KR940001032B1 - 프레스 성형성, 화성처리성 등에 뛰어난 아연계 도금강판 및 그 강판의 제조방법 - Google Patents
프레스 성형성, 화성처리성 등에 뛰어난 아연계 도금강판 및 그 강판의 제조방법 Download PDFInfo
- Publication number
- KR940001032B1 KR940001032B1 KR1019910700888A KR910700888A KR940001032B1 KR 940001032 B1 KR940001032 B1 KR 940001032B1 KR 1019910700888 A KR1019910700888 A KR 1019910700888A KR 910700888 A KR910700888 A KR 910700888A KR 940001032 B1 KR940001032 B1 KR 940001032B1
- Authority
- KR
- South Korea
- Prior art keywords
- zinc
- oxide
- steel sheet
- film
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000126 substance Substances 0.000 title claims description 75
- 238000006243 chemical reaction Methods 0.000 title claims description 65
- 229910001335 Galvanized steel Inorganic materials 0.000 title claims description 54
- 239000008397 galvanized steel Substances 0.000 title claims description 54
- 238000004519 manufacturing process Methods 0.000 title claims description 21
- 239000011701 zinc Substances 0.000 claims description 203
- 229910052725 zinc Inorganic materials 0.000 claims description 144
- 229910000831 Steel Inorganic materials 0.000 claims description 128
- 239000010959 steel Substances 0.000 claims description 128
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 116
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 109
- 238000000576 coating method Methods 0.000 claims description 95
- 239000011248 coating agent Substances 0.000 claims description 90
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 88
- 238000007747 plating Methods 0.000 claims description 82
- 239000010410 layer Substances 0.000 claims description 67
- 238000000034 method Methods 0.000 claims description 63
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 58
- 239000000243 solution Substances 0.000 claims description 56
- 239000007864 aqueous solution Substances 0.000 claims description 51
- 239000011787 zinc oxide Substances 0.000 claims description 44
- 229910052751 metal Inorganic materials 0.000 claims description 43
- 239000002184 metal Substances 0.000 claims description 43
- 229910052698 phosphorus Inorganic materials 0.000 claims description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 32
- 238000005461 lubrication Methods 0.000 claims description 31
- 229910052760 oxygen Inorganic materials 0.000 claims description 31
- 239000002253 acid Substances 0.000 claims description 30
- 229910052748 manganese Inorganic materials 0.000 claims description 30
- 239000001301 oxygen Substances 0.000 claims description 30
- 229910052782 aluminium Inorganic materials 0.000 claims description 27
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 26
- 239000004327 boric acid Substances 0.000 claims description 26
- 239000011247 coating layer Substances 0.000 claims description 23
- 229910052719 titanium Inorganic materials 0.000 claims description 23
- 229910052750 molybdenum Inorganic materials 0.000 claims description 22
- 229910052796 boron Inorganic materials 0.000 claims description 21
- 229910021645 metal ion Inorganic materials 0.000 claims description 21
- 229910052720 vanadium Inorganic materials 0.000 claims description 21
- 229910052721 tungsten Inorganic materials 0.000 claims description 20
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 19
- 239000000084 colloidal system Substances 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 14
- 229910052804 chromium Inorganic materials 0.000 claims description 13
- 230000002378 acidificating effect Effects 0.000 claims description 12
- 229910052809 inorganic oxide Inorganic materials 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 10
- 238000000465 moulding Methods 0.000 claims description 10
- 239000007800 oxidant agent Substances 0.000 claims description 9
- 150000002926 oxygen Chemical class 0.000 claims description 8
- 230000002265 prevention Effects 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 229910001853 inorganic hydroxide Inorganic materials 0.000 claims 2
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- 239000011572 manganese Substances 0.000 description 66
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 64
- 238000005755 formation reaction Methods 0.000 description 38
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 32
- 230000015572 biosynthetic process Effects 0.000 description 31
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 28
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 25
- 238000005868 electrolysis reaction Methods 0.000 description 25
- 229910017604 nitric acid Inorganic materials 0.000 description 25
- 230000000052 comparative effect Effects 0.000 description 22
- 230000001976 improved effect Effects 0.000 description 22
- 238000005096 rolling process Methods 0.000 description 22
- 230000008569 process Effects 0.000 description 20
- 239000010936 titanium Substances 0.000 description 20
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 19
- 239000011667 zinc carbonate Substances 0.000 description 19
- 235000004416 zinc carbonate Nutrition 0.000 description 19
- 229910000010 zinc carbonate Inorganic materials 0.000 description 19
- 239000011651 chromium Substances 0.000 description 17
- 230000001050 lubricating effect Effects 0.000 description 17
- 229910044991 metal oxide Inorganic materials 0.000 description 17
- 229910052742 iron Inorganic materials 0.000 description 16
- 150000004706 metal oxides Chemical class 0.000 description 16
- 150000002500 ions Chemical class 0.000 description 15
- 238000004090 dissolution Methods 0.000 description 14
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 14
- 238000003466 welding Methods 0.000 description 14
- 230000000694 effects Effects 0.000 description 13
- 238000005507 spraying Methods 0.000 description 13
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 12
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 12
- 238000007654 immersion Methods 0.000 description 12
- 239000003921 oil Substances 0.000 description 12
- 238000007739 conversion coating Methods 0.000 description 11
- 229910001297 Zn alloy Inorganic materials 0.000 description 10
- 238000005275 alloying Methods 0.000 description 10
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 10
- 238000005238 degreasing Methods 0.000 description 10
- 239000012535 impurity Substances 0.000 description 10
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 10
- 150000003839 salts Chemical class 0.000 description 10
- 229910004298 SiO 2 Inorganic materials 0.000 description 9
- 229910010413 TiO 2 Inorganic materials 0.000 description 9
- 238000007598 dipping method Methods 0.000 description 9
- 238000005406 washing Methods 0.000 description 9
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 8
- 229910045601 alloy Inorganic materials 0.000 description 8
- 239000000956 alloy Substances 0.000 description 8
- 238000004458 analytical method Methods 0.000 description 8
- 239000011324 bead Substances 0.000 description 8
- 239000011575 calcium Substances 0.000 description 8
- 229910052759 nickel Inorganic materials 0.000 description 8
- 238000003825 pressing Methods 0.000 description 8
- 229910052710 silicon Inorganic materials 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 7
- 239000011609 ammonium molybdate Substances 0.000 description 7
- 235000018660 ammonium molybdate Nutrition 0.000 description 7
- 229940010552 ammonium molybdate Drugs 0.000 description 7
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 7
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 7
- 239000013078 crystal Substances 0.000 description 7
- PYRZPBDTPRQYKG-UHFFFAOYSA-N cyclopentene-1-carboxylic acid Chemical compound OC(=O)C1=CCCC1 PYRZPBDTPRQYKG-UHFFFAOYSA-N 0.000 description 7
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 7
- 239000012286 potassium permanganate Substances 0.000 description 7
- 230000001681 protective effect Effects 0.000 description 7
- 239000000523 sample Substances 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 6
- 230000002411 adverse Effects 0.000 description 6
- -1 containing zinc Chemical compound 0.000 description 6
- 239000010949 copper Substances 0.000 description 6
- 150000004679 hydroxides Chemical class 0.000 description 6
- KFZAUHNPPZCSCR-UHFFFAOYSA-N iron zinc Chemical compound [Fe].[Zn] KFZAUHNPPZCSCR-UHFFFAOYSA-N 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- 239000002244 precipitate Substances 0.000 description 6
- 230000001737 promoting effect Effects 0.000 description 6
- 229910052802 copper Inorganic materials 0.000 description 5
- 239000010419 fine particle Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 238000004611 spectroscopical analysis Methods 0.000 description 5
- UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 230000001276 controlling effect Effects 0.000 description 4
- 238000009713 electroplating Methods 0.000 description 4
- 238000005530 etching Methods 0.000 description 4
- 229910052745 lead Inorganic materials 0.000 description 4
- 229910052749 magnesium Inorganic materials 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 239000012528 membrane Substances 0.000 description 4
- 231100000989 no adverse effect Toxicity 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 229910001392 phosphorus oxide Inorganic materials 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- VSAISIQCTGDGPU-UHFFFAOYSA-N tetraphosphorus hexaoxide Chemical compound O1P(O2)OP3OP1OP2O3 VSAISIQCTGDGPU-UHFFFAOYSA-N 0.000 description 4
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 4
- 206010040844 Skin exfoliation Diseases 0.000 description 3
- 229910052810 boron oxide Inorganic materials 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- 238000000635 electron micrograph Methods 0.000 description 3
- 238000005246 galvanizing Methods 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 239000010687 lubricating oil Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229910000000 metal hydroxide Inorganic materials 0.000 description 3
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 229920000620 organic polymer Polymers 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 229910052718 tin Inorganic materials 0.000 description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 3
- 238000007740 vapor deposition Methods 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 241000694440 Colpidium aqueous Species 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910018663 Mn O Inorganic materials 0.000 description 2
- 229910003176 Mn-O Inorganic materials 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 229910002065 alloy metal Inorganic materials 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 229910052738 indium Inorganic materials 0.000 description 2
- 150000002484 inorganic compounds Chemical class 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 239000011133 lead Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000005300 metallic glass Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 150000007522 mineralic acids Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 238000001637 plasma atomic emission spectroscopy Methods 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 229910000160 potassium phosphate Inorganic materials 0.000 description 2
- 235000011009 potassium phosphates Nutrition 0.000 description 2
- 238000006479 redox reaction Methods 0.000 description 2
- 238000006748 scratching Methods 0.000 description 2
- 230000002393 scratching effect Effects 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000001488 sodium phosphate Substances 0.000 description 2
- 229910000162 sodium phosphate Inorganic materials 0.000 description 2
- 239000011135 tin Substances 0.000 description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 2
- 229910018516 Al—O Inorganic materials 0.000 description 1
- 229910000599 Cr alloy Inorganic materials 0.000 description 1
- 229910017813 Cu—Cr Inorganic materials 0.000 description 1
- 241000350052 Daniellia ogea Species 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 229910017299 Mo—O Inorganic materials 0.000 description 1
- ZGRBQKWGELDHSV-UHFFFAOYSA-N N.[W+4] Chemical compound N.[W+4] ZGRBQKWGELDHSV-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910003077 Ti−O Inorganic materials 0.000 description 1
- 235000015414 Urena lobata Nutrition 0.000 description 1
- 240000006064 Urena lobata Species 0.000 description 1
- 229910007541 Zn O Inorganic materials 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 238000002048 anodisation reaction Methods 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000788 chromium alloy Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- UXKUODQYLDZXDL-UHFFFAOYSA-N fulminic acid Chemical compound [O-][N+]#C UXKUODQYLDZXDL-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000010406 interfacial reaction Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229940085991 phosphate ion Drugs 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- SQTLECAKIMBJGK-UHFFFAOYSA-I potassium;titanium(4+);pentafluoride Chemical compound [F-].[F-].[F-].[F-].[F-].[K+].[Ti+4] SQTLECAKIMBJGK-UHFFFAOYSA-I 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- CMPGARWFYBADJI-UHFFFAOYSA-L tungstic acid Chemical compound O[W](O)(=O)=O CMPGARWFYBADJI-UHFFFAOYSA-L 0.000 description 1
- 150000003681 vanadium Chemical class 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 239000011686 zinc sulphate Substances 0.000 description 1
- 235000009529 zinc sulphate Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D9/00—Electrolytic coating other than with metals
- C25D9/04—Electrolytic coating other than with metals with inorganic materials
- C25D9/08—Electrolytic coating other than with metals with inorganic materials by cathodic processes
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/40—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates
- C23C22/42—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates containing also phosphates
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
- C23C22/53—Treatment of zinc or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/73—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/48—After-treatment of electroplated surfaces
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/34—Anodisation of metals or alloys not provided for in groups C25D11/04 - C25D11/32
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D13/00—Electrophoretic coating characterised by the process
- C25D13/02—Electrophoretic coating characterised by the process with inorganic material
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D13/00—Electrophoretic coating characterised by the process
- C25D13/04—Electrophoretic coating characterised by the process with organic material
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Electrochemistry (AREA)
- Inorganic Chemistry (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Coating With Molten Metal (AREA)
Applications Claiming Priority (37)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1320450A JPH0635678B2 (ja) | 1989-12-12 | 1989-12-12 | プレス性,化成処理性に優れた亜鉛系めっき鋼板 |
| JP01-320450 | 1989-12-12 | ||
| JP01-328782 | 1989-12-19 | ||
| JP1328782A JPH03191092A (ja) | 1989-12-19 | 1989-12-19 | プレス性、化成処理性に優れた亜鉛系めっき鋼板 |
| JP01-328781 | 1989-12-19 | ||
| JP1328784A JPH03191094A (ja) | 1989-12-19 | 1989-12-19 | プレス性、化成処理性に優れた亜鉛系めっき鋼板 |
| JP01-328784 | 1989-12-19 | ||
| JP1328783A JPH03191093A (ja) | 1989-12-19 | 1989-12-19 | プレス性、化成処理性に優れた亜鉛系めっき鋼板 |
| JP1328781A JPH03191091A (ja) | 1989-12-19 | 1989-12-19 | プレス性、化成処理性に優れた亜鉛系めっき鋼板 |
| JP01-328783 | 1989-12-19 | ||
| JP02-048207 | 1990-02-28 | ||
| JP2048207A JPH0696779B2 (ja) | 1990-02-28 | 1990-02-28 | プレス成形性、化成処理性に優れた亜鉛系めっき鋼板 |
| JP02-048209 | 1990-02-28 | ||
| JP02-048208 | 1990-02-28 | ||
| JP2048209A JPH0713307B2 (ja) | 1990-02-28 | 1990-02-28 | プレス成形性、化成処理性に優れた亜鉛系めっき鋼板 |
| JP2048208A JPH0696780B2 (ja) | 1990-02-28 | 1990-02-28 | プレス成形性、化成処理性に優れた亜鉛系めっき鋼板 |
| JP2088695A JPH0696784B2 (ja) | 1990-04-03 | 1990-04-03 | プレス成形性、化成処理性、溶接性に優れた亜鉛系めっき鋼板 |
| JP02-088695 | 1990-04-03 | ||
| JP2088696A JPH0696785B2 (ja) | 1990-04-03 | 1990-04-03 | プレス成形性、化成処理性、溶接性に優れた亜鉛系めっき鋼板 |
| JP2088693A JPH0696782B2 (ja) | 1990-04-03 | 1990-04-03 | プレス成形性、化成処理性、溶接性に優れた亜鉛系めっき鋼板 |
| JP02-088696 | 1990-04-03 | ||
| JP02-088693 | 1990-04-03 | ||
| JP20285090A JPH0711070B2 (ja) | 1990-07-31 | 1990-07-31 | 溶接性、プレス性、化成処理性に優れた亜鉛系めっき鋼板 |
| JP02-202850 | 1990-07-31 | ||
| JP02-204067 | 1990-08-01 | ||
| JP2204067A JP2819427B2 (ja) | 1990-08-01 | 1990-08-01 | プレス成形性、化成処理性に優れた亜鉛系めっき鋼板 |
| JP2204068A JP2819428B2 (ja) | 1990-08-01 | 1990-08-01 | プレス成形性、化成処理性に優れた亜鉛系めっき鋼板 |
| JP02-204068 | 1990-08-01 | ||
| JP21540690A JP2767650B2 (ja) | 1990-08-14 | 1990-08-14 | 溶接性、プレス性、化成処理性に優れた亜鉛系めっき鋼板 |
| JP02-215406 | 1990-08-14 | ||
| JP2305582A JP2691797B2 (ja) | 1990-11-10 | 1990-11-10 | プレス成形性、化成処理性に優れた亜鉛系めっき鋼板 |
| JP02-305582 | 1990-11-10 | ||
| JP02-305581 | 1990-11-10 | ||
| JP02-305583 | 1990-11-10 | ||
| JP2305581A JP2826902B2 (ja) | 1990-11-10 | 1990-11-10 | プレス成形性、化成処理性に優れた亜鉛系めっき鋼板の製造方法 |
| JP30558390 | 1990-11-10 | ||
| PCT/JP1990/001615 WO1991009152A1 (fr) | 1989-12-12 | 1990-12-11 | Tole d'acier galvanisee presentant une aptitude excellente au moulage a pression, a la conversion chimique ou analogue, et procede de fabrication |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR920701528A KR920701528A (ko) | 1992-08-11 |
| KR940001032B1 true KR940001032B1 (ko) | 1994-02-08 |
Family
ID=27586125
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019910700888A Expired - Lifetime KR940001032B1 (ko) | 1989-12-12 | 1990-12-11 | 프레스 성형성, 화성처리성 등에 뛰어난 아연계 도금강판 및 그 강판의 제조방법 |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0456834B1 (de) |
| KR (1) | KR940001032B1 (de) |
| AU (1) | AU629724B2 (de) |
| CA (1) | CA2046288C (de) |
| DE (1) | DE69027428T2 (de) |
| WO (1) | WO1991009152A1 (de) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014104442A1 (ko) * | 2012-12-27 | 2014-07-03 | 주식회사 포스코 | 아연 또는 아연계합금도금 강판용 인산염 용액 및 이를 이용한 아연 또는 아연계합금도금 강판 |
| KR101456346B1 (ko) * | 2010-07-09 | 2014-11-03 | 신닛테츠스미킨 카부시키카이샤 | 용융 아연계 도금 강판 |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2175105C (en) * | 1995-05-23 | 1999-09-21 | C. Ramadeva Shastry | Process for improving the formability and weldability properties of zinc coated steel sheet |
| RU2123067C1 (ru) * | 1997-06-11 | 1998-12-10 | Акционерное общество "ФК" | Раствор для фосфатирования стальных поверхностей |
| CN1269986C (zh) * | 2000-10-19 | 2006-08-16 | 杰富意钢铁株式会社 | 镀锌钢板和它的制造方法,以及冲压成形制品的制造方法 |
| CA2437990C (en) * | 2000-12-04 | 2007-05-08 | Jfe Steel Corporation | Zinc-base plated steel sheet and method for manufacturing same |
| DE60236447D1 (de) † | 2001-10-23 | 2010-07-01 | Sumitomo Metal Ind | Verfahren zur heisspressbearbeitung von einem plattierten stahlprodukt |
| KR100707255B1 (ko) * | 2003-04-18 | 2007-04-13 | 제이에프이 스틸 가부시키가이샤 | 프레스 성형성이 우수한 용융아연 도금강판과 그 제조방법 |
| JP7409998B2 (ja) | 2020-08-27 | 2024-01-09 | 日立Astemo株式会社 | 緩衝器および緩衝器の製造方法 |
| CN117107228B (zh) * | 2023-07-24 | 2024-12-17 | 鞍钢股份有限公司 | 一种装饰性黄变铝锌镁镀层钢板及其制造方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2417133A (en) * | 1940-11-23 | 1947-03-11 | Du Pont | Electrodepositing and heat-treating molybdenum-oxygen deposits |
| EP0034040A1 (de) * | 1980-02-06 | 1981-08-19 | BNF Metals Technology Centre | Verfahren zur Herstellung von Konversionsschichten |
| FR2569203B1 (fr) * | 1984-08-16 | 1989-12-22 | Produits Ind Cie Fse | Procede de traitement par conversion chimique de substrats en zinc ou en l'un de ses alliages, concentre et bain utilises pour la mise en oeuvre de ce procede |
| US4861441A (en) * | 1986-08-18 | 1989-08-29 | Nippon Steel Corporation | Method of making a black surface treated steel sheet |
| JPS63186883A (ja) * | 1987-01-28 | 1988-08-02 | Nippon Steel Corp | スポツト溶接性に優れた亜鉛系めつき鋼板 |
-
1990
- 1990-12-11 DE DE69027428T patent/DE69027428T2/de not_active Expired - Lifetime
- 1990-12-11 EP EP91900051A patent/EP0456834B1/de not_active Expired - Lifetime
- 1990-12-11 AU AU68889/91A patent/AU629724B2/en not_active Expired
- 1990-12-11 WO PCT/JP1990/001615 patent/WO1991009152A1/ja not_active Ceased
- 1990-12-11 CA CA002046288A patent/CA2046288C/en not_active Expired - Lifetime
- 1990-12-11 KR KR1019910700888A patent/KR940001032B1/ko not_active Expired - Lifetime
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101456346B1 (ko) * | 2010-07-09 | 2014-11-03 | 신닛테츠스미킨 카부시키카이샤 | 용융 아연계 도금 강판 |
| WO2014104442A1 (ko) * | 2012-12-27 | 2014-07-03 | 주식회사 포스코 | 아연 또는 아연계합금도금 강판용 인산염 용액 및 이를 이용한 아연 또는 아연계합금도금 강판 |
| US20150329972A1 (en) * | 2012-12-27 | 2015-11-19 | Posco | Phosphate solution for zinc or zinc-based alloy plated steel sheet, and zinc or zinc-based alloy plated steel sheet using the same |
| US9957619B2 (en) | 2012-12-27 | 2018-05-01 | Posco | Phosphate solution for zinc or zinc-based alloy plated steel sheet, and zinc or zinc-based alloy plated steel sheet using the same |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2046288C (en) | 2001-02-06 |
| CA2046288A1 (en) | 1991-06-13 |
| KR920701528A (ko) | 1992-08-11 |
| AU6888991A (en) | 1991-07-18 |
| WO1991009152A1 (fr) | 1991-06-27 |
| DE69027428D1 (de) | 1996-07-18 |
| AU629724B2 (en) | 1992-10-08 |
| DE69027428T2 (de) | 1997-02-13 |
| EP0456834B1 (de) | 1996-06-12 |
| EP0456834A4 (en) | 1992-07-08 |
| EP0456834A1 (de) | 1991-11-21 |
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