JPS6335017B2 - - Google Patents
Info
- Publication number
- JPS6335017B2 JPS6335017B2 JP55002305A JP230580A JPS6335017B2 JP S6335017 B2 JPS6335017 B2 JP S6335017B2 JP 55002305 A JP55002305 A JP 55002305A JP 230580 A JP230580 A JP 230580A JP S6335017 B2 JPS6335017 B2 JP S6335017B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- bonded
- coupler
- color
- phenylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 silver halide Chemical class 0.000 claims description 52
- 238000000034 method Methods 0.000 claims description 43
- 229910052709 silver Inorganic materials 0.000 claims description 31
- 239000004332 silver Substances 0.000 claims description 31
- 239000000463 material Substances 0.000 claims description 29
- 238000012545 processing Methods 0.000 claims description 17
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 12
- 125000004442 acylamino group Chemical group 0.000 claims description 10
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 10
- 125000001424 substituent group Chemical group 0.000 claims description 8
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 7
- 125000004656 alkyl sulfonylamino group Chemical group 0.000 claims description 6
- 125000005843 halogen group Chemical group 0.000 claims description 6
- 125000000565 sulfonamide group Chemical group 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 5
- 125000000623 heterocyclic group Chemical group 0.000 claims description 4
- 125000004471 alkyl aminosulfonyl group Chemical group 0.000 claims description 3
- 125000002947 alkylene group Chemical group 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 125000004957 naphthylene group Chemical group 0.000 claims description 3
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 2
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 36
- 239000000243 solution Substances 0.000 description 33
- 238000011161 development Methods 0.000 description 30
- 239000000975 dye Substances 0.000 description 30
- 239000000839 emulsion Substances 0.000 description 30
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 24
- 239000000203 mixture Substances 0.000 description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 21
- 239000003795 chemical substances by application Substances 0.000 description 15
- 230000008569 process Effects 0.000 description 14
- 230000015572 biosynthetic process Effects 0.000 description 13
- 235000019445 benzyl alcohol Nutrition 0.000 description 12
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 12
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 10
- 239000006185 dispersion Substances 0.000 description 10
- 239000010410 layer Substances 0.000 description 10
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 10
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 9
- 238000009835 boiling Methods 0.000 description 8
- 230000003595 spectral effect Effects 0.000 description 8
- 238000003860 storage Methods 0.000 description 8
- 238000003786 synthesis reaction Methods 0.000 description 8
- 238000005406 washing Methods 0.000 description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 7
- 238000010521 absorption reaction Methods 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 229940101006 anhydrous sodium sulfite Drugs 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 238000009792 diffusion process Methods 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 6
- 125000004423 acyloxy group Chemical group 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000012546 transfer Methods 0.000 description 5
- 108010010803 Gelatin Proteins 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- 229920000159 gelatin Polymers 0.000 description 4
- 239000008273 gelatin Substances 0.000 description 4
- 235000019322 gelatine Nutrition 0.000 description 4
- 235000011852 gelatine desserts Nutrition 0.000 description 4
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- 238000010992 reflux Methods 0.000 description 4
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 4
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 4
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 4
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 3
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical group C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 229960000583 acetic acid Drugs 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 description 3
- 125000004104 aryloxy group Chemical group 0.000 description 3
- 238000004061 bleaching Methods 0.000 description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 3
- 229910052794 bromium Inorganic materials 0.000 description 3
- XZOWIJDBQIHMFC-UHFFFAOYSA-N butanamide Chemical compound CCCC(N)=O.CCCC(N)=O XZOWIJDBQIHMFC-UHFFFAOYSA-N 0.000 description 3
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 125000004093 cyano group Chemical group *C#N 0.000 description 3
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 230000035945 sensitivity Effects 0.000 description 3
- 230000001235 sensitizing effect Effects 0.000 description 3
- 230000000087 stabilizing effect Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- SCVJRXQHFJXZFZ-KVQBGUIXSA-N 2-amino-9-[(2r,4s,5r)-4-hydroxy-5-(hydroxymethyl)oxolan-2-yl]-3h-purine-6-thione Chemical compound C1=2NC(N)=NC(=S)C=2N=CN1[C@H]1C[C@H](O)[C@@H](CO)O1 SCVJRXQHFJXZFZ-KVQBGUIXSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 125000000738 acetamido group Chemical group [H]C([H])([H])C(=O)N([H])[*] 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 125000005110 aryl thio group Chemical group 0.000 description 2
- XNSQZBOCSSMHSZ-UHFFFAOYSA-K azane;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxymethyl)amino]acetate;iron(3+) Chemical compound [NH4+].[Fe+3].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O XNSQZBOCSSMHSZ-UHFFFAOYSA-K 0.000 description 2
- 239000000987 azo dye Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- WGQKYBSKWIADBV-UHFFFAOYSA-N benzylamine Chemical compound NCC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-N 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- 229910021538 borax Inorganic materials 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- KYQODXQIAJFKPH-UHFFFAOYSA-N diazanium;2-[2-[bis(carboxymethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [NH4+].[NH4+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O KYQODXQIAJFKPH-UHFFFAOYSA-N 0.000 description 2
- MQRJBSHKWOFOGF-UHFFFAOYSA-L disodium;carbonate;hydrate Chemical compound O.[Na+].[Na+].[O-]C([O-])=O MQRJBSHKWOFOGF-UHFFFAOYSA-L 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 125000004185 ester group Chemical group 0.000 description 2
- 239000012362 glacial acetic acid Substances 0.000 description 2
- 239000005457 ice water Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 2
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 2
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 229940001482 sodium sulfite Drugs 0.000 description 2
- 235000010265 sodium sulphite Nutrition 0.000 description 2
- 239000004328 sodium tetraborate Substances 0.000 description 2
- 235000010339 sodium tetraborate Nutrition 0.000 description 2
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 2
- 125000000542 sulfonic acid group Chemical group 0.000 description 2
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 2
- 125000003396 thiol group Chemical class [H]S* 0.000 description 2
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- GVEYRUKUJCHJSR-UHFFFAOYSA-N (4-azaniumyl-3-methylphenyl)-ethyl-(2-hydroxyethyl)azanium;sulfate Chemical compound OS(O)(=O)=O.OCCN(CC)C1=CC=C(N)C(C)=C1 GVEYRUKUJCHJSR-UHFFFAOYSA-N 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- PXJHVKRLFWZUNV-UHFFFAOYSA-N 1-n,4-n-dimethylbenzene-1,4-diamine;hydron;dichloride Chemical compound Cl.Cl.CNC1=CC=C(NC)C=C1 PXJHVKRLFWZUNV-UHFFFAOYSA-N 0.000 description 1
- HFZLSTDPRQSZCQ-UHFFFAOYSA-N 1-pyrrolidin-3-ylpyrrolidine Chemical compound C1CCCN1C1CNCC1 HFZLSTDPRQSZCQ-UHFFFAOYSA-N 0.000 description 1
- WJPQLQKQMKOJKB-UHFFFAOYSA-N 2-[4-(2-ethoxyethylsulfonylamino)phenoxy]tetradecanoic acid Chemical compound CCCCCCCCCCCCC(C(O)=O)OC1=CC=C(NS(=O)(=O)CCOCC)C=C1 WJPQLQKQMKOJKB-UHFFFAOYSA-N 0.000 description 1
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 1
- UIZKSVKQIJNZNF-UHFFFAOYSA-N 2-ethoxyethanesulfonyl chloride Chemical compound CCOCCS(Cl)(=O)=O UIZKSVKQIJNZNF-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- QNGVNLMMEQUVQK-UHFFFAOYSA-N 4-n,4-n-diethylbenzene-1,4-diamine Chemical compound CCN(CC)C1=CC=C(N)C=C1 QNGVNLMMEQUVQK-UHFFFAOYSA-N 0.000 description 1
- MTOCKMVNXPZCJW-UHFFFAOYSA-N 4-n-dodecyl-4-n-ethyl-2-methylbenzene-1,4-diamine Chemical compound CCCCCCCCCCCCN(CC)C1=CC=C(N)C(C)=C1 MTOCKMVNXPZCJW-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- LEVWYRKDKASIDU-QWWZWVQMSA-N D-cystine Chemical compound OC(=O)[C@H](N)CSSC[C@@H](N)C(O)=O LEVWYRKDKASIDU-QWWZWVQMSA-N 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 229910021612 Silver iodide Inorganic materials 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- MPLZNPZPPXERDA-UHFFFAOYSA-N [4-(diethylamino)-2-methylphenyl]azanium;chloride Chemical compound [Cl-].CC[NH+](CC)C1=CC=C(N)C(C)=C1 MPLZNPZPPXERDA-UHFFFAOYSA-N 0.000 description 1
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 1
- XCFIVNQHHFZRNR-UHFFFAOYSA-N [Ag].Cl[IH]Br Chemical compound [Ag].Cl[IH]Br XCFIVNQHHFZRNR-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910001508 alkali metal halide Inorganic materials 0.000 description 1
- 150000008045 alkali metal halides Chemical class 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- HTKFORQRBXIQHD-UHFFFAOYSA-N allylthiourea Chemical compound NC(=S)NCC=C HTKFORQRBXIQHD-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- BIVUUOPIAYRCAP-UHFFFAOYSA-N aminoazanium;chloride Chemical compound Cl.NN BIVUUOPIAYRCAP-UHFFFAOYSA-N 0.000 description 1
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 239000001000 anthraquinone dye Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- PGVWVVCAXSOASP-UHFFFAOYSA-N azanium;hydroxy-oxido-oxo-sulfanylidene-$l^{6}-sulfane Chemical compound N.OS(O)(=O)=S PGVWVVCAXSOASP-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- HJMZMZRCABDKKV-UHFFFAOYSA-N carbonocyanidic acid Chemical compound OC(=O)C#N HJMZMZRCABDKKV-UHFFFAOYSA-N 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229960003067 cystine Drugs 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- LOCAIGRSOJUCTB-UHFFFAOYSA-N indazol-3-one Chemical compound C1=CC=C2C(=O)N=NC2=C1 LOCAIGRSOJUCTB-UHFFFAOYSA-N 0.000 description 1
- 239000001013 indophenol dye Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 159000000014 iron salts Chemical class 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 125000004573 morpholin-4-yl group Chemical group N1(CCOCC1)* 0.000 description 1
- XBSZSDGIVSNDOF-UHFFFAOYSA-N n-(4-amino-2-hydroxyphenyl)benzamide Chemical compound OC1=CC(N)=CC=C1NC(=O)C1=CC=CC=C1 XBSZSDGIVSNDOF-UHFFFAOYSA-N 0.000 description 1
- AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 description 1
- CLJDCQWROXMJAZ-UHFFFAOYSA-N n-[2-(4-amino-n-ethyl-3-methylanilino)ethyl]methanesulfonamide;sulfuric acid Chemical compound OS(O)(=O)=O.CS(=O)(=O)NCCN(CC)C1=CC=C(N)C(C)=C1 CLJDCQWROXMJAZ-UHFFFAOYSA-N 0.000 description 1
- CWPNUVRPRDFMNR-UHFFFAOYSA-N n-[2-(4-amino-n-ethylanilino)ethyl]methanesulfonamide Chemical compound CS(=O)(=O)NCCN(CC)C1=CC=C(N)C=C1 CWPNUVRPRDFMNR-UHFFFAOYSA-N 0.000 description 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene-acid Natural products C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000012044 organic layer Substances 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 1
- 235000019252 potassium sulphite Nutrition 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 125000006410 propenylene group Chemical group 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical compound O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- 229940045105 silver iodide Drugs 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229940001584 sodium metabisulfite Drugs 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- NASFKTWZWDYFER-UHFFFAOYSA-N sodium;hydrate Chemical compound O.[Na] NASFKTWZWDYFER-UHFFFAOYSA-N 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical group O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 1
- 125000000475 sulfinyl group Chemical group [*:2]S([*:1])=O 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- YBBRCQOCSYXUOC-UHFFFAOYSA-N sulfuryl dichloride Chemical compound ClS(Cl)(=O)=O YBBRCQOCSYXUOC-UHFFFAOYSA-N 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- ARZGWBJFLJBOTR-UHFFFAOYSA-N tetradecanamide Chemical compound CCCCCCCCCCCCCC(N)=O.CCCCCCCCCCCCCC(N)=O ARZGWBJFLJBOTR-UHFFFAOYSA-N 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 239000001043 yellow dye Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/32—Colour coupling substances
- G03C7/34—Couplers containing phenols
- G03C7/346—Phenolic couplers
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Description
æ¬çºæã¯ã·ã¢ã³è²çŽ ç»åã®åœ¢ææ¹æ³ã«é¢ããã
ã®ã§ãããç¹ã«æ°èŠãªïŒïŒïŒãžã¢ã·ã«ã¢ããåã·
ã¢ã³ã«ãã©ãŒã®ååšäžã§ã«ã©ãŒåçæå ææãçº
è²çŸåããããšã«ããã·ã¢ã³è²çŽ ç»åã圢æãã
æ¹æ³ã«é¢ãããã®ã§ãããæŽã«è©³ããã¯ã溶解
æ§ãåæ£å®å®æ§ãåå åžåç¹æ§ãè¯å¥œã§ããããš
ãã«ãã³ãžã«ã¢ã«ã³ãŒã«ãæé€ããçºè²çŸååŠç
液äžã§ã®è²çŽ 圢æé床ã倧ãããçºè²æ¿åºŠãé«
ãããããç»åä¿åæ§ã«åªããæ°èŠãªã·ã¢ã³ã«ã
ã©ãŒã®ååšäžã§ã·ã¢ã³è²çŽ ç»åã圢æããæ¹æ³ã«
é¢ãããã®ã§ããã æžè²æ³ã«ã©ãŒåçã¯ãåšç¥ã®åŠããè³éŠæ第ïŒ
çŽã¢ãã³ç³»çºè²çŸåå€ããé²å ãããããã²ã³å
éç²åãéå ããããšã«ããçæããçºè²çŸåå€
ã®é žåçæç©ãšé»è²ãã·ã¢ã³ãããŒã³ã¿è²çŽ ã圢
æããã«ãã©ãŒãããã²ã³åéä¹³å€äžã§é žåã«ã
ããªã³ã°ããããšã«ããè²ç»åã圢æããããã
ããã®å Žåãé»è²è²çŽ ã圢æããããã®é»è²ã«ã
ã©ãŒãšããŠã¯ãäžè¬ã«éé掻æ§ã¡ãã¬ã³åºãæã
ãååç©ãçšããããããŒã³ã¿è²çŽ ã圢æããã
ãã®ããŒã³ã¿ã«ãã©ãŒãšããŠã¯ããã©ãŸãã³ç³»ã
ãã©ãŸãªããã³ãã€ãããŸãŒã«ç³»ãã€ã³ããŸãã³
ç³»çã®ååç©ã䜿çšãããããã³ã·ã¢ã³è²çŽ ã圢
æããããã®ã·ã¢ã³ã«ãã©ãŒãšããŠã¯ãããšããŒ
ã«ããã³ããããŒã«æ§æ°Žé žåºãæããååç©ãçš
ããããŠããã åã«ãã©ãŒã¯ãå®è³ªçã«æ°Žäžæº¶æ§ã®é«æ²žç¹ææ©
溶åªã«æãã¯ããã«å¿ èŠã«å¿ããŠè£å©æº¶åªã䜵çš
ããŠæº¶è§£ããããã²ã³åéä¹³å€äžã«æ·»å ããã
ããæãã¯ã¢ã«ã«ãªæ°Žæº¶æ¶²ã«æº¶è§£ããŠä¹³å€äžã«æ·»
å ããããåè ã¯æ²¹æ»Žåæ£æ³ã§ãããåŸè ã¯ã¢ã«
ã«ãªåæ£æ³ã§ããããäžè¬ã«åè ã®æ¹ãåŸè ãã
ãèå ãèç±ãè湿æ§ãç²ç¶æ§ãè²ã®é®®é床çã«
ãããŠåªããŠãããšãããŠããã åã«ãã©ãŒã«èŠæ±ãããåºæ¬çæ§è³ªãšããŠã¯ã
åã«è²çŽ ã圢æããã ãã§ãªããå ãé«æ²žç¹ææ©
溶åªãããã¯ã¢ã«ã«ãªçã«å¯Ÿãã溶解æ§ã倧ãã
ããšããŸãããã²ã³åéåçä¹³å€ãžã®åæ£æ§ãã
ã³å®å®æ§ãããããšãããã«ãã€ãŠåœ¢æãããè²
çŽ ãå ãç±ã湿æ°çã«å¯ŸããŠå ç¢æ§ãæããã
ãšãåå åžåç¹æ§ãè¯å¥œã§ããããšãéææ§ãã
ãããšãçºè²æ¿åºŠã倧ããããšãæŽã«ã¯åŸããã
ç»åãé®®æã§ããããšçã®çš®ã ã®è«žç¹æ§ãæãã
ããšãæãŸããŠããããšãããã·ã¢ã³ã«ãã©ãŒã«
ãããŠã¯ãèç±æ§ãè湿æ§ãèå æ§çã®ç»åä¿å
æ§ã®æ¹è¯ãå¿ èŠãšãããŠããã æŽã«ãæšä»ã®è±å ¬å®³ã®èŠå°ãããçºè²çŸååŠç
液ã«æ·»å ããããã³ãžã«ã¢ã«ã³ãŒã«ã®é€å»ã倧ã
ãªåé¡ãšããŠãšããããããŠããŠããããšããã
äžè¬ã«ãã³ãžã«ã¢ã«ã³ãŒã«ãæ·»å ããªãçºè²çŸå
åŠç液ãçšãããšãããã²ã³åéåçä¹³å€äžã«æ·»
å ãããã«ãã©ãŒã®çºè²æ§ããªãã¡è²çŽ 圢æé床
ããã³æ倧çºè²æ¿åºŠã¯äœäžããã®ãçŸç¶ã§ããã
ãããŠãã·ã¢ã³ã«ãã©ãŒã«ãããŠã¯ããã®åŸåã
èããè¡šããããããã§ããã®ã·ã¢ã³ã«ãã©ãŒã«
ãããŠã¯ããã®çºè²æ§ããã³ãžã«ã¢ã«ã³ãŒã«ã«äŸ
åããªãããšãåæãããŠããããã€äžèšç»åä¿
åæ§ã®æ¹åãšãšãã«ããã®æ¹è¯ç 究ããªãããŠã
ãŠãããããããªãããæ¬çºæè ã®ç¥ãéãã§ã¯
åŸæ¥ç¥ãããŠããã·ã¢ã³ã«ãã©ãŒã«ãããŠãäžèš
ã®å¿ èŠãšãããæ§è³ªããã¹ãŠæºè¶³ããã«ãã©ãŒã¯
æªã èŠåºãããŠã¯ããªãã ããªãã¡ãåŸæ¥ç¥ãããŠããã·ã¢ã³ã«ãã©ãŒã«
ã¯æ¬¡ã®ãããªãã®ããããäŸãã°ç±³åœç¹èš±ç¬¬
2801171å·æ现æžã«èšèŒãããŠããäžèšã«ãã©ãŒ ïŒâãαâïŒïŒïŒïŒâãžâtertâã¢ãã«ããšãã
ã·ïŒãã¿ã³ã¢ãããâïŒïŒïŒâãžâã¯ããâïŒâ
ã¡ãã«ããšããŒã« ã¯ãåŸè¿°ã®å®æœäŸãããæãããªåŠããèå æ§ã¯
è¯å¥œã§ããããèç±æ§ã«æ¬ ç¹ãæããå ããŠãã³
ãžã«ã¢ã«ã³ãŒã«ãžã®çºè²äŸåæ§ã倧ããããã³ãž
ã«ã¢ã«ã³ãŒã«ãæé€ããçºè²çŸååŠç液äžã§ã®æ
倧çºè²æ¿åºŠãäžå åã§ããã ãŸããç¹éæ53â109630å·å ¬å ±ã«èšèŒãããŠã
ãã«ãã©ãŒã¯ãããšããŒã«ã®ïŒïŒïŒäœã«ãžã«ã«ã
ãã«ã¢ããåºã眮æããã«ãã©ãŒã§ããã€ïŒäœçœ®
ã®çœ®æåºã®æ«ç«¯ãïœâã¢ã«ãã«ã¹ã«ããã«ã¢ãã
ããšããã·åºãŸãã¯ïœâã¢ã«ãã«ã¢ããã¹ã«ãã
ã«ããšããã·åºãå°å ¥ããããšã«ãããå¡åžæã
ããã¯çµäºæã®åæ£ã®å®å®æ§ãæ¹è¯ããããšãèš
èŒãããŠããããåŸè¿°ã®å®æœäŸããæãããªåŠ
ããäŸç¶ãã³ãžã«ã¢ã«ã³ãŒã«ãžã®çºè²äŸåæ§ã倧
ããããããã®ç¹ã§ã®æ¹è¯ãæãŸããã ããã«ãç±³åœç¹èš±ç¬¬3839044å·ãç¹éæ47â
37425å·å ¬å ±ãç¹å ¬æ48â36894å·å ¬å ±ãç¹éæ50
â10135å·ãå50â117422å·ãå50â130441å·ã
å50â108841å·ãå50â120334å·å ¬å ±çã«èšèŒã
ããŠãããåŠããããšããŒã«åã·ã¢ã³ã«ãã©ãŒ
ããåŸè¿°ã®å®æœäŸãããæãããªåŠããèç±æ§ã«
åé¡ãæ®ããããæãã¯ãã³ãžã«ã¢ã«ã³ãŒã«ãæ
é€ããçºè²çŸå液äžã§ã®è²çŽ 圢æé床ããã³æ倧
çºè²æ¿åºŠãäžå åã§ãã€ããããŠãã·ã¢ã³ã«ãã©
ãŒã«èŠæ±ãããæ§è³ªããã¹ãŠæºè¶³ãããã®ã§ã¯ãª
ãã ããã§ãæ¬çºæã®ç¬¬ïŒã®ç®çã¯ãåèšã®åŠãã·
ã¢ã³ã«ãã©ãŒãšããŠèŠæ±ãããæãŸããè«žç¹æ§ã
æããã·ã¢ã³ã«ãã©ãŒãæäŸããããšã§ããã æ¬çºæã®ç¬¬ïŒã®ç®çã¯ãã¢ã«ã«ãªãŸãã¯é«æ²žç¹
ææ©æº¶åªçã«å¯Ÿãã溶解æ§ãããã²ã³åéã«ã©ãŒ
åçä¹³å€ã«å¯Ÿããåæ£æ§ããã³å®å®æ§ã«åªããã·
ã¢ã³ã«ãã©ãŒãæäŸããããšã§ããã æ¬çºæã®ç¬¬ïŒã®ç®çã¯ãç»åä¿åæ§ããªãã¡è
ç±æ§ãèå æ§ãè湿æ§ã«åªããããã«ãã³ãžã«ã¢
ã«ã³ãŒã«ãæé€ããçºè²çŸååŠç液äžã§ã®è²çŽ 圢
æé床ã倧ãããé«ãçºè²æ¿åºŠãæããã·ã¢ã³è²
çŽ ç»åãäžããã·ã¢ã³è²çŽ ç»åã®åœ¢ææ¹æ³ãæäŸ
ããããšã§ããã æ¬çºæã®äžèšç®çããã³ä»¥äžã«è¿°ã¹ããã®ä»ã®
ç®çã¯ãããã²ã³åéã«ã©ãŒåçæå ææãç»å
圢æåŠçããã«éããŠãäžèšäžè¬åŒãããŸãã¯
ããã§è¡šããããã·ã¢ã³ã«ãã©ãŒãååšããã
ãããšã«ããéæãããã äžè¬åŒãã äžè¬åŒãã ïŒåŒäžãã¯æ°ŽçŽ ååãŸãã¯ïŒä¹è³20ã®ççŽ æ°
ãæããã¢ã«ãã«åºããR1ã¯çœ®æã¢ã«ãã«ã¹ã«
ããã«ã¢ããåºãŸãã¯çœ®æã¢ã«ãã«ã¢ããã¹ã«ã
ãã«åºããR2ã¯ã¢ã«ãã«åºãã¢ãªãŒã«åºãŸãã¯
ãããç°åºããR3ã¯æ°ŽçŽ ååãŸãã¯ããã²ã³å
åããã¯ããšãã¬ã³åºããããã¬ã³åºãŸãã¯ã¢
ã«ãã¬ã³åºããã¯æ°ŽçŽ ååãŸãã¯ã«ãããªã³ã°
é¢è±åºããïœã¯ïŒãŸãã¯ïŒã®æŽæ°ãè¡šãããïŒ æŽã«åèšäžè¬åŒããããã³ããã®R1ã®äž
ã®ã¢ã«ãã«åºãšããŠã¯ã飜åã®ãã®äžé£œåã®ãã®
ã®ãããã§ãããããŸãçŽéã®ãã®ãåå²ã®ãã®
ã®ãããã§ãããã äŸãã°ã¡ãã¬ã³ããšãã¬ã³ãããªã¡ãã¬ã³ãã
ããã¬ã³ãããã«ã¡ãã¬ã³ãããããã¬ã³åºçã§
ããã ãããã¢ã«ãã«åºã«å°å ¥ããã眮æåºãšããŠã¯
ãªãã·ããã³ããããã·ïŒRâ²ââïŒãã¢ã·ã«ãª
ãã·
ã®ã§ãããç¹ã«æ°èŠãªïŒïŒïŒãžã¢ã·ã«ã¢ããåã·
ã¢ã³ã«ãã©ãŒã®ååšäžã§ã«ã©ãŒåçæå ææãçº
è²çŸåããããšã«ããã·ã¢ã³è²çŽ ç»åã圢æãã
æ¹æ³ã«é¢ãããã®ã§ãããæŽã«è©³ããã¯ã溶解
æ§ãåæ£å®å®æ§ãåå åžåç¹æ§ãè¯å¥œã§ããããš
ãã«ãã³ãžã«ã¢ã«ã³ãŒã«ãæé€ããçºè²çŸååŠç
液äžã§ã®è²çŽ 圢æé床ã倧ãããçºè²æ¿åºŠãé«
ãããããç»åä¿åæ§ã«åªããæ°èŠãªã·ã¢ã³ã«ã
ã©ãŒã®ååšäžã§ã·ã¢ã³è²çŽ ç»åã圢æããæ¹æ³ã«
é¢ãããã®ã§ããã æžè²æ³ã«ã©ãŒåçã¯ãåšç¥ã®åŠããè³éŠæ第ïŒ
çŽã¢ãã³ç³»çºè²çŸåå€ããé²å ãããããã²ã³å
éç²åãéå ããããšã«ããçæããçºè²çŸåå€
ã®é žåçæç©ãšé»è²ãã·ã¢ã³ãããŒã³ã¿è²çŽ ã圢
æããã«ãã©ãŒãããã²ã³åéä¹³å€äžã§é žåã«ã
ããªã³ã°ããããšã«ããè²ç»åã圢æããããã
ããã®å Žåãé»è²è²çŽ ã圢æããããã®é»è²ã«ã
ã©ãŒãšããŠã¯ãäžè¬ã«éé掻æ§ã¡ãã¬ã³åºãæã
ãååç©ãçšããããããŒã³ã¿è²çŽ ã圢æããã
ãã®ããŒã³ã¿ã«ãã©ãŒãšããŠã¯ããã©ãŸãã³ç³»ã
ãã©ãŸãªããã³ãã€ãããŸãŒã«ç³»ãã€ã³ããŸãã³
ç³»çã®ååç©ã䜿çšãããããã³ã·ã¢ã³è²çŽ ã圢
æããããã®ã·ã¢ã³ã«ãã©ãŒãšããŠã¯ãããšããŒ
ã«ããã³ããããŒã«æ§æ°Žé žåºãæããååç©ãçš
ããããŠããã åã«ãã©ãŒã¯ãå®è³ªçã«æ°Žäžæº¶æ§ã®é«æ²žç¹ææ©
溶åªã«æãã¯ããã«å¿ èŠã«å¿ããŠè£å©æº¶åªã䜵çš
ããŠæº¶è§£ããããã²ã³åéä¹³å€äžã«æ·»å ããã
ããæãã¯ã¢ã«ã«ãªæ°Žæº¶æ¶²ã«æº¶è§£ããŠä¹³å€äžã«æ·»
å ããããåè ã¯æ²¹æ»Žåæ£æ³ã§ãããåŸè ã¯ã¢ã«
ã«ãªåæ£æ³ã§ããããäžè¬ã«åè ã®æ¹ãåŸè ãã
ãèå ãèç±ãè湿æ§ãç²ç¶æ§ãè²ã®é®®é床çã«
ãããŠåªããŠãããšãããŠããã åã«ãã©ãŒã«èŠæ±ãããåºæ¬çæ§è³ªãšããŠã¯ã
åã«è²çŽ ã圢æããã ãã§ãªããå ãé«æ²žç¹ææ©
溶åªãããã¯ã¢ã«ã«ãªçã«å¯Ÿãã溶解æ§ã倧ãã
ããšããŸãããã²ã³åéåçä¹³å€ãžã®åæ£æ§ãã
ã³å®å®æ§ãããããšãããã«ãã€ãŠåœ¢æãããè²
çŽ ãå ãç±ã湿æ°çã«å¯ŸããŠå ç¢æ§ãæããã
ãšãåå åžåç¹æ§ãè¯å¥œã§ããããšãéææ§ãã
ãããšãçºè²æ¿åºŠã倧ããããšãæŽã«ã¯åŸããã
ç»åãé®®æã§ããããšçã®çš®ã ã®è«žç¹æ§ãæãã
ããšãæãŸããŠããããšãããã·ã¢ã³ã«ãã©ãŒã«
ãããŠã¯ãèç±æ§ãè湿æ§ãèå æ§çã®ç»åä¿å
æ§ã®æ¹è¯ãå¿ èŠãšãããŠããã æŽã«ãæšä»ã®è±å ¬å®³ã®èŠå°ãããçºè²çŸååŠç
液ã«æ·»å ããããã³ãžã«ã¢ã«ã³ãŒã«ã®é€å»ã倧ã
ãªåé¡ãšããŠãšããããããŠããŠããããšããã
äžè¬ã«ãã³ãžã«ã¢ã«ã³ãŒã«ãæ·»å ããªãçºè²çŸå
åŠç液ãçšãããšãããã²ã³åéåçä¹³å€äžã«æ·»
å ãããã«ãã©ãŒã®çºè²æ§ããªãã¡è²çŽ 圢æé床
ããã³æ倧çºè²æ¿åºŠã¯äœäžããã®ãçŸç¶ã§ããã
ãããŠãã·ã¢ã³ã«ãã©ãŒã«ãããŠã¯ããã®åŸåã
èããè¡šããããããã§ããã®ã·ã¢ã³ã«ãã©ãŒã«
ãããŠã¯ããã®çºè²æ§ããã³ãžã«ã¢ã«ã³ãŒã«ã«äŸ
åããªãããšãåæãããŠããããã€äžèšç»åä¿
åæ§ã®æ¹åãšãšãã«ããã®æ¹è¯ç 究ããªãããŠã
ãŠãããããããªãããæ¬çºæè ã®ç¥ãéãã§ã¯
åŸæ¥ç¥ãããŠããã·ã¢ã³ã«ãã©ãŒã«ãããŠãäžèš
ã®å¿ èŠãšãããæ§è³ªããã¹ãŠæºè¶³ããã«ãã©ãŒã¯
æªã èŠåºãããŠã¯ããªãã ããªãã¡ãåŸæ¥ç¥ãããŠããã·ã¢ã³ã«ãã©ãŒã«
ã¯æ¬¡ã®ãããªãã®ããããäŸãã°ç±³åœç¹èš±ç¬¬
2801171å·æ现æžã«èšèŒãããŠããäžèšã«ãã©ãŒ ïŒâãαâïŒïŒïŒïŒâãžâtertâã¢ãã«ããšãã
ã·ïŒãã¿ã³ã¢ãããâïŒïŒïŒâãžâã¯ããâïŒâ
ã¡ãã«ããšããŒã« ã¯ãåŸè¿°ã®å®æœäŸãããæãããªåŠããèå æ§ã¯
è¯å¥œã§ããããèç±æ§ã«æ¬ ç¹ãæããå ããŠãã³
ãžã«ã¢ã«ã³ãŒã«ãžã®çºè²äŸåæ§ã倧ããããã³ãž
ã«ã¢ã«ã³ãŒã«ãæé€ããçºè²çŸååŠç液äžã§ã®æ
倧çºè²æ¿åºŠãäžå åã§ããã ãŸããç¹éæ53â109630å·å ¬å ±ã«èšèŒãããŠã
ãã«ãã©ãŒã¯ãããšããŒã«ã®ïŒïŒïŒäœã«ãžã«ã«ã
ãã«ã¢ããåºã眮æããã«ãã©ãŒã§ããã€ïŒäœçœ®
ã®çœ®æåºã®æ«ç«¯ãïœâã¢ã«ãã«ã¹ã«ããã«ã¢ãã
ããšããã·åºãŸãã¯ïœâã¢ã«ãã«ã¢ããã¹ã«ãã
ã«ããšããã·åºãå°å ¥ããããšã«ãããå¡åžæã
ããã¯çµäºæã®åæ£ã®å®å®æ§ãæ¹è¯ããããšãèš
èŒãããŠããããåŸè¿°ã®å®æœäŸããæãããªåŠ
ããäŸç¶ãã³ãžã«ã¢ã«ã³ãŒã«ãžã®çºè²äŸåæ§ã倧
ããããããã®ç¹ã§ã®æ¹è¯ãæãŸããã ããã«ãç±³åœç¹èš±ç¬¬3839044å·ãç¹éæ47â
37425å·å ¬å ±ãç¹å ¬æ48â36894å·å ¬å ±ãç¹éæ50
â10135å·ãå50â117422å·ãå50â130441å·ã
å50â108841å·ãå50â120334å·å ¬å ±çã«èšèŒã
ããŠãããåŠããããšããŒã«åã·ã¢ã³ã«ãã©ãŒ
ããåŸè¿°ã®å®æœäŸãããæãããªåŠããèç±æ§ã«
åé¡ãæ®ããããæãã¯ãã³ãžã«ã¢ã«ã³ãŒã«ãæ
é€ããçºè²çŸå液äžã§ã®è²çŽ 圢æé床ããã³æ倧
çºè²æ¿åºŠãäžå åã§ãã€ããããŠãã·ã¢ã³ã«ãã©
ãŒã«èŠæ±ãããæ§è³ªããã¹ãŠæºè¶³ãããã®ã§ã¯ãª
ãã ããã§ãæ¬çºæã®ç¬¬ïŒã®ç®çã¯ãåèšã®åŠãã·
ã¢ã³ã«ãã©ãŒãšããŠèŠæ±ãããæãŸããè«žç¹æ§ã
æããã·ã¢ã³ã«ãã©ãŒãæäŸããããšã§ããã æ¬çºæã®ç¬¬ïŒã®ç®çã¯ãã¢ã«ã«ãªãŸãã¯é«æ²žç¹
ææ©æº¶åªçã«å¯Ÿãã溶解æ§ãããã²ã³åéã«ã©ãŒ
åçä¹³å€ã«å¯Ÿããåæ£æ§ããã³å®å®æ§ã«åªããã·
ã¢ã³ã«ãã©ãŒãæäŸããããšã§ããã æ¬çºæã®ç¬¬ïŒã®ç®çã¯ãç»åä¿åæ§ããªãã¡è
ç±æ§ãèå æ§ãè湿æ§ã«åªããããã«ãã³ãžã«ã¢
ã«ã³ãŒã«ãæé€ããçºè²çŸååŠç液äžã§ã®è²çŽ 圢
æé床ã倧ãããé«ãçºè²æ¿åºŠãæããã·ã¢ã³è²
çŽ ç»åãäžããã·ã¢ã³è²çŽ ç»åã®åœ¢ææ¹æ³ãæäŸ
ããããšã§ããã æ¬çºæã®äžèšç®çããã³ä»¥äžã«è¿°ã¹ããã®ä»ã®
ç®çã¯ãããã²ã³åéã«ã©ãŒåçæå ææãç»å
圢æåŠçããã«éããŠãäžèšäžè¬åŒãããŸãã¯
ããã§è¡šããããã·ã¢ã³ã«ãã©ãŒãååšããã
ãããšã«ããéæãããã äžè¬åŒãã äžè¬åŒãã ïŒåŒäžãã¯æ°ŽçŽ ååãŸãã¯ïŒä¹è³20ã®ççŽ æ°
ãæããã¢ã«ãã«åºããR1ã¯çœ®æã¢ã«ãã«ã¹ã«
ããã«ã¢ããåºãŸãã¯çœ®æã¢ã«ãã«ã¢ããã¹ã«ã
ãã«åºããR2ã¯ã¢ã«ãã«åºãã¢ãªãŒã«åºãŸãã¯
ãããç°åºããR3ã¯æ°ŽçŽ ååãŸãã¯ããã²ã³å
åããã¯ããšãã¬ã³åºããããã¬ã³åºãŸãã¯ã¢
ã«ãã¬ã³åºããã¯æ°ŽçŽ ååãŸãã¯ã«ãããªã³ã°
é¢è±åºããïœã¯ïŒãŸãã¯ïŒã®æŽæ°ãè¡šãããïŒ æŽã«åèšäžè¬åŒããããã³ããã®R1ã®äž
ã®ã¢ã«ãã«åºãšããŠã¯ã飜åã®ãã®äžé£œåã®ãã®
ã®ãããã§ãããããŸãçŽéã®ãã®ãåå²ã®ãã®
ã®ãããã§ãããã äŸãã°ã¡ãã¬ã³ããšãã¬ã³ãããªã¡ãã¬ã³ãã
ããã¬ã³ãããã«ã¡ãã¬ã³ãããããã¬ã³åºçã§
ããã ãããã¢ã«ãã«åºã«å°å ¥ããã眮æåºãšããŠã¯
ãªãã·ããã³ããããã·ïŒRâ²ââïŒãã¢ã·ã«ãª
ãã·
ãåŒããšã¹ãã«ããã³ã«ã«ããã·
ã«
ãåŒãããªããã³ã¡ã«ã«ããïŒRâ²â
âïŒãã¹ã«ããã«ïŒRâ²âSO2âïŒãã¢ãã
ãåŒãã¢ã·ã«
ãåŒãã¢ã·ã«ã¢ã
ã
ãåŒãã«ã«ãã¢ã€ã«
ãåŒãã·ã¢ãïŒïŒ®â¡ïŒ£âïŒãã¹ã«ãã³
ã¢ãã
ãåŒãã¹ã«ãã¢ã¢ã€ã«
ãåŒããªãã·ã¹ã«ããã«ããã³
ïŒRâ²ââSO2âïŒãã¹ã«ããã«ãªãã·ïŒRâ²âSO2
ââïŒããããïŒO2NâïŒãããã²ã³ïŒRâ²ãã
ã³Râ³ã¯ææ©åºã§æ°ŽçŽ ååãå«ããRâ²ããã³Râ³ã¯
äžè«žã«ç°ã圢æããŠãè¯ããïŒã®åºãããããç¹
ã«å¥œãŸããã¯ãªãã·ããã³ããããã·ïŒRâ²â
âïŒãã¢ã·ã«ãªãã·
ââïŒããããïŒO2NâïŒãããã²ã³ïŒRâ²ãã
ã³Râ³ã¯ææ©åºã§æ°ŽçŽ ååãå«ããRâ²ããã³Râ³ã¯
äžè«žã«ç°ã圢æããŠãè¯ããïŒã®åºãããããç¹
ã«å¥œãŸããã¯ãªãã·ããã³ããããã·ïŒRâ²â
âïŒãã¢ã·ã«ãªãã·
ãåŒããšã¹ãã«ã
ãã³ã«ã«ããã·ã«
ãåŒãããªããã³ã¡
ã«ã«ããïŒRâ²ââïŒãã¹ã«ããã«ïŒRâ²âSO2
âïŒãã¢ãã
âïŒãã¢ãã
ãåŒãã¢ã·ã«
ãåŒãã¢ã·ã«ã¢ãã
ãåŒãã·
ã¢ãïŒïŒ®â¡ïŒ£âïŒããããïŒO2NâïŒãããã±ã³
ã®åºïŒRâ²ããã³Râ³ã¯ææ©åºã§æ°ŽçŽ ååãå«ãã
Râ²ããã³Râ³ã¯äžè«žã«ç°ã圢æããŠãè¯ããïŒã§ã
ãã ãŸãR1ãä»ããŠçµã°ãããã¹åïŒïŒïŒâãžã¢
ã·ã«ã¢ããããšããŒã«ã·ã¢ã³ã«ãã©ãŒãæ¬çºæã®
ç®çã«é©åããã·ã¢ã³ã«ãã©ãŒã§ããã R2ã®æŽã«å ·äœçãªãã®ã¯ãã¢ã«ãã«åºãšããŠ
ã¯ãäŸãã°ã¡ãã«ããšãã«ãã€ãœãããã«ããã
ã«ãterâããã«ãããã·ã«ããã³ã¿ãã·ã«ãã·
ã¯ãããã·ã«çã®ååºãã¢ãªãŒã«åºãšããŠã¯ãäŸ
ãã°ããšãã«ãããã¿ã¬ã³çã®ååºããããç°æ®
åºãšããŠã¯ãäŸãã°ãã©ã³åºçã§ãããæŽã«ãã
ãååºã«çœ®æããã眮æåºãšããŠã¯ãäŸãã°ãã
ã²ã³ååïŒå¡©çŽ ãèçŽ ãåŒçŽ çã®åååïŒãã¢ã«
ãã«åºããããåºãããããã·åºãã«ã«ããã·
åºãã¢ããåºãã¹ã«ãåºãã·ã¢ãåºãã¢ã«ã³ãã·
åºãã¢ãªãŒã«ãªãã·åºãã¢ãªãŒã«ããªåºãã¢ã·ã«
ã¢ããåºãã«ã«ãã¢ã€ã«åºããšã¹ãã«åºãã¢ã·ã«
åºãã¢ã·ã«ãªãã·åºãã¹ã«ãã³ã¢ããåºãã¹ã«ã
ã¢ã¢ã€ã«åºãã¹ã«ããã«åºãã¹ã«ããªãã·åºããª
ãã·ã¹ã«ããã«åºçãæããããã ãŸãåè¿°ã®ïŒžã®åºã®ãã¡ãã¢ã«ãã¬ã³åºã®å ·äœ
çãªäŸãšããŠã¯ãäŸãã°ã¡ãã¬ã³ããšãã¬ã³ãã
ãã¬ã³çã®åºãè¡šãããæŽã«ã¢ã«ãã¬ã³åºããã³
ãŸãåè¿°ã®ããšãã¬ã³åºããããã¬ã³åºã«ã¯æ¬¡ã®
åŠã眮æåºã眮æãããŠããŠãããã äŸãã°ã¢ã«ãã«åºïŒäŸãã°ã¡ãã«åºããšãã«
åºãã€ãœããã«åºãããã·ã«åºãterâã¢ãã«åºã
ã·ã¯ãããã·ã«åºããã³ã¿ãã·ã«åºçã®ååºïŒã
ã¢ã«ã±ãã«åºïŒäŸãã°ã¢ãªã«åºçïŒãã¢ãªãŒã«åºã
ãããç°æ®åºãããã²ã³ååïŒäŸãã°å¡©çŽ ãè
çŽ ãåŒçŽ çã®åååïŒããããåºãããããã·åºã
ã«ã«ããã·åºãã¢ããåºãã¹ã«ãåºãã¢ã«ã³ãã·
åºãã¢ãªãŒã«ãªãã·åºãã¢ãªãŒã«ããªåºãã¢ã·ã«
ã¢ããåºãã«ã«ãã¢ã€ã«åºããšã¹ãã«åºãã¢ã·ã«
åºãã¢ã·ã«ãªãã·åºãã¹ã«ãã³ã¢ããåºãã¹ã«ã
ã¢ã¢ã€ã«åºãã¹ã«ããã«åºãã¢ã«ããªãåºçã®å
åºã§ããã ãŸãã¯æ°ŽçŽ ååãŸãã¯ççŽ æ°ïŒã20ã®ã¢ã«ã
ã«åºã§æŽã«ã該ã¢ã«ãã«åºã®å ·äœäŸãšããŠã¯ãäŸ
ãã°ã¡ãã«åºããšãã«åºãããã«åºãããã·ã«åº
çã®ååºã§ããã ã¯æ°ŽçŽ ååãããã¯ã«ãããªã³ã°é¢è±åºãè¡š
ãããã«ãããªã³ã°é¢è±åºã®å ·äœçãªäŸãšããŠã¯
äŸãã°ããã²ã³ååïŒäŸãã°å¡©çŽ ãèçŽ ãåŒçŽ ç
ã®åååïŒãé žçŽ ååãŸãã¯çªçŽ ååãçŽæ¥æŽ»æ§
ç¹ã«çµåããŠããã¢ãªãŒã«ãªãã·åºãã«ã«ãã¢ã€
ã«ãªãã·åºãã«ã«ãã¢ã€ã«ã¡ããã·åºãã¢ã·ã«ãª
ãã·åºãã¢ã«ãã«ãªãã·åºãã¹ã«ãã³ã¢ããåºã
ã³ãã¯é žã€ããåºçãæããããæŽã«å ·äœçãªäŸ
ãšããŠã¯ãç±³åœç¹èš±ç¬¬3471563å·ãç¹éæ47â
37425å·å ¬å ±ãç¹å ¬æ48â36894å·å ¬å ±ãç¹éæ50
â10135å·ãå50â1117422å·ãå50â130441å·ã
å51â108841å·ãå50â120334å·ãå52â18315
å·ãå53â52423å·ãå53â105226å·çã®åå ¬å ±
ã«èšèŒãããŠãããã®ãæçšã§ããã åèšäžè¬åŒããããã³ããã§ç€ºãããåå
ç©ïŒä»¥äžæ¬çºæã®ã«ãã©ãŒãšããïŒã¯ããšããŒã«
ã®ïŒäœãïŒäœã«ããããã¢ã·ã«ã¢ããåºãæãã
æŽã«è©²ã¢ã·ã«ã¢ããã®åºã«çœ®æåºãšããŠäžè¬åŒ
ããã§èŠå®ããR1ã«çœ®æã¢ã«ãã«ã¹ã«ããã«ã¢
ããåºã眮æã¢ã«ãã«ã¢ããã¹ã«ããã«åºã®åŠã
åºãæããããšãç¹åŸŽã§ããã該èŠå®ããåºã®å°
å ¥ã«ããçš®ã ã®è¯å¥œãªç¹æ§ãåŸããããã®ãšèã
ãããã ããªãã¡ãæ¬çºæã®ã«ãã©ãŒã¯ãã¢ã«ã«ãªæã
ã¯é«æ²žç¹ææ©æº¶åªçã«å¯Ÿãã溶解æ§ãåçä¹³å€äž
ãžã®åæ£å®å®æ§ãããããã€åå åžåç¹æ§ãè¯å¥œ
ã§ãããéææ§ããããæŽã«æ¬çºæã®ã«ãã©ãŒã
å«æããæ¬çºæã«ä¿ãã«ã©ãŒä¹³å€ã¯ç»åä¿åæ§ã
å³ã¡èç±ãè湿ãèå æ§ãè¯å¥œã§ããããã€è±å ¬
害ã®èŠ³ç¹ãããã³ãžã«ã¢ã«ã³ãŒã«ãžã®çºè²äŸåæ§
ã®å°ãªããã€ãŸããã³ãžã«ã¢ã«ã³ãŒã«ãæé€ãã
çºè²çŸååŠç液äžã§ã®è²çŽ 圢æé床ã倧ãããçº
è²æ¿åºŠãé«ãçã®æ§è³ªãæããã ãããã«ãåèšå ¬ç¥ã®ã·ã¢ã³ã«ãã©ãŒã®æè¡ã
èšèŒããæç®ãšããŠæããç±³åœç¹èš±ç¬¬2801171å·ã
ãŸãç±³åœç¹èš±ç¬¬3998642å·ãç±³åœç¹èš±ç¬¬3839044å·
ããã«ãŸãç¹éæ53â109630å·å ¬å ±çã«ã¯ãæ¬çº
æã®ã«ãã©ãŒã«ã€ããŠã¯ã瀺åããããŠãããã
åŸè¿°ã®å®æœäŸã§æãããªåŠããæ¬çºæã®ã«ãã©ãŒ
ãçºæ®ããå¹æã«ã¯å šãé©ãã¹ããã®ã§ãã€ãã
ãããŠãæ¬çºæã®ã«ãã©ãŒã¯ããšãããçºè²çŸå
åŠç液äžã®ãã³ãžã«ã¢ã«ã³ãŒã«ãžã®çºè²äŸåæ§ã
æ¹è¯ããããã«ç»åä¿åæ§ãç¹ã«èç±æ§ãæ¹è¯ã
ãããšãç¹åŸŽãšããã 次ã«ãæ¬çºæã®ã«ãã©ãŒã®ä»£è¡šçå ·äœäŸãæã
ãããæ¬çºæã«çšããããæ¬çºæã®ã«ãã©ãŒã¯ã
ãããã«éå®ãããªãã
ã®åºïŒRâ²ããã³Râ³ã¯ææ©åºã§æ°ŽçŽ ååãå«ãã
Râ²ããã³Râ³ã¯äžè«žã«ç°ã圢æããŠãè¯ããïŒã§ã
ãã ãŸãR1ãä»ããŠçµã°ãããã¹åïŒïŒïŒâãžã¢
ã·ã«ã¢ããããšããŒã«ã·ã¢ã³ã«ãã©ãŒãæ¬çºæã®
ç®çã«é©åããã·ã¢ã³ã«ãã©ãŒã§ããã R2ã®æŽã«å ·äœçãªãã®ã¯ãã¢ã«ãã«åºãšããŠ
ã¯ãäŸãã°ã¡ãã«ããšãã«ãã€ãœãããã«ããã
ã«ãterâããã«ãããã·ã«ããã³ã¿ãã·ã«ãã·
ã¯ãããã·ã«çã®ååºãã¢ãªãŒã«åºãšããŠã¯ãäŸ
ãã°ããšãã«ãããã¿ã¬ã³çã®ååºããããç°æ®
åºãšããŠã¯ãäŸãã°ãã©ã³åºçã§ãããæŽã«ãã
ãååºã«çœ®æããã眮æåºãšããŠã¯ãäŸãã°ãã
ã²ã³ååïŒå¡©çŽ ãèçŽ ãåŒçŽ çã®åååïŒãã¢ã«
ãã«åºããããåºãããããã·åºãã«ã«ããã·
åºãã¢ããåºãã¹ã«ãåºãã·ã¢ãåºãã¢ã«ã³ãã·
åºãã¢ãªãŒã«ãªãã·åºãã¢ãªãŒã«ããªåºãã¢ã·ã«
ã¢ããåºãã«ã«ãã¢ã€ã«åºããšã¹ãã«åºãã¢ã·ã«
åºãã¢ã·ã«ãªãã·åºãã¹ã«ãã³ã¢ããåºãã¹ã«ã
ã¢ã¢ã€ã«åºãã¹ã«ããã«åºãã¹ã«ããªãã·åºããª
ãã·ã¹ã«ããã«åºçãæããããã ãŸãåè¿°ã®ïŒžã®åºã®ãã¡ãã¢ã«ãã¬ã³åºã®å ·äœ
çãªäŸãšããŠã¯ãäŸãã°ã¡ãã¬ã³ããšãã¬ã³ãã
ãã¬ã³çã®åºãè¡šãããæŽã«ã¢ã«ãã¬ã³åºããã³
ãŸãåè¿°ã®ããšãã¬ã³åºããããã¬ã³åºã«ã¯æ¬¡ã®
åŠã眮æåºã眮æãããŠããŠãããã äŸãã°ã¢ã«ãã«åºïŒäŸãã°ã¡ãã«åºããšãã«
åºãã€ãœããã«åºãããã·ã«åºãterâã¢ãã«åºã
ã·ã¯ãããã·ã«åºããã³ã¿ãã·ã«åºçã®ååºïŒã
ã¢ã«ã±ãã«åºïŒäŸãã°ã¢ãªã«åºçïŒãã¢ãªãŒã«åºã
ãããç°æ®åºãããã²ã³ååïŒäŸãã°å¡©çŽ ãè
çŽ ãåŒçŽ çã®åååïŒããããåºãããããã·åºã
ã«ã«ããã·åºãã¢ããåºãã¹ã«ãåºãã¢ã«ã³ãã·
åºãã¢ãªãŒã«ãªãã·åºãã¢ãªãŒã«ããªåºãã¢ã·ã«
ã¢ããåºãã«ã«ãã¢ã€ã«åºããšã¹ãã«åºãã¢ã·ã«
åºãã¢ã·ã«ãªãã·åºãã¹ã«ãã³ã¢ããåºãã¹ã«ã
ã¢ã¢ã€ã«åºãã¹ã«ããã«åºãã¢ã«ããªãåºçã®å
åºã§ããã ãŸãã¯æ°ŽçŽ ååãŸãã¯ççŽ æ°ïŒã20ã®ã¢ã«ã
ã«åºã§æŽã«ã該ã¢ã«ãã«åºã®å ·äœäŸãšããŠã¯ãäŸ
ãã°ã¡ãã«åºããšãã«åºãããã«åºãããã·ã«åº
çã®ååºã§ããã ã¯æ°ŽçŽ ååãããã¯ã«ãããªã³ã°é¢è±åºãè¡š
ãããã«ãããªã³ã°é¢è±åºã®å ·äœçãªäŸãšããŠã¯
äŸãã°ããã²ã³ååïŒäŸãã°å¡©çŽ ãèçŽ ãåŒçŽ ç
ã®åååïŒãé žçŽ ååãŸãã¯çªçŽ ååãçŽæ¥æŽ»æ§
ç¹ã«çµåããŠããã¢ãªãŒã«ãªãã·åºãã«ã«ãã¢ã€
ã«ãªãã·åºãã«ã«ãã¢ã€ã«ã¡ããã·åºãã¢ã·ã«ãª
ãã·åºãã¢ã«ãã«ãªãã·åºãã¹ã«ãã³ã¢ããåºã
ã³ãã¯é žã€ããåºçãæããããæŽã«å ·äœçãªäŸ
ãšããŠã¯ãç±³åœç¹èš±ç¬¬3471563å·ãç¹éæ47â
37425å·å ¬å ±ãç¹å ¬æ48â36894å·å ¬å ±ãç¹éæ50
â10135å·ãå50â1117422å·ãå50â130441å·ã
å51â108841å·ãå50â120334å·ãå52â18315
å·ãå53â52423å·ãå53â105226å·çã®åå ¬å ±
ã«èšèŒãããŠãããã®ãæçšã§ããã åèšäžè¬åŒããããã³ããã§ç€ºãããåå
ç©ïŒä»¥äžæ¬çºæã®ã«ãã©ãŒãšããïŒã¯ããšããŒã«
ã®ïŒäœãïŒäœã«ããããã¢ã·ã«ã¢ããåºãæãã
æŽã«è©²ã¢ã·ã«ã¢ããã®åºã«çœ®æåºãšããŠäžè¬åŒ
ããã§èŠå®ããR1ã«çœ®æã¢ã«ãã«ã¹ã«ããã«ã¢
ããåºã眮æã¢ã«ãã«ã¢ããã¹ã«ããã«åºã®åŠã
åºãæããããšãç¹åŸŽã§ããã該èŠå®ããåºã®å°
å ¥ã«ããçš®ã ã®è¯å¥œãªç¹æ§ãåŸããããã®ãšèã
ãããã ããªãã¡ãæ¬çºæã®ã«ãã©ãŒã¯ãã¢ã«ã«ãªæã
ã¯é«æ²žç¹ææ©æº¶åªçã«å¯Ÿãã溶解æ§ãåçä¹³å€äž
ãžã®åæ£å®å®æ§ãããããã€åå åžåç¹æ§ãè¯å¥œ
ã§ãããéææ§ããããæŽã«æ¬çºæã®ã«ãã©ãŒã
å«æããæ¬çºæã«ä¿ãã«ã©ãŒä¹³å€ã¯ç»åä¿åæ§ã
å³ã¡èç±ãè湿ãèå æ§ãè¯å¥œã§ããããã€è±å ¬
害ã®èŠ³ç¹ãããã³ãžã«ã¢ã«ã³ãŒã«ãžã®çºè²äŸåæ§
ã®å°ãªããã€ãŸããã³ãžã«ã¢ã«ã³ãŒã«ãæé€ãã
çºè²çŸååŠç液äžã§ã®è²çŽ 圢æé床ã倧ãããçº
è²æ¿åºŠãé«ãçã®æ§è³ªãæããã ãããã«ãåèšå ¬ç¥ã®ã·ã¢ã³ã«ãã©ãŒã®æè¡ã
èšèŒããæç®ãšããŠæããç±³åœç¹èš±ç¬¬2801171å·ã
ãŸãç±³åœç¹èš±ç¬¬3998642å·ãç±³åœç¹èš±ç¬¬3839044å·
ããã«ãŸãç¹éæ53â109630å·å ¬å ±çã«ã¯ãæ¬çº
æã®ã«ãã©ãŒã«ã€ããŠã¯ã瀺åããããŠãããã
åŸè¿°ã®å®æœäŸã§æãããªåŠããæ¬çºæã®ã«ãã©ãŒ
ãçºæ®ããå¹æã«ã¯å šãé©ãã¹ããã®ã§ãã€ãã
ãããŠãæ¬çºæã®ã«ãã©ãŒã¯ããšãããçºè²çŸå
åŠç液äžã®ãã³ãžã«ã¢ã«ã³ãŒã«ãžã®çºè²äŸåæ§ã
æ¹è¯ããããã«ç»åä¿åæ§ãç¹ã«èç±æ§ãæ¹è¯ã
ãããšãç¹åŸŽãšããã 次ã«ãæ¬çºæã®ã«ãã©ãŒã®ä»£è¡šçå ·äœäŸãæã
ãããæ¬çºæã«çšããããæ¬çºæã®ã«ãã©ãŒã¯ã
ãããã«éå®ãããªãã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
以äžã«æ¬çºæã®ã«ãã©ãŒã®ä»£è¡šçãªåæäŸã瀺
ãã åæäŸ ïŒäŸç€ºã«ãã©ãŒNo.ïŒïŒ ïŒâãã³ãŸã€ã«ã¢ããâïŒâã¯ããâïŒâãα
âïŒïœâãšããã·ãšãã«ã¹ã«ããã«ã¢ããããš
ããã·ïŒâαâïŒããã·ã«ïŒã¢ã»ãã«ã¢ãããã
ãšããŒã«ã®åæ (a) ãšãã«Î±âïŒïœâãšããã·ãšãã«ã¹ã«ããã«
ã¢ããããšããã·ïŒããã©ãã«ããšãŒãïŒäžé
äœïŒ¡ïŒã®åæ ç¹éæ53â109630å·å ¬å ±ã®æ¹æ³ã§åæãããšã
ã«Î±âïŒïœâã¢ããããšããã·ïŒããã©ãã«ããš
ãŒã7.3ïœãšããªãžã³1.9ïœãããã©ããããã©ã³
60mlã«æº¶è§£ã宀枩ã§æ¹æããäžãžããšããã·ãšã
ã«ã¹ã«ããã«ã¯ãã©ã€ã3.6ïœã®ããã©ãããã
ã©ã³æº¶æ¶²20mlã滎äžããã滎äžåŸãæ¹æéæµïŒæ
éåŸåå¿æ··åç©ãæ°·æ°Ž200mlãšæ¿å¡©é ž12mlã®äžãž
ããããé ¢é žãšãã«ã§æœåºããæ°ŽæŽä¹Ÿç¥åŸæ¿çž®ã
ãŠæ®æž£ãã«ã©ã åŠçããŠè€è²ãªã€ã«5.4ïœïŒ54ïŒ ïŒ
ãåŸãããã®ãã®ã®æ§é ãNMRã§ç¢ºèªããã (b) αâïŒïœâãšããã·ãšãã«ã¹ã«ããã«ã¢ãã
ããšããã·ïŒããã©ãã«ã³é žïŒäžéäœïŒ¢ïŒã®å
æ (a)ã§åæããäžéäœïŒ¡ã5.2ïœããšã¿ããŒã«25
mlã«æº¶è§£ããŠæ°Žé žåã«ãªãŠã 2.1ïœã®ãšã¿ããŒã«
溶液20mlãå ããã宀枩ã§ïŒæéåå¿ãããåŸã
åå¿æ··åç©ã1NâHCl40mlãå«ãã æ°·æ°Žäžã«ã
ããé ¢é žãšãã«ã§æœåºåŸãæ°ŽæŽä¹Ÿç¥åŸæ¿çž®ããŠ
5.0ïœïŒ100ïŒ ïŒã®è€è²ãªã€ã«ãåŸãã (c) αâïŒïœâãšããã·ãšãã«ã¹ã«ããã«ã¢ãã
ããšããã·ïŒããã©ãã«ã³é žã¯ãã©ã€ãïŒäžé
äœïŒ£ïŒã®åæ (b)ã§åæããäžéäœB4.6ïœããã³ãŒã³50mlã«
溶解ã宀枩ã§æ¹æããäžãžå¡©åããªãã«ïŒmlãå
ããããã®åŸæ¹æéæµïŒæéåŸãæ¿çž®ããŠè€è²ãª
ã€ã«4.7ïœïŒ100ïŒ ïŒãåŸãã (d) ïŒâãã³ãŸã€ã«ã¢ããâïŒâãαâïŒïœâãšã
ãã·ãšãã«ã¹ã«ããã«ã¢ããããšããã·ïŒâα
âïŒããã·ã«ïŒã¢ã»ãã«ã¢ãããããšããŒã«
ïŒäžéäœïŒ€ïŒã®åæ ïŒâãã³ãŸã€ã«ã¢ããâïŒâã¢ããããšããŒã«
2.2ïœãé ¢é žãšãã«30mlã«æº¶è§£ããŠæ¹æéæµãã
äžãž(c)ã§åæããäžéäœïŒ£ã4.7ïœã®é ¢é žãšãã«
溶液ã滎äžãããæ¹æéæµïŒæéåŸãåå¿æ··åç©
ãæ°Žã«ãããææ©å±€ãååãããæ°ŽæŽä¹Ÿç¥åŸæ¿çž®
ããŠè€è²æ®æž£ãåŸãããã®ãã®ãã¡ã¿ããŒã«ãã
åçµæ¶ããŠçœè²ç²æ«3.9ïœïŒ58ïŒ ïŒãåŸãã èç¹136ã138ãã§æ§é ãNMRã«ãã確èªããã (e) äŸç€ºã«ãã©ãŒNo.ïŒã®åæ (d)ã§åæããäžéäœïŒ€ã2.0ïœãé ¢é žãšãã«ã«
溶解åŸãæ°·å·ããŠæ¹æããäžãžå¡©åã¹ã«ããªã«
0.43ïœã®é ¢é žãšãã«æº¶æ¶²ã滎äžããã滎äžåŸã宀
æž©ã«ãã©ãïŒæéåå¿ããããåå¿æ··åç©ãæ°ŽæŽ
也ç¥åŸæ¿çž®ããŠæ®æž£ãã¢ã»ããããªã«ããåçµæ¶
ãããçœè²ç²æ«1.0ïœïŒ47ïŒ ïŒãåŸãã èç¹ã¯122ã126ãã§ãã€ã«ã·ãŠã¿ã€ã³ãã¹ãã
ãããã²ã³ååã®ååšã確èªããããæ§é ã
NMRã«ãã確èªããã æ¬çºæã®ã«ãã©ãŒã«ã¯ã油溶æ§ã®ãã®ãšã¢ã«ã«
ãªå¯æº¶æ§ã®ãã®ãå å«ãããããã®ãã¡æ²¹æº¶æ§ã®
ãã®ã¯ããããããªã€ã«ã»ãããã¯ãåã«ãã©ãŒ
ãšããŠé«æ²žç¹ææ©æº¶åªçã«æº¶è§£ããŠæ¬çºæã«ä¿ã
ã«ã©ãŒä¹³å€äžã«åæ£å«æãããããšãã§ããããŸ
ãã¢ã«ã«ãªå¯æº¶æ§ã§ãããã®ã¯ãã€ãã·ã€ãŒåæ£
æ³ã«ãã€ãŠæ¬çºæã«ä¿ãã«ã©ãŒä¹³å€äžã«åæ£å«æ
ããããããšãã§ãããã®åã«å±ãããã®ãšããŠ
ã¯ãäŸãã°åèšäŸç€ºã«ãã©ãŒãïŒãçãæããã
ãšãã§ããã æ¬çºæã®ã«ãã©ãŒã®ãã¡ãäŸãã°ãªã€ã«ããã
ã¯ãåã®ãã®ãã«ã©ãŒä¹³å€ã«å«æããããã«ã¯ã
åŸæ¥å ¬ç¥ã®æ¹æ³ã«åŸãã°ãããäŸãã°ããªã¯ã¬ãž
ã«ãã¹ããšãŒãããžããã«ã¹ã¿ã¬ãŒãçã®æ²žç¹
175â以äžã®é«æ²žç¹ææ©æº¶åªãŸãã¯é ¢é žããã«ã
ããããªã³é žããã«çã®äœæ²žç¹æº¶åªã®ããããå
ç¬ã«ãŸãã¯å¿ èŠã«å¿ããŠããããã®æ··å液ã«æ¬çº
æã®ã«ãã©ãŒãåç¬ã§ãŸãã¯äœµçšããŠæº¶è§£ãã
åŸãçé¢æŽ»æ§å€ãå«ããŒã©ãã³æ°Žæº¶æ¶²ãšæ··åãã
次ã«é«é床å転ãããµãŒãŸãã¯ã³ãã€ããã«ã§ä¹³
åããåŸãããã²ã³åéã«æ·»å ããŠæ¬çºæã«äœ¿çš
ããããã²ã³åéä¹³å€ã調æŽããããšãã§ããã ãŸãã«ãã©ãŒãçºè²çŸå液äžã«æ·»å ãããæè¬
å€åŒåã®ã«ãã©ãŒã®ãã®ã¯çºè²çŸå液çã«å¯ŸããŠ
æ·»å ãæãå©ç¹ãããããããã®ç¹æ§çãããçµ
æãšããŠæè¬å åŒåã«ãã©ãŒçã®ããã«åçæå
ææã®æå å±€äžã«æ¬çºæã®ã«ãã©ãŒãå«æããã
ãå Žåãæå å±€ã®èèåãã§ããåŸãããè²ç»å
ã®é®®é床çãåäžããæŽã«çºè²çŸåã«å¯ŸããŠæªã
çžäºäœçšã瀺ãããç¹ã«åå¿æ§ãããããã«è²æ±
æçãæ¹è¯ãããå©ç¹ãæããŠããããŸãæ¬çºæ
ã®ã«ãã©ãŒãçšããŠåŸãããè²çŽ ã¯åèšã®åŠãåª
ããè²åžåç¹æ§ãæããŠããã ãã®ãããªæ¬çºæã®ã«ãã©ãŒã¯ãæ¯äœæ§é ãšã¹
ããªãããªãåºãæãããã®ã«ã€ããŠã¯ãããã
ãšã®çµåããã«ããçš®ã ã®å¿çšæ§ããããããªã
ã¡ã«ãã©ãŒæ®åºããäŸãã°ã¹ã«ãã³é žåºãã«ã«ã
ã³é žåºçã®æ°Žæº¶æ§åºãå°å ¥ãããæ¡æ£æ§ãæãã
ãã®ã§ããå Žåããããã¯æ¬çºæã®ã¹ããªãããª
ãåºèªäœãæ¡æ£æ§ã§ãããã®ã®å Žåã«ã¯æ¡æ£æ§ã«
ãã©ãŒãšããŠã®å©çšãäŸãã°æè¬å€åŒã®åçæè¡
ã«çšãããããã®éã«ãã©ãŒã¯çºè²çŸå液äžã«å«
æããããŠçšããããšãã§ãããäŸãã°äŸç€ºã«ã
ã©ãŒ
ãã åæäŸ ïŒäŸç€ºã«ãã©ãŒNo.ïŒïŒ ïŒâãã³ãŸã€ã«ã¢ããâïŒâã¯ããâïŒâãα
âïŒïœâãšããã·ãšãã«ã¹ã«ããã«ã¢ããããš
ããã·ïŒâαâïŒããã·ã«ïŒã¢ã»ãã«ã¢ãããã
ãšããŒã«ã®åæ (a) ãšãã«Î±âïŒïœâãšããã·ãšãã«ã¹ã«ããã«
ã¢ããããšããã·ïŒããã©ãã«ããšãŒãïŒäžé
äœïŒ¡ïŒã®åæ ç¹éæ53â109630å·å ¬å ±ã®æ¹æ³ã§åæãããšã
ã«Î±âïŒïœâã¢ããããšããã·ïŒããã©ãã«ããš
ãŒã7.3ïœãšããªãžã³1.9ïœãããã©ããããã©ã³
60mlã«æº¶è§£ã宀枩ã§æ¹æããäžãžããšããã·ãšã
ã«ã¹ã«ããã«ã¯ãã©ã€ã3.6ïœã®ããã©ãããã
ã©ã³æº¶æ¶²20mlã滎äžããã滎äžåŸãæ¹æéæµïŒæ
éåŸåå¿æ··åç©ãæ°·æ°Ž200mlãšæ¿å¡©é ž12mlã®äžãž
ããããé ¢é žãšãã«ã§æœåºããæ°ŽæŽä¹Ÿç¥åŸæ¿çž®ã
ãŠæ®æž£ãã«ã©ã åŠçããŠè€è²ãªã€ã«5.4ïœïŒ54ïŒ ïŒ
ãåŸãããã®ãã®ã®æ§é ãNMRã§ç¢ºèªããã (b) αâïŒïœâãšããã·ãšãã«ã¹ã«ããã«ã¢ãã
ããšããã·ïŒããã©ãã«ã³é žïŒäžéäœïŒ¢ïŒã®å
æ (a)ã§åæããäžéäœïŒ¡ã5.2ïœããšã¿ããŒã«25
mlã«æº¶è§£ããŠæ°Žé žåã«ãªãŠã 2.1ïœã®ãšã¿ããŒã«
溶液20mlãå ããã宀枩ã§ïŒæéåå¿ãããåŸã
åå¿æ··åç©ã1NâHCl40mlãå«ãã æ°·æ°Žäžã«ã
ããé ¢é žãšãã«ã§æœåºåŸãæ°ŽæŽä¹Ÿç¥åŸæ¿çž®ããŠ
5.0ïœïŒ100ïŒ ïŒã®è€è²ãªã€ã«ãåŸãã (c) αâïŒïœâãšããã·ãšãã«ã¹ã«ããã«ã¢ãã
ããšããã·ïŒããã©ãã«ã³é žã¯ãã©ã€ãïŒäžé
äœïŒ£ïŒã®åæ (b)ã§åæããäžéäœB4.6ïœããã³ãŒã³50mlã«
溶解ã宀枩ã§æ¹æããäžãžå¡©åããªãã«ïŒmlãå
ããããã®åŸæ¹æéæµïŒæéåŸãæ¿çž®ããŠè€è²ãª
ã€ã«4.7ïœïŒ100ïŒ ïŒãåŸãã (d) ïŒâãã³ãŸã€ã«ã¢ããâïŒâãαâïŒïœâãšã
ãã·ãšãã«ã¹ã«ããã«ã¢ããããšããã·ïŒâα
âïŒããã·ã«ïŒã¢ã»ãã«ã¢ãããããšããŒã«
ïŒäžéäœïŒ€ïŒã®åæ ïŒâãã³ãŸã€ã«ã¢ããâïŒâã¢ããããšããŒã«
2.2ïœãé ¢é žãšãã«30mlã«æº¶è§£ããŠæ¹æéæµãã
äžãž(c)ã§åæããäžéäœïŒ£ã4.7ïœã®é ¢é žãšãã«
溶液ã滎äžãããæ¹æéæµïŒæéåŸãåå¿æ··åç©
ãæ°Žã«ãããææ©å±€ãååãããæ°ŽæŽä¹Ÿç¥åŸæ¿çž®
ããŠè€è²æ®æž£ãåŸãããã®ãã®ãã¡ã¿ããŒã«ãã
åçµæ¶ããŠçœè²ç²æ«3.9ïœïŒ58ïŒ ïŒãåŸãã èç¹136ã138ãã§æ§é ãNMRã«ãã確èªããã (e) äŸç€ºã«ãã©ãŒNo.ïŒã®åæ (d)ã§åæããäžéäœïŒ€ã2.0ïœãé ¢é žãšãã«ã«
溶解åŸãæ°·å·ããŠæ¹æããäžãžå¡©åã¹ã«ããªã«
0.43ïœã®é ¢é žãšãã«æº¶æ¶²ã滎äžããã滎äžåŸã宀
æž©ã«ãã©ãïŒæéåå¿ããããåå¿æ··åç©ãæ°ŽæŽ
也ç¥åŸæ¿çž®ããŠæ®æž£ãã¢ã»ããããªã«ããåçµæ¶
ãããçœè²ç²æ«1.0ïœïŒ47ïŒ ïŒãåŸãã èç¹ã¯122ã126ãã§ãã€ã«ã·ãŠã¿ã€ã³ãã¹ãã
ãããã²ã³ååã®ååšã確èªããããæ§é ã
NMRã«ãã確èªããã æ¬çºæã®ã«ãã©ãŒã«ã¯ã油溶æ§ã®ãã®ãšã¢ã«ã«
ãªå¯æº¶æ§ã®ãã®ãå å«ãããããã®ãã¡æ²¹æº¶æ§ã®
ãã®ã¯ããããããªã€ã«ã»ãããã¯ãåã«ãã©ãŒ
ãšããŠé«æ²žç¹ææ©æº¶åªçã«æº¶è§£ããŠæ¬çºæã«ä¿ã
ã«ã©ãŒä¹³å€äžã«åæ£å«æãããããšãã§ããããŸ
ãã¢ã«ã«ãªå¯æº¶æ§ã§ãããã®ã¯ãã€ãã·ã€ãŒåæ£
æ³ã«ãã€ãŠæ¬çºæã«ä¿ãã«ã©ãŒä¹³å€äžã«åæ£å«æ
ããããããšãã§ãããã®åã«å±ãããã®ãšããŠ
ã¯ãäŸãã°åèšäŸç€ºã«ãã©ãŒãïŒãçãæããã
ãšãã§ããã æ¬çºæã®ã«ãã©ãŒã®ãã¡ãäŸãã°ãªã€ã«ããã
ã¯ãåã®ãã®ãã«ã©ãŒä¹³å€ã«å«æããããã«ã¯ã
åŸæ¥å ¬ç¥ã®æ¹æ³ã«åŸãã°ãããäŸãã°ããªã¯ã¬ãž
ã«ãã¹ããšãŒãããžããã«ã¹ã¿ã¬ãŒãçã®æ²žç¹
175â以äžã®é«æ²žç¹ææ©æº¶åªãŸãã¯é ¢é žããã«ã
ããããªã³é žããã«çã®äœæ²žç¹æº¶åªã®ããããå
ç¬ã«ãŸãã¯å¿ èŠã«å¿ããŠããããã®æ··å液ã«æ¬çº
æã®ã«ãã©ãŒãåç¬ã§ãŸãã¯äœµçšããŠæº¶è§£ãã
åŸãçé¢æŽ»æ§å€ãå«ããŒã©ãã³æ°Žæº¶æ¶²ãšæ··åãã
次ã«é«é床å転ãããµãŒãŸãã¯ã³ãã€ããã«ã§ä¹³
åããåŸãããã²ã³åéã«æ·»å ããŠæ¬çºæã«äœ¿çš
ããããã²ã³åéä¹³å€ã調æŽããããšãã§ããã ãŸãã«ãã©ãŒãçºè²çŸå液äžã«æ·»å ãããæè¬
å€åŒåã®ã«ãã©ãŒã®ãã®ã¯çºè²çŸå液çã«å¯ŸããŠ
æ·»å ãæãå©ç¹ãããããããã®ç¹æ§çãããçµ
æãšããŠæè¬å åŒåã«ãã©ãŒçã®ããã«åçæå
ææã®æå å±€äžã«æ¬çºæã®ã«ãã©ãŒãå«æããã
ãå Žåãæå å±€ã®èèåãã§ããåŸãããè²ç»å
ã®é®®é床çãåäžããæŽã«çºè²çŸåã«å¯ŸããŠæªã
çžäºäœçšã瀺ãããç¹ã«åå¿æ§ãããããã«è²æ±
æçãæ¹è¯ãããå©ç¹ãæããŠããããŸãæ¬çºæ
ã®ã«ãã©ãŒãçšããŠåŸãããè²çŽ ã¯åèšã®åŠãåª
ããè²åžåç¹æ§ãæããŠããã ãã®ãããªæ¬çºæã®ã«ãã©ãŒã¯ãæ¯äœæ§é ãšã¹
ããªãããªãåºãæãããã®ã«ã€ããŠã¯ãããã
ãšã®çµåããã«ããçš®ã ã®å¿çšæ§ããããããªã
ã¡ã«ãã©ãŒæ®åºããäŸãã°ã¹ã«ãã³é žåºãã«ã«ã
ã³é žåºçã®æ°Žæº¶æ§åºãå°å ¥ãããæ¡æ£æ§ãæãã
ãã®ã§ããå Žåããããã¯æ¬çºæã®ã¹ããªãããª
ãåºèªäœãæ¡æ£æ§ã§ãããã®ã®å Žåã«ã¯æ¡æ£æ§ã«
ãã©ãŒãšããŠã®å©çšãäŸãã°æè¬å€åŒã®åçæè¡
ã«çšãããããã®éã«ãã©ãŒã¯çºè²çŸå液äžã«å«
æããããŠçšããããšãã§ãããäŸãã°äŸç€ºã«ã
ã©ãŒ
ãïŒããæããããã
ãŸãæ¬çºæã®ã«ãã©ãŒããäŸãã°ã·ã¢ã³ã«ãã©
ãŒæ®åºãéæ¡æ£æ§ã§ãã¹ããªããã»ãªãåºãæ¡æ£
æ§ã§ãããã«ãã©ãŒãšããŠã¯éæ¡æ£æ§ã®ãããªå
ã®ã«ãã©ãŒã§ãããã®ã¯ãæ¡æ£è»¢åæ³ã«çšããã®
ã«é©ããŠãããæ¡æ£æ§ãååºã«ä»äžããããã«ã¯
äŸãã°äœååéã®åºãéžæããããšããã³ïŒãŸã
ã¯æ°Žæº¶æ§åºãäŸãã°åèšã®åŠãã¹ã«ãã³é žåºçã
å°å ¥ããããšçã®æ段ãçšããã°ããããŸãéæ¡
æ£æ§ãååºã«ä»äžããããã«ã¯ãé·éã®èèªæç
åæ°ŽçŽ æ®åºãå°å ¥ããããšããã³ïŒãŸãã¯æ¯èŒç
é«ååã®åºãéžæããããšçã®æ段ãçšããã°ã
ãã ãã®æ¡æ£è»¢åæ³ã«ã¯ãã·ã¢ã³ã«ãã©ãŒæ®åºãšçº
è²çŸåäž»è¬ãšã®åå¿ã«ããåŸãããã·ã¢ã³è²çŽ ã
å©çšããç»å圢ææ³ãšãçºè²çŸåæã«é¢è±ããã¹
ããªããã»ãªãåºéšåãå©çšããç»å圢ææ³ãšã
ããããæ¬çºæã«ä¿ãç»å圢ææ¹æ³ãé©çšããã
æ¹æ³ã¯åŸè ã®å Žåã§ãããããã«ã¹ããªãããªã
åºãã«ãã©ãŒã®æŽ»æ§ç¹ããé¢è±ããŠåŸãããåå
ç©ãæ¡æ£æ§ã§ããããšãå¿ èŠã§ããããããŠãã®
é¢è±ããååç©ãå©çšããå Žåã«ã¯è©²ååç©ã¯ç
è²ãããŠããããšãå¿ èŠã§ãã€ãŠãäŸãã°ã¢ãŸè²
çŽ çã®è²çŽ éšåãååç©äžã«å«ãããšãèŠæ±ãã
ãããã®è²çŽ éšåãšããŠã¯ã奜ãŸããã¯æ°Žæº¶æ§åº
ãæãããã®ã§ãããã¢ãŸè²çŽ ãã¢ãŸã¡ãã³è²
çŽ ãã€ã³ãã¢ããªã³è²çŽ ãã€ã³ãããšããŒã«è²
çŽ ãã¢ã³ã¹ã©ããã³è²çŽ çã代衚çãªãã®ãšããŠ
æããããããã®æ¡æ£è»¢åæ³ã«çšããã®ã«æãé©
ããæ¬çºæã®ã«ãã©ãŒãšããŠã¯ãäŸãã°äŸç€ºã«ã
ã©ãŒãïŒãçããããããã ãã®æ¡æ£è»¢åæ³ã¯ãåšç¥ã®åŠããæå ææãšå
åææãšã®çµã¿åãããçšããããæå ææã«å¯Ÿ
ããŠé²å ããã®ã¡ãå°ãªããšãçŸåæã«æå ææ
ãšååææãšãéãåãããååææã«ç»åã圢
æããããåçæè¡ã§ãããäŸãã°ã«ãã©ãŒãå«
æããããã²ã³åéæå ææãšãæ¯æäœäžã«äžåŒ
å±€ãäžéå±€çãä»ããŠèšããããååå±€ãæãã
ååææãšã®çµåãããçšããããã²ã³åéæå
ææã«é²å ããã®ã¡ãããã²ã³åéæå ææã®æ
å å±€ãšååææã®ååå±€ãšãå Žåã«ããä¿è·å±€ã
ä»ããŠéãåãããŠããã®ééã«çºè²çŸå液ã䟵
å ¥ããããŠçŸåãè¡ãªããæå å±€äžã«åœ¢æããè²
çŽ ãæ¡æ£ã«ãã€ãŠååå±€ã«è»¢åããããŠãæçµç
ã«ååææã«è²çŽ åã転åããåçæè¡ã§ããã
äžèšæ¡æ£è»¢åæ³ã«ã¯çš®ã ã®æ¹æ³ãããããããã
ã®å Žåã«ãæ¬çºæã®ã«ãã©ãŒã¯æå¹ã«çšããã
ãããããŠæ¬çºæã®ã«ãã©ãŒãã®ããã²ã³åéä¹³
å€äžã«æ·»å ããå Žåãéåžžããã²ã³åéïŒã¢ã«åœ
ãçŽ0.07ã0.7ã¢ã«ã奜ãŸããã¯0.1ã¢ã«ã0.4ã¢ã«
ã®ç¯å²ã§æ¬çºæã®ã«ãã©ãŒãæ·»å ãããã æ¬çºæã®ããã²ã³åéä¹³å€ã¯ãæ¬çºæã®ã«ãã©
ãŒãå«æããèµ€ææ§ä¹³å€ã§ãããããã²ã³åéã«
ã©ãŒåçæå ææã®æ¯æäœäžã«å¡åžä¹Ÿç¥ããããš
ã«ãããèµ€ææ§ä¹³å€å±€ã圢æããããšãã§ããã æ¬çºæã®ã«ãã©ãŒãå«æããããã²ã³åéä¹³å€
ã«çšããããããã²ã³åéãšããŠã¯ãèåéãå¡©
åéãæ²èåéãå¡©èåéãå¡©æ²èåéçã®éåžž
ã®ããã²ã³åéä¹³å€ã«äœ¿çšãããä»»æã®ãã®ãå
å«ãããã æ¬çºæã«çšããããã²ã³åéä¹³å€ãæ§æããã
ãã²ã³åéä¹³å€ã¯ãéåžžè¡ãªããã補æ³ãã¯ã
ããçš®ã ã®è£œæ³ãäŸãã°ç¹å ¬æ46â7772å·å ¬å ±ã«
èšèŒãããŠããåŠãæ¹æ³ããããã¯ç±³åœç¹èš±ç¬¬
2592250å·ã«èšèŒãããŠããåŠãæ¹æ³ãããªãã¡
溶解床ãèåéããã倧ãããå°ãªããšãäžéšã®
éå¡©ãããªãéå¡©ç²åã®ä¹³å€ã圢æãã次ãã§ã
ãã®ç²åã®å°ãªããšãäžéšãèåéå¡©ãŸãã¯æ²è
åéå¡©ã«å€æããçã®æè¬ã³ã³ããŒãžãšã³ä¹³å€ã®
補æ³ããããã¯0.1Ό以äžã®å¹³åç²åŸãæãã埮ç²
åç¶ããã²ã³åéãããªããªãããã³ä¹³å€ã®è£œæ³
çãããã補æ³ã«ãã€ãŠäœæããããšãã§ããã ããã«æ¬çºæã®ããã²ã³åéä¹³å€ã¯ãç¡«é»å¢æ
å€ãäŸãã°ã¢ãªã«ããªã«ã«ããããããªå°¿çŽ ãã·
ã¹ãã³çããŸã掻æ§ãããã¯äžæŽ»æ§ã®ã»ã¬ã³å¢æ
å€ããããŠéå å¢æå€ãäŸãã°ç¬¬ïŒã¹ãºå¡©ãããª
ã¢ãã³çã貎éå±å¢æå€ãäŸãã°éå¢æå€ãå ·äœ
çã«ã¯ã«ãªãŠã ãªãŒãªããªã·ã¢ããŒããã«ãªãŠã
ã¯ãããªãŒã¬ãŒããïŒâãªãŒãã¹ã«ããã³ãºãã¢
ãŸãŒã«ã¡ãã«ã¯ããªãçããããã¯äŸãã°ã«ãã
ãŠã ãããžãŠã ãã€ãªãžãŠã çã®æ°Žæº¶æ§å¡©ã®å¢æ
å€ãå ·äœçã«ã¯ã¢ã³ã¢ããŠã ã¯ãããã©ããŒãã
ã«ãªãŠã ã¯ãããã©ãããŒãããã³ãããªãŠã ã¯
ãããã©ãã€ãçã®åç¬ã§ãããã¯é©å®äœµçšã§å
åŠçã«å¢æãããããšãã§ããã ãŸãæ¬çºæã®ããã²ã³åéä¹³å€ã¯çš®ã ã®å ¬ç¥ã®
åççšæ·»å å€ãå«æããããããšãã§ããã æ¬çºæã«çšããããã²ã³åéã¯èµ€ææ§ä¹³å€ã«å¿
èŠãªæå æ³¢é·åã«æå æ§ãä»äžããããã«ãé©åœ
ãªå¢æè²çŽ ã®éžæã«ããåå å¢æããªããããã
ã®åå å¢æè²çŽ ãšããŠã¯çš®ã ã®ãã®ãçšãããã
ãããã¯ïŒçš®ãããã¯ïŒçš®ä»¥äžäœµçšããããšãã§
ããã æ¬çºæã«ãããŠæå©ã«äœ¿çšãããåå å¢æè²çŽ
ãšããŠã¯ãäŸãã°ç±³åœç¹èš±ç¬¬2269234å·ãå第
2270378å·ãå第2442710å·ãå第2454629å·ãå
第2776280å·ã®åæ现æžçã«èšèŒãããŠããåŠã
ã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ãã³è²çŽ ãŸãã¯è€åã·ã¢
ãã³è²çŽ ã代衚çãªãã®ãšããŠæããããšãã§ã
ãã æ¬çºæã«çšããããšãã§ããçºè²çŸå液ã¯å¥œãŸ
ããã¯ãè³éŠæ第ïŒçŽã¢ãã³ç³»çºè²çŸåäž»è¬ãäž»
æåãšãããã®ã§ããããã®çºè²çŸåäž»è¬ã®å ·äœ
äŸãšããŠã¯ïŒ°âããšãã¬ã³ãžã¢ãã³ç³»ã®ãã®ã代
è¡šçã§ãããäŸãã°ãžãšãã«ââããšãã¬ã³ãž
ã¢ãã³å¡©é žå¡©ããã³ã¢ãã¡ãã«ââããšãã¬ã³
ãžã¢ãã³å¡©é žå¡©ããžã¡ãã«ââããšãã¬ã³ãžã¢
ãã³å¡©é žå¡©ãïŒâã¢ããâïŒâãžãšãã«ã¢ããã
ã«ãšã³å¡©é žå¡©ãïŒâã¢ããâïŒâïŒïŒ®âãšãã«â
âããã·ã«ã¢ããïŒâãã«ãšã³ãïŒâã¢ããâ
ïŒâïŒïŒ®âãšãã«ââβâã¡ã¿ã³ã¹ã«ãã³ã¢ã
ããšãã«ïŒã¢ãããã«ãšã³ç¡«é žå¡©ãïŒâïŒïŒ®âãš
ãã«ââβâã¡ã¿ã³ã¹ã«ãã³ã¢ãããšãã«ã¢ã
ãïŒã¢ããªã³ãïŒâïŒïŒ®âãšãã«ââβâãã
ããã·ãšãã«ã¢ããïŒã¢ããªã³ãïŒâã¢ããâïŒ
âïŒïŒ®âãšãã«ââβâã¡ããã·ãšãã«ïŒã¢ã
ããã«ãšã³çãæããããã ãããŠããããã®çºè²çŸåäž»è¬ã¯åç¬ã§ããã
ã¯ïŒçš®ä»¥äžäœµçšããŠããŸãå¿ èŠã«ããçœé»çŸåäž»
è¬ãäŸãã°ãã€ããããã³çãšäœµçšããŠçšããã
ããæŽã«çºè²çŸå液ã¯äžè¬ã«ãã¢ã«ã«ãªå€ãäŸã
ã°æ°Žé žåãããªãŠã ãæ°Žé žåã¢ã³ã¢ããŠã ãçé ž
ãããªãŠã ãç¡«é žãããªãŠã ãäºç¡«é žãããªãŠã
çãå«ã¿ãæŽã«çš®ã ã®æ·»å å€ãäŸãã°ããã²ã³å
ã¢ã«ã«ãªéå±ãäŸãã°èåã«ãªãŠã ããããã¯çŸ
å調ç¯å€ãäŸãã°ã·ãã©ãžã³é žçãå«æããŠãã
ãã æ¬çºæã«çšããããçºè²çŸåæ³ã¯ãæå ææã
é²å åŸãéåžžã®å åŒçºè²çŸåæ¹æ³ã«ããçºè²çŸå
ããããã®ã§ãããããã®çºè²çŸå液ã¯ãäŸå€ç
ã«ãäŸãã°ããçš®ã®æ¡æ£è»¢åæ³çã«æŒããŠã¯åå
ææäžã«äºãå«æããããããšãè¡ãªããããã
ãã®ãããªæè¡ã«æŒããŠã¯çºè²çŸåäž»è¬ãšã¢ã«ã«
ãªå€ãšãå¥ã ã«ããååææäžã«ã¢ã«ã«ãªå€ã®ã¿
ãå«æãããããããããã¯çºè²çŸåäž»è¬ã®ã¿ã
å«æããããæ¹æ³ãçšããçŸåæã«ä»æ¹ã®ã¢ã«ã«
ãªå€ãããã¯çºè²çŸåäž»è¬ãå«æãã液ã§åŠçã
ãããšãã§ããã äžèšå åŒã«ã©ãŒçšçºè²çŸå液ãšããŠã¯ãäŸãã°
äžèšçµæã®ãã®ã代衚çãªãã®ãšããŠæããã
ãã ãçºè²çŸå液çµæã ãïŒâã¢ããâïŒâã¡ãã«ââãšãã«ââ
ïŒÎ²âã¡ã¿ã³ã¹ã«ãã³ã¢ãããšãã«ïŒâã¢ããªã³
ç¡«é žå¡© 5.0ïœ äºç¡«é žãããªãŠã ïŒç¡æ°Žç©ïŒ 2.0ïœ çé žãããªãŠã ïŒïŒæ°Žåç©ïŒ 50ïœ èåã«ãªãŠã 1.0ïœ æ°Žé žåã«ãªãŠã 0.55ïœ æ°Žãå ããŠïŒãšãããã æ¬çºæã«äœ¿çšããã«ã©ãŒä¹³å€äžã«å«ãŸããæ¬çº
æã®ã«ãã©ãŒã¯ããã®ãããªçºè²çŸå液ã§ããã²
ã³åéãçŸåããéã«çæããçºè²çŸåäž»è¬ã®é ž
åçæç©ãšåå¿ããã·ã¢ã³è²çŽ ã圢æããã ãã®ãããªçºè²çŸåã®åŠçåŸã¯ãéåžžã®åçåŠ
çãäŸãã°ææ©é žãå«ãåæ¢åŸãææ©é žãšãã€ã
ãŸãã¯ããªç¡«é žã¢ã³ã¢ã³çã®å®ççåãå«ãåæ¢
å®ç液ããã€ããŸãã¯ããªç¡«é žã¢ã³ã¢ã³çã®å®ç
æåãå«ãå®ç液ãã¢ããããªã«ã«ãã³é žã®ç¬¬ïŒ
éå¡©ãšããã²ã³åã¢ã«ã«ãªãšãäž»æåãšããæŒçœ
液ãã¢ããããªã«ã«ãã³é žã®ç¬¬ïŒéå¡©ãšããªç¡«é ž
ãããªãŠã ãŸãã¯ããªç¡«é žã¢ã³ã¢ããŠã çã®å®ç
æåãå«ãæŒçœå®ç液ããã®ä»å®å®å液çã®åŠç
液ã«ããåŠçããã³æ°ŽæŽä¹Ÿç¥çã®åŠçããéžæã
ããååŠçãé©å®çµã¿åãããŠè¡ãªãã°ããã 次ã«æ¬çºæãå åŒã«ã©ãŒãã¬æå ææã®åŠçã«
çšããããšãã§ããçºè²çŸååŠçå·¥çšã®ä»£è¡šçãª
å ·äœäŸã瀺ãã ãåŠçå·¥çšã åŠçå·¥çšïŒ33âïŒ âŠâŠåŠçæé çºè²çŸå âŠâŠïŒå15ç§ æŒ çœ âŠâŠïŒå30ç§ æ°Ž æŽ âŠâŠïŒå15ç§ å® ç âŠâŠïŒå30ç§ æ°Ž æŽ âŠâŠïŒå15ç§ å®å®å âŠâŠïŒå30ç§ åèšåŠçå·¥çšã«ãããŠäœ¿çšã§ããååŠç液ã®çµ
æã¯ãäŸãã°äžèšã®åŠãã§ããã ãçºè²çŸå液çµæã ïŒâã¢ããâïŒâã¡ãã«ââãšãã«ââ
ïŒÎ²âããããã·ãšãã«ïŒâã¢ããªã³ç¡«é žå¡©
4.8ïœ ç¡æ°Žäºç¡«é žãããªãŠã 0.14ïœ ããããã·ã¢ãã³ã1/2ç¡«é žå¡© 1.98ïœ ç¡« é ž 0.74mg ç¡æ°Žçé žã«ãªãŠã 28.85ïœ ç¡æ°Žçé žæ°ŽçŽ ã«ãªãŠã 3.46ïœ ç¡æ°Žäºç¡«é žã«ãªãŠã 5.10ïœ èåã«ãªãŠã 1.16ïœ å¡©åãããªãŠã 0.14ïœ ãããªãé ¢é žãïŒãããªãŠã å¡©ïŒïŒæ°Žå¡©ïŒ
1.20ïœ æ°Žé žåã«ãªãŠã 1.48ïœ æ°Žãå ããŠïŒãšããã ãæŒçœæ¶²çµæã ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žéã¢ã³ã¢ããŠã å¡©
100ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žïŒã¢ã³ã¢ããŠã å¡©
10ïœ èåã¢ã³ã¢ããŠã 150ïœ æ°·é ¢é ž 10ml æ°Žãå ããŠïŒãšããã¢ã³ã¢ãã¢æ°ŽãçšããŠPH
6.0ã«èª¿æŽããã ãå®ç液çµæã ããªç¡«é žã¢ã³ã¢ã㢠175.0ïœ ç¡æ°Žäºç¡«é žãããªãŠã 8.6ïœ ã¡ã¿äºç¡«é žãããªãŠã 2.3ïœ æ°Žãå ããŠïŒãšããé ¢é žãçšããŠPH6.0ã«èª¿
æŽããã ãå®å®å液çµæã ãã«ããªã³ïŒ37ïŒ æ°Žæº¶æ¶²ïŒ 1.5ml ã³ãããã¯ã¹ïŒå°è¥¿å åçå·¥æ¥æ ªåŒäŒç€Ÿè£œïŒ
7.5ml æ°Žãå ããŠïŒãšããã 次ã«æ¬çºæãå åŒã«ã©ãŒããžæå ææã®åŠçã«
çšããããšãã§ããçºè²çŸååŠçå·¥çšã®ä»£è¡šçãª
å ·äœäŸã瀺ãã ãåŠçå·¥çšã åŠçå·¥çšïŒ30âïŒ åŠçæé ãçºè²çŸå âŠâŠïŒå30ç§ æŒçœå®ç âŠâŠïŒå30ç§ æ°Ž æŽ âŠâŠïŒå å®å®å âŠâŠïŒåã äžèšåŠçå·¥çšã«ãããŠäœ¿çšã§ããååŠç液ã®çµ
æã¯ãäŸãã°äžèšã®åŠãã§ããã ãçºè²çŸå液çµæ (1)ã ãïŒâã¢ããâïŒâã¡ãã«ââãšãã«ââ
ïŒÎ²âã¡ã¿ã³ã¹ã«ãã³ã¢ãããšãã«ïŒâã¢ããªã³
ç¡«é žå¡© 5.0ïœ ãããµã¡ã¿ãªã³é žãããªãŠã 2.5ïœ ç¡æ°Žäºç¡«é žãããªãŠã 1.85ïœ èåãããªãŠã 1.4ïœ èåã«ãªãŠã 0.5ïœ ããŠç 39.1ïœ æ°Žãå ããŠïŒãšããæ°Žé žåãããªãŠã ãçšã
ãŠPH10.30ã«èª¿æŽããã ãçºè²çŸå液çµæ (2)ã ïŒâã¢ããâïŒâã¡ãã«ââãšãã«ââ
ïŒÎ²âã¡ã¿ã³ã¹ã«ãã³ã¢ãããšãã«ïŒâã¢ããªã³
ç¡«é žå¡© 5.0ïœ ãã³ãžã«ã¢ã«ã³ãŒã« 15.0ml ãããµã¡ã¿ãªã³é žãããªãŠã 2.5ïœ ç¡æ°Žäºç¡«é žãããªãŠã 1.85ïœ èåãããªãŠã 1.4ïœ èåã«ãªãŠã 0.5ïœ ããŠç 39.1ïœ æ°Žãå ããŠïŒãšããæ°Žé žåãããªãŠã ãçšã
ãŠPH10.30ã«èª¿æŽããã äžèšãçºè²çŸå液(1)ã¯ããã³ãžã«ã¢ã«ã³ãŒã«ã
æé€ããçºè²çŸå液çµæã§ãããçºè²çŸå液(2)ã¯
åŸæ¥ã®ãã³ãžã«ã¢ã«ã³ãŒã«ãæ·»å ããéåžžã®çºè²
çŸå液çµæã§ãããæ¬çºæãå åŒã«ã©ãŒããžæå
ææã®åŠçã«çšããå Žåã¯ãäžèšçºè²çŸå液(1)ã
ãã³(2)ã®ããããçšãåŸãããç¹ã«å ¬å®³é²æ¢ã®èŠ³
ç¹ããã¿ãŠäžèšçºè²çŸå液(1)ã®äœ¿çšãæãŸããæ¬
çºæã«ãããŠã¯ããã®æãŸããçºè²çŸå液(1)ã®äœ¿
çšã«ãããŠè¯å¥œãªåçç¹æ§ãåŸãããã ãæŒçœå®ç液çµæã ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žéã¢ã³ã¢ããŠã å¡©
61.0ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žïŒã¢ã³ã¢ããŠã å¡©
5.0ïœ ããªç¡«é žã¢ã³ã¢ããŠã 124.5ïœ ã¡ã¿éäºç¡«é žãããªãŠã 13.3ïœ ç¡æ°Žäºç¡«é žãããªãŠã 2.7ïœ æ°Žãå ããŠïŒãšããã ãå®å®å液çµæã æ°·é ¢é ž 20ml æ°Žãå ããŠïŒãšããé ¢é žãããªãŠã ãçšããŠ
PH3.5ã4.0ã«èª¿æŽããã ãŸããæ¬çºæã®ç»å圢ææ¹æ³ã¯ç¹å ¬æ49â
46419å·å ¬å ±ãç¹éæ51â7929å·ãç¹éæ51â
16023å·ãç¹éæ51â36136å·ã®åå ¬å ±çã«èšèŒã
ããæè¬ç»åè£åŒ·åŠçæ¹æ³ã«äœ¿çšãããæå ææ
ã«ãæå©ã«é©çšããããšãã§ããã 以äžãæ¬çºæãå®æœäŸã«ããå ·äœçã«èª¬æãã
ããããã«ããæ¬çºæã®å®æœã®æ æ§ãéå®ããã
ãã®ã§ã¯ãªãã å®æœäŸ (1) åŸèšç¬¬ïŒè¡šã«ç€ºããããªæ¬çºæã®ã«ãã©ãŒïŒå
èšå ·äœäŸã®çªå·ã§ç€ºããïŒããã³äžèšã®æ¯èŒã«ã
ã©ãŒããïŒããïŒãããçšããåã«ãã©ãŒ10ïœ
ããããããžããã«ãã¿ã¬ãŒã2.5mlãšé ¢é žãšã
ã«20mlãšã®æ··å液ã«å ãã60âã«å æž©ããŠå®å šã«
溶解ããããã®æº¶æ¶²ãã¢ã«ã«ããŒã«ïŒ¢ïŒã¢ã«ãã«
ããã¿ã¬ã³ã¹ã«ãããŒããããŠãã³ç€Ÿè£œïŒã®10ïŒ
氎溶液ïŒmlããã³ãŒã©ãã³ïŒïŒ 氎溶液200mlãšæ··
åããã³ãã€ããã«ãçšããŠä¹³åããããããã®
ã«ãã©ãŒã®åæ£æ¶²ãäœæããã次ãã§ããã®ã«ã
ã©ãŒåæ£æ¶²ã500ïœã®ãŒã©ãã³âå¡©èåéïŒ20ã¢
ã«ïŒ ã®èåéãå«ãïŒä¹³å€ã«æ·»å ããããªãšãã¬
ã³è¢«èŠçŽã«å¡åžã也ç¥ããŠãå®å®ãªå¡åžèãæã
ãïŒçš®ã®ããã²ã³åéã«ã©ãŒåçæå ææïŒè©Šæ
çªå·ãïŒãããïŒãïŒãåŸããåŸãããïŒçš®ã®ã
ãã²ã³åéã«ã©ãŒåçæå ææã®è©Šæããåžžæ³ã«
åŸã€ãŠãŠãšããžé²å ãè¡ãªã€ãåŸãå ·äœäŸãšã
ãŠãåèšããå åŒã«ã©ãŒããžçšçºè²çŸååŠçå·¥çš
ã«åŸã€ãŠãçºè²çŸåãè¡ãªããã·ã¢ã³çºè²ç»åã
åŸãããªããçºè²çŸå液ã¯ãã³ãžã«ã¢ã«ã³ãŒã«ã®
æ·»å ããããã®ãåèšçºè²çŸå液(2)ããšãæ·»å ã
ãªããã®ãåèšçºè²çŸå液(1)ããšã®ïŒçš®ã®çµæ液
ã«ã€ããŠè¡ãªã€ããåŸãããè©Šæã®ããããã«ã€
ããŠãåçç¹æ§ã枬å®ããããã®çµæã第ïŒè¡šã«
瀺ãã
ãŒæ®åºãéæ¡æ£æ§ã§ãã¹ããªããã»ãªãåºãæ¡æ£
æ§ã§ãããã«ãã©ãŒãšããŠã¯éæ¡æ£æ§ã®ãããªå
ã®ã«ãã©ãŒã§ãããã®ã¯ãæ¡æ£è»¢åæ³ã«çšããã®
ã«é©ããŠãããæ¡æ£æ§ãååºã«ä»äžããããã«ã¯
äŸãã°äœååéã®åºãéžæããããšããã³ïŒãŸã
ã¯æ°Žæº¶æ§åºãäŸãã°åèšã®åŠãã¹ã«ãã³é žåºçã
å°å ¥ããããšçã®æ段ãçšããã°ããããŸãéæ¡
æ£æ§ãååºã«ä»äžããããã«ã¯ãé·éã®èèªæç
åæ°ŽçŽ æ®åºãå°å ¥ããããšããã³ïŒãŸãã¯æ¯èŒç
é«ååã®åºãéžæããããšçã®æ段ãçšããã°ã
ãã ãã®æ¡æ£è»¢åæ³ã«ã¯ãã·ã¢ã³ã«ãã©ãŒæ®åºãšçº
è²çŸåäž»è¬ãšã®åå¿ã«ããåŸãããã·ã¢ã³è²çŽ ã
å©çšããç»å圢ææ³ãšãçºè²çŸåæã«é¢è±ããã¹
ããªããã»ãªãåºéšåãå©çšããç»å圢ææ³ãšã
ããããæ¬çºæã«ä¿ãç»å圢ææ¹æ³ãé©çšããã
æ¹æ³ã¯åŸè ã®å Žåã§ãããããã«ã¹ããªãããªã
åºãã«ãã©ãŒã®æŽ»æ§ç¹ããé¢è±ããŠåŸãããåå
ç©ãæ¡æ£æ§ã§ããããšãå¿ èŠã§ããããããŠãã®
é¢è±ããååç©ãå©çšããå Žåã«ã¯è©²ååç©ã¯ç
è²ãããŠããããšãå¿ èŠã§ãã€ãŠãäŸãã°ã¢ãŸè²
çŽ çã®è²çŽ éšåãååç©äžã«å«ãããšãèŠæ±ãã
ãããã®è²çŽ éšåãšããŠã¯ã奜ãŸããã¯æ°Žæº¶æ§åº
ãæãããã®ã§ãããã¢ãŸè²çŽ ãã¢ãŸã¡ãã³è²
çŽ ãã€ã³ãã¢ããªã³è²çŽ ãã€ã³ãããšããŒã«è²
çŽ ãã¢ã³ã¹ã©ããã³è²çŽ çã代衚çãªãã®ãšããŠ
æããããããã®æ¡æ£è»¢åæ³ã«çšããã®ã«æãé©
ããæ¬çºæã®ã«ãã©ãŒãšããŠã¯ãäŸãã°äŸç€ºã«ã
ã©ãŒãïŒãçããããããã ãã®æ¡æ£è»¢åæ³ã¯ãåšç¥ã®åŠããæå ææãšå
åææãšã®çµã¿åãããçšããããæå ææã«å¯Ÿ
ããŠé²å ããã®ã¡ãå°ãªããšãçŸåæã«æå ææ
ãšååææãšãéãåãããååææã«ç»åã圢
æããããåçæè¡ã§ãããäŸãã°ã«ãã©ãŒãå«
æããããã²ã³åéæå ææãšãæ¯æäœäžã«äžåŒ
å±€ãäžéå±€çãä»ããŠèšããããååå±€ãæãã
ååææãšã®çµåãããçšããããã²ã³åéæå
ææã«é²å ããã®ã¡ãããã²ã³åéæå ææã®æ
å å±€ãšååææã®ååå±€ãšãå Žåã«ããä¿è·å±€ã
ä»ããŠéãåãããŠããã®ééã«çºè²çŸå液ã䟵
å ¥ããããŠçŸåãè¡ãªããæå å±€äžã«åœ¢æããè²
çŽ ãæ¡æ£ã«ãã€ãŠååå±€ã«è»¢åããããŠãæçµç
ã«ååææã«è²çŽ åã転åããåçæè¡ã§ããã
äžèšæ¡æ£è»¢åæ³ã«ã¯çš®ã ã®æ¹æ³ãããããããã
ã®å Žåã«ãæ¬çºæã®ã«ãã©ãŒã¯æå¹ã«çšããã
ãããããŠæ¬çºæã®ã«ãã©ãŒãã®ããã²ã³åéä¹³
å€äžã«æ·»å ããå Žåãéåžžããã²ã³åéïŒã¢ã«åœ
ãçŽ0.07ã0.7ã¢ã«ã奜ãŸããã¯0.1ã¢ã«ã0.4ã¢ã«
ã®ç¯å²ã§æ¬çºæã®ã«ãã©ãŒãæ·»å ãããã æ¬çºæã®ããã²ã³åéä¹³å€ã¯ãæ¬çºæã®ã«ãã©
ãŒãå«æããèµ€ææ§ä¹³å€ã§ãããããã²ã³åéã«
ã©ãŒåçæå ææã®æ¯æäœäžã«å¡åžä¹Ÿç¥ããããš
ã«ãããèµ€ææ§ä¹³å€å±€ã圢æããããšãã§ããã æ¬çºæã®ã«ãã©ãŒãå«æããããã²ã³åéä¹³å€
ã«çšããããããã²ã³åéãšããŠã¯ãèåéãå¡©
åéãæ²èåéãå¡©èåéãå¡©æ²èåéçã®éåžž
ã®ããã²ã³åéä¹³å€ã«äœ¿çšãããä»»æã®ãã®ãå
å«ãããã æ¬çºæã«çšããããã²ã³åéä¹³å€ãæ§æããã
ãã²ã³åéä¹³å€ã¯ãéåžžè¡ãªããã補æ³ãã¯ã
ããçš®ã ã®è£œæ³ãäŸãã°ç¹å ¬æ46â7772å·å ¬å ±ã«
èšèŒãããŠããåŠãæ¹æ³ããããã¯ç±³åœç¹èš±ç¬¬
2592250å·ã«èšèŒãããŠããåŠãæ¹æ³ãããªãã¡
溶解床ãèåéããã倧ãããå°ãªããšãäžéšã®
éå¡©ãããªãéå¡©ç²åã®ä¹³å€ã圢æãã次ãã§ã
ãã®ç²åã®å°ãªããšãäžéšãèåéå¡©ãŸãã¯æ²è
åéå¡©ã«å€æããçã®æè¬ã³ã³ããŒãžãšã³ä¹³å€ã®
補æ³ããããã¯0.1Ό以äžã®å¹³åç²åŸãæãã埮ç²
åç¶ããã²ã³åéãããªããªãããã³ä¹³å€ã®è£œæ³
çãããã補æ³ã«ãã€ãŠäœæããããšãã§ããã ããã«æ¬çºæã®ããã²ã³åéä¹³å€ã¯ãç¡«é»å¢æ
å€ãäŸãã°ã¢ãªã«ããªã«ã«ããããããªå°¿çŽ ãã·
ã¹ãã³çããŸã掻æ§ãããã¯äžæŽ»æ§ã®ã»ã¬ã³å¢æ
å€ããããŠéå å¢æå€ãäŸãã°ç¬¬ïŒã¹ãºå¡©ãããª
ã¢ãã³çã貎éå±å¢æå€ãäŸãã°éå¢æå€ãå ·äœ
çã«ã¯ã«ãªãŠã ãªãŒãªããªã·ã¢ããŒããã«ãªãŠã
ã¯ãããªãŒã¬ãŒããïŒâãªãŒãã¹ã«ããã³ãºãã¢
ãŸãŒã«ã¡ãã«ã¯ããªãçããããã¯äŸãã°ã«ãã
ãŠã ãããžãŠã ãã€ãªãžãŠã çã®æ°Žæº¶æ§å¡©ã®å¢æ
å€ãå ·äœçã«ã¯ã¢ã³ã¢ããŠã ã¯ãããã©ããŒãã
ã«ãªãŠã ã¯ãããã©ãããŒãããã³ãããªãŠã ã¯
ãããã©ãã€ãçã®åç¬ã§ãããã¯é©å®äœµçšã§å
åŠçã«å¢æãããããšãã§ããã ãŸãæ¬çºæã®ããã²ã³åéä¹³å€ã¯çš®ã ã®å ¬ç¥ã®
åççšæ·»å å€ãå«æããããããšãã§ããã æ¬çºæã«çšããããã²ã³åéã¯èµ€ææ§ä¹³å€ã«å¿
èŠãªæå æ³¢é·åã«æå æ§ãä»äžããããã«ãé©åœ
ãªå¢æè²çŽ ã®éžæã«ããåå å¢æããªããããã
ã®åå å¢æè²çŽ ãšããŠã¯çš®ã ã®ãã®ãçšãããã
ãããã¯ïŒçš®ãããã¯ïŒçš®ä»¥äžäœµçšããããšãã§
ããã æ¬çºæã«ãããŠæå©ã«äœ¿çšãããåå å¢æè²çŽ
ãšããŠã¯ãäŸãã°ç±³åœç¹èš±ç¬¬2269234å·ãå第
2270378å·ãå第2442710å·ãå第2454629å·ãå
第2776280å·ã®åæ现æžçã«èšèŒãããŠããåŠã
ã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ãã³è²çŽ ãŸãã¯è€åã·ã¢
ãã³è²çŽ ã代衚çãªãã®ãšããŠæããããšãã§ã
ãã æ¬çºæã«çšããããšãã§ããçºè²çŸå液ã¯å¥œãŸ
ããã¯ãè³éŠæ第ïŒçŽã¢ãã³ç³»çºè²çŸåäž»è¬ãäž»
æåãšãããã®ã§ããããã®çºè²çŸåäž»è¬ã®å ·äœ
äŸãšããŠã¯ïŒ°âããšãã¬ã³ãžã¢ãã³ç³»ã®ãã®ã代
è¡šçã§ãããäŸãã°ãžãšãã«ââããšãã¬ã³ãž
ã¢ãã³å¡©é žå¡©ããã³ã¢ãã¡ãã«ââããšãã¬ã³
ãžã¢ãã³å¡©é žå¡©ããžã¡ãã«ââããšãã¬ã³ãžã¢
ãã³å¡©é žå¡©ãïŒâã¢ããâïŒâãžãšãã«ã¢ããã
ã«ãšã³å¡©é žå¡©ãïŒâã¢ããâïŒâïŒïŒ®âãšãã«â
âããã·ã«ã¢ããïŒâãã«ãšã³ãïŒâã¢ããâ
ïŒâïŒïŒ®âãšãã«ââβâã¡ã¿ã³ã¹ã«ãã³ã¢ã
ããšãã«ïŒã¢ãããã«ãšã³ç¡«é žå¡©ãïŒâïŒïŒ®âãš
ãã«ââβâã¡ã¿ã³ã¹ã«ãã³ã¢ãããšãã«ã¢ã
ãïŒã¢ããªã³ãïŒâïŒïŒ®âãšãã«ââβâãã
ããã·ãšãã«ã¢ããïŒã¢ããªã³ãïŒâã¢ããâïŒ
âïŒïŒ®âãšãã«ââβâã¡ããã·ãšãã«ïŒã¢ã
ããã«ãšã³çãæããããã ãããŠããããã®çºè²çŸåäž»è¬ã¯åç¬ã§ããã
ã¯ïŒçš®ä»¥äžäœµçšããŠããŸãå¿ èŠã«ããçœé»çŸåäž»
è¬ãäŸãã°ãã€ããããã³çãšäœµçšããŠçšããã
ããæŽã«çºè²çŸå液ã¯äžè¬ã«ãã¢ã«ã«ãªå€ãäŸã
ã°æ°Žé žåãããªãŠã ãæ°Žé žåã¢ã³ã¢ããŠã ãçé ž
ãããªãŠã ãç¡«é žãããªãŠã ãäºç¡«é žãããªãŠã
çãå«ã¿ãæŽã«çš®ã ã®æ·»å å€ãäŸãã°ããã²ã³å
ã¢ã«ã«ãªéå±ãäŸãã°èåã«ãªãŠã ããããã¯çŸ
å調ç¯å€ãäŸãã°ã·ãã©ãžã³é žçãå«æããŠãã
ãã æ¬çºæã«çšããããçºè²çŸåæ³ã¯ãæå ææã
é²å åŸãéåžžã®å åŒçºè²çŸåæ¹æ³ã«ããçºè²çŸå
ããããã®ã§ãããããã®çºè²çŸå液ã¯ãäŸå€ç
ã«ãäŸãã°ããçš®ã®æ¡æ£è»¢åæ³çã«æŒããŠã¯åå
ææäžã«äºãå«æããããããšãè¡ãªããããã
ãã®ãããªæè¡ã«æŒããŠã¯çºè²çŸåäž»è¬ãšã¢ã«ã«
ãªå€ãšãå¥ã ã«ããååææäžã«ã¢ã«ã«ãªå€ã®ã¿
ãå«æãããããããããã¯çºè²çŸåäž»è¬ã®ã¿ã
å«æããããæ¹æ³ãçšããçŸåæã«ä»æ¹ã®ã¢ã«ã«
ãªå€ãããã¯çºè²çŸåäž»è¬ãå«æãã液ã§åŠçã
ãããšãã§ããã äžèšå åŒã«ã©ãŒçšçºè²çŸå液ãšããŠã¯ãäŸãã°
äžèšçµæã®ãã®ã代衚çãªãã®ãšããŠæããã
ãã ãçºè²çŸå液çµæã ãïŒâã¢ããâïŒâã¡ãã«ââãšãã«ââ
ïŒÎ²âã¡ã¿ã³ã¹ã«ãã³ã¢ãããšãã«ïŒâã¢ããªã³
ç¡«é žå¡© 5.0ïœ äºç¡«é žãããªãŠã ïŒç¡æ°Žç©ïŒ 2.0ïœ çé žãããªãŠã ïŒïŒæ°Žåç©ïŒ 50ïœ èåã«ãªãŠã 1.0ïœ æ°Žé žåã«ãªãŠã 0.55ïœ æ°Žãå ããŠïŒãšãããã æ¬çºæã«äœ¿çšããã«ã©ãŒä¹³å€äžã«å«ãŸããæ¬çº
æã®ã«ãã©ãŒã¯ããã®ãããªçºè²çŸå液ã§ããã²
ã³åéãçŸåããéã«çæããçºè²çŸåäž»è¬ã®é ž
åçæç©ãšåå¿ããã·ã¢ã³è²çŽ ã圢æããã ãã®ãããªçºè²çŸåã®åŠçåŸã¯ãéåžžã®åçåŠ
çãäŸãã°ææ©é žãå«ãåæ¢åŸãææ©é žãšãã€ã
ãŸãã¯ããªç¡«é žã¢ã³ã¢ã³çã®å®ççåãå«ãåæ¢
å®ç液ããã€ããŸãã¯ããªç¡«é žã¢ã³ã¢ã³çã®å®ç
æåãå«ãå®ç液ãã¢ããããªã«ã«ãã³é žã®ç¬¬ïŒ
éå¡©ãšããã²ã³åã¢ã«ã«ãªãšãäž»æåãšããæŒçœ
液ãã¢ããããªã«ã«ãã³é žã®ç¬¬ïŒéå¡©ãšããªç¡«é ž
ãããªãŠã ãŸãã¯ããªç¡«é žã¢ã³ã¢ããŠã çã®å®ç
æåãå«ãæŒçœå®ç液ããã®ä»å®å®å液çã®åŠç
液ã«ããåŠçããã³æ°ŽæŽä¹Ÿç¥çã®åŠçããéžæã
ããååŠçãé©å®çµã¿åãããŠè¡ãªãã°ããã 次ã«æ¬çºæãå åŒã«ã©ãŒãã¬æå ææã®åŠçã«
çšããããšãã§ããçºè²çŸååŠçå·¥çšã®ä»£è¡šçãª
å ·äœäŸã瀺ãã ãåŠçå·¥çšã åŠçå·¥çšïŒ33âïŒ âŠâŠåŠçæé çºè²çŸå âŠâŠïŒå15ç§ æŒ çœ âŠâŠïŒå30ç§ æ°Ž æŽ âŠâŠïŒå15ç§ å® ç âŠâŠïŒå30ç§ æ°Ž æŽ âŠâŠïŒå15ç§ å®å®å âŠâŠïŒå30ç§ åèšåŠçå·¥çšã«ãããŠäœ¿çšã§ããååŠç液ã®çµ
æã¯ãäŸãã°äžèšã®åŠãã§ããã ãçºè²çŸå液çµæã ïŒâã¢ããâïŒâã¡ãã«ââãšãã«ââ
ïŒÎ²âããããã·ãšãã«ïŒâã¢ããªã³ç¡«é žå¡©
4.8ïœ ç¡æ°Žäºç¡«é žãããªãŠã 0.14ïœ ããããã·ã¢ãã³ã1/2ç¡«é žå¡© 1.98ïœ ç¡« é ž 0.74mg ç¡æ°Žçé žã«ãªãŠã 28.85ïœ ç¡æ°Žçé žæ°ŽçŽ ã«ãªãŠã 3.46ïœ ç¡æ°Žäºç¡«é žã«ãªãŠã 5.10ïœ èåã«ãªãŠã 1.16ïœ å¡©åãããªãŠã 0.14ïœ ãããªãé ¢é žãïŒãããªãŠã å¡©ïŒïŒæ°Žå¡©ïŒ
1.20ïœ æ°Žé žåã«ãªãŠã 1.48ïœ æ°Žãå ããŠïŒãšããã ãæŒçœæ¶²çµæã ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žéã¢ã³ã¢ããŠã å¡©
100ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žïŒã¢ã³ã¢ããŠã å¡©
10ïœ èåã¢ã³ã¢ããŠã 150ïœ æ°·é ¢é ž 10ml æ°Žãå ããŠïŒãšããã¢ã³ã¢ãã¢æ°ŽãçšããŠPH
6.0ã«èª¿æŽããã ãå®ç液çµæã ããªç¡«é žã¢ã³ã¢ã㢠175.0ïœ ç¡æ°Žäºç¡«é žãããªãŠã 8.6ïœ ã¡ã¿äºç¡«é žãããªãŠã 2.3ïœ æ°Žãå ããŠïŒãšããé ¢é žãçšããŠPH6.0ã«èª¿
æŽããã ãå®å®å液çµæã ãã«ããªã³ïŒ37ïŒ æ°Žæº¶æ¶²ïŒ 1.5ml ã³ãããã¯ã¹ïŒå°è¥¿å åçå·¥æ¥æ ªåŒäŒç€Ÿè£œïŒ
7.5ml æ°Žãå ããŠïŒãšããã 次ã«æ¬çºæãå åŒã«ã©ãŒããžæå ææã®åŠçã«
çšããããšãã§ããçºè²çŸååŠçå·¥çšã®ä»£è¡šçãª
å ·äœäŸã瀺ãã ãåŠçå·¥çšã åŠçå·¥çšïŒ30âïŒ åŠçæé ãçºè²çŸå âŠâŠïŒå30ç§ æŒçœå®ç âŠâŠïŒå30ç§ æ°Ž æŽ âŠâŠïŒå å®å®å âŠâŠïŒåã äžèšåŠçå·¥çšã«ãããŠäœ¿çšã§ããååŠç液ã®çµ
æã¯ãäŸãã°äžèšã®åŠãã§ããã ãçºè²çŸå液çµæ (1)ã ãïŒâã¢ããâïŒâã¡ãã«ââãšãã«ââ
ïŒÎ²âã¡ã¿ã³ã¹ã«ãã³ã¢ãããšãã«ïŒâã¢ããªã³
ç¡«é žå¡© 5.0ïœ ãããµã¡ã¿ãªã³é žãããªãŠã 2.5ïœ ç¡æ°Žäºç¡«é žãããªãŠã 1.85ïœ èåãããªãŠã 1.4ïœ èåã«ãªãŠã 0.5ïœ ããŠç 39.1ïœ æ°Žãå ããŠïŒãšããæ°Žé žåãããªãŠã ãçšã
ãŠPH10.30ã«èª¿æŽããã ãçºè²çŸå液çµæ (2)ã ïŒâã¢ããâïŒâã¡ãã«ââãšãã«ââ
ïŒÎ²âã¡ã¿ã³ã¹ã«ãã³ã¢ãããšãã«ïŒâã¢ããªã³
ç¡«é žå¡© 5.0ïœ ãã³ãžã«ã¢ã«ã³ãŒã« 15.0ml ãããµã¡ã¿ãªã³é žãããªãŠã 2.5ïœ ç¡æ°Žäºç¡«é žãããªãŠã 1.85ïœ èåãããªãŠã 1.4ïœ èåã«ãªãŠã 0.5ïœ ããŠç 39.1ïœ æ°Žãå ããŠïŒãšããæ°Žé žåãããªãŠã ãçšã
ãŠPH10.30ã«èª¿æŽããã äžèšãçºè²çŸå液(1)ã¯ããã³ãžã«ã¢ã«ã³ãŒã«ã
æé€ããçºè²çŸå液çµæã§ãããçºè²çŸå液(2)ã¯
åŸæ¥ã®ãã³ãžã«ã¢ã«ã³ãŒã«ãæ·»å ããéåžžã®çºè²
çŸå液çµæã§ãããæ¬çºæãå åŒã«ã©ãŒããžæå
ææã®åŠçã«çšããå Žåã¯ãäžèšçºè²çŸå液(1)ã
ãã³(2)ã®ããããçšãåŸãããç¹ã«å ¬å®³é²æ¢ã®èŠ³
ç¹ããã¿ãŠäžèšçºè²çŸå液(1)ã®äœ¿çšãæãŸããæ¬
çºæã«ãããŠã¯ããã®æãŸããçºè²çŸå液(1)ã®äœ¿
çšã«ãããŠè¯å¥œãªåçç¹æ§ãåŸãããã ãæŒçœå®ç液çµæã ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žéã¢ã³ã¢ããŠã å¡©
61.0ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žïŒã¢ã³ã¢ããŠã å¡©
5.0ïœ ããªç¡«é žã¢ã³ã¢ããŠã 124.5ïœ ã¡ã¿éäºç¡«é žãããªãŠã 13.3ïœ ç¡æ°Žäºç¡«é žãããªãŠã 2.7ïœ æ°Žãå ããŠïŒãšããã ãå®å®å液çµæã æ°·é ¢é ž 20ml æ°Žãå ããŠïŒãšããé ¢é žãããªãŠã ãçšããŠ
PH3.5ã4.0ã«èª¿æŽããã ãŸããæ¬çºæã®ç»å圢ææ¹æ³ã¯ç¹å ¬æ49â
46419å·å ¬å ±ãç¹éæ51â7929å·ãç¹éæ51â
16023å·ãç¹éæ51â36136å·ã®åå ¬å ±çã«èšèŒã
ããæè¬ç»åè£åŒ·åŠçæ¹æ³ã«äœ¿çšãããæå ææ
ã«ãæå©ã«é©çšããããšãã§ããã 以äžãæ¬çºæãå®æœäŸã«ããå ·äœçã«èª¬æãã
ããããã«ããæ¬çºæã®å®æœã®æ æ§ãéå®ããã
ãã®ã§ã¯ãªãã å®æœäŸ (1) åŸèšç¬¬ïŒè¡šã«ç€ºããããªæ¬çºæã®ã«ãã©ãŒïŒå
èšå ·äœäŸã®çªå·ã§ç€ºããïŒããã³äžèšã®æ¯èŒã«ã
ã©ãŒããïŒããïŒãããçšããåã«ãã©ãŒ10ïœ
ããããããžããã«ãã¿ã¬ãŒã2.5mlãšé ¢é žãšã
ã«20mlãšã®æ··å液ã«å ãã60âã«å æž©ããŠå®å šã«
溶解ããããã®æº¶æ¶²ãã¢ã«ã«ããŒã«ïŒ¢ïŒã¢ã«ãã«
ããã¿ã¬ã³ã¹ã«ãããŒããããŠãã³ç€Ÿè£œïŒã®10ïŒ
氎溶液ïŒmlããã³ãŒã©ãã³ïŒïŒ 氎溶液200mlãšæ··
åããã³ãã€ããã«ãçšããŠä¹³åããããããã®
ã«ãã©ãŒã®åæ£æ¶²ãäœæããã次ãã§ããã®ã«ã
ã©ãŒåæ£æ¶²ã500ïœã®ãŒã©ãã³âå¡©èåéïŒ20ã¢
ã«ïŒ ã®èåéãå«ãïŒä¹³å€ã«æ·»å ããããªãšãã¬
ã³è¢«èŠçŽã«å¡åžã也ç¥ããŠãå®å®ãªå¡åžèãæã
ãïŒçš®ã®ããã²ã³åéã«ã©ãŒåçæå ææïŒè©Šæ
çªå·ãïŒãããïŒãïŒãåŸããåŸãããïŒçš®ã®ã
ãã²ã³åéã«ã©ãŒåçæå ææã®è©Šæããåžžæ³ã«
åŸã€ãŠãŠãšããžé²å ãè¡ãªã€ãåŸãå ·äœäŸãšã
ãŠãåèšããå åŒã«ã©ãŒããžçšçºè²çŸååŠçå·¥çš
ã«åŸã€ãŠãçºè²çŸåãè¡ãªããã·ã¢ã³çºè²ç»åã
åŸãããªããçºè²çŸå液ã¯ãã³ãžã«ã¢ã«ã³ãŒã«ã®
æ·»å ããããã®ãåèšçºè²çŸå液(2)ããšãæ·»å ã
ãªããã®ãåèšçºè²çŸå液(1)ããšã®ïŒçš®ã®çµæ液
ã«ã€ããŠè¡ãªã€ããåŸãããè©Šæã®ããããã«ã€
ããŠãåçç¹æ§ã枬å®ããããã®çµæã第ïŒè¡šã«
瀺ãã
ãè¡šã
ãªããè¡šäžãæ床ã¯æ¯èŒã«ãã©ãŒãããçšã
ãè©Šæ(4)ã®ãã³ãžã«ã¢ã«ã³ãŒã«æ·»å ç³»ã«ãããæ
床ã100ãšãããšãã®çžå¯Ÿå€ã§ç€ºãããæ¯èŒã«ã
ã©ãŒããïŒããããã³ããã®æ§é ã¯äžèšã«ç€º
ãéãã§ããã æ¯èŒã«ãã©ãŒ ãã ïŒâãαâïŒïŒïŒïŒâãžâtertâã¢ãã«ããšãã
ã·ïŒãã¿ã³ã¢ãããâïŒïŒïŒâãžâã¯ããâïŒâ
ã¡ãã«ããšããŒã«ïŒåèšç±³åœç¹èš±ç¬¬2801171å·èš
èŒã®ãã®ïŒ æ¯èŒã«ãã©ãŒ ãã ïŒâãã³ãã¢ããâïŒâãαâïŒïŒâããã«ã¹ã«
ããã«ã¢ããããšããã·ïŒããã©ãã«ã³ã¢ããã
ããšããŒã«ïŒåèšç¹éæ53â109630å·å ¬å ±ã®ã
ã®ïŒ æ¯èŒã«ãã©ãŒ ãã ïŒâãαâïŒïŒïŒïŒâãžâïœâã¢ãã«ããšãã
ã·ïŒãã¿ã³ã¢ãããâïŒâã¯ããâïŒâã¡ãã«â
ïŒâïŒïŒâããšãã«âïŒâããã©ãŸãªã«ãªãã·ïŒ
ããšããŒã«ïŒåèšç±³åœç¹èš±ç¬¬3839044å·èšèŒã®ã
ã®ïŒ äžèšç¬¬ïŒè¡šããæãããªããã«ãæ¬çºæã®ç»å
圢ææ¹æ³ã«ããåŠçãããè©Šæã¯å¥œãŸããåå åž
åç¹æ§ãæãããŸããã³ãžã«ã¢ã«ã³ãŒã«ãæ·»å ã
ãªãçºè²çŸå液系ã«ãããŠãåŸãããè²ç»åã®æ
床ããã³æ倧æ¿åºŠãæ¯èŒã«ãã©ãŒããïŒããïŒ
ããã®ãããããã倧ããããšããããã å®æœäŸ (2) åèšå®æœäŸ(1)ãšåæ§ã«ããŠïŒçš®ã®ã·ã¢ã³çºè²ç»
å圢æçšæå ææã®è©ŠæïŒã12ãåŸãèå æ§ãè
ç±æ§ãè湿æ§ã®æ€èšãè¡ãªã€ããåŸãããçµæã
第ïŒè¡šã«ç€ºãã
ãè©Šæ(4)ã®ãã³ãžã«ã¢ã«ã³ãŒã«æ·»å ç³»ã«ãããæ
床ã100ãšãããšãã®çžå¯Ÿå€ã§ç€ºãããæ¯èŒã«ã
ã©ãŒããïŒããããã³ããã®æ§é ã¯äžèšã«ç€º
ãéãã§ããã æ¯èŒã«ãã©ãŒ ãã ïŒâãαâïŒïŒïŒïŒâãžâtertâã¢ãã«ããšãã
ã·ïŒãã¿ã³ã¢ãããâïŒïŒïŒâãžâã¯ããâïŒâ
ã¡ãã«ããšããŒã«ïŒåèšç±³åœç¹èš±ç¬¬2801171å·èš
èŒã®ãã®ïŒ æ¯èŒã«ãã©ãŒ ãã ïŒâãã³ãã¢ããâïŒâãαâïŒïŒâããã«ã¹ã«
ããã«ã¢ããããšããã·ïŒããã©ãã«ã³ã¢ããã
ããšããŒã«ïŒåèšç¹éæ53â109630å·å ¬å ±ã®ã
ã®ïŒ æ¯èŒã«ãã©ãŒ ãã ïŒâãαâïŒïŒïŒïŒâãžâïœâã¢ãã«ããšãã
ã·ïŒãã¿ã³ã¢ãããâïŒâã¯ããâïŒâã¡ãã«â
ïŒâïŒïŒâããšãã«âïŒâããã©ãŸãªã«ãªãã·ïŒ
ããšããŒã«ïŒåèšç±³åœç¹èš±ç¬¬3839044å·èšèŒã®ã
ã®ïŒ äžèšç¬¬ïŒè¡šããæãããªããã«ãæ¬çºæã®ç»å
圢ææ¹æ³ã«ããåŠçãããè©Šæã¯å¥œãŸããåå åž
åç¹æ§ãæãããŸããã³ãžã«ã¢ã«ã³ãŒã«ãæ·»å ã
ãªãçºè²çŸå液系ã«ãããŠãåŸãããè²ç»åã®æ
床ããã³æ倧æ¿åºŠãæ¯èŒã«ãã©ãŒããïŒããïŒ
ããã®ãããããã倧ããããšããããã å®æœäŸ (2) åèšå®æœäŸ(1)ãšåæ§ã«ããŠïŒçš®ã®ã·ã¢ã³çºè²ç»
å圢æçšæå ææã®è©ŠæïŒã12ãåŸãèå æ§ãè
ç±æ§ãè湿æ§ã®æ€èšãè¡ãªã€ããåŸãããçµæã
第ïŒè¡šã«ç€ºãã
ãè¡šã
ãªããè¡šäžèå
æ§ã¯ãåŸãããåç»åããã»ã
ã³ããšãŒãã¡ãŒã¿ãŒã§200æéæé²åŸã®æ®çæ¿åºŠ
ããæé²åã®æ¿åºŠã100ãšããŠè¡šãããããŸãè
湿æ§ã¯60âãçžå¯Ÿæ¹¿åºŠ80ïŒ ã®æ¡ä»¶ã§ïŒé±éä¿ååŸ
ã®æ®çæ¿åºŠããè©Šéšåã®æ¿åºŠã100ãšããŠè¡šãã
ããããã«èç±æ§ã¯ã77âã®æ¡ä»¶äžïŒé±éä¿ååŸ
ã®æ®çæ¿åºŠããè©Šéšåã®æ¿åºŠã100ãšããŠè¡šãã
ãã 第ïŒè¡šããæãããªåŠããæ¯èŒã«ãã©ãŒãã
ããã³ããã¯èå æ§ã«ãããŠåªããæ§èœãæã
ãŠããããèç±æ§ã«åé¡ç¹ãæ®ããŠããããŸãæ¯
èŒã«ãã©ãŒããã«ã€ããŠã¯æ¯èŒã«ãã©ãŒãã
ããã³ããã«å¯Ÿãèç±æ§ã«æ¹è¯ãå ããããã«
ãã©ãŒã§ããããèå æ§ã«åé¡ç¹ãæ®ããŠããã äžæ¹ãæ¬çºæã«ä¿ãäŸç€ºã«ãã©ãŒ(1)ïŒïŒ14ïŒïŒ
ïŒ31ïŒã¯ãäžèšæ¯èŒã«ãã©ãŒãããšåçã®èç±
æ§ãæããèå æ§ã®ç¹ã§æ¹è¯ã®å¹æãèªããã
ãã å®æœäŸ (3) åèšæ¬çºæã®ã«ãã©ãŒã§ããäŸç€ºã«ãã©ãŒ(10)ãŸ
ãã¯åèšæ¯èŒã«ãã©ãŒãã10ïœããžããã«ãã¿
ã¬ãŒã25mlãšé ¢é žãšãã«20mlãšã®æ··å液ã«å ã
ãŠã60âã«å æž©ããŠå®å šã«æº¶è§£ããããã®æº¶æ¶²ã
ã¢ã«ã«ããŒã«ïŒ¢ã®10ïŒ æ°Žæº¶æ¶²ïŒmlããã³ãŒã©ãã³
ïŒïŒ 氎溶液200mlãšæ··åããã³ãã€ããã«ãçšã
ãŠä¹³åããŠã«ãã©ãŒã®åæ£æ¶²ãäœæããã次ã
ã§ããã®åæ£æ¶²ã500ïœã®ãã¬çšé«æ床ãŒã©ãã³
æ²èåéïŒæ²åé6.0ã¢ã«ïŒ å«æïŒä¹³å€ã«æ·»å ãã
ã»ã«ããŒã¹ã¢ã»ããŒããã€ã«ã ããŒã¹äžã«å¡åžã
也ç¥ããŠãå®å®ãªå¡åžèãæããããã²ã³åéå
çæå ææã®è©Šæ13ïŒ14ãåŸãããã®ããã²ã³å
éåçæå ææãå®æœäŸ(1)ãšåæ§ã®æ¹æ³ã§é²å
ããåèšããå åŒã«ã©ãŒãã¬çšçºè²çŸåå·¥çšã«åŸ
ã€ãŠçºè²çŸåãè¡ãªããã·ã¢ã³çºè²ç»åãåŸãã åŸãããã·ã¢ã³çºè²ç»åã«ã€ããŠåçç¹æ§ã枬
å®ããããã®çµæã第ïŒè¡šã«ç€ºãã
ã³ããšãŒãã¡ãŒã¿ãŒã§200æéæé²åŸã®æ®çæ¿åºŠ
ããæé²åã®æ¿åºŠã100ãšããŠè¡šãããããŸãè
湿æ§ã¯60âãçžå¯Ÿæ¹¿åºŠ80ïŒ ã®æ¡ä»¶ã§ïŒé±éä¿ååŸ
ã®æ®çæ¿åºŠããè©Šéšåã®æ¿åºŠã100ãšããŠè¡šãã
ããããã«èç±æ§ã¯ã77âã®æ¡ä»¶äžïŒé±éä¿ååŸ
ã®æ®çæ¿åºŠããè©Šéšåã®æ¿åºŠã100ãšããŠè¡šãã
ãã 第ïŒè¡šããæãããªåŠããæ¯èŒã«ãã©ãŒãã
ããã³ããã¯èå æ§ã«ãããŠåªããæ§èœãæã
ãŠããããèç±æ§ã«åé¡ç¹ãæ®ããŠããããŸãæ¯
èŒã«ãã©ãŒããã«ã€ããŠã¯æ¯èŒã«ãã©ãŒãã
ããã³ããã«å¯Ÿãèç±æ§ã«æ¹è¯ãå ããããã«
ãã©ãŒã§ããããèå æ§ã«åé¡ç¹ãæ®ããŠããã äžæ¹ãæ¬çºæã«ä¿ãäŸç€ºã«ãã©ãŒ(1)ïŒïŒ14ïŒïŒ
ïŒ31ïŒã¯ãäžèšæ¯èŒã«ãã©ãŒãããšåçã®èç±
æ§ãæããèå æ§ã®ç¹ã§æ¹è¯ã®å¹æãèªããã
ãã å®æœäŸ (3) åèšæ¬çºæã®ã«ãã©ãŒã§ããäŸç€ºã«ãã©ãŒ(10)ãŸ
ãã¯åèšæ¯èŒã«ãã©ãŒãã10ïœããžããã«ãã¿
ã¬ãŒã25mlãšé ¢é žãšãã«20mlãšã®æ··å液ã«å ã
ãŠã60âã«å æž©ããŠå®å šã«æº¶è§£ããããã®æº¶æ¶²ã
ã¢ã«ã«ããŒã«ïŒ¢ã®10ïŒ æ°Žæº¶æ¶²ïŒmlããã³ãŒã©ãã³
ïŒïŒ 氎溶液200mlãšæ··åããã³ãã€ããã«ãçšã
ãŠä¹³åããŠã«ãã©ãŒã®åæ£æ¶²ãäœæããã次ã
ã§ããã®åæ£æ¶²ã500ïœã®ãã¬çšé«æ床ãŒã©ãã³
æ²èåéïŒæ²åé6.0ã¢ã«ïŒ å«æïŒä¹³å€ã«æ·»å ãã
ã»ã«ããŒã¹ã¢ã»ããŒããã€ã«ã ããŒã¹äžã«å¡åžã
也ç¥ããŠãå®å®ãªå¡åžèãæããããã²ã³åéå
çæå ææã®è©Šæ13ïŒ14ãåŸãããã®ããã²ã³å
éåçæå ææãå®æœäŸ(1)ãšåæ§ã®æ¹æ³ã§é²å
ããåèšããå åŒã«ã©ãŒãã¬çšçºè²çŸåå·¥çšã«åŸ
ã€ãŠçºè²çŸåãè¡ãªããã·ã¢ã³çºè²ç»åãåŸãã åŸãããã·ã¢ã³çºè²ç»åã«ã€ããŠåçç¹æ§ã枬
å®ããããã®çµæã第ïŒè¡šã«ç€ºãã
ïŒïŒ®âãžãšãã«âïŒâã¡ãã«ââããšãã¬
ã³ãžã¢ãã³ 2.0ïœ ç¡æ°Žäºç¡«é žãããªãŠã 2.0ïœ çé žãããªãŠã ïŒïŒæ°Žåç©ïŒ 20.0ïœ èåã«ãªãŠã 1.0ïœ äŸç€ºã«ãã©ãŒ(9) 2.0ïœ æ°Žã§ ïŒãšããã é«æ床æ²èåéä¹³å€ãäžåŒãããããªãšãã¬ã³
ãã¬ãã¿ã¬ãŒããã€ã«ã äžã«å¡åžããŠåŸãããè©Š
æã«ãéåžžã®æ¹æ³ã«ããé²å ãäžããåŸåèšå€åŒ
çºè²çŸå液24âã§30åéçŸåããã çŸååŸã¯åžžæ³ã«ãããïŒåéæ°ŽæŽãïŒåéæŒ
çœãïŒåéæ°ŽæŽãïŒåéå®çã30åéæ°ŽæŽã也ç¥
ãšååŠçãé 次è¡ãªã€ããšãããåžå極倧670nm
ã®åå åžåç¹æ§ã®åªãããã€ä»ã®åçç¹æ§ãåªã
ãã·ã¢ã³ç»åãåŸãããã
ã³ãžã¢ãã³ 2.0ïœ ç¡æ°Žäºç¡«é žãããªãŠã 2.0ïœ çé žãããªãŠã ïŒïŒæ°Žåç©ïŒ 20.0ïœ èåã«ãªãŠã 1.0ïœ äŸç€ºã«ãã©ãŒ(9) 2.0ïœ æ°Žã§ ïŒãšããã é«æ床æ²èåéä¹³å€ãäžåŒãããããªãšãã¬ã³
ãã¬ãã¿ã¬ãŒããã€ã«ã äžã«å¡åžããŠåŸãããè©Š
æã«ãéåžžã®æ¹æ³ã«ããé²å ãäžããåŸåèšå€åŒ
çºè²çŸå液24âã§30åéçŸåããã çŸååŸã¯åžžæ³ã«ãããïŒåéæ°ŽæŽãïŒåéæŒ
çœãïŒåéæ°ŽæŽãïŒåéå®çã30åéæ°ŽæŽã也ç¥
ãšååŠçãé 次è¡ãªã€ããšãããåžå極倧670nm
ã®åå åžåç¹æ§ã®åªãããã€ä»ã®åçç¹æ§ãåªã
ãã·ã¢ã³ç»åãåŸãããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ ããã²ã³åéã«ã©ãŒåçæå ææãïŒïŒïŒâ
ãžã¢ã·ã«ã¢ããããšããŒã«ã·ã¢ã³ã«ãã©ãŒã®ååš
äžã«ç»ååŠçããŠã·ã¢ã³è²çŽ ç»åã圢æãããæ¹
æ³ã«ãããŠã該ã·ã¢ã³ã«ãã©ãŒãäžèšäžè¬åŒ
ãããããã§è¡šããããã·ã¢ã³ã«ãã©ãŒã§ãã
ããšãç¹åŸŽãšããã·ã¢ã³è²ç»å圢ææ¹æ³ã äžè¬åŒãã äžè¬åŒãã ïŒåŒäžãã¯æ°ŽçŽ ååãŸãã¯ïŒä¹è³20ã®ççŽ æ°
ãæããã¢ã«ãã«åºããR1ã¯çœ®æã¢ã«ãã«ã¹ã«
ããã«ã¢ããåºãŸãã¯çœ®æã¢ã«ãã«ã¢ããã¹ã«ã
ãã«åºããR2ã¯ã¢ã«ãã«åºãã¢ãªãŒã«åºãŸãã¯
ãããç°åºããR3ã¯æ°ŽçŽ ååãŸãã¯ããã²ã³å
åããã¯ããšãã¬ã³åºããããã¬ã³åºãŸãã¯ã¢
ã«ãã¬ã³åºããã¯æ°ŽçŽ ååãŸãã¯ã«ãããªã³ã°
é¢è±åºããïœã¯ïŒãŸãã¯ïŒã®æŽæ°ãè¡šããã ãã ãäžè¬åŒããã«ãããŠïœïŒïŒã®æãã
ããšãã¬ã³åºã§ããå Žåã該ããšãã¬ã³åºã«çµå
ããã¢ã·ã«ã¢ããåºã®çµåäœçœ®ãåºæºãšããŠè©²ã
ãšãã¬ã³åºäžã®ãªã«ãäœãŸãã¯ã¡ã¿äœã«çœ®æã¢ã«
ãã«ã¹ã«ããã«ã¢ããåºãçµåããããšã¯ãªãã
ãŸãïœïŒïŒã®æããããšãã¬ã³åºã§ããå Žåã
該ããšãã¬ã³åºã«çµåããã¢ã·ã«ã¢ããåºã®çµå
äœçœ®ãåºæºãšããŠè©²ããšãã«åºäžã®ãªã«ãäœã«çœ®
æã¢ã«ãã«ã¹ã«ããã«ã¢ããåºãçµåããããšã¯
ãªãããŸãR2ãããšãã¬ã³åºã®å Žåã該ããšã
ã«åºã«çµåããã¢ã·ã«ã¢ããåºã®çµåäœçœ®ãåºæº
ãšããŠè©²ããšãã«åºäžã®ãªã«ãäœã«ã¹ã«ãã³ã¢ã
ãåºãçµåããããšã¯ãªãã ãŸãäžè¬åŒããã«ãããŠïœïŒïŒã®æããã
ãšãã¬ã³åºã§ããå Žåã該ããšãã¬ã³åºã«çµåã
ãã¢ã·ã«ã¢ããåºã®çµåäœçœ®ãåºæºãšããŠè©²ããš
ãã¬ã³åºäžã®ãªã«ãäœã«çœ®æã¢ã«ãã«ã¹ã«ããã«
ã¢ããåºãçµåããããšã¯ãªãããŸãR2ã眮æ
åºãæããã¢ã«ãã«åºã§ãã€ãŠè©²çœ®æåºãããšã
ãã·åºã§ããå Žåã該ããšããã·åºã®é žçŽ ååã®
çµåäœçœ®ãåºæºãšããŠè©²ããšããã·åºäžã®ãªã«ã
äœãŸãã¯ã¡ã¿äœã«ã¹ã«ãã³ã¢ããåºãçµåããã
ãšã¯ãªãããŸãR2ã眮æåºãæããããšãã«åº
ã®å Žåã該ããšãã«åºã«çµåããã¢ã·ã«ã¢ããåº
ã®çµåäœçœ®ãåºæºãšããŠè©²ããšãã«åºã®ãªã«ãäœ
ã«ã¹ã«ãã³ã¢ããåºãçµåããããšã¯ãªããïŒ
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP230580A JPS5699341A (en) | 1980-01-11 | 1980-01-11 | Forming method for cyan dye image |
| DE19813100469 DE3100469A1 (de) | 1980-01-11 | 1981-01-09 | "verfahren zur erzeugung eines blaugruenen farbstoffbildes" |
| US06/223,696 US4362810A (en) | 1980-01-11 | 1981-01-09 | Method for forming a cyan dye image |
| GB8100598A GB2069999B (en) | 1980-01-11 | 1981-01-09 | Method for forming a cyan dye image using new 2,5-diacylaminophenol cyan couplers |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP230580A JPS5699341A (en) | 1980-01-11 | 1980-01-11 | Forming method for cyan dye image |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5699341A JPS5699341A (en) | 1981-08-10 |
| JPS6335017B2 true JPS6335017B2 (ja) | 1988-07-13 |
Family
ID=11525639
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP230580A Granted JPS5699341A (en) | 1980-01-11 | 1980-01-11 | Forming method for cyan dye image |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4362810A (ja) |
| JP (1) | JPS5699341A (ja) |
| DE (1) | DE3100469A1 (ja) |
| GB (1) | GB2069999B (ja) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57173835A (en) * | 1981-04-20 | 1982-10-26 | Fuji Photo Film Co Ltd | Silver halide color photosensitive material |
| JPS58106539A (ja) * | 1981-12-18 | 1983-06-24 | Konishiroku Photo Ind Co Ltd | ã«ã©âåçç»åã®åœ¢ææ¹æ³ |
| JPS59105645A (ja) * | 1982-12-09 | 1984-06-19 | Konishiroku Photo Ind Co Ltd | ããã²ã³åéåçæå ææ |
| JPS59166956A (ja) * | 1983-03-14 | 1984-09-20 | Fuji Photo Film Co Ltd | ããã²ã³åéã«ã©âåçæå ææ |
| JPS59177557A (ja) * | 1983-03-28 | 1984-10-08 | Fuji Photo Film Co Ltd | ããã²ã³åéã«ã©âåçæå ææ |
| JPS6055340A (ja) * | 1983-09-06 | 1985-03-30 | Fuji Photo Film Co Ltd | ããã²ã³åéã«ã©âæå ææ |
| JPS60242457A (ja) * | 1984-04-19 | 1985-12-02 | Konishiroku Photo Ind Co Ltd | ããã²ã³åéåçæå ææ |
| JPS6172244A (ja) * | 1984-09-17 | 1986-04-14 | Fuji Photo Film Co Ltd | ããã²ã³åéã«ã©âåçæå ææ |
| EP0269766B1 (en) * | 1986-12-05 | 1991-02-06 | Agfa-Gevaert N.V. | Colour photographic element |
| GB9828147D0 (en) | 1998-12-22 | 1999-02-17 | Eastman Kodak Co | Photographic couplers having improved image dye light stability |
| US6197491B1 (en) * | 1999-12-28 | 2001-03-06 | Eastman Kodak Company | Photographic element, compound, and process |
| US6197490B1 (en) * | 1999-12-28 | 2001-03-06 | Eastman Kodak Company | Photographic element, compound, and process |
| US6518000B1 (en) * | 2002-01-30 | 2003-02-11 | Eastman Kodak Company | Infrared couplers for incorporating and recovering metadata |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE543745A (ja) * | 1954-12-20 | |||
| US3839044A (en) * | 1971-03-25 | 1974-10-01 | Eastman Kodak Co | Silver halide emulsions containing 2-equivalent color couplers |
| US4124396A (en) * | 1977-03-03 | 1978-11-07 | Eastman Kodak Company | 2,5-Dicarbonylaminophenol dye-forming couplers |
| JPS5938577B2 (ja) * | 1979-05-07 | 1984-09-18 | ã³ãã«æ ªåŒäŒç€Ÿ | ã·ã¢ã³è²çŽ ç»åã®åœ¢ææ¹æ³ |
-
1980
- 1980-01-11 JP JP230580A patent/JPS5699341A/ja active Granted
-
1981
- 1981-01-09 US US06/223,696 patent/US4362810A/en not_active Expired - Fee Related
- 1981-01-09 DE DE19813100469 patent/DE3100469A1/de not_active Withdrawn
- 1981-01-09 GB GB8100598A patent/GB2069999B/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB2069999B (en) | 1983-11-30 |
| US4362810A (en) | 1982-12-07 |
| GB2069999A (en) | 1981-09-03 |
| DE3100469A1 (de) | 1981-12-03 |
| JPS5699341A (en) | 1981-08-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS5938577B2 (ja) | ã·ã¢ã³è²çŽ ç»åã®åœ¢ææ¹æ³ | |
| JPS5938576B2 (ja) | ã·ã¢ã³è²çŽ ç»åã®åœ¢ææ¹æ³ | |
| JPH0349092B2 (ja) | ||
| JPH0374375B2 (ja) | ||
| JPH036492B2 (ja) | ||
| JPH0219940B2 (ja) | ||
| JPS6333138B2 (ja) | ||
| US4362810A (en) | Method for forming a cyan dye image | |
| JPH0257295B2 (ja) | ||
| JPS6336656B2 (ja) | ||
| JPH0347489B2 (ja) | ||
| GB2098600A (en) | Sulphonamido-containing 2,5- diacylaminophenol cyan couplers for cyan dye imaging | |
| JPH0234372B2 (ja) | Harogenkaginkaraashashinkankozairyo | |
| US4254213A (en) | Process for forming black dye images | |
| JPH01206338A (ja) | ããã²ã³åéã«ã©ãŒåçæå ææ | |
| JPH0135336B2 (ja) | ||
| JPS6310817B2 (ja) | ||
| JPH01253742A (ja) | ããã²ã³åéã«ã©ãŒåçæå ææ | |
| JPH0243167B2 (ja) | ||
| JPS6310814B2 (ja) | ||
| JPS6329733B2 (ja) | ||
| JPH0135338B2 (ja) | ||
| JPS6258497B2 (ja) | ||
| JPH0450579B2 (ja) | ||
| JPS6310815B2 (ja) |