DK548888A - Katalysatorer, fremgangsmaade til fremstilling heraf samt fremgangsmaade til anvendelse af katalysatorerne - Google Patents

Katalysatorer, fremgangsmaade til fremstilling heraf samt fremgangsmaade til anvendelse af katalysatorerne

Info

Publication number: DK548888A
Authority: DK; Denmark
Prior art keywords: sub; radicals; catalysts; sup; zirconium
Prior art date: 1987-01-30

Application number

DK548888A

Other languages

Danish (da)

English (en)

Other versions

DK548888D0 (da

Inventor

Howard William Turner

Gregory George Hlatky

Original Assignee

Exxon Chemical Patents Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-01-30

Filing date

1988-09-30

Publication date

1988-11-30

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=26678640&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DK548888(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1988-09-30 Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc

1988-09-30 Publication of DK548888D0 publication Critical patent/DK548888D0/da

1988-11-30 Publication of DK548888A publication Critical patent/DK548888A/da

Links

239000003054 catalyst Substances 0.000 title abstract 9
238000000034 method Methods 0.000 title 2
229910052726 zirconium Inorganic materials 0.000 abstract 5
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 4
150000001875 compounds Chemical class 0.000 abstract 4
150000001336 alkenes Chemical class 0.000 abstract 3
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 2
-1 bis(cyclopentadienyl)zirconium Chemical compound 0.000 abstract 2
229910052796 boron Inorganic materials 0.000 abstract 2
150000001993 dienes Chemical class 0.000 abstract 2
ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 abstract 2
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 2
238000006116 polymerization reaction Methods 0.000 abstract 2
239000007848 Bronsted acid Substances 0.000 abstract 1
239000002879 Lewis base Substances 0.000 abstract 1
150000001450 anions Chemical class 0.000 abstract 1
125000003118 aryl group Chemical group 0.000 abstract 1
125000004432 carbon atom Chemical group C* 0.000 abstract 1
150000001768 cations Chemical class 0.000 abstract 1
239000003085 diluting agent Substances 0.000 abstract 1
125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
238000011065 in-situ storage Methods 0.000 abstract 1
150000007527 lewis bases Chemical class 0.000 abstract 1
239000003446 ligand Substances 0.000 abstract 1
239000000178 monomer Substances 0.000 abstract 1
230000007935 neutral effect Effects 0.000 abstract 1
229920000642 polymer Polymers 0.000 abstract 1
239000002685 polymerization catalyst Substances 0.000 abstract 1
239000002904 solvent Substances 0.000 abstract 1
230000000087 stabilizing effect Effects 0.000 abstract 1
125000001424 substituent group Chemical group 0.000 abstract 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Polymerization Catalysts (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Polyesters Or Polycarbonates (AREA)
Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Polymerisation Methods In General (AREA)
Steroid Compounds (AREA)

DK548888A 1987-01-30 1988-09-30 Katalysatorer, fremgangsmaade til fremstilling heraf samt fremgangsmaade til anvendelse af katalysatorerne DK548888A (da)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US880087A	1987-01-30	1987-01-30
US13348087A	1987-12-22	1987-12-22
PCT/US1988/000223 WO1988005793A1 (en)	1987-01-30	1988-01-27	Catalysts, method of preparing these catalysts and method of using said catalysts

Publications (2)

Publication Number	Publication Date
DK548888D0 DK548888D0 (da)	1988-09-30
DK548888A true DK548888A (da)	1988-11-30

Family

ID=26678640

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DK548888A DK548888A (da)	1987-01-30	1988-09-30	Katalysatorer, fremgangsmaade til fremstilling heraf samt fremgangsmaade til anvendelse af katalysatorerne

Country Status (20)

Country	Link
EP (6)	EP0468537B2 (de)
JP (5)	JP2965572B2 (de)
KR (1)	KR960015192B1 (de)
AT (5)	ATE195524T1 (de)
AU (1)	AU617990B2 (de)
BR (1)	BR8805026A (de)
CA (3)	CA1339142C (de)
CZ (1)	CZ57988A3 (de)
DE (6)	DE3856424T3 (de)
DK (1)	DK548888A (de)
ES (5)	ES2094174T5 (de)
FI (1)	FI101477B1 (de)
HU (1)	HU211065B (de)
IL (1)	IL85097A (de)
NO (1)	NO179589C (de)
PL (1)	PL159196B1 (de)
PT (1)	PT86672A (de)
RU (2)	RU2062649C1 (de)
WO (1)	WO1988005793A1 (de)
YU (2)	YU45838B (de)

Families Citing this family (664)

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US5004820A (en) *	1989-08-07	1991-04-02	Massachusetts Institute Of Technology	Preparation of chiral metallocene dihalides
US6686488B2 (en)	1989-08-31	2004-02-03	The Dow Chemical Company	Constrained geometry addition polymerization catalysts
US6075077A (en) *	1989-08-31	2000-06-13	The Dow Chemical Company	Asphalt, bitumen, and adhesive compositions
NZ235032A (en)	1989-08-31	1993-04-28	Dow Chemical Co	Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5763547A (en) *	1992-10-02	1998-06-09	The Dow Chemical Company	Supported catalyst complexes for olefin in polymerization
US6825369B1 (en)	1989-09-14	2004-11-30	The Dow Chemical Company	Metal complex compounds
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DE69026907T2 (de) *	1989-10-10	1996-10-10	Fina Technology	Metallocenkatalysator mit Lewissäure und Alkylaluminium
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ATE137247T1 (de) *	1989-10-30	1996-05-15	Fina Technology	Addition von alkylaluminium zum verbessern eines metallocenkatalysators
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US5189192A (en) *	1991-01-16	1993-02-23	The Dow Chemical Company	Process for preparing addition polymerization catalysts via metal center oxidation
US5206197A (en) *	1991-03-04	1993-04-27	The Dow Chemical Company	Catalyst composition for preparation of syndiotactic vinyl aromatic polymers
JP3117231B2 (ja) *	1991-03-11	2000-12-11	三井化学株式会社	幅広い分子量分布を有するシンジオタクチックポリ−α−オレフィンの製造方法
JP2939354B2 (ja) *	1991-03-26	1999-08-25	出光興産株式会社	スチレン系重合体の製造方法及びその触媒
DE69220272T2 (de) *	1991-03-27	1997-09-25	Idemitsu Kosan Co	Verfahren zur Herstellung eines Styrolpolymerisats
JP2927566B2 (ja) *	1991-03-28	1999-07-28	出光興産株式会社	スチレン系共重合体の製造方法
DE69219932T2 (de) *	1991-03-29	1997-09-11	Idemitsu Kosan Co	Verfahren zur Herstellung eines Homo- oder Copolymerisates des Styrols
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IL85097A (en) *	1987-01-30	1992-02-16	Exxon Chemical Patents Inc	Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
PL276385A1 (en) *	1987-01-30	1989-07-24	Exxon Chemical Patents Inc	Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5218071A (en) †	1988-12-26	1993-06-08	Mitsui Petrochemical Industries, Ltd.	Ethylene random copolymers

1988
- 1988-01-13 IL IL85097A patent/IL85097A/xx unknown
- 1988-01-19 CA CA000556846A patent/CA1339142C/en not_active Expired - Lifetime
- 1988-01-27 EP EP91113752A patent/EP0468537B2/de not_active Expired - Lifetime
- 1988-01-27 KR KR1019880701205A patent/KR960015192B1/ko not_active Expired - Lifetime
- 1988-01-27 ES ES91113752T patent/ES2094174T5/es not_active Expired - Lifetime
- 1988-01-27 EP EP93201185A patent/EP0561479B1/de not_active Revoked
- 1988-01-27 EP EP88300699A patent/EP0277004A1/de not_active Withdrawn
- 1988-01-27 RU SU884356711A patent/RU2062649C1/ru active
- 1988-01-27 RU RU94014628/04A patent/RU2139291C1/ru not_active IP Right Cessation
- 1988-01-27 DE DE3856424T patent/DE3856424T3/de not_active Expired - Lifetime
- 1988-01-27 ES ES93201186T patent/ES2150931T5/es not_active Expired - Lifetime
- 1988-01-27 AT AT93201186T patent/ATE195524T1/de not_active IP Right Cessation
- 1988-01-27 BR BR8805026A patent/BR8805026A/pt not_active IP Right Cessation
- 1988-01-27 DE DE3855668T patent/DE3855668T2/de not_active Revoked
- 1988-01-27 ES ES99201939T patent/ES2229620T3/es not_active Expired - Lifetime
- 1988-01-27 DE DE3855666T patent/DE3855666T3/de not_active Expired - Lifetime
- 1988-01-27 EP EP99201940A patent/EP0949279B1/de not_active Expired - Lifetime
- 1988-01-27 AT AT93201185T patent/ATE145211T1/de not_active IP Right Cessation
- 1988-01-27 EP EP93201186A patent/EP0558158B2/de not_active Expired - Lifetime
- 1988-01-27 DE DE3856574T patent/DE3856574T3/de not_active Expired - Lifetime
- 1988-01-27 EP EP99201939A patent/EP0949278B2/de not_active Expired - Lifetime
- 1988-01-27 ES ES93201185T patent/ES2094461T3/es not_active Expired - Lifetime
- 1988-01-27 HU HU885059A patent/HU211065B/hu not_active IP Right Cessation
- 1988-01-27 AU AU12452/88A patent/AU617990B2/en not_active Expired
- 1988-01-27 AT AT99201940T patent/ATE286515T1/de not_active IP Right Cessation
- 1988-01-27 AT AT91113752T patent/ATE145218T1/de not_active IP Right Cessation
- 1988-01-27 AT AT99201939T patent/ATE281478T1/de not_active IP Right Cessation
- 1988-01-27 ES ES99201940T patent/ES2237031T3/es not_active Expired - Lifetime
- 1988-01-27 JP JP63501583A patent/JP2965572B2/ja not_active Expired - Lifetime
- 1988-01-27 DE DE3856577T patent/DE3856577T2/de not_active Expired - Lifetime
- 1988-01-27 DE DE3855666A patent/DE3855666T4/de not_active Expired - Lifetime
- 1988-01-27 WO PCT/US1988/000223 patent/WO1988005793A1/en not_active Ceased
- 1988-01-28 YU YU16288A patent/YU45838B/sh unknown
- 1988-01-29 CZ CS88579A patent/CZ57988A3/cs unknown
- 1988-01-29 PL PL1988270367A patent/PL159196B1/pl unknown
- 1988-01-29 PT PT86672A patent/PT86672A/pt not_active Application Discontinuation
- 1988-09-22 NO NO884210A patent/NO179589C/no not_active IP Right Cessation
- 1988-09-29 FI FI884487A patent/FI101477B1/fi not_active IP Right Cessation
- 1988-09-30 DK DK548888A patent/DK548888A/da not_active Application Discontinuation
1989
- 1989-09-14 YU YU01786/89A patent/YU178689A/xx unknown
1994
- 1994-08-12 CA CA000616900A patent/CA1337142C/en not_active Expired - Lifetime
1995
- 1995-01-27 JP JP7031643A patent/JP2953686B2/ja not_active Expired - Lifetime
- 1995-01-27 JP JP7031642A patent/JP2918193B2/ja not_active Expired - Lifetime
1997
- 1997-05-09 CA CA000617074A patent/CA1340578C/en not_active Expired - Lifetime
1998
- 1998-12-28 JP JP10374589A patent/JP3119304B2/ja not_active Expired - Lifetime
1999
- 1999-01-06 JP JP11001024A patent/JP3119305B2/ja not_active Expired - Lifetime

Also Published As

Publication number	Publication date
DE3856424T2 (de)	2001-03-15
JPH0834810A (ja)	1996-02-06
DE3855668D1 (de)	1996-12-19
DE3856574T3 (de)	2010-06-10
EP0949279B1 (de)	2005-01-05
NO179589B (no)	1996-07-29
EP0468537B2 (de)	2004-11-24
DE3855668T2 (de)	1997-03-20
KR890700612A (ko)	1989-04-26
WO1988005793A1 (en)	1988-08-11
DK548888D0 (da)	1988-09-30
JPH11255814A (ja)	1999-09-21
PL270367A1 (en)	1988-10-13
DE3856424D1 (de)	2000-09-21
EP0558158A1 (de)	1993-09-01
RU2139291C1 (ru)	1999-10-10
DE3856577T2 (de)	2005-12-29
PL159196B1 (en)	1992-11-30
YU16288A (en)	1990-02-28
ES2229620T3 (es)	2005-04-16
IL85097A (en)	1992-02-16
JP2953686B2 (ja)	1999-09-27
EP0561479A1 (de)	1993-09-22
CZ57988A3 (en)	1995-02-15
ES2094174T5 (es)	2005-06-01
NO179589C (no)	1996-11-06
EP0468537A1 (de)	1992-01-29
EP0949279A3 (de)	2000-09-13
ATE145218T1 (de)	1996-11-15
JP3119304B2 (ja)	2000-12-18
ATE195524T1 (de)	2000-09-15
RU2062649C1 (ru)	1996-06-27
YU45838B (sh)	1992-07-20
NO884210D0 (no)	1988-09-22
AU1245288A (en)	1988-08-24
FI884487A7 (fi)	1988-09-29
DE3855666D1 (de)	1996-12-19
DE3856574T2 (de)	2006-02-02
DE3856574D1 (de)	2004-12-09
YU178689A (en)	1991-04-30
CA1337142C (en)	1995-09-26
AU617990B2 (en)	1991-12-12
DE3856577D1 (de)	2005-02-10
NO884210L (no)	1988-09-22
KR960015192B1 (ko)	1996-11-01
PT86672A (pt)	1989-01-30
DE3855666T4 (de)	1997-09-04
DE3855666T2 (de)	1997-03-27
EP0277004A1 (de)	1988-08-03
ATE286515T1 (de)	2005-01-15
FI884487A0 (fi)	1988-09-29
EP0949278B1 (de)	2004-11-03
ATE145211T1 (de)	1996-11-15
BR8805026A (pt)	1989-10-17
FI101477B (fi)	1998-06-30
EP0561479B1 (de)	1996-11-13
JP2918193B2 (ja)	1999-07-12
CA1339142C (en)	1997-07-29
ES2094174T3 (es)	1997-01-16
DE3855666T3 (de)	2005-06-30
JPH01502036A (ja)	1989-07-13
JP2965572B2 (ja)	1999-10-18
EP0558158B1 (de)	2000-08-16
EP0949279A2 (de)	1999-10-13
EP0949278A3 (de)	2000-09-13
CA1340578C (en)	1999-06-01
EP0949278A2 (de)	1999-10-13
DE3856424T3 (de)	2005-06-23
HU211065B (en)	1995-10-30
ATE281478T1 (de)	2004-11-15
JP3119305B2 (ja)	2000-12-18
JPH11255815A (ja)	1999-09-21
FI101477B1 (fi)	1998-06-30
ES2150931T5 (es)	2005-03-16
ES2094461T3 (es)	1997-01-16
JPH0834809A (ja)	1996-02-06
EP0468537B1 (de)	1996-11-13
EP0949278B2 (de)	2009-11-04
EP0558158B2 (de)	2004-10-06
ES2150931T3 (es)	2000-12-16
ES2237031T3 (es)	2005-07-16

Legal Events

Date	Code	Title	Description
1993-09-27	AHB	Application shelved due to non-payment

Publication	Publication Date	Title
DK548888A (da)	1988-11-30	Katalysatorer, fremgangsmaade til fremstilling heraf samt fremgangsmaade til anvendelse af katalysatorerne
PL276385A1 (en)	1989-07-24	Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
KR100548105B1 (ko)	2006-02-02	α-올레핀계 중합용 촉매용액
US20100036077A1 (en)	2010-02-11	Regioregular polymerization of alpha-olefins to produce polyethylene with a predominance of methyl substituents
Toda et al.	2024	Synthesis, Structural Analysis, and Polymerization Activity of Noncyclopentadienyl Constrained Geometry Complex [Me2Si (Ph2C)(t BuN)] ZrCl2 (thf)
KR20220120655A (ko)	2022-08-30	알파-치환된 아크릴레이트를 제조하는 방법
JP2004123994A (ja)	2004-04-22	環状オレフィン共重合体の製造方法
KR20190081611A (ko)	2019-07-09	올레핀 중합 촉매 및 이를 이용하여 중합된 올레핀계 중합체