RU2012142728A - Частица для доставки - Google Patents

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RU2012142728A
RU2012142728A RU2012142728/05A RU2012142728A RU2012142728A RU 2012142728 A RU2012142728 A RU 2012142728A RU 2012142728/05 A RU2012142728/05 A RU 2012142728/05A RU 2012142728 A RU2012142728 A RU 2012142728A RU 2012142728 A RU2012142728 A RU 2012142728A
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liquid
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Джитен Одхавджи ДИОРА
Джохан СМЕТС
Тодд Арлин СКВАНТЕС
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Дзе Проктер Энд Гэмбл Компани
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/11—Encapsulated compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/02—Making microcapsules or microballoons
    • B01J13/06—Making microcapsules or microballoons by phase separation
    • B01J13/14—Polymerisation; cross-linking
    • B01J13/18—In situ polymerisation with all reactants being present in the same phase
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
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    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
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    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
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    • A—HUMAN NECESSITIES
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    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/02—Making microcapsules or microballoons
    • B01J13/06—Making microcapsules or microballoons by phase separation
    • B01J13/14—Polymerisation; cross-linking
    • B01J13/18—In situ polymerisation with all reactants being present in the same phase
    • B01J13/185—In situ polymerisation with all reactants being present in the same phase in an organic phase
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0097—Dye preparations of special physical nature; Tablets, films, extrusion, microcapsules, sheets, pads, bags with dyes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C11D3/502—Protected perfumes
    • C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/12—Processes in which the treating agent is incorporated in microcapsules
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
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    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
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    • A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
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    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/60—Particulates further characterized by their structure or composition
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Abstract

1. Композиция, содержащая вспомогательный ингредиент и, в пересчете на общий вес композиции, от примерно 0,1% до примерно 50%, от примерно 0,2% до примерно 25%, от примерно 0,5% до примерно 10%, или от примерно 0,75% до примерно 5% частиц, где каждая из указанных частиц независимо имеет размер частиц от примерно 2 микрон до примерно 80 микрон, от примерно 5 микрон до примерно 50 микрон, или от примерно 10 микрон до примерно 30 микрон, причем каждая частица содержит:a) сердцевину, содержащую, в пересчете на общий вес частицы, от примерно 6% до примерно 99,9%, от примерно 11% до примерно 95%, или от примерно 50% до примерно 75%, агента, обеспечивающего полезный эффект, и от примерно 0,1% до примерно 94%, от примерно 5% до примерно 89%, или от примерно 25% до примерно 50%, модификатора распределения и/или модификатора плотности; иb) оболочку, инкапсулирующую указанную сердцевину, причем указанная оболочка содержит, в пересчете на общий вес оболочки, от примерно 50% до примерно 100%, от примерно 70% до примерно 100%, или от примерно 80% до примерно 100% полиакрилата,и указанная композиция представляет собой потребительский продукт.2. Композиция по п.1, в которой указанный агент, обеспечивающий полезный эффект, содержит материал, выбранный из группы, состоящей из ароматизаторов; осветлителей; репеллентов для отпугивания насекомых; силиконов; восков; вкусовых веществ; витаминов; мягчителей тканей; средств для ухода за кожей; ферментов; пробиотиков; конъюгата краситель-полимер; конъюгата краситель-глина; системы доставки ароматизатора; средств, создающих ощущения, в одном аспекте, холодящего агента; аттрактантов, в одном аспекте, феромона; антибактериальных агентов; красителей; �

Claims (26)

1. Композиция, содержащая вспомогательный ингредиент и, в пересчете на общий вес композиции, от примерно 0,1% до примерно 50%, от примерно 0,2% до примерно 25%, от примерно 0,5% до примерно 10%, или от примерно 0,75% до примерно 5% частиц, где каждая из указанных частиц независимо имеет размер частиц от примерно 2 микрон до примерно 80 микрон, от примерно 5 микрон до примерно 50 микрон, или от примерно 10 микрон до примерно 30 микрон, причем каждая частица содержит:
a) сердцевину, содержащую, в пересчете на общий вес частицы, от примерно 6% до примерно 99,9%, от примерно 11% до примерно 95%, или от примерно 50% до примерно 75%, агента, обеспечивающего полезный эффект, и от примерно 0,1% до примерно 94%, от примерно 5% до примерно 89%, или от примерно 25% до примерно 50%, модификатора распределения и/или модификатора плотности; и
b) оболочку, инкапсулирующую указанную сердцевину, причем указанная оболочка содержит, в пересчете на общий вес оболочки, от примерно 50% до примерно 100%, от примерно 70% до примерно 100%, или от примерно 80% до примерно 100% полиакрилата,
и указанная композиция представляет собой потребительский продукт.
2. Композиция по п.1, в которой указанный агент, обеспечивающий полезный эффект, содержит материал, выбранный из группы, состоящей из ароматизаторов; осветлителей; репеллентов для отпугивания насекомых; силиконов; восков; вкусовых веществ; витаминов; мягчителей тканей; средств для ухода за кожей; ферментов; пробиотиков; конъюгата краситель-полимер; конъюгата краситель-глина; системы доставки ароматизатора; средств, создающих ощущения, в одном аспекте, холодящего агента; аттрактантов, в одном аспекте, феромона; антибактериальных агентов; красителей; пигментов; отбеливателей; и их смесей.
3. Композиция по п.2, в которой указанный агент, обеспечивающий полезный эффект, содержит
a) парфюмерное масло; и
b) модификатор распределения.
4. Композиция по п.2, в которой указанный ароматизатор содержит от примерно 2% до примерно 80%, от примерно 20% до примерно 70%, от примерно 30% до примерно 60%, сырьевого материала ароматизатора с ClogP менее 3,5, менее 3, или от примерно 0,5 до примерно 3.
5. Композиция по п.2, в которой указанный ароматизатор содержит от примерно 2% до примерно 80%, от примерно 20% до примерно 70%, от примерно 30% до примерно 60%, сырьевого материала ароматизатора с порогом обнаружения запаха (ODT) менее 50 частей на миллиард, менее 25 частей на миллиард, или от примерно 0,1 частей на миллиард до примерно 25 частей на миллиард.
6. Композиция по п.1, в которой соотношение паровой фазы над продуктом составляет от примерно 0,05 до 0,90, от примерно 0,20 до примерно 0,80, или от примерно 0,2 до примерно 0,40.
7. Способ изготовления композиции, включающий стадию, на которой объединяют вспомогательный ингредиент и, в пересчете на общий вес композиции, от примерно 0,1% до примерно 50%, от примерно 0,2% до примерно 25%, от примерно 0,5% до примерно 10%, или от примерно 0,75% до примерно 5% частиц, где каждая из указанных частиц независимо имеет размер частиц от примерно 2 микрон до примерно 80 микрон, от примерно 5 микрон до примерно 50 микрон, или от примерно 10 микрон до примерно 30 микрон, причем каждая частица содержит:
a) сердцевину, содержащую, в пересчете на общий вес частицы, от примерно 6% до примерно 95%, от примерно 11% до примерно 85%, или от примерно 50% до примерно 75%, агента, обеспечивающего полезный эффект, и от примерно 5% до примерно 94%, от примерно 15% до примерно 89%, или от примерно 25% до примерно 50%, модификатора распределения и/или модификатора плотности; и
b) оболочку, инкапсулирующую указанную сердцевину, причем указанная оболочка содержит, в пересчете на общий вес оболочки, от примерно 50% до примерно 100%, от примерно 70% до примерно 100%, или от примерно 80% до примерно 100%, полиакрилата,
с образованием потребительского продукта.
8. Способ изготовления композиции по п.7, в котором указанные частицы содержатся в суспензии, которую объединяют с указанным вспомогательным ингредиентом.
9. Способ изготовления композиции по п.8, в котором указанная суспензия содержит одну или несколько технологических добавок, выбранных из группы, состоящей из воды, материалов, ингибирующих агрегирование, таких как соли двухвалентных ионов; полимеры, суспендирующие частицы, такие как ксантановая камедь, гуаровая камедь, карбоксиметилцеллюлоза.
10. Способ изготовления композиции по п.7, в котором указанные частицы содержатся в агломерате, который объединяют с указанным вспомогательным материалом.
11. Способ изготовления композиции по п.10, в котором указанный агломерат содержит материалы, выбранные из группы, состоящей из диоксидов кремния, лимонной кислоты, карбоната натрия, сульфата натрия, хлорида натрия, и связующих, таких как силикаты натрия, модифицированные целлюлозы, полиэтиленгликоли, полиакрилаты, полиакриловые кислоты, цеолиты и их смеси.
12. Композиция по п.1, в которой указанный полиакрилат включает статистический полиакрилатный сополимер, содержащий, в пересчете на общий вес полиакрилата:
a) от примерно 0,2% до примерно 2,0%, аминного компонента;
b) от примерно 0,6% до примерно 6,0% карбоновой кислоты; или
c) от примерно 0,1% до примерно 1,0% аминного компонента и от примерно 0,3% до примерно 3,0% карбоновой кислоты.
13. Способ изготовления композиции, включающий стадию, на которой объединяют вспомогательный ингредиент с частицей, изготовленной способом, включающим стадии, на которых:
a) проводят реакцию многофункционального акрилатного мономера и/или многофункционального акрилатного олигомера, в одном аспекте, многофункционального метакрилатного мономера и/или многофункционального метакрилатного олигомера, в агенте, обеспечивающем полезный эффект, содержащем модификатор распределения и/или модификатор плотности, с композицией, содержащей:
i) аминакрилат и/или аминметакрилат и сильную кислоту; или
ii) форму карбоновой кислоты акрилатного и/или метакрилатного мономера и сильное основание; или
iii) аминакрилатный и/или аминметакрилатный мономер и форму карбоновой кислоты акрилатного и/или форму карбоновой кислоты метакрилатного мономера,
с образованием композиции сердцевины,
b) готовят эмульсию, содержащую указанную композицию сердцевины, поверхностно-активное вещество, в одном аспекте, анионное, катионное или нейтральное поверхностно-активное вещество и воду;
c) отверждают указанную эмульсию путем приложения достаточного количества тепловой энергии, УФ энергии и/или энергии электронного пучка к указанной эмульсии для индуцирования достаточной степени свободно-радикальной полимеризации с образованием частицы, имеющей сердцевину, содержащую указанный агент, обеспечивающий полезный эффект, и оболочку, содержащую акрилат, где указанная оболочка инкапсулирует указанный агент, обеспечивающий полезный эффект,
с образованием потребительского продукта.
14. Композиция, содержащая вспомогательный ингредиент и частицу, изготовленную способом, содержащим стадию, включающую использование способа по п.13.
15. Композиция по п.1, в которой указанный вспомогательный компонент композиции выбран из группы, состоящей из полимеров, в одном аспекте, катионного полимера, поверхностно-активных веществ, компонентов, усиливающих моющее действие, хелатирующих агентов, ингибиторов переноса красителей, диспергентов, ферментов, стабилизаторов ферментов, каталитических материалов, активаторов отбеливания, полимерных диспергентов, грязеотталкивающих агентов/агентов, предотвращающих повторное осаждение, осветлителей, конъюгатов краситель-полимер; конъюгатов краситель-глина, пеногасителей, красителей, катализаторов отбеливания, дополнительного ароматизатора и/или системы доставки ароматизаторов, эластификаторов структуры, мягчителей тканей, носителей, гидротропных веществ, технологических добавок, модификаторов реологии, структурообразователей, загустителей, пигментов, воды, и их смесей.
16. Композиция по п.1, содержащая материал, выбранный из группы, состоящей из красителей; ароматизатора; оптических осветлителей; модификаторов реологии, структурообразователей, загустителей, добавок, усиливающих отложение; и их смесей.
17. Композиция по п.1, в которой указанные частицы имеют катионный заряд в интервале значений pH от примерно 2 до примерно 10, от примерно 3 до примерно 9, или от примерно 4 до примерно 8.
18. Композиция по п.1, содержащая добавку, усиливающую отложение, которая содержит полимер, выбранный из группы, включающей: полисахариды, в одном аспекте, катионно модифицированный крахмал и/или катионно модифицированную гуаровую смолу; полисилоксаны; галогениды полидиаллилдиметиламмония; сополимеры полидиаллилдиметиламмония хлорида и поливинилпирролидона; композицию, содержащую полиэтиленгликоль и поливинилпирролидон; акриламиды; имидазолы; галогениды имидазолиния; поливиниламин; сополимеры поливиниламина и N-винилформамида; поливинилформамид, поливиниловый спирт; поливиниловый спирт, сшитый с борной кислотой; полиакриловую кислоту; кроссполимеры полиглицеринового простого эфира и силикона; полиакриловые кислоты, полиакрилаты, сополимеры поливиниламина и олигомеров поливинилового спирта с аминами, в одном аспекте, диэтилентриамином, этилендиамином, бис(3-аминопропил)пиперазином, N,N-бис-(3-аминопропил)метиламином, трис(2-аминоэтил)амином и их смесей; полиэтиленимином, дериватизированным полиэтиленимином, в одном аспекте, этоксилированным полиэтиленимином; полимерное соединение, содержащее по меньшей мере два фрагмента, выбранные из фрагментов, состоящих из группы карбоновой кислоты, аминогруппы, гидроксильной группы и нитрильной группы, в основной цепи полибутадиена, полиизопрена, полибутадиен/стирола, полибутадиен/акрилонитрила, полибутадиена с концевыми карбоксильными группами/акрилонитрила или их комбинаций; предварительно подготовленные коацерваты анионных поверхностно-активных веществ в комбинации с катионными полимерами; полиамины, и их смеси.
19. Композиция по п.1, в которой: по меньшей мере 75% указанных частиц характеризуются прочностью при разрушении от примерно 0,2 МПа до примерно 30 МПа; предпочтительно, от примерно 0,6 МПа до примерно 10 МПа, более предпочтительно, от примерно 1,0 МПа до примерно 5 МПа, наиболее предпочтительно, от примерно 1,2 МПа до примерно 3 МПа.
20. Композиция по п.1, содержащая модификатор реологии, загуститель и/или структурообразователь, имеющий вязкость при высокой скорости сдвига, при величине скорости сдвига 20 с-1 и при 21°C, от 1 до 7000 сП, и вязкость при низкой скорости сдвига, при скорости сдвига 0,5 с-1 при 21°C, более 1000 сП.
21. Композиция по п.1, представляющая собой жидкое моющее средство и содержащая, в пересчете на общий вес жидкого моющего средства, менее примерно 80% воды, от менее примерно 60% до примерно 2% воды, от примерно 45% до примерно 7% воды, от примерно 35% до примерно 9% воды.
22. Композиция по п.1, имеющая вязкость от примерно 10 сП до примерно 999 сП, или от примерно 100 сП до примерно 800 сП, при скорости сдвига 1 с-1.
23. Композиция по п.1, представляющая собой гель, содержащий, в пересчете на общий вес геля, менее примерно 45% воды, от менее примерно 45% до примерно 2% воды, от примерно 45% до примерно 7% воды, от примерно 35% до примерно 9% воды, и имеющий вязкость в неразведенном состоянии от примерно 1000 сП до примерно 10000 сП, или от примерно 1200 сП до примерно 8000 сП.
24. Композиция по п.1, представляющая собой жидкое средство, улучшающее характеристики ткани; твердое средство, улучшающее характеристики ткани; жидкий шампунь; твердый шампунь; кондиционер для волос; средство для мытья тела; твердый антиперспирант; жидкий антиперспирант; твердый дезодорант; жидкий дезодорант; жидкий увлажнитель; твердый увлажнитель; жидкий лосьон; жидкое очищающее средство для лица; твердое очищающее средство для лица; жидкий косметический продукт; твердый косметический продукт; жидкую композицию красителя для волос; твердую композицию красителя для волос; жидкое моющее средство; твердое моющее средство; жидкое средство для очистки твердых поверхностей; твердое средство для очистки твердых поверхностей; или моющее средство в порционной упаковке, включающее моющее средство и водорастворимую пленку, инкапсулирующую указанное моющее средство.
25. Способ обработки и/или очистки места применения, включающий стадии, на которых:
a) необязательно, стирают и/или выполаскивают указанное место применения;
b) вводят в контакт указанное место применения с композицией по любому из пп.1-6, 12 и 14-24; и
c) необязательно, стирают и/или выполаскивают указанное место применения.
26. Место применения, обработанное композицией по любому из пп.1-6, 12 и 14-24.
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