PL400714A1 - Propiconazole salts and processes for their preparation - Google Patents
Propiconazole salts and processes for their preparationInfo
- Publication number
- PL400714A1 PL400714A1 PL400714A PL40071412A PL400714A1 PL 400714 A1 PL400714 A1 PL 400714A1 PL 400714 A PL400714 A PL 400714A PL 40071412 A PL40071412 A PL 40071412A PL 400714 A1 PL400714 A1 PL 400714A1
- Authority
- PL
- Poland
- Prior art keywords
- propiconazole
- salts
- substituent
- preparation
- benzyl
- Prior art date
Links
- STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical class O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 3
- 239000005822 Propiconazole Substances 0.000 abstract 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 229910052740 iodine Chemical group 0.000 abstract 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 2
- 239000003960 organic solvent Substances 0.000 abstract 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 abstract 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Chemical group 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 150000001805 chlorine compounds Chemical group 0.000 abstract 1
- 125000001309 chloro group Chemical group Cl* 0.000 abstract 1
- 239000000417 fungicide Substances 0.000 abstract 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 abstract 1
- 239000011630 iodine Chemical group 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 150000003839 salts Chemical group 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Przedmiotem wynalazku sa sole propikonazolu majace zastosowanie jako srodki grzybobójcze i sposób ich wytwarzania. Sole propikonazolu stanowia czwartorzedowe sole propikonazolu o wzorze ogólnym 1, w których X oznacza anion chlorkowy, bramkowy lub jodkowy, a R oznacza podstawnik metylowy lub prostolancuchowy podstawnik alkilowy zawierajacy od 3 do 20 atomów wegla, lub podstawnik benzylowy, lub allilowy, lub cykloheksylowy. Sposób ich otrzymywania polega na tym, ze propikonazol poddaje sie reakcji z czynnikiem czwartorzedujacym o wzorze ogólnym R-X, w którym R oznacza podstawnik metylowy lub prostolancuchowy podstawnik alkilowy zawierajacy od 3 do 20 atomów wegla, lub podstawnik benzylowy lub allilowy, a X oznacza atom chloru lub bromu, lub jodu przy stosunku molowym propikonazolu do czynnika czwartorzedujacego wynoszacym od 1:1 do 1:3 w rozpuszczalniku organicznym I, w temperaturze od 273 do 363K, w czasie co najmniej 20 godzin, po czym odparowuje sie rozpuszczalnik, a mieszanine poreakcyjna przemywa sie rozpuszczalnikiem organicznym II do momentu usuniecia nieprzereagowanych substratów, a nastepnie produkt suszy sie pod zmniejszonym cisnieniem w temperaturze od 313 do 363K, przez co najmniej 8 godzin.The present invention relates to propiconazole salts for use as fungicides and the process for their preparation. Propiconazole salts are the quaternary salts of propiconazole of the general formula 1 in which X is a chloride, gate or iodide anion, and R is a methyl substituent or straight chain alkyl substituent containing from 3 to 20 carbon atoms, or a benzyl, or allyl or cyclohexyl substituent. The method of their preparation is that propiconazole is reacted with a quaternizing agent of the general formula RX, in which R is a methyl substituent or a straight chain alkyl substituent containing from 3 to 20 carbon atoms, or a benzyl or allyl substituent, and X is a chlorine atom or bromine or iodine at a molar ratio of propiconazole to quaternizing agent of 1: 1 to 1: 3 in organic solvent I, at a temperature of 273 to 363K, for at least 20 hours, after which the solvent is evaporated and the reaction mixture is washed organic solvent II until the removal of unreacted substrates, and then the product is dried under reduced pressure at a temperature from 313 to 363K, for at least 8 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL400714A PL219914B1 (en) | 2012-09-10 | 2012-09-10 | Propiconazole salts and processes for their preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL400714A PL219914B1 (en) | 2012-09-10 | 2012-09-10 | Propiconazole salts and processes for their preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL400714A1 true PL400714A1 (en) | 2014-03-17 |
| PL219914B1 PL219914B1 (en) | 2015-07-31 |
Family
ID=50240926
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL400714A PL219914B1 (en) | 2012-09-10 | 2012-09-10 | Propiconazole salts and processes for their preparation |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL219914B1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL422979A1 (en) * | 2017-09-26 | 2019-04-08 | Instytut Ochrony Roślin - Państwowy Instytut Badawczy W Poznaniu | N-benzyltriticonazole salts, method for obtaining them and application as fungicides |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116589420A (en) * | 2023-05-17 | 2023-08-15 | 东北林业大学 | A kind of polymerizable triazolium salt for wood modification and its preparation method and application |
-
2012
- 2012-09-10 PL PL400714A patent/PL219914B1/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL422979A1 (en) * | 2017-09-26 | 2019-04-08 | Instytut Ochrony Roślin - Państwowy Instytut Badawczy W Poznaniu | N-benzyltriticonazole salts, method for obtaining them and application as fungicides |
Also Published As
| Publication number | Publication date |
|---|---|
| PL219914B1 (en) | 2015-07-31 |
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