CA1299652C - Lithium ion sensor - Google Patents

Lithium ion sensor

Info

Publication number: CA1299652C
Authority: CA; Canada
Prior art keywords: lithium ion; layer; redox; ion sensor; sensor according
Prior art date: 1987-09-21
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000578072A

Other languages

English (en)

French (fr)

Inventor

Noboru Oyama

Toshiyuki Shono

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Terumo Corp

Original Assignee

Terumo Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-09-21

Filing date

1988-09-21

Publication date

1992-04-28

1988-09-21 Application filed by Terumo Corp filed Critical Terumo Corp

1992-04-28 Application granted granted Critical

1992-04-28 Publication of CA1299652C publication Critical patent/CA1299652C/en

2009-04-28 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

229910001416 lithium ion Inorganic materials 0.000 title claims abstract description 79
HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title claims abstract description 77
239000012528 membrane Substances 0.000 claims abstract description 28
-1 amino compound Chemical class 0.000 claims description 36
239000000758 substrate Substances 0.000 claims description 29
229920000642 polymer Polymers 0.000 claims description 24
150000001875 compounds Chemical class 0.000 claims description 14
238000006479 redox reaction Methods 0.000 claims description 10
239000000126 substance Substances 0.000 claims description 8
KDMUFHBMXZLDLI-UHFFFAOYSA-N 6,6-dibenzyl-1,4,8,11-tetraoxacyclotetradecane Chemical compound C1OCCOCCCOCCOCC1(CC=1C=CC=CC=1)CC1=CC=CC=C1 KDMUFHBMXZLDLI-UHFFFAOYSA-N 0.000 claims description 7
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
239000004800 polyvinyl chloride Substances 0.000 claims description 7
239000003575 carbonaceous material Substances 0.000 claims description 6
229920000915 polyvinyl chloride Polymers 0.000 claims description 6
VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical compound C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 claims description 5
229910052751 metal Inorganic materials 0.000 claims description 5
239000002184 metal Substances 0.000 claims description 5
229910052799 carbon Inorganic materials 0.000 claims description 4
230000005669 field effect Effects 0.000 claims description 3
150000002440 hydroxy compounds Chemical class 0.000 claims description 3
230000000379 polymerizing effect Effects 0.000 claims description 3
239000004065 semiconductor Substances 0.000 claims description 3
IMHDGJOMLMDPJN-UHFFFAOYSA-N biphenyl-2,2'-diol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1O IMHDGJOMLMDPJN-UHFFFAOYSA-N 0.000 claims 1
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical class [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 11
238000000034 method Methods 0.000 description 9
150000002500 ions Chemical class 0.000 description 8
125000003118 aryl group Chemical group 0.000 description 7
230000000052 comparative effect Effects 0.000 description 7
238000002474 experimental method Methods 0.000 description 7
239000000243 solution Substances 0.000 description 7
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 6
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 6
230000002411 adverse Effects 0.000 description 6
239000011248 coating agent Substances 0.000 description 6
238000000576 coating method Methods 0.000 description 6
229910001882 dioxygen Inorganic materials 0.000 description 6
229910052744 lithium Inorganic materials 0.000 description 6
230000003647 oxidation Effects 0.000 description 6
238000007254 oxidation reaction Methods 0.000 description 6
239000002904 solvent Substances 0.000 description 6
230000000694 effects Effects 0.000 description 5
239000003792 electrolyte Substances 0.000 description 5
238000006116 polymerization reaction Methods 0.000 description 5
239000011780 sodium chloride Substances 0.000 description 5
AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 4
208000020925 Bipolar disease Diseases 0.000 description 4
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
208000028683 bipolar I disease Diseases 0.000 description 4
230000015271 coagulation Effects 0.000 description 4
238000005345 coagulation Methods 0.000 description 4
KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 4
238000005259 measurement Methods 0.000 description 4
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
229920005597 polymer membrane Polymers 0.000 description 4
229910001414 potassium ion Inorganic materials 0.000 description 4
QZAYGJVTTNCVMB-UHFFFAOYSA-N serotonin Chemical compound C1=C(O)C=C2C(CCN)=CNC2=C1 QZAYGJVTTNCVMB-UHFFFAOYSA-N 0.000 description 4
229910001415 sodium ion Inorganic materials 0.000 description 4
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
239000008280 blood Substances 0.000 description 3
210000004369 blood Anatomy 0.000 description 3
238000005868 electrolysis reaction Methods 0.000 description 3
239000010439 graphite Substances 0.000 description 3
229910002804 graphite Inorganic materials 0.000 description 3
XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 3
229910052808 lithium carbonate Inorganic materials 0.000 description 3
210000000056 organ Anatomy 0.000 description 3
150000002894 organic compounds Chemical class 0.000 description 3
BAZAXWOYCMUHIX-UHFFFAOYSA-M sodium perchlorate Chemical compound [Na+].[O-]Cl(=O)(=O)=O BAZAXWOYCMUHIX-UHFFFAOYSA-M 0.000 description 3
229910001488 sodium perchlorate Inorganic materials 0.000 description 3
125000001424 substituent group Chemical group 0.000 description 3
229920002554 vinyl polymer Polymers 0.000 description 3
GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 2
NXXYKOUNUYWIHA-UHFFFAOYSA-N 2,6-Dimethylphenol Chemical compound CC1=CC=CC(C)=C1O NXXYKOUNUYWIHA-UHFFFAOYSA-N 0.000 description 2
PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 2
IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
AFBPFSWMIHJQDM-UHFFFAOYSA-N N-methylaniline Chemical compound CNC1=CC=CC=C1 AFBPFSWMIHJQDM-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
239000000853 adhesive Substances 0.000 description 2
230000001070 adhesive effect Effects 0.000 description 2
229910000147 aluminium phosphate Inorganic materials 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
238000005229 chemical vapour deposition Methods 0.000 description 2
QBPFLULOKWLNNW-UHFFFAOYSA-N chrysazin Chemical compound O=C1C2=CC=CC(O)=C2C(=O)C2=C1C=CC=C2O QBPFLULOKWLNNW-UHFFFAOYSA-N 0.000 description 2
125000004122 cyclic group Chemical group 0.000 description 2
239000000539 dimer Substances 0.000 description 2
239000007789 gas Substances 0.000 description 2
WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 2
239000000463 material Substances 0.000 description 2
239000000203 mixture Substances 0.000 description 2
229910052697 platinum Inorganic materials 0.000 description 2
229910052594 sapphire Inorganic materials 0.000 description 2
239000010980 sapphire Substances 0.000 description 2
229940076279 serotonin Drugs 0.000 description 2
229910052710 silicon Inorganic materials 0.000 description 2
239000010703 silicon Substances 0.000 description 2
238000006467 substitution reaction Methods 0.000 description 2
239000003115 supporting electrolyte Substances 0.000 description 2
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
SFLSHLFXELFNJZ-QMMMGPOBSA-N (-)-norepinephrine Chemical compound NC[C@H](O)C1=CC=C(O)C(O)=C1 SFLSHLFXELFNJZ-QMMMGPOBSA-N 0.000 description 1
DNXIKVLOVZVMQF-UHFFFAOYSA-N (3beta,16beta,17alpha,18beta,20alpha)-17-hydroxy-11-methoxy-18-[(3,4,5-trimethoxybenzoyl)oxy]-yohimban-16-carboxylic acid, methyl ester Natural products C1C2CN3CCC(C4=CC=C(OC)C=C4N4)=C4C3CC2C(C(=O)OC)C(O)C1OC(=O)C1=CC(OC)=C(OC)C(OC)=C1 DNXIKVLOVZVMQF-UHFFFAOYSA-N 0.000 description 1
OXHNLMTVIGZXSG-UHFFFAOYSA-N 1-Methylpyrrole Chemical compound CN1C=CC=C1 OXHNLMTVIGZXSG-UHFFFAOYSA-N 0.000 description 1
NBQXYAJLUDQSNV-UHFFFAOYSA-N 1-[(4-methylphenyl)methyl]-5-oxopyrrolidine-3-carboxylic acid Chemical compound C1=CC(C)=CC=C1CN1C(=O)CC(C(O)=O)C1 NBQXYAJLUDQSNV-UHFFFAOYSA-N 0.000 description 1
XXKHDSGLCLCFSC-UHFFFAOYSA-N 2,3-diphenylphenol Chemical compound C=1C=CC=CC=1C=1C(O)=CC=CC=1C1=CC=CC=C1 XXKHDSGLCLCFSC-UHFFFAOYSA-N 0.000 description 1
NATVSFWWYVJTAZ-UHFFFAOYSA-N 2,4,6-trichloroaniline Chemical compound NC1=C(Cl)C=C(Cl)C=C1Cl NATVSFWWYVJTAZ-UHFFFAOYSA-N 0.000 description 1
HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 1
NBYLBWHHTUWMER-UHFFFAOYSA-N 2-Methylquinolin-8-ol Chemical compound C1=CC=C(O)C2=NC(C)=CC=C21 NBYLBWHHTUWMER-UHFFFAOYSA-N 0.000 description 1
XQQBUAPQHNYYRS-UHFFFAOYSA-N 2-methylthiophene Chemical compound CC1=CC=CS1 XQQBUAPQHNYYRS-UHFFFAOYSA-N 0.000 description 1
UQRLKWGPEVNVHT-UHFFFAOYSA-N 3,5-dichloroaniline Chemical compound NC1=CC(Cl)=CC(Cl)=C1 UQRLKWGPEVNVHT-UHFFFAOYSA-N 0.000 description 1
LUJMEECXHPYQOF-UHFFFAOYSA-N 3-hydroxyacetophenone Chemical class CC(=O)C1=CC=CC(O)=C1 LUJMEECXHPYQOF-UHFFFAOYSA-N 0.000 description 1
NPFYZDNDJHZQKY-UHFFFAOYSA-N 4-Hydroxybenzophenone Chemical class C1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 NPFYZDNDJHZQKY-UHFFFAOYSA-N 0.000 description 1
QSNSCYSYFYORTR-UHFFFAOYSA-N 4-chloroaniline Chemical compound NC1=CC=C(Cl)C=C1 QSNSCYSYFYORTR-UHFFFAOYSA-N 0.000 description 1
RGHHSNMVTDWUBI-UHFFFAOYSA-N 4-hydroxybenzaldehyde Chemical class OC1=CC=C(C=O)C=C1 RGHHSNMVTDWUBI-UHFFFAOYSA-N 0.000 description 1
FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical class OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
WOYZXEVUWXQVNV-UHFFFAOYSA-N 4-phenoxyaniline Chemical compound C1=CC(N)=CC=C1OC1=CC=CC=C1 WOYZXEVUWXQVNV-UHFFFAOYSA-N 0.000 description 1
RMMXTBMQSGEXHJ-UHFFFAOYSA-N Aminophenazone Chemical compound O=C1C(N(C)C)=C(C)N(C)N1C1=CC=CC=C1 RMMXTBMQSGEXHJ-UHFFFAOYSA-N 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
206010026749 Mania Diseases 0.000 description 1
QENGPZGAWFQWCZ-UHFFFAOYSA-N Methylthiophene Natural products CC=1C=CSC=1 QENGPZGAWFQWCZ-UHFFFAOYSA-N 0.000 description 1
239000004952 Polyamide Chemical class 0.000 description 1
NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 1
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229910008062 Si-SiO2 Inorganic materials 0.000 description 1
229910052581 Si3N4 Inorganic materials 0.000 description 1
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
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PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
239000004809 Teflon Substances 0.000 description 1
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XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
150000001454 anthracenes Chemical class 0.000 description 1
150000001555 benzenes Chemical class 0.000 description 1
210000001185 bone marrow Anatomy 0.000 description 1
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
239000004327 boric acid Substances 0.000 description 1
210000005013 brain tissue Anatomy 0.000 description 1
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OQENBJBTQPIZKA-UHFFFAOYSA-N chrysen-1-amine Chemical compound C1=CC2=C3C=CC=CC3=CC=C2C2=C1C(N)=CC=C2 OQENBJBTQPIZKA-UHFFFAOYSA-N 0.000 description 1
ILSGDBURWYKYHE-UHFFFAOYSA-N chrysene-1,2-diamine Chemical compound C1=CC=CC2=CC=C3C4=CC=C(N)C(N)=C4C=CC3=C21 ILSGDBURWYKYHE-UHFFFAOYSA-N 0.000 description 1
150000001846 chrysenes Chemical class 0.000 description 1
239000002131 composite material Substances 0.000 description 1
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229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
150000001882 coronenes Chemical class 0.000 description 1
229960001577 dantron Drugs 0.000 description 1
238000000151 deposition Methods 0.000 description 1
ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical compound Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 1
HTXDPTMKBJXEOW-UHFFFAOYSA-N dioxoiridium Chemical compound O=[Ir]=O HTXDPTMKBJXEOW-UHFFFAOYSA-N 0.000 description 1
ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 description 1
238000007598 dipping method Methods 0.000 description 1
239000003814 drug Substances 0.000 description 1
230000005518 electrochemistry Effects 0.000 description 1
238000004070 electrodeposition Methods 0.000 description 1
238000010894 electron beam technology Methods 0.000 description 1
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
239000012530 fluid Substances 0.000 description 1
229910021397 glassy carbon Inorganic materials 0.000 description 1
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
229910052737 gold Inorganic materials 0.000 description 1
239000010931 gold Substances 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
125000000623 heterocyclic group Chemical group 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
238000002347 injection Methods 0.000 description 1
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229910000457 iridium oxide Inorganic materials 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
KQPYUDDGWXQXHS-UHFFFAOYSA-N juglone Chemical compound O=C1C=CC(=O)C2=C1C=CC=C2O KQPYUDDGWXQXHS-UHFFFAOYSA-N 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
239000000178 monomer Substances 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
239000012299 nitrogen atmosphere Substances 0.000 description 1
229960002748 norepinephrine Drugs 0.000 description 1
SFLSHLFXELFNJZ-UHFFFAOYSA-N norepinephrine Natural products NCC(O)C1=CC=C(O)C(O)=C1 SFLSHLFXELFNJZ-UHFFFAOYSA-N 0.000 description 1
VWMVAQHMFFZQGD-UHFFFAOYSA-N p-Hydroxybenzyl acetone Natural products CC(=O)CC1=CC=C(O)C=C1 VWMVAQHMFFZQGD-UHFFFAOYSA-N 0.000 description 1
RARSHUDCJQSEFJ-UHFFFAOYSA-N p-Hydroxypropiophenone Chemical class CCC(=O)C1=CC=C(O)C=C1 RARSHUDCJQSEFJ-UHFFFAOYSA-N 0.000 description 1
ATGUVEKSASEFFO-UHFFFAOYSA-N p-aminodiphenylamine Chemical compound C1=CC(N)=CC=C1NC1=CC=CC=C1 ATGUVEKSASEFFO-UHFFFAOYSA-N 0.000 description 1
238000010422 painting Methods 0.000 description 1
229910052763 palladium Inorganic materials 0.000 description 1
125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
KIHQWOBUUIPWAN-UHFFFAOYSA-N phenanthren-9-amine Chemical compound C1=CC=C2C(N)=CC3=CC=CC=C3C2=C1 KIHQWOBUUIPWAN-UHFFFAOYSA-N 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
230000035479 physiological effects, processes and functions Effects 0.000 description 1
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230000005855 radiation Effects 0.000 description 1
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BJOIZNZVOZKDIG-MDEJGZGSSA-N reserpine Chemical compound O([C@H]1[C@@H]([C@H]([C@H]2C[C@@H]3C4=C([C]5C=CC(OC)=CC5=N4)CCN3C[C@H]2C1)C(=O)OC)OC)C(=O)C1=CC(OC)=C(OC)C(OC)=C1 BJOIZNZVOZKDIG-MDEJGZGSSA-N 0.000 description 1
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WKEDVNSFRWHDNR-UHFFFAOYSA-N salicylanilide Chemical compound OC1=CC=CC=C1C(=O)NC1=CC=CC=C1 WKEDVNSFRWHDNR-UHFFFAOYSA-N 0.000 description 1
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229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
KZLBAEPIEKLKNW-UHFFFAOYSA-M sodium;acetonitrile;perchlorate Chemical compound [Na+].CC#N.[O-]Cl(=O)(=O)=O KZLBAEPIEKLKNW-UHFFFAOYSA-M 0.000 description 1
239000007787 solid Substances 0.000 description 1
230000002194 synthesizing effect Effects 0.000 description 1
238000002560 therapeutic procedure Methods 0.000 description 1
229930192474 thiophene Natural products 0.000 description 1
230000001519 thymoleptic effect Effects 0.000 description 1
230000007704 transition Effects 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Landscapes

Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)

CA000578072A 1987-09-21 1988-09-21 Lithium ion sensor Expired - Fee Related CA1299652C (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
JP62234956A JPH0743342B2 (ja)	1987-09-21	1987-09-21	リチウムイオンセンサ
JP62-234956		1987-09-21

Publications (1)

Publication Number	Publication Date
CA1299652C true CA1299652C (en)	1992-04-28

Family

ID=16978892

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000578072A Expired - Fee Related CA1299652C (en)	1987-09-21	1988-09-21	Lithium ion sensor

Country Status (2)

Country	Link
JP (1)	JPH0743342B2 (ja)
CA (1)	CA1299652C (ja)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2900064B1 (fr) *	2006-04-24	2008-12-12	Electricite De France	Membrane selective des ions lithium pour la mesure de la concentration en lithium dans un fluide tel que la fluide du circuit primaire de refroidissement d'un reacteur d'une centrale nucleaire a eau pressurisee

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS61266952A (ja) *	1985-05-21	1986-11-26	Terumo Corp	カリウムイオンセンサ−
JPH0795060B2 (ja) *	1986-01-24	1995-10-11	テルモ株式会社	イオン選択性ｆｅｔセンサ−
JPS62205086A (ja) *	1986-03-03	1987-09-09	Tsuneo Shirai	サイクリツクモネンシンモノアセテイト
JPS63131056A (ja) *	1986-11-20	1988-06-03	Terumo Corp	Ｆｅｔ電極

1987
- 1987-09-21 JP JP62234956A patent/JPH0743342B2/ja not_active Expired - Lifetime
1988
- 1988-09-21 CA CA000578072A patent/CA1299652C/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
JPS6478146A (en)	1989-03-23
JPH0743342B2 (ja)	1995-05-15

Legal Events

Date	Code	Title	Description
2005-04-28	MKLA	Lapsed

Publication	Publication Date	Title
KR900004691B1 (ko)	1990-07-02	이온 선택성 fet 센서
US4798664A (en)	1989-01-17	Ion sensor
EP0247941B1 (en)	1992-11-11	Gas sensor
EP0186210A2 (en)	1986-07-02	Ion sensor
EP0245168B1 (en)	1990-09-12	Ion sensor
US5192417A (en)	1993-03-09	Lithium ion sensor
CA1299652C (en)	1992-04-28	Lithium ion sensor
JPS61251764A (ja)	1986-11-08	↓ｐＨセンサ−
EP0218530B1 (en)	1992-09-09	Ionic concentration measurement method
US5190636A (en)	1993-03-02	Ion-sensitive film, method of producing the same and ion sensor
JPS61213662A (ja)	1986-09-22	ｐＨセンサ−
EP0333861A1 (en)	1989-09-27	Ion-selective fet sensor
JPH0376861B2 (ja)	1991-12-06
JPS6252449A (ja)	1987-03-07	カルシウムイオンセンサ−
JPH0375064B2 (ja)	1991-11-28
JPS62276452A (ja)	1987-12-01	イオン選択性ｆｅｔセンサ
JPH0376863B2 (ja)	1991-12-06
JPS62150150A (ja)	1987-07-04	Ｐｈセンサ−
JPS62180259A (ja)	1987-08-07	アンモニウムイオンセンサ−
JPS61213661A (ja)	1986-09-22	ｐＨセンサ−
JPS62169043A (ja)	1987-07-25	ｐＨセンサ−
JPH0376862B2 (ja)	1991-12-06
JPH0422465B2 (ja)	1992-04-17
JPH0362226B2 (ja)	1991-09-25