
å·åã³å第3418281å·ã®ãããªç¹èš±ã«ãèšèŒãã
ãŠããã é«æž©ãé«å§ã§æ圢å¯èœãªããªã¢ãŸã¡ãã³ã¯ç±³åœ
ç¹èš±ç¬¬3418281å·åã³è±åœç¹èš±ç¬¬1080526å·ã«èšèŒ
ãããŠããããããã®éåäœã¯è¯å¥œãªç±çå®å®æ§
ãšéæ§ãšããã€ãŠãããšäºãããŠãããåžè溶液
ãã泚圢å¯èœãåã¯é«æž©ãé«å§ã§ãã¬ã¹ãããã
ãªã¢ãŸã¡ãã³ã»ãã€ã«ã ã¯ããŒã«ãŒïŒBakerïŒã
ã®1974幎ïŒæïŒæ¥ä»T918005å·ãªãã·ã€ã«ã»ã¬ãŒ
ããïŒOffiâcial GazetteïŒïŒé²è¡åºçç©ïŒã«èš
èŒãããŠãããããããããã®åŸæ¥æ³ã®ã©ãã«ã
çŽæ¥æº¶èé²ç³žããŠãã€ã©ã¡ã³ãã«ããããšãã§ã
ãç°æ¹æ§æº¶èç©ãæçš®ã®è³éŠæããªã¢ãŸã¡ãã³ã
çæããããšã¯èšèŒãããŠããªãã æ¬çºæã«ããã°éåäœæº¶è枩床ã375âããäœ
ããåºæç²åºŠãå°ããšã0.2ã§ã溶èç¶æ ã«ãã
ãŠå åŠçç°æ¹æ§ã瀺ãè³éŠæåã³èç°åŒã®æ°èŠæº¶
è玡糞å¯èœãªããªã¢ãŸã¡ãã³åã³ã¢ãŸã¡ãã³å ±é
åäœãæäŸããããããã«æ¬çºæã«ããã°åŸã§å»¶
䌞ããããšãªããããã®éåäœãã玡糞ãããæ°
èŠæçšãªé åç¹ç¶ãæäŸããããå€ãã®çŽ¡ç³žãã
ãŸãã®ç¹ç¶ã¯å®è³ªçã«åŒç·©ããç¶æ ã§ãåã¯ãã³
ãšåŒµã€ãç¶æ ã§100â以äžã§ããããã®èç¹ä»¥äž
ã®æž©åºŠã«å ç±ãããšé åæ§ãšåŒ·åºŠãšãå¢å ãããŸ
ã屡ã ã¢ãžãŠã©ã¹ãå¢å ããããã®éåäœããä»
ã®æ圢äœãäŸãã°ãã€ã«ã åã³æ£ãã€ããããšã
ã§ããã æ¬çºæã«ããã°éåäœãäžèšåäœ () ïŒïŒïŒ®âR1âïŒïŒ () ãåŒã åã³ () ãåŒã äœãåäœåã³ã¯ããååšãããªãã°å®è³ªç
ã«çã¢ã«éã§ååšããZ1ïŒZ2åã³Z3ã¯åäžåã¯çž
ç°ãããšãã§ããæ°ŽçŽ ååãåã¯ã¡ãã«åã¯ãšã
ã«åºããéžã°ããR1ïŒR2åã³R3㯠(1) åäžåã¯èåããççŽ ç°åŒå å¡ç°ç³»ã§ãã€
ãŠãè³éŠæãããååšãããªãã°ãã®è³éŠç°ã®
ç°ççŽ ã®äžã€ã¯çªçŽ ã§çœ®æããããããšãã§
ãã該ç°ç³»ã®é£é䌞匵çµåã¯ã該çµåãããå
äžç°ã«çµåããŠãããªãã°äºãã«ïŒïŒïŒã®äœçœ®
ã«äœçœ®ããããç°ã€ãç°ã«çµåããŠãããªãã°
å¹³è¡ã§äžã€å察æ¹åã«åã€ãäœçœ®ã«äœçœ®ããå
äžããã³èåããççŽ ç°åŒå å¡ç°ç³»ã®åºããã³ (2) å€ç°ç³»ã§ãã€ãŠãåã ã®ç°ãååŠçµååã¯é·
ããååæ°14ãè¶ ããªãã奜ãŸããã¯ïŒãè¶ ã
ãªãæ¶æ©åäœã«ããçµåãããåç°ã®é£é䌞匵
çµåãïŒïŒïŒã®äœçœ®ã«ãããR1ã¯ååŠçµåã§
ããããšãã§ããå€ç°ç³»ã®åºããæã矀ããéž
ã°ããåºã§ããã ããéžã°ããåèŠæ§é åäœããå®è³ªçã«æãããš
ãç¹åŸŽãšããããªã¢ãŸã¡ãã³åã³ã¢ãŸã¡ãã³å ±é
åäœãæäŸã§ããã (1)ã®äŸã¯ãåŒããåŒã ãåŒããåŒããåŒãã§ã ãã (2)ã®äŸã¯ãåŒã ãåŒã ãåŒã ãåŒãåã³ ãåŒãã§ããã äžè¿°ã®ç°ç³»ã«ã¯ãŸãïŒååã¯ãã以äžã®çœ®æ
åºãäŸãã°äœçŽã¢ã«ãã«ïŒççŽ æ°ïŒãïŒïŒåã³ã¯
ããåºããã€ãã®ãå«ãŸããã ãŸãæ¬çºæã«ãããŠã¯ïŒåã³ã®åäœã®å š
äœã«å¯Ÿãæ倧40ã¢ã«ïŒ ã奜ãŸããã¯æ倧25ã¢ã«ïŒ
ããåè¿°ã®ïŒåã³ã®åäœãšåèŽããªããé
åäœã®å åŠçç°æ¹æ§ããã€æº¶èç©çæèœã劚害ã
ãªãããªã¢ãŸã¡ãã³çæåäœã«ãã€ãŠçœ®æããã
ãŠããããšãã§ããããããã®åäœã«ã¯æ¬¡ã®ãã®
ããããããã¯æ¬çºæãéå®ãããã®ã§ã¯ãªãã ãåŒãïŒïŒ®âïŒCH2ïŒ6âïŒïŒ ãåŒãåã³ ãåŒãäžè¿°ã®ããªã¢ãŸã¡ ãã³ïŒå ±ïŒéåäœã¯å®è³ªã«çã¢ã«éã®åäœåã³
ãå«ãã§ããããåã¯åäœããæããæãã¯
åäœïŒåã³ã®çµåããããæããå¿è«ïŒçš®
ãè¶ ããåäœïŒïŒåã³ïŒãéåäœäžã«ååš
ããããšãã§ãããäŸãã° ãåŒãåã³ãåŒãåäœã æ¬çºæã®å¥œé©ãªããªã¢ãŸã¡ãã³ïŒå ±ïŒéåäœã¯
å®è³ªçã«åäœåã³ããæã€ãŠããããã®ãã
ãªéåäœã«ãããŠã¯ãR1ã¯ã¯ããâãããã¢âã
ã¡ããã·âããã«ãªãâãã¡ãã«âãããããã·
âåã³ãããâïŒïŒïŒâããšãã¬ã³ïŒïŒïŒ4â²âã
ããšãã¬ã³ïŒïŒïŒ3â²âãžã¡ãã«âïŒïŒ4â²âãããš
ãã¬ã³ãïŒïŒïŒâããšãã¬ã³ïŒïŒïŒ4â²âã¡ãã¬ã³
ãžããšãã¬ã³ïŒïŒïŒ4â²âãžã¡ãã¬ã³ãžããšãã¬
ã³ïŒïŒïŒ4â²âããªã¡ãã¬ã³ãžããšãã¬ã³ïŒïŒïŒ
4â²âããã©ã¡ãã¬ã³ãžããšãã¬ã³ïŒïŒïŒïŒâãã
ãã¬ã³ïŒïŒïŒïŒâãããã¬ã³ïŒïŒïŒïŒâãžã¯ãã
âïŒïŒïŒâããšãã¬ã³ïŒãã©ã³ã¹âïŒïŒïŒâã·ã¯
ãããã·ã¬ã³ïŒãã©ã³ã¹âïŒâã¡ãã«âïŒïŒïŒâ
ã·ã¯ãããã·ã¬ã³ïŒãã©ã³ã¹âïŒïŒ4â²âã¡ãã¬ã³
ãžã·ã¯ãããã·ã¬ã³ïŒïŒïŒ3â²âãžã¡ãã«âïŒïŒ
4â²âããã©ã¡ãã¬ã³ãžãªãã·ãžããšãã¬ã³ïŒïŒïŒ
4â²âã¢ãŸãã·ãžããšãã¬ã³ïŒïŒïŒ3â²âãžã¡ãã«â
ïŒïŒ4â²âã¢ãŸãžããšãã¬ã³åã³åçµåããæã矀
ããéžã°ãïŒR2ã¯ïŒïŒïŒâããšãã¬ã³ïŒã¯ãã
âïŒïŒïŒâããšãã¬ã³ïŒã¡ãã«âïŒïŒïŒâããšã
ã¬ã³ïŒïŒïŒ4â²âãããšãã¬ã³ïŒïŒïŒ4â²âãªãã·ãž
ããšãã¬ã³ïŒïŒïŒ4â²âãšãã¬ã³ãžããšãã¬ã³ïŒ
ïŒïŒ4â²âã¡ãã¬ã³ãžããšãã¬ã³ïŒïŒïŒ4â²âãšãã¬
ã³ãžãªãã·ãžããšãã¬ã³ïŒïŒïŒïŒâããªãžããã€
ã«ïŒïŒïŒïŒâãããã¬ã³ïŒïŒïŒïŒâãããã¬ã³ïŒ
ïŒïŒïŒâãããã¬ã³ïŒïŒïŒïŒâãžã¯ããâïŒïŒïŒ
âããšãã¬ã³ïŒïŒïŒïŒâãžããã¢âïŒïŒïŒâããš
ãã¬ã³ïŒïŒïŒïŒâãžã¡ããã·âïŒïŒïŒâããšãã¬
ã³ïŒïŒâããã¢âïŒïŒïŒâããšãã¬ã³ïŒïŒâã¡ã
ãã·âïŒïŒïŒâããšãã¬ã³ïŒåã³ïŒâããããã·
âïŒïŒïŒâããšãã¬ã³åºããæã矀ããéžã°ã
ããããã«å¥œãŸããã¯ãã®ãããªåäœåã³ã®
ç°ç³»ã®å šæ°ã®å°ããšã25ïŒ ã¯ãè¯å¥œã®å å·¥æ§å
ã³ïŒåã¯ããã«äŒŽãè¯å¥œãªå®å®æ§ã®ããã«ãã¯ã
ãåã³ã¡ãã«åºããæã矀ããéžã°ããåºã§ç°ã«
眮æãããŠããã åäœã®ã¿ãååšããå Žåãæãã¯åäœåã³
ãšäžç·ã«ååšããå Žåã«ã¯ãR3ã¯ïŒïŒïŒâã
ãšãã¬ã³ãã¡ãã«âïŒïŒïŒâããšãã¬ã³ãïŒïŒ
4â²âãªãã·ãžããšãã¬ã³ãïŒïŒïŒâãããã¬ã³ã
ïŒïŒïŒâãããã¬ã³åã³ã¯ããâïŒïŒïŒâããšã
ã¬ã³åºããæã矀ããéžã°ããããšã奜ãŸããã éåäœãå®è³ªçã«åäœããæã€ãŠããããå
ã¯ïŒãåã³ã®åäœã®çµåããããæã€ãŠã
ãå Žåããã®ãããªåäœã®ç°ç³»ã®å šæ°ã®å°ãªããš
ã25ïŒ ã¯ã¯ããåã³ã¡ãã«åºããæã矀ããéžã°
ããåºãç°ã«çœ®æããŠããããšã奜ãŸããã 奜é©ãªéåäœã¯(1)è¯å¥œãªåŠçæ§ã®ããã«ã¯ã¡ã
ã«âïŒïŒïŒâããšãã¬ã³ãžã¢ãã³åã³ãã¬ãã¿ã«
ã¢ã«ãããããã€ãããããã®ã§ããã(2)ç¹ç¶ã¯
ç¹ã«é«åŒ·åºŠã§ããããã¡ãã«âïŒïŒïŒâããšãã¬
ã³ãžã¢ãã³ãïŒïŒïŒâããšãã¬ã³ãžã¢ãã³åã³ã
ã¬ãã¿ã«ã¢ã«ãããããã€ãããããã®ã§ããã
ãŸã(3)è¯å¥œãªå æ°Žå解èæ§ããã€ãé«çµæ¶æ§ç¹ç¶
ãã€ããããã«ãã¹ïŒïŒâã¢ããããšãã«ïŒãšã¿
ã³åã³ã¯ãããã¬ãã¿ã«ã¢ã«ãããããã€ããã
ããã®ã§ããã æ¬çºæã®ã¢ãŸã¡ãã³ïŒå ±ïŒéåäœã¯å åŠçã«ç°
æ¹æ§ã®ãã溶èç©ãçæãã375â以äžã奜ãŸã
ãã¯350â以äžã§æº¶èããç¹ç¶åã³ä»ã®æ圢åãž
ã®å å·¥æ§ãäžãããã®ã§ãªããã°ãªããªãããã
ãããé«ã枩床ã§ã¯ãã®æ§é ã«äŸåããŠããªã¢ãŸ
ã¡ãã³ïŒå ±ïŒéåäœã®è¿ éãªå解ãèµ·ãããã®æº¶
èç©ã¯å¹³è¡ã«äžŠãã éåéã®é åãæ§æãããã
ã玡糞工çšã«ãããŠçŽ¡ç³žããç¶æ ã§é åããç¹ç¶
ãçãããã®ãšä¿¡ããããã æ¬çºæã®ããªã¢ãŸã¡ãã³ïŒå ±ïŒéåäœã¯æº¶è玡
糞å¯èœã§ãããã溶è玡糞å¯èœããšã¯æº¶è玡糞ã
ãããšãã§ãããã€ã©ã¡ã³ãã玡糞ããã®ã«å¿ èŠ
ãªæéã®é溶èç¶æ ãä¿æãåŸãããšãæå³ã
ããä»ã®ããªã¢ãŸã¡ãã³ïŒå ±ïŒéåäœã¯æº¶èããª
ããããã«ä»ã®ãã®ã¯é«æž©ã«ãããŠç¬éçã«è»å
åã¯æµåããããã«èŠãã次ã«ç¡¬åããŠäžæº¶èæ§
ç©è³ªã«ãªããããã¯ããã«è¿ éãªéåã«ãããã®
ãšä¿¡ãããããæ¬çºæã®æº¶è玡糞å¯èœéåäœã¯å°
ããšãïŒåé溶èç¶æ ã«ä¿æããåŸãã æ¬çºæã®ããªã¢ãŸã¡ãã³ïŒå ±ïŒéåäœã¯åŒ H2NâR1âNH2 ã®ãžã¢ãã³ãåŒãåŒãã®ãžã¢ã«ããã åã¯ãžã±ãã³ãåã³ïŒåã¯åŒãåŒãã® ã¢ããã¢ã«ãããåã¯ã¢ããã±ãã³ãåã¯ãã®ã
ããªåæã®å®èœåºçã«åçãªèªå°äœãšåå¿ããã
ããšã«ããã€ãããããããã§ãR1ïŒR2åã³R3
㯠(1) åäžåã¯èåããççŽ ç°åŒå å¡ç°ç³»ã§ãã€
ãŠãè³éŠç°ãããååšãããªãã°ãã®è³éŠç°ã®
ç°ççŽ ã®äžã€ã¯çªçŽ ã§çœ®æããããããšãã§
ãã該ç°ç³»ã®é£é䌞匵çµåã¯ã該çµåãããå
äžç°ã«çµåããŠãããªãã°äºãã«ïŒïŒïŒã®äœçœ®
ã«äœçœ®ããããç°ã€ãç°ã«çµåããŠãããªãã°
å¹³è¡ã§äžã€å察æ¹åã«åã€ãäœçœ®ã«äœçœ®ããå
äžããã³èåããççŽ ç°åŒå å¡ç°ç³»ã®åºããã³ (2) å€ç°ç³»ã奜ãŸããã¯ççŽ ç°åŒå€ç°ç³»ã§ãã€
ãŠãåã ã®ç°ãååŠçµååã¯é·ããååæ°14ã
è¶ ããªãã奜ãŸããã¯ïŒãè¶ ããªãæ¶æ©åäœã«
ããçµåãããåç°ã®é£é䌞匵çµåãïŒïŒïŒã®
äœçœ®ã«ãããR1ã¯ååŠçµåã§ããããšãã§ã
ãå€ç°ç³»ã®åº ããæã矀ããéžã°ããåºã§ãããZ1ïŒZ2ïŒåã³
Z3ã¯æ°ŽçŽ åååã¯ã¡ãã«åã¯ãšãã«åºããæã矀
ããéžã°ãããã®ãšããã æ¬çºæã®éåäœãã€ããã®ã«æçšãªãžã¢ãã³ã¯
åŒH2NâR1âNH2ã«å¯Ÿå¿ãããäœãR1ã¯åè¿°ã®
æå³ãæããããžã¢ãã³ã®äžã«ã¯ïŒïŒïŒâããšã
ã¬ã³ãžã¢ãã³ãã¯ããâïŒïŒïŒâããšãã¬ã³ãžã¢
ãã³ãããã¢âïŒïŒïŒâããšãã¬ã³ãžã¢ãã³ãã
ã«ãªãâïŒïŒïŒâããšãã¬ã³ãžã¢ãã³ãã¡ãã«â
ïŒïŒïŒâããšãã¬ã³ãžã¢ãã³ãã¡ããã·âïŒïŒïŒ
âããšãã¬ã³ãžã¢ãã³ããããâïŒïŒïŒâããšã
ã¬ã³ãžã¢ãã³ãïŒïŒïŒâãžã¯ããâïŒïŒïŒâããš
ãã¬ã³ãžã¢ãã³ãïŒïŒ4â²âãžã¢ãããããšãã«ã
ïŒïŒ3â²âãžã¡ãã«âïŒïŒ4â²âãžã¢ãããããšã
ã«ããã¹ïŒïŒâã¢ããããšãã«ïŒãšã¿ã³ãïŒïŒïŒ
âãã¹ïŒïŒâã¢ããããšãã«ïŒãããã³ãïŒïŒïŒ
âãã¹ïŒïŒâã¢ããããšãã«ïŒãã¿ã³ãïŒïŒïŒâ
ããã¿ã¬ã³ãžã¢ãã³ããã©ã³ã¹âïŒïŒïŒâã·ã¯ã
ãããµã³ãžã¢ãã³ãïŒâã¡ãã«âãã©ã³ã¹âïŒïŒ
ïŒâã·ã¯ããããµã³ãžã¢ãã³ããã¹ïŒãã©ã³ã¹â
ïŒâã¢ããã·ã¯ãããã·ã«ïŒã¡ã¿ã³ãããã©ãžã³
çãå«ãŸããããžã¢ãã³ã¯åå¿äžã«äžåå€ãäŸã
ã°çé žãªããŠã ãçšããããšã«ããå¡©ã®åœ¢ïŒäŸã
ã°äºå¡©é žå¡©ïŒã§çšããããšãã§ããã æ¬çºæã®éåäœãã€ããã®ã«æçšãªãžã¢ã«ãã
ãåã³ãžã±ãã³ã¯åŒãåŒãã«å¯Ÿå¿ã ããè²ã§R2ïŒZ1ïŒZ2ã¯åè¿°ã®å®çŸ©ã®éãã§ããã
ãããã®ãã®ã®äžã«ã¯ïŒïŒïŒâãžã¢ã»ãã«ãã³ãŒ
ã³ãïŒïŒ4â²âãžã¢ã»ãã«ãããšãã«ããã¬ãã¿ã«
ã¢ã«ããããã¯ãããã¬ãã¿ã«ã¢ã«ããããã¡ã
ã«ãã¬ãã¿ã«ã¢ã«ããããïŒïŒïŒâãžããªã«ãã«
ããªãžã³ãïŒïŒ4â²âãžããªã«ãã«ãããšãã«ã
ïŒïŒïŒâãžããªã«ãã«ããã¿ã¬ã³ãïŒïŒïŒâãžã
ãªã«ãã«ããã¿ãªã³ãïŒïŒïŒâãžããªã«ãã«ãã
ã¿ãªã³ããã¹ïŒïŒâããªã«ãã«ããšãã«ïŒã¡ã¿
ã³ããã¹ïŒïŒâããªã«ãã«ããšãã«ïŒãšã¿ã³ãã
ã¹ïŒïŒâããªã«ãã«ããšãã«ïŒãšãŒãã«ãïŒïŒïŒ
âãã¹ïŒïŒâããªã«ãã«ããšããã·ïŒãšã¿ã³ã
ïŒïŒïŒâãžã¯ãããã¬ãã¿ã«ã¢ã«ããããïŒïŒïŒ
âãžããã¢ãã¬ãã¿ã«ã¢ã«ããããïŒïŒïŒâãžã¡
ããã·ãã¬ãã¿ã«ã¢ã«ããããïŒâããã¢ãã¬ã
ã¿ã«ã¢ã«ããããïŒâã¡ããã·ãã¬ãã¿ã«ã¢ã«ã
ãããïŒâããããã·ãã¬ãã¿ã«ã¢ã«ãããçã
å«ãŸããã æ¬çºæã®éåäœãã€ããã®ã«æçšãªã¢ããã¢ã«
ãããåã³ã¢ããã±ãã³ã¯åŒãåŒã㫠察å¿ãããè²ã«Z3åã³R3ã¯åè¿°ã®æå³ãæããã
ãããã®äžã«ã¯ïŒâã¢ããâïŒâã¯ãããã³ãºã¢
ã«ããããïŒâã¢ããâïŒâãã«ãªããã³ãºã¢ã«
ããããïŒâã¢ããâïŒâã¡ãã«ãã³ãºã¢ã«ãã
ããïŒâã¢ããâïŒâã¯ããã¢ã»ãããšãã³ãïŒ
âã¢ããâïŒâãã«ãªãã¢ã»ãããšãã³ãåã³ïŒ
âã¢ããâïŒâã¡ãã«ã¢ã»ãããšãã³çãå«ãŸã
ãã ãããã®åæã®çµåããããã¹ãŠç°æ¹æ§æº¶èç©
ãçããããã§ã¯ãªããèç¹ã375â以äžã®éå
äœãçãããããªåæã®çµåããã¯é¿ããªããã°
ãªããªãããšããã®ã¯é«èç¹çæç©ã¯å å·¥ïŒäŸã
ã°çŽ¡ç³žããŠæçšãªç¹ç¶ã«ããïŒãå°é£ã ããã§ã
ãã çµåãã®åæããã€ããããéåäœã¯ç¬éçã«
è»åããåŸéåããŠé溶èæ§ã®åºäœã«ãªããå åŠ
çç°æ¹æ§ã芳枬ãããããšããªãããã«æãã
ãããã®ãããªéåäœã¯æ¬çºæã®ç¯å²å€ã§ããã
溶è玡糞ã§ããªãã®ã§çšéãéå®ããããããã
ãã®ãããªéåäœãã€ããéçšã«ãããŠæ«ç«¯å°é
å€åã¯é£éåæ¢å€ãçšãããšãåŸãããçæç©ã¯
溶èç©ã§å åŠçç°æ¹æ§ã瀺ãæ«ç«¯ãå°éãããé
åäœã§ãããæ¬çºæã«ã¯éåäžæ«ç«¯å°éå€ãå ã
ãŠéåäœã®æ«ç«¯ãå°éãããŠãããåŠãã«æã
ããå åŠçç°æ¹æ§æº¶èç©ãçããããªã¢ãŸã¡ãã³
ïŒå ±ïŒéåäœã®ã¿ãå«ããã®ãšããã æ¬çºæã®ïŒå ±ïŒéåäœã¯ç¹ç¶çææ§ã瀺ãã®ã«
ååãªååéãæããŠãããïŒå ±ïŒéåäœã®ãã
ãã®ã¯åºæç²åºŠã枬å®ããã®ã«çšãããã溶åªäž
ã«äžæº¶ã§ããããšãã§ããããããã®ïŒå ±ïŒéå
äœãåã³åŸè¿°ã®æ¹æ³ã«ãã枬å®ãããåºæç²åºŠã
å°ããšã0.2ã奜ãŸããã¯å°ããšã1.0ã®ãã®ãã
è¯å¥œãªç¹ç¶åã³ãã€ã«ã ãåŸãããã éåäœã®èç¹ã¯æçšåºŠåºæç²åºŠã«äŸåãããå³
ã¡åºæç²åºŠã®äœãéåäœã¯é«ããã®ããäœã枩床
ã§æº¶èããã éåæ¡ä»¶ ããªã¢ãŸã¡ãã³åã³ãã®å ±éåäœã¯é©åœãªåé
äœãããç±éåã奜ãŸããã¯äžæŽ»æ§é°å²æ°äžã§ç¡
æ°Žæ¡ä»¶äžã§éåãããããšã«ããã€ããããšãã§
ãããäŸãã°åæã®ãžã¢ãã³ãšãžã¢ã«ãããïŒå
ã¯ãã®èªå°äœãäŸãã°ãžã¢ã»ã¿ãŒã«ïŒã®åéãå
å¿å®¹åšäžã§äžç·ã«ããã容åšã®å 容ç©ãæ¹æå ç±
ãããã®éå 容ç©ãçªçŽ äžã«ä¿ã€ãåå¿åæãé
åããã«ã€ããŠãå¯æç©ïŒäŸãã°æ°Žåã¯ã¢ã«ã³ãŒ
ã«ïŒãé€å»ãããéåãææã®ç¹ãŸã§é²è¡ãã
ãšãéåäœãååºããŠç²Ÿè£œããã溶èããå Žåã
éæéåäœãçŽæ¥é©åœãªå®¹åšãäŸãã°ç¹ç¶çŽ¡ç³žè£
眮ã«ç§»ããæ圢åãã€ããã å¯æç©ãšå ±æ²žæ··åç©ãã€ãããå¯æç©ãé€å»ã
ãã®ã«åœ¹ç«ã€æº¶åªïŒäŸãã°ãã³ãŒã³ïŒäžã«åå¿å
æã溶ãããéåå®äºåŸãæ²æŸ±ããçæç©ãå¥
ãã溶解ããçæç©ãåé¢ããæ®ãã®æº¶åªãèžçº
ãããã æ¬çºæã®ïŒå ±ïŒéåäœã¯ãŸã極æ§æº¶åªãçšãã
äœæž©éåæ³ã«ããã€ããããšãã§ãããäžã€ã®äŸ¿
å©ãªæ¹æ³ã§ã¯ãžã¢ãã³ãäŸãã°ïŒ®ïŒïŒ®âãžã¡ãã«
ã¢ã»ãã¢ããïŒDMAcïŒãâã¡ãã«ãããªãã³
âïŒïŒNMPïŒããããµã¡ãã«ããªã¹ããªã«ã¢ãã
ïŒHMPAïŒåã¯ãã®æ··åç©ããæã矀ããéžã°ã
ã極æ§ã¢ãã³æº¶åªäžã«å¡©åãªããŠã ãå«ãŸããŠæº¶
解ããããžã¢ã«ããããå ããåå¿æ··åç©ãæ¹æ
ãããæ°æéãªããæ°æ¥éåå¿ãé²è¡ãããã次
ã«åå¿æ··åç©ãé溶åªïŒäŸãã°æ°ŽïŒãšäžç·ã«ãã
æéããååã«æŽæµãïŒäŸãã°æ°ŽããšãŒãã«ãã¡
ã¿ããŒã«ã§ïŒã也ç¥ããåŸå å·¥ããã 次ã®å å·¥ã容æã«ããããã«ããããã®éåäž
æ«ç«¯å°éå€ãåã¯é£éåæ¢å€ãçšããããšãæå©
ã§ãããã¢ããªã³ãïŒâã«ã«ããã·ãã³ãºã¢ã«ã
ãããïŒâã¢ããã¢ã»ãã¢ããªããïŒâã¢ããâ
ïŒâã¡ãã«å®æ¯éŠé žããã³ãºã¢ã«ããããåã³å¡©
åãã³ãŸã€ã«ããããã®åæ¢å€ã«å«ãŸãããå¡©å
ãã³ãŸã€ã«ãçšãããšæºè¶³ãã¹ãçµæãåŸããã
ããäžè¬ã«é±é žãçããè©Šè¬ã¯éåäœãå£åãã
ãããã«äžè¬ã«ã¯é¿ããã¹ãã§ããããããã®å
æ¢å€ã¯æº¶è玡糞äžã«ãããŠéåäœã®ååéã®å¢å
ãæå¶ãããæå°éã«ããã®ã«åœ¹ã«ç«ã€ãäŸãã°
玡糞äžããã«éåãèµ·ãååéãé«ããªãããã
å Žåã«ã¯ã玡糞æäœã«ããäœå質ã®ç¹ç¶ãçãã
ããåã¯äžæããããç¹ç¶ã®åœ¢ã§ç±åŠçãè¡ãªã
å ŽåãæçšåºŠé£éãçé·ããããšãæãŸããã
ãããã以äžã®éåãå®å šã«çŠæ¢ããé£éåæ¢ã¯
é¿ããªããã°ãªããªãã å¿ èŠã«å¿ãä»ã®è©Šè¬ãçšããããšãªãæ«ç«¯ã®å°
éãè¡ãªãããšãã§ãããäŸãã°åå¿åæã®ïŒçš®
ãéå°ã«ïŒååŠéè«çãªé以äžã«ïŒçšãããŸãé
å°ã®åå¿åæãè¿ éã«æ倱ããã®ãé²ãä»ã®æ©æ§
åã¯ééç³»ãçšããã°ãããã¯æ«ç«¯å°éå€ãšããŠ
äœçšããããã®æ¹æ³ã¯ä»ã®éåäœã«ã€ããŠã¯ãªã©
ã³ããã¢ã ã¹ãã«ãã ããšã«ã»ãŽã€ã€
ïŒElsevierïŒåºç瀟1953幎çºè¡ã¢ãŒã«ã»ãã«ïŒR.
HillïŒèãåæéåäœç¹ç¶ïŒFibers from
SyntheticPolymersïŒã106ã107é èšèŒã®ããã«
å ¬ç¥ã§ãããç±çã«å®å®ãªé žåé²æ¢å€ãåå¿æ··å
ç©ã«å ãããšãåŸã®å å·¥ã«æçšãªåœ¹ç®ãæãã ç°æ¹æ§æº¶èç© æ¬çºæã®ããªã¢ãŸã¡ãã³åã³ãã®å ±éåäœã®æº¶
èç¶æ ã«ãããå åŠçç°æ¹æ§ã®ããã«ããããã®
溶èç©ããã€ããããç¹ç¶ã¯é åã匷床åã³åæ
ã¢ãžãŠã©ã¹ãé«ããªãããããã®ç¹ç¶ã®ãããã®
ã§ã¯å®è³ªçã«åŒç·©ããç¶æ åã¯ç·åŒµããç¶æ ã«ã
ããŠç±åŠçã«ãã匷床ãå¢å ãããã ããªã¢ãŸã¡ãã³ïŒå ±ïŒéåäœæº¶èç©ã®å åŠçç°
æ¹æ§ã¯å ¬ç¥æ¹æ³ãå ãã«å€åœ¢ããæ¹æ³ã§æ±ºå®ãã
ããåéæã®å åŠçã«ç°æ¹æ§ããã€ææã¯äº€åå
ååãåä»ããå åŠç³»ã§ã¯å ãééããããçæ¹
æ§ã®ææã«å¯ŸããŠã¯å ã®ééã¯çè«çã«ïŒã§ãã
ããšãç¥ãããŠããããäŸãã°ãšã¹ã»ãšãŒã»ãžã€
ããªã³ïŒS.A.JabarinïŒåã³ã¢ãŒã«ã»ãšã¹ã»ã¹ã
ã€ã³ïŒR.S.SteinïŒã®ãžã€ãŒãã«ã»ãªãŽã»ãã€ãž
ã«ã«ã»ã±ãã¹ããªãŒïŒJ.Phys.Chem.ïŒ77ïŒ399
ïŒ1973ïŒåç §ããæ¬çºæã®ç°æ¹æ§æº¶èç©ã¯åè ã®æ
åã瀺ããäžèšã«ç€ºãç±å åŠçè©ŠéšïŒTOTïŒã«
ãããã®ç¹åŸŽãçšããŠæº¶èç©ãåå®ãããè£ çœ®
ã¯ãã¢ã€ã»ã«ãŒã·ãšã³ããŠã ïŒI.KirshenbaumïŒã
ã¢ãŒã«ã»ããŒã»ã€ãµã¯ãœã³ïŒR.B.IsaacsonïŒãå
ã³ããŽãªãŠãŒã»ã·ãŒã»ããšã€ã¹ãïŒW.C.FeistïŒ
ã®ããªããŒã»ã¬ã¿ãŒãºïŒPolymer LettersïŒèª
ïŒïŒ897ã901ïŒ1964ïŒèšèŒã®è£ 眮ãšåæ§ã§ããã æ圢åã®è£œé æ¬çºæã®ããªã¢ãŸã¡ãã³ïŒå ±ïŒéåäœã¯æ圢
åãäŸãã°ç¹ç¶ããã€ã«ã ãæ£ãåã¯ä»ã®æ圢å
ã¯ãäŸãã°ãã®ç°æ¹æ§æº¶èç©ããã¬ã¹ã玡糞ã泚
圢ãåã¯æŒåºãããšã«ããã€ããããšãã§ããã
åœæ¥çã®å°é家ã¯æ圢åã®ææã®æ§è³ªãåŸããã
ã®åçš®ã®ç°æ¹æ§æº¶èç©ã®ç¯å²å ã«ãããæé©å å·¥
枩床ã容æã«æ±ºå®ããããšãã§ãããç±å解åã¯
çæ¹æ§æº¶èç©ã®çæïŒå³ã¡é床ã®é«æž©ã«å ç±ãã
ããšã«ããïŒãçããããã«æ³šæããªããã°ãªã
ãªãã æ¬çºæã®é«åºŠã«é åãã匷ãç¹ç¶ã¯åè¿°ã®ããª
ã¢ãŸã¡ãã³ïŒå ±ïŒéåäœããã€ãããããç¹ç¶ã
ã€ããããã«ã¯ãïŒå ±ïŒéåäœçææåã®æº¶èé
åã«ããçŽæ¥åŸãããããåã¯ïŒå ±ïŒéåäœã®æ£
åã¯ãããã¯ã溶èããŠåŸããã溶èéåäœã®å¡
ããäŸãã°æº¶èçŽ¡ç³žè£ çœ®ãéããŠçŽ¡ç³žå£éããæ¥
å·é°å²æ°ïŒäŸãã°å®€æž©ã«ä¿ããã空æ°ïŒäžã«æŒåº
ããæ²åãããšã«ããå å·¥ãããæ¬æ现æžã«ãã
ãŠã玡糞ãããŸãã®ç¹ç¶ããšã¯æŒåºããŠéåžžã®æ²
åããããåŸã«å»¶äŒžã䌞匵åã¯çŒçŽãããªãç¹ç¶
ãæå³ãããäºå®ç°æ¹æ§æº¶èç©ã®ã玡糞ãããŸã
ã®ç¹ç¶ãã¯éåžžã®æå³ã«ãããŠãå³ã¡100ïŒ åã¯
ãã以äžå»¶äŒžããããšã¯ã§ããªãã ç¹ç¶ã¯åäžåã¯å€å玡糞å£éããã€ããããšã
䟿å©ã§ããã溶è玡糞ã»ã«ã«ãããŠã¯æº¶èåºåå
ã³çŽ¡ç³žå£éã§ä¿æãããã¹ã枩床ã¯å¿è«çŽ¡ç³žãã¹
ãéåäœã«äŸåãããç±ã¯çŽ¡ç³žå£éåã³ãã®çäž
ã®çã溶èåºåã«ãããããšã奜ãŸãããããã«
ãã€ãŠåºæç²åºŠãäœãä¿ã¡çŽ¡ç³žã容æã«ããããš
ãã§ãããéã¹ã¯ãªãŒã³ãšãã€ã¹ã¯ã玡糞å£é
ããã¯ã«çšããããšãã§ããã玡糞å£éãé¢ãã
ç¹ç¶ã®æ¥å·çšåªè³ªãšããŠã¯ç©ºæ°åã¯çªçŽ ãçšãã
ããšãã§ããã玡糞ãããŸãã®ç¹ç¶ã¯çš®ã ã®é床
ïŒWUSïŒãäŸãã°90ïœïŒå以äžãªãã1200ïœïŒå
以äžã®é床ã§æ²åãããšãã§ããã玡糞䌞匵å å
ã¯çŽ¡ç³žå£éã®åã®å€§ãããæŒåºé床ãåã³æ²åé
床ã«ããå€åããäžè¬ã«ã¯ïŒä»¥äžã§ãããå¿ èŠã«
å¿ã玡糞ãããŸãã®ç¹ç¶ã«ä»äžå€ãã€ããããšã
ã§ããã ãã€ã«ã ã¯éåžžã®æº¶èãã¬ã¹æ³ã«ããã€ããã
ãšãã§ããæ圢åã¯æŒåºè£œåãäŸãã°æ£ã¯éåžžã®
æ¹æ³ã§ã€ããããšãã§ããã ç¹ç¶ããã€ã«ã ãæ£ããã®æ§è³ªãç±åŠçåã³çšé æ¬çºæã®çŽ¡ç³žãããŸãã®ç¹ç¶ã¯é«åºŠã«é åããŠ
ãããããã¯äŸãã°ïŒžç·é åè§ãçŽ45ã以äžã§ã
ãããšã«ãã€ãŠç€ºããããããã«åŒåŒµç¹æ§åã³ä»
ã®æ§è³ªãæãŸããæ§è³ªãæããŠãããäŸãã°å€ã
ã®çŽ¡ç³žãããŸãã®ç¹ç¶ã¯åŒ·åºŠãå°ããšãçŽ40gpd
ã§åæã¢ãžãŠã©ã¹ã¯400gpd以äžïŒå±¡ã 500gpd以
äžïŒã§ããã æ¬çºæã®ç¹ç¶ã¯ç¹ç¶åŒ·åãã©ã¹ããã¯åã³ä»ã®
å·¥æ¥ççšéã«çšããããã ãã®ãããªçšéã®ãããã®ã«ãããŠã¯ãç¹ç¶ã¯
å¡©åºæ§åªè³ªåã¯é«æž©ã«é²åºããããäŸãã°åŒ·åæš¹
èã¯å±¡ã å¡©åºæ§è§ŠåªãçšããŠç¡¬åããããŽã é å
æåã¯äžè¬ã«ææ©ã¢ãã³ãå«ã¿ã硬åã¯ããªãã®
æéé«æž©ã§è¡ãªãããããšãå€ããæ¬çºæã®ç¹ç¶
ã¯äžè¬ã«äžè¿°ã®æ¡ä»¶ã«æµææ§ããããã¢ã«ããªãª
ã³ãæ°Žé žåãããªãŠã ããŽã åã¯å ç±ã«ããèå
ãããåŸç¹ç¶ã¯è¯å¥œãªåŒ·åºŠã®ä¿ææ§ã瀺ãã æ¬çºæã®çŽ¡ç³žãããŸãã®ç¹ç¶ã¯å ç±åŠçæäœã«
ä»ããŠäŸãã°ãã€ã€ã®è£åŒ·ã«æçšãªéåžžã«é«ãåŒ
匵ç¹æ§ããã€æ¬çºæã®ç±åŠçç¹ç¶ãã€ããããšã
ã§ãããé©ãã¹ãããšã«ã¯ãå®è³ªçã«åŒç·©ããç¶
æ ã§ãäŸãã°ã¹ã±ã€ã³ã§ãåã¯è»ãã被èŠããã
ããã€ããŒã»ãã©ãã¯ã¹ïŒFibcrâFraxïŒããã
ã³ã«å·»ããŠãæãã¯ç·åŒµããç¶æ ã§ãäŸãã°ãã
ãããã³äžã§çŽ100â以äžãç¹ç¶ã®èç¹ä»¥äžïŒå¥œ
ãŸããã¯èç¹ãã20âäœã枩床以å ã§ïŒç¹ç¶ãç±
åŠçãããšãéåžžååéã®ç®å®ãšãªãåºæç²åºŠã®
å¢å ãçãããç±åŠçã«ããåºæç²åºŠãå¢å ãã
ç¹ç¶ã¯åŒ·åºŠãå¢å ããããšãèŠåºããããç±åŠç
ã®æž©åºŠåã³æéã¯åºæç²åºŠãå¢å ããããã«éžã°
ãããå ç±æž©åºŠã¯ãã€ã©ã¡ã³ãéã®èåãå®è³ªç
ã«èµ·ã枩床以äžã«ä¿ã€ããšã奜ãŸãããå®çšçãª
ç®çã®ããã«ã¯ã匷床ãå¢å ãããã®ã«ååãªã§
ããã§ãçãæéã®éå ç±ãè¡ãªããéåäœã«ã
ã€ãŠæäœïŒç§éãªããäžè¬çã«ã¯å°ãªããšã1/2
ã24æéåã¯ãã以äžã®å ç±æéãçšãããéåžž
ïŒæé以äžå ç±ããŠããã以äžã®æ¹åã¯åŸãããª
ããå ç±åŠçã¯ç¹ç¶ã«æªåœ±é¿ãåãŒããªãäžæŽ»æ§
é°å²æ°äžã«ãããŠè¡ãªããªããã°ãªããªããçªçŽ
ã¯ãã®ç®çã«å šãé©ããŠããã匷床ãå°ããšã
10gpdã®ç¹ç¶ã奜ãŸãããæ¬çºæã®å€ãã®çŽ¡ç³žã
ããŸãã®ç¹ç¶ãç±åŠçãããšãã®æ°Žæºã®åŒ·åºŠãåŸ
ããããå ç±åŠçããç¹ç¶ã§ã¯ïŒžç·é åè§ã§æž¬å®
ãããé åã®å¢å ãèªãããããæ¬çºæã®å¥œé©ãª
å ç±åŠçããç¹ç¶ã¯ã¢ãžãŠã©ã¹ãå°ããšã
150gpdã䌞ã³ãïŒïŒ 以äžãé åè§ã¯45ã以äžã§ã
ããèç¹ã¯175â以äžã奜ãŸããã¯250â以äžã§ã
ãã 枬å®æ³åã³è©Šéšæ³ ç·é åè§ïŒæ¬æ现æžã§å ±åãããç·é åè§
ïŒO.A.ïŒã¯ã¯ãªãŒã¬ãã¯ïŒKwolekïŒã®ç±³åœç¹èš±
第3671542å·æ¹æ³ïŒã®æ¹æ³ã«ããåŸãããã åºæç²åºŠïŒ åºæç²åºŠïŒÎ·inhïŒã¯åŒ ηinhïŒïŒÎ·relïŒïŒ£ïŒ ã§å®çŸ©ããããηrelã¯çžå¯Ÿç²åºŠã§ãããã¯æº¶åª
100mlã«éåäœ0.5ïœãå«ãæ¿åºŠã§ãããçžå¯Ÿç²åºŠ
ηrelã¯éåäœåžè溶液ã®æ¯çŽ°ç®¡ç²åºŠèšäžã«ããã
æµäžæéãçŽæº¶åªã®æµäžæéã§å²ãããšã«ãã€ãŠ
åŸããããç¹èšããªãéãηrelã決å®ããããã«
çšããããåžè溶液ã¯äžèš(C)ã«ãã€ãŠè¡šãããã
æ¿åºŠã®æº¶æ¶²ã§ãããæµäžæéã¯30âã§æ±ºå®ãã
ãã溶åªã¯æ¿ç¡«é žïŒ98ïŒ H2SO4ïŒã§ãããä»ã®
溶åªïŒäŸãã°ã¡ã¿ã³ã¹ã«ããªã³é žïŒãç¡«é žäžã§å£
åãèµ·ãå Žåã«ã¯çšããããšãã§ããã éåäœè©ŠæïŒåã¯ç¹ç¶ïŒã98ïŒ ç¡«é žåã³å容é
ã®ïŒmmãããã³ã®ç«æ¹ç²ãéããç¶ã®äžã§äžç·
ã«ãã溶液ãçããæäœæéãéåžžã¯10ã25åé
æ¯çªæ©äžã«èŒããããã€ãã³âããšã³ã¹ã±
ïŒCannonâFenskeïŒç²åºŠèšãé転æ³ã«ããå å¡«
ãããžã¯ãã é žã«ãªãŠã ã®é£œå氎溶液ããæãæ
枩槜äžã«å ¥ãããäžåé£ç¶ããŠæµäžæéãçŽã¡ã«
枬å®ãããæ¯çªæäœã¯ææã§è¡ãªãããã¹ãŠã®ç§»
éå·¥çšã¯èæãå ã®äžã§è¿ éã«è¡ãªãã次ã®æž¬å®
ã«ãããŠæº¶æ¶²ã®æµäžæéãæžå°ããå Žåã«ã¯ã
ηinhã®èšç®ã«ã¯æé·æéãçšããã ç¹ç¶ã®åŒåŒµç¹æ§ïŒãã€ã©ã¡ã³ãåã³ç³žã®ç¹æ§ã¯
ã¢ãŒã¬ã³ïŒMorganïŒã®ç±³åœç¹èš±ç¬¬3827998å·èš
èŒã®æ¹æ³ã«ãã枬å®ããããå°ãªããšãïŒåã®ç Ž
æ匷床ãå¹³åããã åãè©Šæã®åäžãã€ã©ã¡ã³ãã®æ§è³ªãšå€ãã€ã©
ã¡ã³ãã»ã¹ãã©ã³ãïŒç³žïŒã®æ§è³ªãšã§ã¯ç°ã€ãçµ
æãåŸããããç¹èšããªãéããã¹ãŠã®æ§è³ªã¯ã
ã€ã©ã¡ã³ãã®æ§è³ªã§ããã å åŠçç°æ¹æ§ïŒå åŠçç°æ¹æ§ã¯äžèšTOTæ³ã«
ãã€ãŠæž¬å®ããã TOT枬å®è£ 眮ãšæµå枩床枬å®è£ 眮 ç±å åŠçè©ŠéšïŒTOTïŒã«ã¯åå é¡åŸ®é¡ãå¿ èŠ
ã§ãããããã¯æ±ãã®ãªãå åŠç³»ãšäžèšã«è¿°ã¹ã
ããã¯ã°ã©ãŠã³ãééçã枬å®ããããšãã§ãã
亀åïŒ90ãïŒåå åãæããååã«é«åºŠãªåžå ä¿
æ°ããã€ãŠãããããã§å ±åãã枬å®æ³ã«ã¯ã©ã€
ãïŒLeitzïŒç€Ÿã®ãã€ã¢ã«ãã¯ã¹ã»ããŒã«
ïŒDialuxâPolïŒé¡åŸ®é¡ã䜿çšãããããã«ãã©
ãã€ãåå åãäž¡çŒçšæ¥çŒã¬ã³ãºãåã³å ç±å°ã
åä»ãããå æ€åºåïŒããã¡ãŒã¿ãŒã®ã»ã³ãµãŒïŒ
ãé¡åŸ®é¡ã®çã®é éšã«åä»ãããé¡åŸ®é¡ã¯32åã®
åçã®äœåè·é¢ã®é·ã察ç©ã¬ã³ãºãæããèµ€è²
ïŒç¬¬äžçŽèµ€è²ïŒã®æ¿ãæããŠãããïŒåŸè ã¯äº€åå
å åãçšãçŒã§èŠ³æž¬ããæã«ã®ã¿çšããååå å
ãš45ãã®è§åºŠããªããŠããïŒãå ¥å°å æºããã®çœè²
å ãåå åãéããå ç±å°äžã®è©Šæãéãã次ã«
åæåšãéããŠå æ€åºåãåã¯æ¥çŒã¬ã³ãºãžåã
ããã¹ã©ã€ãã«ããåãæ¥çŒã¬ã³ãºããå æ€åºåš
ãžãšç§»åãããã䜿çšããå ç±å°ã¯500âã«å ç±
ããããšãã§ãããããŠãããã³ïŒUnitronïŒã
MHSåç空å ç±å°ãç±³åœããµããŠãŒã»ããå·ã
ãŠãŒãã³ã»ãã€ã©ã³ãºïŒNewton HighlandsïŒã
ããŒããã ïŒNeedhamïŒã¹ããªãŒãã66ïŒ02161ïŒ
ã®ãŠãããã³ã»ã€ã¹ããªãŠã¡ã³ãïŒUnitron
InstrumentïŒç€Ÿè£œããçšãããå æ€åºåšããã®
ä¿¡å·ãããªãã¡ãŒã¿ã®å¢å¹ åšã«ããå¢å¹ ããâ
ãªã³ãŒããŒã®ïŒ¹è»žãžäŸçµŠãããå ã®åŒ·åºŠã«å¯Ÿã
ãç³»ã®å¿çã¯çŽç·ç¶ã§ãããèšé²çŽäžã«ããã枬
å®ã®ç²ŸåºŠã¯Â±ïŒmm以å ã§ãã€ããå ç±å°ã«ã¯ïŒå
ã®åä»ããç±é»å¯ŸãåããããŠããããã®ïŒåã¯
âãªã³ãŒããŒã®ïŒžè»žã«é£çµãããŠããå ç±å°
ã®æž©åºŠãèšé²ããä»ã®äžã€ã¯ããã°ã©ã ãããæž©
床ã³ã³ãããŒã©ãŒãžãšé£çµãããŠãããäžèšã®ã
ãã«ããŠã€ããåä»ããéåäœè©Šæã«çŒã§é¡åŸ®é¡
ã®çŠç¹ãåãããïŒäº€ååå åã䜿çšïŒãå è·¯ã
ãã®è©Šæã¯ååºãããã«ããŒã»ã¹ãªããã¯ãã®
ãŸãã«ããŠãããé¡åŸ®é¡ã®ãã©ãã€ãåæèšãå
è·¯ããååºããã¹ã©ã€ããŒã移åãããŠåãå æ€
åºåãžãšç§»åãããç³»ã調ç¯ããâãªã³ãŒã
ãŒã®ïŒ¹è»žã®å šå¹ ã®æ¯ãïŒèšé²çŽäžã§18cmïŒãããª
ãã¡ãŒã¿ã®ä¿¡å·ã®36ïŒ ã«å¯Ÿå¿ããããã«ãããã
ãã¯(1)ãªã³ãŒããŒã®ïŒ¹è»žã®èªã¿ãïŒcmã«å¯Ÿå¿ãã
ããã«äºãéžã°ããå€ã«å æºã®åŒ·åºŠã調ç¯ãã(2)
ããªãã¡ãŒã¿ã®å¢å¹ çã10åã«å¢å ãããããšã«
ãã€ãŠè¡ãªãããããã®çµæãªã³ãŒããŒã®18cmã®
å šå¹ ã®æ¯ããããªãã¡ãŒã¿ã®ä¿¡å·ã®ïŒ18/50ïŒÃ
100ããªãã¡36ïŒ ã«å¯Ÿå¿ããããã«ãªããããã¯
ã°ã©ãŠã³ãã®ééå€ã¯äº€åïŒ90ãïŒåå åãšã«ã
ãŒã»ã¹ãªãããšãè©Šæã眮ããªãå è·¯äžã«å ¥ããŠ
èšé²ãããã䜿çšããç³»ã®ããã¯ã°ã©ãŠã³ãéé
çã¯æž©åºŠã«äŸåãããèšé²çŽã®çŽ0.5cm以äžã§ãª
ããã°ãªããªãã TOTè©Šéšåã³æµå枩床ã®æž¬å®ã«å¯Ÿã倫ã ïŒå
ã®è©Šæã次ã®ããã«ããŠã€ãããçŽç²ãªéåäœã®
äºäžç²ãã«ããŒã»ã¹ãªããã®éã«å ¥ãã亀å
ïŒ90ãïŒåå åã®éã§å ç±å°äžã«ãããŠãçŽ50âïŒ
åã®ããã°ã©ã ãããé床ã§å ç±ããªããçŒã§èŠ³
å¯ãããç²åã®çžãäžžããªãè©Šæ枩床ïŒïŒŽïŒãæµ
åã®ç®å®ã§ããããããèšé²ããã倫ã ã«ããŒã»
ã¹ãªããã«æ¿ãã éåäœç²åããæãè€è£œè©Šæã
ïŒåã®é¡åŸ®é¡ã®ã¹ã©ã€ãã«æ¿ãããã®ã¢ã»ã³ããª
ãŒããå ç±æ¿ã®äžéšã®äžã«ããéŒæ¿ã®äžã«æ¿å ¥ã
ãç±é»å¯Ÿã«ãã枬å®ããã枩床ãïŒïŒŽïŒ10âïŒã«
ãªãããã«äºç±ãããå ç±æ¿äžã«çœ®ãããã®ã¢ã»
ã³ããªãŒãããã«é«æž©ã«å ç±ãããã«ã€ããŠãæš
æã®æŒæ£ã§åè©Šæã«å§åã亀äºã«ãããç²åãè
åããŠæµåããïŒåã®èã液äœãã€ã«ã ãã§ãã
ãŸã§ç¶ãããçŽã¡ã«ã¢ã»ã³ããªãååºããå·åŽ
ããåºäœã®ãã€ã«ã ïŒã«ããŒã»ã¹ãªããã®éã«ä¿
æããããŸãïŒãã¢ã»ã³ããªãŒããåé¢ãããã
ã®éçšã§éåäœè©Šæã¯å®¹æã«ããã«éåããã
ãããã®éçšã«ããè©Šæã®èª¿è£œäžå ç±æéãšæž©åºŠ
ãšãæå°éã«ããããšãéèŠã§ããã éåäœè©Šæãã€ã«ã ã®åãã¯ïŒã6ÎŒmã§ããã
ãšã奜ãŸãããåããããèãããããããã€ã«
ã ã¯ãã®è©Šéšã§ç°æ¹æ§ã瀺ããªãããšããããã
ããããè©Šæãç°æ¹æ§ã瀺ããªããïŒã6ÎŒmã®è©Š
æã«ã€ããŠè©Šéšãç¹°è¿ãå¿ èŠã¯ãªããè©Šæã®åã
ã¯å¹²æžèšã«ãã€ãŠæž¬å®ã§ããããããè¡ãã«ã¯å±
æçæ¢ç¥ã®æ²¹ãè©Šæãåå²ãã«ããŒã»ã¹ãªããã®
éã«æ³šå ¥ããTOTæ³ã§èŠ³æž¬ãã¹ãè©Šæéšåã«è¿
æ¥ããåºåã®ç©ºæ°ãšã®å¢çé¢ã§æ²¹å±€ã®åãã枬å®
ããéæ¥çãªæ¹æ³ã䟿å©ã§ãããåãã枬å®ãã
ããæ²¹ã¯ãã¬ãªã³TFã®åŒåççŽ äžã«çæé浞
挬ãããããè¶ é³æ³¢ã§æ¯çªããããšã«ãã容æã«
é€å»ããããšãã§ããã ã«ããŒã»ã¹ãªããã«æ¿ãã ãã€ã«ã ã®äžã€ã¯
TOTæ³ã«äœ¿çšããä»ã®äžã€ã¯æµå枩床ã®æ±ºå®ã«
䜿çšãããæµå枩床ã¯è©ŠæãTOTè£ çœ®äžã§çŽ50
âïŒåã®ããã°ã©ã ãããé床ã§å ç±ããæã«ã
ã€ã«ã ã®åã®çé«ç·ãå€åãã枩床ã§ããã ãããã®ïŒå ±ïŒéåäœåã¯ç¹ç¶ã®æµå枩床ã¯ã
ã®å±¥æŽã«ãã€ãŠå€åããããšã«æ³šæãã¹ãã§ã
ããäŸãã°é段ç¶ã®å ç±ããããšéåžžæµå枩床ã¯
äžæãããããã«ãã€ãŠæåã®æµå枩床以äžã§ã¯
ãããæ°ããå°éããæµå枩床ããäœã枩床ã§å
ç±ããããšãã§ãããå ±åãããæµå枩床ã¯ãã®
æ¹æ³ã«ãã€ãŠæž¬å®ããããã®ã§ããã TOTæ³ã®è©Šæãå ç±å°ã®äžã«èŒããå æ€åºåš
ãšäº€åããå®è³ªçã«å šéšã®å ãè©Šæãéãããã«
äœçœ®ããããè©Šæã亀åïŒ90ãïŒåå åã®éã«å ¥
ããçªçŽ äžã«ãããŠçŽ50ãïŒåã®ããã°ã©ã ãã
ãé床ã§è©Šæã25âãã465âãŸã§äžæããã€ã€ã
å ã®åŒ·ããšæž©åºŠãšãâãªã³ãŒããŒã«èšé²ã
ããé©åœãªæ€åºŠæ²ç·ãçšãèšé²ããã枩床ããè©Š
æã®æž©åºŠãåŸãã 溶èç©ãçæããïŒå ±ïŒéåäœã¯ãè©Šæã亀å
ïŒ90ãïŒåå åã®éã§ãã®æµå枩床以äžã®æž©åºŠã«å
ç±ããæãããåŸãããç°æ¹æ§æº¶èç©ãéãå ã
èšé²çŽäžã«ãããŠããã¯ã°ã©ãŠã³ãã®ééå ã®æ²
ç·ã®é«ãã®å°ããšãïŒåã§ãããããå°ããšã
0.5cmé«ãé«ãããã€æ²ç·ãäžãããªãã°ãTOT
æ³ã«ãããŠç°æ¹æ§æº¶èç©ãçæãããšèããã
ãããã®ãããªæº¶èç©ãçãããšãå ã®ééæ²ç·
ã¯(1)ãã®å€ïŒé«ãïŒãããã¯ã°ã©ãŠã³ãã®ééæ²
ç·ã®å°ããšãïŒåã«ãªããäžã€ãããããå°ããš
ãçŽ0.5cm倧ã«ãªãããåã¯(2)å°ããšããã®ãã
ãªå€ãŸã§å¢å ãããæ·»ä»å³é¢ã®æ²ç·ïŒ¢ã¯ç°æ¹æ§æº¶
èç©ãçããç³»ã«å¯ŸããŠé垞芳枬ããã匷床æ²ç·
ã®äŸã§ããã 亀åïŒ90ãïŒåå åã®éã§çæ¹æ§æº¶èç©ïŒè©Šæ
ã¯å®å šã«æº¶èããŠããªããã°ãªããªãïŒãçãã
æã®åæåšãéãå ã®åŒ·åºŠã¯å®è³ªçã«ããã¯ã°ã©
ãŠã³ãééæ²ç·ãšåãã§ããïŒã«ããŒã»ã¹ãªãã
ãã€ããªãè©Šæã90ã亀ååå åãçšãèŠéã®å€
åŽã«çœ®ããŠåŸããããã®ïŒãçæ¹æ§æº¶èç©ãçã
ããšãå ã®éé匷床ã¯(1)å®è³ªçã«ããã¯ã°ã©ãŠã³
ãã®éé匷床ã«çããããåã¯(2)é«ãå€ãããã®
ãããªå€ãžãšæžå°ãããæ·»ä»å³é¢ã®æ²ç·ïŒ¡ã¯çæ¹
æ§æº¶èç©ãçããéåäœã®åŒ·åºŠæ²ç·ã®äŸã§ããã æ¬çºæã®ããªã¢ãŸã¡ãã³åã³ã¢ãŸã¡ãã³å ±éå
äœã¯æº¶èç¶æ ã®å šæž©åºŠç¯å²ã«äºããå³ã¡éåäœã®
æµå枩床ããå解枩床åã¯æé«è©Šéšæž©åºŠãŸã§ã«äº
ãã屡ã å åŠçç°æ¹æ§ã瀺ãããããæçš®ã®ããª
ã¢ãŸã¡ãã³ïŒå ±ïŒéåäœã§ã¯ã溶èç©ãç±çã«å
解ãããšãã®äžéšã¯çæ¹çã«ãªãããŸãä»ã®çš®é¡
ã§ã¯ã溶èç©ã®æ§è³ªã¯æž©åºŠãäžãã«ã€ããŠç°æ¹æ§
ããçæ¹æ§ãžãšå®å šã«å€åããã éåäœæº¶è枩床ïŒPMTïŒïŒç¹èšããªãéãäžèš
å®æœäŸã§å ±åãããéåäœã®æº¶è枩床ã¯ã€ã³ã¿ãŒ
ãµã€ãšã³ã¹ã»ãããªãã·ã€ãŒãºïŒInterscience
PublishersïŒ1968幎çºè¡ãœã¬ã³ãœã³ïŒSorenâ
sonïŒåã³ãã€ã³ãã«ïŒCampbellïŒèããã¬ãã©
ãã€ãŽã»ã¡ãœããºã»ãªãŽã»ããªããŒã»ã±ãã¹ããª
ãŒïŒPreparative Methods of Polymer Chemi
âstryïŒã第ïŒç57ã59é èšèŒã®æ¹æ³ïŒ¡ã«ããé«
æž©ã®æ£ã«ã€ããŠæ±ºå®ãããã æ¬çºæã®ç¯å²å ã®å€ãã®ã¢ãŸã¡ãã³å質åã³å ±
éåäœã®äŸãäžèšå®æœäŸã«ç€ºãããããã¯æ§é ã
瀺ãåã«ãã€ãŠç€ºãããŠãããäŸãã°ïŒâã¡ãã«
âïŒïŒïŒâããšãã¬ã³ãžã¢ãã³ãšãã¬ãã¿ã«ã¢ã«
ãããããã€ããããã¢ãŸã¡ãã³å質éåäœã¯ã
ãªïŒãããªãâïŒâã¡ãã«âïŒïŒïŒâããšãã¬ã³
ãããªãã¡ããªãã€ã³âïŒïŒïŒâããšãã¬ã³ã¡ã
ãªãã€ã³ïŒãšåä»ããããã å®æœäŸ ïŒ æ¬å®æœäŸã¯å åŠçç°æ¹æ§ããã€ãããªïŒãããª
ãâïŒâã¡ãã«âïŒïŒïŒâããšãã¬ã³ãããªããš
ããªãã€ã³âïŒïŒïŒâããšãã¬ã³ãšããªãã€ã³ïŒ
ã®ç±ç補é æ³ã瀺ãã 30.5cmã®éå管äžã§ïŒâã¡ãã«âïŒïŒïŒâããš
ãã¬ã³ãžã¢ãã³ïŒ2.44ïœã0.02ã¢ã«ïŒãšïŒïŒïŒâ
ãžã¢ã»ãã«ãã³ãŒã³ïŒ3.24ïœã0.02ã¢ã«ïŒãšãäž
ç·ã«ãããåå¿æ··åç©ããã¹ãŠãããçªçŽ æ°æµäž
ã§ïŒæé156âã«å ç±ããåŸãïŒæé205âã«å ç±
ãããçæç©ãæéãç Žç ããé åæ©äžã§ã¡ã¿ã
ãŒã«åã³æ°Žã§å¥ã ã«æŽæµãã80âã§ç空也ç¥ããŠ
ηinhïŒ0.5ã®éåäœ4.32ïœãåŸãããã®ãã®ã®
PMTã¯370âã§ãã€ãã å®æœäŸ ïŒ æ¬å®æœäŸã¯åæ¢å€ãšããŠïŒâã¢ã»ãã¢ãããã³
ãºã¢ã«ããããçšããããªãâïŒâã¡ãã«âïŒïŒ
ïŒâããšãã¬ã³ãããªãã¡ããªãã€ã³âïŒïŒïŒâ
ããšãã¬ã³ã¡ããªãã€ã³ïŒãããªãâïŒïŒïŒâã
ãšãã¬ã³ãªãã·âïŒïŒïŒâããšãã¬ã³ãããªãã¡
ããªãã€ã³âïŒïŒïŒâããšãã¬ã³ã¡ããªãã€ã³
ïŒã¢ã«æ¯90ïŒ10ïŒå ±éåäœã補é ããæ¹æ³ã瀺ãã HMPAïŒ25mlïŒãNMPïŒ25mlïŒåã³å¡©åãªããŠ
ã ïŒ2.0ïœïŒã®æ··åç©äžã«ïŒâã¡ãã«âïŒïŒïŒâ
ããšãã¬ã³ãžã¢ãã³ïŒ4.4ïœã0.036ã¢ã«ïŒãšãã¹
ïŒïŒâã¢ããããšãã«ïŒãšãŒãã«ïŒ0.80ïœã0.004
ã¢ã«ïŒãå«ã溶液ãæ¹ææ··åããïŒâã¢ã»ãã¢ã
ããã³ãºã¢ã«ãããïŒ0.4ïœïŒãå ãããæ°åã
ãŠãã¬ãã¿ã«ã¢ã«ãããïŒ5.36ïœã0.04ã¢ã«ïŒã
å ããã16æéåŸåå¿æ··åç©ã¯æ¹æäžèœã«ãªãã
åå¿æ··åç©ãæ°Žãšæ··åããæ²æŸ±ããéåäœãå®æœ
äŸïŒã®ããã«ããŠæéãæŽæµã也ç¥ããηinhïŒ
1.1ã®éåäœ9.2ïœãåŸãããã®å ±éåäœã®PMT
ã¯306âã§ãããå åŠçç°æ¹æ§ã®ãã溶èç©ãç
ããã äžèšè¡šïŒã«ã¯äžèšå®æœäŸïŒã®äžè¬çæ¹æ³ã«ãã
ã€ããããæ¬çºæã®ä»ã®ïŒå ±ïŒéåäœã瀺ããã
ããã®åæã«çšãããžã¢ã«ãããã«ã¯ãã¬ãã¿ã«
ã¢ã«ããããã¡ãã«ãã¬ãã¿ã«ã¢ã«ããããïŒïŒ
ïŒâãã¹ïŒïŒâããªã«ãã«ããšããã·ïŒãšã¿ã³ã
åã³ãã¹ïŒïŒâããªã«ãã«ããšãã«ïŒãšãŒãã«ã§
ããã䜿çšãããžã¢ãã³ã«ã¯ïŒâãã«ãªãâãïŒ
âã¯ããâãåã³ïŒâã¡ãã«âïŒïŒïŒâããšãã¬
ã³ãžã¢ãã³ãïŒïŒ3â²âãžã¡ãã«ãã³ããžã³ãïŒïŒ
4â²âã¢ãŸãã·ãžã¢ããªã³ãïŒïŒ3â²âãžã¡ãã«â
ïŒïŒ4â²âãžã¢ããã¢ãŸãã³ãŒã³åã³ïŒïŒïŒâãã¹
ïŒïŒâã¢ããããšããã·ïŒãšã¿ã³ããããå®æœäŸ
ïŒã«ãããŠã¯ãåå¿æº¶åªã¯DMAcã§ããããã®
éåäœè©ŠæãïŒåé300âã«å ç±ããåŸã325âã
211KgïŒcm2ã§20ç§éãã¬ã¹ããå¯ææ§ã®ãã€ã«ã
ãåŸããå®æœäŸïŒã®å ±éåäœãã€ããå Žåããã
ãµã¡ãã¬ã³ãžã¢ãã³ãšïŒâã¡ãã«âïŒïŒïŒâããš
ãã¬ã³ãžã¢ãã³äºå¡©é žå¡©ãçã¢ã«éïŒå€«ã 0.005
ã¢ã«ïŒçšããçæããé žãäžåããçºã«çé žãªã
ãŠã ïŒ0.01ã¢ã«ïŒãçšãããå®æœäŸïŒâïŒã«ãã
ãŠã¯ãåå¿åæã0.002ã¢ã«éãçšããåå¿æº¶åª
ã¯ïŒïŒ ã®LiClãå«ãDMAcïŒNMPïŒ1/1ïŒã§ã
ããå®æœäŸïŒâïŒã«ãããŠã¯åå¿åæ0.0005ã¢ã«
éãçšãã溶åªã¯LiCl5ïŒ ãå«ãDMAcïŒ1.5mlïŒ
ã§ãã€ããæ«ç«¯å°éå€0.004ïœãçšãããå®æœäŸ
ïŒâïŒã§ã¯æº¶åªLiCl5ïŒ ãå«ãDMAcïŒ10mlïŒã§
ãããååå¿åæã0.005ã¢ã«éçšããã 瀺ããããã¹ãŠã®ãã®ããç°æ¹æ§æº¶èç©ã圢æ
ããã ãè¡šã ãè¡šã å®æœäŸ 10 æ¬å®æœäŸã¯ãããªãâïŒâã¡ãã«âïŒïŒïŒâã
ãšãã¬ã³ãããªãã¡ããªãã€ã³âïŒïŒïŒâããšã
ã¬ã³ã¡ããªãã€ã³ïŒãããªãâïŒïŒïŒâããšãã¬
ã³ãããªãã¡ããªãã€ã³âïŒïŒïŒâããšãã¬ã³ã¡
ããªãã€ã³ïŒïŒ95/5ïŒå ±éåäœã®è£œé æ³ã瀺ãã
ãã®å ±éåäœã¯æ圢ããŠæ£ã«ããã HMPAïŒ20mlïŒãNMPïŒ20mlïŒåã³LiClïŒïŒïœïŒ
ã®æ··åç©äžã«ïŒâã¡ãã«âïŒïŒïŒâããšãã¬ã³ãž
ã¢ãã³ïŒ4.64ïœã0.038ã¢ã«ïŒãšïŒïŒïŒâããšã
ã¬ã³ãžã¢ãã³ïŒ0.22ïœã0.002ã¢ã«ïŒãå«ã溶液
äžã«ãããŠçªçŽ äžã§ãã¬ãã¿ã«ã¢ã«ãããïŒ5.36
ïœã0.04ã¢ã«ïŒãå ãããåå¿æ··åç©ã宀枩ã«ã
ããŠ16æéæ¹æããåŸãå®æœäŸïŒãšåæã«ããŠå
åãïŒ110âäžã®çäžïŒÎ·inhïŒ4.7ãPMTïŒ260â
ã®å ±éåäœ8.6ïœãåŸãããã®å ±éåäœæº¶èç©ã¯
å åŠçã«ç°æ¹æ§ã§ããã ãã®çæç©è©Šæãæ£æ圢åã«å ¥ãã15åé300
âã«ä¿ã€ããã®æ£ã®æ²ã匷ãã¯6.3Ã103ãã³ãïŒ
å¹³æ¹ã€ã³ããæ²ãã¢ãžãŠã©ã¹ã¯4.3Ã105ãã³ãïŒ
å¹³æ¹ã€ã³ããéäŒåŒ·ã4.3Ã103ãã³ãïŒå¹³æ¹ã€ã³
ãïŒå€«ã 4.43ïŒ302ïŒ3.02KgïŒcm2ïŒã§ããã å®æœäŸ 11 æ¬å®æœäŸã¯ããªïŒãããªãâïŒâã¡ãã«âïŒïŒ
ïŒâããšãã¬ã³ãããªãã¡ããªãã€ã³âïŒïŒïŒâ
ããšãã¬ã³ã¡ããªãã€ã³ïŒã®è£œé æ³ã瀺ãããã®
çæç©ã¯å åŠçç°æ¹æ§ããã€æº¶èç©ãçããåŒç·©
ç±åŠçã«ããåŒåŒµåŒ·ãã匷åããã匷ãç¹ç¶ã«çŽ¡
糞ããããšãã§ããã ãšã¿ããŒã«200mläžã«ïŒâã¡ãã«âïŒïŒïŒâã
ãšãã¬ã³ãžã¢ãã³ïŒ77.9ïœã0.64ã¢ã«ïŒã®æº¶æ¶²ã
宀枩ã§ã€ããã200mlã®éæµãšã¿ããŒã«äžã«ãã
ãŠãã¬ãã¿ã«ã¢ã«ãããã®ç¬¬äºã®æº¶æ¶²ïŒ81.3ïœã
0.61ã¢ã«ïŒãã€ãã€ãããããã®æº¶æ¶²ãåæã«ïŒ
ã®ããŒã«ãŒã«æ³šããïŒãïŒå以å ã§éåäœã®æ²
柱ãå§ãŸãããã®åå¿æ··åç©ãäžæ©å®€æž©ã§çªçŽ äž
ã«ãããŠæŸçœ®ããããšã¿ããŒã«ãèžçºãããåŸã
éåäœæ®çç©ãïŒã®æ°Žã§æŽæµãã110âã«ãã
ãŠ1.5æéç空也ç¥ããã也ç¥æ®çç©ãå ç±ãã
ã¹ã¯ãªãŠãŒæŒåºæ©äžã§ããã«éåãããã æŒåºç©ã®äžéšãæ圢ããŠãã©ã°ïŒÎ·inhïŒ6.0ïŒ
ã«ããïŒåã®åããã€çŽ¡ç³žå£éãååã®çŽåŸ
0.018cmã玡糞å£é枩床260âã溶èåºå枩床
ïŒMZTïŒ255ã262âããéããŠç©ºæ°äžã«çŽ¡ç³žãã
600ydïŒåã®é床ã§æ²åãïŒ548ïœïŒåããã³
ïŒãä»ã®ããã³ïŒããã³ïŒ¢ïŒã¯900ydïŒåïŒ822
ïœïŒåãMZTïŒ260âïŒã§æ²åã€ããããã³ïŒ¢ã®
ç¹ç¶ã®Î·inhïŒ7.9ã玡糞ãããŸãã®ç³žã®æ§è³ªã¯æ¬¡
ã®éãã ãã㳠  ïŒ Den.  7.3 1.1 916 20.0  6.4 0.2 900 15.1 ããã³ïŒ¡ã®ç³žã®è©Šæããã¢ã€ããŒã»ãã©ãã¯ã¹
ïŒFiberâFraxïŒãçšããŠããã³ã«æ²åããäžèš
ã®æ¡ä»¶ã§çäžã«ãããŠïŒçªçŽ ãé£ç¶çã«æµãïŒå
ç±ããã宀枩160âïŒïŒæéã180âïŒïŒæéã
200âïŒïŒæéã250âïŒ12æéããã®åŠçåŸç¹ç¶
ã¯æ¬¡ã®ãã€ã©ã¡ã³ãã®æ§è³ªã瀺ããïŒ15è©Šæã®å¹³
åïŒãïŒïŒ¥ïŒMiïŒDen.ïŒ28ïŒ3.2ïŒ939ïŒ4.3ãïŒ
æ¬ã®ãã€ã©ã¡ã³ãã«ã€ããŠã¯ïŒŽïŒïŒ¥ïŒMiïŒDen.
ïŒ44ïŒ4.2ïŒ1118ïŒ4.2ã ä»ã®åŠçã«ãããŠã¯ããã³ïŒ¡ã®ç³žã®è©Šæãåé¢
ããŠïŒæ¬ã®ãã€ã©ã¡ã³ã(f)ã«ãããããéŒç·ãã
åçŽã«åäžãã次ã®æ¡ä»¶ã§é£ç¶çã«çªçŽ ãæµããª
ããçäžã§å ç±ããã宀枩ã165âïŒ40åã165ã
230âïŒïŒæéã232âïŒ1.3æéã234âïŒ6.3æ
éããã®åŠçã®åŸãç¹ç¶ã¯ïŒŽïŒïŒ¥ïŒMiïŒDen.ïŒ
38ïŒ4.4ïŒ1012ïŒ3.7ã®æ§è³ªã瀺ããã å®æœäŸ 12 æ¬å®æœäŸã¯å åŠçç°æ¹æ§ããã€æº¶èç©ãçãã
ããªïŒãããªãâïŒïŒïŒâããšãã¬ã³ãããªãã¡
ããªãã€ã³âïŒâã¡ãã«âïŒïŒïŒâããšãã¬ã³ã¡
ããªãã€ã³ïŒã®è£œé æ³ã瀺ãã 宀枩ã«ãããŠïŒâã¡ãã«ãã¬ãã¿ã«ã¢ã«ããã
ïŒ0.20ïœã0.00135ã¢ã«ïŒãïŒïŒïŒâããšãã¬ã³ãž
ã¢ãã³ïŒ0.146ïœã0.00135ã¢ã«ïŒåã³LiCl5ïŒ ã
å«ãHMPAïŒNMPïŒ50ïŒ50容ç©æ¯ïŒã®ç¡æ°Žæ··å
ç©ïŒmlãäžç·ã«ããŠæ¹æãåå¿æ··åç©ãã€ãã€
ãã15ååŸïŒâã¢ã»ãã¢ãããã³ãºã¢ã«ããã
ïŒ0.004ïœïŒãå ãããåå¿æ··åç©ã宀枩ã§ç¡æ°Žæ¡
件äžã§äžæ©æ¹æããæ°Žãå ããŠéåäœãæ²æŸ±ã
ãããããæéããæ°Žãšãšã¿ããŒã«ïŒç¡æ°ŽïŒã§
å¥ã ã«æŽæµãã80âã§ç空也ç¥ãããηinhïŒ0.7ã
PMTïŒ270âã®éåäœçŽ0.2ïœãåŸãããã®æº¶è
ç©ãã270âã«ãããŠçŽ¡ç³žããç¹ç¶ã®æ§è³ªã¯ïŒŽïŒ
ïŒMiïŒDen.ïŒ3.5ïŒ0.55ïŒ684ïŒ6.1ã§ããã ïŒâã¡ãã«ãã¬ãã¿ã«ã¢ã«ãããã¯ïŒâã¡ãã«
âαïŒÎ±â²âïŒïŒïŒâãã·ã¬ã³ãžãªãŒã«ãm.p.78ã
81âãããã¯ãã€ã¹ãããŒã ïŒNystromïŒãšã
ã©ãŠã³ïŒBrownïŒã«ããäžè¬çæ¹æ³ãã¢ã¡ãªã«
ååŠäŒèªïŒJ.Am.Chem.Soc.ïŒ69ïŒ1197ïŒ1947ïŒã
ã«ããïŒâã¡ãã«ãã¬ãã¿ãã€ã«ã¯ãã©ã€ãã
LiAlH4ã§éå ããŠã€ãããããã1Nã®ç¡é žã¢ã³
ã¢ããŠã ã»ãªãŠã ãïŒNH4ïŒ2CeïŒNO3ïŒ6ããçšãã
ãã©ãããã¹ããŒïŒTrahanovskyïŒãã®äžè¬ç
æ¹æ³ããžã€ãŒãã«ã»ãªãŽã»ãªã¬ããã¯ã»ã±ãã¹ã
ãªãŒïŒJ.Org.Chem.ïŒ32ïŒ3865ïŒ1967ïŒãã§é žåã
ãŠã€ããããšãã§ããã30åéå ç±æ¹æããåŸã
åå¿æ··åç©æ°Žæº¶æ¶²ããšãŒãã«ïŒïŒåïŒãšå¡©åã¡ã
ã¬ã³ïŒïŒåïŒã§æœåºãããäžç·ã«ããææ©çžã
NaHCO3ãšæ°Žãšã§æŽæµããåŸãMgSO4äžã§ä¹Ÿç¥
ããã也ç¥ç©ãçå¥ããç液ãèžçºãããŠãè»ã
ãçœè²åºäœã«ããããã65âã§æè¯ãããŠèç¹70
ã71âã®çœè²ç²æ«ãåŸãããã®ç²æ«ãæ°Žããåçµ
æ¶ããèç¹71ã72âã®ïŒâã¡ãã«ãã¬ãã¿ã«ã¢ã«
ããããåŸãã å®æœäŸ 13 æ¬å®æœäŸã¯ããªïŒãããªãâïŒâã¯ããâïŒïŒ
ïŒâããšãã¬ã³ãããªãã¡ããªãã€ã³âïŒïŒïŒâ
ããšãã¬ã³ã¡ããªãã€ã³ïŒã®è£œé æ³åã³ãããã
ã€ãããã匷ãç¹ç¶ã瀺ãããã®éåäœã®æº¶èç©
ã¯å åŠçç°æ¹æ§ã瀺ãã HMPAïŒ30mlïŒãNMPïŒ30mlïŒåã³LiClïŒ3.0ïœïŒ
ãå«ãæ··åç©äžã«ïŒâã¯ããâïŒïŒïŒâããšãã¬
ã³ãžã¢ãã³ïŒ8.58ïœã0.06ã¢ã«ïŒãå«ã溶液ãç
ç¶ãã©ã¹ã³äžã«ãããŠçªçŽ ãæµããªããæ¹æã
ïŒããã«æ¹ææ©ïŒãããã«ïŒâã¢ã»ãã¢ãããã³ãº
ã¢ã«ãããïŒ0.4ïœïŒãå ãããæ°å以å ã§ãã¬
ãã¿ã«ã¢ã«ãããïŒ8.04ïœã0.06ã¢ã«ïŒãå ã
ãã宀枩ã«ãããŠåå¿æ··åç©ãæ¹æãããšãçŽ16
æéåŸã«æ¹æäžèœã«ãªããå®æœäŸïŒã®æ¹æ³ã§åå¿
æ··åç©ãååããηinhïŒ0.7ãPMTïŒ310âã®é
åäœ13.8ïœãåŸãã ãã®éåäœã®æ£ãïŒåã®çŽ¡ç³žå£éãåã®çŽåŸïŒ
0.009inïŒ0.023cmïŒçŽ¡ç³žå£é枩床ïŒ320âã溶èåº
å枩床ïŒ310âãããã¯ã¯ã¹ã¯ãªãŒã³ãå«ããã
éããŠç©ºæ°äžã«æº¶è玡糞ããåŸãããç¹ç¶ã
150ydïŒåïŒ137.2ïœïŒåïŒã§æ²åãã玡糞ãã
ãŸãã®ç¹ç¶ïŒÎ·inhïŒ4.5ïŒã®ãã€ã©ã¡ã³ãã®æ§è³ª
ã¯ïŒŽïŒïŒ¥ïŒMiïŒDen.ïŒ7.4ïŒ1.3ïŒ683ïŒ10.9ã§ã
ããO.A.ïŒ22ãã§ããããã®ç¹ç¶ã®è©Šæããã¢ã€
ããŒã»ãã©ãã¯ã¹ã§æ²åã€ãããã³äžã«ãããŠç
äžã§å ç±åŠçããã宀枩ã150âïŒ30åã150âïŒ
30åã150ã260âïŒ30åã260âïŒ3.5æéãçã
ãååºãã宀枩ã«å·åŽããããã®ç¹ç¶ã®ãã€ã©ã¡
ã³ãã®æ§è³ªã¯ïŒŽïŒïŒ¥ïŒMiïŒDen.ïŒ15.3ïŒ1.9ïŒ
844ïŒ11.1ãO.A.ïŒ10ãã§ããã äžèšè¡šâåã³âã«ãããŠã¯ã¢ãŸã¡ãã³
ïŒå ±ïŒéåäœåã³ãã®å åŠçç°æ¹æ§ã®ãã溶èç©
ãã玡糞ããç¹ç¶ã瀺ããå®æœäŸ14ã19ã®éåäœ
ã¯å®æœäŸïŒã®äžè¬çæ¹æ³ã§ã€ãããå®æœäŸ11ã13
ã®äžè¬çæ¹æ³ã«ãã玡糞ããã䜿çšãããžã¢ã«ã
ããã«ã¯ïŒïŒ4â²âãžããªã«ãã«ãããšãã«ãïŒâ
ã¯ãããã¬ãã¿ã«ã¢ã«ãããããã¬ãã¿ã«ã¢ã«ã
ãããåã³ã€ãœãã¿ã«ã¢ã«ããããå«ãŸããã䜿
çšãããžã¢ãã³ã«ã¯ïŒïŒïŒâããšãã¬ã³ãžã¢ã
ã³ãïŒâã¡ãã«âïŒïŒïŒâããšãã¬ã³ãžã¢ãã³ã
åã³ïŒïŒïŒâãšãã¬ã³ãžã¢ããªã³ãå«ãŸãããå®
æœäŸ16ïŒ19ïŒ19âïŒïŒïŒçš®ã®ãžã¢ãã³ïŒã18åã³19
âïŒïŒïŒçš®ã®ã¢ã«ãããïŒã«ã¯å ±éåäœã瀺ãã
玡糞ãããŸãã®ç¹ç¶ãè¡šâã®ããã«ããŠç±åŠ
çãã匷床åã³äŒžã³ã倧ã«ããã å®æœäŸ19âïŒã®éåäœã«å¯ŸããŠã¯ãåå¿åæã®
ïŒïŒïŒâãã¹ïŒïŒâã¡ãã«âïŒâã¢ããããšãã
ã·ïŒâïœâãã¿ã³åã³ãã¬ãã¿ã«ã¢ã«ããããã
é žåé²æ¢å€ãšããŠããšãã«âαâãããã«ã¢ãã³
ãçšããã³ãŒã³äžã§éæµãããããã³ãŒã³âæ°Žã®
å ±æ²žæ··åç©ãæéããåŸãæ®ã€ããã³ãŒã³ããæ²
柱ããéåäœãçå¥ããåŸãæŽæµã也ç¥ããã å®æœäŸ19âïŒã®éåäœã«å¯ŸããŠã¯ããã¬ãã¿ã«
ã¢ã«ããããã¡ãã«âïŒïŒïŒâããšãã¬ã³ãžã¢ã
ã³åã³ïŒïŒ12âãã¹ïŒïŒâã¡ãã«âïŒâã¢ããã
ãšããã·ïŒâïœâããã«ã³ãåå¿åæãšããŠçš
ããå®æœäŸ19âïŒã®äžè¬çæ¹æ³ã䜿çšãããå®æœ
äŸ19âïŒã®éåäœã«å¯ŸããŠã¯ãåæãšããŠãã¬ã
ã¿ã«ã¢ã«ããããïŒïŒ4â²âããªã«ãã«ãããšã
ã«ãã¡ãã«âïŒïŒïŒâããšãã¬ã³ãžã¢ãã³ãåã³
ïŒâã¢ããã¢ã»ãã¢ããªãïŒæ«ç«¯å°éå€ïŒãã溶
åªãšããŠå¡©åã¡ãã¬ã³ãçšããŠå®æœäŸ19âïŒã®äž
è¬çæ¹æ³ã§è¡ãªã€ãã å®æœäŸ19âïŒã«çšããïŒïŒïŒâãã¹ïŒïŒâã¡ã
ã«âïŒâã¢ããããšããã·ïŒâïœâãã¿ã³ã¯ïŒâ
ã¡ãã«âïŒâãããããšããŒã«ãšïŒïŒïŒâãžãã
ã ãã¿ã³ãšã®çã¢ã«éãç¡æ°Žçé žã«ãªãŠã ãšã¢ã»
ãã³ãšã®æ··åç©ãååšãããŠåå¿ãããããšã«ã
ãã€ããã48æééæµãããåŸã溶åªãé€å»ãã
åºäœçæç©ãååããïŒâã¢ã«ã³ãŒã«ããåçµ
æ¶ãããŠm.p.ïŒ126.5ã127.5âã®ïŒïŒïŒâãã¹
ïŒïŒâã¡ãã«âïŒâãããããšããã·ïŒâïœâã
ã¿ã³ã®è€è²éç¶çµæ¶ãåŸãã溶åªãã¡ã¿ããŒã«ã«
ãããã®ãããååç©ã70âåã¯ãã以äžã§1000
ã15000ãã³ãïŒå¹³æ¹ã€ã³ãã«ãããŠãã©ããŒã»
ããã±ã«è§Šåªãçšããæ°ŽçŽ ã«ããéå ããŠææã®
ãžã¢ãã³åæåã«ããã溶液ãã觊åªãåé¢ãã
溶åªãèžçºããããšã¿ããŒã«ããææã®ãžã¢ãã³
ãåçµæ¶ããïŒæŽ»æ§çïŒãèç¹108ã110âãåæ§
ãªæ¹æ³ã§å®æœäŸ19âïŒã«çšããïŒïŒ12âãã¹ïŒïŒ
âã¡ãã«âïŒâã¢ããããšããã·ïŒâïœâããã«
ã³ïŒm.p.ïŒ93ã94âïŒã¯ïŒïŒ12âãžããã¢ããã«
ã³ããã€ãã€ãã ãè¡šã ãè¡šã ïŒïŒ ïŒïŒ³ïŒ¯ïŒïŒš
ïŒïŒïŒ (0.1ïŒ æ¿åºŠ)
ãè¡šã å®æœäŸ 20 æ¬å®æœäŸã¯ïŒâã¯ãããã¬ãã¿ã«ã¢ã«ãããã
åã³ïŒïŒ4â²âãšãã¬ã³ãžã¢ããªã³ãïŒïŒïŒâããš
ãã¬ã³ãžã¢ãã³ããã¹ïŒïŒâã¢ããããšãã«ïŒãš
ãŒãã«ãåã³ïŒïŒïŒâã·ã¯ããããµã³ãžã¢ãã³ã
ãéžã°ããäžå¯Ÿã®ãžã¢ãã³ããã¢ãŸã¡ãã³ïŒå ±ïŒ
éåäœã補é ããæ¹æ³ã瀺ãããããã®å ±éåäœ
ã®æº¶èç©ã¯å åŠçç°æ¹æ§ãæããã HMPAïŒ10mlïŒãNMPïŒ10mlïŒåã³LiClïŒ0.5ïœïŒ
ã®æ··åç©äžã«ãïŒïŒ4â²âãšãã¬ã³ãžã¢ããªã³
ïŒ2.12ïœã0.01ã¢ã«ïŒåã³ïŒïŒïŒâããšãã¬ã³ãž
ã¢ãã³ïŒ1.08ïœã0.01ã¢ã«ïŒãå«ã溶液ã«çªçŽ æ°
æµäžã«ãããŠïŒâã¯ãããã¬ãã¿ã«ã¢ã«ããã
ïŒ3.36ïœã0.02ã¢ã«ïŒãå ãããåå¿æ··åç©ã宀
æž©ã«ãããŠäžæ©æ¹æããå®æœäŸïŒãšåæ§ã«ããŠå
åãïŒ70ã75ã§ä¹Ÿç¥ïŒãηinhïŒ0.5ãPMTïŒ150â
ã®ïŒãããªãâïŒïŒïŒâããšãã¬ã³ãšãã¬ã³â
ïŒïŒïŒâããšãã¬ã³ãããªãã¡ããªãã³âïŒâã¯
ããâïŒïŒïŒâããšãã¬ã³ã¡ããªãã€ã³ïŒãããª
ãâïŒïŒïŒâããšãã¬ã³ãããªãã¡ããªãã€ã³â
ïŒâã¯ããâïŒïŒïŒïŒããšãã¬ã³ã¡ããªãã€ã³ïŒ
ïŒ50/50ïŒå ±éåäœ5.3ïœãåŸãã äžèšè¡šã«ã¯äžè¿°ã®äžå¯Ÿã®ãžã¢ãã³ãçšãäžè¿°
ã®æ¹æ³ã§äžèšå埩åäœããã€ä»ã®å ±éåäœçµæç©
ãã€ããããããã®ãã®ã¯æº¶èç©äžã«ãããŠå åŠ
çç°æ¹æ§ã瀺ãã ãè¡šã ãè¡šã å®æœäŸ 21 æ¬å®æœäŸã§ã¯ããªïŒãããªãâïŒâã¡ãã«â
ïŒïŒïŒâããšãã¬ã³ãããªãã¡ããªãã€ã³âïŒïŒ
ïŒâããšãã¬ã³ã¡ããªãã€ã³ïŒã®ç¹ç¶ã¯èžçºãã
ã¢ã«ããªãªã³ã«é²åºããåŸåŒåŒµç¹æ§ã®ä¿ææ§ãåª
ç§ãªããšã瀺ãã HMPAïŒ60mlïŒãNMPïŒ60mlïŒåã³LiClïŒ5.0ïœïŒ
ã®æ··åç©äžã«ïŒâã¡ãã«âïŒïŒããšãã¬ã³ãžã¢ã
ã³ïŒ12.2ïœã0.01ã¢ã«ïŒãå«ã溶液ãçªçŽ äžã§
500mlã®æš¹èéã®äžã§æ¹æãããã¬ãã¿ã«ã¢ãã
ïŒ13.4ïœã0.1ã¢ã«ïŒãå ããã30ååŸïŒâã¢ãã
ã¢ã»ãã¢ããªãïŒ0.30ïœïŒãå ããå šéšã§16æé
æ¹æãç¶ãããå®æœäŸïŒãšåæ§ã«åå¿æ··åç©ãå
åããηinhïŒ3.0ãPMTïŒ256âã®éåäœ21.6ïœ
ãåŸããéåäœæº¶èç©ã¯å åŠçç°æ¹æ§ããã€ãŠã
ãã éåäœã®æ£ã溶è玡糞ããã玡糞å£é枩床ïŒ
250âã溶èåºå枩床ïŒ240âãæ²åé床çŽ
500ydïŒåïŒ457ïœïŒåïŒã 玡糞æã®ç¹ç¶ïŒÎ·inhïŒ3.3ïŒã®ãã€ã©ã¡ã³ãã®
åŒåŒµç¹æ§ã¯ïŒŽïŒïŒ¥ïŒMiïŒDen.ïŒïŒïŒ1.6ïŒ789ïŒ
6.4ã§ããã ç¹ç¶ã®å°è©ŠæïŒ0.5ïœïŒåã³0.03mlã®ã¢ã«ããª
ãªã³ãå¯å°ç®¡äžã«ãããŠïŒæé133âã«ãããŠå
ç±ããïŒèžæ°æµŽïŒãç¹ç¶ãååºãã空æ°äžã«ãã
ãŠïŒæéæŸçœ®ããããã®åŠçããç¹ç¶ã¯ïŒŽïŒïŒ¥ïŒ
MiïŒDen.ïŒ8.2ïŒ1.1ïŒ736ïŒ7.4ã§ããã 玡糞æã®ç¹ç¶è©Šæã次ã®æ¡ä»¶ã§å ç±åŠçããã
宀枩ã160âïŒïŒæéã200âïŒïŒæéãåŠçãã
ç¹ç¶ã®ãã€ã©ã¡ã³ãã®æ§è³ªã¯ïŒŽïŒïŒ¥ïŒMiïŒDen.
ïŒ16ïŒ2.2ïŒ867ïŒ7.2ã§ãã€ãã å®æœäŸ 22 æ¬å®æœäŸã§ã¯æ¬çºæã®åäœã¯(1)é«ã¢ãã³å«éã®
ãŽã åæäžã§å ç±èåãããæãåã³(2)å¡©åºæ§ã§
å æ°Žå解ãããæã«ãè¯å¥œã«åŒ·åºŠãä¿æããããš
ã瀺ãããã 第äžéš å®æœäŸ10ã®å ±éåäœã®ä»ã®è£œæ³ã®ç³žã®è©Šæã次
ã®æ¡ä»¶äžã«ãããŠå ç±åŠçããã150âïŒ40åã
180âïŒïŒæéã200âïŒïŒæéïŒåæç枩床150
âïŒãããã«ãã€ãŠæ§è³ªïŒŽïŒïŒ¥ïŒMiïŒDen.ïŒ
9.9ïŒ1.4ïŒ788ïŒ7.3ã®ç¹ç¶ãåŸãããã®ç±åŠçã
ã糞ã®è©Šæãã¹ã±ã€ã³ã«ãã空æ°äžã«ãããŠ154
âïŒ24æéå ç±ããïŒïŒ¥ïŒMiïŒDen.ïŒ6.9ïŒ
0.9ïŒ779ïŒ120ã®ç¹ç¶ãåŸãããã®ç±åŠçããç¹
ç¶ãå糞ãã1000ãããŒã«ã®ã³ãŒãã«ãããã®ã³
ãŒããé«ã¢ãã³å«éã®ãŽã åææäžã«å蟌ãã§è€
åäœãã€ãã€ãããã®è€åäœã154âã§24æéå
ç±èåãããã次ã«ãã®ãŽã ããã«ãšã³ã«ããèš
最ãããç¹ç¶ïŒã³ãŒãïŒãååºããããã®ã³ãŒã
ã«å¯ŸããïŒïŒ¥ïŒMiïŒ2.2ïŒ0.80ïŒ472ïŒ10ã€ã³ã
ç ŽæïŒã§ãããããã¯èé ·ãªè©Šéšæ¡ä»¶äžã«ãããŠ
匷床ã32ïŒ ä¿æããããšã«çžåœããã 第äºéš å®æœäŸ10ã®éåäœã®ä»ã®è£œæ³ã®ç³žè©ŠæïŒïŒâã
ã€ã©ã¡ã³ãïŒãïŒæéïŒ190âãïŒæéïŒ200â
ïŒåæçæž©190âïŒã§ç±åŠçãããã€ã©ã¡ã³ãã®æ§
質ãïŒïŒ¥ïŒMiïŒDen.ïŒ12.5ïŒ2.5ïŒ560ïŒ30.1ã®
ç¹ç¶ãåŸãã ãã®ç¹ç¶è©Šæã次ã®ããã«ããŠå æ°Žå解ããã è©ŠéšïŒ¢âïŒ é·ãïŒã€ã³ãã®ç¹ç¶ã§ç²ãåžãç·
ç¶ã«çž«ããæ°Žäžã§ïŒæéïŒ95âã§å ç±ããã è©ŠéšïŒ¢âïŒ ãã®è©Šéšã¯æ°Žã®ä»£ãã«1Nã®æ°Žé ž
åãããªãŠã 氎溶液ãçšããããšä»¥å€ïŒ¢âïŒãšå
çã§ãããè©ŠéšåŸç¹ç¶ãšåžãšãã¢ã«ã«ãªããªããª
ããŸã§æ°Žäžã§ãœãŒãã³ã°ããã å æ°Žå解åŠçåŸç¹ç¶ãæŽæµã也ç¥ããŠãã€ã©ã¡
ã³ãã®åŒåŒµç¹æ§ã決å®ããã è©ŠéšïŒ¢âïŒã®ç¹ç¶ïŒïŒŽïŒïŒ¥ïŒMiïŒDen.ïŒ8.1ïŒ
1.8ïŒ512ïŒ34.7 è©ŠéšïŒ¢âïŒã®ç¹ç¶ïŒïŒŽïŒïŒ¥ïŒMiïŒDen.ïŒ12.5ïŒ
2.0ïŒ717ïŒ23.3 å®æœäŸ 23 æ¬å®æœäŸã§ã¯æ¬çºæã®ã¢ãŸã¡ãã³ïŒå ±ïŒéåäœ
ç¹ç¶ã¯ãŽã äžã§å ç±çæãããå Žåãè¯å¥œã«åŒ·åºŠ
ãä¿æããããšã瀺ãã å®æœäŸ16ã®å ±éåäœè©ŠæïŒÎ·inhïŒ1.2ïŒãã€ã
ããå ±éåäœã®æ£ã玡糞ãïŒçŽ¡ç³žå£é枩床ïŒ250
ã252âïŒã288ã1271ïœïŒåã®ç¯å²ã§è¥å¹²ã®ç¹ç¶
ããã³ãæ²åãã1271ïœïŒåã§éããããã³ã«å¯Ÿ
ããŠã¯ãã€ã©ã¡ã³ãïŒïŒ¥ïŒMiïŒDen.ïŒ6.4ïŒ
1.1ïŒ717ïŒ4.3ã§ãã€ãã ãããã®ãã€ã©ã¡ã³ã30æ¬ãäºãã«å糞ããŠ
ïŒïŒåïŒã€ã³ãïŒç³žã«ãã230âã§ïŒæéç±åŠçã
ãŠç³žã«ãããåŠçãã糞ã¯ïŒŽïŒïŒ¥ïŒMiïŒDen.ïŒ
11.4ïŒ1.3ïŒ906ïŒ120.5ã®æ§è³ªã瀺ãããã®ç³žïŒæ
ãïŒåïŒã€ã³ãïŒããŽã äžã§åŠçããŠåè©Šéšã
ãããã®çµæãäžèšã«ç€ºãã 糞詊æïŒé·ãçŽ20ã€ã³ãïŒã倫ã é·ãçŽïŒã€ã³
ãã®ïŒæã®ãŽã æ¿ã®éã«é·ææ¹åã«å ¥ãããéã«
糞ãæ¿å ¥ãããŽã æ¿ãäºãã«ãã€ãããšã¯ã©ã³ã
ããçªåºãã糞ã®ç«¯ãããŒãã§æ¢ããŠæããä¿æ
ããããè©Šæçã空æ°äžã§24æé165âã§å ç±ã
ãåŸã宀枩ã«å·åŽãããããåŸç³žã®ç«¯ãã€ã³ã¹ã
ãã³è©Šéšæ©ã«ã¯ã©ã³ãããå蟌ãã 糞ã®ç Žæ匷床
ã決å®ããã é«ã¢ãã³å«éåã³äœã¢ãã³å«éã®å¥ã ã®ãŽã å
ææãçšããã 次ã®çµæãåŸãã ãŽã åææ æå€§ç Žæè·é ãã³ã ïœïŒïœ é«ã¢ãã³å«é 2.83 10.7 äœã¢ãã³å«é 2.61 9.8 ãããã®å€ã¯å€«ã 匷床ã94ïŒ åã³86ïŒ ä¿æãã
å€ã§ããã å®æœäŸ 24 æ¬å®æœäŸã¯ãããªãâïŒâã¡ãã«âïŒïŒïŒâã
ãšãã¬ã³ãããªããã¡ããªãã€ã³ãâïŒïŒïŒâã
ãšãã¬ã³ã¡ããªãã€ã³ãšãããªãâïŒïŒïŒâããš
ãã¬ã³ã¡ããªãã€ã³åäœãïŒïŒïŒïŒïŒã®å²åã§å«
ãŸããäžèŠåå ±éåäœã®æº¶è補é æ³ã瀺ãã æ¹ææ©ãçªçŽ å¹èŸŒç®¡åã³èžçããããåãã
250mlã®äžãå£ãã©ã¹ã³ã«ïŒâã¡ãã«âïŒïŒïŒâ
ããšãã¬ã³ãžã¢ãã³ïŒ7.32ïœã0.06ã¢ã«ïŒãïŒâ
ã¢ãããã³ãºã¢ã«ãããããªãªãŽããŒãã1.58ïœã
0.015ã¢ã«ãηinhïŒ0.08ãã¢ã³ãã©ãã©ããª
ãŒãºïŒLaboratoriesïŒãç±³åœããŠãšãŒã¯å·ãã¬ã³
ãŽãŠãŒïŒPlainviewïŒè£œããåã³ïŒ®ïŒNâ²âïŒïŒïŒ
ïŒâããšãã¬ã³ã¡ããªãã€ã³ïŒãžã¢ããªã³
ïŒ17.88ïœã0.06ã¢ã«ïŒãå ãããäžç·ã«ããæå
ãæ¹æããçªçŽ äžã§30åé250âã«å ç±ããã次
ã«ïŒmmïœã®æžå§äžã§250âã«10åéå ç±ããã
ããåŸåå¿æ··åç©ïŒå åŠçç°æ¹æ§ããã€æº¶èç©ïŒ
ã宀枩ã«å·åŽãããå ç±äžæ°Žåã³ã¢ããªã³ã®éå
å¯æç©ãèžçãæéãããåŸãããåºäœå ±éåäœ
ãéããé åç©äžã§ç Žç ãããã®äžã§ã¢ã»ãã³ã§
æŽæµãã80âã«ãããŠç空也ç¥ãããηinhïŒ3.2ã
PMTïŒ210âã®å ±éåäœ13.3ïœãåŸããããã¯å
åŠçç°æ¹æ§ããã€æº¶èç©ãçããã å ±éåäœã®æ£ãïŒåã®çŽ¡ç³žå£éãåã®çŽåŸ
0.009inïŒ0.023cmïŒã玡糞å£é枩床230âã溶èåºå
枩床225âããéããŠç©ºæ°äžã«æº¶è玡糞ããåŸã
ããç¹ç¶ã500ydïŒåïŒ457.2ïœïŒïŒåã§æ²åãã
玡糞æã®ç¹ç¶ã®ãã€ã©ã¡ã³ãã®æ§è³ªã¯ïŒŽïŒïŒ¥ïŒ
MiïŒDen.ïŒ3.7ïŒ0.7ïŒ556ïŒ7.2ã§ãã€ãããã®ç¹
ç¶ã®äžéšããã¢ã€ããŒã»ãã©ãã¯ã¹ã»ããã³ã«æ²
ä»ããçªçŽ æ°æµäžã§240âã§ïŒæéçäžã§å ç±ã
ããåŠçãããã€ã©ã¡ã³ãã®æ§è³ªã¯ïŒŽïŒïŒ¥ïŒ
MiïŒDen.ïŒ10.3ïŒ1.7ïŒ659ïŒ7.2ã§ãã€ãã 第äºéš ãããªãâïŒâã¡ãã«âïŒïŒïŒâããšãã¬ã³ã
ããªããã¡ããªãã€ã³âïŒâã¯ããâïŒïŒïŒâã
ãšãã¬ã³ã¡ããªãã€ã³åã³ãããªãâïŒïŒïŒâã
ãšãã¬ã³ã¡ããªãã€ã³åäœïŒïŒïŒïŒïŒïŒïŒãå«ã
å ±éåäœãã€ããããã®å ±éåäœã¯å åŠçç°æ¹æ§
ã®ãã溶èç©ãçãããäžèšç¬¬äžéšã®æ¹æ³ãç¹°è¿
ãããã4.88ïœïŒ0.04ã¢ã«ïŒã®ãžã¢ãã³ã2.12ïœ
ïŒ0.02ã¢ã«ïŒã®ããªãªãŽããŒãåã³12.74ïœïŒ0.04
ã¢ã«ïŒã®ïŒ®ïŒNâ²âïŒïŒâã¯ããâïŒïŒïŒâããš
ãã¬ã³ã¡ããªãã€ã³ïŒãžã¢ããªã³ãçšãã250â
ã«ãããŠå€§æ°å§ã§20åéå ç±ããåŸã20åã10mm
ïœã®å§åã§250âã«å ç±ãããηinhïŒ1.5ã
PMTïŒ230âã®å ±éåäœ11.7ïœãåŸãããããã®
ãã®ã¯å åŠçç°æ¹æ§ããã€æº¶èç©ãçæããã å®æœäŸ 25 æ¬å®æœäŸã¯ããªïŒãããªãâïŒâã¡ãã«âïŒïŒ
ïŒâããšãã¬ã³ãããªãã¡ããªãã€ã³â2.6âã
ããã¬ã³ã¡ããªãã€ã³ïŒã®è£œé æ³ã瀺ãã æ¹ææ©åã³èžçããããåããåå¿å®¹åšã«ãã
ãŠãïŒâã¡ãã«âïŒïŒïŒâããšãã¬ã³ãžã¢ãã³
ïŒ1.22ïœã0.01ã¢ã«ïŒåã³ïŒ®ïŒNâ²âïŒïŒïŒïŒâã
ããã¬ã³ãžã¡ããªãã€ã³ïŒâãžã¢ããªã³ïŒ3.3ïœã
0.01ã¢ã«ïŒãå ããããããã®åå¿åæã250â
ã§20åé溶èãæ¹æãããã¢ããªã³å¯æç©ãèžç
ãæéãããåå¿çæç©ãå·åŽããæéããã¢ã»
ãã³ã§æŽæµãã也ç¥ããŠPMTïŒ245âãηinhïŒ
0.6ã®éåäœ3.22ïœãåŸãããã®ãã®ã¯å åŠçç°
æ¹æ§ã®ãã溶èç©ãçããã ïŒNâ²âïŒïŒïŒïŒãããã¬ã³ãžã¡ããªãã€ã³ïŒ
ãžã¢ããªã³ã¯å ããšãã¬ã³ã°ãªã³ãŒã«ãžã¡ãã«ãš
ãŒãã«ïŒ150mlïŒäžã§ïŒïŒïŒâãããã¬ã³ãžã«ã«
ããã«ã¯ãã©ã€ãïŒ50.6ïœã0.02ã¢ã«ïŒãããšã
ã¬ã³ã°ãªã³ãŒã«ãžã¡ãã«ãšãŒãã«ïŒ700mlïŒäžã«
ãªããŠã ããªâïœâãããã·ã¢ã«ãããŠã ãã€ã
ã©ã€ãïŒ103ïœïŒãå«ã溶液ã§éå ããããšã«ã
ãã€ãã€ãããžé žã¯ãã©ã€ããçªçŽ äžã«ãããŠâ
70âã«ãããŠæ¹æãããéå å€ãïŒæé以äžæ»Žäž
ãããããåŸäžç·ã«ããæåãäžæ©æ¹æãã宀枩
ãŸã§æž©ãããåå¿æ··åç©ãæ°·ã®äžã«æ³šããæ²æŸ±ã
ãçœè²çæç©ãéããé«æž©ïŒæ²žéš°ïŒ2Bã¢ã«ã³ãŒ
ã«ã§ãªã湿ã€ãŠããæã«æœåºãããé«æž©ã¢ã«ã³ãŒ
ã«ãšæ®çåºäœãåé¢ããã¢ã«ã³ãŒã«æœåºç©ãèžç
ããŠç²è£œé»è²çµæ¶ã®ïŒïŒïŒâãããã¬ã³ãžã¢ã«ã
ãããèç¹162ã190âïŒæº¶èããªãç©è³ªãè¥å¹²æ®
ãïŒãæ®ã€ãã次ã«ç²è£œãžã¢ã«ãããïŒ4.0ïœïŒ
ãæ¹æããªãããšã¿ããŒã«ïŒ200mlïŒäžã«æº¶è§£ã
ãããã®æº¶æ¶²ã«ã¢ããªã³ïŒïŒmlïŒãå ãããåå¿
æ··åç©ãäžç·ã«ïŒæééæµãããå·åŽãäžèšã®ãž
ã¢ããªã³ã®é»è²æ²æŸ±ãéããæŽæµãã也ç¥ããã
èç¹ïŒ180ã182âã äžèšè¡šïŒå®æœäŸ26ã38ïŒã«ãããŠã¯ãæ¬çºæ
ã®æº¶æ¶²éåæ³ïŒå³ã¡HMPAãNMPãLiClãAA
åæ¢å€ïŒã«ããã€ããããæ¬çºæã®ä»ã®å åŠçç°
æ¹æ§ããã€ã溶èç©ãçããã¢ãŸã¡ãã³ïŒå ±ïŒé
åäœãç¹ç¶åã³ãã€ã«ã ã瀺ãã䜿çšãããžã¢ã
ã³åå¿åæã«ã¯ïŒâã¡ãã«âïŒïŒïŒâããšãã¬ã³
ãžã¢ãã³ãïŒïŒïŒâãžã¢ã»ãã«ãã³ãŒã³ãã¹ãã
ã©ãŸã³ãïŒïŒïŒâãžã¯ããâïŒïŒïŒâããšãã¬ã³
ãžã¢ãã³ãïŒïŒïŒâãã¹ïŒïŒâã¢ããããšãã«ïŒ
ãšã¿ã³ããã¹ïŒïŒâã¢ããããšãã«ïŒã¡ã¿ã³ãã
ã¹ïŒïŒâã¢ããããšãã«ïŒããªãšãŒãã«ãïŒïŒïŒ
âãžã¢ããããã¿ãªã³ãïŒâã¯ããâïŒïŒïŒâã
ãšãã¬ã³ãžã¢ãã³ããããµã¡ãã¬ã³ãžã¢ãã³åã³
ïŒâã¢ãããã³ãŸã€ã«ããã©ãžãããå«ãŸããã
䜿çšãããžã¢ã«ãããåå¿åæã«ã¯ïŒâã¯ããã
ã¬ãã¿ã«ã¢ã«ããããïŒïŒïŒâãã¹ïŒïŒâããªã«
ãã«ããšãã«ïŒãšã¿ã³ãïŒïŒïŒâãžã¯ãããã¬ã
ã¿ã«ã¢ã«ãããããã¬ãã¿ã«ã¢ã«ããããïŒïŒïŒ
âãã¹ïŒïŒâããªã«ãã«ããšããã·ïŒãšã¿ã³ã
ïŒïŒïŒâãžã¯ãããã¬ãã¿ã«ã¢ã«ãããããã¬ã
ã¿ã«ã¢ã«ããããïŒïŒïŒâãã¹ïŒïŒâããªã«ãã«
ããšããã·ïŒãšã¿ã³ãïŒïŒ4â²âãžãã³ãºã¢ã«ãã
ãåã³ã€ãœãã¿ã«ã¢ã«ããããå«ãŸããã å®æœäŸ26ã«ãããŠã¯ãã¹ããã©ãŸã³ãçšããã
ãã®ãã®ã¯ïŒïŒïŒâãžã¢ã»ãã«ãã³ãŒã³ãéå°ã®
ããã©ãžã³æ°Žåç©ãš2Bã¢ã«ã³ãŒã«äžã§éæµïŒ48
æéïŒãããŠåå¿æ··åç©ãå·åŽããèç¹184âã®
çæç©ãåŸãããšã«ããã€ãããå®æœäŸ35ã§çšã
ããžã¢ã«ãããã¯å ãïŒïŒïŒâãã¹ïŒïŒâã«ã«ã
ãã·ããšããã·ïŒãšã¿ã³ã®ãžã¡ãã«ãšã¹ãã«ãã
ãã©ããããã©ã³äžã«ãããŠLiAlH4ã§éå ãã
ïŒïŒïŒâãã¹ïŒïŒâããããã·ã¡ãã«ããšãã
ã·ïŒãšã¿ã³ãèç¹174ã176âãã€ããããšã«ãã€
ãŠã€ãããããããããžã€ãŒãã«ã»ãªãŽã»ãªãŒã¬
ããã¯ã»ã±ãã¹ããªãŒïŒJ.Org.Chem.ïŒèª32ïŒ
3865ãïŒïŒ1967ïŒèšèŒã®äžè¬çæ¹æ³ã§ç¡é žã¢ã³ã¢
ããŠã ã»ãªãŠã ã§æ°·é ¢é žïŒæ°Žäžã«ãããŠé žåããŠ
ææã®ãžã¢ã«ãããã«ãããèç¹112.5ã114âã å®æœäŸ36ã«çšãããžã¢ã«ãããã¯ããã©ããã
ãã©ã³äžã«ãããŠïŒïŒ4â²âãå®æ¯éŠé žã®ãžã¡ãã«
ãšã¹ãã«ãLiAlH4ã§çŽïŒâã«ãããŠéå ããè
ç¹190ã192âã®ïŒïŒ4â²âããã³ãžã«ã¢ã«ã³ãŒã«ã«
ããããšã«ããã€ããããããã®ã¢ã«ã³ãŒã«ããž
ã€ãŒãã«ã»ãªãŒã¬ããã¯ã»ã±ãã¹ãªãŒèª32ïŒ3865
ãïŒïŒ1967ïŒèšèŒã®äžè¬çæ¹æ³ã«ããæ°·é ¢é žïŒæ°Ž
äžã«ãããŠç¡é žã¢ã³ã¢ããŠã ã»ãªãŠã ã§é žåããŠ
ææã®ãžã¢ã«ãããã«ããããã®ãžã¢ã«ãããã®
èç¹ã¯141ã143âã§ããããã¹ãŠã®ç€ºãããããŒ
ã«ã¯ãã€ã©ã¡ã³ãã®å€ã§ãããïŒåã®çŽ¡ç³žå£é
ãåã®çŽåŸ0.009inïŒ0.023cmïŒããéããŠç¹ç¶ã溶è
玡糞ããã ãè¡šã ãè¡šã ãè¡šã
â
ïŒ å ç±åŠçç¹ç¶(çäžãïŒé°å²æ°ããã€ããŒã
ãã©ãã¯ã¹ ã§è¢«èŠããããã³ïŒ235âã3hr)ïŒãã€ã©
ã¡ã³ãã®TãEå¡«MiãDen.ïŒ6.6ã1.4ã517ã37ã
ïŒïŒ å ç±åŠçTãEãMiãDen.ïŒ15ã3.7ã455ã4ã
å®æœäŸ 39 æ¬å®æœäŸã§ã¯æ¬çºæã®åŒåŒµç¹æ§ã¯å ç±åŠçãçš
ããããšã«ããèããå¢åŒ·ãããããšã瀺ããã
ã®å·¥çšã®é²åºæéãçãããåã¯é²åºæž©åºŠãäœã
å ŽåãäŸç€ºããã 第äžéš å®æœäŸ37ã®çŽ¡ç³žãããŸãã®ã¢ãŸã¡ãã³å ±éåäœ
ãã€ã©ã¡ã³ãïŒïŒŽïŒïŒ¥ïŒMiïŒDen.ïŒ3.4ïŒ1.2ïŒ
353ïŒ4.7ïŒãå糞ããŠç³žïŒïŒãã€ã©ã¡ã³ãïŒã«
ããã¿ã«ã¯ã®ãããã«éãã次ãã§ãã¢ã€ããŒã»
ãã©ãã¯ã¹ã§è¢«èŠããéå±ããã³ã«æ²ãããã®
è©ŠæãçªçŽ ãæµããçã®äžã«å ¥ãããã®æž©åºŠã40
åã§å®€æž©ãã150âã«äžãã20åéãã®äžã«ä¿ã€ã
è©Šæãçäžã§çŽ50âã«å·åŽããçããååºãã宀
æž©ã«å·åŽãããåŠçããç¹ç¶ã¯ïŒŽïŒïŒ¥ïŒMiïŒ
Den.ïŒ9.2ïŒ2.0ïŒ439ïŒ5.7ã®æ§è³ªã瀺ãããã®åŠ
çããç¹ç¶ã®äžéšãããã³ã«æ²ããåã³çäžã«ã
ããŠå ç±ãïŒçªçŽ äžã«ãããŠïŒã40åéã«äºã宀
æž©ãã260âã«å ç±ããïŒæé20åé260âã«ä¿
ã€ããããåŸå·åŽããäžè¿°ã®æ¡ä»¶äžã§é€å»ããã
ãã®åŠçããç¹ç¶ã®ãã€ã©ã¡ã³ãã¯ïŒŽïŒïŒ¥ïŒ
MiïŒDen.ïŒ20.0ïŒ3.8ïŒ470ïŒ5.5ã瀺ãã äžèšç¬¬äºéšåã³ç¬¬äžéšã«ãããŠã¯ãåèŠæ§é å
äœ ïŒïŒ®âR1âïŒHCâR2âCHïŒ ããæãã¢ãŸã¡ãã³ïŒå ±ïŒéåäœã®ç¹ç¶ãçšã
ãã第äºéšã«ãããŠã¯éåäœã¯å®æœäŸ17ã§ã€ãã
ãããã®ã«çžåœããããå®æœäŸ24ã®äžè¬ç溶èé
åæ³ã«ãã€ãŠã€ãã€ãã第äžéšã«ãããŠã¯ãéå
äœã¯ç¬¬äºéšãšåæ§ã«ã€ãããããã溶液éåæ³ã«
ãã€ãŠã€ãã€ãã䜿çšããå ±éåäœãšç¹ç¶ã¯å®æœ
äŸ37ã®ãã®ã§ãã€ãã玡糞ã¯åè¿°ãšåãããã«è¡
ãªã€ãã 第äºéš ãã®åŠçã«ãããŠã¯çŽ¡ç³žããããªã¢ãŸç¹ç¶ãçª
çŽ é°å²æ°äžã«ãããŠè¡šèšã®æž©åºŠã«ãããŠ20ç§éå
äžããããã®åæéã®åŠçã«ããåŒåŒµç¹æ§ã¯èã
ãå¢åŒ·ãããã ãè¡šã 第äžéš ãã®åŠçã«ãããŠã¯çŽ¡ç³žæã®ã¢ãŸã¡ãã³ïŒå ±ïŒ
éåäœç¹ç¶ããã¢ã€ããŒã»ãã©ãã¯ã¹ã§è¢«èŠã
ãéå±ããã³ã«æ²ããçïŒçªçŽ é°å²æ°ïŒäžã§äžèš
ã«ç€ºã枩床ã§ïŒæéå ç±ãããè¡šã«ç€ºãããã«
䜿çšããåŠç枩床ã«ãããŠç¹ç¶ã®åŒåŒµç¹æ§ã¯èã
ãæ¹åãããã ãè¡šã å®æœäŸ 40 äžèšè¡šã®åèŠæ§é åäœãåŒãåŒã ã«çžåœããå åŠçç°æ¹æ§ã®æº¶èç©çæã¢ãŸã¡ãã³
ïŒå ±ïŒéåäœã瀺ãã ïŒå ±ïŒéåäœã¯æ°ããåæããïŒâã¢ãããã³
ãºã¢ã«ããããïŒâã¡ãã«âïŒâã¢ãããã³ãºã¢
ã«ããããåã³ïŒâã¡ãã«âïŒâã¢ãããã³ãºã¢
ã«ãããããéžã°ããåå¿åæã®æº¶èéåã«ãã
ã€ãã€ããé ç®ïŒãïŒã«å¯Ÿããå žåçæ¹æ³ã«ãã
ãŠã¯ãé©åœãªåéäœïŒå€«ã çŽ0.02ã¢ã«ïŒãæ¹æ
æ©ãèžçãããåã³çªçŽ å¹èŸŒç®¡ãåä»ããåå¿å®¹
åšäžã§ã¢ããªã³ïŒïŒmlïŒãšå ±ã«å ãããæ¹æãã
åå¿åæãçªçŽ äžã«ãããŠ250âã«ä¿ããã油济
äžã§0.5æéå ç±ããã次ã«çªçŽ ãæµãã®ãæ¢ãã
åå¿åæã1.0mmïœä»¥äžã®å§åã§250âã§0.5æ
éå ç±ïŒæ¹æïŒãããåå¿æ··åç©ãå·åŽããçæ
ç©ãæéããã¢ã»ãã³ã§æŽæµãã也ç¥ããã é ç®ïŒã®å ±éåäœã«å¯ŸããŠã¯ãåã¢ãããã³ãº
ã¢ã«ããã0.096ã¢ã«ãšã¡ãã«âïŒïŒïŒâããšã
ã¬ã³ãžã¢ãã³ïŒç²åºŠå®å®å€ãšããŠäœ¿çšïŒ0.0057ã¢
ã«ãšããã·ã¬ã³ïŒ350mlïŒåã³ããªãã«ãªãé ¢é ž
ïŒ0.25mlïŒãšäžç·ã«ãããåå¿æ··åç©ãïŒæéé
æµããïŒãã³ãŒã³âæ°Žå ±æ²žæ··åç©ãé€å»ããïŒã
å·åŽããå ±éåäœãçå¥ããã¢ã»ãã³ã§æŽæµãã
ç空也ç¥ãããå®æœäŸ13ã®ããã«ããŠå ±éåäœã®
æ£ã玡糞ãïŒçŽ¡ç³žå£é枩床ïŒ240âã溶èåºåæž©
床ïŒ232âïŒãç¹ç¶ã155ïœïŒåã§æ²åãã玡糞ã
ããŸãã®ç¹ç¶ã§ã¯ïŒŽïŒïŒ¥ïŒMiïŒ3.6ïŒ0.8ïŒ638ã§
ãã€ããç¹ç¶è©Šæãã¿ã«ã¯ã§åŠçãã次ãã§222
âã§163æéïŒN2ïŒã«ãããŠçäžã§å ç±ãããè©Š
æã¯é·ãïŒã€ã³ãïŒ15.2cmïŒã§ã¹ã¯ãªãŒã³äžã«æ¯
æãããŠãããå ç±åŠçããç¹ç¶ã¯ïŒŽïŒïŒ¥ïŒMi
ïŒ10.8ïŒ1.9ïŒ709ã§ãã€ãã ãè¡šã ãè¡šã
ã¯ãªãŒã¬ãã¯ïŒKwolekïŒã®ç±³åœç¹èš±ç¬¬3671542
å·ã®ããŒãã«å¯ŸããŠã¯å åŠçç°æ¹æ§ãç¥ãããŠã
ããããªãªã¬ãã€ã³æº¶èç©ã«å¯ŸããŠåœæ¥çã«ãã
ãŠæ¶²æ¶çæåãå ±åãããŠããã æç®ã«ã¯ããªã¢ãŸã¡ãã³ãåã¯ããªïŒã·ããå¡©
åºïŒããåºãèšèŒãããŠããããäŸãã°ããšã³ãµã€
ã¯ãããã€ã¢ã»ãªãŽã»ããªããŒã»ãµã€ãšã³ã¹ã»ã¢
ã³ãã»ãã¯ãããžãŒïŒEncyclopedia of
Polymer Science and TechnologyïŒã第10å·»
659ã670é ïŒ1960幎ïŒããžãŒã»ãšãã»ãã¬ãªãª
ïŒG.F.Dâ²AlelioïŒè ç±³åœããŠãŒãšãŒã¯ãã€ã³ã¿
ãŒãµã€ãšã³ã¹ã»ãããªãã·ã€ãŒãºïŒInterscience
PublishersïŒçºè¡åç §ãããŸãç±³åœç¹èš±ç¬¬3526611
å·åã³å第3418281å·ã®ãããªç¹èš±ã«ãèšèŒãã
ãŠããã é«æž©ãé«å§ã§æ圢å¯èœãªããªã¢ãŸã¡ãã³ã¯ç±³åœ
ç¹èš±ç¬¬3418281å·åã³è±åœç¹èš±ç¬¬1080526å·ã«èšèŒ
ãããŠããããããã®éåäœã¯è¯å¥œãªç±çå®å®æ§
ãšéæ§ãšããã€ãŠãããšäºãããŠãããåžè溶液
ãã泚圢å¯èœãåã¯é«æž©ãé«å§ã§ãã¬ã¹ãããã
ãªã¢ãŸã¡ãã³ã»ãã€ã«ã ã¯ããŒã«ãŒïŒBakerïŒã
ã®1974幎ïŒæïŒæ¥ä»T918005å·ãªãã·ã€ã«ã»ã¬ãŒ
ããïŒOffiâcial GazetteïŒïŒé²è¡åºçç©ïŒã«èš
èŒãããŠãããããããããã®åŸæ¥æ³ã®ã©ãã«ã
çŽæ¥æº¶èé²ç³žããŠãã€ã©ã¡ã³ãã«ããããšãã§ã
ãç°æ¹æ§æº¶èç©ãæçš®ã®è³éŠæããªã¢ãŸã¡ãã³ã
çæããããšã¯èšèŒãããŠããªãã æ¬çºæã«ããã°éåäœæº¶è枩床ã375âããäœ
ããåºæç²åºŠãå°ããšã0.2ã§ã溶èç¶æ ã«ãã
ãŠå åŠçç°æ¹æ§ã瀺ãè³éŠæåã³èç°åŒã®æ°èŠæº¶
è玡糞å¯èœãªããªã¢ãŸã¡ãã³åã³ã¢ãŸã¡ãã³å ±é
åäœãæäŸããããããã«æ¬çºæã«ããã°åŸã§å»¶
䌞ããããšãªããããã®éåäœãã玡糞ãããæ°
èŠæçšãªé åç¹ç¶ãæäŸããããå€ãã®çŽ¡ç³žãã
ãŸãã®ç¹ç¶ã¯å®è³ªçã«åŒç·©ããç¶æ ã§ãåã¯ãã³
ãšåŒµã€ãç¶æ ã§100â以äžã§ããããã®èç¹ä»¥äž
ã®æž©åºŠã«å ç±ãããšé åæ§ãšåŒ·åºŠãšãå¢å ãããŸ
ã屡ã ã¢ãžãŠã©ã¹ãå¢å ããããã®éåäœããä»
ã®æ圢äœãäŸãã°ãã€ã«ã åã³æ£ãã€ããããšã
ã§ããã æ¬çºæã«ããã°éåäœãäžèšåäœ () ïŒïŒïŒ®âR1âïŒïŒ () ãåŒã åã³ () ãåŒã äœãåäœåã³ã¯ããååšãããªãã°å®è³ªç
ã«çã¢ã«éã§ååšããZ1ïŒZ2åã³Z3ã¯åäžåã¯çž
ç°ãããšãã§ããæ°ŽçŽ ååãåã¯ã¡ãã«åã¯ãšã
ã«åºããéžã°ããR1ïŒR2åã³R3㯠(1) åäžåã¯èåããççŽ ç°åŒå å¡ç°ç³»ã§ãã€
ãŠãè³éŠæãããååšãããªãã°ãã®è³éŠç°ã®
ç°ççŽ ã®äžã€ã¯çªçŽ ã§çœ®æããããããšãã§
ãã該ç°ç³»ã®é£é䌞匵çµåã¯ã該çµåãããå
äžç°ã«çµåããŠãããªãã°äºãã«ïŒïŒïŒã®äœçœ®
ã«äœçœ®ããããç°ã€ãç°ã«çµåããŠãããªãã°
å¹³è¡ã§äžã€å察æ¹åã«åã€ãäœçœ®ã«äœçœ®ããå
äžããã³èåããççŽ ç°åŒå å¡ç°ç³»ã®åºããã³ (2) å€ç°ç³»ã§ãã€ãŠãåã ã®ç°ãååŠçµååã¯é·
ããååæ°14ãè¶ ããªãã奜ãŸããã¯ïŒãè¶ ã
ãªãæ¶æ©åäœã«ããçµåãããåç°ã®é£é䌞匵
çµåãïŒïŒïŒã®äœçœ®ã«ãããR1ã¯ååŠçµåã§
ããããšãã§ããå€ç°ç³»ã®åºããæã矀ããéž
ã°ããåºã§ããã ããéžã°ããåèŠæ§é åäœããå®è³ªçã«æãããš
ãç¹åŸŽãšããããªã¢ãŸã¡ãã³åã³ã¢ãŸã¡ãã³å ±é
åäœãæäŸã§ããã (1)ã®äŸã¯ãåŒããåŒã ãåŒããåŒããåŒãã§ã ãã (2)ã®äŸã¯ãåŒã ãåŒã ãåŒã ãåŒãåã³ ãåŒãã§ããã äžè¿°ã®ç°ç³»ã«ã¯ãŸãïŒååã¯ãã以äžã®çœ®æ
åºãäŸãã°äœçŽã¢ã«ãã«ïŒççŽ æ°ïŒãïŒïŒåã³ã¯
ããåºããã€ãã®ãå«ãŸããã ãŸãæ¬çºæã«ãããŠã¯ïŒåã³ã®åäœã®å š
äœã«å¯Ÿãæ倧40ã¢ã«ïŒ ã奜ãŸããã¯æ倧25ã¢ã«ïŒ
ããåè¿°ã®ïŒåã³ã®åäœãšåèŽããªããé
åäœã®å åŠçç°æ¹æ§ããã€æº¶èç©çæèœã劚害ã
ãªãããªã¢ãŸã¡ãã³çæåäœã«ãã€ãŠçœ®æããã
ãŠããããšãã§ããããããã®åäœã«ã¯æ¬¡ã®ãã®
ããããããã¯æ¬çºæãéå®ãããã®ã§ã¯ãªãã ãåŒãïŒïŒ®âïŒCH2ïŒ6âïŒïŒ ãåŒãåã³ ãåŒãäžè¿°ã®ããªã¢ãŸã¡ ãã³ïŒå ±ïŒéåäœã¯å®è³ªã«çã¢ã«éã®åäœåã³
ãå«ãã§ããããåã¯åäœããæããæãã¯
åäœïŒåã³ã®çµåããããæããå¿è«ïŒçš®
ãè¶ ããåäœïŒïŒåã³ïŒãéåäœäžã«ååš
ããããšãã§ãããäŸãã° ãåŒãåã³ãåŒãåäœã æ¬çºæã®å¥œé©ãªããªã¢ãŸã¡ãã³ïŒå ±ïŒéåäœã¯
å®è³ªçã«åäœåã³ããæã€ãŠããããã®ãã
ãªéåäœã«ãããŠã¯ãR1ã¯ã¯ããâãããã¢âã
ã¡ããã·âããã«ãªãâãã¡ãã«âãããããã·
âåã³ãããâïŒïŒïŒâããšãã¬ã³ïŒïŒïŒ4â²âã
ããšãã¬ã³ïŒïŒïŒ3â²âãžã¡ãã«âïŒïŒ4â²âãããš
ãã¬ã³ãïŒïŒïŒâããšãã¬ã³ïŒïŒïŒ4â²âã¡ãã¬ã³
ãžããšãã¬ã³ïŒïŒïŒ4â²âãžã¡ãã¬ã³ãžããšãã¬
ã³ïŒïŒïŒ4â²âããªã¡ãã¬ã³ãžããšãã¬ã³ïŒïŒïŒ
4â²âããã©ã¡ãã¬ã³ãžããšãã¬ã³ïŒïŒïŒïŒâãã
ãã¬ã³ïŒïŒïŒïŒâãããã¬ã³ïŒïŒïŒïŒâãžã¯ãã
âïŒïŒïŒâããšãã¬ã³ïŒãã©ã³ã¹âïŒïŒïŒâã·ã¯
ãããã·ã¬ã³ïŒãã©ã³ã¹âïŒâã¡ãã«âïŒïŒïŒâ
ã·ã¯ãããã·ã¬ã³ïŒãã©ã³ã¹âïŒïŒ4â²âã¡ãã¬ã³
ãžã·ã¯ãããã·ã¬ã³ïŒïŒïŒ3â²âãžã¡ãã«âïŒïŒ
4â²âããã©ã¡ãã¬ã³ãžãªãã·ãžããšãã¬ã³ïŒïŒïŒ
4â²âã¢ãŸãã·ãžããšãã¬ã³ïŒïŒïŒ3â²âãžã¡ãã«â
ïŒïŒ4â²âã¢ãŸãžããšãã¬ã³åã³åçµåããæã矀
ããéžã°ãïŒR2ã¯ïŒïŒïŒâããšãã¬ã³ïŒã¯ãã
âïŒïŒïŒâããšãã¬ã³ïŒã¡ãã«âïŒïŒïŒâããšã
ã¬ã³ïŒïŒïŒ4â²âãããšãã¬ã³ïŒïŒïŒ4â²âãªãã·ãž
ããšãã¬ã³ïŒïŒïŒ4â²âãšãã¬ã³ãžããšãã¬ã³ïŒ
ïŒïŒ4â²âã¡ãã¬ã³ãžããšãã¬ã³ïŒïŒïŒ4â²âãšãã¬
ã³ãžãªãã·ãžããšãã¬ã³ïŒïŒïŒïŒâããªãžããã€
ã«ïŒïŒïŒïŒâãããã¬ã³ïŒïŒïŒïŒâãããã¬ã³ïŒ
ïŒïŒïŒâãããã¬ã³ïŒïŒïŒïŒâãžã¯ããâïŒïŒïŒ
âããšãã¬ã³ïŒïŒïŒïŒâãžããã¢âïŒïŒïŒâããš
ãã¬ã³ïŒïŒïŒïŒâãžã¡ããã·âïŒïŒïŒâããšãã¬
ã³ïŒïŒâããã¢âïŒïŒïŒâããšãã¬ã³ïŒïŒâã¡ã
ãã·âïŒïŒïŒâããšãã¬ã³ïŒåã³ïŒâããããã·
âïŒïŒïŒâããšãã¬ã³åºããæã矀ããéžã°ã
ããããã«å¥œãŸããã¯ãã®ãããªåäœåã³ã®
ç°ç³»ã®å šæ°ã®å°ããšã25ïŒ ã¯ãè¯å¥œã®å å·¥æ§å
ã³ïŒåã¯ããã«äŒŽãè¯å¥œãªå®å®æ§ã®ããã«ãã¯ã
ãåã³ã¡ãã«åºããæã矀ããéžã°ããåºã§ç°ã«
眮æãããŠããã åäœã®ã¿ãååšããå Žåãæãã¯åäœåã³
ãšäžç·ã«ååšããå Žåã«ã¯ãR3ã¯ïŒïŒïŒâã
ãšãã¬ã³ãã¡ãã«âïŒïŒïŒâããšãã¬ã³ãïŒïŒ
4â²âãªãã·ãžããšãã¬ã³ãïŒïŒïŒâãããã¬ã³ã
ïŒïŒïŒâãããã¬ã³åã³ã¯ããâïŒïŒïŒâããšã
ã¬ã³åºããæã矀ããéžã°ããããšã奜ãŸããã éåäœãå®è³ªçã«åäœããæã€ãŠããããå
ã¯ïŒãåã³ã®åäœã®çµåããããæã€ãŠã
ãå Žåããã®ãããªåäœã®ç°ç³»ã®å šæ°ã®å°ãªããš
ã25ïŒ ã¯ã¯ããåã³ã¡ãã«åºããæã矀ããéžã°
ããåºãç°ã«çœ®æããŠããããšã奜ãŸããã 奜é©ãªéåäœã¯(1)è¯å¥œãªåŠçæ§ã®ããã«ã¯ã¡ã
ã«âïŒïŒïŒâããšãã¬ã³ãžã¢ãã³åã³ãã¬ãã¿ã«
ã¢ã«ãããããã€ãããããã®ã§ããã(2)ç¹ç¶ã¯
ç¹ã«é«åŒ·åºŠã§ããããã¡ãã«âïŒïŒïŒâããšãã¬
ã³ãžã¢ãã³ãïŒïŒïŒâããšãã¬ã³ãžã¢ãã³åã³ã
ã¬ãã¿ã«ã¢ã«ãããããã€ãããããã®ã§ããã
ãŸã(3)è¯å¥œãªå æ°Žå解èæ§ããã€ãé«çµæ¶æ§ç¹ç¶
ãã€ããããã«ãã¹ïŒïŒâã¢ããããšãã«ïŒãšã¿
ã³åã³ã¯ãããã¬ãã¿ã«ã¢ã«ãããããã€ããã
ããã®ã§ããã æ¬çºæã®ã¢ãŸã¡ãã³ïŒå ±ïŒéåäœã¯å åŠçã«ç°
æ¹æ§ã®ãã溶èç©ãçæãã375â以äžã奜ãŸã
ãã¯350â以äžã§æº¶èããç¹ç¶åã³ä»ã®æ圢åãž
ã®å å·¥æ§ãäžãããã®ã§ãªããã°ãªããªãããã
ãããé«ã枩床ã§ã¯ãã®æ§é ã«äŸåããŠããªã¢ãŸ
ã¡ãã³ïŒå ±ïŒéåäœã®è¿ éãªå解ãèµ·ãããã®æº¶
èç©ã¯å¹³è¡ã«äžŠãã éåéã®é åãæ§æãããã
ã玡糞工çšã«ãããŠçŽ¡ç³žããç¶æ ã§é åããç¹ç¶
ãçãããã®ãšä¿¡ããããã æ¬çºæã®ããªã¢ãŸã¡ãã³ïŒå ±ïŒéåäœã¯æº¶è玡
糞å¯èœã§ãããã溶è玡糞å¯èœããšã¯æº¶è玡糞ã
ãããšãã§ãããã€ã©ã¡ã³ãã玡糞ããã®ã«å¿ èŠ
ãªæéã®é溶èç¶æ ãä¿æãåŸãããšãæå³ã
ããä»ã®ããªã¢ãŸã¡ãã³ïŒå ±ïŒéåäœã¯æº¶èããª
ããããã«ä»ã®ãã®ã¯é«æž©ã«ãããŠç¬éçã«è»å
åã¯æµåããããã«èŠãã次ã«ç¡¬åããŠäžæº¶èæ§
ç©è³ªã«ãªããããã¯ããã«è¿ éãªéåã«ãããã®
ãšä¿¡ãããããæ¬çºæã®æº¶è玡糞å¯èœéåäœã¯å°
ããšãïŒåé溶èç¶æ ã«ä¿æããåŸãã æ¬çºæã®ããªã¢ãŸã¡ãã³ïŒå ±ïŒéåäœã¯åŒ H2NâR1âNH2 ã®ãžã¢ãã³ãåŒãåŒãã®ãžã¢ã«ããã åã¯ãžã±ãã³ãåã³ïŒåã¯åŒãåŒãã® ã¢ããã¢ã«ãããåã¯ã¢ããã±ãã³ãåã¯ãã®ã
ããªåæã®å®èœåºçã«åçãªèªå°äœãšåå¿ããã
ããšã«ããã€ãããããããã§ãR1ïŒR2åã³R3
㯠(1) åäžåã¯èåããççŽ ç°åŒå å¡ç°ç³»ã§ãã€
ãŠãè³éŠç°ãããååšãããªãã°ãã®è³éŠç°ã®
ç°ççŽ ã®äžã€ã¯çªçŽ ã§çœ®æããããããšãã§
ãã該ç°ç³»ã®é£é䌞匵çµåã¯ã該çµåãããå
äžç°ã«çµåããŠãããªãã°äºãã«ïŒïŒïŒã®äœçœ®
ã«äœçœ®ããããç°ã€ãç°ã«çµåããŠãããªãã°
å¹³è¡ã§äžã€å察æ¹åã«åã€ãäœçœ®ã«äœçœ®ããå
äžããã³èåããççŽ ç°åŒå å¡ç°ç³»ã®åºããã³ (2) å€ç°ç³»ã奜ãŸããã¯ççŽ ç°åŒå€ç°ç³»ã§ãã€
ãŠãåã ã®ç°ãååŠçµååã¯é·ããååæ°14ã
è¶ ããªãã奜ãŸããã¯ïŒãè¶ ããªãæ¶æ©åäœã«
ããçµåãããåç°ã®é£é䌞匵çµåãïŒïŒïŒã®
äœçœ®ã«ãããR1ã¯ååŠçµåã§ããããšãã§ã
ãå€ç°ç³»ã®åº ããæã矀ããéžã°ããåºã§ãããZ1ïŒZ2ïŒåã³
Z3ã¯æ°ŽçŽ åååã¯ã¡ãã«åã¯ãšãã«åºããæã矀
ããéžã°ãããã®ãšããã æ¬çºæã®éåäœãã€ããã®ã«æçšãªãžã¢ãã³ã¯
åŒH2NâR1âNH2ã«å¯Ÿå¿ãããäœãR1ã¯åè¿°ã®
æå³ãæããããžã¢ãã³ã®äžã«ã¯ïŒïŒïŒâããšã
ã¬ã³ãžã¢ãã³ãã¯ããâïŒïŒïŒâããšãã¬ã³ãžã¢
ãã³ãããã¢âïŒïŒïŒâããšãã¬ã³ãžã¢ãã³ãã
ã«ãªãâïŒïŒïŒâããšãã¬ã³ãžã¢ãã³ãã¡ãã«â
ïŒïŒïŒâããšãã¬ã³ãžã¢ãã³ãã¡ããã·âïŒïŒïŒ
âããšãã¬ã³ãžã¢ãã³ããããâïŒïŒïŒâããšã
ã¬ã³ãžã¢ãã³ãïŒïŒïŒâãžã¯ããâïŒïŒïŒâããš
ãã¬ã³ãžã¢ãã³ãïŒïŒ4â²âãžã¢ãããããšãã«ã
ïŒïŒ3â²âãžã¡ãã«âïŒïŒ4â²âãžã¢ãããããšã
ã«ããã¹ïŒïŒâã¢ããããšãã«ïŒãšã¿ã³ãïŒïŒïŒ
âãã¹ïŒïŒâã¢ããããšãã«ïŒãããã³ãïŒïŒïŒ
âãã¹ïŒïŒâã¢ããããšãã«ïŒãã¿ã³ãïŒïŒïŒâ
ããã¿ã¬ã³ãžã¢ãã³ããã©ã³ã¹âïŒïŒïŒâã·ã¯ã
ãããµã³ãžã¢ãã³ãïŒâã¡ãã«âãã©ã³ã¹âïŒïŒ
ïŒâã·ã¯ããããµã³ãžã¢ãã³ããã¹ïŒãã©ã³ã¹â
ïŒâã¢ããã·ã¯ãããã·ã«ïŒã¡ã¿ã³ãããã©ãžã³
çãå«ãŸããããžã¢ãã³ã¯åå¿äžã«äžåå€ãäŸã
ã°çé žãªããŠã ãçšããããšã«ããå¡©ã®åœ¢ïŒäŸã
ã°äºå¡©é žå¡©ïŒã§çšããããšãã§ããã æ¬çºæã®éåäœãã€ããã®ã«æçšãªãžã¢ã«ãã
ãåã³ãžã±ãã³ã¯åŒãåŒãã«å¯Ÿå¿ã ããè²ã§R2ïŒZ1ïŒZ2ã¯åè¿°ã®å®çŸ©ã®éãã§ããã
ãããã®ãã®ã®äžã«ã¯ïŒïŒïŒâãžã¢ã»ãã«ãã³ãŒ
ã³ãïŒïŒ4â²âãžã¢ã»ãã«ãããšãã«ããã¬ãã¿ã«
ã¢ã«ããããã¯ãããã¬ãã¿ã«ã¢ã«ããããã¡ã
ã«ãã¬ãã¿ã«ã¢ã«ããããïŒïŒïŒâãžããªã«ãã«
ããªãžã³ãïŒïŒ4â²âãžããªã«ãã«ãããšãã«ã
ïŒïŒïŒâãžããªã«ãã«ããã¿ã¬ã³ãïŒïŒïŒâãžã
ãªã«ãã«ããã¿ãªã³ãïŒïŒïŒâãžããªã«ãã«ãã
ã¿ãªã³ããã¹ïŒïŒâããªã«ãã«ããšãã«ïŒã¡ã¿
ã³ããã¹ïŒïŒâããªã«ãã«ããšãã«ïŒãšã¿ã³ãã
ã¹ïŒïŒâããªã«ãã«ããšãã«ïŒãšãŒãã«ãïŒïŒïŒ
âãã¹ïŒïŒâããªã«ãã«ããšããã·ïŒãšã¿ã³ã
ïŒïŒïŒâãžã¯ãããã¬ãã¿ã«ã¢ã«ããããïŒïŒïŒ
âãžããã¢ãã¬ãã¿ã«ã¢ã«ããããïŒïŒïŒâãžã¡
ããã·ãã¬ãã¿ã«ã¢ã«ããããïŒâããã¢ãã¬ã
ã¿ã«ã¢ã«ããããïŒâã¡ããã·ãã¬ãã¿ã«ã¢ã«ã
ãããïŒâããããã·ãã¬ãã¿ã«ã¢ã«ãããçã
å«ãŸããã æ¬çºæã®éåäœãã€ããã®ã«æçšãªã¢ããã¢ã«
ãããåã³ã¢ããã±ãã³ã¯åŒãåŒã㫠察å¿ãããè²ã«Z3åã³R3ã¯åè¿°ã®æå³ãæããã
ãããã®äžã«ã¯ïŒâã¢ããâïŒâã¯ãããã³ãºã¢
ã«ããããïŒâã¢ããâïŒâãã«ãªããã³ãºã¢ã«
ããããïŒâã¢ããâïŒâã¡ãã«ãã³ãºã¢ã«ãã
ããïŒâã¢ããâïŒâã¯ããã¢ã»ãããšãã³ãïŒ
âã¢ããâïŒâãã«ãªãã¢ã»ãããšãã³ãåã³ïŒ
âã¢ããâïŒâã¡ãã«ã¢ã»ãããšãã³çãå«ãŸã
ãã ãããã®åæã®çµåããããã¹ãŠç°æ¹æ§æº¶èç©
ãçããããã§ã¯ãªããèç¹ã375â以äžã®éå
äœãçãããããªåæã®çµåããã¯é¿ããªããã°
ãªããªãããšããã®ã¯é«èç¹çæç©ã¯å å·¥ïŒäŸã
ã°çŽ¡ç³žããŠæçšãªç¹ç¶ã«ããïŒãå°é£ã ããã§ã
ãã çµåãã®åæããã€ããããéåäœã¯ç¬éçã«
è»åããåŸéåããŠé溶èæ§ã®åºäœã«ãªããå åŠ
çç°æ¹æ§ã芳枬ãããããšããªãããã«æãã
ãããã®ãããªéåäœã¯æ¬çºæã®ç¯å²å€ã§ããã
溶è玡糞ã§ããªãã®ã§çšéãéå®ããããããã
ãã®ãããªéåäœãã€ããéçšã«ãããŠæ«ç«¯å°é
å€åã¯é£éåæ¢å€ãçšãããšãåŸãããçæç©ã¯
溶èç©ã§å åŠçç°æ¹æ§ã瀺ãæ«ç«¯ãå°éãããé
åäœã§ãããæ¬çºæã«ã¯éåäžæ«ç«¯å°éå€ãå ã
ãŠéåäœã®æ«ç«¯ãå°éãããŠãããåŠãã«æã
ããå åŠçç°æ¹æ§æº¶èç©ãçããããªã¢ãŸã¡ãã³
ïŒå ±ïŒéåäœã®ã¿ãå«ããã®ãšããã æ¬çºæã®ïŒå ±ïŒéåäœã¯ç¹ç¶çææ§ã瀺ãã®ã«
ååãªååéãæããŠãããïŒå ±ïŒéåäœã®ãã
ãã®ã¯åºæç²åºŠã枬å®ããã®ã«çšãããã溶åªäž
ã«äžæº¶ã§ããããšãã§ããããããã®ïŒå ±ïŒéå
äœãåã³åŸè¿°ã®æ¹æ³ã«ãã枬å®ãããåºæç²åºŠã
å°ããšã0.2ã奜ãŸããã¯å°ããšã1.0ã®ãã®ãã
è¯å¥œãªç¹ç¶åã³ãã€ã«ã ãåŸãããã éåäœã®èç¹ã¯æçšåºŠåºæç²åºŠã«äŸåãããå³
ã¡åºæç²åºŠã®äœãéåäœã¯é«ããã®ããäœã枩床
ã§æº¶èããã éåæ¡ä»¶ ããªã¢ãŸã¡ãã³åã³ãã®å ±éåäœã¯é©åœãªåé
äœãããç±éåã奜ãŸããã¯äžæŽ»æ§é°å²æ°äžã§ç¡
æ°Žæ¡ä»¶äžã§éåãããããšã«ããã€ããããšãã§
ãããäŸãã°åæã®ãžã¢ãã³ãšãžã¢ã«ãããïŒå
ã¯ãã®èªå°äœãäŸãã°ãžã¢ã»ã¿ãŒã«ïŒã®åéãå
å¿å®¹åšäžã§äžç·ã«ããã容åšã®å 容ç©ãæ¹æå ç±
ãããã®éå 容ç©ãçªçŽ äžã«ä¿ã€ãåå¿åæãé
åããã«ã€ããŠãå¯æç©ïŒäŸãã°æ°Žåã¯ã¢ã«ã³ãŒ
ã«ïŒãé€å»ãããéåãææã®ç¹ãŸã§é²è¡ãã
ãšãéåäœãååºããŠç²Ÿè£œããã溶èããå Žåã
éæéåäœãçŽæ¥é©åœãªå®¹åšãäŸãã°ç¹ç¶çŽ¡ç³žè£
眮ã«ç§»ããæ圢åãã€ããã å¯æç©ãšå ±æ²žæ··åç©ãã€ãããå¯æç©ãé€å»ã
ãã®ã«åœ¹ç«ã€æº¶åªïŒäŸãã°ãã³ãŒã³ïŒäžã«åå¿å
æã溶ãããéåå®äºåŸãæ²æŸ±ããçæç©ãå¥
ãã溶解ããçæç©ãåé¢ããæ®ãã®æº¶åªãèžçº
ãããã æ¬çºæã®ïŒå ±ïŒéåäœã¯ãŸã極æ§æº¶åªãçšãã
äœæž©éåæ³ã«ããã€ããããšãã§ãããäžã€ã®äŸ¿
å©ãªæ¹æ³ã§ã¯ãžã¢ãã³ãäŸãã°ïŒ®ïŒïŒ®âãžã¡ãã«
ã¢ã»ãã¢ããïŒDMAcïŒãâã¡ãã«ãããªãã³
âïŒïŒNMPïŒããããµã¡ãã«ããªã¹ããªã«ã¢ãã
ïŒHMPAïŒåã¯ãã®æ··åç©ããæã矀ããéžã°ã
ã極æ§ã¢ãã³æº¶åªäžã«å¡©åãªããŠã ãå«ãŸããŠæº¶
解ããããžã¢ã«ããããå ããåå¿æ··åç©ãæ¹æ
ãããæ°æéãªããæ°æ¥éåå¿ãé²è¡ãããã次
ã«åå¿æ··åç©ãé溶åªïŒäŸãã°æ°ŽïŒãšäžç·ã«ãã
æéããååã«æŽæµãïŒäŸãã°æ°ŽããšãŒãã«ãã¡
ã¿ããŒã«ã§ïŒã也ç¥ããåŸå å·¥ããã 次ã®å å·¥ã容æã«ããããã«ããããã®éåäž
æ«ç«¯å°éå€ãåã¯é£éåæ¢å€ãçšããããšãæå©
ã§ãããã¢ããªã³ãïŒâã«ã«ããã·ãã³ãºã¢ã«ã
ãããïŒâã¢ããã¢ã»ãã¢ããªããïŒâã¢ããâ
ïŒâã¡ãã«å®æ¯éŠé žããã³ãºã¢ã«ããããåã³å¡©
åãã³ãŸã€ã«ããããã®åæ¢å€ã«å«ãŸãããå¡©å
ãã³ãŸã€ã«ãçšãããšæºè¶³ãã¹ãçµæãåŸããã
ããäžè¬ã«é±é žãçããè©Šè¬ã¯éåäœãå£åãã
ãããã«äžè¬ã«ã¯é¿ããã¹ãã§ããããããã®å
æ¢å€ã¯æº¶è玡糞äžã«ãããŠéåäœã®ååéã®å¢å
ãæå¶ãããæå°éã«ããã®ã«åœ¹ã«ç«ã€ãäŸãã°
玡糞äžããã«éåãèµ·ãååéãé«ããªãããã
å Žåã«ã¯ã玡糞æäœã«ããäœå質ã®ç¹ç¶ãçãã
ããåã¯äžæããããç¹ç¶ã®åœ¢ã§ç±åŠçãè¡ãªã
å ŽåãæçšåºŠé£éãçé·ããããšãæãŸããã
ãããã以äžã®éåãå®å šã«çŠæ¢ããé£éåæ¢ã¯
é¿ããªããã°ãªããªãã å¿ èŠã«å¿ãä»ã®è©Šè¬ãçšããããšãªãæ«ç«¯ã®å°
éãè¡ãªãããšãã§ãããäŸãã°åå¿åæã®ïŒçš®
ãéå°ã«ïŒååŠéè«çãªé以äžã«ïŒçšãããŸãé
å°ã®åå¿åæãè¿ éã«æ倱ããã®ãé²ãä»ã®æ©æ§
åã¯ééç³»ãçšããã°ãããã¯æ«ç«¯å°éå€ãšããŠ
äœçšããããã®æ¹æ³ã¯ä»ã®éåäœã«ã€ããŠã¯ãªã©
ã³ããã¢ã ã¹ãã«ãã ããšã«ã»ãŽã€ã€
ïŒElsevierïŒåºç瀟1953幎çºè¡ã¢ãŒã«ã»ãã«ïŒR.
HillïŒèãåæéåäœç¹ç¶ïŒFibers from
SyntheticPolymersïŒã106ã107é èšèŒã®ããã«
å ¬ç¥ã§ãããç±çã«å®å®ãªé žåé²æ¢å€ãåå¿æ··å
ç©ã«å ãããšãåŸã®å å·¥ã«æçšãªåœ¹ç®ãæãã ç°æ¹æ§æº¶èç© æ¬çºæã®ããªã¢ãŸã¡ãã³åã³ãã®å ±éåäœã®æº¶
èç¶æ ã«ãããå åŠçç°æ¹æ§ã®ããã«ããããã®
溶èç©ããã€ããããç¹ç¶ã¯é åã匷床åã³åæ
ã¢ãžãŠã©ã¹ãé«ããªãããããã®ç¹ç¶ã®ãããã®
ã§ã¯å®è³ªçã«åŒç·©ããç¶æ åã¯ç·åŒµããç¶æ ã«ã
ããŠç±åŠçã«ãã匷床ãå¢å ãããã ããªã¢ãŸã¡ãã³ïŒå ±ïŒéåäœæº¶èç©ã®å åŠçç°
æ¹æ§ã¯å ¬ç¥æ¹æ³ãå ãã«å€åœ¢ããæ¹æ³ã§æ±ºå®ãã
ããåéæã®å åŠçã«ç°æ¹æ§ããã€ææã¯äº€åå
ååãåä»ããå åŠç³»ã§ã¯å ãééããããçæ¹
æ§ã®ææã«å¯ŸããŠã¯å ã®ééã¯çè«çã«ïŒã§ãã
ããšãç¥ãããŠããããäŸãã°ãšã¹ã»ãšãŒã»ãžã€
ããªã³ïŒS.A.JabarinïŒåã³ã¢ãŒã«ã»ãšã¹ã»ã¹ã
ã€ã³ïŒR.S.SteinïŒã®ãžã€ãŒãã«ã»ãªãŽã»ãã€ãž
ã«ã«ã»ã±ãã¹ããªãŒïŒJ.Phys.Chem.ïŒ77ïŒ399
ïŒ1973ïŒåç §ããæ¬çºæã®ç°æ¹æ§æº¶èç©ã¯åè ã®æ
åã瀺ããäžèšã«ç€ºãç±å åŠçè©ŠéšïŒTOTïŒã«
ãããã®ç¹åŸŽãçšããŠæº¶èç©ãåå®ãããè£ çœ®
ã¯ãã¢ã€ã»ã«ãŒã·ãšã³ããŠã ïŒI.KirshenbaumïŒã
ã¢ãŒã«ã»ããŒã»ã€ãµã¯ãœã³ïŒR.B.IsaacsonïŒãå
ã³ããŽãªãŠãŒã»ã·ãŒã»ããšã€ã¹ãïŒW.C.FeistïŒ
ã®ããªããŒã»ã¬ã¿ãŒãºïŒPolymer LettersïŒèª
ïŒïŒ897ã901ïŒ1964ïŒèšèŒã®è£ 眮ãšåæ§ã§ããã æ圢åã®è£œé æ¬çºæã®ããªã¢ãŸã¡ãã³ïŒå ±ïŒéåäœã¯æ圢
åãäŸãã°ç¹ç¶ããã€ã«ã ãæ£ãåã¯ä»ã®æ圢å
ã¯ãäŸãã°ãã®ç°æ¹æ§æº¶èç©ããã¬ã¹ã玡糞ã泚
圢ãåã¯æŒåºãããšã«ããã€ããããšãã§ããã
åœæ¥çã®å°é家ã¯æ圢åã®ææã®æ§è³ªãåŸããã
ã®åçš®ã®ç°æ¹æ§æº¶èç©ã®ç¯å²å ã«ãããæé©å å·¥
枩床ã容æã«æ±ºå®ããããšãã§ãããç±å解åã¯
çæ¹æ§æº¶èç©ã®çæïŒå³ã¡é床ã®é«æž©ã«å ç±ãã
ããšã«ããïŒãçããããã«æ³šæããªããã°ãªã
ãªãã æ¬çºæã®é«åºŠã«é åãã匷ãç¹ç¶ã¯åè¿°ã®ããª
ã¢ãŸã¡ãã³ïŒå ±ïŒéåäœããã€ãããããç¹ç¶ã
ã€ããããã«ã¯ãïŒå ±ïŒéåäœçææåã®æº¶èé
åã«ããçŽæ¥åŸãããããåã¯ïŒå ±ïŒéåäœã®æ£
åã¯ãããã¯ã溶èããŠåŸããã溶èéåäœã®å¡
ããäŸãã°æº¶èçŽ¡ç³žè£ çœ®ãéããŠçŽ¡ç³žå£éããæ¥
å·é°å²æ°ïŒäŸãã°å®€æž©ã«ä¿ããã空æ°ïŒäžã«æŒåº
ããæ²åãããšã«ããå å·¥ãããæ¬æ现æžã«ãã
ãŠã玡糞ãããŸãã®ç¹ç¶ããšã¯æŒåºããŠéåžžã®æ²
åããããåŸã«å»¶äŒžã䌞匵åã¯çŒçŽãããªãç¹ç¶
ãæå³ãããäºå®ç°æ¹æ§æº¶èç©ã®ã玡糞ãããŸã
ã®ç¹ç¶ãã¯éåžžã®æå³ã«ãããŠãå³ã¡100ïŒ åã¯
ãã以äžå»¶äŒžããããšã¯ã§ããªãã ç¹ç¶ã¯åäžåã¯å€å玡糞å£éããã€ããããšã
䟿å©ã§ããã溶è玡糞ã»ã«ã«ãããŠã¯æº¶èåºåå
ã³çŽ¡ç³žå£éã§ä¿æãããã¹ã枩床ã¯å¿è«çŽ¡ç³žãã¹
ãéåäœã«äŸåãããç±ã¯çŽ¡ç³žå£éåã³ãã®çäž
ã®çã溶èåºåã«ãããããšã奜ãŸãããããã«
ãã€ãŠåºæç²åºŠãäœãä¿ã¡çŽ¡ç³žã容æã«ããããš
ãã§ãããéã¹ã¯ãªãŒã³ãšãã€ã¹ã¯ã玡糞å£é
ããã¯ã«çšããããšãã§ããã玡糞å£éãé¢ãã
ç¹ç¶ã®æ¥å·çšåªè³ªãšããŠã¯ç©ºæ°åã¯çªçŽ ãçšãã
ããšãã§ããã玡糞ãããŸãã®ç¹ç¶ã¯çš®ã ã®é床
ïŒWUSïŒãäŸãã°90ïœïŒå以äžãªãã1200ïœïŒå
以äžã®é床ã§æ²åãããšãã§ããã玡糞䌞匵å å
ã¯çŽ¡ç³žå£éã®åã®å€§ãããæŒåºé床ãåã³æ²åé
床ã«ããå€åããäžè¬ã«ã¯ïŒä»¥äžã§ãããå¿ èŠã«
å¿ã玡糞ãããŸãã®ç¹ç¶ã«ä»äžå€ãã€ããããšã
ã§ããã ãã€ã«ã ã¯éåžžã®æº¶èãã¬ã¹æ³ã«ããã€ããã
ãšãã§ããæ圢åã¯æŒåºè£œåãäŸãã°æ£ã¯éåžžã®
æ¹æ³ã§ã€ããããšãã§ããã ç¹ç¶ããã€ã«ã ãæ£ããã®æ§è³ªãç±åŠçåã³çšé æ¬çºæã®çŽ¡ç³žãããŸãã®ç¹ç¶ã¯é«åºŠã«é åããŠ
ãããããã¯äŸãã°ïŒžç·é åè§ãçŽ45ã以äžã§ã
ãããšã«ãã€ãŠç€ºããããããã«åŒåŒµç¹æ§åã³ä»
ã®æ§è³ªãæãŸããæ§è³ªãæããŠãããäŸãã°å€ã
ã®çŽ¡ç³žãããŸãã®ç¹ç¶ã¯åŒ·åºŠãå°ããšãçŽ40gpd
ã§åæã¢ãžãŠã©ã¹ã¯400gpd以äžïŒå±¡ã 500gpd以
äžïŒã§ããã æ¬çºæã®ç¹ç¶ã¯ç¹ç¶åŒ·åãã©ã¹ããã¯åã³ä»ã®
å·¥æ¥ççšéã«çšããããã ãã®ãããªçšéã®ãããã®ã«ãããŠã¯ãç¹ç¶ã¯
å¡©åºæ§åªè³ªåã¯é«æž©ã«é²åºããããäŸãã°åŒ·åæš¹
èã¯å±¡ã å¡©åºæ§è§ŠåªãçšããŠç¡¬åããããŽã é å
æåã¯äžè¬ã«ææ©ã¢ãã³ãå«ã¿ã硬åã¯ããªãã®
æéé«æž©ã§è¡ãªãããããšãå€ããæ¬çºæã®ç¹ç¶
ã¯äžè¬ã«äžè¿°ã®æ¡ä»¶ã«æµææ§ããããã¢ã«ããªãª
ã³ãæ°Žé žåãããªãŠã ããŽã åã¯å ç±ã«ããèå
ãããåŸç¹ç¶ã¯è¯å¥œãªåŒ·åºŠã®ä¿ææ§ã瀺ãã æ¬çºæã®çŽ¡ç³žãããŸãã®ç¹ç¶ã¯å ç±åŠçæäœã«
ä»ããŠäŸãã°ãã€ã€ã®è£åŒ·ã«æçšãªéåžžã«é«ãåŒ
匵ç¹æ§ããã€æ¬çºæã®ç±åŠçç¹ç¶ãã€ããããšã
ã§ãããé©ãã¹ãããšã«ã¯ãå®è³ªçã«åŒç·©ããç¶
æ ã§ãäŸãã°ã¹ã±ã€ã³ã§ãåã¯è»ãã被èŠããã
ããã€ããŒã»ãã©ãã¯ã¹ïŒFibcrâFraxïŒããã
ã³ã«å·»ããŠãæãã¯ç·åŒµããç¶æ ã§ãäŸãã°ãã
ãããã³äžã§çŽ100â以äžãç¹ç¶ã®èç¹ä»¥äžïŒå¥œ
ãŸããã¯èç¹ãã20âäœã枩床以å ã§ïŒç¹ç¶ãç±
åŠçãããšãéåžžååéã®ç®å®ãšãªãåºæç²åºŠã®
å¢å ãçãããç±åŠçã«ããåºæç²åºŠãå¢å ãã
ç¹ç¶ã¯åŒ·åºŠãå¢å ããããšãèŠåºããããç±åŠç
ã®æž©åºŠåã³æéã¯åºæç²åºŠãå¢å ããããã«éžã°
ãããå ç±æž©åºŠã¯ãã€ã©ã¡ã³ãéã®èåãå®è³ªç
ã«èµ·ã枩床以äžã«ä¿ã€ããšã奜ãŸãããå®çšçãª
ç®çã®ããã«ã¯ã匷床ãå¢å ãããã®ã«ååãªã§
ããã§ãçãæéã®éå ç±ãè¡ãªããéåäœã«ã
ã€ãŠæäœïŒç§éãªããäžè¬çã«ã¯å°ãªããšã1/2
ã24æéåã¯ãã以äžã®å ç±æéãçšãããéåžž
ïŒæé以äžå ç±ããŠããã以äžã®æ¹åã¯åŸãããª
ããå ç±åŠçã¯ç¹ç¶ã«æªåœ±é¿ãåãŒããªãäžæŽ»æ§
é°å²æ°äžã«ãããŠè¡ãªããªããã°ãªããªããçªçŽ
ã¯ãã®ç®çã«å šãé©ããŠããã匷床ãå°ããšã
10gpdã®ç¹ç¶ã奜ãŸãããæ¬çºæã®å€ãã®çŽ¡ç³žã
ããŸãã®ç¹ç¶ãç±åŠçãããšãã®æ°Žæºã®åŒ·åºŠãåŸ
ããããå ç±åŠçããç¹ç¶ã§ã¯ïŒžç·é åè§ã§æž¬å®
ãããé åã®å¢å ãèªãããããæ¬çºæã®å¥œé©ãª
å ç±åŠçããç¹ç¶ã¯ã¢ãžãŠã©ã¹ãå°ããšã
150gpdã䌞ã³ãïŒïŒ 以äžãé åè§ã¯45ã以äžã§ã
ããèç¹ã¯175â以äžã奜ãŸããã¯250â以äžã§ã
ãã 枬å®æ³åã³è©Šéšæ³ ç·é åè§ïŒæ¬æ现æžã§å ±åãããç·é åè§
ïŒO.A.ïŒã¯ã¯ãªãŒã¬ãã¯ïŒKwolekïŒã®ç±³åœç¹èš±
第3671542å·æ¹æ³ïŒã®æ¹æ³ã«ããåŸãããã åºæç²åºŠïŒ åºæç²åºŠïŒÎ·inhïŒã¯åŒ ηinhïŒïŒÎ·relïŒïŒ£ïŒ ã§å®çŸ©ããããηrelã¯çžå¯Ÿç²åºŠã§ãããã¯æº¶åª
100mlã«éåäœ0.5ïœãå«ãæ¿åºŠã§ãããçžå¯Ÿç²åºŠ
ηrelã¯éåäœåžè溶液ã®æ¯çŽ°ç®¡ç²åºŠèšäžã«ããã
æµäžæéãçŽæº¶åªã®æµäžæéã§å²ãããšã«ãã€ãŠ
åŸããããç¹èšããªãéãηrelã決å®ããããã«
çšããããåžè溶液ã¯äžèš(C)ã«ãã€ãŠè¡šãããã
æ¿åºŠã®æº¶æ¶²ã§ãããæµäžæéã¯30âã§æ±ºå®ãã
ãã溶åªã¯æ¿ç¡«é žïŒ98ïŒ H2SO4ïŒã§ãããä»ã®
溶åªïŒäŸãã°ã¡ã¿ã³ã¹ã«ããªã³é žïŒãç¡«é žäžã§å£
åãèµ·ãå Žåã«ã¯çšããããšãã§ããã éåäœè©ŠæïŒåã¯ç¹ç¶ïŒã98ïŒ ç¡«é žåã³å容é
ã®ïŒmmãããã³ã®ç«æ¹ç²ãéããç¶ã®äžã§äžç·
ã«ãã溶液ãçããæäœæéãéåžžã¯10ã25åé
æ¯çªæ©äžã«èŒããããã€ãã³âããšã³ã¹ã±
ïŒCannonâFenskeïŒç²åºŠèšãé転æ³ã«ããå å¡«
ãããžã¯ãã é žã«ãªãŠã ã®é£œå氎溶液ããæãæ
枩槜äžã«å ¥ãããäžåé£ç¶ããŠæµäžæéãçŽã¡ã«
枬å®ãããæ¯çªæäœã¯ææã§è¡ãªãããã¹ãŠã®ç§»
éå·¥çšã¯èæãå ã®äžã§è¿ éã«è¡ãªãã次ã®æž¬å®
ã«ãããŠæº¶æ¶²ã®æµäžæéãæžå°ããå Žåã«ã¯ã
ηinhã®èšç®ã«ã¯æé·æéãçšããã ç¹ç¶ã®åŒåŒµç¹æ§ïŒãã€ã©ã¡ã³ãåã³ç³žã®ç¹æ§ã¯
ã¢ãŒã¬ã³ïŒMorganïŒã®ç±³åœç¹èš±ç¬¬3827998å·èš
èŒã®æ¹æ³ã«ãã枬å®ããããå°ãªããšãïŒåã®ç Ž
æ匷床ãå¹³åããã åãè©Šæã®åäžãã€ã©ã¡ã³ãã®æ§è³ªãšå€ãã€ã©
ã¡ã³ãã»ã¹ãã©ã³ãïŒç³žïŒã®æ§è³ªãšã§ã¯ç°ã€ãçµ
æãåŸããããç¹èšããªãéããã¹ãŠã®æ§è³ªã¯ã
ã€ã©ã¡ã³ãã®æ§è³ªã§ããã å åŠçç°æ¹æ§ïŒå åŠçç°æ¹æ§ã¯äžèšTOTæ³ã«
ãã€ãŠæž¬å®ããã TOT枬å®è£ 眮ãšæµå枩床枬å®è£ 眮 ç±å åŠçè©ŠéšïŒTOTïŒã«ã¯åå é¡åŸ®é¡ãå¿ èŠ
ã§ãããããã¯æ±ãã®ãªãå åŠç³»ãšäžèšã«è¿°ã¹ã
ããã¯ã°ã©ãŠã³ãééçã枬å®ããããšãã§ãã
亀åïŒ90ãïŒåå åãæããååã«é«åºŠãªåžå ä¿
æ°ããã€ãŠãããããã§å ±åãã枬å®æ³ã«ã¯ã©ã€
ãïŒLeitzïŒç€Ÿã®ãã€ã¢ã«ãã¯ã¹ã»ããŒã«
ïŒDialuxâPolïŒé¡åŸ®é¡ã䜿çšãããããã«ãã©
ãã€ãåå åãäž¡çŒçšæ¥çŒã¬ã³ãºãåã³å ç±å°ã
åä»ãããå æ€åºåïŒããã¡ãŒã¿ãŒã®ã»ã³ãµãŒïŒ
ãé¡åŸ®é¡ã®çã®é éšã«åä»ãããé¡åŸ®é¡ã¯32åã®
åçã®äœåè·é¢ã®é·ã察ç©ã¬ã³ãºãæããèµ€è²
ïŒç¬¬äžçŽèµ€è²ïŒã®æ¿ãæããŠãããïŒåŸè ã¯äº€åå
å åãçšãçŒã§èŠ³æž¬ããæã«ã®ã¿çšããååå å
ãš45ãã®è§åºŠããªããŠããïŒãå ¥å°å æºããã®çœè²
å ãåå åãéããå ç±å°äžã®è©Šæãéãã次ã«
åæåšãéããŠå æ€åºåãåã¯æ¥çŒã¬ã³ãºãžåã
ããã¹ã©ã€ãã«ããåãæ¥çŒã¬ã³ãºããå æ€åºåš
ãžãšç§»åãããã䜿çšããå ç±å°ã¯500âã«å ç±
ããããšãã§ãããããŠãããã³ïŒUnitronïŒã
MHSåç空å ç±å°ãç±³åœããµããŠãŒã»ããå·ã
ãŠãŒãã³ã»ãã€ã©ã³ãºïŒNewton HighlandsïŒã
ããŒããã ïŒNeedhamïŒã¹ããªãŒãã66ïŒ02161ïŒ
ã®ãŠãããã³ã»ã€ã¹ããªãŠã¡ã³ãïŒUnitron
InstrumentïŒç€Ÿè£œããçšãããå æ€åºåšããã®
ä¿¡å·ãããªãã¡ãŒã¿ã®å¢å¹ åšã«ããå¢å¹ ããâ
ãªã³ãŒããŒã®ïŒ¹è»žãžäŸçµŠãããå ã®åŒ·åºŠã«å¯Ÿã
ãç³»ã®å¿çã¯çŽç·ç¶ã§ãããèšé²çŽäžã«ããã枬
å®ã®ç²ŸåºŠã¯Â±ïŒmm以å ã§ãã€ããå ç±å°ã«ã¯ïŒå
ã®åä»ããç±é»å¯ŸãåããããŠããããã®ïŒåã¯
âãªã³ãŒããŒã®ïŒžè»žã«é£çµãããŠããå ç±å°
ã®æž©åºŠãèšé²ããä»ã®äžã€ã¯ããã°ã©ã ãããæž©
床ã³ã³ãããŒã©ãŒãžãšé£çµãããŠãããäžèšã®ã
ãã«ããŠã€ããåä»ããéåäœè©Šæã«çŒã§é¡åŸ®é¡
ã®çŠç¹ãåãããïŒäº€ååå åã䜿çšïŒãå è·¯ã
ãã®è©Šæã¯ååºãããã«ããŒã»ã¹ãªããã¯ãã®
ãŸãã«ããŠãããé¡åŸ®é¡ã®ãã©ãã€ãåæèšãå
è·¯ããååºããã¹ã©ã€ããŒã移åãããŠåãå æ€
åºåãžãšç§»åãããç³»ã調ç¯ããâãªã³ãŒã
ãŒã®ïŒ¹è»žã®å šå¹ ã®æ¯ãïŒèšé²çŽäžã§18cmïŒãããª
ãã¡ãŒã¿ã®ä¿¡å·ã®36ïŒ ã«å¯Ÿå¿ããããã«ãããã
ãã¯(1)ãªã³ãŒããŒã®ïŒ¹è»žã®èªã¿ãïŒcmã«å¯Ÿå¿ãã
ããã«äºãéžã°ããå€ã«å æºã®åŒ·åºŠã調ç¯ãã(2)
ããªãã¡ãŒã¿ã®å¢å¹ çã10åã«å¢å ãããããšã«
ãã€ãŠè¡ãªãããããã®çµæãªã³ãŒããŒã®18cmã®
å šå¹ ã®æ¯ããããªãã¡ãŒã¿ã®ä¿¡å·ã®ïŒ18/50ïŒÃ
100ããªãã¡36ïŒ ã«å¯Ÿå¿ããããã«ãªããããã¯
ã°ã©ãŠã³ãã®ééå€ã¯äº€åïŒ90ãïŒåå åãšã«ã
ãŒã»ã¹ãªãããšãè©Šæã眮ããªãå è·¯äžã«å ¥ããŠ
èšé²ãããã䜿çšããç³»ã®ããã¯ã°ã©ãŠã³ãéé
çã¯æž©åºŠã«äŸåãããèšé²çŽã®çŽ0.5cm以äžã§ãª
ããã°ãªããªãã TOTè©Šéšåã³æµå枩床ã®æž¬å®ã«å¯Ÿã倫ã ïŒå
ã®è©Šæã次ã®ããã«ããŠã€ãããçŽç²ãªéåäœã®
äºäžç²ãã«ããŒã»ã¹ãªããã®éã«å ¥ãã亀å
ïŒ90ãïŒåå åã®éã§å ç±å°äžã«ãããŠãçŽ50âïŒ
åã®ããã°ã©ã ãããé床ã§å ç±ããªããçŒã§èŠ³
å¯ãããç²åã®çžãäžžããªãè©Šæ枩床ïŒïŒŽïŒãæµ
åã®ç®å®ã§ããããããèšé²ããã倫ã ã«ããŒã»
ã¹ãªããã«æ¿ãã éåäœç²åããæãè€è£œè©Šæã
ïŒåã®é¡åŸ®é¡ã®ã¹ã©ã€ãã«æ¿ãããã®ã¢ã»ã³ããª
ãŒããå ç±æ¿ã®äžéšã®äžã«ããéŒæ¿ã®äžã«æ¿å ¥ã
ãç±é»å¯Ÿã«ãã枬å®ããã枩床ãïŒïŒŽïŒ10âïŒã«
ãªãããã«äºç±ãããå ç±æ¿äžã«çœ®ãããã®ã¢ã»
ã³ããªãŒãããã«é«æž©ã«å ç±ãããã«ã€ããŠãæš
æã®æŒæ£ã§åè©Šæã«å§åã亀äºã«ãããç²åãè
åããŠæµåããïŒåã®èã液äœãã€ã«ã ãã§ãã
ãŸã§ç¶ãããçŽã¡ã«ã¢ã»ã³ããªãååºããå·åŽ
ããåºäœã®ãã€ã«ã ïŒã«ããŒã»ã¹ãªããã®éã«ä¿
æããããŸãïŒãã¢ã»ã³ããªãŒããåé¢ãããã
ã®éçšã§éåäœè©Šæã¯å®¹æã«ããã«éåããã
ãããã®éçšã«ããè©Šæã®èª¿è£œäžå ç±æéãšæž©åºŠ
ãšãæå°éã«ããããšãéèŠã§ããã éåäœè©Šæãã€ã«ã ã®åãã¯ïŒã6ÎŒmã§ããã
ãšã奜ãŸãããåããããèãããããããã€ã«
ã ã¯ãã®è©Šéšã§ç°æ¹æ§ã瀺ããªãããšããããã
ããããè©Šæãç°æ¹æ§ã瀺ããªããïŒã6ÎŒmã®è©Š
æã«ã€ããŠè©Šéšãç¹°è¿ãå¿ èŠã¯ãªããè©Šæã®åã
ã¯å¹²æžèšã«ãã€ãŠæž¬å®ã§ããããããè¡ãã«ã¯å±
æçæ¢ç¥ã®æ²¹ãè©Šæãåå²ãã«ããŒã»ã¹ãªããã®
éã«æ³šå ¥ããTOTæ³ã§èŠ³æž¬ãã¹ãè©Šæéšåã«è¿
æ¥ããåºåã®ç©ºæ°ãšã®å¢çé¢ã§æ²¹å±€ã®åãã枬å®
ããéæ¥çãªæ¹æ³ã䟿å©ã§ãããåãã枬å®ãã
ããæ²¹ã¯ãã¬ãªã³TFã®åŒåççŽ äžã«çæé浞
挬ãããããè¶ é³æ³¢ã§æ¯çªããããšã«ãã容æã«
é€å»ããããšãã§ããã ã«ããŒã»ã¹ãªããã«æ¿ãã ãã€ã«ã ã®äžã€ã¯
TOTæ³ã«äœ¿çšããä»ã®äžã€ã¯æµå枩床ã®æ±ºå®ã«
䜿çšãããæµå枩床ã¯è©ŠæãTOTè£ çœ®äžã§çŽ50
âïŒåã®ããã°ã©ã ãããé床ã§å ç±ããæã«ã
ã€ã«ã ã®åã®çé«ç·ãå€åãã枩床ã§ããã ãããã®ïŒå ±ïŒéåäœåã¯ç¹ç¶ã®æµå枩床ã¯ã
ã®å±¥æŽã«ãã€ãŠå€åããããšã«æ³šæãã¹ãã§ã
ããäŸãã°é段ç¶ã®å ç±ããããšéåžžæµå枩床ã¯
äžæãããããã«ãã€ãŠæåã®æµå枩床以äžã§ã¯
ãããæ°ããå°éããæµå枩床ããäœã枩床ã§å
ç±ããããšãã§ãããå ±åãããæµå枩床ã¯ãã®
æ¹æ³ã«ãã€ãŠæž¬å®ããããã®ã§ããã TOTæ³ã®è©Šæãå ç±å°ã®äžã«èŒããå æ€åºåš
ãšäº€åããå®è³ªçã«å šéšã®å ãè©Šæãéãããã«
äœçœ®ããããè©Šæã亀åïŒ90ãïŒåå åã®éã«å ¥
ããçªçŽ äžã«ãããŠçŽ50ãïŒåã®ããã°ã©ã ãã
ãé床ã§è©Šæã25âãã465âãŸã§äžæããã€ã€ã
å ã®åŒ·ããšæž©åºŠãšãâãªã³ãŒããŒã«èšé²ã
ããé©åœãªæ€åºŠæ²ç·ãçšãèšé²ããã枩床ããè©Š
æã®æž©åºŠãåŸãã 溶èç©ãçæããïŒå ±ïŒéåäœã¯ãè©Šæã亀å
ïŒ90ãïŒåå åã®éã§ãã®æµå枩床以äžã®æž©åºŠã«å
ç±ããæãããåŸãããç°æ¹æ§æº¶èç©ãéãå ã
èšé²çŽäžã«ãããŠããã¯ã°ã©ãŠã³ãã®ééå ã®æ²
ç·ã®é«ãã®å°ããšãïŒåã§ãããããå°ããšã
0.5cmé«ãé«ãããã€æ²ç·ãäžãããªãã°ãTOT
æ³ã«ãããŠç°æ¹æ§æº¶èç©ãçæãããšèããã
ãããã®ãããªæº¶èç©ãçãããšãå ã®ééæ²ç·
ã¯(1)ãã®å€ïŒé«ãïŒãããã¯ã°ã©ãŠã³ãã®ééæ²
ç·ã®å°ããšãïŒåã«ãªããäžã€ãããããå°ããš
ãçŽ0.5cm倧ã«ãªãããåã¯(2)å°ããšããã®ãã
ãªå€ãŸã§å¢å ãããæ·»ä»å³é¢ã®æ²ç·ïŒ¢ã¯ç°æ¹æ§æº¶
èç©ãçããç³»ã«å¯ŸããŠé垞芳枬ããã匷床æ²ç·
ã®äŸã§ããã 亀åïŒ90ãïŒåå åã®éã§çæ¹æ§æº¶èç©ïŒè©Šæ
ã¯å®å šã«æº¶èããŠããªããã°ãªããªãïŒãçãã
æã®åæåšãéãå ã®åŒ·åºŠã¯å®è³ªçã«ããã¯ã°ã©
ãŠã³ãééæ²ç·ãšåãã§ããïŒã«ããŒã»ã¹ãªãã
ãã€ããªãè©Šæã90ã亀ååå åãçšãèŠéã®å€
åŽã«çœ®ããŠåŸããããã®ïŒãçæ¹æ§æº¶èç©ãçã
ããšãå ã®éé匷床ã¯(1)å®è³ªçã«ããã¯ã°ã©ãŠã³
ãã®éé匷床ã«çããããåã¯(2)é«ãå€ãããã®
ãããªå€ãžãšæžå°ãããæ·»ä»å³é¢ã®æ²ç·ïŒ¡ã¯çæ¹
æ§æº¶èç©ãçããéåäœã®åŒ·åºŠæ²ç·ã®äŸã§ããã æ¬çºæã®ããªã¢ãŸã¡ãã³åã³ã¢ãŸã¡ãã³å ±éå
äœã¯æº¶èç¶æ ã®å šæž©åºŠç¯å²ã«äºããå³ã¡éåäœã®
æµå枩床ããå解枩床åã¯æé«è©Šéšæž©åºŠãŸã§ã«äº
ãã屡ã å åŠçç°æ¹æ§ã瀺ãããããæçš®ã®ããª
ã¢ãŸã¡ãã³ïŒå ±ïŒéåäœã§ã¯ã溶èç©ãç±çã«å
解ãããšãã®äžéšã¯çæ¹çã«ãªãããŸãä»ã®çš®é¡
ã§ã¯ã溶èç©ã®æ§è³ªã¯æž©åºŠãäžãã«ã€ããŠç°æ¹æ§
ããçæ¹æ§ãžãšå®å šã«å€åããã éåäœæº¶è枩床ïŒPMTïŒïŒç¹èšããªãéãäžèš
å®æœäŸã§å ±åãããéåäœã®æº¶è枩床ã¯ã€ã³ã¿ãŒ
ãµã€ãšã³ã¹ã»ãããªãã·ã€ãŒãºïŒInterscience
PublishersïŒ1968幎çºè¡ãœã¬ã³ãœã³ïŒSorenâ
sonïŒåã³ãã€ã³ãã«ïŒCampbellïŒèããã¬ãã©
ãã€ãŽã»ã¡ãœããºã»ãªãŽã»ããªããŒã»ã±ãã¹ããª
ãŒïŒPreparative Methods of Polymer Chemi
âstryïŒã第ïŒç57ã59é èšèŒã®æ¹æ³ïŒ¡ã«ããé«
æž©ã®æ£ã«ã€ããŠæ±ºå®ãããã æ¬çºæã®ç¯å²å ã®å€ãã®ã¢ãŸã¡ãã³å質åã³å ±
éåäœã®äŸãäžèšå®æœäŸã«ç€ºãããããã¯æ§é ã
瀺ãåã«ãã€ãŠç€ºãããŠãããäŸãã°ïŒâã¡ãã«
âïŒïŒïŒâããšãã¬ã³ãžã¢ãã³ãšãã¬ãã¿ã«ã¢ã«
ãããããã€ããããã¢ãŸã¡ãã³å質éåäœã¯ã
ãªïŒãããªãâïŒâã¡ãã«âïŒïŒïŒâããšãã¬ã³
ãããªãã¡ããªãã€ã³âïŒïŒïŒâããšãã¬ã³ã¡ã
ãªãã€ã³ïŒãšåä»ããããã å®æœäŸ ïŒ æ¬å®æœäŸã¯å åŠçç°æ¹æ§ããã€ãããªïŒãããª
ãâïŒâã¡ãã«âïŒïŒïŒâããšãã¬ã³ãããªããš
ããªãã€ã³âïŒïŒïŒâããšãã¬ã³ãšããªãã€ã³ïŒ
ã®ç±ç補é æ³ã瀺ãã 30.5cmã®éå管äžã§ïŒâã¡ãã«âïŒïŒïŒâããš
ãã¬ã³ãžã¢ãã³ïŒ2.44ïœã0.02ã¢ã«ïŒãšïŒïŒïŒâ
ãžã¢ã»ãã«ãã³ãŒã³ïŒ3.24ïœã0.02ã¢ã«ïŒãšãäž
ç·ã«ãããåå¿æ··åç©ããã¹ãŠãããçªçŽ æ°æµäž
ã§ïŒæé156âã«å ç±ããåŸãïŒæé205âã«å ç±
ãããçæç©ãæéãç Žç ããé åæ©äžã§ã¡ã¿ã
ãŒã«åã³æ°Žã§å¥ã ã«æŽæµãã80âã§ç空也ç¥ããŠ
ηinhïŒ0.5ã®éåäœ4.32ïœãåŸãããã®ãã®ã®
PMTã¯370âã§ãã€ãã å®æœäŸ ïŒ æ¬å®æœäŸã¯åæ¢å€ãšããŠïŒâã¢ã»ãã¢ãããã³
ãºã¢ã«ããããçšããããªãâïŒâã¡ãã«âïŒïŒ
ïŒâããšãã¬ã³ãããªãã¡ããªãã€ã³âïŒïŒïŒâ
ããšãã¬ã³ã¡ããªãã€ã³ïŒãããªãâïŒïŒïŒâã
ãšãã¬ã³ãªãã·âïŒïŒïŒâããšãã¬ã³ãããªãã¡
ããªãã€ã³âïŒïŒïŒâããšãã¬ã³ã¡ããªãã€ã³
ïŒã¢ã«æ¯90ïŒ10ïŒå ±éåäœã補é ããæ¹æ³ã瀺ãã HMPAïŒ25mlïŒãNMPïŒ25mlïŒåã³å¡©åãªããŠ
ã ïŒ2.0ïœïŒã®æ··åç©äžã«ïŒâã¡ãã«âïŒïŒïŒâ
ããšãã¬ã³ãžã¢ãã³ïŒ4.4ïœã0.036ã¢ã«ïŒãšãã¹
ïŒïŒâã¢ããããšãã«ïŒãšãŒãã«ïŒ0.80ïœã0.004
ã¢ã«ïŒãå«ã溶液ãæ¹ææ··åããïŒâã¢ã»ãã¢ã
ããã³ãºã¢ã«ãããïŒ0.4ïœïŒãå ãããæ°åã
ãŠãã¬ãã¿ã«ã¢ã«ãããïŒ5.36ïœã0.04ã¢ã«ïŒã
å ããã16æéåŸåå¿æ··åç©ã¯æ¹æäžèœã«ãªãã
åå¿æ··åç©ãæ°Žãšæ··åããæ²æŸ±ããéåäœãå®æœ
äŸïŒã®ããã«ããŠæéãæŽæµã也ç¥ããηinhïŒ
1.1ã®éåäœ9.2ïœãåŸãããã®å ±éåäœã®PMT
ã¯306âã§ãããå åŠçç°æ¹æ§ã®ãã溶èç©ãç
ããã äžèšè¡šïŒã«ã¯äžèšå®æœäŸïŒã®äžè¬çæ¹æ³ã«ãã
ã€ããããæ¬çºæã®ä»ã®ïŒå ±ïŒéåäœã瀺ããã
ããã®åæã«çšãããžã¢ã«ãããã«ã¯ãã¬ãã¿ã«
ã¢ã«ããããã¡ãã«ãã¬ãã¿ã«ã¢ã«ããããïŒïŒ
ïŒâãã¹ïŒïŒâããªã«ãã«ããšããã·ïŒãšã¿ã³ã
åã³ãã¹ïŒïŒâããªã«ãã«ããšãã«ïŒãšãŒãã«ã§
ããã䜿çšãããžã¢ãã³ã«ã¯ïŒâãã«ãªãâãïŒ
âã¯ããâãåã³ïŒâã¡ãã«âïŒïŒïŒâããšãã¬
ã³ãžã¢ãã³ãïŒïŒ3â²âãžã¡ãã«ãã³ããžã³ãïŒïŒ
4â²âã¢ãŸãã·ãžã¢ããªã³ãïŒïŒ3â²âãžã¡ãã«â
ïŒïŒ4â²âãžã¢ããã¢ãŸãã³ãŒã³åã³ïŒïŒïŒâãã¹
ïŒïŒâã¢ããããšããã·ïŒãšã¿ã³ããããå®æœäŸ
ïŒã«ãããŠã¯ãåå¿æº¶åªã¯DMAcã§ããããã®
éåäœè©ŠæãïŒåé300âã«å ç±ããåŸã325âã
211KgïŒcm2ã§20ç§éãã¬ã¹ããå¯ææ§ã®ãã€ã«ã
ãåŸããå®æœäŸïŒã®å ±éåäœãã€ããå Žåããã
ãµã¡ãã¬ã³ãžã¢ãã³ãšïŒâã¡ãã«âïŒïŒïŒâããš
ãã¬ã³ãžã¢ãã³äºå¡©é žå¡©ãçã¢ã«éïŒå€«ã 0.005
ã¢ã«ïŒçšããçæããé žãäžåããçºã«çé žãªã
ãŠã ïŒ0.01ã¢ã«ïŒãçšãããå®æœäŸïŒâïŒã«ãã
ãŠã¯ãåå¿åæã0.002ã¢ã«éãçšããåå¿æº¶åª
ã¯ïŒïŒ ã®LiClãå«ãDMAcïŒNMPïŒ1/1ïŒã§ã
ããå®æœäŸïŒâïŒã«ãããŠã¯åå¿åæ0.0005ã¢ã«
éãçšãã溶åªã¯LiCl5ïŒ ãå«ãDMAcïŒ1.5mlïŒ
ã§ãã€ããæ«ç«¯å°éå€0.004ïœãçšãããå®æœäŸ
ïŒâïŒã§ã¯æº¶åªLiCl5ïŒ ãå«ãDMAcïŒ10mlïŒã§
ãããååå¿åæã0.005ã¢ã«éçšããã 瀺ããããã¹ãŠã®ãã®ããç°æ¹æ§æº¶èç©ã圢æ
ããã ãè¡šã ãè¡šã å®æœäŸ 10 æ¬å®æœäŸã¯ãããªãâïŒâã¡ãã«âïŒïŒïŒâã
ãšãã¬ã³ãããªãã¡ããªãã€ã³âïŒïŒïŒâããšã
ã¬ã³ã¡ããªãã€ã³ïŒãããªãâïŒïŒïŒâããšãã¬
ã³ãããªãã¡ããªãã€ã³âïŒïŒïŒâããšãã¬ã³ã¡
ããªãã€ã³ïŒïŒ95/5ïŒå ±éåäœã®è£œé æ³ã瀺ãã
ãã®å ±éåäœã¯æ圢ããŠæ£ã«ããã HMPAïŒ20mlïŒãNMPïŒ20mlïŒåã³LiClïŒïŒïœïŒ
ã®æ··åç©äžã«ïŒâã¡ãã«âïŒïŒïŒâããšãã¬ã³ãž
ã¢ãã³ïŒ4.64ïœã0.038ã¢ã«ïŒãšïŒïŒïŒâããšã
ã¬ã³ãžã¢ãã³ïŒ0.22ïœã0.002ã¢ã«ïŒãå«ã溶液
äžã«ãããŠçªçŽ äžã§ãã¬ãã¿ã«ã¢ã«ãããïŒ5.36
ïœã0.04ã¢ã«ïŒãå ãããåå¿æ··åç©ã宀枩ã«ã
ããŠ16æéæ¹æããåŸãå®æœäŸïŒãšåæã«ããŠå
åãïŒ110âäžã®çäžïŒÎ·inhïŒ4.7ãPMTïŒ260â
ã®å ±éåäœ8.6ïœãåŸãããã®å ±éåäœæº¶èç©ã¯
å åŠçã«ç°æ¹æ§ã§ããã ãã®çæç©è©Šæãæ£æ圢åã«å ¥ãã15åé300
âã«ä¿ã€ããã®æ£ã®æ²ã匷ãã¯6.3Ã103ãã³ãïŒ
å¹³æ¹ã€ã³ããæ²ãã¢ãžãŠã©ã¹ã¯4.3Ã105ãã³ãïŒ
å¹³æ¹ã€ã³ããéäŒåŒ·ã4.3Ã103ãã³ãïŒå¹³æ¹ã€ã³
ãïŒå€«ã 4.43ïŒ302ïŒ3.02KgïŒcm2ïŒã§ããã å®æœäŸ 11 æ¬å®æœäŸã¯ããªïŒãããªãâïŒâã¡ãã«âïŒïŒ
ïŒâããšãã¬ã³ãããªãã¡ããªãã€ã³âïŒïŒïŒâ
ããšãã¬ã³ã¡ããªãã€ã³ïŒã®è£œé æ³ã瀺ãããã®
çæç©ã¯å åŠçç°æ¹æ§ããã€æº¶èç©ãçããåŒç·©
ç±åŠçã«ããåŒåŒµåŒ·ãã匷åããã匷ãç¹ç¶ã«çŽ¡
糞ããããšãã§ããã ãšã¿ããŒã«200mläžã«ïŒâã¡ãã«âïŒïŒïŒâã
ãšãã¬ã³ãžã¢ãã³ïŒ77.9ïœã0.64ã¢ã«ïŒã®æº¶æ¶²ã
宀枩ã§ã€ããã200mlã®éæµãšã¿ããŒã«äžã«ãã
ãŠãã¬ãã¿ã«ã¢ã«ãããã®ç¬¬äºã®æº¶æ¶²ïŒ81.3ïœã
0.61ã¢ã«ïŒãã€ãã€ãããããã®æº¶æ¶²ãåæã«ïŒ
ã®ããŒã«ãŒã«æ³šããïŒãïŒå以å ã§éåäœã®æ²
柱ãå§ãŸãããã®åå¿æ··åç©ãäžæ©å®€æž©ã§çªçŽ äž
ã«ãããŠæŸçœ®ããããšã¿ããŒã«ãèžçºãããåŸã
éåäœæ®çç©ãïŒã®æ°Žã§æŽæµãã110âã«ãã
ãŠ1.5æéç空也ç¥ããã也ç¥æ®çç©ãå ç±ãã
ã¹ã¯ãªãŠãŒæŒåºæ©äžã§ããã«éåãããã æŒåºç©ã®äžéšãæ圢ããŠãã©ã°ïŒÎ·inhïŒ6.0ïŒ
ã«ããïŒåã®åããã€çŽ¡ç³žå£éãååã®çŽåŸ
0.018cmã玡糞å£é枩床260âã溶èåºå枩床
ïŒMZTïŒ255ã262âããéããŠç©ºæ°äžã«çŽ¡ç³žãã
600ydïŒåã®é床ã§æ²åãïŒ548ïœïŒåããã³
ïŒãä»ã®ããã³ïŒããã³ïŒ¢ïŒã¯900ydïŒåïŒ822
ïœïŒåãMZTïŒ260âïŒã§æ²åã€ããããã³ïŒ¢ã®
ç¹ç¶ã®Î·inhïŒ7.9ã玡糞ãããŸãã®ç³žã®æ§è³ªã¯æ¬¡
ã®éãã ãã㳠  ïŒ Den.  7.3 1.1 916 20.0  6.4 0.2 900 15.1 ããã³ïŒ¡ã®ç³žã®è©Šæããã¢ã€ããŒã»ãã©ãã¯ã¹
ïŒFiberâFraxïŒãçšããŠããã³ã«æ²åããäžèš
ã®æ¡ä»¶ã§çäžã«ãããŠïŒçªçŽ ãé£ç¶çã«æµãïŒå
ç±ããã宀枩160âïŒïŒæéã180âïŒïŒæéã
200âïŒïŒæéã250âïŒ12æéããã®åŠçåŸç¹ç¶
ã¯æ¬¡ã®ãã€ã©ã¡ã³ãã®æ§è³ªã瀺ããïŒ15è©Šæã®å¹³
åïŒãïŒïŒ¥ïŒMiïŒDen.ïŒ28ïŒ3.2ïŒ939ïŒ4.3ãïŒ
æ¬ã®ãã€ã©ã¡ã³ãã«ã€ããŠã¯ïŒŽïŒïŒ¥ïŒMiïŒDen.
ïŒ44ïŒ4.2ïŒ1118ïŒ4.2ã ä»ã®åŠçã«ãããŠã¯ããã³ïŒ¡ã®ç³žã®è©Šæãåé¢
ããŠïŒæ¬ã®ãã€ã©ã¡ã³ã(f)ã«ãããããéŒç·ãã
åçŽã«åäžãã次ã®æ¡ä»¶ã§é£ç¶çã«çªçŽ ãæµããª
ããçäžã§å ç±ããã宀枩ã165âïŒ40åã165ã
230âïŒïŒæéã232âïŒ1.3æéã234âïŒ6.3æ
éããã®åŠçã®åŸãç¹ç¶ã¯ïŒŽïŒïŒ¥ïŒMiïŒDen.ïŒ
38ïŒ4.4ïŒ1012ïŒ3.7ã®æ§è³ªã瀺ããã å®æœäŸ 12 æ¬å®æœäŸã¯å åŠçç°æ¹æ§ããã€æº¶èç©ãçãã
ããªïŒãããªãâïŒïŒïŒâããšãã¬ã³ãããªãã¡
ããªãã€ã³âïŒâã¡ãã«âïŒïŒïŒâããšãã¬ã³ã¡
ããªãã€ã³ïŒã®è£œé æ³ã瀺ãã 宀枩ã«ãããŠïŒâã¡ãã«ãã¬ãã¿ã«ã¢ã«ããã
ïŒ0.20ïœã0.00135ã¢ã«ïŒãïŒïŒïŒâããšãã¬ã³ãž
ã¢ãã³ïŒ0.146ïœã0.00135ã¢ã«ïŒåã³LiCl5ïŒ ã
å«ãHMPAïŒNMPïŒ50ïŒ50容ç©æ¯ïŒã®ç¡æ°Žæ··å
ç©ïŒmlãäžç·ã«ããŠæ¹æãåå¿æ··åç©ãã€ãã€
ãã15ååŸïŒâã¢ã»ãã¢ãããã³ãºã¢ã«ããã
ïŒ0.004ïœïŒãå ãããåå¿æ··åç©ã宀枩ã§ç¡æ°Žæ¡
件äžã§äžæ©æ¹æããæ°Žãå ããŠéåäœãæ²æŸ±ã
ãããããæéããæ°Žãšãšã¿ããŒã«ïŒç¡æ°ŽïŒã§
å¥ã ã«æŽæµãã80âã§ç空也ç¥ãããηinhïŒ0.7ã
PMTïŒ270âã®éåäœçŽ0.2ïœãåŸãããã®æº¶è
ç©ãã270âã«ãããŠçŽ¡ç³žããç¹ç¶ã®æ§è³ªã¯ïŒŽïŒ
ïŒMiïŒDen.ïŒ3.5ïŒ0.55ïŒ684ïŒ6.1ã§ããã ïŒâã¡ãã«ãã¬ãã¿ã«ã¢ã«ãããã¯ïŒâã¡ãã«
âαïŒÎ±â²âïŒïŒïŒâãã·ã¬ã³ãžãªãŒã«ãm.p.78ã
81âãããã¯ãã€ã¹ãããŒã ïŒNystromïŒãšã
ã©ãŠã³ïŒBrownïŒã«ããäžè¬çæ¹æ³ãã¢ã¡ãªã«
ååŠäŒèªïŒJ.Am.Chem.Soc.ïŒ69ïŒ1197ïŒ1947ïŒã
ã«ããïŒâã¡ãã«ãã¬ãã¿ãã€ã«ã¯ãã©ã€ãã
LiAlH4ã§éå ããŠã€ãããããã1Nã®ç¡é žã¢ã³
ã¢ããŠã ã»ãªãŠã ãïŒNH4ïŒ2CeïŒNO3ïŒ6ããçšãã
ãã©ãããã¹ããŒïŒTrahanovskyïŒãã®äžè¬ç
æ¹æ³ããžã€ãŒãã«ã»ãªãŽã»ãªã¬ããã¯ã»ã±ãã¹ã
ãªãŒïŒJ.Org.Chem.ïŒ32ïŒ3865ïŒ1967ïŒãã§é žåã
ãŠã€ããããšãã§ããã30åéå ç±æ¹æããåŸã
åå¿æ··åç©æ°Žæº¶æ¶²ããšãŒãã«ïŒïŒåïŒãšå¡©åã¡ã
ã¬ã³ïŒïŒåïŒã§æœåºãããäžç·ã«ããææ©çžã
NaHCO3ãšæ°Žãšã§æŽæµããåŸãMgSO4äžã§ä¹Ÿç¥
ããã也ç¥ç©ãçå¥ããç液ãèžçºãããŠãè»ã
ãçœè²åºäœã«ããããã65âã§æè¯ãããŠèç¹70
ã71âã®çœè²ç²æ«ãåŸãããã®ç²æ«ãæ°Žããåçµ
æ¶ããèç¹71ã72âã®ïŒâã¡ãã«ãã¬ãã¿ã«ã¢ã«
ããããåŸãã å®æœäŸ 13 æ¬å®æœäŸã¯ããªïŒãããªãâïŒâã¯ããâïŒïŒ
ïŒâããšãã¬ã³ãããªãã¡ããªãã€ã³âïŒïŒïŒâ
ããšãã¬ã³ã¡ããªãã€ã³ïŒã®è£œé æ³åã³ãããã
ã€ãããã匷ãç¹ç¶ã瀺ãããã®éåäœã®æº¶èç©
ã¯å åŠçç°æ¹æ§ã瀺ãã HMPAïŒ30mlïŒãNMPïŒ30mlïŒåã³LiClïŒ3.0ïœïŒ
ãå«ãæ··åç©äžã«ïŒâã¯ããâïŒïŒïŒâããšãã¬
ã³ãžã¢ãã³ïŒ8.58ïœã0.06ã¢ã«ïŒãå«ã溶液ãç
ç¶ãã©ã¹ã³äžã«ãããŠçªçŽ ãæµããªããæ¹æã
ïŒããã«æ¹ææ©ïŒãããã«ïŒâã¢ã»ãã¢ãããã³ãº
ã¢ã«ãããïŒ0.4ïœïŒãå ãããæ°å以å ã§ãã¬
ãã¿ã«ã¢ã«ãããïŒ8.04ïœã0.06ã¢ã«ïŒãå ã
ãã宀枩ã«ãããŠåå¿æ··åç©ãæ¹æãããšãçŽ16
æéåŸã«æ¹æäžèœã«ãªããå®æœäŸïŒã®æ¹æ³ã§åå¿
æ··åç©ãååããηinhïŒ0.7ãPMTïŒ310âã®é
åäœ13.8ïœãåŸãã ãã®éåäœã®æ£ãïŒåã®çŽ¡ç³žå£éãåã®çŽåŸïŒ
0.009inïŒ0.023cmïŒçŽ¡ç³žå£é枩床ïŒ320âã溶èåº
å枩床ïŒ310âãããã¯ã¯ã¹ã¯ãªãŒã³ãå«ããã
éããŠç©ºæ°äžã«æº¶è玡糞ããåŸãããç¹ç¶ã
150ydïŒåïŒ137.2ïœïŒåïŒã§æ²åãã玡糞ãã
ãŸãã®ç¹ç¶ïŒÎ·inhïŒ4.5ïŒã®ãã€ã©ã¡ã³ãã®æ§è³ª
ã¯ïŒŽïŒïŒ¥ïŒMiïŒDen.ïŒ7.4ïŒ1.3ïŒ683ïŒ10.9ã§ã
ããO.A.ïŒ22ãã§ããããã®ç¹ç¶ã®è©Šæããã¢ã€
ããŒã»ãã©ãã¯ã¹ã§æ²åã€ãããã³äžã«ãããŠç
äžã§å ç±åŠçããã宀枩ã150âïŒ30åã150âïŒ
30åã150ã260âïŒ30åã260âïŒ3.5æéãçã
ãååºãã宀枩ã«å·åŽããããã®ç¹ç¶ã®ãã€ã©ã¡
ã³ãã®æ§è³ªã¯ïŒŽïŒïŒ¥ïŒMiïŒDen.ïŒ15.3ïŒ1.9ïŒ
844ïŒ11.1ãO.A.ïŒ10ãã§ããã äžèšè¡šâåã³âã«ãããŠã¯ã¢ãŸã¡ãã³
ïŒå ±ïŒéåäœåã³ãã®å åŠçç°æ¹æ§ã®ãã溶èç©
ãã玡糞ããç¹ç¶ã瀺ããå®æœäŸ14ã19ã®éåäœ
ã¯å®æœäŸïŒã®äžè¬çæ¹æ³ã§ã€ãããå®æœäŸ11ã13
ã®äžè¬çæ¹æ³ã«ãã玡糞ããã䜿çšãããžã¢ã«ã
ããã«ã¯ïŒïŒ4â²âãžããªã«ãã«ãããšãã«ãïŒâ
ã¯ãããã¬ãã¿ã«ã¢ã«ãããããã¬ãã¿ã«ã¢ã«ã
ãããåã³ã€ãœãã¿ã«ã¢ã«ããããå«ãŸããã䜿
çšãããžã¢ãã³ã«ã¯ïŒïŒïŒâããšãã¬ã³ãžã¢ã
ã³ãïŒâã¡ãã«âïŒïŒïŒâããšãã¬ã³ãžã¢ãã³ã
åã³ïŒïŒïŒâãšãã¬ã³ãžã¢ããªã³ãå«ãŸãããå®
æœäŸ16ïŒ19ïŒ19âïŒïŒïŒçš®ã®ãžã¢ãã³ïŒã18åã³19
âïŒïŒïŒçš®ã®ã¢ã«ãããïŒã«ã¯å ±éåäœã瀺ãã
玡糞ãããŸãã®ç¹ç¶ãè¡šâã®ããã«ããŠç±åŠ
çãã匷床åã³äŒžã³ã倧ã«ããã å®æœäŸ19âïŒã®éåäœã«å¯ŸããŠã¯ãåå¿åæã®
ïŒïŒïŒâãã¹ïŒïŒâã¡ãã«âïŒâã¢ããããšãã
ã·ïŒâïœâãã¿ã³åã³ãã¬ãã¿ã«ã¢ã«ããããã
é žåé²æ¢å€ãšããŠããšãã«âαâãããã«ã¢ãã³
ãçšããã³ãŒã³äžã§éæµãããããã³ãŒã³âæ°Žã®
å ±æ²žæ··åç©ãæéããåŸãæ®ã€ããã³ãŒã³ããæ²
柱ããéåäœãçå¥ããåŸãæŽæµã也ç¥ããã å®æœäŸ19âïŒã®éåäœã«å¯ŸããŠã¯ããã¬ãã¿ã«
ã¢ã«ããããã¡ãã«âïŒïŒïŒâããšãã¬ã³ãžã¢ã
ã³åã³ïŒïŒ12âãã¹ïŒïŒâã¡ãã«âïŒâã¢ããã
ãšããã·ïŒâïœâããã«ã³ãåå¿åæãšããŠçš
ããå®æœäŸ19âïŒã®äžè¬çæ¹æ³ã䜿çšãããå®æœ
äŸ19âïŒã®éåäœã«å¯ŸããŠã¯ãåæãšããŠãã¬ã
ã¿ã«ã¢ã«ããããïŒïŒ4â²âããªã«ãã«ãããšã
ã«ãã¡ãã«âïŒïŒïŒâããšãã¬ã³ãžã¢ãã³ãåã³
ïŒâã¢ããã¢ã»ãã¢ããªãïŒæ«ç«¯å°éå€ïŒãã溶
åªãšããŠå¡©åã¡ãã¬ã³ãçšããŠå®æœäŸ19âïŒã®äž
è¬çæ¹æ³ã§è¡ãªã€ãã å®æœäŸ19âïŒã«çšããïŒïŒïŒâãã¹ïŒïŒâã¡ã
ã«âïŒâã¢ããããšããã·ïŒâïœâãã¿ã³ã¯ïŒâ
ã¡ãã«âïŒâãããããšããŒã«ãšïŒïŒïŒâãžãã
ã ãã¿ã³ãšã®çã¢ã«éãç¡æ°Žçé žã«ãªãŠã ãšã¢ã»
ãã³ãšã®æ··åç©ãååšãããŠåå¿ãããããšã«ã
ãã€ããã48æééæµãããåŸã溶åªãé€å»ãã
åºäœçæç©ãååããïŒâã¢ã«ã³ãŒã«ããåçµ
æ¶ãããŠm.p.ïŒ126.5ã127.5âã®ïŒïŒïŒâãã¹
ïŒïŒâã¡ãã«âïŒâãããããšããã·ïŒâïœâã
ã¿ã³ã®è€è²éç¶çµæ¶ãåŸãã溶åªãã¡ã¿ããŒã«ã«
ãããã®ãããååç©ã70âåã¯ãã以äžã§1000
ã15000ãã³ãïŒå¹³æ¹ã€ã³ãã«ãããŠãã©ããŒã»
ããã±ã«è§Šåªãçšããæ°ŽçŽ ã«ããéå ããŠææã®
ãžã¢ãã³åæåã«ããã溶液ãã觊åªãåé¢ãã
溶åªãèžçºããããšã¿ããŒã«ããææã®ãžã¢ãã³
ãåçµæ¶ããïŒæŽ»æ§çïŒãèç¹108ã110âãåæ§
ãªæ¹æ³ã§å®æœäŸ19âïŒã«çšããïŒïŒ12âãã¹ïŒïŒ
âã¡ãã«âïŒâã¢ããããšããã·ïŒâïœâããã«
ã³ïŒm.p.ïŒ93ã94âïŒã¯ïŒïŒ12âãžããã¢ããã«
ã³ããã€ãã€ãã ãè¡šã ãè¡šã ïŒïŒ ïŒïŒ³ïŒ¯ïŒïŒš
ïŒïŒïŒ (0.1ïŒ æ¿åºŠ)
ãè¡šã å®æœäŸ 20 æ¬å®æœäŸã¯ïŒâã¯ãããã¬ãã¿ã«ã¢ã«ãããã
åã³ïŒïŒ4â²âãšãã¬ã³ãžã¢ããªã³ãïŒïŒïŒâããš
ãã¬ã³ãžã¢ãã³ããã¹ïŒïŒâã¢ããããšãã«ïŒãš
ãŒãã«ãåã³ïŒïŒïŒâã·ã¯ããããµã³ãžã¢ãã³ã
ãéžã°ããäžå¯Ÿã®ãžã¢ãã³ããã¢ãŸã¡ãã³ïŒå ±ïŒ
éåäœã補é ããæ¹æ³ã瀺ãããããã®å ±éåäœ
ã®æº¶èç©ã¯å åŠçç°æ¹æ§ãæããã HMPAïŒ10mlïŒãNMPïŒ10mlïŒåã³LiClïŒ0.5ïœïŒ
ã®æ··åç©äžã«ãïŒïŒ4â²âãšãã¬ã³ãžã¢ããªã³
ïŒ2.12ïœã0.01ã¢ã«ïŒåã³ïŒïŒïŒâããšãã¬ã³ãž
ã¢ãã³ïŒ1.08ïœã0.01ã¢ã«ïŒãå«ã溶液ã«çªçŽ æ°
æµäžã«ãããŠïŒâã¯ãããã¬ãã¿ã«ã¢ã«ããã
ïŒ3.36ïœã0.02ã¢ã«ïŒãå ãããåå¿æ··åç©ã宀
æž©ã«ãããŠäžæ©æ¹æããå®æœäŸïŒãšåæ§ã«ããŠå
åãïŒ70ã75ã§ä¹Ÿç¥ïŒãηinhïŒ0.5ãPMTïŒ150â
ã®ïŒãããªãâïŒïŒïŒâããšãã¬ã³ãšãã¬ã³â
ïŒïŒïŒâããšãã¬ã³ãããªãã¡ããªãã³âïŒâã¯
ããâïŒïŒïŒâããšãã¬ã³ã¡ããªãã€ã³ïŒãããª
ãâïŒïŒïŒâããšãã¬ã³ãããªãã¡ããªãã€ã³â
ïŒâã¯ããâïŒïŒïŒïŒããšãã¬ã³ã¡ããªãã€ã³ïŒ
ïŒ50/50ïŒå ±éåäœ5.3ïœãåŸãã äžèšè¡šã«ã¯äžè¿°ã®äžå¯Ÿã®ãžã¢ãã³ãçšãäžè¿°
ã®æ¹æ³ã§äžèšå埩åäœããã€ä»ã®å ±éåäœçµæç©
ãã€ããããããã®ãã®ã¯æº¶èç©äžã«ãããŠå åŠ
çç°æ¹æ§ã瀺ãã ãè¡šã ãè¡šã å®æœäŸ 21 æ¬å®æœäŸã§ã¯ããªïŒãããªãâïŒâã¡ãã«â
ïŒïŒïŒâããšãã¬ã³ãããªãã¡ããªãã€ã³âïŒïŒ
ïŒâããšãã¬ã³ã¡ããªãã€ã³ïŒã®ç¹ç¶ã¯èžçºãã
ã¢ã«ããªãªã³ã«é²åºããåŸåŒåŒµç¹æ§ã®ä¿ææ§ãåª
ç§ãªããšã瀺ãã HMPAïŒ60mlïŒãNMPïŒ60mlïŒåã³LiClïŒ5.0ïœïŒ
ã®æ··åç©äžã«ïŒâã¡ãã«âïŒïŒããšãã¬ã³ãžã¢ã
ã³ïŒ12.2ïœã0.01ã¢ã«ïŒãå«ã溶液ãçªçŽ äžã§
500mlã®æš¹èéã®äžã§æ¹æãããã¬ãã¿ã«ã¢ãã
ïŒ13.4ïœã0.1ã¢ã«ïŒãå ããã30ååŸïŒâã¢ãã
ã¢ã»ãã¢ããªãïŒ0.30ïœïŒãå ããå šéšã§16æé
æ¹æãç¶ãããå®æœäŸïŒãšåæ§ã«åå¿æ··åç©ãå
åããηinhïŒ3.0ãPMTïŒ256âã®éåäœ21.6ïœ
ãåŸããéåäœæº¶èç©ã¯å åŠçç°æ¹æ§ããã€ãŠã
ãã éåäœã®æ£ã溶è玡糞ããã玡糞å£é枩床ïŒ
250âã溶èåºå枩床ïŒ240âãæ²åé床çŽ
500ydïŒåïŒ457ïœïŒåïŒã 玡糞æã®ç¹ç¶ïŒÎ·inhïŒ3.3ïŒã®ãã€ã©ã¡ã³ãã®
åŒåŒµç¹æ§ã¯ïŒŽïŒïŒ¥ïŒMiïŒDen.ïŒïŒïŒ1.6ïŒ789ïŒ
6.4ã§ããã ç¹ç¶ã®å°è©ŠæïŒ0.5ïœïŒåã³0.03mlã®ã¢ã«ããª
ãªã³ãå¯å°ç®¡äžã«ãããŠïŒæé133âã«ãããŠå
ç±ããïŒèžæ°æµŽïŒãç¹ç¶ãååºãã空æ°äžã«ãã
ãŠïŒæéæŸçœ®ããããã®åŠçããç¹ç¶ã¯ïŒŽïŒïŒ¥ïŒ
MiïŒDen.ïŒ8.2ïŒ1.1ïŒ736ïŒ7.4ã§ããã 玡糞æã®ç¹ç¶è©Šæã次ã®æ¡ä»¶ã§å ç±åŠçããã
宀枩ã160âïŒïŒæéã200âïŒïŒæéãåŠçãã
ç¹ç¶ã®ãã€ã©ã¡ã³ãã®æ§è³ªã¯ïŒŽïŒïŒ¥ïŒMiïŒDen.
ïŒ16ïŒ2.2ïŒ867ïŒ7.2ã§ãã€ãã å®æœäŸ 22 æ¬å®æœäŸã§ã¯æ¬çºæã®åäœã¯(1)é«ã¢ãã³å«éã®
ãŽã åæäžã§å ç±èåãããæãåã³(2)å¡©åºæ§ã§
å æ°Žå解ãããæã«ãè¯å¥œã«åŒ·åºŠãä¿æããããš
ã瀺ãããã 第äžéš å®æœäŸ10ã®å ±éåäœã®ä»ã®è£œæ³ã®ç³žã®è©Šæã次
ã®æ¡ä»¶äžã«ãããŠå ç±åŠçããã150âïŒ40åã
180âïŒïŒæéã200âïŒïŒæéïŒåæç枩床150
âïŒãããã«ãã€ãŠæ§è³ªïŒŽïŒïŒ¥ïŒMiïŒDen.ïŒ
9.9ïŒ1.4ïŒ788ïŒ7.3ã®ç¹ç¶ãåŸãããã®ç±åŠçã
ã糞ã®è©Šæãã¹ã±ã€ã³ã«ãã空æ°äžã«ãããŠ154
âïŒ24æéå ç±ããïŒïŒ¥ïŒMiïŒDen.ïŒ6.9ïŒ
0.9ïŒ779ïŒ120ã®ç¹ç¶ãåŸãããã®ç±åŠçããç¹
ç¶ãå糞ãã1000ãããŒã«ã®ã³ãŒãã«ãããã®ã³
ãŒããé«ã¢ãã³å«éã®ãŽã åææäžã«å蟌ãã§è€
åäœãã€ãã€ãããã®è€åäœã154âã§24æéå
ç±èåãããã次ã«ãã®ãŽã ããã«ãšã³ã«ããèš
最ãããç¹ç¶ïŒã³ãŒãïŒãååºããããã®ã³ãŒã
ã«å¯ŸããïŒïŒ¥ïŒMiïŒ2.2ïŒ0.80ïŒ472ïŒ10ã€ã³ã
ç ŽæïŒã§ãããããã¯èé ·ãªè©Šéšæ¡ä»¶äžã«ãããŠ
匷床ã32ïŒ ä¿æããããšã«çžåœããã 第äºéš å®æœäŸ10ã®éåäœã®ä»ã®è£œæ³ã®ç³žè©ŠæïŒïŒâã
ã€ã©ã¡ã³ãïŒãïŒæéïŒ190âãïŒæéïŒ200â
ïŒåæçæž©190âïŒã§ç±åŠçãããã€ã©ã¡ã³ãã®æ§
質ãïŒïŒ¥ïŒMiïŒDen.ïŒ12.5ïŒ2.5ïŒ560ïŒ30.1ã®
ç¹ç¶ãåŸãã ãã®ç¹ç¶è©Šæã次ã®ããã«ããŠå æ°Žå解ããã è©ŠéšïŒ¢âïŒ é·ãïŒã€ã³ãã®ç¹ç¶ã§ç²ãåžãç·
ç¶ã«çž«ããæ°Žäžã§ïŒæéïŒ95âã§å ç±ããã è©ŠéšïŒ¢âïŒ ãã®è©Šéšã¯æ°Žã®ä»£ãã«1Nã®æ°Žé ž
åãããªãŠã 氎溶液ãçšããããšä»¥å€ïŒ¢âïŒãšå
çã§ãããè©ŠéšåŸç¹ç¶ãšåžãšãã¢ã«ã«ãªããªããª
ããŸã§æ°Žäžã§ãœãŒãã³ã°ããã å æ°Žå解åŠçåŸç¹ç¶ãæŽæµã也ç¥ããŠãã€ã©ã¡
ã³ãã®åŒåŒµç¹æ§ã決å®ããã è©ŠéšïŒ¢âïŒã®ç¹ç¶ïŒïŒŽïŒïŒ¥ïŒMiïŒDen.ïŒ8.1ïŒ
1.8ïŒ512ïŒ34.7 è©ŠéšïŒ¢âïŒã®ç¹ç¶ïŒïŒŽïŒïŒ¥ïŒMiïŒDen.ïŒ12.5ïŒ
2.0ïŒ717ïŒ23.3 å®æœäŸ 23 æ¬å®æœäŸã§ã¯æ¬çºæã®ã¢ãŸã¡ãã³ïŒå ±ïŒéåäœ
ç¹ç¶ã¯ãŽã äžã§å ç±çæãããå Žåãè¯å¥œã«åŒ·åºŠ
ãä¿æããããšã瀺ãã å®æœäŸ16ã®å ±éåäœè©ŠæïŒÎ·inhïŒ1.2ïŒãã€ã
ããå ±éåäœã®æ£ã玡糞ãïŒçŽ¡ç³žå£é枩床ïŒ250
ã252âïŒã288ã1271ïœïŒåã®ç¯å²ã§è¥å¹²ã®ç¹ç¶
ããã³ãæ²åãã1271ïœïŒåã§éããããã³ã«å¯Ÿ
ããŠã¯ãã€ã©ã¡ã³ãïŒïŒ¥ïŒMiïŒDen.ïŒ6.4ïŒ
1.1ïŒ717ïŒ4.3ã§ãã€ãã ãããã®ãã€ã©ã¡ã³ã30æ¬ãäºãã«å糞ããŠ
ïŒïŒåïŒã€ã³ãïŒç³žã«ãã230âã§ïŒæéç±åŠçã
ãŠç³žã«ãããåŠçãã糞ã¯ïŒŽïŒïŒ¥ïŒMiïŒDen.ïŒ
11.4ïŒ1.3ïŒ906ïŒ120.5ã®æ§è³ªã瀺ãããã®ç³žïŒæ
ãïŒåïŒã€ã³ãïŒããŽã äžã§åŠçããŠåè©Šéšã
ãããã®çµæãäžèšã«ç€ºãã 糞詊æïŒé·ãçŽ20ã€ã³ãïŒã倫ã é·ãçŽïŒã€ã³
ãã®ïŒæã®ãŽã æ¿ã®éã«é·ææ¹åã«å ¥ãããéã«
糞ãæ¿å ¥ãããŽã æ¿ãäºãã«ãã€ãããšã¯ã©ã³ã
ããçªåºãã糞ã®ç«¯ãããŒãã§æ¢ããŠæããä¿æ
ããããè©Šæçã空æ°äžã§24æé165âã§å ç±ã
ãåŸã宀枩ã«å·åŽãããããåŸç³žã®ç«¯ãã€ã³ã¹ã
ãã³è©Šéšæ©ã«ã¯ã©ã³ãããå蟌ãã 糞ã®ç Žæ匷床
ã決å®ããã é«ã¢ãã³å«éåã³äœã¢ãã³å«éã®å¥ã ã®ãŽã å
ææãçšããã 次ã®çµæãåŸãã ãŽã åææ æå€§ç Žæè·é ãã³ã ïœïŒïœ é«ã¢ãã³å«é 2.83 10.7 äœã¢ãã³å«é 2.61 9.8 ãããã®å€ã¯å€«ã 匷床ã94ïŒ åã³86ïŒ ä¿æãã
å€ã§ããã å®æœäŸ 24 æ¬å®æœäŸã¯ãããªãâïŒâã¡ãã«âïŒïŒïŒâã
ãšãã¬ã³ãããªããã¡ããªãã€ã³ãâïŒïŒïŒâã
ãšãã¬ã³ã¡ããªãã€ã³ãšãããªãâïŒïŒïŒâããš
ãã¬ã³ã¡ããªãã€ã³åäœãïŒïŒïŒïŒïŒã®å²åã§å«
ãŸããäžèŠåå ±éåäœã®æº¶è補é æ³ã瀺ãã æ¹ææ©ãçªçŽ å¹èŸŒç®¡åã³èžçããããåãã
250mlã®äžãå£ãã©ã¹ã³ã«ïŒâã¡ãã«âïŒïŒïŒâ
ããšãã¬ã³ãžã¢ãã³ïŒ7.32ïœã0.06ã¢ã«ïŒãïŒâ
ã¢ãããã³ãºã¢ã«ãããããªãªãŽããŒãã1.58ïœã
0.015ã¢ã«ãηinhïŒ0.08ãã¢ã³ãã©ãã©ããª
ãŒãºïŒLaboratoriesïŒãç±³åœããŠãšãŒã¯å·ãã¬ã³
ãŽãŠãŒïŒPlainviewïŒè£œããåã³ïŒ®ïŒNâ²âïŒïŒïŒ
ïŒâããšãã¬ã³ã¡ããªãã€ã³ïŒãžã¢ããªã³
ïŒ17.88ïœã0.06ã¢ã«ïŒãå ãããäžç·ã«ããæå
ãæ¹æããçªçŽ äžã§30åé250âã«å ç±ããã次
ã«ïŒmmïœã®æžå§äžã§250âã«10åéå ç±ããã
ããåŸåå¿æ··åç©ïŒå åŠçç°æ¹æ§ããã€æº¶èç©ïŒ
ã宀枩ã«å·åŽãããå ç±äžæ°Žåã³ã¢ããªã³ã®éå
å¯æç©ãèžçãæéãããåŸãããåºäœå ±éåäœ
ãéããé åç©äžã§ç Žç ãããã®äžã§ã¢ã»ãã³ã§
æŽæµãã80âã«ãããŠç空也ç¥ãããηinhïŒ3.2ã
PMTïŒ210âã®å ±éåäœ13.3ïœãåŸããããã¯å
åŠçç°æ¹æ§ããã€æº¶èç©ãçããã å ±éåäœã®æ£ãïŒåã®çŽ¡ç³žå£éãåã®çŽåŸ
0.009inïŒ0.023cmïŒã玡糞å£é枩床230âã溶èåºå
枩床225âããéããŠç©ºæ°äžã«æº¶è玡糞ããåŸã
ããç¹ç¶ã500ydïŒåïŒ457.2ïœïŒïŒåã§æ²åãã
玡糞æã®ç¹ç¶ã®ãã€ã©ã¡ã³ãã®æ§è³ªã¯ïŒŽïŒïŒ¥ïŒ
MiïŒDen.ïŒ3.7ïŒ0.7ïŒ556ïŒ7.2ã§ãã€ãããã®ç¹
ç¶ã®äžéšããã¢ã€ããŒã»ãã©ãã¯ã¹ã»ããã³ã«æ²
ä»ããçªçŽ æ°æµäžã§240âã§ïŒæéçäžã§å ç±ã
ããåŠçãããã€ã©ã¡ã³ãã®æ§è³ªã¯ïŒŽïŒïŒ¥ïŒ
MiïŒDen.ïŒ10.3ïŒ1.7ïŒ659ïŒ7.2ã§ãã€ãã 第äºéš ãããªãâïŒâã¡ãã«âïŒïŒïŒâããšãã¬ã³ã
ããªããã¡ããªãã€ã³âïŒâã¯ããâïŒïŒïŒâã
ãšãã¬ã³ã¡ããªãã€ã³åã³ãããªãâïŒïŒïŒâã
ãšãã¬ã³ã¡ããªãã€ã³åäœïŒïŒïŒïŒïŒïŒïŒãå«ã
å ±éåäœãã€ããããã®å ±éåäœã¯å åŠçç°æ¹æ§
ã®ãã溶èç©ãçãããäžèšç¬¬äžéšã®æ¹æ³ãç¹°è¿
ãããã4.88ïœïŒ0.04ã¢ã«ïŒã®ãžã¢ãã³ã2.12ïœ
ïŒ0.02ã¢ã«ïŒã®ããªãªãŽããŒãåã³12.74ïœïŒ0.04
ã¢ã«ïŒã®ïŒ®ïŒNâ²âïŒïŒâã¯ããâïŒïŒïŒâããš
ãã¬ã³ã¡ããªãã€ã³ïŒãžã¢ããªã³ãçšãã250â
ã«ãããŠå€§æ°å§ã§20åéå ç±ããåŸã20åã10mm
ïœã®å§åã§250âã«å ç±ãããηinhïŒ1.5ã
PMTïŒ230âã®å ±éåäœ11.7ïœãåŸãããããã®
ãã®ã¯å åŠçç°æ¹æ§ããã€æº¶èç©ãçæããã å®æœäŸ 25 æ¬å®æœäŸã¯ããªïŒãããªãâïŒâã¡ãã«âïŒïŒ
ïŒâããšãã¬ã³ãããªãã¡ããªãã€ã³â2.6âã
ããã¬ã³ã¡ããªãã€ã³ïŒã®è£œé æ³ã瀺ãã æ¹ææ©åã³èžçããããåããåå¿å®¹åšã«ãã
ãŠãïŒâã¡ãã«âïŒïŒïŒâããšãã¬ã³ãžã¢ãã³
ïŒ1.22ïœã0.01ã¢ã«ïŒåã³ïŒ®ïŒNâ²âïŒïŒïŒïŒâã
ããã¬ã³ãžã¡ããªãã€ã³ïŒâãžã¢ããªã³ïŒ3.3ïœã
0.01ã¢ã«ïŒãå ããããããã®åå¿åæã250â
ã§20åé溶èãæ¹æãããã¢ããªã³å¯æç©ãèžç
ãæéãããåå¿çæç©ãå·åŽããæéããã¢ã»
ãã³ã§æŽæµãã也ç¥ããŠPMTïŒ245âãηinhïŒ
0.6ã®éåäœ3.22ïœãåŸãããã®ãã®ã¯å åŠçç°
æ¹æ§ã®ãã溶èç©ãçããã ïŒNâ²âïŒïŒïŒïŒãããã¬ã³ãžã¡ããªãã€ã³ïŒ
ãžã¢ããªã³ã¯å ããšãã¬ã³ã°ãªã³ãŒã«ãžã¡ãã«ãš
ãŒãã«ïŒ150mlïŒäžã§ïŒïŒïŒâãããã¬ã³ãžã«ã«
ããã«ã¯ãã©ã€ãïŒ50.6ïœã0.02ã¢ã«ïŒãããšã
ã¬ã³ã°ãªã³ãŒã«ãžã¡ãã«ãšãŒãã«ïŒ700mlïŒäžã«
ãªããŠã ããªâïœâãããã·ã¢ã«ãããŠã ãã€ã
ã©ã€ãïŒ103ïœïŒãå«ã溶液ã§éå ããããšã«ã
ãã€ãã€ãããžé žã¯ãã©ã€ããçªçŽ äžã«ãããŠâ
70âã«ãããŠæ¹æãããéå å€ãïŒæé以äžæ»Žäž
ãããããåŸäžç·ã«ããæåãäžæ©æ¹æãã宀枩
ãŸã§æž©ãããåå¿æ··åç©ãæ°·ã®äžã«æ³šããæ²æŸ±ã
ãçœè²çæç©ãéããé«æž©ïŒæ²žéš°ïŒ2Bã¢ã«ã³ãŒ
ã«ã§ãªã湿ã€ãŠããæã«æœåºãããé«æž©ã¢ã«ã³ãŒ
ã«ãšæ®çåºäœãåé¢ããã¢ã«ã³ãŒã«æœåºç©ãèžç
ããŠç²è£œé»è²çµæ¶ã®ïŒïŒïŒâãããã¬ã³ãžã¢ã«ã
ãããèç¹162ã190âïŒæº¶èããªãç©è³ªãè¥å¹²æ®
ãïŒãæ®ã€ãã次ã«ç²è£œãžã¢ã«ãããïŒ4.0ïœïŒ
ãæ¹æããªãããšã¿ããŒã«ïŒ200mlïŒäžã«æº¶è§£ã
ãããã®æº¶æ¶²ã«ã¢ããªã³ïŒïŒmlïŒãå ãããåå¿
æ··åç©ãäžç·ã«ïŒæééæµãããå·åŽãäžèšã®ãž
ã¢ããªã³ã®é»è²æ²æŸ±ãéããæŽæµãã也ç¥ããã
èç¹ïŒ180ã182âã äžèšè¡šïŒå®æœäŸ26ã38ïŒã«ãããŠã¯ãæ¬çºæ
ã®æº¶æ¶²éåæ³ïŒå³ã¡HMPAãNMPãLiClãAA
åæ¢å€ïŒã«ããã€ããããæ¬çºæã®ä»ã®å åŠçç°
æ¹æ§ããã€ã溶èç©ãçããã¢ãŸã¡ãã³ïŒå ±ïŒé
åäœãç¹ç¶åã³ãã€ã«ã ã瀺ãã䜿çšãããžã¢ã
ã³åå¿åæã«ã¯ïŒâã¡ãã«âïŒïŒïŒâããšãã¬ã³
ãžã¢ãã³ãïŒïŒïŒâãžã¢ã»ãã«ãã³ãŒã³ãã¹ãã
ã©ãŸã³ãïŒïŒïŒâãžã¯ããâïŒïŒïŒâããšãã¬ã³
ãžã¢ãã³ãïŒïŒïŒâãã¹ïŒïŒâã¢ããããšãã«ïŒ
ãšã¿ã³ããã¹ïŒïŒâã¢ããããšãã«ïŒã¡ã¿ã³ãã
ã¹ïŒïŒâã¢ããããšãã«ïŒããªãšãŒãã«ãïŒïŒïŒ
âãžã¢ããããã¿ãªã³ãïŒâã¯ããâïŒïŒïŒâã
ãšãã¬ã³ãžã¢ãã³ããããµã¡ãã¬ã³ãžã¢ãã³åã³
ïŒâã¢ãããã³ãŸã€ã«ããã©ãžãããå«ãŸããã
䜿çšãããžã¢ã«ãããåå¿åæã«ã¯ïŒâã¯ããã
ã¬ãã¿ã«ã¢ã«ããããïŒïŒïŒâãã¹ïŒïŒâããªã«
ãã«ããšãã«ïŒãšã¿ã³ãïŒïŒïŒâãžã¯ãããã¬ã
ã¿ã«ã¢ã«ãããããã¬ãã¿ã«ã¢ã«ããããïŒïŒïŒ
âãã¹ïŒïŒâããªã«ãã«ããšããã·ïŒãšã¿ã³ã
ïŒïŒïŒâãžã¯ãããã¬ãã¿ã«ã¢ã«ãããããã¬ã
ã¿ã«ã¢ã«ããããïŒïŒïŒâãã¹ïŒïŒâããªã«ãã«
ããšããã·ïŒãšã¿ã³ãïŒïŒ4â²âãžãã³ãºã¢ã«ãã
ãåã³ã€ãœãã¿ã«ã¢ã«ããããå«ãŸããã å®æœäŸ26ã«ãããŠã¯ãã¹ããã©ãŸã³ãçšããã
ãã®ãã®ã¯ïŒïŒïŒâãžã¢ã»ãã«ãã³ãŒã³ãéå°ã®
ããã©ãžã³æ°Žåç©ãš2Bã¢ã«ã³ãŒã«äžã§éæµïŒ48
æéïŒãããŠåå¿æ··åç©ãå·åŽããèç¹184âã®
çæç©ãåŸãããšã«ããã€ãããå®æœäŸ35ã§çšã
ããžã¢ã«ãããã¯å ãïŒïŒïŒâãã¹ïŒïŒâã«ã«ã
ãã·ããšããã·ïŒãšã¿ã³ã®ãžã¡ãã«ãšã¹ãã«ãã
ãã©ããããã©ã³äžã«ãããŠLiAlH4ã§éå ãã
ïŒïŒïŒâãã¹ïŒïŒâããããã·ã¡ãã«ããšãã
ã·ïŒãšã¿ã³ãèç¹174ã176âãã€ããããšã«ãã€
ãŠã€ãããããããããžã€ãŒãã«ã»ãªãŽã»ãªãŒã¬
ããã¯ã»ã±ãã¹ããªãŒïŒJ.Org.Chem.ïŒèª32ïŒ
3865ãïŒïŒ1967ïŒèšèŒã®äžè¬çæ¹æ³ã§ç¡é žã¢ã³ã¢
ããŠã ã»ãªãŠã ã§æ°·é ¢é žïŒæ°Žäžã«ãããŠé žåããŠ
ææã®ãžã¢ã«ãããã«ãããèç¹112.5ã114âã å®æœäŸ36ã«çšãããžã¢ã«ãããã¯ããã©ããã
ãã©ã³äžã«ãããŠïŒïŒ4â²âãå®æ¯éŠé žã®ãžã¡ãã«
ãšã¹ãã«ãLiAlH4ã§çŽïŒâã«ãããŠéå ããè
ç¹190ã192âã®ïŒïŒ4â²âããã³ãžã«ã¢ã«ã³ãŒã«ã«
ããããšã«ããã€ããããããã®ã¢ã«ã³ãŒã«ããž
ã€ãŒãã«ã»ãªãŒã¬ããã¯ã»ã±ãã¹ãªãŒèª32ïŒ3865
ãïŒïŒ1967ïŒèšèŒã®äžè¬çæ¹æ³ã«ããæ°·é ¢é žïŒæ°Ž
äžã«ãããŠç¡é žã¢ã³ã¢ããŠã ã»ãªãŠã ã§é žåããŠ
ææã®ãžã¢ã«ãããã«ããããã®ãžã¢ã«ãããã®
èç¹ã¯141ã143âã§ããããã¹ãŠã®ç€ºãããããŒ
ã«ã¯ãã€ã©ã¡ã³ãã®å€ã§ãããïŒåã®çŽ¡ç³žå£é
ãåã®çŽåŸ0.009inïŒ0.023cmïŒããéããŠç¹ç¶ã溶è
玡糞ããã ãè¡šã ãè¡šã ãè¡šã
â
ïŒ å ç±åŠçç¹ç¶(çäžãïŒé°å²æ°ããã€ããŒã
ãã©ãã¯ã¹ ã§è¢«èŠããããã³ïŒ235âã3hr)ïŒãã€ã©
ã¡ã³ãã®TãEå¡«MiãDen.ïŒ6.6ã1.4ã517ã37ã
ïŒïŒ å ç±åŠçTãEãMiãDen.ïŒ15ã3.7ã455ã4ã
å®æœäŸ 39 æ¬å®æœäŸã§ã¯æ¬çºæã®åŒåŒµç¹æ§ã¯å ç±åŠçãçš
ããããšã«ããèããå¢åŒ·ãããããšã瀺ããã
ã®å·¥çšã®é²åºæéãçãããåã¯é²åºæž©åºŠãäœã
å ŽåãäŸç€ºããã 第äžéš å®æœäŸ37ã®çŽ¡ç³žãããŸãã®ã¢ãŸã¡ãã³å ±éåäœ
ãã€ã©ã¡ã³ãïŒïŒŽïŒïŒ¥ïŒMiïŒDen.ïŒ3.4ïŒ1.2ïŒ
353ïŒ4.7ïŒãå糞ããŠç³žïŒïŒãã€ã©ã¡ã³ãïŒã«
ããã¿ã«ã¯ã®ãããã«éãã次ãã§ãã¢ã€ããŒã»
ãã©ãã¯ã¹ã§è¢«èŠããéå±ããã³ã«æ²ãããã®
è©ŠæãçªçŽ ãæµããçã®äžã«å ¥ãããã®æž©åºŠã40
åã§å®€æž©ãã150âã«äžãã20åéãã®äžã«ä¿ã€ã
è©Šæãçäžã§çŽ50âã«å·åŽããçããååºãã宀
æž©ã«å·åŽãããåŠçããç¹ç¶ã¯ïŒŽïŒïŒ¥ïŒMiïŒ
Den.ïŒ9.2ïŒ2.0ïŒ439ïŒ5.7ã®æ§è³ªã瀺ãããã®åŠ
çããç¹ç¶ã®äžéšãããã³ã«æ²ããåã³çäžã«ã
ããŠå ç±ãïŒçªçŽ äžã«ãããŠïŒã40åéã«äºã宀
æž©ãã260âã«å ç±ããïŒæé20åé260âã«ä¿
ã€ããããåŸå·åŽããäžè¿°ã®æ¡ä»¶äžã§é€å»ããã
ãã®åŠçããç¹ç¶ã®ãã€ã©ã¡ã³ãã¯ïŒŽïŒïŒ¥ïŒ
MiïŒDen.ïŒ20.0ïŒ3.8ïŒ470ïŒ5.5ã瀺ãã äžèšç¬¬äºéšåã³ç¬¬äžéšã«ãããŠã¯ãåèŠæ§é å
äœ ïŒïŒ®âR1âïŒHCâR2âCHïŒ ããæãã¢ãŸã¡ãã³ïŒå ±ïŒéåäœã®ç¹ç¶ãçšã
ãã第äºéšã«ãããŠã¯éåäœã¯å®æœäŸ17ã§ã€ãã
ãããã®ã«çžåœããããå®æœäŸ24ã®äžè¬ç溶èé
åæ³ã«ãã€ãŠã€ãã€ãã第äžéšã«ãããŠã¯ãéå
äœã¯ç¬¬äºéšãšåæ§ã«ã€ãããããã溶液éåæ³ã«
ãã€ãŠã€ãã€ãã䜿çšããå ±éåäœãšç¹ç¶ã¯å®æœ
äŸ37ã®ãã®ã§ãã€ãã玡糞ã¯åè¿°ãšåãããã«è¡
ãªã€ãã 第äºéš ãã®åŠçã«ãããŠã¯çŽ¡ç³žããããªã¢ãŸç¹ç¶ãçª
çŽ é°å²æ°äžã«ãããŠè¡šèšã®æž©åºŠã«ãããŠ20ç§éå
äžããããã®åæéã®åŠçã«ããåŒåŒµç¹æ§ã¯èã
ãå¢åŒ·ãããã ãè¡šã 第äžéš ãã®åŠçã«ãããŠã¯çŽ¡ç³žæã®ã¢ãŸã¡ãã³ïŒå ±ïŒ
éåäœç¹ç¶ããã¢ã€ããŒã»ãã©ãã¯ã¹ã§è¢«èŠã
ãéå±ããã³ã«æ²ããçïŒçªçŽ é°å²æ°ïŒäžã§äžèš
ã«ç€ºã枩床ã§ïŒæéå ç±ãããè¡šã«ç€ºãããã«
䜿çšããåŠç枩床ã«ãããŠç¹ç¶ã®åŒåŒµç¹æ§ã¯èã
ãæ¹åãããã ãè¡šã å®æœäŸ 40 äžèšè¡šã®åèŠæ§é åäœãåŒãåŒã ã«çžåœããå åŠçç°æ¹æ§ã®æº¶èç©çæã¢ãŸã¡ãã³
ïŒå ±ïŒéåäœã瀺ãã ïŒå ±ïŒéåäœã¯æ°ããåæããïŒâã¢ãããã³
ãºã¢ã«ããããïŒâã¡ãã«âïŒâã¢ãããã³ãºã¢
ã«ããããåã³ïŒâã¡ãã«âïŒâã¢ãããã³ãºã¢
ã«ãããããéžã°ããåå¿åæã®æº¶èéåã«ãã
ã€ãã€ããé ç®ïŒãïŒã«å¯Ÿããå žåçæ¹æ³ã«ãã
ãŠã¯ãé©åœãªåéäœïŒå€«ã çŽ0.02ã¢ã«ïŒãæ¹æ
æ©ãèžçãããåã³çªçŽ å¹èŸŒç®¡ãåä»ããåå¿å®¹
åšäžã§ã¢ããªã³ïŒïŒmlïŒãšå ±ã«å ãããæ¹æãã
åå¿åæãçªçŽ äžã«ãããŠ250âã«ä¿ããã油济
äžã§0.5æéå ç±ããã次ã«çªçŽ ãæµãã®ãæ¢ãã
åå¿åæã1.0mmïœä»¥äžã®å§åã§250âã§0.5æ
éå ç±ïŒæ¹æïŒãããåå¿æ··åç©ãå·åŽããçæ
ç©ãæéããã¢ã»ãã³ã§æŽæµãã也ç¥ããã é ç®ïŒã®å ±éåäœã«å¯ŸããŠã¯ãåã¢ãããã³ãº
ã¢ã«ããã0.096ã¢ã«ãšã¡ãã«âïŒïŒïŒâããšã
ã¬ã³ãžã¢ãã³ïŒç²åºŠå®å®å€ãšããŠäœ¿çšïŒ0.0057ã¢
ã«ãšããã·ã¬ã³ïŒ350mlïŒåã³ããªãã«ãªãé ¢é ž
ïŒ0.25mlïŒãšäžç·ã«ãããåå¿æ··åç©ãïŒæéé
æµããïŒãã³ãŒã³âæ°Žå ±æ²žæ··åç©ãé€å»ããïŒã
å·åŽããå ±éåäœãçå¥ããã¢ã»ãã³ã§æŽæµãã
ç空也ç¥ãããå®æœäŸ13ã®ããã«ããŠå ±éåäœã®
æ£ã玡糞ãïŒçŽ¡ç³žå£é枩床ïŒ240âã溶èåºåæž©
床ïŒ232âïŒãç¹ç¶ã155ïœïŒåã§æ²åãã玡糞ã
ããŸãã®ç¹ç¶ã§ã¯ïŒŽïŒïŒ¥ïŒMiïŒ3.6ïŒ0.8ïŒ638ã§
ãã€ããç¹ç¶è©Šæãã¿ã«ã¯ã§åŠçãã次ãã§222
âã§163æéïŒN2ïŒã«ãããŠçäžã§å ç±ãããè©Š
æã¯é·ãïŒã€ã³ãïŒ15.2cmïŒã§ã¹ã¯ãªãŒã³äžã«æ¯
æãããŠãããå ç±åŠçããç¹ç¶ã¯ïŒŽïŒïŒ¥ïŒMi
ïŒ10.8ïŒ1.9ïŒ709ã§ãã€ãã ãè¡šã ãè¡šã
æ·»ä»å³é¢ã¯ïŒçš®ã®ç°ã€ãããªã¢ãŸã¡ãã³ã®åºäœ
åã³æº¶èç¶æ ã«å¯ŸããŠåŸãããå ã®åŒ·åºŠæ²ç·åã³
ããã¯ã°ã©ãŠã³ãééæ²ç·ã§ãããæ²ç·ïŒ¢ã¯æ¬çº
æã®éåäœã«ãããã®ã§ãããä»ã®æ²ç·ïŒ¡ã¯çæ¹
æ§æº¶èç©ãäžããéåäœã«ãããã®ã§ããã
åã³æº¶èç¶æ ã«å¯ŸããŠåŸãããå ã®åŒ·åºŠæ²ç·åã³
ããã¯ã°ã©ãŠã³ãééæ²ç·ã§ãããæ²ç·ïŒ¢ã¯æ¬çº
æã®éåäœã«ãããã®ã§ãããä»ã®æ²ç·ïŒ¡ã¯çæ¹
æ§æº¶èç©ãäžããéåäœã«ãããã®ã§ããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ éåäœæº¶è枩床ã375âããäœããåºæç²åºŠ
ãå°ããšã0.2ã§ãã€ãŠã溶èç¶æ ã§å åŠçç°æ¹
æ§ã瀺ãäžã€å»¶äŒžããããšãªãã«é åãã€ã©ã¡ã³
ãã«æº¶è玡糞å¯èœã§ãããäžèšåäœ () ïŒïŒïŒ®âR1âïŒïŒ () ãåŒã åã³ () ãåŒã äœãåäœåã³ã¯ããååšãããªãã°å®è³ªç
ã«çã¢ã«éã§ååšããZ1ïŒZ2åã³Z3ã¯åäžåã¯çž
ç°ãããšãã§ããæ°ŽçŽ ååãåã¯ã¡ãã«åã¯ãšã
ã«åºããéžã°ããR1ïŒR2åã³R3㯠(1) åäžåã¯èåããççŽ ç°åŒå å¡ç°ç³»ã§ãã€
ãŠãè³éŠæãããååšãããªãã°ãã®è³éŠç°ã®
ç°ççŽ ã®äžã€ã¯çªçŽ ã§çœ®æããããããšãã§
ãã該ç°ç³»ã®é£é䌞匵çµåã¯ã該çµåãããå
äžç°ã«çµåããŠãããªãã°äºãã«ïŒïŒïŒã®äœçœ®
ã«äœçœ®ããããç°ã€ãç°ã«çµåããŠãããªãã°
å¹³è¡ã§äžã€å察æ¹åã«åã€ãäœçœ®ã«äœçœ®ããå
äžããã³èåããççŽ ç°åŒå å¡ç°ç³»ã®åºããã³ (2) å€ç°ç³»ã§ãã€ãŠãåã ã®ç°ãååŠçµååã¯é·
ããååæ°14ãè¶ ããªãæ¶æ©åäœã«ããçµåã
ããåç°ã®é£é䌞匵çµåãïŒïŒïŒã®äœçœ®ã«ã
ããR1ã¯ãååŠçµåã§ããããšãã§ããå€ç°
ç³»ã®åº ããæã矀ããéžã°ããåºã§ããã ããéžã°ããå埩æ§é åäœããå®è³ªçã«æãããš
ãç¹åŸŽãšããã¢ãŸã¡ãã³ïŒå ±ïŒéåäœã ïŒ ïŒããã³ã®å šåäœã®æ倧40ã¢ã«ïŒ ãã
該ïŒåã³åäœä»¥å€ã®åäœã§ãã€ãŠäžã€è©²ã¢
ãŸã¡ãã³ïŒå ±ïŒéåäœã®å åŠçç°æ¹æ§æº¶èç©åœ¢æ
èœã劚害ããªãããªã¢ãŸã¡ãã³åœ¢ææ§åäœã«ãã€
ãŠçœ®æããããŠããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®
ã¢ãŸã¡ãã³ïŒå ±ïŒéåäœã ïŒ åäœåã³ããå®è³ªçã«ãªãéåäœã®ç¹èš±
è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®ã¢ãŸã¡ãã³ïŒå ±ïŒéå
äœã ïŒ R1ãïŒïŒïŒâããšãã¬ã³ãã¯ããâããã
ã¢âãã¡ããã·âããã«ãªãâãã¡ãã«âããã
ããã·âãåã³ãããâïŒïŒïŒâããšãã¬ã³ã
ïŒïŒ4â²âãããšãã¬ã³ãïŒïŒ3â²âãžã¡ãã«âïŒïŒ
4â²âãããšãã¬ã³ãïŒïŒïŒâã¡ãã¬ã³ãžããšãã¬
ã³ãïŒïŒ4â²âãžã¡ãã¬ã³ãžããšãã¬ã³ãïŒïŒ4â²â
ããªã¡ãã¬ã³ãžããšãã¬ã³ãïŒïŒ4â²âããã©ã¡ã
ã¬ã³ãžããšãã¬ã³ãïŒïŒïŒâãããã¬ã³ãïŒïŒïŒ
âãããã¬ã³ãïŒïŒïŒâãžã¯ããâïŒïŒïŒâããš
ãã¬ã³ããã©ã³ã¹âïŒïŒïŒâã·ã¯ãããã·ã¬ã³ã
ãã©ã³ã¹âïŒâã¡ãã«âïŒïŒïŒâã·ã¯ãããã·ã¬
ã³ããã©ã³ã¹âïŒïŒ4â²âã¡ãã¬ã³ãžã·ã¯ãããã·
ã¬ã³ãïŒïŒ3â²âãžã¡ãã«âïŒïŒ4â²âããã©ã¡ãã¬
ã³ãžãªãã·ãžããšãã¬ã³ãïŒïŒ4â²âã¢ãŸãã·ããš
ãã¬ã³ãïŒïŒ3â²âãžã¡ãã«âïŒïŒ4â²âã¢ãŸãžããš
ãã¬ã³åã³ååŠçµåããæã矀ããéžã°ããR2
ã¯ïŒïŒïŒâããšãã¬ã³ãã¯ããâïŒïŒïŒâããšã
ã¬ã³ãã¡ãã«âïŒïŒïŒâããšãã¬ã³ãïŒïŒ4â²âã
ããšãã¬ã³ãïŒïŒ4â²âãªãã·ãžããšãã¬ã³ãïŒïŒ
4â²âãšãã¬ã³ãžããšãã¬ã³ãïŒïŒ4â²âã¡ãã¬ã³ãž
ããšãã¬ã³ãïŒïŒ4â²âãšãã¬ã³ãžãã·ãžããšãã¬
ã³ãïŒïŒïŒâããªãžã³ãžãã«ãïŒïŒïŒâãããã¬
ã³ãïŒïŒïŒâãããã¬ã³ãïŒïŒïŒâãããã¬ã³ã
ïŒïŒïŒâãžã¯ããâïŒïŒïŒâããšãã¬ã³ãïŒïŒïŒ
âãžããã¢âïŒïŒïŒâããšãã¬ã³ãïŒïŒïŒâãžã¡
ããã·âïŒïŒïŒâããšãã¬ã³ãïŒâããã¢âïŒïŒ
ïŒâããšãã¬ã³ãïŒâã¡ããã·âïŒïŒïŒâããšã
ã¬ã³ãåã³ïŒâããããã·âïŒïŒïŒâããšãã¬ã³
åºããæã矀ããéžã°ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé
èšèŒã®ã¢ãŸã¡ãã³ïŒå ±ïŒéåäœã ïŒ åäœåã³ã®ç°ç³»ã®å šæ°ã®å°ããšã25ïŒ ã
ã¯ããåã³ã¡ãã«åºããæã矀ããéžã°ããåºã§
æ žçœ®æãããŠããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®ã¢
ãŸã¡ãã³ïŒå ±ïŒéåäœã ïŒ R1ãã¡ãã«âïŒïŒïŒâããšãã¬ã³ã§ããç¹
èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®ã¢ãŸã¡ãã³ïŒå ±ïŒéå
äœã ïŒ R1ãïŒïŒïŒâããšãã¬ã³ã§ããç¹èš±è«æ±ã®
ç¯å²ç¬¬ïŒé èšèŒã®ã¢ãŸã¡ãã³ïŒå ±ïŒéåäœã ïŒ ïŒçš®ä»¥äžã®åäœãååšããç¹èš±è«æ±ã®ç¯å²
第ïŒé èšèŒã®ã¢ãŸã¡ãã³ïŒå ±ïŒéåäœã ïŒ R2ãã¯ããâïŒïŒïŒâããšãã¬ã³ã§ããç¹
èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®ã¢ãŸã¡ãã³ïŒå ±ïŒéå
äœã ïŒïŒ R2ãïŒïŒïŒâããšãã¬ã³ã§ããç¹èš±è«æ±
ã®ç¯å²ç¬¬ïŒé èšèŒã®ã¢ãŸã¡ãã³ïŒå ±ïŒéåäœã ïŒïŒ åäœã®ç°ç³»ã®å°ããšã25ïŒ ãã¯ããâå
ã³ã¡ãã«åºããæã矀ããéžã°ããåºã§çœ®æãã
ãŠããå®è³ªçã«åäœããæãç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé èšèŒã®ã¢ãŸã¡ãã³ïŒå ±ïŒéåäœã ïŒïŒ æ«ç«¯ãå°éãããŠããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒ
é èšèŒã®ã¢ãŸã¡ãã³ïŒå ±ïŒéåäœã ïŒïŒ æ«ç«¯ãå°éãããŠããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒ
é èšèŒã®ã¢ãŸã¡ãã³ïŒå ±ïŒéåäœã ïŒïŒ éææ«ç«¯å°éå€ãååšãããåŒ H2NâR1âNH2 ã®ãžã¢ãã³ãåŒãåŒã ã®ãžã¢ã«ãããåã¯ãžã±ãã³ãšãåã³éæåŒ
ãåŒã ã®ã¢ããã¢ã«ãããåã¯ã¢ããã±ãã³æãã¯ãã®
ãããªåæã®å®èœæ§åçèªå°äœãšã äœãäžèšã«æŒãŠã R1ïŒR2åã³R3㯠(1) åäžåã¯èåããççŽ ç°åŒå å¡ç°ç³»ã§ãã€
ãŠãè³éŠæãããååšãããªãã°ãã®è³éŠç°ã®
ç°ççŽ ã®äžã€ã¯çªçŽ ã§çœ®æããããããšãã§
ãã該ç°ç³»ã®é£é䌞匵çµåã¯ã該çµåãããå
äžç°ã«çµåããŠãããªãã°äºãã«ïŒïŒïŒã®äœçœ®
ã«äœçœ®ããããç°ã€ãç°ã«çµåããŠãããªãã°
å¹³è¡ã§äžã€å察æ¹åã«åã€ãäœçœ®ã«äœçœ®ããå
äžããã³èåããççŽ ç°åŒå å¡ç°ç³»ã®åºããã³ (2) å€ç°ç³»ã§ãã€ãŠãåã ã®ç°ãååŠçµååã¯é·
ããååæ°14ãè¶ ããªãæ¶æ©åäœã«ããçµåã
ããåç°ã®é£é䌞匵çµåãïŒïŒïŒã®äœçœ®ã«ã
ããR1ã¯ãååŠçµåã§ããããšãã§ããå€ç°
ç³»ã®åº ããæã矀ããéžã°ããåºã§ãããZ1ïŒZ2åã³Z3
ã¯åäžåã¯çžç°ãããšãã§ããæ°ŽçŽ ååãåã¯ã¡
ãã«åã¯ãšãã«åºããéžã°ãããã®ã§ããã åå¿ãããããšãç¹åŸŽãšããéåäœæº¶è枩床ã
375âããäœããåºæç²åºŠãå°ããšã0.2ã§ãã€
ãŠã溶èç¶æ ã§å åŠçç°æ¹æ§ã瀺ãäžã€å»¶äŒžãã
ããšãªãã«é åãã€ã©ã¡ã³ãã«æº¶è玡糞å¯èœã§ã
ãã¢ãŸã¡ãã³ïŒå ±ïŒéåäœã®è£œæ³ã
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US57623675A | 1975-05-09 | 1975-05-09 | |
| US667431 | 1976-03-19 | ||
| US576236 | 1990-08-31 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59113033A JPS59113033A (ja) | 1984-06-29 |
| JPS6351176B2 true JPS6351176B2 (ja) | 1988-10-13 |
Family
ID=24303525
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58219664A Granted JPS59113033A (ja) | 1975-05-09 | 1983-11-24 | ã¢ãŸã¡ãã³ïŒå ±ïŒéåäœåã³ãã®è£œæ³ |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JPS59113033A (ja) |
| BE (1) | BE841594A (ja) |
| ZA (1) | ZA762745B (ja) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPWO2011102330A1 (ja) * | 2010-02-18 | 2013-06-17 | ç¶ç ååŠæ ªåŒäŒç€Ÿ | æ°èŠããªã¢ãŸã¡ãã³ |
-
1976
- 1976-05-07 BE BE166850A patent/BE841594A/fr not_active IP Right Cessation
- 1976-05-07 ZA ZA762745A patent/ZA762745B/xx unknown
-
1983
- 1983-11-24 JP JP58219664A patent/JPS59113033A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| BE841594A (fr) | 1976-11-08 |
| JPS59113033A (ja) | 1984-06-29 |
| ZA762745B (en) | 1977-06-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS6154815B2 (ja) | ||
| US4122070A (en) | Fibers and anisotropic melts of polyazomethines | |
| Morgan et al. | Aromatic azomethine polymers and fibers | |
| CA1174788A (en) | Poly(ester-amide) capable of forming an anisotropic melt phase derived from 6-hydroxy-2-naphthoic acid, dicarboxylic acid and aromatic monomer capable of forming an amide linkage | |
| US4351917A (en) | Poly(ester-amide) capable of forming an anisotropic melt phase derived from 6-hydroxy-2-naphthoic acid, aromatic monomer capable of forming an amide linkage, and other aromatic hydroxyacid | |
| JP5535069B2 (ja) | çµæ¶åå¯èœããªãšãŒãã«ã€ããé¡ãšãã®è£œé æ¹æ³ããã³åææããèªå°ãããç©å | |
| JPH0240685B2 (ja) | ||
| JPS6354805B2 (ja) | ||
| JPS633891B2 (ja) | ||
| EP0063881A1 (en) | Poly(ester-amide) derived from p-hydroxybenzoic acid, 2,6-naphthalene-dicarboxylic acid and aromatic monomer capable of forming an amide linkage | |
| JPS581722A (ja) | ç°æ¹æ§æº¶èçžã圢æããã溶èå å·¥æ§ããªïŒãšã¹ãã«âã¢ããïŒ | |
| JPH0192410A (ja) | ç¹ç¶çææ§ããªãšã¹ãã«å ±éåäœã®ãã€ã©ã¡ã³ã | |
| JPS588727A (ja) | å åŠçç°æ¹æ§ãéãèç©åœ¢ææ§ã³ããªãšã¹ãã« | |
| US4966956A (en) | Aromatic thermotropic copolyesteramide | |
| JPS60147434A (ja) | å åŠçç°æ¹æ§ããã€çèç©ãçããããªãšã¹ãã«å ±éåäœ | |
| US4309531A (en) | Flexible/rigid copolyamide | |
| JPS6216813B2 (ja) | ||
| JPS5831112A (ja) | ããªããšãã¬ã³ã¹ã«ãã€ãç¹ç¶ | |
| KR800001163B1 (ko) | (ìœ) íŽëŠ¬ìì¡°ë©íŽì ì ì¡°ë°©ë² | |
| Memeger Jr | Novel thermotropic main-chain polyhydrocarbons and block copoly (hydrocarbon azomethines) | |
| JPS60147433A (ja) | ããªãšã¹ãã«å ±éåäœ | |
| JPS59113033A (ja) | ã¢ãŸã¡ãã³ïŒå ±ïŒéåäœåã³ãã®è£œæ³ | |
| JPS60147436A (ja) | å åŠçç°æ¹æ§ããã€çèç©ãçããããªãšã¹ãã«å ±éåäœ | |
| JPH03149224A (ja) | ããªã¢ããããªãã³ã«è©²ããªã¢ããããåŸãããæ圢åããã£ã«ã ããã³ãã¡ã€ã㌠| |
| JPS62205128A (ja) | é«ååè€åäœã®è£œé æ³ |