JPH0434735B2 - - Google Patents
Info
- Publication number
- JPH0434735B2 JPH0434735B2 JP58007152A JP715283A JPH0434735B2 JP H0434735 B2 JPH0434735 B2 JP H0434735B2 JP 58007152 A JP58007152 A JP 58007152A JP 715283 A JP715283 A JP 715283A JP H0434735 B2 JPH0434735 B2 JP H0434735B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- general formula
- carbon atoms
- formula
- groups
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 silver halide Chemical class 0.000 claims description 115
- 229910052709 silver Inorganic materials 0.000 claims description 55
- 239000004332 silver Substances 0.000 claims description 55
- 239000000839 emulsion Substances 0.000 claims description 48
- 125000004432 carbon atom Chemical group C* 0.000 claims description 20
- 239000000463 material Substances 0.000 claims description 17
- 125000000217 alkyl group Chemical group 0.000 claims description 15
- 125000003118 aryl group Chemical group 0.000 claims description 14
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 13
- 125000003545 alkoxy group Chemical group 0.000 claims description 11
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 125000000623 heterocyclic group Chemical group 0.000 claims description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 9
- 125000001951 carbamoylamino group Chemical group C(N)(=O)N* 0.000 claims description 9
- 125000005843 halogen group Chemical group 0.000 claims description 9
- 125000001931 aliphatic group Chemical group 0.000 claims description 8
- 125000004104 aryloxy group Chemical group 0.000 claims description 8
- 125000004442 acylamino group Chemical group 0.000 claims description 7
- 125000004414 alkyl thio group Chemical group 0.000 claims description 7
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 claims description 7
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 7
- 125000000565 sulfonamide group Chemical group 0.000 claims description 7
- 125000004453 alkoxycarbonyl group Chemical group 0.000 claims description 6
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 6
- 238000005859 coupling reaction Methods 0.000 claims description 5
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 4
- 125000004429 atom Chemical group 0.000 claims description 4
- 125000005521 carbonamide group Chemical group 0.000 claims description 4
- 230000008878 coupling Effects 0.000 claims description 4
- 238000010168 coupling process Methods 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 4
- 125000005118 N-alkylcarbamoyl group Chemical group 0.000 claims description 3
- 125000003277 amino group Chemical group 0.000 claims description 3
- 125000006165 cyclic alkyl group Chemical group 0.000 claims description 3
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 125000003342 alkenyl group Chemical group 0.000 claims description 2
- 125000004390 alkyl sulfonyl group Chemical group 0.000 claims description 2
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 125000003107 substituted aryl group Chemical group 0.000 claims 1
- 239000010410 layer Substances 0.000 description 47
- 239000000975 dye Substances 0.000 description 41
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 36
- 238000000034 method Methods 0.000 description 25
- 230000001235 sensitizing effect Effects 0.000 description 15
- 108010010803 Gelatin Proteins 0.000 description 14
- 229920000159 gelatin Polymers 0.000 description 14
- 239000008273 gelatin Substances 0.000 description 14
- 235000019322 gelatine Nutrition 0.000 description 14
- 235000011852 gelatine desserts Nutrition 0.000 description 14
- 238000011161 development Methods 0.000 description 13
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 12
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 12
- 238000001228 spectrum Methods 0.000 description 12
- 239000000243 solution Substances 0.000 description 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 9
- 239000002253 acid Substances 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 8
- 238000012545 processing Methods 0.000 description 8
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 8
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 7
- 229910021612 Silver iodide Inorganic materials 0.000 description 7
- 239000000084 colloidal system Substances 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 7
- 229940045105 silver iodide Drugs 0.000 description 7
- 239000002202 Polyethylene glycol Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000000049 pigment Substances 0.000 description 6
- 229920001223 polyethylene glycol Polymers 0.000 description 6
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
- KXDAEFPNCMNJSK-UHFFFAOYSA-N Benzamide Chemical group NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 description 4
- 229910021529 ammonia Inorganic materials 0.000 description 4
- 239000007844 bleaching agent Substances 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 230000035945 sensitivity Effects 0.000 description 4
- 229910001961 silver nitrate Inorganic materials 0.000 description 4
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 229920003171 Poly (ethylene oxide) Chemical class 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 238000004061 bleaching Methods 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 125000001624 naphthyl group Chemical group 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 2
- XLLIQLLCWZCATF-UHFFFAOYSA-N 2-methoxyethyl acetate Chemical compound COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 2
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- OJGMBLNIHDZDGS-UHFFFAOYSA-N N-Ethylaniline Chemical compound CCNC1=CC=CC=C1 OJGMBLNIHDZDGS-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 125000000738 acetamido group Chemical group [H]C([H])([H])C(=O)N([H])[*] 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 235000010980 cellulose Nutrition 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 229960001484 edetic acid Drugs 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 2
- 125000002971 oxazolyl group Chemical group 0.000 description 2
- 150000004986 phenylenediamines Chemical class 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 239000004848 polyfunctional curative Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 235000010265 sodium sulphite Nutrition 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 2
- 235000000346 sugar Nutrition 0.000 description 2
- 125000004964 sulfoalkyl group Chemical group 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- GVEYRUKUJCHJSR-UHFFFAOYSA-N (4-azaniumyl-3-methylphenyl)-ethyl-(2-hydroxyethyl)azanium;sulfate Chemical compound OS(O)(=O)=O.OCCN(CC)C1=CC=C(N)C(C)=C1 GVEYRUKUJCHJSR-UHFFFAOYSA-N 0.000 description 1
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- LUMLZKVIXLWTCI-NSCUHMNNSA-N (e)-2,3-dichloro-4-oxobut-2-enoic acid Chemical compound OC(=O)C(\Cl)=C(/Cl)C=O LUMLZKVIXLWTCI-NSCUHMNNSA-N 0.000 description 1
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 1
- SDYMYAFSQACTQP-UHFFFAOYSA-N 1,3-benzothiazole-2-sulfonamide Chemical compound C1=CC=C2SC(S(=O)(=O)N)=NC2=C1 SDYMYAFSQACTQP-UHFFFAOYSA-N 0.000 description 1
- BCMCBBGGLRIHSE-UHFFFAOYSA-N 1,3-benzoxazole Chemical group C1=CC=C2OC=NC2=C1 BCMCBBGGLRIHSE-UHFFFAOYSA-N 0.000 description 1
- WKXVETMYCFRGET-UHFFFAOYSA-N 1,3-thiazole-2-sulfonamide Chemical compound NS(=O)(=O)C1=NC=CS1 WKXVETMYCFRGET-UHFFFAOYSA-N 0.000 description 1
- ZRHUHDUEXWHZMA-UHFFFAOYSA-N 1,4-dihydropyrazol-5-one Chemical compound O=C1CC=NN1 ZRHUHDUEXWHZMA-UHFFFAOYSA-N 0.000 description 1
- YLVACWCCJCZITJ-UHFFFAOYSA-N 1,4-dioxane-2,3-diol Chemical compound OC1OCCOC1O YLVACWCCJCZITJ-UHFFFAOYSA-N 0.000 description 1
- SIQZJFKTROUNPI-UHFFFAOYSA-N 1-(hydroxymethyl)-5,5-dimethylhydantoin Chemical compound CC1(C)N(CO)C(=O)NC1=O SIQZJFKTROUNPI-UHFFFAOYSA-N 0.000 description 1
- FYBFGAFWCBMEDG-UHFFFAOYSA-N 1-[3,5-di(prop-2-enoyl)-1,3,5-triazinan-1-yl]prop-2-en-1-one Chemical compound C=CC(=O)N1CN(C(=O)C=C)CN(C(=O)C=C)C1 FYBFGAFWCBMEDG-UHFFFAOYSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 1
- YGDWUQFZMXWDKE-UHFFFAOYSA-N 1-oxido-1,3-thiazole Chemical group [O-]S1=CN=C=C1 YGDWUQFZMXWDKE-UHFFFAOYSA-N 0.000 description 1
- KPVMVJXYXFUVLR-UHFFFAOYSA-N 12-ethyltetradecan-1-amine Chemical compound CCC(CC)CCCCCCCCCCCN KPVMVJXYXFUVLR-UHFFFAOYSA-N 0.000 description 1
- XRGHQBXKSHAQRB-UHFFFAOYSA-N 1h-benzimidazole-2-sulfonamide Chemical compound C1=CC=C2NC(S(=O)(=O)N)=NC2=C1 XRGHQBXKSHAQRB-UHFFFAOYSA-N 0.000 description 1
- PMTLRCDQMKXMRZ-UHFFFAOYSA-N 1h-imidazole-2-sulfonamide Chemical compound NS(=O)(=O)C1=NC=CN1 PMTLRCDQMKXMRZ-UHFFFAOYSA-N 0.000 description 1
- WNOVBLHBCHOXKD-UHFFFAOYSA-N 2,3-bis(2,4,4-trimethylpentan-2-yl)benzene-1,4-diol Chemical compound CC(C)(C)CC(C)(C)C1=C(O)C=CC(O)=C1C(C)(C)CC(C)(C)C WNOVBLHBCHOXKD-UHFFFAOYSA-N 0.000 description 1
- IPAFNZVMBOZODU-UHFFFAOYSA-N 2,4,6-trichlorobenzenesulfonamide Chemical compound NS(=O)(=O)C1=C(Cl)C=C(Cl)C=C1Cl IPAFNZVMBOZODU-UHFFFAOYSA-N 0.000 description 1
- CLDZVCMRASJQFO-UHFFFAOYSA-N 2,5-bis(2,4,4-trimethylpentan-2-yl)benzene-1,4-diol Chemical compound CC(C)(C)CC(C)(C)C1=CC(O)=C(C(C)(C)CC(C)(C)C)C=C1O CLDZVCMRASJQFO-UHFFFAOYSA-N 0.000 description 1
- YKUDHBLDJYZZQS-UHFFFAOYSA-N 2,6-dichloro-1h-1,3,5-triazin-4-one Chemical compound OC1=NC(Cl)=NC(Cl)=N1 YKUDHBLDJYZZQS-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- QTLHLXYADXCVCF-UHFFFAOYSA-N 2-(4-amino-n-ethyl-3-methylanilino)ethanol Chemical compound OCCN(CC)C1=CC=C(N)C(C)=C1 QTLHLXYADXCVCF-UHFFFAOYSA-N 0.000 description 1
- WFXLRLQSHRNHCE-UHFFFAOYSA-N 2-(4-amino-n-ethylanilino)ethanol Chemical compound OCCN(CC)C1=CC=C(N)C=C1 WFXLRLQSHRNHCE-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- MKQNYQGIPARLKO-UHFFFAOYSA-N 2-methoxybenzenesulfonamide Chemical compound COC1=CC=CC=C1S(N)(=O)=O MKQNYQGIPARLKO-UHFFFAOYSA-N 0.000 description 1
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 1
- ROZCUVMFXOURIS-UHFFFAOYSA-N 2-phenylethanesulfonamide Chemical group NS(=O)(=O)CCC1=CC=CC=C1 ROZCUVMFXOURIS-UHFFFAOYSA-N 0.000 description 1
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N 2-propanol Substances CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- XRZDIHADHZSFBB-UHFFFAOYSA-N 3-oxo-n,3-diphenylpropanamide Chemical class C=1C=CC=CC=1NC(=O)CC(=O)C1=CC=CC=C1 XRZDIHADHZSFBB-UHFFFAOYSA-N 0.000 description 1
- NAETXYOXMDYNLE-UHFFFAOYSA-N 3-sulfamoylbenzoic acid Chemical group NS(=O)(=O)C1=CC=CC(C(O)=O)=C1 NAETXYOXMDYNLE-UHFFFAOYSA-N 0.000 description 1
- YLNKRLLYLJYWEN-UHFFFAOYSA-N 4-(2,2-dibutoxyethoxy)-4-oxobutanoic acid Chemical compound CCCCOC(OCCCC)COC(=O)CCC(O)=O YLNKRLLYLJYWEN-UHFFFAOYSA-N 0.000 description 1
- ZNBNBTIDJSKEAM-UHFFFAOYSA-N 4-[7-hydroxy-2-[5-[5-[6-hydroxy-6-(hydroxymethyl)-3,5-dimethyloxan-2-yl]-3-methyloxolan-2-yl]-5-methyloxolan-2-yl]-2,8-dimethyl-1,10-dioxaspiro[4.5]decan-9-yl]-2-methyl-3-propanoyloxypentanoic acid Chemical compound C1C(O)C(C)C(C(C)C(OC(=O)CC)C(C)C(O)=O)OC11OC(C)(C2OC(C)(CC2)C2C(CC(O2)C2C(CC(C)C(O)(CO)O2)C)C)CC1 ZNBNBTIDJSKEAM-UHFFFAOYSA-N 0.000 description 1
- 125000000590 4-methylphenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 1
- XBTWVJKPQPQTDW-UHFFFAOYSA-N 4-n,4-n-diethyl-2-methylbenzene-1,4-diamine Chemical compound CCN(CC)C1=CC=C(N)C(C)=C1 XBTWVJKPQPQTDW-UHFFFAOYSA-N 0.000 description 1
- QNGVNLMMEQUVQK-UHFFFAOYSA-N 4-n,4-n-diethylbenzene-1,4-diamine Chemical compound CCN(CC)C1=CC=C(N)C=C1 QNGVNLMMEQUVQK-UHFFFAOYSA-N 0.000 description 1
- FFAJEKUNEVVYCW-UHFFFAOYSA-N 4-n-ethyl-4-n-(2-methoxyethyl)-2-methylbenzene-1,4-diamine Chemical compound COCCN(CC)C1=CC=C(N)C(C)=C1 FFAJEKUNEVVYCW-UHFFFAOYSA-N 0.000 description 1
- JSTCPNFNKICNNO-UHFFFAOYSA-N 4-nitrosophenol Chemical compound OC1=CC=C(N=O)C=C1 JSTCPNFNKICNNO-UHFFFAOYSA-N 0.000 description 1
- 125000004199 4-trifluoromethylphenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C(F)(F)F 0.000 description 1
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 102000009027 Albumins Human genes 0.000 description 1
- 108010088751 Albumins Proteins 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- KHBQMWCZKVMBLN-UHFFFAOYSA-N Benzenesulfonamide Chemical compound NS(=O)(=O)C1=CC=CC=C1 KHBQMWCZKVMBLN-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920002284 Cellulose triacetate Polymers 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 1
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical class OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 206010052143 Ocular discomfort Diseases 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- 229910006074 SO2NH2 Inorganic materials 0.000 description 1
- 229910006069 SO3H Inorganic materials 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- XOAAWQZATWQOTB-UHFFFAOYSA-N Taurine Natural products NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 1
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical group C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 1
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 1
- XCFIVNQHHFZRNR-UHFFFAOYSA-N [Ag].Cl[IH]Br Chemical compound [Ag].Cl[IH]Br XCFIVNQHHFZRNR-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- 229960000583 acetic acid Drugs 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- 125000005115 alkyl carbamoyl group Chemical group 0.000 description 1
- 125000005599 alkyl carboxylate group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 125000004644 alkyl sulfinyl group Chemical group 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 125000004422 alkyl sulphonamide group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 description 1
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000004421 aryl sulphonamide group Chemical group 0.000 description 1
- 125000005110 aryl thio group Chemical group 0.000 description 1
- XNSQZBOCSSMHSZ-UHFFFAOYSA-K azane;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxymethyl)amino]acetate;iron(3+) Chemical compound [NH4+].[Fe+3].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O XNSQZBOCSSMHSZ-UHFFFAOYSA-K 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 125000000499 benzofuranyl group Chemical group O1C(=CC2=C1C=CC=C2)* 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 150000008366 benzophenones Chemical group 0.000 description 1
- 125000001164 benzothiazolyl group Chemical group S1C(=NC2=C1C=CC=C2)* 0.000 description 1
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 description 1
- 125000004541 benzoxazolyl group Chemical group O1C(=NC2=C1C=CC=C2)* 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- CODNYICXDISAEA-UHFFFAOYSA-N bromine monochloride Chemical compound BrCl CODNYICXDISAEA-UHFFFAOYSA-N 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 1
- OVIZSQRQYWEGON-UHFFFAOYSA-N butane-1-sulfonamide Chemical group CCCCS(N)(=O)=O OVIZSQRQYWEGON-UHFFFAOYSA-N 0.000 description 1
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- COPHVUDURPSYBO-UHFFFAOYSA-N butyl dioctyl phosphate Chemical compound CCCCCCCCOP(=O)(OCCCC)OCCCCCCCC COPHVUDURPSYBO-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004744 butyloxycarbonyl group Chemical group 0.000 description 1
- 150000001661 cadmium Chemical class 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
- WYYQVWLEPYFFLP-UHFFFAOYSA-K chromium(3+);triacetate Chemical compound [Cr+3].CC([O-])=O.CC([O-])=O.CC([O-])=O WYYQVWLEPYFFLP-UHFFFAOYSA-K 0.000 description 1
- 235000013985 cinnamic acid Nutrition 0.000 description 1
- 229930016911 cinnamic acid Natural products 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 125000000596 cyclohexenyl group Chemical group C1(=CCCCC1)* 0.000 description 1
- 125000002433 cyclopentenyl group Chemical group C1(=CCCC1)* 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 description 1
- 125000004663 dialkyl amino group Chemical group 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 1
- XWVQUJDBOICHGH-UHFFFAOYSA-N dioctyl nonanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCC(=O)OCCCCCCCC XWVQUJDBOICHGH-UHFFFAOYSA-N 0.000 description 1
- 150000002012 dioxanes Chemical class 0.000 description 1
- ASMQGLCHMVWBQR-UHFFFAOYSA-M diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)([O-])OC1=CC=CC=C1 ASMQGLCHMVWBQR-UHFFFAOYSA-M 0.000 description 1
- COMFSPSZVXMTCM-UHFFFAOYSA-N dodecane-1-sulfonimidic acid Chemical group CCCCCCCCCCCCS(N)(=O)=O COMFSPSZVXMTCM-UHFFFAOYSA-N 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- YAGKRVSRTSUGEY-UHFFFAOYSA-N ferricyanide Chemical compound [Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] YAGKRVSRTSUGEY-UHFFFAOYSA-N 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 125000002541 furyl group Chemical group 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 229940093915 gynecological organic acid Drugs 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- CRPAPNNHNVVYKL-UHFFFAOYSA-N hexadecane-1-sulfonamide Chemical group CCCCCCCCCCCCCCCCS(N)(=O)=O CRPAPNNHNVVYKL-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 229910000378 hydroxylammonium sulfate Inorganic materials 0.000 description 1
- PTFYQSWHBLOXRZ-UHFFFAOYSA-N imidazo[4,5-e]indazole Chemical compound C1=CC2=NC=NC2=C2C=NN=C21 PTFYQSWHBLOXRZ-UHFFFAOYSA-N 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 125000002883 imidazolyl group Chemical group 0.000 description 1
- 125000005462 imide group Chemical group 0.000 description 1
- 229940079865 intestinal antiinfectives imidazole derivative Drugs 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 150000002503 iridium Chemical class 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 125000005647 linker group Chemical group 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- HNQIVZYLYMDVSB-UHFFFAOYSA-N methanesulfonimidic acid Chemical compound CS(N)(=O)=O HNQIVZYLYMDVSB-UHFFFAOYSA-N 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- ZAKLKBFCSHJIRI-UHFFFAOYSA-N mucochloric acid Natural products OC1OC(=O)C(Cl)=C1Cl ZAKLKBFCSHJIRI-UHFFFAOYSA-N 0.000 description 1
- 125000001419 myristoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- JEUXZUSUYIHGNL-UHFFFAOYSA-N n,n-diethylethanamine;hydrate Chemical compound O.CCN(CC)CC JEUXZUSUYIHGNL-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 150000002832 nitroso derivatives Chemical class 0.000 description 1
- 125000002868 norbornyl group Chemical group C12(CCC(CC1)C2)* 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- VECVSKFWRQYTAL-UHFFFAOYSA-N octyl benzoate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1 VECVSKFWRQYTAL-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- 238000005691 oxidative coupling reaction Methods 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- QUBQYFYWUJJAAK-UHFFFAOYSA-N oxymethurea Chemical compound OCNC(=O)NCO QUBQYFYWUJJAAK-UHFFFAOYSA-N 0.000 description 1
- 229950005308 oxymethurea Drugs 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 1
- 229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 150000003142 primary aromatic amines Chemical class 0.000 description 1
- QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical group CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- NDGRWYRVNANFNB-UHFFFAOYSA-N pyrazolidin-3-one Chemical class O=C1CCNN1 NDGRWYRVNANFNB-UHFFFAOYSA-N 0.000 description 1
- DWJMBQYORXLGAE-UHFFFAOYSA-N pyridine-2-sulfonamide Chemical group NS(=O)(=O)C1=CC=CC=N1 DWJMBQYORXLGAE-UHFFFAOYSA-N 0.000 description 1
- OENLEHTYJXMVBG-UHFFFAOYSA-N pyridine;hydrate Chemical compound [OH-].C1=CC=[NH+]C=C1 OENLEHTYJXMVBG-UHFFFAOYSA-N 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 description 1
- 125000004076 pyridyl group Chemical group 0.000 description 1
- 125000000168 pyrrolyl group Chemical group 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 125000002943 quinolinyl group Chemical group N1=C(C=CC2=CC=CC=C12)* 0.000 description 1
- 150000004053 quinones Chemical class 0.000 description 1
- 150000003283 rhodium Chemical class 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 235000017709 saponins Nutrition 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- SRFKWQSWMOPVQK-UHFFFAOYSA-K sodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxymethyl)amino]acetate;iron(2+) Chemical compound [Na+].[Fe+2].OC(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O SRFKWQSWMOPVQK-UHFFFAOYSA-K 0.000 description 1
- UWSAIOMORQUEHN-UHFFFAOYSA-L sodium;2-[2-[carboxylatomethyl(carboxymethyl)amino]ethyl-(carboxymethyl)amino]acetate;iron(5+) Chemical compound [Na+].[Fe+5].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O UWSAIOMORQUEHN-UHFFFAOYSA-L 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 150000003431 steroids Chemical class 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 229960002317 succinimide Drugs 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 229960003080 taurine Drugs 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 150000003475 thallium Chemical class 0.000 description 1
- 125000000335 thiazolyl group Chemical group 0.000 description 1
- 150000003567 thiocyanates Chemical class 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 1
- 150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 1
- NJPOTNJJCSJJPJ-UHFFFAOYSA-N tributyl benzene-1,3,5-tricarboxylate Chemical compound CCCCOC(=O)C1=CC(C(=O)OCCCC)=CC(C(=O)OCCCC)=C1 NJPOTNJJCSJJPJ-UHFFFAOYSA-N 0.000 description 1
- 150000003639 trimesic acids Chemical class 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/3003—Materials characterised by the use of combinations of photographic compounds known as such, or by a particular location in the photographic element
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Description
æ¬çºæã¯ããã²ã³åéã«ã©ãŒåçææã«é¢ãã
ãã®ã§ãããç¹ã«ç²ç¶æ§ã®æ¹è¯ãããæ®åœ±çšãã
ã²ã³åéã«ã©ãŒåçææã«é¢ãããã®ã§ããã è¿å¹Žå°ããªãŒãããã®ã«ã¡ã©ã®æ®åã«äŒŽããå°
ç»é¢ã®ã«ã©ãŒãã¬ãã倧ããªç»é¢ã®ã«ã©ãŒããªã³
ãã«åŒã䌞ã°ãããããšãå€ããªããåŸæ¥ã«ãå¢
ããŠããè¯ãç²ç¶æ§ãè§£å床ããã€ããšãèŠæ±ã
ããŠããŠããã ãã®ãã¡ç²ç¶æ§ãæ¹è¯ããããã«ã¯T.H.
JamesâTheory of the Photographic Processâ
4th.Ed.P620ãP621ã«èšèŒãããŠããããã«ãã
ã²ã³åéç²åã®æ°ãå€ãããããšãããã³ã«ã©ãŒ
çŸåã«ããçæããè²çŽ ãäžæçã«ãããããšã«
ãã€ãŠæ¹è¯ããããšãã§ãããããããªããåç
æåºŠãç¶æããŠããã²ã³åéç²åãæ°ãå€ããã
ã«ã¯å¡åžééã®å¢å ãããã³ããã«ããè§£å床ã®
å£åãæããã³ã¹ãçã«ãåçæ§èœäžãäžå©ã§ã
ãã åãè²çŽ ã®æ¡æ£ã«ãã€ãŠç²ç¶ãè¯åããã詊ã¿
ã¯è±åœç¹èš±ç¬¬2080640Aã«èšèŒã®ããšããããã
ãè²çŽ æ¡æ£åã«ãã©ãŒãçšãããšRMSç²ç¶æ§ã¯
è¯åãããåŸè¿°ã®ããšãããã®æ¹æ³ã¯èŠèŠçã«äž
å¿«ãªæããäžããã æã ã¯ä»¥åããç²ç¶æ§ã®æ¹è¯ã®ç ç©¶ãããŠãã
ãã以äžã®ãããªããšãèŠåºãããç²ç¶æ¹è¯ã®äž
ææ®µãšããŠé©åºŠã«è²çŽ ãã«ããæ¡æ£æ§è²çŽ ãçæ
ããéæ¡æ£åã«ãã©ãŒïŒä»¥äžåã«è²çŽ æ¡æ£åã«ã
ã©ãŒãšããïŒãçšãããšãããããRMSç²ç¶æ§
ïŒRMSç²ç¶æ§ã«ã€ããŠã¯T.H.JamesãâTheory
of the Photographic Processâ第ïŒçP619ã«èš
èŒãããïŒã¯éåžžã«è¯åãããããããªãããã
ã²ã³åéç²åã®é åããã³çŸå確çã¯ã©ã³ãã ãª
éçšã§ããããããè²çŽ ãæ¡æ£ããŠã«ãã¿é£æ¥ã
ãè²çŽ ãšæ··ãããããšãè²çŽ é²ã®éãªãã倧ãã
ãªããçµæçã«å·šå€§ãªè²çŽ é²ãã©ã³ãã ã«çæã
ãããšã«ãªããããã¯èŠèŠçã«ã¯æ¥µããŠäžå¿«ã§ã
ãããããç²ç¶ã¯æªåããŠã¿ããå Žåãããã ããã§ããã®èŠèŠçãªç²ç¶æªåãæ¹åãããã
ã«çš®ã ç ç©¶ãéããçµæãåŸè¿°ã®äžè¬åŒïŒïŒã
ïŒïŒãïŒïŒãïŒïŒãïŒïŒãïŒXIïŒãŸãã¯ïŒXII
ïŒã§
衚ããããè²çŽ æ¡æ£åã«ãã©ãŒãšå忣乳å€ã䜵
çšããããšã«ããåè¿°ã®èŠèŠçäžå¿«ãããšãé€ã
ããèŠèŠçã«ãRMSç²ç¶ã«ã極ããŠããããç²
ç¶æ§ãæããã«ã©ãŒåçææãæäŸã§ããããšã
èŠåºããã ããªãã¡è²çŽ æ¡æ£åã«ãã©ãŒãçšããå Žåã«ã¯
åã ã®è²çŽ é²ã«ã€ããŠè²çŽ éãåãã®ãŸãŸåšèŸºã«
è²çŽ ãæ¡æ£ããçµæãè²çŽ é²äžã®æ¿åºŠååžãå°ã
ããã€é¢ç©ã®å€§ãããã®ïŒä»¥äžæ¡æ£åè²çŽ é²ãšã
ãïŒã«ãªããããããããRMSå€ã§ç²ç¶ã衚çŸ
ããã°ãæ¹è¯ãããæ°å€ãã§ãŠããããããåè¿°
ããããã«è²çŽ é²ã倧ãããªãããã«è²çŽ é²å士
ãäºãã«éãªãåãããšã«ãªã€ãŠããããããŽã€
ãŒããŒã¹ãã¯ãã«ïŒT.H.JamesèâThe Theory
of Photographic Processâ4th Ed.P.621åç §ïŒ
ã§ç²ç¶ã衚çŸããå Žåãããã®äœåšæ³¢ã®éšåã®ç²
ç¶æ§ã衚ããå€ã¯ãè²çŽ æ¡æ£åã«ãã©ãŒãçšãã
æ¹ãããã€ãŠé«ããªãïŒãã®å€ã¯äœãçšãç²ç¶æ§
ãè¯ãïŒãäŸãã°ã第ïŒå³ã«ãããŠïŒµãïŒããå°
ããæã§ã¯è©Šæ102ã®ç·ã®æ¹ã詊æ101ããäžã«ã
ããããã¯èŠèŠçã«ã¯ããã€ãã®è²çŽ é²ãåºãŸã€
ãŠå€§ããªã¢ãã«ãç®ã«ã€ãããšãæå³ãããå®é
ã«ãè²çŽ æ¡æ£åã«ãã©ãŒãçšãããšããRMSå€
ã§ã®ç²ç¶æ§ãããããå€ã¯è¯ããªã€ãŠããªããã
èŠèŠçã«ã¯æ¥µããŠäžå¿«ãªæããããããç²ç¶æ§ã
æªããšããå°è±¡ãããããããšã«ãªãã ãã®ãããªç³»ã«ãããŠå忣ã®ããã²ã³åéä¹³
å€ãçšãããšäžèšã®æ¡æ£åè²çŽ é²ã®ãµã€ãºååžã
å°ãããªãããã®çµæå€§ããªè²çŽ é²å士ã®éãªã
ãå°ãªããªããäœåšæ³¢éšåã®ãŽã€ããŒã¹ãã¯ãã«
ã®å€ãäžãããããªãã¡èŠèŠçã«å€§ããªã¢ãã«ã
ç®ã«ã€ããªããªãèŠèŠçç²ç¶æ§ãæ¹è¯ãããããš
ã«ãªãã 以äžããæ¬çºæã¯è²çŽ æ¡æ£åã«ãã©ãŒãšå忣
ããã²ã³åéä¹³å€ãçšããããšã«ããèŠèŠçã«ã
ç²ç¶æ§ãéåžžã«è¯ããªã€ãããã²ã³åéã«ã©ãŒæ
å ææã«ãããŠå ·çŸãããã è²çŽ æ¡æ£åã«ãã©ãŒã®æ·»å éã¯éïŒã¢ã«ããã
0.005ã¢ã«ã0.2ã¢ã«ã奜ãŸããã¯0.01ã¢ã«ã0.05
ã¢ã«ã§ããã äžè¬åŒïŒïŒ äžè¬åŒïŒïŒ åŒäžR1ãR2ãR3ããã³R4ã¯åãã§ãã€ãŠãç°
ã€ãŠããããæ°ŽçŽ ååãããã²ã³ååãã¢ã«ãã«
åºïŒäŸãã°ã¡ãã«åºããšãã«åºãã€ãœãããã«
åºãããããã·ãšãã«åºãªã©ïŒãã¢ã«ã³ãã·åº
ïŒäŸãã°ã¡ããã·åºããšããã·åºãã¡ããã·ãšã
ãã·åºãªã©ïŒãã¢ãªãŒã«ãªãã·åºïŒäŸãã°ããšã
ãã·åºãªã©ïŒãã¢ã·ã«ã¢ããåºïŒäŸãã°ã¢ã»ãã«
ã¢ããåºãããªãã«ãªãã¢ã»ãã«ã¢ããåºãªã©ïŒã
ã¹ã«ãã³ã¢ããåºïŒäŸãã°ã¡ã¿ã³ã¹ã«ãã³ã¢ãã
åºããã³ãŒã³ã¹ã«ãã³ã¢ããåºãªã©ïŒãã«ã«ãã¢
ã€ã«åºãã¹ã«ãã¢ã¢ã€ã«åºãã¢ã«ãã«ããªåºãã¢
ã«ãã«ã¹ã«ããã«åºãã¢ã«ã³ãã·ã«ã«ããã«åºã
ãŠã¬ã€ãåºãã·ã¢ãåºãã«ã«ããã·ã«åºãããã
ãã·åºãŸãã¯ã¹ã«ãåºã衚ããããã ãR1ãR2ã
R3ããã³R4ã®ççŽ æ°ã®åèšã¯10ãè¶ããªãã Xâ²ã¯ã«ãã©ãŒã«éæ¡æ£æ§ãäžããççŽ æ°ïŒã
32ã®ãããããã©ã¹ãåºãæãããã€è³éŠæç¬¬ïŒ
çŽã¢ãã³çŸåè¬ã®é žåäœãšã®ã«ãããªã³ã°ã«ãã
é¢è±ãããåºã衚ããã詳ããã¯æ¬¡ã®äžè¬åŒ
ïŒïŒãŸãã¯äžè¬åŒïŒïŒã§è¡šããããšãã§ããã äžè¬åŒïŒïŒ
ãã®ã§ãããç¹ã«ç²ç¶æ§ã®æ¹è¯ãããæ®åœ±çšãã
ã²ã³åéã«ã©ãŒåçææã«é¢ãããã®ã§ããã è¿å¹Žå°ããªãŒãããã®ã«ã¡ã©ã®æ®åã«äŒŽããå°
ç»é¢ã®ã«ã©ãŒãã¬ãã倧ããªç»é¢ã®ã«ã©ãŒããªã³
ãã«åŒã䌞ã°ãããããšãå€ããªããåŸæ¥ã«ãå¢
ããŠããè¯ãç²ç¶æ§ãè§£å床ããã€ããšãèŠæ±ã
ããŠããŠããã ãã®ãã¡ç²ç¶æ§ãæ¹è¯ããããã«ã¯T.H.
JamesâTheory of the Photographic Processâ
4th.Ed.P620ãP621ã«èšèŒãããŠããããã«ãã
ã²ã³åéç²åã®æ°ãå€ãããããšãããã³ã«ã©ãŒ
çŸåã«ããçæããè²çŽ ãäžæçã«ãããããšã«
ãã€ãŠæ¹è¯ããããšãã§ãããããããªããåç
æåºŠãç¶æããŠããã²ã³åéç²åãæ°ãå€ããã
ã«ã¯å¡åžééã®å¢å ãããã³ããã«ããè§£å床ã®
å£åãæããã³ã¹ãçã«ãåçæ§èœäžãäžå©ã§ã
ãã åãè²çŽ ã®æ¡æ£ã«ãã€ãŠç²ç¶ãè¯åããã詊ã¿
ã¯è±åœç¹èš±ç¬¬2080640Aã«èšèŒã®ããšããããã
ãè²çŽ æ¡æ£åã«ãã©ãŒãçšãããšRMSç²ç¶æ§ã¯
è¯åãããåŸè¿°ã®ããšãããã®æ¹æ³ã¯èŠèŠçã«äž
å¿«ãªæããäžããã æã ã¯ä»¥åããç²ç¶æ§ã®æ¹è¯ã®ç ç©¶ãããŠãã
ãã以äžã®ãããªããšãèŠåºãããç²ç¶æ¹è¯ã®äž
ææ®µãšããŠé©åºŠã«è²çŽ ãã«ããæ¡æ£æ§è²çŽ ãçæ
ããéæ¡æ£åã«ãã©ãŒïŒä»¥äžåã«è²çŽ æ¡æ£åã«ã
ã©ãŒãšããïŒãçšãããšãããããRMSç²ç¶æ§
ïŒRMSç²ç¶æ§ã«ã€ããŠã¯T.H.JamesãâTheory
of the Photographic Processâ第ïŒçP619ã«èš
èŒãããïŒã¯éåžžã«è¯åãããããããªãããã
ã²ã³åéç²åã®é åããã³çŸå確çã¯ã©ã³ãã ãª
éçšã§ããããããè²çŽ ãæ¡æ£ããŠã«ãã¿é£æ¥ã
ãè²çŽ ãšæ··ãããããšãè²çŽ é²ã®éãªãã倧ãã
ãªããçµæçã«å·šå€§ãªè²çŽ é²ãã©ã³ãã ã«çæã
ãããšã«ãªããããã¯èŠèŠçã«ã¯æ¥µããŠäžå¿«ã§ã
ãããããç²ç¶ã¯æªåããŠã¿ããå Žåãããã ããã§ããã®èŠèŠçãªç²ç¶æªåãæ¹åãããã
ã«çš®ã ç ç©¶ãéããçµæãåŸè¿°ã®äžè¬åŒïŒïŒã
ïŒïŒãïŒïŒãïŒïŒãïŒïŒãïŒXIïŒãŸãã¯ïŒXII
ïŒã§
衚ããããè²çŽ æ¡æ£åã«ãã©ãŒãšå忣乳å€ã䜵
çšããããšã«ããåè¿°ã®èŠèŠçäžå¿«ãããšãé€ã
ããèŠèŠçã«ãRMSç²ç¶ã«ã極ããŠããããç²
ç¶æ§ãæããã«ã©ãŒåçææãæäŸã§ããããšã
èŠåºããã ããªãã¡è²çŽ æ¡æ£åã«ãã©ãŒãçšããå Žåã«ã¯
åã ã®è²çŽ é²ã«ã€ããŠè²çŽ éãåãã®ãŸãŸåšèŸºã«
è²çŽ ãæ¡æ£ããçµæãè²çŽ é²äžã®æ¿åºŠååžãå°ã
ããã€é¢ç©ã®å€§ãããã®ïŒä»¥äžæ¡æ£åè²çŽ é²ãšã
ãïŒã«ãªããããããããRMSå€ã§ç²ç¶ã衚çŸ
ããã°ãæ¹è¯ãããæ°å€ãã§ãŠããããããåè¿°
ããããã«è²çŽ é²ã倧ãããªãããã«è²çŽ é²å士
ãäºãã«éãªãåãããšã«ãªã€ãŠããããããŽã€
ãŒããŒã¹ãã¯ãã«ïŒT.H.JamesèâThe Theory
of Photographic Processâ4th Ed.P.621åç §ïŒ
ã§ç²ç¶ã衚çŸããå Žåãããã®äœåšæ³¢ã®éšåã®ç²
ç¶æ§ã衚ããå€ã¯ãè²çŽ æ¡æ£åã«ãã©ãŒãçšãã
æ¹ãããã€ãŠé«ããªãïŒãã®å€ã¯äœãçšãç²ç¶æ§
ãè¯ãïŒãäŸãã°ã第ïŒå³ã«ãããŠïŒµãïŒããå°
ããæã§ã¯è©Šæ102ã®ç·ã®æ¹ã詊æ101ããäžã«ã
ããããã¯èŠèŠçã«ã¯ããã€ãã®è²çŽ é²ãåºãŸã€
ãŠå€§ããªã¢ãã«ãç®ã«ã€ãããšãæå³ãããå®é
ã«ãè²çŽ æ¡æ£åã«ãã©ãŒãçšãããšããRMSå€
ã§ã®ç²ç¶æ§ãããããå€ã¯è¯ããªã€ãŠããªããã
èŠèŠçã«ã¯æ¥µããŠäžå¿«ãªæããããããç²ç¶æ§ã
æªããšããå°è±¡ãããããããšã«ãªãã ãã®ãããªç³»ã«ãããŠå忣ã®ããã²ã³åéä¹³
å€ãçšãããšäžèšã®æ¡æ£åè²çŽ é²ã®ãµã€ãºååžã
å°ãããªãããã®çµæå€§ããªè²çŽ é²å士ã®éãªã
ãå°ãªããªããäœåšæ³¢éšåã®ãŽã€ããŒã¹ãã¯ãã«
ã®å€ãäžãããããªãã¡èŠèŠçã«å€§ããªã¢ãã«ã
ç®ã«ã€ããªããªãèŠèŠçç²ç¶æ§ãæ¹è¯ãããããš
ã«ãªãã 以äžããæ¬çºæã¯è²çŽ æ¡æ£åã«ãã©ãŒãšå忣
ããã²ã³åéä¹³å€ãçšããããšã«ããèŠèŠçã«ã
ç²ç¶æ§ãéåžžã«è¯ããªã€ãããã²ã³åéã«ã©ãŒæ
å ææã«ãããŠå ·çŸãããã è²çŽ æ¡æ£åã«ãã©ãŒã®æ·»å éã¯éïŒã¢ã«ããã
0.005ã¢ã«ã0.2ã¢ã«ã奜ãŸããã¯0.01ã¢ã«ã0.05
ã¢ã«ã§ããã äžè¬åŒïŒïŒ äžè¬åŒïŒïŒ åŒäžR1ãR2ãR3ããã³R4ã¯åãã§ãã€ãŠãç°
ã€ãŠããããæ°ŽçŽ ååãããã²ã³ååãã¢ã«ãã«
åºïŒäŸãã°ã¡ãã«åºããšãã«åºãã€ãœãããã«
åºãããããã·ãšãã«åºãªã©ïŒãã¢ã«ã³ãã·åº
ïŒäŸãã°ã¡ããã·åºããšããã·åºãã¡ããã·ãšã
ãã·åºãªã©ïŒãã¢ãªãŒã«ãªãã·åºïŒäŸãã°ããšã
ãã·åºãªã©ïŒãã¢ã·ã«ã¢ããåºïŒäŸãã°ã¢ã»ãã«
ã¢ããåºãããªãã«ãªãã¢ã»ãã«ã¢ããåºãªã©ïŒã
ã¹ã«ãã³ã¢ããåºïŒäŸãã°ã¡ã¿ã³ã¹ã«ãã³ã¢ãã
åºããã³ãŒã³ã¹ã«ãã³ã¢ããåºãªã©ïŒãã«ã«ãã¢
ã€ã«åºãã¹ã«ãã¢ã¢ã€ã«åºãã¢ã«ãã«ããªåºãã¢
ã«ãã«ã¹ã«ããã«åºãã¢ã«ã³ãã·ã«ã«ããã«åºã
ãŠã¬ã€ãåºãã·ã¢ãåºãã«ã«ããã·ã«åºãããã
ãã·åºãŸãã¯ã¹ã«ãåºã衚ããããã ãR1ãR2ã
R3ããã³R4ã®ççŽ æ°ã®åèšã¯10ãè¶ããªãã Xâ²ã¯ã«ãã©ãŒã«éæ¡æ£æ§ãäžããççŽ æ°ïŒã
32ã®ãããããã©ã¹ãåºãæãããã€è³éŠæç¬¬ïŒ
çŽã¢ãã³çŸåè¬ã®é žåäœãšã®ã«ãããªã³ã°ã«ãã
é¢è±ãããåºã衚ããã詳ããã¯æ¬¡ã®äžè¬åŒ
ïŒïŒãŸãã¯äžè¬åŒïŒïŒã§è¡šããããšãã§ããã äžè¬åŒïŒïŒ
ãåŒã
äžè¬åŒïŒïŒ
ãåŒã
åŒäžïŒ¡ã¯é
žçŽ ååãŸãã¯ã€ãªãŠååã衚ããã
ã¯ã¢ãªãŒã«ç°ãŸãã¯ãããç°ã圢æããã®ã«å¿
èŠãªééå±åå矀ã衚ãããã¯çªçŽ ååãšãšã
ã«ïŒå¡ãŸãã¯ïŒå¡ãããç°ã圢æããã®ã«å¿ èŠãª
ééå±åå矀ã衚ããããããã®ç°ã¯ããã«ã¢ãª
ãŒã«ç°ãŸãã¯ãããç°ãšçž®åããŠããŠãããã
ã¯ãã©ã¹ãåºã衚ãããïœã¯æ£ã®æŽæ°ã衚ããã
ïœãè€æ°ã®ãšãã¯åãã§ãã€ãŠãç°ã€ãŠããŠã
ãããç·ççŽ æ°ã¯ïŒã32ã§ãããã¯ââãâ
âãâCOOâãâCONHâãâSO2NHâãâ
NHCONHâãâSO2âãâCOâãâNHâãªã©ã®
é£çµåºãå«ãã§ããŠãããã äžè¬åŒ(1)ã«ãããŠå¥œãŸããä»ã®ã«ãã©ãŒã¯äžèš
äžè¬åŒïŒïŒãïŒïŒãŸãã¯ïŒïŒã§è¡šããããã äžè¬åŒïŒïŒ
ã¯ã¢ãªãŒã«ç°ãŸãã¯ãããç°ã圢æããã®ã«å¿
èŠãªééå±åå矀ã衚ãããã¯çªçŽ ååãšãšã
ã«ïŒå¡ãŸãã¯ïŒå¡ãããç°ã圢æããã®ã«å¿ èŠãª
ééå±åå矀ã衚ããããããã®ç°ã¯ããã«ã¢ãª
ãŒã«ç°ãŸãã¯ãããç°ãšçž®åããŠããŠãããã
ã¯ãã©ã¹ãåºã衚ãããïœã¯æ£ã®æŽæ°ã衚ããã
ïœãè€æ°ã®ãšãã¯åãã§ãã€ãŠãç°ã€ãŠããŠã
ãããç·ççŽ æ°ã¯ïŒã32ã§ãããã¯ââãâ
âãâCOOâãâCONHâãâSO2NHâãâ
NHCONHâãâSO2âãâCOâãâNHâãªã©ã®
é£çµåºãå«ãã§ããŠãããã äžè¬åŒ(1)ã«ãããŠå¥œãŸããä»ã®ã«ãã©ãŒã¯äžèš
äžè¬åŒïŒïŒãïŒïŒãŸãã¯ïŒïŒã§è¡šããããã äžè¬åŒïŒïŒ
ãåŒã
äžè¬åŒïŒïŒ
ãåŒã
äžè¬åŒïŒïŒ
åŒäžR5ã¯ã¢ã·ã«ã¢ããåºïŒäŸãã°ãããã³ã¢
ããåºããã³ãºã¢ããåºïŒãã¢ããªãåºïŒäŸãã°
ïŒâã¯ããã¢ããªãåºãïŒâã¢ã»ãã¢ããã¢ããª
ãåºïŒãŸãã¯ãŠã¬ã€ãåºïŒäŸãã°ããšãã«ãŠã¬ã€
ãåºããã¿ã³ãŠã¬ã€ãåºïŒã衚ãããR6ããã³
R7ã¯åã ãããã²ã³ååãã¢ã«ãã«åºïŒäŸãã°
ã¡ãã«åºããšãã«åºïŒãã¢ã«ã³ãã·åºïŒäŸãã°ã¡
ããã·åºããšããã·åºïŒãã¢ã·ã«ã¢ããåºïŒäŸã
ã°ã¢ã»ãã¢ããåºããã³ãºã¢ããåºïŒãã¢ã«ã³ã
ã·ã«ã«ããã«åºïŒäŸãã°ã¡ããã·ã«ã«ããã«åºïŒã
âã¢ã«ãã«ã«ã«ãã¢ã€ã«åºïŒäŸãã°ïŒ®âã¡ãã«
ã«ã«ãã¢ã€ã«åºïŒããŠã¬ã€ãåºïŒäŸãã°ïŒ®âã¡ã
ã«ãŠã¬ã€ãåºïŒãã·ã¢ãåºãã¢ãªãŒã«åºïŒäŸãã°
ããšãã«åºããããã«åºïŒãïŒïŒ®âãžã¢ã«ãã«
ã¹ã«ãã¢ã¢ã€ã«åºããããåºãããããã·åºãã«
ã«ããã·åºããã³ã¢ãªãŒã«ãªãã·åºãªã©ããéžã°
ããåºã§ïœã¯ïŒãïŒã®æŽæ°ã§ãããïœãïŒä»¥äžã®
ãšãR6ã¯åãã§ãç°ã€ãŠããŠãããããã ãäž
è¬åŒïŒïŒããã³ïŒïŒã§ã¯R5ãšïœåã®R6ãäž
è¬åŒïŒïŒã§ã¯R6ãšR7ã«å«ãŸããççŽ æ°ã®åèš
ã¯10ãè¶ããªããXâ³ã¯äžèšäžè¬åŒïŒïŒãïŒïŒ
ããã³ïŒïŒã衚ããã äžè¬åŒïŒïŒ äžè¬åŒïŒïŒ ââR8 äžè¬åŒïŒïŒ R8ã¯çœ®æãããã¯ç¡çœ®æã®ã¢ã«ãã«åºïŒããš
ãã°ããã«åºãããã·ã«åºãªã©ïŒãã¢ã©ã«ãã«åº
ïŒããšãã°ãã³ãžã«åºãªã©ïŒãã¢ã«ã±ãã«åºïŒããš
ãã°ã¢ãªã«åºãªã©ïŒãŸãã¯ç°ç¶ã¢ã«ãã«åºïŒããš
ãã°ã·ã¯ããã³ãã«åºãªã©ïŒã衚ãã眮æåºãšã
ãŠã¯ããã²ã³ååãã¢ã«ã³ãã·åºïŒããšãã°ãã
ãã·åºãããã·ã«ãªãã·åºãªã©ïŒãã¢ã·ã«ã¢ãã
åºïŒããšãã°ã¢ã»ãã¢ããåºãããã©ãžã«ã³ã¢ã
ãåºãªã©ïŒãã¢ã«ã³ãã·ã«ã«ããã«åºïŒããã©ã
ã·ã«ãªãã·ã«ã«ããã«åºãªã©ïŒãâã¢ã«ãã«ã«
ã«ãã¢ã€ã«åºïŒïŒ®âããã·ã«ã«ã«ãã¢ã€ã«åºãª
ã©ïŒããŠã¬ã€ãåºïŒããã©ãã·ã«ãŠã¬ã€ãåºãª
ã©ïŒãã·ã¢ãåºãã¢ãªãŒã«åºïŒããšãã«åºãªã©ïŒã
ãããåºãã¢ã«ãã«ããªåºïŒããã·ã«ããªåºãª
ã©ïŒãã¢ã«ãã«ã¹ã«ãã€ãã«åºïŒããã©ãã·ã«ã¹
ã«ãã€ãã«åºãªã©ïŒãã¢ã«ãã«ã¹ã«ãã³åºãã¢ã
ãªãåºãã¹ã«ãã³ã¢ããåºïŒãããµãã«ã³ã¹ã«ã
ã³ã¢ããåºãªã©ïŒãâã¢ã«ãã«ã¹ã«ãã¢ã¢ã€ã«
åºãã¢ãªãŒã«ãªãã·åºããã³ã¢ã·ã«åºïŒããã©ã
ã«ãã€ã«åºãªã©ïŒããéžã°ããïœååã¯ïœåã®
R8ã«å«ãŸããççŽ æ°ã®åèšã¯ïŒã32ã§ãããïœ
ã¯ïŒãïŒãïœã¯ïŒãïŒã®æŽæ°ã衚ããã äžè¬åŒ(1)ã§è¡šããããã«ãã©ãŒã®ãã¡ã奜ãŸã
ããã®ã¯æ¬¡ã®äžè¬åŒïŒXIïŒåã³ïŒXIIïŒã§ç€ºãã
ãã äžè¬åŒïŒXIïŒ äžè¬åŒïŒXIIïŒ R9ã¯æ°ŽçŽ ååãççŽ æ°10以äžã®èèªæåºïŒäŸ
ãã°ã¡ãã«ãã€ãœãããã«ãã¢ã·ã«ãã·ã¯ããã
ã·ã«ããªã¯ãã«ã®ãããªã¢ã«ãã«åºïŒãççŽ æ°10
以äžã®ã¢ã«ã³ãã·åºïŒäŸãã°ã¡ããã·ãã€ãœãã
ããã·ããã³ã¿ãã·ããã·ïŒãã¢ãªãŒã«ãªãã·åº
ïŒäŸãã°ããšããã·ãïœâtertâããã«ããšãã
ã·åºïŒã次åŒïŒïŒãïŒïŒã«ç€ºãã¢ã·ã«ã¢ã
ãåºãã¹ã«ãã³ã¢ããåºããŠã¬ã€ãåºãŸãã¯æ¬¡åŒ
ïŒïŒã«ç€ºãã«ã«ãã¢ã€ã«åºã衚ããã âNHâCOâ ïŒïŒ âNHâSO2â ïŒïŒ âNHCONHâ ïŒïŒ åŒäžïŒ§ãGâ²ã¯åäžã§ãç°ã€ãŠããŠããããã
ãããæ°ŽçŽ ååïŒäœãããGâ²ãåæã«æ°ŽçŽ å
åã§ããããšã¯ãªããããGâ²ã®åèšã®ççŽ æ°
ïŒãïŒïŒãççŽ æ°ïŒãïŒã®èèªæåºã奜ãŸããã¯
ççŽ æ°ïŒãïŒã®çŽéåã¯æåãããã¢ã«ãã«åºã
ç°ç¶ã¢ã«ãã«åºïŒããšãã°ã·ã¯ããããã«ãã·ã¯
ãããã·ã«ããã«ããã«ãªã©ïŒããŸãã¯ã¢ãªãŒã«
åºïŒäŸãã°ããšãã«ããããã«ãªã©ïŒã衚ããã
ããã§äžèšã®ã¢ã«ãã«åºãã¢ãªãŒã«åºã¯ããã²ã³
ååïŒäŸãã°ããçŽ ãå¡©çŽ ãªã©ïŒããããåºãã·
ã¢ãåºãæ°Žé žåºãã«ã«ããã·åºãã·ã¢ãåºïŒäŸã
ã°ã¢ãããã¢ã«ãã«ã¢ããããžã¢ã«ãã«ã¢ããã
ã¢ããªããâã¢ã«ãã«ã¢ããªããªã©ïŒãã¢ã«ã
ã«åºïŒäŸãã°åèšã®åŠããã®ïŒãã¢ãªãŒã«åºïŒäŸ
ãã°ããšãã«ãã¢ã»ãã«ã¢ããããšãã«ãªã©ïŒã
ã¢ã«ã³ãã·ã«ã«ããã«åºïŒäŸãã°ããã«ãªãã·ã«
ã«ããã«ãªã©ïŒãã¢ã·ã«ãªãã·ã«ã«ããã«åºãã¢
ããåºïŒäŸãã°ã¢ã»ãã¢ãããã¡ã¿ã³ã¹ã«ãã³ã¢
ãããªã©ïŒãã€ããåºïŒäŸãã°ã³ãã¯é žã€ãããª
ã©ïŒãã«ã«ãã¢ã€ã«åºïŒäŸãã°ïŒ®ïŒïŒ®âãžãšãã«
ã«ã«ãã¢ã€ã«ãªã©ïŒãã¹ã«ãã¢ã¢ã€ã«åºïŒäŸãã°
ïŒïŒ®âãžãšãã«ã¹ã«ãã¢ã¢ã€ã«ãªã©ïŒãã¢ã«ã³
ãã·åºïŒäŸãã°ãšããã·ãããã«ãªãã·ããªã¯ã
ã«ãªãã·ãªã©ïŒãã¢ãªãŒã«ãªãã·åºïŒäŸãã°ããš
ããã·ãã¡ãã«ããšããã·ããªã©ïŒçã§çœ®æãã
ãŠããŠããããR9ã¯äžèšã®çœ®æåºã®ä»ãéåžžçš
ãããã眮æåºãå«ãã§ãããŸããªããR10ã¯æ°Ž
çŽ ååãççŽ æ°10以äžã®èèªæåºãç¹ã«ççŽ æ°ïŒ
ã10ã®ã¢ã«ãã«åºãããã¯äžè¬åŒïŒïŒã§è¡šã
ãããã«ã«ãã¢ã€ã«åºããéžã°ãããR11ãR12ã
R13ãR14ãR15ããã³R16ã¯åã æ°ŽçŽ ååããã
ã²ã³ååãã¢ã«ãã«åºãã¢ãªãŒã«åºãã¢ã«ã³ãã·
åºãã¢ã«ãã«ããªåºããããç°åºãã¢ããåºãã«
ã«ãã³ã¢ããåºãã¹ã«ãã³ã¢ããåºãã¹ã«ãã¢ã
ã«åºãåã¯ã«ã«ããã«åºã衚ãããR11ã¯è©³ãã
ã¯æ¬¡ã®åºã®ããããã衚ããïŒ æ°ŽçŽ ååãããã²ã³ååïŒäŸãã°ã¯ãã«ããã
ã ãªã©ïŒãïŒãªãã12åã®ççŽ ååããã€ç¬¬äžã
第äºãŸãã¯ç¬¬äžã¢ã«ãã«åºïŒããšãã°ã¡ãã«ãã
ããã«ãã€ãœãããã«ãïœâããã«ã第äºãã
ã«ã第äžããã«ãããã·ã«ãããã·ã«ãïŒâã¯ã
ãããã«ãïŒâããããã·ãšãã«ãïŒâããšãã«
ãšãã«ãïŒâïŒïŒïŒïŒïŒïŒâããªã¯ããããšãã«ïŒ
ãšãã«ãïŒâã¢ãããšãã«çïŒãã¢ã«ãã«ããªåº
ïŒäŸãã°ãªã¯ãã«ããªãªã©ïŒãã¢ãªãŒã«åºïŒäŸãã°
ããšãã«ãïŒâã¡ãã«ããšãã«ãïŒïŒïŒïŒïŒâã
ãªã¯ããããšãã«ãïŒïŒïŒâãžããã¢ããšãã«ã
ïŒâããªãã«ãªãã¡ãã«ããšãã«ãïŒâããªãã«
ãªãã¡ãã«ããšãã«ãïŒâããªãã«ãªãã¡ãã«ã
ãšãã«ããããã«ãïŒâã¯ãããããã«ãïŒâãš
ãã«ãããã«çïŒãè€çŽ ç°åŒåºïŒäŸãã°ãã³ãŸã
ã©ãã«åºããã©ãã«åºããã¢ãŸãªã«åºããã³ãŸã
ã¢ãŸãªã«åºãããããã¢ãŸãªã«åºããªããµãŸãªã«
åºããã³ãºãªããµãŸãªã«åºãããããªããµãŸãªã«
åºãããªãžã«åºããããªãã«åºçïŒãã¢ããåº
ïŒäŸãã°ã¢ãããã¡ãã«ã¢ããããžãšãã«ã¢ããã
ããã·ã«ã¢ãããããšãã«ã¢ãããããªã«ã¢ã
ããïŒâã·ã¢ãããšãã«ã¢ãããïŒâããªãã«ãª
ãã¡ãã«ããšãã«ã¢ããããã³ãŸãã¢ãŸãŒã«ã¢ã
ãçïŒãã«ã«ãã³ã¢ããåºïŒäŸãã°ãšãã«ã«ã«ã
ã³ã¢ããããã·ã«ã«ã«ãã³ã¢ãããçã®åŠãã¢ã«
ãã«ã«ã«ãã³ã¢ããåºïŒããšãã«ã«ã«ãã³ã¢ã
ããïŒïŒïŒïŒïŒâããªã¯ããããšãã«ã«ã«ãã³ã¢
ãããïŒâã¡ãã«ããšãã«ã«ã«ãã³ã¢ãããïŒâ
ãšããã·ããšãã«ã«ã«ãã³ã¢ããããããã«ã«ã«
ãã³ã¢ããçã®åŠãã¢ãªãŒã«ã«ã«ãã³ã¢ããåºïŒ
ãã¢ãŸãªã«ã«ã«ãã³ã¢ããããã³ãŸãã¢ãŸãªã«ã«
ã«ãã³ã¢ãããããããã¢ãŸãªã«ã«ã«ãã³ã¢ã
ãããªããµãŸãªã«ã«ã«ãã³ã¢ããããã³ãŸãªããµ
ãŸãªã«ã«ã«ãã³ã¢ãããã€ãããŸãªã«ã«ã«ãã³ã¢
ããããã³ãºã€ãããŸãªã«ã«ã«ãã³ã¢ããçã®åŠ
ãè€çŽ ç°åŒã«ã«ãã³ã¢ããåºçïŒãã¹ã«ãã³ã¢ã
ãåºïŒäŸãã°ããã«ã¹ã«ãã³ã¢ãããããã·ã«ã¹
ã«ãã³ã¢ãããããšãã«ãšãã«ã¹ã«ãã³ã¢ããç
ã®åŠãã¢ã«ãã«ã¹ã«ãã³ã¢ããåºïŒããšãã«ã¹ã«
ãã³ã¢ãããïŒïŒïŒïŒïŒâããªã¯ããããšãã«ã¹
ã«ãã³ã¢ãããïŒâã¡ããã·ããšãã«ã¹ã«ãã³ã¢
ãããïŒâã«ã«ããã·ããšãã«ã¹ã«ãã³ã¢ããã
ãããã«ã¹ã«ãã³ã¢ããçã®åŠãã¢ãªãŒã«ã¹ã«ã
ã³ã¢ããåºïŒãã¢ãŸãªã«ã¹ã«ãã³ã¢ããããã³ãŸ
ãã¢ãŸãªã«ã¹ã«ãã³ã¢ãããã€ãããŸãªã«ã¹ã«ã
ã³ã¢ããããã³ãºã€ãããŸãªã«ã¹ã«ãã³ã¢ããã
ããªãžã«ã¹ã«ãã³ã¢ããçã®åŠãè€çŽ ç°åŒã¹ã«ã
ã³ã¢ããåºãªã©ïŒãã¹ã«ãã¢ãã«åºïŒäŸãã°ãã
ãã«ã¹ã«ãã¢ãã«ããªã¯ãã«ã¹ã«ãã¢ãã«çã®åŠ
ãã¢ã«ãã«ã¹ã«ãã¢ãã«åºïŒããšãã«ã¹ã«ãã¢ã
ã«ãïŒïŒïŒïŒïŒâããªã¯ããããšãã«ã¹ã«ãã¢ã
ã«ãïŒâã¡ããã·ããšãã«ã¹ã«ãã¢ãã«ãããã
ã«ã¹ã«ãã¢ãã«çã®åŠãã¢ãªãŒã«ã¹ã«ãã¢ãã«
åºïŒãã¢ãŸãªã«ã¹ã«ãã¢ãã«ããã³ãŸãã¢ãŸãªã«
ã¹ã«ãã¢ãã«ããªããµãŸãªã«ã¹ã«ãã¢ãã«ããã³
ãºã€ãããŸãªã«ã¹ã«ãã¢ãã«ãããªãžã«ã¹ã«ãã¢
ãã«åºçã®åŠãè€çŽ ç°åŒã¹ã«ãã¢ãã«åºãªã©ïŒã
ãã³ã«ã«ããã«åºïŒäŸãã°ãšãã«ã«ã«ããã«ããª
ã¯ãã«ã«ã«ããã«ãçã®åŠãã¢ã«ãã«ã«ã«ããã«
åºïŒããšãã«ã«ã«ããã«ãïŒïŒïŒïŒïŒâããªã¯ã
ãããšãã«ã«ã«ããã«çã®åŠãã¢ãªãŒã«ã«ã«ãã
ã«åºãããã³ãã¢ãŸãªã«ã«ã«ããã«ããã³ãŸãã¢
ãŸãªã«ã«ã«ããã«ããªããµãŸãªã«ã«ã«ããã«ãã€
ãããŸãªã«ã«ã«ããã«ããã³ãºã€ãããŸãªã«ã«ã«
ããã«åºçã®åŠãè€çŽ ç°åŒã«ã«ããã«åºãªã©ïŒã§
ãããR12ãR13ãR14ããã³R15ã詳ããã¯ãã
ããR11ã«ãããŠè©³ããæãããã®ãæããããš
ãã§ããããã ããäžè¬åŒïŒXIïŒã«ãããR9ã
R11ãR12ãåã³R13ãäžè¬åŒïŒXIIïŒã«ãããR10ã
R11ãR12ãR13ãR14ãåã³R15ã«å«ãŸããççŽ æ°
ã®åèšã¯ãããã10ãè¶ ããªããã¯äžèšã®åŠã
ïŒããã³ãŸãã¯ïŒå¡ç°ã圢æããã«å¿ èŠãªééå±
ååã衚ãããããªãã¡ãã³ãŒã³ç°ãã·ã¯ããã
ã»ã³ç°ãã·ã¯ããã³ãã³ç°ããã¢ãŸãŒã«ç°ããªã
ãµãŸãŒã«ç°ãã€ãããŸãŒã«ç°ãããªãžã³ç°ããã
ãŒã«ç°ãªã©ããã®ãã¡å¥œãŸãããã®ã¯ãã³ãŒã³ç°
ã§ããã ãã¯ççŽ æ°ïŒã32ã®åºããã¡ãââãâ
âãâïŒïŒ®âãä»ããŠã«ãããªã³ãšãŒãšçµåã
ãŠãããè³éŠæäžçŽã¢ãã³çŸåè¬ã®é žåäœãšã«ã
ããªã³ã°ãé¢è±ããåºã衚ããã奜ãŸããã¯ççŽ
æ°ïŒã32ã®ã¢ã«ã³ãã·ãã¢ãªãŒã«ãªãã·ãã¢ã«ã
ã«ããªãã¢ãªãŒã«ããªåºã衚ããããããã®åºã¯
æŽã«ââãââãâNHâãâCONHâãâ
COOâãâSO2NHâãâSOâãâSO2âãâCOâã
ããåºããã³ãºã¢ããåºïŒãã¢ããªãåºïŒäŸãã°
ïŒâã¯ããã¢ããªãåºãïŒâã¢ã»ãã¢ããã¢ããª
ãåºïŒãŸãã¯ãŠã¬ã€ãåºïŒäŸãã°ããšãã«ãŠã¬ã€
ãåºããã¿ã³ãŠã¬ã€ãåºïŒã衚ãããR6ããã³
R7ã¯åã ãããã²ã³ååãã¢ã«ãã«åºïŒäŸãã°
ã¡ãã«åºããšãã«åºïŒãã¢ã«ã³ãã·åºïŒäŸãã°ã¡
ããã·åºããšããã·åºïŒãã¢ã·ã«ã¢ããåºïŒäŸã
ã°ã¢ã»ãã¢ããåºããã³ãºã¢ããåºïŒãã¢ã«ã³ã
ã·ã«ã«ããã«åºïŒäŸãã°ã¡ããã·ã«ã«ããã«åºïŒã
âã¢ã«ãã«ã«ã«ãã¢ã€ã«åºïŒäŸãã°ïŒ®âã¡ãã«
ã«ã«ãã¢ã€ã«åºïŒããŠã¬ã€ãåºïŒäŸãã°ïŒ®âã¡ã
ã«ãŠã¬ã€ãåºïŒãã·ã¢ãåºãã¢ãªãŒã«åºïŒäŸãã°
ããšãã«åºããããã«åºïŒãïŒïŒ®âãžã¢ã«ãã«
ã¹ã«ãã¢ã¢ã€ã«åºããããåºãããããã·åºãã«
ã«ããã·åºããã³ã¢ãªãŒã«ãªãã·åºãªã©ããéžã°
ããåºã§ïœã¯ïŒãïŒã®æŽæ°ã§ãããïœãïŒä»¥äžã®
ãšãR6ã¯åãã§ãç°ã€ãŠããŠãããããã ãäž
è¬åŒïŒïŒããã³ïŒïŒã§ã¯R5ãšïœåã®R6ãäž
è¬åŒïŒïŒã§ã¯R6ãšR7ã«å«ãŸããççŽ æ°ã®åèš
ã¯10ãè¶ããªããXâ³ã¯äžèšäžè¬åŒïŒïŒãïŒïŒ
ããã³ïŒïŒã衚ããã äžè¬åŒïŒïŒ äžè¬åŒïŒïŒ ââR8 äžè¬åŒïŒïŒ R8ã¯çœ®æãããã¯ç¡çœ®æã®ã¢ã«ãã«åºïŒããš
ãã°ããã«åºãããã·ã«åºãªã©ïŒãã¢ã©ã«ãã«åº
ïŒããšãã°ãã³ãžã«åºãªã©ïŒãã¢ã«ã±ãã«åºïŒããš
ãã°ã¢ãªã«åºãªã©ïŒãŸãã¯ç°ç¶ã¢ã«ãã«åºïŒããš
ãã°ã·ã¯ããã³ãã«åºãªã©ïŒã衚ãã眮æåºãšã
ãŠã¯ããã²ã³ååãã¢ã«ã³ãã·åºïŒããšãã°ãã
ãã·åºãããã·ã«ãªãã·åºãªã©ïŒãã¢ã·ã«ã¢ãã
åºïŒããšãã°ã¢ã»ãã¢ããåºãããã©ãžã«ã³ã¢ã
ãåºãªã©ïŒãã¢ã«ã³ãã·ã«ã«ããã«åºïŒããã©ã
ã·ã«ãªãã·ã«ã«ããã«åºãªã©ïŒãâã¢ã«ãã«ã«
ã«ãã¢ã€ã«åºïŒïŒ®âããã·ã«ã«ã«ãã¢ã€ã«åºãª
ã©ïŒããŠã¬ã€ãåºïŒããã©ãã·ã«ãŠã¬ã€ãåºãª
ã©ïŒãã·ã¢ãåºãã¢ãªãŒã«åºïŒããšãã«åºãªã©ïŒã
ãããåºãã¢ã«ãã«ããªåºïŒããã·ã«ããªåºãª
ã©ïŒãã¢ã«ãã«ã¹ã«ãã€ãã«åºïŒããã©ãã·ã«ã¹
ã«ãã€ãã«åºãªã©ïŒãã¢ã«ãã«ã¹ã«ãã³åºãã¢ã
ãªãåºãã¹ã«ãã³ã¢ããåºïŒãããµãã«ã³ã¹ã«ã
ã³ã¢ããåºãªã©ïŒãâã¢ã«ãã«ã¹ã«ãã¢ã¢ã€ã«
åºãã¢ãªãŒã«ãªãã·åºããã³ã¢ã·ã«åºïŒããã©ã
ã«ãã€ã«åºãªã©ïŒããéžã°ããïœååã¯ïœåã®
R8ã«å«ãŸããççŽ æ°ã®åèšã¯ïŒã32ã§ãããïœ
ã¯ïŒãïŒãïœã¯ïŒãïŒã®æŽæ°ã衚ããã äžè¬åŒ(1)ã§è¡šããããã«ãã©ãŒã®ãã¡ã奜ãŸã
ããã®ã¯æ¬¡ã®äžè¬åŒïŒXIïŒåã³ïŒXIIïŒã§ç€ºãã
ãã äžè¬åŒïŒXIïŒ äžè¬åŒïŒXIIïŒ R9ã¯æ°ŽçŽ ååãççŽ æ°10以äžã®èèªæåºïŒäŸ
ãã°ã¡ãã«ãã€ãœãããã«ãã¢ã·ã«ãã·ã¯ããã
ã·ã«ããªã¯ãã«ã®ãããªã¢ã«ãã«åºïŒãççŽ æ°10
以äžã®ã¢ã«ã³ãã·åºïŒäŸãã°ã¡ããã·ãã€ãœãã
ããã·ããã³ã¿ãã·ããã·ïŒãã¢ãªãŒã«ãªãã·åº
ïŒäŸãã°ããšããã·ãïœâtertâããã«ããšãã
ã·åºïŒã次åŒïŒïŒãïŒïŒã«ç€ºãã¢ã·ã«ã¢ã
ãåºãã¹ã«ãã³ã¢ããåºããŠã¬ã€ãåºãŸãã¯æ¬¡åŒ
ïŒïŒã«ç€ºãã«ã«ãã¢ã€ã«åºã衚ããã âNHâCOâ ïŒïŒ âNHâSO2â ïŒïŒ âNHCONHâ ïŒïŒ åŒäžïŒ§ãGâ²ã¯åäžã§ãç°ã€ãŠããŠããããã
ãããæ°ŽçŽ ååïŒäœãããGâ²ãåæã«æ°ŽçŽ å
åã§ããããšã¯ãªããããGâ²ã®åèšã®ççŽ æ°
ïŒãïŒïŒãççŽ æ°ïŒãïŒã®èèªæåºã奜ãŸããã¯
ççŽ æ°ïŒãïŒã®çŽéåã¯æåãããã¢ã«ãã«åºã
ç°ç¶ã¢ã«ãã«åºïŒããšãã°ã·ã¯ããããã«ãã·ã¯
ãããã·ã«ããã«ããã«ãªã©ïŒããŸãã¯ã¢ãªãŒã«
åºïŒäŸãã°ããšãã«ããããã«ãªã©ïŒã衚ããã
ããã§äžèšã®ã¢ã«ãã«åºãã¢ãªãŒã«åºã¯ããã²ã³
ååïŒäŸãã°ããçŽ ãå¡©çŽ ãªã©ïŒããããåºãã·
ã¢ãåºãæ°Žé žåºãã«ã«ããã·åºãã·ã¢ãåºïŒäŸã
ã°ã¢ãããã¢ã«ãã«ã¢ããããžã¢ã«ãã«ã¢ããã
ã¢ããªããâã¢ã«ãã«ã¢ããªããªã©ïŒãã¢ã«ã
ã«åºïŒäŸãã°åèšã®åŠããã®ïŒãã¢ãªãŒã«åºïŒäŸ
ãã°ããšãã«ãã¢ã»ãã«ã¢ããããšãã«ãªã©ïŒã
ã¢ã«ã³ãã·ã«ã«ããã«åºïŒäŸãã°ããã«ãªãã·ã«
ã«ããã«ãªã©ïŒãã¢ã·ã«ãªãã·ã«ã«ããã«åºãã¢
ããåºïŒäŸãã°ã¢ã»ãã¢ãããã¡ã¿ã³ã¹ã«ãã³ã¢
ãããªã©ïŒãã€ããåºïŒäŸãã°ã³ãã¯é žã€ãããª
ã©ïŒãã«ã«ãã¢ã€ã«åºïŒäŸãã°ïŒ®ïŒïŒ®âãžãšãã«
ã«ã«ãã¢ã€ã«ãªã©ïŒãã¹ã«ãã¢ã¢ã€ã«åºïŒäŸãã°
ïŒïŒ®âãžãšãã«ã¹ã«ãã¢ã¢ã€ã«ãªã©ïŒãã¢ã«ã³
ãã·åºïŒäŸãã°ãšããã·ãããã«ãªãã·ããªã¯ã
ã«ãªãã·ãªã©ïŒãã¢ãªãŒã«ãªãã·åºïŒäŸãã°ããš
ããã·ãã¡ãã«ããšããã·ããªã©ïŒçã§çœ®æãã
ãŠããŠããããR9ã¯äžèšã®çœ®æåºã®ä»ãéåžžçš
ãããã眮æåºãå«ãã§ãããŸããªããR10ã¯æ°Ž
çŽ ååãççŽ æ°10以äžã®èèªæåºãç¹ã«ççŽ æ°ïŒ
ã10ã®ã¢ã«ãã«åºãããã¯äžè¬åŒïŒïŒã§è¡šã
ãããã«ã«ãã¢ã€ã«åºããéžã°ãããR11ãR12ã
R13ãR14ãR15ããã³R16ã¯åã æ°ŽçŽ ååããã
ã²ã³ååãã¢ã«ãã«åºãã¢ãªãŒã«åºãã¢ã«ã³ãã·
åºãã¢ã«ãã«ããªåºããããç°åºãã¢ããåºãã«
ã«ãã³ã¢ããåºãã¹ã«ãã³ã¢ããåºãã¹ã«ãã¢ã
ã«åºãåã¯ã«ã«ããã«åºã衚ãããR11ã¯è©³ãã
ã¯æ¬¡ã®åºã®ããããã衚ããïŒ æ°ŽçŽ ååãããã²ã³ååïŒäŸãã°ã¯ãã«ããã
ã ãªã©ïŒãïŒãªãã12åã®ççŽ ååããã€ç¬¬äžã
第äºãŸãã¯ç¬¬äžã¢ã«ãã«åºïŒããšãã°ã¡ãã«ãã
ããã«ãã€ãœãããã«ãïœâããã«ã第äºãã
ã«ã第äžããã«ãããã·ã«ãããã·ã«ãïŒâã¯ã
ãããã«ãïŒâããããã·ãšãã«ãïŒâããšãã«
ãšãã«ãïŒâïŒïŒïŒïŒïŒïŒâããªã¯ããããšãã«ïŒ
ãšãã«ãïŒâã¢ãããšãã«çïŒãã¢ã«ãã«ããªåº
ïŒäŸãã°ãªã¯ãã«ããªãªã©ïŒãã¢ãªãŒã«åºïŒäŸãã°
ããšãã«ãïŒâã¡ãã«ããšãã«ãïŒïŒïŒïŒïŒâã
ãªã¯ããããšãã«ãïŒïŒïŒâãžããã¢ããšãã«ã
ïŒâããªãã«ãªãã¡ãã«ããšãã«ãïŒâããªãã«
ãªãã¡ãã«ããšãã«ãïŒâããªãã«ãªãã¡ãã«ã
ãšãã«ããããã«ãïŒâã¯ãããããã«ãïŒâãš
ãã«ãããã«çïŒãè€çŽ ç°åŒåºïŒäŸãã°ãã³ãŸã
ã©ãã«åºããã©ãã«åºããã¢ãŸãªã«åºããã³ãŸã
ã¢ãŸãªã«åºãããããã¢ãŸãªã«åºããªããµãŸãªã«
åºããã³ãºãªããµãŸãªã«åºãããããªããµãŸãªã«
åºãããªãžã«åºããããªãã«åºçïŒãã¢ããåº
ïŒäŸãã°ã¢ãããã¡ãã«ã¢ããããžãšãã«ã¢ããã
ããã·ã«ã¢ãããããšãã«ã¢ãããããªã«ã¢ã
ããïŒâã·ã¢ãããšãã«ã¢ãããïŒâããªãã«ãª
ãã¡ãã«ããšãã«ã¢ããããã³ãŸãã¢ãŸãŒã«ã¢ã
ãçïŒãã«ã«ãã³ã¢ããåºïŒäŸãã°ãšãã«ã«ã«ã
ã³ã¢ããããã·ã«ã«ã«ãã³ã¢ãããçã®åŠãã¢ã«
ãã«ã«ã«ãã³ã¢ããåºïŒããšãã«ã«ã«ãã³ã¢ã
ããïŒïŒïŒïŒïŒâããªã¯ããããšãã«ã«ã«ãã³ã¢
ãããïŒâã¡ãã«ããšãã«ã«ã«ãã³ã¢ãããïŒâ
ãšããã·ããšãã«ã«ã«ãã³ã¢ããããããã«ã«ã«
ãã³ã¢ããçã®åŠãã¢ãªãŒã«ã«ã«ãã³ã¢ããåºïŒ
ãã¢ãŸãªã«ã«ã«ãã³ã¢ããããã³ãŸãã¢ãŸãªã«ã«
ã«ãã³ã¢ãããããããã¢ãŸãªã«ã«ã«ãã³ã¢ã
ãããªããµãŸãªã«ã«ã«ãã³ã¢ããããã³ãŸãªããµ
ãŸãªã«ã«ã«ãã³ã¢ãããã€ãããŸãªã«ã«ã«ãã³ã¢
ããããã³ãºã€ãããŸãªã«ã«ã«ãã³ã¢ããçã®åŠ
ãè€çŽ ç°åŒã«ã«ãã³ã¢ããåºçïŒãã¹ã«ãã³ã¢ã
ãåºïŒäŸãã°ããã«ã¹ã«ãã³ã¢ãããããã·ã«ã¹
ã«ãã³ã¢ãããããšãã«ãšãã«ã¹ã«ãã³ã¢ããç
ã®åŠãã¢ã«ãã«ã¹ã«ãã³ã¢ããåºïŒããšãã«ã¹ã«
ãã³ã¢ãããïŒïŒïŒïŒïŒâããªã¯ããããšãã«ã¹
ã«ãã³ã¢ãããïŒâã¡ããã·ããšãã«ã¹ã«ãã³ã¢
ãããïŒâã«ã«ããã·ããšãã«ã¹ã«ãã³ã¢ããã
ãããã«ã¹ã«ãã³ã¢ããçã®åŠãã¢ãªãŒã«ã¹ã«ã
ã³ã¢ããåºïŒãã¢ãŸãªã«ã¹ã«ãã³ã¢ããããã³ãŸ
ãã¢ãŸãªã«ã¹ã«ãã³ã¢ãããã€ãããŸãªã«ã¹ã«ã
ã³ã¢ããããã³ãºã€ãããŸãªã«ã¹ã«ãã³ã¢ããã
ããªãžã«ã¹ã«ãã³ã¢ããçã®åŠãè€çŽ ç°åŒã¹ã«ã
ã³ã¢ããåºãªã©ïŒãã¹ã«ãã¢ãã«åºïŒäŸãã°ãã
ãã«ã¹ã«ãã¢ãã«ããªã¯ãã«ã¹ã«ãã¢ãã«çã®åŠ
ãã¢ã«ãã«ã¹ã«ãã¢ãã«åºïŒããšãã«ã¹ã«ãã¢ã
ã«ãïŒïŒïŒïŒïŒâããªã¯ããããšãã«ã¹ã«ãã¢ã
ã«ãïŒâã¡ããã·ããšãã«ã¹ã«ãã¢ãã«ãããã
ã«ã¹ã«ãã¢ãã«çã®åŠãã¢ãªãŒã«ã¹ã«ãã¢ãã«
åºïŒãã¢ãŸãªã«ã¹ã«ãã¢ãã«ããã³ãŸãã¢ãŸãªã«
ã¹ã«ãã¢ãã«ããªããµãŸãªã«ã¹ã«ãã¢ãã«ããã³
ãºã€ãããŸãªã«ã¹ã«ãã¢ãã«ãããªãžã«ã¹ã«ãã¢
ãã«åºçã®åŠãè€çŽ ç°åŒã¹ã«ãã¢ãã«åºãªã©ïŒã
ãã³ã«ã«ããã«åºïŒäŸãã°ãšãã«ã«ã«ããã«ããª
ã¯ãã«ã«ã«ããã«ãçã®åŠãã¢ã«ãã«ã«ã«ããã«
åºïŒããšãã«ã«ã«ããã«ãïŒïŒïŒïŒïŒâããªã¯ã
ãããšãã«ã«ã«ããã«çã®åŠãã¢ãªãŒã«ã«ã«ãã
ã«åºãããã³ãã¢ãŸãªã«ã«ã«ããã«ããã³ãŸãã¢
ãŸãªã«ã«ã«ããã«ããªããµãŸãªã«ã«ã«ããã«ãã€
ãããŸãªã«ã«ã«ããã«ããã³ãºã€ãããŸãªã«ã«ã«
ããã«åºçã®åŠãè€çŽ ç°åŒã«ã«ããã«åºãªã©ïŒã§
ãããR12ãR13ãR14ããã³R15ã詳ããã¯ãã
ããR11ã«ãããŠè©³ããæãããã®ãæããããš
ãã§ããããã ããäžè¬åŒïŒXIïŒã«ãããR9ã
R11ãR12ãåã³R13ãäžè¬åŒïŒXIIïŒã«ãããR10ã
R11ãR12ãR13ãR14ãåã³R15ã«å«ãŸããççŽ æ°
ã®åèšã¯ãããã10ãè¶ ããªããã¯äžèšã®åŠã
ïŒããã³ãŸãã¯ïŒå¡ç°ã圢æããã«å¿ èŠãªééå±
ååã衚ãããããªãã¡ãã³ãŒã³ç°ãã·ã¯ããã
ã»ã³ç°ãã·ã¯ããã³ãã³ç°ããã¢ãŸãŒã«ç°ããªã
ãµãŸãŒã«ç°ãã€ãããŸãŒã«ç°ãããªãžã³ç°ããã
ãŒã«ç°ãªã©ããã®ãã¡å¥œãŸãããã®ã¯ãã³ãŒã³ç°
ã§ããã ãã¯ççŽ æ°ïŒã32ã®åºããã¡ãââãâ
âãâïŒïŒ®âãä»ããŠã«ãããªã³ãšãŒãšçµåã
ãŠãããè³éŠæäžçŽã¢ãã³çŸåè¬ã®é žåäœãšã«ã
ããªã³ã°ãé¢è±ããåºã衚ããã奜ãŸããã¯ççŽ
æ°ïŒã32ã®ã¢ã«ã³ãã·ãã¢ãªãŒã«ãªãã·ãã¢ã«ã
ã«ããªãã¢ãªãŒã«ããªåºã衚ããããããã®åºã¯
æŽã«ââãââãâNHâãâCONHâãâ
COOâãâSO2NHâãâSOâãâSO2âãâCOâã
ãåŒãçã®äºäŸ¡ã®åº
ãå«ãã§ããŠããããæŽã«ãããã®åºã¯â
COOHãâSO3HãâOHãâSO2NH2ã®ããã«ã¢ã«
ã«ãªã§è§£é¢ããåºãå«ãããšãç¹ã«å¥œãŸããããŸ
ãR9ãR10ãR11ãR12ãR13ãR14ãR15ããã
çµåããããšã§ã«ãã©ãŒãå®è³ªäžèæ¡æ£åããã
ãšãå¯èœã§ããã è²çŽ æ¡æ£åã«ãã©ãŒã®å ·äœäŸãäžèšã«ç€ºãã æ¬çºæã«ããããããã®ååç©ã¯ç±³åœç¹èš±ç¬¬
4264723å·ã第3227554å·ã第4310619å·ã第
4301235å·ãç¹éæ57â4044å·ã56â126833å·ã
50â122935å·ãªã©ã«èšèŒã®æ¹æ³ã«ãã€ãŠåæã§ã
ãã æ¬çºæã«ä¿ããããã®ååç©ã¯ç¹éæ56â1938
å·ãå57â3934å·ãå53â105226å·çã«èšèŒãã
ãæ¹æ³ã§å®¹æã«åæã§ããã æ¬çºæã«ãããå忣ããã²ã³åéä¹³å€ãšã¯ã
ã¢ããŒãã€ãŒäžãéãæã®é»æ°äŒå°åºŠã®å·®ããæ±
ããããã²ã³åéå šç²åã®ééåã¯åæ°ååžã«ã
ããŠããã²ã³åéã®å¹³åç²åãµã€ãºã®0.6åãã
1.4åã®å€ã®ç¯å²ã«ããã²ã³åéå šç²åã®90ïŒ ä»¥
äžãå«ãŸãããããªä¹³å€ãããã ãã®å忣乳å€ã®å¹³åç²åãµã€ãºã¯0.1ÎŒã3ÎŒã
奜ãŸããã¯0.4ÎŒã2ÎŒã§ãããããã²ã³åéçµæã¯
èåéãå¡©åéãå¡©èåéãæ²èåéãå¡©æ²èå
éãããã§ãããããïŒã¢ã«ïŒ 以äžã®æ²åéãå«
ãæ²èåéã§ç¹ã«ãã®å¹æã倧ããã æ¬çºæã®å忣乳å€ã¯ãç±³åœç¹èš±ç¬¬3574623å·
æçްæžã«èšèŒãããæ¹æ³ãè±åœç¹èš±1520976å·æ
现æžã«èšèŒã®æ¹æ³ãç¡é žéãšã¢ã«ã«ãªãã©ã€ãã
åæã«æ··åããŠåå¿æ¶²äžã®pAgãäžå®ã«ä¿ã¡ã€ã€
ããã²ã³åéç²åãäœãããããã³ã³ãããŒã«ã
ããã«ãžãšããæ³ãããã³ã¢ã³ã¢ãã¢ãçšããŠæ¡
æ£åŸéã®æ¡ä»¶äžã§ç²åãæé·ãããæ¹æ³ïŒç¹éæ
55â142329ïŒãªã©ã§è£œé ããããšãã§ããã åçä¹³å€ã®çµåå€ãŸãã¯ä¿è·ã³ãã€ããšããŠ
ã¯ããŒã©ãã³ãçšããã®ãæå©ã§ãããããã以
å€ã®èŠªæ°Žæ§ã³ãã€ããçšããããšãã§ããã ããšãã°ãŒã©ãã³èªå°äœããŒã©ãã³ãšä»ã®é«å
åãšã®ã°ã©ããããªããŒãã¢ã«ããã³ãã«ãŒã€ã³
çã®èçœè³ªïŒããããã·ãšãã«ã»ã«ããŒã¹ãã«ã«
ããã·ã¡ãã«ã»ã«ããŒã¹ãã»ã«ããŒãºç¡«é žãšã¹ã
ã«é¡çã®åŠãã»ã«ããŒã¹èªå°äœãã¢ã«ã®ã³é žãœãŒ
ããæŸ±ç²èªå°äœãªã©ã®ç³èªå°äœïŒããªããã«ã¢ã«
ã³ãŒã«ãããªããã«ã¢ã«ã³ãŒã«éšåã¢ã»ã¿ãŒã«ã
ããªââããã«ãããªãã³ãããªã¢ã¯ãªã«é žã
ããªã¡ã¿ã¯ãªã«é žãããªã¢ã¯ãªã«ã¢ãããããªã
ãã«ã€ãããŸãŒã«ãããªããã«ãã©ãŸãŒã«çã®å
äžãããã¯å ±éåäœã®åŠãå€çš®ã®åæèŠªæ°Žæ§é«å
åç©è³ªãçšããããšãã§ããã ãŒã©ãã³ãšããŠã¯ç³ç°åŠçãŒã©ãã³ã®ã»ãé žåŠ
çãŒã©ãã³ãBull.Soc.Sci.Phot.JapanãNo.16ã
30é ïŒ1966ïŒã«èšèŒããããããªé µçŽ åŠçãŒã©ã
ã³ãçšããŠããããåãŒã©ãã³ã®å æ°Žåè§£ãé µçŽ
åè§£ç©ãçšããããšãã§ããã ããã²ã³åéç²å圢æãŸãã¯ç©ççæã®éçšã«
ãããŠãã«ãããŠã å¡©ãäºéå¡©ãéå¡©ãã¿ãªãŠã
å¡©ãã€ãªãžãŠã å¡©ãŸãã¯ãã®é¯å¡©ãããžãŠã å¡©ãŸ
ãã¯ãã®é¯å¡©ãéå¡©ãŸãã¯éé¯å¡©ãªã©ãå ±åãã
ãŠãããã æ¬çºæã®æå ææã®åçä¹³å€å±€ãŸãã¯ä»ã®èŠªæ°Ž
æ§ã³ãã€ãå±€ã«ã¯å¡åžå©å€ã垯é»é²æ¢ãã¹ããªæ§
æ¹è¯ãä¹³ååæ£ãæ¥ç鲿¢ããã³åçç¹æ§æ¹è¯
ïŒããšãã°çŸåä¿é²ã硬調åã墿ïŒãªã©çš®ã ã®
ç®çã§çš®ã ã®ç颿޻æ§å€ãå«ãã§ãããã ããšãã°ãµããã³ïŒã¹ããã€ãç³»ïŒãã¢ã«ãã¬
ã³ãªããµã€ãèªå°äœïŒäŸãã°ããªãšãã¬ã³ã°ãªã³
ãŒã«ãããªãšãã¬ã³ã°ãªã³ãŒã«ïŒããªãããã¬ã³
ã°ãªã³ãŒã«çž®åç©ãããªãšãã¬ã³ã°ãªã³ãŒã«ã¢ã«
ãã«ãšãŒãã«é¡ãŸãã¯ããªãšãã¬ã³ã°ãªã³ãŒã«ã¢
ã«ãã«ã¢ãªãŒã«ãšãŒãã«é¡ãããªãšãã¬ã³ã°ãªã³
ãŒã«ãšã¹ãã«é¡ãããªãšãã¬ã³ã°ãªã³ãŒã«ãœã«ã
ã¿ã³ãšã¹ãã«é¡ãããªã¢ã«ãã¬ã³ã°ãªã³ãŒã«ã¢ã«
ãã«ã¢ãã³ãŸãã¯ã¢ããé¡ãã·ãªã³ãŒã³ã®ããªãš
ãã¬ã³ãªããµã€ãä»å ç©é¡ïŒãã°ãªã·ããŒã«èªå°
äœïŒããšãã°ã¢ã«ã±ãã«ã³ãã¯é žããªã°ãªã»ãª
ããã¢ã«ãã«ããšããŒã«ããªã°ãªã»ãªãïŒãå€äŸ¡
ã¢ã«ã³ãŒã«ã®èèªé žãšã¹ãã«é¡ãç³ã®ã¢ã«ãã«ãš
ã¹ãã«é¡ãªã©ã®éã€ãªã³æ§ç颿޻æ§å€ïŒã¢ã«ãã«
ã«ã«ãã³é žå¡©ãã¢ã«ãã«ã¹ã«ããªã³é žå¡©ãã¢ã«ã
ã«ãã³ãŒã³ã¹ã«ããªã³é žå¡©ãã¢ã«ãã«ããã¿ã¬ã³
ã¹ã«ããªã³é žå¡©ãã¢ã«ãã«ç¡«é žãšã¹ãã«é¡ãã¢ã«
ãã«ãªã³é žãšã¹ãã«é¡ãâã¢ã·ã«ââã¢ã«ã
ã«ã¿ãŠãªã³é¡ãã¹ã«ãã³ãã¯é žãšã¹ãã«é¡ãã¹ã«
ãã¢ã«ãã«ããªãªãã·ãšãã¬ã³ã¢ã«ãã«ããšãã«
ãšãŒãã«é¡ãããªãªãã·ãšãã¬ã³ã¢ã«ãã«ãªã³é ž
ãšã¹ãã«é¡ãªã©ã®ãããªãã«ã«ããã·åºãã¹ã«ã
åºããã¹ãåºãç¡«é žãšã¹ãã«åºãçé žãšã¹ãã«åº
çã®é žæ§åºãå«ãã¢ããªã³ç颿޻æ§å€ïŒã¢ããé ž
é¡ãã¢ããã¢ã«ãã«ã¹ã«ãã³é žé¡ãã¢ããã¢ã«ã
ã«ç¡«é žãŸãã¯çé žãšã¹ãã«é¡ãã¢ã«ãã«ãã¿ã€ã³
é¡ãã¢ãã³ãªãã·ãé¡ãªã©ã®äž¡æ§ç颿޻æ§å€ïŒã¢
ã«ãã«ã¢ãã³å¡©é¡ãèèªæãããã¯è³éŠæç¬¬ïŒçŽ
ã¢ã³ã¢ããŠã å¡©é¡ãããªãžããŠã ãã€ãããŸãªãŠ
ã ãªã©ã®è€çŽ ç°ç¬¬ïŒçŽã¢ã³ã¢ããŠã å¡©é¡ãããã³
èèªæãŸãã¯è€çŽ ç°ãå«ããã¹ãããŠã ãŸãã¯ã¹
ã«ãããŠã å¡©é¡ãªã©ã®ã«ããªã³ç颿޻æ§å€ãçšã
ãããšãã§ããã æ¬çºæã®åçæå ææã®åçä¹³å€å±€ã«ã¯æåºŠäž
æãã³ã³ãã©ã¹ãäžæããŸãã¯çŸåä¿é²ã®ç®ç
ã§ãäŸãã°ããªã¢ã«ãã¬ã³ãªãã·ããŸãã¯ãã®ãš
ãŒãã«ããšã¹ãã«ãã¢ãã³ãªã©ã®èªå°äœãããªãš
ãŒãã«ååç©ãããªã¢ã«ããªãªã³é¡ãåçŽã¢ã³ã¢
ããŠã å¡©ååç©ããŠã¬ã¿ã³èªå°äœãå°¿çŽ èªå°äœã
ã€ãããŸãŒã«èªå°äœãïŒâãã©ãŸãªãã³é¡çãå«
ãã§ããããäŸãã°ç±³åœç¹èš±2400532å·ãå
2423549å·ãå2716062å·ãå3617280å·ãå
3772021å·ãå3808003å·ãè±åœç¹èš±1488991å·ç
ã«èšèŒããããã®ãçšããããšãã§ããã æ¬çºæãçšããŠäœãããåçæå ææã«ã¯ã寞
æ³å®å®æ§ã®æ¹è¯ãªã©ã®ç®çã§ãæ°Žäžæº¶ãŸãã¯é£æº¶
æ§åæããªããŒã®åæ£ç©ãå«ãããšãã§ãããã
ãšãã°ã¢ã«ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããã¢ã«ã³ã
ã·ã¢ã«ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããã°ãªã·ãžã«
ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããïŒã¡ã¿ïŒã¢ã¯ãªã«ã¢ããã
ããã«ãšã¹ãã«ïŒããšãã°é ¢é žããã«ïŒãã¢ã¯ãª
ããããªã«ããªã¬ãã€ã³ãã¹ãã¬ã³ãªã©ã®åç¬ã
ããã¯çµåãããŸãã¯ããããšã¢ã¯ãªã«é žãã¡ã¿
ã¢ã¯ãªã«é žãαïŒÎ²âäžé£œåãžã«ã«ãã³é žããã
ããã·ã¢ã«ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããã¹ã«ããª
ã¢ã«ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããã¹ãã¬ã³ã¹ã«ã
ãªã³é žãªã©ãšã®çµåããåéäœæåãšããããªã
ãŒãçšããããšãã§ããã æ¬çºæãçšããŠäœãããæå ææã®åçåŠçã«
ã¯ãäŸãã°ãªãµãŒãã»ãã€ã¹ã¯ããŒãžã€ãŒ
ïŒResearch DisclosureïŒ176å·ç¬¬28ã30é ïŒRD
â17643ïŒã«èšèŒãããŠãããããªãå ¬ç¥ã®æ¹æ³
åã³å ¬ç¥ã®åŠçæ¶²ã®ãããããé©çšããããšãã§
ããããã®åçåŠçã¯ãç®çã«å¿ããŠãéç»åã
圢æããåçåŠçïŒé»çœåçåŠçïŒããããã¯è²
çŽ åã圢æããåçåŠçïŒã«ã©ãŒåçåŠçïŒã®ã
ããã§ãã€ãŠããããåŠçæž©åºŠã¯æ®é18âãã50
âã®éã«éžã°ãããã18âããäœã枩床ãŸãã¯50
âãè¶ããæž©åºŠãšããŠãããã å®çæ¶²ãšããŠã¯äžè¬ã«çšããããçµæã®ãã®ã
çšããããšãã§ãããå®çå€ãšããŠã¯ããªç¡«é ž
å¡©ãããªã·ã¢ã³é žå¡©ã®ã»ããå®çå€ãšããŠã®å¹æ
ãç¥ãããŠããææ©ç¡«é»ååç©ãçšããããšãã§
ãããå®çæ¶²ã«ã¯ç¡¬èå€ãšããŠæ°Žæº¶æ§ã¢ã«ãããŠ
ã å¡©ãå«ãã§ãããã è²çŽ åã圢æããå Žåã«ã¯åžžæ³ãé©çšã§ããã
ããšãã°ããã¬ããžæ³ïŒäŸãã°âJournal of the
Society of Motion Picture and Television
Engineersâã61å·»ïŒ1953幎ïŒã667ã701é ã«èšèŒ
ãããŠããïŒïŒé»çœçŸåäž»è¬ãå«ãçŸåæ¶²ã§çŸå
ããŠãã¬éåãã€ãããã€ãã§å°ãªããšãäžåã®
äžæ§ãªé²å ãŸãã¯ä»ã®é©åœãªã«ããªåŠçãè¡ãª
ããåŒãç¶ããŠçºè²çŸåãè¡ãªãããšã«ããè²çŽ
éœç»åãåŸãã«ã©ãŒå転æ³ãªã©ãçšããããã ã«ã©ãŒçŸåæ¶²ã¯ãäžè¬ã«çºè²çŸåäž»è¬ãå«ãã¢
ã«ã«ãªæ§æ°Žæº¶æ¶²ããæããçºè²çŸåäž»è¬ã¯å ¬ç¥ã®
äžçŽè³éŠæã¢ãã³çŸåå€ãäŸãã°ããšãã¬ã³ãžã¢
ãã³é¡ïŒäŸãã°ïŒâã¢ããâïŒïŒ®âãžãšãã«ã¢
ããªã³ãïŒâã¡ãã«âïŒâã¢ããâïŒïŒ®âãžãš
ãã«ã¢ããªã³ãïŒâã¢ããââãšãã«ââβ
âããããã·ãšãã«ã¢ããªã³ãïŒâã¡ãã«âïŒâ
ã¢ããââãšãã«ââβâããããã·ãšãã«
ã¢ããªã³ãïŒâã¡ãã«âïŒâã¢ããââãšãã«
ââβâã¡ã¿ã³ã¹ã«ãã¢ãããšãã«ã¢ããªã³ã
ïŒâã¢ããâïŒâã¡ãã«ââãšãã«ââβâ
ã¡ããã·ãšãã«ã¢ããªã³ãªã©ïŒãçšããããšãã§
ããã ãã®ä»L.F.A.MasonèPhotographic
Processing ChemistryïŒFocal Pressåã1966幎ïŒ
ã®226ã229é ãç±³åœç¹èš±2193015å·ãå2592364
å·ãç¹éæ48â64933å·ãªã©ã«èšèŒã®ãã®ãçšã
ãŠããã ã«ã©ãŒçŸåæ¶²ã¯ãã®ã»ãPHç·©è¡å€ãçŸåæå¶å€
ãªããã«ããªé²æ¢å€ãªã©ãå«ãããšãã§ããããŸ
ãå¿ èŠã«å¿ããŠã硬氎è»åå€ãä¿æå€ãææ©æº¶
å€ãçŸåä¿é²å€ãè²çŽ åœ¢æã«ãã©ãŒããã¶ãã
å€ãè£å©çŸåè¬ãç²æ§ä»äžå€ãããªã«ã«ãã³é žç³»
ãã¬ãŒãå€ãé žå鲿¢å€ãªã©ãå«ãã§ãããã ãããæ·»å å€ã®å ·äœäŸã¯ãªãµãŒãã»ãã€ã¹ã¯ã
ãŒãžã€ãŒïŒRDâ17643ïŒã®ä»ãç±³åœç¹èš±ç¬¬
4083723å·ã西ç¬å ¬éïŒOLSïŒ2622950å·ãªã©ã«
èšèŒãããŠããã çºè²çŸååŸã®åçä¹³å€å±€ã¯éåžžãæŒçœåŠçãã
ããæŒçœåŠçã¯å®çåŠçãšåæã«è¡ãªãããŠãã
ãããåå¥ã«è¡ãªãããŠããããæŒçœå€ãšããŠã¯
éïŒïŒãã³ãã«ãïŒïŒãã¯ãã ïŒïŒãé ïŒïŒ
ãªã©ã®å€äŸ¡éå±ã®ååç©ãéé žé¡ãããã³é¡ãã
ãããœååç©ãªã©ãçšããããã ããšãã°ããšãªã·ã¢ã³åç©ïŒéã¯ãã é žå¡©ïŒé
ïŒïŒãŸãã¯ã³ãã«ãïŒïŒã®ææ©é¯å¡©ãããšã
ã°ãšãã¬ã³ãžã¢ãã³åé ¢é žããããªãããªé ¢é žã
ïŒïŒïŒâãžã¢ãã³âïŒâãããããŒã«åé ¢é žãªã©
ã®ã¢ããããªã«ã«ãã³é žé¡ãããã¯ã¯ãšã³é žãé
ç³é žããªã³ãŽé žãªã©ã®ææ©é žã®é¯å¡©ïŒéç¡«é žå¡©ã
éãã³ã¬ã³é žå¡©ïŒããããœããšããŒã«ãªã©ãçšã
ãããšãã§ããããããã®ãã¡ããšãªã·ã¢ã³åã«
ãªããšãã¬ã³ãžã¢ãã³åé ¢é žéïŒïŒãããªãŠã
ããã³ãšãã¬ã³ãžã¢ãã³åé ¢é žéïŒïŒã¢ã³ã¢ã
ãŠã ã¯ç¹ã«æçšã§ããããšãã¬ã³ãžã¢ãã³åé ¢é ž
éïŒïŒé¯å¡©ã¯ç¬ç«ã®æŒçœæ¶²ã«ãããŠããäžæ²¿æŒ
çœå®çæ¶²ã«ãããŠãæçšã§ããã æŒçœãŸãã¯æŒçœå®çæ¶²ã«ã¯ãç±³åœç¹èš±3042520
å·ãå3241966å·ãç¹å ¬æ45â8506å·ãç¹å ¬æ45
â8836å·ãªã©ã«èšèŒã®æŒçœä¿é²å€ãç¹éæ53â
65732å·ã«èšèŒã®ããªãŒã«ååç©ã®ä»ãçš®ã ã®æ·»
å å€ãå ããããšãã§ããã æ¬çºæã«çšããããåçä¹³å€ã¯ãã¡ãã³è²çŽ é¡
ãã®ä»ã«ãã€ãŠåå 墿ãããŠããã æçšãªå¢æè²çŽ ã¯äŸãã°ãã€ãç¹èš±929080å·ã
ç±³åœç¹èš±2493748å·ãå2503776å·ãå2519001å·ã
å2912329å·ãå3656959å·ãå3672897å·ãå
4025349å·ãè±åœç¹èš±1242588å·ãç¹å ¬æ44â
14030å·ã«èšèŒããããã®ã§ããã ãããã®å¢æè²çŽ ã¯åç¬ã«çšããŠãããããã
ããã®çµåããçšããŠãããã墿è²çŽ ã®çµåã
ã¯ç¹ã«åŒ·è²å¢æã®ç®çã§ãã°ãã°çšãããããã
ã®ä»£è¡šäŸã¯ç±³åœç¹èš±2688545å·ãå2977229å·ãå
3397060å·ãå3522052å·ãå3527641å·ãå
3617293å·ãå3628964å·ãå3666480å·ãå
3672898å·ãå3679428å·ãå3814609å·ãå
4026707å·ãè±åœç¹èš±1344281å·ãç¹å ¬æ43â4936
å·ãå53â12375å·ãç¹éæ52â110618å·ãå52
â109925å·ã«èšèŒãããŠããã æ¬çºæã¯æ¯æäœäžã«å°ãªããšãïŒã€ã®ç°ãªãå
å æåºŠãæããå€å±€å€è²åçææã«ãé©çšã§ã
ããå€å±€å€©ç¶è²åçææã¯ãéåžžæ¯æäœäžã«èµ€æ
æ§ä¹³å€å±€ãç·ææ§ä¹³å€å±€ãããã³éææ§ä¹³å€å±€ã
åã å°ãªããšãäžã€æããããããã®å±€ã¯é åºã¯
å¿ èŠã«å¿ããŠä»»æã«ããã¹ããèµ€ææ§ä¹³å€å±€ã«ã·
ã¢ã³åœ¢æã«ãã©ãŒããç·ææ§ä¹³å€å±€ã«ããŒã³ã¿åœ¢
æã«ãã©ãŒããéææ§ä¹³å€å±€ã«ã€ãšããŒåœ¢æã«ã
ã©ãŒãããããå«ãã®ãéåžžã§ããããå Žåã«ã
ãç°ãªãçµåãããšãããšãã§ããã æ¬çºæãçšããŠäœãããåçæå ææã«ã¯ãç¡
æ©ãŸãã¯ææ©ã®ç¡¬èå€ã嫿ããŠãããäŸãã°ã¯
ãã å¡©ïŒã¯ãã æã°ããé ¢é žã¯ãã ãªã©ïŒãã¢ã«
ãããé¡ïŒãã«ã ã¢ã«ããããã°ãªãªããµãŒã«ã
ã°ã«ã¿ãŒã«ã¢ã«ããããªã©ïŒãâã¡ãããŒã«å
åç©ïŒãžã¡ãããŒã«å°¿çŽ ãã¡ãããŒã«ãžã¡ãã«ã
ãã³ãã€ã³ãªã©ïŒããžãªããµã³èªå°äœïŒïŒïŒïŒâ
ãžããããã·ãžãªããµã³ãªã©ïŒã掻æ§ããã«åå
ç©ïŒïŒïŒïŒïŒïŒâããªã¢ã¯ãªãã€ã«âãããµãã
ãââããªã¢ãžã³ãïŒïŒïŒâããã«ã¹ã«ããã«
âïŒâãããããŒã«ãªã©ïŒã掻æ§ããã²ã³ååç©
ïŒïŒïŒïŒâãžã¯ãã«âïŒâããããã·ââããª
ã¢ãžã³ãªã©ïŒãã ã³ããã²ã³é žé¡ïŒã ã³ã¯ãã«é žã
ã ã³ããšããã·ã¯ãã«é žãªã©ïŒããªã©ãåç¬ãŸã
ã¯çµåãããŠçšããããšãã§ããã æ¬çºæãçšããŠäœãããæå ææã«ã¯èŠªæ°Žæ§ã³
ãã€ãå±€ã«çŽ«å€ç·åžåå€ãå«ãã§ãããããšãã°
ã¢ãªãŒã«åºã§çœ®æããããã³ãŸããªã¢ãŸãŒã«åå
ç©ãïŒâãã¢ãŸãªãã³ååç©ããã³ãŸããšãã³å
åç©ãæ¡ç®é žãšã¹ãã«ååç©ããã¿ãžãšã³åå
ç©ããã³ãŸãªããµãŸãŒã«ååç©ãããã«çŽ«å€ç·åž
åæ§ã®ããªããŒãªã©ãçšããããšãã§ããããã
ãã®çŽ«å€ç·åžåå€ã¯äžèšèŠªæ°Žæ§ã³ãã€ãå±€äžã«åº
å®ãããŠãããã 玫å€ç·åžåå€ã®å ·äœäŸã¯ãç±³åœç¹èš±3533794å·ã
å3314794å·ãå3352681å·ãç¹éæ46â2784å·ã
ç±³åœç¹èš±3705805å·ãå3707375å·ãå4045229å·ã
å3700455å·ãå3499762å·ã西ç¬ç¹èš±åºé¡å ¬å
1547863å·ãªã©ã«èšèŒãããŠããã æ¬çºæãçšããŠäœãããæå ææã«ã¯ãã€ã«ã¿
ãŒææãšããŠããããã¯ã€ã©ãžãšãŒã·ãšã³é²æ¢ã
ã®ä»çš®ã ã®ç®çã§ãæ°Žæº¶æ§ææã嫿ããŠããã
ãã®ãããªææã«ã¯ãªããœããŒã«ææããããªã
ãœããŒã«ææãã¹ããªã«ææãã¡ãã·ã¢ãã³æ
æãã·ã¢ãã³ææåã³ã¢ãŸææãå å«ããããäž
ã§ããªããœããŒã«ææïŒãããªããœããŒã«ææå
ã³ã¡ãã·ã¢ãã³ææãæçšã§ããã çšãåŸãå ·äœäŸã¯è±åœç¹èš±546708å·ãå584609
å·ãå1265842å·ãå1410488å·ãç±³åœç¹èš±
2274782å·ãå2286714å·ãå2526632å·ãå
2606833å·ãå2956879å·ãå3148187å·ãå
3247127å·ãå3481927å·ãå3575704å·ãå
3653905å·ãå3718472å·ã«èšèŒãããŠããã æ¬çºæãçšããŠäœãããåçæå ææã®åçä¹³
å€å±€ã«ã¯è²çŽ æ¡æ£åã«ãã©ãŒä»¥å€ã«å ¬ç¥ã®è²åœ¢æ
ã«ãã©ãŒãããªãã¡çºè²çŸååŠçã«ãããŠè³éŠæ
ïŒçŽã¢ãã³çŸåè¬ïŒäŸãã°ãããšãã¬ã³ãžã¢ãã³
èªå°äœããã¢ããããšããŒã«èªå°äœãªã©ïŒãšã®é ž
åã«ãããªã³ã°ã«ãã€ãŠçºè²ãããååç©ãäŸã
ã°ãããŒã³ã¿ã«ãã©ãŒãšããŠãïŒâãã©ãŸãã³ã«
ãã©ãŒããã©ãŸããã³ãã€ãããŸãŒã«ã«ãã©ãŒã
ã·ã¢ãã¢ã»ãã«ã¯ããã³ã«ãã©ãŒãééã¢ã·ã«ã¢
ã»ããããªã«ã«ãã©ãŒçããããã€ãšããŒã«ãã©
ãŒãšããŠãã¢ã·ã«ã¢ã»ãã¢ããã«ãã©ãŒïŒäŸãã°
ãã³ãŸã€ã«ã¢ã»ãã¢ããªãé¡ããããã€ã«ã¢ã»ã
ã¢ããªãé¡ïŒãçããããã·ã¢ã³ã«ãã©ãŒãšããŠã
ããããŒã«ã«ãã©ãŒãããã³ããšããŒã«ã«ãã©
ãŒãçãããããããã®ã«ãã©ãŒã¯ååäžã«ãã©
ã¹ãåºãšãã°ããçæ°Žåºãæããéæ¡æ£ã®ãã®ã
æãŸãããã«ãã©ãŒã¯éã€ãªã³ã«å¯ŸãïŒåœéæ§ã
ããã¯ïŒåœéæ§ã®ã©ã¡ãã§ãããããŸãè²è£æ£ã®
广ããã€ã«ã©ãŒãã«ãã©ãŒããããã¯çŸåã«ãš
ããªã€ãŠçŸåæå¶å€ãæŸåºããã«ãã©ãŒïŒããã
ãDIRã«ãã©ãŒïŒã§ãã€ãŠãããããŸãDIRã«ã
ã©ãŒä»¥å€ã«ããã«ãããªã³ã°åå¿ã®çæç©ãç¡è²
ã§ãã€ãŠçŸåæå¶å€ãæŸåºããç¡åè²DIRã«ãã
ãªã³ã°ååç©ãå«ãã§ãããã ã«ãã©ãŒãããã²ã³åéä¹³å€å±€ã«å°å ¥ããã«ã¯
å ¬ç¥ã®æ¹æ³ããšãã°ç±³åœç¹èš±2322027å·ã«èšèŒã®
æ¹æ³ãªã©ãçšãããããããšãã°ãã¿ãŒã«é žã¢ã«
ãã«ãšã¹ãã«ïŒãžããã«ãã¿ã¬ãŒãããžãªã¯ãã«
ãã¿ã¬ãŒããªã©ïŒããªã³é žãšã¹ãã«ïŒãžããšãã«
ããªã¹ããšãŒããããªããšãã«ããªã¹ããšãŒãã
ããªã¯ã¬ãžã«ããªã¹ããšãŒãããžãªã¯ãã«ããã«
ããªã¹ããšãŒãïŒãã¯ãšã³é žãšã¹ãã«ïŒããšãã°
ã¢ã»ãã«ã¯ãšã³é žããªããã«ïŒã宿¯éŠé žãšã¹ã
ã«ïŒããšãã°å®æ¯éŠé žãªã¯ãã«ïŒãã¢ã«ãã«ã¢ã
ãïŒããšãã°ãžãšãã«ã©ãŠãªã«ã¢ããïŒãèèªé ž
ãšã¹ãã«é¡ïŒããšãã°ãžãããã·ãšãã«ãµã¯ã·ã
ãŒãããžãªã¯ãã«ã¢ãŒã¬ãŒãïŒãããªã¡ã·ã³é žãš
ã¹ãã«é¡ïŒããšãã°ããªã¡ã·ã³é žããªããã«ïŒãª
ã©ããŸãã¯æ²žç¹çŽ30âä¹è³150âã®ææ©æº¶åªãã
ãšãã°é ¢é žãšãã«ãé ¢é žããã«ã®ããšãäœçŽã¢ã«
ãã«ã¢ã»ããŒããããããªã³é žãšãã«ãïŒçŽãã
ã«ã¢ã«ã³ãŒã«ãã¡ãã«ã€ãœããã«ã±ãã³ãβâãš
ããã·ãšãã«ã¢ã»ããŒããã¡ãã«ã»ããœã«ãã¢ã»
ããŒãçã«æº¶è§£ããã®ã¡ã芪氎æ§ã³ãã€ãã«åæ£
ããããäžèšã®é«æ²žç¹ææ©æº¶åªãšäœæ²žç¹ææ©æº¶åª
ãšãæ··åããŠçšããŠãããã ãŸãç¹éæ51â39853å·ãç¹éæ51â59943å·ã«
èšèŒãããŠããéåç©ã«ãã忣æ³ã䜿çšããã
ãšãã§ããã ã«ãã©ãŒãã«ã«ãã³é žãã¹ã«ããªã³é žã®ããšã
é žåºãæããå Žåã«ã¯ãã¢ã«ã«ãªæ§æ°Žæº¶æ¶²ãšããŠ
芪氎æ§ã³ãã€ãäžã«å°å ¥ãããã æ¬çºæã¯ãã®å®æœæ æ§ã«ãããŠã髿åŽä¹³å€å±€
ã§å®æœãããšç¹ã«å¹æã倧ããã æ¬çºæã¯é¢è±åºã®æ¡æ£æ§ãç¹ã«å€§ããDIRã«ã
ã©ãŒåã¯ç¹éæ54â145135ãBritâ2072363èšèŒ
ã®ã¿ã€ãã³ã°èª¿ç¯åºããã€ãDIRã«ãã©ãŒãšçµã¿
åããããšãç¹ã«å¥œãŸããã 宿œäŸ ïŒ ä»¥äžã®ããã«ããŠå忣乳å€ïŒ¡ã調補ããã ãŸãèåã«ãª0.01ã¢ã«ãã¢ã³ã¢ãã¢1.4ã¢ã«ã
å«ãïŒã®ãŒã©ãã³æ°Žæº¶æ¶²ãåå¿å®¹åšã«å ¥ããã
ãã«ç¡é žé0.27ã¢ã«ãå«ã氎溶液500c.c.ãšèåã«
ãª0.24ã¢ã«ãæ²åã«ãª0.043ã¢ã«ãå«ã氎溶液500
c.c.ãšãåæã«ã30åãããŠãæ·»å äžã¯ããã²ã³ã€
ãªã³ãéã€ãªã³ã«å¯ŸããŠ0.2ïœïŒéå°ã«ãªãã
ãã«èª¿ç¯ãã€ã€æ·»å ããããã®åŸé žãçšããŠã¢ã³
ã¢ãã¢ãäžåããåŸãããã«0.62ã¢ã«ã®ç¡é žéã
å«ã氎溶液500c.c.ãšèåã«ãª0.71ã¢ã«ãæ²åã«ãª
0.01ã¢ã«ãå«ã氎溶液500c.c.ãšãåæã«30åãã
ãŠãæ·»å äžã¯ããã²ã³ã€ãªã³ãéã€ãªã³ã«å¯ŸããŠ
0.2ïœïŒéå°ã«ãªãããã«èª¿ç¯ãã€ã€æ·»å ããã ãã®ä¹³å€ã¯ãå šç²åã®92ïŒ ãå¹³åç²åãµã€ãºã®
±40ïŒ ã®ç¯å²å ã«å ¥ã€ãŠãããµã€ãºååžããã€ãŠ
ããã æ¯èŒã®ããã®å€åæ£ä¹³å€ïŒ¢ã¯ä»¥äžã®ããã«èª¿è£œ
ããã ãŸãèåã«ãª0.3ã¢ã«ãæ²åã«ãª0.036ã¢ã«ãå«
ããŒã©ãã³æ°Žæº¶æ¶²ãåå¿å®¹åšäžã«å ¥ããããã«
1.3ã¢ã«ã®ç¡é žéãå«ã氎溶液ããã³èåã«ãª1.1
ã¢ã«ãæ²åã«ãª0.042ã¢ã«ãå«ã氎溶液ãåæã«
40åéã§æ·»å ããã ãã®ä¹³å€ã¯å šç²åã®85ïŒ ãå¹³åç²åãµã€ãºã®Â±
40ïŒ ã®ç¯å²å ã«å ¥ã€ãŠãããµã€ãºååžããã€ãŠã
ãã å忣乳å€ïŒ¡ãå€åæ£ä¹³å€ïŒ¢ããããå ¬ç¥ãæ¹
æ³ã§æé©ç¹ãŸã§åŸçããã 以äžã®ä¹³å€ã第ïŒå±€ã«çšãã以äžã®ããã«ããŠ
詊æ101ã103ã調補ããã ã»ã«ããŒã¹ããªã¢ã»ããŒããã€ã«ã æ¯æäœäžã«
äžèšã«ç€ºããããªçµæã®åå±€ãããªãå€å±€ã«ã©ãŒ
æå ææãäœè£œããã 第ïŒå±€ïŒãã¬ãŒã·ãšã³é²æ¢å±€ é»è²ã³ãã€ãéãå«ããŒã©ãã³å±€ 第ïŒå±€ïŒäžéå±€ ïŒïŒïŒâãžâïœâãªã¯ãã«ãã€ããããã³ã®
ä¹³å忣ç©ãå«ããŒã©ãã³å±€ 第ïŒå±€ïŒç¬¬ïŒèµ€æä¹³å€å±€ æ²èåéä¹³å€ïŒæ²åéïŒïŒã¢ã«ïŒ ïŒâŠéå¡åžé
1.79ïœïŒm2 墿è²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠïŒÃ10-5ã¢ã« 墿è²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠ1.5Ã10-5ã¢ã« ã«ãã©ãŒïŒ¡âŠéïŒã¢ã«ã«å¯ŸããŠ0.4ã¢ã« ã«ãã©ãŒïŒ£âŠéïŒã¢ã«ã察ããŠ0.003ã¢ã« ã«ãã©ãŒïŒ€âŠéïŒã¢ã«ã«å¯ŸããŠ0.0006ã¢ã« 第ïŒå±€ïŒç¬¬ïŒèµ€æä¹³å€å±€ æ²èåéä¹³å€ïŒæ²åéïŒïŒã¢ã«ïŒ ïŒâŠéå¡åžé
1.4ïœïŒm2 墿è²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠïŒÃ10-5ã¢ã« 墿è²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠ1.2Ã10-5ã¢ã« ã«ãã©ãŒïŒ¥âŠéïŒã¢ã«ã«å¯ŸããŠ0.02ã¢ã« ã«ãã©ãŒïŒ£âŠéïŒã¢ã«ã«å¯ŸããŠ0.0016ã¢ã« 第ïŒå±€ïŒäžéå±€ 第ïŒå±€ãšåã 第ïŒå±€ïŒç¬¬ïŒç·æä¹³å€å±€ æ²èåéä¹³å€ïŒæ²åéïŒïŒã¢ã«ïŒ ïŒâŠå¡åžéé
1.5ïœïŒm2 墿è²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠïŒÃ10-5ã¢ã« 墿è²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠïŒÃ10-5ã¢ã« ã«ãã©ãŒïŒ¢âŠéïŒã¢ã«ã«å¯ŸããŠ0.05ã¢ã« ã«ãã©ãŒïŒâŠéïŒã¢ã«ã«å¯ŸããŠ0.008ã¢ã« ã«ãã©ãŒïŒ€âŠéïŒã¢ã«ã«å¯ŸããŠ0.0015ã¢ã« 第ïŒå±€ïŒç¬¬ïŒç·æä¹³å€å±€ åèšã®è£œé æ³ã§äœè£œããå€åæ£æ²å±€åéä¹³å€ïŒ¢
ïŒæ²åéïŒïŒã¢ã«ïŒ ïŒâŠå¡åžéé1.6ïœïŒm2 墿è²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠ2.5Ã10-5ã¢ã« 墿è²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠ0.8Ã10-5ã¢ã« ã«ãã©ãŒïŒ¢âŠéïŒã¢ã«ã«å¯ŸããŠ0.02ã¢ã« ã«ãã©ãŒïŒâŠéïŒã¢ã«ã«å¯ŸããŠ0.003ã¢ã« ã«ãã©ãŒïŒ€âŠéïŒã¢ã«ã«å¯ŸããŠ0.0003ã¢ã« 第ïŒå±€ïŒã€ãšããŒãã€ã«ã¿ãŒå±€ ãŒã©ãã³æ°Žæº¶æ¶²äžã«é»è²ã³ãã€ãéãšïŒã»ïŒ
âãžâïœâãªã¯ãã«ãã€ããããã³ã®ä¹³å忣
ç©ãšãå«ããŒã©ãã³å±€ã 第ïŒå±€ïŒç¬¬ïŒéæä¹³å€å±€ æ²èåéä¹³å€ïŒæ²åéïŒïŒã¢ã«ïŒ ïŒâŠå¡åžéé
1.5ïœïŒm2 ã«ãã©ãŒïŒ¹âŠéïŒã¢ã«ã«å¯ŸããŠ0.25ã¢ã« 第10å±€ïŒç¬¬ïŒéæä¹³å€å±€ æ²èåéïŒæ²åéïŒïŒã¢ã«ïŒ ïŒâŠå¡åžéé1.1
ïœïŒm2 ã«ãã©ãŒïŒ¹âŠéïŒã¢ã«ã«å¯ŸããŠ0.06ã¢ã« 第11å±€ïŒä¿è·å±€ ããªã¡ãã«ã¡ã¿ãã¢ã¯ãªã¬ãŒãç²åïŒçŽåŸçŽ
1.5ÎŒïŒãå«ããŒã©ãã³å±€ãå¡åžã åå±€ã«ã¯äžèšçµæç©ã®ä»ã«ããŒã©ãã³ç¡¬åå€ã
ç颿޻æ§å€ãæ·»å ããã 以äžã®åŠãããŠäœè£œãã詊æã詊æ101ãšããã 詊æãäœãã®ã«çšããååç© å¢æè²çŽ ïŒã¢ã³ãããâïŒã»5â²âãžã¯ããâ
ïŒã»3â²âãžâïŒÎ³âã¹ã«ããããã«ïŒâïŒâãšã
ã«âãã¢ã«ã«ãã·ã¢ãã³ãããããµã€ãã»ããª
ãžããŠã å¡© 墿è²çŽ ïŒã¢ã³ãããâïŒâãšãã«âïŒã»3â²â
ãžâïŒÎ³âã¹ã«ããããã«ïŒâïŒã»ïŒã»4â²ã»5â²â
ãžãã³ãŸãã¢ã«ã«ãã·ã¢ãã³ãããããµã€ãã»
ããªãšãã«ã¢ãã³å¡© 墿è²çŽ ïŒã¢ã³ãããâïŒâãšãã«âïŒã»5â²â
ãžã¯ããâïŒã»3â²âãžïŒÎ³âã¹ã«ããããã«ïŒ
ãªããµã«ã«ãã·ã¢ãã³ã»ãããªãŠã å¡© 墿è²çŽ ïŒã¢ã³ãããâïŒã»ïŒã»5â²ã»6â²âãã
ã©ã¯ããâïŒã»1â²âãžãšãã«âïŒã»3â²âãžâ
ïœÎ²âãβâïŒÎ³âã¹ã«ãããããã·ïŒãšããã·ã
ãšãã«ã€ãããŸãã«ã«ãã·ã¢ãã³ãããããµã€
ããããªãŠã å¡© 詊æ102ïŒè©Šæ101ã®ã«ãã©ãŒïŒ¢ã®ãããã«ã«ãã©
ãŒïŒâïŒãã«ãã©ãŒïŒ¢ãšçã¢ã«ã§çœ®ãæãã以
å€è©Šæ101ãšåæ§ã«äœè£œããã 詊æ103ïŒè©Šæ102ã®ç¬¬ïŒå±€ã«å忣乳å€ïŒ¡ãçšã
ã以å€ã¯è©Šæ102ãšåæ§ã«äœè£œããã åŸããã詊æ101ã103ãçœå ã§ãŠãšããžé²å ã
ãããšãããã»ãŒåçã®æåºŠãé調ã®ãã®ãåŸã
ããã ããã§çšããçŸååŠçã¯äžèšã®éãã«38âã§è¡
ãªã€ãã ïŒ ã«ã©ãŒçŸåâŠâŠïŒå15ç§ ïŒ æŒçœâŠâŠïŒå30ç§ ïŒ æ°ŽæŽâŠâŠïŒå15ç§ ïŒ å®çâŠâŠïŒå30ç§ ïŒ æ°ŽæŽâŠâŠïŒå15ç§ ïŒ å®å®âŠâŠïŒå15ç§ åå·¥çšã«çšããåŠçæ¶²çµæã¯äžèšã®ãã®ã§ã
ãã ã«ã©ãŒçŸåæ¶² ãããäžé ¢é žãããªãŠã 1.0ïœ äºç¡«é žãããªãŠã 4.0ïœ çé žãããªãŠã 30.0ïœ èåã«ãª 1.4ïœ ããããã·ã«ã¢ãã³ç¡«é žå¡© 2.4ïœ ïŒâïŒïŒ®âãšãã«ââβããããã·ãšãã«ã¢ã
ãïŒâïŒâã¡ãã«âã¢ããªã³ç¡«é žå¡© 4.5ïœ æ°Žãå ããŠ ïŒ æŒçœæ¶² èåã¢ã³ã¢ããŠã 160.0ïœ ã¢ã³ã¢ãã¢æ°ŽïŒ28ïŒ ïŒ 25.0ml ãšãã¬ã³ãžã¢ãã³âåé ¢é žãããªãŠã éå¡© 130ïœ æ°·é ¢é ž 14ml æ°Žãå ããŠ ïŒ å®çæ¶² ããã©ããªãªã³é žãããªãŠã 2.0ïœ äºç¡«é žãããªãŠã 4.0ïœ ããªç¡«é žã¢ã³ã¢ããŠã ïŒ70ïŒ ïŒ 175.0ml éäºç¡«é žãããªãŠã 4.6ïœ æ°Žãå ããŠ ïŒ å®å®æ¶² ãã«ããªã³ 8.0ml æ°Žãå ããŠ ïŒ ãããã®è©Šæã®ããŒã³ã¿è²åã®ç²ç¶æ§ã«ã€ããŠ
æ £çšã®RMSæ³ã§å€å®ãããRMSæ³ã«ããç²ç¶æ§
ã®å€å®ã¯åœäºè éã§ã¯åšç¥ã®äºã§ãããâThe
Theory of the Photographic Processâ4th
Ed.P619ã«èšèŒãããŠãããæž¬å®éå£ã¯10ÎŒãšã
ãã ãŸã詊æ101ã103ã«ã€ããŠ110ãµã€ãºã«å å·¥ã
ãŠå®ææ®åœ±ãè¡ããã€ãã§ãã€ãããµã€ãºã«ããª
ã³ãããŠç²ç¶æ§ã®å¿çè©äŸ¡ãè¡ãªã€ãã ããã«è©Šæ101ã103ã®ããŒã³ã¿è²åã®ç²ç¶æ§ã«
ã€ããŠãŽã€ããŒã¹ãã¯ãã«ïŒæž¬å®éå£ã¯10ÎŒïŒã
æ±ããã 以äžã®ãã¡ãRMSç²ç¶æ§å€ãå¿çè©äŸ¡ã®çµæ
ã«ã€ããŠè¡šïŒã«ãŸãšããã
COOHãâSO3HãâOHãâSO2NH2ã®ããã«ã¢ã«
ã«ãªã§è§£é¢ããåºãå«ãããšãç¹ã«å¥œãŸããããŸ
ãR9ãR10ãR11ãR12ãR13ãR14ãR15ããã
çµåããããšã§ã«ãã©ãŒãå®è³ªäžèæ¡æ£åããã
ãšãå¯èœã§ããã è²çŽ æ¡æ£åã«ãã©ãŒã®å ·äœäŸãäžèšã«ç€ºãã æ¬çºæã«ããããããã®ååç©ã¯ç±³åœç¹èš±ç¬¬
4264723å·ã第3227554å·ã第4310619å·ã第
4301235å·ãç¹éæ57â4044å·ã56â126833å·ã
50â122935å·ãªã©ã«èšèŒã®æ¹æ³ã«ãã€ãŠåæã§ã
ãã æ¬çºæã«ä¿ããããã®ååç©ã¯ç¹éæ56â1938
å·ãå57â3934å·ãå53â105226å·çã«èšèŒãã
ãæ¹æ³ã§å®¹æã«åæã§ããã æ¬çºæã«ãããå忣ããã²ã³åéä¹³å€ãšã¯ã
ã¢ããŒãã€ãŒäžãéãæã®é»æ°äŒå°åºŠã®å·®ããæ±
ããããã²ã³åéå šç²åã®ééåã¯åæ°ååžã«ã
ããŠããã²ã³åéã®å¹³åç²åãµã€ãºã®0.6åãã
1.4åã®å€ã®ç¯å²ã«ããã²ã³åéå šç²åã®90ïŒ ä»¥
äžãå«ãŸãããããªä¹³å€ãããã ãã®å忣乳å€ã®å¹³åç²åãµã€ãºã¯0.1ÎŒã3ÎŒã
奜ãŸããã¯0.4ÎŒã2ÎŒã§ãããããã²ã³åéçµæã¯
èåéãå¡©åéãå¡©èåéãæ²èåéãå¡©æ²èå
éãããã§ãããããïŒã¢ã«ïŒ 以äžã®æ²åéãå«
ãæ²èåéã§ç¹ã«ãã®å¹æã倧ããã æ¬çºæã®å忣乳å€ã¯ãç±³åœç¹èš±ç¬¬3574623å·
æçްæžã«èšèŒãããæ¹æ³ãè±åœç¹èš±1520976å·æ
现æžã«èšèŒã®æ¹æ³ãç¡é žéãšã¢ã«ã«ãªãã©ã€ãã
åæã«æ··åããŠåå¿æ¶²äžã®pAgãäžå®ã«ä¿ã¡ã€ã€
ããã²ã³åéç²åãäœãããããã³ã³ãããŒã«ã
ããã«ãžãšããæ³ãããã³ã¢ã³ã¢ãã¢ãçšããŠæ¡
æ£åŸéã®æ¡ä»¶äžã§ç²åãæé·ãããæ¹æ³ïŒç¹éæ
55â142329ïŒãªã©ã§è£œé ããããšãã§ããã åçä¹³å€ã®çµåå€ãŸãã¯ä¿è·ã³ãã€ããšããŠ
ã¯ããŒã©ãã³ãçšããã®ãæå©ã§ãããããã以
å€ã®èŠªæ°Žæ§ã³ãã€ããçšããããšãã§ããã ããšãã°ãŒã©ãã³èªå°äœããŒã©ãã³ãšä»ã®é«å
åãšã®ã°ã©ããããªããŒãã¢ã«ããã³ãã«ãŒã€ã³
çã®èçœè³ªïŒããããã·ãšãã«ã»ã«ããŒã¹ãã«ã«
ããã·ã¡ãã«ã»ã«ããŒã¹ãã»ã«ããŒãºç¡«é žãšã¹ã
ã«é¡çã®åŠãã»ã«ããŒã¹èªå°äœãã¢ã«ã®ã³é žãœãŒ
ããæŸ±ç²èªå°äœãªã©ã®ç³èªå°äœïŒããªããã«ã¢ã«
ã³ãŒã«ãããªããã«ã¢ã«ã³ãŒã«éšåã¢ã»ã¿ãŒã«ã
ããªââããã«ãããªãã³ãããªã¢ã¯ãªã«é žã
ããªã¡ã¿ã¯ãªã«é žãããªã¢ã¯ãªã«ã¢ãããããªã
ãã«ã€ãããŸãŒã«ãããªããã«ãã©ãŸãŒã«çã®å
äžãããã¯å ±éåäœã®åŠãå€çš®ã®åæèŠªæ°Žæ§é«å
åç©è³ªãçšããããšãã§ããã ãŒã©ãã³ãšããŠã¯ç³ç°åŠçãŒã©ãã³ã®ã»ãé žåŠ
çãŒã©ãã³ãBull.Soc.Sci.Phot.JapanãNo.16ã
30é ïŒ1966ïŒã«èšèŒããããããªé µçŽ åŠçãŒã©ã
ã³ãçšããŠããããåãŒã©ãã³ã®å æ°Žåè§£ãé µçŽ
åè§£ç©ãçšããããšãã§ããã ããã²ã³åéç²å圢æãŸãã¯ç©ççæã®éçšã«
ãããŠãã«ãããŠã å¡©ãäºéå¡©ãéå¡©ãã¿ãªãŠã
å¡©ãã€ãªãžãŠã å¡©ãŸãã¯ãã®é¯å¡©ãããžãŠã å¡©ãŸ
ãã¯ãã®é¯å¡©ãéå¡©ãŸãã¯éé¯å¡©ãªã©ãå ±åãã
ãŠãããã æ¬çºæã®æå ææã®åçä¹³å€å±€ãŸãã¯ä»ã®èŠªæ°Ž
æ§ã³ãã€ãå±€ã«ã¯å¡åžå©å€ã垯é»é²æ¢ãã¹ããªæ§
æ¹è¯ãä¹³ååæ£ãæ¥ç鲿¢ããã³åçç¹æ§æ¹è¯
ïŒããšãã°çŸåä¿é²ã硬調åã墿ïŒãªã©çš®ã ã®
ç®çã§çš®ã ã®ç颿޻æ§å€ãå«ãã§ãããã ããšãã°ãµããã³ïŒã¹ããã€ãç³»ïŒãã¢ã«ãã¬
ã³ãªããµã€ãèªå°äœïŒäŸãã°ããªãšãã¬ã³ã°ãªã³
ãŒã«ãããªãšãã¬ã³ã°ãªã³ãŒã«ïŒããªãããã¬ã³
ã°ãªã³ãŒã«çž®åç©ãããªãšãã¬ã³ã°ãªã³ãŒã«ã¢ã«
ãã«ãšãŒãã«é¡ãŸãã¯ããªãšãã¬ã³ã°ãªã³ãŒã«ã¢
ã«ãã«ã¢ãªãŒã«ãšãŒãã«é¡ãããªãšãã¬ã³ã°ãªã³
ãŒã«ãšã¹ãã«é¡ãããªãšãã¬ã³ã°ãªã³ãŒã«ãœã«ã
ã¿ã³ãšã¹ãã«é¡ãããªã¢ã«ãã¬ã³ã°ãªã³ãŒã«ã¢ã«
ãã«ã¢ãã³ãŸãã¯ã¢ããé¡ãã·ãªã³ãŒã³ã®ããªãš
ãã¬ã³ãªããµã€ãä»å ç©é¡ïŒãã°ãªã·ããŒã«èªå°
äœïŒããšãã°ã¢ã«ã±ãã«ã³ãã¯é žããªã°ãªã»ãª
ããã¢ã«ãã«ããšããŒã«ããªã°ãªã»ãªãïŒãå€äŸ¡
ã¢ã«ã³ãŒã«ã®èèªé žãšã¹ãã«é¡ãç³ã®ã¢ã«ãã«ãš
ã¹ãã«é¡ãªã©ã®éã€ãªã³æ§ç颿޻æ§å€ïŒã¢ã«ãã«
ã«ã«ãã³é žå¡©ãã¢ã«ãã«ã¹ã«ããªã³é žå¡©ãã¢ã«ã
ã«ãã³ãŒã³ã¹ã«ããªã³é žå¡©ãã¢ã«ãã«ããã¿ã¬ã³
ã¹ã«ããªã³é žå¡©ãã¢ã«ãã«ç¡«é žãšã¹ãã«é¡ãã¢ã«
ãã«ãªã³é žãšã¹ãã«é¡ãâã¢ã·ã«ââã¢ã«ã
ã«ã¿ãŠãªã³é¡ãã¹ã«ãã³ãã¯é žãšã¹ãã«é¡ãã¹ã«
ãã¢ã«ãã«ããªãªãã·ãšãã¬ã³ã¢ã«ãã«ããšãã«
ãšãŒãã«é¡ãããªãªãã·ãšãã¬ã³ã¢ã«ãã«ãªã³é ž
ãšã¹ãã«é¡ãªã©ã®ãããªãã«ã«ããã·åºãã¹ã«ã
åºããã¹ãåºãç¡«é žãšã¹ãã«åºãçé žãšã¹ãã«åº
çã®é žæ§åºãå«ãã¢ããªã³ç颿޻æ§å€ïŒã¢ããé ž
é¡ãã¢ããã¢ã«ãã«ã¹ã«ãã³é žé¡ãã¢ããã¢ã«ã
ã«ç¡«é žãŸãã¯çé žãšã¹ãã«é¡ãã¢ã«ãã«ãã¿ã€ã³
é¡ãã¢ãã³ãªãã·ãé¡ãªã©ã®äž¡æ§ç颿޻æ§å€ïŒã¢
ã«ãã«ã¢ãã³å¡©é¡ãèèªæãããã¯è³éŠæç¬¬ïŒçŽ
ã¢ã³ã¢ããŠã å¡©é¡ãããªãžããŠã ãã€ãããŸãªãŠ
ã ãªã©ã®è€çŽ ç°ç¬¬ïŒçŽã¢ã³ã¢ããŠã å¡©é¡ãããã³
èèªæãŸãã¯è€çŽ ç°ãå«ããã¹ãããŠã ãŸãã¯ã¹
ã«ãããŠã å¡©é¡ãªã©ã®ã«ããªã³ç颿޻æ§å€ãçšã
ãããšãã§ããã æ¬çºæã®åçæå ææã®åçä¹³å€å±€ã«ã¯æåºŠäž
æãã³ã³ãã©ã¹ãäžæããŸãã¯çŸåä¿é²ã®ç®ç
ã§ãäŸãã°ããªã¢ã«ãã¬ã³ãªãã·ããŸãã¯ãã®ãš
ãŒãã«ããšã¹ãã«ãã¢ãã³ãªã©ã®èªå°äœãããªãš
ãŒãã«ååç©ãããªã¢ã«ããªãªã³é¡ãåçŽã¢ã³ã¢
ããŠã å¡©ååç©ããŠã¬ã¿ã³èªå°äœãå°¿çŽ èªå°äœã
ã€ãããŸãŒã«èªå°äœãïŒâãã©ãŸãªãã³é¡çãå«
ãã§ããããäŸãã°ç±³åœç¹èš±2400532å·ãå
2423549å·ãå2716062å·ãå3617280å·ãå
3772021å·ãå3808003å·ãè±åœç¹èš±1488991å·ç
ã«èšèŒããããã®ãçšããããšãã§ããã æ¬çºæãçšããŠäœãããåçæå ææã«ã¯ã寞
æ³å®å®æ§ã®æ¹è¯ãªã©ã®ç®çã§ãæ°Žäžæº¶ãŸãã¯é£æº¶
æ§åæããªããŒã®åæ£ç©ãå«ãããšãã§ãããã
ãšãã°ã¢ã«ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããã¢ã«ã³ã
ã·ã¢ã«ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããã°ãªã·ãžã«
ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããïŒã¡ã¿ïŒã¢ã¯ãªã«ã¢ããã
ããã«ãšã¹ãã«ïŒããšãã°é ¢é žããã«ïŒãã¢ã¯ãª
ããããªã«ããªã¬ãã€ã³ãã¹ãã¬ã³ãªã©ã®åç¬ã
ããã¯çµåãããŸãã¯ããããšã¢ã¯ãªã«é žãã¡ã¿
ã¢ã¯ãªã«é žãαïŒÎ²âäžé£œåãžã«ã«ãã³é žããã
ããã·ã¢ã«ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããã¹ã«ããª
ã¢ã«ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããã¹ãã¬ã³ã¹ã«ã
ãªã³é žãªã©ãšã®çµåããåéäœæåãšããããªã
ãŒãçšããããšãã§ããã æ¬çºæãçšããŠäœãããæå ææã®åçåŠçã«
ã¯ãäŸãã°ãªãµãŒãã»ãã€ã¹ã¯ããŒãžã€ãŒ
ïŒResearch DisclosureïŒ176å·ç¬¬28ã30é ïŒRD
â17643ïŒã«èšèŒãããŠãããããªãå ¬ç¥ã®æ¹æ³
åã³å ¬ç¥ã®åŠçæ¶²ã®ãããããé©çšããããšãã§
ããããã®åçåŠçã¯ãç®çã«å¿ããŠãéç»åã
圢æããåçåŠçïŒé»çœåçåŠçïŒããããã¯è²
çŽ åã圢æããåçåŠçïŒã«ã©ãŒåçåŠçïŒã®ã
ããã§ãã€ãŠããããåŠçæž©åºŠã¯æ®é18âãã50
âã®éã«éžã°ãããã18âããäœã枩床ãŸãã¯50
âãè¶ããæž©åºŠãšããŠãããã å®çæ¶²ãšããŠã¯äžè¬ã«çšããããçµæã®ãã®ã
çšããããšãã§ãããå®çå€ãšããŠã¯ããªç¡«é ž
å¡©ãããªã·ã¢ã³é žå¡©ã®ã»ããå®çå€ãšããŠã®å¹æ
ãç¥ãããŠããææ©ç¡«é»ååç©ãçšããããšãã§
ãããå®çæ¶²ã«ã¯ç¡¬èå€ãšããŠæ°Žæº¶æ§ã¢ã«ãããŠ
ã å¡©ãå«ãã§ãããã è²çŽ åã圢æããå Žåã«ã¯åžžæ³ãé©çšã§ããã
ããšãã°ããã¬ããžæ³ïŒäŸãã°âJournal of the
Society of Motion Picture and Television
Engineersâã61å·»ïŒ1953幎ïŒã667ã701é ã«èšèŒ
ãããŠããïŒïŒé»çœçŸåäž»è¬ãå«ãçŸåæ¶²ã§çŸå
ããŠãã¬éåãã€ãããã€ãã§å°ãªããšãäžåã®
äžæ§ãªé²å ãŸãã¯ä»ã®é©åœãªã«ããªåŠçãè¡ãª
ããåŒãç¶ããŠçºè²çŸåãè¡ãªãããšã«ããè²çŽ
éœç»åãåŸãã«ã©ãŒå転æ³ãªã©ãçšããããã ã«ã©ãŒçŸåæ¶²ã¯ãäžè¬ã«çºè²çŸåäž»è¬ãå«ãã¢
ã«ã«ãªæ§æ°Žæº¶æ¶²ããæããçºè²çŸåäž»è¬ã¯å ¬ç¥ã®
äžçŽè³éŠæã¢ãã³çŸåå€ãäŸãã°ããšãã¬ã³ãžã¢
ãã³é¡ïŒäŸãã°ïŒâã¢ããâïŒïŒ®âãžãšãã«ã¢
ããªã³ãïŒâã¡ãã«âïŒâã¢ããâïŒïŒ®âãžãš
ãã«ã¢ããªã³ãïŒâã¢ããââãšãã«ââβ
âããããã·ãšãã«ã¢ããªã³ãïŒâã¡ãã«âïŒâ
ã¢ããââãšãã«ââβâããããã·ãšãã«
ã¢ããªã³ãïŒâã¡ãã«âïŒâã¢ããââãšãã«
ââβâã¡ã¿ã³ã¹ã«ãã¢ãããšãã«ã¢ããªã³ã
ïŒâã¢ããâïŒâã¡ãã«ââãšãã«ââβâ
ã¡ããã·ãšãã«ã¢ããªã³ãªã©ïŒãçšããããšãã§
ããã ãã®ä»L.F.A.MasonèPhotographic
Processing ChemistryïŒFocal Pressåã1966幎ïŒ
ã®226ã229é ãç±³åœç¹èš±2193015å·ãå2592364
å·ãç¹éæ48â64933å·ãªã©ã«èšèŒã®ãã®ãçšã
ãŠããã ã«ã©ãŒçŸåæ¶²ã¯ãã®ã»ãPHç·©è¡å€ãçŸåæå¶å€
ãªããã«ããªé²æ¢å€ãªã©ãå«ãããšãã§ããããŸ
ãå¿ èŠã«å¿ããŠã硬氎è»åå€ãä¿æå€ãææ©æº¶
å€ãçŸåä¿é²å€ãè²çŽ åœ¢æã«ãã©ãŒããã¶ãã
å€ãè£å©çŸåè¬ãç²æ§ä»äžå€ãããªã«ã«ãã³é žç³»
ãã¬ãŒãå€ãé žå鲿¢å€ãªã©ãå«ãã§ãããã ãããæ·»å å€ã®å ·äœäŸã¯ãªãµãŒãã»ãã€ã¹ã¯ã
ãŒãžã€ãŒïŒRDâ17643ïŒã®ä»ãç±³åœç¹èš±ç¬¬
4083723å·ã西ç¬å ¬éïŒOLSïŒ2622950å·ãªã©ã«
èšèŒãããŠããã çºè²çŸååŸã®åçä¹³å€å±€ã¯éåžžãæŒçœåŠçãã
ããæŒçœåŠçã¯å®çåŠçãšåæã«è¡ãªãããŠãã
ãããåå¥ã«è¡ãªãããŠããããæŒçœå€ãšããŠã¯
éïŒïŒãã³ãã«ãïŒïŒãã¯ãã ïŒïŒãé ïŒïŒ
ãªã©ã®å€äŸ¡éå±ã®ååç©ãéé žé¡ãããã³é¡ãã
ãããœååç©ãªã©ãçšããããã ããšãã°ããšãªã·ã¢ã³åç©ïŒéã¯ãã é žå¡©ïŒé
ïŒïŒãŸãã¯ã³ãã«ãïŒïŒã®ææ©é¯å¡©ãããšã
ã°ãšãã¬ã³ãžã¢ãã³åé ¢é žããããªãããªé ¢é žã
ïŒïŒïŒâãžã¢ãã³âïŒâãããããŒã«åé ¢é žãªã©
ã®ã¢ããããªã«ã«ãã³é žé¡ãããã¯ã¯ãšã³é žãé
ç³é žããªã³ãŽé žãªã©ã®ææ©é žã®é¯å¡©ïŒéç¡«é žå¡©ã
éãã³ã¬ã³é žå¡©ïŒããããœããšããŒã«ãªã©ãçšã
ãããšãã§ããããããã®ãã¡ããšãªã·ã¢ã³åã«
ãªããšãã¬ã³ãžã¢ãã³åé ¢é žéïŒïŒãããªãŠã
ããã³ãšãã¬ã³ãžã¢ãã³åé ¢é žéïŒïŒã¢ã³ã¢ã
ãŠã ã¯ç¹ã«æçšã§ããããšãã¬ã³ãžã¢ãã³åé ¢é ž
éïŒïŒé¯å¡©ã¯ç¬ç«ã®æŒçœæ¶²ã«ãããŠããäžæ²¿æŒ
çœå®çæ¶²ã«ãããŠãæçšã§ããã æŒçœãŸãã¯æŒçœå®çæ¶²ã«ã¯ãç±³åœç¹èš±3042520
å·ãå3241966å·ãç¹å ¬æ45â8506å·ãç¹å ¬æ45
â8836å·ãªã©ã«èšèŒã®æŒçœä¿é²å€ãç¹éæ53â
65732å·ã«èšèŒã®ããªãŒã«ååç©ã®ä»ãçš®ã ã®æ·»
å å€ãå ããããšãã§ããã æ¬çºæã«çšããããåçä¹³å€ã¯ãã¡ãã³è²çŽ é¡
ãã®ä»ã«ãã€ãŠåå 墿ãããŠããã æçšãªå¢æè²çŽ ã¯äŸãã°ãã€ãç¹èš±929080å·ã
ç±³åœç¹èš±2493748å·ãå2503776å·ãå2519001å·ã
å2912329å·ãå3656959å·ãå3672897å·ãå
4025349å·ãè±åœç¹èš±1242588å·ãç¹å ¬æ44â
14030å·ã«èšèŒããããã®ã§ããã ãããã®å¢æè²çŽ ã¯åç¬ã«çšããŠãããããã
ããã®çµåããçšããŠãããã墿è²çŽ ã®çµåã
ã¯ç¹ã«åŒ·è²å¢æã®ç®çã§ãã°ãã°çšãããããã
ã®ä»£è¡šäŸã¯ç±³åœç¹èš±2688545å·ãå2977229å·ãå
3397060å·ãå3522052å·ãå3527641å·ãå
3617293å·ãå3628964å·ãå3666480å·ãå
3672898å·ãå3679428å·ãå3814609å·ãå
4026707å·ãè±åœç¹èš±1344281å·ãç¹å ¬æ43â4936
å·ãå53â12375å·ãç¹éæ52â110618å·ãå52
â109925å·ã«èšèŒãããŠããã æ¬çºæã¯æ¯æäœäžã«å°ãªããšãïŒã€ã®ç°ãªãå
å æåºŠãæããå€å±€å€è²åçææã«ãé©çšã§ã
ããå€å±€å€©ç¶è²åçææã¯ãéåžžæ¯æäœäžã«èµ€æ
æ§ä¹³å€å±€ãç·ææ§ä¹³å€å±€ãããã³éææ§ä¹³å€å±€ã
åã å°ãªããšãäžã€æããããããã®å±€ã¯é åºã¯
å¿ èŠã«å¿ããŠä»»æã«ããã¹ããèµ€ææ§ä¹³å€å±€ã«ã·
ã¢ã³åœ¢æã«ãã©ãŒããç·ææ§ä¹³å€å±€ã«ããŒã³ã¿åœ¢
æã«ãã©ãŒããéææ§ä¹³å€å±€ã«ã€ãšããŒåœ¢æã«ã
ã©ãŒãããããå«ãã®ãéåžžã§ããããå Žåã«ã
ãç°ãªãçµåãããšãããšãã§ããã æ¬çºæãçšããŠäœãããåçæå ææã«ã¯ãç¡
æ©ãŸãã¯ææ©ã®ç¡¬èå€ã嫿ããŠãããäŸãã°ã¯
ãã å¡©ïŒã¯ãã æã°ããé ¢é žã¯ãã ãªã©ïŒãã¢ã«
ãããé¡ïŒãã«ã ã¢ã«ããããã°ãªãªããµãŒã«ã
ã°ã«ã¿ãŒã«ã¢ã«ããããªã©ïŒãâã¡ãããŒã«å
åç©ïŒãžã¡ãããŒã«å°¿çŽ ãã¡ãããŒã«ãžã¡ãã«ã
ãã³ãã€ã³ãªã©ïŒããžãªããµã³èªå°äœïŒïŒïŒïŒâ
ãžããããã·ãžãªããµã³ãªã©ïŒã掻æ§ããã«åå
ç©ïŒïŒïŒïŒïŒïŒâããªã¢ã¯ãªãã€ã«âãããµãã
ãââããªã¢ãžã³ãïŒïŒïŒâããã«ã¹ã«ããã«
âïŒâãããããŒã«ãªã©ïŒã掻æ§ããã²ã³ååç©
ïŒïŒïŒïŒâãžã¯ãã«âïŒâããããã·ââããª
ã¢ãžã³ãªã©ïŒãã ã³ããã²ã³é žé¡ïŒã ã³ã¯ãã«é žã
ã ã³ããšããã·ã¯ãã«é žãªã©ïŒããªã©ãåç¬ãŸã
ã¯çµåãããŠçšããããšãã§ããã æ¬çºæãçšããŠäœãããæå ææã«ã¯èŠªæ°Žæ§ã³
ãã€ãå±€ã«çŽ«å€ç·åžåå€ãå«ãã§ãããããšãã°
ã¢ãªãŒã«åºã§çœ®æããããã³ãŸããªã¢ãŸãŒã«åå
ç©ãïŒâãã¢ãŸãªãã³ååç©ããã³ãŸããšãã³å
åç©ãæ¡ç®é žãšã¹ãã«ååç©ããã¿ãžãšã³åå
ç©ããã³ãŸãªããµãŸãŒã«ååç©ãããã«çŽ«å€ç·åž
åæ§ã®ããªããŒãªã©ãçšããããšãã§ããããã
ãã®çŽ«å€ç·åžåå€ã¯äžèšèŠªæ°Žæ§ã³ãã€ãå±€äžã«åº
å®ãããŠãããã 玫å€ç·åžåå€ã®å ·äœäŸã¯ãç±³åœç¹èš±3533794å·ã
å3314794å·ãå3352681å·ãç¹éæ46â2784å·ã
ç±³åœç¹èš±3705805å·ãå3707375å·ãå4045229å·ã
å3700455å·ãå3499762å·ã西ç¬ç¹èš±åºé¡å ¬å
1547863å·ãªã©ã«èšèŒãããŠããã æ¬çºæãçšããŠäœãããæå ææã«ã¯ãã€ã«ã¿
ãŒææãšããŠããããã¯ã€ã©ãžãšãŒã·ãšã³é²æ¢ã
ã®ä»çš®ã ã®ç®çã§ãæ°Žæº¶æ§ææã嫿ããŠããã
ãã®ãããªææã«ã¯ãªããœããŒã«ææããããªã
ãœããŒã«ææãã¹ããªã«ææãã¡ãã·ã¢ãã³æ
æãã·ã¢ãã³ææåã³ã¢ãŸææãå å«ããããäž
ã§ããªããœããŒã«ææïŒãããªããœããŒã«ææå
ã³ã¡ãã·ã¢ãã³ææãæçšã§ããã çšãåŸãå ·äœäŸã¯è±åœç¹èš±546708å·ãå584609
å·ãå1265842å·ãå1410488å·ãç±³åœç¹èš±
2274782å·ãå2286714å·ãå2526632å·ãå
2606833å·ãå2956879å·ãå3148187å·ãå
3247127å·ãå3481927å·ãå3575704å·ãå
3653905å·ãå3718472å·ã«èšèŒãããŠããã æ¬çºæãçšããŠäœãããåçæå ææã®åçä¹³
å€å±€ã«ã¯è²çŽ æ¡æ£åã«ãã©ãŒä»¥å€ã«å ¬ç¥ã®è²åœ¢æ
ã«ãã©ãŒãããªãã¡çºè²çŸååŠçã«ãããŠè³éŠæ
ïŒçŽã¢ãã³çŸåè¬ïŒäŸãã°ãããšãã¬ã³ãžã¢ãã³
èªå°äœããã¢ããããšããŒã«èªå°äœãªã©ïŒãšã®é ž
åã«ãããªã³ã°ã«ãã€ãŠçºè²ãããååç©ãäŸã
ã°ãããŒã³ã¿ã«ãã©ãŒãšããŠãïŒâãã©ãŸãã³ã«
ãã©ãŒããã©ãŸããã³ãã€ãããŸãŒã«ã«ãã©ãŒã
ã·ã¢ãã¢ã»ãã«ã¯ããã³ã«ãã©ãŒãééã¢ã·ã«ã¢
ã»ããããªã«ã«ãã©ãŒçããããã€ãšããŒã«ãã©
ãŒãšããŠãã¢ã·ã«ã¢ã»ãã¢ããã«ãã©ãŒïŒäŸãã°
ãã³ãŸã€ã«ã¢ã»ãã¢ããªãé¡ããããã€ã«ã¢ã»ã
ã¢ããªãé¡ïŒãçããããã·ã¢ã³ã«ãã©ãŒãšããŠã
ããããŒã«ã«ãã©ãŒãããã³ããšããŒã«ã«ãã©
ãŒãçãããããããã®ã«ãã©ãŒã¯ååäžã«ãã©
ã¹ãåºãšãã°ããçæ°Žåºãæããéæ¡æ£ã®ãã®ã
æãŸãããã«ãã©ãŒã¯éã€ãªã³ã«å¯ŸãïŒåœéæ§ã
ããã¯ïŒåœéæ§ã®ã©ã¡ãã§ãããããŸãè²è£æ£ã®
广ããã€ã«ã©ãŒãã«ãã©ãŒããããã¯çŸåã«ãš
ããªã€ãŠçŸåæå¶å€ãæŸåºããã«ãã©ãŒïŒããã
ãDIRã«ãã©ãŒïŒã§ãã€ãŠãããããŸãDIRã«ã
ã©ãŒä»¥å€ã«ããã«ãããªã³ã°åå¿ã®çæç©ãç¡è²
ã§ãã€ãŠçŸåæå¶å€ãæŸåºããç¡åè²DIRã«ãã
ãªã³ã°ååç©ãå«ãã§ãããã ã«ãã©ãŒãããã²ã³åéä¹³å€å±€ã«å°å ¥ããã«ã¯
å ¬ç¥ã®æ¹æ³ããšãã°ç±³åœç¹èš±2322027å·ã«èšèŒã®
æ¹æ³ãªã©ãçšãããããããšãã°ãã¿ãŒã«é žã¢ã«
ãã«ãšã¹ãã«ïŒãžããã«ãã¿ã¬ãŒãããžãªã¯ãã«
ãã¿ã¬ãŒããªã©ïŒããªã³é žãšã¹ãã«ïŒãžããšãã«
ããªã¹ããšãŒããããªããšãã«ããªã¹ããšãŒãã
ããªã¯ã¬ãžã«ããªã¹ããšãŒãããžãªã¯ãã«ããã«
ããªã¹ããšãŒãïŒãã¯ãšã³é žãšã¹ãã«ïŒããšãã°
ã¢ã»ãã«ã¯ãšã³é žããªããã«ïŒã宿¯éŠé žãšã¹ã
ã«ïŒããšãã°å®æ¯éŠé žãªã¯ãã«ïŒãã¢ã«ãã«ã¢ã
ãïŒããšãã°ãžãšãã«ã©ãŠãªã«ã¢ããïŒãèèªé ž
ãšã¹ãã«é¡ïŒããšãã°ãžãããã·ãšãã«ãµã¯ã·ã
ãŒãããžãªã¯ãã«ã¢ãŒã¬ãŒãïŒãããªã¡ã·ã³é žãš
ã¹ãã«é¡ïŒããšãã°ããªã¡ã·ã³é žããªããã«ïŒãª
ã©ããŸãã¯æ²žç¹çŽ30âä¹è³150âã®ææ©æº¶åªãã
ãšãã°é ¢é žãšãã«ãé ¢é žããã«ã®ããšãäœçŽã¢ã«
ãã«ã¢ã»ããŒããããããªã³é žãšãã«ãïŒçŽãã
ã«ã¢ã«ã³ãŒã«ãã¡ãã«ã€ãœããã«ã±ãã³ãβâãš
ããã·ãšãã«ã¢ã»ããŒããã¡ãã«ã»ããœã«ãã¢ã»
ããŒãçã«æº¶è§£ããã®ã¡ã芪氎æ§ã³ãã€ãã«åæ£
ããããäžèšã®é«æ²žç¹ææ©æº¶åªãšäœæ²žç¹ææ©æº¶åª
ãšãæ··åããŠçšããŠãããã ãŸãç¹éæ51â39853å·ãç¹éæ51â59943å·ã«
èšèŒãããŠããéåç©ã«ãã忣æ³ã䜿çšããã
ãšãã§ããã ã«ãã©ãŒãã«ã«ãã³é žãã¹ã«ããªã³é žã®ããšã
é žåºãæããå Žåã«ã¯ãã¢ã«ã«ãªæ§æ°Žæº¶æ¶²ãšããŠ
芪氎æ§ã³ãã€ãäžã«å°å ¥ãããã æ¬çºæã¯ãã®å®æœæ æ§ã«ãããŠã髿åŽä¹³å€å±€
ã§å®æœãããšç¹ã«å¹æã倧ããã æ¬çºæã¯é¢è±åºã®æ¡æ£æ§ãç¹ã«å€§ããDIRã«ã
ã©ãŒåã¯ç¹éæ54â145135ãBritâ2072363èšèŒ
ã®ã¿ã€ãã³ã°èª¿ç¯åºããã€ãDIRã«ãã©ãŒãšçµã¿
åããããšãç¹ã«å¥œãŸããã 宿œäŸ ïŒ ä»¥äžã®ããã«ããŠå忣乳å€ïŒ¡ã調補ããã ãŸãèåã«ãª0.01ã¢ã«ãã¢ã³ã¢ãã¢1.4ã¢ã«ã
å«ãïŒã®ãŒã©ãã³æ°Žæº¶æ¶²ãåå¿å®¹åšã«å ¥ããã
ãã«ç¡é žé0.27ã¢ã«ãå«ã氎溶液500c.c.ãšèåã«
ãª0.24ã¢ã«ãæ²åã«ãª0.043ã¢ã«ãå«ã氎溶液500
c.c.ãšãåæã«ã30åãããŠãæ·»å äžã¯ããã²ã³ã€
ãªã³ãéã€ãªã³ã«å¯ŸããŠ0.2ïœïŒéå°ã«ãªãã
ãã«èª¿ç¯ãã€ã€æ·»å ããããã®åŸé žãçšããŠã¢ã³
ã¢ãã¢ãäžåããåŸãããã«0.62ã¢ã«ã®ç¡é žéã
å«ã氎溶液500c.c.ãšèåã«ãª0.71ã¢ã«ãæ²åã«ãª
0.01ã¢ã«ãå«ã氎溶液500c.c.ãšãåæã«30åãã
ãŠãæ·»å äžã¯ããã²ã³ã€ãªã³ãéã€ãªã³ã«å¯ŸããŠ
0.2ïœïŒéå°ã«ãªãããã«èª¿ç¯ãã€ã€æ·»å ããã ãã®ä¹³å€ã¯ãå šç²åã®92ïŒ ãå¹³åç²åãµã€ãºã®
±40ïŒ ã®ç¯å²å ã«å ¥ã€ãŠãããµã€ãºååžããã€ãŠ
ããã æ¯èŒã®ããã®å€åæ£ä¹³å€ïŒ¢ã¯ä»¥äžã®ããã«èª¿è£œ
ããã ãŸãèåã«ãª0.3ã¢ã«ãæ²åã«ãª0.036ã¢ã«ãå«
ããŒã©ãã³æ°Žæº¶æ¶²ãåå¿å®¹åšäžã«å ¥ããããã«
1.3ã¢ã«ã®ç¡é žéãå«ã氎溶液ããã³èåã«ãª1.1
ã¢ã«ãæ²åã«ãª0.042ã¢ã«ãå«ã氎溶液ãåæã«
40åéã§æ·»å ããã ãã®ä¹³å€ã¯å šç²åã®85ïŒ ãå¹³åç²åãµã€ãºã®Â±
40ïŒ ã®ç¯å²å ã«å ¥ã€ãŠãããµã€ãºååžããã€ãŠã
ãã å忣乳å€ïŒ¡ãå€åæ£ä¹³å€ïŒ¢ããããå ¬ç¥ãæ¹
æ³ã§æé©ç¹ãŸã§åŸçããã 以äžã®ä¹³å€ã第ïŒå±€ã«çšãã以äžã®ããã«ããŠ
詊æ101ã103ã調補ããã ã»ã«ããŒã¹ããªã¢ã»ããŒããã€ã«ã æ¯æäœäžã«
äžèšã«ç€ºããããªçµæã®åå±€ãããªãå€å±€ã«ã©ãŒ
æå ææãäœè£œããã 第ïŒå±€ïŒãã¬ãŒã·ãšã³é²æ¢å±€ é»è²ã³ãã€ãéãå«ããŒã©ãã³å±€ 第ïŒå±€ïŒäžéå±€ ïŒïŒïŒâãžâïœâãªã¯ãã«ãã€ããããã³ã®
ä¹³å忣ç©ãå«ããŒã©ãã³å±€ 第ïŒå±€ïŒç¬¬ïŒèµ€æä¹³å€å±€ æ²èåéä¹³å€ïŒæ²åéïŒïŒã¢ã«ïŒ ïŒâŠéå¡åžé
1.79ïœïŒm2 墿è²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠïŒÃ10-5ã¢ã« 墿è²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠ1.5Ã10-5ã¢ã« ã«ãã©ãŒïŒ¡âŠéïŒã¢ã«ã«å¯ŸããŠ0.4ã¢ã« ã«ãã©ãŒïŒ£âŠéïŒã¢ã«ã察ããŠ0.003ã¢ã« ã«ãã©ãŒïŒ€âŠéïŒã¢ã«ã«å¯ŸããŠ0.0006ã¢ã« 第ïŒå±€ïŒç¬¬ïŒèµ€æä¹³å€å±€ æ²èåéä¹³å€ïŒæ²åéïŒïŒã¢ã«ïŒ ïŒâŠéå¡åžé
1.4ïœïŒm2 墿è²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠïŒÃ10-5ã¢ã« 墿è²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠ1.2Ã10-5ã¢ã« ã«ãã©ãŒïŒ¥âŠéïŒã¢ã«ã«å¯ŸããŠ0.02ã¢ã« ã«ãã©ãŒïŒ£âŠéïŒã¢ã«ã«å¯ŸããŠ0.0016ã¢ã« 第ïŒå±€ïŒäžéå±€ 第ïŒå±€ãšåã 第ïŒå±€ïŒç¬¬ïŒç·æä¹³å€å±€ æ²èåéä¹³å€ïŒæ²åéïŒïŒã¢ã«ïŒ ïŒâŠå¡åžéé
1.5ïœïŒm2 墿è²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠïŒÃ10-5ã¢ã« 墿è²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠïŒÃ10-5ã¢ã« ã«ãã©ãŒïŒ¢âŠéïŒã¢ã«ã«å¯ŸããŠ0.05ã¢ã« ã«ãã©ãŒïŒâŠéïŒã¢ã«ã«å¯ŸããŠ0.008ã¢ã« ã«ãã©ãŒïŒ€âŠéïŒã¢ã«ã«å¯ŸããŠ0.0015ã¢ã« 第ïŒå±€ïŒç¬¬ïŒç·æä¹³å€å±€ åèšã®è£œé æ³ã§äœè£œããå€åæ£æ²å±€åéä¹³å€ïŒ¢
ïŒæ²åéïŒïŒã¢ã«ïŒ ïŒâŠå¡åžéé1.6ïœïŒm2 墿è²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠ2.5Ã10-5ã¢ã« 墿è²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠ0.8Ã10-5ã¢ã« ã«ãã©ãŒïŒ¢âŠéïŒã¢ã«ã«å¯ŸããŠ0.02ã¢ã« ã«ãã©ãŒïŒâŠéïŒã¢ã«ã«å¯ŸããŠ0.003ã¢ã« ã«ãã©ãŒïŒ€âŠéïŒã¢ã«ã«å¯ŸããŠ0.0003ã¢ã« 第ïŒå±€ïŒã€ãšããŒãã€ã«ã¿ãŒå±€ ãŒã©ãã³æ°Žæº¶æ¶²äžã«é»è²ã³ãã€ãéãšïŒã»ïŒ
âãžâïœâãªã¯ãã«ãã€ããããã³ã®ä¹³å忣
ç©ãšãå«ããŒã©ãã³å±€ã 第ïŒå±€ïŒç¬¬ïŒéæä¹³å€å±€ æ²èåéä¹³å€ïŒæ²åéïŒïŒã¢ã«ïŒ ïŒâŠå¡åžéé
1.5ïœïŒm2 ã«ãã©ãŒïŒ¹âŠéïŒã¢ã«ã«å¯ŸããŠ0.25ã¢ã« 第10å±€ïŒç¬¬ïŒéæä¹³å€å±€ æ²èåéïŒæ²åéïŒïŒã¢ã«ïŒ ïŒâŠå¡åžéé1.1
ïœïŒm2 ã«ãã©ãŒïŒ¹âŠéïŒã¢ã«ã«å¯ŸããŠ0.06ã¢ã« 第11å±€ïŒä¿è·å±€ ããªã¡ãã«ã¡ã¿ãã¢ã¯ãªã¬ãŒãç²åïŒçŽåŸçŽ
1.5ÎŒïŒãå«ããŒã©ãã³å±€ãå¡åžã åå±€ã«ã¯äžèšçµæç©ã®ä»ã«ããŒã©ãã³ç¡¬åå€ã
ç颿޻æ§å€ãæ·»å ããã 以äžã®åŠãããŠäœè£œãã詊æã詊æ101ãšããã 詊æãäœãã®ã«çšããååç© å¢æè²çŽ ïŒã¢ã³ãããâïŒã»5â²âãžã¯ããâ
ïŒã»3â²âãžâïŒÎ³âã¹ã«ããããã«ïŒâïŒâãšã
ã«âãã¢ã«ã«ãã·ã¢ãã³ãããããµã€ãã»ããª
ãžããŠã å¡© 墿è²çŽ ïŒã¢ã³ãããâïŒâãšãã«âïŒã»3â²â
ãžâïŒÎ³âã¹ã«ããããã«ïŒâïŒã»ïŒã»4â²ã»5â²â
ãžãã³ãŸãã¢ã«ã«ãã·ã¢ãã³ãããããµã€ãã»
ããªãšãã«ã¢ãã³å¡© 墿è²çŽ ïŒã¢ã³ãããâïŒâãšãã«âïŒã»5â²â
ãžã¯ããâïŒã»3â²âãžïŒÎ³âã¹ã«ããããã«ïŒ
ãªããµã«ã«ãã·ã¢ãã³ã»ãããªãŠã å¡© 墿è²çŽ ïŒã¢ã³ãããâïŒã»ïŒã»5â²ã»6â²âãã
ã©ã¯ããâïŒã»1â²âãžãšãã«âïŒã»3â²âãžâ
ïœÎ²âãβâïŒÎ³âã¹ã«ãããããã·ïŒãšããã·ã
ãšãã«ã€ãããŸãã«ã«ãã·ã¢ãã³ãããããµã€
ããããªãŠã å¡© 詊æ102ïŒè©Šæ101ã®ã«ãã©ãŒïŒ¢ã®ãããã«ã«ãã©
ãŒïŒâïŒãã«ãã©ãŒïŒ¢ãšçã¢ã«ã§çœ®ãæãã以
å€è©Šæ101ãšåæ§ã«äœè£œããã 詊æ103ïŒè©Šæ102ã®ç¬¬ïŒå±€ã«å忣乳å€ïŒ¡ãçšã
ã以å€ã¯è©Šæ102ãšåæ§ã«äœè£œããã åŸããã詊æ101ã103ãçœå ã§ãŠãšããžé²å ã
ãããšãããã»ãŒåçã®æåºŠãé調ã®ãã®ãåŸã
ããã ããã§çšããçŸååŠçã¯äžèšã®éãã«38âã§è¡
ãªã€ãã ïŒ ã«ã©ãŒçŸåâŠâŠïŒå15ç§ ïŒ æŒçœâŠâŠïŒå30ç§ ïŒ æ°ŽæŽâŠâŠïŒå15ç§ ïŒ å®çâŠâŠïŒå30ç§ ïŒ æ°ŽæŽâŠâŠïŒå15ç§ ïŒ å®å®âŠâŠïŒå15ç§ åå·¥çšã«çšããåŠçæ¶²çµæã¯äžèšã®ãã®ã§ã
ãã ã«ã©ãŒçŸåæ¶² ãããäžé ¢é žãããªãŠã 1.0ïœ äºç¡«é žãããªãŠã 4.0ïœ çé žãããªãŠã 30.0ïœ èåã«ãª 1.4ïœ ããããã·ã«ã¢ãã³ç¡«é žå¡© 2.4ïœ ïŒâïŒïŒ®âãšãã«ââβããããã·ãšãã«ã¢ã
ãïŒâïŒâã¡ãã«âã¢ããªã³ç¡«é žå¡© 4.5ïœ æ°Žãå ããŠ ïŒ æŒçœæ¶² èåã¢ã³ã¢ããŠã 160.0ïœ ã¢ã³ã¢ãã¢æ°ŽïŒ28ïŒ ïŒ 25.0ml ãšãã¬ã³ãžã¢ãã³âåé ¢é žãããªãŠã éå¡© 130ïœ æ°·é ¢é ž 14ml æ°Žãå ããŠ ïŒ å®çæ¶² ããã©ããªãªã³é žãããªãŠã 2.0ïœ äºç¡«é žãããªãŠã 4.0ïœ ããªç¡«é žã¢ã³ã¢ããŠã ïŒ70ïŒ ïŒ 175.0ml éäºç¡«é žãããªãŠã 4.6ïœ æ°Žãå ããŠ ïŒ å®å®æ¶² ãã«ããªã³ 8.0ml æ°Žãå ããŠ ïŒ ãããã®è©Šæã®ããŒã³ã¿è²åã®ç²ç¶æ§ã«ã€ããŠ
æ £çšã®RMSæ³ã§å€å®ãããRMSæ³ã«ããç²ç¶æ§
ã®å€å®ã¯åœäºè éã§ã¯åšç¥ã®äºã§ãããâThe
Theory of the Photographic Processâ4th
Ed.P619ã«èšèŒãããŠãããæž¬å®éå£ã¯10ÎŒãšã
ãã ãŸã詊æ101ã103ã«ã€ããŠ110ãµã€ãºã«å å·¥ã
ãŠå®ææ®åœ±ãè¡ããã€ãã§ãã€ãããµã€ãºã«ããª
ã³ãããŠç²ç¶æ§ã®å¿çè©äŸ¡ãè¡ãªã€ãã ããã«è©Šæ101ã103ã®ããŒã³ã¿è²åã®ç²ç¶æ§ã«
ã€ããŠãŽã€ããŒã¹ãã¯ãã«ïŒæž¬å®éå£ã¯10ÎŒïŒã
æ±ããã 以äžã®ãã¡ãRMSç²ç¶æ§å€ãå¿çè©äŸ¡ã®çµæ
ã«ã€ããŠè¡šïŒã«ãŸãšããã
ã衚ã
衚ïŒã¯ãè²çŽ æ¡æ£åã«ãã©ãŒãçšãã詊æ102
ã¯è©Šæ101ããRMSç²ç¶å€ã§ã¿ããšç²ç¶ãæ¹è¯ã
ããŠããããšã瀺ããŠããããããèŠèŠçã«ã¯é«
æ¿åºŠéšã§è²çŽ ã®ãããŸããç®ã«ã€ããç²ç¶ããã
ã€ãŠæªãã¿ããããšã瀺ããŠããã ãã®ããšã¯ãŽã€ããŒã¹ãã¯ãã«ïŒç¬¬ïŒå³ïŒãã¿
ããšèª¬æãã€ãã 第ïŒå³ã¯ãè²çŽ æ¡æ£åã«ãã©ãŒãçšãã詊æ
102ã®ã¹ãã¯ãã«ãïŒãµã€ã¯ã«ïŒmmããäœåšæ³¢ã§
詊æ101ã®ããããé«ãäœçœ®ã«ããŠããã詊æ102
ã«ãããŠè²çŽ é²ãéãªã€ãŠããããšã瀺ããŠã
ããäžæ¹å忣乳å€ãçšãã詊æ103ã§ã¯ãã®ã¹
ãã¯ãã«ã¯å šé åã§è©Šæ101ããäœãæã«äœçœ®ã
ãŠãããå¿ççç²ç¶æ§ãããã¿ããããšãšäžèŽã
ãã 宿œäŸ ïŒ å®æœäŸïŒã§äœè£œãã詊æ101ã®ç¬¬ïŒå±€ã®ã«ãã©
ãŒïŒ¥ã®ä»£ãã«ã«ãã©ãŒïŒ£âïŒãçšããä¹³å€ãå€å
æ£ä¹³å€ïŒ¢ã«çœ®ãæãããã以å€ã¯è©Šæ101ãšåã
ããã«ããŠè©Šæ202ã調補ããããã®è©Šæ202ã®ç¬¬
ïŒå±€ã®ä¹³å€ãå忣乳å€ïŒ¡ã«å€æŽãã以å€ã¯è©Šæ
202ãšåæ§ã«ããŠè©Šæ203ã調補ããã 詊æ101ã202ã203ã«ã€ããŠå®æœäŸïŒãšåæ§ã®
åŠçããããã®åŠçæžè©Šæã«ã€ããŠRMSå€ããŽ
ã€ããŒã¹ãã¯ãã«ãæ±ããä»ã«ç²ç¶æ§ã®å¿çè©äŸ¡
ãè¡ãªã€ãããããã®çµæã衚ïŒã«ãŸãšããã
ã¯è©Šæ101ããRMSç²ç¶å€ã§ã¿ããšç²ç¶ãæ¹è¯ã
ããŠããããšã瀺ããŠããããããèŠèŠçã«ã¯é«
æ¿åºŠéšã§è²çŽ ã®ãããŸããç®ã«ã€ããç²ç¶ããã
ã€ãŠæªãã¿ããããšã瀺ããŠããã ãã®ããšã¯ãŽã€ããŒã¹ãã¯ãã«ïŒç¬¬ïŒå³ïŒãã¿
ããšèª¬æãã€ãã 第ïŒå³ã¯ãè²çŽ æ¡æ£åã«ãã©ãŒãçšãã詊æ
102ã®ã¹ãã¯ãã«ãïŒãµã€ã¯ã«ïŒmmããäœåšæ³¢ã§
詊æ101ã®ããããé«ãäœçœ®ã«ããŠããã詊æ102
ã«ãããŠè²çŽ é²ãéãªã€ãŠããããšã瀺ããŠã
ããäžæ¹å忣乳å€ãçšãã詊æ103ã§ã¯ãã®ã¹
ãã¯ãã«ã¯å šé åã§è©Šæ101ããäœãæã«äœçœ®ã
ãŠãããå¿ççç²ç¶æ§ãããã¿ããããšãšäžèŽã
ãã 宿œäŸ ïŒ å®æœäŸïŒã§äœè£œãã詊æ101ã®ç¬¬ïŒå±€ã®ã«ãã©
ãŒïŒ¥ã®ä»£ãã«ã«ãã©ãŒïŒ£âïŒãçšããä¹³å€ãå€å
æ£ä¹³å€ïŒ¢ã«çœ®ãæãããã以å€ã¯è©Šæ101ãšåã
ããã«ããŠè©Šæ202ã調補ããããã®è©Šæ202ã®ç¬¬
ïŒå±€ã®ä¹³å€ãå忣乳å€ïŒ¡ã«å€æŽãã以å€ã¯è©Šæ
202ãšåæ§ã«ããŠè©Šæ203ã調補ããã 詊æ101ã202ã203ã«ã€ããŠå®æœäŸïŒãšåæ§ã®
åŠçããããã®åŠçæžè©Šæã«ã€ããŠRMSå€ããŽ
ã€ããŒã¹ãã¯ãã«ãæ±ããä»ã«ç²ç¶æ§ã®å¿çè©äŸ¡
ãè¡ãªã€ãããããã®çµæã衚ïŒã«ãŸãšããã
ã衚ã
衚ïŒããè²çŽ æ¡æ£åã·ã¢ã³ã«ãã©ãŒã䜿ã€ã詊
æ202ã¯RMSå€ã¯å°ãããªã€ãŠãããã倧ããªã
ã©ãçºçããç²ç¶ãåŽã€ãŠæªãã¿ããããšãæã
ãã§ããããã®è©äŸ¡ã¯ç¬¬ïŒå³ã®ãŽã€ãŒããŒã¹ãã¯
ãã«ã«ãããŠè©Šæ202ã®ã¹ãã¯ãã«ãïŒãµã€ã¯
ã«ïŒmmããäœåšæ³¢ã®æã§è©Šæ101ã®ããããäžã«
ããããšãšäžèŽããã詊æ202ã«å忣乳å€ïŒ¡ã
çµåãã詊æ203ã¯ãŽã€ããŒã¹ãã¯ãã«ãå šé å
ã§è©Šæ101ã202ã®ããããäžã«ããã衚ïŒã®å¿ç
çè©äŸ¡ãšäžèŽããã
æ202ã¯RMSå€ã¯å°ãããªã€ãŠãããã倧ããªã
ã©ãçºçããç²ç¶ãåŽã€ãŠæªãã¿ããããšãæã
ãã§ããããã®è©äŸ¡ã¯ç¬¬ïŒå³ã®ãŽã€ãŒããŒã¹ãã¯
ãã«ã«ãããŠè©Šæ202ã®ã¹ãã¯ãã«ãïŒãµã€ã¯
ã«ïŒmmããäœåšæ³¢ã®æã§è©Šæ101ã®ããããäžã«
ããããšãšäžèŽããã詊æ202ã«å忣乳å€ïŒ¡ã
çµåãã詊æ203ã¯ãŽã€ããŒã¹ãã¯ãã«ãå šé å
ã§è©Šæ101ã202ã®ããããäžã«ããã衚ïŒã®å¿ç
çè©äŸ¡ãšäžèŽããã
第ïŒå³âŠâŠè©Šæ101ã102ã103ã®ããŒã³ã¿åã®
ãŽã€ãŒããŒã¹ãã¯ãã«ã§ããã第ïŒå³âŠâŠè©Šæ
101ã202ã203ã®ã·ã¢ã³åã®ãŽã€ãŒããŒã¹ãã¯ã
ã«ã§ããã
ãŽã€ãŒããŒã¹ãã¯ãã«ã§ããã第ïŒå³âŠâŠè©Šæ
101ã202ã203ã®ã·ã¢ã³åã®ãŽã€ãŒããŒã¹ãã¯ã
ã«ã§ããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ éæå±€ãç·æå±€ãèµ€æå±€ãããªãããã²ã³å
éä¹³å€å±€ã®å°ãªããšãäžå±€ã«ãçºè²çŸåäž»è¬ã®é ž
åçæç©ãšåå¿ããŠé©åºŠã«è²çŽ ãã«ããäžè¬åŒ
ïŒïŒãïŒïŒãïŒïŒãïŒïŒãïŒïŒãïŒXIïŒãŸã
ã¯
ïŒXIIïŒã§è¡šããããæ¡æ£æ§è²çŽ ãçæãããé
æ¡æ£æ§ã«ãã©ãŒãšãå忣ã®ããã²ã³åéä¹³å€ãš
ãã䜵çšããããšãç¹åŸŽãšããããã²ã³åéã«ã©
ãŒåçæå ææã äžè¬åŒïŒïŒ äžè¬åŒïŒïŒ åŒäžR1ãR2ãR3ããã³R4ã¯åãã§ãã€ãŠãç°
ã€ãŠããããæ°ŽçŽ ååãããã²ã³ååãã¢ã«ãã«
åºãã¢ã«ã³ãã·åºãã¢ãªãŒã«ãªãã·åºãã¢ã·ã«ã¢
ããåºãã¹ã«ãã³ã¢ããåºãã«ã«ãã¢ã€ã«åºãã¹
ã«ãã¢ã¢ã€ã«åºãã¢ã«ãã«ããªåºãã¢ã«ãã«ã¹ã«
ããã«åºãã¢ã«ã³ãã·ã«ã«ããã«åºããŠã¬ã€ã
åºãã·ã¢ãåºãã«ã«ããã·ã«åºãããããã·åºãŸ
ãã¯ã¹ã«ãåºã衚ããããã ãR1ãR2ãR3ãã
ã³R4ã®ççŽ æ°ã®åèšã¯10ãè¶ããªãã Xâ²ã¯ã«ãã©ãŒã«éæ¡æ£æ§ãäžããççŽ æ°ïŒã
32ã®ãã©ã¹ãåºãæãããã€è³éŠæç¬¬ïŒçŽã¢ãã³
çŸåè¬ã®é žåäœãšã®ã«ãããªã³ã°ã«ããé¢è±ãã
ãåºã衚ããã äžè¬åŒïŒïŒ ãåŒã äžè¬åŒïŒïŒ ãåŒã äžè¬åŒïŒïŒ åŒäžR5ã¯ã¢ã·ã«ã¢ããåºãã¢ããªãåºãŸãã¯
ãŠã¬ã€ãåºã衚ãããR6ããã³R7ã¯åã ããã
ã²ã³ååãã¢ã«ãã«åºãã¢ã«ã³ãã·åºãã¢ã·ã«ã¢
ããåºãã¢ã«ã³ãã·ã«ã«ããã«åºãâã¢ã«ãã«
ã«ã«ãã¢ã€ã«åºããŠã¬ã€ãåºãã·ã¢ãåºãã¢ãªãŒ
ã«åºãïŒïŒ®âãžã¢ã«ãã«ã¹ã«ãã¢ã¢ã€ã«åºãã
ããåºãããããã·åºãã«ã«ããã·åºããã³ã¢ãª
ãŒã«ãªãã·åºããéžã°ããåºã§ïœã¯ïŒãïŒã®æŽæ°
ã§ãããïœãïŒä»¥äžã®ãšãR6ã¯åãã§ãç°ã€ãŠ
ããŠãããããã ãäžè¬åŒïŒïŒããã³ïŒïŒã§
ã¯R5ãšïœåã®R6ãäžè¬åŒïŒïŒã§ã¯R6ãšR7ã«å«
ãŸããççŽ æ°ã®åèšã¯10ãè¶ããªããXâ³ã¯äžèš
äžè¬åŒïŒïŒãïŒïŒããã³ïŒïŒã衚ããã äžè¬åŒïŒïŒ äžè¬åŒïŒïŒ ââR8 äžè¬åŒïŒïŒ R8ã¯çœ®æãããã¯ç¡çœ®æã®ã¢ã«ãã«åºãã¢ã©
ã«ãã«åºãã¢ã«ã±ãã«åºãç¡çœ®æãããã¯çœ®æã¢
ãªãŒã«åºãŸãã¯ç°ç¶ã¢ã«ãã«åºã衚ãããïœåå
ã¯ïœåã®R8ã«å«ãŸããççŽ æ°ã®åèšã¯ïŒã32ã§
ãããïœã¯ïŒãïŒãïœã¯ïŒãïŒã®æŽæ°ã衚ããã äžè¬åŒïŒXIïŒ äžè¬åŒïŒXIIïŒ R9ã¯æ°ŽçŽ ååãççŽ æ°10以äžã®èèªæåºãç
çŽ æ°10以äžã®ã¢ã«ã³ãã·åºãã¢ãªãŒã«ãªãã·åºã
次åŒïŒïŒãïŒïŒã«ç€ºãã¢ã·ã«ã¢ããåºã
ã¹ã«ãã³ã¢ããåºããŠã¬ã€ãåºãŸãã¯æ¬¡åŒïŒ
ïŒã«ç€ºãã«ã«ãã¢ã€ã«åºã衚ããã âNHâCOâ ïŒïŒ âNHâSO2â ïŒïŒ âNHCONHâ ïŒïŒ åŒäžïŒ§ãGâ²ã¯åäžã§ãç°ã€ãŠããŠããããã
ãããæ°ŽçŽ ååïŒäœãããGâ²ãåæã«æ°ŽçŽ å
åã§ããããšã¯ãªããããGâ²ã®åèšã®ççŽ æ°
ïŒãïŒïŒãççŽ æ°ïŒãïŒã®èèªæåºããŸãã¯ã¢ãª
ãŒã«åºã衚ãããR10ã¯æ°ŽçŽ ååãççŽ æ°10以äž
ã®èèªæåºã衚ãããR11ãR12ãR13ãR14ãR15
ããã³R16ã¯åã æ°ŽçŽ ååãããã²ã³ååãã¢ã«
ãã«åºãã¢ãªãŒã«åºãã¢ã«ã³ãã·åºãã¢ã«ãã«ã
ãªåºããããç°åºãã¢ããåºãã«ã«ãã³ã¢ãã
åºãã¹ã«ãã³ã¢ããåºãã¹ã«ãã¢ãã«åºãåã¯ã«
ã«ããã«åºã衚ããã ãã ããäžè¬åŒïŒXIïŒã«ãããR9ãR11ãR12ã
åã³R13ãäžè¬åŒïŒXIIïŒã«ãããR10ãR11ãR12ã
R13ãR14ãåã³R15ã«å«ãŸããççŽ æ°ã®åèšã¯ã
ããã10ãè¶ ããªããã¯ïŒãŸãã¯ïŒå¡ç°ã圢æ
ããã«å¿ èŠãªééå±ååã衚ããã ãã¯ççŽ æ°ïŒã32ã®åºããã¡ãââãâ
âãâïŒïŒ®âãä»ããŠã«ãããªã³ã°äœãšçµåã
ãŠãããè³éŠæäžçŽã¢ãã³çŸåè¬ã®é žåäœãšã«ã
ããªã³ã°ãé¢è±ããåºã衚ããã
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58007152A JPS59131936A (ja) | 1983-01-19 | 1983-01-19 | ããã²ã³åéã«ã©âåçæå ææ |
| DE8484100558T DE3477699D1 (en) | 1983-01-19 | 1984-01-19 | Silver halide color photographic light-sensitive material |
| EP84100558A EP0114674B1 (en) | 1983-01-19 | 1984-01-19 | Silver halide color photographic light-sensitive material |
| US06/572,049 US4536472A (en) | 1983-01-19 | 1984-01-19 | Silver halide color photographic light-sensitive material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58007152A JPS59131936A (ja) | 1983-01-19 | 1983-01-19 | ããã²ã³åéã«ã©âåçæå ææ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59131936A JPS59131936A (ja) | 1984-07-28 |
| JPH0434735B2 true JPH0434735B2 (ja) | 1992-06-08 |
Family
ID=11658092
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58007152A Granted JPS59131936A (ja) | 1983-01-19 | 1983-01-19 | ããã²ã³åéã«ã©âåçæå ææ |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4536472A (ja) |
| EP (1) | EP0114674B1 (ja) |
| JP (1) | JPS59131936A (ja) |
| DE (1) | DE3477699D1 (ja) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0621944B2 (ja) * | 1983-02-16 | 1994-03-23 | ã³ãã«æ ªåŒäŒç€Ÿ | ããã²ã³åéåçæå ææ |
| JPS59191036A (ja) * | 1983-04-14 | 1984-10-30 | Fuji Photo Film Co Ltd | ããã²ã³åéåçæå ææ |
| JPS6063536A (ja) * | 1983-09-17 | 1985-04-11 | Konishiroku Photo Ind Co Ltd | ããã²ã³åéåçæå ææ |
| JPS6064348A (ja) * | 1983-09-19 | 1985-04-12 | Konishiroku Photo Ind Co Ltd | ããã²ã³åéã«ã©âåçæå ææ |
| JPH0640211B2 (ja) * | 1984-02-10 | 1994-05-25 | ã³ãã«æ ªåŒäŒç€Ÿ | ããã²ã³åéã«ã©âåçæå ææ |
| DE3585044D1 (de) * | 1984-03-29 | 1992-02-13 | Konishiroku Photo Ind | Photographisches silberhalogenidmaterial. |
| JPH0617985B2 (ja) * | 1984-04-20 | 1994-03-09 | ã³ãã«æ ªåŒäŒç€Ÿ | ããã²ã³åéå€å±€ã«ã©ãŒåçæå ææ |
| JPS60229029A (ja) * | 1984-04-26 | 1985-11-14 | Fuji Photo Film Co Ltd | ããã²ã³åéã«ã©âåçæå ææ |
| JPS60232550A (ja) * | 1984-05-02 | 1985-11-19 | Fuji Photo Film Co Ltd | ããã²ã³åéã«ã©âåçæå ææ |
| US4740453A (en) * | 1984-12-27 | 1988-04-26 | Fuji Photo Film Co., Ltd. | Silver halide photosensitive material containing a compound capable of releasing a photographically useful group |
| DE3681305D1 (de) * | 1985-02-16 | 1991-10-17 | Konishiroku Photo Ind | Lichtempfindliches photographisches material. |
| US5342748A (en) * | 1985-04-20 | 1994-08-30 | Konica Corporation | Color photographic light-sensitive material for printing use |
| JPS61246748A (ja) * | 1985-04-24 | 1986-11-04 | Konishiroku Photo Ind Co Ltd | ããã²ã³åéã«ã©âåçæå ææ |
| JPS61273543A (ja) * | 1985-05-29 | 1986-12-03 | Fuji Photo Film Co Ltd | ããã²ã³åéã«ã©âåçæå ææ |
| DE3541858C2 (de) * | 1985-11-27 | 1998-01-29 | Agfa Gevaert Ag | Farbfotografisches Aufzeichnungsmaterial |
| DE3606086A1 (de) * | 1986-02-26 | 1987-08-27 | Agfa Gevaert Ag | Farbfotografisches aufzeichnungsmaterial |
| DE3625616A1 (de) * | 1986-07-29 | 1988-02-11 | Agfa Gevaert Ag | Farbfotografisches aufzeichnungsmaterial mit 2-aequivalentpurpurkupplern |
| US5246820A (en) * | 1992-03-03 | 1993-09-21 | Eastman Kodak Company | Carbamic acid solubilized smearing couplers |
| JPH07140592A (ja) * | 1993-11-16 | 1995-06-02 | Konica Corp | ããã²ã³åéåçæå ææ |
| CN1190901C (zh) * | 1998-01-09 | 2005-02-23 | çå®¶è²å©æµŠçµåæéå ¬åž | çšäºå°nïŒæ¯ç¹æºåçŒç /è§£ç 䞺对åºçmïŒæ¯ç¹ä¿¡éåç讟å€ä»¥åå°mïŒæ¯ç¹ä¿¡éåçŒç /è§£ç 䞺nïŒæ¯ç¹æºåçè®Ÿå€ |
| GB201906322D0 (en) * | 2019-05-03 | 2019-06-19 | Denyer William H | Fat |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5638043A (en) * | 1979-09-05 | 1981-04-13 | Fuji Photo Film Co Ltd | Color image forming method |
| JPS56126833A (en) * | 1980-03-12 | 1981-10-05 | Fuji Photo Film Co Ltd | Forming method for color image |
| JPS5912169B2 (ja) * | 1980-07-04 | 1984-03-21 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | ããã²ã³åéã«ã©âæå ææ |
| US4420556A (en) * | 1980-09-11 | 1983-12-13 | Eastman Kodak Company | Photographic silver halide materials |
| GB2083640B (en) * | 1980-09-11 | 1984-05-31 | Kodak Ltd | Photographic silver halide materials |
| EP0070182B1 (en) * | 1981-07-10 | 1988-10-12 | Konica Corporation | Light-sensitive color photographic material |
-
1983
- 1983-01-19 JP JP58007152A patent/JPS59131936A/ja active Granted
-
1984
- 1984-01-19 EP EP84100558A patent/EP0114674B1/en not_active Expired
- 1984-01-19 US US06/572,049 patent/US4536472A/en not_active Expired - Lifetime
- 1984-01-19 DE DE8484100558T patent/DE3477699D1/de not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE3477699D1 (en) | 1989-05-18 |
| EP0114674B1 (en) | 1989-04-12 |
| EP0114674A3 (en) | 1986-06-11 |
| US4536472A (en) | 1985-08-20 |
| JPS59131936A (ja) | 1984-07-28 |
| EP0114674A2 (en) | 1984-08-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4489155A (en) | Silver halide color photographic materials with diffusible dye for improving graininess | |
| EP0114674B1 (en) | Silver halide color photographic light-sensitive material | |
| EP0115303B1 (en) | Silver halide colour photographic light-sensitive material | |
| JPH0354329B2 (ja) | ||
| JPH0310287B2 (ja) | ||
| JPS6338695B2 (ja) | ||
| JPH0519138B2 (ja) | ||
| US4755454A (en) | Element having a silver halide photographic layer on a polyolefin coated paper base | |
| EP0096873B1 (en) | Silver halide color photographic light-sensitive materials | |
| JPH0417410B2 (ja) | ||
| US4729944A (en) | Silver halide photographic light-sensitive material | |
| JPH0345813B2 (ja) | ||
| US4705743A (en) | Silver halide color photographic light-sensitive material | |
| JPH0235972B2 (ja) | ||
| JPH0623831B2 (ja) | æ°èŠãªå±€æ§æã®ããã²ã³åéã«ã©âåçæå ææ | |
| JPH0341816B2 (ja) | ||
| JPH0254536B2 (ja) | ||
| JPH0238940B2 (ja) | ||
| JPS6370853A (ja) | è±éæ§ã®æ¹è¯ãããããã²ã³åéã«ã©âåçæå ææ | |
| JPH0374814B2 (ja) | ||
| JPH0548899B2 (ja) | ||
| JPS6093435A (ja) | ããã²ã³åéã«ã©âåçæå ææ | |
| JPH0548898B2 (ja) | ||
| JPH0355814B2 (ja) | ||
| JPH0711689B2 (ja) | ããã²ã³åéã«ã©âåçæå ææ |