SU484678A3 - Способ получени малеинового ангидрида - Google Patents

Способ получени малеинового ангидрида

Info

Publication number: SU484678A3
Authority: SU; USSR - Soviet Union
Prior art keywords: catalyst; vanadium; acid; phosphorus; oxygen
Prior art date: 1972-01-03

Application number

SU1847795A

Other languages

English (en)

Russian (ru)

Inventor

Майкл Богосиан Эдвард

Original Assignee

Стандарт Ойл Компани Оф Индиана (Фирма)

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1972-01-03

Filing date

1972-11-03

Publication date

1975-09-15

1972-11-03 Application filed by Стандарт Ойл Компани Оф Индиана (Фирма) filed Critical Стандарт Ойл Компани Оф Индиана (Фирма)

1975-09-15 Application granted granted Critical

1975-09-15 Publication of SU484678A3 publication Critical patent/SU484678A3/ru

Links

FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 title description 5
238000004519 manufacturing process Methods 0.000 title 1
239000003054 catalyst Substances 0.000 description 58
238000000034 method Methods 0.000 description 18
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 15
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 13
239000011574 phosphorus Substances 0.000 description 11
239000012190 activator Substances 0.000 description 10
229910052698 phosphorus Inorganic materials 0.000 description 10
239000001273 butane Substances 0.000 description 9
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 9
229910052720 vanadium Inorganic materials 0.000 description 9
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 9
239000000203 mixture Substances 0.000 description 8
239000002253 acid Substances 0.000 description 7
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 6
238000006243 chemical reaction Methods 0.000 description 6
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 5
125000004429 atom Chemical group 0.000 description 5
230000003197 catalytic effect Effects 0.000 description 5
238000002474 experimental method Methods 0.000 description 5
230000003647 oxidation Effects 0.000 description 5
238000007254 oxidation reaction Methods 0.000 description 5
150000003839 salts Chemical class 0.000 description 5
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
239000010949 copper Substances 0.000 description 4
239000001301 oxygen Substances 0.000 description 4
229910052760 oxygen Inorganic materials 0.000 description 4
-1 phosphorus compound Chemical class 0.000 description 4
238000002360 preparation method Methods 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 3
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
LEABNKXSQUTCOW-UHFFFAOYSA-N [O].[P].[V] Chemical compound [O].[P].[V] LEABNKXSQUTCOW-UHFFFAOYSA-N 0.000 description 3
150000007513 acids Chemical class 0.000 description 3
ZHXZNKNQUHUIGN-UHFFFAOYSA-N chloro hypochlorite;vanadium Chemical compound [V].ClOCl ZHXZNKNQUHUIGN-UHFFFAOYSA-N 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
229910052802 copper Inorganic materials 0.000 description 3
229910052744 lithium Inorganic materials 0.000 description 3
239000002245 particle Substances 0.000 description 3
239000000047 product Substances 0.000 description 3
239000002994 raw material Substances 0.000 description 3
239000002904 solvent Substances 0.000 description 3
IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 2
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
241000765309 Vanadis Species 0.000 description 2
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
229910000147 aluminium phosphate Inorganic materials 0.000 description 2
150000008064 anhydrides Chemical class 0.000 description 2
229910052797 bismuth Inorganic materials 0.000 description 2
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 2
239000003638 chemical reducing agent Substances 0.000 description 2
ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 2
RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 description 2
229910001882 dioxygen Inorganic materials 0.000 description 2
230000000694 effects Effects 0.000 description 2
239000007789 gas Substances 0.000 description 2
239000011521 glass Substances 0.000 description 2
KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
235000006408 oxalic acid Nutrition 0.000 description 2
239000007787 solid Substances 0.000 description 2
239000000758 substrate Substances 0.000 description 2
DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 2
229910052725 zinc Inorganic materials 0.000 description 2
239000011701 zinc Substances 0.000 description 2
JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 description 1
HTXMJCHSFOPGME-UHFFFAOYSA-N 4,7-dimethoxy-1,3-benzodioxole Chemical compound COC1=CC=C(OC)C2=C1OCO2 HTXMJCHSFOPGME-UHFFFAOYSA-N 0.000 description 1
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
241000533363 Apion Species 0.000 description 1
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
229910021592 Copper(II) chloride Inorganic materials 0.000 description 1
YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical class C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
UDGPORNILMTQCV-UHFFFAOYSA-K [O-]P([O-])([O-])=O.O.[V+5] Chemical compound [O-]P([O-])([O-])=O.O.[V+5] UDGPORNILMTQCV-UHFFFAOYSA-K 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000009835 boiling Methods 0.000 description 1
UBAZGMLMVVQSCD-UHFFFAOYSA-N carbon dioxide;molecular oxygen Chemical compound O=O.O=C=O UBAZGMLMVVQSCD-UHFFFAOYSA-N 0.000 description 1
229910002091 carbon monoxide Inorganic materials 0.000 description 1
239000000969 carrier Substances 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
FLGMAMYMYDIKLE-UHFFFAOYSA-N chloro hypochlorite;phosphane Chemical compound P.ClOCl FLGMAMYMYDIKLE-UHFFFAOYSA-N 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
239000003086 colorant Substances 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
230000009918 complex formation Effects 0.000 description 1
SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 1
238000001035 drying Methods 0.000 description 1
239000002360 explosive Substances 0.000 description 1
239000003546 flue gas Substances 0.000 description 1
235000019253 formic acid Nutrition 0.000 description 1
239000008240 homogeneous mixture Substances 0.000 description 1
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
229910000043 hydrogen iodide Inorganic materials 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
150000002443 hydroxylamines Chemical class 0.000 description 1
239000003701 inert diluent Substances 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
239000011630 iodine Substances 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
239000001282 iso-butane Substances 0.000 description 1
238000002955 isolation Methods 0.000 description 1
239000000463 material Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
150000001247 metal acetylides Chemical class 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
239000007800 oxidant agent Substances 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
150000003016 phosphoric acids Chemical class 0.000 description 1
125000004437 phosphorous atom Chemical group 0.000 description 1
229910001392 phosphorus oxide Inorganic materials 0.000 description 1
239000000843 powder Substances 0.000 description 1
239000000376 reactant Substances 0.000 description 1
238000010992 reflux Methods 0.000 description 1
230000002441 reversible effect Effects 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000000741 silica gel Substances 0.000 description 1
229910002027 silica gel Inorganic materials 0.000 description 1
HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
229910010271 silicon carbide Inorganic materials 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
239000000126 substance Substances 0.000 description 1
NNPPMTNAJDCUHE-UHFFFAOYSA-N trimethylmethane Natural products CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 1
229910001935 vanadium oxide Inorganic materials 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1
150000003751 zinc Chemical class 0.000 description 1
235000005074 zinc chloride Nutrition 0.000 description 1
239000011592 zinc chloride Substances 0.000 description 1

Landscapes

Furan Compounds (AREA)

SU1847795A 1972-01-03 1972-11-03 Способ получени малеинового ангидрида SU484678A3 (ru)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US21517672A	1972-01-03	1972-01-03

Publications (1)

Publication Number	Publication Date
SU484678A3 true SU484678A3 (ru)	1975-09-15

Family

ID=22801974

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SU1847795A SU484678A3 (ru)	1972-01-03	1972-11-03	Способ получени малеинового ангидрида

Country Status (5)

Country	Link
AR (1)	AR194858A1 (cs)
AU (1)	AU468293B2 (cs)
CS (1)	CS190376B2 (cs)
RO (1)	RO62347A (cs)
SU (1)	SU484678A3 (cs)

1972
- 1972-11-03 SU SU1847795A patent/SU484678A3/ru active
- 1972-11-14 AU AU48840/72A patent/AU468293B2/en not_active Expired
- 1972-11-15 AR AR24516472A patent/AR194858A1/es active
- 1972-11-20 CS CS786572A patent/CS190376B2/cs unknown
- 1972-11-20 RO RO7286272A patent/RO62347A/ro unknown

Also Published As

Publication number	Publication date
AU4884072A (en)	1974-05-16
AU468293B2 (en)	1976-01-08
RO62347A (cs)	1977-08-15
CS190376B2 (en)	1979-05-31
AR194858A1 (es)	1973-08-24

Publication	Publication Date	Title
US3987063A (en)	1976-10-19	Process for the production of maleic anhydride from butane
JPH03238051A (ja)	1991-10-23	メタクリル酸製造用触媒の調製法
JPS5827255B2 (ja)	1983-06-08	不飽和脂肪酸の製造方法
JPS5826329B2 (ja)	1983-06-02	フホウワシボウサンノセイゾウホウ
JP3101821B2 (ja)	2000-10-23	メタクリル酸製造用触媒の調製法
CZ290055B6 (cs)	2002-05-15	Oxidační katalyzátor ze směsi oxidů fosforu a vanadu a způsob jeho přípravy
SU484678A3 (ru)	1975-09-15	Способ получени малеинового ангидрида
JPH03137937A (ja)	1991-06-12	メタクリル酸製造用触媒の調整法
JP3209778B2 (ja)	2001-09-17	メタクリル酸製造用触媒の調製法
JPS61114739A (ja)	1986-06-02	不飽和カルボン酸製造用触媒の調製法
US4088602A (en)	1978-05-09	Dehydrogenation catalyst
EP0253896A1 (en)	1988-01-27	Process for producing methacrylic acid and catalysts for the process
JPH03167152A (ja)	1991-07-19	メタクリル酸の製造法
JPH11179209A (ja)	1999-07-06	メタクリル酸製造用触媒およびそれを用いたメタクリル酸の製造法
JPH02119942A (ja)	1990-05-08	メタクリル酸製造用触媒の調製法
JPS5824419B2 (ja)	1983-05-20	フホウワカルボンサンノセイゾウホウホウ
JP2883454B2 (ja)	1999-04-19	不飽和カルボン酸の製造方法
US3670017A (en)	1972-06-13	Production of unsaturated aliphatic acids
JPH04128247A (ja)	1992-04-28	メタクロレイン及びメタクリル酸の製造法
JP3800676B2 (ja)	2006-07-26	グリオキシル酸の製造方法
JP2592325B2 (ja)	1997-03-19	不飽和カルボン酸の製造法
JPS5826740B2 (ja)	1983-06-04	不飽和カルボン酸の製造方法
JPH0320237A (ja)	1991-01-29	メタクロレイン及びメタクリル酸の製造法
JP2928397B2 (ja)	1999-08-03	不飽和カルボン酸の製造方法
JP2883455B2 (ja)	1999-04-19	不飽和カルボン酸の製造方法