ES2106021T3 - Compuestos complejos de metal, procedimiento para su preparacion y metodo de uso. - Google Patents

Compuestos complejos de metal, procedimiento para su preparacion y metodo de uso.

Info

Publication number
ES2106021T3
ES2106021T3 ES90309962T ES90309962T ES2106021T3 ES 2106021 T3 ES2106021 T3 ES 2106021T3 ES 90309962 T ES90309962 T ES 90309962T ES 90309962 T ES90309962 T ES 90309962T ES 2106021 T3 ES2106021 T3 ES 2106021T3
Authority
ES
Spain
Prior art keywords
hydrogen
monociclopentadienil
eta
atoms
procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES90309962T
Other languages
English (en)
Other versions
ES2106021T5 (es
Inventor
James C Stevens
David R Neithamer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27019786&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2106021(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of ES2106021T3 publication Critical patent/ES2106021T3/es
Application granted granted Critical
Publication of ES2106021T5 publication Critical patent/ES2106021T5/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/28—Titanium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

COMPUESTO QUE CONTIENE UN COMPLEJO METALICO DE MONOCICLOPENTADIENIL O MONOCICLOPENTADIENIL SUSTITUIDO, UTILES COMO CATALIZADORES DE POLIMERIZACION POR ADICION, QUE SE CORRESPONDE CON LA FORMULA: CPMXN+A-CICLOPENTADIENIL O ETA-5-CICLOPENTADIENIL SUSTITUIDO OPCIONALMENTE UNIDO DE FORMA COVALENTE A M MEDIANTE UN SUSTITUYENTE; M ES UN METAL DE GRUPO 3-10 O LA SERIE LANTANIDA DE LA TABLA PERIODICA UNIDA EN MODO DE ENLACE ETA-5 AL GRUPO DE CICLOPENTADIENILO O CICLOPENTADIENILO SUSTITUIDO; CADA APARICION DE X ES HIBRIDA O UNA MITAD SELECCIONADA DE HALO, ALQUILO, ARILO, SILILO, GERMILO, ARILOXILO, ALCOHOXILO, AMIDA, SILOXILO Y SUS COMBINACIONES CON HASTA 20 ATOMOS QUE NO SEAN DE HIDROGENO, LIGANDOS DE BASE LEWIS NEUTRA HASTA 20 ATOMOS QUE NO SEAN DE HIDROGENO; U OPCIONALMENTE X CON CP FORMA UN METALOCICLO DE HASTA 20 ATOMOS QUE NO SEAN DE HIDROGENO CON M; N ES 1 O 2 SEGUN LA VALENCIA DE M; Y ACIDA BRONSTED.
ES90309962T 1989-09-14 1990-09-12 Compuestos complejos de metal, procedimiento para su preparacion y metodo de uso. Expired - Lifetime ES2106021T5 (es)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US40716989A 1989-09-14 1989-09-14
US407169 1989-09-14
US547728 1990-07-03
US07/547,728 US5064802A (en) 1989-09-14 1990-07-03 Metal complex compounds

Publications (2)

Publication Number Publication Date
ES2106021T3 true ES2106021T3 (es) 1997-11-01
ES2106021T5 ES2106021T5 (es) 2004-03-16

Family

ID=27019786

Family Applications (1)

Application Number Title Priority Date Filing Date
ES90309962T Expired - Lifetime ES2106021T5 (es) 1989-09-14 1990-09-12 Compuestos complejos de metal, procedimiento para su preparacion y metodo de uso.

Country Status (20)

Country Link
US (2) US5064802A (es)
EP (2) EP0765882A3 (es)
JP (2) JP2736935B2 (es)
KR (1) KR0168048B1 (es)
CN (1) CN1028369C (es)
BR (1) BR9004695A (es)
CA (1) CA2025332C (es)
DE (1) DE69031413T3 (es)
ES (1) ES2106021T5 (es)
FI (1) FI100104B (es)
GE (1) GEP19991571B (es)
HK (1) HK1001919A1 (es)
HU (1) HU218602B (es)
IL (1) IL95598A (es)
NO (1) NO302702B1 (es)
NZ (1) NZ235215A (es)
RO (1) RO106411B1 (es)
RU (1) RU2095363C1 (es)
SG (1) SG43055A1 (es)
YU (1) YU47114B (es)

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* Cited by examiner, † Cited by third party
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CA2025332A1 (en) 1991-03-15
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DE69031413D1 (de) 1997-10-16
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CA2025332C (en) 2001-12-04
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