JPH0239781B2 - - Google Patents
Info
- Publication number
- JPH0239781B2 JPH0239781B2 JP57196575A JP19657582A JPH0239781B2 JP H0239781 B2 JPH0239781 B2 JP H0239781B2 JP 57196575 A JP57196575 A JP 57196575A JP 19657582 A JP19657582 A JP 19657582A JP H0239781 B2 JPH0239781 B2 JP H0239781B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- coupler
- cyan
- latex
- color
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- -1 aromatic primary amine Chemical class 0.000 claims description 86
- 229920000642 polymer Polymers 0.000 claims description 84
- 239000004816 latex Substances 0.000 claims description 56
- 229920000126 latex Polymers 0.000 claims description 56
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 28
- 239000000839 emulsion Substances 0.000 claims description 28
- 239000000463 material Substances 0.000 claims description 28
- 229910052709 silver Inorganic materials 0.000 claims description 23
- 239000004332 silver Substances 0.000 claims description 23
- 239000000178 monomer Substances 0.000 claims description 18
- 229910052801 chlorine Inorganic materials 0.000 claims description 15
- 239000002253 acid Substances 0.000 claims description 14
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 13
- 239000000460 chlorine Substances 0.000 claims description 13
- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- 125000002947 alkylene group Chemical group 0.000 claims description 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 8
- 238000005859 coupling reaction Methods 0.000 claims description 7
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 6
- 230000008878 coupling Effects 0.000 claims description 5
- 238000010168 coupling process Methods 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- 229910001413 alkali metal ion Inorganic materials 0.000 claims description 2
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 claims description 2
- 125000004122 cyclic group Chemical group 0.000 claims description 2
- 238000000034 method Methods 0.000 description 48
- 239000000243 solution Substances 0.000 description 33
- 238000011161 development Methods 0.000 description 30
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 27
- 150000001875 compounds Chemical class 0.000 description 25
- 108010010803 Gelatin Proteins 0.000 description 24
- 229920000159 gelatin Polymers 0.000 description 24
- 239000008273 gelatin Substances 0.000 description 24
- 235000019322 gelatine Nutrition 0.000 description 24
- 235000011852 gelatine desserts Nutrition 0.000 description 24
- 238000004519 manufacturing process Methods 0.000 description 20
- 239000007864 aqueous solution Substances 0.000 description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 19
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
- 238000012545 processing Methods 0.000 description 15
- 239000000203 mixture Substances 0.000 description 13
- 239000003960 organic solvent Substances 0.000 description 12
- 239000000084 colloidal system Substances 0.000 description 11
- 229920001577 copolymer Polymers 0.000 description 11
- 238000006116 polymerization reaction Methods 0.000 description 11
- 150000003839 salts Chemical class 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 10
- 239000000975 dye Substances 0.000 description 10
- 230000008569 process Effects 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000007787 solid Substances 0.000 description 9
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 8
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 7
- 238000009835 boiling Methods 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- 125000001424 substituent group Chemical group 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 206010070834 Sensitisation Diseases 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 6
- 238000007720 emulsion polymerization reaction Methods 0.000 description 6
- 230000002829 reductive effect Effects 0.000 description 6
- 230000035945 sensitivity Effects 0.000 description 6
- 230000008313 sensitization Effects 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 5
- 238000004061 bleaching Methods 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 229910052731 fluorine Inorganic materials 0.000 description 5
- 125000005843 halogen group Chemical group 0.000 description 5
- 239000003999 initiator Substances 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 5
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 5
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 4
- 229910052794 bromium Inorganic materials 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 238000004821 distillation Methods 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 230000002209 hydrophobic effect Effects 0.000 description 4
- 239000003112 inhibitor Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- UIERETOOQGIECD-UHFFFAOYSA-N Angelic acid Natural products CC=C(C)C(O)=O UIERETOOQGIECD-UHFFFAOYSA-N 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 3
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical class OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 210000000988 bone and bone Anatomy 0.000 description 3
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 125000004093 cyano group Chemical group *C#N 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 125000001153 fluoro group Chemical group F* 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- HNQIVZYLYMDVSB-UHFFFAOYSA-N methanesulfonimidic acid Chemical group CS(N)(=O)=O HNQIVZYLYMDVSB-UHFFFAOYSA-N 0.000 description 3
- 125000004170 methylsulfonyl group Chemical group [H]C([H])([H])S(*)(=O)=O 0.000 description 3
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 3
- 230000000379 polymerizing effect Effects 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 3
- 235000010265 sodium sulphite Nutrition 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 3
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 3
- QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- GGZHVNZHFYCSEV-UHFFFAOYSA-N 1-Phenyl-5-mercaptotetrazole Chemical compound SC1=NN=NN1C1=CC=CC=C1 GGZHVNZHFYCSEV-UHFFFAOYSA-N 0.000 description 2
- VEPOHXYIFQMVHW-XOZOLZJESA-N 2,3-dihydroxybutanedioic acid (2S,3S)-3,4-dimethyl-2-phenylmorpholine Chemical compound OC(C(O)C(O)=O)C(O)=O.C[C@H]1[C@@H](OCCN1C)c1ccccc1 VEPOHXYIFQMVHW-XOZOLZJESA-N 0.000 description 2
- GIXSFSVVKULPEK-UHFFFAOYSA-N 2,4-dichloro-3-methylphenol Chemical compound CC1=C(Cl)C=CC(O)=C1Cl GIXSFSVVKULPEK-UHFFFAOYSA-N 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- XLLIQLLCWZCATF-UHFFFAOYSA-N 2-methoxyethyl acetate Chemical compound COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 2
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Natural products CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 229930185605 Bisphenol Natural products 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- WTDHULULXKLSOZ-UHFFFAOYSA-N Hydroxylamine hydrochloride Chemical compound Cl.ON WTDHULULXKLSOZ-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- OJGMBLNIHDZDGS-UHFFFAOYSA-N N-Ethylaniline Chemical compound CCNC1=CC=CC=C1 OJGMBLNIHDZDGS-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Natural products C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 125000000738 acetamido group Chemical group [H]C([H])([H])C(=O)N([H])[*] 0.000 description 2
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 125000004442 acylamino group Chemical group 0.000 description 2
- 125000004423 acyloxy group Chemical group 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 125000004453 alkoxycarbonyl group Chemical group 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 125000004104 aryloxy group Chemical group 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 125000000649 benzylidene group Chemical group [H]C(=[*])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 239000000872 buffer Substances 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 150000001767 cationic compounds Chemical class 0.000 description 2
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 150000004292 cyclic ethers Chemical class 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 238000010556 emulsion polymerization method Methods 0.000 description 2
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical class OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- PTFYQSWHBLOXRZ-UHFFFAOYSA-N imidazo[4,5-e]indazole Chemical compound C1=CC2=NC=NC2=C2C=NN=C21 PTFYQSWHBLOXRZ-UHFFFAOYSA-N 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 239000002184 metal Chemical class 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 2
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- GYHFUZHODSMOHU-UHFFFAOYSA-N nonanal Chemical compound CCCCCCCCC=O GYHFUZHODSMOHU-UHFFFAOYSA-N 0.000 description 2
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 2
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920002401 polyacrylamide Polymers 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000003505 polymerization initiator Substances 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000003672 processing method Methods 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 238000007342 radical addition reaction Methods 0.000 description 2
- 239000012966 redox initiator Substances 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- 125000005415 substituted alkoxy group Chemical group 0.000 description 2
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 2
- 125000000565 sulfonamide group Chemical group 0.000 description 2
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical class OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- LUMLZKVIXLWTCI-NSCUHMNNSA-N (e)-2,3-dichloro-4-oxobut-2-enoic acid Chemical compound OC(=O)C(\Cl)=C(/Cl)C=O LUMLZKVIXLWTCI-NSCUHMNNSA-N 0.000 description 1
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 1
- BCMCBBGGLRIHSE-UHFFFAOYSA-N 1,3-benzoxazole Chemical class C1=CC=C2OC=NC2=C1 BCMCBBGGLRIHSE-UHFFFAOYSA-N 0.000 description 1
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 1
- 125000001989 1,3-phenylene group Chemical group [H]C1=C([H])C([*:1])=C([H])C([*:2])=C1[H] 0.000 description 1
- ZRHUHDUEXWHZMA-UHFFFAOYSA-N 1,4-dihydropyrazol-5-one Chemical compound O=C1CC=NN1 ZRHUHDUEXWHZMA-UHFFFAOYSA-N 0.000 description 1
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 1
- YGDWUQFZMXWDKE-UHFFFAOYSA-N 1-oxido-1,3-thiazole Chemical class [O-]S1=CN=C=C1 YGDWUQFZMXWDKE-UHFFFAOYSA-N 0.000 description 1
- TZMSYXZUNZXBOL-UHFFFAOYSA-N 10H-phenoxazine Chemical compound C1=CC=C2NC3=CC=CC=C3OC2=C1 TZMSYXZUNZXBOL-UHFFFAOYSA-N 0.000 description 1
- KPVMVJXYXFUVLR-UHFFFAOYSA-N 12-ethyltetradecan-1-amine Chemical compound CCC(CC)CCCCCCCCCCCN KPVMVJXYXFUVLR-UHFFFAOYSA-N 0.000 description 1
- QTLHLXYADXCVCF-UHFFFAOYSA-N 2-(4-amino-n-ethyl-3-methylanilino)ethanol Chemical compound OCCN(CC)C1=CC=C(N)C(C)=C1 QTLHLXYADXCVCF-UHFFFAOYSA-N 0.000 description 1
- WFXLRLQSHRNHCE-UHFFFAOYSA-N 2-(4-amino-n-ethylanilino)ethanol Chemical compound OCCN(CC)C1=CC=C(N)C=C1 WFXLRLQSHRNHCE-UHFFFAOYSA-N 0.000 description 1
- DLLMHEDYJQACRM-UHFFFAOYSA-N 2-(carboxymethyldisulfanyl)acetic acid Chemical compound OC(=O)CSSCC(O)=O DLLMHEDYJQACRM-UHFFFAOYSA-N 0.000 description 1
- WYGWHHGCAGTUCH-UHFFFAOYSA-N 2-[(2-cyano-4-methylpentan-2-yl)diazenyl]-2,4-dimethylpentanenitrile Chemical compound CC(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)C WYGWHHGCAGTUCH-UHFFFAOYSA-N 0.000 description 1
- URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 description 1
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 1
- SZTBMYHIYNGYIA-UHFFFAOYSA-N 2-chloroacrylic acid Chemical compound OC(=O)C(Cl)=C SZTBMYHIYNGYIA-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- KRTDQDCPEZRVGC-UHFFFAOYSA-N 2-nitro-1h-benzimidazole Chemical class C1=CC=C2NC([N+](=O)[O-])=NC2=C1 KRTDQDCPEZRVGC-UHFFFAOYSA-N 0.000 description 1
- SEEZWGFVHCMHJF-UHFFFAOYSA-N 2-nitrosophenol Chemical class OC1=CC=CC=C1N=O SEEZWGFVHCMHJF-UHFFFAOYSA-N 0.000 description 1
- GCABLKFGYPIVFC-UHFFFAOYSA-N 3-(1-benzofuran-2-yl)-3-oxopropanenitrile Chemical compound C1=CC=C2OC(C(CC#N)=O)=CC2=C1 GCABLKFGYPIVFC-UHFFFAOYSA-N 0.000 description 1
- PXDAXYDMZCYZNH-UHFFFAOYSA-N 3-methyl-2h-1,3-benzothiazole Chemical compound C1=CC=C2N(C)CSC2=C1 PXDAXYDMZCYZNH-UHFFFAOYSA-N 0.000 description 1
- XRZDIHADHZSFBB-UHFFFAOYSA-N 3-oxo-n,3-diphenylpropanamide Chemical compound C=1C=CC=CC=1NC(=O)CC(=O)C1=CC=CC=C1 XRZDIHADHZSFBB-UHFFFAOYSA-N 0.000 description 1
- VFXXTYGQYWRHJP-UHFFFAOYSA-N 4,4'-azobis(4-cyanopentanoic acid) Chemical compound OC(=O)CCC(C)(C#N)N=NC(C)(CCC(O)=O)C#N VFXXTYGQYWRHJP-UHFFFAOYSA-N 0.000 description 1
- ZNBNBTIDJSKEAM-UHFFFAOYSA-N 4-[7-hydroxy-2-[5-[5-[6-hydroxy-6-(hydroxymethyl)-3,5-dimethyloxan-2-yl]-3-methyloxolan-2-yl]-5-methyloxolan-2-yl]-2,8-dimethyl-1,10-dioxaspiro[4.5]decan-9-yl]-2-methyl-3-propanoyloxypentanoic acid Chemical compound C1C(O)C(C)C(C(C)C(OC(=O)CC)C(C)C(O)=O)OC11OC(C)(C2OC(C)(CC2)C2C(CC(O2)C2C(CC(C)C(O)(CO)O2)C)C)CC1 ZNBNBTIDJSKEAM-UHFFFAOYSA-N 0.000 description 1
- ZFIQGRISGKSVAG-UHFFFAOYSA-N 4-methylaminophenol Chemical compound CNC1=CC=C(O)C=C1 ZFIQGRISGKSVAG-UHFFFAOYSA-N 0.000 description 1
- LGMWBTURBRPNCJ-UHFFFAOYSA-N 4-n,4-n-diethyl-2-methoxybenzene-1,4-diamine Chemical compound CCN(CC)C1=CC=C(N)C(OC)=C1 LGMWBTURBRPNCJ-UHFFFAOYSA-N 0.000 description 1
- XBTWVJKPQPQTDW-UHFFFAOYSA-N 4-n,4-n-diethyl-2-methylbenzene-1,4-diamine Chemical compound CCN(CC)C1=CC=C(N)C(C)=C1 XBTWVJKPQPQTDW-UHFFFAOYSA-N 0.000 description 1
- QNGVNLMMEQUVQK-UHFFFAOYSA-N 4-n,4-n-diethylbenzene-1,4-diamine Chemical compound CCN(CC)C1=CC=C(N)C=C1 QNGVNLMMEQUVQK-UHFFFAOYSA-N 0.000 description 1
- MTGIPEYNFPXFCM-UHFFFAOYSA-N 4-n-(2-ethoxyethyl)-4-n-ethyl-2-methylbenzene-1,4-diamine Chemical compound CCOCCN(CC)C1=CC=C(N)C(C)=C1 MTGIPEYNFPXFCM-UHFFFAOYSA-N 0.000 description 1
- QZHXKQKKEBXYRG-UHFFFAOYSA-N 4-n-(4-aminophenyl)benzene-1,4-diamine Chemical compound C1=CC(N)=CC=C1NC1=CC=C(N)C=C1 QZHXKQKKEBXYRG-UHFFFAOYSA-N 0.000 description 1
- GKIFPROMYBQIHS-UHFFFAOYSA-N 4-n-ethyl-2-methoxy-4-n-(2-methoxyethyl)benzene-1,4-diamine Chemical compound COCCN(CC)C1=CC=C(N)C(OC)=C1 GKIFPROMYBQIHS-UHFFFAOYSA-N 0.000 description 1
- LRUDIIUSNGCQKF-UHFFFAOYSA-N 5-methyl-1H-benzotriazole Chemical compound C1=C(C)C=CC2=NNN=C21 LRUDIIUSNGCQKF-UHFFFAOYSA-N 0.000 description 1
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical class [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- OWNRRUFOJXFKCU-UHFFFAOYSA-N Bromadiolone Chemical compound C=1C=C(C=2C=CC(Br)=CC=2)C=CC=1C(O)CC(C=1C(OC2=CC=CC=C2C=1O)=O)C1=CC=CC=C1 OWNRRUFOJXFKCU-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 229920002284 Cellulose triacetate Polymers 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 1
- 229910003803 Gold(III) chloride Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- BZORFPDSXLZWJF-UHFFFAOYSA-N N,N-dimethyl-1,4-phenylenediamine Chemical compound CN(C)C1=CC=C(N)C=C1 BZORFPDSXLZWJF-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- QPFYXYFORQJZEC-FOCLMDBBSA-N Phenazopyridine Chemical class NC1=NC(N)=CC=C1\N=N\C1=CC=CC=C1 QPFYXYFORQJZEC-FOCLMDBBSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 241001125046 Sardina pilchardus Species 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
- SRNKZYRMFBGSGE-UHFFFAOYSA-N [1,2,4]triazolo[1,5-a]pyrimidine Chemical compound N1=CC=CN2N=CN=C21 SRNKZYRMFBGSGE-UHFFFAOYSA-N 0.000 description 1
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 1
- XCFIVNQHHFZRNR-UHFFFAOYSA-N [Ag].Cl[IH]Br Chemical compound [Ag].Cl[IH]Br XCFIVNQHHFZRNR-UHFFFAOYSA-N 0.000 description 1
- 229910052946 acanthite Inorganic materials 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 238000007754 air knife coating Methods 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000005153 alkyl sulfamoyl group Chemical group 0.000 description 1
- 125000004422 alkyl sulphonamide group Chemical group 0.000 description 1
- 125000004414 alkyl thio group Chemical group 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000011126 aluminium potassium sulphate Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 150000001414 amino alcohols Chemical class 0.000 description 1
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 235000011162 ammonium carbonates Nutrition 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 1
- 239000002280 amphoteric surfactant Chemical group 0.000 description 1
- 239000012431 aqueous reaction media Substances 0.000 description 1
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 1
- 229910001864 baryta Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- 150000001565 benzotriazoles Chemical group 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- ZJRCIQAMTAINCB-UHFFFAOYSA-N benzoylacetonitrile Chemical compound N#CCC(=O)C1=CC=CC=C1 ZJRCIQAMTAINCB-UHFFFAOYSA-N 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 150000001649 bromium compounds Chemical class 0.000 description 1
- 239000006172 buffering agent Substances 0.000 description 1
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 1
- COPHVUDURPSYBO-UHFFFAOYSA-N butyl dioctyl phosphate Chemical compound CCCCCCCCOP(=O)(OCCCC)OCCCCCCCC COPHVUDURPSYBO-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000298 carbocyanine Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Substances ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
- 235000013985 cinnamic acid Nutrition 0.000 description 1
- 229930016911 cinnamic acid Natural products 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical class OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- HSLXSZISQMKXDM-UHFFFAOYSA-N copper;pyridine-2-carboxylic acid Chemical class [Cu].OC(=O)C1=CC=CC=N1.OC(=O)C1=CC=CC=N1 HSLXSZISQMKXDM-UHFFFAOYSA-N 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical class OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- XWVQUJDBOICHGH-UHFFFAOYSA-N dioctyl nonanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCC(=O)OCCCCCCCC XWVQUJDBOICHGH-UHFFFAOYSA-N 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- ASMQGLCHMVWBQR-UHFFFAOYSA-M diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)([O-])OC1=CC=CC=C1 ASMQGLCHMVWBQR-UHFFFAOYSA-M 0.000 description 1
- MQRJBSHKWOFOGF-UHFFFAOYSA-L disodium;carbonate;hydrate Chemical compound O.[Na+].[Na+].[O-]C([O-])=O MQRJBSHKWOFOGF-UHFFFAOYSA-L 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- AFOSIXZFDONLBT-UHFFFAOYSA-N divinyl sulfone Chemical class C=CS(=O)(=O)C=C AFOSIXZFDONLBT-UHFFFAOYSA-N 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 150000002344 gold compounds Chemical class 0.000 description 1
- RJHLTVSLYWWTEF-UHFFFAOYSA-K gold trichloride Chemical compound Cl[Au](Cl)Cl RJHLTVSLYWWTEF-UHFFFAOYSA-K 0.000 description 1
- 229940076131 gold trichloride Drugs 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 229910000378 hydroxylammonium sulfate Inorganic materials 0.000 description 1
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical class Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 1
- NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- LOCAIGRSOJUCTB-UHFFFAOYSA-N indazol-3-one Chemical compound C1=CC=C2C(=O)N=NC2=C1 LOCAIGRSOJUCTB-UHFFFAOYSA-N 0.000 description 1
- RSAZYXZUJROYKR-UHFFFAOYSA-N indophenol Chemical compound C1=CC(O)=CC=C1N=C1C=CC(=O)C=C1 RSAZYXZUJROYKR-UHFFFAOYSA-N 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 150000004694 iodide salts Chemical class 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 230000001617 migratory effect Effects 0.000 description 1
- ZAKLKBFCSHJIRI-UHFFFAOYSA-N mucochloric acid Natural products OC1OC(=O)C(Cl)=C1Cl ZAKLKBFCSHJIRI-UHFFFAOYSA-N 0.000 description 1
- 150000004780 naphthols Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 235000012149 noodles Nutrition 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- VECVSKFWRQYTAL-UHFFFAOYSA-N octyl benzoate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1 VECVSKFWRQYTAL-UHFFFAOYSA-N 0.000 description 1
- 150000004010 onium ions Chemical class 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- QWYZFXLSWMXLDM-UHFFFAOYSA-M pinacyanol iodide Chemical compound [I-].C1=CC2=CC=CC=C2N(CC)C1=CC=CC1=CC=C(C=CC=C2)C2=[N+]1CC QWYZFXLSWMXLDM-UHFFFAOYSA-M 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920006295 polythiol Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- GRLPQNLYRHEGIJ-UHFFFAOYSA-J potassium aluminium sulfate Chemical compound [Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRLPQNLYRHEGIJ-UHFFFAOYSA-J 0.000 description 1
- 229910000343 potassium bisulfate Inorganic materials 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical compound O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 description 1
- NDGRWYRVNANFNB-UHFFFAOYSA-N pyrazolidin-3-one Chemical class O=C1CCNN1 NDGRWYRVNANFNB-UHFFFAOYSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 1
- 150000004053 quinones Chemical class 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 238000006462 rearrangement reaction Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 235000019512 sardine Nutrition 0.000 description 1
- 150000003378 silver Chemical class 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 229940056910 silver sulfide Drugs 0.000 description 1
- XUARKZBEFFVFRG-UHFFFAOYSA-N silver sulfide Chemical compound [S-2].[Ag+].[Ag+] XUARKZBEFFVFRG-UHFFFAOYSA-N 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229940079827 sodium hydrogen sulfite Drugs 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000012089 stop solution Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- 125000005156 substituted alkylene group Chemical group 0.000 description 1
- NVBFHJWHLNUMCV-UHFFFAOYSA-N sulfamide Chemical class NS(N)(=O)=O NVBFHJWHLNUMCV-UHFFFAOYSA-N 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 125000004149 thio group Chemical group *S* 0.000 description 1
- 235000010215 titanium dioxide Nutrition 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- NJPOTNJJCSJJPJ-UHFFFAOYSA-N tributyl benzene-1,3,5-tricarboxylate Chemical compound CCCCOC(=O)C1=CC(C(=O)OCCCC)=CC(C(=O)OCCCC)=C1 NJPOTNJJCSJJPJ-UHFFFAOYSA-N 0.000 description 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
- 150000003639 trimesic acids Chemical class 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 150000003754 zirconium Chemical class 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/32—Colour coupling substances
- G03C7/34—Couplers containing phenols
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/32—Colour coupling substances
- G03C7/327—Macromolecular coupling substances
- G03C7/3275—Polymers obtained by reactions involving only carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Description
æ¬çºæã¯è³éŠæäžçŽã¢ãã³çŸåè¬ã®é
žåäœãšã«
ãããªã³ã°ãããæ°èŠãªã·ã¢ã³è²å圢æããªããŒ
ã«ãã©ãŒã®ã©ããã¯ã¹ãå«æããããã²ã³åéã«
ã©ãŒåçæå ææã«é¢ãããã®ã§ããã ããã²ã³åéåçæå ææã«é²å ãäžããããš
çºè²çŸåããããšã«ããé žåãããè³éŠæäžçŽã¢
ãã³çŸåè¬ãšè²çŽ 圢æã«ãã©ãŒãšãåå¿ããè²ç»
åãåŸãããããšã¯ããç¥ãããŠããã ããã²ã³åéã«ã©ãŒåçææãçºè²çŸåããã
ãšã«ããé žåãããè³éŠæäžçŽã¢ãã³çŸåè¬ãšã«
ãã©ãŒãšãåå¿ããŠã€ã³ãããšããŒã«ãã€ã³ãã¢
ããªã³ãã€ã³ããã³ãã¢ãŸã¡ãã³ãããšãããµãž
ã³ãããšããžã³åã³ããã«é¡ããè²çŽ ãã§ããè²
ç»åã圢æãããããšã¯ç¥ãããŠããããã®æ¹åŒ
ã«ãããŠã¯éåžžè²åçŸã«ã¯æžè²æ³ã䜿ãããéã
ç·ãããã³èµ€ã«éžæçã«æå ããããã²ã³åéä¹³
å€ãšããããäœè²é¢ä¿ã«ããã€ãšããŒãããŒã³
ã¿ãããã³ã·ã¢ã³ã®è²ç»å圢æå€ãšã䜿çšãã
ãã ã€ãšããŒè²ç»åã圢æããããã«ã¯äŸãã°ã¢ã·
ã«ã¢ã»ãã¢ããªããåã¯ãã³ãŸã€ã«ã¡ã¿ã³ç³»ã«ã
ã©ãŒã䜿ãããããŒã³ã¿è²ç»åã圢æããããã«
ã¯äž»ãšããŠãã©ãŸãã³ããã©ãŸããã³ãã€ãããŸ
ãŒã«ãã·ã¢ãã¢ã»ãããšãã³ãŸãã¯ã€ã³ããŸãã³
ç³»ã«ãã©ãŒã䜿ãããã·ã¢ã³è²ç»åã圢æããã
ãã«ã¯äž»ãšããŠããšããŒã«ç³»ã«ãã©ãŒãäŸãã°ã
ãšããŒã«é¡åã³ããããŒã«é¡ã䜿ãããã ã«ã©ãŒã«ãã©ãŒã¯åçš®ã®èŠä»¶ã«åèŽãããã®ã§
ãªããã°ãªãããäŸãã°è¯å¥œãªåå ç¹æ§ãæãã
çºè²çŸåã«ããå ã枩床ãããã³æ¹¿åºŠã«å¯Ÿãé·æ
éã«ãããé«åºŠã®å®å®æ§ã瀺ãæŽæåãäžããã
ãšãå¿ èŠã§ããã ãšããã§ãå€å±€ã«ã©ãŒæå ææã§ã¯ãæ··è²ãå°
ãããè²åçŸãããããããã«ããããã®ã«ãã©
ãŒãåé¢ããå±€ãåºå®ããããšãå¿ èŠã§ãããã
ã®ã«ãã©ãŒã®èæ¡æ£åã®æ¹æ³ã«ã¯å€ããç¥ãããŠ
ããã ãã®ïŒã€ã®æ¹æ³ã¯ã«ãã©ãŒã®ååäžã«ãæ¡æ£ã
é²ãããé·éã®èèªæåºãå°å ¥ãããã®ã§ããã
ãã®æ¹æ³ã«ããã«ãã©ãŒã¯ãŒã©ãã³æ°Žæº¶æ¶²ãšæ··å
ããªãããã¢ã«ã«ãªã«å¯æº¶åãããŠãŒã©ãã³æ°Žæº¶
液ã«æ·»å ãããããããã¯é«æ²žç¹ã®ææ©æº¶å€ã«ãš
ãããŠãŒã©ãã³æ°Žæº¶æ¶²äžã«ä¹³ååæ£ããããšãå¿
èŠã§ããã ãã®ãããªã«ã©ãŒã«ãã©ãŒã¯ä¹³å€äžã§çµæ¶ã®æ
åºãåŒãèµ·ãããããããã¯é«æ²žç¹ã®ææ©æº¶å€ã
çšããå Žåã«ã¯ä¹³å€å±€ãè»åãããããå€éã®ãŒ
ã©ãã³ãå¿ èŠãšãããã®çµæä¹³å€å±€ãèãããã
ãšããèŠæã«éã®çµæãããããã ã«ãã©ãŒãèæ¡æ£åããå¥ã®æ¹æ³ã¯åéäœã«ã
ã©ãŒã®éåã§åŸãããããªããŒã«ãã©ãŒãã©ãã
ã¯ã¹ã®åœ¢ã§å©çšããæ¹æ³ã§ããã ããªããŒã«ãã©ãŒãã©ããã¯ã¹ã®åœ¢ã§èŠªæ°Žæ§ã³
ãã€ãçµæç©ã«å ããæ¹æ³ãšããŠã¯ãåŸæ¥ãä¹³å
éåæ³ã§äœãããã©ããã¯ã¹ãçŽæ¥ãŒã©ãã³ãã
ã²ã³åéä¹³å€ã«å ããæ¹æ³ãšåéäœã«ãã©ãŒã®é
åã§åŸããã芪油æ§ããªããŒã«ãã©ãŒããŒã©ãã³
氎溶液äžã«ã©ããã¯ã¹ã®åœ¢ã§åæ£ããæ¹æ³ãç¥ã
ããŠãããåè ã®ä¹³åéåæ³ã®äŸã¯æ°Žæ§ãŒã©ãã³
äžã§ã®ä¹³åéåæ³ãç±³åœç¹èš±3370952å·ã«ãæ°Žäž
ã§ã®ä¹³åéåæ³ãç±³åœç¹èš±4080211å·ã«èšèŒãã
ãŠãããåŸè ã®èŠªæ²¹æ§ããªããŒã«ãã©ãŒã©ããã¯
ã¹ã®åœ¢ã§åæ£ããæ¹æ³ã®äŸã¯ç±³åœç¹èš±3451820å·
ã«èšèŒãããŠããã ããªããŒã«ãã©ãŒãã©ããã¯ã¹ã®åœ¢ã§èŠªæ²¹æ§ã³
ãã€ãçµæç©ã«å ããæ¹æ³ã«ã¯ä»ã®æ¹æ³ã«æ¯ã¹ãŠ
å€ãã®å©ç¹ããã€ã ãŸããçæ°Žæ§çŽ æãã©ããã¯ã¹åãããŠããã
ã圢æãããèã®åŒ·åºŠãå£åãããããšããªãã
ãŸããã©ããã¯ã¹ã¯é«æ¿åºŠã®åéäœã«ãã©ãŒãå«
ãããšãåºæ¥ãã®ã§ã容æã«é«æ¿åºŠã®ã«ãã©ãŒã
ä¹³å€ã«å«æãããããšãã§ãããããç²åºŠã®å¢å€§
ãå°ãªãããèãèãã§ãã·ã€ãŒããã¹ãæ¹è¯ã§
ããç¹ã§ãããããã«ãå šãé移è¡æ§ã®ããæ··è²
ããªãä¹³å€èäžã®äžã§ã«ãã©ãŒãæåºããããšã
å°ãªãããšã§ããã ãã®ããã«ããªããŒã«ãã©ãŒãã©ããã¯ã¹ã®åœ¢
ã§ãŒã©ãã³ããã²ã³åéä¹³å€ã«å ãããã®ãšããŠ
ã¯ãäŸãã°ç±³åœç¹èš±4080211å·ãç±³åœç¹èš±1247688
å·ãç±³åœç¹èš±3451820å·ã«ã¯ãã®è£œé æ¹æ³ãšïŒåœ
éããŒã³ã¿ããªããŒã«ãã©ãŒã©ããã¯ã¹ãã西ç¬
ç¹èš±272591å·åã³ç±³åœç¹èš±3926436å·ã«ã¯ç«¶äºã«
ãã©ãŒãšã®å ±éåã©ããã¯ã¹ãç±³åœç¹èš±ç¬¬
3767412å·ãResearch Disclosure21728ïŒ1982幎ïŒ
ã«ã¯ã·ã¢ã³ããªããŒã«ãã©ãŒã©ããã¯ã¹ãç¥ãã
ãŠããã ããããªããã·ã¢ã³ããªããŒã«ãã©ãŒã®ã©ãã
ã¯ã¹ã«ã¯åèšãããããªå€ãã®åªããç¹åŸŽãæã
ãªãã次ã®ãããªæ¹è¯ãã¹ãåé¡ããããç¹ã«ç±
å ç¢æ§ã«ã€ããŠã¯åŒ·ãæ¹è¯ãæãŸããŠããã ïŒ çŸååŠçåŸã®ã«ã©ãŒåçã«ãããŠã·ã¢ã³è²å
ã®ç±åã³æ¹¿ç±ã«å¯Ÿããå ç¢æ§ãäœãã ïŒ ã«ãããªã³ã°ã®åå¿é床ãå£ãããçæãã
è²çŽ ã®æ床ãé調ãããã³è²çŽ æ¿åºŠãäœãã ãããã€ãŠæ¬çºæã®ç®çã¯ç¬¬ïŒã«çŸååŠçåŸã®
ã«ã©ãŒåçã«ãããŠç±ããã³æ¹¿ç±ã«å¯ŸããŠå ç¢ãª
è²ç»åã圢æããæ°èŠãªã·ã¢ã³è²å圢æããªããŒ
ã«ãã©ãŒã®ã©ããã¯ã¹ãæäŸããããšã§ããã æ¬çºæã®ç®çã¯ç¬¬ïŒã«çºè²æ§ã®èããç§ããæ°
èŠãªã·ã¢ã³è²å圢æããªããŒã«ãã©ãŒã©ããã¯ã¹
ãæäŸããããšã§ããã æ¬çºæã®ç®çã¯ç¬¬ïŒã«æ°èŠãªã·ã¢ã³è²å圢æã
ãªããŒã«ãã©ãŒã©ããã¯ã¹ã®ååšã®ããšã«ããã²
ã³åéä¹³å€ãçŸåããããšã«ãã€ãŠã·ã¢ã³è²ç»å
ã圢æããæ¹æ³ãæäŸããããšã§ããã æ¬çºæã®ç®çã¯ç¬¬ïŒã«æ°èŠãªã·ã¢ã³è²å圢æã
ãªããŒã«ãã©ãŒã®ã©ããã¯ã¹ãå«æããããã²ã³
åéã«ã©ãŒåçæå ææãåçåŠçæ¹æ³ãããã¯
ç»å圢ææ¹æ³ãæäŸããããšã«ããã æ¬çºæè çã¯çš®ã ã®ç 究ãéããçµææ¬çºæã®
ãããã®ç®çã¯è³éŠæäžçŽã¢ãã³çŸåè¬ã®é žåäœ
ãšã«ãããªã³ã°ããŠææã圢æãããäžèšäžè¬åŒ
ããã«å¯Ÿå¿ããã·ã¢ã³ã«ãã©ãŒåéäœã®å埩å
äœãäžè¬åŒããã«å¯Ÿå¿ããé žæåãå«æãããš
ãã¬ã³æ§äžé£œååéäœã®å埩åäœããã³ã¡ãã«ã¢
ã¯ãªã¬ãŒãã®å埩åäœã®å°ãªããšãïŒã€ãå埩å
äœãšããŠæããã·ã¢ã³è²çŽ 圢æããªããŒã«ãã©ãŒ
ã®ã©ããã¯ã¹ãä¹³å€å±€äžã«å«æããããã²ã³åé
åçæå ææã«ããéæãããã ïŒåŒäžR1ã¯æ°ŽçŽ ååãççŽ ïŒãïŒåã®äœçŽã¢
ã«ãã«åºãŸãã¯å¡©çŽ ãè¡šãããã¯é žåãããè³
éŠæäžçŽã¢ãã³çŸåè¬ãšã«ãããªã³ã°ããŠã·ã¢ã³
ææã圢æãããã·ã¢ã³ã«ãã©ãŒæ®åºãè¡šãããïŒ ïŒåŒäžR2ã¯æ°ŽçŽ ååãççŽ æ°ïŒãïŒåã®äœçŽ
ã¢ã«ãã«åºãŸãã¯å¡©çŽ ãè¡šãããã¯âCOOãŸ
ãã¯âCONHâãè¡šãããã¯ççŽ æ°ïŒã10å
ã®ã¢ã«ãã¬ã³åºãããã¯ã¢ã©ã«ãã¬ã³åºãŸãã¯ç
çŽ æ°ïŒã10ã®ããšãã¬ã³åºãè¡šãããã¢ã«ãã¬ã³
åºã¯çŽéã§ããåå²éã§ãç°ç¶ã§ããããã¯â
COOMãŸãã¯âSO3Mãè¡šããããã ãïŒã¯æ°ŽçŽ
ã€ãªã³ãã¢ã«ã«ãªéå±ã€ãªã³ãã¢ã«ã«ãªåé¡éå±
ã€ãªã³ãŸãã¯ã¢ã³ã¢ããŠã ã€ãªã³ãè¡šãããïœã¯
ïŒãŸãã¯ïŒãè¡šããã ãã詳ããã¯æ¬çºæã®ã·ã¢ã³è²å圢æããªããŒ
ã«ãã©ãŒã©ããã¯ã¹ã«ãããŠé žåãããè³éŠæäž
çŽã¢ãã³çŸåè¬ãšã«ãããªã³ã°ããŠã·ã¢ã³è²åã
圢æããã·ã¢ã³ã«ãã©ãŒæ®åºããšããŠã¯ããšã
ãŒã«åãããããã¯ãããããã¯ããããŒã«
åããã奜ãŸããã åŒäžR3ã¯æ°ŽçŽ ååãŸãã¯ççŽ æ°ïŒãïŒåã®äœ
çŽã¢ã«ãã«åºãè¡šãããã¯äžè¬åŒããã®NH
åºã«çµåããççŽ æ°ïŒã10åã®ç¡çœ®æãŸãã¯çœ®æ
ã¢ã«ãã¬ã³åºãã¢ã©ã«ãã¬ã³åºãããã¯ããšãã¬
ã³åºãè¡šãããã¢ã«ãã¬ã³åºã¯çŽéã§ãåå²ããŠ
ããããïŒã¢ã«ãã¬ã³åºãšããŠã¯äŸãã°ã¡ãã¬ã³ã
ã¡ãã«ã¡ãã¬ã³ããžã¡ãã«ã¡ãã¬ã³ããžã¡ãã¬
ã³ãããªã¡ãã¬ã³ãããã©ã¡ãã¬ã³ããã³ã¿ã¡ã
ã¬ã³ããããµã¡ãã¬ã³ããã·ã«ã¡ãã«ãã¢ã©ã«ã
ã¬ã³åºãšããŠã¯äŸãã°ãã³ãžãªãã³ãããšãã¬ã³
åºãšããŠã¯äŸãã°ïœâããšãã¬ã³ãïœâããšãã¬
ã³ãã¡ãã«ããšãã¬ã³åºãªã©ããããïŒ R4ã¯æ°ŽçŽ ååããŸãã¯ççŽ æ°ïŒãïŒåã®äœçŽ
ã¢ã«ãã«åºïŒäŸãã°ã¡ãã«åºããšãã«åºãŸãã¯ïœ
âããã«åºãªã©ïŒã§ãR5ã¯ç¡çœ®æãŸãã¯çœ®æã¢
ã«ãã«åºãããšãã«åºãŸãã¯ããšãã«ã¢ããåºã
è¡šããã ã¯ããã²ã³ååïŒããçŽ ååãå¡©çŽ ååãè
çŽ ååïŒãã¯æ°ŽçŽ ååãããã²ã³ååïŒäŸãã°
ããçŽ ååãå¡©çŽ ååãèçŽ ååïŒãŸãã¯çœ®æã¢
ã«ã³ãã·åºãè¡šããã ïœïŒïœã¯åã ïŒãŸãã¯ïŒãè¡šããã ããã§ïŒ€ã§è¡šããããã¢ã«ãã¬ã³åºãã¢ã©ã«ã
ã¬ã³åºããŸãã¯ããšãã¬ã³åºã®çœ®æåºãšããŠã¯ã¢
ãªãŒã«åºïŒäŸãã°ããšãã«åºïŒããããåºãæ°Žé ž
åºãã·ã¢ãåºãã¹ã«ãåºãã¢ã«ã³ãã·åºïŒäŸãã°
ã¡ããã·åºïŒãã¢ãªãŒã«ãªãã·åºïŒäŸãã°ããšã
ãã·åºïŒãã¢ã·ã«ãªãã·åºïŒäŸãã°ã¢ã»ããã·
åºïŒãã¢ã·ã«ã¢ããåºïŒäŸãã°ã¢ã»ãã«ã¢ãã
åºïŒãã¹ã«ãã³ã¢ããåºïŒäŸãã°ã¡ã¿ã³ã¹ã«ãã³
ã¢ããåºïŒãã¹ã«ãã¢ã¢ã€ã«åºïŒäŸãã°ã¡ãã«ã¹
ã«ãã¢ã¢ã€ã«åºïŒãããã²ã³ååïŒäŸãã°ããçŽ ã
å¡©çŽ ãèçŽ ãªã©ïŒãã«ã«ããã·åºãã«ã«ãã¢ã€ã«
åºïŒäŸãã°ã¡ãã«ã«ã«ãã¢ã€ã«åºïŒãã¢ã«ã³ãã·
ã«ã«ããã«åºïŒäŸãã°ã¡ããã·ã«ã«ããã«åºãª
ã©ïŒãã¹ã«ããã«åºïŒäŸãã°ã¡ãã«ã¹ã«ããã«åºïŒ
ãæããããããã®çœ®æåºãïŒã€ä»¥äžãããšãã¯
åãã§ãç°ã€ãŠãããã ãŸãã§è¡šãããã眮æã¢ã«ã³ãã·åºã®çœ®æåº
ãšããŠã¯ã¢ãªãŒã«åºïŒäŸãã°ããšãã«åºïŒããã
ãåºãæ°Žé žåºãã·ã¢ãåºãã¹ã«ãåºãã¢ã«ã³ãã·
åºïŒäŸãã°ã¡ããã·åºïŒãã¢ãªãŒã«ãªãã·åºïŒäŸ
ãã°ããšããã·åºïŒãã¢ã·ã«ãªãã·åºïŒäŸãã°ã¢
ã»ããã·åºïŒãã¢ã·ã«ã¢ããåºïŒäŸãã°ã¢ã»ãã«
ã¢ããåºïŒãã¢ã«ãã«ã¹ã«ãã³ã¢ããåºïŒäŸãã°
ã¡ã¿ã³ã¹ã«ãã³ã¢ããåºïŒãã¢ã«ãã«ã¹ã«ãã¢ã¢
ã€ã«åºïŒäŸãã°ã¡ãã«ã¹ã«ãã¢ã¢ã€ã«åºïŒããã
ã²ã³ååïŒäŸãã°ããçŽ ãå¡©çŽ ãèçŽ ãªã©ïŒãã«
ã«ããã·åºãã¢ã«ãã«åºã«ã«ãã¢ã€ã«åºïŒäŸãã°
ã¡ãã«ã«ã«ãã¢ã€ã«åºïŒãã¢ã«ã³ãã·ã«ã«ããã«
åºïŒäŸãã°ã¡ããã·ã«ã«ããã«åºãªã©ïŒãã¢ã«ã
ã«åºã¹ã«ããã«åºïŒäŸãã°ã¡ãã«ã¹ã«ããã«åºãª
ã©ïŒãã¢ã«ãã«ããªåºïŒäŸãã°Î²âã«ã«ããã·ãš
ãã«ããªåºãªã©ïŒãªã©ãæããããããã®çœ®æåº
ãïŒã€ä»¥äžãããšãã¯åãã§ãç°ã€ãŠãããã ããã«R5ã§è¡šããããã¢ã«ãã«åºãããšãã«
åºã®çœ®æåºãšããŠã¯ããçŽ ååã奜ãŸãããããš
ãã«ã¢ããåºã®çœ®æåºãšããŠã¯ãããåºãã·ã¢ã
åºãã¹ã«ãã³ã¢ããåºïŒäŸãã°ã¡ã¿ã³ã¹ã«ãã³ã¢
ããåºïŒããã«ãã¢ã¢ã€ã«åºïŒäŸãã°ã¡ãã«ã¹ã«
ãã¢ã¢ã€ã«åºïŒãããã²ã³ååïŒäŸãã°ããçŽ ã
å¡©çŽ ãèçŽ ïŒãã«ã«ãã¢ã€ã«åºïŒäŸãã°ã¡ãã«ã«
ã«ãã¢ã€ã«åºïŒãã¹ã«ããã«åºïŒäŸãã°ã¡ãã«ã¹
ã«ããã«åºïŒãæããããããããã®çœ®æåºãïŒ
ã€ä»¥äžãããšãã¯åãã§ãç°ãªã€ãŠãããã äžè¬åŒããã«å¯Ÿå¿ããè³éŠæäžçŽã¢ãã³çŸå
è¬ãšé žåã«ãããªã³ã°ããèœåãæããªãé žæå
ãå«æãããšãã¬ã³æ§äžé£œååéäœãšããŠã¯ã¢ã¯
ãªã«é žãαâã¯ããã¢ã¯ãªã«é žãαâã¢ã«ã¢ã¯ãª
ã«é žïŒäŸãã°ã¡ã¿ã¯ãªã«é žïŒçããã³ããããã
èªå°ãããé žæåãå«æãããšã¹ãã«ãããã¯ã¢
ããã§ãããåèšäžè¬åŒããã®ïŒ¢ã¯ã¢ã«ãã¬ã³
åºãã¢ã©ã«ãã¬ã³åºããŸãã¯ããšãã¬ã³åºãè¡šã
ããã¢ã«ãã¬ã³åºãµçŽéã§ããåå²éã§ããç°ç¶
ã§ããããã¢ã«ãã¬ã³åºãšããŠã¯äŸãã°ã¡ãã¬
ã³ãã¡ãã«ã¡ãã¬ã³ããšãã¬ã³ãã¡ãã«ãšãã¬
ã³ããžã¡ãã«ãšãã¬ã³ãããªã¡ãã¬ã³ãããã©ã¡
ãã¬ã³ããã³ã¿ã¡ãã¬ã³ããããµã¡ãã¬ã³ããã
ã³ãã·ã«ã¡ãã¬ã³ãã¢ã©ã«ãã¬ã³åºãšããŠã¯äŸã
ã°ãã³ãžãªãã³ãããšãã¬ã³åºãšããŠã¯äŸãã°ïœ
âããšãã¬ã³ããã³ïœâããšãã¬ã³ãªã©ãããã äžè¬åŒãããäžè¬åŒããã§è¡šããããå埩
åäœã¯ïŒçš®é¡ä»¥äžå«ãã§ãããã æ¬çºæã«çšããããã·ã¢ã³ããªããŒã«ãã©ãŒã©
ããã¯ã¹ã¯åèšããããã«åéäœã«ãã©ãŒã®éå
ã§åŸããã芪油æ§ããªããŒã«ãã©ãŒãææ©æº¶åªã«
溶ããããã®ããŒã©ãã³æ°Žæº¶æ¶²äžã«ã©ããã¯ã¹ã®
圢ã§ä¹³ååæ£ããŠäœã€ãŠãããããããã¯çŽæ¥ä¹³
åéåæ³ã§äœã€ãŠãããã 芪油æ§ããªããŒã«ãã©ãŒããŒã©ãã³æ°Žæº¶æ¶²äžã«
ã©ããã¯ã¹ã®åœ¢ã§ä¹³ååæ£ããæ¹æ³ã«ã€ããŠã¯ç±³
åœç¹èš±3451820å·ã«ãä¹³åéåã«ã€ããŠã¯ç±³åœç¹
蚱第4080211å·ãå3370952å·ã«èšèŒãããŠããæ¹
æ³ãçšããããšãåºæ¥ãã 次ã«ã·ã¢ã³ããªããŒã«ãã©ãŒã®äžè¬çéåæ³ã«
ã€ããŠè¿°ã¹ãã ãšãã¬ã³ç³»äžé£œååºäœåéäœã®ããªãŒã©ãžã«ã«
éåã¯ååŠçéå§å€ã®ç±å解ãŸãã¯é žåæ§ååç©
ã«ãããéå å€ã®äœçšïŒã¬ããã¯ã¹éå§å€ïŒãŸã
ã¯ç©ççäœçšäŸãã°çŽ«å€ç·ãŸãã¯ä»ã®é«ãšãã«ã®
ãŒèŒ»å°ãé«åšæ³¢çã«ãã圢æãããããªãŒã©ãžã«
ã«ã®åéäœååã«ä»å ããããšã«ãã€ãŠéå§ãã
ãã äž»ãªååŠçéå§å€ãšããŠã¯ããŒãµã«ããšãŒã
ïŒäŸãã°ã¢ã³ã¢ããŠã ããŒãµã«ããšãŒããããã³
ã«ãªãŠã ããŒãµã«ããšãŒããªã©ïŒã¢ãŸãã¹ç³»éå
éå§å€ïŒäŸãã°ïŒïŒ2â²âã¢ãŸãã¹ã€ãœé ·é žãžã¡ã
ã«ãïŒïŒ2â²âã¢ãŸãã¹ã€ãœé ·é žãžãšãã«ãïŒïŒ
2â²âã¢ãŸãã¹ã€ãœããããããªã«ãïŒïŒ2â²âã¢ãŸ
ãã¹âïŒïŒïŒïŒâãžã¡ãã«ãã¬ããããªã«ïŒãã
ã³ïŒïŒ4â²âã¢ãŸãã¹âïŒïŒâã·ã¢ããã¬ãªã¢ã³é žïŒ
ãªã©ïŒãããŒãªããµã€ãç³»éåéå§å€ïŒäŸãã°ã
ã³ãŸã€ã«ããŒãªããµã€ããã¯ãããã³ãŒã³ããŒãª
ããµã€ããããã³éé žåæ°ŽçŽ ãªã©ïŒãããã æ®éã®ã¬ããã¯ã¹éå§å€ã«ã¯éé žåæ°ŽçŽ âé
ïŒïŒå¡©ãéç¡«é žã«ãªâéç¡«é žã«ãªãŠã ãã»ãªãŠ
ã å¡©ã¢ã«ã³ãŒã«çãããã éå§å€ã®äŸããã³ãã®äœçšã¯F.A.Boveyè
ãFmulsion polymerizationãInterscience
Publishes Inc.New Yorkçºè¡1955幎第59â第93
é ã«èšèŒãããŠããã 芪油æ§ããªããŒã«ãã©ãŒã®éåã«çšãããã溶
åªãšããŠã¯éåžžåéäœãšç¡éã«æ··åãããšåæã«
çæãã芪油æ§ããªããŒã«ãã©ãŒã®è¯æº¶åªã§ãã
ãããéå§å€ãšãåå¿ããããªãŒã©ãžã«ã«ä»å é
åã®éåžžã®äœçšã劚害ããªããã®ãæãŸãããå ·
äœçã«ã¯äŸãã°ãè³éŠæçåæ°ŽçŽ ïŒäŸãã°ãã³ãŒ
ã³ããã«ãšã³ãªã©ïŒãçåæ°ŽçŽ ïŒäŸãã°ïœâãã
ãµã³ãªã©ïŒãã¢ã«ã³ãŒã«ïŒäŸãã°ã¡ã¿ããŒã«ããš
ã¿ããŒã«ãïœâãããããŒã«ãã€ãœãããããŒ
ã«ãtertâãã¿ããŒã«ãªã©ïŒãã±ãã³ïŒäŸãã°ã¢
ã»ãã³ãã¡ãã«ãšãã«ã±ãã³ãªã©ïŒãç°ç¶ãšãŒã
ã«ïŒäŸãã°ããã©ããããã©ã³ããžãªããµã³ãª
ã©ïŒããšã¹ãã«ïŒäŸãã°é ¢é žãšãã«ãªã©ïŒãå¡©çŽ å
çåæ°ŽçŽ ïŒäŸãã°å¡©åã¡ãã¬ã³ãã¯ãããã«ã ãª
ã©ïŒãã¢ããïŒäŸãã°ãžã¡ãã«ãã«ã ã¢ããããž
ã¡ãã«ã¢ã»ãã¢ãããªã©ïŒãã¹ã«ããã·ãïŒäŸã
ã°ãžã¡ãã«ã¹ã«ããã·ããªã©ïŒããããªã«ïŒäŸã
ã°ã¢ã»ããããªã«ãªã©ïŒãããã³ãã®çµåããçš
ããããšãåºæ¥ãã äžæ¹åºäœæ°Žäžæº¶æ§åéäœã«ãã©ãŒã®ä¹³åéåã¯
éåžžæ°Žç³»ãããã¯æ°ŽïŒææ©æº¶åªç³»ã§è¡ãããã®é
䜿çšããææ©æº¶åªãšããŠã¯äžèšææ©æº¶åªãšåãã
ãã«(1)åºäœæ°Žäžæº¶æ§åéäœã«ãã©ãŒã«å¯Ÿããå®è³ª
çã«äžæŽ»æ§ã§ããã(2)ããªãŒã©ãžã«ã«ä»å éåã®
éåžžã®äœçšã劚害ããªããã®ã§ããã(3)éåäžã
ãã³ïŒãŸãã¯ïŒéååŸèžçã«ãã€ãŠæ°Žæ§åå¿åªäœ
ãã容æã«é€å»ãããäœæ²žç¹ã§ãããã®ã奜ãŸã
ãã奜ãŸããäŸããããã°ççŽ æ°ïŒãïŒåã®äœçŽ
ã¢ã«ã³ãŒã«ïŒäŸãã°ã¡ã¿ããŒã«ããšã¿ããŒã«ãã
ãã³ã€ãœãããããŒã«ïŒãã±ãã³ïŒäŸãã°ã¢ã»ã
ã³ïŒãå¡©çŽ åçåæ°ŽçŽ ïŒäŸãã°ã¯ãããã«ã ïŒãè³
éŠæçåæ°ŽçŽ ïŒäŸãã°ãã³ãŒã³ïŒãç°ç¶ãšãŒãã«
ïŒäŸãã°ããã©ããããã©ã³ïŒããšã¹ãã«ïŒäŸäŸã
ã°ãšãã«ã¢ã»ããŒãïŒããããªã«ïŒäŸãã°ã¢ã»ã
ãããªã«ïŒçãããã ãŸãä¹³åéåã®ããçšããããä¹³åå€ãšããŠã¯
çé¢æŽ»æ§ãæã€ååç©ãçšãããã奜ãŸããã¯ç³
ãããã¹ã«ãããŒãããã³ãµã«ããšãŒããã«ããª
ã³ååç©ãäž¡æ§ååç©ããã³é«ååä¿è·ã³ãã€ã
ãæããããããããã®çŸ€ã®äŸããã³ãããã®äœ
çšã¯Belgische Chemische Industrieã第28å·»ã
第16ã第20é ïŒ1963幎ïŒã«èšèŒãããŠããã éå枩床ã¯çæããããªããŒã®ååéãéå§å€
ã®çš®é¡ãªã©ãšé¢é£ããŠèšå®ããå¿ èŠãããïŒâ以
äžãã100â以äžãŸã§å¯èœã§ããããéåžžã¯30â
ã100âã®ç¯å²ã§éåããã 次ã«ã芪油æ§ããªããŒã«ãã©ãŒããŒã©ãã³æ°Žæº¶
液äžã«ã©ããã¯ã¹ã®åœ¢ã§åæ£ããéã芪油æ§ããª
ããŒã«ãã©ãŒã溶解ããããã«çšããææ©æº¶åªã¯
åæ£æ¶²ãå¡åžããåããããã¯ïŒããŸã奜ãŸãã
ãªããïŒå¡åžããåæ£æ¶²ã®ä¹Ÿç¥äžã®æ°åã®éã«é€
ãããã溶åªãé€å»ããæ¹æ³ãšããŠã¯ããšãã°ãŒ
ã©ãã³ããŒãã«åã§æ°ŽæŽããããšã«ããé€å»ãã
ãããã«ããçšåºŠæ°Žæº¶æ§ã®ãã®ãããã³åŽé§ä¹Ÿ
ç¥ãç空ãŸãã¯æ°Žèžæ°ããŒãžã³ã°æ³ã«ãã€ãŠé€ã
ãããã®ãããã åããã®é€å»ãããææ©æº¶åªãšããŠã¯ãšã¹ãã«
äŸãã°äœçŽã¢ã«ãã«ãšã¹ãã«ãäœçŽã¢ã«ãã«ãšãŒ
ãã«ãã±ãã³ãããã²ã³åçåæ°ŽçŽ ããšãã°å¡©å
ã¡ãã¬ã³ãŸãã¯ããªã¯ãããšãã¬ã³ãããçŽ åç
åæ°ŽçŽ ãã¢ã«ã³ãŒã«äŸãã°ïœâããã«ã¢ã«ã³ãŒ
ã«ãïœâãªã¯ãã«ã¢ã«ã³ãŒã«ãããã³ãããã®çµ
åããå å«ããã 芪油æ§ããªããŒã«ãã©ãŒãåæ£ããåæ£å€ãšã
ãŠã¯ãã©ã®ãããªåœ¢åŒã®ãã®ãçšããŠããããã€
ãªã³æ§çé¢æŽ»æ§å€ç¹ã«ãã¢ããªã³æ§åã®ãã®ã奜
é©ã§ããã âã»ãã«ãã¿ã€ã³ãâã¢ã«ãã«ã¢ãããã
ããªã³é žå¡©ãâã¢ã«ãã«ã€ãããžããããªã³é ž
å¡©ã®ãããªäž¡æ§åã®ãã®ãçšããããšãã§ããã ãŸããããªããŒã«ãã©ãŒãšè³éŠæäžçŽã¢ãã³çŸ
åè¬ã®é žåäœãã圢æãããææã®è²åãã調ç¯
ããå¡åžããä¹³å€ã®ããã¿æ§ãæ¹åããããã«ã
æ°žä¹ ç溶åªãããªãã¡é«æ²žç¹ïŒ200â以äžïŒã®æ°Ž
äžæ··åæ§ææ©æº¶åªãå ããŠãããã ãŸããæçµã®ä¹³å€ç®èã®åããã§ããã ãèã
ãé«ãé®®æ床ãç¶æããããã«ãã®æ°žä¹ ç溶åªã®
æ¿åºŠã¯äœãããããšãæãŸããã ããªããŒã«ãã©ãŒäžã«å ããäžè¬åŒããã«å¯Ÿ
å¿ããçºè²éšåã®å²åã¯éåžžïŒã80ééïŒ ãæãŸ
ããããè²åçŸãçºè²æ§åã³å®å®æ§ã®ç¹ã§ã¯20ã
70ééïŒ ã奜ãŸãããäžè¬åŒããã«å¯Ÿå¿ããé
çºè²éšåã®å²åã¯éåžžïŒã30ééïŒ ãæãŸããã
è²åçŸæ§ãçºè²æ§åã³å ç¢æ§ã®ç¹ã§ã¯ïŒã20éé
ïŒ ã奜ãŸããã ãŸããã¡ãã«ã¢ã¯ãªã¬ãŒãã¯éåžž20ã95ééïŒ
ãæãŸããããè²åçŸæ§ãçºè²æ§åã³å ç¢æ§ã®ç¹
ã§ã¯30ã70ééïŒ ã奜ãŸããããã®å Žåã®åœåå
éïŒïŒã¢ã«ã®åéäœã«ãã©ãŒãå«ãããªããŒã®ã°
ã©ã æ°ïŒã¯çŽ250ã4000ã§ãããããã«éå®ãã
ãã®ã§ã¯ãªãã æ¬çºæã«åŸãéåããã·ã¢ã³ããªããŒã«ãã©ãŒ
ã®ã©ããã¯ã¹ãäœãã®ã«é©ããåéäœã«ãã©ãŒã®
äŸã¯åçš®æç®äŸãã°ç±³åœç¹èš±2976294ãå
3767412ãå4080211ãå4128427ãResearch
Disclosure21728ïŒ1982幎ïŒã«ã¿ãããã 代衚äŸã¯äžèšã®åŠããã®ã§ãããããã«éå®ã
ããã®ã§ã¯ãªãã 次ã«æ¬çºæã«åŸãã·ã¢ã³ããªããŒã«ãã©ãŒã®ã©
ããã¯ã¹ãäœãã®ã«é©ããäžè¬åŒããã«å¯Ÿå¿ã
ãé žæåãå«æãããšãã¬ã³æ§äžé£œååéäœãšã
ãŠã¯äžèšã®åŠããã®ãããããããã«éå®ããã
ãã®ã§ã¯ãªãã
ãããªã³ã°ãããæ°èŠãªã·ã¢ã³è²å圢æããªããŒ
ã«ãã©ãŒã®ã©ããã¯ã¹ãå«æããããã²ã³åéã«
ã©ãŒåçæå ææã«é¢ãããã®ã§ããã ããã²ã³åéåçæå ææã«é²å ãäžããããš
çºè²çŸåããããšã«ããé žåãããè³éŠæäžçŽã¢
ãã³çŸåè¬ãšè²çŽ 圢æã«ãã©ãŒãšãåå¿ããè²ç»
åãåŸãããããšã¯ããç¥ãããŠããã ããã²ã³åéã«ã©ãŒåçææãçºè²çŸåããã
ãšã«ããé žåãããè³éŠæäžçŽã¢ãã³çŸåè¬ãšã«
ãã©ãŒãšãåå¿ããŠã€ã³ãããšããŒã«ãã€ã³ãã¢
ããªã³ãã€ã³ããã³ãã¢ãŸã¡ãã³ãããšãããµãž
ã³ãããšããžã³åã³ããã«é¡ããè²çŽ ãã§ããè²
ç»åã圢æãããããšã¯ç¥ãããŠããããã®æ¹åŒ
ã«ãããŠã¯éåžžè²åçŸã«ã¯æžè²æ³ã䜿ãããéã
ç·ãããã³èµ€ã«éžæçã«æå ããããã²ã³åéä¹³
å€ãšããããäœè²é¢ä¿ã«ããã€ãšããŒãããŒã³
ã¿ãããã³ã·ã¢ã³ã®è²ç»å圢æå€ãšã䜿çšãã
ãã ã€ãšããŒè²ç»åã圢æããããã«ã¯äŸãã°ã¢ã·
ã«ã¢ã»ãã¢ããªããåã¯ãã³ãŸã€ã«ã¡ã¿ã³ç³»ã«ã
ã©ãŒã䜿ãããããŒã³ã¿è²ç»åã圢æããããã«
ã¯äž»ãšããŠãã©ãŸãã³ããã©ãŸããã³ãã€ãããŸ
ãŒã«ãã·ã¢ãã¢ã»ãããšãã³ãŸãã¯ã€ã³ããŸãã³
ç³»ã«ãã©ãŒã䜿ãããã·ã¢ã³è²ç»åã圢æããã
ãã«ã¯äž»ãšããŠããšããŒã«ç³»ã«ãã©ãŒãäŸãã°ã
ãšããŒã«é¡åã³ããããŒã«é¡ã䜿ãããã ã«ã©ãŒã«ãã©ãŒã¯åçš®ã®èŠä»¶ã«åèŽãããã®ã§
ãªããã°ãªãããäŸãã°è¯å¥œãªåå ç¹æ§ãæãã
çºè²çŸåã«ããå ã枩床ãããã³æ¹¿åºŠã«å¯Ÿãé·æ
éã«ãããé«åºŠã®å®å®æ§ã瀺ãæŽæåãäžããã
ãšãå¿ èŠã§ããã ãšããã§ãå€å±€ã«ã©ãŒæå ææã§ã¯ãæ··è²ãå°
ãããè²åçŸãããããããã«ããããã®ã«ãã©
ãŒãåé¢ããå±€ãåºå®ããããšãå¿ èŠã§ãããã
ã®ã«ãã©ãŒã®èæ¡æ£åã®æ¹æ³ã«ã¯å€ããç¥ãããŠ
ããã ãã®ïŒã€ã®æ¹æ³ã¯ã«ãã©ãŒã®ååäžã«ãæ¡æ£ã
é²ãããé·éã®èèªæåºãå°å ¥ãããã®ã§ããã
ãã®æ¹æ³ã«ããã«ãã©ãŒã¯ãŒã©ãã³æ°Žæº¶æ¶²ãšæ··å
ããªãããã¢ã«ã«ãªã«å¯æº¶åãããŠãŒã©ãã³æ°Žæº¶
液ã«æ·»å ãããããããã¯é«æ²žç¹ã®ææ©æº¶å€ã«ãš
ãããŠãŒã©ãã³æ°Žæº¶æ¶²äžã«ä¹³ååæ£ããããšãå¿
èŠã§ããã ãã®ãããªã«ã©ãŒã«ãã©ãŒã¯ä¹³å€äžã§çµæ¶ã®æ
åºãåŒãèµ·ãããããããã¯é«æ²žç¹ã®ææ©æº¶å€ã
çšããå Žåã«ã¯ä¹³å€å±€ãè»åãããããå€éã®ãŒ
ã©ãã³ãå¿ èŠãšãããã®çµæä¹³å€å±€ãèãããã
ãšããèŠæã«éã®çµæãããããã ã«ãã©ãŒãèæ¡æ£åããå¥ã®æ¹æ³ã¯åéäœã«ã
ã©ãŒã®éåã§åŸãããããªããŒã«ãã©ãŒãã©ãã
ã¯ã¹ã®åœ¢ã§å©çšããæ¹æ³ã§ããã ããªããŒã«ãã©ãŒãã©ããã¯ã¹ã®åœ¢ã§èŠªæ°Žæ§ã³
ãã€ãçµæç©ã«å ããæ¹æ³ãšããŠã¯ãåŸæ¥ãä¹³å
éåæ³ã§äœãããã©ããã¯ã¹ãçŽæ¥ãŒã©ãã³ãã
ã²ã³åéä¹³å€ã«å ããæ¹æ³ãšåéäœã«ãã©ãŒã®é
åã§åŸããã芪油æ§ããªããŒã«ãã©ãŒããŒã©ãã³
氎溶液äžã«ã©ããã¯ã¹ã®åœ¢ã§åæ£ããæ¹æ³ãç¥ã
ããŠãããåè ã®ä¹³åéåæ³ã®äŸã¯æ°Žæ§ãŒã©ãã³
äžã§ã®ä¹³åéåæ³ãç±³åœç¹èš±3370952å·ã«ãæ°Žäž
ã§ã®ä¹³åéåæ³ãç±³åœç¹èš±4080211å·ã«èšèŒãã
ãŠãããåŸè ã®èŠªæ²¹æ§ããªããŒã«ãã©ãŒã©ããã¯
ã¹ã®åœ¢ã§åæ£ããæ¹æ³ã®äŸã¯ç±³åœç¹èš±3451820å·
ã«èšèŒãããŠããã ããªããŒã«ãã©ãŒãã©ããã¯ã¹ã®åœ¢ã§èŠªæ²¹æ§ã³
ãã€ãçµæç©ã«å ããæ¹æ³ã«ã¯ä»ã®æ¹æ³ã«æ¯ã¹ãŠ
å€ãã®å©ç¹ããã€ã ãŸããçæ°Žæ§çŽ æãã©ããã¯ã¹åãããŠããã
ã圢æãããèã®åŒ·åºŠãå£åãããããšããªãã
ãŸããã©ããã¯ã¹ã¯é«æ¿åºŠã®åéäœã«ãã©ãŒãå«
ãããšãåºæ¥ãã®ã§ã容æã«é«æ¿åºŠã®ã«ãã©ãŒã
ä¹³å€ã«å«æãããããšãã§ãããããç²åºŠã®å¢å€§
ãå°ãªãããèãèãã§ãã·ã€ãŒããã¹ãæ¹è¯ã§
ããç¹ã§ãããããã«ãå šãé移è¡æ§ã®ããæ··è²
ããªãä¹³å€èäžã®äžã§ã«ãã©ãŒãæåºããããšã
å°ãªãããšã§ããã ãã®ããã«ããªããŒã«ãã©ãŒãã©ããã¯ã¹ã®åœ¢
ã§ãŒã©ãã³ããã²ã³åéä¹³å€ã«å ãããã®ãšããŠ
ã¯ãäŸãã°ç±³åœç¹èš±4080211å·ãç±³åœç¹èš±1247688
å·ãç±³åœç¹èš±3451820å·ã«ã¯ãã®è£œé æ¹æ³ãšïŒåœ
éããŒã³ã¿ããªããŒã«ãã©ãŒã©ããã¯ã¹ãã西ç¬
ç¹èš±272591å·åã³ç±³åœç¹èš±3926436å·ã«ã¯ç«¶äºã«
ãã©ãŒãšã®å ±éåã©ããã¯ã¹ãç±³åœç¹èš±ç¬¬
3767412å·ãResearch Disclosure21728ïŒ1982幎ïŒ
ã«ã¯ã·ã¢ã³ããªããŒã«ãã©ãŒã©ããã¯ã¹ãç¥ãã
ãŠããã ããããªããã·ã¢ã³ããªããŒã«ãã©ãŒã®ã©ãã
ã¯ã¹ã«ã¯åèšãããããªå€ãã®åªããç¹åŸŽãæã
ãªãã次ã®ãããªæ¹è¯ãã¹ãåé¡ããããç¹ã«ç±
å ç¢æ§ã«ã€ããŠã¯åŒ·ãæ¹è¯ãæãŸããŠããã ïŒ çŸååŠçåŸã®ã«ã©ãŒåçã«ãããŠã·ã¢ã³è²å
ã®ç±åã³æ¹¿ç±ã«å¯Ÿããå ç¢æ§ãäœãã ïŒ ã«ãããªã³ã°ã®åå¿é床ãå£ãããçæãã
è²çŽ ã®æ床ãé調ãããã³è²çŽ æ¿åºŠãäœãã ãããã€ãŠæ¬çºæã®ç®çã¯ç¬¬ïŒã«çŸååŠçåŸã®
ã«ã©ãŒåçã«ãããŠç±ããã³æ¹¿ç±ã«å¯ŸããŠå ç¢ãª
è²ç»åã圢æããæ°èŠãªã·ã¢ã³è²å圢æããªããŒ
ã«ãã©ãŒã®ã©ããã¯ã¹ãæäŸããããšã§ããã æ¬çºæã®ç®çã¯ç¬¬ïŒã«çºè²æ§ã®èããç§ããæ°
èŠãªã·ã¢ã³è²å圢æããªããŒã«ãã©ãŒã©ããã¯ã¹
ãæäŸããããšã§ããã æ¬çºæã®ç®çã¯ç¬¬ïŒã«æ°èŠãªã·ã¢ã³è²å圢æã
ãªããŒã«ãã©ãŒã©ããã¯ã¹ã®ååšã®ããšã«ããã²
ã³åéä¹³å€ãçŸåããããšã«ãã€ãŠã·ã¢ã³è²ç»å
ã圢æããæ¹æ³ãæäŸããããšã§ããã æ¬çºæã®ç®çã¯ç¬¬ïŒã«æ°èŠãªã·ã¢ã³è²å圢æã
ãªããŒã«ãã©ãŒã®ã©ããã¯ã¹ãå«æããããã²ã³
åéã«ã©ãŒåçæå ææãåçåŠçæ¹æ³ãããã¯
ç»å圢ææ¹æ³ãæäŸããããšã«ããã æ¬çºæè çã¯çš®ã ã®ç 究ãéããçµææ¬çºæã®
ãããã®ç®çã¯è³éŠæäžçŽã¢ãã³çŸåè¬ã®é žåäœ
ãšã«ãããªã³ã°ããŠææã圢æãããäžèšäžè¬åŒ
ããã«å¯Ÿå¿ããã·ã¢ã³ã«ãã©ãŒåéäœã®å埩å
äœãäžè¬åŒããã«å¯Ÿå¿ããé žæåãå«æãããš
ãã¬ã³æ§äžé£œååéäœã®å埩åäœããã³ã¡ãã«ã¢
ã¯ãªã¬ãŒãã®å埩åäœã®å°ãªããšãïŒã€ãå埩å
äœãšããŠæããã·ã¢ã³è²çŽ 圢æããªããŒã«ãã©ãŒ
ã®ã©ããã¯ã¹ãä¹³å€å±€äžã«å«æããããã²ã³åé
åçæå ææã«ããéæãããã ïŒåŒäžR1ã¯æ°ŽçŽ ååãççŽ ïŒãïŒåã®äœçŽã¢
ã«ãã«åºãŸãã¯å¡©çŽ ãè¡šãããã¯é žåãããè³
éŠæäžçŽã¢ãã³çŸåè¬ãšã«ãããªã³ã°ããŠã·ã¢ã³
ææã圢æãããã·ã¢ã³ã«ãã©ãŒæ®åºãè¡šãããïŒ ïŒåŒäžR2ã¯æ°ŽçŽ ååãççŽ æ°ïŒãïŒåã®äœçŽ
ã¢ã«ãã«åºãŸãã¯å¡©çŽ ãè¡šãããã¯âCOOãŸ
ãã¯âCONHâãè¡šãããã¯ççŽ æ°ïŒã10å
ã®ã¢ã«ãã¬ã³åºãããã¯ã¢ã©ã«ãã¬ã³åºãŸãã¯ç
çŽ æ°ïŒã10ã®ããšãã¬ã³åºãè¡šãããã¢ã«ãã¬ã³
åºã¯çŽéã§ããåå²éã§ãç°ç¶ã§ããããã¯â
COOMãŸãã¯âSO3Mãè¡šããããã ãïŒã¯æ°ŽçŽ
ã€ãªã³ãã¢ã«ã«ãªéå±ã€ãªã³ãã¢ã«ã«ãªåé¡éå±
ã€ãªã³ãŸãã¯ã¢ã³ã¢ããŠã ã€ãªã³ãè¡šãããïœã¯
ïŒãŸãã¯ïŒãè¡šããã ãã詳ããã¯æ¬çºæã®ã·ã¢ã³è²å圢æããªããŒ
ã«ãã©ãŒã©ããã¯ã¹ã«ãããŠé žåãããè³éŠæäž
çŽã¢ãã³çŸåè¬ãšã«ãããªã³ã°ããŠã·ã¢ã³è²åã
圢æããã·ã¢ã³ã«ãã©ãŒæ®åºããšããŠã¯ããšã
ãŒã«åãããããã¯ãããããã¯ããããŒã«
åããã奜ãŸããã åŒäžR3ã¯æ°ŽçŽ ååãŸãã¯ççŽ æ°ïŒãïŒåã®äœ
çŽã¢ã«ãã«åºãè¡šãããã¯äžè¬åŒããã®NH
åºã«çµåããççŽ æ°ïŒã10åã®ç¡çœ®æãŸãã¯çœ®æ
ã¢ã«ãã¬ã³åºãã¢ã©ã«ãã¬ã³åºãããã¯ããšãã¬
ã³åºãè¡šãããã¢ã«ãã¬ã³åºã¯çŽéã§ãåå²ããŠ
ããããïŒã¢ã«ãã¬ã³åºãšããŠã¯äŸãã°ã¡ãã¬ã³ã
ã¡ãã«ã¡ãã¬ã³ããžã¡ãã«ã¡ãã¬ã³ããžã¡ãã¬
ã³ãããªã¡ãã¬ã³ãããã©ã¡ãã¬ã³ããã³ã¿ã¡ã
ã¬ã³ããããµã¡ãã¬ã³ããã·ã«ã¡ãã«ãã¢ã©ã«ã
ã¬ã³åºãšããŠã¯äŸãã°ãã³ãžãªãã³ãããšãã¬ã³
åºãšããŠã¯äŸãã°ïœâããšãã¬ã³ãïœâããšãã¬
ã³ãã¡ãã«ããšãã¬ã³åºãªã©ããããïŒ R4ã¯æ°ŽçŽ ååããŸãã¯ççŽ æ°ïŒãïŒåã®äœçŽ
ã¢ã«ãã«åºïŒäŸãã°ã¡ãã«åºããšãã«åºãŸãã¯ïœ
âããã«åºãªã©ïŒã§ãR5ã¯ç¡çœ®æãŸãã¯çœ®æã¢
ã«ãã«åºãããšãã«åºãŸãã¯ããšãã«ã¢ããåºã
è¡šããã ã¯ããã²ã³ååïŒããçŽ ååãå¡©çŽ ååãè
çŽ ååïŒãã¯æ°ŽçŽ ååãããã²ã³ååïŒäŸãã°
ããçŽ ååãå¡©çŽ ååãèçŽ ååïŒãŸãã¯çœ®æã¢
ã«ã³ãã·åºãè¡šããã ïœïŒïœã¯åã ïŒãŸãã¯ïŒãè¡šããã ããã§ïŒ€ã§è¡šããããã¢ã«ãã¬ã³åºãã¢ã©ã«ã
ã¬ã³åºããŸãã¯ããšãã¬ã³åºã®çœ®æåºãšããŠã¯ã¢
ãªãŒã«åºïŒäŸãã°ããšãã«åºïŒããããåºãæ°Žé ž
åºãã·ã¢ãåºãã¹ã«ãåºãã¢ã«ã³ãã·åºïŒäŸãã°
ã¡ããã·åºïŒãã¢ãªãŒã«ãªãã·åºïŒäŸãã°ããšã
ãã·åºïŒãã¢ã·ã«ãªãã·åºïŒäŸãã°ã¢ã»ããã·
åºïŒãã¢ã·ã«ã¢ããåºïŒäŸãã°ã¢ã»ãã«ã¢ãã
åºïŒãã¹ã«ãã³ã¢ããåºïŒäŸãã°ã¡ã¿ã³ã¹ã«ãã³
ã¢ããåºïŒãã¹ã«ãã¢ã¢ã€ã«åºïŒäŸãã°ã¡ãã«ã¹
ã«ãã¢ã¢ã€ã«åºïŒãããã²ã³ååïŒäŸãã°ããçŽ ã
å¡©çŽ ãèçŽ ãªã©ïŒãã«ã«ããã·åºãã«ã«ãã¢ã€ã«
åºïŒäŸãã°ã¡ãã«ã«ã«ãã¢ã€ã«åºïŒãã¢ã«ã³ãã·
ã«ã«ããã«åºïŒäŸãã°ã¡ããã·ã«ã«ããã«åºãª
ã©ïŒãã¹ã«ããã«åºïŒäŸãã°ã¡ãã«ã¹ã«ããã«åºïŒ
ãæããããããã®çœ®æåºãïŒã€ä»¥äžãããšãã¯
åãã§ãç°ã€ãŠãããã ãŸãã§è¡šãããã眮æã¢ã«ã³ãã·åºã®çœ®æåº
ãšããŠã¯ã¢ãªãŒã«åºïŒäŸãã°ããšãã«åºïŒããã
ãåºãæ°Žé žåºãã·ã¢ãåºãã¹ã«ãåºãã¢ã«ã³ãã·
åºïŒäŸãã°ã¡ããã·åºïŒãã¢ãªãŒã«ãªãã·åºïŒäŸ
ãã°ããšããã·åºïŒãã¢ã·ã«ãªãã·åºïŒäŸãã°ã¢
ã»ããã·åºïŒãã¢ã·ã«ã¢ããåºïŒäŸãã°ã¢ã»ãã«
ã¢ããåºïŒãã¢ã«ãã«ã¹ã«ãã³ã¢ããåºïŒäŸãã°
ã¡ã¿ã³ã¹ã«ãã³ã¢ããåºïŒãã¢ã«ãã«ã¹ã«ãã¢ã¢
ã€ã«åºïŒäŸãã°ã¡ãã«ã¹ã«ãã¢ã¢ã€ã«åºïŒããã
ã²ã³ååïŒäŸãã°ããçŽ ãå¡©çŽ ãèçŽ ãªã©ïŒãã«
ã«ããã·åºãã¢ã«ãã«åºã«ã«ãã¢ã€ã«åºïŒäŸãã°
ã¡ãã«ã«ã«ãã¢ã€ã«åºïŒãã¢ã«ã³ãã·ã«ã«ããã«
åºïŒäŸãã°ã¡ããã·ã«ã«ããã«åºãªã©ïŒãã¢ã«ã
ã«åºã¹ã«ããã«åºïŒäŸãã°ã¡ãã«ã¹ã«ããã«åºãª
ã©ïŒãã¢ã«ãã«ããªåºïŒäŸãã°Î²âã«ã«ããã·ãš
ãã«ããªåºãªã©ïŒãªã©ãæããããããã®çœ®æåº
ãïŒã€ä»¥äžãããšãã¯åãã§ãç°ã€ãŠãããã ããã«R5ã§è¡šããããã¢ã«ãã«åºãããšãã«
åºã®çœ®æåºãšããŠã¯ããçŽ ååã奜ãŸãããããš
ãã«ã¢ããåºã®çœ®æåºãšããŠã¯ãããåºãã·ã¢ã
åºãã¹ã«ãã³ã¢ããåºïŒäŸãã°ã¡ã¿ã³ã¹ã«ãã³ã¢
ããåºïŒããã«ãã¢ã¢ã€ã«åºïŒäŸãã°ã¡ãã«ã¹ã«
ãã¢ã¢ã€ã«åºïŒãããã²ã³ååïŒäŸãã°ããçŽ ã
å¡©çŽ ãèçŽ ïŒãã«ã«ãã¢ã€ã«åºïŒäŸãã°ã¡ãã«ã«
ã«ãã¢ã€ã«åºïŒãã¹ã«ããã«åºïŒäŸãã°ã¡ãã«ã¹
ã«ããã«åºïŒãæããããããããã®çœ®æåºãïŒ
ã€ä»¥äžãããšãã¯åãã§ãç°ãªã€ãŠãããã äžè¬åŒããã«å¯Ÿå¿ããè³éŠæäžçŽã¢ãã³çŸå
è¬ãšé žåã«ãããªã³ã°ããèœåãæããªãé žæå
ãå«æãããšãã¬ã³æ§äžé£œååéäœãšããŠã¯ã¢ã¯
ãªã«é žãαâã¯ããã¢ã¯ãªã«é žãαâã¢ã«ã¢ã¯ãª
ã«é žïŒäŸãã°ã¡ã¿ã¯ãªã«é žïŒçããã³ããããã
èªå°ãããé žæåãå«æãããšã¹ãã«ãããã¯ã¢
ããã§ãããåèšäžè¬åŒããã®ïŒ¢ã¯ã¢ã«ãã¬ã³
åºãã¢ã©ã«ãã¬ã³åºããŸãã¯ããšãã¬ã³åºãè¡šã
ããã¢ã«ãã¬ã³åºãµçŽéã§ããåå²éã§ããç°ç¶
ã§ããããã¢ã«ãã¬ã³åºãšããŠã¯äŸãã°ã¡ãã¬
ã³ãã¡ãã«ã¡ãã¬ã³ããšãã¬ã³ãã¡ãã«ãšãã¬
ã³ããžã¡ãã«ãšãã¬ã³ãããªã¡ãã¬ã³ãããã©ã¡
ãã¬ã³ããã³ã¿ã¡ãã¬ã³ããããµã¡ãã¬ã³ããã
ã³ãã·ã«ã¡ãã¬ã³ãã¢ã©ã«ãã¬ã³åºãšããŠã¯äŸã
ã°ãã³ãžãªãã³ãããšãã¬ã³åºãšããŠã¯äŸãã°ïœ
âããšãã¬ã³ããã³ïœâããšãã¬ã³ãªã©ãããã äžè¬åŒãããäžè¬åŒããã§è¡šããããå埩
åäœã¯ïŒçš®é¡ä»¥äžå«ãã§ãããã æ¬çºæã«çšããããã·ã¢ã³ããªããŒã«ãã©ãŒã©
ããã¯ã¹ã¯åèšããããã«åéäœã«ãã©ãŒã®éå
ã§åŸããã芪油æ§ããªããŒã«ãã©ãŒãææ©æº¶åªã«
溶ããããã®ããŒã©ãã³æ°Žæº¶æ¶²äžã«ã©ããã¯ã¹ã®
圢ã§ä¹³ååæ£ããŠäœã€ãŠãããããããã¯çŽæ¥ä¹³
åéåæ³ã§äœã€ãŠãããã 芪油æ§ããªããŒã«ãã©ãŒããŒã©ãã³æ°Žæº¶æ¶²äžã«
ã©ããã¯ã¹ã®åœ¢ã§ä¹³ååæ£ããæ¹æ³ã«ã€ããŠã¯ç±³
åœç¹èš±3451820å·ã«ãä¹³åéåã«ã€ããŠã¯ç±³åœç¹
蚱第4080211å·ãå3370952å·ã«èšèŒãããŠããæ¹
æ³ãçšããããšãåºæ¥ãã 次ã«ã·ã¢ã³ããªããŒã«ãã©ãŒã®äžè¬çéåæ³ã«
ã€ããŠè¿°ã¹ãã ãšãã¬ã³ç³»äžé£œååºäœåéäœã®ããªãŒã©ãžã«ã«
éåã¯ååŠçéå§å€ã®ç±å解ãŸãã¯é žåæ§ååç©
ã«ãããéå å€ã®äœçšïŒã¬ããã¯ã¹éå§å€ïŒãŸã
ã¯ç©ççäœçšäŸãã°çŽ«å€ç·ãŸãã¯ä»ã®é«ãšãã«ã®
ãŒèŒ»å°ãé«åšæ³¢çã«ãã圢æãããããªãŒã©ãžã«
ã«ã®åéäœååã«ä»å ããããšã«ãã€ãŠéå§ãã
ãã äž»ãªååŠçéå§å€ãšããŠã¯ããŒãµã«ããšãŒã
ïŒäŸãã°ã¢ã³ã¢ããŠã ããŒãµã«ããšãŒããããã³
ã«ãªãŠã ããŒãµã«ããšãŒããªã©ïŒã¢ãŸãã¹ç³»éå
éå§å€ïŒäŸãã°ïŒïŒ2â²âã¢ãŸãã¹ã€ãœé ·é žãžã¡ã
ã«ãïŒïŒ2â²âã¢ãŸãã¹ã€ãœé ·é žãžãšãã«ãïŒïŒ
2â²âã¢ãŸãã¹ã€ãœããããããªã«ãïŒïŒ2â²âã¢ãŸ
ãã¹âïŒïŒïŒïŒâãžã¡ãã«ãã¬ããããªã«ïŒãã
ã³ïŒïŒ4â²âã¢ãŸãã¹âïŒïŒâã·ã¢ããã¬ãªã¢ã³é žïŒ
ãªã©ïŒãããŒãªããµã€ãç³»éåéå§å€ïŒäŸãã°ã
ã³ãŸã€ã«ããŒãªããµã€ããã¯ãããã³ãŒã³ããŒãª
ããµã€ããããã³éé žåæ°ŽçŽ ãªã©ïŒãããã æ®éã®ã¬ããã¯ã¹éå§å€ã«ã¯éé žåæ°ŽçŽ âé
ïŒïŒå¡©ãéç¡«é žã«ãªâéç¡«é žã«ãªãŠã ãã»ãªãŠ
ã å¡©ã¢ã«ã³ãŒã«çãããã éå§å€ã®äŸããã³ãã®äœçšã¯F.A.Boveyè
ãFmulsion polymerizationãInterscience
Publishes Inc.New Yorkçºè¡1955幎第59â第93
é ã«èšèŒãããŠããã 芪油æ§ããªããŒã«ãã©ãŒã®éåã«çšãããã溶
åªãšããŠã¯éåžžåéäœãšç¡éã«æ··åãããšåæã«
çæãã芪油æ§ããªããŒã«ãã©ãŒã®è¯æº¶åªã§ãã
ãããéå§å€ãšãåå¿ããããªãŒã©ãžã«ã«ä»å é
åã®éåžžã®äœçšã劚害ããªããã®ãæãŸãããå ·
äœçã«ã¯äŸãã°ãè³éŠæçåæ°ŽçŽ ïŒäŸãã°ãã³ãŒ
ã³ããã«ãšã³ãªã©ïŒãçåæ°ŽçŽ ïŒäŸãã°ïœâãã
ãµã³ãªã©ïŒãã¢ã«ã³ãŒã«ïŒäŸãã°ã¡ã¿ããŒã«ããš
ã¿ããŒã«ãïœâãããããŒã«ãã€ãœãããããŒ
ã«ãtertâãã¿ããŒã«ãªã©ïŒãã±ãã³ïŒäŸãã°ã¢
ã»ãã³ãã¡ãã«ãšãã«ã±ãã³ãªã©ïŒãç°ç¶ãšãŒã
ã«ïŒäŸãã°ããã©ããããã©ã³ããžãªããµã³ãª
ã©ïŒããšã¹ãã«ïŒäŸãã°é ¢é žãšãã«ãªã©ïŒãå¡©çŽ å
çåæ°ŽçŽ ïŒäŸãã°å¡©åã¡ãã¬ã³ãã¯ãããã«ã ãª
ã©ïŒãã¢ããïŒäŸãã°ãžã¡ãã«ãã«ã ã¢ããããž
ã¡ãã«ã¢ã»ãã¢ãããªã©ïŒãã¹ã«ããã·ãïŒäŸã
ã°ãžã¡ãã«ã¹ã«ããã·ããªã©ïŒããããªã«ïŒäŸã
ã°ã¢ã»ããããªã«ãªã©ïŒãããã³ãã®çµåããçš
ããããšãåºæ¥ãã äžæ¹åºäœæ°Žäžæº¶æ§åéäœã«ãã©ãŒã®ä¹³åéåã¯
éåžžæ°Žç³»ãããã¯æ°ŽïŒææ©æº¶åªç³»ã§è¡ãããã®é
䜿çšããææ©æº¶åªãšããŠã¯äžèšææ©æº¶åªãšåãã
ãã«(1)åºäœæ°Žäžæº¶æ§åéäœã«ãã©ãŒã«å¯Ÿããå®è³ª
çã«äžæŽ»æ§ã§ããã(2)ããªãŒã©ãžã«ã«ä»å éåã®
éåžžã®äœçšã劚害ããªããã®ã§ããã(3)éåäžã
ãã³ïŒãŸãã¯ïŒéååŸèžçã«ãã€ãŠæ°Žæ§åå¿åªäœ
ãã容æã«é€å»ãããäœæ²žç¹ã§ãããã®ã奜ãŸã
ãã奜ãŸããäŸããããã°ççŽ æ°ïŒãïŒåã®äœçŽ
ã¢ã«ã³ãŒã«ïŒäŸãã°ã¡ã¿ããŒã«ããšã¿ããŒã«ãã
ãã³ã€ãœãããããŒã«ïŒãã±ãã³ïŒäŸãã°ã¢ã»ã
ã³ïŒãå¡©çŽ åçåæ°ŽçŽ ïŒäŸãã°ã¯ãããã«ã ïŒãè³
éŠæçåæ°ŽçŽ ïŒäŸãã°ãã³ãŒã³ïŒãç°ç¶ãšãŒãã«
ïŒäŸãã°ããã©ããããã©ã³ïŒããšã¹ãã«ïŒäŸäŸã
ã°ãšãã«ã¢ã»ããŒãïŒããããªã«ïŒäŸãã°ã¢ã»ã
ãããªã«ïŒçãããã ãŸãä¹³åéåã®ããçšããããä¹³åå€ãšããŠã¯
çé¢æŽ»æ§ãæã€ååç©ãçšãããã奜ãŸããã¯ç³
ãããã¹ã«ãããŒãããã³ãµã«ããšãŒããã«ããª
ã³ååç©ãäž¡æ§ååç©ããã³é«ååä¿è·ã³ãã€ã
ãæããããããããã®çŸ€ã®äŸããã³ãããã®äœ
çšã¯Belgische Chemische Industrieã第28å·»ã
第16ã第20é ïŒ1963幎ïŒã«èšèŒãããŠããã éå枩床ã¯çæããããªããŒã®ååéãéå§å€
ã®çš®é¡ãªã©ãšé¢é£ããŠèšå®ããå¿ èŠãããïŒâ以
äžãã100â以äžãŸã§å¯èœã§ããããéåžžã¯30â
ã100âã®ç¯å²ã§éåããã 次ã«ã芪油æ§ããªããŒã«ãã©ãŒããŒã©ãã³æ°Žæº¶
液äžã«ã©ããã¯ã¹ã®åœ¢ã§åæ£ããéã芪油æ§ããª
ããŒã«ãã©ãŒã溶解ããããã«çšããææ©æº¶åªã¯
åæ£æ¶²ãå¡åžããåããããã¯ïŒããŸã奜ãŸãã
ãªããïŒå¡åžããåæ£æ¶²ã®ä¹Ÿç¥äžã®æ°åã®éã«é€
ãããã溶åªãé€å»ããæ¹æ³ãšããŠã¯ããšãã°ãŒ
ã©ãã³ããŒãã«åã§æ°ŽæŽããããšã«ããé€å»ãã
ãããã«ããçšåºŠæ°Žæº¶æ§ã®ãã®ãããã³åŽé§ä¹Ÿ
ç¥ãç空ãŸãã¯æ°Žèžæ°ããŒãžã³ã°æ³ã«ãã€ãŠé€ã
ãããã®ãããã åããã®é€å»ãããææ©æº¶åªãšããŠã¯ãšã¹ãã«
äŸãã°äœçŽã¢ã«ãã«ãšã¹ãã«ãäœçŽã¢ã«ãã«ãšãŒ
ãã«ãã±ãã³ãããã²ã³åçåæ°ŽçŽ ããšãã°å¡©å
ã¡ãã¬ã³ãŸãã¯ããªã¯ãããšãã¬ã³ãããçŽ åç
åæ°ŽçŽ ãã¢ã«ã³ãŒã«äŸãã°ïœâããã«ã¢ã«ã³ãŒ
ã«ãïœâãªã¯ãã«ã¢ã«ã³ãŒã«ãããã³ãããã®çµ
åããå å«ããã 芪油æ§ããªããŒã«ãã©ãŒãåæ£ããåæ£å€ãšã
ãŠã¯ãã©ã®ãããªåœ¢åŒã®ãã®ãçšããŠããããã€
ãªã³æ§çé¢æŽ»æ§å€ç¹ã«ãã¢ããªã³æ§åã®ãã®ã奜
é©ã§ããã âã»ãã«ãã¿ã€ã³ãâã¢ã«ãã«ã¢ãããã
ããªã³é žå¡©ãâã¢ã«ãã«ã€ãããžããããªã³é ž
å¡©ã®ãããªäž¡æ§åã®ãã®ãçšããããšãã§ããã ãŸããããªããŒã«ãã©ãŒãšè³éŠæäžçŽã¢ãã³çŸ
åè¬ã®é žåäœãã圢æãããææã®è²åãã調ç¯
ããå¡åžããä¹³å€ã®ããã¿æ§ãæ¹åããããã«ã
æ°žä¹ ç溶åªãããªãã¡é«æ²žç¹ïŒ200â以äžïŒã®æ°Ž
äžæ··åæ§ææ©æº¶åªãå ããŠãããã ãŸããæçµã®ä¹³å€ç®èã®åããã§ããã ãèã
ãé«ãé®®æ床ãç¶æããããã«ãã®æ°žä¹ ç溶åªã®
æ¿åºŠã¯äœãããããšãæãŸããã ããªããŒã«ãã©ãŒäžã«å ããäžè¬åŒããã«å¯Ÿ
å¿ããçºè²éšåã®å²åã¯éåžžïŒã80ééïŒ ãæãŸ
ããããè²åçŸãçºè²æ§åã³å®å®æ§ã®ç¹ã§ã¯20ã
70ééïŒ ã奜ãŸãããäžè¬åŒããã«å¯Ÿå¿ããé
çºè²éšåã®å²åã¯éåžžïŒã30ééïŒ ãæãŸããã
è²åçŸæ§ãçºè²æ§åã³å ç¢æ§ã®ç¹ã§ã¯ïŒã20éé
ïŒ ã奜ãŸããã ãŸããã¡ãã«ã¢ã¯ãªã¬ãŒãã¯éåžž20ã95ééïŒ
ãæãŸããããè²åçŸæ§ãçºè²æ§åã³å ç¢æ§ã®ç¹
ã§ã¯30ã70ééïŒ ã奜ãŸããããã®å Žåã®åœåå
éïŒïŒã¢ã«ã®åéäœã«ãã©ãŒãå«ãããªããŒã®ã°
ã©ã æ°ïŒã¯çŽ250ã4000ã§ãããããã«éå®ãã
ãã®ã§ã¯ãªãã æ¬çºæã«åŸãéåããã·ã¢ã³ããªããŒã«ãã©ãŒ
ã®ã©ããã¯ã¹ãäœãã®ã«é©ããåéäœã«ãã©ãŒã®
äŸã¯åçš®æç®äŸãã°ç±³åœç¹èš±2976294ãå
3767412ãå4080211ãå4128427ãResearch
Disclosure21728ïŒ1982幎ïŒã«ã¿ãããã 代衚äŸã¯äžèšã®åŠããã®ã§ãããããã«éå®ã
ããã®ã§ã¯ãªãã 次ã«æ¬çºæã«åŸãã·ã¢ã³ããªããŒã«ãã©ãŒã®ã©
ããã¯ã¹ãäœãã®ã«é©ããäžè¬åŒããã«å¯Ÿå¿ã
ãé žæåãå«æãããšãã¬ã³æ§äžé£œååéäœãšã
ãŠã¯äžèšã®åŠããã®ãããããããã«éå®ããã
ãã®ã§ã¯ãªãã
ãè¡šã
ãè¡šã
ãè¡šã
次ã«æ¬çºæã®ä»£è¡šçãªåæäŸã瀺ãã
è£œæ³ ïŒïŒ
補æ³äŸ (1)
ïŒâã¡ã¿ã¯ãªã«ã¢ããâïŒïŒïŒâãžã¯ããâïŒ
âã¡ãã«ããšããŒã«(1)ãšã¡ãã«ã¢ã¯ãªã¬ãŒããšã¡
ã¿ã¯ãªã«é žãšã®å ±éåããªããŒïŒèŠªæ²¹æ§ããªããŒ
(A)ïŒ åéäœã«ãã©ãŒ(1)20ïœãã¡ãã«ã¢ã¯ãªã¬ãŒã16
ïœãã¡ã¿ã¯ãªã«é žïŒïœããžãªããµã³200mlã®æ··å
ç©ãçªçŽ æ°æµäžæ¹æäž80âã«å ç±ããåŸãã¢ãŸã
ã¹ã€ãœé ·é žãžã¡ãã«600mgãå«ããžãªããµã³10ml
ãå ãéåãéå§ãããïŒæéåå¿ããåŸåå¿æ¶²
ãå·åŽããæ°Ž1.5ã«æ³šãæåºããåºäœãå¥ãã
ããã«ååæ°Žã§æŽæµããã ãã®åºäœãæžå§äžå ç±ä¹Ÿç¥ããäºã«ãã芪油æ§
ããªããŒ(A)ã37.2ïœåŸãã ãã®ããªããŒã«ãã©ãŒã¯å¡©çŽ åæãã圢æãã
ãå ±éåäœã50.3ïŒ ã®åéäœã«ãã©ãŒ(1)ãå«æã
ãŠããäºã瀺ããã 次ã«èŠªæ²¹æ§ããªããŒã«ãã©ãŒ(A)ããŒã©ãã³æ°Žæº¶
液äžã«ã©ããã¯ã¹ã®åœ¢ã§åæ£ããæ¹æ³ã«ã€ããŠèš
ãããŸã次ã®ããã«ããŠ(a)ãš(b)ã®ïŒçš®ã®æº¶æ¶²ã調
æŽããã (a) 骚ãŒã©ãã³ã®3.0ééïŒ æ°Žæº¶æ¶²ïŒ35âã«ãã
ãŠPH5.6ïŒ200ïœã38âã«å ç±ããã©ãŠãªã«ç¡«é ž
ãããªãŠã ã®10ééïŒ æ°Žæº¶æ¶²16mlãå ããã (b) äžèšèŠªæ²¹æ§ããªããŒã«ãã©ãŒ(A)20ïœã38âã«
ãããŠé ¢é žãšãã«200mlã«æº¶ããã 次ãã§ã溶液(b)ãé«éã§ãããŸãäžã®ççºé²æ¢
æ··åæ©ã«å ¥ãããã®äžãžæº¶æ¶²(a)ãæ¥éã«å ãïŒå
éãããŸããåŸãæ··åæ©ãåæ¢ããæžå§çå»ã«ã
ãé ¢é žãšãã«ãé€ããããã®ããã«ããŠèŠªæ²¹æ§ã
ãªããŒã«ãã©ãŒãåžãŒã©ãã³æº¶æ¶²äžã«åæ£ãã©ã
ãã¯ã¹ïŒAâ²ïŒãäœã€ãã 補æ³äŸ (2) ïŒâã¢ã¯ãªã«ã¢ããâïŒïŒïŒâãžã¯ããâïŒâ
ã¡ãã«ããšããŒã«(2)ãšã¡ãã«ã¢ã¯ãªã¬ãŒããšã¢ã¯
ãªã«é žãšã®å ±éåããªããŒïŒèŠªæ²¹æ§ããªããŒã«ã
ã©ãŒ(B)ïŒ åéäœã«ãã©ãŒ(2)20ïœãã¡ãã«ã¢ã¯ãªã¬ãŒã16
ïœãã¢ã¯ãªã«é žïŒïœããžãªããµã³200mlã®æ··åç©
ãçªçŽ æ°æµäžæ¹æäž80âã«å ç±ããåŸãã¢ãŸãã¹
ã€ãœé ·é žãžã¡ãã«600mgãå«ããžãªããµã³10mlã
å ãéåãéå§ãããïŒæéåå¿ããåŸåå¿æ¶²ã
å·åŽããæ°Ž1.5ã«æ³šãæåºããåºäœãå¥ãã
ããã«ååæ°Žã§æŽæµããã ãã®åºäœãæžå§äžå ç±ä¹Ÿç¥ããäºã«ãã芪油æ§
ããªããŒ(B)ã37.5ïœåŸãã ãã®ããªããŒã«ãã©ãŒã¯å¡©çŽ åæãã圢æãã
ãå ±éåäœã49.9ïŒ ã®åéäœã«ãã©ãŒ(2)ãå«æã
ãŠããäºã瀺ããã 次ã«èŠªæ²¹æ§ããªããŒã«ãã©ãŒ(B)ããŒã©ãã³æ°Žæº¶
液äžã«ã©ããã¯ã¹ã®åœ¢ã§åæ£ããæ¹æ³ã«ã€ããŠèš
ãããŸã次ã®ããã«ããŠ(a)ãš(b)ã®ïŒçš®ã®æº¶æ¶²ã調
æŽããã (a) 骚ãŒã©ãã³ã®3.0ééïŒ æ°Žæº¶æ¶²ïŒ35âã«ãã
ãŠPH5.6ïŒ200ïœã38âã«å ç±ããã©ãŠãªã«ç¡«é ž
ãããªãŠã ã®10ééïŒ æ°Žæº¶æ¶²16mlãå ããã (b) äžèšèŠªæ²¹æ§ããªããŒã«ãã©ãŒ(B)20ïœã38âã«
ãããŠé ¢é žãšãã«200mlã«æº¶ããã 次ãã§ã溶液(b)ãé«éã§ãããŸãäžã®ççºé²æ¢
æ··åæ©ã«å ¥ãããã®äžãžæº¶æ¶²(a)ãæ¥éã«å ãïŒå
éãããŸããåŸãæ··åæ©ãåæ¢ããæžå§çå»ã«ã
ãé ¢é žãšãã«ãé€ããããã®ããã«ããŠèŠªæ²¹æ§ã
ãªããŒã«ãã©ãŒãåžãŒã©ãã³æº¶æ¶²äžã«åæ£ãã©ã
ãã¯ã¹ïŒBâ²ïŒãäœã€ãã 補é äŸ (3) ïŒâïŒïŒâã¡ã¿ã¯ãªã«ã¢ãããããã³ã¢ããïŒâ
ïŒïŒïŒâãžã¯ããâïŒâã¡ãã«ããšããŒã«(9)ãšã¡
ãã«ã¢ã¿ãªã¬ãŒããšã¡ã¿ã¯ãªã«é žãšã®å ±éåããª
ããŒïŒèŠªæ²¹æ§ããªããŒã«ãã©ãŒ(C)ïŒ åéäœã«ãã©ãŒ(9)20ïœãã¡ãã«ã¢ã¯ãªã¬ãŒã18
ïœãã¡ã¿ã¯ãªã«é žïŒïœãå«ããžãªããµã³200mlã®
æ··åç©ãçªçŽ æ°æµäžæ¹æäž80âã«å ç±ããåŸãã¢
ãŸãã¹ã€ãœé ·é žãžã¡ãã«600mgãå«ããžãªããµã³
10mlãå ãéåãéå§ãããïŒæéåå¿ããåŸå
å¿æ¶²ãå·åŽããæ°Ž1.5ã«æ³šãæåºããåºäœã
å¥ããããã«ååæ°Žã§æŽæµããã ãã®åºäœãæžå§äžå ç±ä¹Ÿç¥ããäºã«ãã芪油æ§
ããªããŒ(C)ã38.2ïœåŸãã ãã®ããªããŒã«ãã©ãŒã¯å¡©çŽ åæãã圢æãã
ãå ±éåäœã50.5ïŒ ã®åéäœã«ãã©ãŒ(9)ãå«æã
ãŠããäºã瀺ããã 次ã«èŠªæ²¹æ§ããªããŒã«ãã©ãŒ(C)ããŒã©ãã³æ°Žæº¶
液äžã«ã©ããã¯ã¹ã®åœ¢ã§åæ£ããæ¹æ³ã«ã€ããŠèš
ãããŸã次ã®ããã«ããŠ(a)ãš(b)ã®ïœïŒçš®ã®æº¶æ¶²ã
調æŽããã (a) 骚ãŒã©ãã³ã®3.0ééïŒ æ°Žæº¶æ¶²ïŒ35âã«ãã
ãŠPH5.6ïŒ200ïœã38âã«å ç±ããã©ãŠãªã«ç¡«é ž
ãããªãŠã ã®10ééïŒ æ°Žæº¶æ¶²16mlãå ããã (b) äžèšèŠªæ²¹æ§ããªããŒã«ãã©ãŒ(C)20ïœã38âã«
ãããŠé ¢é žãšãã«200mlã«æº¶ããã 次ãã§ã溶液(b)ãé«éã§ãããŸãã®ççºé²æ¢æ··
åæ©ã«å ¥ãããã®äžãžæº¶æ¶²(a)ãæ¥éã«å ãïŒåé
ãããŸããåŸãæ··åæ©ãåæ¢ããæžå§çå»ã«ãã
é ¢é žãšãã«ãé€ããããã®ããã«ããŠèŠªæ²¹æ§ããª
ããŒã«ãã©ãŒãåžãŒã©ãã³æº¶æ¶²ã«åæ£ãã©ããã¯
ã¹ïŒCâ²ïŒãäœã€ãã 補é äŸ (4)ãïŒ22ïŒ åèšåéäœã«ãã©ãŒãçšã補é äŸ(1)ã(3)ã®å ±é
åäœãšåæ§ãªæ¹æ³ã§äžèšã®èŠªæ²¹æ§ããªããŒã«ãã©
ãŒ(D)ãïŒïŒ¶ïŒãäœã€ãã
âã¡ãã«ããšããŒã«(1)ãšã¡ãã«ã¢ã¯ãªã¬ãŒããšã¡
ã¿ã¯ãªã«é žãšã®å ±éåããªããŒïŒèŠªæ²¹æ§ããªããŒ
(A)ïŒ åéäœã«ãã©ãŒ(1)20ïœãã¡ãã«ã¢ã¯ãªã¬ãŒã16
ïœãã¡ã¿ã¯ãªã«é žïŒïœããžãªããµã³200mlã®æ··å
ç©ãçªçŽ æ°æµäžæ¹æäž80âã«å ç±ããåŸãã¢ãŸã
ã¹ã€ãœé ·é žãžã¡ãã«600mgãå«ããžãªããµã³10ml
ãå ãéåãéå§ãããïŒæéåå¿ããåŸåå¿æ¶²
ãå·åŽããæ°Ž1.5ã«æ³šãæåºããåºäœãå¥ãã
ããã«ååæ°Žã§æŽæµããã ãã®åºäœãæžå§äžå ç±ä¹Ÿç¥ããäºã«ãã芪油æ§
ããªããŒ(A)ã37.2ïœåŸãã ãã®ããªããŒã«ãã©ãŒã¯å¡©çŽ åæãã圢æãã
ãå ±éåäœã50.3ïŒ ã®åéäœã«ãã©ãŒ(1)ãå«æã
ãŠããäºã瀺ããã 次ã«èŠªæ²¹æ§ããªããŒã«ãã©ãŒ(A)ããŒã©ãã³æ°Žæº¶
液äžã«ã©ããã¯ã¹ã®åœ¢ã§åæ£ããæ¹æ³ã«ã€ããŠèš
ãããŸã次ã®ããã«ããŠ(a)ãš(b)ã®ïŒçš®ã®æº¶æ¶²ã調
æŽããã (a) 骚ãŒã©ãã³ã®3.0ééïŒ æ°Žæº¶æ¶²ïŒ35âã«ãã
ãŠPH5.6ïŒ200ïœã38âã«å ç±ããã©ãŠãªã«ç¡«é ž
ãããªãŠã ã®10ééïŒ æ°Žæº¶æ¶²16mlãå ããã (b) äžèšèŠªæ²¹æ§ããªããŒã«ãã©ãŒ(A)20ïœã38âã«
ãããŠé ¢é žãšãã«200mlã«æº¶ããã 次ãã§ã溶液(b)ãé«éã§ãããŸãäžã®ççºé²æ¢
æ··åæ©ã«å ¥ãããã®äžãžæº¶æ¶²(a)ãæ¥éã«å ãïŒå
éãããŸããåŸãæ··åæ©ãåæ¢ããæžå§çå»ã«ã
ãé ¢é žãšãã«ãé€ããããã®ããã«ããŠèŠªæ²¹æ§ã
ãªããŒã«ãã©ãŒãåžãŒã©ãã³æº¶æ¶²äžã«åæ£ãã©ã
ãã¯ã¹ïŒAâ²ïŒãäœã€ãã 補æ³äŸ (2) ïŒâã¢ã¯ãªã«ã¢ããâïŒïŒïŒâãžã¯ããâïŒâ
ã¡ãã«ããšããŒã«(2)ãšã¡ãã«ã¢ã¯ãªã¬ãŒããšã¢ã¯
ãªã«é žãšã®å ±éåããªããŒïŒèŠªæ²¹æ§ããªããŒã«ã
ã©ãŒ(B)ïŒ åéäœã«ãã©ãŒ(2)20ïœãã¡ãã«ã¢ã¯ãªã¬ãŒã16
ïœãã¢ã¯ãªã«é žïŒïœããžãªããµã³200mlã®æ··åç©
ãçªçŽ æ°æµäžæ¹æäž80âã«å ç±ããåŸãã¢ãŸãã¹
ã€ãœé ·é žãžã¡ãã«600mgãå«ããžãªããµã³10mlã
å ãéåãéå§ãããïŒæéåå¿ããåŸåå¿æ¶²ã
å·åŽããæ°Ž1.5ã«æ³šãæåºããåºäœãå¥ãã
ããã«ååæ°Žã§æŽæµããã ãã®åºäœãæžå§äžå ç±ä¹Ÿç¥ããäºã«ãã芪油æ§
ããªããŒ(B)ã37.5ïœåŸãã ãã®ããªããŒã«ãã©ãŒã¯å¡©çŽ åæãã圢æãã
ãå ±éåäœã49.9ïŒ ã®åéäœã«ãã©ãŒ(2)ãå«æã
ãŠããäºã瀺ããã 次ã«èŠªæ²¹æ§ããªããŒã«ãã©ãŒ(B)ããŒã©ãã³æ°Žæº¶
液äžã«ã©ããã¯ã¹ã®åœ¢ã§åæ£ããæ¹æ³ã«ã€ããŠèš
ãããŸã次ã®ããã«ããŠ(a)ãš(b)ã®ïŒçš®ã®æº¶æ¶²ã調
æŽããã (a) 骚ãŒã©ãã³ã®3.0ééïŒ æ°Žæº¶æ¶²ïŒ35âã«ãã
ãŠPH5.6ïŒ200ïœã38âã«å ç±ããã©ãŠãªã«ç¡«é ž
ãããªãŠã ã®10ééïŒ æ°Žæº¶æ¶²16mlãå ããã (b) äžèšèŠªæ²¹æ§ããªããŒã«ãã©ãŒ(B)20ïœã38âã«
ãããŠé ¢é žãšãã«200mlã«æº¶ããã 次ãã§ã溶液(b)ãé«éã§ãããŸãäžã®ççºé²æ¢
æ··åæ©ã«å ¥ãããã®äžãžæº¶æ¶²(a)ãæ¥éã«å ãïŒå
éãããŸããåŸãæ··åæ©ãåæ¢ããæžå§çå»ã«ã
ãé ¢é žãšãã«ãé€ããããã®ããã«ããŠèŠªæ²¹æ§ã
ãªããŒã«ãã©ãŒãåžãŒã©ãã³æº¶æ¶²äžã«åæ£ãã©ã
ãã¯ã¹ïŒBâ²ïŒãäœã€ãã 補é äŸ (3) ïŒâïŒïŒâã¡ã¿ã¯ãªã«ã¢ãããããã³ã¢ããïŒâ
ïŒïŒïŒâãžã¯ããâïŒâã¡ãã«ããšããŒã«(9)ãšã¡
ãã«ã¢ã¿ãªã¬ãŒããšã¡ã¿ã¯ãªã«é žãšã®å ±éåããª
ããŒïŒèŠªæ²¹æ§ããªããŒã«ãã©ãŒ(C)ïŒ åéäœã«ãã©ãŒ(9)20ïœãã¡ãã«ã¢ã¯ãªã¬ãŒã18
ïœãã¡ã¿ã¯ãªã«é žïŒïœãå«ããžãªããµã³200mlã®
æ··åç©ãçªçŽ æ°æµäžæ¹æäž80âã«å ç±ããåŸãã¢
ãŸãã¹ã€ãœé ·é žãžã¡ãã«600mgãå«ããžãªããµã³
10mlãå ãéåãéå§ãããïŒæéåå¿ããåŸå
å¿æ¶²ãå·åŽããæ°Ž1.5ã«æ³šãæåºããåºäœã
å¥ããããã«ååæ°Žã§æŽæµããã ãã®åºäœãæžå§äžå ç±ä¹Ÿç¥ããäºã«ãã芪油æ§
ããªããŒ(C)ã38.2ïœåŸãã ãã®ããªããŒã«ãã©ãŒã¯å¡©çŽ åæãã圢æãã
ãå ±éåäœã50.5ïŒ ã®åéäœã«ãã©ãŒ(9)ãå«æã
ãŠããäºã瀺ããã 次ã«èŠªæ²¹æ§ããªããŒã«ãã©ãŒ(C)ããŒã©ãã³æ°Žæº¶
液äžã«ã©ããã¯ã¹ã®åœ¢ã§åæ£ããæ¹æ³ã«ã€ããŠèš
ãããŸã次ã®ããã«ããŠ(a)ãš(b)ã®ïœïŒçš®ã®æº¶æ¶²ã
調æŽããã (a) 骚ãŒã©ãã³ã®3.0ééïŒ æ°Žæº¶æ¶²ïŒ35âã«ãã
ãŠPH5.6ïŒ200ïœã38âã«å ç±ããã©ãŠãªã«ç¡«é ž
ãããªãŠã ã®10ééïŒ æ°Žæº¶æ¶²16mlãå ããã (b) äžèšèŠªæ²¹æ§ããªããŒã«ãã©ãŒ(C)20ïœã38âã«
ãããŠé ¢é žãšãã«200mlã«æº¶ããã 次ãã§ã溶液(b)ãé«éã§ãããŸãã®ççºé²æ¢æ··
åæ©ã«å ¥ãããã®äžãžæº¶æ¶²(a)ãæ¥éã«å ãïŒåé
ãããŸããåŸãæ··åæ©ãåæ¢ããæžå§çå»ã«ãã
é ¢é žãšãã«ãé€ããããã®ããã«ããŠèŠªæ²¹æ§ããª
ããŒã«ãã©ãŒãåžãŒã©ãã³æº¶æ¶²ã«åæ£ãã©ããã¯
ã¹ïŒCâ²ïŒãäœã€ãã 補é äŸ (4)ãïŒ22ïŒ åèšåéäœã«ãã©ãŒãçšã補é äŸ(1)ã(3)ã®å ±é
åäœãšåæ§ãªæ¹æ³ã§äžèšã®èŠªæ²¹æ§ããªããŒã«ãã©
ãŒ(D)ãïŒïŒ¶ïŒãäœã€ãã
ãè¡šã
åéäœã«ãã©ãŒãéçºè²æ§é
žæåå«æåéäœã
ãã³éçºè²æ§åéäœMAã®éã¯è£œé æã®ä»èŸŒã¿é
ãè¡šããã ãããã®èŠªæ²¹æ§ããªããŒã«ãã©ãŒã®åæ£ãåèš
補æ³äŸ(1)ã(3)ãšåæ§ã«ã©ããã¯ã¹ã«åæ£ããããš
ãã§ããã è£œæ³ ïŒïŒ 補é äŸ ïŒ23ïŒ ïŒâã¡ã¿ã¯ãªã«ã¢ããâïŒïŒïŒâãžã¯ããâïŒ
âã¡ãã«ããšããŒã«(1)ãšã¡ãã«ã¢ã¯ãªã¬ãŒããšã¡
ã¿ã¯ãªã«é žã®å ±éåããªããŒïŒããªããŒã«ãã©ãŒ
ã©ããã¯ã¹ïŒïŒïŒ ïŒã®ãã©ã¹ã³äžãªã¬ã€ã«ã¡ãã«ã¿ãŠã©ã€ãïŒ
ïœãå«ãïŒã®æ°Žæº¶æ¶²ãæ¹æäžçªçŽ æ°æµãéãã€
ã€85âã«å ç±ãããã®æ°Žæº¶æ¶²ã«éç¡«é žã«ãªãŠã ïŒ
ïŒ æ°Žæº¶æ¶²15mlãå ããåŸãåéäœã«ãã©ãŒ(1)20
ïœãã¡ãã«ã¢ã¯ãªã¬ãŒã16ïœãã¡ã¿ã¯ãªã«é žïŒïœ
ãã¡ã¿ããŒã«300mlã«å ç±æº¶è§£ãã溶液ã20åé
ã§æ»Žäžããã ïŒæéåå¿åŸéç¡«é žã«ãªãŠã ïŒïŒ 氎溶液ãïŒml
å ãããæŽã«ïŒæéåå¿ããåŸã¡ã¿ããŒã«ãçå»
ããã 圢æããã©ããã¯ã¹ãå·åŽåŸ1Nã®æ°Žé žåãã
ãªãŠã ã§ã©ããã¯ã¹æº¶æ¶²ãPH6.0ã«èª¿æŽãããé
ããã 圢æããã©ããã¯ã¹ã®éåäœæ¿åºŠã¯5.2ïŒ ãå¡©
çŽ åæã¯éåäœäžã«52.6ïŒ ã®åéäœã«ãã©ãŒ(1)ã
å«ãŸããŠããäºã«ç€ºããã 補æ³äŸ ïŒ24ïŒ ïŒâïŒïŒâã¡ã¿ã¯ãªã«ã¢ãããããã³ã¢ããïŒâ
ïŒïŒïŒâãžã¯ããâïŒâã¡ãã«ããšããŒã«(9)ãšã¡
ãã«ã¢ã¯ãªã¬ãŒããšã¡ã¿ã¯ãªã«é žãšã®å ±éåããª
ããŒïŒããªããŒã«ãã©ãŒã©ããã¯ã¹ïŒïŒïŒ ïŒã®ãã©ã¹ã³äžãªã¬ã€ã«ã¡ãã«ã¿ãŠã©ã€ã
2.1ïœãå«ã400mlã®æ°Žæº¶æ¶²ãæ¹æäžçªçŽ æ°æµãé
ãã€ã€80âã«å ç±ãããã®æ°Žæº¶æ¶²ã«éç¡«é žã«ãªãŠ
ã ïŒïŒ 氎溶液ãïŒmlãã¡ãã«ã¢ã¯ãªã¬ãŒããïŒïœ
å ããã ïŒæéåŸåéäœã«ãã©ãŒ(9)ã20ïœãã¡ãã«ã¢ã¯
ãªã¬ãŒã16ïœãã¡ã¿ã¯ãªã«é žïŒïœãã¡ã¿ããŒã«
200mlãå ããåŸéç¡«é žã«ãªãŠã ã®ïŒïŒ 氎溶液ã
14mlãïŒæéåŸã«ïŒmlå ãããæŽã«ïŒæéåå¿ã
ãåŸæªåå¿ã®ã¡ãã«ã¢ã¯ãªã¬ãŒãããã³ã¡ã¿ããŒ
ã«ãçå»ããã 圢æããã©ããã¯ã¹ãå·åŽåŸ1Nã®æ°Žé žåãã
ãªãŠã ã§ã©ããã¯ã¹æº¶æ¶²ãPH6.0ã«èª¿æŽããéã
ãã 圢æããã©ããã¯ã¹ã®éåäœæ¿åºŠã¯11.6ïŒ ãå¡©
çŽ åæã¯éåäœäžã«48.1ïŒ ã®åéäœã«ãã©ãŒ(9)ã
å«ãŸããŠããäºã瀺ããã 補æ³äŸ ïŒ25ïŒãïŒ37ïŒ åèšåéäœã«ãã©ãŒãçšã補æ³äŸïŒ24ïŒã®å ±é
åäœãšåæ§ãªæ¹æ³ã§äžèšã®ããªããŒã«ãã©ãŒã©ã
ãã¯ã¹ïŒïŒãïŒïŒãäœã€ãã
ãã³éçºè²æ§åéäœMAã®éã¯è£œé æã®ä»èŸŒã¿é
ãè¡šããã ãããã®èŠªæ²¹æ§ããªããŒã«ãã©ãŒã®åæ£ãåèš
補æ³äŸ(1)ã(3)ãšåæ§ã«ã©ããã¯ã¹ã«åæ£ããããš
ãã§ããã è£œæ³ ïŒïŒ 補é äŸ ïŒ23ïŒ ïŒâã¡ã¿ã¯ãªã«ã¢ããâïŒïŒïŒâãžã¯ããâïŒ
âã¡ãã«ããšããŒã«(1)ãšã¡ãã«ã¢ã¯ãªã¬ãŒããšã¡
ã¿ã¯ãªã«é žã®å ±éåããªããŒïŒããªããŒã«ãã©ãŒ
ã©ããã¯ã¹ïŒïŒïŒ ïŒã®ãã©ã¹ã³äžãªã¬ã€ã«ã¡ãã«ã¿ãŠã©ã€ãïŒ
ïœãå«ãïŒã®æ°Žæº¶æ¶²ãæ¹æäžçªçŽ æ°æµãéãã€
ã€85âã«å ç±ãããã®æ°Žæº¶æ¶²ã«éç¡«é žã«ãªãŠã ïŒ
ïŒ æ°Žæº¶æ¶²15mlãå ããåŸãåéäœã«ãã©ãŒ(1)20
ïœãã¡ãã«ã¢ã¯ãªã¬ãŒã16ïœãã¡ã¿ã¯ãªã«é žïŒïœ
ãã¡ã¿ããŒã«300mlã«å ç±æº¶è§£ãã溶液ã20åé
ã§æ»Žäžããã ïŒæéåå¿åŸéç¡«é žã«ãªãŠã ïŒïŒ 氎溶液ãïŒml
å ãããæŽã«ïŒæéåå¿ããåŸã¡ã¿ããŒã«ãçå»
ããã 圢æããã©ããã¯ã¹ãå·åŽåŸ1Nã®æ°Žé žåãã
ãªãŠã ã§ã©ããã¯ã¹æº¶æ¶²ãPH6.0ã«èª¿æŽãããé
ããã 圢æããã©ããã¯ã¹ã®éåäœæ¿åºŠã¯5.2ïŒ ãå¡©
çŽ åæã¯éåäœäžã«52.6ïŒ ã®åéäœã«ãã©ãŒ(1)ã
å«ãŸããŠããäºã«ç€ºããã 補æ³äŸ ïŒ24ïŒ ïŒâïŒïŒâã¡ã¿ã¯ãªã«ã¢ãããããã³ã¢ããïŒâ
ïŒïŒïŒâãžã¯ããâïŒâã¡ãã«ããšããŒã«(9)ãšã¡
ãã«ã¢ã¯ãªã¬ãŒããšã¡ã¿ã¯ãªã«é žãšã®å ±éåããª
ããŒïŒããªããŒã«ãã©ãŒã©ããã¯ã¹ïŒïŒïŒ ïŒã®ãã©ã¹ã³äžãªã¬ã€ã«ã¡ãã«ã¿ãŠã©ã€ã
2.1ïœãå«ã400mlã®æ°Žæº¶æ¶²ãæ¹æäžçªçŽ æ°æµãé
ãã€ã€80âã«å ç±ãããã®æ°Žæº¶æ¶²ã«éç¡«é žã«ãªãŠ
ã ïŒïŒ 氎溶液ãïŒmlãã¡ãã«ã¢ã¯ãªã¬ãŒããïŒïœ
å ããã ïŒæéåŸåéäœã«ãã©ãŒ(9)ã20ïœãã¡ãã«ã¢ã¯
ãªã¬ãŒã16ïœãã¡ã¿ã¯ãªã«é žïŒïœãã¡ã¿ããŒã«
200mlãå ããåŸéç¡«é žã«ãªãŠã ã®ïŒïŒ 氎溶液ã
14mlãïŒæéåŸã«ïŒmlå ãããæŽã«ïŒæéåå¿ã
ãåŸæªåå¿ã®ã¡ãã«ã¢ã¯ãªã¬ãŒãããã³ã¡ã¿ããŒ
ã«ãçå»ããã 圢æããã©ããã¯ã¹ãå·åŽåŸ1Nã®æ°Žé žåãã
ãªãŠã ã§ã©ããã¯ã¹æº¶æ¶²ãPH6.0ã«èª¿æŽããéã
ãã 圢æããã©ããã¯ã¹ã®éåäœæ¿åºŠã¯11.6ïŒ ãå¡©
çŽ åæã¯éåäœäžã«48.1ïŒ ã®åéäœã«ãã©ãŒ(9)ã
å«ãŸããŠããäºã瀺ããã 補æ³äŸ ïŒ25ïŒãïŒ37ïŒ åèšåéäœã«ãã©ãŒãçšã補æ³äŸïŒ24ïŒã®å ±é
åäœãšåæ§ãªæ¹æ³ã§äžèšã®ããªããŒã«ãã©ãŒã©ã
ãã¯ã¹ïŒïŒãïŒïŒãäœã€ãã
ãè¡šã
é æã®ä»èŸŒã¿éãè¡šããã
æ¬çºæã®ã·ã¢ã³ããªããŒã«ãã©ãŒã©ããã¯ã¹ã¯
åç¬ã§ãããã¯ïŒçš®ä»¥äžãæ··åããŠäœ¿çšã§ããã æ¬çºæã®ã·ã¢ã³ããªããŒã«ãã©ãŒã©ããã¯ã¹ã¯
ç±³åœç¹èš±4080211å·ã西ç¬ç¹èš±2725591ãç±³åœç¹èš±
3926436å·åã³Research Disclosure21728å·ãªã©
ã«èšèŒãããã·ã¢ã³ããªããŒã«ãã©ãŒã©ããã¯ã¹
ã䜵çšããããšãã§ããã ãŸããæ¬çºæã®ã·ã¢ã³ããªããŒã«ãã©ãŒã©ãã
ã¯ã¹ã«çæ°Žæ§ã·ã¢ã³çºè²ã«ãã©ãŒã®ããšããŒã«ã«
ãã©ãŒãããã³ããããŒã«ã«ãã©ãŒãããšãã°ã
ç±³åœç¹èš±2369929å·ãå2434272å·ãå2474293å·ã
å2521908ãå2895826å·ãå3034892å·ãå
3311476å·ãå3458315å·ãå3476563å·ãå
3583971ãå3591383å·ãå3767411å·ãå4004929
å·ã西ç¬ç¹èš±åºé¡2414830å·ãå2454329å·ãç¹é
æ48â59838ãå51â26034å·ãå48â5055å·ãå
51â146828å·ãå55â73050å·ã«èšèŒã®ã·ã¢ã³ã«
ãã©ãŒãç±³åœç¹èš±2269158å·ãå2272191å·ãå
2304940å·ãå2311020å·ãå2322027å·ãå
2360289å·ãå2772163å·ãå2801170å·ãå
2801171å·ãå3619195å·ãè±åœç¹èš±1151590å·ã
ç¬åœç¹èš±1143707å·ãªã©ã«èšèŒã®æ¹æ³ã§èŠªæ°Žæ§ã³
ãã€ãã«åæ£ããåæ£ç©ããç¹å ¬æ51â39853ãª
ã©ã«èšèŒã®æ¹æ³ã§å«æµžïŒããŒãïŒããŠäœ¿çšããã
ãšãã§ããããäžèšã®çæ°Žæ§ã·ã¢ã³ã«ãã©ãŒãæ¬
çºæã®ã·ã¢ã³ããªããŒã«ãã©ãŒã©ããã¯ã¹ã«ç¹é
æ51â59942ãå54â32552ãç±³åœç¹èš±4199363ãª
ã©ã«èšèŒã®æ¹æ³ã§å«æµžïŒããŒãïŒãããŠäœ¿çšãã
ããšãã§ãããããã§å«æµžïŒããŒãïŒãšã¯çæ°Žæ§
ã·ã¢ã³ã«ãã©ãŒãã·ã¢ã³ããªããŒã«ãã©ãŒã©ãã
ã¯ã¹å éšã«å«ãŸããç¶æ ããããã¯ã·ã¢ã³ã«ãã©
ãŒã©ããã¯ã¹è¡šé¢ã«æ²ç©ããŠããç¶æ ãæå³ã
ããããããå«æµžïŒããŒãïŒããããªãæ©æ§ã§èµ·
ãããã¯æ£ç¢ºã«ã¯ããã€ãŠããªãã æ¬çºæã®ã·ã¢ã³ããªããŒã«ãã©ãŒã©ããã¯ã¹ã«
æå ææã«æ±ããããç¹æ§ãæºè¶³ããããã«ç±³åœ
ç¹èš±3148062å·ãå3227554å·ãå3733201å·ãå
3617291å·ãå3703375å·ãå3615506å·ãå
3265506å·ãå3620745å·ãå3632345å·ãå
3869291å·ãå3642485å·ãå3770436å·ãå
3808945å·ãè±åœç¹èš±1201110å·ãå1236767å·ã
ãªã©ã«èšèŒã®çŸåæå¶å€æŸåºïŒDIRïŒã«ãã©ãŒã
ç±³åœç¹èš±2269158å·ãå2272191å·ãå2304940å·ã
å2311020å·ãå2322027å·ãå2360289å·ãå
2772163å·ãå2801170å·ãå2801171å·ãå
3619195å·ãè±åœç¹èš±1151590å·ãç¬åœç¹èš±
1143707å·ãªã©ã«èšèŒã®æ¹æ³ã§èŠªæ°Žæ§ã³ãã€ãã«
åæ£ããåæ£ç©ãç¹å ¬æ51â39853ãªã©ã«èšèŒã®
æ¹æ³ã§å«æµžããŠäœ¿çšããããšãã§ããããäžèšã®
ãããªDIRã«ãã©ãŒãã·ã¢ã³ããªããŒã«ãã©ãŒã©
ããã¯ã¹ã«ç¹éæ51â59942ãå54â32552ãç±³åœ
ç¹èš±4199363å·ãªã©ã«èšèŒã®æ¹æ³ã§å«æµžãããŠã
䜿çšããããšãã§ããã ãŸãç¬åœå ¬é2529350å·ãå2448063å·ãå
2610546å·ãç±³åœç¹èš±3928041å·ãå3958993å·ã
å3961959å·ãå4049455å·ãå4052213å·ãå
3379529å·ãå3043690å·ãå3364022å·ãå
3297445å·ãå3287129å·ããªã©ã«èšèŒã®DIRåå
ç©ã䜵çšããŠäœ¿çšããããšãã§ããã ãŸããç±³åœç¹èš±3876428å·ãå3580722å·ãå
2998314å·ãå2808329å·ãå2742832å·ãå
2689793å·ãªã©ã«èšèŒã®ç«¶äºã«ãã©ãŒãç±³åœç¹èš±
2336327å·ãå2728659å·ãå2336327å·ãå
2403721å·ãå2701197å·ãå3700453å·ãªã©ã«èš
èŒã®ã¹ãã€ã³é²æ¢å€ãè±åœç¹èš±1326889å·ãç±³åœ
ç¹èš±3432300å·ãå3698909å·ãå3574627å·ãå
3573050å·ãå3764337å·ãªã©ã«èšèŒã®è²çŽ åå®å®
å€ãªã©ãšäœµçšããããšãã§ããã æ¬çºæã䜿ã€ãŠã«ã©ãŒåçæå ææãäœãã«ã¯
ã·ã¢ã³åœ¢æã«ãã©ãŒä»¥å€ã®äžè¬ã«è¯ãç¥ãããã«
ãã©ãŒã䜿çšããããšãã§ããã ã«ãã©ãŒã¯ååäžã«ãã©ã¹ãåºãšåŒã°ããçæ°Ž
åºãæããéæ¡æ£æ§ã®ãã®ãæãŸãããã«ãã©ãŒ
ã¯éã€ãªã³ã«å¯ŸãïŒåœéæ§ãããã¯ïŒåœéæ§ã®ã©
ã¡ãã§ãããããŸãè²è£æ£ã®å¹æããã€ã«ã©ãŒ
ãã»ã«ãã©ãŒããããã¯çŸåã«ãšããªã€ãŠçŸåæ
å¶å€ãæŸåºããã«ãã©ãŒãå«ãã§ããããã«ãã©
ãŒã¯ã«ãããªã³ã°åå¿ã®çæç©ãç¡è²ã§ãããã
ãªã«ãã©ãŒã§ãããã é»è²çºè²ã«ãã©ãŒãšããŠã¯å ¬ç¥ã®ééã±ãã¡ã
ã¬ã³ç³»ã«ãã©ãŒãçšããããšãã§ããããããã®
ãã¡ãã³ãŸã€ã«ã¢ã»ãã¢ããªãç³»ããã³ãããã€
ã«ã¢ã»ãã¢ããªãç³»ååç©ã¯æå©ã§ãããçšãã
ãé»è²çºè²ã«ãã©ãŒã®å ·äœäŸã¯ãç±³åœç¹èš±
2875057å·ãå3265506å·ãå3408194å·ãå
3551155å·ãå3582322å·ãå3725072å·ãå
3891445å·ã西ç¬ç¹èš±1547868å·ã西ç¬åºé¡
2219917å·ãå2261361å·ãå2414006å·ãè±åœç¹
èš±1425020å·ãç¹å ¬æ51â10783å·ãç¹éæ47â
26133å·ãå48â73147å·ãå51â102636å·ãå50
â6341å·ãå50â123342å·ãå50â130442å·ãå
51â21827å·ãå50â87650å·ãªã©ã«èšèŒãããã
ã®ã§ããã ããŒã³ã¿çºè²ã«ãã©ãŒãšããŠã¯ãïŒâãã©ãŸã
ã³ã«ãã©ãŒããã©ãŸããã³ãã€ãããŸãŒã«ã«ãã©
ãŒãã·ã¢ãã¢ã»ãã«ã¯ããã³ã«ãã©ãŒãééã¢ã·
ã«ã¢ã»ããããªã«ã«ãã©ãŒçããããããšãã°ç±³
åœç¹èš±2600788å·ãå2983608å·ãå3062653å·ã
å3127269å·ãå3311476å·ãå3419391å·ãå
3519429å·ãå3558319å·ãå3582322å·ãå
3615506å·ãå3834908å·ãå3891445å·ã西ç¬ç¹
èš±1810464å·ã西ç¬ç¹èš±åºé¡ïŒOLSïŒ2408665å·ã
å2417945å·ãå2418959å·ãå2424467å·ãç¹å ¬
æ40â6031å·ãç¹éæ51â20826å·ãå52â58922
å·ãå49â129538å·ãå49â74027å·ãå50â
159336å·ãå52â42121å·ãå49â74028å·ãå50
â60233å·ãå51â26541å·ãå53â55122å·ããª
ã©ã«èšèŒããããã®ãããã äžèšã®ã«ãã©ãŒã¯åäžå±€ã«äºçš®ä»¥äžå«ãããšã
ã§ãããåäžååç©ãç°ãªãïŒä»¥äžã®å±€ã«å«ãã§
ãããã æ¬çºæã®ããªããŒã«ãã©ãŒã¯ã«ãã©ãŒåéäœã«
察å¿ããéšåãéïŒã¢ã«ã«å¯ŸããŠïŒÃ10-3ã¢ã«ãª
ããïŒÃ10-1ã¢ã«ã奜ãŸããã¯ïŒÃ10-2ãªããïŒ
Ã10-1ã¢ã«ã«ãªãããã«æ·»å ãããã äžèšã®ã«ãã©ãŒãããã²ã³åéä¹³å€å±€ã«å°å ¥ã
ãã«ã¯ãå ¬ç¥ã®æ¹æ³ããšãã°ç±³åœç¹èš±2322027å·
ã«èšèŒã®æ¹æ³ãªã©ãçšããããã«ãã©ãŒã芪氎æ§
ã³ãã€ãã«åæ£ããåŸã«ãããã²ã³åéä¹³å€ãšæ··
åãããã ã«ãã©ãŒãã«ã«ãã³é žãã¹ã«ããªã³é žã®ããšã
é žåºãæããå Žåã«ã¯ãã¢ã«ã«ãªæ§æ°Žæº¶æ¶²ãšããŠ
芪氎æ§ã³ãã€ãäžã«å°å ¥ãããã æ¬çºæã«äœ¿çšãããããã²ã³åéä¹³å€ã¯ãå¡©å
éãèåéã®ã»ãã«æ··åããã²ã³åéãããšãã°
å¡©èåéãæ²èåéãå¡©æ²èåéçãããªãããŒ
ã©ãã³ã®åŠã芪氎æ§é«ååäžã«åŸ®çŽ°ã«åæ£ããã
ãã®ã§ãããåäžãªç²åãµã€ãºããã€ãã®ããåº
ãç²åãµã€ãºååžããã€ãã®ãŸã§ããŸãå¹³åç²å
ãµã€ãºãçŽ0.1ãã¯ãã³ããçŽïŒãã¯ãã³ã«è³ã
åºç¯å²ãªåæ£ç¶æ ã«ãããã®ãæå ææã®äœ¿çšç®
çã«å¿ããŠéžæãããããããããã²ã³åéä¹³å€
ã¯ãäŸãã°ã·ã³ã°ã«ãããã¯ããã«ãžãšããæ³ã
ãããã¯ã³ã³ãããŒã«ããã«ãžãšããæ³çã®æ··å
æ³ã«ãã€ãŠãããã«äŸãã°ã¢ã³ã¢ãã¢æ³ãäžæ§
æ³ãé žæ§æ³çã®çææ¹æ³ã«ãã€ãŠèª¿è£œããåŸãã
ãŸããããããã²ã³åéä¹³å€ã¯ãç¡«é»å¢æãéå¢
æãéå å¢æã®åŠãååŠå¢æãåããŠããŠãã
ããããªãªãã·ãšãã¬ã³ååç©ããªããŠã ååç©
ã®ãããªæ床äžæå€ãå«æããŠããŠãããããŸã
æœåãäž»ãšããŠè¡šé¢ã«åœ¢æããåã®ä¹³å€ã°ããã§
ãªããŠãç²åå éšã«åœ¢æããå éšæœååã®ãã®ã
æ¬çºæã«äœ¿çšããããšãã§ããããŸãå¥ã ã«åœ¢æ
ããïŒçš®ä»¥äžã®ããã²ã³åéåçä¹³å€ãæ··åããŠ
ãããã æ¬çºæã®æå å±€ãæ§æãã芪氎æ§é«ååç©è³ªãš
ããŠã¯ããŒã©ãã³ã®åŠãèçœè³ªãããªããã«ã¢ã«
ã³ãŒã«ãããªããã«ãããªãã³ãããªã¢ã¯ãªã«ã¢
ããã®åŠãé«ååéé»è§£è³ªãã¢ã«ã®ã³é žå¡©ãããª
ã¢ã¯ãªã«é žå¡©ã®åŠãé žæ§é«ååç©è³ªããããã³è»¢
äœåå¿ã«ãã€ãŠåŠçããããªã¢ã¯ãªã«ã¢ãããã¢
ã¯ãªã«é žãšïŒ®âããã«ã€ãããŸãŒã«ã®å ±éåç©ã®
åŠãé«ååäž¡æ§é»è§£è³ªãUS.4215195ã«èšèŒã®æ¶
æ©æ§ããªããŒãªã©ãé©ããŠããããŸããããé£ç¶
çžããªã芪氎æ§é«ååç©è³ªã¯ãåæ£ãããçæ°Žæ§
é«ååç©è³ªãäŸãã°ããªã¢ã¯ãªã«é žããã«ãšã¹ã
ã«çã®ã©ããã¯ã¹ãå«ãã§ããŠãããã æ¬çºæã«çšããããããã²ã³åéåçä¹³å€ã¯ã
ãŸãåžžæ³ã«ãã€ãŠååŠå¢æãããããšãã§ããã
ååŠå¢ææã«ã¯ããšãã°ç±³åœç¹èš±2399083å·ãå
2540085å·ãå2597856å·ãå2597915å·ã«ç€ºãã
ããããªå¡©åéé žéãäžå¡©åéãªã©éååç©ãç±³
åœç¹èš±2448060å·ãå2540086ãå2556245å·ãå
2566263å·ãå2598079å·ã«ç€ºããããããªçœéã
ãã©ãžãŠã ãã€ãªãžãŠã ãããžãŠã ãã«ãããŠã
ã®ãããªè²Žéå±ã®å¡©é¡ãç±³åœç¹èš±1574944å·ãå
2410689å·ãå3189458å·ãå3501313å·çã«èšèŒ
ãããŠãããããªãéå¡©ãšåå¿ããŠç¡«åéã圢æ
ããã€ãªãŠååç©ãç±³åœç¹èš±2487850å·ãå
2518698å·ãå2521925å·ãå2521926å·ãå
2694637å·ãå2983610å·ãå3201254å·ã«èšèŒã
ããŠãããããªç¬¬äžã¹ãºå¡©ãã¢ãã³é¡ããã®ä»ã®
éå æ§ç©è³ªãªã©ããããããã æ¬çºæã®åçä¹³å€ã«ã¯æå ææã®è£œé å·¥çšãä¿
åäžæãã¯åŠçäžã®æ床äœäžãã«ããªã®çºçãé²
ãããã«çš®ã ã®ååç©ãæ·»å ããããšãã§ããã
ãããã®ååç©ã¯ïŒâããããã·âïŒâã¡ãã«â
ïŒïŒïŒïŒ3aïŒïŒâããã©ã¶ã€ã³ãã³ãïŒâã¡ã
ã«ãã³ãŸãã¢ãŸãŒã«ãïŒâããšãã«âïŒâã¡ã«ã«
ããããã©ãŸãŒã«ãã¯ãããå€ãã®è€çŽ ç°åå
ç©ãå«æ°Žéååç©ãã¡ã«ã«ããååç©ãéå±å¡©é¡
ãªã©æ¥µããŠå€ãã®ååç©ãå€ãããç¥ãããŠã
ãã 䜿çšã§ããååç©ã®äžäŸã¯ãK.MeesèâThe
Theory of the Photographic ProcessâïŒç¬¬ïŒ
çã1966幎ïŒã«åæç®ãæããŠèšãããŠããã»ã
次ã®ç¹èš±ã«ãèšãããŠãããç±³åœç¹èš±1758576å·ã
å2110178å·ãå2131038å·ãå2173628å·ãå
2697040å·ãå2304962å·ãå2324123å·ãå
2394198å·ãå2444605ãïŒå·ãå2566245å·ãå
2694716å·ãå2697099å·ãå2708162å·ãå
2728663ãïŒå·ãå2476536å·ãå2824001å·ãå
2843491å·ãå2886437å·ãå3052544å·ãå
3137577å·ãå3220839å·ãå3226231å·ãå
3236652å·ãå3251691å·ãå3252799å·ãå
3287135å·ãå3326681å·ãå3420668å·ãå
3622339å·ãè±åœç¹èš±893428å·ãå403789å·ãå
1173609å·ãå1200188å·ã æ¬çºæã®åçä¹³å€ã«ã¯çé¢æŽ»æ§å€ãåç¬ãŸãã¯
æ··åããŠæ·»å ããŠãããããããã¯å¡åžå©å€ãšã
ãŠçšãããããã®ã§ããããæãšããŠãã®ä»ã®ç®
çãããšãã°ä¹³ååæ£ãå¢æã垯é»é²æ¢ãæ¥çé²
æ¢ãªã©ã®ããã«ãé©çšãããã ãããã®çé¢æŽ»æ§å€ã¯ãµããã³ãªã©ã®å€©ç¶çé¢
掻æ§å€ãã¢ã«ãã¬ã³ãªããµã€ãç³»ãã°ãªã»ãªã³
ç³»ãã°ãªã·ããŒã«ç³»ãªã©ã®ãããªã³çé¢æŽ»æ§å€ã
é«çŽã¢ã«ãã«ã¢ãã³é¡ã第ïŒçŽã¢ã³ã¢ããŠã å¡©
é¡ãããªãžã³ãã®ä»ã®è€çŽ ç°é¡ããã¹ãããŠã å
ã¯ã¹ã«ãããŠã é¡ãªã©ã®ã«ããªã³çé¢æŽ»æ§å€ãã«
ã«ãã³é žãã¹ã«ãã³é žãçé žãç¡«é žãšã¹ãã«åºã
çé žãšã¹ãã«åºçã®é žæ§åºãå«ãã¢ããªã³çé¢æŽ»
æ§å€ãã¢ããé žé¡ãã¢ããã¹ã«ãã³é¡ãã¢ããã¢
ã«ã³ãŒã«ã®ç¡«é žãŸãã¯çé žãšã¹ãã«é¡çã®äž¡æ§æŽ»
æ§å€ã«ãããããã ããã䜿çšãåŸãçé¢æŽ»æ§å€ååç©äŸã®äžéšã¯
ç±³åœç¹èš±2271623å·ãå2240472å·ãå2288226å·ã
å2739891å·ãå3068101å·ãå3158484å·ãå
3201253å·ãå3210191å·ãå3294540å·ãå
3415649å·ãå3441413å·ãå3442654å·ãå
3475174å·ãå3545974å·ã西ãã€ãç¹èš±å ¬é
1942665å·ãè±åœç¹èš±1077317å·ãå1198450å·ã
ã¯ãããå°ç°è¯å¹³ä»èãçé¢æŽ»æ§å€ã®åæãšãã®
å¿çšãïŒæ§æžåº1964幎çïŒããã³A.W.ããªã€è
ããµãŒããšã¹ ã¢ã¯ãã€ã ãšãŒãžãšã³ããïŒã€ã³
ã¿ãŒãµã€ãšã³ã¹ ãããªã±ãŒã·ãšã³ ã€ã³ã³ãŒã
ã¬ãŒãã€ã1958幎çïŒãJ.P.ã·ã¹ãªãŒèããšã³ãµ
ã€ã¯ãããã€ã¢ ãªã ãµãŒããšã¹ ã¢ã¯ãã€ã
ãšãŒãžãšã³ã第ïŒå·»ãïŒã±ãã«ã«ãããªãã·ã
ã«ã³ãããŒ1964幎çïŒãªã©ã®ææžã«èšèŒãããŠã
ãã åçä¹³å€ã¯ã·ã¢ãã³ãã¡ãã·ã¢ãã³ãã«ã«ãã·
ã¢ã³çã®ã·ã¢ãã³è²çŽ é¡ã®åç¬ãããã¯çµåã䜿
çšãŸãã¯ããããšã¹ããªã«ææçãšã®çµåã䜿çš
ã«ãã€ãŠåå æ床ã匷è²å¢æãè¡ãããšãã§ã
ãã ãããã®è²å¢ææè¡ã¯å€ãããç¥ãããŠããã
ç±³åœç¹èš±2688545å·ãå2912329å·ãå3397060å·ã
å3615635å·ãå3628964å·ãè±åœç¹èš±1195302å·ã
å1242588å·ãå1293862å·ã西ãã€ãç¹èš±å ¬é
2030326å·ãå2121780å·ãç¹å ¬æ43â4936å·ãå
44â14030å·ããªã©ã«ãèšèŒãããããã®éžæã¯
å¢æãã¹ãæ³¢é·åãæ床çæå ææã®ç®çãçšé
ã«å¿ããŠä»»æã«å®ããããšãã§ããã æ¬çºæã«äœ¿çšãããæå ææã®èŠªæ°Žæ§ã³ãã€ã
å±€ãç¹ã«ãŒã©ãã³å±€ã¯åçš®ã®æ¶æ©å€ã«ãã€ãŠç¡¬è
ããããšãã§ãããäŸãã°ã¯ãã å¡©ããžã«ã³ããŠ
ã å¡©ã®ãããªç¡æ©ååç©ïŒã ã³ã¯ããŒã«é žãªãã
ç¹å ¬æ46â1872å·ã«èšèŒãããŠããïŒâããšãã
ã·âïŒâã¯ãã«ãã¬ã¢ã«ãããé žã®åŠãã¢ã«ãã
ãç³»ååç©ãå€ãã®å Žåæ¬çºæã«æçšã§ãããã
ç¹å ¬æ34â7133å·ã«èšèŒãããŠããè€æ°åã®ãšã
ãã·ç°ãæããååç©ãç¹å ¬æ37â8790ã«èšèŒã
ããŠããããªãŒïŒïŒâã¢ãžãªãžã«ïŒååç©ã䞊ã³
ã«ç±³åœç¹èš±3362827å·ã3325287å·ã«èšèŒãããŠã
ã掻æ§ããã²ã³ååç©ãç±³åœç¹èš±2994611å·ãå
3582322å·ããã«ã®ãŒç¹èš±ç¬¬686440å·ãªã©ã§ç¥ã
ããŠããããã«ã¹ã«ãã³ç³»ååç©ãªã©ã®éã¢ã«ã
ããç³»æ¶æ©å€ã¯ãæ¬çºæã«äœ¿çšããæå ææã«äœ¿
çšããã®ã«ç¹ã«é©ããŠããã æ¬çºæã®ããã²ã³åéåçä¹³å€ã¯ãå€ãã®å Žå
æ¯æäœäžã«çœ®ãããŠãããæ¯æäœãšããŠã¯ãç®ç
ã«å¿ããŠã¬ã©ã¹ãéå±ãé¶åšã®ãããªç¡¬ããã®
ãããã®ä»ã®å¯ææ§ã®ãã®ã䜿çšããããå¯ææ§
æ¯æäœã®ä»£è¡šçãªäŸãšããŠã¯ãã»ã«ããŒãºãã€ã
ã¬ãŒããã€ã«ã ãã»ã«ããŒãºã¢ã»ããŒããã€ã«
ã ãããªããã«ã¢ã»ã¿ãŒã«ãã€ã«ã ãããªã¹ãã¬
ã³ãã€ã«ã ãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããã€ã«
ã ãããªã«ãŒãããŒããã€ã«ã åã³ãããã®ç©å±€
ç©çãããããã©ã€ã¿ãŸãã¯Î±âãªã¬ãã€ã³ããª
ããŒç¹ã«ããªãšãã¬ã³ãããªãããã¬ã³ããšãã¬
ã³ããã³ã³ããªããŒçã«ãã€ãŠè¢«èŠãããçŽãç¹
å ¬æ47â19068ã«ç€ºãããŠãããããªç²é¢åãã
è¡šé¢ããã€ãã©ã¹ããã¯ãã€ã«ã ãæå©ã«äœ¿çšã
ããããããã®æ¯æäœã¯ãæå ææã®ç®çã«å¿ã
ãŠãéæãªãã®ãææãé¡æãæ·»å ããŠçè²ãã
ãã®ããã¿ã³ãã¯ã€ãçãæ·»å ããŠäžéæåãã
ãã®ãã«ãŒãã³ãã©ãã¯çãæ·»å ããŠé®å æ§ã«ã
ããã®çããéžæã§ããã åçæå ææã®åå±€ã¯ãã€ããã³ãŒãããšã¢ãŒ
ãã€ãã³ãŒããã«ãŒãã³ã³ãŒãããããã¯ç±³åœç¹
èš±2681294å·ã«èšèŒã®ããããŒã䜿çšãããšã¯ã¹
ãã«âãžãšã³ã³ãŒããå«ãçš®ã ã®å¡åžæ³ã«ãã€ãŠ
å¡åžããããšãã§ãããå¿ èŠã«å¿ããŠãç±³åœç¹èš±
2761791å·ãå3508947å·åã³å2941898å·ãå
3526528å·ãªã©ã«èšèŒã®æ¹æ³ã«ããïŒçš®åã¯ãã
以äžã®å±€ãåæã«å¡åžããããšãã§ããã ã«ãã©ãŒãããã²ã³åéä¹³å€å±€ã«å°å ¥ããã«ã¯
å ¬ç¥ã®æ¹æ³ããšãã°ç±³åœç¹èš±2322027å·ã«èšèŒã®
æ¹æ³ãªã©ãçšãããããããšãã°ãã¿ãŒã«é žã¢ã«
ãã«ãšã¹ãã«ïŒãžããã«ãã¿ã¬ãŒãããžãªã¯ãã«
ãã¿ã¬ãŒããªã©ïŒããªã³é žãšã¹ãã«ïŒãžããšãã«
ããªã¹ããšãŒããããªããšãã«ããªã¹ããšãŒãã
ããªã¯ã¬ãžã«ããªã¹ããšãŒãããžãªã¯ãã«ããã«
ããªã¹ããšãŒãïŒãã¯ãšã³é žãšã¹ãã«ïŒããšãã°
ã¢ã»ãã«ã¯ãšã³é žããªããã«ïŒãå®æ¯éŠé žãšã¹ã
ã«ïŒããšãã°å®æ¯éŠé žãªã¯ãã«ïŒãã¢ã«ãã«ã¢ã
ãïŒããšãã°ãžãšãã«ã©ãŠãªã«ã¢ããïŒãèèªé ž
ãšã¹ãã«é¡ïŒããšãã°ãžãããã·ãšãã«ãŒã¯ã·ã
ãŒãããžãªã¯ãã«ã¢ãŒã¬ãŒãïŒãããªã¡ã·ã³é žãš
ã¹ãã«é¡ïŒããšãã°ããªã¡ã·ã³é žããªããã«ïŒãª
ã©ããŸãã¯æ²žç¹çŽ30âä¹è³150âã®ææ©æº¶åªãã
ãšãã°é ¢é žãšãã«ãé ¢é žããã«ã®ããšãäœçŽã¢ã«
ãã«ã¢ã»ããŒããããããªã³é žãšãã«ãïŒçŽãã
ã«ã¢ã«ã³ãŒã«ãã¡ãã«ã€ãœããã«ã±ãã³ãβâãš
ããã·ãšãã«ã¢ã»ããŒããã¡ãã«ã»ããœã«ãã¢ã»
ããŒãçã«æº¶è§£ããã®ã¡ã芪氎æ§ã³ãã€ãã«åæ£
ããããäžèšã®é«æ²žç¹ææ©æº¶åªãšäœæ²žç¹ææ©æº¶åª
ãšãæ··åããŠçšããŠãããã ãŸãç¹å ¬æ51â39853å·ãç¹éæ51â59943å·ã«
èšèŒãããŠããéåç©ã«ããåæ£æ³ã䜿çšããã
ãšãã§ããã ã«ãã©ãŒãã«ã«ãã³é žãã¹ã«ããªã³é žã®ããšã
é žåºãæããå Žåã«ã¯ãã¢ã«ã«ãªæ§æ°Žæº¶æ¶²ãšããŠ
芪氎æ§ã³ãã€ãäžã«å°å ¥ãããã æ¬çºæãå®æœäŸããã«éããŠäžèšã®å ¬ç¥ã®éè²
é²æ¢å€ã䜵çšããããšãã§ãããŸãæ¬çºæã«çšã
ãè²åå®å®å€ã¯åç¬ãŸãã¯ïŒçš®ä»¥äžäœµçšããããš
ãã§ãããå ¬ç¥ã®éè²é²æ¢å€ãšããŠã¯ããã€ãã
ããã³èªå°äœæ²¡é£åé žèªå°äœãâã¢ã«ã³ãã·ã
ãšããŒã«é¡ãâãªãã·ããšããŒã«èªå°äœåã³ã
ã¹ããšããŒã«é¡çãããã ãã€ããããã³èªå°äœã®å ·äœäŸã¯ç±³åœç¹èš±ç¬¬
2360290å·ãå2418613å·ãå2675314å·ãå
2701197å·ãå2704713å·ãå2728659å·ãå
2732300å·ãå2735765å·ãå2710801å·ãå
2816028å·ãè±åœç¹èš±1363921å·ãçã«èšèŒãããŠ
ããã没é£åé žèªå°äœã®ããã«ç±³åœç¹èš±3457079
å·ãå3069262å·çã«èšèŒãããŠãããâã¢ã«
ã³ãã·ããšããŒã«é¡ã®ããã¯ç±³åœç¹èš±2735765å·ã
å3698909å·ãç¹å ¬æ49â20977å·ãå52â6623å·
ã«èšèŒãããŠãããâãªãã·ããšããŒã«èªå°äœ
ã®ããã¯ç±³åœç¹èš±3432300å·ãå3573050å·ãå
3574627å·ãå3764337å·ãç¹éæ52â35633å·ã
å52â147434å·ãå52â152225å·ã«èšèŒãããŠã
ãããã¹ããšããŒã«é¡ã®ããã¯ãç±³åœç¹èš±
3700455å·ã«èšèŒãããŠããã æ¬çºæã®æå ææã«ã¯èŠªæ°Žæ§ã³ãã€ãå±€ã«çŽ«å€
ç·åžåå€ãå«ãã§ãããããšãã°ã¢ãªãŒã«åºã§çœ®
æããããã³ãŸããªã¢ãŸãŒã«ååç©ïŒããšãã°ç±³
åœç¹èš±3533794å·ã«èšèŒã®ãã®ïŒãïŒâãã¢ãŸãªã
ã³ååç©ïŒããšãã°ç±³åœç¹èš±3314794å·ãå
3352681å·ã«èšèŒã®ãã®ïŒããã³ãŸããšãã³ååç©
ïŒããšãã°ç¹éæ46â2784å·ã«èšèŒã®ãã®ïŒãã±ã€
ãé žãšã¹ãã«ååç©ïŒããšãã°ç±³åœç¹èš±3705805
å·ãå3707375å·ã«èšèŒã®ãã®ïŒããããã¯ãã³ãŸ
ãªããµãŸãŒã«ååç©ïŒããšãã°ç±³åœç¹èš±3499762
å·ã«èšèŒã®ãã®ïŒãçšããããšãã§ããã玫å€ç·
åžåæ§ã®ã«ãã©ãŒïŒããšãã°Î±âããããŒã«ç³»ã®
ã·ã¢ã³è²çŽ 圢æã«ãã©ãŒïŒã玫å€ç·åžåæ§ã®ããª
ããŒãªã©ãçšããŠãããããããã®çŽ«å€ç·åžåå€
ã¯ç¹å®ã®å±€ã«åªæãããŠãããããŸãããããã®
玫å€ç·åžåå€ã¯æ¬çºæã®ã·ã¢ã³ããªããŒã«ãã©ãŒ
ãšåäžã®å±€ã«å«ãŸããŠãããã æ¬çºæã®æå ææã¯ãæè²æ§ãšçºè²æ§ãšãç°ã
ä¹³å€å±€ãéããŠæ¯æäœã«å¡åžãããŠããåãè¬ã
ãéå±€æ§æåã«ãããŠããç²åç¶ã«æ圢ãããæ
è²æ§ãšçºè²æ§ãšãç°ãä¹³å€ãæ··åããŠæ¯æäœã«å¡
åžãããŠããåãè¬ãããã¯ã¹ãã»ãã±ããåã«
ãããŠãå®çŸããããæ¬çºæã®æå ææã¯çš®ã ã®
圢ã«ãããŠå®çŸããããäŸãã°ã«ã©ãŒãã¬ãã€ã«
ã ãã«ã©ãŒããžãã€ã«ã ãã«ã©ãŒå転ãã€ã«ã ã
ã«ã©ãŒå°ç»çŽãã«ã©ãŒå転å°ç»çŽãªã©ãããã æ¬çºæã®ã«ã©ãŒåçæå ææã®è²çŽ ç»åãåŸã
çºã«ã¯ãé²å åŸãçŸååŠçãå¿ èŠã§ãããçŸååŠ
çãšã¯ãåºæ¬çã«ã¯ãçºè²çŸåïŒæŒçœïŒå®çå·¥çš
ãå«ãã§ããããã®å Žååå·¥çšãç¬ç«ããå Žå
ãããã®äžã®äºå·¥çšä»¥äžããããã®æ©èœãæã€ã
åŠç液ã䜿ã€ãŠãäžåã®åŠçã§æžãŸããŠããŸãå Ž
åãããããŸãåå·¥çšå ±å¿ èŠã«å¿ããŠïŒå以äžã«
åããŠåŠçããããšãã§ãããå°çŸååŠçå·¥çšã«
ã¯äžã®ã»ãå硬èãäžåã第äžçŸåïŒé»çœçŸåïŒã
å®å®åãæ°ŽæŽçã®è«žå·¥çšãå¿ èŠã«ãã€ãŠãçµåã
ããŠãããåŠç枩床ã¯ãæå ææãåŠçåŠæ¹ã«ã
ã€ãŠå¥œãŸããç¯å²ã«èšå®ããããäžè¬ã«ã¯ã18â
ãã60âã®éã«èšå®ãããããšãå€ãããªããäž
é£ã®åŠçåå·¥çšã®èšå®æž©åºŠãåäžã§ããå¿ èŠã¯ãª
ãã çºè²çŸå液ã¯ãã®é žåçæç©ãã«ãã©ãŒãšåŒã°
ããçºè²å€ãšåå¿ããŠçºè²çæç©ãäœãååç©ã
ãªãã¡çŸåäž»è¬ãå«ãPHãïŒä»¥äžã奜ãŸããã¯ïŒ
ã12ã®ã¢ã«ã«ãªæ°Žæº¶æ¶²ã§ãããäžèšçŸåäž»è¬ã¯è³
éŠæç°äžã«äžçŽã¢ããåºãæã¡é²å ãããããã²
ã³åéãçŸåããèœåã®ããååç©ãªããã¯ãã
ã®ãããªååç©ã圢æããåé§äœãæå³ãããã
ãšãã°ïŒâã¢ããâïŒïŒ®ãžãšãã«ã¢ããªã³ãïŒ
âã¡ãã«âïŒâã¢ããâïŒïŒ®âãžãšãã«ã¢ããª
ã³ãïŒâã¢ããââãšãã«ââβâãããã
ã·ãšãã«ã¢ããªã³ãïŒâã¡ãã«âïŒâã¢ããâ
âãšãã«ââβâããããã·ãšãã«ã¢ããªã³ïŒ
âã¢ããâïŒâã¡ãã«ââãšãã«ââβâã¡
ã¿ã³ã¹ã«ãã¢ãããšãã«ã¢ããªã³ãïŒâã¢ããâ
ïŒïŒ®âãžã¡ãã«ã¢ããªã³ãïŒâã¢ããâïŒâã¡
ããã·âïŒïŒ®âãžãšãã«ã¢ããªã³ãïŒâã¢ãã
âïŒâã¡ãã«ââãšãã«ââβâãšããã·ãš
ãã«ã¢ããªã³ãïŒâã¢ããâïŒâã¡ããã·ââ
ãšãã«ââβâã¡ããã·ãšãã«ã¢ããªã³ãïŒâ
ã¢ããâïŒâβâã¡ã¿ã³ã¹ã«ãã¢ãããšãã«â
ïŒïŒ®âãžãšãã«ã¢ãªã³ããã®å¡©ïŒããšãã°ç¡«é ž
å¡©ãå¡©é žå¡©ãäºç¡«é žå¡©ãïœâãã«ãšã³ã¹ã«ãã³é ž
å¡©ãªã©ïŒã奜ãŸãã代衚äŸãšããŠæããããŠã
ãããã®ä»ç±³åœç¹èš±ç¬¬2193015å·ãå2592364å·ã
ç¹éæ48â64933å·æãã¯L.F.A.Masonè
Photographic Processing ChemistryïŒFocal
PressâLondonç1966幎çºè¡ïŒã®226â229é T.
H.JamesèâThe Theory of the Photographic
ProcessâïŒMacMillanãNew York第ïŒç
ïŒ1977ïŒã®pp315â320ãªã©ã«ãèšãããŠããããŸ
ãâThe Theory of the Photographic
ProcessâïŒç¬¬ïŒçïŒã®pp311â315ãªã©ã«èšèŒã®
ã¢ããããšããŒã«é¡ãçšããŠããããããã«ãïŒ
âãã©ãŸãªãã³é¡ãšã®äœµçšãå¯èœã§ããã çºè²çŸå液ã«ã¯å¿ èŠã«å¿ããŠçš®ã ã®æ·»å å€ãå
ããããšãã§ããããã®äž»ãªäŸã«ã¯ãã¢ã«ã«ãªå€
ïŒããšãã°ã¢ã«ã«ãªéå±ãã¢ã³ã¢ããŠã ã®æ°Žé žå
ç©ãçé žå¡©ãçé žå¡©ïŒãPH調ç¯ãããã¯ç·©è¡å€
ïŒããšãã°é ¢é žãç¡Œé žã®ãããªåŒ±é žã匱塩åºãã
ããã®å¡©ïŒãçŸåä¿é²å€ïŒããšãã°ç±³åœç¹èš±
2648604å·ãå3671247å·çã«èšãããŠããåçš®ã®
ããªãžãŠã ååç©ãã«ããªã³æ§ã®ååç©é¡ãç¡é ž
ã«ãªãŠã ãç¡é žãããªãŠã ãç±³åœç¹èš±2533990å·ã
å2577127å·ãå2950970å·çã«èšãããŠãããã
ãªããªãšãã¬ã³ã°ãªã³ãŒã«çž®åç©ããã®èªå°äœ
é¡ãè±åœç¹èš±1020033å·ãå1020032å·ã®èšèŒã®å
åç©ã§ä»£è¡šãããŠãããããªããªããªãšãŒãã«é¡
ãªã©ã®ãããªã³æ§ååç©é¡ãç±³åœç¹èš±3068097å·
èšèŒã®ååç©ã§ä»£è¡šããããããªãµã«ãã¢ã€ããš
ã¹ãã«ããã€ããªããŒååç©ããã®ä»ããªãžã³ã
ãšã¿ããŒã«ã¢ãã³çææ©ã¢ãã³é¡ããã³ãžã«ã¢ã«
ã³ãŒã«ãããã©ãžã³é¡ãªã©ïŒãã«ããªé²æ¢å€ïŒã
ãšãã°èåã¢ã«ã«ãªããšãŒåã¢ã«ã«ãªãç±³åœç¹èš±
2496940å·ãå2656271å·ã«èšèŒã®ããããã³ãã€
ãããŸãŒã«é¡ãã¯ãããã¡ã«ã«ãããã³ãã€ãã
ãŸãŒã«ãïŒâã¡ãã«ãã³ãããªã¢ãŸãŒã«ãïŒâã
ãšãã«âïŒâã¡ã«ã«ããããã©ãŸãŒã«ãç±³åœç¹èš±
3113864å·ãå3342596å·ãå3295976å·ãå
3615522å·ãå3597199å·çã«èšèŒã®è¿ éåŠççšã®
ååç©é¡ãè±åœç¹èš±972211å·ã«èšèŒã®ããªã¹ã«ã
ãªãã«ååç©ãæãã¯ç¹å ¬æ46â41675å·ã«èšèŒ
ãããŠãããããªããšããžã³ïŒ®ãªãã·ãé¡ããã®
ä»ç§åŠåç䟿芧ãäžå·»ã29é ãã47é ã«èšèŒãã
ãŠãããã¶ãæå¶å€ãªã©ïŒããã®ã»ãç±³åœç¹èš±
3161513å·ãå3161514å·ãè±åœç¹èš±1030442å·ã
å1144481å·ãå1251558å·ãèšèŒã®ã¹ãã€ã³åã¯
ã¹ã©ããžé²æ¢å€ããŸãç±³åœç¹èš±3536487å·çã§ç¥
ãããŠããéå±€å¹æä¿é²å€ãä¿æå€ïŒããšãã°äº
ç¡«é žå¡©ãé žæ§äºç¡«é žå¡©ãããããã·ã«ã¢ãã³å¡©é ž
å¡©ããã«ã ãµã«ãã¢ã€ããã¢ã«ã«ããŒã«ã¢ãã³ãµ
ã«ãã¢ã€ãéå ç©ãªã©ïŒãããã æ¬çºæã®ã«ã©ãŒåçæå ææã¯çºè²çŸåã«å ç«
ã€å·¥çšãè¡ãªãããšãã§ããã ã«ã©ãŒå転ãã€ã«ã ã®ç¬¬äžçŸå液ãçºè²çŸåã«
å ç«ã€å·¥çšã§ããããã€ããããã³ãïŒâããšã«
âïŒâãã©ãŸãªãã³ãâã¡ãã«âïœâã¢ããã
ãšããŒã«çã®çŸåäž»è¬ãäžã€ä»¥äžå«ãã ã¢ã«ã«ãª
氎溶液ãçšããããŠãããä»ã«ç¡«é žãããªãŠã ç
ã®ç¡æ©å¡©é¡ãããŠç ãããŠé žãæ°Žé žåãããªãŠ
ã ãçé žãããªãŠã çã®PH調ç¯å€ãç·©è¡å€ããã
ã²ã³åã¢ã«ã«ãªïŒäŸãã°ãèåã«ãªãŠã ïŒããã®
ä»ã®çŸåã«ããªé²æ¢å€ãå«ãŸããŠããã äžèšååŠçå·¥çšã«ãããŠäŸç€ºããåæ·»å å€ãå
ã³ãã®æ·»å éã¯ã«ã©ãŒåçåŠçæ³ã«ãããŠããç¥
ãããŠããã çºè²çŸååŸãã«ã©ãŒåçææã¯éåžžæŒçœåã³å®
çããããæŒçœãšå®çãšãçµåããŠæŒçœå®ç济ãš
ããããšãã§ãããæŒçœå€ã«ã¯å€ãã®ååç©ãçš
ãããããããã®äžã§ãããšãªã·ã¢ã³é žå¡©é¡ãé
ã¯ãã é žå¡©ã氎溶æ§éïŒïŒå¡©ã氎溶æ§ã³ãã«ã
ïŒïŒå¡©ã氎溶æ§é ïŒïŒå¡©ã氎溶æ§ããã³é¡ã
ããããœããšããŒã«ãéïŒïŒãã³ãã«ãïŒïŒã
é ïŒïŒãªã©ã®å€äŸ¡ã«ããªã³ãšææ©é žã®é¯å¡©ãã
ãšãã°ãšãã¬ã³ãžã¢ãã³åé ¢é žããããªãããªé ¢
é žãã€ãããžé ¢é žãâããããã·ãšãã«ãšãã¬
ã³ãžã¢ãã³ããªé ¢é žã®ãããªã¢ããããªã«ã«ã³
é žãããã³é žãé ç³é žããªã³ãŽé žããžã°ãªã³ãŒã«
é žããžããªã°ãªã³ãŒã«é žãªã©ã®éå±é¯å¡©ãïŒïŒïŒ
âãžãã³ãªã³é žé é¯å¡©ãªã©ãéé žé¡ãããšãã°ã¢
ã«ãã«éé žãéç¡«é žå¡©ãéãã³ã¬ã³é žå¡©ãéé žå
æ°ŽçŽ ãªã©ã次äºå¡©çŽ é žå¡©ãå¡©çŽ ãèçŽ ããµã©ã·ç²
ãªã©ãã®åç¬ãããã¯é©åœãªçµã¿åããäžè¬çã§
ããããã®åŠç液ã«ã¯æŽã«ç±³åœç¹èš±3042520å·ã
å3241966å·ãç¹å ¬æ45â8506å·ãå45â8836å·
ãªã©ã«èšèŒã®æŒçœä¿é²å€ãã¯ãããçš®ã ã®æ·»å å€
ãå ããããšãã§ããã å®çã«ã¯åŸæ¥ããç¥ãããŠããå®ç液ã®ããã
ãã䜿çšã§ãããå³ã¡ãå®çå€ãšããŠã¯ãããªç¡«
é žã®ã¢ã³ã¢ããŠã ããããªãŠã ãã«ãªãŠã å¡©ã50
ã200ïœïŒã®çšåºŠã«çšãããããã®ä»ã«äºç¡«é ž
å¡©ãç°æ§éäºç¡«é žå¡©ãªã©ã®å®å®åå€ãã«ãªæã°ã
ãªã©ã®ç¡¬èå€ãé ¢é žå¡©ãããŠé žå¡©ãªã©ã®PHç·©è¡å€
ãªã©ãå«ãããšãã§ãããå®ç液ã¯PHïŒãã倧ã
ããåã¯ãã以äžã§ããã æŒçœæµŽãå®ç济åã³æŒçœå®ç济ã«ã€ããŠã¯ç±³åœ
ç¹èš±3582322å·ãç¹éæ48â101934å·ããã€ãç¹
蚱第1051117å·ãªã©ã«èšèŒã®æ¹æ³ãé©çšã§ããã å®æœäŸ ïŒ ããªãšãã¬ã³ã§äž¡é¢ã©ãããŒãããçŽæ¯æäœäž
ã«ã次ã®ç¬¬ïŒå±€ïŒæäžå±€ïŒã第ïŒå±€ïŒæäžå±€ïŒã
é 次å¡åžããŠã«ã©ãŒåçæå ææïŒè©ŠæïŒïŒãäœ
æãããïŒè¡šïŒïŒè¡šäžmgïŒm2ã¯å¡åžéãè¡šããïŒ
æ¬çºæã®ã·ã¢ã³ããªããŒã«ãã©ãŒã©ããã¯ã¹ã¯
åç¬ã§ãããã¯ïŒçš®ä»¥äžãæ··åããŠäœ¿çšã§ããã æ¬çºæã®ã·ã¢ã³ããªããŒã«ãã©ãŒã©ããã¯ã¹ã¯
ç±³åœç¹èš±4080211å·ã西ç¬ç¹èš±2725591ãç±³åœç¹èš±
3926436å·åã³Research Disclosure21728å·ãªã©
ã«èšèŒãããã·ã¢ã³ããªããŒã«ãã©ãŒã©ããã¯ã¹
ã䜵çšããããšãã§ããã ãŸããæ¬çºæã®ã·ã¢ã³ããªããŒã«ãã©ãŒã©ãã
ã¯ã¹ã«çæ°Žæ§ã·ã¢ã³çºè²ã«ãã©ãŒã®ããšããŒã«ã«
ãã©ãŒãããã³ããããŒã«ã«ãã©ãŒãããšãã°ã
ç±³åœç¹èš±2369929å·ãå2434272å·ãå2474293å·ã
å2521908ãå2895826å·ãå3034892å·ãå
3311476å·ãå3458315å·ãå3476563å·ãå
3583971ãå3591383å·ãå3767411å·ãå4004929
å·ã西ç¬ç¹èš±åºé¡2414830å·ãå2454329å·ãç¹é
æ48â59838ãå51â26034å·ãå48â5055å·ãå
51â146828å·ãå55â73050å·ã«èšèŒã®ã·ã¢ã³ã«
ãã©ãŒãç±³åœç¹èš±2269158å·ãå2272191å·ãå
2304940å·ãå2311020å·ãå2322027å·ãå
2360289å·ãå2772163å·ãå2801170å·ãå
2801171å·ãå3619195å·ãè±åœç¹èš±1151590å·ã
ç¬åœç¹èš±1143707å·ãªã©ã«èšèŒã®æ¹æ³ã§èŠªæ°Žæ§ã³
ãã€ãã«åæ£ããåæ£ç©ããç¹å ¬æ51â39853ãª
ã©ã«èšèŒã®æ¹æ³ã§å«æµžïŒããŒãïŒããŠäœ¿çšããã
ãšãã§ããããäžèšã®çæ°Žæ§ã·ã¢ã³ã«ãã©ãŒãæ¬
çºæã®ã·ã¢ã³ããªããŒã«ãã©ãŒã©ããã¯ã¹ã«ç¹é
æ51â59942ãå54â32552ãç±³åœç¹èš±4199363ãª
ã©ã«èšèŒã®æ¹æ³ã§å«æµžïŒããŒãïŒãããŠäœ¿çšãã
ããšãã§ãããããã§å«æµžïŒããŒãïŒãšã¯çæ°Žæ§
ã·ã¢ã³ã«ãã©ãŒãã·ã¢ã³ããªããŒã«ãã©ãŒã©ãã
ã¯ã¹å éšã«å«ãŸããç¶æ ããããã¯ã·ã¢ã³ã«ãã©
ãŒã©ããã¯ã¹è¡šé¢ã«æ²ç©ããŠããç¶æ ãæå³ã
ããããããå«æµžïŒããŒãïŒããããªãæ©æ§ã§èµ·
ãããã¯æ£ç¢ºã«ã¯ããã€ãŠããªãã æ¬çºæã®ã·ã¢ã³ããªããŒã«ãã©ãŒã©ããã¯ã¹ã«
æå ææã«æ±ããããç¹æ§ãæºè¶³ããããã«ç±³åœ
ç¹èš±3148062å·ãå3227554å·ãå3733201å·ãå
3617291å·ãå3703375å·ãå3615506å·ãå
3265506å·ãå3620745å·ãå3632345å·ãå
3869291å·ãå3642485å·ãå3770436å·ãå
3808945å·ãè±åœç¹èš±1201110å·ãå1236767å·ã
ãªã©ã«èšèŒã®çŸåæå¶å€æŸåºïŒDIRïŒã«ãã©ãŒã
ç±³åœç¹èš±2269158å·ãå2272191å·ãå2304940å·ã
å2311020å·ãå2322027å·ãå2360289å·ãå
2772163å·ãå2801170å·ãå2801171å·ãå
3619195å·ãè±åœç¹èš±1151590å·ãç¬åœç¹èš±
1143707å·ãªã©ã«èšèŒã®æ¹æ³ã§èŠªæ°Žæ§ã³ãã€ãã«
åæ£ããåæ£ç©ãç¹å ¬æ51â39853ãªã©ã«èšèŒã®
æ¹æ³ã§å«æµžããŠäœ¿çšããããšãã§ããããäžèšã®
ãããªDIRã«ãã©ãŒãã·ã¢ã³ããªããŒã«ãã©ãŒã©
ããã¯ã¹ã«ç¹éæ51â59942ãå54â32552ãç±³åœ
ç¹èš±4199363å·ãªã©ã«èšèŒã®æ¹æ³ã§å«æµžãããŠã
䜿çšããããšãã§ããã ãŸãç¬åœå ¬é2529350å·ãå2448063å·ãå
2610546å·ãç±³åœç¹èš±3928041å·ãå3958993å·ã
å3961959å·ãå4049455å·ãå4052213å·ãå
3379529å·ãå3043690å·ãå3364022å·ãå
3297445å·ãå3287129å·ããªã©ã«èšèŒã®DIRåå
ç©ã䜵çšããŠäœ¿çšããããšãã§ããã ãŸããç±³åœç¹èš±3876428å·ãå3580722å·ãå
2998314å·ãå2808329å·ãå2742832å·ãå
2689793å·ãªã©ã«èšèŒã®ç«¶äºã«ãã©ãŒãç±³åœç¹èš±
2336327å·ãå2728659å·ãå2336327å·ãå
2403721å·ãå2701197å·ãå3700453å·ãªã©ã«èš
èŒã®ã¹ãã€ã³é²æ¢å€ãè±åœç¹èš±1326889å·ãç±³åœ
ç¹èš±3432300å·ãå3698909å·ãå3574627å·ãå
3573050å·ãå3764337å·ãªã©ã«èšèŒã®è²çŽ åå®å®
å€ãªã©ãšäœµçšããããšãã§ããã æ¬çºæã䜿ã€ãŠã«ã©ãŒåçæå ææãäœãã«ã¯
ã·ã¢ã³åœ¢æã«ãã©ãŒä»¥å€ã®äžè¬ã«è¯ãç¥ãããã«
ãã©ãŒã䜿çšããããšãã§ããã ã«ãã©ãŒã¯ååäžã«ãã©ã¹ãåºãšåŒã°ããçæ°Ž
åºãæããéæ¡æ£æ§ã®ãã®ãæãŸãããã«ãã©ãŒ
ã¯éã€ãªã³ã«å¯ŸãïŒåœéæ§ãããã¯ïŒåœéæ§ã®ã©
ã¡ãã§ãããããŸãè²è£æ£ã®å¹æããã€ã«ã©ãŒ
ãã»ã«ãã©ãŒããããã¯çŸåã«ãšããªã€ãŠçŸåæ
å¶å€ãæŸåºããã«ãã©ãŒãå«ãã§ããããã«ãã©
ãŒã¯ã«ãããªã³ã°åå¿ã®çæç©ãç¡è²ã§ãããã
ãªã«ãã©ãŒã§ãããã é»è²çºè²ã«ãã©ãŒãšããŠã¯å ¬ç¥ã®ééã±ãã¡ã
ã¬ã³ç³»ã«ãã©ãŒãçšããããšãã§ããããããã®
ãã¡ãã³ãŸã€ã«ã¢ã»ãã¢ããªãç³»ããã³ãããã€
ã«ã¢ã»ãã¢ããªãç³»ååç©ã¯æå©ã§ãããçšãã
ãé»è²çºè²ã«ãã©ãŒã®å ·äœäŸã¯ãç±³åœç¹èš±
2875057å·ãå3265506å·ãå3408194å·ãå
3551155å·ãå3582322å·ãå3725072å·ãå
3891445å·ã西ç¬ç¹èš±1547868å·ã西ç¬åºé¡
2219917å·ãå2261361å·ãå2414006å·ãè±åœç¹
èš±1425020å·ãç¹å ¬æ51â10783å·ãç¹éæ47â
26133å·ãå48â73147å·ãå51â102636å·ãå50
â6341å·ãå50â123342å·ãå50â130442å·ãå
51â21827å·ãå50â87650å·ãªã©ã«èšèŒãããã
ã®ã§ããã ããŒã³ã¿çºè²ã«ãã©ãŒãšããŠã¯ãïŒâãã©ãŸã
ã³ã«ãã©ãŒããã©ãŸããã³ãã€ãããŸãŒã«ã«ãã©
ãŒãã·ã¢ãã¢ã»ãã«ã¯ããã³ã«ãã©ãŒãééã¢ã·
ã«ã¢ã»ããããªã«ã«ãã©ãŒçããããããšãã°ç±³
åœç¹èš±2600788å·ãå2983608å·ãå3062653å·ã
å3127269å·ãå3311476å·ãå3419391å·ãå
3519429å·ãå3558319å·ãå3582322å·ãå
3615506å·ãå3834908å·ãå3891445å·ã西ç¬ç¹
èš±1810464å·ã西ç¬ç¹èš±åºé¡ïŒOLSïŒ2408665å·ã
å2417945å·ãå2418959å·ãå2424467å·ãç¹å ¬
æ40â6031å·ãç¹éæ51â20826å·ãå52â58922
å·ãå49â129538å·ãå49â74027å·ãå50â
159336å·ãå52â42121å·ãå49â74028å·ãå50
â60233å·ãå51â26541å·ãå53â55122å·ããª
ã©ã«èšèŒããããã®ãããã äžèšã®ã«ãã©ãŒã¯åäžå±€ã«äºçš®ä»¥äžå«ãããšã
ã§ãããåäžååç©ãç°ãªãïŒä»¥äžã®å±€ã«å«ãã§
ãããã æ¬çºæã®ããªããŒã«ãã©ãŒã¯ã«ãã©ãŒåéäœã«
察å¿ããéšåãéïŒã¢ã«ã«å¯ŸããŠïŒÃ10-3ã¢ã«ãª
ããïŒÃ10-1ã¢ã«ã奜ãŸããã¯ïŒÃ10-2ãªããïŒ
Ã10-1ã¢ã«ã«ãªãããã«æ·»å ãããã äžèšã®ã«ãã©ãŒãããã²ã³åéä¹³å€å±€ã«å°å ¥ã
ãã«ã¯ãå ¬ç¥ã®æ¹æ³ããšãã°ç±³åœç¹èš±2322027å·
ã«èšèŒã®æ¹æ³ãªã©ãçšããããã«ãã©ãŒã芪氎æ§
ã³ãã€ãã«åæ£ããåŸã«ãããã²ã³åéä¹³å€ãšæ··
åãããã ã«ãã©ãŒãã«ã«ãã³é žãã¹ã«ããªã³é žã®ããšã
é žåºãæããå Žåã«ã¯ãã¢ã«ã«ãªæ§æ°Žæº¶æ¶²ãšããŠ
芪氎æ§ã³ãã€ãäžã«å°å ¥ãããã æ¬çºæã«äœ¿çšãããããã²ã³åéä¹³å€ã¯ãå¡©å
éãèåéã®ã»ãã«æ··åããã²ã³åéãããšãã°
å¡©èåéãæ²èåéãå¡©æ²èåéçãããªãããŒ
ã©ãã³ã®åŠã芪氎æ§é«ååäžã«åŸ®çŽ°ã«åæ£ããã
ãã®ã§ãããåäžãªç²åãµã€ãºããã€ãã®ããåº
ãç²åãµã€ãºååžããã€ãã®ãŸã§ããŸãå¹³åç²å
ãµã€ãºãçŽ0.1ãã¯ãã³ããçŽïŒãã¯ãã³ã«è³ã
åºç¯å²ãªåæ£ç¶æ ã«ãããã®ãæå ææã®äœ¿çšç®
çã«å¿ããŠéžæãããããããããã²ã³åéä¹³å€
ã¯ãäŸãã°ã·ã³ã°ã«ãããã¯ããã«ãžãšããæ³ã
ãããã¯ã³ã³ãããŒã«ããã«ãžãšããæ³çã®æ··å
æ³ã«ãã€ãŠãããã«äŸãã°ã¢ã³ã¢ãã¢æ³ãäžæ§
æ³ãé žæ§æ³çã®çææ¹æ³ã«ãã€ãŠèª¿è£œããåŸãã
ãŸããããããã²ã³åéä¹³å€ã¯ãç¡«é»å¢æãéå¢
æãéå å¢æã®åŠãååŠå¢æãåããŠããŠãã
ããããªãªãã·ãšãã¬ã³ååç©ããªããŠã ååç©
ã®ãããªæ床äžæå€ãå«æããŠããŠãããããŸã
æœåãäž»ãšããŠè¡šé¢ã«åœ¢æããåã®ä¹³å€ã°ããã§
ãªããŠãç²åå éšã«åœ¢æããå éšæœååã®ãã®ã
æ¬çºæã«äœ¿çšããããšãã§ããããŸãå¥ã ã«åœ¢æ
ããïŒçš®ä»¥äžã®ããã²ã³åéåçä¹³å€ãæ··åããŠ
ãããã æ¬çºæã®æå å±€ãæ§æãã芪氎æ§é«ååç©è³ªãš
ããŠã¯ããŒã©ãã³ã®åŠãèçœè³ªãããªããã«ã¢ã«
ã³ãŒã«ãããªããã«ãããªãã³ãããªã¢ã¯ãªã«ã¢
ããã®åŠãé«ååéé»è§£è³ªãã¢ã«ã®ã³é žå¡©ãããª
ã¢ã¯ãªã«é žå¡©ã®åŠãé žæ§é«ååç©è³ªããããã³è»¢
äœåå¿ã«ãã€ãŠåŠçããããªã¢ã¯ãªã«ã¢ãããã¢
ã¯ãªã«é žãšïŒ®âããã«ã€ãããŸãŒã«ã®å ±éåç©ã®
åŠãé«ååäž¡æ§é»è§£è³ªãUS.4215195ã«èšèŒã®æ¶
æ©æ§ããªããŒãªã©ãé©ããŠããããŸããããé£ç¶
çžããªã芪氎æ§é«ååç©è³ªã¯ãåæ£ãããçæ°Žæ§
é«ååç©è³ªãäŸãã°ããªã¢ã¯ãªã«é žããã«ãšã¹ã
ã«çã®ã©ããã¯ã¹ãå«ãã§ããŠãããã æ¬çºæã«çšããããããã²ã³åéåçä¹³å€ã¯ã
ãŸãåžžæ³ã«ãã€ãŠååŠå¢æãããããšãã§ããã
ååŠå¢ææã«ã¯ããšãã°ç±³åœç¹èš±2399083å·ãå
2540085å·ãå2597856å·ãå2597915å·ã«ç€ºãã
ããããªå¡©åéé žéãäžå¡©åéãªã©éååç©ãç±³
åœç¹èš±2448060å·ãå2540086ãå2556245å·ãå
2566263å·ãå2598079å·ã«ç€ºããããããªçœéã
ãã©ãžãŠã ãã€ãªãžãŠã ãããžãŠã ãã«ãããŠã
ã®ãããªè²Žéå±ã®å¡©é¡ãç±³åœç¹èš±1574944å·ãå
2410689å·ãå3189458å·ãå3501313å·çã«èšèŒ
ãããŠãããããªãéå¡©ãšåå¿ããŠç¡«åéã圢æ
ããã€ãªãŠååç©ãç±³åœç¹èš±2487850å·ãå
2518698å·ãå2521925å·ãå2521926å·ãå
2694637å·ãå2983610å·ãå3201254å·ã«èšèŒã
ããŠãããããªç¬¬äžã¹ãºå¡©ãã¢ãã³é¡ããã®ä»ã®
éå æ§ç©è³ªãªã©ããããããã æ¬çºæã®åçä¹³å€ã«ã¯æå ææã®è£œé å·¥çšãä¿
åäžæãã¯åŠçäžã®æ床äœäžãã«ããªã®çºçãé²
ãããã«çš®ã ã®ååç©ãæ·»å ããããšãã§ããã
ãããã®ååç©ã¯ïŒâããããã·âïŒâã¡ãã«â
ïŒïŒïŒïŒ3aïŒïŒâããã©ã¶ã€ã³ãã³ãïŒâã¡ã
ã«ãã³ãŸãã¢ãŸãŒã«ãïŒâããšãã«âïŒâã¡ã«ã«
ããããã©ãŸãŒã«ãã¯ãããå€ãã®è€çŽ ç°åå
ç©ãå«æ°Žéååç©ãã¡ã«ã«ããååç©ãéå±å¡©é¡
ãªã©æ¥µããŠå€ãã®ååç©ãå€ãããç¥ãããŠã
ãã 䜿çšã§ããååç©ã®äžäŸã¯ãK.MeesèâThe
Theory of the Photographic ProcessâïŒç¬¬ïŒ
çã1966幎ïŒã«åæç®ãæããŠèšãããŠããã»ã
次ã®ç¹èš±ã«ãèšãããŠãããç±³åœç¹èš±1758576å·ã
å2110178å·ãå2131038å·ãå2173628å·ãå
2697040å·ãå2304962å·ãå2324123å·ãå
2394198å·ãå2444605ãïŒå·ãå2566245å·ãå
2694716å·ãå2697099å·ãå2708162å·ãå
2728663ãïŒå·ãå2476536å·ãå2824001å·ãå
2843491å·ãå2886437å·ãå3052544å·ãå
3137577å·ãå3220839å·ãå3226231å·ãå
3236652å·ãå3251691å·ãå3252799å·ãå
3287135å·ãå3326681å·ãå3420668å·ãå
3622339å·ãè±åœç¹èš±893428å·ãå403789å·ãå
1173609å·ãå1200188å·ã æ¬çºæã®åçä¹³å€ã«ã¯çé¢æŽ»æ§å€ãåç¬ãŸãã¯
æ··åããŠæ·»å ããŠãããããããã¯å¡åžå©å€ãšã
ãŠçšãããããã®ã§ããããæãšããŠãã®ä»ã®ç®
çãããšãã°ä¹³ååæ£ãå¢æã垯é»é²æ¢ãæ¥çé²
æ¢ãªã©ã®ããã«ãé©çšãããã ãããã®çé¢æŽ»æ§å€ã¯ãµããã³ãªã©ã®å€©ç¶çé¢
掻æ§å€ãã¢ã«ãã¬ã³ãªããµã€ãç³»ãã°ãªã»ãªã³
ç³»ãã°ãªã·ããŒã«ç³»ãªã©ã®ãããªã³çé¢æŽ»æ§å€ã
é«çŽã¢ã«ãã«ã¢ãã³é¡ã第ïŒçŽã¢ã³ã¢ããŠã å¡©
é¡ãããªãžã³ãã®ä»ã®è€çŽ ç°é¡ããã¹ãããŠã å
ã¯ã¹ã«ãããŠã é¡ãªã©ã®ã«ããªã³çé¢æŽ»æ§å€ãã«
ã«ãã³é žãã¹ã«ãã³é žãçé žãç¡«é žãšã¹ãã«åºã
çé žãšã¹ãã«åºçã®é žæ§åºãå«ãã¢ããªã³çé¢æŽ»
æ§å€ãã¢ããé žé¡ãã¢ããã¹ã«ãã³é¡ãã¢ããã¢
ã«ã³ãŒã«ã®ç¡«é žãŸãã¯çé žãšã¹ãã«é¡çã®äž¡æ§æŽ»
æ§å€ã«ãããããã ããã䜿çšãåŸãçé¢æŽ»æ§å€ååç©äŸã®äžéšã¯
ç±³åœç¹èš±2271623å·ãå2240472å·ãå2288226å·ã
å2739891å·ãå3068101å·ãå3158484å·ãå
3201253å·ãå3210191å·ãå3294540å·ãå
3415649å·ãå3441413å·ãå3442654å·ãå
3475174å·ãå3545974å·ã西ãã€ãç¹èš±å ¬é
1942665å·ãè±åœç¹èš±1077317å·ãå1198450å·ã
ã¯ãããå°ç°è¯å¹³ä»èãçé¢æŽ»æ§å€ã®åæãšãã®
å¿çšãïŒæ§æžåº1964幎çïŒããã³A.W.ããªã€è
ããµãŒããšã¹ ã¢ã¯ãã€ã ãšãŒãžãšã³ããïŒã€ã³
ã¿ãŒãµã€ãšã³ã¹ ãããªã±ãŒã·ãšã³ ã€ã³ã³ãŒã
ã¬ãŒãã€ã1958幎çïŒãJ.P.ã·ã¹ãªãŒèããšã³ãµ
ã€ã¯ãããã€ã¢ ãªã ãµãŒããšã¹ ã¢ã¯ãã€ã
ãšãŒãžãšã³ã第ïŒå·»ãïŒã±ãã«ã«ãããªãã·ã
ã«ã³ãããŒ1964幎çïŒãªã©ã®ææžã«èšèŒãããŠã
ãã åçä¹³å€ã¯ã·ã¢ãã³ãã¡ãã·ã¢ãã³ãã«ã«ãã·
ã¢ã³çã®ã·ã¢ãã³è²çŽ é¡ã®åç¬ãããã¯çµåã䜿
çšãŸãã¯ããããšã¹ããªã«ææçãšã®çµåã䜿çš
ã«ãã€ãŠåå æ床ã匷è²å¢æãè¡ãããšãã§ã
ãã ãããã®è²å¢ææè¡ã¯å€ãããç¥ãããŠããã
ç±³åœç¹èš±2688545å·ãå2912329å·ãå3397060å·ã
å3615635å·ãå3628964å·ãè±åœç¹èš±1195302å·ã
å1242588å·ãå1293862å·ã西ãã€ãç¹èš±å ¬é
2030326å·ãå2121780å·ãç¹å ¬æ43â4936å·ãå
44â14030å·ããªã©ã«ãèšèŒãããããã®éžæã¯
å¢æãã¹ãæ³¢é·åãæ床çæå ææã®ç®çãçšé
ã«å¿ããŠä»»æã«å®ããããšãã§ããã æ¬çºæã«äœ¿çšãããæå ææã®èŠªæ°Žæ§ã³ãã€ã
å±€ãç¹ã«ãŒã©ãã³å±€ã¯åçš®ã®æ¶æ©å€ã«ãã€ãŠç¡¬è
ããããšãã§ãããäŸãã°ã¯ãã å¡©ããžã«ã³ããŠ
ã å¡©ã®ãããªç¡æ©ååç©ïŒã ã³ã¯ããŒã«é žãªãã
ç¹å ¬æ46â1872å·ã«èšèŒãããŠããïŒâããšãã
ã·âïŒâã¯ãã«ãã¬ã¢ã«ãããé žã®åŠãã¢ã«ãã
ãç³»ååç©ãå€ãã®å Žåæ¬çºæã«æçšã§ãããã
ç¹å ¬æ34â7133å·ã«èšèŒãããŠããè€æ°åã®ãšã
ãã·ç°ãæããååç©ãç¹å ¬æ37â8790ã«èšèŒã
ããŠããããªãŒïŒïŒâã¢ãžãªãžã«ïŒååç©ã䞊ã³
ã«ç±³åœç¹èš±3362827å·ã3325287å·ã«èšèŒãããŠã
ã掻æ§ããã²ã³ååç©ãç±³åœç¹èš±2994611å·ãå
3582322å·ããã«ã®ãŒç¹èš±ç¬¬686440å·ãªã©ã§ç¥ã
ããŠããããã«ã¹ã«ãã³ç³»ååç©ãªã©ã®éã¢ã«ã
ããç³»æ¶æ©å€ã¯ãæ¬çºæã«äœ¿çšããæå ææã«äœ¿
çšããã®ã«ç¹ã«é©ããŠããã æ¬çºæã®ããã²ã³åéåçä¹³å€ã¯ãå€ãã®å Žå
æ¯æäœäžã«çœ®ãããŠãããæ¯æäœãšããŠã¯ãç®ç
ã«å¿ããŠã¬ã©ã¹ãéå±ãé¶åšã®ãããªç¡¬ããã®
ãããã®ä»ã®å¯ææ§ã®ãã®ã䜿çšããããå¯ææ§
æ¯æäœã®ä»£è¡šçãªäŸãšããŠã¯ãã»ã«ããŒãºãã€ã
ã¬ãŒããã€ã«ã ãã»ã«ããŒãºã¢ã»ããŒããã€ã«
ã ãããªããã«ã¢ã»ã¿ãŒã«ãã€ã«ã ãããªã¹ãã¬
ã³ãã€ã«ã ãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããã€ã«
ã ãããªã«ãŒãããŒããã€ã«ã åã³ãããã®ç©å±€
ç©çãããããã©ã€ã¿ãŸãã¯Î±âãªã¬ãã€ã³ããª
ããŒç¹ã«ããªãšãã¬ã³ãããªãããã¬ã³ããšãã¬
ã³ããã³ã³ããªããŒçã«ãã€ãŠè¢«èŠãããçŽãç¹
å ¬æ47â19068ã«ç€ºãããŠãããããªç²é¢åãã
è¡šé¢ããã€ãã©ã¹ããã¯ãã€ã«ã ãæå©ã«äœ¿çšã
ããããããã®æ¯æäœã¯ãæå ææã®ç®çã«å¿ã
ãŠãéæãªãã®ãææãé¡æãæ·»å ããŠçè²ãã
ãã®ããã¿ã³ãã¯ã€ãçãæ·»å ããŠäžéæåãã
ãã®ãã«ãŒãã³ãã©ãã¯çãæ·»å ããŠé®å æ§ã«ã
ããã®çããéžæã§ããã åçæå ææã®åå±€ã¯ãã€ããã³ãŒãããšã¢ãŒ
ãã€ãã³ãŒããã«ãŒãã³ã³ãŒãããããã¯ç±³åœç¹
èš±2681294å·ã«èšèŒã®ããããŒã䜿çšãããšã¯ã¹
ãã«âãžãšã³ã³ãŒããå«ãçš®ã ã®å¡åžæ³ã«ãã€ãŠ
å¡åžããããšãã§ãããå¿ èŠã«å¿ããŠãç±³åœç¹èš±
2761791å·ãå3508947å·åã³å2941898å·ãå
3526528å·ãªã©ã«èšèŒã®æ¹æ³ã«ããïŒçš®åã¯ãã
以äžã®å±€ãåæã«å¡åžããããšãã§ããã ã«ãã©ãŒãããã²ã³åéä¹³å€å±€ã«å°å ¥ããã«ã¯
å ¬ç¥ã®æ¹æ³ããšãã°ç±³åœç¹èš±2322027å·ã«èšèŒã®
æ¹æ³ãªã©ãçšãããããããšãã°ãã¿ãŒã«é žã¢ã«
ãã«ãšã¹ãã«ïŒãžããã«ãã¿ã¬ãŒãããžãªã¯ãã«
ãã¿ã¬ãŒããªã©ïŒããªã³é žãšã¹ãã«ïŒãžããšãã«
ããªã¹ããšãŒããããªããšãã«ããªã¹ããšãŒãã
ããªã¯ã¬ãžã«ããªã¹ããšãŒãããžãªã¯ãã«ããã«
ããªã¹ããšãŒãïŒãã¯ãšã³é žãšã¹ãã«ïŒããšãã°
ã¢ã»ãã«ã¯ãšã³é žããªããã«ïŒãå®æ¯éŠé žãšã¹ã
ã«ïŒããšãã°å®æ¯éŠé žãªã¯ãã«ïŒãã¢ã«ãã«ã¢ã
ãïŒããšãã°ãžãšãã«ã©ãŠãªã«ã¢ããïŒãèèªé ž
ãšã¹ãã«é¡ïŒããšãã°ãžãããã·ãšãã«ãŒã¯ã·ã
ãŒãããžãªã¯ãã«ã¢ãŒã¬ãŒãïŒãããªã¡ã·ã³é žãš
ã¹ãã«é¡ïŒããšãã°ããªã¡ã·ã³é žããªããã«ïŒãª
ã©ããŸãã¯æ²žç¹çŽ30âä¹è³150âã®ææ©æº¶åªãã
ãšãã°é ¢é žãšãã«ãé ¢é žããã«ã®ããšãäœçŽã¢ã«
ãã«ã¢ã»ããŒããããããªã³é žãšãã«ãïŒçŽãã
ã«ã¢ã«ã³ãŒã«ãã¡ãã«ã€ãœããã«ã±ãã³ãβâãš
ããã·ãšãã«ã¢ã»ããŒããã¡ãã«ã»ããœã«ãã¢ã»
ããŒãçã«æº¶è§£ããã®ã¡ã芪氎æ§ã³ãã€ãã«åæ£
ããããäžèšã®é«æ²žç¹ææ©æº¶åªãšäœæ²žç¹ææ©æº¶åª
ãšãæ··åããŠçšããŠãããã ãŸãç¹å ¬æ51â39853å·ãç¹éæ51â59943å·ã«
èšèŒãããŠããéåç©ã«ããåæ£æ³ã䜿çšããã
ãšãã§ããã ã«ãã©ãŒãã«ã«ãã³é žãã¹ã«ããªã³é žã®ããšã
é žåºãæããå Žåã«ã¯ãã¢ã«ã«ãªæ§æ°Žæº¶æ¶²ãšããŠ
芪氎æ§ã³ãã€ãäžã«å°å ¥ãããã æ¬çºæãå®æœäŸããã«éããŠäžèšã®å ¬ç¥ã®éè²
é²æ¢å€ã䜵çšããããšãã§ãããŸãæ¬çºæã«çšã
ãè²åå®å®å€ã¯åç¬ãŸãã¯ïŒçš®ä»¥äžäœµçšããããš
ãã§ãããå ¬ç¥ã®éè²é²æ¢å€ãšããŠã¯ããã€ãã
ããã³èªå°äœæ²¡é£åé žèªå°äœãâã¢ã«ã³ãã·ã
ãšããŒã«é¡ãâãªãã·ããšããŒã«èªå°äœåã³ã
ã¹ããšããŒã«é¡çãããã ãã€ããããã³èªå°äœã®å ·äœäŸã¯ç±³åœç¹èš±ç¬¬
2360290å·ãå2418613å·ãå2675314å·ãå
2701197å·ãå2704713å·ãå2728659å·ãå
2732300å·ãå2735765å·ãå2710801å·ãå
2816028å·ãè±åœç¹èš±1363921å·ãçã«èšèŒãããŠ
ããã没é£åé žèªå°äœã®ããã«ç±³åœç¹èš±3457079
å·ãå3069262å·çã«èšèŒãããŠãããâã¢ã«
ã³ãã·ããšããŒã«é¡ã®ããã¯ç±³åœç¹èš±2735765å·ã
å3698909å·ãç¹å ¬æ49â20977å·ãå52â6623å·
ã«èšèŒãããŠãããâãªãã·ããšããŒã«èªå°äœ
ã®ããã¯ç±³åœç¹èš±3432300å·ãå3573050å·ãå
3574627å·ãå3764337å·ãç¹éæ52â35633å·ã
å52â147434å·ãå52â152225å·ã«èšèŒãããŠã
ãããã¹ããšããŒã«é¡ã®ããã¯ãç±³åœç¹èš±
3700455å·ã«èšèŒãããŠããã æ¬çºæã®æå ææã«ã¯èŠªæ°Žæ§ã³ãã€ãå±€ã«çŽ«å€
ç·åžåå€ãå«ãã§ãããããšãã°ã¢ãªãŒã«åºã§çœ®
æããããã³ãŸããªã¢ãŸãŒã«ååç©ïŒããšãã°ç±³
åœç¹èš±3533794å·ã«èšèŒã®ãã®ïŒãïŒâãã¢ãŸãªã
ã³ååç©ïŒããšãã°ç±³åœç¹èš±3314794å·ãå
3352681å·ã«èšèŒã®ãã®ïŒããã³ãŸããšãã³ååç©
ïŒããšãã°ç¹éæ46â2784å·ã«èšèŒã®ãã®ïŒãã±ã€
ãé žãšã¹ãã«ååç©ïŒããšãã°ç±³åœç¹èš±3705805
å·ãå3707375å·ã«èšèŒã®ãã®ïŒããããã¯ãã³ãŸ
ãªããµãŸãŒã«ååç©ïŒããšãã°ç±³åœç¹èš±3499762
å·ã«èšèŒã®ãã®ïŒãçšããããšãã§ããã玫å€ç·
åžåæ§ã®ã«ãã©ãŒïŒããšãã°Î±âããããŒã«ç³»ã®
ã·ã¢ã³è²çŽ 圢æã«ãã©ãŒïŒã玫å€ç·åžåæ§ã®ããª
ããŒãªã©ãçšããŠãããããããã®çŽ«å€ç·åžåå€
ã¯ç¹å®ã®å±€ã«åªæãããŠãããããŸãããããã®
玫å€ç·åžåå€ã¯æ¬çºæã®ã·ã¢ã³ããªããŒã«ãã©ãŒ
ãšåäžã®å±€ã«å«ãŸããŠãããã æ¬çºæã®æå ææã¯ãæè²æ§ãšçºè²æ§ãšãç°ã
ä¹³å€å±€ãéããŠæ¯æäœã«å¡åžãããŠããåãè¬ã
ãéå±€æ§æåã«ãããŠããç²åç¶ã«æ圢ãããæ
è²æ§ãšçºè²æ§ãšãç°ãä¹³å€ãæ··åããŠæ¯æäœã«å¡
åžãããŠããåãè¬ãããã¯ã¹ãã»ãã±ããåã«
ãããŠãå®çŸããããæ¬çºæã®æå ææã¯çš®ã ã®
圢ã«ãããŠå®çŸããããäŸãã°ã«ã©ãŒãã¬ãã€ã«
ã ãã«ã©ãŒããžãã€ã«ã ãã«ã©ãŒå転ãã€ã«ã ã
ã«ã©ãŒå°ç»çŽãã«ã©ãŒå転å°ç»çŽãªã©ãããã æ¬çºæã®ã«ã©ãŒåçæå ææã®è²çŽ ç»åãåŸã
çºã«ã¯ãé²å åŸãçŸååŠçãå¿ èŠã§ãããçŸååŠ
çãšã¯ãåºæ¬çã«ã¯ãçºè²çŸåïŒæŒçœïŒå®çå·¥çš
ãå«ãã§ããããã®å Žååå·¥çšãç¬ç«ããå Žå
ãããã®äžã®äºå·¥çšä»¥äžããããã®æ©èœãæã€ã
åŠç液ã䜿ã€ãŠãäžåã®åŠçã§æžãŸããŠããŸãå Ž
åãããããŸãåå·¥çšå ±å¿ èŠã«å¿ããŠïŒå以äžã«
åããŠåŠçããããšãã§ãããå°çŸååŠçå·¥çšã«
ã¯äžã®ã»ãå硬èãäžåã第äžçŸåïŒé»çœçŸåïŒã
å®å®åãæ°ŽæŽçã®è«žå·¥çšãå¿ èŠã«ãã€ãŠãçµåã
ããŠãããåŠç枩床ã¯ãæå ææãåŠçåŠæ¹ã«ã
ã€ãŠå¥œãŸããç¯å²ã«èšå®ããããäžè¬ã«ã¯ã18â
ãã60âã®éã«èšå®ãããããšãå€ãããªããäž
é£ã®åŠçåå·¥çšã®èšå®æž©åºŠãåäžã§ããå¿ èŠã¯ãª
ãã çºè²çŸå液ã¯ãã®é žåçæç©ãã«ãã©ãŒãšåŒã°
ããçºè²å€ãšåå¿ããŠçºè²çæç©ãäœãååç©ã
ãªãã¡çŸåäž»è¬ãå«ãPHãïŒä»¥äžã奜ãŸããã¯ïŒ
ã12ã®ã¢ã«ã«ãªæ°Žæº¶æ¶²ã§ãããäžèšçŸåäž»è¬ã¯è³
éŠæç°äžã«äžçŽã¢ããåºãæã¡é²å ãããããã²
ã³åéãçŸåããèœåã®ããååç©ãªããã¯ãã
ã®ãããªååç©ã圢æããåé§äœãæå³ãããã
ãšãã°ïŒâã¢ããâïŒïŒ®ãžãšãã«ã¢ããªã³ãïŒ
âã¡ãã«âïŒâã¢ããâïŒïŒ®âãžãšãã«ã¢ããª
ã³ãïŒâã¢ããââãšãã«ââβâãããã
ã·ãšãã«ã¢ããªã³ãïŒâã¡ãã«âïŒâã¢ããâ
âãšãã«ââβâããããã·ãšãã«ã¢ããªã³ïŒ
âã¢ããâïŒâã¡ãã«ââãšãã«ââβâã¡
ã¿ã³ã¹ã«ãã¢ãããšãã«ã¢ããªã³ãïŒâã¢ããâ
ïŒïŒ®âãžã¡ãã«ã¢ããªã³ãïŒâã¢ããâïŒâã¡
ããã·âïŒïŒ®âãžãšãã«ã¢ããªã³ãïŒâã¢ãã
âïŒâã¡ãã«ââãšãã«ââβâãšããã·ãš
ãã«ã¢ããªã³ãïŒâã¢ããâïŒâã¡ããã·ââ
ãšãã«ââβâã¡ããã·ãšãã«ã¢ããªã³ãïŒâ
ã¢ããâïŒâβâã¡ã¿ã³ã¹ã«ãã¢ãããšãã«â
ïŒïŒ®âãžãšãã«ã¢ãªã³ããã®å¡©ïŒããšãã°ç¡«é ž
å¡©ãå¡©é žå¡©ãäºç¡«é žå¡©ãïœâãã«ãšã³ã¹ã«ãã³é ž
å¡©ãªã©ïŒã奜ãŸãã代衚äŸãšããŠæããããŠã
ãããã®ä»ç±³åœç¹èš±ç¬¬2193015å·ãå2592364å·ã
ç¹éæ48â64933å·æãã¯L.F.A.Masonè
Photographic Processing ChemistryïŒFocal
PressâLondonç1966幎çºè¡ïŒã®226â229é T.
H.JamesèâThe Theory of the Photographic
ProcessâïŒMacMillanãNew York第ïŒç
ïŒ1977ïŒã®pp315â320ãªã©ã«ãèšãããŠããããŸ
ãâThe Theory of the Photographic
ProcessâïŒç¬¬ïŒçïŒã®pp311â315ãªã©ã«èšèŒã®
ã¢ããããšããŒã«é¡ãçšããŠããããããã«ãïŒ
âãã©ãŸãªãã³é¡ãšã®äœµçšãå¯èœã§ããã çºè²çŸå液ã«ã¯å¿ èŠã«å¿ããŠçš®ã ã®æ·»å å€ãå
ããããšãã§ããããã®äž»ãªäŸã«ã¯ãã¢ã«ã«ãªå€
ïŒããšãã°ã¢ã«ã«ãªéå±ãã¢ã³ã¢ããŠã ã®æ°Žé žå
ç©ãçé žå¡©ãçé žå¡©ïŒãPH調ç¯ãããã¯ç·©è¡å€
ïŒããšãã°é ¢é žãç¡Œé žã®ãããªåŒ±é žã匱塩åºãã
ããã®å¡©ïŒãçŸåä¿é²å€ïŒããšãã°ç±³åœç¹èš±
2648604å·ãå3671247å·çã«èšãããŠããåçš®ã®
ããªãžãŠã ååç©ãã«ããªã³æ§ã®ååç©é¡ãç¡é ž
ã«ãªãŠã ãç¡é žãããªãŠã ãç±³åœç¹èš±2533990å·ã
å2577127å·ãå2950970å·çã«èšãããŠãããã
ãªããªãšãã¬ã³ã°ãªã³ãŒã«çž®åç©ããã®èªå°äœ
é¡ãè±åœç¹èš±1020033å·ãå1020032å·ã®èšèŒã®å
åç©ã§ä»£è¡šãããŠãããããªããªããªãšãŒãã«é¡
ãªã©ã®ãããªã³æ§ååç©é¡ãç±³åœç¹èš±3068097å·
èšèŒã®ååç©ã§ä»£è¡šããããããªãµã«ãã¢ã€ããš
ã¹ãã«ããã€ããªããŒååç©ããã®ä»ããªãžã³ã
ãšã¿ããŒã«ã¢ãã³çææ©ã¢ãã³é¡ããã³ãžã«ã¢ã«
ã³ãŒã«ãããã©ãžã³é¡ãªã©ïŒãã«ããªé²æ¢å€ïŒã
ãšãã°èåã¢ã«ã«ãªããšãŒåã¢ã«ã«ãªãç±³åœç¹èš±
2496940å·ãå2656271å·ã«èšèŒã®ããããã³ãã€
ãããŸãŒã«é¡ãã¯ãããã¡ã«ã«ãããã³ãã€ãã
ãŸãŒã«ãïŒâã¡ãã«ãã³ãããªã¢ãŸãŒã«ãïŒâã
ãšãã«âïŒâã¡ã«ã«ããããã©ãŸãŒã«ãç±³åœç¹èš±
3113864å·ãå3342596å·ãå3295976å·ãå
3615522å·ãå3597199å·çã«èšèŒã®è¿ éåŠççšã®
ååç©é¡ãè±åœç¹èš±972211å·ã«èšèŒã®ããªã¹ã«ã
ãªãã«ååç©ãæãã¯ç¹å ¬æ46â41675å·ã«èšèŒ
ãããŠãããããªããšããžã³ïŒ®ãªãã·ãé¡ããã®
ä»ç§åŠåç䟿芧ãäžå·»ã29é ãã47é ã«èšèŒãã
ãŠãããã¶ãæå¶å€ãªã©ïŒããã®ã»ãç±³åœç¹èš±
3161513å·ãå3161514å·ãè±åœç¹èš±1030442å·ã
å1144481å·ãå1251558å·ãèšèŒã®ã¹ãã€ã³åã¯
ã¹ã©ããžé²æ¢å€ããŸãç±³åœç¹èš±3536487å·çã§ç¥
ãããŠããéå±€å¹æä¿é²å€ãä¿æå€ïŒããšãã°äº
ç¡«é žå¡©ãé žæ§äºç¡«é žå¡©ãããããã·ã«ã¢ãã³å¡©é ž
å¡©ããã«ã ãµã«ãã¢ã€ããã¢ã«ã«ããŒã«ã¢ãã³ãµ
ã«ãã¢ã€ãéå ç©ãªã©ïŒãããã æ¬çºæã®ã«ã©ãŒåçæå ææã¯çºè²çŸåã«å ç«
ã€å·¥çšãè¡ãªãããšãã§ããã ã«ã©ãŒå転ãã€ã«ã ã®ç¬¬äžçŸå液ãçºè²çŸåã«
å ç«ã€å·¥çšã§ããããã€ããããã³ãïŒâããšã«
âïŒâãã©ãŸãªãã³ãâã¡ãã«âïœâã¢ããã
ãšããŒã«çã®çŸåäž»è¬ãäžã€ä»¥äžå«ãã ã¢ã«ã«ãª
氎溶液ãçšããããŠãããä»ã«ç¡«é žãããªãŠã ç
ã®ç¡æ©å¡©é¡ãããŠç ãããŠé žãæ°Žé žåãããªãŠ
ã ãçé žãããªãŠã çã®PH調ç¯å€ãç·©è¡å€ããã
ã²ã³åã¢ã«ã«ãªïŒäŸãã°ãèåã«ãªãŠã ïŒããã®
ä»ã®çŸåã«ããªé²æ¢å€ãå«ãŸããŠããã äžèšååŠçå·¥çšã«ãããŠäŸç€ºããåæ·»å å€ãå
ã³ãã®æ·»å éã¯ã«ã©ãŒåçåŠçæ³ã«ãããŠããç¥
ãããŠããã çºè²çŸååŸãã«ã©ãŒåçææã¯éåžžæŒçœåã³å®
çããããæŒçœãšå®çãšãçµåããŠæŒçœå®ç济ãš
ããããšãã§ãããæŒçœå€ã«ã¯å€ãã®ååç©ãçš
ãããããããã®äžã§ãããšãªã·ã¢ã³é žå¡©é¡ãé
ã¯ãã é žå¡©ã氎溶æ§éïŒïŒå¡©ã氎溶æ§ã³ãã«ã
ïŒïŒå¡©ã氎溶æ§é ïŒïŒå¡©ã氎溶æ§ããã³é¡ã
ããããœããšããŒã«ãéïŒïŒãã³ãã«ãïŒïŒã
é ïŒïŒãªã©ã®å€äŸ¡ã«ããªã³ãšææ©é žã®é¯å¡©ãã
ãšãã°ãšãã¬ã³ãžã¢ãã³åé ¢é žããããªãããªé ¢
é žãã€ãããžé ¢é žãâããããã·ãšãã«ãšãã¬
ã³ãžã¢ãã³ããªé ¢é žã®ãããªã¢ããããªã«ã«ã³
é žãããã³é žãé ç³é žããªã³ãŽé žããžã°ãªã³ãŒã«
é žããžããªã°ãªã³ãŒã«é žãªã©ã®éå±é¯å¡©ãïŒïŒïŒ
âãžãã³ãªã³é žé é¯å¡©ãªã©ãéé žé¡ãããšãã°ã¢
ã«ãã«éé žãéç¡«é žå¡©ãéãã³ã¬ã³é žå¡©ãéé žå
æ°ŽçŽ ãªã©ã次äºå¡©çŽ é žå¡©ãå¡©çŽ ãèçŽ ããµã©ã·ç²
ãªã©ãã®åç¬ãããã¯é©åœãªçµã¿åããäžè¬çã§
ããããã®åŠç液ã«ã¯æŽã«ç±³åœç¹èš±3042520å·ã
å3241966å·ãç¹å ¬æ45â8506å·ãå45â8836å·
ãªã©ã«èšèŒã®æŒçœä¿é²å€ãã¯ãããçš®ã ã®æ·»å å€
ãå ããããšãã§ããã å®çã«ã¯åŸæ¥ããç¥ãããŠããå®ç液ã®ããã
ãã䜿çšã§ãããå³ã¡ãå®çå€ãšããŠã¯ãããªç¡«
é žã®ã¢ã³ã¢ããŠã ããããªãŠã ãã«ãªãŠã å¡©ã50
ã200ïœïŒã®çšåºŠã«çšãããããã®ä»ã«äºç¡«é ž
å¡©ãç°æ§éäºç¡«é žå¡©ãªã©ã®å®å®åå€ãã«ãªæã°ã
ãªã©ã®ç¡¬èå€ãé ¢é žå¡©ãããŠé žå¡©ãªã©ã®PHç·©è¡å€
ãªã©ãå«ãããšãã§ãããå®ç液ã¯PHïŒãã倧ã
ããåã¯ãã以äžã§ããã æŒçœæµŽãå®ç济åã³æŒçœå®ç济ã«ã€ããŠã¯ç±³åœ
ç¹èš±3582322å·ãç¹éæ48â101934å·ããã€ãç¹
蚱第1051117å·ãªã©ã«èšèŒã®æ¹æ³ãé©çšã§ããã å®æœäŸ ïŒ ããªãšãã¬ã³ã§äž¡é¢ã©ãããŒãããçŽæ¯æäœäž
ã«ã次ã®ç¬¬ïŒå±€ïŒæäžå±€ïŒã第ïŒå±€ïŒæäžå±€ïŒã
é 次å¡åžããŠã«ã©ãŒåçæå ææïŒè©ŠæïŒïŒãäœ
æãããïŒè¡šïŒïŒè¡šäžmgïŒm2ã¯å¡åžéãè¡šããïŒ
ãè¡šã
ãè¡šã
è©ŠæïŒã®ã·ã¢ã³ã«ãã©ãŒçšæº¶åªãé€ããä»ã¯è©Š
æïŒãšåæ§ã«ããŠè©ŠæïŒãäœæããããŸãè©ŠæïŒ
ã®ã·ã¢ã³ã«ãã©ãŒã次åŒïŒãïŒãïŒã®æ§é ã®èŠªæ²¹
æ§ã·ã¢ã³ããªããŒã«ãã©ãŒã®ã©ããã¯ã¹400mgïŒ
m2ã«ããä»ã¯è©ŠæïŒãšåæ§ã«ããŠè©ŠæïŒãïŒãã
ã³ïŒãäœæããã æŽã«ã·ã¢ã³ã«ãã©ãŒãæ¬çºæã®è£œé äŸã®èŠªæ²¹æ§
ã·ã¢ã³ããªããŒã«ãã©ãŒA400mgïŒm2ã®ã©ããã¯
ã¹ãããã³ããªããŒã«ãã©ãŒã©ããã¯ã¹400
mgïŒm2ïŒéåäœééïŒã«ãããä»ã¯è©ŠæïŒãšåæ§
ã«ããŠè©ŠæïŒããã³ïŒãäœæããã åè©Šæã«é£ç¶ãŠãšããžãä»ããŠèµ€è²å é²å ãäž
ãã以äžã®åŠçå·¥çšã«ããçŸååŠçããã åŠçå·¥çš çºè²çŸå 33â ïŒå30ç§ æŒçœå®ç 33â ïŒå30ç§ æ°Ž æŽ 30â ïŒå 也 ç¥ çºè²çŸå液çµæ ãã³ãžã«ã¢ã«ã³ãŒã« 15ml äºç¡«é žãããªãŠã ïŒïœ èåã«ãªãŠã 0.4ïœ ããããã·ã«ã¢ãã³ç¡«é žå¡© ïŒïœ ïŒâïŒïŒ®âãšãã«ââβâã¡ã¿ã³ã¹ã«ãã³ã¢
ããïŒâïŒâã¡ãã«ã¢ããªã³ã»ã»ã¹ãç¡«é žå¡©ïŒïœ çé žãããªãŠã ïŒïŒæ°Žå¡©ïŒ 30ïœ æ°Žãå ããŠ1000ml PH10.1 æŒçœå®ç液çµæ ãšãã¬ã³ãžã¢ãã³ïŒé ¢é žç¬¬ïŒéå¡© 45ïœ äºç¡«é žãããªãŠã 10ïœ ããªç¡«é žã¢ã³ã¢ããŠã 70ïŒ æ°Žæº¶æ¶² 160ml ãšãã¬ã³ãžã¢ãã³ïŒé ¢é žïŒãããªãŠã å¡© ïŒïœ æ°Žãå ããŠ1000ml PH6.8 çŸååŠçããåè©Šæã®çºè²æ¿åºŠã枬å®ãããå
è©Šæã®ã«ããªãã¬ã³ããæé«æ¿åºŠãè¡šïŒã«ç€ºãã
æïŒãšåæ§ã«ããŠè©ŠæïŒãäœæããããŸãè©ŠæïŒ
ã®ã·ã¢ã³ã«ãã©ãŒã次åŒïŒãïŒãïŒã®æ§é ã®èŠªæ²¹
æ§ã·ã¢ã³ããªããŒã«ãã©ãŒã®ã©ããã¯ã¹400mgïŒ
m2ã«ããä»ã¯è©ŠæïŒãšåæ§ã«ããŠè©ŠæïŒãïŒãã
ã³ïŒãäœæããã æŽã«ã·ã¢ã³ã«ãã©ãŒãæ¬çºæã®è£œé äŸã®èŠªæ²¹æ§
ã·ã¢ã³ããªããŒã«ãã©ãŒA400mgïŒm2ã®ã©ããã¯
ã¹ãããã³ããªããŒã«ãã©ãŒã©ããã¯ã¹400
mgïŒm2ïŒéåäœééïŒã«ãããä»ã¯è©ŠæïŒãšåæ§
ã«ããŠè©ŠæïŒããã³ïŒãäœæããã åè©Šæã«é£ç¶ãŠãšããžãä»ããŠèµ€è²å é²å ãäž
ãã以äžã®åŠçå·¥çšã«ããçŸååŠçããã åŠçå·¥çš çºè²çŸå 33â ïŒå30ç§ æŒçœå®ç 33â ïŒå30ç§ æ°Ž æŽ 30â ïŒå 也 ç¥ çºè²çŸå液çµæ ãã³ãžã«ã¢ã«ã³ãŒã« 15ml äºç¡«é žãããªãŠã ïŒïœ èåã«ãªãŠã 0.4ïœ ããããã·ã«ã¢ãã³ç¡«é žå¡© ïŒïœ ïŒâïŒïŒ®âãšãã«ââβâã¡ã¿ã³ã¹ã«ãã³ã¢
ããïŒâïŒâã¡ãã«ã¢ããªã³ã»ã»ã¹ãç¡«é žå¡©ïŒïœ çé žãããªãŠã ïŒïŒæ°Žå¡©ïŒ 30ïœ æ°Žãå ããŠ1000ml PH10.1 æŒçœå®ç液çµæ ãšãã¬ã³ãžã¢ãã³ïŒé ¢é žç¬¬ïŒéå¡© 45ïœ äºç¡«é žãããªãŠã 10ïœ ããªç¡«é žã¢ã³ã¢ããŠã 70ïŒ æ°Žæº¶æ¶² 160ml ãšãã¬ã³ãžã¢ãã³ïŒé ¢é žïŒãããªãŠã å¡© ïŒïœ æ°Žãå ããŠ1000ml PH6.8 çŸååŠçããåè©Šæã®çºè²æ¿åºŠã枬å®ãããå
è©Šæã®ã«ããªãã¬ã³ããæé«æ¿åºŠãè¡šïŒã«ç€ºãã
ãè¡šã
è¡šãããããããã«ãæ¯èŒäŸã®èŠªæ²¹æ§ã·ã¢ã³ã
ãªããŒã«ãã©ãŒã®ã©ããã¯ã¹ãå«ãè©ŠæïŒã¯çºè²
ãäžååã§ããããæ¬çºæã®èŠªæ²¹æ§ã·ã¢ã³ããªã
ãŒã«ãã©ãŒã®ã©ããã¯ã¹ãå«ãè©ŠæïŒãïŒã¯è¯å¥œ
ãªçºè²æ§ã瀺ããŠããã 次ã«çŸååŠçåŸã®è©ŠæïŒãïŒã80âã»ãŒä¹Ÿç¥é°
å²æ°äžã«ïŒé±éä¿ååŸã®ã·ã¢ã³è²ç»åã®åæ¿åºŠ
ïŒD1.0ãD2.0ïŒã«å¯Ÿããæ¿åºŠäœäžçãè¡šïŒã«ç€ºãã
ãªããŒã«ãã©ãŒã®ã©ããã¯ã¹ãå«ãè©ŠæïŒã¯çºè²
ãäžååã§ããããæ¬çºæã®èŠªæ²¹æ§ã·ã¢ã³ããªã
ãŒã«ãã©ãŒã®ã©ããã¯ã¹ãå«ãè©ŠæïŒãïŒã¯è¯å¥œ
ãªçºè²æ§ã瀺ããŠããã 次ã«çŸååŠçåŸã®è©ŠæïŒãïŒã80âã»ãŒä¹Ÿç¥é°
å²æ°äžã«ïŒé±éä¿ååŸã®ã·ã¢ã³è²ç»åã®åæ¿åºŠ
ïŒD1.0ãD2.0ïŒã«å¯Ÿããæ¿åºŠäœäžçãè¡šïŒã«ç€ºãã
ãè¡šã
ãè¡šã
è¡šïŒã«ãããŠæ¿åºŠäœäžçïŒïŒ
ïŒãäœãã»ã©ç±å
ç¢æ§ãåªããŠããããšã瀺ããããã«ããå€ãã
ãã«æ¬çºæã®ã·ã¢ã³ã«ãã©ãŒã¯æ¯èŒäŸè©ŠæïŒãïŒ
ã«ããã¹ç±å ç¢æ§ãèããè¯å¥œã§ããã å®æœäŸ ïŒ äžé ¢é žã»ã«ããŒãºæ¯æäœäžã«ã次ã®ç¬¬ïŒå±€ïŒæ
äžå±€ïŒã第ïŒå±€ïŒæäžå±€ïŒãå¡åžããŠå€å±€ã«ã©ãŒ
æå ãã€ã«ã ïŒè©ŠæïŒïŒãäœæãããïŒè¡šäžmgïŒ
m2ã¯å¡åžéãè¡šãããïŒïŒè¡šïŒïŒ
ç¢æ§ãåªããŠããããšã瀺ããããã«ããå€ãã
ãã«æ¬çºæã®ã·ã¢ã³ã«ãã©ãŒã¯æ¯èŒäŸè©ŠæïŒãïŒ
ã«ããã¹ç±å ç¢æ§ãèããè¯å¥œã§ããã å®æœäŸ ïŒ äžé ¢é žã»ã«ããŒãºæ¯æäœäžã«ã次ã®ç¬¬ïŒå±€ïŒæ
äžå±€ïŒã第ïŒå±€ïŒæäžå±€ïŒãå¡åžããŠå€å±€ã«ã©ãŒ
æå ãã€ã«ã ïŒè©ŠæïŒïŒãäœæãããïŒè¡šäžmgïŒ
m2ã¯å¡åžéãè¡šãããïŒïŒè¡šïŒïŒ
ãè¡šã
ãè¡šã
è©ŠæïŒã®ã·ã¢ã³ã«ãã©ãŒçšæº¶åªãé€ããä»ã¯è©Š
æïŒãšåæ§ã«ããŠè©ŠæïŒãäœæãããæŽã«è©ŠæïŒ
ã®ã·ã¢ã³ã«ãã©ãŒãäžèšã®æ§é ã®èŠªæ²¹æ§ã·ã¢ã³ã
ãªããŒã«ãã©ãŒ1500mgïŒm2ã«å€æŽããã»ãã¯è©Šæ
ïŒãšåæ§ã«ããŠè©Šæ10ãäœæããã æŽã«è©Šæ10ã®èŠªæ²¹æ§ã·ã¢ã³ããªããŒã«ãã©ãŒã®
ã©ããã¯ã¹ãæ¬çºæã®è£œæ³äŸã®èŠªæ²¹æ§ã·ã¢ã³ããª
ããŒã«ãã©ãŒïŒïŒ®ïŒ1500mgïŒm2ãïŒïŒ£ïŒ1500mgïŒ
m2ãïŒïŒ¯ïŒ1500mgïŒm2ã®ã©ããã¯ã¹ãããã³ããª
ããŒã«ãã©ãŒã©ããã¯ã¹1500mgïŒm2ã«ãããŠè©Š
æ11ã12ã13ããã³14ãäœæããã åè©Šæãã€ã«ã ã«é£ç¶ãŠãšããžãéããŠãéè²
å ã»ç·è²å ã»èµ€è²å ã®é²å ãäžããäžèšã®çŸååŠ
çãæœããã çŸååŠçå·¥çš çºè²çŸå 36â ïŒå å æ¢ 36â 40ç§ ç¬¬äžå®ç 36â 40ç§ æŒ çœ 36â ïŒå 第äºå®ç 36â 40ç§ æ°Ž æŽ 30â 30ç§ çºè²çŸå液çµæ äºç¡«é žãããªãŠã ïŒïœ ïŒâã¢ããâïŒâã¡ãã«âïŒïŒ®âãžãšãã«ã¢
ãªã³ ïŒïœ çé žãããªãŠã 20ïœ èåã«ãªãŠã ïŒïœ æ°Žãå ããŠ ïŒ PH10.5 åæ¢æ¶²çµæ ç¡«é žïŒ6NïŒ 50ml æ°Žãå ããŠ ïŒ PH1.0 å®ç液çµæ ããªç¡«é žã¢ã³ã¢ãŠã 60ïœ äºç¡«é žãããªãŠã ïŒïœ äºç¡«é žæ°ŽçŽ ãããªãŠã 10ïœ æ°Žãå ããŠ ïŒ PH5.8 æŒçœæ¶²çµæ ããšãªã·ã¢ã³åã«ãªãŠã 30ïœ èåã«ãªãŠã 15ïœ æ°Žãå ããŠ ïŒ PH6.5 çŸååŠçåŸã®åè©Šæã®èµ€è²é²å éšåã®çºè²æ¿åºŠ
ã枬å®ãããåè©Šæã®ã«ããªãã¬ã³ããæé«æ¿åºŠ
ãè¡šïŒã«ç€ºãã ãŸãçŸååŠçåŸã®è©ŠæïŒã14ã80âã»ãŒä¹Ÿç¥é°
å²æ°äžã«ïŒé±éä¿åããåŸã®ã·ã¢ã³è²ç»åã®åæ¿
床ïŒD1.0ãD2.0ïŒã«å¯Ÿããæ¿åºŠäœäžçãè¡šïŒã«ç€º
ãã
æïŒãšåæ§ã«ããŠè©ŠæïŒãäœæãããæŽã«è©ŠæïŒ
ã®ã·ã¢ã³ã«ãã©ãŒãäžèšã®æ§é ã®èŠªæ²¹æ§ã·ã¢ã³ã
ãªããŒã«ãã©ãŒ1500mgïŒm2ã«å€æŽããã»ãã¯è©Šæ
ïŒãšåæ§ã«ããŠè©Šæ10ãäœæããã æŽã«è©Šæ10ã®èŠªæ²¹æ§ã·ã¢ã³ããªããŒã«ãã©ãŒã®
ã©ããã¯ã¹ãæ¬çºæã®è£œæ³äŸã®èŠªæ²¹æ§ã·ã¢ã³ããª
ããŒã«ãã©ãŒïŒïŒ®ïŒ1500mgïŒm2ãïŒïŒ£ïŒ1500mgïŒ
m2ãïŒïŒ¯ïŒ1500mgïŒm2ã®ã©ããã¯ã¹ãããã³ããª
ããŒã«ãã©ãŒã©ããã¯ã¹1500mgïŒm2ã«ãããŠè©Š
æ11ã12ã13ããã³14ãäœæããã åè©Šæãã€ã«ã ã«é£ç¶ãŠãšããžãéããŠãéè²
å ã»ç·è²å ã»èµ€è²å ã®é²å ãäžããäžèšã®çŸååŠ
çãæœããã çŸååŠçå·¥çš çºè²çŸå 36â ïŒå å æ¢ 36â 40ç§ ç¬¬äžå®ç 36â 40ç§ æŒ çœ 36â ïŒå 第äºå®ç 36â 40ç§ æ°Ž æŽ 30â 30ç§ çºè²çŸå液çµæ äºç¡«é žãããªãŠã ïŒïœ ïŒâã¢ããâïŒâã¡ãã«âïŒïŒ®âãžãšãã«ã¢
ãªã³ ïŒïœ çé žãããªãŠã 20ïœ èåã«ãªãŠã ïŒïœ æ°Žãå ããŠ ïŒ PH10.5 åæ¢æ¶²çµæ ç¡«é žïŒ6NïŒ 50ml æ°Žãå ããŠ ïŒ PH1.0 å®ç液çµæ ããªç¡«é žã¢ã³ã¢ãŠã 60ïœ äºç¡«é žãããªãŠã ïŒïœ äºç¡«é žæ°ŽçŽ ãããªãŠã 10ïœ æ°Žãå ããŠ ïŒ PH5.8 æŒçœæ¶²çµæ ããšãªã·ã¢ã³åã«ãªãŠã 30ïœ èåã«ãªãŠã 15ïœ æ°Žãå ããŠ ïŒ PH6.5 çŸååŠçåŸã®åè©Šæã®èµ€è²é²å éšåã®çºè²æ¿åºŠ
ã枬å®ãããåè©Šæã®ã«ããªãã¬ã³ããæé«æ¿åºŠ
ãè¡šïŒã«ç€ºãã ãŸãçŸååŠçåŸã®è©ŠæïŒã14ã80âã»ãŒä¹Ÿç¥é°
å²æ°äžã«ïŒé±éä¿åããåŸã®ã·ã¢ã³è²ç»åã®åæ¿
床ïŒD1.0ãD2.0ïŒã«å¯Ÿããæ¿åºŠäœäžçãè¡šïŒã«ç€º
ãã
ãè¡šã
ãè¡šã
ãè¡šã
è¡šïŒãïŒãããããããã«ãæ¬çºæã®è©Šæ11ã
14ã¯æ¯èŒäŸã®è©ŠæïŒã10ã«ããã¹çºè²æ§ã»ç±å ç¢
æ§ãšãã«è¯å¥œã§ããããšããããã å®æœäŸ ïŒ å®æœäŸïŒã®è©ŠæïŒããã³ïŒãšåäžã®æ§æã§è©Šæ
15ããã³16ãäœæããããŸãè©Šæ16ã®ã·ã¢ã³ã«ã
ã©ãŒã®ãããã«äžèšã®æ§é ã®èŠªæ²¹æ§ã·ã¢ã³ããªã
ãŒã«ãã©ãŒã®ã©ããã¯ã¹ã䜿çšããŠè©Šæ17ãäœæ
ããã æŽã«è©Šæ17ã®èŠªæ²¹æ§ã·ã¢ã³ããªããŒã«ãã©ãŒã®
ã©ããã¯ã¹ã®ãããã«æ¬çºæã®è£œæ³äŸã®èŠªæ²¹æ§ã·
ã¢ã³ããªããŒã«ãã©ãŒH400mgïŒm2ãB400mgïŒ
m2ã400mgïŒm2ã®ã©ããã¯ã¹ã«ãããŠè©Šæ18ïŒ
19ããã³20ãäœæããã åè©Šæã«é£ç¶ãŠãšããžãéããŠèµ€è²å é²å ãäž
ããå®æœäŸïŒãšåãåŠçå·¥çšã«ããçŸååŠçã
ãã çŸååŠçåŸã®è©Šæ15ã20ã80âã»ãŒä¹Ÿç¥é°å²æ°
äžã«ïŒé±éä¿ååŸã®ã·ã¢ã³è²ç»åã®åæ¿åºŠïŒD1.
0ãD2.0ïŒã«å¯Ÿããæ¿åºŠäœäžçãè¡šïŒã«ç€ºãã
14ã¯æ¯èŒäŸã®è©ŠæïŒã10ã«ããã¹çºè²æ§ã»ç±å ç¢
æ§ãšãã«è¯å¥œã§ããããšããããã å®æœäŸ ïŒ å®æœäŸïŒã®è©ŠæïŒããã³ïŒãšåäžã®æ§æã§è©Šæ
15ããã³16ãäœæããããŸãè©Šæ16ã®ã·ã¢ã³ã«ã
ã©ãŒã®ãããã«äžèšã®æ§é ã®èŠªæ²¹æ§ã·ã¢ã³ããªã
ãŒã«ãã©ãŒã®ã©ããã¯ã¹ã䜿çšããŠè©Šæ17ãäœæ
ããã æŽã«è©Šæ17ã®èŠªæ²¹æ§ã·ã¢ã³ããªããŒã«ãã©ãŒã®
ã©ããã¯ã¹ã®ãããã«æ¬çºæã®è£œæ³äŸã®èŠªæ²¹æ§ã·
ã¢ã³ããªããŒã«ãã©ãŒH400mgïŒm2ãB400mgïŒ
m2ã400mgïŒm2ã®ã©ããã¯ã¹ã«ãããŠè©Šæ18ïŒ
19ããã³20ãäœæããã åè©Šæã«é£ç¶ãŠãšããžãéããŠèµ€è²å é²å ãäž
ããå®æœäŸïŒãšåãåŠçå·¥çšã«ããçŸååŠçã
ãã çŸååŠçåŸã®è©Šæ15ã20ã80âã»ãŒä¹Ÿç¥é°å²æ°
äžã«ïŒé±éä¿ååŸã®ã·ã¢ã³è²ç»åã®åæ¿åºŠïŒD1.
0ãD2.0ïŒã«å¯Ÿããæ¿åºŠäœäžçãè¡šïŒã«ç€ºãã
ãè¡šã
ãè¡šã
è¡šãããããããã«æ¬çºæã®è©Šæ18ã20ã¯æ¯èŒ
äŸã®è©Šæ15ã17ã«ããã¹è¯å¥œãªç±å ç¢æ§ã瀺ãã
ãšããããã
äŸã®è©Šæ15ã17ã«ããã¹è¯å¥œãªç±å ç¢æ§ã瀺ãã
ãšããããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ è³éŠæäžçŽã¢ãã³çŸåè¬ã®é žåäœãšã«ãããª
ã³ã°ããŠææã圢æãããäžèšäžè¬åŒããã«å¯Ÿ
å¿ããã·ã¢ã³ã«ãã©ãŒåéäœã®å埩åäœãäžè¬åŒ
ããã«å¯Ÿå¿ããé žæåãå«æãããšãã¬ã³æ§äž
飜ååéäœã®å埩åäœããã³ã¡ãã«ã¢ã¯ãªã¬ãŒã
ã®å埩åäœã®å°ãªããšãïŒã€ãå埩åäœãšããŠæ
ããã·ã¢ã³è²çŽ 圢æããªããŒã«ãã©ãŒã®ã©ããã¯
ã¹ãä¹³å€å±€äžã«å«æããããã²ã³åéåçæå æ
æã ïŒåŒäžR1ã¯æ°ŽçŽ ååãççŽ ïŒãïŒåã®äœçŽã¢
ã«ãã«åºãŸãã¯å¡©çŽ ãè¡šãããã¯é žåãããè³
éŠæäžçŽã¢ãã³çŸåè¬ãšã«ãããªã³ã°ããŠã·ã¢ã³
ææã圢æãããã·ã¢ã³ã«ãã©ãŒæ®åºãè¡šãããïŒ ïŒåŒäžR2ã¯æ°ŽçŽ ååãççŽ æ°ïŒãïŒåã®äœçŽ
ã¢ã«ãã«åºãŸãã¯å¡©çŽ ãè¡šãããã¯âCOOâ
ãŸãã¯âCONHâãè¡šãããã¯ççŽ æ°ïŒã10
åã®ã¢ã«ãã¬ã³åºãããã¯ã¢ã©ã«ãã¬ã³åºãŸãã¯
ççŽ æ°ïŒã10ã®ããšãã¬ã³åºãè¡šãããã¢ã«ãã¬
ã³åºã¯çŽéã§ããåå²éã§ãç°ç¶ã§ããããã¯
âCOOMãŸãã¯âSO3Mãè¡šããããã ãïŒã¯æ°Ž
çŽ ååã€ãªã³ãã¢ã«ã«ãªéå±ã€ãªã³ãã¢ã«ã«ãªå
é¡éå±ã€ãªã³ãŸãã¯ã¢ã³ã¢ããŠã ã€ãªã³ãè¡šã
ããïœã¯ïŒãŸãã¯ïŒãè¡šããã
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57196575A JPS5986048A (ja) | 1982-11-09 | 1982-11-09 | ããã²ã³åéã«ã©âåçæå ææ |
| GB08329711A GB2133170B (en) | 1982-11-09 | 1983-11-07 | Silver halide color photographic material containing polymeric cyan-forming coupler |
| DE19833340376 DE3340376A1 (de) | 1982-11-09 | 1983-11-08 | Lichtempfindliches farbphotographisches silberhalogenidmaterial |
| US06/549,947 US4511647A (en) | 1982-11-09 | 1983-11-09 | Silver halide color photographic light-sensitive material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57196575A JPS5986048A (ja) | 1982-11-09 | 1982-11-09 | ããã²ã³åéã«ã©âåçæå ææ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5986048A JPS5986048A (ja) | 1984-05-18 |
| JPH0239781B2 true JPH0239781B2 (ja) | 1990-09-07 |
Family
ID=16360017
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57196575A Granted JPS5986048A (ja) | 1982-11-09 | 1982-11-09 | ããã²ã³åéã«ã©âåçæå ææ |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4511647A (ja) |
| JP (1) | JPS5986048A (ja) |
| DE (1) | DE3340376A1 (ja) |
| GB (1) | GB2133170B (ja) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS615249A (ja) * | 1984-06-19 | 1986-01-11 | Konishiroku Photo Ind Co Ltd | ããã²ã³åéã«ã©âåçæå ææ |
| JPS6139045A (ja) * | 1984-07-31 | 1986-02-25 | Fuji Photo Film Co Ltd | ããã²ã³åéã«ã©âåçæå ææ |
| US4755296A (en) * | 1985-03-21 | 1988-07-05 | Occidental Chemical Corporation | Integrated biological-adsorption process for treating waste water |
| JPS6291947A (ja) * | 1985-10-18 | 1987-04-27 | Fuji Photo Film Co Ltd | ããã²ã³åéã«ã©âåçæå ææ |
| JPH077201B2 (ja) * | 1985-10-19 | 1995-01-30 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | ããã²ã³åéã«ã©âåçæå ææã®åŠçæ¹æ³ |
| DE3608744A1 (de) * | 1986-03-15 | 1987-09-17 | Agfa Gevaert Ag | Polymerer purpurkuppler und farbfotografisches aufzeichnungsmaterial, das diesen polymeren purpurkuppler enthaelt |
| JPH07111567B2 (ja) * | 1987-03-25 | 1995-11-29 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | ããã²ã³åéã«ã©ãŒåçæå ææã®åŠçæ¹æ³ |
| GB8729197D0 (en) * | 1987-12-15 | 1988-01-27 | Ciba Geigy Ag | Preparation of polymeric colour couplers |
| US5237030A (en) * | 1988-05-06 | 1993-08-17 | Eastman Kodak Company | Polymeric couplers prepared in the presence of a coupler solvent |
| EP0357069B1 (en) * | 1988-09-01 | 1995-10-25 | Eastman Kodak Company | Color photographic elements with polymeric couplers |
| US5234807A (en) * | 1991-11-21 | 1993-08-10 | Eastman Kodak Company | Microemulsion polymerization - processes for dispersing photographically useful components |
| US5360710A (en) * | 1992-05-06 | 1994-11-01 | Eastman Kodak Company | Color photographic materials containing polymeric couplers |
| US5354642A (en) * | 1992-08-10 | 1994-10-11 | Eastman Kodak Company | Polymeric couplers for heat image separation systems |
| EP0690344A1 (en) | 1994-06-29 | 1996-01-03 | Konica Corporation | Silver halide color photographic light-sensitive material |
| US5620838A (en) * | 1994-12-21 | 1997-04-15 | Eastman Kodak Company | Photographic elements containing directly dispersible UV absorbing polymers and method of making such elements and polymers |
| DE19755810A1 (de) * | 1997-12-16 | 1999-06-17 | Agfa Gevaert Ag | Farbfotografisches Silberhalogenidmaterial |
| DE10111655A1 (de) * | 2001-03-12 | 2002-10-02 | Agfa Gevaert Ag | Inkjet-Tinte |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1453057A (en) * | 1973-02-26 | 1976-10-20 | Agfa Gevaert | Polymeric colour forming and competing couplers |
| DE3064831D1 (en) * | 1979-10-15 | 1983-10-20 | Agfa Gevaert Nv | Copolymer latex and photographic silver halide materials containing such latex |
| US4438278A (en) * | 1980-06-09 | 1984-03-20 | Eastman Kodak Company | Polymerizable ethylenically unsaturated amide compounds |
-
1982
- 1982-11-09 JP JP57196575A patent/JPS5986048A/ja active Granted
-
1983
- 1983-11-07 GB GB08329711A patent/GB2133170B/en not_active Expired
- 1983-11-08 DE DE19833340376 patent/DE3340376A1/de not_active Withdrawn
- 1983-11-09 US US06/549,947 patent/US4511647A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| GB2133170B (en) | 1986-01-15 |
| US4511647A (en) | 1985-04-16 |
| JPS5986048A (ja) | 1984-05-18 |
| GB8329711D0 (en) | 1983-12-07 |
| DE3340376A1 (de) | 1984-05-10 |
| GB2133170A (en) | 1984-07-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4435503A (en) | Silver halide color photographic light-sensitive material | |
| JPS6116064B2 (ja) | ||
| JPH0239781B2 (ja) | ||
| JPS6148700B2 (ja) | ||
| JPS61169831A (ja) | æå æ§å®å®ååçèšé²ææ | |
| US4455366A (en) | Silver halide color photographic light-sensitive material | |
| US4388404A (en) | Silver halide color photographic light-sensitive material | |
| JPH0318702B2 (ja) | ||
| US4474870A (en) | Silver halide color photographic light-sensitive material | |
| JPS6365140B2 (ja) | ||
| US4444870A (en) | Silver halide color photographic light-sensitive material | |
| JPH0619524B2 (ja) | çºæ±çŸè±¡åã³ã¹ã¿ããã¯ãâã¯çºçãé²æ¢ããããã²ã³åéåçæå ææ | |
| US4496650A (en) | Silver halide color photographic light-sensitive material | |
| US4495272A (en) | Silver halide color photographic light-sensitive material | |
| JPH0239780B2 (ja) | ||
| JPS5814668B2 (ja) | ã·ã€ã·ã³ãšãŠã²ã³ãŸãŠã€ã¯ | |
| US4416978A (en) | Silver halide color photographic light-sensitive material | |
| JPS6157618B2 (ja) | ||
| JPH0248099B2 (ja) | Harogenkaginkaraakankozairyo | |
| JPH0322972B2 (ja) | ||
| JPS6355543A (ja) | çºæ±çŸè±¡åã³ã¹ã¿ããã¯ãâã¯çºçãé²æ¢ããããã²ã³åéåçæå ææ | |
| JPS6037459B2 (ja) | åççšã·ã¢ã³ã«ãã©â | |
| JPH0231374B2 (ja) | Harogenkaginkaraakankozairyo | |
| JPS63121846A (ja) | ããã²ã³åéã«ã©âåçæå ææ | |
| JPS6127737B2 (ja) |